TW201112488A - Manufacturing method of thin film antenna - Google Patents

Manufacturing method of thin film antenna Download PDF

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TW201112488A
TW201112488A TW98131966A TW98131966A TW201112488A TW 201112488 A TW201112488 A TW 201112488A TW 98131966 A TW98131966 A TW 98131966A TW 98131966 A TW98131966 A TW 98131966A TW 201112488 A TW201112488 A TW 201112488A
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Taiwan
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manufacturing
film
gel
touch panel
film antenna
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TW98131966A
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Chinese (zh)
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TWI401838B (en
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Kuo-Ching Chiang
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Kuo-Ching Chiang
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Priority to TW98131966A priority Critical patent/TWI401838B/en
Priority to US12/724,806 priority patent/US8585911B2/en
Publication of TW201112488A publication Critical patent/TW201112488A/en
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Publication of TWI401838B publication Critical patent/TWI401838B/en

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Abstract

The present invention discloses a manufacturing method of thin film antenna, comprising preparing gel, followed by coating the gel on a substrate to form a transparent thin film. Thermal process is performed to heat the thin film. The gel includes PEO having In(NO)3.3H2O, In(Ac)3, SnCl2.2H2O, or Sn(C2O4) contained thereof.

Description

201112488 六、發明說明: 【發明所屬之技術領域】 本發明係有關於一種天線,尤其是關於一種薄膜天線 之製造方法。 、、 【先前技術】 近年來無線傳輸技術乃普遍發展於世界各地,而絕大 部f之無線裝置,如行動電話、個人數位助理以及數位電 視等’均需使用接收傳輸訊號之接收裝置。由於資訊傳遞 =位化’㈣如聲音訊號、影像訊號等之各種資訊得以 編解石人電㈤、仃動裝置等處理,而藉由聲音與影像 :金如丁’更可增進上述資訊種類之頻帶壓縮。而數位 二傳?能製造容易且有效地傳遞此種資訊至終端 式電話Γ 將聲音影像資料(AV資料)傳遞至一可攜 無線傳輸模組乃藉由連接器來安裝或分離於主要裳 1將自主要裝置之資料可館存在快閃記憶體卜i 至主要Me H 傳遞至主要裝置。當其安褒 要哀置%,此無線傳輸模組 進行主要裝置出之天線部份 線與天線元件通常製造在特 = 對廷些電路之用狳牲 土攸上,針 視,所以在這此電路中值、阻杬特性之控制乃不容忽 鍵之㈣與發射天線的長度便為關 :之❼十要素。兩個影響基底 吏為闕 介電常數(有時稱作相對介 ”關鍵因素為 ;丨電㊉數)以及介電損失(有時稱 201112488 作散逸係數),其中介電常數決定訊號於基底材料中之傳遞 速度,以及傳輸線與其他施作在基板上之零件的訊號收發 相關長度。而介電損失係為訊號於基底材料中傳遞所造成 之耗損,此耗損會隨頻率之變大而增多。 印刷傳輸線、被動電路以及用於射頻電路之發射元件 通常以下列三種方式其中之一來形成。第一種為微帶線 (micro-strip)結構,將訊號線放置在板狀物表面上並提供一 導電層,此導電層一般稱為接地面。第二種為埋式微帶線 _ (buried micro-strip)結構,除了其訊號線被一介電基底材料 覆蓋外,其餘均與第一種結構相似。第三種為帶狀線 (strip-line)結構,其訊號線乃炎在兩導電(接地)面之間,並 且天線配置在印刷電路板之主要平面上。對於車輛之應 用,此類系統絕大部分的解決方式均為將鞭狀天線安裝在 車頂,而相對於現今汽車設計之潮流,乃將這些天線嵌入 車輛結構中,以減少天線對於車輛美觀上與空氣動力上之 φ影響。並且,將數種電信服務整合進單一天線將可降低製 造之成本。天線可接收頻帶包含:調頻(Frequency Modulation ; FM)、個人手機系統(Personal Handyphone System ; PHS)、Wireless car aperture、全球移動通信系統 (System For Mobile ; GSM 900、GSM 1800)、分石馬多重存 取(Code Division Multiple Access ; CDMA)、一般封包式無 線月艮務(General Package Radio Service ; GPRS)、藍芽 (Bluetooth)、無線網路(Wireless Local Area Network ; WLAN)以及數位電視之頻帶。 201112488 某些天線結構僅能在預設之頻帶中運作,此乃頻率受 =天線之特性因而不適合多頻運作之緣故,並且天線之 ^不外乎金屬或合金,其若形成於破璃之上將影響能見 度。此外金屬原物料上漲成本提高。 【發明内容】 本發明係關於具有下列特徵之薄膜天線之製造方法。 -種薄膜天線製造方法,包含備置導電凝膠,將 凝谬塗佈於-基材表面上形成導電薄膜;將該導電型薄膜 '熱處理形成薄膜天線。其令導電性凝膠配置步驟包含備置 屬化合物。該稀類氧化物包含聚乙職 〇),♦乙烯氧化物(PE0)至少包含in(N 3 。其中金屬化合物包含 ^锡化合物。基板包含PCB、陶£、高分子、玻璃或纖 另實施例中,本發明揭露__種薄膜天線製造方法, 無機聚合物’利用無機物備置凝膠;將該凝膠塗佈 並:二面上形成薄膜;將該薄膜熱處理形成薄膜天線。 類。言=Hprcursor)為驗性氧化物,無機鹽及有機鹽 …,匕3 Sl〇2、Ti〇2或/及Ζη02。盔機豳包含氣化 物或/及罐酸鹽;有機鹽包含醋酸鹽。”,、機…-化 本發明之優點為不採用貴重之金屬原物料,故 :=用:膠凝膠與塗佈製造天線將使製造所得4 更輕、更小、更降低成本且製程簡化並環保。上述 方法亦可做為觸控面板透明電極製作方法’或顯示器透明 201112488 電極製作方法。 【實施方式】 本發月揭路考重〉專膜天線,本發明之較佳實施例包含 在物體上形成透明導電圖樣。一保護層可視需求塗佈在透 明導電圖樣上。物體可包含手持裝置基材或殼體、顯示表 面擔風玻璃、車輛之後視鏡、建築物窗戶等。