TW201109035A - Composition - Google Patents

Abstract

Concentrated conditioning shampoo composition comprising from 27-70% wt. cleaning phase, a conditioning gel phase and an oil selected from triglyceride oils, hydrocarbon oils, ester oils, polyolefin oil and mixtures thereof wherein the conditioning gel phase comprises: (a) fatty material; (b) a gel network anionic surfactant comprising an alkyl group with from 16 to 30 carbons; (c) cationic surfactant; wherein the conditioning gel network has no overall charge or is anionic.

Description

201109035 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a triglyceride containing a triglyceride. [Prior Art] Diester oil has been modified, although it has prior art, it still needs to include glycerin. Concentrated conditioning shampoo composition. SUMMARY OF THE INVENTION Accordingly, the present invention provides a concentrated conditioning shampoo composition according to the scope of the patent application. The compositions according to the present invention provide improved moisturizing conditioning feel for concentrated shampoos. This is especially surprising because local surfactants are prone to rustling and a messy sensation. Triglyceride oils Suitable triglycerides S oils include fats and oils (including natural fats and oils) such as jojoba oil, soybean oil, sunflower oil, rice bran oil, avocado oil, Almond oil, eucalyptus oil, sesame oil, sesame oil, coconut oil, coconut tree oil, sunflower oil, oil; cocoa butter; butter, lard' · hardened oil obtained by hydrogenation of the aforementioned oil; and synthetic glycerin , di- and tri-acid esters (such as glyceryl myristate and 2-ethylhexanoic acid). Preferably, the triglyceride oil is from 5 to 1 weight by weight of the composition. /. There is, in particular, 0.2 to 5% by weight, in particular 〇. 5 to 3% by weight. Suitable hydrocarbon oils for hydrocarbon oils have at least 12 carbon atoms' and include rocky oil, poly 148372.doc 201109035 smoky oil, mineral oil, saturated and unsaturated dodecane, saturated and unsaturated tridecane, saturated and not Saturated tetradecane, saturated and unsaturated pentadecane, saturated and unsaturated hexadecane, and mixtures thereof. It is also suitable to use a branched hydrocarbon isomer of these compounds and a polymeric hydrocarbon such as polyisobutylene having a high carbon number chain length. Mixtures of any of the above may also be employed. Preferably, from 10 to 100% by weight of the hydrocarbon oil has a viscosity of from 0.01 to 60 〇 cPs as measured according to ASTM D-445 at 3 Torr. Preferably, the smoky oil is present in an amount of from 5 to 1% by weight, based on the weight of the composition, especially from 0.2 to 5% by weight, and especially from 0.5 to 3% by weight. Ester Oil The other component used in the compositions of the present invention is an ester oil. The ester oil imparts conditioning benefits to the shampoo. Suitable ester oils have at least one carbon atom and include a hydrocarbyl chain derived from a fatty acid or an alcohol. The general g oil is a chemical formula R, C〇〇R, ◎ wherein R' and R independently represent an alkyl group or an alkenyl group, and the total number of carbon atoms in R and R is at least 10', preferably at least 20. It is also possible to use a carboxylic acid di- and a tri-alkyl group and an alkenyl group. Mixtures of any of the above may also be employed. Preferably, the ester oil is present in an amount of up to 5% by weight, based on the weight of the composition, especially from 0.2 to 5% by weight, and especially from 〇5 to 3 parts by weight/0. Polyalphaphthalene oleum Suitable polyalphaolefin oils include those derived from oxime alkylene monomers having from 6 to 16 carbons, preferably from 6 to 12 carbons. Non-limiting examples of these materials 148372.doc 201109035 Examples include 1-hexene, 1-octyl, decimene, dodecene, tetradecene, 1-hexadecene, branched isomers (such as 4-methylpentene) and mixtures thereof. Hydrogenated polydecene is another suitable material. Preferably, the poly-α-lean hydrocarbon oil comprises a pure molecular weight of about 5 之 in the _obil company under the trade name Puresyn 6, a puresyn 1 具有 having a molecular weight of about 3 〇〇, and a puresyn having a molecular weight of about 6,000. 3 〇〇 癸 。 。 。. Preferably, the poly"olefin oil is present in an amount of from 5 to 1% by weight, based on the weight of the composition, especially '0.2 to 5% by weight' and especially 〇(1)% by weight. Conditioning gel phase The conditioning gel network comprises: (a) a fatty material; comprising an alkyl group having 16 to 30 (b) gel network anionic surfactant carbon; (c) a cationic surfactant; wherein the conditioning The gel network as a whole is uncharged or anionic. The cationic surfactant provides improved stability of the fat f/anionic surfactant gel network to result in improved conditioning benefits for compositions that also include a non-cationic cleansing phase. The difference in carbon bond length between the anionic surfactant in the cleansing phase and the anionic surfactant in