TW201017353A - Low emission and energy saving apparatus for performance testing of fuel cells - Google Patents

Low emission and energy saving apparatus for performance testing of fuel cells Download PDF

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Publication number
TW201017353A
TW201017353A TW097141809A TW97141809A TW201017353A TW 201017353 A TW201017353 A TW 201017353A TW 097141809 A TW097141809 A TW 097141809A TW 97141809 A TW97141809 A TW 97141809A TW 201017353 A TW201017353 A TW 201017353A
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gas
fuel cell
unit
low
control unit
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TW097141809A
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Chinese (zh)
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TWI372953B (en
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Yu-Ching Tsai
Wen-Tang Hong
Hung-Yu Wang
Wei-Ping Huang
Ruey-Yi Lee
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Atomic Energy Council
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

A low emission and energy saving apparatus for fuel cell performance testing is disclosed, which comprises: a system control unit, a temperature control unit, a gas/water supply unit, a heat recycle unit, a gas preheating and reforming unit, a furnace and compressible force loading unit, a fuel cell stack, an electrical loading and performance measurement unit, a gas/pressure analysis unit, a gas cooling and water recycle system, a security monitoring unit and a human machine interface. This apparatus can be used for Fuel Cells' testing, especially for Solid Oxide Fuel Cells. Low emission and energy saving can be achieved during Fuel Cells' performance testing.

Description

201017353 九、發明說明: 【發明所屬之技術領域】 本發明係有關於一種低污染節能型燃料電池堆測 試裝置,尤指一種可提供燃料電池於測試時所需之溫度 及氣/液流等運轉條件,並可進行電池堆性能等各種分 析與測試’以及可降低大量電能消耗與污染排放之低污 染節能型燃料電池堆測試裝置。 【先前技術】 ❹ 按,燃料電池因具備低污染及高能源轉換效 率之特性’成為近年來極受矚目之能源供應技術 ,其依電解質種類不同,可區分為質子薄膜燃料 • 電池(PEMFC )、鹼性燃料電池(AFC )、磷酸燃 料電池(PAFC )、熔融碳酸鹽燃料電池(MCFC ) 及固態氧化物燃料電池(S0FC )等。以溫度分類 而言’該質子薄膜燃料電池、該鹼性燃料電池及 該磷酸燃料電池係屬於低溫型,該熔融碳酸鹽燃 ❹ 料電池係屬於中溫型,而該固態氧化物燃料電池 則係屬於高溫型,另外,亦有直接曱醇燃料電池 (DMFC)及金屬-空氣混合型電池等。其中,該固 態氧化物燃料電池由於具有高能量效率與循環系 統能利用未反應之燃料及高溫廢熱等特性,因此 成為眾多燃料電池中研究發展之重要對象。 關於該固態氧化物燃料電池之操作原理:燃 料與氧化劑(空氣或氧氣)在進入該固態氧化物 5 201017353 燃料電池陰極與陽極之前,必須先被預熱至接近 該固態氧化物燃料電池其電池堆之操作溫度( 6 0 0〜1 0 0 0 ° C ),而燃料之選用,除了一般燃料電 池常用之氫氣之外,亦可使用重組器,將碳氫燃 料轉換為富含氫氣之氣體後再提供該固態氧化物 燃料電池使用。 與一般低溫型燃料電池發電原理不同的是, 該固態氧化物燃料電池除了需操作在6 0 0〜 ⑩ 1 0 0 0 ° C之高溫外,該固態氧化物燃料電池内部之 電化學反應機制係藉由在一電池片(M e m b r a n e Electrolyte Assembly,MEA)之陰極側形成氧離 子,並且透過固態電解質層声移至陽極側與氫氣 、一氧化碳或碳氫燃料進行反應,而其反應產物 為電子、水與熱能。由於該固態氧化物燃料電池 在南溫下運作’因此無論其陽極產物或陰極產物 ’其排出電池堆之溫度與電池堆操作溫度相近。 φ 而此高品質之熱能係可以利用熱交換器進行回收 ’以作為預熱電池堆陰陽極入口氣體之熱源。在 燃料電池之操作中,無論係低溫型或高溫型,在 考慮電化學反應中之濃度極化效應之下,進入電 池堆中之燃料並不會被1 0 〇%的利用。其燃料利用 率在固態氧化物燃料電池中常見均為60%〜85%。 因此在電池堆之出口,相對會有15〜40%不等之辦 料未經過電化學反應消耗。而針對 置’常見之方法為設置-燃燒器將其燃燒= 6 201017353 釋放之熱能則藉由熱交換器進行回收,以 統預熱之能量來源。 由於固態氧化物燃料電池相較於低溫 料電池,係具有燃料選擇性高、效率高以 熱電共生系統彈性大之優點。因此近年來 研究有逐步升高之趨勢。在固態氧化物燃 之研發過程中,電池堆之測試係必然之程 般而言’電池堆之測試係藉由電池堆之測 參 進行。就低溫型燃料電池測試站而言,典 中華民國專利公報公告第Μ 5 7 2 4 6 2號所述 含有氣體供應部、電池堆負載控制部、系 部以及人機監控介面所組成:。然而,早在 利出現之前,相關之燃料電池測試設施已 ’因此該專利所描述之系統架構為低溫型 池測試領域早已採用多時之基本架構。m 唯’上述專利相對之組成係無法直接 φ 高溫型燃料電池堆以及高溫型燃料電池堆 件之測試使用。故,一般習用者係無法 者於實際使用時之所需。 / 【發明内容】 本發明之主要目的係在於,克服習知 =遇之上述問題並提供一種可針對燃料 灯手動或自動化測試,以及於測試過裎中 作為系 型之燃 及合併 其相關 料電池 序。一 試站來 型者如 ’係包 統控制 該篇專 然出現 燃料電 應用於 衍生組 合使用 技藝所 池堆進 可大量 7 201017353 消耗及污染排放之低污染節能 池堆測試裝置。 「寸電 本發明之次要目的係在於,可提供燃料 於測試時所需之溫度及氣/液流等運轉條件,间〉也 亦可進行電池堆性能等各種分析與測試。 時 鲁 鲁 本發明之另一目的係在於,藉由本發明各 輔助次糸統,係可確保長時程測試工作之穩〜固 與女全性’且在加入餘熱回收部後,⑤電池:’生 試過程中係可大量減少電能消耗與污染排放,:i 此在大幅降低電池堆測試站之功率消耗之同口 亦可兼顧環保考量與降低研發測試之成本。 切μ ί達以上之目的,本發明係一種低污染節能 =燃料電池堆測試裝置,其至少係由一系統控 ^ 一與该系統控制部連通之溫度控制部、一與 5亥系統控制部連通之氣/液體供應部、一與該系統 控制部及該氣/液體供應部連通之餘熱回收部、一 f該溫度控制部、該氣/液體供應部及該餘熱回收 ,連通之^體預熱與重組單元、一與該溫度控制 部連通之高溫爐與壓縮負載部、一配置於該高溫 爐與壓縮負栽部内’且與該餘熱回收部及該氣體 預熱與重組單元連通之燃料電池、一與該系統控 =4及j燃料電池連通之負載控制暨特性量測 J 一與^系統控制部、該氣/液體供應部、該餘 ‘、’、回收α卩遠氣體預熱與重組單元及該燃料電池 連通之乱體成分/壓力分析部、一與該氣/液體供 8 201017353 應部及該氣體成分/壓力分析部連通之排氣冷卻 =水,回收部、一與該系統控制部連通之安全性 監控部以及—與該系統控制部連通之人機監控介 、構成。可測試尚溫型燃料電池之固態氧化物 ·’’’:,,池之性能,並且可大幅降低傳統測試裝置 之^率4耗與污染排放。此外,本測試裝置之餘 二回收。卩係具有三種配置型態,其第一種配置型 匕為同日守配置該餘熱回收部之前置熱交換器、後 Φ 置$交換器及燃燒器,並且針對該燃燒器之高溫 排氣進行熱能回收;第二種配置型態為同時配置 °亥餘熱回收部之後置熱交換器及燃燒器,唯該燃 燒器之高溫排氣並不作熱能回收;以及第三種配 置型態為僅配置該餘熱回收部之後置熱交換器, 此為最簡易與經濟型之配置。 【實施方式】 請參閱『第1圖〜第5圖』所示,係分別為 ❹ ^發明之基本架構方塊示意圖、本發明第一較佳 實施例之第一氣/液流環路配置型態示意圊、本發 0月第一較佳實施例之第二氣/液流環路配置型態 思圖、本發明第一較佳實施例之第三氣/液流壞 路配置型態示意圖及本發明第二較佳實施例之第 一氣/液流環路配置型態示意圖。如圖所示:本發 明係一種低污染節能型燃料電池堆測試裝置,其 至少係由一系統控制部1 〇、一溫度控制部1 1 9 201017353 、一氣/液體供應部1 2、一可選擇配置與否與配 置型態之餘熱回收部1 3、一氣體預熱與重組單 元1 4、一高溫爐與壓縮負載部1 5、一燃料電· 池1 6、一負載控制暨特性量測部1 7、一氣體 成分/壓力分析部1 8、一排氣冷卻與水源回收部 1 9、一安全性監控部2 〇以及一人機監控介面 2 1所構成。可測試高溫型燃料電池之固態氧化 物燃料電池(S0FC )之性能,並且可大幅降低傳 ❹統測試裝置之功率消耗與污染排放。 上述所提之系統控制部1 〇係具有一可程式 邏輯控制器(Programmable Logic Controller, PLC )或係具微處理器之控制器、一訊號擷取系統 、一工業級電腦及一訊號與電力線,用以監控系 統之所有狀態,其中’該可程式邏輯控制器(或 具微處理器之控制器)係作為該溫度控制部1 1 、該氣/液體供應部1 2、該餘熱回收部1 3、該 瘳 負載控制暨特性量測部1 7、該氣體成分/壓力分 析部1 8、該安全性監控部2 〇以及該人機監控 介面2 1等次元件之控制中樞。 該溫度控制部1 1係與該系統控制部1 〇連 通,其至少包含有一溫度感測器及一溫度控制器 ’且該溫度感測器係可用以量測本測試襄置區域 溫度,並可為熱電耦;該溫度控制器係為比例積 分控制器(PID Control ler ),可用以控制該氣 體預熱與重組早元1 4及該南溫爐與壓縮負載部201017353 IX. Description of the Invention: [Technical Field] The present invention relates to a low-pollution energy-saving fuel cell stack testing device, and more particularly to a temperature and gas/liquid flow required for a fuel cell to be tested. Conditions, and can carry out various analysis and testing of battery stack performance, and a low-pollution energy-saving fuel cell stack test device that can reduce a large amount of power consumption and pollution emissions. [Prior Art] ❹ According to the fact that fuel cells have low pollution and high energy conversion efficiency, they have become the most popular energy supply technology in recent years. They can be classified into proton thin film fuels and batteries (PEMFC) depending on the type of electrolyte. Alkaline fuel cell (AFC), phosphoric acid fuel cell (PAFC), molten carbonate fuel cell (MCFC), and solid oxide fuel cell (S0FC). In terms of temperature classification, the proton thin film fuel cell, the alkaline fuel cell and the phosphoric acid fuel cell are of a low temperature type, and the molten carbonate fuel cell is a medium temperature type, and the solid oxide fuel cell is It is a high-temperature type, and there are also direct sterol fuel cells (DMFC) and metal-air hybrid batteries. Among them, the solid oxide fuel cell has become an important target for research and development of many fuel cells because of its high energy efficiency and the ability of the recycling system to utilize unreacted fuel and high-temperature waste heat. Regarding the operating principle of the solid oxide fuel cell: the fuel and the oxidant (air or oxygen) must be preheated to the cell of the solid oxide fuel cell before entering the solid oxide 5 201017353 fuel cell cathode and anode. The operating temperature (600 to 1 0 0 ° C), and the choice of fuel, in addition to the hydrogen commonly used in fuel cells, can also use a recombiner to convert hydrocarbon fuel into a hydrogen-rich gas. The solid oxide fuel cell is provided for use. Different from the general low-temperature fuel cell power generation principle, the solid oxide fuel cell has an electrochemical reaction mechanism inside the solid oxide fuel cell except that it needs to operate at a high temperature of 60 to 10 1 0 ° C. Oxygen ions are formed on the cathode side of a semiconductor wafer (MEA), and the solid electrolyte layer is acoustically moved to the anode side to react with hydrogen, carbon monoxide or hydrocarbon fuel, and the reaction product is electrons and water. With heat. Since the solid oxide fuel cell operates at south temperature, the temperature of the discharged stack regardless of its anode product or cathode product is similar to the stack operating temperature. φ This high-quality thermal energy can be recovered by means of a heat exchanger as a heat source for preheating