TW201122071A - Adhesion composition, adhesion agent and adhesion sheet. - Google Patents

Adhesion composition, adhesion agent and adhesion sheet. Download PDF

Info

Publication number
TW201122071A
TW201122071A TW099136666A TW99136666A TW201122071A TW 201122071 A TW201122071 A TW 201122071A TW 099136666 A TW099136666 A TW 099136666A TW 99136666 A TW99136666 A TW 99136666A TW 201122071 A TW201122071 A TW 201122071A
Authority
TW
Taiwan
Prior art keywords
copolymer
acrylate copolymer
meth
monomer
functional group
Prior art date
Application number
TW099136666A
Other languages
Chinese (zh)
Other versions
TWI493002B (en
Inventor
Takayuki Arai
Tadashi Matano
Atsushi Kurokawa
Original Assignee
Lintec Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lintec Corp filed Critical Lintec Corp
Publication of TW201122071A publication Critical patent/TW201122071A/en
Application granted granted Critical
Publication of TWI493002B publication Critical patent/TWI493002B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/40—Adhesives in the form of films or foils characterised by release liners
    • C09J7/403—Adhesives in the form of films or foils characterised by release liners characterised by the structure of the release feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)
  • Polarising Elements (AREA)

Abstract

This invention provides an adhesion composition, the method for manufacturing the adhesion composition, an adhesion agent and an adhesion sheet having excellent light leakage resistance and durability when applied in optical components such as polarization plates. An adhesion composition, containing a first (metha) acrylate copolymer (A) with the average molecular weight of 700 thousands to 2.5 million, a second (metha) acrylate copolymer (B) with the average molecular weight of 8000 to 250 thousands, and a cross-linking agent (C), additionally the ratio of the second (metha)acrylate copolymer (B) with respect to 100 parts by mass of the first (metha)acrylate copolymer (A) is 5 to 50 parts by mass. The second (metha)acrylate copolymer (B) comprises a monomer having a functional group (b1) highly reactive to the cross-linking agent (C) so as to form a structural constituent. Further, in the second (metha)acrylate copolymer (B), the ratio of the monomer of the copolymer exceeds 1 mass%. The first (metha)acrylate copolymer (A) does not comprise a monomer having a functional group reactive to the cross-linking agent (C) to form a structural constituent or comprises a monomer having a functional group (a1) with the reactivity lower than the functional group (b1) of the second (metha)acrylate copolymer (B) to the cross-linking agent (C) so as to form a structural constituent.