the conditioning gel will improve the stability of the gel network and maintain its integrity in the shampoo composition. Preferably, the (4) and cationic surface of the gel network towel are active, and the carbon chain length difference of (4) comprises 4 carbon atoms, preferably a paste carbon atom ^ 148372.doc 201109035 preferably the two active agents contain the same The amount of carbon. More preferably, the other comprises a single alkyl group having a carbon-tooth length difference of 4 or less, and more than 2 paper lengths, and the best θ is the same length. This can help maintain the stability of the gel network. Preferably, the carbon network of the gel network cationic surface active is present in the mono-alkyl group. More preferably, the gel network has a cationic surface activity of from 16 to 30 carbons. The conditioning gel network is made prior to incorporation of the remaining components of the composition. The oil can be dispersed in the conditioning gel phase or added later before the package is incorporated into the shampoo. ~ GN Cationic Surfactant Preferably, the conditioning gel network comprises a cationic surfactant having 14 to 3 carbons. Preferably, the carbon system in the gel network cationic surfactant is present in a single alkyl group. More preferably, the gel network cationic surfactant has from 16 to 30 carbons. Q Preferably, the cationic surfactant has the formula Ν»(Ι12)(Ι13) (Ιΐν where Ri, R2, R3 and R4 are independently (Ci6 to C3Q) alkyl or benzyl. Preferably, One of R1, R2, R3 and R4, two or two of which are independently (C to C3〇)alkyl groups and the remaining R1, R2, R3 and R4 groups or such groups are alkane The base or the benzyl group may optionally contain one or more or -COO-) and/or ether (-0-) bonds in the base bond. The alkyl group may optionally be substituted with one or more via groups. The alkyl group may be straight or branched, and cyclic (when having three or more alkyl groups of 148372.doc 201109035 carbon atoms). The alkyl group can be saturated or can contain one or more carbon-carbon double bonds (eg, an oil base). The alkyl group is optionally ethoxylated on the alkyl chain via one or more extended ethyloxy groups. Suitable cationic surfactants for use in the conditioner compositions according to the present invention include hexadecyltrimethylammonium chloride, gasification of twenty-two yards of trimethyl sulphate, hexadecanoyl decyl rust, and chlorinated tetramethyl chloride. Ammonium, tetraethylammonium chloride, octadecyl-methylbenzylammonium chloride, chlorinated trimethylammonium chloride, pEG_2_oleyl ammonium chloride and its corresponding hydroxide. Other suitable cationic surfactants include those under the CTFA name Quaternium _5, quaternary salt salt, and quaternary ammonium salt -18. a mixture of any of the foregoing substances

suitable. Cationic surfactants which are particularly suitable for use in the conditioning agent according to the present invention are, for example, gasified cetyltrimethylammonium commercially available from the GENAMi N CTAC product of Hoechst Celanese. Another cationic surfactant which is particularly suitable for use in conditioners according to the present invention is, for example, behenyl chloride, commercially available from the company, GENAMIN KDMP. Another example of a positive ionic surfactant suitable for use in the present invention (alone or in combination with one or more other cationic conditioning surfactants) is a combination of the following (1) and (ii): (i) corresponding to the following general formula (1) Amidoxime: /R2

R^ONHCCHj^N \r3 wherein R is a hydrocarbyl chain having 1 or more carbon atoms, and R2 and R3 are independently selected from a hydrocarbyl chain of 1 to 10 carbon atoms and 148372.doc 201109035 m is 1 to An integer of about ι〇; and (ii) an acid. The term hydrocarbyl chain as used herein means an alkyl chain or an alkenyl chain. Preferred amine amino amine compounds are those corresponding to the formula (1) wherein R1 is a hydrocarbon group having from about 11 to about 24 carbon atoms, and R2 and R3 are each independently a hydrocarbon group having from 1 to about 4 carbon atoms. (preferably an alkyl group), and m is an integer from 1 to about 4. Preferably, 'R2 and R3 are anthracenyl or ethyl. Preferably, m is 2 or 3, i.e., an extended or extended propyl group. Preferred guanamine amines suitable for use herein include stearyl propyl dimethyl dimethylamine, stearyl propyl propyl diethylamine, stearyl amide ethyl diethyl amide, stearyl amide Dimethylamine, palmitoylpropyl dimethylamine, palmitosylpropyldiethylamine, palmitosylethyldiethylamine, palmitoylethyldiamine, behenamide Propyldiamine, behenylpropyldiethylamine, behenylethyldiethylamine, behenylethyl dimethylamine, arachidonic acid propylidene Amine, arachidonic acid propyldiethylamine, arachidonic acid ethyl diethylamine, arachidonic acid ethyl dimethylamine, and mixtures thereof. Suitable guanamine amines for use herein are stearyl propyl dimethyl dimethylamine, stearyl amidoethyl diethylamine, and mixtures thereof.

