201040018 六、發明說明： 【發明所屬之技術領域】 本發明為一種非PVC系壓延加工的聚烯烴組合物，可採用傳統 製作聚氯乙烯膠布的壓延製程所製成聚稀烴朦布。 、/ 【先前技術】 近年來，世界各國對環保議題，愈來愈重視，先進國家為解決 此-存在已久的環保問題，乃姆歡__法規，要求各個 ’逐步限制或強制回收各式塑膠製品，如歐盟已在其相關法令中，針 〇 對包裝材料與塑膠製品成分’明文限制不得使用特定重金屬、聚氯乙 烯(Poly vinyl chloride，簡稱PVC)或苯乙稀等成分，以期降低 對環境生態的絲。此外’多家全球知名企業為了其環保形象，也多 自發性的宣佈其PVC限用政策，包括包裝材料、建材、零件等。 故有業者利用其他環保塑化材料，如中華民國公告之既脱斗號 . 專利所述，以聚乙烯_穴％1哪’簡稱PE)、乙稀_醋酸乙烯醋共聚 ^KEthylene-vinyl acetate Copolymer ’ 簡稱EVA)或聚乙稀·醋酸乙烯 • 酯共聚合物acetate，簡稱pEVA)等，以T_Die加工 製作出具有壓紋的塑膠布。由於PE、EVA或四从等材料特性，與 ❹PVf並獨’故以傳統製作PVC驗布的製造方法是無法用以製作 ^相同品質的PE、EVA或PEVA壓紋布，必須添講新設備(T_Die 機)或大幅修改傳統製作PVC壓紋布的設備，才能製作生產。 壓延加工是像统製作PVC壓紋布最為經濟與高效率之製造方法 ’可製得具有厚度謹宅米至2.0絲的塑膠布或塑膠膜。壓延的 =娜布（或塑膠膜）可立即熱定型為各式形狀，廣泛應用包括 匕裝、水池與游泳池内襄、平面藝術、表面飾板、文具或糾等產品 .雖然T-Die力口工法可以製造出優越品質的塑膠布或塑谬膜，但是丁_ Die加工法沒有壓延法的產率和經濟之優點。 因PE、EVA或PEVA等材料的韌性好，但在高溫時pE、EVA 或PEVA等材料熔融強度不夠，使得熔融狀的塑料於壓延機引出， 8 201040018 ί 錢行熱觀與細。故—般_塑膠布 的塑膠布(或塑膜二料通過該Z型模具’即可製作出平面狀 入一劣舳、多、再對該塑膠布進行冷卻定型，然後將塑膠布導 入一加熱滾壓輪組，進行壓紋之後，立即進行冷卻處理〇 / 或一般PE、EVA或ΡΕνΑ娜布時，因PE、嫩 生好但彈性喊性差之雛，輪拉伸 ϋ體【紋隻的模糊不清’且在滾壓立體凸紋時，對pe、 ，因;不膠布的連續酿造成傷害，_製成的壓紋塑膠布 X、，或不均勻’極易在壓紋位置被撕裂。聚烯烴材料以壓 L法加工，溶雜度高容易雜，致扭力增Α，不易加工，如 以觀法製作一種表面舰立體清晰且結構“ 句勻的膠布，即成為業界致力研究的一個課題。 【發明内容】201040018 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a non-PVC type calendered polyolefin composition which can be produced by a calendering process of a conventional polyvinyl chloride tape. / / [Previous technology] In recent years, countries around the world have paid more and more attention to environmental protection issues. In order to solve this problem, the advanced countries have long been responsible for environmental protection issues, and they are required to gradually limit or force various types of recycling. Plastic products, such as the European Union, in its relevant laws and regulations, the packaging materials and plastic products are 'exclusively restricted to use certain heavy metals, polyvinyl chloride (PVC) or styrene, in order to reduce the The silk of environmental ecology. In addition, many globally renowned companies have spontaneously announced their PVC restriction policies, including packaging materials, building materials and parts, for their environmental image. Therefore, some operators use other environmentally-friendly plasticized materials, such as the Republic of China Announcement, which is the name of the hopper. The patent says that the polyethylene _ acupoint %1 which is referred to as PE), ethylene _ vinyl acetate vinegar copolymer KEthylene-vinyl acetate Copolymer 'Abbreviated as EVA) or polyethylene, vinyl acetate, ester acetate (pEVA), etc., T_Die processing to produce embossed plastic cloth. Due to the material properties of PE, EVA or Si-Bei, the manufacturing method of PVC fabric inspection with traditional PVF cannot be used to make PE, EVA or PEVA embossed fabric of the same quality, and new equipment must be added. T_Die machine) or the equipment that traditionally made PVC embossed cloth can be modified to produce. Calendering is the most economical and efficient manufacturing method for making PVC embossed fabrics. It can be made of plastic or plastic film with a thickness of 2 to 2 wires. Calendered = Nabu (or plastic film) can be instantly heat-set into a variety of shapes, including a wide range of applications including armor, pool and swimming pool interiors, flat art, veneer, stationery or correction products. Although T-Die force The method can produce a superior quality plastic or plastic film, but the D-die process has no yield and economic advantages of the calendering method. Due to the good toughness of materials such as PE, EVA or PEVA, the melting strength of materials such as pE, EVA or PEVA is not high enough at high temperatures, so that the molten plastic is drawn out in the calender, 8 201040018 ί Money is hot and fine. Therefore, the plastic cloth of the plastic cloth (or the plastic film can pass through the Z-shaped mold to make a flat shape into a bad shape, and then the plastic cloth is cooled and shaped, and then the plastic cloth is introduced into a heating. Rolling wheel set, after embossing, immediately after cooling 〇 / or general PE, EVA or ΡΕνΑ Nabu, due to PE, tender and good, but the elasticity of shouting poor chicks, the wheel stretched the body Unclear 'and when rolling three-dimensional relief, on pe, , because; no continuous damage caused by the tape, _ embossed plastic cloth X, or uneven 'very easy to be torn at the embossed position The polyolefin material is processed by the pressure L method, the solubility is high and easy to be mixed, the torsion force is increased, and it is difficult to process. For example, by making a surface ship with a three-dimensionally clear and structurally uniform sentence, it has become a research institute in the industry. Problem. [Summary of the Invention]
餘押出:射出、壓延等加工方法之不同，成型狀況亦 5，/、料組合配方經特別研究。為解決上述以壓延法製作表面壓 =立體清晰且結構強度均勻的非PVC系樹脂膠布之魏，經本發明人 、之貝驗赌纣發現，先使特殊組成的烯烴組合物及其他助劑的配方 用混合機混合均勻再經萬馬力機⑽丄製，狐x300HP)均句混練初 步膠化成融溶狀，再經軋輪機(N-P.C製，26x84xl50HP)充分谬化， 其膝化過程如圖一所示。當樹脂進入膠化過程，膠化後經壓延能順利 被加工成膠布薄膜。 本f明的主要目的在於提供非PVC系組成的聚烯烴組合物，亦 "T直接採用製作聚氯乙稀膠布的傳統壓延製程，獲得不同厚度之各式 幸人貝與硬質、表面光滑平整或壓紋立體清晰且結構強度均勻的膠布值 膠膜0 其製法為：使用非PVC系組成的聚烯烴混合物及其它添加助劑 的混合料先將所有原料以混合機混合均勻後引入萬馬力機均勻混煉， 再經由軋輪機充分膠化後，以壓延力口工製得一種聚稀煙膠布。這種聚 烯烴膠布具有可回收，且對環境較無污染之膠布。 201040018 本發明的聚烯烴組合物，因為可直接使用製作聚氣乙烯膠布的 傳統製程，不須增添或修改現有設備，可加工成聚烯烴膠布，因此本 發明之聚烯烴、址合物’經加工所得膠布具有加工成本低廉、產速快及 環保的優點。經由此壓延產出單層聚稀烴膠布，可以二層以上之膠布 貼合’產生更高厚度的堆疊結福膠布。 【實施方式】 本發明的聚烯烴膠布，其厚度介於002〜20 _，係藉由特殊組 成的聚嫦烴組合物，製成不同軟硬度之聚烯烴膠布。 ❹ Ο _ ^發明的聚烯烴膠布的製法，是先將聚烯烴組合物與助劑用混 合機混合均勻後引入萬馬力機均勻混煉，料温控制在13〇_2〇〇<>c經札 ，機’再翻製作聚氣乙稀膠布的傳統製程，就可製得具有加工 製程簡單，設備成本低廉及產速快之優點的聚稀烴膠布。 b本發明之製法亦可依各種膠布性能需要添加滑劑、抗氧化劑、 紫外線吸賴、耐糊、抗靜細、填細、色料及其他改質劑。 ^此，本發明的聚稀烴膠布，是由下列步驟所製得： ⑴將每百分重量之聚稀烴组合物樹脂1〇〇 PHR(Parts per Hundred忒 =sm)與滑劑〇.i〜15 PHR、可塑劑〇卜见pRR、助劑（包括改質 劑^几氧化劑、抗_劑、耐燃劑、填充劑、分散劑及紫外線吸收 劑等）0.1〜80 PHR及色料(》15 PHRa混合機混合均句 入萬馬力機均勻混煉。 (2)料溫控制在130〜2〇〇。〇，經乳輪機辄後，將均勻雜的混合料 ’以壓延機加工成型’其熱熔膠布厚度控制介於〇〇5 〜2 〇 入或不引^花輪組，壓製或不壓製所需的紋路，及 ()再將膠布引入冷卻輪組冷卻定型，經捲取製得。 