201102344 、發明說明： 【發明所屬之技術領域】 2發明係關於-種氫氣純化織’特別於 =J氣體所含的-氧化碳的氫氣純化裝置，並且利用用於g 虱I置的燃料’來作為氫氣純化裝置的冷㈣。 " •【先前技術】 _專難公告號w_/32513「對氫氣移除―氧化碳的201102344, invention description: [Technical field to which the invention pertains] 2 The invention relates to a hydrogen purification apparatus for purifying a hydrogen-containing carbon dioxide contained in a gas, and using a fuel for g 虱I As a hydrogen purification device (4). " • [Prior Art] _Special difficulty announcement number w_/32513 "Removal of hydrogen - carbon oxide
• 反應器與處理（REACT0R AND PROCESS FOR REMOVAL OF CARBON :· _oxidef_h撤謂)」已揭露一種反應器⑽CT〇R)， 用來對燃料電池的氫氣燃料提供了移除一氧化碳的作法，使得 不會發生一氧化碳毒化鉑觸媒的情形。恥〇〇/32513對於熱交 換處理的手段乃是讓冷卻劑以泵為動力，在一個部分管路經過 該反應器的封閉的迴路中一直循環重覆地使用，讓管路其中的 , 冷卻劑與反應器中的熱交換器進行熱交換。 *、 另一 WIP0專利案公告號W0 93/19005「從氣體媒介移除 春 一氧化碳的方法和設備（METHOD OF AND APPARATUS FOR REMOVING CARBON MONOXIDE FROM GASEOUS MEDIA)」已揭露 一種方法和設備（METHOD OF AND APPARATUS)，用來對燃料 電池的甲醇水溶液液態燃料提供了移除一氧化碳的作法。 W093/19005對於熱交換處理的手段乃是從將外部冷卻劑注入 於去除一氧化碳的設備’然後流通於設備的冷卻管（(：〇〇111^ coil),最後流出於設備。然而，w〇93/19〇〇5所使用的冷卻劑 3 [S1 201102344 來利用作為冷卻 並未揭示到將用於重整器的重整反應的燃料， 劑0 本發明發明人有鑑於上述去除富氫氣體所含一山 習知技藝仍有改良之處，乃亟思發明 7化厌的 » ^ 又艮種氳氣純化裝 ’除了可絲富氫紐所含-氧化麵之外，尚可對燃料槽 内的燃料進行重整反應前先進行預熱。 【發明内容】 本發明的第-目的在於提供一種氫氣純化褒置，除了可 去除富氫氣體所含-氧化碳的之外，尚可將催化劑溫度控 制在適合進行-氧化碳移除之催化反應的特定^圍 内，且同時對燃料槽内的燃料進行預熱。 本發明的第二目的在於提供—種發電裝置，乃具有氮氣 純化裝置。 ’ 本發明的第三目的在於提供一種燃料處理裝置，乃具有 氫氣純化裝置。 為達上述m本發明提供—贱氣純化裝置， 包括.冗又體’係-密閉式結構，且具有一個内部空間，其 中該内部空間係用於放置催化劑；—氣體注入口，係設置於 該殼體，以及係絲引人外部的空氣或氧氣至_部空間； -富氫氣體注人Π，係設置於該_，以及制來引入一富 氫氣體至_部空間的前側；—氫氣出口，係設置於該殼體 is] 4 201102344 且係位於勒部空關後側，以及制來使_富氫氣體與 該催化劑發生-氧化碳選擇性反應後的一純化氣氣流出；二 ^卻劑輸送管，射齡卻纖送管的—末端縣路連接於 一燃料槽的-心，以及該冷卻繼送管的另—末端係管路 連胁該燃料槽的-入口 ’以及一部份中間段的該冷卻劑輸 二係穿貫於該殼體的内部空間，其中該催化劑係包圍著該 部財間段的該冷卻劑輸送管；其中該冷卻劑輸送管係^ 輸送該燃料槽的燃料，其中該燃料自該燃料槽的該出口流出 而流入於該冷卻職送管，再流經通過勒部空間，最後流 回至該燃料槽的該入口而回到該燃料槽内。 再者，為達上述之第二目的，本發明提供—種發電裝置， 包括：-燃料槽，係儲存一燃料，以及係具有至少兩個出口 與至少一個人口；—氫氣純化裝置，包含：-殼體，係一密 狀结構，且具有—_部空間，其中_部空間係用於放 置-劑’·-氣體注入口，係設置於該殼體，以及係用來 入夕部的空氣或氧氣至該内部空間；氫氣體注入口， 錢置於該f體，以及係用來引入一富氯氣體至該内部空間 的别側’-氫氣出口，係設置於該殼體且係位於該内部空間 •的後側g及係用來使得該富氫氣體與該催化劑發生一氧化 碳選擇性反細—崎*^，·-糊輸送管，里中 該冷部劑輸送管的-末·管路連接顯簡槽的一出口， 以及該冷卻_鮮㈣—末端絲路輪於魏料槽的一 201102344 入口，以及—部份中·的該冷卻劑輸送管係穿貫於該殼體 的内部空間’其巾該催铺聽歸該部份巾間段的該冷卻 劑輸送管；其中該冷卻劑輸送管係用來輸送該燃料槽的燃 料，其中該燃料自該燃料槽的出口流出而流入於該冷卻劑輸 送管’再流經通過該内部空間，最後流回至該燃料槽的入口； 一燃料前處理裝置，係管路連接於該燃料槽的另一個出口， 以及係官路連接於該氫氣純化裝置的富氫氣體注入口，以及 係用於將輸入於該燃料前處理裝置的燃料進行製氫反應；一 燃料電池裝置，係管路連接於該氫氣純化裝置的氫氣出口， 以及係用來產生電力。 再者為達上述之弟二目的，本發明提供一種燃料處理 裝置，包括：一燃料槽，係儲存一燃料，以及係具有至少兩 個出口與至少一個入口；一氫氣純化裝置，包含：一殼體， 係-密閉式結構’且具有—個内部空間，其中該内部空間係 用於放置一催化劑；一氣體注入口，係設置於該殼體，以及 係用來引入外部的空氣或氧氣至該内部空間；一富氫氣體注 入口 ’係設置於該殼體’以及伽來引人—富統體至該内 部空間的_ ;-氫氣出口，係設置於該殼體且係位於該内 部空間的後側，以及係用來使得該富氩氣體與該催化劑發生 一氧化碳選擇性反應後的一純化氫氣流出；一冷卻劑輸送 官，其中該冷卻劑輸送管的一末端係管路連接於該燃料槽的 一出口，以及該冷卻劑輸送管的另一末端係管路連接於該燃 201102344 ;.:曰的入口以及。P份中間段的該冷卻劑輸送管係穿貫 於該殼體_部郎，其巾_化舰⑽辆部份中間段 的該冷卻·送管；其㈣冷卻雜送管伽錢送料 槽的燃料’其中該燃料自該燃料槽的出Π流出而流入於該冷 部劑輸送管’再流經通過該内部空間，最後流回至該燃料槽 的入口，-燃料丽處理裝置，係管路連接於該燃料槽的另一 個出口 ’以及係管路連接於該氫氣純化裝置的f氫氣體注入 口’以及係用於將輸入於該燃料前處理裝置的燃料進行製氯 反應。 為使貴審查委員對本發明之構造、特徵及其使用功效 有更深-層㈣識赠解，轉健之可行實_並配合圖 式泮細說明如下： [實施方式】 本發明氫氣純化裝置的重要特色：乃是利用用於製氫反應 的燃料’來作為-氧化碳選擇性反應的熱交換冷卻劑，如此一 來，在熱交換過程之中，藉以將催化劑溫度控制在適合進 行一氧化碳移除之催化反應的特定範圍内，同時該燃料 亦被預熱處理，然後，再注人於製氫反絲置進行製氣。 第一圖顯示本發明氫氣純化裝置的架構圖。本發明氫氣純 化裝置10的第一項功能，是用來移除燃料前處理震置3〇(請 參見第二圖）的製氫反應生成物中所含的一氧化碳(C〇)。本發 201102344 明氫氣純化震置1G的第二項功能’是在純化氫氣的同時，能 夠對燃料_理裝置3G所用的製氫崎進行預熱。 