TW201107822A - Polarization switching element, and projector and television using the same - Google Patents

Polarization switching element, and projector and television using the same Download PDF

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TW201107822A
TW201107822A TW098128328A TW98128328A TW201107822A TW 201107822 A TW201107822 A TW 201107822A TW 098128328 A TW098128328 A TW 098128328A TW 98128328 A TW98128328 A TW 98128328A TW 201107822 A TW201107822 A TW 201107822A
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liquid crystal
voltage
polarization
light
crystal material
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TW098128328A
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Chinese (zh)
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Atsushi Nakano
Eiji Yamaichi
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Nano Loa Inc
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Abstract

This invention provides a polarization switching element and projector and television using the polarization switching element. The polarization switching element includes at least a pair of transparent substrates which respectively include transparent electrodes on the surfaces thereof, a liquid crystal material disposed between the pair of transparent substrates, a voltage applying means for applying voltage to the liquid crystal material via the pair of transparent electrodes, and a polarization state detecting means provided on the light emission side of the pair of transparent substrates. The voltage to be applied from the voltage applying means to the liquid crystal material is adjusted based on the feedback of a signal from the polarization state detecting means to the voltage applying means.

Description

201107822 六、發明說明: 【發明所屬之技術領域】 本發明係關於一種偏光開關元件、使用該偏光開關元件 之才又衫機及電視,特別係關於一種使用液晶之偏光開關元 件、使用該偏光開關元件之投影機及電視。 【先前技術】 先前,液晶元件利用可以電壓控制該液晶之光透過率之 原理而作為顯示器應用至今。另一方面,作為液晶元件之 顯示器以外之用途,可考慮迴轉入射光之偏光面而出射之 偏光開關元件(例如’參照專利文獻丨)。 偏光開關元件一般而言係進行將直線偏光光之偏光方向 迴轉90 C或不旋轉這2種作用,藉由施加電壓等而將該2種 偏光狀態進行切換動作之元件。該偏光開關元件已知有使 用TN(扭轉向列型)液晶材料者。 專利文獻1日本特開2007-121893號公報 【發明内容】 發明所欲解決之問題 但,對於使用先前之液晶之偏光開關元件,存在對構成 偏光開關兀件之液晶施加之電壓所產生之應答比較不穩定 之問題點。 本發明之目的在於提供一種可容易地實現穩定地開關應 答之偏光開關元件。 本發明之另一目的在於提供一種使用前述偏光開關元件 之投影機及電視。 142774.doc 201107822 解決問題之技術手段 本發明者精心研究之結果,發現將使用液晶之偏光開關 元件中關於該偏光狀態自身之資訊,向應對液晶施加之電 壓反饋’對前述目的之達成十分有效。 本發明之偏光開關元件係基於前述見解者,更具體而 吕’其特徵在於,該偏光開關元件係至少具備以下者:於 各自之表面上具有透明電極之一對透明基板;配置於該一 對透明基板間之液晶材料;介以前述一對透明電極對前述 液晶材料施加電壓之電壓施加機構;及設於前述一對透明 基板之光出射側之偏光狀態檢測機構;且,基於來自前述 偏光狀態檢測機構之信號對前述電壓施加機構之反饋,而 凋整來自前述電壓施加機構對前述液晶材料施加之電壓。 本發明包含例如以下之態樣。 π] —種偏光開關元件,其特徵在於,該偏光開關元件 係至少具備以下者: 於各自之表面上具有透明電極之一對透明基板; 配置於該一對透明基板間之液晶材料; ;丨以則述一對透明電極對前述液晶材料施加電壓之電壓 施加機構;及 :月』述對透明基板之光出射側之偏光狀態檢測機 基於來自前 機構之反饋, 料施加之電壓 述偏光狀態檢測機構之信號對前述電壓施加 而調整來自如述電壓施加機構對前述液晶材 142774.doc 201107822 [2] 如[1 ]之偏光開關元件,其中前述液晶材料係由分極 遮蔽型層列液晶或強介電性液晶構成。 [3] 如[1]或[2]之偏光開關元件,其中藉由對前述液晶 材料施加電壓,使從一對透明基板之光入射侧入射之光之 第1偏光狀態改變成與該第1偏光狀態不同之第2偏光狀 態。201107822 VI. Description of the Invention: [Technical Field] The present invention relates to a polarizing switch element, a machine for using the same, and a television, and more particularly to a polarizing switch element using a liquid crystal, using the polarizing switch Component projector and TV. [Prior Art] Previously, liquid crystal cells have been used as display applications by the principle of voltage control of the transmittance of the liquid crystal. On the other hand, as a use other than the display of the liquid crystal element, a polarization switching element that emits light by rotating the polarizing surface of the incident light can be considered (for example, 'refer to the patent document 。). In the case of the polarization switching element, generally, the two polarizations of the linearly polarized light are rotated by 90 C or not, and the two types of polarization states are switched by applying a voltage or the like. As the polarizing switch element, a TN (Twisted Nematic) liquid crystal material is known. Patent Document 1 Japanese Laid-Open Patent Publication No. 2007-121893 SUMMARY OF THE INVENTION Problems to be Solved by the Invention However, for a polarizing switch element using a liquid crystal of the prior art, there is a comparison of responses generated by voltages applied to liquid crystals constituting the polarizing switch element. The problem of instability. SUMMARY OF THE INVENTION An object of the present invention is to provide a polarization switching element which can easily realize a stable switching response. Another object of the present invention is to provide a projector and a television using the aforementioned polarizing switch element. 142774.doc 201107822 Technical Solution to Problem As a result of intensive studies by the present inventors, it has been found that the use of information on the polarization state itself in a liquid crystal polarization switch element to apply voltage feedback to the liquid crystal is very effective for achieving the above object. The polarizing switch element of the present invention is based on the above-mentioned knowledge, and more specifically, the polarizing switch element has at least one of: a transparent substrate having one pair of transparent electrodes on each surface; a liquid crystal material between the transparent substrates; a voltage applying mechanism that applies a voltage to the liquid crystal material via the pair of transparent electrodes; and a polarization state detecting mechanism provided on a light emitting side of the pair of transparent substrates; and based on the polarized state The signal from the detecting mechanism feeds back the voltage applying mechanism, and the voltage applied from the voltage applying mechanism to the liquid crystal material is eroded. The present invention encompasses, for example, the following aspects. a π]-type polarization switching element, characterized in that the polarization switching element has at least one of: a pair of transparent electrodes having a transparent electrode on each surface; a liquid crystal material disposed between the pair of transparent substrates; a voltage applying mechanism for applying a voltage to the liquid crystal material by a pair of transparent electrodes; and a polarizing state detecting machine for emitting light on the light emitting side of the transparent substrate, based on feedback from the front mechanism, detecting a state of the polarized light applied by the material The signal of the mechanism is applied to the voltage application to adjust the polarization switching element from the liquid crystal material 142774.doc 201107822 [2] [1], wherein the liquid crystal material is composed of a polarization shielding type lining liquid crystal or a strong medium. Electrical liquid crystal. [3] The polarizing switch element according to [1] or [2], wherein a first polarizing state of light incident from a light incident side of the pair of transparent substrates is changed to the first one by applying a voltage to the liquid crystal material The second polarization state in which the polarization state is different.