在一實施 例中電源可選擇性地輕合至此天線結構以提供熱能或電 力,使此透明導電圖樣可除去玻璃上之霧氣或溼氣。天線 輸入阻抗匹配,JL φ钟λ憎+ & 人 ” Τ饋入ν電傳輸線乃以如300歐姆、50 ^姆或7 5歐姆之傳輸線製成。 導電圖樣之材料包含具有金屬之氧化物,其中該金屬 最好為-個或以上選自金、辞、銀、把、始、姥、釘、銅、 鐵、鎳、鈷、錫、鈦、銦、鋁、鈕、鎵、鍺、銻,而某些 以此方法製成之導電材質為透明,且假使此天線附著於玻 其將具有視覺穿透力。或者,此天線可形成在全球 籲足位系統(GPS)、無線滑鼠、無線鍵盤、遙控器、筆記型 電腦或打動電話等等之殼體或螢幕上可降低屏蔽效應。可 藉由空間變異(space_diversity)或極化變異技術來改進接 收系統。在此亦可採用兩個或數個之天線,而使用本發明 所述之技術其優點在於複數個附著於同一物體之天線可以 低成本來含括不同之結構。此饋入結構乃為本領域習知之 技術,其他天線之結構亦可應用於本發明相同之領域與精 神中。 天線之製作方法包含備置一基板,基板可以為pcB、 201112488 陶瓷、高分子、玻璃、纖維(例如紙纖維)等,較佳為PET, 其具可曲性’溫度可耐攝氏一百多度。隨之備製塗佈溶劑, 其步驟包含: 於低;^下形成無機聚合物(in〇rganiC p〇lymeric network); 將此無機物在低於此氧化物溶點的溫度下轉換成凝 膠; 前趨物(precursor)可為鹼性氧化物(alk_〇xides), 籲[M(OR)n,Rx-M(〇R)n-x];無機鹽(例如氯化物、硝酸鹽);有 機鹽類(例如醋酸鹽、acetylacetonate)。上述程序包含溶液 轉換成膠體;及鹼性物的置換。參閱第一圖及第二圖。 以溶膠·凝膠法(Sol-Gel)與旋轉塗佈法(Spin c〇ating) 製作Ti〇2,添加不同比例APTMS(Si〇2)# 丁丨〇2顆粒間的 黏結劑,來增加Ti〇2顆粒間的接觸面積,以降低内電阻, 細化晶粒。Ti〇2顆粒接觸面積變大,其中添加5wt%ApTMs #的Ti〇2電極,具較佳光電轉換。舉一實施例而言,利用上 述程序可製作天線塗佈溶液,上述前趨物可包含 Si(〇C/H5)4,Ti(OC2H5)4 或/及 Zr(〇C3H7)4 ;初始溶液成份: 鹼性氧化物:酒精=1:18_2〇,鹼性氧化物:水=1:1_2,較佳為 鹼性氧化物:酒精:水=1:19 3:1 85,pH=3 5。以上可製作 2 i〇2 ’ Si〇2-2;r02。塗佈可採旋轉塗佈,每分鐘2⑼〇 轉。 在另一實施例中,可在In2〇3得到In氧化物,將其與 Sn處理可得IT〇溶膠凝膠液,將其旋轉塗佈後可得加 201112488 薄膜。其製作實施例包含混合10 wt %及5 Wt %的聚乙 缔氧化物PEO poly (ethylene oxide)溶液與In、Sn化合物 例如 In(N0)3.3H20, In(Ac)3, SnCl2.2H20,或 Sn(c2〇4),之 後以熱分解處理,溫度為攝氏450至600間。前趨物莫爾 比例約為9:l(In/Sn)。 之後使其乾燥化後,可裁切或壓印成天線圖案;亦可 利用網印技術’配合塗佈製作天線圖案。表面上具有圖樣 化溶液之基材將經由室溫至攝氏九十度之溫度處理使此溶 液乾躁,以得到一透明導電層。接續,再以高於攝氏—百 度之溫度例如攝氏180度至22〇度間之溫度進行熱處理大 約一至二小時或以電磁輻射照射烘烤來降低薄膜之電阻並 增進其透光度。 ''201112488 VI. Description of the Invention: [Technical Field] The present invention relates to an antenna, and more particularly to a method of manufacturing a film antenna. [Prior Art] In recent years, wireless transmission technology has been widely developed all over the world, and most wireless devices such as mobile phones, personal digital assistants, and digital televisions need to use receiving devices that receive transmission signals. Since the information transmission = localization' (4), various information such as audio signals and video signals can be edited by Shiren (5), swaying devices, etc., and the sound and image: Jin Ruding can enhance the above information types. Band compression. The digital second pass can make it easy and efficient to transmit such information to the terminal phone. The audio image data (AV data) is transmitted to a portable wireless transmission module, which is installed or separated by the connector. The data from the main device can be transferred from the flash memory to the main device. When the amp is to be stunned by %, the wireless transmission module performs the main part of the antenna part of the line and the antenna element is usually manufactured on the special circuit for the circuit, so it is here. The control of the circuit's median value and the resistance characteristic is not to be able to ignore the key (4) and the length of the transmitting antenna is off: the ten elements. The two substrates affecting the enthalpy are the dielectric constant (sometimes referred to as the relative mediator) and the dielectric loss (sometimes called 201112488 as the dissipation factor), where the dielectric constant determines the signal on the substrate material. The transmission speed in the transmission line and the length of the signal transmission and transmission of other parts applied to the substrate. The dielectric loss is the loss caused by the transmission of the signal in the substrate material, and the loss increases as the frequency becomes larger. Printed transmission lines, passive circuits, and radiating elements for RF circuits are typically