Commercially available guanamine amines are commercially available from Inolex (Philadelphia Pennsylvania, USA) under the tradename LEXAMINE S-13 and from the stearylamine base of Nikko (Tokyo, Japan) under the trade name AMIDOAMINE MSP. Propyldiamine, commercially available from Nikko's stearylamine ethyldiethylamine under the trade name AMIDOAMINE 148372.doc 201109035 S, available from Croda (North Humberside, England) under the trade name INCROMINE BB. Propyl dimethylamine, and various guanamine amines available from Scher (Clifton New Jersey, USA) under the trade name SCHERCODINE series. The acid (ii) is any organic or mineral acid which can protonate the guanamine amine in the hair care composition. Suitable acids suitable for use herein include chloric acid, acetic acid, tartaric acid, fumaric acid, lactic acid, maleic acid, succinic acid, and mixtures thereof. Preferably, the acid is selected from the group consisting of acetic acid, tartaric acid, hydrogen acid, fumaric acid, and mixtures thereof. The primary function of the acid is to protonate the amine amine in the hair care composition' thus forming a tertiary amine salt (TAS) in place in the § hair composition. The TAS is functionally a non-permanent quaternary ammonium or pseudo quaternary ammonium cationic surfactant. Suitably, the acid is included in an amount sufficient to protonate all of the guanamine amine present, i.e., at least in an amount equivalent to the amount of guanamine present in the composition. The cationic surfactant is present in an amount ranging from 〇〇1 to 1% by weight, more preferably from 0.02 to 7.5% by weight, most preferably 〇〇5, based on the total weight of the cationic surfactant. Up to 5 weights 0/〇. GN Fatty Material The conditioning gel network of the compositions of the present invention preferably comprises a fatty material. Preferably, the fatty material is selected from the group consisting of fatty acids, fatty acid guanamines, fatty alcohols, fatty acid esters, and mixtures thereof. Preferably, the fatty material comprises a fat having from 14 to 3 carbon atoms, H8372.doc 1Λ201109035, more preferably 16 to 22 carbon atoms. Examples of suitable aliphatic alcohols include cetyl alcohol, octadecyl alcohol, and hydrazine blends & An example of a suitable fatty acid vinegar is glyceryl monostearate. The content of the fatty substance in the composition of the present invention is suitably from 0.01 to 1% by weight, preferably from 〇 to 5% by weight, based on the weight of the composition. Preferably, the ratio between the fatty substance and the gel network anionic surfactant

For example, 〇·1:1 to chaos·b is preferably m50:I, more preferably ΐ5:ι to 1 〇: 1 and most preferably about 2:1. Preferably, the anionic and fatty materials of the gel network comprise an alkyl group having 4 or less, preferably 2 carbons, and most preferably the same carbon number. More preferably, the other comprises a monoalkyl group of 4 or less, more preferably 2 or less, and the same length. This can help maintain the stability of the gel network. GN Anionic Surfactant The conditioned gel phase of the compositions of the present invention preferably comprises a gel network anionic surfactant. The Ο-anionic surfactant comprises a chain of filaments having from 16 to 3G carbons, preferably from 16 to 22 carbons. Preferably, the carbon network in the gel network anionic surfactant is present in a single alkyl group. The gel network includes an anionic surfactant to achieve an anionic charge throughout the gel network or to render the gel network as a whole uncharged. The alpha gel network anionic surfactant is present in an amount of from 0.1 to 5% by weight, based on the weight of the composition, and more preferably from 5 to 2% by weight. Cleansing phase 148372.doc 201109035 This cleansing phase includes cleaning surfactants. The cleansing phase anionic surfactant has from 8 to 14 carbon atoms, more preferably from 10 and most preferably from 12 carbon atoms. More preferably, the carbon systems are present in a single-hospital base. Preferred anionic cleaning surfactants include metal sulphate sulfates, more preferably thioether sulfate vinegar. A particularly good anionic cleaning surfactant includes sodium lauryl sulfate. Province: Moon phase comprises 27 to 7 weights by weight of the composition. The cleaning surfactant is preferably 35 to 5 % by weight. Cationic Deposition Polymer The composition according to the invention