氫氣純化裝置10乃包括：殼體101、富氫氣體注入口 1〇3、 氣妝'主入口 105、氫氣出口 107與冷卻劑輸送管109，兹分別 发明如后内文。殼體1〇1係為密閉式結構，且具有一個内部空 間101a。叙體1〇例如採行密閉式圓柱體的容器結構。内部空 間l〇la係設置-催化劑區101b。富氫氣體注入口 1〇3係設置 * φ 於成虹10卜以及係用來引入富氫氣體至内部空間l〇la的前 •側。富氫氣體注入口 103可採行設置錢體1〇1的前側，且設 置位置疋位於内部空間l〇la的前側的前方。氣體注入口 1〇5 係設置於殼體ΗΠ，以及係用來狀外部的空氣或氧氣至内部 空間l〇la。氣體注入口 105可採行設置在殼體1〇1的上側， 設置位置是位於内部空間ma的前侧的上方。氮氣出口 1〇7 — 係設置於殼體101且係位於内部空間101a的後側，以及係用 • 綠得富氫氣體與催化劑區10此内的催化劑發生一氧化碳移 除催化反應後的純化氫氣流出。氫氣出口 1〇7可採行設置在殼 體101的後側’設置位置是位於内部空間施的後侧的後方。 冷卻劑輸送f⑽触巾絲路連接於燃料槽 20的出口 20a，以及冷卻劑輸送管109的另-末端則是管路連 接於燃料槽20的人Π施。—部料間段的冷卻劑輸送管1〇9 係穿貫於殼體HU的内部空間1Gla，並且催化劑區垂内的 催化劑乃包·該部射間段物嶋送管膨該部份中 201102344 間段的冷卻劑輪# 送管，並且_二二狀的輸 101a 是不相通 B &的冷部劑輪送管109與内部空間• Reactor and treatment (REACT0R AND PROCESS FOR REMOVAL OF CARBON:· _oxidef_h withdrawal) has disclosed a reactor (10) CT〇R), which is used to remove carbon monoxide from the fuel cell's hydrogen fuel so that it does not occur. The case of carbon monoxide poisoning platinum catalyst. The method of heat exchange treatment of the shame/32513 is to make the coolant pump-powered, and to use it repeatedly in a closed loop of a part of the pipeline through the reactor, so that the coolant in the pipeline Heat exchange with the heat exchanger in the reactor. *, another method and apparatus (METHOD OF AND APPARATUS) has been disclosed in another WOP0 Patent Publication No. WO 93/19005 "METHOD OF AND APPARATUS FOR REMOVING CARBON MONOXIDE FROM GASEOUS MEDIA" ), which is used to provide a method for removing carbon monoxide from a liquid fuel of methanol in a fuel cell. The means of heat exchange treatment of W093/19005 is from the injection of external coolant into the equipment for removing carbon monoxide, and then flows to the cooling pipe of the equipment ((:〇〇111^ coil), and finally flows out to the equipment. However, w〇93 /19〇〇5 used coolant 3 [S1 201102344 to utilize the fuel which is not disclosed as a reforming reaction to be used for the reformer, the agent 0 is invented by the inventors of the present invention in view of the above-mentioned removal of hydrogen-rich gas There is still room for improvement in the skill of a mountain, and it is invented by the singer of the singularity of the singularity of the singularity of the singularity of the sputum. The fuel is subjected to preheating before the reforming reaction. SUMMARY OF THE INVENTION The first object of the present invention is to provide a hydrogen purification device which can control the temperature of the catalyst in addition to the carbon oxide contained in the hydrogen-rich gas. The fuel in the fuel tank is preheated in a specific range suitable for the catalytic reaction of carbon monoxide removal, and at the same time, the fuel in the fuel tank is preheated. A second object of the present invention is to provide a power generating apparatus having a nitrogen purifying apparatus. invented A third object is to provide a fuel processing apparatus having a hydrogen purifying apparatus. The present invention provides a helium gas purifying apparatus, comprising a redundant body-closed structure, and having an internal space, wherein the interior The space is used for placing the catalyst; the gas injection port is disposed in the casing, and the air or