Description

201122071 六、發明說明： 【發明所屬之技術領域】 本發明係關於-種粘著性組成物、粘著性組成物之製 方法點著劑（父聯粘著性組成物之材料）以及粘著片； 特別是關於-種適合作為偏光板等之光學構件用之枯著性 組成物、粘著性組成物之製造方法、點著劑以及帖著片。 【先前技術】 -般在液晶面板’為了偏光板或相位差板，接合在破 璃基板等’因& ’大多是使用由粘著劑組成物而形成之粕 著劑層。但是’偏光板或相位差板等之光學構件係容易由 於熱等而收縮，因此’由於熱履歷而發生收縮，結果，指 出所謂層積於該光學構件之粘著劑層無法追蹤其收縮，在 界面產生剝離（所謂浮起、剝離），或者是發生由於起因 於光學構件收縮時之應力而使得光學構件之光學軸偏離之 所造成之光漏（所謂植白）之問題。 作為用以防止這個之方法係列舉（丨）藉由粘著力變高 且形態安疋性良好之粘著劑層貼合於偏光板等之光學構件 而抑制光學構件之收縮本體之方法或者是（2 )使用光學構 件收縮時之應力小之粘著劑層之方法。作為（丨）之方法係 正如專利文獻1所示，有效地使用儲藏彈性率變高之粘著 劑層。另一方面，作為（2 )之方法係有效地使用能夠柔軟 地對應於變形之應力緩和性呈良好之粘著劑層。但是，向 來在企圖形成此種應力緩和性良好之粘著劑層之狀態下， 4 201122071 必須極端地降低該站著劑a由—— …層中之父聯密度。在像這樣時， 有所謂降低粘著劑層本身之強存二aα A u 河 < 強度而惡化耐久性之問題發 生。 於是，在專利文獻2〜/ 胺基曱酸乙酯彈性體等，添 極端地降低枯著劑層之交聯 著劑組成物，在粘著劑層， 得到耐光漏性及耐久性。 ’藉由可塑劑、流動性石躐和 加於丙烯系粘著劑，來取代呈 密度’而適度地軟化得到之枯 賦予應力緩和性，企圖藉此而 【先前技術文獻】 •【專利文獻】 【專利文獻1】日本特開2006 — 235568號公報 【專利文獻2】曰本特開平5 — 4551 7號公報 【專利文獻3】曰本特開平9— 137143號公報 【專利文獻4】日本特開2〇〇5 — 1 94366號公報 【發明内容】 【發明所欲解決之課題】 但是，在藉由添加可塑劑或流動性石蠟之粘著劑組成 物而形成之粘著劑層，由於經時而流出可塑劑或流動性石 蠟，發生污染液晶胞等之各種問題。此外，在添加胺基甲 酸乙I旨彈性體之粘著劑組成物，由和其他成分之相溶=之 方面來看的話，則限制胺基甲酸乙酯彈性體之添加量因 此，應力緩和性之改善係不充分，並且，由於丙烯系粘著 劑和胺基曱酸乙酯彈性體之相溶性而發生白濁等之問題。 5 201122071 像這樣，在先前技術，不容易根本地改善由光學構件用之 粘著劑組成物來形成之粘著劑層之耐光漏性及耐久性。 本發明係有鑑於此種實狀而完成的，其目的係提供一 種適用於偏光板等之光學構件時之耐光漏性和耐久性兩者 良好的粘著性組成物、該粘著性組成物之製造方法、粘著 劑以及粘著片。 【用以解決課題之手段】 為了達成前述目的’因此，在第1，本發明係提供一 種點著性組成物，係含有重量平均分子量7〇萬〜25〇萬之 第1之（曱基）丙稀酸酯共聚物（A)、重量平均分子量 8000〜25萬之第2之（曱基）丙烯酸酯共聚物（b)和交 聯劑（C)且前述第2之（甲基）丙烯酸酯共聚物（b )相 對於100質量份之前述第1之（甲基）丙烯酸酯共聚物（A) 之比例為5〜50質量份的粘著性組成物，其特徵在於：前 述第2之（甲基）丙烯酸酯共聚物（b)係包含具有和前述 交聯劑（C )之高反應性之官能基（bl )之單體而成為構造 成分，並且’在該第2之（甲基）丙烯酸酯共聚物（B)中， 成為前述單體之比例超過1質量％之共聚物，前述第1之 (曱基）丙烯酸醋共聚物（A)係不包含具有和前述交聯劑 (C)之反應性之官能基之單體而成為構造成分，或者是包 含具有和前述交聯劑（C)之反應性低於前述第2之（曱基） 丙烯酸酯共聚物（B)之前述官能基（bl )之官能基（) 之單體，來作為構造成分（發明1)。 在交聯前述發明（發明1 )之粘著性組成物之粘著劑， 201122071 向來係藉由以呈可塑劑地使用之低分子量之共聚物（B )， 來形成由於交聯之所造成之三次元網目構造，在其三次元 網目構造’纏繞無交聯之高分子量之共聚物（A )，而發揮 良好之應力緩和性。藉由使用具有該良好之應力缓和性之 枯著劑’而4到在適用於偏光板等之光學構件時之耐光漏 性和耐久性兩者良好的粘著片。 在前述發明（發明，前述第丄之（甲基）丙稀酸 酯共聚物（A)係最好是不包含具有和前述交聯劑（c)之 南反應性之官能基之單體而成為構造成分（發明2 )。 在前述發明（發明卜2)，最好是前述第k (甲幻 丙烯酸s旨共聚物⑴之和前述交聯劑（c)之低反應性之 官能基（⑴係，基’前述第（曱基）丙稀酸醋共聚 物⑴之和前述交聯劑（c)之高反應性之官能基⑴） 係羥基，前述交聯劑（c)係異氰酸醋 在前述發明(發明3)，前述第…:基發)： 醋共聚物（A)係最好是含有含缓基單體Q〜 作為構成該以物之單體單位（發 之枯著片，具有良好之再工作性。 错此而使传到 =述發明(發明3、4) ’前述第2之（曱基）丙烯 文曰物（B)係最好是含有含羥基單體3〜質量％， 來作為構成該共聚物之單體單位（發8月5)。藉此而使得 到之粘者片，具有更加良好之耐久性。 ，前述發明（發明3〜5)，前述異氛酸I系交聯劑之 3有1係最好是該異氰酸㈣交聯劑之異氰❹旨基相對於 201122071 月j辻_第2之（曱基）丙稀酸醋共聚物（b )之和前述交聯劑 (C)之南反應性之官能基（bl )之量，成為〇. 1〜5當量 之量（發明6)。 在别述發明（發明1〜6 )，最好是還含有矽烧偶合劑 (D )(發明 7 )。 在刖述發明（發明7)，前述矽烷偶合劑（D)之含有 量係最好是相對於前述第】之（甲基）丙烯酸酯共聚物（A) 之100質量份而成為0.05〜0.5質量份（發明8)。 在第2 ’本發明係提供一種粘著性組成物之製造方法， 係製造前述粘著性組成物（發明】〜6 )之方法，其特徵在 於包括： 以轉化率50〜90%，對於構成前述第1之（甲基）丙 烯酸醋共聚物U)之單體’進行自由基聚合，製造前述第 1之（甲基）丙烯酸酯共聚物⑴之製程⑴； 在前述第1之（甲基）丙稀酸酉旨共聚物⑴之存在下， 對於殘留在前述第1之（甲基）丙烯酸醋共聚物⑴聚合 時之單體以及具有和前述交聯劑u)之高反應性之官能基 (Μ)之單體’進行自由基共聚合，製造前述第2之（甲 基）丙烯酸酯共聚&⑴之製程（2);以及， 添加前述交聯劑（C)之製程（3)(發明9)。 在前述發明（發明9)，最好是在製造前述第2之（甲 基）丙烯酸醋共聚物（Β)之製程（2)，以轉化率7〇〜1〇。 %，對於殘留在前述第1之（甲基）丙_共聚物⑴ 聚合時之單體以及具有和前述交聯劑Κ)之高反應性之官 8 201122071 能基Cbl)之單體’進行自由基共聚合（發明ι〇)。 在刖述發明（發明9、1。）’最好是在製造前述粘著 !生組成物（發明7、8 )之狀態下，還包括添加前述石夕院偶 合劑（D)之製程（發明11 )。 在第3本發明係提供一種粘著劑，交聯前述粘著性 組成物（發明1〜8 )而組成（發明丨2 )。 在第4，本發明係提供一種點著片，係包括基材和枯 者劑層之點者片，盆輯 .义 ”将徵在於.則述粘著劑層係由前述粘 著劑（發明12 )而組成（發明丨3)。 在⑴述發明（發.明！ 3 )，.前述基材係最好是光學構件 (發明14 )。 在第5 ’本發明係提供-種粘著片’係包括2片之剝 離片以及夾持於前述剝離片而接合在前述2片之剝離片之 剝離面之枯著劑層的㈣片，其特徵在於：前述㈣劑； 係由前述钻著劑（發明12)而組成（發明15)。 θ 【發明效果】 在交聯本發明之枯著性組成物之枯著劑，向來係藉由 以呈：塑劑地使用之低分子量之共聚物，來形成由於交聯 無交聯之高分子量之^::厂網目構造，纏繞 ^ 之共聚物，而發揮良好之應力緩和性。 ^由使用具有該良好之應力緩和性之㈣劑，而得到在適 於偏光板等之光學構件時耐光 的點著片。 錢和耐久性兩者良好 201122071 【實施方式】 在以下’就本發明之實施形態而進行說明。 (粘著性組成物） 本實施形態之粘著性組成物係含有重量平均分子量7〇 萬〜25 0萬之第1之（曱基）丙烯酸酯共聚物、重量 平均分子篁8000〜25萬之第2之（曱基）丙烯酸酯共聚物 (B )和交聯劑（C )，最好是還含有矽烷偶合劑（D )。此 外，在本s兒明書，所謂（曱基）丙烯酸酯係表示丙烯酸酯 和甲基丙烯酸酯兩者。其他之類似用語也相同。 第2之（曱基）丙烯酸酯共聚物（b )係以具有和交聯 劑（C)之高反應性之官能基（bl)之單體，來作為構造成 分’該單體之共聚物（B )之構成比例係超過1質量％ 。 另一方面’第1之（甲基）丙烯酸酯共聚物（A)係不 包含具有和交聯劑（C )之反應性之官能基之單體而成為構 造成分’或者疋具有和交聯劑（C )之反應性低於第2之（曱 基）丙烯酸醋共聚物（B)之前述官能基（bl)之官能基（ai) 之單體，來作為構造成分。 前述（甲基）丙烯酸酯共聚物（A)或（B)係最好是 酯部分之烷基之碳數為1〜2〇之（曱基）丙烯酸酯和具有 反應性官能基之單體（含反應性官能基單體）以及由於要 求而使用之其他之單體之共聚物。此外，第1之（甲基） 丙烯酸醋共聚物（A )係最好是不含有前述含反應性官能基 單體而成為構造成分。 作為酯部分之烷基之碳數為1〜2〇之（曱基）丙烯酸 10 201122071 係列舉例如（曱基）丙烯酸甲酿、（曱基）丙烯酸乙醋、 X曱土）丙稀酸丙酿、（甲基）丙稀酸丁醋、（甲基）丙 烯馱戊自曰、（甲基）丙烯酸己酯 '(曱基）丙烯酸環己酯、 (曱基）丙烯酸2-乙基己基、（甲基）丙稀酸異辛醋、 (曱基）丙稀酸 丙烯酸十四燒西旨 烯酸硬脂醯等。 夭醋、（曱基）丙烯酸十二烷酯、（曱基） '(甲基）丙烯酸十六烷醯、（曱基）丙 這些係可以單獨使用，並且，也可以組合 2種以上而使用。 另方面，作為含反應性官能基單體係最好是列舉在 分子内具有羥基之單體（含羥基單體）、在分子内具有羧 土之單體（含叛基單體）、在分子内具有胺基之單體（含 胺基單體）等。 作為含羥基單體係列舉例如（曱基）丙烯酸2—羥基 乙基（甲基）丙烯酸2 —羥基丙基、（曱基）丙烯酸3 一羥基丙基、（甲基）丙烯酸2一羥基丁基、（甲基）丙 烯13羥基丁基、（甲基）丙烯酸4一羥基丁基等之（甲 基）丙烯酸羥基烷基酯等。這些係可以單獨使用，並且， 也可以組合2種以上而使用。 作為3叛基單體係列舉例如丙稀酸、甲基丙烯酸'丁 烯&順丁烯二酸、衣康酸、檸康酸、乙酸乙烯等之乙烯 性不飽和羧酸。這些係可以單獨使用’並且，也可以組合 2種以上而使用。 作為含胺基單體係列舉例如（甲基）丙烯酸胺基乙酯、 (曱基）丙烯酸N，N—二甲基胺基乙基、（甲基）丙烯酸 11 201122071 甲基）丙烯酸t一丁基胺基乙基 ’並且，也可以組合2種以上而 N，N — -一曱基胺基丙基、 等。這些係可以單獨使用 使用。 此外，作為前述其他之單體係列舉例如（甲基）丙稀 酸環己S旨等之具有脂肪族環之（曱基）丙烯酸醋、（甲基） 丙烯酸笨酯等之具有芳香族環之（曱基）㈣酸酯、丙烯 醯胺、曱基丙烯醯胺等之非交聯性丙烯醯胺、苯乙烯等。 這些係可以單獨使用，並且，也可以組合2種以上而使用。 此外，使用於第1之（甲基）丙烯酸酯共聚物（A )之 含反應性官能基（al)單體以及使用於第2之（曱基）丙 烯酸酯共聚物（B )之含反應性官能基（bl )單體之選擇係 藉由和使用之交聯劑（C )之反應性之關係而決定。細節係 欽述於後面。 在此’第2之（曱基）丙烯酸酯共聚物（b )係超過丄 質量％而含有前述含反應性官能基（bl )單體，其上限係 通常為50質量％。最好是含有3〜40質量％之前述含反應 性官能基（bl)單體，特別最好是含有5〜25質量％ 。藉 由以前述範圍’來含有含反應性官能基（bl)單體，而最 好是第2之（曱基）丙烯酸酯共聚物（B)之交聯程度，在 和第1之（曱基）丙烯酸酯共聚物（A)之組合，得到之枯 著劑之應力緩和性係變得良好。此外’在含反應性官能基 (bl)單體之含有量為1質量％以下’第2之（曱基）丙 烯酸酯共聚物（B )之交聯係不充分’由於這樣而降低财久 性。另一方面，在含反應性官能基（bl)單體之含有量超 12 201122071 t 50質畺％時，第2之（甲基）丙稀酸酯共聚物（b)之 父聯係成為過度，恐怕會由於這樣而降低對於被附著體之 貼合適當性。此外，藉由含反應性官能基（bl )單體之含 有量之上限成為40質量％而使得到之粘著片之耐久性，更 加地良好。 在本實施形態，前述第2之（甲基）丙烯酸酯系共聚 物（B)係可以單獨使用丨種，並且’也可以組合2種以上 而使用。 第2之（曱基）丙烯酸酯共聚物（B)之重量平均分子 里係8000〜25萬，最好是2萬〜15萬。.也就是說，第2 之（曱基）丙烯酸酯共聚物（Β)係成為低分子量聚合物成 刀此外，本說明書之重量平均分子量係藉由凝膠滲透色 谱法（GPC)而測定之聚笨乙烯換算之值。 藉由第2之（曱基）丙烯酸酯共聚物之重量平均 分子量位處於前述範圍内，而在本實施形態之粘著性組成 物，形成特有之三次元網目構造，有助於良好之應力緩和 也就是說，在第2之（曱基） 重量平均分子量未滿8〇〇〇，無法得到良好之三次元網目構 ^另#面，在第2之（曱基）丙烯酸醋共聚物（Β)之 重量平均分子量超過25萬時，降低相溶性，不容易成為共 聚物（A )和共聚物（β )良好地纏繞之狀態，不容易形成 作為目的之特有之網目構造，變差於耐久性及再工作性。 第1之（甲基）丙烯酸酯共聚物"）係不包含具有和 父聯幻（C )之反應性之官能基之單體而成為構造成分，或 13 201122071 者是包含具有和交聯劑（c)之反應性低於第2之（曱基） 丙稀酸醋共聚物（B)之前述官能基（Μ)之官能基（ai) 之単體，來作為構造成分，接著，最好是不包含具有和交 聯劑（C)之高反應性之官能基之單體而成為構造成分。 第1之（甲基）丙烯酸酯共聚物（A)係可以不包含具 有和交聯劑（C)之反應性之官能基之單體，但是，在包含 具有反應性低於第2之（甲基）丙烯酸酯共聚物（b)之反 應性官能基（bl )之反應性官能基（al )之單體時，促進 第2之（甲基）丙烯酸酯共聚物（B)和交聯劑（c)之反 應，或者是在使用矽烷偶合劑（D)之狀態下，第1之（曱 基）丙烯酸酷共聚物（A)之反應性官能基（al )係反應於 該矽烷偶合劑（D)之烷氧基甲矽烷基等，可以調整第丨之 (曱基）丙烯酸酯共聚物（A)之凝集程度，能夠得到要求 之接合性’有理想之狀態發生。 在第1之（曱基）丙烯酸酯共聚物（A)含有前述含反 應性官能基（al )單體之狀態下，其含有量係通常為2〇質 量％以下，最好是15質量％以下，特別最好是1〇質量％ 以下在含反應性官能基（al)單體之含有量超過20質量 %時’第1之（甲基）丙烯酸酯共聚物（A)係過度地凝集， 恐怕會無法得到要求之應力緩和性。此外，由賦予再工作 性之觀點來看的話，含反應性官能基（al )單體之含有量 係最好是15質量％以下。 第1之（甲基）丙烯酸酯共聚物（A)係最好是不包含 在分子内具有和交聯劑（c )之反應性同等以上於第2之（甲 14 201122071 基）丙烯酸酯共聚物（B)之反應性官能基（bl)之官能基 之單體，但是，假設是在含有之狀態下，在分子内具有該 官能基之單體之含有量係最好是在共聚物（A)中，成為1 質量％以下，特別最好是0.5質量％以下。在該單體之含 有量超過1質量％時，恐怕會妨礙應該優先地反應之第2 之（曱基）丙烯酸酯共聚物（B)和交聯劑（C)之反應。 在本實施形態’前述第1之（曱基）丙烯酸酯共聚物 (A)係可以單獨使用1種，並且，也可以組合2種以上而 使用。 第1之（甲基）丙烯酸酯共聚物（A)之重量平均分子 ΐ係70萬〜250萬’最好是1〇〇萬〜2〇〇萬。也就是說， 第1之（曱基）丙烯酸酯共聚物（Α)係成為高分子量聚合 物成分。 藉由第1之（曱基）丙細酸g旨共聚物（Α)之重量平均 分子量位處於前述範圍内，而在第2之（曱基）丙稀酸酉旨 共聚物（B)形成之三次元網目構造，良好地纏繞該第1之 (甲基）丙烯酸酯共聚物（A )，有助於良好之應力緩和性， 並且，和被附著體之密合性或者是在高熱·濕熱條件下之 接合耐久性係變得充分’能夠防止浮起或剝離等。 在此，在第1之（甲基）丙烯酸酯共聚物（A)之重量 平均分子量未滿70萬之時，降低（A)成分之凝集力，恐 怕會變差於耐久性及再工作性。此外，在第1之（曱基7 丙烯酸醋共聚物（A)之重量平均分子量超過25〇萬之時， 得到之钻著劑係過度硬，恐怕會無法得到要求之應力緩和 15 201122071 性。 % 2 ^ ( 曱基）内稀酸酉旨共聚物（B)相對於1〇〇質量 份之第1之r田篁、 、 旦 ）丙烯酸酯共聚物（A )之比例係5〜50 i伤最好是1〇〜3〇質量份。 比例而含有第1之（甲基）@烯酸酯共聚物 CA)和第？夕r w ^ \ 之（甲基）丙烯酸醋共聚物（Β)之粘著性組 ?物：得到之枯著劑’第2之（甲基）丙歸酸g旨共聚物⑴ ，分子量聚合物）係透過交聯劑⑴而形成三次元網目 化，在其三次元網目構造，藉由無交聯之第1之（曱基 丙稀酸醋共聚物（A)(古八·？旦取人44、 、幻（间刀子里汆合物）纏繞之構造而發 輝良好之硬力緩和性。並蕻 X且猎由一-人7L網目構造之存在 .維持得到之粘著劑之強度，因此，耐久性變高。 作為交聯劑（C)係最好是列舉異氛酸s旨^聯劑、環 氣系交聯劑、氮雜環丙烧系交聯劑、金屬f合系交聯劑等。 異氰酸醋系交聯劑係至少包含聚異合物。作 為聚異氣酸_化合物係列舉例如甲代苯撐二異氰酸酿、二 笨基甲烷二異氰酸酯、苯二甲基-里盖 τ暴—異乱酸酯等之芳香族聚 異氘酸酯、六亞甲基二異氰酸酯等 伽两族聚異虱酸酯、 異佛爾酮二異氰酸酯、加氫二苯基甲产_ 不丞1Ρ烷一異氰酸酯等之 環式聚異氰酸酯等、以及這此之输_服 曰 之細—脲、異氰酸酯體、甚 至乙烯乙二醇、丙二醇、新戊二醇、三 起'甲基丙烧、篦游201122071 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a method for producing an adhesive composition, an adhesive composition, a material (a material of a parent adhesive composition), and adhesion In particular, the present invention relates to a dry composition suitable for use as an optical member such as a polarizing plate, a method for producing an adhesive composition, a dot, and a tablet. [Prior Art] As in the case of a liquid crystal panel, a polarizing plate or a retardation plate is bonded to a glass substrate or the like, and an adhesive layer formed of an adhesive composition is often used. However, the optical member such as a polarizing plate or a phase difference plate is likely to shrink due to heat or the like, and therefore shrinks due to the heat history. As a result, it is pointed out that the adhesive layer laminated on the optical member cannot track its shrinkage. The interface is peeled off (so-called floating, peeling), or a problem occurs in light leakage (so-called whitening) caused by the deviation of the optical axis of the optical member due to the stress caused by shrinkage of the optical member. As a method for preventing this, a method of suppressing shrinkage of an optical member by bonding an adhesive layer having a high adhesive force and good formability to an optical member such as a polarizing plate or the like is 2) A method of using an adhesive layer having a small stress when the optical member is shrunk. As a method of (丨), as shown in Patent Document 1, an adhesive layer having a high storage modulus is used. On the other hand, as the method (2), an adhesive layer which is soft in response to deformation and which has a good stress relaxation property is effectively used. However, in the state in which an attempt is made to form such an adhesive layer having good stress relaxation, 4 201122071 must extremely reduce the density of the parent in the layer a. In such a case, there is a problem that the strength of the adhesive layer itself is lowered and the durability is deteriorated. Then, in Patent Document 2 to /Aminoethyl phthalate elastomer, the crosslinker composition of the binder layer is extremely reduced, and the light leakage resistance and durability are obtained in the adhesive layer. 'Using a plasticizer, a fluid sarcophagus, and a propylene-based adhesive to replace the density-moderately softened and imparted stress relaxation, in an attempt to use this [Prior Art Document] • [Patent Document] [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. In the case of the invention, the adhesive layer formed by adding an adhesive composition of a plasticizer or a fluid paraffin is used for the passage of time. The plasticizer or the fluid paraffin flows out, and various problems such as contamination of the liquid crystal cell occur. In addition, when the adhesive composition of the elastomer of the urethane is added, it is limited by the compatibility with other components, and the amount of the urethane elastomer is limited. Therefore, the stress relaxation property is improved. The improvement is insufficient, and the problem of white turbidity or the like occurs due to the compatibility of the propylene-based adhesive and the amino-based phthalic acid ethyl ester elastomer. 5 201122071 As described above, in the prior art, it is not easy to fundamentally improve the light leakage resistance and durability of the adhesive layer formed of the adhesive composition for an optical member. The present invention has been made in view of such a solid shape, and an object thereof is to provide an adhesive composition which is excellent in light leakage resistance and durability when applied to an optical member such as a polarizing plate, and the adhesive composition Manufacturing method, adhesive, and adhesive sheet. [Means for Solving the Problem] In order to achieve the above object, the first aspect of the present invention provides a punctuable composition comprising a first (weight group) having a weight average molecular weight of 70,000 to 250,000. A acrylate copolymer (A), a second (fluorenyl) acrylate copolymer (b) having a weight average molecular weight of 8,000 to 250,000, and a crosslinking agent (C) and the aforementioned (meth) acrylate The adhesive composition of the copolymer (b) in an amount of 5 to 50 parts by mass based on 100 parts by mass of the first (meth) acrylate copolymer (A), characterized in that the second (the second) The methyl acrylate copolymer (b) is a structural component comprising a functional group (bl) having high reactivity with the crosslinking agent (C), and is in the second (methyl) In the acrylate copolymer (B), the copolymer having a ratio of the monomer of more than 1% by mass, the first (fluorenyl) acrylate copolymer (A) does not contain the crosslinking agent (C) a reactive functional monomer as a structural component, or comprising and having a crosslinker C) lower than that of the reaction of the second (Yue-yl) acrylate-functional copolymer (B) of the functional group (BL) of () of the monomer, as a structure component (Invention 1). In the adhesive agent for crosslinking the adhesive composition of the above invention (Invention 1), 201122071 has been formed by crosslinking (B) with a low molecular weight copolymer (B) which is used as a plasticizer. The three-dimensional mesh structure constructs a high-molecular-weight copolymer (A) which is wound without cross-linking in its three-dimensional mesh structure, and exerts good stress relaxation. An adhesive sheet which is excellent in both light leakage resistance and durability when applied to an optical member such as a polarizing plate by using a drying agent having such good stress relaxation property. In the above invention (the invention, the (meth) acrylate copolymer (A) is preferably a monomer which does not contain a functional group having a south reactivity with the crosslinking agent (c). Structural composition (Invention 2). In the above invention (Invention 2), the functional group ((1) of the above-mentioned kth (meth)acrylic acid copolymer (1) and the aforementioned crosslinking agent (c) is preferably a low reactivity. The functional group (1) based on the above-mentioned (indenyl) acrylate copolymer (1) and the above-mentioned crosslinking agent (c) is a hydroxyl group, and the aforementioned crosslinking agent (c) is isocyanate The above invention (Invention 3), the above-mentioned:: ketone): The vinegar copolymer (A) preferably contains a slow-containing monomer Q~ as a monomer unit constituting the object (a dry film having Good reworkability. The invention is passed to the invention (Inventions 3 and 4). The second (the fluorenyl) propylene hydrazine (B) is preferably a hydroxy group-containing monomer. , as a monomer unit constituting the copolymer (August 5), thereby making the sticky sheet more durable, and the aforementioned invention 3 to 5), 3 of the above-mentioned isocyanic acid I-based crosslinking agent is preferably one of the isocyanate groups of the isocyanic acid (tetra) crosslinking agent relative to 201122071 j j _ 2nd (fluorenyl) The amount of the functional group (bl) of the acrylic acid acrylate copolymer (b) and the south reactivity of the above crosslinking agent (C) is 〇. 1 to 5 equivalents (Invention 6). Inventive 1 to 6), it is preferable to further contain a terpene coupling agent (D) (Invention 7). In the above invention (Invention 7), the content of the decane coupling agent (D) is preferably in comparison with the above 100 parts by mass of the (meth) acrylate copolymer (A) is 0.05 to 0.5 parts by mass (Invention 8). In the second ', the present invention provides a method for producing an adhesive composition, which is manufactured as described above. The method of the adhesive composition (Invention)~6), which comprises: performing a radical at a conversion ratio of 50 to 90% for the monomer constituting the first (meth)acrylic acid vinegar copolymer U) Polymerization to produce the first (meth) acrylate copolymer (1) process (1); in the presence of the first (meth) acrylate acid copolymer (1), Free radical copolymerization of a monomer remaining in the polymerization of the first (meth)acrylic acid vine copolymer (1) and a monomer having a high reactivity (Μ) with the crosslinking agent u), Process 2 (2) for producing the above-mentioned (meth) acrylate copolymer &(1); and Process (3) for adding the above-mentioned crosslinking agent (C) (Invention 9). In the above invention (Invention 9), the process (2) of producing the above-mentioned (meth)acrylic acid vinegar copolymer (Β) is preferably carried out at a conversion ratio of 7 〇 to 1 Torr. %, free for the monomer remaining in the polymerization of the first (meth)propane-copolymer (1) and the monomer having the high reactivity with the above-mentioned crosslinking agent 20118 201122071, Cbl) Base copolymerization (invention ι〇). In the state of the invention (Inventions 9, 1), it is preferable to further include the process of adding the aforementioned Shi Xiyuan coupling agent (D) in the state of producing the above-mentioned adhesive composition (Inventions 7, 8). 11). The third invention provides an adhesive which is crosslinked by the above-mentioned adhesive composition (Inventions 1 to 8) (Invention 2). In a fourth aspect, the present invention provides a dot-sheet, which comprises a substrate and a layer of a dry agent layer, which is characterized in that the adhesive layer is composed of the aforementioned adhesive (invention) 12) The composition (Invention 3). In the invention (1), the substrate is preferably an optical member (Invention 14). In the 5th 'The present invention provides an adhesive sheet. A four-part release sheet and a (four) sheet which is sandwiched between the release sheet and joined to the release layer of the release sheets of the two release sheets, and characterized in that the (four) agent is the aforementioned drill (Invention 15) Composition (Invention 15) θ [Effect of the Invention] The crosslinking agent of the dry composition of the present invention is conventionally obtained by using a low molecular weight copolymer which is used as a plastic agent. To form a high molecular weight structure which is crosslinked without cross-linking, a mesh structure of the factory, and a copolymer which is wound, and exhibits good stress relaxation. ^ By using a (four) agent having such good stress relaxation, When it is suitable for optical members such as polarizing plates, it is resistant to light. The money and durability are both good 201122071 [ EMBODIMENT OF THE INVENTION The following description of the embodiment of the present invention will be described. (Adhesive composition) The adhesive composition of the present embodiment contains the first one having a weight average molecular weight of 70,000 to 250,000. The acrylate copolymer, the second (fluorenyl) acrylate copolymer (B) having a weight average molecular weight of 8,000 to 250,000, and the crosslinking agent (C) preferably further contain a decane coupling agent (D). Further, in the present specification, the term "fluorenyl" acrylate means both acrylate and methacrylate. Other similar terms are also the same. The second (fluorenyl) acrylate copolymer (b) is The monomer having a functional group (bl) having high reactivity with the crosslinking agent (C) is used as a structural component. The composition ratio of the copolymer (B) of the monomer is more than 1% by mass. The (meth) acrylate copolymer (A) of the first embodiment does not contain a monomer having a functional group reactive with the crosslinking agent (C), and is a structural component 'or hydrazine and a crosslinking agent (C). The aforementioned functional group having lower reactivity than the second (fluorenyl) acrylate copolymer (B) The monomer of the functional group (ai) of bl) is used as a structural component. The above (meth) acrylate copolymer (A) or (B) is preferably an alkyl group having an alkyl group having a carbon number of 1 to 2 〇. a copolymer of a (mercapto) acrylate and a reactive functional group-containing monomer (containing a reactive functional group monomer) and other monomers used as required. In addition, the first (meth)acrylic acid vinegar The copolymer (A) is preferably a structural component which does not contain the reactive functional group-containing monomer. The alkyl group having an alkyl group as an ester moiety is 1 to 2 fluorene (mercapto) acrylic acid 10 201122071 series, for example (曱基)acrylic brewing, (mercapto) acrylic vinegar, X bauxite, acrylic acid, (meth) butyl acetonate, (meth) propylene pentane, (meth) acrylate Hexyl ester '(fluorenyl) hexyl hexyl acrylate, 2-ethylhexyl (meth) acrylate, isobutyl vinegar (meth) acrylate, (decyl) acrylic acid hexamethacrylate Lipid and so on. Anthracene vinegar, (decyl) decyl acrylate, (mercapto) '(meth) hexadecane hydride, (mercapto) propyl. These may be used alone or in combination of two or more. On the other hand, as the reactive functional group-containing single system, a monomer having a hydroxyl group in the molecule (hydroxy group-containing monomer), a monomer having a carboxyl group in the molecule (including a tetamine monomer), and a molecule are preferably used. A monomer having an amine group (an amine group-containing monomer) or the like. Examples of the hydroxyl group-containing monomer include 2-hydroxyethyl 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylic acid, and 2-hydroxybutyl (meth)acrylate. A (meth)acrylic acid hydroxyalkyl ester such as (meth) propylene 13 hydroxybutyl or (meth)acrylic acid 4-hydroxybutyl group. These systems may be used alone or in combination of two or more. Examples of the three repellent monomer series include ethylenically unsaturated carboxylic acids such as acrylic acid, methacrylic acid 'butene & maleic acid, itaconic acid, citraconic acid, and vinyl acetate. These systems may be used singly or in combination of two or more. As a series of amine-containing monomers, for example, aminoethyl (meth)acrylate, N,N-dimethylaminoethyl (meth)acrylate, (meth)acrylic acid 11 201122071 methyl)acrylic acid t-butyl Further, it is also possible to combine two or more kinds of N,N--fluorenylaminopropyl groups, and the like. These lines can be used separately. In addition, as the other monomer series, an aromatic ring having an aliphatic ring such as (meth)acrylic acid vinegar or (meth)acrylic acid ester such as (meth)acrylic acid cyclohexene (Amidyl) (tetra) non-crosslinkable acrylamide, styrene, etc., such as an acid ester, acrylamide, decyl acrylamide. These systems may be used alone or in combination of two or more. Further, the reactivity of the reactive functional group (al) monomer used in the first (meth) acrylate copolymer (A) and the (meth) acrylate copolymer (B) used in the second The choice of functional group (bl) monomer is determined by the reactivity of the crosslinker (C) used. The details are stated in the back. Here, the second (fluorenyl) acrylate copolymer (b) contains the reactive functional group (bl) monomer in an amount exceeding 丄 mass%, and the upper limit is usually 50% by mass. It is preferable to contain 3 to 40% by mass of the above-mentioned reactive functional group (bl) monomer, and particularly preferably 5 to 25% by mass. By containing the reactive functional group (bl) monomer in the above range ', and preferably the second (fluorenyl) acrylate copolymer (B), the degree of crosslinking is the same as that of the first The combination of the acrylate copolymer (A) and the stress relaxation property of the obtained primer are good. Further, the content of the reactive functional group (bl) monomer is 1% by mass or less. The second (indenyl) acrylate copolymer (B) is insufficiently linked. This reduces the longevity. On the other hand, when the content of the reactive functional group (bl) monomer exceeds 12 201122071 t 50 mass %, the parental relationship of the second (meth) acrylate copolymer (b) becomes excessive, I am afraid that this will reduce the suitability of the attachment to the attached body. Further, the upper limit of the content of the monomer having a reactive functional group (bl) is 40% by mass, so that the durability of the adhesive sheet is further improved. In the present embodiment, the second (meth)acrylate-based copolymer (B) may be used alone or in combination of two or more. The weight average molecular weight of the second (fluorenyl) acrylate copolymer (B) is 8,000 to 250,000, preferably 20,000 to 150,000. That is, the second (fluorenyl) acrylate copolymer (Β) is a low molecular weight polymer forming tool. Further, the weight average molecular weight of the present specification is determined by gel permeation chromatography (GPC). The value of stupid ethylene conversion. Since the weight average molecular weight of the second (fluorenyl) acrylate copolymer is within the above range, the adhesive composition of the present embodiment forms a unique three-dimensional mesh structure, which contributes to good stress relaxation. That is to say, in the second (fluorenyl) weight average molecular weight is less than 8 〇〇〇, a good three-dimensional network structure is not obtained, and the second (fluorenyl) acrylic acid vinegar copolymer (Β) When the weight average molecular weight exceeds 250,000, the compatibility is lowered, and the copolymer (A) and the copolymer (β) are not easily entangled, and it is not easy to form a mesh structure peculiar to the purpose, which is deteriorated in durability and Reworkability. The first (meth) acrylate copolymer ") is a structural component which does not contain a functional group having reactivity with a parent conjugate (C), or 13 201122071 which contains a crosslinking agent and a crosslinking agent (c) a steroid having a lower reactivity than the functional group (ai) of the aforementioned functional group (Μ) of the (meth) acrylate copolymer (B), as a structural component, and then preferably It is a structural component which does not contain the functional group which has the high reactivity with the crosslinking agent (C). The (meth) acrylate copolymer (A) of the first embodiment may not contain a monomer having a functional group reactive with the crosslinking agent (C), but contains a reactivity lower than that of the second (A) When the monomer of the reactive functional group (al) of the reactive functional group (b1) of the acrylate copolymer (b) is used, the second (meth) acrylate copolymer (B) and the crosslinking agent are promoted ( The reaction of c), or in the state of using the decane coupling agent (D), the reactive functional group (al) of the first (fluorenyl) acrylate copolymer (A) is reacted with the decane coupling agent (D). The alkoxymethyl sulfonyl group or the like can adjust the degree of aggregation of the bis(indenyl) acrylate copolymer (A), and the desired bonding property can be obtained. In the state in which the first (fluorenyl) acrylate copolymer (A) contains the reactive functional group (al) monomer, the content thereof is usually 2% by mass or less, preferably 15% by mass or less. In particular, it is preferable that the first (meth) acrylate copolymer (A) is excessively aggregated when the content of the reactive functional group (al) monomer exceeds 20% by mass. Will not be able to get the required stress mitigation. Further, the content of the reactive functional group (al) monomer is preferably 15% by mass or less from the viewpoint of imparting reworkability. The first (meth) acrylate copolymer (A) is preferably one which does not contain a acrylate copolymer having a reactivity equivalent to that of the crosslinking agent (c) in the molecule or more than that of the second (A14, 2011,201,071,071) acrylate copolymer. (B) a monomer having a functional group of a reactive functional group (bl), but it is assumed that, in the state of being contained, a monomer having a functional group in the molecule is preferably a copolymer (A) In the case of 1% by mass or less, particularly preferably 0.5% by mass or less. When the content of the monomer exceeds 1% by mass, the reaction of the second (fluorenyl) acrylate copolymer (B) and the crosslinking agent (C) which should be preferentially reacted may be hindered. In the present embodiment, the first (nonyl) acrylate copolymer (A) may be used singly or in combination of two or more. The weight average molecular weight of the first (meth) acrylate copolymer (A) is from 700,000 to 2.5 million', preferably from 1,000,000 to 2,000,000. That is, the first (fluorenyl) acrylate copolymer (Α) is a high molecular weight polymer component. The weight average molecular weight of the first (fluorenyl)propionic acid g copolymer (Α) is in the above range, and the second (fluorenyl) acrylate acid copolymer (B) is formed. The ternary mesh structure is excellent in winding the first (meth) acrylate copolymer (A), contributing to good stress relaxation, and adhesion to the adherend or in high heat and humidity conditions. The lower joint durability is sufficient to prevent floating, peeling, and the like. Here, when the weight average molecular weight of the first (meth) acrylate copolymer (A) is less than 700,000, the cohesive force of the component (A) is lowered, and the durability and reworkability may be deteriorated. Further, in the case where the weight average molecular weight of the thiol 7 acryl vinegar copolymer (A) exceeds 250,000, the obtained drilling agent is excessively hard, and the required stress relaxation may not be obtained 15 201122071. 2 ^ ( fluorenyl) internal dilute acid copolymer (B) relative to 1 〇〇 part by mass of the first r 篁, 旦) acrylate copolymer (A) ratio of 5 to 50 i injured most It is 1 〇 to 3 〇 mass parts. The ratio of the first (meth)@ enoate copolymer CA) and the first? Rrw ^ \ (meth)acrylic acid vinegar copolymer (Β) adhesion group: the obtained primer '2nd (meth) acryl acid g copolymer (1), molecular weight polymer) Through the cross-linking agent (1) to form a three-dimensional mesh, in its three-dimensional mesh structure, by the first without cross-linking (mercapto-acrylic acid vinegar copolymer (A) (an ancient eight · Dandan take people 44 , and illusion (the knives in the knives) entangled structure and shines well with the hard mitigation. And 蕻X and hunting by the existence of a one-man 7L mesh structure. Maintain the strength of the obtained adhesive, therefore, The durability is high. The crosslinking agent (C) is preferably an isomeric acid s-linking agent, a ring-based crosslinking agent, an azacyclopropene-based crosslinking agent, or a metal-containing crosslinking agent. The isocyanate-based cross-linking agent contains at least a polyisomer. As a polyisophthalic acid-compound series, for example, phenylene diisocyanate, diphenylmethane diisocyanate, benzodimethyl- Liga τ violent - aromatic polyisophthalic acid ester such as heteropolyester, hexamethylene diisocyanate, etc. Hydrogenated diphenyl-formaldehyde _ a cyclic polyisocyanate such as a non-monodecane monoisocyanate, and the like, and a fine-urea, isocyanate, or even ethylene glycol, propylene glycol, neopentyl glycol , three 'methyl propyl burning, travel