適入利用不同聚稀煙樹脂具有不同特性黏度加以組合，使立 =顧，工所使用的聚烯烴組合物樹脂，係選自非聚t ，/ m乙婦㈣etMene，簡稱PE)、聚丙烯咖解_ne 間私沖）、乙烯-醋酸乙烯酯共聚合物卿‘㈣娜恤 201040018Remaining: different processing methods such as injection and calendering, and the molding condition is also 5, /, the material combination formula has been specially studied. In order to solve the above-mentioned non-PVC-based resin tape which has a surface pressure=three-dimensionally clear and uniform structural strength by the calendering method, it has been found by the inventors of the present invention that the olefin composition and other auxiliary agents of a special composition are first formulated. Mixing with a mixer and then kneading with a 10,000 horsepower machine (10), the fox x300HP) is initially kneaded into a melt-like state, and then fully smashed by a rolling mill (NP.C system, 26x84xl50HP). Shown. When the resin enters the gelation process, it can be processed into a film of tape after calcination. The main purpose of this f is to provide a polyolefin composition composed of non-PVC, and also directly adopt the traditional calendering process of making polyvinyl chloride tape to obtain various thicknesses of various types of shells and hard, smooth surface or The embossed value film with uniform embossing and uniform structural strength is prepared by using a mixture of non-PVC-based polyolefin mixture and other additives, first mixing all the raw materials in a mixer and introducing them into a 10,000-horsepower machine. After mixing, and then fully gelatinized by the rolling mill, a poly-smoke tape is obtained by rolling. This polyolefin tape has a recyclable tape that is less polluting to the environment. 201040018 The polyolefin composition of the present invention can be processed into a polyolefin tape without the need to add or modify existing equipment without the need to add or modify existing equipment, so that the polyolefin and the address compound of the present invention are processed. The obtained tape has the advantages of low processing cost, fast production speed and environmental protection. By thus calendering a single-layered polycarbonate tape, it is possible to bond two or more layers of tape to produce a higher thickness of the stacked bond fabric. [Embodiment] The polyolefin tape of the present invention has a thickness of 002 to 20 Å, and a polyolefin tape of different hardness is formed by a specially formed polyanthracene composition. ❹ Ο _ ^ Invented polyolefin tape is prepared by mixing the polyolefin composition and the auxiliary agent with a mixer and then introducing it into a 10,000-horse machine for uniform mixing. The material temperature is controlled at 13〇_2〇〇<> After passing through the traditional process of making a gas-filled polyethylene tape, the machine can produce a poly-hydrocarbon tape with the advantages of simple processing, low equipment cost and fast production speed. b The method of the present invention can also add a lubricant, an antioxidant, an ultraviolet ray, a paste, a static, a fine, a color, and other modifiers depending on the performance of various adhesives. ^, the polythene rubber tape of the present invention is obtained by the following steps: (1) 1% by weight of the polythene composition resin per resin (Parts per Hundred 忒 = sm) and a slip agent 〇.i ~15 PHR, plasticizer, see pRR, additives (including modifiers, several oxidants, anti-agents, flame retardants, fillers, dispersants and UV absorbers, etc.) 0.1~80 PHR and colorants ("15 The PHRa mixer mixes evenly into the 10,000-horsepower machine for uniform mixing. (2) The material temperature is controlled at 130~2〇〇.