201107236 六、發明說明： 【發明所屬之技術領域】 本發明係-種奈純管的複合材料及其製造方法，該方法係使奈 米石炭管原本呈緊密_的線狀結構舒展開來，且在已展開的線狀結構 中填充及附著氧化鋅奈米粒子及二氧切奈米粒子，使得所製成的複 合材料中奈米碳管的線狀結構，不再因二次團聚，而緊密糾纏在一起， 以有效增加該複合材料中奈米碳管的材料均勻性、導電及散熱等特 性，且大幅減少每一單位複合材料中奈米碳管的含量。 【先前技術】 目前，奈米碳管依其結構特徵，主要分成單壁恤扯,腕carb〇n nanotubes，簡稱SWNTs)與多壁(multi_walled⑽⑽騰伽⑹，簡稱 MWNT柏大類’料奈㈣f在製糾程巾可能集結成束 (bundle) ’且每-層都可被視為呈捲曲無缝中空管狀的石墨烯 (graphene) ’參目第1圖所示，且有著不同的螺旋向量c/+购 (cWral vector) ’其中αι、α2是石墨稀的單位向量，一般以⑴，叫來表 不每-單層的捲曲方向。另，根據奈米碳管中碳六邊形沿管轴的偏向 (orientation) ’奈求碳管尚可區分成下列三種結構，參閱幻圖所示： ⑴若m=n，參閱第2⑻圖所示，（n，n胸爯為扶椅型(_冰邮奈米碳 管； ⑺若㈣，參閱第2刚所示，(n,〇)被稱為鑛齒型㈤興)奈米碳管； 及 (3)其他(n，m)則被稱為螺旋型(chir論㈣奈米碳管，參閱第2⑻圖所 201107236 示0 此外，奈米碳管的許多特性與該螺旋向量息息侧，以導電特性 _，-個(n，m)的單壁奈米碳管，若2n + m = 3q (q為整數），.則 見金屬特f生硕，即呈現半導體特性。因此，所有扶椅 呈現金屬導電特性哪，㈣，t晴單壁奈米碳管 的體特性。至於’多壁奈米碳管則可被視為係由不同管徑 '丁、未妷g，以共官軸的方式，多層組合而成。 螺旋=論奈米碳管係單壁或多壁結構，或為扶椅型、鑛齒型或 一 4奴官結構均可被視為—個準-維的線狀材料，且係以任 二，形成—緊密賴線狀結構’蝴3圖所示，係一 ===!：=#碳管錢鮮付崎下呈現的緊 表面/ t為奈米碳管具備質量輕、高強度、高韋刃性、高 今，-二:=Γ等優異的材料特性，故自1991年被發現迄 用潛力。= 力研究的—重要材料，具有極高的應 中，製作出已有業者試圖將奈米碳管添加且均勻混合至塗料 作出各式導電塗料或抗靜電塗料’以期將 獅，綱輪物咖靡繼 缠的線狀㈣。惟’誠如歧，㈣奈米碳聽-呈緊密糾 或抗靜奈米奸被添加至_中’製作成各式導電塗料 導電或抗料電麟祕静綠触無法達成預期的 等導電塗料’鮮為_此一錄’乃細增加奈米碳管在該 科或抗㈣塗料中的含量，以期提高其導電或抗靜電特性， 2〇1107236 =，=:法，不僅導致製作成本居高不下，亦因奈米碳管的含量較 :及八緊密糾纏的線狀結構與彼此間的團聚效應，而在 ^率較差、透光林均勻、_厚度不—及塗 =題=成相關產品良率大幅降低，進而對奈米碳管在此一領= 應用，形成了一道難以突破的障礙。 ^ ’辦設·-種翻秘米碳管複合娜，使得 米妙的線狀結構得崎展開來，料會因二次團聚，而再次 雜在-起’財效增加該複合材料中奈米碳管的材料均勾性、 ^及散熱料性，且大幅減少每—單位複合材料中奈米碳管的含 里，即成為本發明在此欲探討的一重要課題。 【發明内容】 有紐前述傳統奈米碳管在塗料應用領域發生的諸多問題，發明 人經過長久努力研究與實驗，終於開發設計出本發明的—齡米碳管 ====其製造方法，以該複合材料时米碳管的線狀結構 付以舒制來，而大幅減少該複合材射奈雜管的含量，且有效增 加該複合材料中奈米碳管的材料均勻性、導電及散熱等特性。曰 、本發明之-目的，係在提供—縣米碳管的複合材料及其製造方 法’該方法係將奈米碳管粉末與酒精，添加至一超音波振靈麟機， ’使得奈米碳管原本呈緊密糾纏的線狀結構能 在酒精中舒展開來，且均勾地分散在酒精中，形成黏稠狀之酒精溶 液，在該酒精溶液中添加氧化辞奈米粒子的分散液，該分散液係由 201107236 水、水溶性壓克力粉末、水溶性黏著劑及氧化鋅奈米粒子等成份，均 勻混合而成的水溶液，其中該水溶性壓克力粉末係一水溶性分散劑， 其作用係在溶解於水中後，能在後續的超音波振蓋及授拌過程中，使 氧化鋅奈米粒子及奈米碳管均勻且分散地懸浮在酒精溶液中，該水溶 性#著劑的作用係在氧化鋅奈米粒子被混合入該水溶液時，能均勾披 覆在氧化鋅奈米粒子的表面上；嗣，繼續進行超音波振盪及授拌，俟 攪拌均勻後’氧化辞奈米粒子會均勻地填充且附著至每一奈米碳管已 _舒展開的線狀結構中，使得每一奈米碳管的線狀結構能維持在大幅展 開的狀態；最後，以過濾裝置對酒精溶液進行過濾後，再施以烘乾處 理並對元全烘乾後所獲得的材料進行機械性的粉碎處理，即能得到 奈米碳管的複合材料。此時，由於該複合㈣巾每—奈米碳管已展開 的線狀結構巾均觀及崎有氧化·錄子，如此，將使其線狀結 構不會再次目聚驗態，除能有效增加該複合材射奈米碳 nr4均勻性、導電及散鮮特性外，雜大幅減少每—單位複合 機物的^碳㈣含量，錢透過氧化鋅奈餘子，實現對病菌等有 實驗^g ’使其具備長效麵__自潔能力。經 cl ；；Γ (如.Μ克力樹脂)_，將使該塗料且 薄臈電阻咖价_—，當年_/平方(—一-)的 料具備1〇-_/平方的薄膜ir、添加夏至12〇/〇或抓，將使該塗 血糖劑電極上料㈣料，或=降合作為觸控面板、 塗料具備109~】1歐姆/平方的 _，、+加I至5%以下，以使該 裝、抗靜電包裝材料塗裝的抗靜=使^塗料適合作為無塵室塗 且均具有長效型抗菌防黴的 201107236 自潔能力。 本發明之另―目的’係在提供—種奈米碳管的複合材料及其製造 機，造該=線奈米碳㈣編精’添加至—超音波振賴拌 構^丁振4及擾掉’使得奈米碳管原本呈緊密糾纏的線狀結 籌it 開來，形麟雛之酒精職；在_精溶液中添 =:的分紐:該分散液係由水、氯化辞粉末、水溶性壓克力粉 夫呈L碰黏者鮮成份，均勾混合而成的水溶液，其中該氯化鋅粉 、有可完全溶雜水额，域在水溶财_鱗料的特性， 2鋅=子具有親乳的活性’極易與奈米碳管林純物的金屬氧化物 理吸附，且均勾地附著在奈米碳管的表面上，該水溶性201107236 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a composite material of a neat tube and a method for producing the same, which is a method in which a nano-carbon tube is originally stretched and has a linear structure, and The zinc oxide nano particles and the dioxon nanoparticles are filled and adhered in the unfolded linear structure, so that the linear structure of the carbon nanotubes in the prepared composite material is no longer tight due to secondary agglomeration. Entangled together to effectively increase the material uniformity, conductivity and heat dissipation characteristics of the carbon nanotubes in the composite material, and greatly reduce the content of carbon nanotubes in each unit of composite material. [Prior Art] At present, the carbon nanotubes are mainly divided into single-walled shirts, wrist carb〇n nanotubes (referred to as SWNTs) and multi-walled (multi_walled(10)(10) Tengga (6), referred to as MWNT cypress class 'materials (four) f in accordance with their structural characteristics. The correction wipes may be bundled 'bundle' and each layer can be considered as a graphene with a curly, seamless hollow tubular shape as shown in Figure 1, with different spiral vectors c/+ (cWral vector) 'where αι, α2 are graphite thin unit vectors, generally (1), called to indicate the direction of the curl of each-single layer. In addition, according to the carbon hexagon in the carbon nanotubes along the tube axis (orientation) 'The carbon tube can be divided into the following three structures, as shown in the magic map: (1) If m=n, see Figure 2(8), (n, n chest is a chair type (_冰邮奈(6) If (4), as shown in the second, (n, 〇) is called the mineral tooth type (5) Xing) carbon nanotubes; and (3) other (n, m) is called the spiral type (Chir (4) carbon nanotubes, see Fig. 2(8), 201107236 shows 0. In addition, many characteristics of the carbon nanotubes and the spiral vector are closely related to the conductive properties _ - (n, m) single-walled carbon nanotubes, if 2n + m = 3q (q is an integer), then see the metal characteristics, that is, the semiconductor characteristics. Therefore, all the chair presents metal conductive properties (4), the physical characteristics of t-single-walled carbon nanotubes. As for the 'multi-walled carbon nanotubes', it can be regarded as a combination of different diameters, 'd, not g, in a common axis, multi-layer combination Spiral = On the carbon nanotube system single-wall or multi-wall