oxygen that is drawn outside the wire to the space; the hydrogen-rich gas is injected into the body, and is set in the _, and To introduce a hydrogen-rich gas to the front side of the _ space; the hydrogen outlet is disposed in the casing is] 4 201102344 and is located at the rear side of the Lechu air-conditioning, and is made to cause hydrogen-rich gas and the catalyst to occur - a purified gas stream after the selective reaction of carbon oxide; the second delivery agent tube, the end of the fiber delivery tube is connected to the center of a fuel tank, and the other end of the cooling relay tube The coolant line of the fuel tank is connected to the inlet of the fuel tank and a portion of the middle portion of the coolant is passed through the internal space of the casing, wherein the catalyst surrounds the coolant of the section Duct; where the cold The fuel delivery pipe system delivers fuel of the fuel tank, wherein the fuel flows out of the outlet of the fuel tank and flows into the cooling service pipe, flows through the space of the Lech, and finally flows back to the inlet of the fuel tank. And returning to the fuel tank. Further, in order to achieve the above second object, the present invention provides a power generation device comprising: a fuel tank for storing a fuel, and having at least two outlets and at least one population; - a hydrogen purification device comprising: - a housing, a dense structure, and having a space of - a portion, wherein the space is for placing a - 'gas injection port, is provided in the housing, and is a system Air or oxygen used to enter the inner space; hydrogen gas injection port, money placed in the body, and used to introduce a chlorine-rich gas to the other side of the internal space '-hydrogen outlet, is set in The casing is located on the rear side g of the inner space and is used to cause the hydrogen-rich gas and the catalyst to selectively decarburize the carbon monoxide-salt-,--- paste conveying pipe, wherein the cold portion agent is transported Tube-end-pipe connection simplification slot An outlet, and the cooling_fresh (four)-end wire wheel is at a 201102344 inlet of the weir, and the portion of the coolant delivery pipe runs through the interior space of the casing. Paving the coolant delivery pipe to the portion of the towel; wherein the coolant delivery pipe is for conveying fuel of the fuel tank, wherein the fuel flows out from the outlet of the fuel tank and flows into the coolant delivery pipe 'Reflowing through the internal space, and finally flowing back to the inlet of the fuel tank; a fuel pretreatment device connected to the other outlet of the fuel tank, and a hydrogen rich circuit connected to the hydrogen purification device a gas injection port for performing a hydrogen production reaction on the fuel input to the fuel pretreatment device; a fuel cell device connected to the hydrogen outlet of the hydrogen purification device and used to generate electric power. The present invention provides a fuel processing apparatus comprising: a fuel tank for storing a fuel, and having at least two outlets and at least one inlet; and a hydrogen purification device comprising: a shell