Claims (1)
201100168 七、申請專利範圍： 1. 該微孔多孔質物質為’⑻以氧化鋁(Al2〇3)及氧化矽(Si02)為主成 分、或(b)含炭成分或含氧化矽成分、或(C)以上⑻與⑻的混合物，並具有 微孔吸附(物理吸附)及表面陽離子交換(離子吸附)功能的天然或人工合 成的多孔質物質。 2. 該微孔多孔質物質的平均孔徑為3A~50〇A(lA=0.1nm)之範圍。 3. 該微孔多孔質物質的平均粒徑為lum〜2〇〇um之範圍。 4. 將該微孔多孔質物質施行附著加工時所使用的濕式黏著劑為，以水 玻璃(砂酸鈉水溶液)為代表的無機系黏著劑，或以有機系合成樹脂或合成 樹脂乳劑為主成分並以水分或以苯類、醇類、酮類、烷類、醛類等其中 至少一種的有機溶媒作為溶劑的一種濕式合成樹脂黏著劑。 Ο 5.將該微孔多孔質物質施行附著加工時所施加的附著對象基材為，含 有纖維類或陶瓷土類或塑膠類或不織布類等其中至少一種的材料或其應 用製品。 6. 將該微孔多孔質物質，添加在如申請專利範圍第4項的濕式黏著劑 中，並使其附著於如申請範圍第5項的附著對象基材上時的加工方法為， 浸泡加工與印刷加工。 7. 將該微孔多孔質物質，添加在如申請專利範圍第4項的濕式黏著劑 中’並放入模具中加壓成形的加工方法。 8. 將該微孔多孔質物質，與石膏或水泥等固態硬化剤混合加水後，放 入模具中自然硬化或加壓硬化成形的加工方法。 〇 9.將該微孔多孔質物質，添加在以聚胺甲酸系樹脂(PU)或乙嫌-醋酸乙 铺系樹脂(EVA)為主劑㈣式藥劑中-起混合發泡成形的加工方法。 10.將該微孔多孔質物質，添加在濕式造紙紙漿中混合攪拌，並依傳統 的造紙工程製成紙類製品的加工方法。 Π.如申請專利範圍第6項的加工方法中，本發明係先將該微孔多孔質 物質以該濕式黏著劑中所含有的同等或類似的有機溶媒、或以水分等溶 劑(以下簡稱含浸液)施行含浸封孔處理後，再添加於該滿式黏著劑中混合 攪拌$稱加工液)的—種前處理加卫方法。並在施行浸泡或印刷等附 著加工後，以自然乾燥或以含浸液軌化點附近的溫度加熱乾燥的—種 後處理加工方法。 12.如申請專利範圍第7項的加工方法中，本發明係先將該微孔多孔質 物質以該濕式黏著劑所含有的同等或類似的有機溶媒、或以水分等溶劑 6 201100168 浸封孔處理後’再添加於該濕式黏著劑中混合挽 J簡，f)的一種前處理加工方法。並在放入模具中施行加磨成 二者然乾燥或以含浸液的汽化點附近的溫度加熱乾燥的一 種後處理加工方法。 13. 請專利範圍第8項的加王方法中，本發明係先將該微孔多孔質 浸於固化成形所需的水分(以下簡稱含浸液)巾封孔處理後，再添加 石膏或水泥等固態硬化劑混合挽拌(以下簡稱加工液)的一種前處理加工 方$ 〇並在放入模具中加壓或自然硬化成形後，以自然乾燥或以含浸液 的汽化點附近的溫度加熱乾燥的一種後處理加工方法。 Ο201100168 VII. Patent application scope: 1. The microporous porous material is '(8) with alumina (Al2〇3) and cerium oxide (SiO2) as the main component, or (b) carbon-containing component or cerium oxide-containing component, or (C) A mixture of the above (8) and (8), and a natural or artificially synthesized porous substance having a function of microporous adsorption (physical adsorption) and surface cation exchange (ion adsorption). 2. The average pore diameter of the microporous porous material is in the range of 3A to 50 Å A (lA = 0.1 nm). 3. The average particle diameter of the microporous porous material is in the range of lum~2〇〇um. 4. The wet adhesive used for the adhesion processing of the microporous porous material is an inorganic adhesive represented by water glass (sodium aluminate aqueous solution) or an organic synthetic resin or a synthetic resin emulsion. The main component is a wet synthetic resin adhesive containing water or an organic solvent containing at least one of benzenes, alcohols, ketones, alkanes, aldehydes and the like as a solvent. Ο 5. The substrate to be adhered applied when the microporous porous material is subjected to the adhesion processing is a material containing at least one of a fiber or a ceramic soil, a plastic or a non-woven fabric, or a product thereof. 6. The method for processing the microporous porous material in a wet adhesive as disclosed in claim 4, and attaching it to the substrate to be attached according to item 5 of the application scope is: soaking Processing and printing processing. 7. A method of pressurizing the microporous porous material by adding it to a wet adhesive as set forth in Patent Application No. 4, and placing it in a mold. 8. The microporous porous material is mixed with water, such as gypsum or cement, and then added to water, and then placed in a mold to be naturally hardened or press hardened. 