TW201024360A - EVA plastic compound, preparation method and application for foaming products - Google Patents

EVA plastic compound, preparation method and application for foaming products Download PDF

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TW201024360A
TW201024360A TW97151180A TW97151180A TW201024360A TW 201024360 A TW201024360 A TW 201024360A TW 97151180 A TW97151180 A TW 97151180A TW 97151180 A TW97151180 A TW 97151180A TW 201024360 A TW201024360 A TW 201024360A
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eva
bridging
temperature
rubber
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TW97151180A
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yi-nan Liu
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yi-nan Liu
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Abstract

The invention provides an EVA plastic compound. The EVA plastic compound comprises the following weight constituents: EVA base stock that is 60-75KG; glue that is 2-4KG; a filler that is 1.5-2.5KG; a foaming agent that is 1.1-2.0KG; a crosslinking agent that is 0.6-0.8KG; a crosslinking auxiliary agent that is 0.4-0.6KG; activator that is 1.2-1.4KG; a lubricating agent that is 0.9-1.3 KG; a flowing agent that is 0.8-1.2KG; a modification agent that is 0.4-0.6KG; and color mater batch that is 0.8-3.0KG. The invention also provides a preparation method for the foregoing compounds and application for plastic products using the compounds. These products, such as sun helmets, cool hats, and leather cell phone cases, made of the EVA plastic compound of the invention are soft, light weight without toxicity and have environmental protection and low costs.

Description

201024360 六、發明說明: 【發明所屬之技術領域】 本發明涉及一種EVA橡塑組合物、該組合物的製儳方法以及 該组合物用作橡塑製品的應用。 【先前技術】 EVA橡塑製品是新型環保塑膠發泡材料,具有良好的緩衝、抗 震、隔熱、防潮、抗化學腐蝕等優點,且無秦、不吸水^ EVA橡塑 製品經設計可加工成形,其防震性能優於聚苯乙烯(泡沫)等傳 ® 統發泡材料,且符合環保要求,廣泛用於工藝拖鞋、沙灘涼拖、 保健拖和休閒拖的製作及箱包内襯、兒童拼圖玩具、浴板、潔具 密封墊、塑膠地板、隔音隔熱、車座墊、漁網漂等領域。 但是,現有EVA橡塑材料較硬,不易製成較薄的製品,因此無 法在一次遮陽帽、涼帽、手機套等領域得到廣泛的應用。 【發明内容】 本發明所要解決的技術問題是解決現有的PA橡塑材料製品 ®硬度較大,無法在一次遮陽帽、涼帽、手機套等領域得到廣泛的 應用的問題》 為了解決上述技術問題,本發明所採用的技術方案是提供一 種EVA橡塑組合物,包括以下重量的组分: EVA 基料 60 〜75KG ; 標膠 2〜4KG ; 填充劑 1.5〜2.5KG ; 發泡劑 1.1〜2.0KG; 201024360 架橋劑 0. 6 〜0,8KG ; 架橋助劑 〇· 4〜0· 6KG ; 活性劑 1.2 〜1.4KG ; 潤滑劑 0.9〜1.3KG ; 流動劑 〇· 8〜1.2KG ; EVA改質劑 〇. 4〜0. 6KG ; 顏料 0.8〜3.0KG。 所述EVA基料為EVA乙烯-醋酸乙烯共聚物與熱塑性彈性體的 混合物’該混合物中EVA乙婦-醋酸乙烯共聚物的重量百分比為46 〜54%。 所述填充劑為滑石粉,所述發泡劑為AC發泡劑,所述標膠為 3L標膠,所述活性劑為氧化鋅,所述架橋劑為無味!)〇>,所述架 橋助劑為三稀丙基異氣腺酸酯,所述流動劑為脂肪酸酯,所述EVA 改質劑為超微粒活性劑。 ® 所述满滑劑為硬脂酸和硬腊酸鋅的混合物,該混合物中硬脂 酸的重量百分比為33〜38.5%。 所述顏料包括多種色母或者多種色母與鈦白粉的組合,以使 該組合物具有不同的顏色。 本發明還提供了該EVA橡塑組合物的製僙方法,包括以下步 驟: 步驟一:按以下重量準備原料組分·•基料,6〇〜75KG ;構 膠,2〜4KG ;填充劑,1.5〜2.5KG ;發泡劑,1· 1〜2. 〇KG ;架橋 201024360 劑,0.6〜0.8KG ;架橋助劑,〇. 4〜〇. 6KG ;活性劑’ 1· 2〜1· 4KG ’ 潤滑劑,0. 9〜1. 3KG ;流動劑’ 〇· 8〜1.2KG ; EVA改質劑’ 〇·4〜 0· 6KG ;顏料,〇· 8〜3.0KG ; 步驟二:密煉作業; A、開啟密煉主機,設定溫度為T7〜83SC,倒入EVA基料,楳 膠,填充劑,架橋助劑,活性劑’潤滑劑,流動劑,EVA改質劑’ 色母,壓下壓力錘; ❹ B、密煉溫度調整為95〜100QC,翻料、清掃粉塵,保持時間7 分鐘; C、 密煉溫度調整為1〇5〜ll〇QC,翻料、清掃粉塵,倒入發泡 劑和架橋劑,保持時間1〇分鐘; D、 密煉溫度調整為H52C,翻料、清掃粉塵,保持時間n分 鐘; ❹ E、密煉溫度調整為118〜12代,保持時間12分錢 將密練主機之内的物料倒出; 步驟三:開煉作業; A、開啟開煉主機,設定溫度為65〜7〇吒; ^調整滚輪間隙2〜3_,將步碌二中所得的物料打㈣ c、割下物料; 步驟四:造粒作業; 85=啟造粒機,龜度設定為75〜㈣,模頭溫度設定 201024360 B、 將步驟三中割下的物料投入造粒機; C、 切刀轉速設定為20〜25HZ,控制造粒長度為2〜3mm。 本發明還提供了上述EVA橡塑組合物用作發泡製品的應用,包 括以下步驟: 步称一:安裝欲加工製品的配套模具; 步称二:將橡塑組合物投入射出機; 步驟三:射出機設定溫度為177〜183 QC,硫化時間為220秒 〇 〜240秒; 步驟四:設定射出機射槍溫度為82、83、85、87 QC中的一種, 對應設疋射搶壓力和最低射出速度分別為:6〇f3ar、2mm/s; 65bar、 2· 66咖/s; 70bar、2· 83 咖/s; 75bar、3mm/s;或 80 bar、3.17mm/s; 步驟五、用風搶將模具内清理乾淨,噴適董脫模水; 步驟六、用風搶吹幹模具内脫模水後,注入所需料量,合模; 步驟七、開模後迅速取出成品,套在楦頭上至完全冷卻。 © 本發明中由於發泡劑、活性劑、潤滑劑、EVA改質劑和流動劑 的合理配比’使得使用本發明的EVA橡塑組合物製成的遮陽帽、 涼帽、手機套等製品,柔軟、輕便而且無毒、環保,成本低。 【實施方式】 下面結合具體實施方式對本發明進行詳細的說明。 本發明包括以下重量的組分: EVA 基料 60 〜75KG ; 標膠 2〜4KG ; 201024360 填充劑 1.5 〜2.5KG ; 發泡劑 1.1 〜2.0KG ; 架橋劑 0· 6〜0· 8KG ; 架橋助劑 0· 4〜0· 6KG ; 活性劑 1.2〜1.4KG; 潤滑劑 0.9〜1.3KG; 流動劑 0.8〜1.2KG; EVA改質劑 0.4〜0.6KG ; 顏料 0· 8〜3· 0KG。 