the anode and cathode inlet gases of the stack. In the operation of a fuel cell, whether it is a low temperature type or a high temperature type, the fuel entering the battery stack is not utilized by 10% by weight in consideration of the concentration polarization effect in the electrochemical reaction. Its fuel utilization rate is generally 60% to 85% in solid oxide fuel cells. Therefore, at the outlet of the stack, relatively 15 to 40% of the materials are not consumed by the electrochemical reaction. For the common method, set-burner burns it = 6 201017353 The heat released is recovered by the heat exchanger to preheat the energy source. Since the solid oxide fuel cell is superior to the low temperature battery, it has the advantages of high fuel selectivity and high efficiency to make the thermoelectric symbiosis system more flexible. Therefore, research has gradually increased in recent years. In the development of solid oxides, the test of the stack is inevitable. The test of the stack is carried out by the measurement of the stack. For the low-temperature fuel cell test station, the code of the Republic of China Patent Gazette No. 5 7 2 4 6 2 contains a gas supply unit, a stack load control unit, a system, and a human-machine monitoring interface: However, prior to the advent of profitability, related fuel cell testing facilities have been used. Therefore, the system architecture described in this patent is a basic architecture that has been used for a long time in the field of cryogenic pool testing. m Only the relative composition of the above patents cannot be directly tested for φ high temperature fuel cell stacks and high temperature fuel cell stacks. Therefore, the average user is not able to use it in actual use. SUMMARY OF THE INVENTION The main object of the present invention is to overcome the above problems and to provide a fuel cell for manual or automated testing of fuel lamps, as well as for burning and merging related materials in a test raft. sequence. A test station is like a 'package control'. This article is dedicated to the use of fuel and electricity. It is used in a combination of technology and technology. The pool can be piled up in a large number of 7 201017353 low-pollution energy-saving pool reactor test equipment for consumption and pollution. The second objective of the present invention is to provide fuels for the temperature and gas/liquid flow required for testing, and to perform various analyses and tests such as battery stack performance. Another object of the invention is to ensure the stability and long-term testing of the long-term test work by the auxiliary sub-systems of the present invention, and after adding the waste heat recovery unit, the battery is: It can greatly reduce the power consumption and pollution emissions: i This can greatly reduce the power consumption of the battery test station and also consider the environmental considerations and reduce the cost of R&D testing. The invention is a kind of purpose. Low pollution energy saving=fuel cell stack testing device, which is controlled by at least one system, a temperature control unit connected to the system control unit, a gas/liquid supply unit connected to the 5H system control unit, and a system control And a heat recovery unit connected to the gas/liquid supply unit, a temperature control unit, the gas/liquid supply unit, and the waste heat recovery unit, the body preheating and recombining unit, and the temperature a high temperature furnace connected to the system and a compression load portion, a fuel cell disposed in the high temperature furnace and the compression load portion, and connected to the waste heat recovery portion and the gas preheating and recombining unit, and the system control = 4 and j fuel cell communication load control and characteristic measurement J1 and ^ system control unit, the gas/liquid supply unit, the remainder ', ', recovery α卩 far gas preheating and recombination unit and the fuel cell connected to the disorder a component/pressure analysis unit, an exhaust gas cooling unit connected to the gas/liquid supply unit 8 201017353 and the gas component/pressure analysis unit, a water recovery unit, a safety monitoring unit connected to the system control unit, and It is a human-machine monitoring interface that is connected to the control unit of the system. It can test the solid oxide of the fuel cell of the temperature-type fuel cell, and the performance of the pool can greatly reduce the rate and pollution of the traditional test device. In addition, the rest of the test device is recycled. The lanthanide system has three configuration types, and the first configuration type is configured to configure the heat recovery unit front heat exchanger, the rear Φ unit, and the fuel. And recovering the heat energy for the high-temperature exhaust gas of the burner; the second configuration type is to simultaneously arrange the heat exchanger and the burner after the heat recovery unit, but the high-temperature exhaust of the burner is not used for heat recovery And the third configuration type is to arrange only the heat recovery unit after the heat exchanger, which is the simplest and most economical configuration. [Embodiment] Please refer to "1st to 5th" The schematic diagram of the basic architecture of the invention, the first gas/liquid flow loop configuration of the first preferred embodiment of the present invention, and the second gas/liquid of the first preferred embodiment of the present invention. The flow loop configuration configuration diagram, the third gas/liquid flow bad road configuration configuration diagram of the first preferred embodiment of the present invention, and the first gas/liquid flow loop configuration type of the second preferred embodiment of the present invention The present invention is a low-pollution energy-saving fuel cell stack testing device, which is at least composed of a system control unit 1 , a temperature control unit 1 1 9 201017353 , and a gas/liquid supply unit 2 . Optional configuration and configuration The heat recovery unit 13 , a gas preheating and recombining unit 14 , a high temperature furnace and a compression load unit 15 , a fuel electric battery 16 , a load control and characteristic measuring unit 17 , a gas component The pressure analysis unit 18 includes an exhaust gas cooling and water source recovery unit 19, a safety monitoring unit 2, and a human machine monitoring interface 21. It can test the performance of solid oxide fuel cell (S0FC) for high temperature fuel cells and significantly reduce the power consumption and pollution emissions of the transmission test equipment. The system control unit 1 mentioned above has a programmable logic controller (PLC) or a controller of a microprocessor, a signal acquisition system, an industrial grade computer, and a signal and power line. Used to monitor all states of the system, wherein 'the programmable logic controller (or controller with microprocessor) is used as the temperature control unit 1 1 , the gas/liquid supply unit 2 2, and the waste heat recovery unit 13 The load control and characteristic measuring unit 17 , the gas component/pressure analysis unit 18 , the safety monitoring unit 2 , and the control center of the secondary component such as the human-machine monitoring interface 2 1 . The temperature control unit 1 1 is in communication with the system control unit 1 , and includes at least a temperature sensor and a temperature controller, and the temperature sensor can be used to measure the temperature of the test device region, and It is a thermocouple; the temperature controller is a proportional integral controller (PID Controller), which can be used to control the gas preheating and recombination early element 14 and the south temperature furnace and the compression load section.