formed in one of three ways. The first is a micro-strip structure that places signal lines on the surface of the board and provides a conductive layer, generally referred to as a ground plane. The second is a buried micro-strip structure, except that the signal line is covered by a dielectric substrate material, and the first structure Similarly, the third is a strip-line structure in which the signal line is between two conductive (ground) faces and the antenna is placed on the main plane of the printed circuit board. For the application of vehicles, most of the solutions for such systems are to install the whip antenna on the roof of the car. Compared with the current trend of car design, these antennas are embedded in the vehicle structure to reduce the antenna's aesthetic appearance. The aerodynamic impact of φ. Moreover, the integration of several telecommunication services into a single antenna will reduce the cost of manufacturing. The antenna receive band includes: Frequency Modulation (FM), Personal Handyphone System (PHS), Wireless car aperture, Global System for Mobile Communications (System For Mobile; GSM 900, GSM 1800), Code Division Multiple Access (CDMA), General Package Radio Service (GPRS) , Bluetooth, Wireless Local Area Network (WLAN), and digital TV band. 201112488 Some antenna structures can only operate in a preset frequency band, which is due to the characteristics of the antenna = not suitable for many Frequency operation, and the antenna is no more than metal or alloy, if it is formed in the glass Further, the present invention relates to a method for manufacturing a film antenna having the following features: A method for manufacturing a film antenna comprising preparing a conductive gel and applying a gel to - A conductive film is formed on the surface of the substrate; the conductive film is heat treated to form a film antenna. It allows the conductive gel configuration step to comprise a host compound. The rare oxide comprises polyethylation, ♦ the ethylene oxide (PE0) comprises at least (N 3 ), wherein the metal compound comprises a tin compound. The substrate comprises a PCB, a ceramic, a polymer, a glass or a fiber. The invention discloses a method for manufacturing a film antenna, wherein an inorganic polymer is prepared by using an inorganic material; the gel is coated and a film is formed on both sides; and the film is heat-treated to form a film antenna. Class = Hprcursor It is an inorganic oxide, an inorganic salt and an organic salt..., 匕3 Sl〇2, Ti〇2 or/and Ζη02. The helmet machine contains a gasification or/and a can acid salt; the organic salt contains an acetate salt. The advantage of the present invention is that it does not use precious metal raw materials, so: = use: gelatin gel and coating to manufacture the antenna will make the manufacturing result 4 lighter, smaller, lower cost and simplified process The above method can also be used as a method for manufacturing a transparent electrode of a touch panel or a method for manufacturing a transparent display of the display 201112488. [Embodiment] The present invention discloses a special embodiment of the present invention. A transparent conductive pattern is formed thereon. A protective layer can be coated on the transparent conductive pattern as needed. The object can include a handheld device substrate or housing, a display surface windshield, a vehicle rearview mirror, a building window, etc. In an embodiment The medium power supply can be selectively coupled to the antenna structure to provide thermal energy or power, so that the transparent