油等之和含低分子活性氫化合物 L <夂應物之加合體等。浐 些係可以單獨使用1種，並且，也 ^ 也了 U組合2種以上而 16 201122071 作為％氧系交聯 丙基胺基”)環己Γ ，3 苯二甲基二胺、乙烯乙: 二環氧丙基麵、 雙（N，N—二環氧 丨’ Ν，Ν ，Ν’ —四環氧丙基一m — :二環氧丙基醚、1，6—己烷二醇 以單獨使用1種，並且 苯胺、二環氧Η ^基Μ二環氧丙基越、二環氧丙基 虱兩基胺等。這些係可 也可以組合9 。2種以上而使用。 作為氮雜環丙烷系交 4, 4， ~雔w你列舉例如二苯基甲烷一 ， 又 氮雜環丙烷羧基醯胺）、二敍甲- 十氮雜環丙烧基丙酸酯、四…甲；："甲基丙院二 環丙院基丙酸醋、甲苯—24 :/基U-氮雜 . 本2,4—雙（ί —氮雜環丙烷羧基醯 胺）、二乙缚三聚氰胺、雙間苯二 if^^, ,0 W 甲基鼠雜 ~ — 1 一（2—甲基氮雜環丙烷）膦、三羥甲基 丙说三 ~~ β — ( C) w ^ 甲土氮雜環丙院）丙酸醋等。這些係可 以單獨使用！種’並且’也可以組合2種以上而使用-:、 在金屬螯合系交聯劑’有金屬原子為鋁、鍅、鈦、辞、 鐵錫等之螯合化合物，但是，由性能之方面來看的話， 則最好是鋁螯合化合物。作為鋁螯合化合物係列舉例如二 異丙氧基銘單油稀基乙醯乙酸醋、單異丙氧基銘雙油烯基 乙醯乙酸酯、單異丙氧基鋁單油酸酯單乙基乙醯乙酸酯、 二異丙氧基鋁單月桂基乙醯乙酸酯、二異丙氧基鋁單硬脂 醯乙醯乙酸酯、二異丙氧基鋁單異硬脂醯乙醯乙酸酯等。 這些係可以單獨使用1種，並且，也可以組合2種以上而 使用。 交聯劑（C )之含有量係最好是該交聯劑（◦)之交聯 17 201122071 為0.1〜5當量之量，特別最好是〇.2 述交聯性基之量未滿〇. 1當量 經時粘著力而變差於再工作性。 性基（例如異氰酸酯基）相對 共聚物（B)之反應性官能基 聯’在前述交聯性基之量超過 於第2之（曱基）丙烯酸酯 bl )(例如羥基）之量而成 當量之量。在前 恐怕會無法充分地進行交 當量時，恐怕會提高貼附 此外’在本實施形態，除了前述交聯劑（C)以外，也 可以在不損害本發明效果之範圍Θ ’併用反應性高於共聚 物（B)反應性官能基（bl)之共聚物（A)之反應性官能 基（al)之反應性之其他之交聯劑（指出在併用2種類以 上之交聯劑之狀態而除去其添加量最多之種類之交聯劑以 外之殘留之種類之交聯劑）^具體地說，在共聚物（a)之 反應性官能基（al)為羧基且共聚物（B)之反應性官能基 (bl )為羥基且交聯劑（c )為異氰酸酯系交聯劑之狀態下， 作為其他之父聯劑係可以添加少量之環氧系交聯劑。此種 其他交聯劑之添加係在共聚物（B)構成之三次元網目構 4，無充分地纏繞共聚物（A) ’有效於凝集力不足之狀態。 在添加其他交聯劑之狀態下，作為其添加量係最好是 相對於共聚物（A)及（B)之合計1〇〇質量份而成為〇. 〇1 〜1質量份。 在此’作為交聯劑（C)和（甲基）丙烯酸酯共聚物（A) 及（B )之各個之含反應性官能基單體之組合係在交聯劑（C ) 為異氰酸酯系交聯劑之狀態下，最好是選擇含羧基單體， 來作為共聚物（A)之含反應性官能基（ai)單體，選擇含 18 201122071 羥基單體或含胺基單體，來作為共聚物（B)之含反應性官 能基（bl)單體。 另一方面，在交聯劑（C)為環氧系交聯劑、氮雜環丙 院系交聯劑或金屬螯合系交聯劑之狀態下，最好是選擇含 羥基單體’來作為共聚物（A)之含反應性官能基（al)單 體，選擇含羧基單體，來作為共聚物（β)之含反應性官能 基（bl )單體。 因為形成在交聯劑（C )和共聚物（β )間之鍵之柔軟 性以及交聯反應之穩定性 '甚至共聚物（Β )之反應性基呈 適度地反應於矽烷偶合劑（D).而有助於共聚物（Β)之凝 集力提高，所以，特別最好是交聯劑（c)成為異氰酸酯系 乂聯劑’共聚物（A )之含反應性官能基（al )單體成為含 幾基單體’共聚物（β)之含反應性官能基（bl)單體成為 含羥基單體。 本實施形態之粘著性組成物係最好是還含有矽烷偶合 劑（D)。在含有該矽烷偶合劑（D )時，在第丄之（甲基） 丙稀酸i旨共聚物⑴具㈣基之狀態下，我偶合劑⑷ 之烷氧基甲矽烷基等和第！之（甲基）丙烯酸酯共聚物⑴ 之竣基發生反應，因此，可以調整第^ (甲基）丙煉酸 黯共聚物（A)之凝集程度’能夠得到要求之接合性。此外， 在含有镶合劑（D)時，例如在偏光板貼合於液晶玻璃 胞等之狀態下，枯著劑和液晶玻璃胞之間之密合性係變得 更加良好。 作為該我偶合劑⑴係在分子内具有至少i個烧氧 19 201122071 基甲石夕烧基之有機石夕化合物，和枯著劑成分之相溶性呈良 好，並且，具有光透過性，例如在實質上，適合為透明。 此種石夕烧偶合劑（D)之添加量係最好是相對於1〇〇質量份 之第1之（甲基）丙烯酸醋共聚物⑴而成為〇 〇5〜〇·5 質量份’特別最好是〇_1〜〇_3質量份。 作為石夕烧偶合劑（D)之具體例係列舉乙稀基三甲氧基 石夕院、乙烯基三乙氧基石夕烧、甲基丙稀酿基丙基三甲氧基 石夕院等之含聚合性不飽和基石夕化合物、3—環氧丙氧基丙基 三甲氧基矽烷、2- (3,4一環氧環己基）乙基三甲氧基矽 院等之具有環氧構造之石夕化合物、3—胺基丙基三甲氧基石夕 炫、N— (2-胺基乙基）_3—胺基丙基三甲氧基魏、n C 2 一 胺基乙基）一 3 ~ Hi： re, m ti- 胺基丙基甲基二甲氧基矽烷等之 含胺基矽化合物、3 -氯丙基三甲氧基矽烷等。這些係可以 單獨使用1種’並且，也可以組合2種以上而使用。 可以在前述钻著性組成物，由於要求而添加通常使用 於丙烯系枯著劑之各種添加劑、例如點著賦予劑、氧化防 止劑、紫外線吸收劑、光安定劑、軟化劑、填充劑、帶電 防止劑、折射率調整劑等。 [魅著性組成物之製造方法] 前述粘著性組成物係可以例如按照以下而進行製造。 也就是說H，最好是在後面敘述之聚合溶媒中， 分別在各個’藉由通常之自由基聚合法而調製（甲基）丙 稀酸酉旨共聚物⑴及（B)。接著，混合得到之兩共聚物 之溶液’加人稀釋溶媒而使得固態成分濃度成為1()〜4〇質 20 201122071 量％ 。在最後，藉由依序地添加交聯劑（c)及石夕燒偶合劑 (D )，充分地進行混合’而得到以溶媒來稀釋之粘著性組 成物。 此外，前述粘著性組成物係最好是藉由以下顯示之一 系列聚合而製造。 具體地說’ （1)以轉化率50〜90% ，對於構成第1 之（曱基）丙烯酸酯共聚物（A)之單體，進行自由基聚合， 在製造第1之（甲基）丙烯酸酯共聚物（A)之後；（2) 在前述第1之（甲基）丙烯酸酯共聚物（A)之存在下，對 於殘留在第1之（甲基）丙稀酸a|共聚物（A)聚合時之單 體以及具有和交聯劑（C)之高反應性之官能基（bi)之單 體以及由於要求而使用之其他單體，最好是以轉化率70〜 職’進行自由基共聚合，製造第2之（甲基）丙稀酸醋 :聚物⑻，接著；（3)添加交聯劑（c)及/或彻 合劑（D) ( (D)成分由於要求）。 構成製程（1)之第 帛 （曱基）丙烯酸酯共聚物（A) I旱體係正如前^ 之碳數為i 2n …最好是至少含有醋部分之烷基 r (2 2°之（甲基）两稀酸醋。在該狀態下，於製 ^ ( 2)，殘留在第i之（曱某 合時之單體係適…二)丙輪共聚物⑴聚 (甲基）丙稀酸酿。 ^之说基之“"〜2。之 前述—系列聚合係可以由 藉由溶液聚合法等而^ *求而使用聚合起始劑， 乙酯、乙酽 進仃。作為聚合溶媒係列舉例如乙酸 酯 甲苯、丙酮、己烧 g敲n~ 丁基、乙酸異丁 21 201122071 甲基乙基甲_等’可以併用2種類以上。 物等，可劑係列舉偶氮基系化合物、有機過氧化 例如2,2,—偶氮種：以上。作為偶氮基系化合物係列舉 偶氮—氮丁腈、2,2，一偶氮（2—甲基丁 , 偶氮（環己燒1-腈）、2, 2，_偶氮 基戊腈）、2 2，一但备μ 二甲 二甲基22，’ ^ ’甲基—4—甲氧基戊猜）、 ，2 —偶氮（2—曱基丙酸酯）、4, 4， ^ ；：氛基戊酸）、以，-偶氮（2_經基甲基丙腈）偶=4 偶氮[2~~ (2 —咪唑啉—2—醯）丙烷]等。 —作為有機過氧化物係列舉例如過氧化笨醯、t— 丁基全 ::酸龜、枯烯氫化過氧化物、二異丙基過氧化二碳酸醋、 二—n〜丙基過氧化二碳酸醋、二（2—乙氧基乙基）過氧 =碳酸S旨、t-丁基過氧化新癸酸、t—丁基過氧化特戊 酸酿、（3’5,5-三甲基己醯基）過氧化物、二丙酿基過氧 化物、二乙醯基過氧化物等。 在製程（3 )，最好是在添加交聯劑（c )和矽烷偶合 劑（D )兩者之狀態下，在分別藉由溶劑而稀釋交聯劑（[) 和石夕燒偶合劑（D)來成為規定之濃度後，依序地添加。 此外，在則述一系列聚合，適度地調整使用之各單體 之里而使得第丨之（甲基）丙烯酸酯共聚物（A)和第2之 (甲基）丙烯酸酯共聚物（B)之比值以及官能基之含有量 成為前述範圍。此外，適度地調整聚合條件而使得第丨之 (甲基）丙烯酸酯共聚物（A)和第2之（甲基）丙烯酸酯 共聚物（B)之重量平均分子量成為前述範圍。 22 201122071 [粘著劑] 本實施形態之粘著劑係交聯莫 士、‘ I. #引述枯者性組成物而組 成。别述枯著性組成物之交聯 ’、了以藉由加熱處理而進 仃。此外，該加熱處理係也可兼 衆具於揮發粘著性組成物 之稀釋溶媒等之時之乾燥處理。 。在進行加熱處理之狀態下’加熱溫度係最好是5。〜15。 特別最好疋70〜1 20 c。此外，加熱時間係最好是3〇 秒鐘〜3分鐘，特別最好是5〇秒鐘〜2分鐘。此外，特別 最好是在加熱處理後’於常溫（例如23t、5〇%RH)，設 置1〜2星期程度之養生期間。 藉由前述加熱處理（及養生），藉由交聯劑（c)而交 聯第2之（甲基）丙烯酸酯共聚物⑷’形成三次元網目 構造’同時，在其三次元網目構造…之（甲基）丙烯 酸醋共聚物⑴並無造成直接之化學鍵，或者是藉由極為 少之化學鍵而進行纏繞。此外’纟帛i之（曱基）丙烤酸 醋共聚物⑴具錢基之狀態下1 !之（甲基）丙稀酸 酯共聚物（A )係反應於矽烷偶合劑（D )而進行規定程度 之凝集。 以上說明之粘著劑係最好是可以使用作為光學構件 用’例如適合於偏光板和相位差板之接合或者是偏光板（偏 光膜）或相位差板（相位差膜）和玻璃基板之接合。藉由 刖述枯著劑而形成之點著劑層係具有非常良好之應力緩和 性’因此，即使是在被附著體之尺寸變化大之狀態下，也 能夠以枯著劑層，來吸收•缓和可以由於其尺寸變化而產 23 201122071 生之應力，所以，經過長期間而不容易由被附著體來剝離， 同時’在使用於前述光學構件時’可以有效地防止光漏。 也就是說’本實施形態之枯著劑係達成耐光漏性和耐久性 兩者。 [粘著片] 正如圖1所示，帛1實施形態之枯著片1A係藉著由下 面開始依序地剝離片12、層積於剝離片12之剝離面之粘 著劑層11和層積於粘著劑層丨丨之基材13來構造。， 此外，正如圖2所示，第2實施形態之㈣^ ΐβ係由 2片之剝離片12a、12b以及失持於該2片之剝離片心、 i2b而接合在這些2片之剝離片⑸、⑽之剝離面之枯著 劑層Η來構成。此外，本說明書之所謂剝離片之_面係 指在剝離片而具有剝離性之面，包含施行剝離處理之面以 及即使是不施行剝離處理也顯示剝離性之 Ί可—0 即使是在任何一種枯著片1Α、1Β，點 由交聯前㈣著性組成物而組成之㈣劑來構心 點者劑層U之厚度係配合㈣片1Α、 而適度地決定，但是，通當Α 使用目的 疋通吊為5〜l00#m，最好 "之範圍’例如在使料^學構件 卜 之粘著劑層之狀態下，最好θ j疋偏光板用 "m。 ^ 1〇〜5一’特別是10〜30 作為基材U係並無特别限制， 基材片係可以全部使用。例如除乍為通吊㈣片之 也可以列舉使用螺费絲：學構件以外， ““之纖維之織布或不 24 201122071 ::之=紙、玻璃紙、含浸紙、塗佈紙等之紙類；紹、 發泡體胺基甲酸乙醋發泡體、聚乙烯發泡體等之 稀對笨二甲酸醋、聚丁歸對笨二甲酸酿、聚 烯本-甲酸醋等之聚酉旨膜、聚胺基甲醆 膣、职工α 乙烯 、、“烯犋、聚氯乙烯膜、聚偏氯乙烯膜、聚乙烯醇膜、 乙稀乙酸乙、烯共聚物膜、聚笨乙稀膜、聚碳酸醋膜、丙 稀樹脂膜、原菠烷系樹脂膜、環烯烴樹脂膜等之塑膠獏； 廷些2種以上之層積體等。塑膠膜係可 二軸延伸。 心丁軸延伸或 作為光學構件係列舉例如偏光板（偏光膜）、偏光子、 相位差板（相位差膜）、視野角補償膜、亮度提升膜、對 t:提升膜等。即使是在其中，偏光板（偏光膜）係也容易 收縮尺寸受化大，因此，由耐光漏性之觀點來看的話， 則適合成為形成前述粘著劑層1 1之對象。 基材13之厚度係也由於其種類而不同，但是，例如在 光4構件之狀態下，通常為〜5〇〇#m，最好是证 〜300 // m。 作為剝離片1 2、12a、1 2b係使用例如聚乙烯膜、聚丙 烯膜、聚丁烯膜、聚丁二烯膜、聚曱基戊烯膜、聚氣乙烯 膜、氯乙烯共聚物膜、聚乙烯對苯二甲酸酯膜、聚乙烯苯 一甲酸酯膜、聚丁烯對笨二甲酸酯膜、聚胺基甲酸乙酯膜、 乙烯乙酸乙烯膜、離子鍵聚合物樹脂膜、乙烯·（甲基） 丙稀酸共聚物膜、乙烯·（甲基）丙烯酸酯共聚物膜、聚 苯乙烯膜、聚碳酸酯膜、聚醯亞胺膜、氟樹脂膜、液晶聚 25 201122071 合t膜等。此外，也使用這些之交聯膜。此外，也可以是 這些之層積膜。 乜疋 声11最之好輔離片之剝離面（特別是接合於點著劑 曰 之面），施行剝離處理。作為#田μ ^ 劑係列舉例如醇酸系氟。1離處理之剝離 婦煙系1系之剝離劑。ι系、不飽和聚醋系、聚 就剝離片12、12a、121)之 但是，通常A 20〜⑴ a而卜並無特別限制， 币馮心〜150/zm程度。 為了製造前述粘著片u, 面，塗佈包含前㈣著性組成物之溶液制;；片心=離 而㈣著劑層u之後，在其㈣劑層u，= =理 此外，就加埶處理2 g «積基材13。 :、處理之條件而言’正如前面之敘述。The sum of the oil and the like contains a low molecular weight active hydrogen compound L < an additive of the acantant and the like. These systems can be used alone or in combination with two or more U and 16 201122071 as a % oxygen-crosslinked propylamine group") cyclohexanyl, 3 benzenedimethyldiamine, ethylene B: Diepoxypropyl surface, bis(N,N-diepoxide oxime Ν, Ν, Ν'-tetraepoxypropyl-m-: diglycidyl ether, 1,6-hexane diol One type may be used alone, and an aniline, a diepoxy fluorenyl hydrazide propyl group, a diepoxypropyl fluorenyl amide group, etc. may be used in combination of two or more. Cyclopropane is 4, 4, ~雔w, for example, diphenylmethane-, azacyclopropanecarboxy decylamine, di-n-methyl-decahydropropionyl propionate, tetrazole; "Methylpropanol 2-cyclopropane-based propionic acid vinegar, toluene- 24:/based U-aza. 2,4-bis(ί-azetidinecarboxyguanamine), diethyl melamine, double Benzene di-if^^, , 0 W methyl-m-xan~-1 mono-(2-methylaziridine)phosphine, tris-hydroxymethylpropane three~~ β — (C) w ^ Cyclopropylamine) propionic acid vinegar, etc. These systems can be separate It is also possible to use two or more kinds of 'and' types -:, in the metal chelate crosslinking agent, a metal compound is a chelate compound of aluminum, ruthenium, titanium, rhodium, iron tin, etc., but by performance In terms of aspects, it is preferably an aluminum chelate compound. As a series of aluminum chelate compounds, for example, diisopropoxy oil, sulphuric acid, acenaphthyl acetate, monoisopropoxy Acetate, monoisopropoxy aluminum monooleate monoethyl acetoacetate, diisopropoxy aluminum monolaurylacetate acetate, diisopropoxy aluminum monostearate Acetate, diisopropoxy aluminum monoisostearate, acetonitrile acetate, etc. These may be used alone or in combination of two or more. The content of the crosslinking agent (C) Preferably, the crosslinking agent (◦) is crosslinked 17 201122071 in an amount of 0.1 to 5 equivalents, particularly preferably 〇. 2, the amount of the crosslinking group is less than 〇. 1 equivalent by time adhesion Poor reworkability. The reactive functional group of the group (for example, isocyanate group) relative to the copolymer (B) exceeds the amount of the crosslinkable group described above. The amount of (曱) acrylate bl) (for example, a hydroxyl group) is equivalent to an amount. In the case where it is feared that the cross-linking amount may not be sufficiently performed, the attachment may be improved. In addition, in the present embodiment, in addition to the aforementioned cross-linking In addition to the agent (C), it is also possible to use a reactive functional group (al) of the copolymer (A) having a reactivity higher than that of the copolymer (B) reactive functional group (bl) without impairing the effects of the present invention. Other cross-linking agent having reactivity (indicating that a cross-linking agent of a type other than the cross-linking agent having the most added amount in the state in which two or more kinds of cross-linking agents are used in combination is used) When the reactive functional group (al) of the substance (a) is a carboxyl group and the reactive functional group (b1) of the copolymer (B) is a hydroxyl group and the crosslinking agent (c) is an isocyanate crosslinking agent, the other is A small amount of an epoxy crosslinking agent can be added to the parent crosslinking agent. The addition of such other crosslinking agent is in the three-dimensional network structure 4 composed of the copolymer (B), and the copolymer (A) is not sufficiently wound to be effective in a state in which the cohesive force is insufficient. In the state in which the other crosslinking agent is added, the amount thereof is preferably 〇1 to 1 part by mass based on 1 part by mass of the total of the copolymers (A) and (B). Here, the combination of the reactive functional group-containing monomer as the crosslinking agent (C) and the (meth) acrylate copolymers (A) and (B) is an isocyanate-based crosslinking agent (C). In the state of the crosslinking agent, it is preferred to select a carboxyl group-containing monomer as the reactive functional group (ai) monomer of the copolymer (A), and select a hydroxyl group monomer or an amine group-containing monomer containing 18 201122071 as The reactive functional group (bl) monomer of the copolymer (B). On the other hand, in the state where the crosslinking agent (C) is an epoxy crosslinking agent, azacyclopropene crosslinking agent or a metal chelate crosslinking agent, it is preferred to select a hydroxyl group-containing monomer. As the reactive functional group (al) monomer of the copolymer (A), a carboxyl group-containing monomer is selected as the reactive functional group (bl) monomer of the copolymer (β). Because of the softness of the bond formed between the crosslinking agent (C) and the copolymer (β) and the stability of the crosslinking reaction, even the reactive group of the copolymer (Β) is moderately reacted with the decane coupling agent (D). Further, it contributes to an increase in the cohesive force of the copolymer (Β), and therefore it is particularly preferable that the crosslinking agent (c) becomes a reactive functional group (al) monomer of the isocyanate coupling agent 'A (A). The reactive functional group (bl) monomer which becomes a monomer-containing monomer 'β (β) becomes a hydroxyl group-containing monomer. The adhesive composition of the present embodiment preferably further contains a decane coupling agent (D). In the case where the decane coupling agent (D) is contained, the alkoxymethyl sulfonyl group of the coupling agent (4) and the like are in the state in which the (meth) acrylic acid (the) copolymer (1) has a (d) group. Since the thiol group of the (meth) acrylate copolymer (1) reacts, the degree of aggregation of the (meth) succinic acid ruthenium copolymer (A) can be adjusted to obtain the desired bondability. Further, when the setting agent (D) is contained, for example, in a state in which the polarizing plate is bonded to the liquid crystal cell or the like, the adhesion between the drying agent and the liquid crystal glass cell is further improved. The organic coupling agent (1) is an organic stone compound having at least i calcining oxygen 19 201122071 ketone group in the molecule, and has good compatibility with a dry agent component, and has light permeability, for example, In essence, it is suitable for transparency. The amount of the sulphur coupling agent (D) to be added is preferably 〇〇5 to 〇·5 parts by mass relative to 1 part by mass of the first (meth)acrylic acid vinegar copolymer (1). It is best to 〇_1~〇_3 parts by mass. As a specific example series of the Shixi siuchuan coupling agent (D), the polymerization property of ethylene trimethoxy zexiyuan, vinyl triethoxy zebra, methyl propyl propyl trimethoxy shixi, etc. An epoxy-based compound, such as an unsaturated cyclamate compound, 3-glycidoxypropyltrimethoxydecane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxyanthracene, 3-aminopropyltrimethoxyxanthene, N-(2-aminoethyl)_3-aminopropyltrimethoxywei, n C 2 monoaminoethyl)-3 ~ Hi: re, m An amine group-containing hydrazine compound such as ti-aminopropylmethyldimethoxydecane or the like, 3-chloropropyltrimethoxydecane or the like. These systems may be used singly or in combination of two or more. In the above-mentioned drilling composition, various additives generally used for the propylene-based drying agent, such as a spotting agent, an oxidation inhibitor, an ultraviolet absorber, a light stabilizer, a softener, a filler, and a charge, may be added as required. Preventing agent, refractive index adjusting agent, and the like. [Manufacturing Method of Charming Composition] The above-described adhesive composition can be produced, for example, as follows. Namely, it is preferable to prepare (meth)acrylic acid copolymers (1) and (B) in each of the polymerization solvents described later by the usual radical polymerization method. Next, the solution of the two copolymers obtained by mixing is added to a diluted solvent so that the solid concentration becomes 1 () to 4 〇 20 201122071 % by weight. Finally, by adding the crosslinking agent (c) and the ceramsite coupling agent (D) in this order, the mixing is sufficiently carried out to obtain an adhesive composition diluted with a solvent. Further, the above-mentioned adhesive composition is preferably produced by a series of polymerizations shown below. Specifically, (1) the monomer constituting the first (fluorenyl) acrylate copolymer (A) is subjected to radical polymerization at a conversion ratio of 50 to 90% to produce the first (meth)acrylic acid. After the ester copolymer (A); (2) in the presence of the first (meth) acrylate copolymer (A), for the (meth) acrylic acid a | copolymer remaining in the first (A) The monomer at the time of polymerization and the monomer having a high reactivity (bi) with the crosslinking agent (C) and other monomers used as required, preferably at a conversion rate of 70~ The base copolymerization is carried out to produce a second (meth)acrylic acid vinegar:polymer (8), followed by (3) a crosslinking agent (c) and/or a crosslinking agent (D) (the component (D) is required). The 帛(曱-based) acrylate copolymer (A) constituting the process (1) I has a carbon number of i 2n as the former, and preferably an alkyl group containing at least a vinegar moiety (2 2° (A) Base) two dilute acid vinegar. In this state, in the preparation of ^ (2), residual in the i (a single system suitable for a certain time) two-wheel copolymer (1) poly (methyl) acrylic acid The above-mentioned series-polymerization system can be used as a polymerization solvent by using a polymerization initiator, ethyl ester or ethyl hydrazine by a solution polymerization method or the like. For example, acetate toluene, acetone, hexanol butyl n-butyl, isobutyl acetate 21 201122071 methyl ethyl ketone, etc. may be used in combination of two or more types, and the like may be an azo-based compound. Organic peroxidation such as 2, 2, - azo species: above. As an azo-based compound series, azo-nitrobutyronitrile, 2,2, monoazo (2-methylbutyl, azo (cyclohexane) 1-nitrile), 2, 2,-azo valeronitrile, 2 2, but not dimethyl dimethyl 22, ' ^ 'methyl 4-methoxypenta), 2 - even Nitrogen Ester), 4, 4, ^;: aryl valeric acid), -, azo (2_ mercaptomethylpropionitrile), even = 4 azo [2~~ (2 - imidazoline-2-pyrene) Propane], etc. - as an organic peroxide series, for example, albino, t-butyl full: acid turtle, cumene hydroperoxide, diisopropyl peroxydicarbonate, di-n to C Base oxydicarbonate, di(2-ethoxyethyl)peroxy=carbonic acid, t-butyl peroxy neodecanoic acid, t-butyl peroxypivalic acid, (3'5, 5-trimethylhexyl) peroxide, dipropyl alcohol peroxide, diethyl hydrazine peroxide, etc. In the process (3), it is preferred to add a crosslinking agent (c) and a decane couple In the state of both the mixture (D), the crosslinking agent ([) and the sulphur coupling agent (D) are diluted with a solvent to form a predetermined concentration, and then sequentially added. Series polymerization, moderately adjusting the ratio of the monomer (meth) acrylate copolymer (A) and the (meth) acrylate copolymer (B) and the functional group Content becomes the aforementioned Further, the polymerization conditions are moderately adjusted so that the weight average molecular weight of the (meth) acrylate copolymer (A) and the (meth) acrylate copolymer (B) of the second oxime becomes the aforementioned range. [Adhesive] The adhesive of the present embodiment is composed of crosslinked Moss, 'I. # quoting the dry composition, and the cross-linking of the dry composition', by heat treatment Further, the heat treatment system may be subjected to a drying treatment in the case where a solvent or the like of the volatile adhesive composition is diluted. The heating temperature is preferably 5 in the heat treatment state. ~15. Especially best 疋70~1 20 c. Further, the heating time is preferably from 3 sec to 3 minutes, particularly preferably from 5 sec to 2 min. Further, it is particularly preferable to set a curing period of about 1 to 2 weeks at room temperature (e.g., 23t, 5〇% RH) after the heat treatment. By the above heat treatment (and maintenance), the second (meth) acrylate copolymer (4) is crosslinked by the crosslinking agent (c) to form a three-dimensional network structure 'at the same time, in its three-dimensional mesh structure... The (meth)acrylic acid vinegar copolymer (1) does not cause a direct chemical bond or is entangled by a very small number of chemical bonds. In addition, the '(i) ketone vinegar copolymer (1) has a hydroxyl group, and the (meth) acrylate copolymer (A) is reacted with the decane coupling agent (D). A defined degree of agglutination. The adhesive agent described above is preferably used as an optical member, for example, for bonding of a polarizing plate and a phase difference plate or bonding of a polarizing plate (polarizing film) or a phase difference plate (retardation film) and a glass substrate. . The dot layer formed by arranging the drying agent has very good stress relaxation property. Therefore, even in the state where the size of the adherend changes greatly, it can be absorbed by the layer of the coating agent. The relaxation can produce a stress of 23 201122071 due to the dimensional change thereof, so that it is not easily peeled off by the adherend after a long period of time, and at the same time, 'when used in the aforementioned optical member', the light leakage can be effectively prevented. That is to say, the binder of the present embodiment achieves both light leakage resistance and durability. [Adhesive sheet] As shown in Fig. 1, the dried sheet 1A of the 帛1 embodiment is obtained by sequentially peeling the sheet 12 from the lower side and laminating the adhesive layer 11 and the layer laminated on the peeling surface of the release sheet 12. It is constructed by a substrate 13 which is deposited on the adhesive layer. Further, as shown in Fig. 2, the (four) ΐβ system of the second embodiment is bonded to the two release sheets (5) by two release sheets 12a and 12b and a release sheet core and i2b which are lost to the two sheets. (10) The peeling surface of the peeling surface is composed of a layer of the coating agent. In addition, the surface of the peeling sheet of the present specification means a surface having a peeling property on a release sheet, and includes a surface subjected to a release treatment and exhibiting releasability even without performing a peeling treatment - even in any one The thickness of the film is 1 Α, 1 Β, and the (4) agent consisting of the cross-linking composition before the cross-linking (4) agent is used to form a layer. The thickness of the layer U is matched with (4) 1 Α, and is moderately determined, but the purpose of use is疋通吊为为5〜l00#m, preferably the range of ', for example, in the state of the adhesive layer of the material member, preferably θ j 疋 polarizer with " m. ^1〇~5一' In particular, 10~30 The substrate U is not particularly limited, and the substrate sheet can be used in its entirety. For example, in addition to the 吊 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ; Shao, foaming amine hydroxyacetate foam, polyethylene foam, etc., such as dilute dibenzoic acid vinegar, polybutyric acid, stearic dicarboxylic acid, polyene, formic acid, etc. , polyaminomethazine, workers α ethylene, “olefin oxime, polyvinyl chloride film, polyvinylidene chloride film, polyvinyl alcohol film, ethylene glycol, olefin copolymer film, polystyrene film, poly a plastic carbonate film such as a carbonated vinegar film, an acryl resin film, a raw spinel resin film, or a cycloolefin resin film; a laminate of two or more kinds thereof; the plastic film may be biaxially stretched. Examples of the optical member include a polarizing plate (polarizing film), a polarizer, a phase difference plate (retardation film), a viewing angle compensation film, a brightness enhancement film, a pair of t: a lift film, etc. Even in the case, a polarizing plate (polarizing film) The system is also easy to shrink, and the size is greatly increased. Therefore, from the viewpoint of light leakage resistance, The thickness of the substrate 13 is also different depending on the type thereof. However, for example, in the state of the light 4 member, it is usually 〜5〇〇#m, preferably证~300 // m. As the release sheet 1, 2, 12a, 1 2b, for example, a polyethylene film, a polypropylene film, a polybutene film, a polybutadiene film, a polydecyl pentene film, a polyethylene film is used. , a vinyl chloride copolymer film, a polyethylene terephthalate film, a polyvinyl benzoate film, a polybutene phthalate film, a polyurethane film, an ethylene vinyl acetate film, Ionomer polymer resin film, ethylene·(meth)acrylic acid copolymer film, ethylene·(meth)acrylate copolymer film, polystyrene film, polycarbonate film, polyimide film, fluororesin Membrane, liquid crystal poly 25 201122071 combined with t film, etc. In addition, these crosslinked films are also used. In addition, these may be laminated films. The best part of the squeaking 11 is the peeling surface of the auxiliary film (especially the bonding Stripping treatment is applied to the surface of the agent. As the #田μ^ agent series, for example, alkyd-based fluorine is used. It is a stripping agent for the stripping system of the flue-cured tobacco system. The ι-based, unsaturated poly- vinegar-based, poly-pure-off sheets 12, 12a, 121), but usually A 20~(1) a is not particularly limited, To the extent of ~150/zm. In order to manufacture the aforementioned adhesive sheet u, the surface is coated with a solution containing the former (four) composition; the core is separated from the (iv) coating layer u, and in the (four) layer u, = In addition, it is treated by adding 2 g «product substrate 13. :, the conditions of the treatment 'as described above.