所述EVA基料為EVA乙烯-醋酸乙烯共聚物與熱塑性彈性體的 混合物’其中所述EVA乙烯-醋酸乙烯共聚物與熱塑性彈性艎的混 合物中EVA乙烯-醋酸乙烯共聚物的重量百分比為46〜54%。 Ο ❹ 所述填充劑為滑石粉,所述發泡劑為AC發泡劑,所述標膠為 3L標膠,所述活性劑為氧化鋅,所述架橋劑為無味pep,所述架 橋助劑為三烯丙基異氰脲酸酯,型號為PC18 ;所述流動劑為高分 子量脂肪酸酯,如丙二酵脂肪酸酯或聚乙二醇脂肪酸酯,型號為 L709 ;所述EVA改質劑為超微粒活性劑,型號為K133 » 所述潤滑劑為硬脂酸和硬脂酸鋅的混合物,該混合物中硬脂 酸的重量百分比為33〜38.5%。 所述顏料包括多種色母或者多種色母與鈦白粉的組合,以使 該組合物具有不同的顏色。下面結合具體實施例進行說明。 實施例一: 201024360 本發明包括以下重量百分比的組分: EVA乙烯-醋酸乙烯共聚物 35KG ; 7467熱塑性彈性體 20KG ; 735熱塑性彈性體 12. 5KG ; 3L標膠 3KG ; RB510滑石粉 2KG; AC6000H發泡劑 1.1KG; 〇 無味DCP架橋劑 0.7KG ; 氧化鋅 1. 26KG ; 三烯丙基異氰脲酸酯 0· 5KG ; 硬脂酸 0· 4KG ; 硬脂酸辞 0. 68KG ; L709流動劑 1KG ; K133EVA 改質劑 0.5KG; 〇 色母 1503 0.54KG ; 色母1372 0.063KG ; 色母3513 0.025KG ; 色母1509 0.19KG。 本實施例的橡塑組合物顏色為紅色。 實施例二: 本發明包括以下重量百分比的組分: EVA乙烯-醋酸乙烯共聚物 30KG ; 201024360 7467熱塑性彈性體 20KG ; 735熱塑性彈性體 10KG ; 3L標膠 2KG ; RB510 滑石粉 1.5KG; AC6000H 發泡劑 1.1KG; 無味DCP架橋劑 0.6KG ; 氧化鋅 1.2KG; φ 三烯丙基異氱脲酸酯 0. 4KG ; 硬脂酸 0. 3KG ; 硬脂酸鋅 0. 6KG ; L709 流動劑 0.8KG ; K133EVA 改質劑 0.4KG ; 鈦白粉R109 0.8KG ; 黃色母 3513 0.44KG; ⑩ 黃色母3515 1.58KG。 本實施例的橡塑組合物顏色為黃色。 實施例三: 本發明包括以下重量百分比的組分: EVA乙烯-醋睃乙烯共聚物 40KG ; 7467熱塑性彈性體 25KG ; 735熱塑性彈性體 10KG ; 3L標膠 4KG ; 201024360 RB510 滑石粉 2.5KG; AC6000H 發泡劑 2.0KG; 無味DCP架橋劑 0.8KG; 氧化鋅 1.3KG; 三烯丙基異氟脲酸酯 0.6KG ; 硬脂酸 0.5KG ; 硬脂酸鋅 0.8KG ;201024360 VI. Description of the Invention: [Technical Field] The present invention relates to an EVA rubber composition, a method for preparing the composition, and the use of the composition as a rubber product. [Prior Art] EVA rubber and plastic products are new environmentally friendly plastic foam materials, which have good buffering, shock resistance, heat insulation, moisture resistance, chemical corrosion resistance, etc., and no Qin, no water absorption ^ EVA rubber and plastic products are designed to be processed Its shockproof performance is superior to that of polystyrene (foam) and other foaming materials, and it meets environmental protection requirements. It is widely used in the production of craft slippers, beach sandals, health care trailers and leisure trailers, luggage linings, children's puzzles. , bath boards, sanitary ware gaskets, plastic flooring, sound insulation, car seat cushions, fishing nets and other fields. However, the existing EVA rubber and plastic materials are hard and are not easy to be made into thin products, so they cannot be widely used in the fields of sun hats, cool hats, and mobile phone cases. SUMMARY OF THE INVENTION The technical problem to be solved by the present invention is to solve the problem that the existing PA rubber material product® has a large hardness and cannot be widely applied in the fields of a sun visor, a cool hat, a mobile phone case, etc. In order to solve the above technical problems, The technical solution adopted by the present invention is to provide an EVA rubber-plastic composition comprising the following components: EVA base 60~75KG; standard glue 2~4KG; filler 1.5~2.5KG; foaming agent 1.1~2.0KG 201024360 bridging agent 0. 6 ~ 0,8KG; bridging aid 〇·4~0·6KG; active agent 1.2~1.4KG; lubricant 0.9~1.3KG; flow agent 〇·8~1.2KG; EVA modifier 〇. 4~0. 6KG; pigment 0.8~3.0KG. The EVA base material is a mixture of EVA ethylene-vinyl acetate copolymer and a thermoplastic elastomer. The weight percentage of the EVA methyl-vinyl acetate copolymer in the mixture is 46 to 54% by weight. The filler is talc, the foaming agent is an AC foaming agent, the standard glue is 3L standard glue, the active agent is zinc oxide, and the bridging agent is odorless!) 〇 The bridging aid is tris-propyl isogaslate, the flow agent is a fatty acid ester, and the EVA modifier is an ultrafine active agent. The slip agent is a mixture of stearic acid and zinc stearate, and the weight percentage of stearic acid in the mixture is 33 to 38.5%. The pigment comprises a plurality of color masterbatch or a combination of a plurality of color masterbatch and titanium dioxide to impart a different color to the composition. The invention also provides a method for preparing the EVA rubber-plastic composition, comprising the following steps: Step 1: preparing raw material components according to the following weights: • base material, 6〇~75KG; gelatin, 2~4KG; filler, 1.5~2.5KG; foaming agent, 1·1~2. 