〇9. The microporous porous material is added to a processing method of mixing foam molding by using a polyurethane resin (PU) or an ethyl acetate-based resin (EVA) as a main agent (IV) . 10. The microporous porous material is added to a wet papermaking pulp to be mixed and stirred, and processed into a paper product according to a conventional papermaking process.加工. In the processing method of claim 6, the present invention first uses the microporous porous material as an equivalent or similar organic solvent contained in the wet adhesive, or a solvent such as moisture (hereinafter referred to as The impregnation liquid is subjected to the impregnation sealing treatment, and then added to the full-type adhesive and mixed and stirred to be a processing liquid. And after performing the immersion or printing and other attachment processing, the method of post-processing is dried by natural drying or by heating at a temperature near the point of the impregnation liquid. 12. In the processing method of claim 7, the present invention first encapsulates the microporous porous material with an equivalent or similar organic solvent contained in the wet adhesive or with a solvent such as moisture 6 201100168 A pretreatment processing method after the hole treatment is further added to the wet adhesive to mix and pull J, f). And a post-treatment processing method in which it is placed in a mold and subjected to grinding to dry or to heat and dry at a temperature near the vaporization point of the impregnation liquid. 13. In the method of adding the king of the eighth aspect of the patent, the present invention firstly immerses the microporous porous material in the water required for solidification molding (hereinafter referred to as an impregnation liquid), and then adds gypsum or cement. The solid-state hardener is mixed with a pre-treatment process (hereinafter referred to as a working fluid) and is dried or placed in a mold for pressing or natural hardening, and then dried naturally or at a temperature near the vaporization point of the impregnation liquid. A post-processing processing method. Ο
14.如申請專利範圍第9項的加工方法中，本發明係先將該微孔多孔質 物質含浸於發泡成形所料赋藥劑巾的，除了發泡樹齡劑和黏著劑 以外的藥劑，如架橋催賴等藥劑(以下_含浸液)中封减理後，再添 加主劑和黏著劑等其他藥劑混合授拌(以下簡稱加工液)的一種前處理加 工方法。並在施行發泡成形後’以自然乾燥或以含浸液的汽化點附近的 溫度加熱乾燥的一種後處理加工方法。 15. 如申請專利範圍第10項的加工方法中，本發明係先將該微孔多孔 質物質含浸於造紙工程所需的水分(以下簡稱含浸液)中封孔處理後，再添 加造紙紙漿等造紙工程所需的原料混合挽拌(以下簡稱加工液)的一種前 處理加工方法。並在造紙工程完成後，以自然乾燥或以含浸液的汽化點 附近的溫度加熱乾燥的一種後處理加工方法。 16. 如申請專利範圍第1項中的，含炭成分係指如活性炭或竹炭類之微 孔多孔質物質，含氧化矽成分係指如矽凝膠類之微孔多孔質 物質’含氧化鋁及氧化矽成分係指其結晶構造中因帶有負電荷而具有 5〇Meq/l〇〇g以上陽離子交換容量(CEC)的沸石類(zedifc)微孔多孔質物 質。其中’不論是天然礦石沸石或人工合成沸石或以各種燃灰為原料再 生製造而成的資源再生沸石都是沸石類的典型代表例。 17. 如申請專利範圍第11項〜第15項中的含浸封孔處理，係利用微孔 對液體的毛細現象(毛細管作用)將含浸液吸引進入多孔質物質的微孔内 部而達到封孔效果。藉此可防止因加工液中的，如樹脂、石膏、水泥、 紙漿織維等固態成分或發泡劑、黏著劑等藥劑對微孔内部的滲透所造成 的加工後的微孔堵塞進而減低微孔應有的吸附能力的現象。 18·如申請專利範圍第11項〜第15項中的含浸封孔處理的封孔效果(封 孔率），主要取決於含浸液的表面張力和密度、及微孔的半徑。亦即，含 7 201100168 浸液的表面張力愈大、或含浸液的密度與微孔的半徑愈小，含浸液會更 容易的被吸引進入微孔内，可達到更大的封孔效果》 19. 如申請專利範圍第U項〜第15項中的含浸封孔處理的封孔效果(封 孔率）’為了防止含浸封孔處理後的微孔内的含浸液，在前處理加工過程 中與微孔外部的加工液接觸而發生擴散現象，導致加工液中的固態成分 或其他藥劑擴散滲透進入微孔内，封孔率最好不得大於95〇/p “ 20. 如申請專利範圍第π項〜第15項中的含浸封孔處理時所使用的溶 劑、藥劑或水分等含浸液’基於封孔效果的考量，其表面張力最好是介 於HniN/n^OmN/mpOt)之範圍’其密度最好是等於或小於ig/cc。 21·如申請專利範圍第η項和第12項中的加工液，可依加工條件的需 要或微孔多孔質物質的粒徑大小，添加適量的水分或有機溶媒等溶劑調 〇 整其黏度大小。亦即，微孔多孔質物質的粒徑愈小，則加工液的黏度愈 大’可增加微孔多孔質物質在後處理加工後的露出度。 ’ 22. 如申請專利範圍第2項中的微孔多孔質物質的平均孔徑，基於封孔 效果的考量，不得大於500Α，且不得小於水分子或有機溶媒等溶劑成分 的分子徑。亦即，微孔多孔質物質的平均孔徑最好是介於3入飞⑽入之範 圍。 23. 如申請專利範圍第3項中的微孔多孔質物質的平均粒徑，基於濕式 黏著劑的加工特性(黏度與黏著強度)的考量，最好是介於lum〜2〇〇11〇1之 範圍。亦即’如徼孔多孔質物質的粒徑小於1職時，則會因加工液的高 黏度而景>響其在加工液中的分散性及後處理加工後的均勻性；如微孔多 Q 孔質物質的粒徑大於200um時，則會因加工液的低黏度(低黏著強度)而 降低其在附著對象基材上的附著性β 24. 如申請專利範園第4項中的濕式黏著劑係擇自，聚醋酸乙烯系⑺乂八) 樹脂或其、谈·紐乙齡(EVA)樹脂或其_、麗克力系樹脂或 其乳劑、聚胺甲酸系(PU)樹腊或其乳劑、環氧系樹腊或其乳劑、乙酸系 纖維素(MC或CMC)、水玻璃(砂酸納水溶液Na2si〇3)等為主成分的其中 至少一種的黏著劑。 、 2^如申請專利範圍第4項中的濕式合成樹脂黏著劑，可依主成分的樹 脂種類選料合的糊。卿，非極性騎水賴絲好朝苯類、醇 類、酮類、烷類、醛類等其中至少一種的有機溶媒作為溶劑(溶液系），而 具極性的親水性樹脂或其乳劑可選用水分作為主要溶劑(水分散系）。 26.如申請專利範圍第4項中的濕式合成樹磨黏著劑，為了防止彿石類 8 201100168 微孔多孔質物質的表面因黏著劑的堆積而造成表面陽離子交換功能的喪 失或劣化現象’最好選用陰離子型(具負極性或負電荷)的樹脂或其乳劑。 27. 如申請專利範圍第4項中的濕式合成樹脂黏著劑，可依如申請範圍 第5項中的附著對象基材的親水性及其使用目的選擇適合的樹脂或其乳 劑。亦即，附著對象基材為親水性並適用於氣體吸附材及水質淨化材時， 最好選用如聚醋酸乙烯系(PVA)或乙稀-醋酸乙嫌系樹脂(EVA)等親水性 較大的樹脂或其乳劑。而附著對象基材為疏水性或僅適用於氣體吸附材 時，可選用如壓克力系或聚胺甲酸系(PU)等親水性較小或具疏水性的樹 脂或其乳劑》 28. 如申請專利範圍第5項中的附著對象基材，纖維類係擇自人造絲鐵 維、棉纖維、紙漿中至少一種的纖維，陶瓷土類係擇自含氧化物、氮化 〇 物、硼化物、碳化物中至少一種的黏土、高嶺土等陶瓷土，塑膠類係擇 自以尚分子量的合成樹鹿為主要成分的聚丙嫌(PP)、聚乙儲(PE)、聚氯乙 嫌(PVC)、聚對苯二甲酸乙二酯(pet)、聚苯乙燦(pS)或仙8樹脂十至少 一種的塑膠材料，不織布類係擇自以任何纖維為原料的一種無紡布。 29. 如申請專利範圍第6項中的加工方法，浸泡加工係將⑻纖維類 織布類基材浸泡於如申請專利範圍如項的加工液中一定時間後從加工 ，中取出’再以上τ滾輪將其錄的加卫液播出，或將⑼喊類基材一 邊浸泡於同加讀中-邊滾域拌的—種加卫方法^印刷加 布類或娜類基材平整固定後，以網印等印刷方式將^工液 全面的或局部的均勻塗抹在基材上的一種加工方法。 狀 〇 請專利範圍第7項中的加卫方法，係將如中請專利範圍第12 種加工3絲紙贴f ’域成科塊或崎ώ赫对造粒的一 =·如申請專利範園第8項中的加工方法係將如申請專利 32二具中自然:硬化或加麼硬化成形的一種加工方法。 =加工液取細巾自峨^%=^法糊範圍第Μ 項的^工申液料i範傳圍統第的方法’係以如申請專利範圍第！5 法。液利用傳統的造紙方法或既成的造紙設備造紙的一種加工方 :工孔錄料濕式加工法 "範圍第25項的，纖維類和不織布基材加工製 201100168 品可應用作減體吸畴、水f淨化材、鱗包 j 域鮮包裝材、壁域簾等室_材等。 所加項的本發顿微孔纽質师的濕式加工法 的製抑，可應用作為氣體吸附材、水質淨化材、抗菌劑或精 油芳香劑或驅蚊避蟲劑等各種機能材料的載體等。 L6.經J請專利範圍第13項的本發明的微孔多孔質物質的濕式加工法 工製ΐ的製品，可應用作為氣體吸酣、室内顺建材、除臭造形 置物、抗菌劑或芳香劑等各種機能材料的載體等。 Ο 37.經申請專利範圍帛Μ項的本發明的微孔多孔質物質的濕式加工法 所加工製颜製品’可應肖料縫吸耐、吸耐、保鮮包裝材 墊/床墊/座塾/地毯墊等各種充填材等。 讯經申請專利範圍帛ls項的本發明的微孔多孔質物f的濕式加工法 所加工製成的製品’可應用作為氣體吸附材、水質淨化材、保鮮包 壁紙窗簾等室内用材等。 展材14. In the processing method of claim 9, the present invention first impregnates the microporous porous material with a medicament other than the foaming agent and the adhesive, such as a foaming agent and an adhesive. After the agent is immersed in a remedy (hereinafter, the immersion liquid), a pretreatment processing method in which another agent such as a main agent and an adhesive is mixed and mixed (hereinafter referred to as a working liquid) is added. And after performing the foam forming, a post-treatment processing method of drying by natural drying or heating at a temperature near the vaporization point of the impregnation liquid. 15. In the processing method of claim 10, the present invention first impregnates the microporous porous material with water (hereinafter referred to as an impregnation liquid) required for papermaking, and then adds papermaking pulp, etc. A pretreatment processing method for mixing and mixing raw materials (hereinafter referred to as processing fluids) required for papermaking engineering. And after the completion of the papermaking process, a post-treatment processing method which is naturally dried or dried by heating at a temperature near the vaporization point of the impregnation liquid. 