201017353 1 5中高溫爐之電熱輸出功率,以符合 之升溫速率與溫度。 該氣/液體供應部1 2係與該系統 0連通,其至少包含有複數個流量控制 、一氣體加濕器1 2 2及複數條岐管1 可進一步包含複數個鼓風機12 4 (如 示)。該氣/液體供應部1 2係用以輸入 、氧化劑及水之氣/液體,並由該些流量 2 1及該些鼓風機1 2 4控制在該燃料 、該重組器1 4 2及該燃燒器1 3 1中戶 液體流量,其中,該鼓風機1 2 4係可 源之第二選項,並且亦可應用於第3圖 之配置架構,以去除本測試裝置對於空 之需求。 該餘熱回收部1 3係具有三種配置 第一至第三種配置型態皆與該系統控制 該氣/液體供應部1 ‘2連通,係用以對言 供應部1 2輸入之氣/液體進行第一階 。其中,該第一種配置型態如第2圖所 少包含有一燃燒器1 3 1 、一前置熱交 2及一後置熱交換器1 3 3 ,且該燃燒 所排放之高溫氣體將導入該後置熱交換 進行餘熱回收;該第二種配置型態如第 ,係至少包含有該燃燒器1 3 1及該後 器1 3 3 ,與上述第一種配置型態相較 測試所需 控制部1 器1 2 1 2 3,並 第5圖所 作為燃料 控制器1 電池1 6 斤需之氣/ 作為空氣 與第4圖 氣壓縮機 型態,其 部1 0及 兹氣/液體 段之升溫 示,係、至 換器1 3 器1 3 1 器1 3 3 3圖所示 置熱交換 ,係省略 201017353 該前置熱交換器元件’且其燃燒器1 3 1排放之 高溫廢氣,僅直接排放至大氣環境中而不進行餘 熱之回收;以及該第三種配置型態如第4圖所示· ’與上述第一種配置型態相較,僅保留該後置熱 父換器1 3 3 ,此為最簡易产經濟型之配置型態 。於其中,上述第一、二種配置型態中之燃燒器 1 3 1 ’係可為多孔性介質燃燒器或觸媒式燃燒 器。 .......201017353 1 5 The electric heating output power of the medium and high temperature furnace to meet the heating rate and temperature. The gas/liquid supply unit 12 is in communication with the system 0, and includes at least a plurality of flow control, a gas humidifier 1 2 2 and a plurality of manifolds 1 further comprising a plurality of blowers 12 4 (shown) . The gas/liquid supply unit 12 is used for inputting, oxidizing agent and water gas/liquid, and is controlled by the flow rate 2 1 and the blowers 1 2 4 at the fuel, the recombiner 1 4 2 and the burner. 1 3 1 medium liquid flow, wherein the blower 1 2 4 is the second option of the source, and can also be applied to the configuration of the third figure to remove the need for the test device to be empty. The waste heat recovery unit 13 has three configurations. The first to third configurations are all in communication with the system to control the gas/liquid supply unit 1 '2, and are used to perform gas/liquid input to the supply unit 12 First order. Wherein, the first configuration type includes a burner 1 3 1 , a front heat exchange 2 and a rear heat exchanger 1 3 3 as shown in FIG. 2, and the high temperature gas discharged from the combustion is introduced. The post-heat exchange performs waste heat recovery; the second configuration type, as described above, includes at least the burner 133 and the rear 134, which are required for testing compared with the first configuration type described above. The control unit 1 is 1 2 1 2 3, and the fifth figure is used as the fuel controller 1 battery 1 6 kg of gas / as the air and the 4th gas compressor type, the part 10 and the gas / liquid section The temperature rise indicates that the heat exchange is performed as shown in the figure, and the high temperature exhaust gas discharged from the burner 1 13 is omitted. It is only discharged directly into the atmosphere without recovery of waste heat; and the third configuration type is as shown in Fig. 4 'Compared with the first configuration type above, only the post-heat master is retained. 1 3 3 , This is the most simple and economical configuration type. The burner 1 3 1 ' in the first and second configurations described above may be a porous medium burner or a catalytic burner. .......