[4] 如[3]之偏光開關元件,其中藉由調整對前述液晶材 料之施加電壓,維持並輸出前述第1偏光狀態之光。 [5] 如[3]或[4]之偏光開關元件,其中前述第1偏光狀態 係直線偏光,前述第2偏光狀態係使前述直線偏光之振動 面90°迴轉之直線偏光。 [6]如[1]至[5]中任一項之偏光開關元件,其中前述偏 光狀態檢測機構至少具備丨個偏光機構及檢測透過該偏光 機構之光之強度之光檢測器。 [7]如[1]至[6]中任一項之偏光開關元件,其中前述電 壓施加機構係具備:檢測來自前述偏光狀態檢測機構之信 號之感測器信號檢測機構;輸入指定偏光狀態之命令之輸 入機構;基於藉由前述輸人機構所輸人之命令與藉由感測 器信號檢測機構所檢測之信號’而決定對前述液晶施加之 電壓之控制機構;及基於來自前述控制機構之信號,而對 前述透明電極施加電壓之電壓輸出機構。 L/J之偏光開關元件 L〇J 戈〇 ^ · ......心t则揭;稱具備畜 ,於該記憶機構中記憶控制程式’於維持並輸出肯 1偏光狀態之光之情形時,該控制程式係以使來自弟 142774.doc 201107822 偏光狀態檢測機構之信號強度成為最大之方式,決定對前 述透明電極施加之電壓值,並將用於該電塵輸出之信號傳 輸至前述電壓輸出機構。 [9] 一種投影機,其特徵在於,其係至少包含以下者: 用於顯示所輸入之影像信號之空間光調變元件、照明光學 系統、光學單A、用於將通過該光學單元之光擴大投射之 投影光學系統,及空間光調變元件之投影機; 刖述光學單兀包含偏光開光元件;且該偏光開關元件係 如[1]至[8]中任一項之偏光開關元件,其至少具備: 於各自之表面上具有透明電極之一對透明基板;配置於 該對透明基板間之液晶材料;介以前述一對透明電極對 前述液晶材料施加電壓之電壓施加機構;及設於前述一對 透明基板之光出射側之偏光狀態檢測機構;且,基於來自 前述偏光狀態檢測機構之信號之對前述電壓施加機構之反 饋而調整來自前述電壓施加機構對前述液晶材料施加之 電壓。 [1 〇]種電視,其特徵在於,其係至少包含用於顯示 所輸入之影像信號之顯示装置及偏光開關元件者; 前述偏光開關元件係如π]至[8]中任一項之偏光開關元 件’其至少具備: 於各自之表面上具有透明電極之一對透明基板;配置於 «玄對透明基板間之液晶材料;介以前述一對透明電極對 刚述液晶材料施加電壓之電壓施加機構;及設於前述一對 透明基板之光出射側之偏光狀態檢測機構;且,基於來自 142774.doc 201107822 前述偏光狀態檢測機構之信號之對前述電壓施加機構之反 饋’而調整來自前述電壓施加機構對前述液晶材料施加之 電壓。 • 發明之效果 ; 根據本發明,提供一種偏光開關元件,其可藉由檢測透 過構成偏光開關兀件之液晶之光之偏光狀態,將該檢測信 號反饋至電壓施加機構,實現穩定之開關應答。 ❹ 【實施方式】 (偏光開關元件) 本發明之偏光開關元件係至少具備:於各自之表面上具 有透明電極之一對透明基板;配置於該一對透明基板間2 . 液晶材料;介以前述一對透明電極對前述液晶材料施加電 、 M之電壓施加機構;及設於前述-對透明基板之光出射側 之偏光狀態檢測機構。本發明中,基於來自前述偏光狀態 檢測機構之信號之對前述電壓施加機構之反饋,調整來自 〇 耵述電壓施加機構對前述液晶材料施加之電壓。 (消光比) 本發明中,前述「穩定之開關應答」之程度,宜測定消 光比作為指標,以將該消光比維持在最佳狀態之方式進行 • 凋整通$,LCD所使用之消光比,意味著透過光量(或 W光最小之情形之光量與透過光量(或反射光量)最大 之情形之光量比。但,此處所用之「消光比」(extincti〇n ratio),係特定之直線偏光入射到元件時,來自該元件之 出射光中偏光方向90。迴轉之直線偏光之強度相對於特定 142774.doc 201107822 之直線偏光之強度之比。 5亥消光比降低時’其他偏光光存在「泄漏」傾向。如此 看來,消光比宜盡可能高地維持。 (消光比之測定方法) "光匕可藉由圖2所示之偏光狀態檢測部η測定。參照 ;元件之光出射側言免置偏光狀態檢測部Μ。偏光板 。二使用透過特定之直線偏光者’偏光板⑵系使用透過 :紋轉之直線偏光者。將特定之直線偏光入射到元件, =元件出射之光中,特定之直線偏光之強度可藉由光檢測 姦33測疋’ 9〇旋轉之直線偏光之強度可藉由光檢測器34 測定。又,計算藉由光檢測器34測定到之光強度(即,9〇。 走轉之直線偏光之強度)相對於藉由光檢測器3 3測定到之 光強度(即’特定之直線偏光之強度)之比,可得到消光 比。 (「消光比」維持之較好態樣) 對以岫述光檢測器33、34所得到之信號,以後述之電壓 控制部等常時監視,使根據所得到之信號而運算之消光比 維持在特定之值以上,以此方式對元件施加電壓,可始終 將消光比保持在較高值。 (基本性態樣) 圖1係表示本發明之態樣之一態樣(基本性態樣)之偏光 開關元件10之模式剖面圖。參照圖i,偏光開關元件丨〇係 於例如由低膨脹玻璃構成之2片透明基板丨丨、12上,設置 例如由ITO(imlium-tin oxide ··銦錫氧化物)構成之透明電 142774.doc 201107822 極13、14,此外於其上形成聚醯亞胺膜或81〇斜向蒸鍍作 為液θβ配向膜15、16。形成有如此之液晶配向膜ι5、〗6之 透明基板11、12,為使目標間隙均一,故於其間夾持由玻 • 璃珠等構成之間隔構件19,將除液晶注入口(未圖示)以外 • 之周圍,以例如由uv硬化型接著劑構成之密封材17密 封’之後’從液晶注入口注入PSS(P〇larization Shielded Smectic :分極遮蔽型層列)液晶材料或強介電性液晶材料 0 等之液晶材料21後’將液晶注入口以環氧樹脂系接著劑等 接著劑硬化封止。 又,偏光開關元件1 0具備:檢測出射光之偏光狀態之偏 光狀態檢測部22 ’反饋來自該偏光狀態檢測部22之信號之 - 反饋機構24 ;及基於來自反饋機構24之信號而控制對電極 • 13、14施加之電壓之電壓控制部23。 前述構成之偏光開關元件1 0,於未對透明電極丨3、丨4間 施加電壓之狀態下’係使入射之直線偏光之光原樣透過; 〇 在施加特定之電壓時,係使入射之直線偏光之偏光方向旋 轉90°透過’藉此,作為偏光開關進行動作。此時,因液 晶可使用PSS液晶或強介電性液晶故可高速開關。又,此 • 時’因藉由偏光狀態檢測部22檢測出射之光之偏光狀態, 將該信號藉由反饋機構24輸入電壓控制部23,電壓控制部 23基於該信號對電極13、14施加電壓,故可得到穩定之應 - 答。 (偏光狀態檢測部) 圖2係表示偏光狀態檢測部(感測器)22之構成之方塊 142774.doc 201107822 圖。偏光狀態檢測部22具備透過第1直線偏光狀態之光之 偏光板3 1、透過與第1直線偏光狀態9〇。旋轉之第2直線偏 光狀態之光之偏光板32、檢測透過偏光板3 1之光強度之光 檢測器33、及檢測透過偏光板32之光強度之光檢測器34, 且將來自光檢測器33、34之信號反饋至電壓控制部23。 作為前述光檢測器33、34,可使用例如應用物理手冊、 應用物理學會編、丸善、第2版、第36頁〜4〇頁所記載之裝 置。 虽例如第1直線偏光狀態之光入射到該偏光狀態檢測部 22時’會透過偏光板3〗,藉由光檢測器33檢測該透過之 光’將彳§號介以反饋機構24輸送至電壓控制部23。另一方 面’當第2直線偏光狀態之光入射到該偏光狀態檢測部22 時,會透過偏光板32 ’藉由光檢測器34檢測該透過之光, 將該信號介以反饋機構24輸送至電壓控制部23。 (電壓控制部) 圖3係表示電壓控制部23之構成之方塊圖。電壓控制部 23具備介以反饋構件24而被輸入來自偏光狀態檢測部(咸 測器之信號之感測器信號檢測部41、電壓輸出部42、 輪入袭置43及控制部44。輸入裝置43係輸入用於指定出射 光之偏光狀態之信號之裝置。控制部44係基於來自輸入裝 置43所輸入之指定信號與來自感測器信號檢測部Μ之信 唬,決定對電極13、14施加之電壓,並向電壓輸出部“輸 送指令信號。電壓輸出部42具有電源,基於來自控制部2 之指令信號控制來自該電源之輸出電壓,而對電極13、1 4 142774.doc -10- 201107822 施加特定之電壓。 感測器信號檢測部41具有放A電料,絲自偏光狀態 檢測部22之信號放大而向控制部料輸出。又,當來自光檢 測部33、34之信號充分大之情形時,亦可構成為不以感測 器信號檢測部進行信號之放大,而將來自光檢測部仏 34之信號輸入至控制部44。 (控制部)[4] The polarizing switch element according to [3], wherein the light of the first polarized state is maintained and output by adjusting an applied voltage to the liquid crystal material. [5] The polarizing switch element according to [3] or [4] wherein the first polarization state is linearly polarized, and the second polarization state is linearly polarized by 90° rotation of the vibration plane of the linearly polarized light. [6] The polarizing switch element according to any one of [1] to [5] wherein the polarization state detecting means includes at least one of a polarizing means and a photodetector for detecting the intensity of light transmitted through the polarizing means. [7] The polarizing switch element according to any one of [1], wherein the voltage applying mechanism includes: a sensor signal detecting mechanism that detects a signal from the polarized state detecting mechanism; and inputs a specified polarized state. a command input mechanism; a control mechanism that determines a voltage applied to the liquid crystal based on a command input by the input unit and a signal detected by the sensor signal detecting mechanism; and based on the control mechanism A voltage output mechanism that applies a voltage to the transparent electrode. L/J polarized switch element L〇J 〇 〇 ^ · ...... heart t is revealed; said that there is a livestock, in the memory mechanism, the memory control program 'maintains and outputs the light of Ken 1 polarized state The control program determines the voltage value applied to the transparent electrode in such a manner as to maximize the signal intensity of the polarization detecting means from the 142774.doc 201107822, and transmits a signal for the electric dust output to the voltage. Output mechanism. [9] A projector comprising at least: a spatial light modulation element for displaying an input image signal, an illumination optical system, an optical single A, and light for passing the optical unit a projector for expanding a projection projection optical system and a spatial light modulation component; a description of the optical unit includes a polarization light-emitting element; and the polarization switch element is a polarization switch element according to any one of [1] to [8], At least: a transparent substrate having a transparent electrode on each surface; a liquid crystal material disposed between the pair of transparent substrates; a voltage applying mechanism for applying a voltage to the liquid crystal material via the pair of transparent electrodes; The polarization state detecting means of the pair of transparent substrates on the light exit side; and the voltage applied from the voltage applying means to the liquid crystal material is adjusted based on feedback of the signal from the polarization state detecting means to the voltage applying means. [1 〇] a television characterized in that it includes at least a display device for displaying an input image signal and a polarization switching element; and the polarization switching element is polarized light of any one of π] to [8] The switching element s has at least: a pair of transparent substrates having transparent electrodes on respective surfaces; a liquid crystal material disposed between the transparent substrates; and a voltage application of a voltage applied to the liquid crystal material by the pair of transparent electrodes And a polarization state detecting mechanism provided on a light exit side of the pair of transparent substrates; and adjusting the voltage application from the voltage application mechanism based on a signal from the polarized state detecting mechanism of 142774.doc 201107822 The voltage applied by the mechanism to the aforementioned liquid crystal material. According to the present invention, there is provided a polarization switching element which can feed back a detection signal to a voltage applying mechanism by detecting a polarization state of light passing through a liquid crystal constituting a polarization switch element, thereby realizing a stable switching response. [Embodiment] (Polarizing Switching Element) The polarizing switch element of the present invention includes at least one transparent substrate having a transparent electrode on each surface thereof, and a liquid crystal material disposed between the pair of transparent substrates. A pair of transparent electrodes apply a voltage applying means for applying electric energy to the liquid crystal material, and a polarizing state detecting means provided on the light emitting side of the transparent substrate. In the present invention, the voltage applied from the liquid crystal material by the voltage applying means is adjusted based on feedback from the voltage applying means from the signal of the polarization detecting means. (extinction ratio) In the present invention, the degree of the "stable switching response" is preferably measured as an extinction ratio, and the extinction ratio is maintained at an optimum state. , means the amount of light transmitted (or the amount of light with the smallest amount of light and the amount of transmitted light (or the amount of reflected light) is the largest.) However, the extincti〇n ratio used here is a specific straight line. When the polarized light is incident on the element, the direction of polarization of the emitted light from the element is 90. The ratio of the intensity of the linearly polarized light of the rotation to the intensity of the linearly polarized light of the specific 142774.doc 201107822. 