comprises a cation which is polymerized in a preferred embodiment. The cation-deposited auxiliary polymer of the mouth may be a homopolymer which is substituted by a cation or formed from a monomer of the two or the ethic. The weight average (I) molecular weight of the polymer is generally between (10) _ and 2 _ _ Dalton (dah〇n). The polymers may have a cationic containing group such as a quaternary ammonium or protonated amine group, or a mixture thereof. If the molecular weight of the polymer is too low, the conditioning effect is poor. If: two may be in the pouring of the composition, (four) high ductility viscosity leads to the problem of group & a cation-containing milk group is generally used as a cationic monomer unit monomer::: a substituent. Thus, when the polymer is not a homopolymer, it can be a few times earlier than the spacer non-cationic precursor.泫Special polymer is described in Section A Cosmetic Ingredient Guide τρ Δ广. n. V (CTFA Cosmetic Ingredient

Directory). The ratio of the cation to the % ionic early aging is selected as the polymer having a subcharge density within the desired range (generally 〇·2 to 3. 〇 148372.doc 12 201109035 meq/gm). The cationic charge density of the polymer can be suitably determined by the Kjeldahl method described by the US Pharmacopoeia under nitrogen test chemical test conditions. For example, 'suitable cationic polymers include copolymers of vinyl monomers having a cationic amine or quaternary ammonium functional groups having a water-soluble spacer monomer such as (meth) acrylamide, alkyl and dialkyl ( Methyl) acrylamide, alkyl (meth) acrylate, vinyl caprolactone and vinyl pyrrolidine. The monomer substituted with a benzyl group and a second group preferably has a C1-C7 alkyl group, more preferably a C1-3 group. Other suitable spacers include vinyl esters, vinyl alcohol, maleic anhydride, propylene glycol, and ethylene glycol. The cationic amine can be a primary, secondary or tertiary amine, depending on the particular species and pH of the composition. Generally, 'secondary and tertiary amines (specifically tertiary amines) are preferred. The amine-substituted vinyl monomer and amine can be polymerized in the form of an amine and then converted to ammonium by quaternization. 〇 The cationic polymer may comprise a mixture of monomer units derived from an amine and/or quaternary ammonium substituted monomer and/or a compatible spacer monomer. Suitable cationic polymers include, for example: - polymers containing cationic diallyl quaternary ammonium, including, for example, dinonyl diallyl ammonium chloride homopolymers and referred to as poly in industrial (CTFA), respectively Copolymer of quaternary ammonium salt 6 and polyquaternary ammonium salt 7 of acrylamide and vaporized dimercaptopropyl ammonium; - aminoalkyl group of unsaturated carboxylic acid (having 3 to 5 carbon atoms) Homopolymers and copolymers of ester mineral acid salts (described in US Patent 4,009,256); 148372.doc -13-201109035 - Cationic polypropylamines are described in 95/22311). Other cationic polymers which may be employed include cationic polysaccharide polymers such as cationic cellulose, biological starch derivatives, and cationic guar derivatives. Cationic poly-audiopolymers suitable for use in the compositions of the present invention include monomers of the formula: A-0-[R-N+(R1)(R2)(r3)Xj wherein: A is a glucose residue such as starch or fiber f glucose residue. R is an alkylene group, an alkyloxyalkylene group, a polyoxyalkylene group, or a hydroxyalkylene group, or a combination thereof. Rl, R2 and R3 independently represent a deutero, aryl, alkylarylalkyl, alkoxyalkyl or alkoxyaryl group, each group containing up to about 18 carbon atoms . The total number of carbon atoms per cationic moiety (i.e., the total number of carbon atoms in R, R and R3) is preferably about or less, and X is an anionic counterion. Another class of cationic celluloses include polymeric quaternary ammonium salts of hydroxyethyl cellulose obtained by reaction with an epoxide substituted with lauryl decyl ammonium in the industrial (CTFA). Such materials are commercially available, for example, from Amerchol under the trade name Polymer LM-200. Other suitable cationic polysaccharide polymers include those containing a quaternary nitrogen cellulose puzzle (e.g., as described in U.S. Patent 3,962,41,8), and a copolymer of etherified cellulose and starch (e.g., as described in U.S. Patent 3,958,581).

