TW201138933A - Adsorbent material fluidized cyclotron cleaner - Google Patents

Adsorbent material fluidized cyclotron cleaner Download PDF

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Publication number
TW201138933A
TW201138933A TW99115416A TW99115416A TW201138933A TW 201138933 A TW201138933 A TW 201138933A TW 99115416 A TW99115416 A TW 99115416A TW 99115416 A TW99115416 A TW 99115416A TW 201138933 A TW201138933 A TW 201138933A
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Taiwan
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rotary
adsorbent
fluidized
type
revolving body
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TW99115416A
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Chinese (zh)
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TWI487563B (en
Inventor
shao-zu Xie
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Cherng Jye Air Cond Co Ltd
shao-zu Xie
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Abstract

The present invention relates to an adsorbent material fluidized cyclotron cleaner, which includes a cyclotron body with a plurality of housing chambers filled with absorbent material; a reducer (geared motor) for driving the cyclotron body; and an adsorption material filling unit, provided with an effluent pipe and a feed pipe correspondingly to the cyclotron body so as to enable the housing chambers of the cyclotron body to discharge adsorbent material from the effluent pipe and send the adsorbent material into the feed pipe. In this way, the problem of limited purification capacity in the prior art is solved, and cleaning ability can be significantly improved without heat accumulation problem.