〇KG; bridging 201024360 agent, 0.6~0.8KG; bridging aid, 〇. 4~〇. 6KG; active agent '1·2~1· 4KG ' Lubricant, 0. 9~1. 3KG; flow agent '〇·8~1.2KG; EVA modifier '〇·4~ 0·6KG; pigment, 〇·8~3.0KG; Step 2: mixing operation; A, open the mixing host, set the temperature to T7 ~ 83SC, pour EVA base, silicone, filler, bridging aid, active agent 'lubricant, flow agent, EVA modifier' color masterbatch, pressure reduction Hammer; ❹ B, the mixing temperature is adjusted to 95~100QC, turning and cleaning the dust, keeping the time for 7 minutes; C, the mixing temperature is adjusted to 1〇5~ll〇QC, turning the material, cleaning the dust, pouring the foam Agent and bridging agent, keep the time for 1 minute; D, the mixing temperature is adjusted to H52C, turning and cleaning the dust, keeping the time n minutes; ❹ E, the mixing temperature is adjusted to 118~12 Generation, keep the time 12 cents to pour out the materials inside the compact host; Step 3: Open the refining operation; A, open the refining host, set the temperature to 65~7〇吒; ^Adjust the roller gap 2~3_, will The material obtained in Step 2 is (4) c, cut off the material; Step 4: Granulation operation; 85 = Start granulator, the turtle is set to 75~(4), the die temperature is set to 201024360 B, and the step 3 is cut off. The material is put into the granulator; C, the cutter speed is set to 20~25HZ, and the granulation length is controlled to 2~3mm. The invention also provides the application of the above EVA rubber-plastic composition as a foamed product, comprising the following steps: Step 1: installing a matching mold for processing the product; Step 2: putting the rubber-plastic composition into the injection machine; The setting temperature of the injection machine is 177~183 QC, and the curing time is 220 seconds 〇~240 seconds. Step 4: Set the temperature of the injection gun to 82, 83, 85, 87 QC, corresponding to the smashing pressure and The minimum injection speeds are: 6〇f3ar, 2mm/s; 65bar, 2.66 coffee/s; 70bar, 2.83 coffee/s; 75bar, 3mm/s; or 80 bar, 3.17mm/s; Step V. Use the wind to grab the mold clean and spray the Dong mold water; Step 6. After blowing the mold to remove the mold water, fill the required amount of material, and close the mold; Step 7. Quickly remove the finished product after opening the mold. Set on the hoe to completely cool. In the present invention, a reasonable proportion of a foaming agent, an active agent, a lubricant, an EVA modifier and a flow agent makes a sun visor, a cool hat, a mobile phone case and the like which are made using the EVA rubber composition of the present invention. Soft, lightweight and non-toxic, environmentally friendly and low cost. [Embodiment] Hereinafter, the present invention will be described in detail in conjunction with specific embodiments. The invention comprises the following components by weight: EVA base 60~75KG; standard glue 2~4KG; 201024360 filler 1.5~2.5KG; foaming agent 1.1~2.0KG; bridging agent 0·6~0·8KG; Agent 0·4~0·6KG; active agent 1.2~1.4KG; lubricant 0.9~1.3KG; flow agent 0.8~1.2KG; EVA modifier 0.4~0.6KG; pigment 0·8~3·0KG. The EVA base material is a mixture of EVA ethylene-vinyl acetate copolymer and a thermoplastic elastomer, wherein the weight percentage of the EVA ethylene-vinyl acetate copolymer in the mixture of the EVA ethylene-vinyl acetate copolymer and the thermoplastic elastomer is 46~ 54%.