5 When the extinction ratio decreases, 'the other polarized light exists.' Therefore, the extinction ratio should be maintained as high as possible. (Measurement method of extinction ratio) "The aperture can be measured by the polarization state detecting unit η shown in Fig. 2. Reference; light exiting of the component The polarizing plate is not used. The polarizing plate is used. The polarizing plate (2) that transmits a specific linear polarizer is a linear polarizer that transmits through the grain: a specific linear polarized light. In the light emitted from the component, the intensity of the specific linear polarization can be measured by the light detection. The intensity of the linear polarization of the rotation can be determined by the photodetector 34. Again, the light is calculated by the light detector 34. The intensity of the light measured by the detector 34 (i.e., 9 〇. the intensity of the linear polarized light) is relative to the ratio of the light intensity measured by the photodetector 33 (i.e., the intensity of the specific linear polarized light). The extinction ratio is obtained. (The "extinction ratio" is maintained in a good state.) The signals obtained by illuminating the photodetectors 33 and 34 are constantly monitored by a voltage control unit or the like described later, and are calculated based on the obtained signals. The extinction ratio is maintained above a certain value, and a voltage is applied to the element in this manner, and the extinction ratio can always be kept at a high value. (Basic Aspect) FIG. 1 shows one aspect of the aspect of the present invention (basic) FIG. 1 is a schematic cross-sectional view of the polarizing switch element 10, for example, on two transparent substrates 丨丨, 12 made of low-expansion glass, for example, made of ITO (imlium-tin oxide). ··Indium Tin Oxide) The transparent dielectric 142774.doc 201107822 pole 13, 14, in addition to the formation of polyimine film or 81 〇 oblique vapor deposition as liquid θβ alignment film 15, 16 formed such a liquid crystal alignment film ι5, 〗 6 In order to make the target gap uniform, the transparent substrates 11 and 12 sandwich the spacer member 19 made of glass beads or the like, and are surrounded by a liquid crystal injection port (not shown), for example, by a uv-hardening type. After the sealant 17 is sealed, the liquid crystal material 21 such as a PSS (Polelar Shielded Smectic) liquid crystal material or a ferroelectric liquid crystal material 0 is injected from the liquid crystal injection port. The inlet is hardened and sealed with an adhesive such as an epoxy resin adhesive. Further, the polarization switch element 10 includes a feedback state detecting unit 22 that detects a polarization state of the emitted light, a feedback mechanism 24 that feeds back the signal from the polarization state detecting unit 22, and a counter electrode based on a signal from the feedback mechanism 24. • Voltage control unit 23 for the voltage applied by 13, 14. In the state in which the voltage is not applied to the transparent electrodes 丨3 and 丨4, the polarized light-switching element 10 is configured to transmit the incident linearly polarized light as it is; 〇 when a specific voltage is applied, the incident straight line is applied The polarization direction of the polarized light is rotated by 90° to transmit, thereby operating as a polarizing switch. At this time, since the liquid crystal can use PSS liquid crystal or ferroelectric liquid crystal, it can be switched at a high speed. In addition, when the polarization state of the emitted light is detected by the polarization state detecting unit 22, the signal is input to the voltage control unit 23 via the feedback means 24, and the voltage control unit 23 applies voltage to the electrodes 13 and 14 based on the signal. Therefore, you can get a stable response - A. (Polarization state detecting unit) Fig. 2 is a block diagram showing the configuration of the polarization state detecting unit (sensor) 22 142774.doc 201107822. The polarization state detecting unit 22 includes a polarizing plate 3 1 that transmits light in a first linearly polarized state, and a transmission and a first linear polarization state 9 〇. a polarizing plate 32 that rotates the light in the second linearly polarized state, a photodetector 33 that detects the light intensity transmitted through the polarizing plate 31, and a photodetector 34 that detects the intensity of the light transmitted through the polarizing plate 32, and will be from the photodetector The signals of 33 and 34 are fed back to the voltage control unit 23. As the photodetectors 33 and 34, for example, an apparatus described in the application physics manual, the Applied Physics Society, Maruzen, 2nd edition, pages 36 to 4 can be used. For example, when the light in the first linearly polarized state is incident on the polarization detecting portion 22, 'the polarizing plate 3 is transmitted, and the transmitted light is detected by the photodetector 33'. The 彳§ is transmitted to the voltage via the feedback mechanism 24. Control unit 23. On the other hand, when the light of the second linearly polarized state is incident on the polarization detecting portion 22, the transmitted light is detected by the photodetector 34 through the polarizing plate 32', and the signal is transmitted to the feedback mechanism 24 via the feedback mechanism 24. Voltage control unit 23. (Voltage Control Unit) FIG. 3 is a block diagram showing the configuration of the voltage control unit 23. The voltage control unit 23 is provided with a sensor signal detecting unit 41, a voltage output unit 42, a wheeling place 43 and a control unit 44 that receive a signal from a polarization detecting unit (a signal from a salt detector) via a feedback member 24. The device for inputting a signal for specifying the polarization state of the emitted light is input from the control unit 44. The control unit 44 determines the application of the electrodes 13 and 14 based on the signal input from the sensor signal detecting unit 与 from the designation signal input from the input device 43. The voltage is supplied to the voltage output unit. The voltage output unit 42 has a power supply, and the output voltage from the power source is controlled based on a command signal from the control unit 2, and the counter electrode 13, 14 142774.doc -10- 201107822 A specific voltage is applied. The sensor signal detecting unit 41 has a discharge of the A material, and the signal from the polarization state detecting unit 22 is amplified and output to the control unit. Further, when the signals from the light detecting units 33 and 34 are sufficiently large, In other cases, the signal from the photodetecting unit 仏34 may be input to the control unit 44 without amplifying the signal by the sensor signal detecting unit. (Control unit)