structure, or for the chair type, mineral tooth type or a 4 slave structure can be regarded as a quasi-dimensional linear material, and In any two, the formation - close to the line structure 'Butter 3', shown as a ===!:=# carbon tube money to pay for the tight surface / t for the carbon nanotubes with light weight, high Strength, high-definition, high-rise, -2:=Γ, and other excellent material properties, so it has been discovered since 1991. The strength of the research - important materials, has a very high response, has produced The industry is trying to add and evenly mix the carbon nanotubes to the coating to make various conductive coatings or antistatic coatings, in order to tie the lions and stalks to the line (4). (4) Nano-carbon listening - is closely entangled or anti-static glutinous rice is added to _ in the 'making a variety of conductive coatings conductive or anti-material electric Lin secret green touch can not achieve the expected conductive paint 'fresh _ this one Recording 'is fine to increase the content of carbon nanotubes in the section or anti-(four) coatings, in order to improve its conductive or anti-static properties, 2〇1107236 =, =: method, not only leads to high production costs, but also because of nano The content of the carbon tube is relatively lower than that of the eight closely entangled linear structures and the agglomeration effect between them, and the yield is poor, the uniformity of the light-transmissive forest, the thickness of the coating is not reduced, and the yield of the relevant product is greatly reduced. The application of carbon nanotubes in this collar has created an obstacle that is difficult to break through. ^ 'Settings · - Kind of secret rice carbon tube composite Na, so that the Mi Mi's linear structure is unfolding, and it is expected to be mixed again due to secondary agglomeration - increase the nanometer in the composite material The material of the carbon tube is hooked, ^ and heat-dissipating, and the inclusion of the carbon nanotubes in each unit of composite material is greatly reduced, which is an important subject of the present invention. SUMMARY OF THE INVENTION In view of the many problems that have occurred in the application field of the conventional conventional carbon nanotubes, the inventors have finally developed and designed the carbon nanotubes of the present invention ==== the manufacturing method thereof after long-term efforts and experiments. When the composite material is used, the linear structure of the carbon nanotubes is relaxed, and the content of the composite material is greatly reduced, and the material uniformity, conduction and heat dissipation of the carbon nanotubes in the composite material are effectively increased. And other characteristics.曰, the object of the present invention is to provide a composite material of a county carbon tube and a manufacturing method thereof. The method is to add a carbon nanotube powder and an alcohol to an ultrasonic sonic machine, 'making nano The carbon tube originally has a tightly entangled linear structure which can be stretched out in the alcohol, and is dispersed in the alcohol to form a viscous alcohol solution, and a dispersion of the oxidized smectite particles is added to the alcohol solution. The dispersion is an aqueous solution obtained by uniformly mixing 201107236 water, a water-soluble acrylic powder, a water-soluble adhesive, and zinc oxide nano particles, wherein the water-soluble acrylic powder is a water-soluble dispersant, After being dissolved in water, the zinc oxide nanoparticles and the carbon nanotubes can be uniformly and dispersedly suspended in the alcohol solution in the subsequent ultrasonic vibrating cover and the mixing process. When the zinc oxide nanoparticles are mixed into the aqueous solution, they can all be coated on the surface of the zinc oxide nanoparticles; 嗣, continue to perform ultrasonic vibration and mixing, and stir evenly after the oxidation. The sub-mass will be evenly filled and attached to the linear structure of each nanocarbon tube, so that the linear structure of each carbon nanotube can be maintained in a state of large expansion; finally, the filter device is used for alcohol After the solution is filtered, the material is dried and subjected to mechanical pulverization treatment, and the composite material of the carbon nanotubes can be obtained. At this time, since the composite (four) towel has a linear structure towel that has been unfolded per nanocarbon tube and has an oxidized record, so that the linear structure will not be re-aggregated again, in addition to being effective. Increasing the uniformity, conductivity and dispersing characteristics of the nano-carbon nr4 of the composite material, the amount of carbon (four) per unit compound is greatly reduced, and the money passes through the zinc oxide naphtha to realize the experiment on the pathogen. 