填充 ❹ the filler is talc, the foaming agent is an AC foaming agent, the standard glue is 3L standard glue, the active agent is zinc oxide, the bridging agent is odorless pep, and the bridging aid The agent is triallyl isocyanurate, model PC18; the flow agent is a high molecular weight fatty acid ester, such as a malonate fatty acid ester or a polyethylene glycol fatty acid ester, model L709; the EVA The modifier is a microparticulate active agent, model K133. The lubricant is a mixture of stearic acid and zinc stearate, and the weight percentage of stearic acid in the mixture is 33 to 38.5%. The pigment comprises a plurality of color masterbatch or a combination of a plurality of color masterbatch and titanium dioxide to impart a different color to the composition. The following description will be made in conjunction with specific embodiments. Example 1: 201024360 The present invention comprises the following components by weight: EVA ethylene-vinyl acetate copolymer 35KG; 7467 thermoplastic elastomer 20KG; 735 thermoplastic elastomer 12. 5KG; 3L standard glue 3KG; RB510 talc powder 2KG; AC6000H hair Foaming agent 1.1KG; 〇 odorless DCP bridging agent 0.7KG; zinc oxide 1. 26KG; triallyl isocyanurate 0 · 5KG; stearic acid 0 · 4KG; stearic acid 0. 68KG; L709 flow agent 1KG; K133EVA modifier 0.5KG; enamel 1503 0.54KG; masterbatch 1372 0.063KG; masterbatch 3513 0.025KG; masterbatch 1509 0.19KG. The rubber composition of this embodiment is red in color. Example 2: The present invention comprises the following components by weight: EVA ethylene-vinyl acetate copolymer 30KG; 201024360 7467 thermoplastic elastomer 20KG; 735 thermoplastic elastomer 10KG; 3L standard rubber 2KG; RB510 talc powder 1.5KG; AC6000H foaming Agent 1.1KG; odorless DCP bridging agent 0.6KG; zinc oxide 1.2KG; φ triallyl isophthalic acid ester 0. 4KG; stearic acid 0. 3KG; zinc stearate 0. 6KG; L709 flow agent 0.8KG ; K133EVA modifier 0.4KG; titanium dioxide R109 0.8KG; yellow mother 3513 0.44KG; 10 yellow mother 3515 1.58KG. The rubber composition of this embodiment is yellow in color. Example 3: The present invention comprises the following components by weight: EVA ethylene-acetic acid ethylene copolymer 40KG; 7467 thermoplastic elastomer 25KG; 735 thermoplastic elastomer 10KG; 3L standard rubber 4KG; 201024360 RB510 talc powder 2.5KG; AC6000H hair Foaming agent 2.0KG; odorless DCP bridging agent 0.8KG; zinc oxide 1.3KG; triallyl isoflurane 0.6KG; stearic acid 0.5KG; zinc stearate 0.8KG;

L709 流動劑 1.2KG; K133EVA 改質劑 0.6KG;L709 flow agent 1.2KG; K133EVA modifier 0.6KG;

鈦白粉R109 1KG 紫色母 7504 0. 79KG ; 紅色母 1509 0.017KG; 藍色母 5504 0.023KG ; 黑色母 8504 0.023KG。 本實施例的橡塑組合物顏色為紫色。 實施例四: 本發明包括以下重量百分比的組分: EVA7350乙烯-醋酸乙烯共聚物 32KG ; 7467熱塑性彈性體 22KG ; 735熱塑性彈性體 15KG ; 3L 標膠 3. 5KG ; RB510 滑石粉 2.0KG; 201024360Titanium dioxide R109 1KG purple mother 7504 0. 79KG; red mother 1509 0.017KG; blue mother 5504 0.023KG; black mother 8504 0.023KG. The rubber composition of this embodiment is purple in color. Example 4: The present invention comprises the following components by weight: EVA7350 ethylene-vinyl acetate copolymer 32KG; 7467 thermoplastic elastomer 22KG; 735 thermoplastic elastomer 15KG; 3L standard rubber 3. 5KG; RB510 talc 2.0KG; 201024360

AC6000H發泡劑 1. 5KG; 無味DCP架橋劑 0· 7KG ; 氧化鋅 1.3KG; 三烯丙基異H腺酸酯 0· 5KG ; 硬脂酸 0.4KG ; 硬脂酸鋅 0. 7KG ; L709流動劑 1.1KG ; K133EVA改質劑 0. 5KG ; 鈦白粉R103 0.5KG ; 藍色母5505 0· 8KG ; 紅色母1375 0.81KG ; 黃色母5513 0.144KG 本實施例的橡塑組合物顏色為白色。 本發明還提供了該橡合物的製備方法,包括以下步 ®驟: 步驟一:按以下重量準備原料组分:EVA基料,6〇〜75KG;標 膠,2〜4KG ;填充劑,1.5〜2.5KG ;發泡刺,1· 1〜2· 〇KG ;架橋 劑,〇· 6〜0· 8KG ;架橋助劑,0· 4〜〇· 6KG ;活性劑,1. 2〜1.4KG ; 潤滑劑,〇· 9〜1.3KG ;流動舞],〇· g〜L 2KG ; EVA改質劑,〇. 4〜 〇· 6KG ;色母,0.8〜3· 0KG ; 步驟二:密煉作業;AC6000H foaming agent 1. 5KG; odorless DCP bridging agent 0 · 7KG; zinc oxide 1.3KG; triallyl iso-H agglomerate 0 · 5KG; stearic acid 0.4KG; zinc stearate 0. 7KG; Agent 1.1KG; K133EVA modifier 0. 5KG; Titanium dioxide R103 0.5KG; Blue mother 5505 0·8KG; Red mother 1375 0.81KG; Yellow mother 5513 0.144KG The rubber composition of this embodiment is white. The invention also provides a preparation method of the rubber, comprising the following steps: Step 1: Prepare the raw material components according to the following weight: EVA base material, 6〇~75KG; standard glue, 2~4KG; filler, 1.5 ~2.5KG; foaming thorn, 1·1~2· 〇KG; bridging agent, 〇·6~0·8KG; bridging aid, 0·4~〇·6KG; active agent, 1. 2~1.4KG; Lubricant, 〇·9~1.3KG; mobile dance], 〇·g~L 2KG; EVA modifier, 〇. 4~ 〇·6KG; color masterbatch, 0.8~3·0KG; Step 2: Mixing operation;