conductive pattern can remove mist or moisture on the glass. The antenna input impedance is matched, JL φ clock λ 憎 + &; ” Τ The ν electric transmission line is made of a transmission line such as 300 ohms, 50 ohms or 75 ohms. The material of the conductive pattern comprises an oxide having a metal, wherein the metal is preferably one or more selected from the group consisting of gold, rhodium, silver, rhodium, ruthenium, rhodium, copper, iron, nickel, cobalt, tin, titanium, indium. , aluminum, button, gallium, germanium, tantalum, and some of the conductive materials made by this method are transparent, and if this antenna is attached to the glass, it will have visual penetrating power. Alternatively, the antenna can be formed on a housing or screen of a global foothold system (GPS), wireless mouse, wireless keyboard, remote control, notebook or mobile phone to reduce the shielding effect. The receiving system can be improved by spatial variability (space_diversity) or polarization variation techniques. Two or more antennas may also be used herein, and the technique described in the present invention has the advantage that a plurality of antennas attached to the same object can include different structures at low cost. This feedthrough structure is a technique well known in the art, and the structure of other antennas can also be applied to the same fields and spirits of the present invention. The method for fabricating the antenna comprises preparing a substrate, which may be pcB, 201112488 ceramic, polymer, glass, fiber (for example, paper fiber), etc., preferably PET, which has a flexibility of temperature of more than one hundred degrees Celsius. Preparing a coating solvent, the step comprising: forming an inorganic polymer (in〇rganiC p〇lymeric network) at a low level; converting the inorganic substance into a gel at a temperature lower than a melting point of the oxide; The precursor may be a basic oxide (alk_〇xides), [M(OR)n, Rx-M(〇R)nx]; an inorganic salt (such as chloride, nitrate); an organic salt Classes (eg acetate, acetylacetonate). The above procedure involves the conversion of the solution to a colloid; and the replacement of the basic substance. See the first and second figures. Ti〇2 was prepared by Sol-Gel method and spin coating method, and a binder was added between different ratios of APTMS(Si〇2)#丁丨〇2 particles to increase Ti.接触 2 contact area between particles to reduce internal resistance and refine grains. The Ti〇2 particle contact area becomes large, and a Tiwt2 electrode of 5 wt% ApTMs # is added, which has better photoelectric conversion. In one embodiment, the antenna coating solution can be prepared by the above procedure, and the precursor can include Si(〇C/H5)4, Ti(OC2H5)4 or/and Zr(〇C3H7)4; initial solution composition : Alkaline oxide: Alcohol = 1:18_2 〇, basic oxide: water = 1:1_2, preferably basic oxide: alcohol: water = 1:19 3:1 85, pH = 3 5. The above can produce 2 i〇2 ′ Si〇2-2; r02. The coating can be spin coated at 2 (9) rpm. In another embodiment, an In oxide can be obtained at In2〇3, which can be treated with Sn to obtain an IT〇 sol-gel solution, which can be spin-coated to obtain a 201112488 film. The preparation example comprises mixing 10 wt% and 5 wt% of a polyethylene oxide PEO poly (ethylene oxide) solution with In, Sn compounds such as In(N0)3.3H20, In(Ac)3, SnCl2.2H20, or Sn (c2 〇 4), followed by thermal decomposition treatment, the temperature is between 450 and 600 ° C. The precursor Moire ratio is about 9:1 (In/Sn). After it is dried, it can be cut or embossed into an antenna pattern; the