〇, after the milk turbine is smashed, the homogeneous mixed mixture is processed by calendering. The thickness of the melted cloth is controlled between 〇〇5 and 2, and the required wheel is pressed or not pressed, and () the tape is introduced into the cooling wheel set for cooling and shaping, and is obtained by winding. Using different polysmoke resins with different intrinsic viscosities, the polyolefin composition resin used in the work is selected from non-poly t, / m et al (four) etMene, referred to as PE), polypropylene coffee solution _ Ne inter-private), ethylene-vinyl acetate copolymer polymer Qing '(四)娜恤201040018
Copolymer，簡稱 EVA)、熱塑性聚稀烴(Thermoplastic polyolefin，簡 稱TPO)或熱塑性塑膠彈性體(Thermoplastic Elastomer，簡稱TPE)的 其中二種或二種以上的組合物。 其中’聚乙浠(PE)，可以是高密度聚乙烯(High Density Polyethylene，簡稱 HOPE)、低密度聚乙烯(Low Density Ply ethylene， 間稱 LDPE)、線性低密度聚乙稀(l〇w Linear Density Polyethylene，簡 稱 LLDPE)或是戊金屬 PE (Metallocene Polyethylene，簡稱 mPE) 〇 聚丙烯(PP)，是均聚聚丙烯(PP_H)、嵌段共聚聚丙烯(PP_B)、無 規共聚聚丙烯(PP-R)。 ΟCopolymer (abbreviated as EVA), thermoplastic polyolefin (TPM) or Thermoplastic Elastomer (TPE), of which two or more of them are combined. Among them, 'polyethylene phthalate (PE), which can be high density polyethylene (High Density Polyethylene, HOPE for short), low density polyethylene (Low Density Ply ethylene, LDPE), linear low density polyethylene (l〇w Linear) Density Polyethylene (LLDPE) or Metallocene Polyethylene (mPE) 〇 Polypropylene (PP), is a homopolypropylene (PP_H), block copolymer polypropylene (PP_B), random copolymer polypropylene (PP) -R). Ο
乙稀-醋酸乙稀酯共聚合物拓从），其醋酸乙稀I旨Acetate content，簡稱VA)含量可為卜28 %。 熱塑性聚烯烴(TPO)或熱塑性塑膠彈性體(TPE)，是動態硫化聚 烯烴TPE、嵌段共聚pp和聚烯烴類pe的共混物、聚酸胺類ρΕ 、含氟TPE、帶官能基的SEBS類TPE，浠烴系的ΤΡΟ，τρο中有 聚丙’烯(PP)或乙烯丙烯橡膠(EPDM)的混合物、乙烯_辛烯聚合的共 聚物、乙稀丁烯共聚物、乙稀-丙烯聚合的共聚物、乙烯·α稀烴乒聚 物等。 /月劑之使用，對聚烯:^樹脂在壓延機成型加工很重要，在高溫 熔融狀態不與膠布機金屬表面相枯。本發明使用的滑劑是魏酸系、 脂肪酸酯系、脂肪酸臨胺類、石徵烴系、金屬石驗類、有機石夕系之滑 劑，可利用上述不同種類的滑劑之一種或一種以上配合。 本發明使用可麵彳可調整成品的軟硬度亦可改善加玉滑性 塑劑包括雜_可麵、高分子触可麵、加工鱗， ^曰可塑舰自彡絲雛g旨、六^化#_旨、彳 磷義類、職類、麟族二酸輔；高分子魏可塑劑選自 承夭二酸丙烯酯；加城選自硕基油、;姆油、芳香基油。 ^烴膠布因應不同物性要求，使用各獅劑，包括:改質劑、 、抗囷劑、—劑、觀劑、錄劑及紫外線吸收劑的1中 種或-種以上搭配而成。其中改質舰自：甲基丙稀酸甲醋二 201040018 烯:苯乙烯共聚合物、乙烯·醋酸乙烯酯共聚合物；抗氧化劑選自：受 . ,# ^ —-，）充菌劑 自：；3¼糸化合物:如各種磷酸酯類耐燃劑、磷酸氨類耐j 阻驗類、磷酸酯類；抗菌劑選自：有機石申 卜燃劑、芳香 自:含磷系化合物:如各種磷酸酯類耐燃劑^ ^耐燃劑選 族St充氫姆:如氫心氫氣化銘 -，真充』選自.石反祕、枯土、滑石粉、石炭酸舞、帝母於、 石i石、矽f粉;分散劑選自:矽垸偶合劑、锆鋁偶合劑；i外ϊ吸 巧，選自減苯基笨并三嗤類紫外線吸收劑、或甲類 外線吸收劑的其中-種或一種以上。 戰Ethyl acetate-ethyl acetate co-polymer extension), its Acetate content (VA) content can be 28%. Thermoplastic polyolefin (TPO) or thermoplastic elastomer (TPE), which is a blend of dynamically vulcanized polyolefin TPE, block copolymer pp and polyolefin pe, polyamine ρΕ, fluorine-containing TPE, functionalized SEBS-based TPE, anthraquinone-based hydrazine, τρο having a mixture of polypropylene 'ene (PP) or ethylene propylene rubber (EPDM), ethylene-octene polymerized copolymer, ethylene butene copolymer, ethylene-propylene polymerization Copolymer, ethylene·α-least phenopolymer, and