’為了製造前述枯著片1B 離片12a(或12M夕在某一邊之剝 兄1 Zb )之剝離面，塗佈 之塗佈溶液，在進彳 ，述粘者性組成物 其枯著劑層^，重#其他邊之_ 12;層1之後’在 離面》 a (或12a)之剝 作為用Μ稀釋枯著性組成物而成 劑係使用例如己燒、庚院、環己炫布:; 夜之稀釋洛 二甲苯等之芳香族煙、二氣甲烧、，肪_、甲苯、 甲醇、乙醇、丙酶 ' I乙烷等之鹵化烴、 丙醇、丁醇、1—甲氣其 9 丙酮、甲基乙基甲酮9 Τ氧基-2-丙醇等之醇、 暴曱_、2-戊酮、異佛爾 乙酸乙醋、乙酸丁 _ %己®^之酮、 劑等。 曰_曰、 洛纖劑等之溶纖劑系溶 26 201122071 作為像這樣調製 -^ 表之丄佈溶液之濃度•粘度係 夠塗佈之範圍即可， f Ύ ^是能 址.s — 並無特別限制，可以配合狀况 選疋。例如進行稀經；& 、度 逆仃稀釋而使得粘著性組 〜4〇質量％ 。此外， 辰屋成為10 ^ 在侍到塗佈溶液之際，稀釋溶 添加係並非必要條件， 合則寻之 如果粘著性組成物為可塗佈t # 4的話，則可w τ .、* , 土即 < 拈度 、加稀釋溶劑。在該狀態下，粘菩 成物係直接成為塗佈〉容液。 者性組 作為塗佈前述塗佑,竹 . 佈/奋液之方法係可以利用例如椁你# 佈法、刮刀塗佈法、麼 杯條塗 '，，、相凹版印刷塗佈法等。 、布法、 在此，例如為了製造由液晶胞和偏光板而 顯示裝置，因此，可以佶 之液日日 使用偏光板，來作為粘著片u 材1 3 ’剝離該4U：发μ t A <暴 該枯者片1A之剝離片12， 層11和液晶胞。 <枯者劑 此外’例如為了贺；止Αs ! 兰4 k在液日日胞和偏光板之間配置相你 差板之液晶顯示裝置，闵！_μ _ Α 位 裝置因此，可以剝離粘著片1β :T12a(或i2b)，貼合露出之-著劑層 接者’剝離其他邊之剝離片12b (或12a)，貼八/曰 之粘著劑層11和相位差柘 〇路出 P 1A . ^ ，並且’剥離使用偏光板之粘著 片1A之剝離片]_2，來_彳纟著 來作為基材13，貼合露出之 11和相位差板。 #劑層 如果藉由以上之枯著片1Α、1Β的話， 具有非常良好之應力緩和性，因此，例如即使是在適二丨 偏先板之接合之狀態下’也可以藉著點著劑層η而吸收： 27 201122071 緩和能夠由於偏光板之變形來產生之應力，藉此而發揮良 好之耐光漏性以及高度之耐久性。 谷易理解本發明而記載 因此，揭示於前述實施 之技術範圍之全部之設 以上說明之實施形態係為了 的’並非記載而用以限定本發明。 形態之各要素係也包含屬於本發明 計變更或均等物之要旨。 例如可以省略粘著片j A 省略枯著片1B之剝離片12 a 【實施例】 之剝離片1 2，並且，也可以 、12 b之任何一種。 .在以下’藉由實施例等而更加具體地說明本發明，彳 是’本發明之範圍係並非限定於這些實施例等。 [實施例1] 1.製程（1) 在包括攪拌機、溫产斗 π、ώ入'In order to manufacture the peeling surface of the above-mentioned dry sheet 1B from the sheet 12a (or 12M on one side), the coating solution is applied, and the adherent layer of the adhesive composition is described. ^,重#Other side _ 12; After layer 1 'beyond the surface' a (or 12a) stripping as a dilution of the dry composition with hydrazine, such as hexane, Gengyuan, Cycloheximide :; nighttime dilution of aromatic xylene such as xylene, dioxane, fat, toluene, methanol, ethanol, propane 'I ethane and other halogenated hydrocarbons, propanol, butanol, 1-methyl The alcohol of 9 acetone, methyl ethyl ketone 9 decyloxy-2-propanol, sputum _, 2-pentanone, isophoric acid ethyl acetate, butyl acetate _% hexane ketone, agent Wait.溶 曰 曰 洛 洛 洛 洛 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 There is no special restriction and it can be selected in accordance with the situation. For example, the thinning; & degree, the reverse 仃 dilution makes the adhesion group ~ 4 〇 mass%. In addition, Chen House becomes 10 ^. When the coating solution is applied, it is not necessary to dilute the dissolved addition system. If the adhesive composition is coatable t # 4, then w τ ., * , soil is < 拈 degree, add dilution solvent. In this state, the succulent system directly becomes a coating liquid. The group is coated with the above-mentioned coating, and the method of bamboo cloth/exciting liquid can be, for example, 椁 椁 # # # # 刮 刮 刮 刮 刮 刮 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 In this case, for example, in order to manufacture a display device composed of a liquid crystal cell and a polarizing plate, the polarizing plate can be used as a bonding material, and the 4U can be peeled off as a bonding material u 3 : a μ t A <The peeling sheet 12, layer 11 and liquid crystal cell of the dry film 1A. <The dry agent In addition, for example, for the congratulation; Α s! Lan 4k is arranged between the liquid Japanese and the polarizing plate, the liquid crystal display device of your difference, oh! _μ _ Α position device, therefore, the adhesive sheet 1β : T12a (or i2b) can be peeled off, and the exposed lacquer splicer 'peeles off the other side of the peeling sheet 12b (or 12a), sticking the octagonal adhesion The agent layer 11 and the phase difference path P 1A . ^ , and 'peeling off the release sheet of the adhesive sheet 1A using the polarizing plate 1', are used as the substrate 13, and the exposed 11 and phase are adhered. Bad board. The agent layer has very good stress relaxation property by the above-mentioned dry film 1 Α, 1 ,, and therefore, for example, even in the state of bonding the slabs of the second slabs, it is possible to η absorption: 27 201122071 The stress generated by the deformation of the polarizing plate is alleviated, thereby achieving excellent light leakage resistance and high durability. The invention is described in the above-described embodiments, and the embodiments described above are intended to be illustrative of the invention. Each element of the form also includes the gist of the change or equivalent of the present invention. For example, the adhesive sheet j A may be omitted, and the release sheet 12 a of the dried sheet 1B may be omitted. [Example] The release sheet 1 2 may be any one of 12 b. The present invention will be more specifically described by the following examples, and the scope of the present invention is not limited to the embodiments and the like. [Example 1] 1. Process (1) Including mixer, temperature production π, intrusion