a body-series-closed structure' and having an internal space, wherein the internal space is for placing a catalyst; a gas injection port is provided in the casing, and is used to introduce external air or oxygen to the body An internal space; a hydrogen-rich gas injection port is disposed in the casing and a gas-extracting-rich body to the internal space; the hydrogen outlet is disposed in the casing and is located in the inner space a rear side, and a purified hydrogen gas for selectively reacting the argon-enriched gas with the catalyst; wherein a coolant delivery unit, wherein an end of the coolant delivery tube is connected to the fuel tank An outlet of the coolant delivery pipe and the other end of the coolant delivery pipe are connected to the inlet 201102344; The coolant delivery pipe of the middle portion of the P portion runs through the casing _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ a fuel in which the fuel flows out of the outlet of the fuel tank and flows into the cold agent delivery pipe and flows through the internal space and finally flows back to the inlet of the fuel tank. The other outlet 'connected to the fuel tank and the f-hydrogen gas injection port connected to the hydrogen purification unit and the fuel input to the fuel pretreatment apparatus are subjected to a chlorine production reaction. In order to enable the reviewing committee to have a deeper-layer (four) knowledge solution for the structure, characteristics and use efficiency of the present invention, it is feasible to implement the following: [Embodiment] The hydrogen purification device of the present invention is important. Features: It uses the fuel used in the hydrogen production reaction as a heat exchange coolant for the selective reaction of carbon oxides, so that during the heat exchange process, the catalyst temperature is controlled to be suitable for carbon monoxide removal. Within the specific range of the catalytic reaction, the fuel is also pre-heat treated, and then injected into the hydrogen production counter-filament to carry out gas production. The first figure shows the architectural diagram of the hydrogen purification apparatus of the present invention. The first function of the hydrogen purifying apparatus 10 of the present invention is to remove carbon monoxide (C〇) contained in the hydrogen production reaction product of the fuel pretreatment 3 〇 (see Fig. 2). This is the second function of the 1G of hydrogen purification, which is capable of preheating the hydrogen gas used in the fuel 3G device while purifying hydrogen. The hydrogen purifying apparatus 10 includes a casing 101, a hydrogen-rich gas injection port 1〇3, a makeup "main inlet 105", a hydrogen outlet 107, and a coolant delivery pipe 109, respectively, which are hereby incorporated by reference. The casing 1〇1 is of a hermetic structure and has an internal space 101a. The body 1 is, for example, a container structure in which a closed cylinder is taken. The internal space l〇la is provided - a catalyst zone 101b. Hydrogen-rich gas injection port 1〇3 system setting * φ is in the rainbow and is used to introduce hydrogen-rich gas to the front side of the