the like. The use of the /month agent is important for the formation of the polyene: resin in the calender molding process, and does not withstand the metal surface of the tape machine in the high temperature molten state. The slip agent used in the present invention is a Wei acid system, a fatty acid ester system, a fatty acid amine, a stone hydrocarbon system, a metal stone test, an organic stone slip agent, and one of the above various types of slip agents may be used. One or more combinations. The invention can use the surface hardness to adjust the softness and hardness of the finished product, and can also improve the addition of the jade sliding plastic agent, including the miscellaneous surface, the polymer touchable surface, and the processing scale, and the composite plastic ship from the silkworm g. Hua #_ _, 彳 义 义 、 职 职 职 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ;; Hydrocarbon adhesive tapes are prepared by using various lion agents, including: modifiers, anti-caries agents, agents, agents, recording agents and UV absorbers, in accordance with different physical properties. Among them, the modified ship is: methyl methacrylate methyl ketone II 201040018 olefin: styrene copolymer, ethylene vinyl acetate copolymer; antioxidant selected from: accept., # ^ —-,) bactericide from :; 31⁄4 糸 compound: such as various phosphate flame retardants, ammonia phosphate resistance test, phosphates; antibacterial agent selected from: organic stone Shenbu, aromatic from: phosphorus compounds: such as various phosphoric acid Ester flame retardant ^ ^ flame retardant selected family St hydrogen charge: such as hydrogen heart hydrogenation Ming -, true charge is selected from the stone anti-mystery, dry soil, talcum powder, carbolic acid dance, emperor in the stone, stone i stone,矽f powder; the dispersing agent is selected from the group consisting of: bismuth coupling agent, zirconium aluminum coupling agent; i sputum absorbing, selected from the group consisting of a phenyl group and a triterpenoid ultraviolet absorber, or a class A external absorbent or More than one. war
色料’可視產品的色相需求酌予添加，或為有機系色料 無機糸色料，亦可採無機、有機色料混合方式或透明不加色料。… 在使用上，本發明的聚烯烴膠布可以單層使用外，還可以加埶 方式，溫控在80°C〜180。〇貼合成多層使用。 下^將以實施例更具體地說明本發明，雖然以較佳之實施例被 露加以詳述，惟本發明之技術及權利範圍不受其所限制。 〔實施例1〕 生產厚度0.09 mm的聚烯烴膠布，其製法為： ⑴依表1的的配方1，將聚烯烴混合物樹脂（其中EVA之VA 含量為8~28%)、滑劑、可塑劑、助劑（包括改質劑、耐燃 劑、填充劑及紫外線吸收劑）等原物料用混合機混合均勻後 ，引入萬馬力機均勻混煉，均勻膠化； (2) 料溫控制在130°C〜200°C ’經軋輪機膠化後，將充分反應的 混合料’以壓延機加工成型厚度控制於0.09 mm的熱熔膠布 成型； (3) 再經或不經膠布引入壓花輪組，壓製或不壓製所需的紋路； 及 (4) 將膠布引入冷卻輪組冷卻定型，經捲取製成本發明之厚度為 0.09mm的聚烯烴膠布，其拉力強度md為65.2 kgcm2，CD 為 45·4 kg/cm2，伸長率 MD 為 861kg/cm2，CD 為 1010 kg/cm2，及撕裂之強度 MD 為 35.2 kg/cm2，CD 為 37.0kg/cm2 12 201040018 。其手感佳，而有真皮柔勃性。 〔實施例2〕 生產厚度〇.15mm的聚烯烴膠布’依表1的配方2及其製法皆同 實施例1。聚烯烴膠布之拉力強度MD為63.4 kg/cm2，CD為49.8 kg/cm2 ’ 伸長率 MD 為 684 kg/cm2 ’ CD 為 987 kg/cm2，及撕裂強度 之MD為35.4 kg/cm2 ’ CD為36.2kg/cm2。其手感佳’而有真皮柔勒 性。 〔實施例3〕 ❹生產厚度0.2 _的聚烯烴膠布，依表1的配方3及其製法皆同 實施例1。聚烯烴膠布之拉力強度MD為126.7 kg/cm2，CD為116.7 kg/cm2 ’ 伸長率之 MD 為 500 kg/cm2 ’ CD 為 690 kg/cm2，及撕裂強 度之MD為85.5 kg/cm2 ’ CD為72.1kg/cm2。其手感稍佳，真皮柔勃 性則不如實施例1及2。 