A particularly suitable class of cationic polysaccharide polymers can be employed as cationic guar gum derivatives, such as guar hydroxypropyltrimethylammonium hydride (available from Rhodia in the series of such jaguar trademarks). Examples of such materials are jAGUAR 148372.doc -14-201109035 C13S, JAGUAR C14, JAGUAR C15 and JAGUAR C17. Mixtures of any of the above cationic polymers may be employed. The cationic polymer is generally present in the range of the shampoo of the present invention in an amount of from 〇〇1 to $% by weight based on the total weight of the cationic polymer based on the total reset of the σ substance, preferably 〇·〇5 to 2 weight. /. More preferably 〇 至 7 to i 2 weight 〇 / 〇. More preferably, the hair care composition of the present invention is aqueous, i.e., the other has water or an aqueous solution' or a liquid crystalline phase (the liquid crystalline phase ◎ Phase) as the main component. Suitably, the composition comprises water in an amount of from 10 to 98% by weight, preferably from 30 to 95% by weight, based on the total weight of the composition. The composition according to the invention preferably comprises polyfluorene oxide. Particularly preferred polyoxymethylene conditioning agents are polyoxynoxy emulsions, such as those formed by polyoxymethylene, such as polydiorganotoxioxane, specifically the CTFA name is dimethicone. Polydimethyl methoxy oxane, CTFA name is dimethiconol, polydidecyl fluorenyl oxyalkylene having a base group, and CTFA name is amodimethic 〇ne The amine functional group polydimethyloxane. The emulsion droplets generally have a Sauter mean droplet diameter (D3, 2) of from 〇 〇丨 to 2 μm, more preferably from 0.2 to 1 μm in the compositions of the present invention. A suitable method for determining the Sauter mean droplet diameter (1) 3, 2) is carried out according to laser light scattering using an instrument such as a Malvern particle size analyzer. Suitable polyoxylized emulsions for use in the compositions of the present invention are available from polyoxo suppliers such as Dow Corning and GE Silicones. The use of such pre-formed polyoxo-emulsions is preferred for ease of handling and control of the particle size of the polyoxyl oxide. 148372.doc 15 201109035. The pre-formed polyoxoemulsions may generally additionally comprise suitable emulsifiers (such as anionic or nonionic emulsifiers, or mixtures thereof), and may be by chemical emulsification methods such as emulsion polymerization, or by employing high shear mixing. Prepared by mechanical emulsification. Typically, a pre-formed polyoxo-emulsion having a Sauter mean droplet diameter (D3, 2) of less than 0.15 microns is referred to as a microemulsion. Examples of suitable pre-formed polyoxyn emulsions include emulsions DC2-1766, DC2-1784, DC-1785, DC-1786, DC-1788 and microemulsions DC2-1865 and DC2-1870, all available from Dow Corning. DC7051 is the preferred polyoxane. These are all emulsions/microemulsions of dimethyl polyoxyl alcohol. Amine based eucalyptus emulsions (such as DC 2-8177 and DC 939) and SME 253 (available from GE Silicones) are also suitable. Polyoxyn emulsions of a particular class of high molecular weight surface-active block copolymers which have been blended with, for example, the polyoxynoxy emulsion droplets described in WO 03/094874 are also suitable. Among such materials, the polyoxyxide emulsion droplets are preferably formed by a polydiorganotoxime such as the one described above. A preferred form of the surface active block copolymer is according to the following chemical formula: H0(CH2CH20)x(CH(CH3)CH20)y(CH2CH20)xH wherein the average value of X is 4 or greater, and the average value of y is 25 or more. Another preferred form of the surface active block copolymer is according to the formula: (HO(CH2CH20)a(CH(CH3)CH20)b)2-N-CH2-CH2-N((OCH2CH(CH3))b ( OCH2CH2)aOH)2 wherein the average value of a is 2 or more, and the average value of b is 6 or more. Mixtures of any of the above-mentioned polyoxo-oxygen emulsions may also be employed. 148372.doc -16 - 201109035 The above poly-stone emulsion is generally present in the composition of the present invention in an amount ranging from G._i5 wt%, preferably 0.5 to the total weight of the total weight of the composition. 12% by weight. The polyoxime is preferably present in an amount of from 5 to 15% by weight, more preferably (1)%. Additional Ingredients to Improve Efficiency The compositions of the present invention may comprise the following energy and/or consumer acceptability as desired.