'Let it have a long-lasting surface __ self-cleaning ability. By cl;; Γ (such as Μ克力树脂) _, will make the coating and thin 臈 咖 咖 , , 当 当 当 当 当 当 当 当 当 平方 平方 平方 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备Adding the summer solstice 12 〇 / 〇 or grab, will make the blood smear electrode (4) material, or = drop cooperation for the touch panel, the paint has 109 ~ 1 ohm / square _, + + plus I to 5% or less In order to make the antistatic and anti-static packaging materials coated, the anti-static coating is suitable for use as a clean room coating and has a long-acting antibacterial and anti-mildew 201107236 self-cleaning ability. Another object of the present invention is to provide a composite material of a carbon nanotube and a manufacturing machine thereof, and to make the line nano carbon (four) compiling the 'added to-- ultrasonic wave vibrating mixing ^ Ding Zhen 4 and the disturbance "Let's make the carbon nanotubes originally tightly entangled in the form of a line-up, the alcoholic form of the stalks; the addition of = in the _ fine solution: the dispersion is made of water, chlorinated powder The water-soluble acrylic powder is an aqueous solution which is mixed with the fresh ingredients of the L-adhesive, and the mixture is mixed with the aqueous solution, wherein the zinc chloride powder has a completely soluble amount of water, and the domain is in the characteristics of water-soluble squama, 2 Zinc = sub-milk-active activity is extremely easy to physically oxidize with metal oxides of pure carbon nanotube forest, and is attached to the surface of the carbon nanotubes.
It! . S W H滅奈米碳管均社分散地懸浮在酒精溶液中，該水溶性黏 作⑽在後續的超雜振奴娜過針，能均勻披覆在辞離 子^面上，’繼續進行超音波振盪及攪拌1在該酒精溶液中添 、: <原劑’俟該還原劑與酒精溶液獅均勻後，該還原劑會在酒精 提供電子’使得鋅離子絲由取得電子，而還原成鋅奈米粒 :，在^盪及獅過程中，將更多氧氣經由空氣幫浦輸入該酒精 =’使得鋅奈米粒子能利用本身親氧的活性，與氧鍵結，進而形 ^化辞奈餘子，且·啦奈米碳㈣表面上，如此，氧 構==卩^勻地填>充且崎至每—奈米碳管已舒制的線狀結 不米石反官的線狀結構能維持在大幅展開的狀態，制， =氣及烘乾處理後，對完全峨後所獲得的材料進行機械性的粉碎 处理’即能得到奈米碳管的複合材料。此時，由於該複合材料中每— 201107236 奈米碳管已展_線狀結射均填充及畴有氧化鋅奈餘子，使得 其線狀結構能維持在大幅展開的狀態，而不會再次團聚，故货 减複錄射奈米碳管的材料均勻性、導電及散_特性，且能^ 幅減少每一單位複合材料中奈米碳管的含量。 本發明之又-目的’尚包括在制精溶射添加親水性的二氧化 石夕卜魏.雜子，使得制精溶液巾奈米碳管、氧化辞 .==奈米粒子均勻混合後，二氧切奈米粒子能均句:填充 風辛不未粒子及奈米碳管線狀結構間的縫隙中 管的咖吉構能大幅展開；嗣，經過濾及烘乾處理後，對 :獲:的材二進行機械性的粉碎處理’即能得到奈米碳管的複二 混人至’觸複合_ _量百分比均勻添加且 二：：崎’將使該塗料具備⑼歐姆/平方的 包其添加1至12%或15%，將使該塗料 、’方的馳軌，使得該餅_合作糊控 上的導雷學斗;4·,十、—丄 板企糖劑電極 歐姆/平方^ 加量至5%吓錢該塗料具備f 電阻，使得職料極適合作為無塵 包裝材料塗裝的抗靜電塗料。 $抗靜电 進一步為^4^4^麟核_目的、技轉财細效，有更 識解解，_—實施例，並配合_，_明如下 【實施方式】 按’乳化鋅料粒子具有半導體哺性，在室 ， 鋅，具有更高的導雷胜K 皿，較鬼狀氧化 V電特性。此外，氧化鋅奈米粒子也具有—種催化劑 201107236 的電子結構，因其晶粒尺寸與歧相當或D、，尺寸效 · ΐ價糾，使其光吸收能力顯著增強，因此二光照射二 •二:=電過半梅_的光子，射 從價帶激發到導:===結;中:-個電子會 洞和空氣巾的水分子⑽） 續’當電 子中氫氧基㈣子，姊過梳學反應，搶奪水分 自由 ，失去電子的魏基糊變成不錢的氫氧 (·0Η)，不安定的氫氧自由基一旦遇到外來的或附在氧化 二=上的有機物時，會藉由搶奪對方電子的方式，使自己趨於 二’如此哪有娜卩魏化，賴成水和二氧化碳，消散在* ΐ有機鋅奈米粒子能作為強氧化劑，實現對黴菌、細菌和病: ，會產_性、無紐、無繼職性及不受 “響㈣多優點，被劍於油漆、油墨、塗料及瓣等產品中， 可使產品具有長效型抗菌防黴的自潔能力。 本發明即利用氧化鋅奈米粒子的特性，而將氧化辞奈米粒子應用 =米碟管複合材料的製作過程，以使奈米碳f原本呈緊密糾纏的線 、、，。構舒展開來後，將氧化鋅奈米粒子均勻地填充及附著至已展開的 奈米碳管的線狀結射，令缝成的複合·中奈米碳管的線料 構，除不會再次團聚而緊密_在一起，以有效增加該複合材料中: 未碳管的材料均勻性、導電及散解特性，从幅減少每—單位複I 材料中奈米碳管的含量外’尚可藉附著在奈米碳管中的氧化鋅奈米二 子’使得該複合材料具備長效型抗菌防徽的自潔能力。在本發明之第 一個較佳實施例，為了使氧化鋅奈米粒子能均勻地填充及畴至奈米 201107236 碳管的線狀結構中’該實施例的製造方法包括下列步驟，參閱第4圖 所示： (401) 將奈米碳管粉末與酒精，以一預定重量百分比，如： 1:20〜1:200，添加至一超音波振盈授拌機，以一預定轉速，如： 200轉/分鐘〜5〇〇〇轉/分鐘，進行一預定時間的超音波振盪及攪 拌，如：10分鐘〜2小時，使得奈米碳管原本呈緊密糾纏的線狀 結構能在酒精中舒展開來，且均勻地分散在酒精中，形成一黏 稠狀之酒精溶液； (402) 在該’目精’谷液巾添力預定重量百分比的氧化鋅奈米粒子的分 散液’如：5%〜30%，該分散液係由水、水溶性壓克力粉末、 水溶性黏著劑及氧化鋅奈米粒子等成份，依一預定重量百分 比’均勻混合而成的水溶液’其中該水溶性壓克力粉末係一水 雜分㈣，其侧係在轉於水愤，能錢續的超音波振 盪及觀過財’使氧倾奈餘子及絲碳❾㈣且分散地 縣翻射，該水雜黏著_作用係錢化辞奈料立 子被混合入該水溶液時’能均勻披覆在氧化辞奈米粒子的表面 上； (403)繼續進行超音波振盪及解1定時間，如：丨〜8小時，俟 勻授拌後，氧化鋅奈求粒子會均勻地填充至每一奈米碳管 展開的線狀結構中，使得每—奈米碳管的線狀結構 幅展開的狀態； 、准寺在大 (404) 利用—過濾裝置_精溶錢行過紐，再細鮮 (405) 對完全烘乾類獲得的_，進行細_销理，即能得 201107236 到奈求碳管的複合材料。辦，餅該複合材射每一奈米碳 5中均填充及附著有氧化鋅奈米粒子，將使其線狀結構不會再 次團聚成緊密糾纏狀態，該奈米碳管及氧化辞奈米粒子間係存 在一預定重量比例’如：。 嗣，經發明人賴複合鄉實際躺至—轉(如：壓克力樹脂） 之製作，且在該複合材料與料均勻混合後，均勻塗佈於—板 上(膜厚：ΗΜ0㈣硬化後，對其進行導電數據的量測可知，當將該 複合材料以10%重量百分比均勻添加且混合至該塗料中將使該塗料 具備ιοό歐姆/平方的薄膜電阻，當提高其添加量至12%或15%，將使 該塗料具備10“歐姆/平方的薄膜電阻，使得該塗料極適合作為觸控 面板、血糖劑電極上的導電塗料，或藉由降低其添加量至5%以下， 以使該塗料具備f歐姆/平方的_電阻，使得該塗料極適合作為 無塵室塗裝、抗靜電包裝材料塗裝的抗靜電塗料，且均具有長效型抗 菌防黴的自潔能力。 在該第-個實關中’魏化鋅奈餘子的分散液係由水、氧化 鋅奈米粒子、水雜壓克力粉末及水雜黏著_成份，依下列的重 量百分比，均勻混合而成： (1) 水：如：去離子水或純水等，其重量百分比為5〇%〜97 6% ; (2) 氧化鋅的奈米粒子：其重量百分比為G 2%〜1G%，在該實施例中， 係先將氧化鋅研磨成奈米(nanometer)大小的粒子，丨奈米等於十億 分之1米(l〇9meter)’或奈米級大小的粒子，介於分子和次微米間 的奈米粒子，其形狀係以片狀結構為最佳，其平均厚度為2〇奈 米’平均長度為200〜400奈米； 12 201107236 ⑶水洛性壓克力粉末：其重量百分比為2%〜3〇%，其中該水溶性壓 克力粕末係一水溶性分散劑，在該實施例中，該水溶性壓克力粉 末係*丙烯生物(p〇lyacr^lic acid心办也㈣，其作用係在 溶解於水中後，能在超音波振盛及授拌過程中，使氧化鋅奈米粒 子及7Γ、米反g均勻且分散地懸浮在酒精溶液中，而不致發生沉殿 或崎結制現象，如此，該等氧化辞奈絲子始能隨水溶液順 利地滲入且填充至每一奈米碳管已舒展開的線狀結構中；及 (4)水洛性黏著劑：其重量百分比為〇2%〜1〇% ’該水溶性黏著劑係 ^以包覆在水溶液巾均勻对散的氧化鋅奈錄子的表面在該 實化例中，該水〉容性黏著劑係包含聚尿g旨樹脂仲她挪 P〇lymer)、从甲基比咯酮（N-Methyl Pyrrolidone)及三乙胺 (Liethylamme)等麟，以在氧鱗奈練子該水溶液順利地 摩入且填充至每一奈米石炭管已舒展開的線狀結構中後，能在後續 ，燥處理時’使氧化鋅奈米粒子能藉其表面所披覆的該水溶性黏 著劑’穩定地崎在每—奈米碳管已舒展開的線狀結構中，使得 ♦每-奈米礙管能保持在舒展開的結構狀態，且令氧化鋅奈米粒子 月匕與奈米石反官永久結合在一起’產生長效型抗菌防黴的效果。 在該第-個實施例中’㈣—般市售奈米碳f的平均直徑為9$ 奈米’平均長度為L5微米(即1500奈米），表面積25〇〜米平方/ 公克，其含碳量為9〇% ’且包含1()%的奸金屬氧化物，該等金屬氧 =為奈米碳管提供了金屬基及導電特性，由於氧化鋅奈米粒子上的 氧容易與奈米碳管中^純物的金騎化物提供的金屬基形成物理吸 附，故當氧靖奈練子时舰被添加妓輸級巾，且繼續進 201107236 行超音f振盤及授拌時’氧化鋅奈米粒子極易因此而均句地填充至每 奈求=已舒展開的線狀結射，且在完成烘乾處理後，藉由該水 '奋隹1ίί劑’附著在每一奈米碳管已舒展開的線狀結構中，使得每一 不米叙心保持在舒展開的雜結構狀態，而不會再次團聚成糾纏狀 態。 