Description

201138933 六、發明說明: 【發明所屬之技術領域】 本發明係有關一種吸附材流體化迴旋式淨化器,尤指 一種將一迴旋體分隔成複數個用於充填吸附材之容置室, 並把吸附材流體化輸送到外部進行脫附程序之設計者。 【先前技術】 按’生活和生産中廣泛應用的有機溶劑極易揮發成氣 體,故又名揮發性有機物(v〇latile 0rganic c〇mp〇unds, VOCs),但因多數v〇Cs對人體有一定之毒性,必須加以焚 化或回收,而在進行焚化或回收程序之前,通常會利用淨 化器先將VOCs吸附淨化,再脫附進行後續之焚化或回收處 理程序,其中,轉輪型或轉環型之迴旋式淨化器為常見之 淨化器,而習知如第一圖所示之轉輪型迴旋式淨化器(1〇) 與如第二圖所示之轉環型迴旋式淨化器(2〇),其結構型態 係於具有氣流通道之固體基材塗佈一層吸附材粉末所構 成,固體基材由陶瓷、玻璃或活性碳纖維紙所燒結成,吸 附材種類乃視欲處理氣體之成份而有所不同,一般可採用 活性碳或沸石;於是,習知轉輪型或轉環型迴旋式淨化器 乃因減速機(Geared motor,30)之帶動而轉動(1〜10RPH ; 大部份為2〜6RPH),轉輪(或轉環)位於吸附區⑴或21) 内之吸附材’乃進行第—階段之吸附程序,將廢氣中之v〇Cs =常溫下予以吸附,淨化後之氣體直接排放至大氣;而隨 者轉輪(或轉環)之轉動,當吸附職後之吸附材轉至脫附 區(12或22)時,即進人第二階段之脫附程序,藉熱空氣自 [S] -3- 201138933 脫附區將VOCs脫附出來,而脫附出來之VOCs則可進行另 一階段之焚化或冷凝回收處理。 次按,由於習知轉輪型或轉環型迴旋式淨化器,因其 固體基材並不具備淨化能力,而實際具備淨化能力之吸附 材僅佔整體體積之30%以下,致使單位體積之淨化能力受 限;此外,提供吸附材塗佈附著之固體基材,容易造成大 ' 量熱蓄積,進而必須停機解決熱蓄積之問題。 【發明内容】 本發明之主要目的,係欲解決先前技術單位體積淨化 • 能力受限之問題,而具有大幅提升淨化能力之功效。 本發明之另一目的,則具有無熱蓄積問題之功效。 本發明之又一目的,乃具有搭配外部脫附而提升脫附 效率之功效。 為達上述功效,本發明之結構特徵,係包括有: 一迴旋體,具有複數個充填吸附材之容置室; 一減速機,驅動該迴旋體;以及 一吸附材充填單元,相對該迴旋體設置有出料管與入 • 料管,而讓該迴旋體之容置室於該出料管送出吸附材且於 該入料管送入吸附材者。 此外,該迴旋體包括轉輪型迴旋體與轉環型迴旋體。 . 該轉輪型迴旋體之左、右輪側面與該轉環型迴旋體之内、 外環面具有氣流通孔。該轉輪型迴旋體與轉環型迴旋體以 複數個隔板分隔成複數個容置室。該轉輪型迴旋體與轉環 型迴旋體以複數個容置室單體所組合成。該吸附材由活性 [S3 -4- 201138933 碳、沸石或氧化鋁等多孔系材料直接製作成型。該吸附材 包括顆粒狀、球狀與柱狀等結構型態。該吸附材充填單元 與外部之脫附器連接。 【實施方式】 首先,請參閱第三圖所示,本發明之第一實施例,係 將一轉輪型迴旋體(40a)徑向設置複數個隔板(41),而分隔 成複數個充填可動式吸附材(50)之容置室(42),並藉一減 速機(30)驅動該轉輪型迴旋體(40a),且令一吸附材充填單 元(60)相對該轉輪型迴旋體(40a)設置有出料管(61)與入 料管(62),致使該轉輪型迴旋體(40a)之容置室(42)藉該出 料管(61)送出吸附材(50)且由該入料管(62)送入吸附材 (50)者。然而,該吸附材充填單元(60)再與外部之脫附器 連接,進行吸附材之脫附程序,但因非為本案之專利標的, 在此不再贅述。該吸附材(50)由活性碳、沸石、氧化鋁或 樹脂等多孔系材料直接製作成型,而包括顆粒狀、球狀、 橢圓狀與柱狀等結構型態。 接著,請參閱第四圖所示,本發明之第二實施例與第 一實施例之不同處在於:非以隔板分隔出容置室,係以複 數個圓形排列之容置室單體(43)組合成轉輪型迴旋體 (40b)。另者,請參閱第五圖所示,本發明之第三實施例與 第一實施例之不同處在於:迴旋體非為轉輪型,係為徑向 設置複數個隔板(71)而分隔成複數個容置室(72)之轉環型 迴旋體(70a)。又,請參閱第六圖所示,本發明之第四實施 [Si -5- 201138933 例與第三實施例之不同處在於:非以隔板分隔出容置室, 係以複數個環形排列之容置室單體(7 3)組合成轉輪型迴旋 體(70b)。然而,該轉輪型迴旋體(40a或40b)之左、右輪 側面與該轉環型迴旋體(70a或70b)之内、外環面具有令吸 附材(50 )不致掉落之氣流通孔。 基於如是之構成,再以第一實施例之結構型態配合第 七圖說明淨化程序,圖中將轉輪型迴旋體(40a)分隔成八個 充填可動式吸附材(50)之容置室(42),而有機溶劑廢氣輸 送管可罩覆住八、6、(:、0、£、?等六個位置之容置室(42) 之一側,亦即迴旋至此六個位置之容置室(42)乃成為有機 溶劑之吸附區,吸附區内部充填之吸附材(50)會將有機溶 劑吸附,而讓通過吸附區之氣流淨化;接著,當容置室(42) 迴旋至G位置之出料區時,即藉該出料管(61)送出内部已 吸附有機溶劑之吸附材(50),俾以進行吸附材(50)之脫附 程序;最後,當容置室(42)迴旋至Η位置之入料區時,即 藉該入料管(62)送入已完成脫附程序之吸附材(50),準備 進行下一個吸附、出料與入料之有機溶劑淨化循環。 是故,由於本發明與習知迴旋式淨化器之吸附區面積 相當,但因習知迴旋式淨化器之吸附材僅佔整體體積之30 %以下,而本發明之吸附材是由活性碳、沸石、氧化鋁或 樹脂等多孔系材料直接製作成型而流體化充填於吸附區, 致使淨化能力可達先前技術之三倍以上,而具有大幅提升 淨化能力之功效。又,本發明藉吸附材充填單元將完成吸 附程序之吸附材輸送到外部進行脫附程序,吸附程序所產 生之廢熱並不會蓄積在迴旋體内部,具有無熱蓄積問題且201138933 VI. Description of the invention: [Technical field of the invention] The present invention relates to a fluidized swirling purifier for adsorbing materials, in particular to a housing body which is divided into a plurality of housing chambers for filling the adsorbing materials, and The adsorbent material is fluidized and transported to the outside for the designer of the desorption procedure. [Prior Art] Organic solvents widely used in life and production are highly volatile into gases, so they are also known as volatile organic compounds (v〇latile 0rganic c〇mp〇unds, VOCs), but because most v〇Cs have Certain toxicity must be incinerated or recycled. Before incineration or recovery procedures, the VOCs are usually adsorbed and purified by a purifier, followed by desorption for subsequent incineration or recovery processes, in which a rotary or rotary ring is used. The type of rotary converter is a common purifier, and the conventional rotary type purifier (1〇) shown in the first figure and the rotary type rotary converter shown in the second figure (2) 〇), the structure is formed by coating a solid substrate with a gas flow channel with a layer of adsorbent powder, and the solid substrate is sintered by ceramic, glass or activated carbon fiber paper, and the type of adsorbent is a component of the gas to be treated. However, activated carbon or zeolite is generally used; therefore, the conventional rotary or rotary-type rotary converter is rotated by a geared motor (30) (1 to 10 RPH; most For 2 6RPH), the rotating material (or the rotating ring) in the adsorption zone (1) or 21) is subjected to the adsorption process of the first stage, and the v〇Cs in the exhaust gas is adsorbed at normal temperature, and the purified gas is directly discharged. To the atmosphere; and the rotation of the runner (or the swivel), when the adsorbent material after the adsorption is transferred to the desorption zone (12 or 22), it enters the second stage of the desorption procedure, borrowing hot air [S] -3- 201138933 The desorption zone desorbs the VOCs, while the desorbed VOCs can be incinerated or condensed for another stage. Sub-press, due to the conventional rotary-type or rotary-type rotary converter, because the solid substrate does not have the purification ability, the actual adsorption capacity of the adsorption material only accounts for less than 30% of the total volume, resulting in unit volume The purification ability is limited; in addition, the solid substrate coated with the adsorbent material is attached, which tends to cause large 'quantum heat accumulation, and must be stopped to solve the problem of heat accumulation. SUMMARY OF THE INVENTION The main object of the present invention is to solve the problem of limited capacity per unit volume purification in the prior art, and to greatly improve the purification ability. Another object of the invention is to have the effect of no heat accumulation problems. Another object of the present invention is to enhance the efficiency of desorption with external desorption. In order to achieve the above effects, the structural features of the present invention include: a rotating body having a plurality of receiving chambers filled with adsorbing materials; a reducer