圖4係控制部44之方塊構成圖。控制部44由微型電腦等 構成,具備CPU51、輸入部52、輸出部53及記憶部 又,於記憶部54中m隐控制程式之記憶區域55;記 憶用於得到第i偏光狀態而施加之電壓之第i電壓值之記憶 區域m己憶用於得到第2偏光狀態而施加之電壓之第2 電壓值之記憶區域57。 控制部44按如下所述進行動作。將來自輸人裝置43之例 如指定第1偏光狀態之信號輸人到輸人部52。cpu5i按照 控制程式55,讀取被輸人至輸人部52之信號與記憶於記憶 454之第1電壓值,並從輸出部53輸出至電壓輸出部。 電壓輸出部42對電極施加第i電壓值之電壓。藉由偏光狀 態檢測部檢測出之感測器信號,從輪人部邱輸入,咖 以使該感測器信號成為最大之方式,從輸出部兄輸出調整 信號,調整電壓輸出部42。藉此,可得到穩定之第i偏光 狀態。又’從輸人裝置43將指定例如第2偏光狀態之信號 輸入至輸人部52。哪51按照控制程式55,讀取被輸入至 輸入4 52之#號與記憶於記憶部54之第2電壓值,而從輸 142774.doc 201107822 出部53輸出至電壓輸出部42。電壓輸出部42對電極施加第 2電壓值之電壓。藉由偏光狀態檢測部 號’從輸入部52被輸一以使該感測器信號成為2 之方式,從輸出部53輸出調整信號,調整電壓輸出部42。 藉此’可得到穩定之第2偏光狀態。 (偏光開關元件之動作) 參照圖5及圖6,對圖}所示態樣之偏光開關元件之動作 進行說明。 參照圖5,從基板12側入射第!偏光狀態(直線偏光61)之 光⑼。從電㈣制部23之輸人裝置43將例如指偏光 狀態之信號輸人至輸人部52。CPU51按照控制程式55,讀 取被輸入至輸入部52之信號與記憶於記憶部54之第i電壓 值’並從輸出部53輸出至電壓輸出部42。電壓輸出部仏對 電極絲第1電壓值之電壓。藉由偏光狀態檢測部檢測出 ,感測益信號’從輸入部52被輸入,cpu以使該感測器信 號成為最大之方式,從輸出部53輸出調整信號,調整電壓 輸出部42。藉此,可得到穩定之第^光狀態(直線偏光 63)。 參照圖6 ’從輪入裝置43將例如指定第2偏光狀態之信號 輸^輸人部52eCPU51按照控制程式55,讀取被輸入至輸 入°卩52之化號與記憶於記憶部54之第2電壓值,並從輸出 P 53輸出至電壓輸出部42。電壓輸出部對電極施加第2 電壓值之電壓。藉由偏光狀態檢測部檢測出之感測器信 °’ k輸入52被輸入,cpu以使該感測器信號成為最大 142774.doc 201107822 ^方式’從輸出部53輸出調整信號,調整電壓輸出部42。 藉此可仔到穩定之第2偏光狀態(直線偏光65)。 (穩定之應答) ㈤述圖1之_樣中,因具有檢測透過液晶而人射之光之 • $光狀’°、之偏光狀態檢測機構’ JL該檢測信號藉由反饋機 構予以反饋,而將藉由電麼施加機構調整後之電麼施加於 液晶,故可取得穩定之應答之效果。 (液晶材料) 在『違反本發明之主旨之範圍0,對可使用於本發明之 牛等之液曰曰材料並無特殊限制。一般而言,液晶之應答 速度θ衫響使用该液晶之偏光開關元件之開關速度。從 • 該開關速度之觀點考量,相較於™液晶,較好地為使用 . 例如後述之Pss液晶或強介電性液晶。 (強介電性液晶) 在不違反本發明之主旨之範圍内,對可使用於本發明之 〇 70件等之強介電性液晶材料並無特殊限制。從應答速度之 觀點考量,較好地為可使用下述之強介電性液晶材料。 (使用PSS液晶或強介電性液晶之元件) 如前所述,本態樣之偏光開關元件,使用PSS液晶或強 電性液晶作為液晶材料,從提高液晶之應答速度之觀點 .而S較佳。於如此之態樣中,可獲得進一步提高液晶之開 關速度之效果。將如此之液晶之開關速度之增加,再加上 前述本發明之「穩定之應答」,可高速且穩定地開關,故 可得到下述之相乘效果,例如應用於用於觀看立體影像之 142774.doc •13· 201107822 3維顯示器等情形’交互切換右眼用之影像與左眼用之影 像可使觀者無不協調感,可以自然之感覺觀看立體影像。 (投影機) 以下,對使用本發明之態樣之偏光開關元件基於圖7進 打說明。圖7係表示本發明之態樣之投影機之模式剖面 圖。该投影機60係使用上述本發明之偏光開關元件1〇之投 影機,具備:用於表示所輸入之影像信號之空間光調變元 件6 1,照明光學系統62 ;包含偏光開關元件丨〇之光學單元 63 ;用於將通過光學單元63之光擴大投射至屏幕64之投影 光學系統65 ;驅動空間光調變元件61之調變元件驅動電路 66 ;驅動偏光開關元件1〇之偏光開關元件驅動電路67。 該投影機60使來自空間光調變元件61之光通過偏光開關 元件10。此時,接受來自調變元件驅動電路66之信號,藉 由偏光開關元件驅動電路67,使偏光開關元件1〇動作。藉 此,使偏光狀態切換,將該偏光狀態切換後之光投影至屏 幕。藉由具備透過左右不同之偏光方向之光之偏光板之鏡 片觀看該被投影之影像,可看到立體影像。此時,因本態 樣下之偏光開關元件可高速開關且穩定地應答,故可看到 高品質之影像。 (電視) 以下,對使用本發明之態樣之偏光開關元件之電視基於 圖8進行說明。圖8係表示本發明之態樣之電視之方塊圖 (概略構成圖)。該電視70係使用前述本發明之偏光開關元 件10之電視,具備用於表示所輸入之影像信號之顯示裝置 142774.doc -14- 201107822 71、偏光開關元件ίο、驅動顯示裝置71之顯示裝置驅動電 路7 2、驅動偏光開關元件丨〇之偏光開關元件驅動電路乃。 ,電視70使來自顯示裝置71之光通過偏光開關元件1〇。 此時’接受來自顯示裝置驅動電路72之信號,#由偏光開 關兀件驅動電路73’使偏光開關元件1〇動作。藉此使偏光 狀態切換’右眼用之影像與左眼用之影像按時間分割以交 互不同之偏光狀藉由具備透過左右不同之偏光方FIG. 4 is a block diagram of the control unit 44. The control unit 44 is configured by a microcomputer or the like, and includes a CPU 51, an input unit 52, an output unit 53, and a storage unit. In the memory unit 54, the memory area 55 of the program is implicitly controlled. The voltage applied to obtain the ith polarization state is memorized. The memory region m of the i-th voltage value has a memory region 57 for the second voltage value of the voltage applied to obtain the second polarization state. The control unit 44 operates as follows. A signal from the input device 43 such as a signal specifying the first polarization state is input to the input unit 52. The cpu 5i reads the signal input to the input unit 52 and the first voltage value stored in the memory 454 in accordance with the control program 55, and outputs it from the output unit 53 to the voltage output unit. The voltage output unit 42 applies a voltage of the i-th voltage value to the electrode. The sensor signal detected by the polarization state detecting unit is input from the person in the wheel, and the sensor signal is maximized. The adjustment signal is output from the output unit and the voltage output unit 42 is adjusted. Thereby, a stable ith polarization state can be obtained. Further, a signal specifying, for example, the second polarization state is input from the input device 43 to the input unit 52. 51, in accordance with the control program 55, reads the ## input to the input 4 52 and the second voltage value stored in the memory unit 54, and outputs it to the voltage output unit 42 from the output unit 142774.doc 201107822. The voltage output unit 42 applies a voltage of a second voltage value to the electrodes. The polarization state detecting unit No. ' is input from the input unit 52 so that the sensor signal becomes 2, and the adjustment signal is output from the output unit 53 to adjust the voltage output unit 42. Thereby, a stable second polarization state can be obtained. (Operation of Polarizing Switch Element) The operation of the polarization switching element of the aspect shown in Fig.} will be described with reference to Figs. 5 and 6 . Referring to Fig. 5, the first incident from the substrate 12 side! Light in the polarized state (linear polarized light 61) (9). A signal indicating, for example, a polarization state is input from the input device 43 of the electric (four) unit 23 to the input unit 52. The CPU 51 reads the signal input to the input unit 52 and the i-th voltage value 'stored in the memory unit 54 in accordance with the control program 55, and outputs it from the output unit 53 to the voltage output unit 42. The voltage output unit 电压 the voltage of the first voltage value of the wire electrode. The polarization state detecting unit detects that the sensory signal is input from the input unit 52, and the CPU outputs the adjustment signal from the output unit 53 so that the sensor signal is maximized, and the voltage output unit 42 is adjusted. Thereby, a stable second light state (linear polarized light 63) can be obtained. Referring to Fig. 6 'the signal input/output unit 52eCPU 51 that specifies the second polarization state, for example, from the wheeling device 43, reads the input number input to the input port 52 and the second memory in the memory unit 54 in accordance with the control program 55. The voltage value is output from the output P 53 to the voltage output portion 42. The voltage output unit applies a voltage of the second voltage value to the electrode. The sensor signal 'k input 52 detected by the polarization state detecting unit is input, and the cpu is used to make the sensor signal maximum 142774.doc 201107822 ^method 'output adjustment signal from the output unit 53 to adjust the voltage output portion 42. Thereby, the stable second polarization state (linear polarization 65) can be achieved. (Stable response) (5) In the sample of Fig. 1, because of the detection of light transmitted through the liquid crystal, the light is detected by the feedback mechanism. The electric power adjusted by the electric application mechanism is applied to the liquid crystal, so that a stable response can be obtained. (Liquid crystal material) The liquid helium material which can be used for the cattle of the present invention is not particularly limited in the range of the scope of the present invention. In general, the response speed of the liquid crystal θ is the switching speed of the polarization switching element using the liquid crystal. From the viewpoint of the switching speed, it is preferably used as compared with the TM liquid crystal. For example, Pss liquid crystal or ferroelectric liquid crystal to be described later. (Strong dielectric liquid crystal) The ferroelectric liquid crystal material which can be used for the present invention of the present invention is not particularly limited as long as it does not deviate from the gist of the present invention. From the viewpoint of the response speed, it is preferred to use the above-mentioned ferroelectric liquid crystal material. (Element using PSS liquid crystal or ferroelectric liquid crystal) As described above, the polarization switching element of the present aspect uses PSS liquid crystal or ferroelectric liquid crystal as the liquid crystal material, and is preferable from the viewpoint of improving the response speed of the liquid crystal. In such a manner, the effect of further increasing the switching speed of the liquid crystal can be obtained. The increase in the switching speed of such a liquid crystal, together with the "stable response" of the present invention, enables high-speed and stable switching, so that the following multiplication effect can be obtained, for example, for 142774 for viewing stereoscopic images. .doc •13· 201107822 3D display and other situations 'Interactively switching the image for the right eye and the image for the left eye can make the viewer feel uncomfortable and can naturally view the stereo image. (Projector) Hereinafter, a polarization switching element using the aspect of the present invention will be described based on Fig. 7 . Fig. 7 is a schematic cross-sectional view showing the projector of the aspect of the invention. The projector 60 is a projector using the above-described polarization switching element 1 of the present invention, and includes a spatial light modulation element 161 for indicating an input image signal, an illumination optical system 62, and a polarization switching element. The optical unit 63; the projection optical system 65 for expanding the light passing through the optical unit 63 to the screen 64; the modulation element driving circuit 66 for driving the spatial light modulation element 61; and the polarization switching element driving for driving the polarization switching element 1 Circuit 67. The projector 60 passes light from the spatial light modulation element 61 through the polarization switch element 10. At this time, the signal from the modulation element drive circuit 66 is received, and the polarization switch element drive circuit 67 is operated to operate the polarization switch element 1?. Thereby, the polarization state is switched, and the light after the polarization state is switched is projected onto the screen. The stereoscopic image can be seen by viewing the projected image by a mirror having a polarizing plate that transmits light of different polarization directions. At this time, since the polarization switch element in this aspect can be switched at a high speed and stably responded, a high-quality image can be seen. (Television) Hereinafter, a television using the polarization switching element of the aspect of the present invention will be described based on Fig. 8 . Fig. 8 is a block diagram (schematic configuration diagram) of a television showing an aspect of the present invention. The television 70 is a television using the polarizing switch element 10 of the present invention, and includes a display device 142774.doc -14-201107822 71 for indicating an input image signal, a polarization switch element ίο, and a display device driving the display device 71. The circuit 7 drives the polarization switching element driving circuit of the polarization switching element 丨〇. The television 70 passes the light from the display device 71 through the polarization switch element 1A. At this time, the signal from the display device drive circuit 72 is received, and the polarization switch element 1 is operated by the polarization switch element drive circuit 73'. Thereby, the polarization state is switched, and the image for the right eye and the image for the left eye are time-divided to have different polarizations, and the polarized light having different left and right sides is provided.

