201041737 六、發明說明： 【發明所屬之技術領域】 本發明關於觸控面板所使用的層合壓出樹脂板及表面 塗覆板。 【先前技術】 例如’於導航系統、攜帶資訊終端、產業機械的操作 0 面板、個人電腦的畫面、攜帶式遊戲機等中，使用附有透 明電極的觸控面板。作爲觸控面板所用的板，除了薄的玻 璃，還可舉出樹脂製板。於觸控面板中，例如有以手指直 接接觸而操作者或藉由觸控筆來操作者等，透明性、耐衝 撃性、輕量性、表面的不易損傷性係被重視。對於如此的 要求，由於薄的玻璃係耐衝撃性、輕量性差，故近來多使 用樹脂製板。 作爲對應於此等要求的樹脂製板，專利文獻1中記載 Q 於聚碳酸酯樹脂薄片的至少一面上層合有硬度85〜95的 熱塑性聚胺基甲酸酯樹脂層之聚碳酸酯樹脂積層板。又， 專利文獻2中記載於高分子樹脂基板上依順序層合厚度爲 5 0〜3 0 0 μιη的鉛筆硬度爲3 Η以上之活性光線硬化層（A )、與厚度爲1〜20μιη的鉛筆硬度爲4H以上之硬塗層（ Β)而成的高分子樹脂積層體。 然而，專利文獻1中記載的樹脂製板係藉由在聚碳酸 酯樹脂薄片上所層合的聚胺基甲酸酯樹脂層來彌補聚碳酸 酯樹脂薄片的容易損傷性。但是，聚胺基甲酸酯樹脂由於 -5- 201041737 剛性低，而受到基材的聚碳酸酯樹脂薄片之影響’以觸控 筆等描寫文字等之際，表面會變形。 又，專利文獻2中記載的樹脂製板，係藉由在活性光 線硬化層（A)上層合硬塗層（B)，而可提高硬塗層（B )的硬度。然而，由於必須在基板上分別層合活性光線硬 化層（A )與硬塗層（B )，故在生產性有問題。 [先前技術文獻] [專利文獻] [專利文獻1]特開平7-2053 85號公報 [專利文獻2]特開200 1 -322 1 97號公報 【發明內容】 發明所欲解決的問題 本發明之課題爲提供表面不易損傷，而且比較容易製 造的觸控面板用層合壓出樹脂板以及觸控面板用表面塗覆 板。 用以解決問題的手段 本發明者爲了解決上述問題，重複專心致力的硏究， 結果發現由以下的構成所組成的解決手段，終於完成本發 明。 (1) 一種觸控面板用層合壓出樹脂板，其係於聚碳 酸酯樹脂層的觸控側之表面上，藉由共壓出成形來層合丙 -6 - 201041737 烯酸樹脂層所成。 (2) 如前述（1)記載的觸控面板用層合壓出樹脂板 ，其中前述聚碳酸酯樹脂層的厚度係全體的厚度之50 %以 上。 (3) 如前述（1)或（2)記載的觸控面板用層合壓 出樹脂板，其係於前述聚碳酸酯樹樹脂層的兩面，層合丙 烯酸樹脂層所成。 0 (4)如前述（1)〜（3)中任一項記載的觸控面板 用層合壓出樹脂板，其中前述丙烯酸樹脂層係由甲基丙烯 酸樹脂及橡膠狀聚合物所成。 (5) —種觸控面板用表面塗覆板，其係於前述（1) 〜（4 )中任一項之層合壓出樹脂板的觸控側之表面上， 被覆硬化膜所成。 (6) 如前述（5)記載的觸控面板用表面塗覆板，其 中前述硬化膜係具有耐擦傷性的硬化皮膜。 ❹ 發明的效果 本發明的層合壓出樹脂板，由於表面不易損傷，故適 合利用於觸控面板用途。又，於前述層合壓出樹脂板的觸 控側之表面上被覆硬化膜所成表面塗覆板，係可合適地利 用於使前端爲尖的觸控筆等進行碰觸之用途。而且，本發 明的層合壓出樹脂板係藉由共壓出成形而得的板，由於不 需要如以往地在基板上分別層合活性光線硬化層與硬塗層 ，故可比較容易地製造。 201041737 【實施方式】 實施發明的形態 本發明的層合壓出樹脂板（以下亦稱爲壓出樹脂板） ，係於聚碳酸酯樹脂層的至少觸控側之表面上，藉由共壓 出成形來層合丙烯酸樹脂層所成，使用於觸控面板。 構成前述聚碳酸酯樹脂層的聚碳酸酯樹脂，係單體單 位彼此的鍵結部皆由碳酸酯基（-0- ( c = o ) -0-)所構成 的聚合物。 作爲前述聚碳酸酯樹脂，例如可舉出藉由界面聚縮合 法、熔融酯交換法等使1種以上的二價酚與1種以上的羰 基化劑反應而得之樹脂’藉由固相酯交換法等使碳酸酯預 聚物聚合而得之樹脂，藉由開環聚合法使環狀碳酸酯化合 物聚合而得之樹脂等。 作爲前述二價酚，例如可舉出氫醌、間苯二酚、 4，4 ’ -二羥基聯苯、雙（4 -羥苯基）甲烷、雙{ ( 4 -羥基-3,5-二甲基）苯基}甲烷、1,1_雙（4_羥苯基）乙烷、1，1_ 雙（4-羥苯基）-1-苯基乙烷、2,2_雙羥苯基）丙烷（ 通稱雙酚A) 、2，2-雙{ (4-羥基-3-甲基）苯基}丙烷、 2,2-雙{ (4 -羥基-3,5 -二甲基）苯基}丙烷、2,2-雙{ (4-羥 基-3, 5-二溴）苯基}丙烷' 2,2-雙{(3-異丙基-4-羥基）苯 基}丙烷、2,2-雙{ (4 -羥基-3-苯基）苯基}丙烷、2,2-雙（ 4·羥苯基）丁烷、2,2 -雙（4-羥苯基）-3 -甲基丁烷、2，2-雙（4-羥苯基）-3,3 -二甲基丁烷、2,4-雙（4 -羥苯基）-2-甲基丁烷、2,2-雙（4 -羥苯基）戊烷、2,2-雙（4 -羥苯基 -8- 201041737 )-4-甲基戊烷、ι，ΐ-雙（4-羥苯基）環己烷、 羥苯基）-4-異丙基環己烷、1,1-雙（4-羥苯基 甲基環己烷、9,9-雙（4-羥苯基）莽、9,9-雙{ 甲基）苯基}弗、α,α’-雙（4-羥苯基）-〇-二異 α,α’-雙（4-羥苯基）-m-二異丙基苯、α，α’-雙 )-Ρ-二異丙基苯、1,3-雙（4-羥苯基）-5,7-二 、4,4’-二羥基二苯基颯、4,4’-二羥基二苯基亞 0 二羥基二苯基硫化物、4,4’-二羥基二苯基酮、 基二苯基醚、4，4’-二羥基二苯基酯等。 其中，較佳爲使用由雙酚A、2,2-雙{ ( 4-基）苯基}丙烷、2,2_雙（4-羥苯基）丁烷、2, 苯基）-3-甲基丁烷、2,2·雙（4-羥苯基）-3,3-、2,2-雙（4·羥苯基）-4-甲基戊烷、1，1_雙（4 3,3,5-三甲基環己烷及〇1，〇1’-雙（4-羥苯基）-111 苯所組成族群所選出的1種以上之二價酚，更 Q 的單獨使用，雙酚Α與1，1-雙（4-羥苯基）-3 環己烷之倂用、雙酚A與2,2-雙{( 4-羥基-3-}丙烷及α，α’-雙（4_羥苯基）-m-二異丙基苯所 所選出的1種以上之二價酚之倂用。 作爲前述羰基化劑，例如可舉出光氣等的 酸二苯酯等的碳酸酯、二價酚的二鹵甲酸酯等 等。 作爲構成前述丙烯酸樹脂層的丙烯酸樹脂 甲基丙烯酸樹脂。前述甲基丙烯酸樹脂可爲甲 1，1-雙（4-)-3,3,5-三 (4-羥基-3- 丙基苯、 (4-羥苯基 甲基金剛烷 丨颯、4,4’-4,4’-二羥 •羥基-3-甲 2-雙（4-羥 二甲基丁烷 羥苯基）--二異丙基 佳爲雙酚A ,3,5-三甲基 甲基）苯基 •組成族群 羰基鹵、碳 的鹵甲酸酯 ，一般使用 基丙烯酸甲 -9- 201041737 酯單位1 ο 〇重量％的甲基丙烯酸甲酯均聚物，也可爲甲基 丙烯酸甲酯和與該甲基丙烯酸甲酯可共聚合的1種以上之 其它單體的共聚物。其中，較佳爲以甲基丙烯酸甲酯單位 當作主成分的樹脂，具體地較佳爲含有50重量％以上的 甲基丙烯酸甲酯單位之甲基丙烯酸甲酯樹脂，更佳爲含有 70重量％以上的甲基丙烯酸甲酯單位之甲基丙烯酸甲酯樹 脂。 作爲與前述甲基丙烯酸甲酯可共聚合的其它單體’例 如可舉出甲基丙烯酸乙酯、甲基丙烯酸丁酯、甲基丙烯酸 環己酯、甲基丙烯酸苯酯、甲基丙烯酸苄酯、甲基丙烯酸 2-乙基己酯、甲基丙烯酸2-羥乙酯等的甲基丙烯酸甲酯以 外之甲基丙烯酸酯類，或丙烯酸甲酯、丙烯酸乙酯、丙烯 酸丁酯、丙烯酸環己酯、丙烯酸苯酯、丙烯酸苄酯、丙烯 酸2-乙基己酯' 丙烯酸2-羥乙酯等的丙烯酸酯類。又， 亦可舉出苯乙烯或經取代的苯乙烯類，例如氯苯乙烯、溴 苯乙烯等的幽化苯乙烯類，或乙烯基甲苯、α-甲基苯乙烯 等的烷基苯乙烯類。再者，也可舉出甲基丙烯酸、丙烯酸 等的不飽和酸類、丙烯腈、甲基丙烯腈、馬來酸酐、苯基 馬來醯亞胺、環己基馬來醯亞胺等。 丙烯酸樹脂層較佳爲含有橡膠狀聚合物。藉此，可使 層合壓出樹脂板不易破裂。特別地，較佳爲藉由於甲基丙 烯酸樹脂中混合橡膠狀聚合物，而使丙烯酸樹脂層成爲由 甲基丙烯酸樹脂及橡膠狀聚合物所成的層。作爲前述橡膠 狀聚合物’例如可舉出丙烯酸系多層構造聚合物，或於5 -10- 201041737 〜80重量份的橡膠狀聚合物中接枝聚合20〜95重量份的 丙嫌酸系不飽和單體等之乙烯性不飽和單體而成的接枝共 聚物等。 前述丙烯酸系多層構造聚合物較佳爲含有20〜60重 量％左右的橡膠彈性層，較佳爲具有硬質層當作最外層， 更佳爲含有硬質層當作最內層。 前述橡膠彈性層較佳係玻璃轉移點（T g )未達2 5 °C 0 的丙烯酸系聚合物之層，具體地較佳爲對由丙烯酸低級烷 酯、甲基丙烯酸低級烷酯、丙烯酸低級烷氧基烷酯、丙烯 酸氰乙酯、丙烯醯胺、丙烯酸羥基低級烷酯、甲基丙烯酸 羥基低級烷酯、丙烯酸及甲基丙烯酸所選出的1種以上之 單官能單體，以甲基丙烯酸烯丙酯等的多官能單體進行交 聯所成的聚合物之層。作爲低級烷基，可舉出碳數1〜8 個左右的直鏈或支鏈烷基，作爲低級烷氧基烷基，可舉出 碳數1〜8個左右的直鏈或支鏈烷氧基烷基。 Q 前述硬質層較佳係Tg爲25 °C以上的丙烯酸系聚合物 之層，具體地較佳爲以具有碳數1〜4個的烷基之甲基丙 烯酸烷酯單獨地或當作主成分所聚合成的均聚物或共聚物 。當爲以甲基丙烯酸烷酯當作主成分的共聚物時，作爲共 聚合成分，可使用其它甲基丙烯酸烷酯或丙烯酸烷酯、苯 乙烯、經取代的苯乙烯、丙烯腈、甲基丙烯腈等的單官能 單體，再者亦可添加多官能單體當作交聯聚合物。 丙烯酸系多層構造聚合物，例如記載於特公昭5 5 -2 75 76號公報、特開平6-8073 9號公報、特開昭49-23 292 -11 - 201041737 號公報等中。 於在前述5〜80重量份的橡膠狀聚合物中接枝聚合 20〜95重量份的乙烯性不飽和單體而成的接枝共聚物中 ’作爲前述橡膠狀聚合物，例如可使用聚丁二烯橡膠、丙 烯腈/丁二烯共聚物橡膠、苯乙烯/ 丁二烯共聚物橡膠等的 二烯系橡膠、聚丙烯酸丁酯、聚丙烯酸丙酯、聚丙烯酸 2-乙基己酯等的丙烯酸系橡膠、乙烯/丙烯/非共軛二烯系 橡膠等。又，作爲於此橡膠狀聚合物中接枝共聚合用的乙 烯性單體，例如可舉出苯乙烯、丙烯腈、（甲基）丙烯酸 烷酯等。此等接枝共聚物例如記載於特開昭5 5 - 1 4 7 5 1 4號 公報、特公昭47-9740號公報等中。 於使橡膠狀聚合物分散在丙烯酸樹脂中時，相對於 1〇〇重量份的丙烯酸樹脂，通常以3〜150重量份，較佳 以5〜5 0重量份之比例使橡膠狀聚合物分散。橡膠狀聚合 物的量若太多，則表面硬度會降低。又，橡膠狀聚合物的 量若太少，則難以得到使層合壓出樹脂板不易破裂的效果 〇 再者，於聚碳酸酯樹脂層及丙烯酸樹脂層中，各自例 如亦可添加光擴散劑、消光劑、染料、光安定劑、紫外線 吸收劑、抗氧化劑、脫模劑、難燃劑、抗靜電劑等的1種 以上之添加劑。 本發明的層合壓出樹脂板係藉由共壓出成形將聚碳酸 酯樹脂層與丙烯酸樹脂層層合一體化而製造。此共壓出成 形係可藉由使用2台或3台的一軸或二軸之壓出機，將前 -12- 201041737 述聚碳酸酯樹脂層的材料與丙烯酸樹脂層的材料各自熔融 混煉後，通過供料頭式（feedblock )模頭或多歧管（ multi-manifold)模頭等來層合而進行。 經層合一體化的薄片狀之熔融層合壓出樹脂板，例如 可使用輥單元等來進行冷卻固化，而得到本發明的層合壓 出樹脂板。以下’參照圖面來詳細說明本發明的層合壓出 樹脂板之製造方法的一實施形態。 q 圖1係顯示本實施形態的層合壓出樹脂板之製造方法 的槪略說明圖。圖2係顯示本實施形態的金屬輥及彈性輥 之槪略截面說明圖。如圖1中所示地，首先將聚碳酸酯樹 脂及丙烯酸樹脂各自以個別的壓出機1、2加熱，一邊熔 融混煉’ 一邊由共壓出成形用的模頭3壓出，而層合一體 化。 接著，將由模頭3所共壓出的薄片狀熔融層合壓出樹 脂板4，夾入在略水平方向中相對向配置的2支冷卻輥5 Q 中，而得到觸控面板用層合壓出樹脂板11。 冷卻輥5係如圖2所示也，由高剛性的金屬輥6與在 外周部具備金屬製薄膜9的彈性輥，即金屬彈性輥7所構 成。金屬輥6及金屬彈性輥7係至少一方連接於馬達等的 旋轉驅動手段，兩輥以指定的圓周速度旋轉而構成。 高剛性的金屬輥6係將在金屬輥6及金屬彈性輥7間 所扶持後的薄片狀層合壓出樹脂板1 1捲繞之捲繞輥。金 屬輥6係沒有特別的限定，可採用以往在壓出成形所使用 的一般金屬輥。作爲具體例，可舉出鑽孔型輥或螺旋輥等 -13- 201041737 。金屬輥6的表面狀態，例如可爲鏡面’也可具有花紋或 凹凸等。 金屬彈性輥7具備略圓柱狀的旋轉自如設置之軸輥8 、及以覆蓋此軸輥8的外周面之方式所配置之與熔融層合 壓出樹脂板4接觸的圓筒形金屬製薄膜9，在此等軸輥8 與金屬製薄膜9之間封入流體1 0，藉此金屬彈性輥7顯 示彈性。前述軸輥8係沒有特別的限定，例如由不銹鋼等 所構成。 金屬製薄膜9例如係由不銹鋼等所構成，其厚度較佳 爲2〜5mm左右。此金屬製薄膜9更佳爲具有彎曲性或可 撓性等’較佳爲沒有焊接部的無縫構造。具備如此金屬製 薄膜9的金屬彈性輥7，係耐久性優異，同時若將金屬製 薄膜9鏡面化，也可與通常的鏡面輥同樣的操作，若在金 屬製薄膜9上賦予花紋或凹凸，則成爲可轉印其形狀的輥 ，故使用容易。 將金屬製薄膜9固定在軸輥8的兩端部，於軸輥8與 金屬製薄膜9之間封入流體1 〇。作爲流體1 〇，例如可舉 出水、油等。藉由對此流體1 〇進行溫度控制，而可控制 金屬彈性輕7的溫度。於前述溫度控制中，例如可採用 PID控制或ON-OFF控制等眾所周知的控制方法。再者， 亦可使用空氣等的氣體代替流體1〇。 若在如此的金屬輕6與金屬彈性輥7間扶持熔融層合 壓出樹脂板4，則金屬彈性輥7係經由熔融層合壓出樹脂 板4，沿著金屬輥6的外周面以凹狀進行彈性變形，金屬 -14- 201041737 彈性輥7與金屬輥6係經由熔融層合壓出樹脂板4而以指 定的接觸長度L進行接觸。 前述接觸長度L可爲1〜20mm，較佳爲1〜10mm， 更佳爲1〜7mm。爲了使前述接觸長度L成爲指定的値， 例如可藉由調整金屬製薄膜9的厚度、流體10的封入量 等來任意地進行。再者，前述接觸長度L係意味經由熔融 層合壓出樹脂板4，連接金屬彈性輥7與金屬輥6開始接 0 觸的點與結束接觸之點的直線之長度。 若以接觸長度L使金屬彈性輥7與金屬輥6經由熔融 層合壓出樹脂板4進行接觸，則金屬輥6及金屬彈性輥7 係變成對於熔融層合壓出樹脂板4以面接觸而固定，在此 等輥間所扶持的熔融層合壓出樹脂板4係一邊被均勻加壓 成面狀，一邊進行製膜。若如此地進行製膜，則可抑制應 變殘留在層合壓出樹脂板U內，所得之層合壓出樹脂板 1 1的加熱收縮特性與遲滯値有變小的傾向。因此，對於 Q 該層合壓出樹脂板11，在溫度環境嚴苛的場所之使用中 ，具有抑制觸控面板的變形之效果。 具體地，在160°C的熱環境下將層合壓出樹脂板11 放置3 0分鐘時的層合壓出樹脂板1 1之壓出方向的收縮率 S 1 ( % )及寬度方向的收縮率S 2 ( % )，皆有成爲0〜5 % 的傾向。收縮率SI、S2爲負，即未達〇%時，若將層合壓 出樹脂板加熱，則進行膨脹，在該層合壓出樹脂板上被覆 硬化膜時，於該硬化膜中導入龜裂而有發生破裂之虞。又 ’收縮率s 1、S 2若超過5 % ’則在加熱層合壓出樹脂板之 -15- 201041737 際’收縮變大’所得製品的收獲率降低。前述收縮率Si 、S 2的算出方法係如後述。 又’層合壓出樹脂板11係有遲滯値變成2〇〇nm以下 的傾向。於液晶面板上安裝觸控面板時，構成該觸控面板 的層合壓出樹脂板11之遲滯値若爲200nm以下，即使戴 用偏光眼鏡’也不會發生在觸控面板看到著色的現象。前 述遲滯値係如後述地，藉由微小面積雙折射率計進行測定 所得之値。 在減小層合壓出樹脂板1 1的加熱收縮特性與遲滯値 的方面’於金屬輥6與金屬彈性輥7內夾持熔融層合壓出 樹脂板4而進行成形之際，較佳爲在冷卻固化前或冷卻固 化的過程中，於兩輥內夾持熔融層合壓出樹脂板4。具體 地，相對於聚碳酸酯樹脂或丙烯酸樹脂的熱變形溫度（Th )而言，金屬輥6及金屬彈性輥7的表面溫度（Tr)宜爲 (Th-2(TC ) STrS ( Th + 20t )，較佳爲（Th-15。。）201041737 VI. Description of the Invention: [Technical Field] The present invention relates to a laminated extruded resin sheet and a surface coated sheet used in a touch panel. [Prior Art] For example, in a navigation system, a portable information terminal, an operation panel of an industrial machine, a screen of a personal computer, a portable game machine, or the like, a touch panel with a transparent electrode is used. As the board used for the touch panel, in addition to the thin glass, a resin plate can be cited. In the touch panel, for example, an operator or a stylus pen is directly contacted by a finger, and transparency, impact resistance, light weight, and surface non-damage are emphasized. For such a request, since a thin glass is resistant to punching and lightness, a resin plate has recently been used. Patent Document 1 discloses a polycarbonate resin laminate in which a thermoplastic polyurethane resin layer having a hardness of 85 to 95 is laminated on at least one surface of a polycarbonate resin sheet. . Further, Patent Document 2 discloses that an active ray hardened layer (A) having a pencil hardness of 3 Å or more and a pencil having a thickness of 1 to 20 μm is laminated on the polymer resin substrate in this order with a thickness of 50 to 300 μm. A polymer resin laminate having a hardness of 4H or more of a hard coat layer (Β). However, the resin plate described in Patent Document 1 compensates for the easy damage of the polycarbonate resin sheet by the polyurethane resin layer laminated on the polycarbonate resin sheet. However, the polyurethane resin is affected by the polycarbonate resin sheet of the substrate due to the low rigidity of -5-201041737. When the characters are written by a stylus or the like, the surface is deformed. Further, in the resin plate described in Patent Document 2, the hardness of the hard coat layer (B) can be improved by laminating the hard coat layer (B) on the active optically-curable layer (A). However, since the active light hardening layer (A) and the hard coat layer (B) must be laminated separately on the substrate, there is a problem in productivity. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. The subject is to provide a laminated resin sheet for a touch panel and a surface coating sheet for a touch panel which are not easily damaged on the surface and which are relatively easy to manufacture. Means for Solving the Problems In order to solve the above problems, the inventors of the present invention have repeatedly focused their efforts on the above-mentioned problems, and have found that the present invention has finally been completed by the following means. (1) A laminated and extruded resin sheet for a touch panel which is laminated on a surface of a touch side of a polycarbonate resin layer and laminated by a co-extrusion molding to form a propylene-6 - 201041737 olefin resin layer to make. (2) The laminated resin sheet for a touch panel according to the above (1), wherein the polycarbonate resin layer has a thickness of 50% or more of the entire thickness. (3) The laminated and extruded resin sheet for a touch panel according to the above (1) or (2), which is formed by laminating an acrylic resin layer on both surfaces of the polycarbonate resin layer. The laminated resin sheet for a touch panel according to any one of the above aspects, wherein the acrylic resin layer is made of a methacrylic resin and a rubbery polymer. (5) A surface-coated board for a touch panel which is formed by coating a cured film on a surface of a touch-side of a laminated and extruded resin sheet according to any one of the above (1) to (4). (6) The surface-coated board for a touch panel according to the above (5), wherein the cured film has a scratch-resistant hardened film.效果 Effect of the Invention The laminated and extruded resin sheet of the present invention is suitable for use in a touch panel because the surface is not easily damaged. Further, the surface-coated sheet formed by coating the cured film on the surface on the contact side of the laminated resin sheet can be suitably used for the touch of a stylus having a sharp tip. Further, the laminated extruded resin sheet of the present invention is obtained by co-extrusion molding, and since it is not necessary to laminate the active light hardening layer and the hard coat layer on the substrate as in the related art, it is relatively easy to manufacture. . [Embodiment] The embodiment of the present invention is a laminate extrusion resin sheet (hereinafter also referred to as an extrusion resin sheet) which is formed on the surface of at least the touch side of the polycarbonate resin layer by co-extrusion. It is formed by laminating an acrylic resin layer and used for a touch panel. The polycarbonate resin constituting the polycarbonate resin layer is a polymer composed of a carbonate group (-0-(c = o) - 0-) in which the bonding sites of the monomer units are each. The polycarbonate resin is, for example, a resin obtained by reacting one or more kinds of divalent phenols with one or more kinds of carbonylating agents by an interfacial polycondensation method, a melt transesterification method, or the like, by a solid phase ester. A resin obtained by polymerizing a carbonate prepolymer such as an exchange method, a resin obtained by polymerizing a cyclic carbonate compound by a ring-opening polymerization method, or the like. Examples of the divalent phenol include hydroquinone, resorcin, 4,4′-dihydroxybiphenyl, bis(4-hydroxyphenyl)methane, and bis{(4-hydroxy-3,5-di). Methyl)phenyl}methane, 1,1-bis(4-hydroxyphenyl)ethane, 1,1-bis(4-hydroxyphenyl)-1-phenylethane, 2,2-dihydroxyphenyl Propane (commonly known as bisphenol A), 2,2-bis{(4-hydroxy-3-methyl)phenyl}propane, 2,2-bis{(4-hydroxy-3,5-dimethyl)benzene Propane, 2,2-bis{(4-hydroxy-3,5-dibromo)phenyl}propane ' 2,2-bis{(3-isopropyl-4-hydroxy)phenyl}propane, 2 , 2-bis{(4-hydroxy-3-phenyl)phenyl}propane, 2,2-bis(4-hydroxyphenyl)butane, 2,2-bis(4-hydroxyphenyl)-3 Methyl butane, 2,2-bis(4-hydroxyphenyl)-3,3-dimethylbutane, 2,4-bis(4-hydroxyphenyl)-2-methylbutane, 2, 2-bis(4-hydroxyphenyl)pentane, 2,2-bis(4-hydroxyphenyl-8-201041737)-4-methylpentane, ι,ΐ-bis(4-hydroxyphenyl) ring Hexane, hydroxyphenyl)-4-isopropylcyclohexane, 1,1-bis(4-hydroxyphenylmethylcyclohexane, 9,9-bis(4-hydroxyphenyl)anthracene, 9, 9-bis{methyl)phenyl}fu, α,α'-double (4 -hydroxyphenyl)-fluorene-diiso-α,α'-bis(4-hydroxyphenyl)-m-diisopropylbenzene, α,α'-bis)-fluorene-diisopropylbenzene, 1, 3-bis(4-hydroxyphenyl)-5,7-di, 4,4'-dihydroxydiphenylanthracene, 4,4'-dihydroxydiphenyl y0 dihydroxydiphenyl sulfide, 4 4'-dihydroxydiphenyl ketone, bisphenylene ether, 4,4'-dihydroxydiphenyl ester, and the like. Among them, it is preferred to use bisphenol A, 2,2-bis{(4-yl)phenyl}propane, 2,2-bis(4-hydroxyphenyl)butane, 2,phenyl)-3- Methyl butane, 2,2·bis(4-hydroxyphenyl)-3,3-, 2,2-bis(4-hydroxyphenyl)-4-methylpentane, 1,1_bis (4) One or more divalent phenols selected from the group consisting of 3,3,5-trimethylcyclohexane and hydrazine 1, 〇1'-bis(4-hydroxyphenyl)-111 benzene, and more separately used for Q , bisphenolphthalein with 1,1-bis(4-hydroxyphenyl)-3cyclohexane, bisphenol A and 2,2-bis{(4-hydroxy-3-}propane and α,α' - bis(4-hydroxyphenyl)-m-diisopropylbenzene, which is used in combination with one or more kinds of divalent phenols. Examples of the carbonylating agent include diphenyl esters such as phosgene. An equivalent of a carbonate, a divalent phenol dihaloate, etc. As an acrylic resin methacrylic resin constituting the aforementioned acrylic resin layer, the aforementioned methacrylic resin may be a 1,1-bis(4-)-3. ,3,5-tris(4-hydroxy-3-propylbenzene, (4-hydroxyphenylmethyladamantane, 4,4'-4,4'-dihydroxy-hydroxy-3-methyl 2- Bis(4-hydroxydimethylbutanoloxyphenyl)-diisopropyl Bisphenol A, 3,5-trimethylmethyl)phenyl • Group of carbonyl halides, carbon haloformates, generally based on methacrylic acid methyl-9- 201041737 ester unit 1 ο 〇% by weight of methacrylic acid The ester homopolymer may also be a copolymer of methyl methacrylate and one or more other monomers copolymerizable with the methyl methacrylate. Among them, it is preferably used as a methyl methacrylate unit. The resin of the main component is specifically preferably a methyl methacrylate resin containing 50% by weight or more of methyl methacrylate unit, more preferably a methacrylic acid group containing 70% by weight or more of methyl methacrylate unit. Ester resin. Examples of other monomers copolymerizable with the aforementioned methyl methacrylate include ethyl methacrylate, butyl methacrylate, cyclohexyl methacrylate, phenyl methacrylate, and methyl group. a methacrylate other than methyl methacrylate such as benzyl acrylate, 2-ethylhexyl methacrylate or 2-hydroxyethyl methacrylate, or methyl acrylate, ethyl acrylate or butyl acrylate. Cyclohexyl acrylate, Acrylates such as phenyl acrylate, benzyl acrylate, 2-ethylhexyl acrylate 2-hydroxyethyl acrylate, etc. Further, styrene or substituted styrene such as chlorostyrene may be mentioned. a styrene styrene such as brominated styrene or an alkyl styrene such as vinyl toluene or α-methyl styrene. Further, an unsaturated acid such as methacrylic acid or acrylic acid or acrylonitrile may be mentioned. , methacrylonitrile, maleic anhydride, phenyl maleimide, cyclohexylmaleimide, etc. The acrylic resin layer preferably contains a rubbery polymer, whereby the laminate can be extruded out of the resin sheet. Not easy to break. In particular, it is preferred that the acrylic resin layer be a layer composed of a methacrylic resin and a rubbery polymer by mixing a rubbery polymer in a methacrylic resin. The rubbery polymer is, for example, an acrylic multilayer structure polymer, or graft polymerized in a rubber polymer of 5 -10-201041737 to 80 parts by weight in an amount of 20 to 95 parts by weight of a propylene acid unsaturated. A graft copolymer obtained by using an ethylenically unsaturated monomer such as a monomer. The acrylic multilayer structure polymer preferably has a rubber elastic layer of about 20 to 60% by weight, preferably has a hard layer as the outermost layer, and more preferably contains a hard layer as the innermost layer. The rubber elastic layer is preferably a layer of an acrylic polymer having a glass transition point (T g ) of less than 25 ° C 0 , and particularly