The composition may comprise a co-surfactant physical or cleaning property. To give the composition an aesthetic appearance, /, an example of a surfactant is a nonionic surfactant, which comprises a t amount ranging from 0 5 to 10 weights based on the total weight of the composition. 〇·7 to 6 wt%. For example, representative nonionic surfactants comprising the shampoo compositions of the present invention include aliphatic (crcu) primary or secondary linear linear or branched alcohols or phenols and alkylene oxides (usually epoxy B) The condensation product of an alkane, and generally having 6 to 3 oxirane groups. Other representative nonionic surfactants include mono or dialkyl chain alcohol amines. Examples include coco mono or diethanolamine and cocomonoisopropanol oxime. A particularly preferred nonionic surfactant is coco monoethanolamine. The additional nonionic surfactant included in the shampoo compositions of the present invention is an alkyl polyglucoside (APG). Typically, the APG is an APG comprising an alkyl group, wherein the alkyl group is attached (via a bridging group as needed) to - or a plurality of glycosyl blocks. A preferred APG is defined by the following chemical formula: R〇-(G)n 148372.doc 201109035 wherein R is a saturable or SI group. A branched or straight chain alkyl group which may be unsaturated, and G of R may represent an average alkyl chain length of from about C5 to about r + , 々C2G. Preferably, the Han watch does not have an average scale of C8 to about C丨2 . Q , ^ 7Λ _ base chain length. Optimally, the value of R is between about 9.5 and . g may be selected from the group consisting of "^ D ' 葡箱煃#. 6 early (four) residues, and preferably ~ " selected from the group consisting of glucose, xylose, lactose, fructose, gamma sugar and derivatives thereof. Ground, G is (iv) sugar. The degree of polymerization 11 is a value of from about 1 to about 1 Torr or more. Preferably, the value of 'η is between about 1. and force 2. optimally, the value of η is between From about i 3 to about 1.5. - Suitable for hospital-based polydextrose for commercial use in the present invention, and includes such materials as identified by the following trade names: from the company _ix NS10 'Plantaren 12 from Henkel Corporation Other sugar-derived nonionic surfactants included in the compositions of the present invention include C]G-C18 N-alkyl (Ci-C6) polyhydroxy fatty acid decyl amines (such as described in Example qing 92 〇 6154 and Us 5 194 (d) kb N-mercaptoglucoside fe), and N-alkoxy polyhydroxy fatty acid decylamine (such as c ^ _Ci8N_ (3_t oxypropyl) glucosamine A preferred example of a co-surfactant is an amphoteric or zwitterionic surfactant' in an amount ranging from 0.5 to about 1% by weight based on the total weight of the composition. 1 to 6% by weight. Examples of the amphoteric or two-ionic surfactant include alkylamine oxides, burnt betaine, alkylguanidinopropyl betaine, and alkylsulfonic acid betaine (renering betaines). , alkyl glycinate, alkyl carboxylic acid glycinate, alkyl 148372.doc -18- 201109035 amphoteric acetate, alkyl amphopropionate, alkyl amphoglycine, alkyl The amidinopropyl group is based on a ketone test, a sulfhydryl citrate salt and a thiol glutamate, wherein the alkyl group and the fluorenyl group have 8 to 19 carbon atoms. It is suitable for use in the shampoo of the present invention. Typical amphoteric and zwitterionic surfactants include laurylamine oxide, cocodimethyl dimethyl sulfobetaine, lauryl betaine, cocoyl propyl propyl betaine and cocoyl amphoteric Acetic acid.

A particularly preferred amphoteric or zwitterionic surfactant is cocoyl amide-based propyl beet. Mixtures of any of the foregoing amphoteric or zwitterionic surfactants are also suitable. A preferred mixture is a mixture of cocoyl guanidinopropyl betaine and the additional two axillary or zwitterionic surfactants described above. Preferably, the other amphoteric or zwitterionic surfactant is sodium cocoamphoacetate. /, The compositions of the present invention may comprise other ingredients for improved efficacy and/or consumer acceptance. Such ingredients include fragrances, dyes and pigments, pH adjusters, pearlizing agents or non-clear agents, viscosity modifiers, and preservatives or anti-microbial agents, each of which is present in an amount effective to achieve its purpose. Generally, the amount of ingredients included in