在本發明之第二個最佳實施例中，為了使氣化辞奈米粒子能更順 利地被填充及附著至奈米碳管的線狀結構中，該實施例的製造方法包 括下列步驟，參閱第5圖所示： (501)碳管粉末與酒精’以1:2〇〜1:2〇〇的重量百分比，添加至 超曰波振盪麟機’以200轉/分鐘〜5〇〇〇轉/分鐘的轉速，進 行1〜8小時的超音波振盪及攪拌，使得奈米碳管原本呈緊密糾 纏的線狀結構的能在酒精中舒展開來，形成一黏稠狀之酒精溶 液； (5〇2)在該酒精溶液中添加2〇%〜6〇%重量百分比的氯化辞的分散 液’该分散液係由水、氯化辞粉末、水溶性壓克力粉末及水溶 性黏著劑等成份，依-預定重量百分比，均勻混合而成的水溶 液，其中該氯化鋅粉末具有可完全溶解於水溶液，且能在水溶 液中解離出鋅離子的特性，又因鋅離子具有親氧的活性，極易 …τ'米碳管巾金屬氧化物上的氧形成物理吸附’而在後續的超 音波振4及攪拌過程中’均勻地附著在奈米碳管的表面上，該 水溶性壓克力粉末係-水溶性分散劑，其作用係在溶解於水中 後’能在後續的超音波振i及攪拌過程令，使奈米碳管均勻且 分散地懸浮在酒精溶液中，該水溶性黏著劑的作用係在後續的 201107236 超曰波振盪及攪拌過程甲，能均勻披覆在鋅離子的表面上； (5〇3)繼續進行超音波録及獅卜8树，且在缝及攪掉過程 中將還原劑添力σ至酒精溶液中，挨該還原劑與酒精溶液授 拌均勻後，該還原劑能在酒精溶液中提供電子 藉由取得奸’㈣縣料米奸,，在錄 將更夕軋氣經由空氣幫浦輸入該酒精溶液中，使得鋅奈米 粒子能利用本身親氧的活性，與氧鍵結，進而形成氧化辞夺米 φ 粒子，且逐漸附著在奈米碳管的表面上，如此，氧化鋅奈米粒 子P a均句地填充至每一奈米碳管已展開的線狀轉構中，使得 其線狀結構能維持在大幅展開的狀態； (504)以過餘置對酒精溶液進行過錢，再施以縣處理； (5〇5)對完全烘乾後所獲得的材料，進行機械性的粉碎處理，即能得 =米礙管的複合材料，此時，該複合材料中奈米碳管及氧化 辞不米粒子間係存在·〜簡的重量比例。 關在Γ第二個實施例中，該氯化辞分散液係由水、氯化鋅粉末、還 制、水,壓克力粉末及水溶性轉解成份，依下列的重量百分 比’均勻混合而成： ^ ί .如·去離子水或純水等，其重量百分比為20%〜97% ; αδ%〜4()%，娜鋅粉末具可完 於水，且能在水帽離出鋅離子的特性，又因辞離子 中金屬氧化物 :管:::r超音波振物掉過程中，均勻地附著在奈米 201107236 (3) 水溶性壓克力粉末：其重量百分比為2%〜3〇%，其中該水溶性壓 克力粉末係一水溶性分散劑，在該實施例中，該水溶性壓克力粉 末係一I丙烯酸衍生物(p〇lyacrylicacid derivative)，其作用係在溶 解於水中後，能在超音波振盪及攪拌過程中，使奈米碳管均勻且 分散地懸浮在酒精溶液中，而不致發生沉澱或淤積結塊的現象； 及 (4) 水/谷性黏者劑.其重量百分比為〇 2%〜1〇%，該水溶性黏著劑係用 以包覆在鋅離子的表面，在該實施例中，該水溶性黏著劑係包含聚 尿酯樹脂(Urethane polymer)、N-曱棊比咯酮(N-Methyl Pyrrolidone) · 及三乙胺(Triethylamine)等成份，以在後續乾燥處理時，使已形成 的氧化鋅奈米粒子能藉其表面所彼覆的該水溶性黏著劑，穩定地附 著在每一奈米碳管已舒展開的線狀結構中，產生長效型抗菌防黴的 效果。 此外，在該第二個實施例中，該還原劑在該酒精溶液中的的重量 百分比為0.5%〜1〇%，係由乙二胺四乙酸二鈉塩(EDTA 2Na)、氫氧化 卸(KOH)及碳酸氫鉀(KHC〇3))等成份，依預定的重量百分比，混合而 鲁 成的水溶液，其中乙二胺四乙酸二鈉塩在該還原劑中的重量百分比為 αΐ5%〜3% ’氫氧化鉀的重量百分比為0.08%〜1.5%，碳酸氫鉀的重量 百分比為0.3%〜6〇/〇，該還原劑能在混合溶液中提供鋅離子還原成鋅奈 米粒子所需的電子，使得鋅離子能藉由該還原劑，還原成鋅奈米粒 子’嗣’在氧氣被經由空氣幫浦輸入該酒精溶液的過程中，使鋅奈米 粒子能利用本身親氧的活性，與氧鍵結，即能逐漸在奈米碳管的表面 上形成氧化鋅奈米粒子。 16 201107236 在本發明之第三個最佳實施例中，為了使該第一及第二個最佳實 施例所製作的複合材料中奈米碳管具備更佳的材料均勾性及導電特 性’且雜=步降低每—單位複合㈣巾奈米碳管的含量，該實施例 的製造方法係在前述分散液中額外添加〇2%〜1〇%重量比的 性的二氧化石夕(或石夕烧類)奈米粒子，其形狀係以球狀結構為最佳，其 平均粒控為20奈米，表面積357米平方/公克，當在該第一及第二個 最財_之製妨財，賴分舰添加魏餘射，繼續進行 超音波縫及_處辦，該分舰巾⑽水雜壓克力粉末係能在 超音波f及觀過雜，使氧鱗奈綠子、二氧切奈絲子及 奈来碳管均勻且分散地懸浮在酒精溶液中，該水溶性黏著劑則能均句 披覆在氧鱗奈錄子及二氧化料練子表面上，使得完成超音波 .振盪及授拌後’氧化鋅奈米粒子會均勻地填充至每一奈米碳管已舒展 開的線狀!4冓中’且二氧化石夕奈米粒子會均勻地填充至氧化辞奈米粒 :及奈米碳管線狀結構_縫隙中，使得每—奈米碳管的線狀結構在 完成過濾及縣處理’能縣在最大的展開狀態，最後，錄完全棋 .乾的材料，進行機械性的粉碎處理後，即能得到奈米碳管的複合材 料’該複合材料中奈米碳管、二氧化石夕奈米粒子及氧化辞奈米粒子間 係存在25:1:4〜1:4:1的重量比例。此時，由於該複合材料中每一奈米 炭ΐ句係呈最大巾田度展開的線狀結構，且每一奈米碳管已展開的線狀 結構中均填充及瞒有氧化辞奈綠子及二氧姆奈練子，使得其 線狀結構不會發生再次圑聚，而變成緊密顺的狀L經發明人 將亥複&材料貝際應用至一塗料(如：壓克力樹脂)之製作，且在該複 合材料與該塗柄勻混合後，均勻塗佈於pvc板上(膜厚：1G〜3〇响 17 201107236 =後’對其進行導電數據的量測可知’ #將該複合材料以跳重量 勻添加且混合至該塗朴，將使該塗料具備w歐姆/米平方 材‘特=，其，特性為該第—及第二個最佳實施例所製作的複合 :的賴電阻(1G歐姆/平方）請倍，當提高其添加量至12%或 人=^該_備1G2〜3歐姆/平方的_阻，使得該塗料極適 =乍為觸控面板、血糖㈣極上料電塗料，或藉由降低其添加量至 =下^使該塗料具備心歐姆/平方的_阻，使得該塗料極 乍為無塵室塗裝、抗靜電包裝材料塗裝的抗靜電塗料，且均且有 ίΓ二•徽的咖力。因此，在該第一及第二個最佳實施例的 it杨二祕報彻_粒子，將使所製成的複合材料中 不未奴官具備更佳的材料均勻性及導電特性，且能進—步降低 位複合材料中奈米碳管的含量。 _ .按’以上所述，僅為本發_若干最佳具體實_，惟本發 =不偈限於此’任何熟悉該項技藝者在本發明領域内，可輕易兒 及的變化或修飾，皆應涵蓋在以下本發明的申請專利範圍中。^ 【圖式簡單說明】 _ 第1圖係傳統奈米碳管的螺旋向量結構示意圖； 不同類型傳統奈米礙管的結構示意圖，其中(a)為扶椅型 ’丁、反g )為錄齒型奈米碳管’（c)為螺旋型奈米碳管； 第3圖係傳統奈米碳管的線狀結構的微觀示意圖； 第4圖係本發明的第一個最佳實施例的製程示意圖；及 第5圖係本發明的第二個最佳實施例的製程示意圖。 18 201107236 【主要元件符號說明】It! The SWH carbon nanotubes are dispersed in the alcohol solution in a dispersed manner. The water-soluble adhesive (10) can be evenly coated on the surface of the ion in the subsequent super-vibration nuno, 'continue Ultrasonic oscillation and agitation 1 is added to the alcohol solution: <Original agent'俟 After the reducing agent is evenly mixed with the alcohol solution lion, the reducing agent will provide electrons in the alcohol so that the zinc ion wire is reduced by electrons. Zinc nano-grain: In the process of swaying and lion, more oxygen is input into the alcohol via the air pump = 'so that the zinc nanoparticles can utilize their own oxophilic activity to bond with oxygen, and then form Yuzi, and · Lai Nai carbon (four) on the surface, so, the oxygen structure == 卩 ^ evenly filled > filling and saki to each - the carbon nanotubes have been relaxed the line of knots of non-meter stone anti-official line The structure can be maintained in a state of large expansion, and after the gas treatment and the drying treatment, the material obtained after the complete crucible is mechanically pulverized, that is, the composite material of the carbon nanotube can be obtained. At this time, since each of the 201107236 carbon nanotubes in the composite material has been expanded and the domains are filled with zinc oxide, the linear structure can be maintained in a state of large expansion, and will not be again Reunion, the goods reduce the material uniformity, conductivity and dispersion characteristics of the carbon nanotubes, and can reduce the content of carbon nanotubes in each unit of composite material. The still-purpose of the present invention also includes the addition of a hydrophilic silica stone in the preparation of a fine spray, so that the carbon nanotubes and the oxidized water are uniformly mixed. Oxygen-cut nanoparticle can be uniformly sentenced: the cajic structure of the tube in the gap between the filling of the wind and the nano-carbon pipeline-like structure is greatly developed; 嗣, after filtering and drying, the pair: Material 2 is mechanically pulverized', that is, the quaternary mixture of the carbon nanotubes can be obtained until the 'touch compound _ _ percentage percentage is evenly added and the second:: saki' will make the coating have a (9) ohm/square package. 