Μ 又°十、回 '他冷卻器、滴下裝置及I 導入官之反應容器，步 裝入n~ 丁基丙烯酸酯97. 〇 丙烯酸3. 0質量份、系_ , 買置伤、叫15G.G質量份和2,2， 氮丁腈0.06質量份，择 虱- 精田氮氣而取代前述反應容器内 氣。在該氮氣氛下中，推被灿 益円之二 fin°r , y- is m 仃攪拌，同時，升溫反應溶液至 C ’在反應6小時之後 又今部至室溫為止。在此，藉由 後面敘述之方法而對於 $，砝^ Θ τ 了於侍到之溶液之一部分，進行GPC測 疋確§忍重$平均分子 萬之共聚物（A)之生成。此 外，此時之轉化率（卺八^ ^ m ^ A m i·! Λ 13早體而得到之共聚物之質量除以 使用作為原料之單體 2.製程（2) 、、“量之值）係m。 28 201122071 在藉由前述製程（1)而得到之共聚物（A)之溶液， 添加曱笨150質量份、2—羥基乙基丙烯酸酯2.2質量份和 2,2’ ~偶氮（2,4_二甲基戊腈）〇.50質量份，升溫至7〇 C ’在反應6小時之後’冷卻至室溫為止。在此，再度對 於得到之溶液之一部分，進行GPC測定，確認在前述共聚 物（A )之重量平均分子量1 5〇萬之波峰頂部幾乎無變化發 生’同時’藉著由此次之GPC測定之結果，來扣除製程（1 ) 之GPC測定之結果，而確認新的重量平均分子量4萬之共 聚物（B)之生成。在該溶液’加入乙酸乙酯，得到固態成 分23· 0質量％之丙烯系聚合物溶液（共聚物（A)和共聚 物（B)之混合物之溶液）。在此，共聚物（A)和共聚物 (B)之混合比係由於前述製程（n之轉化率為8〇%而成 為80: 20之質量比。 3·製程（3 ) 分取藉由前述製程（2)而得到之丙烯系聚合物溶液 固態成分換算10。質量份，#由曱基乙基曱酮，來進行稀 釋而成為固態成分濃度20質量％。接著，作為交聯劑（c) 係添加相當於共聚物⑷之羥基i當量之量之三羥甲基丙 院之曱代苯擇二異氰酸醋（TDI系、）附加物（日本聚胺基 甲酸乙s旨公司製、商品名稱「KGr〇nate l」）。在最後， 作為钱偶合劑（D)係藉由添加3—環氧丙氧基丙基三甲 氧^院（信越化學公51製、商品名稱「Κβ咖」）之〇·2 質量份’充分地進行攪拌，而得到粘著性組成物之稀釋溶 液。 29 201122071 % 在此，將該粘著性組成物之練合，顯示於表1。此外， 記載於表1之縮寫等之細節係正如以下。 [共聚物（A)及（B)] BA: η — 丁基丙烯酸酯 ΑΑ :丙稀酸 ΗΕΑ : 2 —羥基乙基丙烯酸酯 ΗΒΑ : 4 —羥基丁基丙烯酸酯 ΗΕΜΑ : 2 —羥基乙基甲基丙烯酸酯 DEM:甲基丙烯酸ν，Ν—2—二曱基胺基乙基 [交聯劑（C )] •異氰酸酯系交聯劑 TDI系：三羥甲基丙烷之甲代苯撐二異氰酸酯附加物 (日本聚胺基甲酸乙酯公司製、商品名稱「K〇r〇nate L」） 異氣酸醋系：六亞曱基二異氰酸酯之異氰酸酯體（日 本聚胺基甲酸乙酯公司製、商品名稱「K〇r〇nate HXR」） •其他之交聯劑（環氧系交聯劑）Μ and then ten, back to the 'his cooler, drip device and I introduced the official reaction vessel, stepped into n ~ butyl acrylate 97. 〇 acrylic acid 3. 0 parts by mass, _, buy wounds, called 15G. G parts by mass and 0.06 parts by mass of 2,2, nitrogen butyronitrile, instead of the above-mentioned reaction vessel internal gas. Under the nitrogen atmosphere, the two fins, y-is m 推 were stirred, and the reaction solution was heated to C ′ after 6 hours of reaction and then to room temperature. Here, the formation of the copolymer (A) by GPC measurement and the weighting of the average molecular weight is performed for a part of the solution of $, 砝^ Θ τ by the method described later. In addition, the conversion rate at this time (卺8^^m ^ A mi·! Λ 13 early body obtained by dividing the mass of the copolymer by the use of the monomer as a raw material 2. Process (2), "the value of the amount" 28 201122071 In the solution of the copolymer (A) obtained by the aforementioned process (1), 150 parts by mass of hydrazine, 2.2 parts by mass of 2-hydroxyethyl acrylate, and 2,2'-azo ( 50 parts by mass of 2,4-dimethylvaleronitrile), and the temperature was raised to 7 ° C. ' After 6 hours of reaction, 'cooled to room temperature. Here, GPC measurement was again performed on one part of the obtained solution. There is almost no change in the top of the peak of the weight average molecular weight of the copolymer (A) of 15 million. 'At the same time, the result of GPC measurement by the process (1) is subtracted from the result of the GPC measurement of this process, and it is confirmed. A new copolymer of weight average molecular weight of 40,000 (B) is produced. In this solution, ethyl acetate is added to obtain a propylene-based polymer solution (copolymer (A) and copolymer (B) having a solid content of 23.0% by mass. a solution of the mixture). Here, the mixing ratio of the copolymer (A) and the copolymer (B) In the above process (the conversion ratio of n is 8〇% and the mass ratio is 80: 20. 3. Process (3) The propylene-based polymer solution obtained by the above process (2) is converted into a solid content of 10. And the content of the solid component is 20% by mass. Then, as the crosslinking agent (c), a trimethylol group corresponding to the hydroxyl group i equivalent of the copolymer (4) is added.丙 曱 曱 择 择 择 择 异 异 异 T T T T ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( 丙 丙 丙 丙 丙 丙 丙) Adhesive composition was obtained by adding 3 parts by mass of 2-glycidoxypropyltrimethoxide (Shin-Etsu Chemical Co., Ltd., product name "Κβ咖") 29 201122071 % Here, the adhesion of the adhesive composition is shown in Table 1. Further, the details of the abbreviations and the like described in Table 1 are as follows. [Copolymer (A) and ( B)] BA: η — Butyl acrylate ΑΑ : 丙 丙 : 2 — Hydroxyethyl acrylate ΗΒ : 4 -Hydroxybutyl acrylate ΗΕΜΑ : 2 -Hydroxyethyl methacrylate DEM: methacrylic acid ν, fluoren-2-yl decylaminoethyl [crosslinking agent (C )] • Isocyanate crosslinking TDI: a phenylene diisocyanate addendum of trimethylolpropane (manufactured by Japan Polyurethane Co., Ltd., trade name "K〇r〇nate L") Isocyanate of diisocyanate (manufactured by Japan Polyurethane Co., Ltd., trade name "K〇r〇nate HXR") • Other crosslinking agent (epoxy crosslinking agent)