preferably a lower alkyl acrylate, a lower alkyl methacrylate, or a lower acrylic acid. One or more monofunctional monomers selected from the group consisting of alkoxyalkyl esters, cyanoethyl acrylate, acrylamide, hydroxy hydroxy lower alkyl esters, hydroxy lower alkyl methacrylates, acrylic acid and methacrylic acid, with methacrylic acid A layer of a polymer obtained by crosslinking a polyfunctional monomer such as allyl ester. Examples of the lower alkyl group include a linear or branched alkyl group having about 1 to 8 carbon atoms, and examples of the lower alkoxyalkyl group include a linear or branched alkoxy group having about 1 to 8 carbon atoms. Alkyl group. Q The hard layer is preferably a layer of an acrylic polymer having a Tg of 25 ° C or higher, and specifically preferably an alkyl methacrylate having an alkyl group having 1 to 4 carbon atoms, alone or as a main component. A homopolymer or copolymer polymerized. When it is a copolymer containing alkyl methacrylate as a main component, as the copolymerization component, other alkyl methacrylate or alkyl acrylate, styrene, substituted styrene, acrylonitrile, methacryl can be used. A monofunctional monomer such as a nitrile may be added as a crosslinked polymer by adding a polyfunctional monomer. For example, Japanese Laid-Open Patent Publication No. Hei. No. Hei. In the graft copolymer obtained by graft-polymerizing 20 to 95 parts by weight of an ethylenically unsaturated monomer to the above-mentioned 5 to 80 parts by weight of the rubbery polymer, 'as the rubbery polymer, for example, polybutylene can be used. Diene rubber such as diene rubber, acrylonitrile/butadiene copolymer rubber, styrene/butadiene copolymer rubber, polybutyl acrylate, polypropyl acrylate, 2-ethylhexyl polyacrylate, etc. Acrylic rubber, ethylene/propylene/non-conjugated diene rubber, and the like. Further, examples of the ethylene monomer for graft copolymerization in the rubbery polymer include styrene, acrylonitrile, and alkyl (meth)acrylate. Such a graft copolymer is described in, for example, JP-A-59-147A, and JP-A-47-9740. When the rubbery polymer is dispersed in the acrylic resin, the rubbery polymer is usually dispersed in an amount of from 3 to 150 parts by weight, preferably from 5 to 50 parts by weight, based on 1 part by weight of the acrylic resin. If the amount of the rubbery polymer is too large, the surface hardness is lowered. Further, if the amount of the rubbery polymer is too small, it is difficult to obtain an effect that the laminated resin sheet is less likely to be broken. Further, for example, a light diffusing agent may be added to each of the polycarbonate resin layer and the acrylic resin layer. One or more additives such as a matting agent, a dye, a light stabilizer, a UV absorber, an antioxidant, a mold release agent, a flame retardant, and an antistatic agent. The laminated extruded resin sheet of the present invention is produced by laminating and integrating a polycarbonate resin layer and an acrylic resin layer by co-extrusion molding. The co-extrusion molding system can melt-knead the material of the polycarbonate resin layer of the first -12-201041737 and the material of the acrylic resin layer by using two or three one-axis or two-axis extruders. It is carried out by laminating by a feedblock die or a multi-manifold die or the like. The resin sheet is extruded and laminated by laminating and laminating, and the laminate can be cooled and solidified by, for example, a roll unit or the like to obtain a laminated extruded resin sheet of the present invention. Hereinafter, an embodiment of a method for producing a laminated extruded resin sheet of the present invention will be described in detail with reference to the drawings. Fig. 1 is a schematic explanatory view showing a method of manufacturing the laminated extruded resin sheet of the embodiment. Fig. 2 is a schematic cross-sectional view showing the metal roll and the elastic roll of the embodiment. As shown in Fig. 1, first, each of the polycarbonate resin and the acrylic resin is heated by the individual extruders 1, 2, and melt-kneaded, while being pressed out by the die 3 for co-extrusion molding. Integration. Then, the sheet-like molten laminate which is uniformly pressed by the die 3 is pressed out of the resin sheet 4, and is sandwiched between the two cooling rolls 5Q which are disposed in the horizontal direction in the horizontal direction, thereby obtaining the lamination pressure for the touch panel. The resin plate 11 is taken out. As shown in Fig. 2, the cooling roll 5 is composed of a highly rigid metal roll 6 and an elastic roll 7 having a metal film 9 at its outer peripheral portion, i.e., a metal elastic roll 7. At least one of the metal roller 6 and the metal elastic roller 7 is connected to a rotation driving means such as a motor, and the two rollers are rotated at a predetermined peripheral speed. The high-rigidity metal roll 6 is a sheet-like lamination in which the metal roll 6 and the metal elastic roll 7 are supported, and the winding roll in which the resin sheet 11 is wound is extruded. The metal roller 6 is not particularly limited, and a general metal roller which has been conventionally used for extrusion molding can be used. Specific examples include a drill-type roll or a spiral roll, etc. -13-201041737. The surface state of the metal roll 6 may be, for example, a mirror surface, or may have a pattern or a concavity or the like. The metal elastic roller 7 includes a shaft roller 8 that is rotatably provided in a substantially cylindrical shape, and a cylindrical metal film 9 that is placed in contact with the molten laminated resin sheet 4 so as to cover the outer peripheral surface of the shaft roller 8. The fluid 10 is sealed between the isometric roller 8 and the metal film 9, whereby the metal elastic roller 7 exhibits elasticity. The shaft roller 8 is not particularly limited, and is made of, for example, stainless steel. The metal film 9 is made of, for example, stainless steel or the like, and has a thickness of preferably about 2 to 5 mm. The metal film 9 is more preferably a flexible structure having flexibility or flexibility, and preferably has no welded portion. The metal elastic roller 7 having the metal film 9 is excellent in durability, and when the metal film 9 is mirror-finished, the pattern or the unevenness can be imparted to the metal film 9 in the same manner as a normal mirror roll. Since it becomes a roll which can transfer shape, it is easy to use. The metal film 9 is fixed to both end portions of the shaft roller 8, and a fluid 1 封 is sealed between the shaft roller 8 and the metal film 9. Examples of the fluid 1 水 include water, oil, and the like. The temperature of the metal elastic light 7 can be controlled by controlling the temperature of the fluid 1 。. In the aforementioned temperature control, for example, a well-known control method such as PID control or ON-OFF control can be employed. Further, a gas such as air may be used instead of the fluid. When the resin sheet 4 is melt-laminated and supported between the metal light 6 and the metal elastic roller 7, the metal elastic roller 7 presses the resin sheet 4 via the melt lamination, and is recessed along the outer peripheral surface of the metal roll 6. The elastic deformation is performed, and the metal-14-201041737 elastic roller 7 and the metal roller 6 are pressed out of the resin sheet 4 by melt lamination, and are brought into contact at a predetermined contact length L. The contact length L may be 1 to 20 mm, preferably 1 to 10 mm, more preferably 1 to 7 mm. In order to make the contact length L a predetermined flaw, for example, the thickness of the metal thin film 9 and the amount of the fluid 10 to be sealed can be arbitrarily adjusted. Further, the contact length L means that the resin sheet 4 is pressed out by fusion lamination, and the length of the line connecting the metal elastic roller 7 and the metal roller 6 to the point where the contact is started and the point at which the contact ends is reached. When the metal elastic roller 7 and the metal roller 6 are brought into contact with the resin sheet 4 via the melt lamination by the contact length L, the metal roller 6 and the metal elastic roller 7 are brought into contact with each other by the molten laminate extrusion resin sheet 4. In the molten layer which is supported by the rolls, the resin sheet 4 is pressed and uniformly pressed into a planar shape to form a film. When the film formation is carried out in this manner, it is possible to prevent the