16. In the first paragraph of the patent application, the carbon-containing component refers to a microporous porous material such as activated carbon or bamboo charcoal, and the cerium oxide-containing component refers to a microporous porous material such as cerium gel. The cerium oxide component is a zeolite-based (zedifc) microporous porous material having a cation exchange capacity (CEC) of 5 〇Meq/l 〇〇g or more due to a negative charge in its crystal structure. Among them, the resource-regenerated zeolite which is produced by natural ore zeolite or synthetic zeolite or regenerated by using various kinds of ash is a typical representative example of zeolites. 17. For the impregnation sealing treatment in the 11th to 15th paragraphs of the patent application, the capillary phenomenon (capillary action) of the liquid is used to attract the impregnation liquid into the pores of the porous substance to achieve the sealing effect. . Therefore, it is possible to prevent microporous clogging after processing due to penetration of solid components such as resin, gypsum, cement, pulp, etc., or foaming agents, adhesives, and the like into the inside of the micropores in the working fluid, thereby reducing micromanagement. The phenomenon that the pores should have the adsorption capacity. 18. The sealing effect (sealing rate) of the impregnation sealing treatment in the eleventh to fifteenth claims of the patent application mainly depends on the surface tension and density of the impregnation liquid and the radius of the micropores. That is, the greater the surface tension of the 7 201100168 immersion liquid, or the smaller the density of the impregnation liquid and the radius of the micropores, the more easily the impregnation liquid is attracted into the micropores, which can achieve a larger sealing effect. . For the sealing effect (sealing rate) of the impregnation sealing treatment in the U- to 15th section of the patent application scope, in order to prevent the impregnation liquid in the micropores after the impregnation sealing treatment, during the pretreatment processing The diffusion of the working fluid outside the micropores causes diffusion of solid components or other agents in the processing fluid into the micropores, and the sealing ratio is preferably not more than 95 〇 / p " 20. For example, the πth item of the patent application scope ~ The impregnation liquid such as solvent, chemical or water used in the impregnation sealing treatment in item 15 is based on the sealing effect, and the surface tension is preferably in the range of HniN/n^OmN/mpOt) The density is preferably equal to or less than ig/cc. 21· As in the processing liquids of items n and 12, the amount of water may be added depending on the processing conditions or the particle size of the microporous porous material. Or solvent such as organic solvent The viscosity is small, that is, the smaller the particle size of the microporous porous material, the greater the viscosity of the working fluid 'can increase the exposure of the microporous porous material after post-treatment.' 