〔實施例4〕 生產厚度0.1mm的聚烯烴膠布，依表1的配方4及其製法皆同 - 實施例卜聚烯烴膠布之拉力強度MD為74.6 kg/cm2，CD為68.9 kg/cm2 ’ 伸長率之 MD 為 690 kg/cm2，CD 為 836 kg/cm2，及撕裂強 ^ 度之MD為40.6 kg/cm，CD為40.3kg/cm2。其手感猶佳，真皮柔動 U 性則不如實施例1及2。 ' ’、 〔實施例5〕 生產厚度〇.1_的聚烯煙膠布，依表1的配方5及其製法皆同 實施例1。聚烯烴膠布之拉力強度MD為81.2 kg/cm2，CD為 70.6kg/cm2 ’ 伸長率之 MD 為 719kg/cm2，CD 為 958kg/cm2，及撕裂 強度之MD為52.6 kg/cm2，CD為55.8kg/cm2。其手感稍佳，真皮柔 韌性則接近實施例1及2。 / ^ 〔實施例6〕 生產厚度〇·3_的聚烯烴膠布，依表1的配方6及其製法皆同 實施例1。聚烯烴膠布之拉力強度MD為102 kgcm2，CD為 13 201040018 62.7kg/cm2，伸長率之MD 為 58 kg/cm2，CD 為 62kg/Cin2，及撕裂強 ‘度之MD為69.0 kg/cm2，CD為39.2kg/cm2。其手感稍佳，真皮柔韌 性則接近實施例1及2。 一 ^ 〔實施例7〕 生產厚度〇.2mm的聚烯烴膠布，依表1的配方7及其製法皆同 實施例1。聚烯烴膠布之拉力強度MD為59.1kg/cm2，CD為 97.3kg/cm2，伸長率之 MD 為 524㈣cm2，CD 為 447kgCm2，及撕裂 強度之MD為43.1kg/cm2，CD為30kg/cm2。其手感稍佳，真皮柔韌 性則接近實施例1及2。 ’、 Ο 〔比較例1〕 T-Die加工生產厚度為〇.2 mm的白色PEVA膠布。其拉力強度The coloring material 'can be added according to the hue requirement of the product, or it can be an organic coloring material, an inorganic coloring material, or an inorganic or organic coloring material mixing method or a transparent non-coloring material. ... In use, the polyolefin tape of the present invention can be used in a single layer, and can also be twisted in a manner of temperature control at 80 ° C to 180 °. 〇Paste and use in multiple layers. The invention will be more specifically described by the following examples, which are not to be construed as limited. [Example 1] A polyolefin tape having a thickness of 0.09 mm was produced by the following method: (1) According to Formula 1 of Table 1, a polyolefin mixture resin (in which the VA content of EVA is 8 to 28%), a slip agent, a plasticizer The raw materials such as additives (including modifiers, flame retardants, fillers and UV absorbers) are uniformly mixed by a mixer, and then uniformly kneaded by a 10,000-horse machine to uniformly gel; (2) The temperature of the material is controlled at 130°. C~200 °C 'After the rolling mill is gelatinized, the fully reacted mixture is formed by a calender to form a hot-melt tape with a thickness controlled to 0.09 mm; (3) the embossing wheel set is introduced with or without a tape. And (4) introducing the tape into the cooling wheel set for cooling and shaping, and winding the polyolefin tape of the present invention to a thickness of 0.09 mm, the tensile strength md is 65.2 kgcm2, and the CD is 45· 4 kg/cm2, elongation MD was 861 kg/cm2, CD was 1010 kg/cm2, and tear strength MD was 35.2 kg/cm2, and CD was 37.0 kg/cm2 12 201040018. It has a good feel and a soft leather. [Example 2] A polyolefin tape having a thickness of 1515 mm was produced. The formulation 2 according to Table 1 and the preparation method thereof were the same as in Example 1. The tensile strength MD of the polyolefin tape is 63.4 kg/cm2, the CD is 49.8 kg/cm2', the elongation MD is 684 kg/cm2' CD is 987 kg/cm2, and the MD of the tear strength is 35.4 kg/cm2 'CD 36.2 kg/cm2. It has a good feel and has a leather softness. [Example 3] A polyolefin tape having a thickness of 0.2 Å was produced, and the formulation 3 according to Table 1 and the preparation method thereof were the same as in Example 1. The tensile strength MD of the polyolefin tape is 126.7 kg/cm2, the CD is 116.7 