1 to 12% or 15%, will make the coating, 'the side of the rail, so that the cake _ cooperative paste control on the thunderstorming; 4, 10, - 丄 plate sugar agent electrode ohm / square ^ plus The amount of 5% scares the paint with f resistance, making the material very suitable as an antistatic coating for dust-free packaging materials. $Antistatic further for ^4^4^麟核_purpose, technology transfer benefits, more understanding, _-example, and with _, _ Ming as follows [embodiment] Press 'Emulsified zinc particles have Semiconductor feeding, in the chamber, zinc, has a higher lead-free K-plate, which is more oxidized than the ghost-like V-electric characteristics. In addition, the zinc oxide nanoparticles also have the electronic structure of the catalyst 201107236, because the grain size is comparable to the difference or D, the size effect and the price correction, the light absorption capacity is significantly enhanced, so the two light irradiation two Two: = photons of electricity over half plum, shot from the valence band to the guide: === knot; medium: - an electron hole and water molecules of the air towel (10) Continued 'When the electron is in the hydroxyl group (four), 姊After combing the reaction, robbing the water freely, the Wei Ke paste that loses the electrons becomes the hydrogen and oxygen (·0Η), and the unstable hydroxyl radicals will encounter the organic matter attached to the external oxidation or the oxidation. By robbing each other's electrons, I tend to be two. So where is Naa Wei Wei, Lai Cheng Shui and carbon dioxide, dissipated in * ΐ organic zinc nanoparticles can be used as a strong oxidant to achieve mold, bacteria and disease: Produce _ sex, no new, no successor and no advantage of "sound (four), by the sword in paint, ink, paint and petals, etc., the product can have long-acting antibacterial and mildew proof self-cleaning ability. The invention utilizes the characteristics of zinc oxide nanoparticles to oxidize Nano particle application = the production process of the rice-disc composite material, so that the nano-carbon f is originally tightly entangled, and the zinc oxide nano-particles are evenly filled and adhered to the expanded structure. The linear jetting of the carbon nanotubes causes the sewed composite medium-neutral carbon nanotubes to be closely packed together in order to effectively increase the composite material: Material uniformity, conductivity and dispersibility characteristics, from the reduction of the content of carbon nanotubes per unit of complex I material, 'the zinc oxide nano-seconds attached to the carbon nanotubes' can make the composite The self-cleaning ability of the long-acting antibacterial anti-indicator. In the first preferred embodiment of the present invention, in order to uniformly fill and align the zinc oxide nanoparticles into the linear structure of the carbon nanotube 201107236 carbon nanotubes The manufacturing method of the example includes the following steps, as shown in Fig. 4: (401) Adding the carbon nanotube powder and alcohol to a supersonic vibration at a predetermined weight percentage, such as 1:20~1:200 The mixing machine, at a predetermined speed, such as: 200 rev / min ~ 5 〇 〇〇/min, perform a predetermined period of ultrasonic oscillation and agitation, such as: 10 minutes to 2 hours, so that the carbon nanotubes originally tightly entangled linear structure can be stretched out in alcohol and evenly dispersed In alcohol, a viscous alcohol solution is formed; (402) a dispersion of zinc oxide nanoparticles in a predetermined weight percentage is added to the 'eyes' liquid towel, such as: 5% to 30%, the dispersion a water-soluble acrylic powder, a water-soluble acrylic powder, a water-soluble adhesive, and a zinc oxide nanoparticle, which are uniformly mixed according to a predetermined weight percentage, wherein the water-soluble acrylic powder is a water-based mixture (4), the side of the system is in the water anger, the energy can continue the ultrasonic oscillation and view the wealth of 'the oxygen and the carbon and the carbon ❾ (four) and scattered county magnified, the water is sticky _ role is money When the mixture is mixed into the aqueous solution, it can be uniformly coated on the surface of the oxidized nanoparticle; (403) Continue the ultrasonic oscillation and solve the solution for a certain period of time, such as: 丨~8 hours, after mixing , zinc oxide, the particles will be evenly filled to each In the linear structure in which the carbon nanotubes are unfolded, the linear structure of each carbon nanotube is unfolded; the quasi-ji is in the large (404) utilization-filter device _ fine money, and then fresh ( 405) For the _ obtained by the complete drying class, the _ is sold, that is, the composite material of the 201107236 to the carbon tube can be obtained. The cake and the composite material are filled and adhered with zinc oxide nano particles in each nanometer carbon 5, so that the linear structure will not be agglomerated again into a tightly entangled state, the carbon nanotubes and the oxidized nanometer. There is a predetermined weight ratio 'such as: between the particles.