A、開啟密煉主機,設定溫度為77〜83QC,如78 QC、80 QC 201024360 或82 2C,倒入EVA基料,標膠,填充劑,架橋助劑,活性劑潤 滑劑’流動劑,EVA改質劑,色母,壓下壓力錘; B、 密煉溫度調整為95〜100eC,如95 QC、98 %或1〇〇 〇c , 翻料、清掃粉塵,保持時間7分鐘; C、 密煉溫度調整為1〇5〜110QC,如105 1〇8 qC或11〇 %, 翻料、清掃粉塵,倒入發泡劑和架橋劑,保持時間1〇分鐘· D、 密煉溫度調整為115aC,翻料、清掃粉塵,保持時間u分 〇 鐘; E、 密煉溫度調整為118〜1202C,保持時間12分鐘,之後, 將密煉主機之内的物料倒出; 步驟三:開煉作業; A、 開啟開煉主機,設定溫度為65〜70QC,如65 QC、68 eC 或 70 aC ; B、 調整滾輪間隙為2〜3mm,如2咖、2.5mm或3咖,將步 ❹驟二中所得的物料打薄兩次; C、 割下物料; 步驟四:造粒作業; A、開啟造粒機’料管溫度設定為75〜85qc,如75 Qc、8〇 ec 或85 QC ’模頭溫度設定為85〜95QC,如85 SC、90 QC或95 aC ; β、將步驟三中割下的物料投入造粒機; C、切刀轉速設定為2〇〜25ΗΖ,控制造粒長度為2〜3_。 本發明還提供了上述EVA橡塑組合物用作發泡製品的應用,包 12 201024360 括以下步驟: 步驟一:安裝欲加工製品的配套模具; 步称二:將橡塑組合物顆粒投入全自動舰射出機,型號為 SC-906L2 〇 步驟三:射出機設定溫度為Π7〜183 aC,硫化時間為220秒 〜240秒,如射出機溫度為178 qC、18〇吒或182吒,硫化時間 分別為240秒、230秒或220秒; ® 步驟四:設定射出機射搶溫度為82、83、85、87 QC中的一種, 設疋射搶壓力和最低射出速度分別為:6〇bar、2mm/s ; 65bar、 2. 66mm/s; 70bar、2· 83 咖/s; 75bar、3咖/s;或 80 bar、3· 17咖/s ; 例如’射出機射搶溫度為82 SC射搶壓力為60bar,最低射出速度 為2咖/s ; 步驟五、用風搶將模具内清理乾淨,喷適量脫模水; 步驟六、用風搶吹幹模具内脫模水後,注入所需料董,合模; ® 步驟七、開模後迅速取出成品,套在楦頭上至完全冷卻。 本發明通過組合物中發泡劑、活性劑、潤滑劑和流動劑的合 理配比’使得使用該EVA橡塑組合物製成的遮陽帽、涼帽、手機 套等製品,柔軟、輕便而且無毒、環保,成本低。 本發明不局限於上述最佳實施方式,任何人應該得知在本發 明的啟示下作出的結構變化,凡是與本發明具有相同或相近的技 術方案’均落入本發明的保護範圍之内。 【圖式簡單說明】 13 201024360 無 【主要元件符號說明】 無A, open the mixing host, set the temperature to 77~83QC, such as 78 QC, 80 QC 201024360 or 82 2C, pour EVA base material, standard glue, filler, bridging aid, active agent lubricant 'flow agent, EVA Modifier, color masterbatch, press down the pressure hammer; B, the mixing temperature is adjusted to 95~100eC, such as 95 QC, 98% or 1〇〇〇c, turning and cleaning the dust, keeping the time for 7 minutes; C, dense The refining temperature is adjusted to 1〇5~110QC, such as 105 1〇8 qC or 11〇%, turn the material, sweep the dust, pour the foaming agent and bridging agent, keep the time for 1 ··D, and adjust the mixing temperature to 115aC. , turn the material, clean the dust, keep the time u minutes ;; E, the mixing temperature is adjusted to 118~1202C, hold the time for 12 minutes, after which, the material inside the mixing host is poured out; Step 3: Open the operation; A. Open the main engine, set the temperature to 65~70QC, such as 65 QC, 68 eC or 70 aC; B, adjust the roller gap to 2~3mm, such as 2 coffee, 2.5mm or 3 coffee, will be in step 2 The obtained material is thinned twice; C. Cut the material; Step 4: Granulation operation; A. Turn on the granulator's tube temperature setting 75~85qc, such as 75 Qc, 8〇ec or 85 QC 'The die temperature is set to 85~95QC, such as 85 SC, 90 QC or 95 aC; β, the material cut in step 3 is put into the granulator; C The cutter speed is set to 2〇~25ΗΖ, and the granulation length is controlled to 2~3_. The invention also provides the application of the above EVA rubber and plastic composition as a foamed product, and the package 12 201024360 comprises the following steps: Step 1: installing a matching mold for the product to be processed; Step 2: putting the rubber and plastic composition particles into automatic Ship injection machine, model SC-906L2 〇Step 3: The set temperature of the injection machine is Π7~183 aC, the vulcanization time is 220 seconds~240 seconds, if the injection machine temperature is 178 qC, 18〇吒 or 182吒, the vulcanization time respectively 240 seconds, 230 seconds or 220 seconds; ® Step 4: Set the shooting temperature of the injection machine to one of 82, 83, 85, 87 QC, set the smashing pressure and the minimum injection speed: 6 〇 bar, 2 mm /s ; 65bar, 2. 