strain from remaining in the laminated and extruded resin sheet U, and the heat shrinkage characteristics and the hysteresis of the laminated laminated resin sheet 1 tend to be small. Therefore, the laminated resin sheet 11 is laminated and has an effect of suppressing deformation of the touch panel in use in a place where the temperature environment is severe. Specifically, the shrinkage ratio S 1 ( % ) and the shrinkage in the width direction of the lamination-extrusion resin sheet 1 in the laminated resin sheet 11 when the laminate is pressed out of the resin sheet 11 in a thermal environment of 160 ° C for 30 minutes The rate S 2 (%) has a tendency to become 0 to 5 %. When the shrinkage ratios SI and S2 are negative, that is, when the laminate is not pressed to 〇%, if the laminate is pressed out of the resin sheet to be heated, expansion is performed, and when the cured resin film is coated on the laminated resin sheet, the turtle is introduced into the cured film. Cracked and there is a rupture. Further, when the shrinkage ratios s 1 and S 2 exceed 5%, the yield of the product obtained by heating and laminating the resin sheet from -15 to 201041737 and shrinking to increase is lowered. The method of calculating the shrinkage ratios Si and S 2 will be described later. Further, the laminated resin sheet 11 tends to have a hysteresis of 2 〇〇 nm or less. When the touch panel is mounted on the liquid crystal panel, if the hysteresis of the laminated resin sheet 11 constituting the touch panel is 200 nm or less, even if the polarized glasses are worn, the coloring of the touch panel does not occur. . The hysteresis described above is measured by a micro area double refractometer as described later. In order to reduce the heat shrinkage characteristics and hysteresis of the laminated resin sheet 1 1, when the metal sheet 6 and the metal elastic roller 7 are sandwiched by the melt lamination and extrusion of the resin sheet 4, it is preferably formed. The resin sheet 4 is pressed and laminated in the two rolls before the cooling and solidification or during the cooling and solidification. Specifically, the surface temperature (Tr) of the metal roll 6 and the metal elastic roll 7 is preferably (Th-2(TC) STrS (Th + 20t) with respect to the heat distortion temperature (Th) of the polycarbonate resin or the acrylic resin. ), preferably (Th-15.)
^Tr ^ ( Th+10°C )，更佳爲（Th-10°C ) ( Th + 5°C )的範圍。 另一方面，若表面溫度爲（Tr)比（Th-2 0 °C )還低 的溫度，則收縮率S2有變小的傾向。又，若表面溫度（^Tr ^ ( Th + 10 ° C ), more preferably (Th - 10 ° C ) (Th + 5 ° C ). On the other hand, when the surface temperature is a temperature lower than (Tr) ratio (Th-2 0 °C), the shrinkage ratio S2 tends to be small. Also, if the surface temperature (
Tr )爲比（Th + 2 0°C )還高的溫度，則收縮率S1變大，遲 滯値亦有變大的傾向。還有，來自輥的剝離痕跡殘留在層 合壓出樹脂板1 1上，有損害外觀的傾向。 表面溫度（Tr )係以聚碳酸酯樹脂及丙烯酸樹脂中熱 變形溫度（Th )高的樹脂爲基準。熱變形溫度（Th )係 -16- 201041737 沒有特別的限定，通常爲60〜200 °C左右。熱變形溫度（ Th)係依據ASTM D-648所測定之溫度。 金屬輥6與金屬彈性輥7間所夾持後的薄片狀層合壓 出樹脂板11，係在捲繞於金屬輥6後，藉由未圖示的牽 引輥，邊在搬送輥上冷卻邊牽引，藉此而得到層合壓出樹 脂板1 1。 接著，說明本發明的層合壓出樹脂板之製造方法的另 0 一實施形態。圖3係顯示本實施形態的彈性輥之槪略截面 說明圖。再者，圖3中，與前述圖1、圖2相同的構成部 分係附有相同的符號，而省略說明。 如圖3所示地，本實施形態的金屬彈性輥1 5，係以 圓筒形的金屬製薄膜17被覆略圓柱狀之旋轉自如設置的 軸輥1 6之外周面的金屬彈性輥。 軸輥1 6例如係由矽橡膠等的橡膠所成的橡膠輥，藉 此金屬彈性輥1 5可顯示彈性。藉由調整前述橡膠的硬度 Q ’亦可使前述接觸長度L成爲指定的値。 金屬製薄膜1 7例如係由不銹鋼等所成，其厚度較佳 爲0.2〜1mm左右。 爲了構成可溫度控制的金屬彈性輥1 5，例如可將背 托（back-up )冷卻輥安裝在金屬彈性輥15，其它構成由 於與前述實施形態同樣，故省略說明。 本發明的層合壓出樹脂板係可爲僅在聚碳酸酯樹脂層 的觸控側表面上層合有丙烯酸樹脂層之2層構造板，也可 爲在聚碳酸酯樹脂層的兩面層合有丙烯酸樹脂層的3層構 -17- 201041737 造板。 此處，3層構造板亦取決於丙烯酸樹脂層的厚度或丙 烯酸樹脂之種類，而面衝撃性會降低，變容易破裂。因此 ，於層合壓出樹脂板成爲3層構造時，較佳爲使橡膠狀聚 合物分散在丙烯酸樹脂層中。藉此，可抑制層合壓出樹脂 板的面衝撃性降低、變容易破裂。 另一方面，層合壓出樹脂板若爲3層構造，則剛性有 上升的傾向，在觸控面板操作時，會容易防止變形。又， 於該層合壓出樹脂板的兩面設置硬化膜時，亦可在兩面塗 覆相同組成的硬化材料。再者，於層合壓出樹脂板爲3層 構造時，兩丙烯酸樹脂層的組成可互相相同或不同。 本發明的層合壓出樹脂板通常爲薄片狀，其厚度通常 爲0.1〜2mm，較佳爲0.2〜1mm，更佳爲0.3〜0.7mm。 又，於本發明的層合壓出樹脂板中，聚碳酸酯樹脂層 的厚度較佳爲全體厚度的50%以上，尤佳爲70%以上，更 佳爲80%以上。藉此，層合壓出樹脂板成爲更難以破裂者 。再者，相對於全體厚度而言，聚碳酸酯樹脂層的厚度通 常爲95%以下，較佳爲90%以下。 於重視丙烯酸樹脂層的表面硬度時，其厚度較佳爲 ΙΟμηι以上，更佳爲20〜200μηι。再者，於3層構造時， 兩丙烯酸樹脂層的厚度可互相相同或不同。層合壓出樹脂 板的厚度係可藉由從前述模頭3所壓出的熔融層合壓出樹 脂板4之厚度、2支冷卻輥5之間隔來調整。 當操作觸控面板的人係以手指碰觸觸控面板時，本發 -18- 201041737 明的層合壓出樹脂版之丙烯酸樹脂層則合適作爲觸控面。 當操作觸控面板的人使用前端尖的觸控筆等來碰觸觸控面 板時，較佳爲使用在本發明的層合壓出樹脂板之觸控側的 表面上被覆硬化膜而成的表面塗覆板。 表面上設有硬化膜者具耐久性方面優異。再者，聚碳 酸酯層側基本上不當作觸控面使用，但是在其表面上亦可 設置硬化膜。 q 本發明的觸控面板用表面塗覆板，係在前述本發明的 層合壓出樹脂板之觸控側的表面上被覆硬化膜所成。作爲 前述硬化膜，例如可舉出由熱硬化性樹脂、電離輻射線硬 化樹脂等所成的膜。 以下’將含有熱硬化性樹脂、電離輻射線硬化樹脂等 的樹脂組成物亦稱爲「硬化性樹脂組成物」。 作爲前述熱硬化性樹脂，例如可舉出酚樹脂、尿素樹 月旨、對苯二甲酸二烯丙酯樹脂、蜜胺樹脂、胍胺樹脂 '不 Q 飽和聚酯系樹脂、聚胺基甲酸酯系樹脂、環氧樹脂、胺基 醇酸樹脂、蜜胺-尿素共縮合樹脂、矽樹脂、聚矽氧烷樹 脂等。於前述熱硬化性樹脂中，例如亦可添加交聯劑、聚 合引發劑等的硬化劑、聚合促進劑、溶劑、黏度調節劑、 體質顏料等。作爲硬化劑’通常對於聚胺基甲酸酯系樹脂 及聚胺基甲酸酯系樹脂’使用異氰酸酯、有機磺酸等，對 於環氧樹脂’使用胺’對於不飽和聚酯系樹脂，使用甲基 乙基酮過氧化物等的過氧化物、偶氮雙異丁酯等的自由基 引發劑。 -19- 201041737 作爲則述電離輻射線硬化樹脂，例如可舉出由在分子 中具有丙烯醯基、甲基丙烯醯基等的聚合性不飽和鍵、硫 酉手基或環氧基的預聚物、寡聚物及/或單體所成樹脂等。 作爲BU述電離轄射線硬化樹脂’具體地例如可舉出（甲基 )丙烯酸酯化合物、矽系化合物、不飽和聚酯化合物、環 氧化合物等。 於此等之中’較宜使用砂系化合物或1種以上的（甲 基）丙烯酸酯系化合物。作爲矽系化合物的具體例，例如 可舉出二官能矽系化合物、三官能矽系化合物、四官能矽 系化合物等。作爲二官能矽系化合物，例如可舉出γ _環氧 丙氧基丙基甲基二乙氧基矽烷、甲基丙烯醯氧基乙基甲基 二甲氧基矽烷、苯基甲基二甲氧基矽烷、乙烯基甲基二甲 氧基矽烷等。作爲三官能矽系化合物，例如可舉出γ _環氧 丙氧基丙基三甲氧基矽烷、β·(3,4_環氧基環己基）乙基 三甲氧基矽烷、苯基三甲氧基矽烷、甲基丙烯醯氧基乙基 二甲氧基矽烷、乙烯基三甲氧基矽烷、甲基三甲氧基矽院 等。作爲四官能矽系化合物’例如可舉出四甲氧基砂院、 四乙氧基矽烷、四丙氧基矽烷、四異丙氧基矽烷、四丁氧 基矽烷等。 作爲前述丙烯酸酯系化合物的具體例，例如可舉出單 官能（甲基）丙烯酸酯、二官能（甲基）丙烯酸酯、三官 0匕（甲基）丙嫌酸酯、四吕能（甲基）丙嫌酸醋、五官能 以上的（甲基）丙烯酸酯等。作爲單官能（甲基）丙烯酸 酯’例如可舉出（甲基）丙烯酸甲酯、（甲基）丙烯酸乙 -20- 201041737 酯、（甲基）丙烯酸丁酯、（甲基）丙烯酸環 基）丙嫌酸苯酯、（甲基）丙嫌酸苄酯、（甲 2-乙基己酯、（甲基）丙烯酸2-羥乙醋、環己 胺丁氧基乙基丙烯酸酯、甲氧基乙二醇（甲基 、（甲基）丙烯酸縮水甘油酯、（甲基）丙烯 酯、丙烯酸丙烯醯胺、二丙酮丙烯醯胺、丙烯 此等二官能（甲基）丙烯酸酯，例如可舉出單 q 甲基）丙烯酸酯、1，6-己二醇二（甲基）丙烯g 二醇二（甲基）丙烯酸酯等。作爲三官能（甲 酯，例如可舉出三羥甲基丙烷三（甲基）丙烯 甲基乙烷三（甲基）丙烯酸酯、五甘油三（甲 酯、季戊四醇三（甲基）丙烯酸酯、四羥甲基 基）丙烯酸酯、甘油三（甲基）丙烯酸酯、二 (甲基）丙烯酸酯、三[(甲基）丙烯醯氧基乙 酸酯等。作爲四官能（甲基）丙烯酸酯，例如 Q 四醇四（甲基）丙烯酸酯、四羥甲基甲烷四（ 酸酯、四羥甲基甲烷四丙烯酸酯、二季戊四醇 丙燒酸酯等。作爲五官能以上的（甲基）丙稀 可舉出二季戊四醇五（甲基）丙烯酸酯、二季 甲基）丙烯酸酯、三季戊四醇八（甲基）丙烯 又’亦可使用膦腈（phosphazene)化合物 中導入有（甲基）丙烯醯基的膦腈系（甲基） 合物；由在分子中具有至少2個異氰酸酯基的 分子中具有（甲基）丙烯醯氧基和羥基的化合 己酯、（甲 基）丙烯酸 基馬來酸亞 )丙烯酸酯 酸2-羥丙 腈等。作爲 乙二醇二（ 度酯、新戊 基）丙烯酸 酸酯、三羥 基）丙烯酸 甲烷三（甲 季戊四醇三 基]異氰尿 可舉出季戊 甲基）丙烯 四（甲基） 酸酯，例如 戊四醇六（ 酸酯等。 的膦腈環 丙烯酸酯化 化合物與在 物之反應所 -21 - 201041737 得的胺基甲酸乙酯（甲基）丙烯酸酯化合物；由在分子中 具有至少2個羧醯鹵基的化合物與在分子中具（甲基）丙 烯醯氧基和羥基的化合物之反應所得的聚酯（甲基）丙烯 酸酯化合物；上述各化合物的二聚物、三聚物等的寡聚物 等。 再者，由此等矽系化合物或（甲基）丙烯酸酯系化合 物所得之硬化膜，爲了提高其硬度，較佳爲含有1種以上 的無機微粒子。作爲前述無機微粒子，例如可舉出無機化 合物的氧化物、複氧化物、不定比氧化物、氧化物的合金 等，具體地可舉出氧化矽、氧化鋁、氧化鈦、氧化锆、氧 化铈、氧化錫、氧化鈹、氧化銻及Ce203 . Ti02、TaOx -Si〇2、SiOx . SiO ' MgO . A1203、BaO . Ti〇2 等。 由電離輻射線硬化樹脂所成的膜，係可藉由在前述電 離輻射線硬化樹脂等中添加1種以上的光聚合引發劑及/ 或1種以上的光增感劑，照射電離輻射線而得到。 作爲光聚合引發劑，例如可使用苯乙酮類、二苯甲酮 類、米蚩苯甲醯基苯甲酸酯、α-戊肟酯、四甲基秋蘭姆單 硫化物、噻噸酮類。作爲光增感劑，例如可使用正丁胺、 三乙胺、三正丁膦等。 再者，電離輻射線係意味電磁波或荷電粒子線中具有 可將分子聚合、交聯的能量子之輻射線，通常使用紫外線 、電子線。作爲紫外線源，例如可舉出超高壓水銀燈、高 壓水銀燈、低壓水銀燈、碳弧、黑光燈、金屬鹵化物燈等 的光源。 -22- 201041737 光聚合引發劑的添加量’相對於1 〇 0質量份之構成硬 化膜的樹脂而言，較佳爲0 · 1〜1 0質量份左右。 於本發明的硬化膜之硬化性樹脂組成物中，按照目的 亦可添加以往所使用的各種添加劑。作爲前述添加劑，例 如可舉出界面活性劑、均平劑、染料、顏料、抗氧化劑、 紫外線吸收劑、安定劑、難燃劑、可塑劑等。 作爲在層合壓出樹脂板表面被覆硬化膜的硬化性樹脂 0 組成物之方法’例如可舉出微凹槽輥塗佈法、輥塗法、浸 塗法、旋塗法、口模式塗佈法、澆鑄轉印法、流塗法、噴 塗法等。 如此所形成的硬化膜之厚度較佳爲1〜ΙΟμπι，更佳爲 2〜6μιη。該厚度若太小，則耐擦傷性會變不充分，而若 太大，則在暴露於闻溫局濕下時，容易發生裂紋。硬化膜 的厚度係可藉由調整在層合壓出樹脂板的表面上所塗佈的 硬化性樹脂組成物之每單位面積的量或硬化性樹脂組成物 Q 中所含的固體成分之濃度來調節。 特別地，於所例示的此等硬化膜中，較佳爲具有耐擦 傷性的硬化皮膜。作爲具有耐擦傷性的硬化皮膜，可舉出 在多官能（甲基）丙烯酸酯系化合物中添加無機微粒子而 成的皮膜，在胺基甲酸乙酯（甲基）丙烯酸酯化合物中添 加無機微粒子而成的皮膜、使四烷氧基矽硬化而成的皮膜 〇 如此所得之本發明的層合壓出樹脂板及表面塗覆板， 例如可使用作爲導航系統或攜帶資訊終端、產業機械的操 -23- 201041737 作面板、個人電腦的畫面、攜帶型遊戲機等的觸控面板用 構件。 又，於使用本發明的層合壓出樹脂板及表面塗覆板當 作觸控面板時’可進行熱成形等的二次成形、印刷、開孔 寺的加工’裁切處理成指定的形狀或大小。而且，使用2 層構造的層合壓出樹脂板之情況，通常以丙烯酸樹脂層成 爲表側（即操作觸控面板的人之接觸側），設置觸控面板 。又’使用3層構造的層合壓出樹脂板之情況，當兩丙烯 酸樹脂層的厚度互相不同時，較佳爲以厚度大的丙烯酸樹 脂層成爲表側’設置觸控面板。由本發明的層合壓出樹脂 板及表面塗覆板所成的觸控面板係不易損傷。 以下顯示本發明的實施例’惟本發明不受此等所限定 。再者’以下實施例中’表示含量或使用量的份，只要沒 有特別的記載，則係以重量爲基準。又，以下實施例及比 @例I所使用的壓出裝置之構成係如以下。 壓出機1:螺桿直徑65mm、一軸、附排氣孔（東芝機械 (股）製）。 壓出機2 :螺桿直徑45mm、一軸、附排氣孔（日立造船 (股）製）。 供料頭：2種3層及2種2層分配（曰立造船（股）製） 〇 模頭3 : T型模頭，唇寬1 400mm、唇間隔lmm (日立造 船（股）製）。 寧比橫型、面長1 4 0 0 m m、直徑3 0 0 m m φ的冷卻輥2支。 -24- 201041737 如圖1中所示地配置壓出機1 ' 2、模頭3，將供料頭 配置在指定位置。接著，於前述2支冷卻輕中，將最接近 壓出機1、2的輥當作1號輥，將捲繞輥當作2號輥’如 以下地構成各輥。 <輥構成1 > 以圖2所示的構成當作輥構成1。具體地，如以下地 0 構成的1號輥及2號輥。 (1號輥） 配置金屬製薄膜9，以使覆蓋軸輥8的外周面’將在 軸輥8與金屬製薄膜9之間封入有流體1 〇的金屬彈性輕 7當作1號輥。軸輥8、金屬製薄膜9及流體1 0係如以下 Q 軸輥8:不銹鋼製 金屬製薄膜9:厚度2mm的不錄銅製之鏡面金屬套 筒 流體1 〇 :油，藉由控制此油的溫度’而可控制金屬 彈性輕7的溫度。更具體地’藉由溫度調節機的ON-OFF 控制來加熱、冷卻前述油而可溫度控制’使在軸輕8與金 屬製薄膜9之間循瓌。 (2號輥） -25- 201041737 以表面狀態爲鏡面的不錢鋼製的螺旋輥作爲高剛性的 金屬輥6，將其當作2號輥。 再者，金屬彈性輥7與金屬輥6經由熔融層合壓出樹 脂板4進行接觸的接觸長度L係4mm。 <輕構成2 > 1號輥及2號輥皆爲高剛性的金屬輥（表面狀態爲鏡 面的不銹鋼製之螺旋輥）。 以下實施例及比較例所使用的樹脂係如下。 樹脂1:僅芳香族聚碳酸酯的聚合物（住友DOW( 股）製的「Calibre 301-10」）。熱變形溫度（Th)爲 1 40°C 。 樹脂2 :甲基丙烯酸甲酯/丙烯酸甲酯=98/2 (重量比 )的共聚物。熱變形溫度（Th )爲1 0 0 °C。 樹脂3:於91重量％的甲基丙烯酸甲酯/丙烯酸甲酯 = 96/4(重量比）之共聚物中含有9重量％的下述參考例所 得之丙烯酸系多層構造聚合物的丙烯酸樹脂系組成物。熱 變形溫度（Th)爲i〇〇t：。 樹脂4:於79重量％的甲基丙烯酸甲酯/丙烯酸甲酯 = 96M (重量比）之共聚物中含有21重量％的下述參考例 所得之丙烯酸系多層構造聚合物的丙烯酸樹脂系組成物。 熱變形溫度（T h )爲1 〇 〇 °c。 [參考例] -26- 201041737 (橡膠狀聚合物的製造） 依據特公昭55-275 76號的實施例中記載的方法，製 造由3層構造所成的丙烯酸系多層構造聚合物。具體地， 首先於內容積5L的玻璃製反應容器內，投入1700克離子 交換水、0.7克碳酸鈉、0.3克過硫酸鈉，在氮氣流下攪 拌後，投入4_46克Pelex OT-P ((股）花王製）、150克 離子交換水、150克甲基丙烯酸甲酯、0.3克甲基丙烯酸 0 烯丙酯後，升溫到7 5 °C，繼續攪拌1 5 0分鐘。 