向之光之偏歧之鏡片觀看該影像,可看到立體影像。此 時’因本態樣下之偏光開關元件可高速開關且穩定地應 °故可看到间°〇質之影像(關於如此立體影像電視之原 理之詳細情況’例如可參照文獻:日本特開平9_219876號 公報)。 (液晶元件) 本發明之態樣之液晶元件(液晶開關元件)至少包含一對 基板與配置於該一對基板之間之液晶材料。 (液晶材料) 本發明中’只要係為適用本發明之方式,與施加電場之 大小,及/或具有對應⑨方向之光學轴方位之迴轉之可構 成電氣光學元件之液晶材料,可*受特殊限制地使用。本 發明中,是否可使用某種液晶材料,可由以下之「光學軸 方位之迴轉之確認方法」確認。χ,基於本發明中能夠以 特定之高速應答之觀點而較適合使用之論點而言,某種液 晶材料是否可於充分之速度下應答,可由以下之「應答時 間之確認方法」確認。 142774.doc •15· 201107822 (光學軸方位之迴轉之確認方法) 、,作為液晶元件之光學財位之迴轉之敎方法,於將偏 光片垂直配置於析光片之正交尼科爾稜鏡配置中設置液晶 凡件之情形’當光學軸與析光片之吸收軸—致之情形時透 過光之強度最小。因此,在正交尼科爾稜鏡配置中可得到 透過光之最小強度之角度即為光學軸方位之角纟。此時, 處於未對液晶元件施加電場之狀態。以此為基準角度對 液晶元件施加電場,尋找可得到正交尼科爾稜鏡配置中之 透過光量之最小強度之角度。因存在施加電場後成為最小 強度之角《,與前述之基準角度偏離之角度即為該最小強 度之角度,故只要在電場之大小或方向改變時觀察對應於 變化量之回轉角之增減,便可確認光學軸方向有所迴轉。 作為用於確認之裝置例,與光學軸方位之確認方法同樣可 以圖13之構成確認。 (應答時間之確認方法) 於液晶元件中觀察光學轴方位之迴轉之情形時,該迴轉 之速度即為應答時間。在將偏光片與析光片垂直配置之正 交尼科爾稜鏡配置中以透過光量最小之角度配置液晶元 件,對液晶S件施加電場。因藉纟電場施加而使光學軸方 位迴轉’故透過光量產生變化。因此,該透過光量之變化 程度即為迴轉之變化程度。將未施加電場之狀態之透過光 量設為G% ’將藉由電場施加而改變並成為最終穩定狀態 之透過光量設為100%時,從未施加電場之狀態起施加電 場而使透過光量從1〇%變成9〇%之時間為上升應答時間 142774.doc -16- 201107822 k施加電場之狀態起停止電場施加而使透過光量從90%變 成1〇%之時間為下降應答時間。例如,於PSS-LCD申,上 升應答時間、下降應答時間均為400 左右。作為用於確 • ⑽之裝置例’與後述之「光學軸方位之確認方法」之情形 • 相同’可以圖13之構成確認。 • (PSS-LCD) 本發明中可較好地使用之液晶材料,PSS-LCD,即該液 〇 ΒΒ材料中之初期分子配向具有相對於配向處理方向大致平 行之方向’且液晶材料於實質不存在外部施加電壓之下, 相對於對基板至少完全未展現垂直之自發分極者。 (初期分子排列) 本發月中,液晶材料中之初期分子配向(或方向),液晶 . 分子之長軸具有相對於液晶分子之配向處理方向大致平行 之方向。液晶分子之長轴具有相對於配向處理大致平行之 广] °延—事實,例如可以下述之做法確認。為使本發明之 〇 液晶70件可展現所希望之顯示性能,藉由以下之方法所測 足之摩擦方向與液晶分子之配向方向間之角度(絕對值)較 好地為3。以下’更好地為2。以下’特別好為丨。以下。出於 嚴=性考慮,當聚醯亞胺膜等聚合物配向膜受到摩擦之情 形時,已知會於聚醯亞胺最表層誘發雙折射,而據此賦予 . 軸此外,一般而言,已知液晶分子之長軸與慢軸平行 配向。就幾乎所有的聚醯亞胺配向膜而言,已知會在摩擦 方向與k轴間產生某種角度偏差。一般,偏差比較小,可 為勺7度。但,該角度之偏差,作為極端之例,如聚苯 142774.doc -17- 201107822 ^烯之情形可為9G度。因此’本發明中,摩擦方向與液晶 分子之長軸(即光軸)之配向方向間之角度可較好地為3。以 下。該時點,液晶分子之長軸與因摩擦等於聚合物(聚酿 亞胺等)、聚合物配向膜中提供之慢軸之配向方向,較好 地為3。以下,更好地為2。以下,特別好為丨。以下。 如前所述,在本發明中配向處理方向係指決定液晶分子 長軸之配向方向之慢軸(於聚合物最表層)之方向。 <對液晶分子測定初期分子配向狀態之方法> 一般’液晶分子之長軸與光軸相—致。因此,於使偏光 片垂直配置於析光片之正交尼科爾稜鏡配置中設置液晶面 板之情形下’透過光線之強度於液晶之光軸與析光片之吸 收轴相一致之情形時為最小。初期配向軸之方向可一面測 定液晶面板所透過光線之強度,並在正交尼科爾稜鏡配置 中藉由迴轉之方法敎,藉此,可測W予透過光線之最 小強度之角度。 <測定液晶分子長軸方向與配向處理方向之平行度之方法> 摩擦方向係藉由設定角決定,藉由摩擦而提供之聚合物 配向膜最表層之慢軸’係由聚合物配向膜之種類、膜製造 方法、,摩擦強度等決定。因& ’若提供與慢軸之方向平行 之消光位之情形時,可確認分子長軸即分子光軸與慢抽之 方向平行。 (自發分極) 本發明巾’在初期分子配向彳φ,自發分極(類似於強 介電性液晶之情形之自發分極)至少不會發生於垂直於基 142774.doc -18- 201107822 板之方向。本發明中所述之「未提供實質性自發分極之初 期分子配向,係不發生自發分極者」,可藉由例如以下之 方法確認。 <測定存在垂直於基板之自發分極之方法> 當液晶胞中之液晶呈右白施八#々& 狀日日/、有自發分極之情形,特別是在自發 Ο ❹ 分極發生於初期狀態下之基板方向,即初期狀態下垂直於 電場方向(即無外部電場之情形之)之情形中,將低頻率三 角波電壓(約G.l ΗΖ)施加於液晶胞時,施加電壓會從正反 轉成負,或從負反轉成正之極性變化,且自發分極之方向 會從上方方向反轉成下方方向,或從下方方向反轉成上方 向在如此之反轉之同時,輸送實際之電荷(即產生電 )自發刀極,、於她加電場之極性反轉時反轉。因此, 會出現如圖9所示之峰值狀電流。峰值狀電流之積分值對 應於所要輸送之全量電荷,即對應於自發分極之強度。以 该測定觀察非學值狀電流之情形時,可直接藉由如此之現 象證明無自發分極反轉之發生。此外,當觀察到如圖10所 不之^之直線增加之情料,可發現液晶分子之長轴對 應於電場強度之增加,而於兮楚+ γ ^ @於5亥專之分子配向方向連續性或 持續變化。換言之,如阁彳η私_ 圖1〇所不之該例中,可發現對應於 所施加之電場強度,而因誘導分極等使分子配向方向產生 變化。 (基板) 發月中可使用之基板’只要是可賦予前述之特定「初 …配向狀態」者’並無特殊限定。換言之,本發” 142774.doc -19- 201107822 所適用之基板可從LCD之使用法或用途、其材料及尺寸等 觀點來適當地選擇。 (PSS-LCD材料) 本發明中適宜使用之PSS-LCD液晶材料,只要是可賦予 前述之特定「初期分子配向狀態」者,並無特殊限定。換 言之,本發明中所適用之液晶材料可從物理性特性、電氣 或顯示性此等觀點適當地選擇。例如,如文獻所例示之各 種各樣之液晶材料(包含各種各樣之強介電性或非強介電 性液晶材料),一般而言皆可於本發明中使用。本發明 中了使用之如此之液晶材料之特定較好例,可列舉如 下。 [化1]The image is viewed from the lens of the eccentricity of the light, and a stereoscopic image can be seen. At this time, the polarized switching element in this aspect can be switched at a high speed and stably, so that the image of the enamel can be seen (for details of the principle of such a stereoscopic television), for example, reference: Japanese Patent Laid-Open No. 9_219876 Bulletin). (Liquid Crystal Element) A liquid crystal element (liquid crystal switching element) according to an aspect of the present invention includes at least a pair of substrates and a liquid crystal material disposed between the pair of substrates. (Liquid Crystal Material) In the present invention, as long as it is a mode in which the present invention is applied, a liquid crystal material which can constitute an electro-optical element with a magnitude of an applied electric field and/or a rotation of an optical axis corresponding to nine directions can be *special Use restricted. In the present invention, whether or not a certain liquid crystal material can be used can be confirmed by the following "method for confirming the rotation of the optical axis direction". That is, based on the argument that the liquid crystal material can be responsive at a sufficient speed based on the argument that the specific high-speed response can be used in the present invention, it can be confirmed by the following "validation method of response time". 142774.doc •15·201107822 (Method for confirming the rotation of the optical axis). As a method of turning the optical position of the liquid crystal element, the polarizer is vertically arranged on the crossed Nicols of the deposited sheet. In the case where the liquid crystal parts are set in the configuration, the intensity of the transmitted light is minimized when the optical axis and the absorption axis of the thin film are in the case. Therefore, the angle of the minimum intensity of transmitted light in the crossed Nicols configuration is the angle 纟 of the optical axis. At this time, the electric field is not applied to the liquid crystal element. Using this as a reference angle, an electric field is applied to the liquid crystal element to find the angle at which the minimum intensity of the transmitted light in the crossed Nicols configuration can be obtained. Since the angle at which the electric field is the minimum intensity after the application of the electric field is the angle of the minimum intensity, the angle of the minimum intensity is observed as long as the magnitude or direction of the electric field changes, and the increase or decrease of the revolving angle corresponding to the amount of change is observed. It is confirmed that the optical axis direction has been rotated. As an example of the apparatus for confirming, the method of confirming the orientation of the optical axis can be confirmed by the configuration of Fig. 13. (Method of confirming response time) When the optical axis orientation is observed in the liquid crystal element, the speed of the rotation is the response time. In the orthogonal Nicol setting in which the polarizer and the phosphor are arranged perpendicularly, the liquid crystal element is disposed at an angle at which the amount of transmitted light is the smallest, and an electric field is applied to the liquid crystal S. Since the optical axis is rotated by the application of the electric field, the amount of transmitted light changes. Therefore, the degree of change in the amount of transmitted light is the degree of change in rotation. When the amount of transmitted light in a state where no electric field is applied is set to G%', when the amount of transmitted light which is changed by the application of the electric field and becomes the final stable state is set to 100%, an electric field is applied from the state where the electric field is not applied, and the amount of transmitted light is changed from 1 The time when 〇% becomes 9〇% is the rising response time 142774.doc -16- 201107822 k The time during which the electric field is applied starts the application of the stop electric field, and the time when the amount of transmitted light is changed from 90% to 1% is the falling response time. For example, in the PSS-LCD application, the rise response time and fall response time are all around 400. The case where the device example of (10) is used and the "method of confirming the optical axis direction" to be described later is the same. The configuration of Fig. 13 can be confirmed. • (PSS-LCD) The liquid crystal material which can be preferably used in the present invention, PSS-LCD, that is, the initial molecular alignment in the liquid helium material has a direction substantially parallel to the direction of the alignment treatment, and the liquid crystal material is substantially Below the external applied voltage, the spontaneous splitter is at least not perpendicular to the substrate. (Initial Molecular Alignment) In the present month, the initial molecular alignment (or direction) in the liquid crystal material, the liquid crystal. The long axis of the molecule has a direction substantially parallel to the alignment processing direction of the liquid crystal molecules. The long axis of the liquid crystal molecules has a width which is substantially parallel with respect to the alignment treatment, and can be confirmed, for example, by the following method. In order to make the liquid crystal 70 of the present invention exhibit desired display properties, the angle (absolute value) between the rubbing direction of the foot and the alignment direction of the liquid crystal molecules is preferably 3 by the following method. The following 'better is 2. The following 'especially good for you. the following. For the sake of strictness, when a polymer alignment film such as a polyimide film is rubbed, it is known that birefringence is induced at the outermost layer of polyimine, and is thereby imparted to the shaft. In addition, in general, It is known that the long axis and the slow axis of the liquid crystal molecules are aligned in parallel. For almost all polyimine alignment films, it is known that there is some angular deviation between the rubbing direction and the k-axis. In general, the deviation is relatively small, which can be 7 degrees. However, the deviation of the angle, as an extreme example, such as polyphenyl 142774.doc -17- 201107822 ^ ene can be 9G degrees. Therefore, in the present invention, the angle between the rubbing direction and the alignment direction of the long axis (i.e., the optical axis) of the liquid crystal molecules is preferably 3. the following. At this point, the long axis of the liquid crystal molecules and the direction of alignment of the slow axis provided by the polymer (polyimide or the like) and the polymer alignment film are preferably 3 in terms of friction. Below, better is 2. The following is particularly good. the following. As described above, in the present invention, the direction of the alignment treatment means the direction of the slow axis (in the outermost layer of the polymer) which determines the alignment direction of the long axis of the liquid crystal molecule. <Method for measuring initial molecular alignment state of liquid crystal molecules> Generally, the long axis of the liquid crystal molecules is aligned with the optical axis. Therefore, in the case where the liquid crystal panel is disposed in the crossed Nicols configuration in which the polarizer is vertically disposed in the phosphor, the intensity of the transmitted light is consistent with the absorption axis of the liquid crystal. For the smallest. The direction of the initial alignment axis can measure the intensity of the light transmitted through the liquid crystal panel and rotate it in a crossed Nicols configuration, thereby measuring the angle of the minimum intensity of the transmitted light. <Method for measuring the parallelism between the long axis direction of the liquid crystal molecules and the alignment treatment direction> The rubbing direction is determined by the set angle, and the slow axis of the outermost layer of the polymer alignment film provided by friction is composed of the polymer alignment film The type, film production method, and friction strength are determined. When &' provides a matte position parallel to the direction of the slow axis, it can be confirmed that the molecular long axis, that is, the molecular optical axis, is parallel to the slow drawing direction. (Spontaneous polarization) The inventive towel 'in the initial molecular alignment 彳 φ, the spontaneous polarization (similar to the spontaneous polarization of the case of a ferroelectric liquid crystal) does not occur at least perpendicular to the direction of the base 142774.doc -18-201107822. The "initial molecular alignment which does not provide substantial spontaneous polarization is not a spontaneous polarization" as described in the present invention can be confirmed by, for example, the following method. <Measurement of the presence of a spontaneous polarization perpendicular to the substrate> When the liquid crystal in the liquid crystal cell is in the right white Shi Ba &# shape, there is a spontaneous polarization, especially in the spontaneous Ο ❹ In the case of the substrate in the state, that is, in the initial state perpendicular to the direction of the electric field (that is, in the case of no external electric field), when a low-frequency triangular wave voltage (about G1 ΗΖ) is applied to the liquid crystal cell, the applied voltage is reversed from positive to negative. Negative, or from negative to positive polarity change, and the direction of the spontaneous polarization will be reversed from the upper direction to the lower direction, or from the lower direction to the upper direction, and the opposite direction is reversed, the actual charge is delivered ( That is, the electricity is generated by the spontaneous knife pole, which is reversed when the polarity of the applied electric field is reversed. Therefore, a peak current as shown in Fig. 9 appears. The integrated value of the peak current corresponds to the total amount of charge to be delivered, i.e., the intensity corresponding to the spontaneous polarization. When the non-study current is observed by the measurement, the occurrence of spontaneous polarization inversion can be directly confirmed by such a phenomenon. In addition, when observing the increase of the straight line as shown in Fig. 10, it can be found that the long axis of the liquid crystal molecule corresponds to the increase of the electric field strength, and the molecular alignment direction of the 亥 + + γ ^ @ Sexual or continuous change. In other words, in this case, as shown in Fig. 1, it can be found that the intensity of the applied electric field is changed, and the orientation of the molecules is changed by the induced polarization or the like. (Substrate) The substrate which can be used in the month of the month is not particularly limited as long as it can be given the specific "initial alignment state" described above. In other words, the substrate to which the present invention is applied can be appropriately selected from the viewpoints of the use method or use of the LCD, its material and size, etc. (PSS-LCD material) PSS- suitable for use in the present invention The LCD liquid crystal material is not particularly limited as long as it can impart the specific "initial molecular alignment state" described above. In other words, the liquid crystal material to which the present invention is applied can be appropriately selected from the viewpoints of physical properties, electrical properties, or display properties. For example, a wide variety of liquid crystal materials (including a wide variety of ferroelectric or non-strong dielectric liquid crystal materials) as exemplified in the literature can be generally used in the present invention. Specific preferred examples of the liquid crystal material used in the present invention are as follows. [Chemical 1]