kg/cm2', the MD of the elongation is 500 kg/cm2' CD is 690 kg/cm2, and the MD of the tear strength is 85.5 kg/cm2 'CD It is 72.1 kg/cm2. The hand feels slightly better, and the dermal softness is not as good as in Examples 1 and 2. [Example 4] A polyolefin tape having a thickness of 0.1 mm was produced, and the formulation according to Table 1 and the preparation method thereof were the same - the tensile strength MD of the polyolefin tape of the example was 74.6 kg/cm2, and the CD was 68.9 kg/cm2' elongation. The MD of the rate was 690 kg/cm2, the CD was 836 kg/cm2, and the MD of the tear strength was 40.6 kg/cm, and the CD was 40.3 kg/cm2. The hand feels good, and the softness of the leather is not as good as in Examples 1 and 2. ' </ RTI> [Example 5] A olefinic enamel cloth having a thickness of 〇.1_ was produced, and the formulation 5 according to Table 1 and the preparation method thereof were the same as in Example 1. The tensile strength MD of the polyolefin tape is 81.2 kg/cm2, the CD is 70.6 kg/cm2', the MD of the elongation is 719 kg/cm2, the CD is 958 kg/cm2, and the MD of the tear strength is 52.6 kg/cm2, and the CD is 55.8. Kg/cm2. The hand feel is slightly better, and the leather flexibility is close to that of Examples 1 and 2. / ^ [Example 6] A polyolefin tape having a thickness of 〇·3_ was produced, and the formulation 6 according to Table 1 and the preparation method thereof were the same as in Example 1. The tensile strength MD of the polyolefin tape is 102 kgcm2, the CD is 13 201040018 62.7kg/cm2, the MD of the elongation is 58 kg/cm2, the CD is 62kg/Cin2, and the MD of the tear strength is 69.0 kg/cm2. The CD was 39.2 kg/cm2. The hand feel is slightly better, and the dermal flexibility is close to that of Examples 1 and 2. [Example 7] A polyolefin tape having a thickness of 22 mm was produced, and the formulation 7 according to Table 1 and the preparation method thereof were the same as in Example 1. The tensile strength MD of the polyolefin tape was 59.1 kg/cm2, the CD was 97.3 kg/cm2, the MD of the elongation was 524 (four) cm2, the CD was 447 kg Cm2, and the MD of the tear strength was 43.1 kg/cm2, and the CD was 30 kg/cm2. The hand feel is slightly better, and the dermal flexibility is close to that of Examples 1 and 2. ', Ο [Comparative Example 1] T-Die was processed to produce a white PEVA tape having a thickness of 〇.2 mm. Tensile strength
MD 為 117.6 kg/cm2，CD 為 106.5kg/cm2，伸長率之 MD 為 650 kg/cm2 ’ CD 為 213 kgcm2 ’ 及撕裂強度之 MD 為 67.5 kg/cm2，CD 為69.3k&cm2。其手感較硬，而無柔勃性。 〔比較例2〕 - T-Die加工生產厚度0.09 mm的半透明PEVA膠布。其拉力強度 MD 為 75.3 kg/cm2 ’ CD 為 59.5kg/cm2，伸長率之 MD 為 357 kg/cm2 ’ CD 為 326 kg/cm2 ’ 及撕裂強度之 MD 為 42.1 kg/cm2，CD 為 ϋ 58.9kg/cm2。其手感較硬，而無柔韌性。 14 201040018 表1 配方 配方 1 配方 2 配方 3 配方 4 配方 5 配方 6 配方 7 比較例 1 比較例 2 樹月旨 滑劑 可塑劑 ------- 助劑 ---- -色料 ----- 聚丙烯(PP) 65 30 36 50 35 30 - 聚乙烯 -醋酸 乙烯酯 膠布 (PEVA, 白色） 聚乙烯 -醋酸 乙烯酯 膠布 (PEVA, 半透明 ) 聚乙烯(PE) 10 - 18 - 15 35 38 _ _ 熱塑性聚烯烴ΟΓΡΟ) 55 46 - 50 27 24 乙稀-醋酸乙烯酯共聚合物 (EVA) 5 - - 33 - - - »\， —1 _ ^塑性塑膠彈性體ΟΡΕ、 20 15 - 17 - 8 38_ 硬脂酸 — 0.1 0.2 0.2 0.2 0.1 - - 脂肪酸醯胺 0.1 0.2 0.2 0.1 - 0.3 η 而' 脂肪_ 0.1 02 0.2 0.1 - - 0.3 非酜酸酯可塑劑 2 - 5 5 3 - - _高分子聚酯可塑劑 3 3 3 3 3 - 20 加工油 _ 2 2 - - - :質劑 甲WNt曱路丁場 3 3 3 _ - - - 1外線 ：收劑 羥基二苯甲酮 0.3 0.3 0.3 0.3 0.3 0.15 碳酸約 50 50 20 - 15 70 L燃劑 氫氧化銘 5 5 5 - - 45 一 Tl〇2 - 5 5 5 - 4.5 4.8 ------- ，工聽(。