driving the rotating body; and an adsorbing material filling unit opposite to the rotating body The discharge pipe and the inlet pipe are disposed, and the accommodation chamber of the rotary body is sent to the adsorption pipe and the adsorption material is fed into the suction pipe. In addition, the convolution body includes a revolver type revolving body and a swivel type revolving body. The left and right wheel sides of the runner type revolving body and the inner and outer ring faces of the swivel type revolving body have airflow through holes. The revolver type revolving body and the swivel type revolving body are divided into a plurality of accommodating chambers by a plurality of partition plates. The revolver type revolving body and the swivel type revolving body are combined in a plurality of accommodation chamber units. The adsorbent is directly formed from a porous material such as activated carbon [S3 -4- 201138933 carbon, zeolite or alumina. The adsorbent material includes structural forms such as pellets, spheres, and columns. The adsorbent material filling unit is connected to an external desorber. [Embodiment] First, referring to the third embodiment, in the first embodiment of the present invention, a plurality of partitions (41) are radially disposed in a rotating wheel type revolving body (40a), and are divided into a plurality of fillings. a accommodating chamber (42) of the movable adsorbing material (50), and driving the rotary-type revolving body (40a) by a reducer (30), and rotating a absorbing material filling unit (60) relative to the rotating wheel type The body (40a) is provided with a discharge pipe (61) and a feed pipe (62), so that the accommodation chamber (42) of the rotary-type rotary body (40a) feeds the adsorption material through the discharge pipe (61) (50) And the material that is fed into the adsorbent (50) by the feed pipe (62). However, the adsorbing material filling unit (60) is further connected to the external desorber to perform the desorption process of the adsorbing material, but it is not a patent of the present invention and will not be described herein. The adsorbent (50) is directly formed from a porous material such as activated carbon, zeolite, alumina or resin, and includes a structural form such as a pellet, a sphere, an ellipse or a column. Next, referring to the fourth embodiment, the second embodiment of the present invention is different from the first embodiment in that the accommodating chamber is not separated by a partition, and the accommodating chamber is arranged in a plurality of circular arrays. (43) Combined into a revolver type revolving body (40b). In addition, referring to the fifth figure, the third embodiment of the present invention is different from the first embodiment in that the revolving body is not a reel type, and is separated by a plurality of partitions (71) arranged in the radial direction. The plurality of slewing chambers (72) are swivel-type revolving bodies (70a). Moreover, referring to the sixth embodiment, the fourth embodiment of the present invention [Si-5-201138933 differs from the third embodiment in that the accommodating chamber is not separated by a partition, and is arranged in a plurality of annular shapes. The accommodating chamber unit (73) is combined into a revolver type revolving body (70b). However, the left and right wheel sides of the runner type revolving body (40a or 40b) and the inner and outer ring faces of the swivel type revolving body (70a or 70b) have airflow passages for preventing the adsorbing material (50) from falling. hole. Based on the configuration of the first embodiment, the cleaning procedure is described in conjunction with the seventh embodiment, in which the runner-type revolving body (40a) is divided into eight housing chambers filled with movable adsorbing materials (50). (42), and the organic solvent exhaust pipe can cover one side of the six (6, 6), (0, £, ?, etc.) housings (42), that is, the capacity of the six positions The chamber (42) is an adsorption zone for the organic solvent, and the adsorbent material (50) filled inside the adsorption zone adsorbs the organic solvent and purifies the gas stream passing through the adsorption zone; then, when the accommodation chamber (42) is swirled to G When the discharge zone of the position is taken, the adsorption material (50) which has adsorbed the organic solvent inside is sent out by the discharge pipe (61), and the desorption process of the adsorption material (50) is carried out; finally, when the accommodation room (42) When returning to the feeding zone of the Η position, the feed pipe (62) is fed into the adsorbent material (50) which has completed the desorption process, and is ready for the next organic solvent purification cycle of adsorption, discharge and feed. Therefore, since the present invention is equivalent to the area of the adsorption zone of the conventional cyclone purifier, it is known from the prior art. The adsorbent material of the rotary purifier only accounts for less than 30% of the whole volume, and the adsorbent material of the present invention is directly formed by a porous material such as activated carbon, zeolite, alumina or resin, and is fluidized and filled in the adsorption zone, thereby purifying The ability is up to more than three times that of the prior art, and has the effect of greatly improving the purification ability. Moreover, the present invention uses the adsorption material filling unit to transport the adsorption material that completes the adsorption process to the outside for the desorption process, and the waste heat generated by the adsorption process is Does not accumulate inside the cyclone, has no heat accumulation problem and