66mm / s; 70bar, 2. 83 coffee / s; 75bar, 3 coffee / s; or 80 bar, 3 · 17 coffee / s; for example, 'shooting machine shooting temperature is 82 SC shot The pressure is 60 bar, the minimum injection speed is 2 coffee / s; Step 5, use the wind to grab the mold clean, spray the appropriate amount of mold release water; Step six, use the wind to blow dry mold mold release water, inject the required materials Dong, mold clamping; ® Step 7. After the mold is opened, the finished product is quickly taken out and placed on the steamed bread to completely cool. The invention makes the sun visor, the cool hat, the mobile phone sleeve and the like made by using the EVA rubber composition by the reasonable ratio of the foaming agent, the active agent, the lubricant and the flow agent in the composition, and is soft, light and non-toxic. Environmentally friendly and low cost. The present invention is not limited to the above-described preferred embodiments, and it should be understood that any structural changes made by the present invention, which are the same or similar to the present invention, are within the scope of the present invention. [Simple description of the diagram] 13 201024360 None [Main component symbol description] None

Claims (1)

201024360 七、申請專利範圍: 1、種EVA橡塑組合物,其特徵在於包括以下重董的組分: EVA 基料 60〜75KG ; 標膠 2 〜4KG ; 填充劑 1.5〜2.5KG; 發泡劑 1.1〜2.0KG; 架橋劑 0· 6〜0· 8KG ; 架橋助劑 0· 4〜0· 6KG ; 活性劑 1.2〜1.4KG; 潤滑劑 0.9〜1.3KG; 流動劑 0.8〜1.2KG ; EVA改質劑 0· 4〜0· 6KG ; 顏料 0.8〜3. 0KG 〇 2、如權利要求1所述的EVA橡塑組合物,其特徵在於所述eva ❹基料為EVA乙烯-醋酸乙烯共聚物與熱塑性彈性體的混合物’該混 合物中EVA乙烯-醋酸乙烯共聚物的重董百分比為46〜54%。 3、如權利要求1所述的EVA橡塑組合物,其特徵在於所述標 膠為3L標膠,所述填充劑為滑石粉,所述發泡劑為AC發泡劑, 所述活性劑為氧化鋅,所述架橋劑為無味DCP架橋劑,所述架橋 助劑為三烯丙基異氰脲酸酯,所述流動劑為脂肪酸酯,所述EVA 改質劑為超微粒活性劑,所述顏料包括兩種以上的色母或者兩種 以上的色母與鈦白粉的組合。 15 201024360 4、 如權利要求1所述的EVA橡塑組合物,其特徵在於所 滑劑為硬脂酸和硬脂酸鋅的混合物,該混合物中硬脂酸的重量百 分比為33〜38.5%。201024360 VII. Patent application scope: 1. EVA rubber and plastic composition, characterized by including the following components of heavy Dong: EVA base 60~75KG; standard glue 2~4KG; filler 1.5~2.5KG; foaming agent 1.1~2.0KG; bridging agent 0·6~0·8KG; bridging aid 0·4~0·6KG; active agent 1.2~1.4KG; lubricant 0.9~1.3KG; flow agent 0.8~1.2KG; EVA modification The agent E.g. The mixture of elastomers' percentage of the EVA ethylene-vinyl acetate copolymer in the mixture is 46 to 54%. The EVA rubber composition according to claim 1, wherein the standard glue is 3L standard glue, the filler is talc powder, the foaming agent is AC foaming agent, and the active agent is In the case of zinc oxide, the bridging agent is an odorless DCP bridging agent, the bridging aid is triallyl isocyanurate, the flow agent is a fatty acid ester, and the EVA modifier is an ultrafine active agent. The pigment includes two or more color masterbatches or a combination of two or more color masterbatch and titanium white powder. 15 201024360 4. The EVA rubber composition according to claim 1, wherein the slip agent is a mixture of stearic acid and zinc stearate, and the weight percentage of stearic acid in the mixture is from 33 to 38.5% by weight. 5、 如權利要求1所述的EVA橡塑組合物,其特徵在於包括以 下重量的組分: EVA乙烯-醋酸乙烯共聚物 35KG; 7467熱塑性彈性髋 20KG ; 735熱塑性彈性髋 12.5KG ; 3L標膠 3KG ; RB510滑石粉 2KG; AC6000H發泡劑 1· 1KG ; 無味DCP架橋劑 0· 7KG ; 三烯丙基異氟腺酸_ 0.5KG ; 氧化鋅 1.26KG ; 硬脂酸 0.4KG ; 硬脂酸鋅 0.68KG ; 高分子量脂肪酸醋 1KG ; 超微粒活性劑 0.5KG ; 色母1503 0.54KG ; 色母1372 0.063KG ; 色母3513 0.025KG ; 色母1509 0· 19KG。 201024360 ’其特徵在於包括以 6、如權利要求1所述的EVA橡塑組合物 下重董的組分: EVA乙烯-醋酸乙烯共聚物 30KG ; 7467熱塑性彈性髏 20KG ; 735熱塑性彈性體 i〇KG ; 3L標膠 2KG ; RB510 滑石粉 1.5KG; ❹ AC6000H 發泡劑 1.1KG; 無味DCP架橋劑 0. 6KG ; 氧化辞 1.2KG; 三烯丙基異氰脲酸酯 0.4KG ; 硬脂酸 0.3KG ; 硬脂酸鋅 0. 6KG ; 高分子量脂肪酸酯 0.8KG; ® 超微粒活性劑 〇. 4KG; 鈦白粉R109 〇. 8KG ; 黃色母 3513 0.44KG; 黃色母 3515 1.58KG » 其特徵在於包括以 7、如權利要求1所述的EVA橡塑組合物, 下重量的組分: EVA乙烯-醋酸乙烯共聚物 40KG ; 7467熱塑性彈性體 25孤; 17 201024360 735熱塑性彈性體 10KG ; 3L標膠 4KG ; RB510 滑石粉 2.5KG; AC6000H 發泡劑 2.0KG; 無味DCP架橋劑 0.8KG; 氧化鋅 1.3KG ; 三烯丙基異氰脲酸酯 0. 