22. As claimed in the patent scope The average pore diameter of the microporous porous material in the two items shall not exceed 500 Α based on the sealing effect, and shall not be less than the molecular diameter of the solvent component such as water molecules or organic solvents, that is, the average pore diameter of the microporous porous material. It is best to be in the range of 3 into the fly (10). 23. The average particle size of the microporous porous material in the third paragraph of the patent application is based on the processing characteristics (viscosity and adhesion strength) of the wet adhesive. Preferably, it is in the range of lum~2〇〇11〇1. That is, if the particle size of the porous material of the pupil is less than 1, it will be processed due to the high viscosity of the processing liquid. Dispersibility in liquid and uniformity after post-treatment; if the particle size of microporous multi-Q pore material is more than 200um, the substrate will be lowered due to the low viscosity (low adhesion strength) of the processing liquid. Adhesion β on the application 24. The wet adhesive in item 4 is selected from the group consisting of poly(vinyl acetate) (7) 乂8) resin or its Renewal EVA resin or its _, rickett resin or its emulsion, polyurethane Adhesion of at least one of the main component of the PU powder or its emulsion, epoxy wax or emulsion thereof, acetic acid cellulose (MC or CMC), water glass (Na2si〇3 aqueous solution) 2, such as the wet synthetic resin adhesive in the fourth paragraph of the patent application, can be selected according to the type of resin of the main component. Qing, non-polar riding water is good to benzene, alcohol, An organic solvent of at least one of a ketone, an alkane, an aldehyde, and the like is used as a solvent (solution system), and a hydrophilic hydrophilic resin or an emulsion thereof may optionally use water as a main solvent (water dispersion system). 26. The wet synthetic tree grinding adhesive according to item 4 of the patent application scope, in order to prevent the surface cation exchange function from being lost or deteriorated due to the accumulation of adhesive on the surface of the Foshan 8 201100168 microporous porous material. An anionic (negative or negatively charged) resin or emulsion thereof is preferred. 27. The wet synthetic resin adhesive of claim 4, wherein a suitable resin or an emulsion thereof can be selected according to the hydrophilicity of the substrate to be adhered in the fifth aspect of the application and the purpose of use thereof. That is, when the substrate to be adhered is hydrophilic and is suitable for use in a gas adsorbent material and a water purification material, it is preferable to use a hydrophilic resin such as polyvinyl acetate (PVA) or ethylene-acetate (EVA). Resin or its emulsion. When the substrate to be attached is hydrophobic or only suitable for a gas adsorbent, a hydrophilic or hydrophobic resin such as an acrylic or polyurethane (PU) or an emulsion thereof may be used. The substrate to be attached in the fifth application of the patent scope, the fibers are selected from at least one of rayon, cotton fiber and pulp, and the ceramic soil is selected from the group consisting of oxides, tantalum nitrides and boride. At least one of the carbides, clay, kaolin and other ceramic soils, and the plastics are selected from the group consisting of polyacrylic acid (PP), polyethylidene (PE), and polychloroethylene (PVC) which are mainly composed of synthetic tree deer. A plastic material of at least one of polyethylene terephthalate (pet), polystyrene (pS) or celery 8 resin, and a non-woven fabric selected from a nonwoven fabric using any fiber. 