t S J -6- 201138933 脫附效率提升之功效。 綜上所述,本發明所揭示之技術手段,確具「新穎性」、 「進步性」及「可供產業利用」等發明專利要件,祈請鈞 局惠賜專利,以勵發明,無任德感。 惟,上述所揭露之圖式、說明,僅為本發明之較佳實 施例,大凡熟悉此項技藝人士,依本案精神範疇所作之修 ' 飾或等效變化,仍應包括本案申請專利範圍内。 【圖式簡單說明】 第一圖係習知轉輪型迴旋式淨化器之結構說明圖。 • 第二圖係習知轉環型迴旋式淨化器之結構說明圖。 第三圖係本發明第一實施例之結構說明圖。 第四圖係本發明第二實施例之結構說明圖。 第五圖係本發明第三實施例之結構說明圖。 第六圖係本發明第四實施例之結構說明圖。 第七圖係本發明淨化程序之說明圖。 【主要元件符號說明】 φ (10)轉輪型迴旋式淨化器 (20)轉環型迴旋式淨化器 (11、21)吸附區 (12、22)脫附區 (30)減速機 - (40a、40b)轉輪型迴旋體 (41) 隔板 (42) 容置室 201138933 (43)容置室單體 (50)吸附材 (60) 吸附材充填單元 (61) 出料管 (62) 入料管 (70a、70b)轉環型迴旋體 (71) 隔板 (72) 容置室 (73) 容置室單體 •t S J -6- 201138933 The effect of desorption efficiency improvement. In summary, the technical means disclosed in the present invention have the invention patents such as "novelty", "progressiveness" and "available for industrial use", and pray for the patent to be invented by the bureau. German sense. However, the drawings and descriptions disclosed above are only preferred embodiments of the present invention, and those skilled in the art, which are subject to the spirit of the present invention, should still include the scope of the patent application. . [Simple description of the drawings] The first figure is a structural explanatory diagram of a conventional rotary-type rotary converter. • The second diagram is a structural illustration of a conventional rotary-type rotary converter. The third drawing is a structural explanatory view of the first embodiment of the present invention. The fourth drawing is a structural explanatory view of a second embodiment of the present invention. The fifth drawing is a structural explanatory view of a third embodiment of the present invention. Figure 6 is a structural explanatory view of a fourth embodiment of the present invention. The seventh drawing is an explanatory diagram of the purification process of the present invention. [Main component symbol description] φ (10) rotary type rotary converter (20) rotary type rotary converter (11, 21) adsorption zone (12, 22) desorption zone (30) reducer - (40a 40b) Rotary type revolving body (41) Separator (42) accommodating chamber 201138933 (43) accommodating chamber unit (50) absorbing material (60) absorbing material filling unit (61) discharging tube (62) Feed pipe (70a, 70b) swivel type revolving body (71) partition plate (72) accommodation room (73) accommodation room unit •