信越化學 N’N’N , N —四環氧丙基一m—苯樓二甲基 菱瓦斯化學公司製、商品名稱「TETRAD — X」） [矽烷偶合劑（D )] KBM403: 3 —環惫 $ 备 m ^ w 展乳丙氧基丙基二甲氣基石夕烧 公司製、商品名稱「KBM403」） KBE9007: 3-異氰自㈣旨丙基三乙氧基錢 公司製、商品名稱「KBE9007」） °化學 K B E 4 0 3 · 3 〜捲 環氣丙氧基丙基三乙氧基矽燒 V 越化學 30 201122071 公司製、商品名稱「KBE403」） 一在藉由刮刀塗敷器而塗佈得到之枯著性組成物之稀釋 :液於藉由矽s同系剝離劑來對於聚乙烯對苯二甲酸酯膜之 早面進行剝離處理之剝離片（Lingteck公司製、sp — PET3811、厚度：38//m)之剝離處理面而使得乾燥後之厚 2成為之後，在紙’進行丄分鐘之加熱處理 成粘著劑層。 接著，藉著貼合由附有盤狀液晶層之偏光膜之所组成 =光膜和視野角擴大膜呈一體化之偏光板而接合枯著劑 狀液曰曰層，在23C、50%之RH，進行7日之養生， 而得到附有粘著劑層之偏光板。 [實施例2〜34、比較例卜6] =了調整反應條件錢得共聚物（A)之轉化率成為表 之:時改變各單體之添加量而使得構成㈣性組成物 !而^造^Γ成為表1之值以夕卜，其餘係相同於實施例 裏&附有粘著劑層之偏光板。Shin-Etsu Chemical N'N'N, N-tetraepoxypropyl-m-phenylene dimethyl sulphide chemical company, trade name "TETRAD — X") [decane coupling agent (D)] KBM403: 3 - ring惫 ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ K K K K K K KBE9007") °Chemical KBE 4 0 3 · 3 ~ Coiled aeropropyloxypropyl triethoxy oxime V Yue Chemical 30 201122071 Company-made, trade name "KBE403") One coated by a knife applicator Dilution of the dry composition obtained by the cloth: a peeling sheet for peeling off the early surface of the polyethylene terephthalate film by a 矽s homologous release agent (manufactured by Lingteck, sp-PET 3811, thickness) After the peeling treatment surface of :38/m) was made to have the thickness 2 after drying, the paper was subjected to heat treatment for a minute to form an adhesive layer. Then, by bonding a polarizing plate composed of a polarizing film with a disk-shaped liquid crystal layer and a light-shielding film and a viewing angle-enlarging film, the liquid-like liquid layer is bonded, at 23 C, 50%. RH, for 7 days of maintenance, and obtained a polarizing plate with an adhesive layer. [Examples 2 to 34, Comparative Example 6] = Adjusting the reaction conditions The conversion ratio of the copolymer (A) was expressed as follows: when the amount of each monomer was changed, the composition of the (four) composition was formed. ^Γ becomes the value of Table 1, and the rest are the same as in the embodiment, the polarizing plate with the adhesive layer attached.

[實施例3 5 J 和丙2 之聚合方法’共聚合丙稀酸丁酷97質量份[Example 3 Polymerization Method of 5 J and C 2] Copolymerization of 98 parts by mass of butyl acrylate

測定）2質量份’而得到重量平均分子量150萬（GPC )之共聚物u)。同樣地，藉由妓 90晳I /八i 日田，、策合兩烯酸丁醋 、重知和丙烯酸2 —羥基乙酯丨〇質量、 均分子量4萬⑽測定）之共聚物而得到重量平 ::得到之共聚物⑴之8。質量份和共聚物⑷之 …藉由甲基乙基甲嗣來進行稀釋而成為固態成分 31 201122071 相同於實施例 使用該粘著性 附有粘著劑層 濃度20% ，得到丙烯系聚合物溶液。然後， 1而得到粘著性組成物之稀釋溶液。接著， 組成物之稀釋溶液，相同於實施例丨而製造 之偏光板。 [試驗例1 ](枯著力之測定—再工作性之評價） 由在實施例或比較例來得到之附有粘著劑層之偏光 板’切出25龍幅寬、10_長之樣本，剝除剥離片，在透 過露出之粘著劑層而貼附於無鹼玻璃 -)之後，藉由栗原製作所公司製之高，鋼而在=; 50C，進行20分鐘之加壓。然後，在抓、5〇% rh之條 件下而放置24小時之後，使用抗拉試驗機公 司裝Tensil〇n)，按照jIS z 〇237，以剝離速度3〇〇腿 剝離角度180度之條件，來測定點著力（N/25mm)。 此外在23 C、50% Rfj之條件下而放置14曰之後， 相同於前面之敘述而測定枯著力（貼附14曰後之㈣力； N/25mm)。此外，理相夕, Γ理想之粘著力之範圍係0. lN/25mm以 上、25N/25mm 未滿。 之基準而進 ◎ 未滿25Ν/ 根據前述貼附14日後之枯著力，藉由以下 行再工作性之評價。將結果顯示於表2。 貼附14日後之點著力為20N/25mm以下： 貼附14日後之軲著力為超過20N/25mm、 25mm :〇 貼附14日後之點著力為25N/25inm以上：χ [試驗例2](凝膠分率之測定） 32 201122071 使用藉由矽酮系剝離劑 之單面進行制Μ#% +於聚乙烯對苯二甲酸酯膜 心早tu進仃剝離處理之剝離 PET·!、厚度：…幻，來=gteck公司製、SP — 用於附有枯著劑層之偏光代在貫施例或比較例而使 具體地說，藉由在實《I 偏光板，製㈣著片。 稽田在貫鉍例或比 粘著劑層上，声積前过' 4丨 # 之厚度25 " m之 f槓刚述剝離片而垃 作由制離《 / ^ _ 乃而接合剝離處理面側，來製 作由剝離4人㈣劑層/ 在_、5叫條件下:構…成之㈣片。 7曰之春^ y 下，對於得到之粘著片，進行 養生。然後，對於該粘菩 之尺十，直^ ’取樣成為80mmx80mm 之尺寸’其粘著劑層包裝於 ,由浐穷η 於製網目（網目尺寸200 )， 籍由精在天平而僅秤量粘曰 M1。 考之貝1。以此時之質量作為 使用索克斯累特（s〇xhl r s )回流萃取器，在乙酸 “曰浴劑’浸潰枯著劑之樣本 “ 處理。鈇德^ ^ 進仃回机，進行16小時之 環境下1乾24小時，並且^度咖、相對濕度5〇%之 小時。藉由精密天平而僅蘇胃。8〇。之烤箱中’乾燥12 ,,* 秤量乾燥後之粘著劑之質量。以 此時之質量作為M2。凝朦八玄/The measurement was carried out in an amount of 2 parts by mass to obtain a copolymer u) having a weight average molecular weight of 1.5 million (GPC). Similarly, the weight is obtained by a copolymer of 90 Å I / 八i Hita, butyl acetoate, and 2, hydroxyethyl acrylate, and a molecular weight of 40,000 (10). :: 8 of the obtained copolymer (1). The parts by mass and the copolymer (4) are diluted with methyl ethylformamidine to form a solid component 31 201122071 The same as the embodiment, the adhesive is used with an adhesive layer concentration of 20% to obtain a propylene-based polymer solution. . Then, 1 , a diluted solution of the adhesive composition was obtained. Next, a diluted solution of the composition was prepared in the same manner as in the example of the polarizing plate. [Test Example 1] (Measurement of dryness - evaluation of reworkability) A sample of 25 auger width and 10 mm length was cut out from the polarizing plate with the adhesive layer obtained in the examples or the comparative examples. The peeling sheet was peeled off, and after being adhered to the alkali-free glass through the exposed adhesive layer, the steel was pressed at a temperature of 50 ° C for 20 minutes by a steel produced by Kurihara Seisakusho Co., Ltd. Then, after being placed under conditions of scratching and 5〇% rh for 24 hours, Tensil〇n) was used by a tensile tester, and according to jIS z 〇237, the peeling speed was 3, and the leg peeling angle was 180 degrees. To measure the point (N/25mm). Further, after placing 14 在 under the conditions of 23 C and 50% Rfj, the dryness was measured in the same manner as the above description (the force after attaching 14 ;; N/25 mm). In addition, the reason for the ideal adhesion is 0. lN/25mm or more, 25N/25mm is not full. On the basis of the standard ◎ less than 25 Ν / According to the above-mentioned 14 days after the attachment, the following work re-workability evaluation. The results are shown in Table 2. After the 14th day of attachment, the force is 20N/25mm or less: After 14 days of attachment, the force is more than 20N/25mm, 25mm: 14After 14 days, the point is 25N/25inm or more: χ [Test Example 2] Determination of the gel fraction) 32 201122071 Using a single side of an anthrone-based stripper to make a Μ#% + peeling PET on a polyethylene terephthalate film core early peeling treatment, thickness: ... illusion, come = gteck company, SP - used for the polarizing agent with the layer of the coating agent in the example or comparative example, specifically, by the actual "I polarizing plate, system (4) film. In the case of the 铋 铋 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 比 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' On the side of the face, the film is made by stripping 4 people (four) of the agent layer / under the condition of _, 5: 7曰之春^ y, for the obtained adhesive sheet, to maintain health. Then, for the sticky tenth of the stick, the 'sampling becomes the size of 80mmx80mm', the adhesive layer is packaged, and the mesh is meshed by the mesh (the mesh size is 200), and the weight is only measured in the balance. M1. Test Bay 1. At this time, the mass was used as a sample using a Soxrex (s〇xhl s) reflux extractor, and a sample of the acetic acid "bathing agent" was impregnated with the detergent.鈇德 ^ ^ Into the machine back, for 16 hours in a 16-hour environment, and ^ degrees coffee, relative humidity of 5 〇% of the hour. With a precision balance, only the stomach. 8〇. In the oven, 'dry 12,,* weigh the amount of the adhesive after drying. Take the quality at this time as M2. Condensed eight mysterious /

⑽而声- 分率（％ )係藉由（M2/MU X 义不。將結果顯示於表2 0 [試驗例3](光學性能之測定） 使用藉由石夕_系剝離劑 之單面進行剝離處理之剝離片（广 '對本—甲酸醋膜 吧難、厚度：38心片（Llngteck公司製、sp- 用於附有粘二 “ m ’來取代在實施例或比較例而使 '者1層之偏光板製作之偏光板，製作粘著片。 33 201122071 具體地忒，藉由在實施例或比較例來 點著劑層上，；藉_^'+.在 之厚度25//Π1之 作由剝離片/ #荖#丨& / & 離處理面側，來製 在23。广 剝離片之構造而組成之點著片。 在23C、5〇%RH之條件姑者片 7日之養生。妙尨外# 、件到之點著片，進行 ，，、、、，就該粘著片之粘著劑；s & & 濁計（曰本電色工業公司製' 而測定混濁值⑴。將結果顯示於表）2按照爪·5 混濁值之範圍係〇〜5% 。 。此外，理想之 [試驗例4 ](耐久性之評價） 使用裁斷裝i (获野製作所 - 600 ) > -,, 』I之超級切割器、PN1 偏光板而：為：比較例來得到之附_劑層之 出之Μ = Γ 離片，在透過露 玻璃(康寧公㈣™) 藉由栗原製作所製之高塵銷而在〇 5MPam 订2 0分鐘之加壓。 然:，投入至下列之各耐久條件之環境 時後，使用10倍之放大鏡而 ^ 仃規察外觀之變化係將以 下作為基準。將結果顯示於表2。 ◎:在4邊，無缺點發生。 〇:在4邊，由外圍端部開始至〇.6襲以上之部位， 無缺點發生。 X:在4邊之至幻邊，由外圍端部開始至0.—以上 :部位，有浮起、剝離、發泡、條紋等之…上之點 者劑之外觀異常缺點發生。 34 201122071 <财久條件> • b〇c、相對濕度9〇% • 80°c、乾燥 [試驗例5](光漏性試驗） 使用裁斷裝置（荻野製作(10) The sound-fraction rate (%) is determined by (M2/MU X meaning. The results are shown in Table 2 0 [Test Example 3] (Measurement of optical properties) Using one side of the Shi Xi _ stripping agent Peeling sheet for peeling treatment (Guang's own - formic acid vinegar film is difficult, thickness: 38 core sheets (manufactured by Llngteck Co., Ltd., sp- for attaching sticky two "m' to replace the one in the embodiment or the comparative example" A polarizing plate made of a polarizing plate of one layer is used to form an adhesive sheet. 33 201122071 Specifically, by applying a layer on the agent layer in the embodiment or the comparative example; borrowing _^'+. in the thickness of 25//Π1 The stripping sheet / #荖#丨& / & from the side of the processing surface, is made at 23. The structure of the wide stripping sheet is composed of the sheet. In the condition of 23C, 5〇% RH The health of the day. Miao Yuwai #, pieces to the point of the film, carry,,,,,, the adhesive of the adhesive sheet; s && turbidity meter (made by Sakamoto Electric Industrial Co., Ltd.) The turbidity value (1) was measured. The results are shown in Table 2. The range of the turbidity value of the claw·5 is 〇~5%. In addition, the ideal [Test Example 4] (Evaluation of Durability) using the cutting device i (野野所- 600 ) > -,, 』I super cutter, PN1 polarizer and: for the comparison example to get the _ agent layer out of the Μ = Γ off-chip, in the through the open glass (Corning Gong (four) TM) Pressurize the 尘 5MPam for 20 minutes by the high dust sold by Kurihara. However: After investing in the following environment of each endurance condition, use a 10x magnifying glass to observe the appearance. The change is based on the following. The results are shown in Table 2. ◎: On the 4 sides, no defects occur. 〇: On the 4 sides, from the peripheral end to the 〇.6 or more, no defects occur. From the 4th edge to the phantom edge, from the peripheral end to 0.—above: the part, there are floating, peeling, foaming, streaking, etc. The appearance of the agent is abnormal. 34 201122071 < Long-term condition> b〇c, relative humidity 9〇% • 80°c, dry [Test Example 5] (Light leakage test) Using a cutting device (made by Takino

- 600 ) 』衣之超級切割器、PN /…例或比較例來得到之附有枯著劑層之 偏光板而成為233mmx3〇9 φ ^ ^ 刺除剝離片，在透過霜- 600 ) 』 之 超级 超级 超级 超级 超级 超级 超级 超级 超级 PN 超级 超级 超级 超级 超级 超级 超级 超级 超级 超级 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233 233

出枯者劑層而貼附於無驗玻璃（康寧公司製、EagleXG ^後’藉由栗原製作所製之高壓銷而在G.5MPa、5(rc，達 仃20分鐘之加壓·。此外，前述貼合係在無驗玻璃之表背 面，進打附有㈣劑層之偏光板而使得偏光轴成為直交偏 光狀態（偏光軸：z45。、Z135。）。在該狀態下，在8( C、乾燥環境下而放置5⑽小時之後，藉由以下顯示之方 法而評價光漏性。將結果顯示於表2。 &lt;光漏性之評價&gt; 使用大塚電子公司製之MCPD — 2000而測定圖3所示之 各區域之亮度，藉由公式△L* = [(b+c+(1+e)/4] —a (但是，a、b、c、d及e係分別為A區域、B區域、ς區 域、D區域及ε區域之預先決定之測定點（各區域之中央 部之1部位）之亮度。）而求出亮度差△ L*，作為光漏性。 △ L之值越小而顯示光漏越少。 在此，前述重量平均分子量係使用凝膠滲透色错法 (GPC )，藉由以下之條件而測定（GPC測定）之聚笨乙稀 換算之重量平均分子量。 35 201122071 &lt;測定條件&gt; HLC- 8020 :TOSOH公司製 • GPC測定裝置：TOSOH公司製、 • GPC柱（以下列之順序來通過） TSK guard column HXL — Η TSK gel GMHXL ( x2)The dry agent layer is attached to the non-test glass (manufactured by Corning Co., Ltd., EagleXG^', and is pressed at G.5 MPa and 5 (rc, 20 minutes by the high pressure pin manufactured by Kurihara Co., Ltd.). The bonding is performed on the back surface of the non-inspective glass, and the polarizing plate with the (four) agent layer is attached so that the polarizing axis becomes a state of orthogonal polarization (polarizing axis: z45., Z135.). In this state, at 8 (C) After leaving for 5 (10) hours in a dry environment, the light leakage property was evaluated by the method shown below. The results are shown in Table 2. <Evaluation of light leakage> Using a MCPD-2000 manufactured by Otsuka Electronics Co., Ltd. The brightness of each region shown in 3 is represented by the formula ΔL* = [(b+c+(1+e)/4] - a (however, a, b, c, d, and e are respectively A region, B The brightness of the predetermined measurement point (one part of the central part of each area) of the region, the ς region, the D region, and the ε region is obtained.) The luminance difference ΔL* is obtained as the light leakage property. The smaller the value of ΔL The smaller the light leakage is, the weight average molecular weight is determined by the gel permeation chromatic method (GPC) by the following conditions (GPC). 35 201122071 &lt;Measurement conditions&gt; HLC-8020: manufactured by TOSOH Co., Ltd. • GPC measuring device: manufactured by TOSOH Co., Ltd., • GPC column (passed in the following order) TSK guard Column HXL — Η TSK gel GMHXL ( x2)