接著，由另一入口，歷經90分鐘添加689克丙儲酸 丁酯、162克苯乙烯、17克甲基丙烯酸烯丙酯的混合物及 0.85克過硫酸鈉、7.4克PelexOT-P和50克離子交換水 的混合物，再繼續聚合90分鐘。 完成聚合後，由各自的口，歷經30分鐘添加326克 甲基丙烯酸酯、14克丙烯酸乙酯的混合物與30克溶解有 0.34克過硫酸鈉的離子交換水。 Q 添加結束後，再保持60分鐘而完成聚合。將所得之 乳膠投入0.5 %氯化鋁水溶液中以使聚合物凝聚。以溫水 來洗淨其5次後，進行乾燥而得到丙烯酸系多層構造聚合 物。 [實施例1〜1 1] <層合壓出樹脂板的製作> 作爲樹脂層A，將表1所示種類的樹脂在壓出機1中 熔融混煉，供應給供料頭。另一方面，作爲樹脂層B，將 -27- 201041737 表1所示種類的樹脂在壓出機2中熔融混煉’供應給供料 頭。以由壓出機1供應給供料頭的樹脂層A成爲主層’ 由壓出機2供應給供料頭的樹脂層B成爲表層（單面/上 側）的方式，進行共壓出成形。 然後，將由模頭3所壓出的熔融層合壓出樹脂板4， 一邊以表1中所示的輥構成之1號輕及2號_來夾持’ 一 邊進行製膜，而得到表1中所示厚度的由2層構造所成之 層合壓出樹脂板。又，1號輥的表面溫度爲120°C，2號輥 的表面溫度爲1 30°C。此等溫度係實測各輥的表面溫度之 値。又，表1中的壓出機1、2之「厚度」表示樹脂層A 、B的各厚度。表1中的「總厚度」表示所得之層合壓出 橫脂板的總厚度。 <表面塗覆板的製作> 於所得之各層合壓出樹脂板的觸控側之表面上，即樹 脂層B的表面上，被覆硬化膜，而得到表面塗覆板。具體 地，首先將作爲單體之5〇份的二季戊四醇六丙烯酸酯、 5 0份的季戊四醇四丙烯酸酯、作爲引發劑之4.5份的汽巴 特殊化學品（股）製的IRGACURE 184、1.5份的 IRGACURE 907、作爲均平劑之0.1份的BYK化學日本( 股）製的ΒΥΚ-3Ό7，各自混合在125份的異丁醇及125份 的1 -甲氧基-2-丙醇之溶劑中，而得到混合液體。 其次，藉由1 6號的桿塗機，將此混合液體塗佈在樹 脂層B的表面上’使用1 2 0 W的高壓水銀燈照射〇 5 j /c m 2 -28- 201041737 的紫外線而使硬化，而在樹脂層B的表面上形成厚度約 3 · 5 μ m的硬化膜，得到表面塗覆板。 [實施例12〜22及比較例1] 作爲樹脂層A，將表1所示種類的樹脂在壓出機1中 熔融混煉，供應給供料頭。另一方面，作爲樹脂層B，將 表1所示種類的樹脂在壓出機2中熔融混煉，供應給供料 0 頭。以由壓出機1供應給供料頭的樹脂層A成爲中間層 ，由壓出機2供應給供料頭的樹脂層B成爲兩表層之方式 ，進行共壓出成形。 然後，將由模頭3所壓出的熔融層合壓出樹脂板4， 一邊以表1中所示的輥構成之1號輥及2號輥來夾持，一 邊進行製膜，而得到表1中所示厚度的由3層構造所成之 層合壓出樹脂板。又，1號輥的表面溫度爲11(TC，2號輥 的表面溫度爲1 2 5 °C。 Q 於所得的各層合壓出樹脂板之樹脂層B、B中，在任 意選定的一方之樹脂層B的表面上，與前述實施例1〜11 同樣地，形成厚度約3.5 μιη的硬化膜，得到表面塗覆板。 [比較例2〜4 ] 將表1所示種類的樹脂在壓出機1中熔融混煉，依供 料頭及模頭3的順序進行供給。然後，將由模頭3所壓出 的熔融壓出樹脂板，一邊以表1中所示的輥構成之1號輥 及2號輥來夾持，一邊進行製膜，而得到表丨中所示厚度 -29- 201041737 的由單層構造所成的壓出樹脂板。 於所得之各壓出樹脂板的任意一面上，與前述實施例 1〜1 1同樣地，形成厚度約3 · 5 μιη的硬化膜，得到表面塗 覆板。 <評價> 對於所得之各壓出樹脂板（實施例1〜22及比較例1 〜4)，進行收縮率及遲滯値的評價。又，對於各壓出樹 脂板及各表面塗覆板，進行鉛筆硬度及觸控筆評價。以下 顯示各評價方法，同時在表1中一倂顯示其結果。 (收縮率） 首先，由所得之壓出樹脂板中切出約1 0 cm見方大小 的試驗片，分別測定此試驗片之壓出方向的尺寸（MDO ) 及寬度方向的尺寸（TDO)。接著，於金屬製的墊上，鋪 上嬰兒爽身粉（和光堂（股）製的SiCCar〇l-Hi」），在 其上放置則述試驗片’投入160 °C的供箱中30分鐘。 然後，分別測定經自然冷卻的試驗片之壓出方向的尺 寸（MD)及寬度方向的尺寸（TD)，將所得之各尺寸代 入式：收縮率S1 = {1-(MD/MD0) }xi〇〇，式··收縮率 S2 = { 1- ( TD/TDO ) }xl〇〇，算出收縮率 SI、S2。又，由 所算出的收縮率SI、S2算出比（S1/S2 )。於表1中的收 縮率S 1、S2中’+的結果表示收縮，-的結果表示膨脹。 -30- 201041737 (遲滯値） 由所得之壓出樹脂板切出5 0mm見方大小的試驗片， 使用微小面積雙折射率計（王子計測機器（股）製的「 KOBRA-CCO/X」）來測定此試驗片的遲滯値。 (鉛筆硬度） 依據JISK5600來測定。再者，實施例1〜11的壓出 0 樹脂板之測定面係樹脂層B。又，於表1的鉛筆硬度中， 「樹脂板」表示壓出樹脂板，「塗覆板」表示表面塗覆板 〇 (觸控筆評價） 於壓出樹脂板及表面塗覆板的表面上，使用任天堂（ 股）公司製的「DS觸控筆」，以手普通地描寫文字，目 視確認經摩擦部分的損傷狀況。再者，實施例1〜1 1的壓 Q 出樹脂板之表面係樹脂層B。又，判定基準係使用以下者 〇 〇：無損傷 △:淺的損傷 x :深的損傷 -31 - 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- — *— y^" CSJ 一 i ϋ :CS 11 (In cn 辑 _ 1 jo in ’择 胸 i r- >1 oc :隹 l〇N p 1 i •p II π哪黑1 kl - _ i 隹 ||B cn 隹 !l (_ in 1 5 i 崔 J®5 i 握 JS oo Ϊ n jp a、 1 ]? >進 (|ί· CS 厚 g ρ 藝 進 _ J ιι· i E ；I J± si l[i :m m 。蓉踩揉S餾恥趦发甚觀4趦绶)£橄圧：|§-蓉姐鏃£魈趙整^搂你淞«)|二：>1(1 -32- 201041737 如表1可明知，與比較例1〜4的壓出樹 實施例1〜2 2的壓出樹脂板係在鉛筆硬度及觸 示較良好的結果’表面不易損傷。又，可知老 板上被覆硬化膜’則提高表面的不易損傷性。 用輕構成1的實施例1〜4、6〜8、12〜21之 係收縮率及遲滯値小者。 另一方面，對於實施例1〜11之由2層精 0 出樹脂板’以手來彎曲該壓出樹脂板，評價是 曲性）。其結果爲該壓出樹脂板顯示即使彎曲 的結果。又，於由3層構造所成的實施例12、 樹脂板中，對於丙烯酸樹脂層爲由甲基丙烯酸 狀聚合物所成的層之實施例1 6〜2 2的壓出樹f 述同樣地評價彎曲性。其結果爲該壓出樹脂板 曲也不易破裂的結果。 Q 【圖式簡單說明】 圖1係顯示本發明的一實施形態之觸控面 出樹脂板的製造方法之槪略說明圖。 圖2係顯示本發明的一實施形態之金屬輕 槪略截面說明圖。 圖3係顯示本發明的另一實施形態之彈性 面說明圖。 【主要元件符號說明】 旨板相比， 控筆評價顯 在壓出樹脂 特別地，採 g出樹脂板 造所成的壓 否破裂（彎 也不易破裂 22之壓出 樹脂及橡膠 聲板，與上 顯示即使彎 板用層合壓 及彈性輥的 輥的槪略截 -33- 201041737 1、2 :壓出機 3 :模頭 4 :熔融層合壓出樹脂板 5 :冷卻輥 6 :金屬輥 7、 1 5 :金屬彈性輥 8、 1 6 :軸輥 9、 1 7 :金屬製薄膜 1 〇 :流體 1 1 :觸控面板用層合壓出樹脂板 -34-When Tr ) is a temperature higher than (Th + 20 °C), the shrinkage ratio S1 becomes large, and the retardation 値 tends to become large. Further, the peeling marks from the rolls remain on the laminated extruded resin sheet 1 1 and tend to impair the appearance. The surface temperature (Tr) is based on a resin having a high heat distortion temperature (Th) in the polycarbonate resin and the acrylic resin. The heat distortion temperature (Th) system -16-201041737 is not particularly limited and is usually about 60 to 200 °C. The heat distortion temperature (Th) is a temperature determined in accordance with ASTM D-648. The sheet-like laminated and sandwiched resin sheet 11 sandwiched between the metal roll 6 and the metal elastic roll 7 is wound around the metal roll 6 and then cooled on the transfer roll by a pulling roll (not shown). Traction, thereby obtaining a laminated resin sheet 11 by lamination. Next, another embodiment of the method for producing a laminated extruded resin sheet of the present invention will be described. Fig. 3 is a schematic cross-sectional view showing the elastic roller of the embodiment. In FIG. 3, the same components as those in FIG. 1 and FIG. 2 are denoted by the same reference numerals, and description thereof will be omitted. As shown in Fig. 3, the metal elastic roller 15 of the present embodiment is coated with a cylindrical metal film 17 to cover a metal elastic roller on the outer circumferential surface of the shaft roller 16 which is provided in a substantially cylindrical shape. The shaft roller 16 is, for example, a rubber roller made of rubber such as rubber, whereby the metal elastic roller 15 can exhibit elasticity. The contact length L may be set to a predetermined enthalpy by adjusting the hardness Q' of the rubber. The metal film 17 is made of, for example, stainless steel or the like, and its thickness is preferably about 0.2 to 1 mm. In order to constitute the temperature-controllable metal elastic roller 15, for example, a back-up cooling roller can be attached to the metal elastic roller 15, and the other configuration is the same as that of the above embodiment, and thus the description thereof will be omitted. The laminated extruded resin sheet of the present invention may be a two-layer structural sheet in which an acrylic resin layer is laminated only on the touch side surface of the polycarbonate resin layer, or may be laminated on both sides of the polycarbonate resin layer. The three-layer structure of the acrylic resin layer is -17-201041737. Here, the three-layer structure plate also depends on the thickness of the acrylic resin layer or the type of the acrylic resin, and the surface flushing property is lowered to be easily broken. Therefore, when the laminated resin sheet is formed into a three-layer structure, it is preferred to disperse the rubber-like polymer in the acrylic resin layer. Thereby, it is possible to suppress the surface flushing property of the laminated and extruded resin sheet from being lowered and being easily broken. On the other hand, when the laminated resin sheet has a three-layer structure, the rigidity tends to increase, and it is easy to prevent deformation during the operation of the touch panel. Further, when a cured film is provided on both surfaces of the laminated resin sheet, a hardened material having the same composition may be coated on both surfaces. Further, when the laminated resin sheet is formed into a three-layer structure, the compositions of the two acrylic resin layers may be the same or different from each other. The laminated extruded resin sheet of the present invention is usually in the form of a sheet and has a thickness of usually 0.1 to 2 mm, preferably 0.2 to 1 mm, more preferably 0.3 to 0.7 mm. Further, in the laminated extruded resin sheet of the present invention, the thickness of the polycarbonate resin layer is preferably 50% or more, more preferably 70% or more, and still more preferably 80% or more. Thereby, laminating and extruding the resin sheet becomes more difficult to break. Further, the thickness of the polycarbonate resin layer is usually 95% or less, preferably 90% or less, based on the entire thickness. When the surface hardness of the acrylic resin layer is emphasized, the thickness thereof is preferably ΙΟμηι or more, more preferably 20 to 200 μm. Further, in the three-layer configuration, the thickness of the two acrylic resin layers may be the same or different from each other. The thickness of the laminated resin sheet can be adjusted by the thickness of the resin sheet 4 and the interval between the two cooling rolls 5 by melt lamination from the die 3 described above. When the person operating the touch panel touches the touch panel with a finger, the laminated acrylic resin layer of the present invention is suitable as a touch surface. When the person who operates the touch panel touches the touch panel with a tip stylus or the like, it is preferably formed by coating a surface on the touch side of the laminated resin sheet of the present invention with a cured film. Surface coated panels. A cured film is provided on the surface to have excellent durability. Further, the side of the polycarbonate layer is not substantially used as a touch surface, but a cured