antenna pattern can also be fabricated by screen printing technology. The substrate having the patterned solution on the surface is treated with a temperature of from room temperature to 90 degrees Celsius to dry the solution to obtain a transparent conductive layer. After the continuation, the heat treatment is performed at a temperature higher than the temperature of Celsius-100 degrees Celsius, for example, between 180 degrees Celsius and 22 degrees Celsius for about one to two hours or by irradiation with electromagnetic radiation to reduce the electrical resistance of the film and increase its transmittance. ''

本發明揭露附著於窗戶、玻璃或擋風玻璃至少一面上 之透明天線結構。一傳輸線可藉由歐姆接觸或一電容或電 導麵合機制來搞合至天線結構之圖樣。一除濕電源可藉由 傳輸線耦合至此天線結構以提供熱能至此圖樣來除去玻璃 或窗戶上之霧氣或水分。因&,在某些情況中,此結構可 包含雙重功能,作為—接收訊號以及除霧或除濕之裝置。 在八他實化例中上述各實施例之材質可包含導電高分 碳或導電膠來提升導電度。利用非金屬材質將使 ^ ^ 〇 ^更)降低成本(不採用貴重之金屬原物料)以 及製程簡化。例如傳統约 勾知用銅材,其重且昂貴。相反的 本I明採用非金屬材質作或^ ^ .^ ^ ^ 貝作為天線。非金屬天線在此指的是 天線主體不採用金屬原物料,非不含金屬添加物、或顆粒。 201112488 上述材質得透過移印之技術製作,製程較金屬材質容易且 不會污染環境,傳統天線採用蝕刻或電鍍汙染問題嚴重。 且此薄膜式天線可以附著於不規則或不平表面。此外,手 持裝置之傳統天線均配置於印刷電路板上,故極易與電子 元件間造成干擾。但是依據本發明可以將天線自電路板上 移走。若其為透明,則可以貼附於銀幕或玻璃或外表面。 一實施例為採用導電高分子,其可以利用前驅物製作 (precursor monomer),其選自塞吩(thiophenes)、石西吩 (selenophenes)、碌吩(tellurophenes)、°比 11 各(pyrroles)、苯 胺(anilines)、多環芳香族(polycyclic aromatics),以此製作 高分子可包含但不限於聚塞吩(polythiophenes)、聚砸吩 (poly(selenophenes) ' (poly(tellurophenes)) ' ^ ^ (polypyrroles)、聚苯胺(polyanilines)、多環芳香族聚合物 (polycyclic aromatic polymers)等。美國專利 US. Patent Application 20080017852 to Huh; Dal Ho et al·,發明名稱 為 “Conductive Polymer Composition Comprising Organic Ionic Salt and Optoelectronic Device Using the Same” 揭露 製作導電高分子之方法可做參考。再另一實施例中,導電 高分子為有機高分子半導體(organic polymer semiconductor)或有機半導體(organic semiconductor)。導電 聚乙炔(polyacetylenes)型態包含聚乙炔(p〇iyacetyiene)、聚 吡咯(polypyrrole)、聚苯胺(polyaniiine)及其衍生物 (derivatives)。導電有機高分子通常具有延伸非定域鍵 (extended delocalized bonds),此造成導帶結構(band r 1 201112488 structure) ’類似於矽但是具有定域態(l〇caiized states)。此 零能隙(zero-band gap)導電向分子具有類金屬行為。 導電膠體可以包含至少一種玻璃、金屬微粒以及添加 物。其中該玻璃選自下列族群之一或其組合:氧化鋁 (Al2〇3)、氧化硼(B2〇3)、二氧化矽(Si02)、氧化鐵(Fe2〇3)、 氧化填(P2〇5)、二孰化鈦(Ti〇2)、氧化侧/蝴酸/四棚酸鈉 (B203/ H3B03/ Na2B4〇7)、氧化錯(Pbo)、氧化鎂(MgO)、 氧化鎵(Ga203)、氧化鋰(Li2〇)、五氧化二釩(v2〇5)、過氧 鲁化鋅(Zn〇2)、氧化鈉(仏2〇) '氧化鍅(Zr〇2)、氧化鉈/三氧 化二鉈/氫氧化鉈(Τ1〇/Τ12〇3/Τ10Η)、氧化鎳/鎳(Nio/ Ni)、一氧化Μ(Μη02)、氧化銅(CuO)、氧化銀(Ag〇)、氧 化銳(SqO3)、氧化锶(Sr〇)、氧化鋇(Ba〇)、氧化鈣(Ca〇)、 雀匕(T1)、氧化鋅(Zn〇)。添加物可以包含油酸(〇leic acid)。 天線得包含不同形狀。倒F天線可參閱2〇〇7年7月3曰 提出申請之美國專利公開第20080001826號。上述各實施 φ方式亦可製作太陽能導電電極。天線結構可配置於手持裝 置行動電活、筆記型電腦、個人數位助理、可攜式裝置、 、L 載八近场通戒(Near Field Communication; NFC)應 用。 〜 對熟悉此領域技,本創作雖以較佳實例闊明如 上,然其並非用以限定本創作精神。在不脫離本創作之精 範圍:所作之修改與類似的配置,均應包含在下述之 月專利In圍内’此知圍應覆蓋所有類似修改與類似結 構’且應做最寬廣的詮釋。 201112488 【圖式簡單說明】 第一圖為溶液-凝膠反應。 第二圖為鹼性氧化物凝膠反應。 【主要元件符號說明】 無The present invention discloses a transparent antenna structure attached to at least one side of a window, glass or windshield. A transmission line can be coupled to the pattern of the antenna structure by an ohmic contact or a capacitive or electrical conduction mechanism. A dehumidification power source can be coupled to the antenna structure by a transmission line to provide thermal energy to the pattern to remove mist or moisture from the glass or window. Because of &, in some cases, this structure can include dual functions as a means of receiving signals and defogging or dehumidifying. In the eight embodiments, the materials of the above embodiments may include conductive high carbon or conductive paste to enhance conductivity. The use of non-metallic materials will reduce the cost of ^ ^ 〇 ^) (no precious metal raw materials) and process simplification. For example, the traditional use of copper is heavy and expensive. In contrast, this is a non-metallic material or ^ ^ .