❹ 該氣體預熱與重組單元1 4係與該溫度控制 1 1、該氣/液體供應部1 2及該餘熱回收部1 3連通’其至少包含有一電熱器141及一重組 器1 4 2,係用以對該氣/液體供應部1 2輸入之 氣/液體進行第二階段之預熱與燃料重組。 該高溫爐與壓縮負載部1 5係與該溫度控制 部1 1連通,其至少包含有一高溫爐及一壓縮負 載元件係用以對該燃料電池1 6加溢並施加璧 細力’其中該高溫爐係由該溫度控制部1 1之溫 度控制器控制溫度。 該燃料 載部1 5内 部1 3及該 少包含有— 電池1 6係配置於該高溫爐與壓縮負 ,且該燃料電池1 6係與該餘熱回收 氣體預熱與重組單元1 4連通,其至 電池堆,係用以進行化學反應產生電 立11玄負栽控制暨特性量測部1 7係與該系統控 制。卩1 0及該燃料電池1 6連通,其至少包含有 201017353 一電子負載機及一交流阻抗分析儀,係用以量 該燃料電池1 6之性能特性’其中,該電子里'、 機係與該燃料電池1 6形成串聯回路,田、、載 巾以自動 調節内部電阻負載以量測該燃料電池(堆)1 在不同負載下之特性;該交流阻抗分析儀係與兮 燃料電池1 6形成並聯回路,用以提供〃 ^ 之交流訊號以檢測該燃料電池1 6之阻抗特性。 該氣體成分/壓力分析部1 8係與該系統护^ 制部1 0、該氣/液體供應部1 2、該餘熱回收^ 1 3、泫氣體預熱與重組單元1 4及該燃料電、、也 16連通’其至少包含有一氣體分析儀及一壓力/ 差壓感測器,係用以分析包含該重組器1 4 2、 該燃料電池1 6及該燃燒器1 3 1等出口之產氣 成分且評估各元件之部分性能,並監控裝置中部 分區段之壓力狀況’且上述與該氣體成分/壓力分 析部1 8連通之各部其氣體採樣順序係由該系統 控制部1 〇調控’其中,該氣體分析儀係可為氣 相層析儀、線上氣體分析儀(〇n_line Gas Analyzer)或煙道氣體分析儀。 該排氣冷卻與水源回收部1 9係與該氣/液 體供應部1 2及遠氣體成分./壓力分析部1 8連 通’其至少包含有一排氣冷卻模組1 9 1及一冷 .凝水過滤與儲存槽1 9 2 ’係用以冷卻敦置末端 之高溫廢氣以冷凝成水收集於一儲存槽,並供該 氣/液體供應部1 2使用。 201017353 連通: = 2 〇係與該系統控制部1 〇 ◦之可程式邏輯二制:立運:在該系統控制部1 π ^、科控制益、一有害氣體感測器 :::系、統,係用以對整體裝置作安全性:Γ 並觸發該系統控制部1 0之安全程序。控, 連通名21係與該系統控制部1 〇 供/、各有一監視鮝幕及一指令輪入气 ::: 系用以數值化、圖形化及表格化之監控介; 制部"之工業級電腦後處= 控式營幕搭配滑鼠與鍵盤、或觸 是,藉由上诚:u"至该系統控制部1 〇。如 燃料電池堆測試Γί構成一全新之低污染節能型 圖所當t發明於第-種配置型態時(如第2、5 :及·^後置ί I於该重組器1 4 2、燃燒器1 3 3 0 7各铋Τ父換器1 3 3分別連通多數逆止閥 制…3f 〇係分別對應連接-個流量控 電量控制器121係連… 邏輯部"之可程式 元件之控制器)作為各次 件及其感測器之 輯0制。α = \程式4輯控制11,#由該可程式邏 工制益中繼該訊號擷取系統之資料至該工業級 14 201017353 電細中進行資料後處理與儲存之動作,於其中, 所有感剩器與次元件之訊號係由該訊號與電力線 連结 5 兮 ^ 孩可程式邏輯控制器k該工業級電腦。待. 11玄工業級電腦作業完成後,係透過該人機監控介 面2 1以數值化、圖形化及表格化之監制介面顯 不。與此同時,使用者亦可透過該人機監控介面 2 1下達控制指令’並與上述流程相反之訊號流 傳遞方向達到控制各次元件之目標。其中,該系 © 統控制部1 〇與各元件及其感測器之通訊,除了 该溫度感測器及該壓力/差壓感測器係以類比訊 號傳輪之外,其餘皆係以數位訊號傳輸,並可為 RS-23 2、RS-48 5、RS-4 22及GPIB等各式數位通訊 協定或透過TCP/IP等網路通訊協定之方式。 於一較佳實施例中,如上述第2圖所示之第 一種配置型態’本發明係用以測試使用高溫型之 燃料電池。當欲檢驗燃料電池之性能時,係由該 ❺ 氣/液體供應部1 2同時輸入包含氫氣、天然氣或 碳氫燃料等之燃料、水以及包含純氧或空氣等之 氧化劑’並經由個別之岐管1 2 3將上述輸入之 燃料、水及氧化劑等氣/液體通過該餘熱回收部1 3 ’於進行第一階段之升溫時,係將該氣/液體供 應部1 2提供給陰極之氣流k由一比例式控制閥 5 0輪入至該前置熱交換器1 3 2中進行部分預 熱以及同步降低進入該燃燒器1 3 1入口之氣流 溫度’隨後係將預熱完之氣流輸入至該後置熱交 201017353 換器 一階段 由該餘 供。若 時’則 前,係 動作。 配置型 無此比 之配置 3 3中進行再次預熱’藉此完成第 之升溫’而其氣流升溫所需之熱能,則可 熱回收部1 3藉由回收部分元件熱能來提 該燃料電池1 6之陽極氣體有加濕之需求 燃料氣體在進入該燃料電池(堆)1 6之 可以該氣體加濕器1 2 2進行氣體之加濕 其中’若係採用上述第3圖所示之第二種 態或第4圖所示之第三種配置型態時,則 例式控制閥5 〇以及前置熱交換器1 3 2 待上述氣/液體經過第一階段之預熱後,係接 著通過該氣體預熱與重組單元1 4進行第二階段 之預熱與燃料重組,由該電熱器1 4 1預熱該燃 料電池1 6陰/陽極氣流,以作為補償或微調該餘 熱回收部1 3不足之熱源。而該重組器χ 4 2則 叮將輸入之天然氣配合水及空氣重組成富氫氣體 Φ :並讓該富氫氣體輸出至該燃料電池1 6進行化 學反應產生電能。 b备過上述二次預熱後之氣/液體係循著陰極 與陽極個別之岐管1 2 3,穿過該高溫爐與壓縮 負載部1 5進入該燃料電池1 6之陰/陽極中。於 其中’係由該高溫爐將該燃料電池1 6加溫至7 〇 〇 〜°C,以提供該燃料電池(堆)丄6啟動初 期之預熱及穩態運作時之持溫;並且,係可在該 燃料電池(堆)1 6頂部直接放置一定重量之耐 於δ亥兩溫爐外部之液壓裝置 (堆)1 6負載元件之壓縮 元件可透過一可耐高溫之陶 化加負載於該燃料電池1 6 料電池1(堆)16之氣密性 1 6之性能特性再由該負載 7量測。係可以習知之電子 析儀與該燃料電池1 6串聯 燃料電池1 6之電壓、電流 燃料電池1 6之阻抗特性。 不之第一種配置型態中,當 需富氫氣體進行化學反應, 放之殘餘燃料與空氣排放至 合燃燒時,該溫度控制部1 隨時偵測該燃料電池1 6及 轉溫度。當該溫度感測器偵 時’係將從陰極排放之高溫 父換器132中,藉由一冷 南溫陰極氣流之溫度後,再 中混合燃燒’最後再將燃燒 後置熱霁換器1 3 3加熱來 2提供i之氣流,以大幅減少 疋1 4辧需消耗之電力。於 交換器1 3 2之冷端氣流量 201017353 熱金屬塊,或以一位 作為提供該燃料電池 力來源。該壓縮負載 瓷或金屬枉體,間接 頂部’進而確保該燃 〇 上述該燃料電池 控制暨特性量測部1 Φ 負載機及交流阻抗分 或並聯’藉以量測該 與功率曲線,以及該 在上述第2圖所 該燃料電池1 6以所 並·將其陰陽極個別排 該燃燒器1 3 1中混 1之溫度感測器即可 Φ 該燃燒器1 3 1之運 測出運轉溫度為高溫 氣流輸入至該前置熱 端氣流先行初步降低 進入該燃燒器1 3 1 後產生之熱量藉由該 自該氣/液體供應部1 該氣體預熱與重組單 其中,進入該前置熱 17 201017353 係由該系統控制部1 0進行控制。此外,若係採 用上述第3圖所示之第二種配置型態時,則從該 燃料電池(堆)1 6陰/陽極個別排放之空氣與殘. 餘燃料在排放至該燃燒器i 3 i中混合燃燒以減 少污染後,即逕自排放至大氣環境中而不進行熱 忐之回收;若係採用上述第4圖所示之第三種配 置型態時,則從該燃料電池(堆)i 6陰/陽極個 別排放之空氣與殘餘燃料係不加以混合烬燒,僅 ❹The gas preheating and recombining unit 14 is connected to the temperature control unit 1 , the gas/liquid supply unit 12 and the waste heat recovery unit 13 and includes at least one electric heater 141 and a recombiner 1 4 2 . The second stage of preheating and fuel recombination is performed on the gas/liquid input to the gas/liquid supply unit 12. The high temperature furnace and the compression load portion 15 are in communication with the temperature control unit 11 and include at least one high temperature furnace and a compression load element for overflowing the fuel cell 16 and applying a fine force 'the high temperature The furnace system controls the temperature by the temperature controller of the temperature control unit 11. The fuel carrier 15 interior 13 and the battery 16 are disposed in the high temperature furnace and compressed negatively, and the fuel cell 16 is in communication with the waste heat recovery gas preheating and recombining unit 14 To the battery stack, it is used to carry out chemical reaction to produce the electric vertical 11 Xuan negative plant control and characteristic measurement department 1 7 series with the system control.卩10 and the fuel cell 16 are connected, and at least include an electronic loader of 201017353 and an AC impedance analyzer for measuring the performance characteristics of the fuel cell 16. wherein the electronic system and the system The fuel cell 16 forms a series circuit, the field, the towel is automatically adjusted to adjust the internal resistance load to measure the characteristics of the fuel cell (heap) 1 under different loads; the AC impedance analyzer is formed with the helium fuel cell 16 A parallel circuit is provided to provide an alternating current signal of 〃^ to detect the impedance characteristic of the fuel cell 16. The gas component/pressure analysis unit 18 is connected to the system protection unit 10, the gas/liquid supply unit 1, the waste heat recovery unit, the helium gas preheating and recombination unit 14 and the fuel, And 16-connected' at least one gas analyzer and a pressure/differential pressure sensor for analyzing the output including the recombiner 1 4 2, the fuel cell 16 and the burner 133 The gas composition and evaluation of part of the performance of each component, and monitoring the pressure condition of a portion of the device in the device' and the gas sampling sequence of each of the above-mentioned portions in communication with the gas component/pressure analysis portion 18 is regulated by the system control portion 1 The gas analyzer can be a gas chromatograph, a 气体n_line Gas Analyzer or a flue gas analyzer. The exhaust gas cooling and water source recovery unit 19 is in communication with the gas/liquid supply unit 1 2 and the far gas component/pressure analysis unit 1 8 and includes at least one exhaust gas cooling module 1 9 1 and a cold condensation. The water filtration and storage tank 1 9 2 ' is used to cool the high temperature exhaust gas at the end of the tank to be condensed into water and collected in a storage tank for use by the gas/liquid supply unit 12. 