TSK gel G2000HXL •測定溶媒：四氫化呋喃 •測定溫度：40°C 36 201122071 【表1】 共聚物(A) 共聚物（B) Mw(A)/(B) ⑷ 交聯劑（C): [NCO] 其他之交聯剞： 矽炫偶合劑 組成 組成 (轉化率%) 異氰酸酯系 交聯劑 /[OH] 環氧系交聨劑 (D) 實施例1 150萬/4萬 1.0 實施例2 80萬/4萬 1.0 實施例3 100萬/4萬 1.0 實施例4 200萬/4萬 80 1.0 - 實施例5 0.5 實施例6 BA/AA/HEA=87. 3/2.7/10 2.0 實施例7 150萬/4萬 1.0 0.1 實施例8 95 1.0 實施例9 90 1.0 實施例10 70 1.0 實施例11 150萬/1萬 1.0 實施例12 BA/AA=97/3 150萬/10萬 TDI系 1.0 KBM403 實施例13 150萬/20萬 1.0 實施例14 BA/AA/HEA=94.1/2.9/3 3.0 實施例15 BA/AA/HEA=92. 2/2. 8/5 3.0 實施例16 BA/AA/HEA=82. 5/2. 5/15 1.0 實施例17 BA/AA/HEA=82. 5/2. 5/15 0.5 實施例18 BA/AA/HEA=77. 6/2.4/20 0.5 實施例19 BA/AA/HEA=77. 6/2. 4/20 0.3 實施例20 BA/AA/HEA=67. 9/2. 1/30 0.3 實施例21 BA/AA/HEA=67. 9/2.1/30 0.1 實施例22 BA/AA/HEA=48. 5/1.5/50 0. 1 0.2 實施例23 BA=100 BA/HEA=90/10 1.0 KBE9007 實施例24 BA/AA=99. 5/0. 5 BA/AA/HEA=89. 6/0. 4/10 150萬/4萬 1.0 實施例25 BA/AA=95/5 BA/AA/HEA=85. 5/4. 5/10 80 1.0 KBM403 實施例26 BA/AA=90/10 BA/AA/HEA=81/9/10 0.5 實施例27 BA/AA/HEA=87. 3/2. 7/10 1.0 KBE403 實施例28 BA/AA=97/3 BA/AA/HEA=87. 3/2. 7/10 異氰酸酯系 1.0 實施例29 BA/AA/HBA=87. 3/2. 7/10 1.0 實施例30 BA/AA/HEMA=87.3/2. 7/10 1.0 實施例31 BA/AA=80/20 BA/HEA=72/18/10 1.0 實施例32 BA/AA/HEA=94.1/2.9/3 6.0 實施例33 BA/AA/HEA=92. 2/2. 8/5 6.0 實施例34 BA/AA/HEA/DEM= 1.0 KBM403 86.4/2. 7/10/0.9 TDI系 實施例35 BA/HEA=90/10 150萬/4萬 1.0 比較例1 BA/AA=97/3 BA/AA/HEA=87. 3/2. 7/10 50萬/4萬 1.0 比較例2 BA/AA/HEA=96/3/l 150萬/4萬 1.0 比較例3 150萬/5千 1.0 比較例4 BA/AA/HEA=87. 3/2.7/10 150萬/30萬 1.0 比較例5 150萬/4萬 50 1.0 比較例6 150萬/4萬 99 1.0 37 201122071 【表2】 耐久性（500h) 而十光漏性 粘著力 (N/25mm) 再工作性 凝膠分率 (%) 混濁值 (% ) 60°C、90% RH 80°C、dry 實施例1 ◎ ◎ 1.4 4.8 〇 74 0.8 實施例2 〇 〇 1.2 8.8 〇 70 0.7 實施例3 〇 ◎ 1.3 7.5 〇 78 0.8 實施例4 ◎ ◎ 1.6 3.9 ◎ 72 0.8 實施例5 〇 ◎ 1.0 3.2 ◎ 59 0.7 實施例6 ◎ ◎ 1.7 11.1 〇 84 0.8 實施例7 ◎ ◎ 1.7 4.0 ◎ 82 0.8 實施例8 ◎ ◎ 1.8 4.2 ◎ 41 0.7 實施例9 ◎ ◎ 1.6 4.4 〇 56 0.7 實施例10 〇 〇 1.3 6.4 〇 84 0.9 實施例11 〇 ◎ 1.1 3.8 ◎ 62 0.8 實施例12 ◎ ◎ 1.3 9.1 〇 73 0.9 實施例13 ◎ ◎ 1.2 11.2 〇 76 0.9 實施例14 〇 〇 1.6 6.0 〇 79 8.9 實施例15 • Ο 〇 1.4 6.5 〇 86 9.5 實施例16 ◎ ◎ 1.5 6.7 〇 80 1.6 實施例17 ◎ 〇 1.3 2.8 ◎ 68 1.1 實施例18 ◎ ◎ 1.1 5.9 〇 69 1.8 實施例19 ◎ ◎ 0.9 4.3 〇 54 1.5 實施例20 ◎ ◎ 1.0 3.9 ◎ 59 2.2 實施例21 〇 ◎ 0.9 3.2 ◎ 43 1.9 實施例22 〇 〇 0.8 2.9 ◎ 52 2.9 實施例23 〇 ◎ 1.1 2.2 〇 49 1.9 實施例24 〇 ◎ 1.2 2.9 〇 62 1.5 實施例25 ◎ ◎ 1.6 14.1 〇 77 0.8 實施例26 ◎ ◎ 1.9 13.4 〇 87 0.6 實施例27 〇 ◎ 1.4 4.7 〇 75 0.8 實施例28 〇 〇 1.3 6.9 〇 70 0.8 實施例29 ◎ ◎ 1.4 5.1 〇 78 0.8 實施例30 ◎ ◎ 1.8 6.2 〇 73 0.8 實施例31 ◎ ◎ 2.6 27 X 88 0.7 實施例32 ◎ 〇 1.7 17.2 X 88 20 實施例33 ◎ ◎ 1.6 19.1 X 91 21 實施例34 〇 〇 1.2 2.1 〇 93 0.6 實施例35 ◎ ◎ 1.8 5.0 〇 73 1.2 比較例1 X X 0.7 13.0 X 62 0.7 比較例2 X X 0.5 12.4 〇 12 0.9 比較例3 X 〇 1.0 5.7 〇 48 0.7 比較例4 X X 1.2 13.7 X 74 1.5 比較例5 X X 1.5 8.2 〇 82 1.9 比較例6 X X 0.4 8.7 〇 10 0.7 38 201122071 由表2而明白地顯示：在實施例得到之附有粘著劑層 之偏光板係、在耐久性，纟問題發生，也具有良好之耐光漏 性。此外，就調整共聚物（A )中之丙烯酸之導入量和交聯 劑（C)之添加量之實施例而言，也具有良好之再工 作性，並且，也抑制混濁值變低，具有良好之透明性。此 外，藉由一系列之聚合而得到丙烯系聚合物溶液之實施例 1係比起以相同之練合且藉由摻合系而得到丙烯系聚合物 /谷液之貫她例3 5，還具有良好之耐光漏性，混濁值變低。 就比較例1而言，第1之（甲基）丙烯酸酯共聚物（A) 之重量平均分子量過度小，因此，耐久性及再工作性變差。 就比較例2而言，帛2之（曱基）丙稀酸醋共聚物（b)之 羥基之含有量過度少，因此，凝膠分率（交聯之程度）變 低’财久性變差。就比較例3而言，帛2之（甲基）丙烯 酸酯共聚物（B)之重量平均分子量過度小，因此，耐久性 變差。就比較例4而言’第2之（甲基）@烯酸酯共聚物 (B)之重量平均分子量過度大，因此，耐久性及再工作性 變差。就比較例5而言，第2之（甲基）&amp;稀酸醋共聚物 (B)之含有量過度多’因此’耐久性變差。就比較例6而 言，第2之（甲基）丙烯酸酯共聚物（B)之含有量過度少， 因此，凝膠分率（交聯之程度）變低，耐久性變差。 【產業上之可利用性】 本發明之粘著性組成物及粘著劑係適合於光學構件、 &quot;如偏光板或相位差板之接合，並且’本發明之粘著片係 適合作為偏光板或相位差板等之光學構件用之粘著片。 39 201122071 【圖式簡單說明】 圖1係本發明之第1實施形態之粘著片之剖面圖。 圖2係本發明之第2實施形態之粘著片之剖面圖。 圖3係顯示附有粘著劑層之偏光板之光漏性試驗之測 定區域之圖。 【主要元件符號說明】 1A〜粘著片； 1B〜粘著片； 11〜枯著劑層； 1 2〜剝離片； 12a〜剝離片； 12b〜剝離片； 1 3〜基材。 40TSK gel G2000HXL • Determination of solvent: tetrahydrofuran • Measurement temperature: 40 ° C 36 201122071 [Table 1] Copolymer (A) Copolymer (B) Mw (A) / (B) (4) Crosslinking agent (C): [ NCO] Other cross-linking 剞: 矽 偶 coupling composition (conversion %) Isocyanate cross-linking agent / [OH] Epoxy intercalating agent (D) Example 1 1.5 million / 40,000 1.0 Example 2 80 10,000 / 40,000 Example 3 3 million / 40,000 1.0 Example 4 2 million / 40,000 80 - Example 5 0.5 Example 6 BA / AA / HEA = 87. 3 / 2.7/10 2.0 Example 7 150 10,000/40,000 1.0 0.1 Example 8 95 1.0 Example 9 90 1.0 Example 10 70 1.0 Example 11 1.5 million / 100,000 Example 12 BA / AA = 97 / 3 1.5 million / 100,000 TDI 1.0 KBM403 Implementation Example 13 1.5 million/200,000 1.0 Example 14 BA/AA/HEA=94.1/2.9/3 3.0 Example 15 BA/AA/HEA=92. 2/2. 8/5 3.0 Example 16 BA/AA/HEA =82. 5/2. 5/15 1.0 Example 17 BA/AA/HEA=82. 5/2. 5/15 0.5 Example 18 BA/AA/HEA=77. 6/2.4/20 0.5 Example 19 BA/AA /HEA=77. 6/2. 4/20 0.3 Example 20 BA/AA/HEA=67. 9/2. 1/30 0.3 Example 21 BA/AA/HEA=67. 9/2.1/30 0.1 Implementation Example 22 BA/AA/HEA=48. 5/1.5/50 0. 1 0.2 Example 23 BA=100 BA/HEA=90/10 1.0 KBE9007 Example 24 BA/AA=99. 5/0. 5 BA/ AA/HEA=89. 6/0. 4/10 1.5 million/40,000 1.0 Example 25 BA/AA=95/5 BA/AA/HEA=85. 5/4. 5/10 80 1.0 KBM403 Example 26 BA/AA=90/10 BA/AA/HEA=81/9/10 0.5 Example 27 BA/AA/HEA=87. 3/2. 7/10 1.0 KBE403 Example 28 BA/AA=97/3 BA /AA/HEA=87. 3/2. 7/10 Isocyanate System 1.0 Example 29 BA/AA/HBA=87. 3/2. 7/10 1.0 Example 30 BA/AA/HEMA=87.3/2. /10 1.0 Example 31 BA/AA=80/20 BA/HEA=72/18/10 1.0 Example 32 BA/AA/HEA=94.1/2.9/3 6.0 Example 33 BA/AA/HEA=92. 2 /2. 8/5 6.0 Example 34 BA/AA/HEA/DEM= 1.0 KBM403 86.4/2. 7/10/0.9 TDI Example 35 BA/HEA=90/10 1.5 million/40,000 1.0 Comparative Example 1 BA/AA=97/3 BA/AA/HEA=87. 3/2. 7/10 500,000/40,000 1.0 Comparative Example 2 BA/AA/HEA=9 6/3/l 1.5 million/40,000 1.0 Comparative Example 3 1.5 million/5 thousand 1.0 Comparative Example 4 BA/AA/HEA=87. 3/2.7/10 1.5 million/300,000 1.0 Comparative Example 5 1.5 million/40,000 50 1.0 Comparative Example 6 1.5 million / 40,000 99 1.0 37 201122071 [Table 2] Durability (500h) and ten-light leakage adhesion (N/25mm) Reworkability gel fraction (%) Haze value (%) 60 ° C, 90% RH 80 ° C, dry Example 1 ◎ ◎ 1.4 4.8 〇 74 0.8 Example 2 〇〇 1.2 8.8 〇 70 0.7 Example 3 〇 ◎ 1.3 7.5 〇 78 0.8 Example 4 ◎ ◎ 1.6 3.9 ◎ 72 0.8 Example 5 〇 ◎ 1.0 3.2 ◎ 59 0.7 Example 6 ◎ ◎ 1.7 11.1 〇 84 0.8 Example 7 ◎ ◎ 1.7 4.0 ◎ 82 0.8 Example 8 ◎ ◎ 1.8 4.2 ◎ 41 0.7 Example 9 ◎ ◎ 1.6 4.4 〇 56 0.7 Example 10 〇〇1.3 6.4 〇84 0.9 Example 11 〇 ◎ 1.1 3.8 ◎ 62 0.8 Example 12 ◎ ◎ 1.3 9.1 〇 73 0.9 Example 13 ◎ ◎ 1.2 11.2 〇76 0.9 Example 14 〇〇1.6 6.0 〇 79 8.9 Example 15 • Ο 〇 1.4 6.5 〇 86 9.5 Example 16 ◎ ◎ 1.5 6.7 〇 80 1.6 Example 17 ◎ 〇 1. 3 2.8 ◎ 68 1.1 Example 18 ◎ 6.1 1.1 5.9 〇 69 1.8 Example 19 ◎ ◎ 0.9 4.3 〇 54 1.5 Example 20 ◎ ◎ 1.0 3.9 ◎ 59 2.2 Example 21 〇 ◎ 0.9 3.2 ◎ 43 1.9 Example 22 〇〇 0.8 2.9 ◎ 52 2.9 Example 23 〇 ◎ 1.1 2.2 〇 49 1.9 Example 24 〇 ◎ 1.2 2.9 〇 62 1.5 Example 25 ◎ ◎ 1.6 14.1 〇 77 0.8 Example 26 ◎ ◎ 1.9 13.4 〇 87 0.6 Example 27 〇 ◎ 1.4 4.7 〇75 0.8 Example 28 〇〇1.3 6.9 〇70 0.8 Example 29 ◎ ◎ 1.4 5.1 〇78 0.8 Example 30 ◎ ◎ 1.8 6.2 〇 73 0.8 Example 31 ◎ ◎ 2.6 27 X 88 0.7 Example 32 ◎ 〇 1.7 17.2 X 88 20 Example 33 ◎ ◎ 1.6 19.1 X 91 21 Example 34 〇〇 1.2 2.1 〇 93 0.6 Example 35 ◎ ◎ 1.8 5.0 〇 73 1.2 Comparative Example 1 XX 0.7 13.0 X 62 0.7 Comparative Example 2 XX 0.5 12.4 〇12 0.9 Comparative Example 3 X 〇1.0 5.7 〇48 0.7 Comparative Example 4 XX 1.2 13.7 X 74 1.5 Comparative Example 5 XX 1.5 8.2 〇82 1.9 Comparative Example 6 XX 0.4 8.7 〇10 0.7 38 201122071 It is clearly shown in Table 2: In the embodiment The polarizing plate with the pressure-sensitive adhesive layer, occurs in durability, Si problems, also has good properties of light leakage. Further, in the examples in which the amount of introduction of the acrylic acid in the copolymer (A) and the amount of the crosslinking agent (C) are adjusted, the reworkability is also improved, and the haze value is also suppressed to be low and has good Transparency. Further, Example 1 in which a propylene-based polymer solution was obtained by a series of polymerizations was obtained by the same practice and obtained by blending a propylene-based polymer/gluten solution. It has good light leakage resistance and low turbidity value. In Comparative Example 1, the weight average molecular weight of the first (meth) acrylate copolymer (A) was excessively small, and thus durability and reworkability were deteriorated. In Comparative Example 2, the content of the hydroxyl group of the (mercapto)acrylic acid vinegar copolymer (b) of ruthenium 2 was excessively small, and therefore, the gel fraction (degree of crosslinking) became low. difference. In Comparative Example 3, the weight average molecular weight of the (meth) acrylate copolymer (B) of ruthenium 2 was excessively small, and thus the durability was deteriorated. In Comparative Example 4, the weight average molecular weight of the second (meth)@ enoate copolymer (B) was excessively large, and thus durability and reworkability were deteriorated. In Comparative Example 5, the content of the second (meth) &amp; dilute vinegar copolymer (B) was excessively large, and thus the durability was deteriorated. In the case of Comparative Example 6, the content of the second (meth) acrylate copolymer (B) is excessively small, so that the gel fraction (degree of crosslinking) is lowered and the durability is deteriorated. [Industrial Applicability] The adhesive composition and the adhesive of the present invention are suitable for bonding of an optical member, such as a polarizing plate or a phase difference plate, and the adhesive sheet of the present invention is suitable as a polarizing film. An adhesive sheet for an optical member such as a plate or a phase difference plate. 39 201122071 [Brief Description of the Drawings] Fig. 1 is a cross-sectional view showing an adhesive sheet according to a first embodiment of the present invention. Fig. 2 is a cross-sectional view showing an adhesive sheet according to a second embodiment of the present invention. Fig. 3 is a view showing a measurement area of a light leakage test of a polarizing plate with an adhesive layer. [Main component symbol description] 1A~adhesive sheet; 1B~adhesive sheet; 11~drying layer; 1 2~peeling sheet; 12a~peeling sheet; 12b~peeling sheet; 1 3~substrate. 40

Claims (1)