^ ^ ^ shell as an antenna. The non-metallic antenna here means that the antenna body does not use metal raw materials, and does not contain metal additives or particles. 201112488 The above materials can be made by the technique of pad printing. The process is easier than metal and does not pollute the environment. The traditional antenna is seriously etched or electroplated. And the film antenna can be attached to an irregular or uneven surface. In addition, the conventional antenna of the handheld device is disposed on the printed circuit board, so that it is easy to cause interference with the electronic components. However, the antenna can be removed from the board in accordance with the present invention. If it is transparent, it can be attached to a screen or glass or outer surface. One embodiment employs a conductive polymer which can be made from a precursor monomer selected from the group consisting of thiophenes, selenophenes, tellurophenes, pyrroles, Anions and polycyclic aromatics can be used to make polymers including, but not limited to, polythiophenes, poly(selenophenes) (poly(tellurophenes)' ^ ( Polypyrroles), polyanilines, polycyclic aromatic polymers, etc. US Patent US Patent Application 20080017852 to Huh; Dal Ho et al., entitled "Conductive Polymer Composition Comprising Organic Ionic Salt and Optoelectronic Device Using the Same" discloses a method for fabricating a conductive polymer. In another embodiment, the conductive polymer is an organic polymer semiconductor or an organic semiconductor. Polyacetylenes are conductive. ) type includes polyacetylene (p〇iyacetyiene), polypyrrole (polypyr) Role), polyaniiine and its derivatives. Conductive organic polymers usually have extended delocalized bonds, which cause the band structure (band r 1 201112488 structure) 'similar to 矽Having a localized state. The zero-band gap has a metalloid behavior to the molecule. The conductive colloid may comprise at least one glass, metal particles, and an additive, wherein the glass is selected from the group consisting of One or a combination thereof: alumina (Al2〇3), boron oxide (B2〇3), cerium oxide (SiO 2 ), iron oxide (Fe 2 〇 3 ), oxidized filling (P 2 〇 5), titanium dihalide ( Ti〇2), oxidized side/folic acid/sodium sulphate (B203/H3B03/Na2B4〇7), oxidized (Pbo), magnesium oxide (MgO), gallium oxide (Ga203), lithium oxide (Li2〇), Vanadium pentoxide (v2〇5), zinc peroxygenate (Zn〇2), sodium oxide (仏2〇) 'Zr〇2, yttria/niobium oxide/barium hydroxide (Τ1) 〇/Τ12〇3/Τ10Η), nickel oxide/nickel (Nio/Ni), niobium monoxide (Μη02), copper oxide (CuO), silver oxide (Ag〇), oxygen Sharpening (SqO3), strontium oxide (Sr〇), barium oxide (Ba〇), calcium oxide (Ca〇), gar (T1), zinc oxide (Zn〇). The additive may comprise oleic acid. The antenna has to be shaped differently. The inverted-F antenna is described in U.S. Patent Publication No. 20080001826, filed on Jan. 3, 2008. The solar conductive electrode can also be fabricated by the above-described φ method. The antenna structure can be configured for handheld mobile devices, notebook computers, personal digital assistants, portable devices, and Near Field Communication (NFC) applications. ~ For the familiarity with this field of technology, this creation is not limited to the spirit of this creation, although it is more broadly illustrated. Without departing from the scope of this work, the modifications and similar configurations are to be included in the following patents, which should cover all similar modifications and similar structures and should be interpreted broadly. 201112488 [Simple description of the diagram] The first picture shows the solution-gel reaction. The second picture shows the alkaline oxide gel reaction. [Main component symbol description] None