6KG ; φ 硬脂酸 0.5KG ; 硬脂酸鋅 0.8KG ; 高分子量脂肪酸酯 1.2KG; 超微粒活性劑 0.6KG; 鈦白粉R109 1KG 紫色母 7504 0. 79KG ; 紅色母 1509 0.017KG ; 〇 藍色母 5504 0.023KG; 黑色母 8504 0. 023KG 8、如權利要求1所述的EVA橡塑組合物,其特徵在於包括以 下重量的組分: 乙烯-醋酸乙烯共聚物EVA7350 32KG; 7467熱塑性彈性體 22KG; 735熱塑性彈性體 15KG ; 3L標膠 3.5KG ; 18 201024360 RB510滑石粉 2.0KG ; AC6000H發泡劑 1. 5KG; 無味DCP架橋劑 0.7KG ; 氧化鋅 1.4KG ; 三烯丙基異11腺酸酯 0· 5KG ; 硬脂酸 0.4KG ; 硬脂酸鋅 0· 7KG ; 高分子量脂肪酸酯 1.1KG ; 超微粒活性刺 0· 5KG ; 欽白粉R103 0· 5KG ; 藍色母5505 0.8KG ; 紅色母1375 0.81KG ; 黃色母5513 0.144KG« 9、-種EVA橡塑組合物的製備方法,其特徵在於包括以下步 ❿ 称: 步驟一:按以下重量準備原料組分:EVA基料,6〇〜75KG ;標 膠’ 2〜4KG ;填充劑,1.5〜2.5KG ;發泡劑,1· 1〜2· 〇KG ;架橋 劑,0. 6〜0· 8KG ;架橋助劑’ 0· 4〜〇· 6KG ;活性劑,1. 2〜1. 4KG ; 潤滑劑,0.9〜1.3KG ;流動劑,0·8〜1.2KG ; EVA改質劑,0.4〜 0· 6KG ;色母,〇. 8〜3.0KG ; 步驟二•·密煉作業; A、開啟密煉主機,設定溫度為77〜83eC,倒入EVA基料,標 19 201024360 膠,填充劑,架橋助劑,活性劑,潤滑劑,流動剤,EVA改質劑, 色母,壓下壓力錘; B、 密煉溫度調整為95〜100QC ’翻料、清掃粉塵,保持時間7 分鐘; C、 密煉溫度調整為105〜110吒,翻料、清掃粉塵,倒入發泡 劑和架橋劑,保持時間10分鐘; D、 密煉溫度調整為115QC ’翻料、清掃粉塵,储時間u分 〇 鐘; E、 密煉溫度調整為118〜120QC ’保持時間12分鐘,之後, 將密煉主機之内的物料倒出; 步驟三:開煉作業; A、 開啟開煉主機,設定溫度為65〜7〇% ; B、 調整滾輪間隙2〜3mm ,將步驟二中所得的物料打薄兩次; C、 割下物料; ❿ 步驟四:造粒作業; A、 開啟造粒機,料管溫度設定為75〜85吒,模頭溫度設定為 85〜95QC ; B、 將步驟三中割下的物料投入造粒機; C、 切刀轉速設定為2〇〜25HZ ,控制造粒長度為2〜3fflm。 10、一種如權利要求i所述的EVA橡塑組合物用作發泡製品的 應用,其特徵在於包括以下步称: 步驟一:安裝欲加工製品的配套模具; 20 201024360 步驟二:將橡塑組合物投入射出機; 步驟三:射出機設定溫度為177〜183 SC,硫化時間為22〇秒 〜240秒; 步驟四:設定射出機射搶溫度為82、83、85、87吒中的一種, 對應設定射搶壓力和最低射出速度分別為:6〇bar、2fflffl/s; 65bar、 2.66mm/s ; 70bar、2· 83 咖/s; 75bar、3min/s;或 80 bar、3· 17ram/s; 步驟五、用風槍將模具内清理乾淨,喷適董脫模水; ❿ 步驟六、用風搶吹幹模具内脫模水後,用射出機注入所需料 量,合模; 步禪七、開模後迅速取出成品,套在檀頭上至完全冷卻。 21 201024360 四、指定代表圖: (一) 本案指定代表圖為:第(無)圖。 (二) 本代表圖之元件符號簡單說明: jfe 7%%^ 五、本案若有化學式時,請揭示最能顯示發明特徵的化學式5. The EVA rubber composition according to claim 1, comprising the following components: EVA ethylene-vinyl acetate copolymer 35KG; 7467 thermoplastic elastic hip 20KG; 735 thermoplastic elastic hip 12.5KG; 3L standard adhesive 3KG; RB510 talcum powder 2KG; AC6000H foaming agent 1·1KG; odorless DCP bridging agent 0·7KG; triallyl isoflurane _ 0.5KG; zinc oxide 1.26KG; stearic acid 0.4KG; zinc stearate 0.68KG; high molecular weight fatty acid vinegar 1KG; ultrafine particle active agent 0.5KG; color masterbatch 1503 0.54KG; color masterbatch 1372 0.063KG; masterbatch 3513 0.025KG; masterbatch 1509 0 · 19KG. 201024360 'Characteristically comprising the components of the EVA rubber composition according to claim 1, comprising: EVA ethylene-vinyl acetate copolymer 30KG; 7467 thermoplastic elastomer 髅 20KG; 735 thermoplastic elastomer i〇KG 3L standard glue 2KG; RB510 talcum powder 1.5KG; ❹ AC6000H foaming agent 1.1KG; odorless DCP bridging agent 0. 6KG; oxidation word 1.2KG; triallyl isocyanurate 0.4KG; stearic acid 0.3KG Zinc stearate 0. 6KG; high molecular weight fatty acid ester 0.8KG; ® ultrafine particle active agent 〇. 4KG; titanium dioxide R109 〇. 8KG; yellow mother 3513 0.44KG; yellow mother 3515 1.58KG » 7. The EVA rubber-plastic composition according to claim 1, the lower weight component: EVA ethylene-vinyl acetate copolymer 40KG; 7467 thermoplastic elastomer 25 orphan; 17 201024360 735 thermoplastic elastomer 10KG; 3L standard rubber 4KG; RB510 talcum powder 2.5KG; AC6000H foaming agent 2.0KG; odorless DCP bridging agent 0.8KG; zinc oxide 1.3KG; triallyl isocyanurate 0. 6KG; φ stearic acid 0.5KG; zinc stearate 0.8 KG ; high molecular weight fatty acid ester 1.2KG Ultrafine particle active agent 0.6KG; titanium dioxide R109 1KG purple mother 7504 0. 79KG; red mother 1509 0.017KG; indigo mother 5504 0.023KG; black mother 8504 0. 023KG 8. EVA rubber according to claim 1. A plastic composition characterized by comprising the following components: ethylene-vinyl acetate copolymer EVA7350 32KG; 7467 thermoplastic elastomer 22KG; 735 thermoplastic elastomer 15KG; 3L standard rubber 3.5KG; 18 201024360 RB510 talc 2.0KG; AC6000H Foaming agent 1. 