internal space l〇la. The hydrogen-rich gas injection port 103 can adopt a front side on which the money body 1〇1 is disposed, and the set position 疋 is located in front of the front side of the internal space l〇1a. The gas injection port 1〇5 is disposed in the casing ΗΠ, and is used to form air or oxygen outside to the internal space l〇la. The gas injection port 105 may be disposed on the upper side of the casing 1〇1, and the installation position is located above the front side of the internal space ma. The nitrogen gas outlet 1〇7 is disposed in the casing 101 and is located on the rear side of the internal space 101a, and the purified hydrogen gas flows out after the carbon monoxide removal catalytic reaction of the catalyst in the green gas rich catalyst and the catalyst zone 10 . The hydrogen outlet 1〇7 can be disposed at the rear side of the casing 101. The installation position is located behind the rear side of the internal space. The coolant delivery f(10) touchscreen wire is connected to the outlet 20a of the fuel tank 20, and the other end of the coolant delivery pipe 109 is a conduit for the pipe to be connected to the fuel tank 20. - the coolant delivery pipe 1〇9 of the inter-material section runs through the internal space 1G1a of the casing HU, and the catalyst in the catalyst zone is covered by the injection zone. The interval of the coolant wheel # is sent to the tube, and the _two-shaped input 101a is the non-communicating B & cold-form agent transfer tube 109 and the internal space
係用來輸送燃獅的燃料。燃料自 流此流出，而流入於冷卻劑輸送_，再 再去^^㈣間1Gla ’最後，流回至燃料槽2〇的入口 20b。 胁i緊鄰於燃料槽2〇的出口咖的附近’泵40可串聯連 ;1:7 20a與冷卻劑輸送管⑽之間。果仙可以用來推進 燃料的循環流動。 @ f二圖顯示本购氫氣純化裝置的變化實施例的架構 圖第-圖的氫氣純化裝置1〇，是為多階式的純化氫氣裝 置而第圖氫氣純化裝置1〇是為一階式的純化氫氣裝置。 在氫氣純化裝置1()，中，氣體注入口娜的設置數量是至少 二個（含）以上，複數個氣體注入口 1〇5，係設置於殼體1〇卜 以及係用來引人外部的空氣或氧氣至内部空間皿a的複數個 催化劑區1〇1’ b。複數個氣體注入口 1〇5，可採行設置在殼 粗101的上側，設置位置是分別位於每一個催化劑區丨〇1，b 的前側的上方。 在弟二圖中’複數個催化劑區10 Γ b採行多段(Segment) 方式放置在内部空間l〇la，茲以第二圖的三個催化劑區 1〇1’ b為例說明，這三個催化劑區1〇1’ b分成三段方式，而 每一段催化劑區101’ b接續排列，且相鄰的催化劑區101’ b 201102344 之間可以間隔著一個小距離。 位於内部空間1Qla的富缝體的流動方向，乃是與位於 内部空間施ό觸份中間段的冷卻劑輸送管⑽的燃料的 流動方向，採行彼此反方向。 燃料槽20的燃料種類的選擇，乃端視於燃料前處理裝置 3〇(請參見第三圖）的製&反應是使用何種燃料而決定，料槽 2—0的燃料亦是用來作為氫氣純化展置1Q、⑽的冷卻劑。當 • ㈣氣體以及㉙（或A氣)進人畴帥101a後，在催化劑 區l〇lb、101，b催化劑的作用下進行移除一氧化碳的催化反 應’並放出大量的熱。在泵4〇的推進作用下，燃料槽2〇的燃 料經由冷卻劑輸送管1〇9的輸送而通過内部空間， 料通過内部空間101a的同時，並且吸收熱量，然後，被預熱 的燃料再流回至燃料槽2〇。 催化劑區101b、101，b内的催化劑可以直接採用用於一 馨氧化碳選擇性氧化反應的習知催化劑、或是用於一氧化碳選擇 性甲院化反應的習知催化劑、或是可用於其他移除一氧化碳的 反應的其它催化劑。 再者，设置一個冷卻劑流量控制單元5〇，用來控制冷卻 劑輸送管109的燃料流量或流速。冷卻劑流量控制單元的 組成可包括一個微控制器與至少一個以上的溫度感測器。溫度 感測器是用來測量内部空間l〇la的溫度，微控制器依據溫度 值的大小，對泵40的運作進行控制，使得冷卻劑輸送管1〇9 201102344 。又再者，It is used to transport fuel for lions. The fuel flows out of this flow, and flows into the coolant delivery _, and then goes to the ^1 (4) between 1Gla' and finally flows back to the inlet 20b of the fuel tank 2〇. The threat i is adjacent to the vicinity of the outlet of the fuel tank 2', and the pump 40 can be connected in series; 1:7 20a and the coolant delivery pipe (10). Fruit can be used to promote the circulation of fuel. @f 二图 shows the structural diagram of the modified embodiment of the hydrogen purifying apparatus. The hydrogen purifying apparatus of the first drawing is a multi-stage purified