嗣, after the inventor Lai compound township actually lay down to-turn (such as: acrylic resin), and after the composite material and material are uniformly mixed, evenly coated on the plate (film thickness: ΗΜ0 (four) hardened, By measuring the conductivity data, it is known that when the composite material is uniformly added at 10% by weight and mixed into the coating, the coating material has a film resistance of ιοό ohm/square, when the addition amount is increased to 12% or 15% will give the coating a 10" ohm/square film resistance, making the coating ideal for use as a conductive coating on touch panels, blood glucose electrodes, or by reducing the amount added to less than 5%. The paint has a f ohm/square Ω resistance, making the coating extremely suitable as an antistatic coating for clean room coating and antistatic packaging materials, and both have long-acting antibacterial and antibacterial self-cleaning ability. - The solid dispersion of 'Weihua Zhan Naizi' is made up of water, zinc oxide nanoparticles, water-based acrylic powder and water-adhesive_component, which are uniformly mixed according to the following weight percentages: (1) Water: eg deionized Or pure water, etc., the weight percentage thereof is 5〇%~97 6%; (2) the zinc particles of zinc oxide: the weight percentage thereof is G 2%~1G%, in this embodiment, the zinc oxide is first ground. Nanometer-sized particles, 丨 nanometer equals 1 billionth of a meter (l〇9meter)' or nanometer-sized particles, nanoparticles between molecules and submicron, the shape of which is The sheet structure is optimal, and the average thickness thereof is 2 〇 nanometer 'average length is 200 to 400 nm; 12 201107236 (3) Hydrazine acrylic powder: its weight percentage is 2% to 3 〇%, wherein the water is soluble The acrylic crucible is a water-soluble dispersing agent. In this embodiment, the water-soluble acrylic powder is a propylene-based organism (p〇lyacr^lic acid) (4), and its action is after dissolving in water. In the process of ultrasonic vibration and mixing, the zinc oxide nanoparticles and 7Γ, m anti-g are uniformly and dispersedly suspended in the alcohol solution without causing a sinking or stagnation phenomenon. The oxidized reticulata can be smoothly infiltrated with the aqueous solution and filled into the linear structure in which each carbon nanotube has been stretched. And (4) water-based adhesive: the weight percentage is 〇2%~1〇% 'The water-soluble adhesive is coated on the surface of the aqueous solution to uniformly disperse the surface of the zinc oxide naphtha in the real In the chemical example, the water-based adhesive agent comprises a polyurea, a resin, a P-lymer, a N-Methyl Pyrrolidone, and a triethylamine (Liethylamme). The aqueous solution of the oxidized scales is smoothly filled and filled into the linear structure in which each nano-carboniferous tube has been stretched, so that the zinc oxide nanoparticles can be coated on the surface during the subsequent drying treatment. The water-soluble adhesive covered is 'stablely in the linear structure in which each of the carbon nanotubes has been stretched, so that the ♦ per-nano tube can be maintained in a stretched state, and the zinc oxide nano particles are allowed to be The combination of the moon and the nano-stone is permanently combined to produce a long-lasting antibacterial and mildew-proof effect. In the first embodiment, the average diameter of the commercially available nanocarbon f is 9$ nm, the average length is L5 micrometers (ie, 1500 nanometers), and the surface area is 25 〇 to m 2 / gram, which includes The carbon content is 9〇%' and contains 1% of the metal oxides, which provide metal-based and conductive properties for the carbon nanotubes, because the oxygen on the zinc oxide nanoparticles is easy to interact with the nano In the carbon tube, the metal base provided by the pure gold compound of the carbon tube forms a physical adsorption. Therefore, when the oxygen Jingnai practiced the ship, the ship was added with a smear-grade towel, and continued to enter the 201107236 supersonic f-vibration plate and the oxidation during the mixing. The zinc nanoparticles are easily filled into the linear protrusions that have been stretched out, and after the drying process, the water is adhered to each nanometer. The carbon tube has been stretched out in a linear structure, so that each of the non-small cores is maintained in a stretched heterostructure state without being agglomerated again into an entangled state. In a second preferred embodiment of the present invention, in order to allow the gasified nanoparticle to