1111

Claims (1)

201112488 七、申請專利範圍: 1. 一種薄膜天線製造方法,包含: 備置導電性凝膠; 將該導電性凝膠塗佈於一基材表面上形成導電薄骐; 將該導電型薄膜熱處理形成薄膜天線。 2. 士二求項1所述之薄膜天線之製造方法,其中該導電性 凝膠配置步驟包含備置烯類氧化物與金屬化合物。 3. 如请求項2所述之薄膜天線之製造方法,其中該烯類氧 化物包含聚乙烯氧化物(pE〇)。 4. 如叫求項3所述之薄膜天線之製造方法,其中該聚乙烯 氧化物(PE〇)至少包含 In(N0)3.3H20,In(Ac)3, SnCl2.2H2〇,或 Sn(C2〇4)。 5. 如請求項2所述之薄膜天線之製造方法,其中該金屬化 合物包含銦、錫化合物。 6·如請求項1所述之薄膜天線之製造方法,其中該基板包 含PCB、陶瓷、高分子、玻璃或纖維。 7.如請求項1所述之薄膜天線之製造方法,其中該基材包 含 PET ° 12 201112488 8. —種薄膜天線製造方法,包含·· 形成無機聚合物; 利用該無機物備置凝膠; 將該凝膠塗佈於基材表面上形成薄膜; 將該薄臈熱處理形成薄膜天線。 鲁9. %請求項8所述之薄膜天線之製造方法, 3 PCB、/T匈莞、高分子、玻璃或纖維。 10.如请求項8所述之薄膜天線之製造方法, 含 ΪΈΤ。 11. 如凊求項8所述之薄膜天線之製造方氽 含 Ti〇2 〇 12. 如請求項8所述之薄膜天線之製造方法 含 Zn〇2 〇 13. 如凊求項8所述之薄臈天線之製造方法 含 Si〇2 〇 14. 如凊求項8所述之薄膜天線之製造方法 含驗性氧化物、無機鹽、有機鹽。 其_該基板包 中該基材包 ,&中該凝膠包 ,其中該凝膠包 ,其中該凝膠包 ,其中前趨物包 13 201112488 15. 如請求項15所述之薄膜天線之製造方法’其中該無機 鹽包含氣化物或/及硝酸鹽。 16. 如請求項15所述之薄膜天線之製造方法,其中該有機 鹽包含醋酸鹽。 17. 如請求項15所述之薄膜天線之製造方法,其中該前趨 物包含 Si(〇C2H5)4 ’ Ti(〇C2H5)4 或/及 Zr(OC3H7)4。 18. 一種觸控面板薄膜電極製造方法,包含: 備置導電性凝膠; 將及導電性凝膠塗佈於一透明基材表面上形成導電薄 臈; 將該導電型薄膜熱處理形成薄膜透明電極。 j明求項18所述之觸控面板薄膜電極製造方法,其中 亥電性凝勝配置步驟句令Y卷罢,膝步g & & 合物 且v郤匕3備置烯類氧化物與金屬化 求項19所述之觸控面板薄膜電極製造方法,其中 '類氧化物包含聚乙烯氧化物(ρΕ〇)。 21 ·如請求項20所述之觸於面叔键 <〈觸衩面扳溥膜電極製造方法,其申 201112488 該聚乙烯氧化物(PEO)至少包含in(N〇)3.3H2〇, In(Ac)3, SnCl2‘2H20,或 Sn(C204)。 22.如請求項18所述之觸控面板薄膜電極製造方法,其中 該金屬化合物包含銦、錫化合物。 23 ·如請求項18所述之觸控面板薄膜電極製造方法,其中 該透明基板包含玻璃。 24. 如請求項18所述之觸控面板薄膜電極製造方法,其中 該透明基材包含PET。 25. —種觸控面板薄膜電極製造方法,包含: 形成無機聚合物; 利用該無機物備置凝膠; ♦冑該凝膠塗佈於基材表Φ上形成薄膜 將該薄獏熱處理形成薄膜透明電極。201112488 VII. Patent application scope: 1. A method for manufacturing a film antenna, comprising: preparing a conductive gel; applying the conductive gel on a surface of a substrate to form a conductive thin crucible; heat treating the conductive film to form a film antenna. 2. The method of manufacturing a film antenna according to Item 1, wherein the conductive gel disposing step comprises preparing an olefin oxide and a metal compound. 3. The method of producing a film antenna according to claim 2, wherein the olefin oxide comprises polyethylene oxide (pE 〇). 4. The method of manufacturing a film antenna according to claim 3, wherein the polyethylene oxide (PE〇) comprises at least In(N0)3.3H20, In(Ac)3, SnCl2.2H2〇, or Sn(C2) 〇 4). 5. The method of producing a film antenna according to claim 2, wherein the metal compound comprises indium or a tin compound. The method of manufacturing a film antenna according to claim 1, wherein the substrate comprises a PCB, a ceramic, a polymer, a glass or a fiber. 7. The method of manufacturing a film antenna according to claim 1, wherein the substrate comprises PET ° 12 201112488. 8. A method for manufacturing a film antenna, comprising: forming an inorganic polymer; preparing a gel using the inorganic material; The gel is applied to the surface of the substrate to form a film; the thin crucible is heat treated to form a film antenna. Lu 9. The method for manufacturing a film antenna according to claim 8, 3 PCB, /T Hung Wan, polymer, glass or fiber. 10. The method of manufacturing a film antenna according to claim 8, comprising ΪΈΤ. 11. The manufacturing method of the film antenna according to Item 8 is Ti〇2 〇12. The method for manufacturing a film antenna according to claim 8 contains Zn〇2 〇13. The method for producing a thin-twist antenna includes Si〇2 〇14. The method for producing a film antenna according to claim 8 includes an organic oxide, an inorganic salt, and an organic salt. The substrate package of the substrate package, & the gel pack, wherein the gel pack, wherein the gel pack, wherein the precursor pack 13 201112488 15. The film antenna of claim 15 A method of manufacture wherein the inorganic salt comprises a vapor or/and a nitrate. 