hydrogen apparatus, and the hydrogen purifying apparatus 1 is a first-order type. Purify the hydrogen unit. In the hydrogen purification device 1 (), the number of gas injection ports is at least two (inclusive), and a plurality of gas injection ports 1 〇 5 are provided in the casing 1 and are used to attract the outside. Air or oxygen to a plurality of catalyst zones 1〇1' b of the inner space a. A plurality of gas injection ports 1〇5 may be disposed on the upper side of the shell thickness 101, and the installation positions are respectively located above the front side of each of the catalyst zones 丨〇1, b. In the second diagram, the 'multiple catalyst zones 10 Γ b are placed in the internal space l〇la, and the three catalyst zones 1〇1' b of the second figure are taken as an example. The catalyst zone 1〇1'b is divided into three stages, and each stage of the catalyst zone 101'b is successively arranged, and the adjacent catalyst zones 101'b 201102344 may be spaced apart by a small distance. The flow direction of the rich body located in the internal space 1Qla is the flow direction of the fuel in the coolant delivery pipe (10) located in the middle portion of the internal space application bias, and is reversed in the opposite direction. The fuel type of the fuel tank 20 is selected based on the fuel pretreatment device 3 (see the third figure) and the reaction is determined by the fuel used. The fuel of the trough 2-0 is also used. The coolant of 1Q and (10) was exhibited as hydrogen purification. When (4) gas and 29 (or A gas) enter the domain 101a, the catalytic reaction of removing carbon monoxide is carried out under the action of the catalyst zone l〇lb, 101, b catalyst and a large amount of heat is released. Under the action of the pump 4〇, the fuel of the fuel tank 2〇 passes through the internal space through the delivery of the coolant delivery pipe 1〇9, passes through the internal space 101a, and absorbs heat, and then, the preheated fuel is re-heated. Flow back to the fuel tank 2〇. The catalyst in the catalyst zone 101b, 101, b can be directly used as a conventional catalyst for selective oxidation reaction of a sweet carbon oxide, or a conventional catalyst for selective carbon monoxide reaction, or can be used for other shifts. Other catalysts other than the reaction of carbon monoxide. Further, a coolant flow control unit 5 is provided for controlling the fuel flow rate or flow rate of the coolant delivery pipe 109. The composition of the coolant flow control unit can include a microcontroller and at least one temperature sensor. The temperature sensor is used to measure the temperature of the internal space l〇la, and the microcontroller controls the operation of the pump 40 according to the temperature value, so that the coolant delivery pipe 1〇9 201102344. Again,