be more smoothly filled and adhered to the linear structure of the carbon nanotube, the manufacturing method of this embodiment includes the following steps, Refer to Figure 5: (501) Carbon tube powder and alcohol 'by weight ratio of 1:2〇~1:2〇〇, added to the ultra-chopper oscillator machine' at 200 rpm~5〇〇〇 The rotation speed of rpm is performed for 1~8 hours of ultrasonic vibration and stirring, so that the carbon nanotubes which are originally tightly entangled linear structure can be stretched out in alcohol to form a viscous alcohol solution; 〇 2) adding 2% to 6% by weight of the chlorinated dispersion in the alcohol solution. The dispersion is composed of water, chlorinated powder, water-soluble acrylic powder, water-soluble adhesive, and the like. An aqueous solution obtained by uniformly mixing the components according to a predetermined weight percentage, wherein the zinc chloride powder has a property of being completely soluble in an aqueous solution and capable of dissociating zinc ions in an aqueous solution, and the zinc ion has an oxophilic activity. Extremely easy...τ' m carbon tube towel oxygen on metal oxide Physically adsorbed' and uniformly adhered to the surface of the carbon nanotube during subsequent ultrasonic vibration 4 and agitation, the water-soluble acrylic powder-water-soluble dispersant, which acts in the water After the subsequent ultrasonic vibration and stirring process, the carbon nanotubes are uniformly and dispersedly suspended in the alcohol solution. The function of the water-soluble adhesive is in the subsequent 201107236 ultra-chopper oscillation and stirring process. , can evenly cover the surface of zinc ions; (5〇3) continue to record the ultrasonic and lion 8 trees, and add the reducing agent to the alcohol solution during the sewing and agitation process, After the agent and the alcohol solution are evenly mixed, the reducing agent can provide electrons in the alcohol solution by obtaining the rape of the (4) county meter, and in the recording of the gas, the air is pumped into the alcohol solution through the air pump to make the zinc The nanoparticle can utilize its own oxophilic activity to bond with oxygen to form an oxidized rice φ particle, and gradually adheres to the surface of the carbon nanotube. Thus, the zinc oxide nanoparticle P a is uniformly filled. To every nano carbon tube has been unfolded In the linear transformation, the linear structure can be maintained in a state of large expansion; (504) the excess of the alcohol solution is used for the excess, and then applied to the county; (5〇5) after the complete drying The obtained material is subjected to mechanical pulverization treatment, that is, a composite material of the meter-inhibited tube can be obtained. At this time, the weight ratio of the carbon nanotubes and the oxidized non-rice particles in the composite material is present. In the second embodiment, the chlorinated dispersion is uniformly mixed by water, zinc chloride powder, remanufactured, water, acrylic powder and water-soluble transesterification component according to the following weight percentages. Cheng: ^ ί . Such as deionized water or pure water, etc., its weight percentage is 20% ~ 97%; α δ% ~ 4 ()%, Na zinc powder can be finished in water, and can be separated from the water cap The characteristics of the ion, and the metal oxide in the ion: tube:::r ultrasonic wave vibrating material, evenly attached to the nano 201107236 (3) water-soluble acrylic powder: its weight percentage is 2%~ 3〇%, wherein the water-soluble acrylic powder is a water-soluble dispersant. In this embodiment, the water-soluble acrylic powder is a p〇lyacrylic acid derivative, and its action is dissolved. After being in water, the carbon nanotubes can be uniformly and dispersedly suspended in the alcohol solution during ultrasonic oscillation and stirring without precipitation or siltation and agglomeration; and (4) water/grain sticky The weight percentage is 〇2%~1〇%, and the water-soluble adhesive is used for coating zinc ions. In this embodiment, the water-soluble adhesive comprises Urethane polymer, N-Methyl Pyrrolidone, and Triethylamine. In the subsequent drying treatment, the formed zinc oxide nanoparticles can be stably attached to the stretched linear structure of each carbon nanotube by the water-soluble adhesive on the surface thereof, resulting in long-lasting effect. Antibacterial and mildewproof effect. In addition, in the second embodiment, the weight percentage of the reducing agent in the alcohol solution is 0.5% to 1% by weight, which is dehydrated by disodium edetate (EDTA 2Na). An aqueous solution of KOH) and potassium hydrogencarbonate (KHC〇3)), which is mixed according to a predetermined weight percentage, wherein the weight percentage of disodium edetate in the reducing agent is αΐ5%~3 % 'potassium hydroxide is 0.08%~1.5% by weight, and the weight percentage of potassium hydrogencarbonate is 0.3%~6〇/〇. The reducing agent can provide the zinc ions to be reduced into zinc nanoparticles in the mixed solution. The electrons enable zinc ions to be reduced to zinc nanoparticles by the reducing agent, and the zinc nanoparticles can utilize their own oxophilic activity during the process of oxygen being introduced into the alcohol solution via the air pump. Oxygen bonding, which gradually forms zinc oxide nanoparticles on the surface of the carbon nanotubes. 