〇 165 165 160 155 145 157 153 155 150 厚度(mm) 0.09 0.15 0.2 0.1 0.1 0.3 0.2 0.2 0.09 參(真皮柔韌感） 〇 〇 Δ △+ 〇 △+ 〇 X X 物性 --~----- 拉力強度 (kg/cm2) MD 65.2 63.4 126.7 74.6 81.2 102 59.1 117.6 75.3 CD 45.4 49.8 116.7 68.9 70.6 62.7 97.3 106.5 59.5 伸長率 (%) MD 861 684 500 690 719 58 524 650 357 CD 1010 987 690 836 958 62 447 213 326 撕裂強度 (kg/cm2) MD 35.2 35.4 85.5 40.6 52.6 69.0 43.1 67.5 42.1 CD 37.0 36.2 72.1 40.3 55.8 39.2 30.0 693 58.9 說明：〗·配方用量單位為·· PHR (每百份重量樹脂） 2. 物性測·· ASTMD~638 3. 手感(真皮柔韌感>:◎〇0△+△>< 有真皮柔韌感 -►無真皮柔韌感 4. MD:直向(Machine Direction) 5. CD:橫向(Cross Direction) 15The MD is 117.6 kg/cm2, the CD is 106.5 kg/cm2, the MD of the elongation is 650 kg/cm2' CD is 213 kgcm2' and the MD of the tear strength is 67.5 kg/cm2, and the CD is 69.3k&cm2. It feels harder and has no suppleness. [Comparative Example 2] - T-Die was processed to produce a translucent PEVA tape having a thickness of 0.09 mm. The tensile strength MD is 75.3 kg/cm2 'CD is 59.5 kg/cm2, the MD of elongation is 357 kg/cm2 'CD is 326 kg/cm2' and the MD of tear strength is 42.1 kg/cm2, CD is ϋ 58.9 Kg/cm2. It has a harder feel and no flexibility. 14 201040018 Table 1 Recipe Recipe 1 Recipe 2 Recipe 3 Recipe 4 Formulation 5 Formulation 6 Formulation 7 Comparative Example 1 Comparative Example 2 Shu Yue Slip Agent Plasticizer ------- Additive --- Color Material -- --- Polypropylene (PP) 65 30 36 50 35 30 - Polyethylene-vinyl acetate tape (PEVA, white) Polyethylene-vinyl acetate tape (PEVA, translucent) Polyethylene (PE) 10 - 18 - 15 35 38 _ _ Thermoplastic Polyolefin 55) 55 46 - 50 27 24 Ethylene-Vinyl Acetate Copolymer (EVA) 5 - - 33 - - - »\, -1 _ ^ Plastic Plastic Elastomer ΟΡΕ, 20 15 - 17 - 8 38_ Stearic acid — 0.1 0.2 0.2 0.2 0.1 - - Fatty acid decylamine 0.1 0.2 0.2 0.1 - 0.3 η and ' Fat _ 0.1 02 0.2 0.1 - - 0.3 Non-phthalate plasticizer 2 - 5 5 3 - - _ Polymer Polyester Plasticizer 3 3 3 3 3 - 20 Processing Oil _ 2 2 - - - : Quality Agent A WNt曱 Luding Field 3 3 3 _ - - - 1 Outside Line: Receiving Hydroxybenzophenone 0.3 0.3 0.3 0.3 0.3 0.15 Carbonate about 50 50 20 - 15 70 L Fuel Hydroxide Ming 5 5 5 - - 45 One Tl〇2 - 5 5 5 - 4.5 4.8 ------- , Gongyi (.〇165 165 160 155 145 157 153 1 55 150 Thickness (mm) 0.09 0.15 0.2 0.1 0.1 0.3 0.2 0.2 0.09 Reference (skin softness) 〇〇Δ △+ 〇△+ 〇XX Physical properties--~----- Tensile strength (kg/cm2) MD 65.2 63.4 126.7 74.6 81.2 102 59.1 117.6 75.3 CD 45.4 49.8 116.7 68.9 70.6 62.7 97.3 106.5 59.5 Elongation (%) MD 861 684 500 690 719 58 524 650 357 CD 1010 987 690 836 958 62 447 213 326 Tear strength (kg/cm2) MD 35.2 35.4 85.5 40.6 52.6 69.0 43.1 67.5 42.1 CD 37.0 36.2 72.1 40.3 55.8 39.2 30.0 693 58.9 Description: The formula is in the amount of PHR (per hundred parts by weight of resin) 2. Physical properties ··ASTMD~638 3. Feel (Leather flexibility]: ◎〇0△+△>< has leather flexibility-► no leather flexibility 4. MD: Machine Direction 5. CD: Cross Direction 15