film may be provided on the surface thereof. The surface-coated board for a touch panel of the present invention is formed by coating a surface of the touch-sensitive resin sheet of the present invention with a cured film. As the cured film, for example, a film made of a thermosetting resin, an ionizing radiation hardening resin or the like can be given. The resin composition containing a thermosetting resin, an ionizing radiation curing resin, or the like is also referred to as a "curable resin composition". Examples of the thermosetting resin include a phenol resin, a urea resin, a diallyl terephthalate resin, a melamine resin, a guanamine resin, a non-Q saturated polyester resin, and a polyaminocarboxylic acid. An ester resin, an epoxy resin, an amino alkyd resin, a melamine-urea co-condensation resin, an anthracene resin, a polydecane resin, or the like. In the thermosetting resin, for example, a curing agent such as a crosslinking agent or a polymerization initiator, a polymerization accelerator, a solvent, a viscosity modifier, an extender pigment, or the like may be added. As the curing agent, 'isocyanate, organic sulfonic acid, etc. are usually used for the polyurethane resin and the polyurethane resin, and the amine is used for the epoxy resin. For the unsaturated polyester resin, a A peroxide initiator such as a ketene peroxide or a radical initiator such as azobisisobutyl acrylate. -19-201041737 The ionizing radiation-curable resin is, for example, a prepolymer which has a polymerizable unsaturated bond such as an acrylonitrile group or a methacryl fluorenyl group in the molecule, a sulfonium group or an epoxy group. A resin, an oligomer, and/or a monomer. Specific examples of the ionizing radiation curable resin of the BU include, for example, a (meth) acrylate compound, an anthraquinone compound, an unsaturated polyester compound, and an epoxy compound. Among these, it is preferred to use a sand-based compound or one or more (meth)acrylate-based compounds. Specific examples of the quinone compound include a difunctional fluorene compound, a trifunctional fluorene compound, and a tetrafunctional quinone compound. Examples of the difunctional fluorene-based compound include γ-glycidoxypropylmethyldiethoxydecane, methacryloxyethylmethyldimethoxydecane, and phenylmethyldimethyl. Oxydecane, vinylmethyldimethoxydecane, and the like. Examples of the trifunctional fluorene-based compound include γ-glycidoxypropyltrimethoxydecane, β·(3,4-epoxycyclohexyl)ethyltrimethoxydecane, and phenyltrimethoxy.矽, methacryloxyethyl dimethoxy decane, vinyl trimethoxy decane, methyl trimethoxy fluorene, and the like. Examples of the tetrafunctional fluorene-based compound 'tetramethoxy silicate, tetraethoxy decane, tetrapropoxy decane, tetraisopropoxy decane, tetrabutoxy decane, and the like. Specific examples of the acrylate-based compound include monofunctional (meth) acrylate, difunctional (meth) acrylate, triammonium methacrylate (meth) acrylate, and tetraluene (A). Base) Aromatic vinegar, penta-functional or higher (meth) acrylate, and the like. Examples of the monofunctional (meth)acrylates include methyl (meth)acrylate, ethyl (meth)acrylate-20-201041737, butyl (meth)acrylate, and (meth)acrylic acid ring. Acetyl phenyl acrylate, (meth) propyl benzyl benzoate, (methyl 2-ethylhexyl acrylate, 2-hydroxyethyl methacrylate, cyclohexylamine butoxyethyl acrylate, methoxy Examples of the difunctional (meth) acrylate such as ethylene glycol (glycidyl (meth) acrylate, (meth) acrylate, acrylamide, diacetone acrylamide, propylene, etc.) Mono q methyl acrylate, 1,6-hexanediol di(meth) propylene g diol di(meth) acrylate, etc. As a trifunctional (methyl ester, for example, trimethylolpropane III is exemplified (Meth)propylene methylethane tri(meth)acrylate, pentaglycerol tris(methyl ester, pentaerythritol tri(meth)acrylate, tetramethylol)acrylate, glycerol tri(meth)acrylate , di(meth)acrylate, tris[(meth)acryloxyacetate, etc. as a functional (meth) acrylate such as Q tetraol tetra(meth) acrylate, tetramethylol methane tetraester, tetramethylol methane tetraacrylate, dipentaerythritol propionate, etc. as a pentafunctional The above (meth) propylene may be exemplified by dipentaerythritol penta (meth) acrylate, diquaternary methyl acrylate, tripentaerythritol octa (meth) propylene, and phosphazene compound. (meth)acrylonitrile-based phosphazene-based (meth) compound; a hexyl ester having a (meth) acryloxy group and a hydroxyl group in a molecule having at least two isocyanate groups in a molecule, (methyl) Acrylic acid maleic acid sub) acrylate acid 2-hydroxypropionitrile, etc. as ethylene glycol di(di ester, neopentyl) acrylate, trihydroxy) methacrylate methane (pentaerythritol triyl) isocyanuric acid A pentaerythromethyl propylene tetra(methyl) acid ester, for example, a phosphazene cyclic acrylated compound such as pentaerythritol hexahydrate (such as a phosphazene cyclic acrylated compound and a reaction product of the compound - 21-201041737) Ethyl ester (methyl) An acrylate compound; a polyester (meth) acrylate compound obtained by reacting a compound having at least 2 carboxy fluorenyl halides in a molecule with a compound having a (meth) propylene oxy group and a hydroxyl group in the molecule; An oligomer such as a dimer or a trimer of each compound, etc. Further, the cured film obtained from the oxime compound or the (meth) acrylate compound is preferably contained in order to increase the hardness thereof. Examples of the inorganic fine particles include, for example, an oxide of an inorganic compound, a double oxide, an alloy of an indefinite ratio oxide, and an oxide, and specific examples thereof include cerium oxide, aluminum oxide, and titanium oxide. Zirconium oxide, cerium oxide, tin oxide, cerium oxide, cerium oxide, and Ce203. Ti02, TaOx-Si〇2, SiOx. SiO 'Mg. A1203, BaO. Ti〇2, and the like. The membrane formed of the ionizing radiation-curable resin may be irradiated with ionizing radiation by adding one or more kinds of photopolymerization initiators and/or one or more kinds of photosensitizers to the ionizing radiation curing resin or the like. get. As the photopolymerization initiator, for example, acetophenone, benzophenone, rice branyl benzoyl benzoate, α-pentanyl ester, tetramethyl thiuram monosulfide, thioxanthone can be used. class. As the photosensitizer, for example, n-butylamine, triethylamine, tri-n-butylphosphine or the like can be used. Further, the ionizing radiation system means a radiation having an energy beam which can polymerize and crosslink molecules in an electromagnetic wave or a charged particle beam, and ultraviolet rays and electron lines are usually used. Examples of the ultraviolet light source include a light source such as an ultrahigh pressure mercury lamp, a high pressure mercury lamp, a low pressure mercury lamp, a carbon arc, a black light, and a metal halide lamp. -22-201041737 The amount of the photopolymerization initiator added is preferably from about 0.1 to about 10 parts by mass based on 1 part by mass of the resin constituting the hardened film. In the curable resin composition of the cured film of the present invention, various additives conventionally used may be added according to the purpose. The above-mentioned additives may, for example, be surfactants, leveling agents, dyes, pigments, antioxidants, ultraviolet absorbers, stabilizers, flame retardants, plasticizers and the like. The method of laminating the composition of the curable resin 0 in which the surface of the resin sheet is laminated and cured is, for example, a microgroove roll coating method, a roll coating method, a dip coating method, a spin coating method, or a die coating method. Method, casting transfer method, flow coating method, spraying method, and the like. The thickness of the cured film thus formed is preferably from 1 to ΙΟμπι, more preferably from 2 to 6 μm. If the thickness is too small, the scratch resistance may become insufficient, and if it is too large, cracks may easily occur when exposed to a wet temperature. The thickness of the cured film can be adjusted by adjusting the amount per unit area of the curable resin composition applied on the surface of the laminated resin sheet or the solid content contained in the curable resin composition Q. Adjustment. Particularly, among the cured films exemplified, a hardened film having scratch resistance is preferred. Examples of the hardened film having scratch resistance include a film in which inorganic fine particles are added to a polyfunctional (meth)acrylate compound, and inorganic fine particles are added to the ethyl urethane (meth)acrylate compound. The formed film and the film obtained by hardening the tetraalkoxy oxime, the laminated pressure-extracted resin sheet and the surface-coated board of the present invention thus obtained can be used, for example, as a navigation system or an information terminal, an industrial machine. 