16. The method of producing a film antenna according to claim 15, wherein the organic salt comprises an acetate. 17. The method of fabricating a film antenna according to claim 15, wherein the precursor comprises Si(〇C2H5)4'Ti(〇C2H5)4 or/and Zr(OC3H7)4. 18. A method of manufacturing a touch panel thin film electrode, comprising: preparing a conductive gel; and coating a conductive gel on a surface of a transparent substrate to form a conductive thin film; and heat treating the conductive film to form a thin film transparent electrode. The method for manufacturing a touch panel film electrode according to claim 18, wherein the step of arranging the yoke is performed, the step Y is performed, the knee is g && The method for producing a touch panel thin film electrode according to claim 19, wherein the 'oxide-like oxide comprises polyethylene oxide (ρΕ〇). 21. The method according to claim 20, wherein the polyethylene oxide (PEO) comprises at least (N〇)3.3H2〇, In (Ac)3, SnCl2'2H20, or Sn(C204). The method of manufacturing a touch panel film electrode according to claim 18, wherein the metal compound comprises indium or a tin compound. The method of manufacturing a touch panel film electrode according to claim 18, wherein the transparent substrate comprises glass. 24. The method of manufacturing a touch panel film electrode according to claim 18, wherein the transparent substrate comprises PET. 25. A method of manufacturing a touch panel film electrode, comprising: forming an inorganic polymer; preparing a gel using the inorganic material; ♦ applying the gel to a surface of the substrate Φ to form a film, and heat treating the thin enamel to form a thin film transparent electrode . 忒透明基板包含玻璃。 所述之觸控面板薄膜電極製造方法,其中The transparent substrate contains glass. The method for manufacturing a touch panel film electrode, wherein 面板薄膜電極,其中該透明基 15 201112488 28. 如請求項25所述 丄t 啊役由扳溥臈電極制4 +、 s亥凝膠包含Ti02。 衣k方法,其中 29. 如請求们5所敎觸控面板薄 該凝膠包含Zn〇,。 、和Ik方法,其中 其中 心::25所述之觸控面板薄膜電極製造方法, 11亥凝勝包含Si02。 3 1 ·如凊求項25所述之觸护面柘 其中 前趨物、a 寻臈電極製造方法, I 3鹼性乳化物、無機鹽、有機鹽。 32::ί項31所述之觸控面板薄膜電極製造方法,i中 5亥無機鹽包含氣化物或/及硝酸鹽。 '、 33.如明求項31所述之觸控面板薄臈電極製造方法,其中 遠有機鹽包含醋酸鹽。 二月长項25所述之觸控面板薄膜電極製造方法,其中 X 4 趨物包含 Si(oc2h5)4 ,Ti(OC2H5)4 或 / 及 Zr(〇C3Jj7)4 〇 16Panel film electrode, wherein the transparent substrate 15 201112488 28. As claimed in claim 25, 丄t is made of iridium electrode 4 +, s hai gel contains TiO 2 . The clothing k method, wherein 29. As requested by the 5 touch panel thinner, the gel contains Zn〇. And the Ik method, wherein the method of manufacturing the touch panel thin film electrode according to the core:: 25, the haisheng includes SiO 2 . 3 1 · The contact surface described in Item 25, wherein the precursor, a method for producing the electrode, I 3 alkaline emulsion, inorganic salt, organic salt. 32: The method for manufacturing a touch panel thin film electrode according to claim 31, wherein the inorganic salt of the sulphide contains a vapor or/and a nitrate. The method of manufacturing a thin-touch electrode of a touch panel according to claim 31, wherein the far organic salt comprises an acetate. The method for manufacturing a touch panel film electrode according to the item of claim 25, wherein the X 4 trend comprises Si(oc2h5)4, Ti(OC2H5)4 or / and Zr(〇C3Jj7)4 〇16
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