201122071 七、申請專利範圍： 1 · 一種粘著性組成物，含有重量平均分子量70萬〜 250萬之第1之（曱基）丙烯酸酯共聚物（A)、重量平均 分子量8000〜25萬之第2之（甲基）丙烯酸酯共聚物（B) 和交聯劑（C)且前述第2之（曱基）丙烯酸酯共聚物（B) 才目對於1 00質量份之前述第1之（曱基）丙烯酸酯共聚物 (A) 之比例為5〜5〇質量份， 其特徵在於： 前述第2之（曱基）丙烯酸酯共聚物（B)係包含具有 和前述交聯劑（C)之高反應性之官能基（bl )之單體而成 為構造成分’並且，在該第2之（曱基）丙烯酸酯共聚物 (B) 中，成為前述單體之比例超過1質量％之共聚物，前 述第1之（甲基）丙烯酸酯共聚物（A)係不包含具有和前 述交聯劑（C )之反應性之官能基之單體而成為構造成分， 或者是包含具有和前述交聯劑（C )之反應性低於前述第2 之（甲基）丙烯酸酯共聚物（B)之前述官能基（bl)之官 能基（al )之單體，來作為構造成分。 2. 如申請專利範圍第1項之粘著性組成物，其中，前 述第1之（曱基）丙烯酸酯共聚物（A)係不包含具有和前 述交聯劑（C )之高反應性之官能基之單體而成為構造成分。 3. 如申請專利範圍第1項之粘著性組成物，其中，前 述第1之（曱基）丙烯酸酯共聚物（A)之和前述交聯劑（c) 之低反應性之官能基（al )係羧基，前述第2之（甲基） 兩烯酸酯共聚物（B )之和前述交聯劑（C )之高反應性之 41 201122071 官能基（bl)係經基，前述交聯劑（c)係異氰酸酯系交聯 劑。 4.如申請專利範圍第3項之粘著性組成物，其中’前 述第1之（曱基）丙烯酸酯共聚物（A)係含有含羧基單體 0〜15質量％ ’來作為構成該共聚物之單體單位。 5 ·如申請專利範圍第3項之粘著性組成物，其中，前 述第2之（甲基）丙烯酸酯共聚物（B)係含有含羥基單體 3〜40質量％ ’來作為構成該共聚物之單體單位。 6. 如申請專利範圍第3項之粘著性組成物，其中，前 述異氛S文S曰系父聯劑之含有量係該異氰酸酯系交聯劑之異 氛酸醋基相對於前述第2之（甲基）丙烯酸醋共聚物（B) 之和刖述父聯劑（C )之高反應性之官能基（Μ)之量，成 為0.1〜5當量之量。 7. 如申請專利範圍第1項之粘著性組成物，其中，還 含有矽烷偶合劑（D )。 8. 如申請專利範圍帛7項之㈣性組成物，其中，前 述矽烷偶合劑（D)之含有量係相對於前述第i之（甲基） 丙稀酸S旨共聚物（A)之1〇〇暂旦於而士、&amp; n &lt; iuu質里伤而成為〇 〇5〜〇·5質量 份。 9_ -種粘著性組成物之製造方法’製造申請專利範援 第1項所述之粘著性組成物， 其特徵在於包括： 以轉化率50〜90% ，對於構成前述第1之（甲基 浠酸酯共聚物（Α)之單體，進杆自由其 進仃目由基聚合，製造前述J 42 201122071 ) 1之（甲基）丙烯酸酯共聚物（A)之製程（1 ); 在别述第1之（甲基）丙烯酸酯共聚物（A)之存在下， 對於殘留在前述第1之（曱基）丙烯酸酿共聚物（A)聚合 時之輩*§* L”》θ 及具有和前述交聯劑（C)之高反應性之官能基 (bl)之單體，進行自由基共聚合，製造前述第2之（甲 基）丙稀酸顆共聚物（B)之製程（2);以及， 添加前述交聯劑（C)之製程（3)。 1 〇.如申請專利範圍第9項之粘著性組成物之製造方 法其中，在製造前述第2之（曱基）丙烯酸酯共聚物（B) 之製程（2 )，以轉化率7〇〜1〇〇% ，對於殘留在前述第1 =(曱基）丙烯酸酯共聚物（A)聚合時之單體以及具有和 引述父如劑（C )之高反應性之官能基（bl )之單體，進行 自由基共聚合。 U ·如申請專利範圍第9項之粘著性組成物之製造方 法其中’在製造巾請專利範圍第7項所述之枯著性級成 '’還包括添加前述矽烷偶合劑（D )之製程。 12'種粘著劑’其特徵在於：交聯申請專利範圍第1 8項中任-項所述之粘著性組成物而組成。 I3.—種粘著片，包括基材和粘著劑層， 其特徵在於： 月j述點著劑層係由申請專利範圍S i 2項 劍而鈿〇、 〜者 月1J述基 I4.如申請專利範圍第13項之粘著片，其中 材係光學構件。 43 201122071 1 5. —種粘著片，包括2片之剝離片以及夾持於前述剝 離片而接合在前述2片之剝離片之剝離面之粘著劑層， 其特徵在於： 前述粘著劑層係由申請專利範圍第12項所述之粘著 劑而組成。 44201122071 VII. Patent application scope: 1 · An adhesive composition containing the first (fluorenyl) acrylate copolymer (A) having a weight average molecular weight of 700,000 to 2.5 million, and a weight average molecular weight of 8,000 to 250,000 2 (meth) acrylate copolymer (B) and crosslinker (C) and the aforementioned 2 (fluorenyl) acrylate copolymer (B) are for 1 00 parts by mass of the aforementioned first one (曱) The ratio of the acrylate copolymer (A) is 5 to 5 parts by mass, and the second (fluorenyl) acrylate copolymer (B) contains the crosslinking agent (C). a monomer having a highly reactive functional group (bl) as a structural component' and a copolymer having a ratio of the above monomer of more than 1% by mass in the second (fluorenyl) acrylate copolymer (B) The first (meth) acrylate copolymer (A) is a structural component which does not contain a functional group having a reactivity with the crosslinking agent (C), or contains and crosslinks with the foregoing. The reactivity of the agent (C) is lower than that of the above (meth) acrylate copolymer (B) A monomer of the functional group (al) of the aforementioned functional group (bl) as a structural component. 2. The adhesive composition according to claim 1, wherein the first (fluorenyl) acrylate copolymer (A) does not contain a high reactivity with the crosslinking agent (C). The monomer of the functional group becomes a structural component. 3. The adhesive composition according to claim 1, wherein the functional group of the first (indenyl) acrylate copolymer (A) and the aforementioned crosslinking agent (c) are low-reactive ( Al) is a carboxyl group, and the second (meth) enoate copolymer (B) is highly reactive with the crosslinking agent (C). 41 201122071 Functional group (bl) is a trans group, the aforementioned cross-linking The agent (c) is an isocyanate crosslinking agent. 4. The adhesive composition of claim 3, wherein the 'the first (fluorenyl) acrylate copolymer (A) contains 0 to 15% by mass of the carboxyl group-containing monomer as the copolymer Monomeric unit of matter. 5. The adhesive composition according to claim 3, wherein the second (meth) acrylate copolymer (B) contains 3 to 40% by mass of the hydroxyl group-containing monomer as a constituent of the copolymerization. Monomeric unit of matter. 6. The adhesive composition of claim 3, wherein the content of the heterogeneous S-based parent-linked agent is an isocyanate group of the isocyanate-based crosslinking agent relative to the second The amount of the (meth)acrylic acid vinegar copolymer (B) and the amount of the highly reactive functional group (Μ) of the parent reagent (C) is 0.1 to 5 equivalents. 7. The adhesive composition of claim 1, wherein the decane coupling agent (D) is further contained. 8. The composition according to claim 4, wherein the content of the decane coupling agent (D) is 1 relative to the (i) (i) of the (i) (meth) acrylic acid S copolymer (A) 〇〇 〇〇 于 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 9_ - A method for producing an adhesive composition, wherein the adhesive composition according to the first aspect of the invention is characterized in that: the conversion rate is 50 to 90%, and the first one is formed. a process for preparing a (meth) acrylate copolymer (A) of the above J 42 201122071) 1 by using a monomer of a phthalic acid ester copolymer (Α), which is freely polymerized from the base; In the presence of the (meth) acrylate copolymer (A) of the first aspect, for the generation of the first (曱-based) acrylic styrene copolymer (A), the generation *§* L" θ and A monomer having a functional group (bl) having high reactivity with the above-mentioned crosslinking agent (C), which is subjected to radical copolymerization to produce the above-mentioned second (meth)acrylic acid copolymer (B) ( 2); and, the process (3) of adding the aforementioned crosslinking agent (C). The manufacturing method of the adhesive composition according to claim 9 of the patent application, wherein the second (the base) is manufactured. Process for the acrylate copolymer (B) (2), with a conversion of 7 〇 to 1%, for the remaining 1 = (mercapto) propylene The monomer in the polymerization of the acid ester copolymer (A) and the monomer having the functional group (bl) having high reactivity with the parent (C) are subjected to radical copolymerization. U. The method for producing an adhesive composition of the present invention, wherein the 'dryness level described in the seventh paragraph of the patent specification for manufacturing the towel' includes the process of adding the aforementioned decane coupling agent (D). 12' type adhesive It is characterized in that it is composed of an adhesive composition as described in Item No. 18 of the patent application. I3. An adhesive sheet comprising a substrate and an adhesive layer, characterized in that: The month of the application of the agent layer is from the scope of application of the patent scope S i 2 swords, and the month of the moon is 1 I. The adhesive sheet of claim 13 of the patent scope, wherein the material is an optical member. 43 201122071 1 5. An adhesive sheet comprising two release sheets and an adhesive layer sandwiched between the release sheets and joined to the release surfaces of the two release sheets, wherein the adhesive layer is It is composed of the adhesive described in the scope of patent application.
TW099136666A 2009-12-28 2010-10-27 An adhesive composition, an adhesive, and an adhesive sheet TWI493002B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2009296952A JP5595034B2 (en) 2009-12-28 2009-12-28 Adhesive composition, adhesive and adhesive sheet

Publications (2)

Publication Number Publication Date
TW201122071A true TW201122071A (en) 2011-07-01
TWI493002B TWI493002B (en) 2015-07-21

Family

ID=44172558

Family Applications (1)

Application Number Title Priority Date Filing Date
TW099136666A TWI493002B (en) 2009-12-28 2010-10-27 An adhesive composition, an adhesive, and an adhesive sheet

Country Status (4)

Country Link
JP (1) JP5595034B2 (en)
KR (1) KR101796142B1 (en)
CN (1) CN102108272B (en)
TW (1) TWI493002B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI488938B (en) * 2012-03-09 2015-06-21 Nitto Denko Corp Adhesive tape
TWI621677B (en) * 2013-03-06 2018-04-21 Lintec Corp Adhesive sheet and manufacturing method of adhesive sheet

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5562173B2 (en) * 2010-08-19 2014-07-30 リンテック株式会社 Adhesive composition, adhesive and adhesive sheet
JP5602670B2 (en) * 2011-03-31 2014-10-08 リンテック株式会社 Adhesive and adhesive sheet
JP5611880B2 (en) * 2011-03-31 2014-10-22 リンテック株式会社 Adhesive and adhesive sheet
JP5638439B2 (en) * 2011-03-31 2014-12-10 リンテック株式会社 Adhesive and adhesive sheet
JP5595321B2 (en) * 2011-03-31 2014-09-24 リンテック株式会社 Adhesive composition, adhesive and adhesive sheet
JP5758673B2 (en) * 2011-03-31 2015-08-05 リンテック株式会社 Adhesive and adhesive sheet
JP5613108B2 (en) * 2011-06-28 2014-10-22 リンテック株式会社 Adhesive composition, adhesive and adhesive sheet
JP6014953B2 (en) * 2011-11-09 2016-10-26 学校法人慶應義塾 Method for designing polarizing plate with pressure-sensitive adhesive, method for producing liquid crystal panel, method for producing polarizing plate, method for producing polarizing plate with pressure-sensitive adhesive, and method for producing pressure-sensitive adhesive
KR20130073003A (en) * 2011-12-22 2013-07-02 제일모직주식회사 Adhesive composition for polarizer plate, polarizer plate comprising adhesive layer including the same and liquid crystal display comprising the same
JP6065486B2 (en) * 2011-12-27 2017-01-25 東洋インキＳｃホールディングス株式会社 Foam adhesive
JP5932430B2 (en) * 2012-03-28 2016-06-08 リンテック株式会社 Adhesive composition, adhesive and adhesive sheet
JP6002220B2 (en) * 2012-06-05 2016-10-05 日本カーバイド工業株式会社 Adhesive composition for polarizing plate, polarizing plate with adhesive, and display device
JP6216519B2 (en) * 2013-03-04 2017-10-18 リンテック株式会社 Adhesive composition, adhesive and adhesive sheet
SG11201507012WA (en) * 2013-03-06 2015-10-29 Furukawa Electric Co Ltd Non-crosslinkable adhesive composition, and adhesive sheet
WO2014204132A1 (en) * 2013-06-18 2014-12-24 주식회사 엘지화학 Thin polarizer with excellent optical properties, method for manufacturing same, and polarizing plate and display device comprising thin polarizer
JP6432336B2 (en) * 2014-12-24 2018-12-05 信越化学工業株式会社 Isocyanate group-containing organopolysiloxane compound, method for producing the same, adhesive, pressure-sensitive adhesive, and coating agent
JP6237611B2 (en) * 2014-12-24 2017-11-29 信越化学工業株式会社 Isocyanate group-containing organosilicon compound, production method thereof, adhesive, pressure-sensitive adhesive, and coating agent
KR102271569B1 (en) * 2015-03-17 2021-07-02 린텍 가부시키가이샤 Adhesive composition, adhesive agent, and adhesive sheet
JP6511659B2 (en) * 2015-06-08 2019-05-15 藤森工業株式会社 Pressure-sensitive adhesive layer for optical film, and pressure-sensitive adhesive film for optical film
JP2016173589A (en) * 2016-05-04 2016-09-29 学校法人慶應義塾 Polarizer with adhesive, liquid crystal panel, and adhesive
CN106520034A (en) * 2016-11-02 2017-03-22 深圳市胜宝莱光电科技有限公司 Pressure-sensitive adhesive for reflection type high-durability polaroid and polaroid with pressure-sensitive adhesive applied
JP6488343B2 (en) * 2017-09-14 2019-03-20 リンテック株式会社 Adhesive sheet
CN111290067A (en) * 2020-04-02 2020-06-16 佛山纬达光电材料股份有限公司 Polaroid for wide-viewing-angle liquid crystal display

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09113724A (en) * 1995-10-16 1997-05-02 Sekisui Chem Co Ltd Tacky adhesive type polarizing plate
JP4036272B2 (en) * 1996-07-18 2008-01-23 日東電工株式会社 Adhesive composition and adhesive sheet
JP4534431B2 (en) * 2003-04-30 2010-09-01 東洋インキ製造株式会社 Adhesive and optical member using the same
JP5422091B2 (en) * 2003-12-26 2014-02-19 東洋インキＳｃホールディングス株式会社 Antistatic acrylic adhesive
KR100668943B1 (en) * 2004-04-23 2007-01-12 주식회사 엘지화학 Acrylic Pressure-Sensitive Adhesive Composition for the Polarizing Film
JP5269282B2 (en) * 2004-08-11 2013-08-21 住友化学株式会社 Adhesive
JP2006137844A (en) * 2004-11-12 2006-06-01 Toyo Ink Mfg Co Ltd Adhesive and liquid crystal cell member using the same
US7585570B2 (en) * 2005-04-14 2009-09-08 Sumitomo Chemical Company, Limited Adhesives and optical laminates including the same
JP5011798B2 (en) * 2005-04-14 2012-08-29 住友化学株式会社 Adhesive
JP5023470B2 (en) * 2005-11-04 2012-09-12 住友化学株式会社 Acrylic resin composition and pressure-sensitive adhesive
KR100932887B1 (en) * 2005-12-14 2009-12-21 주식회사 엘지화학 Acrylic pressure-sensitive adhesive composition
JP5026252B2 (en) * 2007-07-06 2012-09-12 株式会社日本触媒 Solvent-type re-peeling pressure-sensitive adhesive composition and re-peeling pressure-sensitive adhesive product
JP5243197B2 (en) * 2008-11-18 2013-07-24 日東電工株式会社 Optical member pressure-sensitive adhesive composition, optical member pressure-sensitive adhesive layer, pressure-sensitive adhesive optical member, and image display device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI488938B (en) * 2012-03-09 2015-06-21 Nitto Denko Corp Adhesive tape
TWI621677B (en) * 2013-03-06 2018-04-21 Lintec Corp Adhesive sheet and manufacturing method of adhesive sheet

Also Published As

Publication number Publication date
JP2011137065A (en) 2011-07-14
KR20110076773A (en) 2011-07-06
JP5595034B2 (en) 2014-09-24
CN102108272A (en) 2011-06-29
CN102108272B (en) 2015-05-13
KR101796142B1 (en) 2017-11-10
TWI493002B (en) 2015-07-21

Similar Documents

Publication Publication Date Title
TW201122071A (en) Adhesion composition, adhesion agent and adhesion sheet.
TWI809001B (en) Adhesive for repetitive bending device, adhesive sheet, repetitive bending laminated member, and repetitive bending device
CN107216837B (en) Pressure-sensitive adhesive composition, pressure-sensitive adhesive, and pressure-sensitive adhesive sheet
KR101914459B1 (en) Adhesive composition, adhesive and adhesive sheet
TWI570213B (en) Adhesive and adhesive tape
TWI704203B (en) Adhesive layer, optical film with adhesive layer, optical laminate and image display device
JP6071224B2 (en) Adhesive sheet
TWI570203B (en) Adhesive compositions, adhesives, and adhesive sheets
JP5517831B2 (en) Adhesive composition, adhesive and adhesive sheet
TWI551661B (en) Adhesive composition, adhesive and adhesive sheet
TWI723275B (en) Adhesive layer, optical film with adhesive layer, optical laminate and image display device
TWI546364B (en) Adhesive composition, adhesive and adhesive sheet
JP2007119667A5 (en)
TWI755436B (en) Adhesive composition, adhesive and adhesive sheet
WO2021192423A1 (en) Adhesive sheet and laminate
JP6738622B2 (en) Adhesive composition and adhesive sheet
TWI527864B (en) Adhesive compositions, adhesives, and adhesive sheets
KR101899373B1 (en) An adhesive and adhesion sheet
JP2024040443A (en) Adhesive sheet, repeated bending laminate member and repeated bending device
KR20200104787A (en) Adhesive for repeatedly foldable device, adhesive sheet, repeatedly foldable laminate member and repeatedly foldable device
TW201245389A (en) Adhesive and adhesion strip
TWI537360B (en) Adhesive and adhesive tape
JP7008467B2 (en) Adhesive sheet and display
JP6708017B2 (en) Pressure-sensitive adhesive composition, pressure-sensitive adhesive using the same, and pressure-sensitive adhesive for polarizing plate
TWI527870B (en) Adhesive and adhesive tape