201017353 Connectivity: = 2 〇 与 该 该 该 该 该 该 该 该 该 : 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立 立Used to secure the overall device: Γ and trigger the security program of the system control unit 10. The control, the connection name 21 system and the system control unit 1 provide /, each has a monitoring screen and a command wheel air inlet::: is used for numerical, graphical and tabular monitoring media; Department " After the industrial grade computer = control the camping screen with the mouse and keyboard, or touch, by Shangcheng: u" to the system control department 1 〇. For example, the fuel cell stack test 构成ί constitutes a brand new low-pollution energy-saving map when it is invented in the first configuration type (such as 2nd, 5th, and ^^ post ί I in the recombiner 1 4 2, burning 1 3 3 0 7 铋Τ 换 换 1 1 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 As a component of each sub-piece and its sensor. α = \ Program 4 series control 11, # is the program logic to relay the signal to the system to the industrial level 14 201017353 in the fine data for post-processing and storage, in which all sense The signal of the residual device and the secondary component is connected by the signal and the power line. 5 兮^ The child programmable logic controller k is the industrial grade computer. After the 11th industrial-grade computer operation is completed, the man-machine monitoring interface 2 is displayed by the supervisory interface of numerical, graphical and tabular. At the same time, the user can also send the control command by the man-machine monitoring interface 2 and the direction of the signal flow opposite to the above process reaches the goal of controlling each component. Wherein, the system control unit 1 communicates with each component and its sensor, except that the temperature sensor and the pressure/differential pressure sensor are analogous to the signal transmission wheel, and the others are digitally digitized. Signal transmission, and can be RS-23 2, RS-48 5, RS-4 22 and GPIB various digital communication protocols or through the network communication protocol such as TCP / IP. In a preferred embodiment, the first configuration shown in Fig. 2 above is for testing a fuel cell using a high temperature type. When the performance of the fuel cell is to be tested, the helium/liquid supply unit 12 simultaneously inputs a fuel containing hydrogen, natural gas or hydrocarbon fuel, water, and an oxidant containing pure oxygen or air, and The tube 1 2 3 passes the gas/liquid, such as the fuel, water, and oxidant, which are input as described above, through the waste heat recovery unit 1 3 ' when the temperature rise in the first stage is performed, and the gas/liquid supply unit 1 2 supplies the gas flow to the cathode. A pre-heating and a simultaneous reduction of the temperature of the gas stream entering the inlet of the burner 1 3 1 by a proportional control valve 50 is introduced into the front heat exchanger 1 3 2, and then the preheated gas stream is input to The post-heating 201017353 converter is staged by the remainder. If it is then, then it will act. The configuration type does not have the heat energy required to perform the preheating in the configuration 3 3 to complete the first temperature increase and the air flow is heated, and the heat recovery unit 13 picks up the fuel cell 1 by recovering part of the heat energy of the component. The anode gas of 6 has the requirement of humidification. When the fuel gas enters the fuel cell (heap), the gas humidifier can be humidified by the gas humidifier 1 2 2, if the second method shown in the third figure is used. In the case of the third configuration type shown in Fig. 4, the example control valve 5 〇 and the front heat exchanger 1 3 2 are passed through the first stage after the gas/liquid is preheated. The gas preheating and recombining unit 14 performs the second stage of preheating and fuel recombination, and the fuel cell 16 cathode/anode gas stream is preheated by the electric heater 14 1 to compensate or fine tune the waste heat recovery unit 13 Insufficient heat source. The recombiner χ 4 2 then recombines the input natural gas with water and air to form a hydrogen-rich gas Φ : and outputs the hydrogen-rich gas to the fuel cell 16 for chemical reaction to generate electric energy. b After the above secondary preheating, the gas/liquid system follows the cathode and anode individual manifolds 1 2 3 and passes through the high temperature furnace and the compression load portion 15 into the cathode/anode of the fuel cell 16. The fuel cell 16 is heated to 7 〇〇 ° ° C by the high temperature furnace to provide the temperature during the initial heating and steady state operation of the fuel cell (heap) 丄 6; The hydraulic device (heap) of the load of the outside of the furnace can be placed directly on the top of the fuel cell (heap) 16. The compression element of the load element can be permeable to a high temperature resistant ceramic. The performance characteristics of the gas tightness 16 of the fuel cell 16 (battery) 1 are again measured by the load 7. A conventional electronic analyzer is connected in series with the fuel cell 16. The voltage and current of the fuel cell 16 are the impedance characteristics of the fuel cell 16. In the first configuration, when the hydrogen-rich gas is required to be chemically reacted, and the residual fuel and the air are discharged to the combustion, the temperature control unit 1 detects the fuel cell 16 and the temperature at any time. When the temperature sensor detects the time, it will be discharged from the cathode of the high temperature parent converter 132, and then by a cold south temperature cathode gas flow temperature, then the mixed combustion is performed, and finally the combustion is performed after the heat exchanger 1 3 3 Heat 2 to provide the air flow of i to greatly reduce the power required to consume 疋14. The cold end gas flow of the exchanger 1 3 2 201017353 hot metal block, or one bit as a source of fuel cell power. The compression-loaded porcelain or metal body, the indirect top portion 'and thereby ensuring the combustion of the fuel cell control and characteristic measuring portion 1 Φ load machine and the AC impedance minute or parallel' to measure the power curve, and the above The fuel cell 16 in Fig. 2 is a temperature sensor in which the cathode and anode are individually mixed with the burner 1 3 1 to be Φ. The burner 1 3 1 is measured and the operating temperature is high. The airflow is input to the front hot end airflow to firstly reduce the heat generated after entering the combustor 1 3 1 by the gas preheating and recombining the gas from the gas/liquid supply part 1 into the preheating 17 201017353 The system control unit 10 controls the system. In addition, if the second configuration type shown in FIG. 3 is used, the air and residual fuel discharged from the fuel cell (heap) 16 cathode/anode are discharged to the burner i 3 . i mixed combustion to reduce pollution, that is, self-discharge to the atmosphere without recovery of heat; if the third configuration type shown in Figure 4 above is used, then the fuel cell (heap) is used. The air and residual fuels of the i 6 cathode/anode are not mixed and burned, only ❹