crh c8h170 8n17Crh c8h170 8n17

[化2][Chemical 2]

142774.doc -20- 201107822 (配向膜) 本發明中可使用之配向膜,只要是可賦予前述之特定 「初期分子配向狀態」者,並無特殊限定。換言之,本發 / 日月中所適用之配向膜可從物理性特性、電氣或顯示性能等 ㈣適當地選擇。例如,如文獻所例示之各種各樣之配向 • 膜’一般而言皆可於本發明中使用。本發明中,可使用之 如此之液晶材料之特定較好例,可列舉如下。 〇 $合物配向膜:聚醯亞胺、聚醯胺、聚酿胺-酿亞胺 無機配向膜:Si02、SiO、丁82〇5等 本發明中,作為前述之基板、液晶材料及配向膜,根據 需要可使用記載於日刊王業新聞社(日本、東京)發行之 ' 「以叫^ CryStal Device Handbo〇k」(1989)之各項目所對 • 應之材料、成分或構成要素。 (其他構成要素) 為構成本發明之液晶開關元件所使用之透明電極、電極 〇 目案、間隔件及偏光板等其他材料、構成要素或成分,只 要在不違反本發明之目的之範圍内(即該等只要是可鹎S 前述之特定「初期分子配向狀態」者),並無特殊限定。 除此之外,本發明中可使用來製造之液晶開關元件之方 ”法,除將液晶開關元件構成為賦予前述之特定「初期分子 、㈣狀態」以外’並無特殊限定1㈣於構成液晶:關 疋件之各種各樣的材料、構成要素或成分之詳細情況,根 據需要’可參照曰刊工業新聞社(日本、東京)發行之 「Liquid Crystal Device Handbook」(1989)。 142774.doc 201107822 (用於實現特定之初期配向之手段) a用於實現如此之配向狀態之手段或方策,只要是可實現 則j之特定之「初期分子配向狀態」I,並無特殊限定。 換言之’本發明中,用於實現所適用之特定之初期配向之 手段或方策,可從物理性特性、電氣或顯示性能等觀點來 適當地選擇。 (用於賦予初期配向之較好手段) 」艮據本發明者們之知見’前述之所適用之初期配向,可 藉由使用以下之配向膜(在藉由燒成而形成之配向膜之情 形中其厚度以燒成後之厚度表示)及摩擦處理而容易地 實現。另-方面’ it常之強介電性液晶元件中,配向膜之 厚度為3〇〇〇A(埃)以下,摩擦強度(即摩擦之壓入量)為0.3 mm以下。 配向膜之厚度.較好地為4〇〇〇A以上更好地為 以上(特別好為6000A以上)。 摩擦強度(即摩擦之壓入量):較好地為〇3匪以上,更 好地為0.4 mm以上(特別好為〇 45 mm以上)。 鈾述之配向膜厚度及摩擦強度可以例如後述之製造例i 所述之方法測定。 本發明中,亦可適宜使用具有日本特願2〇〇7_28182號中 揭示之其他構成之PSS-LCD。 實施例 製造例1 使用市售之FLC混合物材料(默克(merck) : zli_4851_ 142774.doc •22· 201107822 10〇)、液晶性光聚合物質(大日本墨水化學工業:UCL-001)及聚合開始劑(默克:光起始劑(Darocure)1173)’基於 曰本特開平11-21554號(特願平09-174463號),組裝成液晶 元件。混合物係具有93質量%之ZLT-4851-100FLC混合 • 物、6質量%iUCL-001及1質量%之光起始劑1173。 此處所使用之基板,係於其上具有ITO膜之玻璃基板 (Nono Loa公司(Nono Loa Inc_)所市售之石夕硼酸玻璃,厚度 ❹ 〇·7 mm,尺寸 50 mm><50 mm)。 藉由使用旋轉塗佈機塗佈聚醯亞胺配向材料,然後,將 所得到之膜預烤,最後將所得到之生成物於無塵烤箱中燒 成’形成聚醯亞胺配向膜。關於此處所應使用之一般性工 - 業程序之詳細情況’根據需要,可參照文獻「Liquid • Crystal Display Techniques」Sangyo Tosho(1996 ’ 東京), Chapter 6 〇 對於液晶分子配向膜用,使用RN-1199(日產化學工業) 〇 作為1〜丨.5。之預傾角配向物質。作為硬化層之配向層之厚 度設定為4500A〜5〇0〇A。將該硬化配向層之表面藉由縲縈 布(Yoshikwa Kako製,商品名19RY),以如圖12所示相對 _ 於基板之中心方向成30度之角度之方式摩擦。摩擦之壓入 量’於兩基板上均為0.5 mm 〇 <摩擦條件> 摩擦之壓入量:0.5 mm 摩擦數:1次 工作臺移動速度:2 mm/秒 142774.doc -23- 201107822 軋輥迴轉頻率:1000 rpm(R=4〇mm) 作為間隔件使用平均粒徑為i. 6微米之二氧化石夕粒子。 元成之胞間隙測定值為1.8微米。將前述混合材料於丨丨 等分注入胞中。注入混合材料後,控制周邊溫度以^分 鐘2°C之比例慢慢冷卻至混合材料呈現強介電性液晶相 (40 C )。之後,藉由自然冷卻使面板到達充分室溫時,對 面板施加10分鐘、+/-10 V、頻率5〇〇 Hz之三角波電壓(使 用NF Circuit Block公司製之函數波產生器,商品名: WF1946F)。施加電壓10分鐘之後,保持相同的電壓施 加,並照射365 nm之紫外線(使用uvp公司製紫外線,商 品名:UVL-56)。照射之條件係5〇〇〇 mJ/cm2。關於此處所 應使用之一般性工業程序之詳細情況,根據需要可參照文 獻「Liquid Crystal Display Techniques」Sangyo Tosho (1996,東京),Chapter 6。 關於此處所應使用之一般性工業程序之詳細情況,根據 需要可參照文獻「The Optics of Thermotropic Liquid142774.doc -20-201107822 (Alignment film) The alignment film which can be used in the present invention is not particularly limited as long as it can impart the specific "initial molecular alignment state" described above. In other words, the alignment film to which this issue/day is applied can be appropriately selected from physical properties, electrical or display properties, etc. (4). For example, various alignments as exemplified in the literature can be generally used in the present invention. Specific preferred examples of such a liquid crystal material which can be used in the present invention are as follows. 〇$ conjugate film: polyimine, polyamine, polyamine-nitride, inorganic alignment film: SiO 2 , SiO, butyl 82 〇 5, etc., in the present invention, as the aforementioned substrate, liquid crystal material and alignment film If necessary, you can use the materials, ingredients, or components of the items listed in the "CryStal Device Handbo〇k" (1989) issued by the Nikkan News Agency (Japan, Tokyo). (Other components) Other materials, constituent elements or components such as a transparent electrode, an electrode, a spacer, a polarizing plate, and the like which are used in the liquid crystal switching element of the present invention are within the scope of the object of the present invention ( In other words, the above-mentioned specific "initial molecular alignment state" is not particularly limited as long as it is the specific "initial molecular alignment state" described above. In addition, in the present invention, the method of the liquid crystal switching element can be used to form a liquid crystal switching element, except that the liquid crystal switching element is configured to impart the above-mentioned specific "initial molecule, (four) state". For details of the various materials, components, or components of the product, please refer to the "Liquid Crystal Device Handbook" (1989) issued by the Kokusai Industrial News Agency (Japan, Tokyo). 142774.doc 201107822 (means for achieving a specific initial alignment) a means or means for realizing such an alignment state, as long as it is achievable, the specific "initial molecular alignment state" I of j is not particularly limited. In other words, in the present invention, means or means for realizing the specific initial alignment to be applied can be appropriately selected from the viewpoints of physical properties, electrical properties, display performance, and the like. (Good means for imparting initial alignment) "As far as the inventors know, the initial alignment to which the above is applied can be achieved by using the following alignment film (in the case of an alignment film formed by firing) The thickness thereof is easily expressed by the thickness after firing and the rubbing treatment. In the other aspect, the thickness of the alignment film is 3 〇〇〇A (angstrom) or less, and the frictional strength (i.e., the amount of friction) is 0.3 mm or less. The thickness of the alignment film is preferably 4 Å or more, more preferably the above (particularly preferably 6000 A or more). The frictional strength (i.e., the amount of friction intrusion) is preferably 〇3 匪 or more, more preferably 0.4 mm or more (particularly preferably 〇 45 mm or more). The aligning film thickness and the frictional strength of uranium can be measured, for example, by the method described in Production Example i to be described later. In the present invention, a PSS-LCD having another configuration disclosed in Japanese Patent Application No. Hei. EXAMPLES Production Example 1 A commercially available FLC mixture material (merck: zli_4851_ 142774.doc • 22·201107822 10〇), a liquid crystalline photopolymer (Japan Pharmaceutical Industry: UCL-001), and polymerization were used. The agent (Merck: Light Starter (Darocure) 1173) was assembled into a liquid crystal element based on the Japanese Patent Application Laid-Open No. Hei 11-21554 (Japanese Patent Application No. Hei 09-174463). The mixture was composed of 93% by mass of ZLT-4851-100FLC mixed material, 6% by mass of iUCL-001, and 1% by mass of photoinitiator 1173. The substrate used herein is a glass substrate having an ITO film thereon (Shih-Boron glass commercially available from Nono Loa Inc., thickness ❹ 〇 7 mm, size 50 mm >< 50 mm) . The polyimine alignment material was coated by using a spin coater, and then the obtained film was pre-baked, and finally the resultant product was fired in a dust-free oven to form a polyimide film. For details of the general industrial procedures to be used here, please refer to the document "Liquid • Crystal Display Techniques" Sangyo Tosho (1996 'Tokyo), Chapter 6 〇 for liquid crystal molecular alignment films, using RN- 1199 (Nissan Chemical Industry) 〇 as 1 ~ 丨.5. Pretilt angle alignment material. The thickness of the alignment layer as the hardened layer was set to 4500 A to 5 〇 0 〇 A. The surface of the hardened alignment layer was rubbed by a crepe cloth (manufactured by Yoshikwa Kako, trade name: 19RY) so as to be at an angle of 30 degrees with respect to the center direction of the substrate as shown in Fig. 12 . The pressing amount of friction '0.5 mm on both substrates 〇<friction conditions> frictional pressing amount: 0.5 mm friction number: 1 table moving speed: 2 mm/sec 142774.doc -23- 201107822 Roller gyration frequency: 1000 rpm (R = 4 〇 mm) As the spacer, a particle size of i. 6 μm is used. The cell gap measurement of Yuancheng was 1.8 microns. The aforementioned mixed material is aliquoted into the cells in 丨丨. After the mixed material was injected, the peripheral temperature was controlled to be slowly cooled at a rate of 2 ° C to a mixed material exhibiting a ferroelectric liquid crystal phase (40 C ). After that, when the panel reaches a sufficient room temperature by natural cooling, a triangular wave voltage of 10 kHz, +/- 10 V, and frequency 5 〇〇 is applied to the panel (using a function wave generator manufactured by NF Circuit Block Co., Ltd., trade name: WF1946F). After applying the voltage for 10 minutes, the same voltage was applied and irradiated with ultraviolet rays of 365 nm (using ultraviolet light manufactured by UVp, trade name: UVL-56). The conditions of the irradiation were 5 〇〇〇 mJ/cm 2 . For details of the general industrial procedures used here, refer to the article "Liquid Crystal Display Techniques" Sangyo Tosho (1996, Tokyo), Chapter 6, as needed. For details of the general industrial procedures to be used here, refer to the document "The Optics of Thermotropic Liquid" as needed.