the step is typically up to 5% by weight based on the total composition weight. [Embodiment] The present invention is further described by the following non-limiting examples. All percentages used for 71 71 71 71 71 71 71 71 71 71 71 71 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 148372.doc 19-201109035 Example 1 INCI name ash % (ad%) Example 1 Example 2 Example 3 Example 4 Sodium lauryl ether 70 34.28 34.28 34.28 34.28 Cocoyl guanyl propyl beet test 30 10.66 - 10.66 • 揶Eudecylamine MEA 85 - 2.0 - 2.0 Ethylene glycol distearate 35 4.0 4.0 4.0 4.0 Dimercaptohydroxanol DC1788 50 12.0 12.0 12.0 12.0 Glycine Soybean Oil 100 4.0 4.0 4.0 4.0 Perfume 100 0.8 0.8 0.8 0.8 guar by propyl tridecyl ammonium chloride 100 0.4 0.4 0.4 0.4 sodium chloride 100 - - 1.0 1.0 propylene glycol 100 - - - - dimercapto polyoxyl alkanol DC7123 50 - - - - DMDM carbendazim and 3-block-2-propionyl butyl decanoate 50 0.2 0.2 0.2 0.2 Water supplemented to 100 Supplementary amount to 100 Supplementary amount to 100 Supplementary amount to 100 INCI name ash % (ad%) Example 5 Example 6 Example 7 Example 8 Sodium lauryl ether sulfate 70 34.28 34.28 34.28 34.28 Cocoyl decyl propyl beet test 30 10.66 _ 10.66 Cocoamine MEA 85 - 2.0 - 2.0 Ethylene glycol distearate 35 4.0 4.0 4.0 4.0 II曱Polyoxyalkanol DC1788 50 12.0 12.0 8.0 8.0 Amino acid soybean oil 100 4.0 4.0 4.0 4.0 Perfume 100 0.8 0.8 0.8 0.8 guar hydroxypropyltrimethylammonium oxide 100 0.4 0.4 0.4 0.4 Sodium chloride 100 - - 1.0 1.0 Propylene glycol 100 10.0 10.0 - - Diterpene polyoxyl Alkanol DC7123 50 - - 4.0 4.0 DMDM carbendazim and 3-bromo-2-propionyl butyl decanoate 50 0.2 0.2 0.2 0.2 Water supplemented to 100 Supplementary amount to 100 Supplementary amount to 100 Supplementary amount to 100 148372.doc -20- 201109035 INCI name ash % (ad%) Example 9 Example 10 Example 11 Example 12 Sodium lauryl ether sulfate 70 34.28 34.28 34.28 34.28 Cocoyl-based aminopropyl beet test 30 10.66 10.66 - Coconut meal Amine MEA 85 - 2.0 - 2.0 Ethylene glycol distearate 35 4.0 4.0 4.0 4.0 Dimethyl methoxyalkanol DC 1788 50 12.0 12.0 12.0 12.0 Glycine soy oil 100 3.0 3.0 3.0 3.0 Perfume 100 0.8 0.8 0.8 0.8 Guar by propyltrimethylammonium chloride 100 0.4 0.4 0.4 0.4 Hazelnut oil 100 2.0 2.0 2.0 2.0 Chlorinated sodium 100 - - 1.0 1.0 Propylene glycol 100 - - - - Diterpene polyoxyl alkanol DC7123 50 - - - - DMDM carbendazim and 3-iodo-2-propynylamino Acid butyl ester 0.2 50 0.2 0.2 0.2 Water qs to 100 complementary to the added amount of the added amount of 100 to 100 qs to 100 Example 2 supplemented when necessary to replace the oil produced according to this process for all formulations are prepared according to the present invention. In another pot, at least 8% of the water is heated to about 80 °C. A cationic (dodecylamethylenetrimethylammonium chloride) surfactant, a fatty alcohol, and a secondary anionic surfactant (wax whale stearyl sulfate) were added to the pot using high speed stirring. When a homogeneous dispersion was obtained, the mixture was stirred and cooled to about 45 ° C at the same speed. The mixture was then added to a concentrated primary surfactant (sodium lauryl ether sulfate) in a high speed dispersing mixer equipped with a double pulping tray and a doctor blade. The components are mixed under high shear and under vacuum. Next, the remaining components were mixed under the same conditions. Add triacetin oil before adding water. The remaining water system is added to the formulation at the end. 148372.doc -21 - 201109035 Example 3 The following formulations were made to evaluate the benefits of the present invention for a suitable comparison set. The other can be manufactured by a similar process. INCI Name Ash % (ad%) Comparison 1 Comparison 2 Comparison 3 (no gel) Comparison 4 (gel) Example 1 (gel + oil) Example 2 (gel + oil) Sodium lauryl ether 70 20.00 20.00 34.28 34.28 34.28 34.28 Norse-based aminopropyl beet test 30 5.33 5.33 10.66 10.66 10.66 _ coconut decylamine 85 - - - - - 2.0 Carboxylic acid preparation 100 0.4 0.4 - - - - Ethylene glycol distearate 35 4.0 4.0 4.0 4.0 4.0 4.0 Diterpene polyoxyl alkanol/TEA-DOBS 50 6.0 6.0 12.0 12.0 12.0 12.0 Wax whale stearyl sodium 100 - - 0.6 0.6 0.6 Wax whale stearyl alcohol 100 - - - 1 1 1 gas Tetracamenium trimethylammonium 77.5 - 0.06 0.06 0.06 Mineral oil 100 - 3 - - 1.0 1.0 Perfume 100 0.8 0.8 0.8 0.8 0.8 0.8 Guar hydroxypropyl trimethylated ammonium oxide 100 