恍應罕）’錢縣40的運倾行㈣，贿冷卻劑輸送管 109的燃料流量或流速獲得控制。 的燃料流量或流读權彡呈i允也丨 50的組成進一步包括一個水位計， 槽20的燃料水位。微控制器依據才 而獲得燃料槽20的燃料的消耗率Q 供應率），然狳對s 40的運你冷t 〜再者’為了能夠讓空氣（或氧氣)在内部空間⑻a能夠與 田觀體彼此均勻混合-起，因此，在内部空間ι〇ι&且鄰位 於對應的氣體注人口 105、105,的位置，乃分別設置擾流元 件(〜圖未顯示），擾流元件的功能就是用來使得空氣(或氧氣） 與富氫氣體均城合-起。擾流元件可採料會與位於内部 空間101a的物質、空氣以及氫氣發生化學反應，且熱穩定性 好的金屬絲網。 第二圖顯示具有本發明氫氣純化裝置的發電裝置的架構 圖。本發明發電裝置60乃包括有上述的氫氣純化裝置1〇(或 虱氣純化裝置10，）、上述的燃料槽2〇、燃料前處理裝置卯 與燃料電池裝置70。 在第三圖中，冷卻劑輸送管109的一末端係管路連接於 燃料槽20的出口 20a ’以及冷卻劑輸送管109的另一末端係 管路連接於燃料槽20的入口 2〇b，以及一部份中間段的冷卻 劑輪送管109係穿貫於殼體ιοί的内部空間1〇la。催化劑區 101 b内的催化劑係包圍著該部份中間段的冷卻劑輸送管 201102344 109。燃料前處理裳置3()係管路連接於燃料槽2()的出口脱， =膽、管路連接於氫氣純化裝置1〇(或氫氣純化裝幻0,)的 田氫氣人口⑽’以及係祕將輸人於麵愤處理裝置 30的燃料進行製氫反應。燃料電池裳置7〇係管路連接於 純化裝置10(或氫氣純化裝置1〇,）的氮氣 用來產生電力。 第四圖顯示具有本發明氫氣純化裝置的燃料處理裝置的 • 架構圖。本發明燃料處理裝置80乃包括有上述的氫氣純財 置峨氫氣純化裝置10,）、上述的燃料槽2〇、與燃料前處 理裝置3〇。燃料處理裝置80在相較於第三圖的發電裝置6〇， 腸斗處理裝置80省略了燃料電池裳置7〇。燃料處理裳置卯 者重於燃料的處理，並可以針對所需之應用而與不同的裝置 連接。 ^ 上述的燃料前處理裝置30可以直接採用習知製氫襄置， 齡例如_ f知燃料重整器，來將甲醇溶賴料進行重整反應 而獲得富氫氣體。 〜 上述的燃料電池裝置7G可以直接制f知燃料電池裝 置’例如採用習知質子交換膜燃料電池，其係利用氫氣與空 氣（或氧氣)來作為燃料。 上述的燃料前處理裝置30與燃料槽20(請參閱第三圖與 第四圖）之間的燃料輪送管路與出口 2〇c之間更可以再串聯一 泵（未繪示），藉以控制燃料的流量。 [s] 12 201102344 本發明的氫氣純化裝置以及具有氫氣純化裝置的發電裝 置或燃料處理裝置，乃直接利用燃料前處理裝置的燃料當作 冷卻劑，用來對氫氣純化裝置的催化劑進行冷卻，同時，燃 料也藉此達到了預熱，此即為本發明的優點及功效顯著增進 所在。恍应罕) 'The movement of the Qianxian 40 (four), the fuel flow or flow rate of the bribe coolant delivery pipe 109 is controlled. The composition of the fuel flow or flow reading 彡 允 丨 丨 50 further includes a water level gauge, the fuel level of the tank 20. The microcontroller obtains the fuel consumption rate of the fuel tank 20 according to the supply rate Q), and then the cold s 40 for you to transport the cold t ~ again 'in order to be able to let the air (or oxygen) in the internal space (8) a can with Tian Guan The bodies are uniformly mixed with each other, and therefore, in the internal space ι〇ι& and adjacent to the corresponding gas injection populations 105, 105, the spoiler elements (not shown) are respectively provided, and the function of the spoiler elements is It is used to make air (or oxygen) and hydrogen-rich gas uniform. The spoiler element can pick up a metal mesh that chemically reacts with the substance, air, and hydrogen located in the internal space 101a, and is thermally stable. The second figure shows the architecture of a power generating apparatus having the hydrogen purifying apparatus of the present invention. The power generating device 60 of the present invention includes the above-described hydrogen purifying device 1 (or helium purifying device 10), the above-described fuel tank 2, a fuel pretreatment device 卯, and a fuel cell device 70. In the third figure, one end of the coolant delivery pipe 109 is connected to the outlet 20a' of the fuel tank 20 and the other end of the coolant delivery pipe 109 is connected to the inlet 2〇b of the fuel tank 20. And a part of the intermediate section of the coolant transfer pipe 109 is passed through the internal space 1〇1a of the casing ιοί. The catalyst in the catalyst zone 101b surrounds the coolant delivery pipe 201102344 109 of the intermediate section. The pre-treatment of the fuel pre-treatment 3 () line is connected to the outlet of the fuel tank 2 (), and the pipeline is connected to the hydrogen purification unit (10) of the hydrogen purification unit 1 (or hydrogen purification unit illusion 0). The secretary will enter the fuel of the indignant treatment device 30 to produce hydrogen. The fuel cell is placed in a 7-inch line connected to the nitrogen of the purification unit 10 (or the hydrogen purification unit 1) to generate electricity. The