Crystals」Tayl or and Francis : 1998 ’ 英國倫敦;Chapter 8及 Chapter 9。 製造例2 mm。 對於液晶分子配向膜用,使用RN-1199(日產化學工業) 作為1〜1.5 °之預傾角配向物質。作為硬化層之配向層之厚 度設定為6500A〜7000A。將該硬化配向層之表面藉由 Rayon布’以相對於如圖12所示之基板之中心線成3〇度之 角度之方式摩擦。摩擦之壓入量,於兩基板上均為〇5 I42774.doc -24- 201107822 作為間隔件使用平均粒徑為丨.6微米之二氧化矽粒子。完 成之胞間隙測定值為1 _ 8微米。於該胞中,將市售之FLC混 合物材料(默克:ZLI-4851-100)以110。(;溫度等分注入。注 入混合材料後,控制周邊溫度,以丨分鐘丨之比例慢慢冷 . 部使171^材料至呈現強介電性液晶相(40。〇。在從層列入相 至對掌性層列C相之該慢冷過程(從75〇c至4(Γ(:)中,施加 +/-2 V、頻率500 Hz之三角波電壓。面板溫度到達4〇<t 〇 後,將施加之三角波電壓提高至+/-10V。之後藉由自然冷 部,持續施加直到面板溫度到達室溫。該面板之初期分子 配向方向,雖於大部分之視野下與摩擦方向相同,但在極 其受限之面中出現+/_2〇度之摩擦角偏差。 • 本製造例中,可發現慢冷階段下之過大電壓施加使得初 期FLC分子配向降低。例如,以表示層列A相之溫度,施 加+/-5 V左右之電壓後,沿摩擦方向出現斑紋狀之配向缺 陷。—旦發生該類型之缺陷,對掌性層列c相(強介電性液 〇 晶相)不排除有缺陷。雖慢冷下之電壓施加是有效的,但 該條件應被嚴格控制。於該等之製造例中,於以下情況下 可侍到良好之結果故為較好:於層列入為i ν/μ1Ώ以下,從 層列Α相至手性SmC相之轉移溫度之1〇t下為丨5 以 — 下,從相轉移溫度至2(TC下為5 ν/μηι以下,比其低之溫度 範圍下為7.5 V/μιη以下。 製造例3 對於液晶分子配向膜用,使用RN_1199(日產化學工業) 作為l〜i.5。之預傾角配向物質。將作為硬化層之配向層之 142774.doc -25- 201107822 厚度設定為6500A〜7000A。將該硬化配向層之表面藉由縲 縈布’以相對於如圖12所示之基板之中心線成3〇度之角度、 之方式摩擦1擦之壓人量’於兩基板均為Μ咖。作為 間隔件使用平均粒徑為丨.8微米之二氧化矽粒子。完成之 胞間隙測定值為2.0微米。於該胞中,將記載於文獻Crystals" Tayl or and Francis: 1998 'London, England; Chapter 8 and Chapter 9. Manufacturing example 2 mm. For the liquid crystal molecular alignment film, RN-1199 (Nissan Chemical Industries Co., Ltd.) was used as a pretilt alignment material of 1 to 1.5 °. The thickness of the alignment layer as the hardened layer was set to 6500A to 7000A. The surface of the hardened alignment layer was rubbed by the Rayon cloth at an angle of 3 degrees with respect to the center line of the substrate as shown in Fig. 12. The amount of friction intrusion was 〇5 I42774.doc -24- 201107822 on both substrates. As the spacer, cerium oxide particles having an average particle diameter of 丨.6 μm were used. The measured cell gap was 1 _ 8 microns. In this cell, a commercially available FLC mixture material (Merck: ZLI-4851-100) was used at 110. (The temperature is aliquoted. After injecting the mixed material, control the ambient temperature and slowly cool it at a ratio of 丨 minute .. The 171 ^ material is brought to the surface of the ferroelectric liquid crystal (40. 〇. To the slow cooling process of the C phase of the palm layer (from 75〇c to 4 (Γ(:), apply a +/-2 V, frequency 500 Hz triangular wave voltage. The panel temperature reaches 4〇<t 〇 After that, the applied triangular wave voltage is increased to +/-10 V. Then, the natural cold portion is continuously applied until the panel temperature reaches room temperature. The initial molecular alignment direction of the panel is the same as the rubbing direction in most of the field of view. However, the friction angle deviation of +/_2 〇 is present in the extremely limited surface. • In this manufacturing example, it is found that excessive voltage application in the slow cooling phase causes the initial FLC molecular alignment to decrease. For example, to represent the smectic phase A phase The temperature, after applying a voltage of about +/- 5 V, there is a streaky alignment defect along the rubbing direction. Once this type of defect occurs, the c-phase (strong dielectric liquid twin phase) of the palm layer is not Excludes defects. Although the voltage application under slow cooling is effective, The parts should be strictly controlled. In these manufacturing examples, good results are obtained in the following cases: it is better to be included in the layer below i ν / μ1 ,, from 层 Α phase to chiral SmC phase The transfer temperature is 1 〇t at 〇5, and from the phase transfer temperature to 2 (5 ν/μηι or less at TC, and 7.5 V/μηη or less in the lower temperature range. Production Example 3 For Liquid Crystal For molecular alignment film, use RN_1199 (Nissan Chemical Industry Co., Ltd.) as the pretilt alignment material of l~i.5. Set the thickness of 142774.doc -25-201107822 as the alignment layer of the hardened layer to 6500A~7000A. The surface of the alignment layer is rubbed by the rubbing fabric at an angle of 3 degrees with respect to the center line of the substrate as shown in FIG. 12, and both substrates are used as the spacer. The cerium oxide particles having an average particle diameter of 丨.8 μm were used. The calculated cell gap was 2.0 μm. In this cell, it will be described in the literature.

Molecular Crystals and The liquid crystals ; r Naphthalene BaseMolecular Crystals and The liquid crystals ; r Naphthalene Base

Ferroelectric liquid crystal and Its Electro Optical Properties j ;Ferroelectric liquid crystal and Its Electro Optical Properties j ;

Vol.243,pp.77_pp.90,(1994)之萘系 FLC混合物材料於丨3〇〇c 溫度等分注入。該液晶材料在室溫下之螺旋間距為25 mm 〇 注入液晶材料後,控制周邊溫度’以丨分鐘丨它之比例從 130°C慢慢冷卻至呈現強介電性液晶相之5〇r。從層列八相 冷卻至對掌性層列c相之該慢冷過程(9(rc至5〇。(:)中,施 加+/-1 V、頻率500 Hz之三角波電壓。面板溫度到達5〇<t 後,將施加之三角波電壓提高至+/_7 V。之後藉由自然冷 卻’持續施加直至面板溫度到達室溫。該面板之初期分子 配向方向’於大部分之視野面中與摩擦方向相同。只有極 小面可見到與摩擦角之+/_17度之偏差。該面板之電氣應答 測定’作為以偏光顯微鏡測定下之2〇倍左右之視野範圍之 平均’顯示類比灰階開關。於本製造例中又發現,慢冷期 間之施加電壓並非限定於三角波,即使是正弦波、矩形波 亦可有效使平行於摩擦方向之初期分子配向穩定化。 將前述製造例中所得到之結果整理於以下之表1。 製造例之摘要 142774.doc -26· 201107822 [表l] 光感 受性 配向條件 電壓施加條件 實施例 基本FLC 純粹 配向膜 摩擦 溫度慢 物質 材料 傾角 厚度 壓入量 冷速度 古 肉 /JEL 低溫 (度) (A) (mm) fc/分) 製造例1 有 ZLI-4851-100 1 5000 0.5 2 無 土 10V、 500 Hz、 三角波 比較製造例1 有 ZLI-4851-100 1 200 0.5 2 無 土 10V、 500 Hz、 三角波 比較製造例2 有 ZLI-4851-100 1 5000 0.1 2 無 ±10V、 500 Hz、 三角波 製造例2 無 ZLI-4851-100 1 7000 0.5 1 士2 V、 ±10V、 500 Hz、 500 Hz、 三角波 三角波 比較製造例3 有 ZLI-4851-100 1 5000 0.5 5 無 ±10V、 500 Hz、 三角波 比較製造例4 無 ZLI-485 Μ 00 1 7000 0.1 1 士2 V、 土 10 V、 500 Hz、 500 Hz > 三角波 三角波 比較製造例5 無 ZLI-4851-100 1 200 0.1 1 士2 V、 土 10V、 500 Hz、 500 Hz、 三角波 三角波 比較製造例6 無 ZLI-4851-100 I 200 0.5 1 士2 V、 ±10 V、 500 Hz、 500 Hz ' 三角波 三角波 比較製造例7 有 ZLI-4851-100 6.5 5000 0.5 2 無 士 10V、 500 Hz ^ 三角波 比較製造例8 有 ZLI-4851-100 6.5 200 0.5 2 無 土 10V、 500Hz ' 三角波 比較製造例9 有 ZLI-4851-100 6.5 5000 0.1 2 無 土 10V、 500 Hz、 三角波 製造例3 無 萘 1 7000 0.6 1 ±1 V、 土7 V、 500 Hz、 500 Hz、 三角波 三角波 比較製造例10 無 萘 600 0.2 1 土1 V、 ±7V、 500 Hz > 500Hz、 三角波 三角波 比較製造例11 無 萘 7000 0.2 土1 V、 土7 V、 500 Hz、 500 Hz、 三角波 三角波 比較製造例12 無 萘 7000 0.6 3 無 ±7 V、 500 Hz、 三角波The naphthalene-based FLC mixture material of Vol. 243, pp. 77_pp. 90, (1994) is aliquoted at a temperature of 丨3〇〇c. The liquid crystal material has a spiral pitch of 25 mm at room temperature. After the liquid crystal material is injected, the peripheral temperature is controlled to slowly cool from 130 ° C to 5 〇r which exhibits a strong dielectric liquid crystal phase. From the slab eight-phase cooling to the slow cooling process to the palm phase c-phase (9 (rc to 5 〇. (:), apply a +/-1 V, frequency 500 Hz triangular wave voltage. Panel temperature reaches 5 After 〇<t, increase the applied triangular wave voltage to +/_7 V. Then continue to apply by natural cooling until the panel temperature reaches room temperature. The initial molecular alignment direction of the panel is in most of the field of view and friction The direction is the same. Only the very small surface can be seen to deviate from the friction angle by +/_17 degrees. The electrical response of the panel is measured as 'average of the field of view range of about 2 times as measured by a polarizing microscope'. In the present manufacturing example, it has been found that the applied voltage during the slow cooling period is not limited to the triangular wave, and even the sine wave or the rectangular wave can effectively stabilize the initial molecular alignment parallel to the rubbing direction. Table 1 below. Summary of Manufacturing Example 142774.doc -26· 201107822 [Table 1] Photoreceptive alignment condition voltage application condition Example Basic FLC Pure alignment film friction temperature slow substance Material Inclination Thickness Pressing Rate Cold Rate Ancient Meat/JEL Low Temperature (degrees) (A) (mm) fc/min) Manufacturing Example 1 ZLI-4851-100 1 5000 0.5 2 Soilless 10V, 500 Hz, Triangle Wave Comparison Manufacturing Example 1 There are ZLI-4851-100 1 200 0.5 2 soilless 10V, 500 Hz, triangular wave comparison manufacturing example 2 ZLI-4851-100 1 5000 0.1 2 No ±10V, 500 Hz, triangular wave manufacturing example 2 No ZLI-4851-100 1 7000 0.5 1 ± 2 V, ±10V, 500 Hz, 500 Hz, triangular wave triangular wave comparison Manufacturing example 3 ZLI-4851-100 1 5000 0.5 5 No ±10V, 500 Hz, triangular wave comparison Manufacturing example 4 No ZLI-485 Μ 00 1 7000 0.1 1 ± 2 V, soil 10 V, 500 Hz, 500 Hz > Triangle wave triangular wave comparison manufacturing example 5 No ZLI-4851-100 1 200 0.1 1 ± 2 V, soil 10V, 500 Hz, 500 Hz, triangular wave Triangle wave comparison manufacturing example 6 No ZLI-4851-100 I 200 0.5 1 ± 2 V, ±10 V, 500 Hz, 500 Hz 'Triangular wave triangular wave comparison manufacturing example 7 ZLI-4851-100 6.5 5000 0.5 2 None 1 0V, 500 Hz ^ Triangle wave comparison manufacturing example 8 ZLI-4851-100 6.5 200 0.5 2 Soilless 10V, 500Hz 'Triangular wave comparison manufacturing example 9 ZLI-4851-100 6.5 5000 0.1 2 Soilless 10V, 500 Hz, triangular wave manufacturing Example 3: No naphthalene 1 7000 0.6 1 ±1 V, soil 7 V, 500 Hz, 500 Hz, triangular wave triangular wave comparison manufacturing example 10 naphthalene-free 600 0.2 1 soil 1 V, ±7 V, 500 Hz > 500 Hz, triangular wave triangular wave comparison manufacturing Example 11 No naphthalene 7000 0.2 Soil 1 V, soil 7 V, 500 Hz, 500 Hz, triangular wave triangular wave comparison Manufacturing Example 12 No naphthalene 7000 0.6 3 No ±7 V, 500 Hz, triangular wave

關於以上態樣所說明之構成、配置關係等僅係可理解、 實施本發明之程度而例示者。因此本發明並非局限於所說 •27 142774.doc 201107822 明之態樣者,在不脫離專利請求範圍所示之技術性思想之 範圍内可變更為各種各樣之形態。 產業上之利用可能性 如前所述,本發明之偏光開關元件,具有可容易地得到 穩定之應答之優秀特徵。因&,本發明之偏光開關元件, 亦可容易地賦予較好之消光比。 穩定之應答 於觀看立體 於觀看立體The configurations, arrangement relationships, and the like described in the above aspects are merely illustrative of the extent to which the invention can be understood and implemented. Therefore, the present invention is not limited to the above-described embodiments, and may be varied in various forms without departing from the scope of the technical idea shown in the scope of the patent claims. Industrial Applicability As described above, the polarizing switch element of the present invention has an excellent feature that a stable response can be easily obtained. The polarizing switch element of the present invention can easily impart a good extinction ratio because of & Stable response to viewing stereoscopic viewing stereo