將其殘餘燃料排放至大氣中,而其高溫空氣則進 入該後置熱交換器1 3 3中。 在上述第2圖所示之第一種配置型態中,當 ㈣燒器1 3 1 Λ 1氣通過該餘熱回收部丄3 中:後置熱交換器133後,係接著通過該氣體 、刀/壓力刀析邻1 8。在本丨發明中,除了該餘熱 回收部"有通過該氣體成丨分/壓力分析部i 8 :外1 112夜供應部1 2、該氣體預熱與重組 線連結至該氣體成分電壓池力 之氣體採樣順序,則由上述各部 藉由該氣體成分該;調控。 4 2、該燃料電池 丄b以及§亥燃丈堯器q 土特性、並由產氣特性之資料中評估各元二之: *與刼作效率。而該氣體成分,壓力分析部1 8令 之壓力/差壓感測器,則可監控 段之壓力狀況,藉I、B1…^懷刊裝置部伤區 藉量測官路中單點之錶壓或兩不 201017353 同區位之差壓,得知氣流通過各元件時所造成之 壓降,並可以此壓降資料提供該系統控制部丄〇 判別管路是否堵塞或元件運作有積碳狀況以及作 為是否需採取處置程序之依據。 當離開該氣體成分/壓力分析部1 8之廢氣 ’係接著進入該排氣冷卻與水源回收部1 9。由 該排氣冷卻與水源回收部1 9之排氣冷卻模組1 9 1冷卻系統末端之南溫廢氣,以使廢氣中之水 ❹ 蒸汽得以冷凝成液態水以利收集。而該排氣冷卻 與水源回收部1 9之冷凝水過濾與儲存槽i 9 2 則可將南溫排氣冷卻時產生之冷凝水收集於一儲 存槽後,經過濾心過濾後,提供給該氣/液體供應 部1 2所需之水源。藉此大幅減少本裝置對於純 水設備之需求。 由於該燃料電池16本身採用之燃料均有爆 炸之危險性,因此係由該安全性監控部2 〇以獨 © 立運作於該系統控制部10之可程式邏輯控制器 ,當系統發生洩漏或危及操作人員安全之事件時 ,由此-可程式邏輯控制器(或具微處理器之控 制器)直接關斷所有氣流(氣氣除外)之供應, 並由該安全性監控部20内連接有該系統控制部 1 〇及該氣/液體供應部1 ? / 丨丄z之不斷電系統,提供 本發明在市電斷電後,可古 y j有一緩衝時間及足夠之 電力執行電池堆保護程序以B权 斤以及緊急關機程序。例 如切斷燃料之供應,以及剎 A刊用氮氣沖洗該燃料電 19 201017353 =6 :極端等動作。❿配置於該安全性”部 二=體谓測器,則可監控本裝置是否有 A、、、枓洩/属或有害氣體洩漏’如一氧化碳。 之地點可配置於本裝置中(區域監測)或實ς = 廠房(全廠環境監測)巾。其中,該有害氣體偵 測器之輸出訊號係與該系統控制部丄〇社,去 有害氣體濃度達到預設警示值時,則由該系:統二 制部上〇進行系統緊急停機之程序, 閉二 參 料供應閥等。 如是,利用本發明之測試裝置係可針 1 燃料電池堆進行手動或自動化測試。由本 提供燃料電池於測試時所需之溫度及氣/液流等 運轉條件。另外’藉由本發明之各個辅助次系统 ’更可確保長時程測試工作之穩定性與安全性, 且在加入餘熱回收部後,係可大幅降低電池堆測 試站之功率消耗與污染排放’以達到節能環保之 目的,進而降低研發測試之成本。 4上所述,本發明係—秦低污染節能型燃料 電池堆,試裝置,可有效改‘習用之種種缺點, 可測試高溫型燃料電池之固態氧化物燃料電池之 性能,藉以除了提供燃料電池於測試時所需之溫 度及氣/液流等運轉條件,並可大幅降低電池堆測 試站之功率消耗與污染排放,以達到節能環保之 目的且降低研發測試之成本,進而使本發明之 生能更進步、更實用、更符合使用者之所須,確 20 201017353The residual fuel is discharged to the atmosphere, and its high temperature air is introduced into the afterheat exchanger 13 3 . In the first configuration shown in Fig. 2, when the (four) burner 1 3 1 Λ 1 gas passes through the waste heat recovery unit 3: the rear heat exchanger 133, the gas and the knife are passed through / Pressure knife analysis of neighbors 18. In the present invention, in addition to the waste heat recovery unit " there is a gas splitting/pressure analysis unit i 8 : an outer 1 112 night supply unit 1 2, the gas preheating and recombination line is connected to the gas component voltage pool The gas sampling sequence of the force is controlled by the above components by the gas component; 4 2. The characteristics of the fuel cell 丄b and § sea-burning device and the characteristics of the gas-producing characteristics are as follows: * and the efficiency of the operation. The gas component and the pressure analysis unit of the pressure analysis unit 18 can monitor the pressure condition of the section, and use the I, B1, ... Pressure or two non-201017353 differential pressure between the same location, to know the pressure drop caused by the airflow through the components, and the pressure drop data can provide the system control department to determine whether the pipeline is blocked or the carbon operation of the component operation and As a basis for the need for a disposal procedure. The exhaust gas leaving the gas component/pressure analysis unit 18 then enters the exhaust gas cooling and water source recovery unit 19. The exhaust gas cooling module 1 9 of the exhaust gas cooling and water recovery unit 19 cools the south temperature exhaust gas at the end of the system so that the water vapor in the exhaust gas is condensed into liquid water for collection. The condensate water filtration and storage tank i 9 2 of the exhaust gas cooling and water source recovery unit 19 can collect the condensed water generated when the south temperature exhaust gas is cooled, collect it in a storage tank, filter it through the filter core, and provide it to the The water source required for the gas/liquid supply unit 12. This greatly reduces the need for pure water equipment in this unit. Since the fuel used in the fuel cell 16 itself has a risk of explosion, the safety monitoring unit 2 operates the programmable logic controller of the system control unit 10 independently, and when the system leaks or jeopardizes In the event of operator safety, the programmable logic controller (or the controller with the microprocessor) directly shuts off the supply of all airflows (except gas), and is connected by the safety monitoring unit 20 The system control unit 1 and the gas/liquid supply unit 1 ? / 丨丄z of the uninterruptible power system provide the present invention, after the mains power is cut off, the yj can have a buffer time and sufficient power to perform the stack protection program to B Power and emergency shutdown procedures. For example, the supply of fuel is cut off, and the fuel is flushed with nitrogen. 19 201017353 =6: Extreme action. ❿ ❿ 该 该 该 该 该 该 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = Or the actual plant = the whole plant environmental monitoring towel. The output signal of the harmful gas detector and the system control department, when the harmful gas concentration reaches the preset warning value, the system: The system of the second division is to carry out the system emergency shutdown procedure, close the second supply valve, etc. If yes, the test device of the invention can be used for manual or automated testing of the fuel cell stack of the needle 1. The fuel cell is provided for testing. Operating conditions such as temperature and gas/liquid flow are required. In addition, the stability and safety of long-term test work can be ensured by the auxiliary sub-systems of the present invention, and can be greatly reduced after being added to the waste heat recovery unit. The power consumption and pollution discharge of the battery test station is to achieve the purpose of energy saving and environmental protection, thereby reducing the cost of R&D testing. 4 As described above, the present invention is a low-pollution energy-saving fuel. The battery stack and test device can effectively change the shortcomings of the conventional use, and can test the performance of the solid oxide fuel cell of the high temperature fuel cell, in addition to providing the temperature and gas/liquid flow required for the test of the fuel cell. And can greatly reduce the power consumption and pollution emissions of the battery test station, in order to achieve the purpose of energy saving and environmental protection and reduce the cost of research and development testing, thereby making the life of the invention more progressive, more practical and more suitable for the user, Indeed 20 201017353