fourth figure shows an architectural diagram of a fuel processing apparatus having the hydrogen purification apparatus of the present invention. The fuel processing apparatus 80 of the present invention includes the above-described hydrogen-purifying hydrogen purification apparatus 10, the above-described fuel tank 2, and a pre-fueling apparatus 3A. The fuel treatment device 80 omits the fuel cell skirt 7 相 compared to the power generation device 6 of the third diagram. Fuel handling is more important than fuel handling and can be connected to different equipment for the desired application. The above-described fuel pretreatment device 30 can directly perform a reforming reaction to obtain a hydrogen-rich gas by using a conventional hydrogen generator, such as a fuel reformer. ~ The above-described fuel cell device 7G can directly manufacture a fuel cell device, for example, a conventional proton exchange membrane fuel cell using hydrogen gas and air (or oxygen) as a fuel. A pump (not shown) may be further connected between the fuel pre-processing device 30 and the fuel tank 20 (please refer to the third and fourth figures) between the fuel transfer line and the outlet 2〇c. Control the flow of fuel. [s] 12 201102344 The hydrogen purification device of the present invention and the power generation device or the fuel treatment device having the hydrogen purification device directly use the fuel of the fuel pretreatment device as a coolant for cooling the catalyst of the hydrogen purification device while The fuel also achieves preheating, which is a significant improvement of the advantages and effects of the present invention.
惟以上所述者，僅為本發明之較佳實施例，當不能用以 限定本發啊實施之麵，凡縣於本技藝人顿明顯可作 I化與修飾，皆應視為不悖離本發明之實質内容。 【圖式簡單說明】 第圖顯示本發明氫氣純化裝置的架構圖。 $圖顯示本务a月氫氣純化裝置的變化實施例的架構圖。 =二圖顯示具有轉明氫氣·裝獅發電裝置的架構圖。 第四圖顯示具有本發明氫氣純化裝置的燃料處理 隐圖。 木 【主要元件符號說明】 1〇 ' 10 氫氣純化震置 101殼體 lQla 内部空間 10比、101’ b催化劑區 103 富氫氣體注入口 105 ' 105> 氣體注入口 201102344 107 氫氣出口 109 冷卻劑輸送管 20 燃料槽 20a 出口 20b 入口 20c 出口 30 燃料電池前處理裝置 40 泵 50 冷卻劑流量控制單元 60 發電裝置 70 燃料電池裝置 80 燃料處理裝置However, the above is only a preferred embodiment of the present invention, and when it cannot be used to limit the implementation of the present invention, it is obvious that the county is clearly capable of being modified and modified by the skilled person. The essence of the invention. BRIEF DESCRIPTION OF THE DRAWINGS The figure shows the architecture of the hydrogen purifying apparatus of the present invention. The figure shows the architectural diagram of a variation of the hydrogen purification unit of the month. = The second diagram shows the architecture of a hydrogen-filled lion-powered unit. The fourth figure shows a fuel processing map with the hydrogen purifying apparatus of the present invention. Wood [Main component symbol description] 1〇' 10 Hydrogen purification shock 101 housing lQla Internal space 10 ratio, 101' b Catalyst zone 103 Hydrogen-rich gas injection port 105 '105> Gas injection port 201102344 107 Hydrogen outlet 109 Coolant delivery Tube 20 fuel tank 20a outlet 20b inlet 20c outlet 30 fuel cell pretreatment device 40 pump 50 coolant flow control unit 60 power generation device 70 fuel cell device 80 fuel treatment device