16 201107236 In a third preferred embodiment of the present invention, in order to make the carbon nanotubes in the composite material produced by the first and second preferred embodiments have better material uniformity and electrical conductivity characteristics' And the amount of the per unit-unit composite (four) towel carbon nanotubes is reduced, and the manufacturing method of the embodiment is to additionally add 〇2% to 1% by weight of the weight of the dioxide to the dispersion (or The stone particles of the Shixi-burning type are best in the shape of a spherical structure, and the average particle size is 20 nm, and the surface area is 357 m square/g, which is the first and second most profitable For the fortune, Lai sub-ship added Wei Yu shot, continue to carry out ultrasonic stitching and _ handling, the sub-ship towel (10) water miscellaneous acrylic powder system can be used in the ultrasonic wave f and view, so that the oxygen scale green, The dioxane and the carbon nanotubes are uniformly and dispersedly suspended in the alcohol solution, and the water-soluble adhesive can be uniformly coated on the surface of the oxygen scale and the dioxide material to complete the super Sound waves. After oscillating and mixing, the zinc oxide nanoparticles will be evenly filled to the line where each nano carbon tube has been stretched. !4冓中中, and the dioxide particles of the sulphur dioxide will be uniformly filled into the oxidized yttrium granules: and the carbon-carbon line-like structure _ gaps, so that the linear structure of each-carbon nanotubes is completed in the filtration and county Processing 'Energy County's maximum unfolding state, and finally, recording the complete chess. Dry material, after mechanical pulverization treatment, can obtain the carbon nanotube composite material'. The carbon nanotubes and dioxide in the composite material There is a weight ratio of 25:1:4 to 1:4:1 between the Shixi nanoparticle and the oxidized nanoparticle. At this time, since each nano-carbon anthrax in the composite material has a linear structure with the largest towel width, and the linear structure of each carbon nanotube has been expanded and filled with oxidized green The sub- and dioxones are tempered so that the linear structure does not re-converge and become compact. L is applied by the inventor to apply a coating to a coating (eg, acrylic resin). Manufactured, and after the composite material and the handle are uniformly mixed, uniformly coated on the pvc board (film thickness: 1G~3〇 17 17 072 712 = after 'the measurement of the conductive data is known' # The composite material is uniformly added in a jump weight and mixed to the coating, which will give the coating a w ohm/meter square material, which is characterized by the composite produced by the first and second preferred embodiments: The resistance of the lag (1G ohms/square) should be doubled, when the amount of addition is increased to 12% or the number of people = ^ _ 1G2 ~ 3 ohms / square _ resistance, making the coating extremely suitable = touch panel, blood sugar (4) Electrolytic coatings on the poles, or by reducing the amount of addition to = to make the coating have a ohmic resistance of ohms/square, so that the coating It is an antistatic coating for clean room coating and antistatic packaging materials, and it has the coffee power of the two. Therefore, it is in the first and second preferred embodiments. The second secret report _ particles will make the composite materials have better material uniformity and conductive properties, and can further reduce the content of carbon nanotubes in the composite material. According to the above, it is only the present invention _ some best concrete _, but the hair is not limited to this. Anyone who is familiar with the art can easily change or modify in the field of the invention. It is covered by the following patent application scope of the present invention. ^ [Simple description of the drawing] _ Figure 1 is a schematic diagram of the spiral vector structure of a conventional carbon nanotube; schematic diagram of the structure of different types of conventional nano-tubes, wherein (a) is The chair type 'Ding, anti-g) is the recording type carbon nanotube '(c) is the spiral type carbon nanotube; the third picture is the microscopic diagram of the linear structure of the traditional carbon tube; A schematic diagram of a process of the first preferred embodiment of the present invention; and Figure 5 is the second most preferred embodiment of the present invention A schematic diagram of the process of the preferred embodiment. 18 201107236 [Main component symbol description]