已符合發明真免丨+ A ^申請之要件,爰依法提出專利申 請。 =以上所述者’僅為本#明之較佳實施例而. 已田不能以此限定本發明會施之範圍;故,凡 ^發明申明專利範圍及發明說明書内容所作之 =單的等效變化與修飾,皆應仍屬本發明專利涵 蓋之範圍内。 【圖式簡單說明】 ,1圖’係本發明之基丰架構方塊示意圖。 第2圖’係本發明第一較佳實施例之第一氣/ 卜 液流環路配置型態示意圖。 第3圖’係本發明第一較佳實施例之第二氣/ 液流環路配置型態示意圖。 第4圖’係本發明第一較佳實施例之第三氣/ 液流環路配置型態示意圖。 第5圖’係本發明第二較佳實施例之第一氣 液流環路配置型態示意圖。 【主要元件符號說明】 系統控制部1 〇 溫度控制部1 1 氣/液體供應部1 2 流量控制器1 2 1 氣體加濕器1 2 2 岐管1 2 3 21 201017353 鼓風機1 2 4 餘熱回收部1 3 燃燒器131 前置熱交換器1 3 2 後置熱交換器133 氣體預熱與重組單元14 電熱器1 4 1 重組器1 4 2 高溫爐與壓縮負載部1 5 燃料電池1 6 負載控制暨特性量測部1 7 氣體成分/壓力分析部1 8 排氣冷卻與水源回收部1 9 排氣冷卻模組1 9 1 冷凝水過濾與儲存槽1 9 2 安全性監控部2 0 人機監控介面21 逆止閥3 0 電磁閥4 0 比例式控制閥5 0 22It has met the requirements of the invention and the application of the patent, and filed a patent application according to law. The above description is only a preferred embodiment of the present invention. The field may not limit the scope of the invention; therefore, the equivalent variation of the invention is determined by the scope of the invention and the contents of the invention description. And modifications are still within the scope of the invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a block diagram of the base structure of the present invention. Fig. 2 is a schematic view showing the configuration of the first gas/bu flow loop of the first preferred embodiment of the present invention. Fig. 3 is a schematic view showing the configuration of a second gas/liquid flow circuit of the first preferred embodiment of the present invention. Fig. 4 is a schematic view showing the configuration of a third gas/liquid flow circuit of the first preferred embodiment of the present invention. Fig. 5 is a schematic view showing the configuration of the first gas-liquid flow circuit of the second preferred embodiment of the present invention. [Description of main components] System control unit 1 〇 Temperature control unit 1 1 Gas/liquid supply unit 1 2 Flow controller 1 2 1 Gas humidifier 1 2 2 Tube 1 2 3 21 201017353 Blower 1 2 4 Heat recovery unit 1 3 Burner 131 Front heat exchanger 1 3 2 Rear heat exchanger 133 Gas preheating and recombination unit 14 Electric heater 1 4 1 Recombiner 1 4 2 High temperature furnace and compression load 1 5 Fuel cell 1 6 Load control Cum characteristic measuring unit 1 7 Gas composition/pressure analysis unit 1 8 Exhaust cooling and water recovery unit 1 9 Exhaust cooling module 1 9 Condensate filtration and storage tank 1 9 2 Safety monitoring unit 2 0 Human machine monitoring Interface 21 check valve 3 0 solenoid valve 4 0 proportional control valve 5 0 22

Claims (1)

201017353 十、申請專利範圍: 1 · 一種低污染節能型燃料電池堆測試裝置,係 包括·’ 一系統控制部,係具有一可程式邏輯控 制器(Programmable Logic Controller, PLC )或具微處理器之控制器、一訊號擷取系統 、一工業級電腦及一訊號與電力線,用以監 控系統之所有狀態; ❹ 一溫度控制部,係率該系統控制部連通 ,其至少包含有一溫度感測器及一溫度控制 器; 一氣/液體供應部,係與該系統控制部連 通’其至少包含有複數個流量控制器、一氣 體加濕器及複數條岐管,係用以輸入作為燃 料、氧化劑及水之氣/液體;201017353 X. Patent application scope: 1 · A low-pollution energy-saving fuel cell stack test device, including a system control unit, having a programmable logic controller (PLC) or a microprocessor a controller, a signal acquisition system, an industrial grade computer, and a signal and power line for monitoring all states of the system; ❹ a temperature control unit, the system control unit is connected, and at least one temperature sensor is included a temperature controller; the gas/liquid supply unit is in communication with the system control unit. The vehicle includes at least a plurality of flow controllers, a gas humidifier and a plurality of manifolds for inputting as fuel, oxidant and water. Gas/liquid ^ 印叹邵,係與該系統控制部及t 氣/液體供應部連通,其至少包含有一燃蜱e 、一前置熱交換器及~後置熱交換器; 以對該氣/液體供應部輪入之氣/液體進行〗 :階段之升溫,並將該燃燒器所排放之言、 氣體導入該後置熱交換器進行餘熱回收… 一氣體預熱與重組單元,係與該溫度^ 1邛、该亂/液體供應部及該餘熱回收部連〗 ’其至少包含有一電熱器及一重組器,係 23 ❿ ❿ 201017353 以對該氣/液體供應部輸入之氣/液體 二階段之預熱與燃料重組; 一高溫爐與壓縮負載部,係與該 制部連通,其至少包含有一高溫爐及 負載元件,係用以對該燃料電池加溫 壓縮力,其中該高溫爐係由該溫度控 溫度控制器控制溫度; 一燃料電池,係配置於該高溫爐 負載部内,且該燃料電池係與該餘熱 及該氣體預熱與重組單元連通,其至 有一電池堆,係用以進行化學反應產 一負載控制暨特性量測部,係與 控制部及該燃料電池連通,其至少包 I 電子負載機及一交流阻抗分析儀,係 測該燃料電池之性能特性; 一氣體成分/壓力分析部,係與該 制部、該氣/液體供應部、該餘熱回收 氣體預熱與重組單元及該燃料電池連 至少包含有一氣體分析儀及一壓力/ I 測器,係用以分析包含該重組器、該 池及該燃燒器等出口之產氣成分且評 件之部分性能,並監控裝置中部分區 力狀況,其中上述與該氣體成分/壓力 進行第 溫度控 一壓縮 並施加 制部之 與壓縮 回收部 少包含 生電能 該系統 含有一 用以量 糸統控 部、該 通,其 差壓感 燃料電 估各元 段之壓 分析部 24 201017353 丨 連通之各部其氣體採樣順序係由該系統控制 部調控; -排氣冷卻與水源回收部’係與該氣,液 體供應部及该氣體成分/壓力分析部連通,其 至少包含有:排氣冷卻模組及—冷凝水過渡 與儲存糟,係用以冷卻灰置末端之高溫廢氣 以冷凝成水收集於一儲存槽,並供該氣/液體 供應部使用;^ Infrared, connected to the system control unit and the t gas/liquid supply unit, comprising at least one burner e, a front heat exchanger and a rear heat exchanger; to the gas/liquid supply unit The gas/liquid in the entrainment is carried out: the temperature rises in the stage, and the words and gases emitted by the burner are introduced into the post-heat exchanger for waste heat recovery... A gas preheating and recombining unit is associated with the temperature ^ 1邛The chaos/liquid supply unit and the waste heat recovery unit are provided with at least one electric heater and a recombinator, and the system is 23 ❿ ❿ 201017353 to preheat the gas/liquid two-stage input to the gas/liquid supply unit. a fuel recombination; a high temperature furnace and a compression load portion connected to the system, the at least one high temperature furnace and the load component for heating and compressing the fuel cell, wherein the high temperature furnace is controlled by the temperature The controller controls the temperature; a fuel cell is disposed in the load portion of the high temperature furnace, and the fuel cell is in communication with the residual heat and the gas preheating and recombining unit, and has a battery stack for performing a chemical reaction a load control and characteristic measuring unit is connected to the control unit and the fuel cell, and at least comprises an I electronic load machine and an AC impedance analyzer for measuring performance characteristics of the fuel cell; a gas component/pressure analysis unit, And the gas supply unit, the gas/liquid supply unit, the waste heat recovery gas preheating and recombining unit, and the fuel cell connection comprising at least one gas analyzer and a pressure/I detector for analyzing the recombiner, The gas production component of the outlet of the pool and the burner and the partial performance of the evaluation, and monitoring the partial force condition of the device, wherein the gas component/pressure is subjected to temperature control and compression, and the compression and recovery portion is applied to the portion. Included in the system, the system includes a pressure analysis unit 24, which is used to measure the differential pressure fuel element. The gas sampling sequence is controlled by the system control unit. The exhaust gas cooling and water source recovery unit communicates with the gas, the liquid supply unit, and the gas component/pressure analysis unit, and includes at least: Air cooling module and - storing the condensed water and bad transition, temperature exhaust gas system for cooling the end opposite to the ash into water collected in a condensate storage tank, and the gas supply / liquid supply portion used; 參 一安全性監控部,係與該系統控制部連 通,其至少包含有獨立運作在該系統控制部 之可程式邏輯控制器、一有害氣體感測器及 一不斷電系統,係用以+整體裝置作安全性 監控’並觸發該系統控制部之安全程序; 一人機監控介面,係與該系統控制部連 通,其至少包含有一監視勞幕及一指令輸入 設備,係用以數值化、圖形化及表格化之監 控介面顯示經該系統控制部之工業級電腦後 處理之資訊,並下達控制指令至該系統控制 部;以及 其中’ S玄可程式邏輯控制器係作為該溫 度控制部、該氣/液體供應部、該餘熱回收部 、f負載控制暨特性量測部、該氣體成分/壓 力勿析部、該安全性監控部以及該人機監控 介面之控制中樞。 25 201017353 · 2 ·依據申請專利範圍第i項所述 ^燃料電池堆測試裝置丨其中, /、 οσ @些流#批 制态係用以控制在該燃料電池、該 时工 3 5亥燃燒器中所需之氣/液體流量。 、、器及 依據申請專利範圍第1項所述 ^ m ^ L <低· 染節能 i燃枓電池堆測試裝置,其中, 應部传$小-Γ Μ 产〆 氣/液體供 。。丨係至少可輸入氫氣、天 。 ·'、、孔或碳氫燃料 4 ⑩ 7 依據申請專利範圍第1項所述之低、、-仇〜▲ 型燃料電池堆測試裝置,其中,':7木卽’ 應部係至少可輸入純氧或空氣。