23- 201041737 A member for a touch panel such as a panel, a screen for a personal computer, or a portable game machine. In addition, when the laminated extruded resin sheet and the surface-coated sheet of the present invention are used as a touch panel, 'secondary forming, printing, and processing of a hole temple can be performed, and the processing is cut into a predetermined shape. Or size. Further, in the case where the resin sheet is laminated by using a two-layer structure, the touch panel is usually provided with the acrylic resin layer as the front side (i.e., the contact side of the person who operates the touch panel). Further, in the case where the resin sheet is laminated by using a three-layer structure, when the thicknesses of the two acrylic resin layers are different from each other, it is preferable to provide the touch panel with the acrylic resin layer having a large thickness as the front side. The touch panel formed by laminating the resin sheet and the surface coating sheet of the present invention is not easily damaged. The following examples of the invention are shown, but the invention is not limited thereto. Further, 'in the following examples' indicates the content of the content or the amount used, and is based on the weight unless otherwise specified. Further, the following examples and the configuration of the extrusion device used in Example 1 are as follows. Extruder 1: Screw diameter 65 mm, one shaft, and vent hole (made by Toshiba Machine Co., Ltd.). Extruder 2: Screw diameter 45 mm, one shaft, and venting holes (made by Hitachi Shipbuilding Co., Ltd.). Feeding head: 2 types of 3 layers and 2 types of 2 layers (manufactured by 造立造船), 模 Die 3: T-die, lip width 1 400mm, lip spacing 1mm (Hitachi Shipbuilding Co., Ltd.). Ning is a chiller roll with a transverse shape, a face length of 1 400 m, and a diameter of 300 m m φ. -24- 201041737 The extruder 1 '2, die 3 is arranged as shown in Fig. 1, and the supply head is placed at the designated position. Next, among the above two cooling lamps, the rolls closest to the extruders 1, 2 are regarded as No. 1 rolls, and the winding rolls are regarded as No. 2 rolls'. <Roll Configuration 1 > The configuration shown in Fig. 2 is referred to as a roll configuration 1. Specifically, the No. 1 roller and the No. 2 roller are constructed as follows. (No. 1 roller) The metal film 9 is placed so that the outer peripheral surface of the cover shaft roller 8 is a metal elastic light 7 in which a fluid 1 is sealed between the shaft roller 8 and the metal film 9 as a No. 1 roller. The shaft roller 8, the metal film 9 and the fluid 10 are, for example, the following Q-axis roller 8: a stainless steel metal film 9: a mirror-shaped metal sleeve fluid of a thickness of 2 mm, which is not recorded in copper. 〇: oil, by controlling the oil The temperature 'can control the temperature of the metal elastic light 7. More specifically, the temperature can be controlled by heating and cooling the oil by the ON-OFF control of the temperature controller to circulate between the shaft light 8 and the metal film 9. (Roll No. 2) -25- 201041737 A steel roller which is a mirrorless surface with a mirror surface is used as a high-rigidity metal roller 6, and it is regarded as a No. 2 roller. Further, the contact length L of the metal elastic roller 7 and the metal roller 6 which were brought into contact with the resin sheet 4 by melt lamination was 4 mm. <Light Composition 2 > Both the No. 1 roller and the No. 2 roller are high-rigidity metal rolls (spiral rolls made of stainless steel having a mirror surface). The resins used in the following examples and comparative examples are as follows. Resin 1: Polymer of only aromatic polycarbonate ("Calibre 301-10" manufactured by Sumitomo Dow Co., Ltd.). The heat distortion temperature (Th) is 1 40 °C. Resin 2: a copolymer of methyl methacrylate/methyl acrylate = 98/2 (weight ratio). The heat distortion temperature (Th) is 1 0 0 °C. Resin 3: Acrylic resin containing 9 wt% of the acrylic multilayer structure polymer obtained in the following Reference Examples in a copolymer of 91% by weight of methyl methacrylate/methyl acrylate = 96/4 (weight ratio) Composition. The heat distortion temperature (Th) is i〇〇t:. Resin 4: Acrylic resin composition containing 21% by weight of the acrylic multilayer structure polymer obtained in the following Reference Examples in a copolymer of 79% by weight of methyl methacrylate/methyl acrylate = 96 M (weight ratio) . The heat distortion temperature (T h ) is 1 〇 〇 °c. [Reference Example] -26-201041737 (Production of a rubbery polymer) An acrylic multilayer structure polymer obtained by a three-layer structure was produced according to the method described in the examples of JP-A-55-27576. Specifically, first, 1700 g of ion-exchanged water, 0.7 g of sodium carbonate, and 0.3 g of sodium persulfate were placed in a glass reaction vessel having an internal volume of 5 L, and after stirring under a nitrogen stream, 4 to 46 g of Pelex OT-P ((share) was charged. Kao), 150 g of ion-exchanged water, 150 g of methyl methacrylate, and 0.3 g of allyl methacrylate were heated to 75 ° C and stirring was continued for 150 minutes. Next, from another inlet, a mixture of 689 grams of butyl acrylate, 162 grams of styrene, 17 grams of allyl methacrylate, and 0.85 grams of sodium persulfate, 7.4 grams of PelexOT-P, and 50 grams of ions were added over 90 minutes. The mixture of water was exchanged and polymerization was continued for another 90 minutes. After the completion of the polymerization, a mixture of 326 g of methacrylate, 14 g of ethyl acrylate and 30 g of ion-exchanged water in which 0.34 g of sodium persulfate was dissolved was added from the respective ports over 30 minutes. After the Q addition is completed, the polymerization is completed by holding for another 60 minutes. The resulting latex was poured into a 0.5% aqueous solution of aluminum chloride to coagulate the polymer. After washing five times with warm water, it was dried to obtain an acrylic multilayer structure polymer. [Examples 1 to 1 1] <Production of laminated extruded resin sheet> As the resin layer A, the resin of the type shown in Table 1 was melt-kneaded in the extruder 1 and supplied to a supply head. On the other hand, as the resin layer B, the resin of the type shown in Table 1 of -27-201041737 was melt-kneaded in the extruder 2 to be supplied to the supply head. The resin layer A supplied from the extruder 1 to the supply head becomes the main layer. The resin layer B supplied from the extruder 2 to the supply head is formed into a surface layer (single side/upper side), and is subjected to co-extrusion molding. Then, the molten laminate extruded from the die 3 was pressed out of the resin sheet 4, and the film was formed by sandwiching the No. 1 light and the No. 2 _ which were formed by the rolls shown in Table 1, and the sheet 1 was obtained. The laminate formed of the two-layer structure shown in the thickness is pressed out of the resin sheet. Further, the surface temperature of the No. 1 roller was 120 ° C, and the surface temperature of the No. 2 roller was 1, 30 ° C. These temperatures are used to measure the surface temperature of each roll. Further, the "thickness" of the extruders 1 and 2 in Table 1 indicates the respective thicknesses of the resin layers A and B. The "total thickness" in Table 1 indicates the total thickness of the resulting laminate pressed out of the transverse grease board. <Preparation of surface-coated sheet> The surface of the touch panel on the touch side of the obtained resin sheet, i.e., the surface of the resin layer B, was coated with a cured film to obtain a surface-coated sheet. Specifically, first, 5 parts of dipentaerythritol hexaacrylate as a monomer, 50 parts of pentaerythritol tetraacrylate, and 4.5 parts of an IVAGAURE 184, 1.5 parts of a Ciba Specialty Chemical Co., Ltd. as an initiator. IRGACURE 907, 0.1 parts of BYK Chemical Co., Ltd. as a leveling agent, ΒΥΚ-3Ό7, each mixed in a solvent of 125 parts of isobutanol and 125 parts of 1-methoxy-2-propanol And get a mixed liquid. Next, the mixed liquid was applied onto the surface of the resin layer B by a rod coater of No. 6 'The ultraviolet