本發明之偏光開關元件,基於前述特徵(即 及/或較好之消光比),既可適宜利用於作為用 影像之偏光開關元件,亦可適宜利用於作為用 影像之投影機及電視。 【圖式簡單說明】 圖1係表示本發明之態樣之偏光開關 • 1丁 <棋式剖面 圖2係表示本發明之態樣 〜rr <侷光狀態檢 測部之框構成圖; 圖3係表示本發明之態樣之偏光開 之框構成; 件之電壓控制部 圖4係表示本發明之態樣之偏光開 之控制部之框構成圖; 件之電壓控制部 圖5係說明偏光開關元件之動作之圖; 圖6係說明偏光開關元件之動作之圖; 圖7係表示本發明之態樣之投影機之模式剖面圖· 圖8係表示本發明之態樣之電視之模式剖面圖. 圖9係表示三角波電壓施加 ’ 广刀于配向開關之間之分 142774.doc -28- 201107822 極開關電流之例之圖; 圖10係表示先前之SSFLCD面板之情形中開關之間之分 極開關峰值電流之例之圖; 刀 . 圖U(a)〜(e)係用於說明PS-V-FLCD之c_指向矢資料之楔 , 式圖; ' 圖12係用於說明積層面板之摩擦角之模式圖;及 圖13係表示本發明中可使用之適合光學軸方位之嚴密測 D 定之要素之一例之構成之模式立體圖。 【主要元件符號說明】 10 偏光開關元件 11、12 透明基板 13、14 透明電極 15、16 液晶配向膜 17 密封材 19 間隔構件 21 液晶材料 22 偏光狀態檢測部(感測器) 23 電壓控制部 24 反饋機構 31、32 偏光板 33、34 光檢測器 41 感測器信號檢測部 42 電壓輸出部 43 輸入裴置 142774.doc -29- 201107822 44 控制部 60 投影機 70 電視 80 PMT 81 不波益 82 PSS-LCD 胞 83 偏光片 84 背光 85 機能發電機 142774.doc -30-The polarizing switch element of the present invention can be suitably used as a polarizing switch element as an image based on the above characteristics (i.e., and/or a good extinction ratio), and can be suitably used as a projector and a television as an image. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a view showing a configuration of a polarizing switch according to an aspect of the present invention. FIG. 2 is a block diagram showing a state of the present invention. 3 is a frame structure of a polarized light according to the aspect of the present invention; FIG. 4 is a block diagram showing a control unit of a polarized light according to the aspect of the present invention; and a voltage control unit of the device is shown in FIG. FIG. 6 is a view showing the operation of the polarizing switch element; FIG. 7 is a schematic sectional view showing the projector of the aspect of the present invention. FIG. 8 is a schematic sectional view showing the aspect of the television of the present invention. Fig. 9 is a diagram showing an example of a triangular switching voltage application 142774.doc -28-201107822 pole switching current between the directional switches; Fig. 10 is a diagram showing the polarization between the switches in the case of the prior SSFLCD panel. Diagram of the peak current of the switch; knife. Figures U(a) to (e) are used to illustrate the wedge of the c_directional data of the PS-V-FLCD, and the figure is shown; ' Figure 12 is used to illustrate the laminated panel. Schematic diagram of the friction angle; and FIG. 13 shows that it can be used in the present invention. A stereoscopic view of a configuration suitable for one of the elements of the optical axis orientation. [Description of main component symbols] 10 Polarizing switch elements 11, 12 Transparent substrates 13, 14 Transparent electrodes 15, 16 Liquid crystal alignment film 17 Sealing material 19 Spacer member 21 Liquid crystal material 22 Polarized state detecting portion (sensor) 23 Voltage control portion 24 Feedback mechanism 31, 32 polarizing plate 33, 34 photodetector 41 sensor signal detecting portion 42 voltage output portion 43 input device 142774.doc -29-201107822 44 control unit 60 projector 70 TV 80 PMT 81 not wave benefit 82 PSS-LCD Cell 83 Polarizer 84 Backlight 85 Function Generator 142774.doc -30-

Claims (1)

201107822 七、申請專利範圍: i -種偏光開關元件’其特徵在於,其係至少具備 者: 於各自之表面上具有透明電極之一對透明基板; 配置於該一對透明基板間之液晶材料; 介以剛述一對透明電極對前述液晶材料施加電壓之電 壓施加機構;及 設於前述一對透明基板之光出射側之偏光狀態檢測機 構;且 基於來自前述偏光狀態檢測機構之信號對前述電壓施 加機構之反饋,而調整來自前述電壓施加機構對前述液 晶材料施加之電壓。 2. 如請求項1之偏光開關元件,其中前述液晶材料係由分 極遮蔽型層列液晶或強介電性液晶構成。 3. 如請求項1或2之偏光開關元件,其中藉由對前述液晶材 料施加電壓’使從一對透明基板之光入射側入射之光之 第1偏光狀態改變成與該第1偏光狀態不同之第2偏光狀 態。 4. 如請求項3之偏光開關元件,其中藉由調整對前述液晶 材料之施加電壓,維持並輸出前述第1偏光狀態之光。 5 ·如請求項3之偏光開關元件,其中前述第1偏光狀態係直 線偏光,前述第2偏光狀態係使前述直線偏光之振動面 90°迴轉之直線偏光。 6.如請求項4之偏光開關元件’其中前述第1偏光狀態係直 142774.doc 201107822 線偏光’則述第2偏光狀態係使前述直線偏光之振動面 90°迴轉之直線偏光。 7·如請求項1或2之偏光開關元件,其中前述偏光狀態檢測 機構至少具備1個偏光機構及檢測透過該偏光機構之光 之強度之光檢測器。 8.如請求項1或2之偏光開關元件,其中前述電壓施加機構 係具備:檢測來自前述偏光狀態檢測機構之信號之威測 器信號檢測機構;輸入指定偏光狀態之命令之輸入機 構;基於藉由前述輸入機構所輸入之命令與藉由感測器 信號檢測機構所檢測之信號,而決定對前述液晶施加之 電壓之控制機構;及基於來自前述控制機構之信號而 對Θ述透明電極施加電壓之電壓輸出機構。 9如叫求項8之偏光開關元件,其中前述控制機構具備記 憶機構;於該記憶機構中記憶控制程式,在維持並輸出 則述第1偏光狀態之光之情形下,該控制程式係以使來 自前述偏光狀態檢測機構之信號強度成為最大之方式, 决疋對前述透明電極施加之電壓值,並將用於該電壓輸 出之信號傳輸至前述電壓輸出機構。 10. 一種投影機,其特徵在於,其係至少包含以下者:用於 顯不所輸入之影像信號之空間光調變元件、照明光學系 =、光學單元、用於將通過該光學單元之光擴大投射之 投影光學系統,及空間光調變元件; 月J迷光學單疋包含偏光開光元件;且該偏光開關元件 係如請求項1或2之偏光開關元件,其至少具備: 142774.doc 201107822 於各自之表面上具有透明電極之一對透明基板;配置 於5亥一對透明基板間之液晶材料;介以前述一對透明電 極對則述液晶材料施加電壓之電壓施加機構;及設於前 述一對透明基板之光出射侧之偏光狀態檢測機構;且, • 基於來自前述偏光狀態檢測機構之信號對前述電壓施加 機構之反饋,而調整來自前述電壓施加機構對前述液晶 材料施加之電壓。 〇 u.種電視,其特徵在於:其係至少包含用於顯示所輸入 之影像信號之顯示裝置及偏光開關元件者; 月’J述偏光開關元件係如請求項丨或2之偏光開關元件, 其至少具備: 於各自之表面上具有透明電極之一對透明基板;配置 • 於該:對透明基板間之液晶材^介以前述-對透明電 極對前述液晶材料施加電壓之電壓施加 述—對透明基板之光出射側之偏光狀態檢測機構 〇 基於來自前述偏光狀態檢測機構之信號對前述電壓施加 機構之反饋,而調整來自前述電壓施加機構對前述液晶 材料施加之電壓。 142774.doc201107822 VII. Patent application scope: i-type polarizing switch element' is characterized in that it has at least one of: a transparent substrate having one transparent electrode on each surface; a liquid crystal material disposed between the pair of transparent substrates; a voltage application mechanism for applying a voltage to the liquid crystal material with a pair of transparent electrodes; a polarization state detecting means provided on a light exit side of the pair of transparent substrates; and a voltage based on a signal from the polarization state detecting means The feedback from the mechanism is applied to adjust the voltage applied from the aforementioned voltage applying mechanism to the liquid crystal material. 2. The polarizing switch element of claim 1, wherein the liquid crystal material is composed of a polarization shielding type smectic liquid crystal or a ferroelectric liquid crystal. 3. The polarizing switch element according to claim 1 or 2, wherein a first polarization state of light incident from a light incident side of the pair of transparent substrates is changed to be different from the first polarization state by applying a voltage ' to the liquid crystal material The second polarization state. 4. The polarizing switch element of claim 3, wherein the light of the first polarized state is maintained and output by adjusting an applied voltage to the liquid crystal material. The polarization switching element according to claim 3, wherein the first polarization state is linearly polarized, and the second polarization state is linearly polarized by 90° rotation of the linearly polarized vibration surface. 6. The polarizing switch element of claim 4, wherein the first polarization state is straight 142774.doc 201107822 linearly polarized light, wherein the second polarization state is a linearly polarized light that rotates the vibration plane of the linearly polarized light by 90°. The polarizing switch element according to claim 1 or 2, wherein the polarization state detecting means includes at least one polarizing means and a photodetector for detecting the intensity of light transmitted through the polarizing means. 8. The polarizing switch element of claim 1 or 2, wherein the voltage applying mechanism comprises: a detector signal detecting means for detecting a signal from the polarized state detecting means; and an input means for inputting a command for specifying a polarized state; a control mechanism for determining a voltage applied to the liquid crystal by a command input by the input means and a signal detected by the sensor signal detecting means; and applying a voltage to the transparent electrode based on a signal from the control means Voltage output mechanism. 9. The polarizing switch element of claim 8, wherein the control means comprises a memory means; wherein the memory means stores a control program for maintaining and outputting the light of the first polarization state, wherein the control program is The signal intensity from the polarization state detecting means is maximized, and the voltage value applied to the transparent electrode is determined, and a signal for the voltage output is transmitted to the voltage output means. 10. A projector, characterized in that it comprises at least: a spatial light modulation element for displaying an input image signal, an illumination optical system, an optical unit, and light for passing the optical unit The projected projection optical system and the spatial light modulation component; the moonlight optical unit comprises a polarizing light-emitting element; and the polarizing switch element is the polarization switching element of claim 1 or 2, which has at least: 142774.doc 201107822 a transparent substrate having a transparent electrode on each surface; a liquid crystal material disposed between a pair of transparent substrates; and a voltage applying mechanism for applying a voltage to the liquid crystal material via the pair of transparent electrode pairs; a polarization detecting mechanism of the pair of transparent substrates on the light exit side; and: adjusting a voltage applied from the voltage applying means to the liquid crystal material based on feedback from the voltage applying means from a signal from the polarized state detecting means. The television is characterized in that it comprises at least a display device for displaying an input image signal and a polarization switching element; and the polarized switching element of the month is a polarization switching element of the request item 2 or 2, The method has at least: a pair of transparent electrodes having transparent electrodes on the respective surfaces; and the arrangement: the liquid crystal material between the transparent substrates is subjected to the aforementioned voltage application to the transparent electrode to apply a voltage to the liquid crystal material The polarization state detecting means on the light exit side of the transparent substrate adjusts the voltage applied from the voltage applying means to the liquid crystal material based on the feedback from the voltage applying means from the signal from the polarization state detecting means. 142774.doc
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