29. If the processing method in the sixth paragraph of the patent application is applied, the soaking processing system (8) the fiber-like woven fabric substrate is immersed in the processing liquid as claimed in the patent application for a certain period of time, and then taken out from the processing, and then τ The roller broadcasts the recorded accelerator liquid, or (9) shouts the substrate while immersing it in the same reading-side-rolling-mixing method--printing plus cloth or Na-type substrate flattening and fixing, A processing method in which a working liquid is uniformly or partially uniformly applied to a substrate by a printing method such as screen printing. In the case of the scope of patent application, the method of reinforcement is to apply the patent for the 12th processing of the 3rd paper, the f' domain, or the granulation. The processing method in item 8 of the garden will be a natural one in the patent application 32: hardening or hardening forming. = The processing liquid takes the fine towel from the 峨^%=^法糊范围第Μ The item ^工申液料 i Fan Chuan Encyclopedia's method is as follows: 5 methods. The liquid is processed by a conventional papermaking method or a papermaking equipment of a conventional papermaking machine: the wet processing method of the working hole recording material", the scope of the 25th item, the processing of the fibrous and non-woven substrate substrate 201100168 can be applied as a reduction body , water f purification materials, scales j domain fresh packaging materials, wall curtains and other room materials. The suppression of the wet processing method of the Benton Microporous Newcomer can be applied as a carrier for various functional materials such as gas adsorbing materials, water purification materials, antibacterial agents or essential oil fragrances or mosquito repellents. Wait. L6. The product of the wet processing method of the microporous porous material of the present invention according to Item 13 of the Patent Application No. 13 can be applied as a gas suction, an indoor building material, a deodorizing storage, an antibacterial agent or a fragrance. Carriers of various functional materials such as agents. Ο 37. The wet processing method of the microporous porous material of the present invention according to the scope of the patent application is processed by the wet processing method, which can be used for the suction resistance, the absorption resistance, the fresh-keeping packaging material pad/mattress/seat Various filling materials such as 塾/carpet mats. The product processed by the wet processing method of the microporous porous material f of the present invention, which is a patent application, is applied as a gas adsorbing material, a water purification material, a fresh-keeping cloth, a wallpaper curtain, and the like. Exhibition material