rays of 〇 5 j /cm 2 -28- 201041737 were irradiated with a high-pressure mercury lamp of 1 2 0 W to harden. On the surface of the resin layer B, a cured film having a thickness of about 3 · 5 μm was formed to obtain a surface-coated sheet. [Examples 12 to 22 and Comparative Example 1] As the resin layer A, the resin of the type shown in Table 1 was melt-kneaded in the extruder 1 and supplied to the supply head. On the other hand, as the resin layer B, the resin of the type shown in Table 1 was melt-kneaded in the extruder 2 and supplied to the supply head. The resin layer A supplied from the extruder 1 to the supply head is an intermediate layer, and the resin layer B supplied from the extruder 2 to the supply head is formed into a two-layer layer, and is subjected to co-extrusion molding. Then, the molten laminate extruded from the die 3 was pressed out of the resin sheet 4, and the film was formed by sandwiching the No. 1 roll and the No. 2 roll formed by the rolls shown in Table 1, and the obtained sheet was obtained. The laminate formed of the three-layer structure shown in the thickness is pressed out of the resin sheet. Further, the surface temperature of the No. 1 roll was 11 (TC, and the surface temperature of the No. 2 roll was 1 2 5 ° C. Q was obtained in any of the resin layers B and B of the resin sheet obtained by lamination of each of the obtained laminates. On the surface of the resin layer B, a cured film having a thickness of about 3.5 μm was formed in the same manner as in the above Examples 1 to 11, and a surface-coated plate was obtained. [Comparative Examples 2 to 4] The resin of the type shown in Table 1 was extruded. The machine 1 is melt-kneaded and supplied in the order of the supply head and the die 3. Then, the melt extruded from the die 3 is pressed out of the resin sheet, and the No. 1 roll is formed by the rolls shown in Table 1. And the No. 2 roll was used for the film formation, and the extruded resin sheet which consists of a single layer structure of thickness -29-201041737 shown in the surface was obtained. On the one side of each obtained resin plate. A cured film having a thickness of about 3 · 5 μm was formed in the same manner as in the above Examples 1 to 1 to obtain a surface-coated sheet. <Evaluation> For each of the obtained extruded resin sheets (Examples 1 to 22 and comparison) Example 1 to 4), evaluation of shrinkage ratio and hysteresis 。. Further, for each of the extruded resin sheets and the respective surface-coated sheets, Pencil hardness and stylus evaluation. The evaluation methods are shown below, and the results are shown in Table 1. (Shrinkage ratio) First, a test of about 10 cm square is cut out from the obtained extruded resin sheet. The sheet was measured for the size (MDO) in the extrusion direction and the dimension (TDO) in the width direction of the test piece. Then, on the metal pad, the baby talcum powder (the SiCCar〇l-Hi manufactured by Hikaru) was placed. ”), the test piece placed on the test piece was placed in a box at 160 ° C for 30 minutes. Then, the size (MD) and the dimension in the width direction (TD) of the naturally cooled test piece were measured. Substituting the obtained dimensions into the formula: shrinkage ratio S1 = {1-(MD/MD0) }xi〇〇, formula··shrinkage ratio S2 = { 1- ( TD/TDO ) }xl〇〇, calculate the shrinkage rate SI Further, the ratio (S1/S2) is calculated from the calculated shrinkage rates SI and S2. The results of '+ in the shrinkage ratios S1 and S2 in Table 1 indicate shrinkage, and the result of - indicates expansion. 201041737 (hysteresis 値) Cut out a 50 mm square test piece from the resulting extruded resin sheet, using a small area of birefringence The retardation 此 of this test piece was measured by the "KOBRA-CCO/X" manufactured by Oji Scientific Instruments Co., Ltd. (pencil hardness). It was measured according to JIS K5600. Further, the resin of Example 1 to 11 was extruded. The measurement surface of the board is the resin layer B. Further, in the pencil hardness of Table 1, "resin board" means an extruded resin sheet, and "coating board" means a surface coating board (stylus evaluation) for extruding a resin. On the surface of the board and the surface-coated board, the "DS stylus" manufactured by Nintendo Co., Ltd. was used to describe the characters in a normal manner, and the damage of the rubbed portion was visually confirmed. Further, the pressure of the examples 1 to 1 1 was the surface of the resin sheet B. In addition, the following criteria are used for the determination criteria: no damage △: shallow damage x: deep damage -31 - 201041737 one by one] m 赙 remaining I 〇〇〇〇o 〇〇〇〇〇〇〇〇〇o 〇〇〇〇〇〇0 <<<<3 am 蔺靼<<3<3<<<<3<<J<3<1<1 0 <3 <1 ο 0 <3 <1 <1 <\ <3 XXXX mm Μ m button m 醵η 5 工 CO X CO X CO X OJ s co co 5 5 5 X CM X CNJ 5 5 XXX ψ ψ m CO XXXXXXXXX CO X CO XXX CD QQ ca X ω XX CO X m X m CO m CO mo CO ί 美 Ρ 1 and E c CO r — 宕CM CO <D CO <〇ε 5 «2 00 卜i〇〇> og »-· l〇CSJ 兮布<〇5 inch<〇eg CSJ co CSI 芝IO IO LO 5 CM CO in (Ο ΙΟ i£> » ·» l〇in a> 00 to co CM CM CM CO CO CO CO Io OJ oc^i csi ΙΟ r- o cn τ- Ι 0 csi CM 1 ID csi C> J 1 ΊΤ» CO CO p »- to T- S r·* CO r— CO ρ 〆Τ o eja o CO CNJ f— CNJ CM CO SR CO iq <»" 00 o to o CO ο CO d 卜 o* CNJ 0 1 V- o CSJ o ▼— 〇> o T— a> d 卜 o 卜· to o <〇o ο 1 in o <〇T—CO ω 忒σ> ΙΟ <〇<6 00 <si <〇V-» CO <d οα τ— cr> or— <〇OJ CNI cvi lO XT CM C5 CJ t— CNJ Gas CSI r- o 00 Bu· o CO 卜·iq ▼— Hall chain m TTTf w rrtl gl r· OJ r— r— 1-· CM CM CSJ t—· y— 1·—one CM CM T~ m st EE 5 ay T—CO o To o iO o CO d 1—in iq CM CO o in csi in o 00 o to iq CD CSI T — ΙΟ ΙΟ in o — CJ % 1 o O- PC/PMMA PC/PMMA PC/PMMA I PC/PMMA PC /PMMA ο Q- PC/PMMA PC/PMMA PC/PMMA PG/PMMA -< is £ PMMA/PC/PMMA PMMA/PC/PMMA PMMA/PC/PMMA ss % Q_ Contains 1 1 m O. Change o Q. Variable PMMA/PC/PNMA 1 Q-^ % CL· Μ ο _ £ PMMA/PC/PMMA PC/PMMA/PC oogo 0.07/0.07 0.07/0.07 l iOO/LO.O 1 g 〇sog 〇o I 0.07/0.07 1 \ 0.07/0.07 ! ε O p ε ο ο 0.07/0.07 SOO/SOO CS m 田 m Μ £ £ ε sog 〇so ε osogosogdgo 5 so 1 1 1 PQ 幽m SX2 ιίπΙ CM CM CNJ cst CM CM CsJ CM CM Cs» €SI CO csi Cs» CM c>i CO CO CO _丨一Φ <£>〇<〇CO eo •r- 1 1 1 <D CO 々· CNI ϊ 壬m 53⁄41 ffi Wt £ Ρ ε 〇CO o CO CNl o 3 oo P o CO 〇> o 03⁄4 00 CO o 卜 5 CO oo % o % d> % o CD CO o CO CO o <幽oc to 丨雠一- - — *- y^" CSJ 一i ϋ :CS 11 (In cn _ 1 jo in 'choose i r- >1 oc :隹l〇N p 1 i •p II π黑黑 1 kl - _ i 隹||B cn 隹!l (_ in 1 5 i Cui J®5 i grip JS oo Ϊ n jp a, 1 ]? >In (|ί· CS Thick g ρ艺进_ J ιι·i E ; IJ± si l[i :mm . Rong 揉 揉 馏 馏 馏 馏 甚 甚 甚 甚 甚 甚 甚 甚 £ 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 圧 蓉 蓉 蓉 蓉 蓉 蓉 蓉 蓉 蓉 蓉 蓉 蓉 蓉 蓉 蓉It is understood that the extruded resin sheets of Examples 1 to 2 of Comparative Examples 1 to 4 have a good pencil hardness and a good touch, and the surface is not easily damaged. Further, it is known that the cured coating on the boss is improved. The surface is not easily damaged. The shrinkage ratio and hysteresis of Examples 1 to 4, 6 to 8, and 12 to 21 which are lightly composed of 1 are small. On the other hand, for the examples 1 to 11, the layer 2 is fine. The resin sheet was bent by hand to bend the resin sheet, and the evaluation was a curvature. As a result, the extruded resin sheet showed the result of being bent even. Further, in Example 12 and the resin sheet which were formed of a three-layer structure, the extrusion tree f of the example 16 to 2 2 in which the acrylic resin layer was a layer made of a methacrylic polymer was similarly described. Evaluate the bendability. As a result, the extruded resin sheet is not easily broken. [Brief Description of the Drawings] Fig. 1 is a schematic explanatory view showing a method of manufacturing a touch panel resin sheet according to an embodiment of the present invention. Fig. 2 is a cross-sectional explanatory view showing a metal light in an embodiment of the present invention. Fig. 3 is an explanatory view showing an elastic surface of another embodiment of the present invention. [Description of main component symbols] Compared with the purpose of the control panel, the evaluation of the control pen is particularly effective in pressing the resin, and the pressure generated by the resin plate is broken (the bent resin is not easily broken and the resin and the rubber sound plate are broken). The above shows the squeezing of the roll for the bending plate and the roll of the elastic roller - 33 - 201041737 1 , 2 : the extruder 3 : the die 4 : the molten laminate is pressed out of the resin plate 5 : the cooling roll 6 : the metal roll 7, 1 5: metal elastic roller 8, 16: shaft roller 9, 17: metal film 1 〇: fluid 1 1 : laminated panel for touch panel extruded resin plate - 34-