[SI -8-[SI -8-

Claims (1)

201138933 七、申請專利範圍: 1 ·一種吸附材流體化迴旋式淨化器,係包括有: 一迴旋體’具有複數個充填吸附材之容置室; 一減速機’驅動該迴旋體;以及 一吸附材充填單元,相對該迴旋體設置有出料管與入 料管,而讓該迴旋體之容置室於該出料管送出吸附材且於 該入料管送入吸附材者。 • 2 ·如申請專利範圍第1項所述之吸附材流體化迴旋 式淨化器’其中’該迴旋體包括轉輪型迴旋體與轉環型迴 旋體。 3 ·如申請專利範圍第2項所述之吸附材流體化迴旋 式淨化器’其中’該轉輪型迴旋體之左、右輪側面與該轉 環型迴旋體之内、外環面具有氣流通孔。 • 4 ·如申請專利範圍第3項所述之吸附材流體化迴旋 式淨化器,其中,該轉輪型迴旋體與轉環型迴旋體以複數 個隔板分隔成複數個容置室。 5 .如申請專利範圍第3項所述之吸附材流體化迴旋 式淨化器,其中,該轉輪型迴旋體與轉環型迴旋體以複數 個容置室單體所組合成。 LSI -9- 201138933 6如申凊專利範圍第1至5項任一項所述之吸附材 流體化迴旋式淨化器,其中,該吸附材由 活性碳、沸石、 氧化鋁或樹脂等多孔系材料直接製作成型。 7 ·如申請專利範圍第6項所述之吸附材流體化迴旋 式淨化器’其中,該吸附材包括顆粒狀、球狀、橢圓狀與 柱狀等結構型態。201138933 VII. Patent application scope: 1 · A fluidized fluidized rotary purifier for adsorbing materials, comprising: a rotating body 'a plurality of filling chambers filled with adsorbing materials; a reducer' driving the rotating body; and an adsorption The material filling unit is provided with a discharge pipe and a feeding pipe relative to the rotating body, and the receiving chamber of the rotating body is sent to the suction pipe in the discharging pipe and the adsorbing material is fed into the feeding pipe. • The adsorbent fluidized rotary purifier as described in claim 1 wherein the revolving body comprises a revolver type revolving body and a swivel type revolving body. 3. The fluidized rotary swirler of the adsorbent according to claim 2, wherein the left and right wheel sides of the rotor type revolving body and the inner and outer ring surfaces of the swivel type revolving body have gas Flow hole. The fluid-feeding rotary converter of the adsorbent according to claim 3, wherein the rotary-type rotor and the rotary-type rotary body are separated into a plurality of accommodation chambers by a plurality of partitions. 5. The adsorbent fluidized rotary converter according to claim 3, wherein the rotary-type rotator and the rotary-type rotator are combined in a plurality of accommodating chamber monomers. The sorbent material fluidized rotary converter according to any one of claims 1 to 5, wherein the adsorbent is made of a porous material such as activated carbon, zeolite, alumina or resin. Direct molding. 7. The adsorbent fluidized swirling purifier described in claim 6 wherein the adsorbent material comprises a granular, spherical, elliptical or columnar structural form. 8 ·如申請專利範圍第6項所述之吸附材流體化迴旋 式淨化器,其中,該吸附材充填單元與外部之脫附器連接。8. The adsorbent fluidized rotary converter according to claim 6, wherein the adsorbent filling unit is connected to an external desorber.
TW99115416A 2010-05-14 2010-05-14 Adsorbent material fluidized cyclotron cleaner TW201138933A (en)

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US7166149B2 (en) * 2004-01-12 2007-01-23 Uop Llc Adsorption process for continuous purification of high value gas feeds
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