0.15 0.15 0.3 0.3 0.3 0.3 Guar Hydroxypropyltrimethylammonium hydride 100 0.05 0.05 0.1 0.1 0.1 0.1 Sodium chloride 100 0.5 0.5 - - - - DMDM carbendazim and 3-iodo-2-propynyl butyl carbamate 50 0.2 0, 2 0.2 0.2 0.2 0.2 Water to replenish the appropriate amount to 100 Supplementary amount to 100 Supplementary amount to 100 Supplementary amount to 100 Supplement Appropriate amount to 100 Supplements The right amount to 100 evaluated benefits is a wet coating feel. Benefit comparison 1 Comparison 2 Comparison 3 (half dose) Comparison 4 (half dose) Example 1 (half dose) Wet coating feel 3.05 3.2 3.5 3.95 (control comparison 1 has 95% significant difference) 4.55 (control comparison I has 99% Significant differences) Example 4 The following is a shampoo formulation prepared via a similar process. 148372.doc -22- 201109035 INCI name ash % (ad%) Example 1 Example 2 Example 3 Example 4 Sodium lauryl ether 70 34.28 34.28 34.28 34.28 Cocoyl allylamyl propyl beet test 30 10.66 10.66 - Cocoamide 85 - 2.0 - 2.0 Ethylene glycol distearate 35 4.0 4.0 4.0 4.0 Dimethyl phthalol/TEA-DOBS 50 12.0 12.0 12.0 12.0 Wax whale stearyl sulphate 100 0.3 0.3 0.3 0.3 Wax whale hard fat Alcohol 100 0.5 0.5 0.5 0.5 Tetramethylammonium chloride 77,5 0.03 0.03 - - Cetyltrimethylammonium chloride 29 - - 0.085 0.085 Trimethylolpropane tricaprylate / tridecanoate 100 1.0 1.0 1.0 1.0 Perfume 100 0.8 0.8 0.8 0.8 guar propyl tridecyl ammonium chloride 100 0.4 0.4 0.4 0.4 DMDM carbendazim and 3-iodo-2-propynyl butyl carbamate 50 0.2 0.2 0.2 0.2 Water supplemented to 100 Appropriate amount to 100 Supplementary amount to 100 Supplementary amount to 100 Example 5 To demonstrate the improved wet coating feel of the compositions of the present invention, a comparison between the formulations shown below was performed. INCI name ash % (ad%) Comparison 1 (no gel, no oil) Comparison 2 (gel) Example 1 Example 2 Example 3 Example 4 Sodium lauryl ether 70 34.28 34.28 34.28 34.28 34.28 34.28 Propyl betaine 30 10.66 10.66 10.66 10.66 - Cocoamine MEA 85 - - - 2.0 - 2.0 Carboxylic acid preparation 100 - - - - - - Ethylene glycol distearate 35 4.0 4.0 4.0 4.0 4.0 4.0 Dimerization矽 烷 醇 TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE TE 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Dodecyltrimethylammonium 77.5 - 0.03 0.03 0.03 * Will be hexadecyltrifluoroammonium chloride 29.0 - 0.085 0.085 Hydrogenated to 14 dilute hydrocarbon polymer 100 ** 1.0 1.0 1.0 1.0 Perfume 100 0.8 0.8 0.8 0.8 0.8 0.8 Melon Propyltrimethylammonium hydride 100 0.4 0.4 0.4 0.4 0.4 0.4 DMDM carbendazim and butyl 3-iodo-2-propynylcarbamate 50 0.2 0.2 0.2 0.2 0.2 0.2 Water supplemented to 100 replenishment Appropriate amount to 100 Supplementary amount to 100 Supplementary amount to 100 supplements Appropriate amount to 100 Supplement Appropriate amount to 100 Benefits Comparison 1 Comparison 2 Example 1 Wet coating feel 0.5 0.79 (99% difference) 0.81 (99.9% difference) 148372.doc 24-

Claims (1)

201109035 VII. Patent Application Range: 1 · A shrinking conditioning shampoo composition comprising 27 to 70% by weight of the cleansing phase, conditioning gel phase and selected from the group consisting of triglycerides, hydrocarbon oils, ester oils, poly An oil of olefin oil and mixtures thereof, wherein the conditioning gel phase comprises: '(a) a fatty material; (b) a gelling network anionic surfactant comprising an alkyl group having 16 to 3 carbons; (c) a cationic surfactant; wherein the conditioning gel network is generally uncharged or anionic. 2. The composition of claim 1, wherein the conditioning gel phase comprises a fatty material selected from the group consisting of aliphatic alcohols, fatty acid esters, fatty acids, and fatty acid decylamines. 3. The composition of claim 2, wherein the fatty material is linear or branched & has from 14 to 30 carbons. The composition of any of the preceding claims, wherein the conditioning gel phase comprises a cationic surfactant having from 16 to 30 carbons. The composition of any one of the claims, wherein the conditioning gel phase comprises an anionic surfactant having from 16 to 22 carbons. 6. A composition according to any of the preceding claims, which comprises a cationic deposition polymer. 7. A composition according to any of the preceding claims, which comprises polyoxyl. 148372.doc 201109035 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: (none) 148372.doc