5KG; odorless DCP bridging agent 0.7KG; zinc oxide 1.4KG; triallyl iso 11 adenosate 0 · 5KG; stearic acid 0.4KG; zinc stearate 0 · 7KG; high molecular weight fatty acid Ester 1.1KG; ultrafine particle active thorn 0 · 5KG; white powder R103 0 · 5KG; blue mother 5505 0.8KG; red mother 1375 0.81KG; yellow mother 5513 0.144KG « 9, - EVA rubber and plastic composition preparation method It is characterized by the following steps: Step 1: Prepare the raw material components according to the following weight: EVA base material, 6〇~75KG; standard rubber '2~4KG; filler, 1.5~2.5KG; foaming agent, 1 · 1~2· 〇KG; bridging agent, 0. 6~0· 8KG; bridging aid '0·4~〇·6KG; active agent, 1. 2~1. 4KG; lubricant, 0.9~1.3KG; flow agent, 0·8~1.2KG; EVA modification Agent, 0.4~0·6KG; color masterbatch, 〇. 8~3.0KG; Step 2•·Misting operation; A. Turn on the mixing host, set the temperature to 77~83eC, pour into EVA base material, mark 19 201024360 glue , filler, bridging aid, active agent, lubricant, flowing crucible, EVA modifier, color masterbatch, pressing pressure hammer; B, mixing temperature adjustment to 95~100QC 'turning, cleaning dust, holding time 7 Minutes; C, the mixing temperature is adjusted to 105~110吒, turn the material, clean the dust, pour the foaming agent and bridging agent, keep the time for 10 minutes; D, adjust the temperature to 115QC 'turning, cleaning dust, storage Time u minutes ;; E, the mixing temperature is adjusted to 118~120QC 'holding time 12 minutes, after which, the material inside the mixing host is poured out; Step 3: Open the operation; A, open the open host, set The temperature is 65~7〇%; B, adjust the roller gap 2~3mm, and thin the material obtained in step 2 twice; C. Cut the material; ❿ Step 4: Granulation operation; A. Turn on the granulator, set the temperature of the tube to 75~85吒, and set the temperature of the die to 85~95QC. B. Put the material cut in step 3 into the production. Granulator; C, cutter speed is set to 2 〇 ~ 25HZ, control granulation length is 2 ~ 3fflm. 10. The use of the EVA rubber composition according to claim i as a foamed article, comprising the following steps: Step 1: installing a matching mold for the product to be processed; 20 201024360 Step 2: rubber and plastic The composition is put into the injection machine; Step 3: The setting temperature of the injection machine is 177~183 SC, and the vulcanization time is 22 〇 to 240 seconds; Step 4: setting the shooting temperature of the injection machine to be one of 82, 83, 85, 87 吒Corresponding set shooting pressure and minimum injection speed are: 6〇bar, 2fflffl/s; 65bar, 2.66mm/s; 70bar, 2·83 coffee/s; 75bar, 3min/s; or 80 bar, 3·17ram / s; Step 5, clean the mold with a wind gun, spray Dong Dong mold water; ❿ Step six, use the wind to blow dry mold release water, use the injection machine to fill the required amount, mold; Step by step, after the mold is opened, the finished product is quickly taken out and placed on the sandal head to completely cool. 21 201024360 IV. Designation of representative drawings: (1) The representative representative of the case is: (No). (2) A brief description of the symbol of the representative figure: jfe 7%%^ 5. If there is a chemical formula in this case, please reveal the chemical formula that best shows the characteristics of the invention.
TW97151180A 2008-12-26 2008-12-26 EVA plastic compound, preparation method and application for foaming products TW201024360A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI595993B (en) * 2016-09-20 2017-08-21 Simple Green Co Ltd Continuous mixed lottery elastic mat manufacturing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI595993B (en) * 2016-09-20 2017-08-21 Simple Green Co Ltd Continuous mixed lottery elastic mat manufacturing method

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