°Λ軋/液體4 依據申請專利範圍第丄項所九— ^•燃料電池堆測試裝置,1 /巧木即負 部之配置型態亦可為二,该餘熱回咕 後置熱交換器。〜、匕3有該燃燒器及言 範圍第1項所述之低污染節*1 敦置,其中,該餘熱二 器。置型'"亦可為只包含有該後置熱交拓 利範圍第所述之低污染“ =電池堆測試敦置U中,該氣/液體供 . /包含複數個鼓風機。 二.申請專利範圍$ 1項所述之低污染節能 ·.表料電池堆測試裴置,其中,該溫度感測 26 8 201017353 器及該壓力/差壓感測器係 糸u類比訊號斑該 糸統控制部通訊傳輸。 一 •依據申請專利範圍第1項所 汀述之低π染節能 型燃料電池堆測試裝置,I A A[7 ^ 昇中,該系統控制 部係以數位訊號與各元件诵 τ项矾傳輸,並可為 RS-232、RS-485、RS-422 ' 々 為 'S -〇 i-Λ ^ π GPIB之各式數位 通机協定或透過TCP/IP網敗、s — J略通訊協定之方式 0 ^ 0 ·依據申請專利範圍第i 能型燃料電池堆測試裝置^之低π染郎 !=以控制該氣體預熱與重組單元及該 爐與壓縮負載部中f溫爐之電熱輸出功 1 ·依據申請專利範圍第3 丄項所述之低污毕筋 能型燃料電池堆測試裝置,5木郎 載几件係可在該電池堆 、 ❹ 旦夕#1 Λ Μ部直接放置一定重 里之耐熱金屬塊,或俜 邾# t r x你u —位於該高溫爐外 口 P之液壓裝置作為其壓 π Μ 一、 、i細力來源,並透過一 、尚溫之陶瓷或金屬# „ & U 勒往體,間接施加負载 方、忑燃枓電池頂部。 2 ·依據申請專利範圍第 台匕刑祕1 固弟1項所述之低污染節 月b聖U料電池堆測試 >、 俜可將4 Μ 、置,其中,該尚溫爐 你·)將δ亥燃料電池加、、w 捍板分A 电加,皿至700〜1 000。〇用以 ^池堆啟動初期之預熱以及穩態運作 27 201017353 二依據申請專利範圍第1項所述之低污染節 能型燃料電池堆測試裝置,其中,該電子負 栽機係與該燃料電池形咸串聯回路,用以自 動調節内部電阻負載以&測該電池堆在不同 負载下之特性。 4 处依據申請專利範圍第、項所述之低污染節 燃料電池堆測試裝置,其中,該交流阻 抗分析儀係與該燃料電池形成並聯回路,用 ς ί、不同頻率之交流訊號以檢測該燃料電 池之阻抗特性。 Α依據申凊專利範圍第1項所述之低污染節 吨型燃料電池堆測試裝置’其中,該燃燒器 係可為多孔性介質燃燒器或觸媒式燃燒器。 ▲依據申凊專利範圍第1項所述之低污染節 ΐ型,料電池堆測試裝置,其中,該前置熱 父換器之冷端氣流量係由該系統控制 控制。 1 依據申凊專利範圍第1項所述之低污染節 能型燃料電池堆測試裝置,其中,該氣體分 析儀係可為氣相層析儀、線上氣體分析儀( On—hne Gas Analyzer)或煙道氣體分析儀 〇 8处依據申請專利範圍第1項所述之低污染節 能型燃料電池堆測試裝置,其中,該可程式 邏輯控制器係用以執行自動化控制程序,並 28 201017353 中繼該訊號擷取系統之資料至該工業 〇 1 9 ·依據申請專利範圍第1項所述之低 能型燃料電池堆測試裝置,其中,該 控介面係可為電腦螢幕搭配滑鼠與鍵 觸控式螢幕。 2 0 ·依據申請專利範圍第1項所述之低 能型燃料電池堆測試裝£,其中,該 、該燃燒器及該後置熱交換器更可進 別連通多數逆止閥,各逆止閥係分別 接一個流量控制器,而各流量控制器 多數電磁閥進行控制。 級電腦 污染節 人機監 盤、或 污染節 重組器 一步分 對應連 係連接The security monitoring unit is connected to the system control unit, and includes at least a programmable logic controller, a harmful gas sensor and an uninterruptible power system independently operating in the system control unit. The overall device is used for security monitoring' and triggers the security program of the system control unit; a human-machine monitoring interface is connected to the system control unit, and at least includes a monitoring screen and an instruction input device for digitizing and graphics And the tabular monitoring interface displays the post-processing information of the industrial grade computer of the control unit of the system, and issues a control command to the system control unit; and wherein the 'S-programmable logic controller is used as the temperature control unit, The gas/liquid supply unit, the waste heat recovery unit, the f load control and characteristic measurement unit, the gas component/pressure analysis unit, the safety monitoring unit, and the control center of the human-machine monitoring interface. 25 201017353 · 2 · According to the scope of the patent application section i, the fuel cell stack test device, /, οσ @ some stream # batch system is used to control the fuel cell, the time 3 5 Hai burner The gas/liquid flow required in the process. , , and according to the scope of patent application No. 1 ^ m ^ L < low · dyeing energy-saving i burning battery stack test device, which should be transmitted by the Ministry of small gas - liquid gas supply / liquid supply. . At least hydrogen and gas can be input to the lanthanide system. · ', hole or hydrocarbon fuel 4 10 7 According to the scope of the patent application, the low, the - qi ~ ▲ type fuel cell stack test device, where ': 7 raft ' should be at least input Pure oxygen or air. ° Λ rolling / liquid 4 According to the scope of the application of the scope of the ninth - ^ • fuel cell stack test device, 1 / Qiaomu that the negative configuration can also be two, the residual heat back to the rear heat exchanger. ~, 匕 3 has the burner and the low pollution section *1 described in item 1 of the scope, which is the waste heat device. The type '" can also be included in the low-contamination area described in the post-heating extension range = = cell stack test in the U, the gas / liquid supply. / contains a plurality of blowers. The low-pollution energy-saving metering battery stack test device described in the range of $1, wherein the temperature sensing 26 8 201017353 and the pressure/differential pressure sensor system are similar to the signal spot control system. Communication transmission. 1. According to the low-π dyeing and energy-saving fuel cell stack test device described in the first paragraph of the patent application scope, IAA [7 ^ liter, the system control department transmits digital signals and components τ 矾And can be RS-232, RS-485, RS-422 '々'S-〇i-Λ ^ π GPIB of all kinds of digital machine agreement or through TCP / IP network failure, s - J slightly communication agreement 0 ^ 0 · According to the patent application scope, the i-type fuel cell stack test device ^ low π dye Lang! = to control the gas preheating and recombination unit and the electric heating output of the f and furnace in the furnace and compression load section 1 · Low-sludge energy-type fuel electric power according to the third paragraph of the patent application scope The pool stack test device, 5 wood lang, can be placed in the battery stack, the 1 夕 # 1 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 直接 tr tr tr tr tr tr tr tr tr tr tr tr tr tr tr tr tr tr tr tr tr The hydraulic device acts as a source of fine pressure of π Μ 、 , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , 2 · According to the scope of the application for patents, the first one of the low-pollution festivals, the low-contamination festival, the b-U-battery test, and the U 俜 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置 置Add the δHai fuel cell, and the w 捍 plate to A, and add the dish to 700~1 000.预 预 ^ 池 池 池 池 池 池 池 池 池 池 池 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 2010 27 27 27 27 27 27 27 27 27 27 27 27 27 27 27 A salty series circuit that automatically adjusts the internal resistive load to measure the characteristics of the stack under different loads. 4. The low-pollution fuel cell stack test device according to the scope of the patent application, wherein the AC impedance analyzer forms a parallel circuit with the fuel cell, and detects the fuel by using alternating frequency signals of different frequencies. The impedance characteristics of the battery. The low-pollution ton-type fuel cell stack test apparatus according to claim 1, wherein the burner may be a porous medium burner or a catalytic burner. ▲ According to the low pollution section , type, the material stack test device described in claim 1 of the claim, wherein the cold end gas flow of the preheating parent exchanger is controlled by the system. 1 The low-pollution energy-saving fuel cell stack testing device according to claim 1, wherein the gas analyzer can be a gas chromatograph, an on-hne gas analyzer or a smoke. The gas analyzer 〇8 is in accordance with the low-pollution energy-saving fuel cell stack testing device described in claim 1, wherein the programmable logic controller is used to execute an automatic control program, and 28 201017353 relays the signal Extracting system information to the industry 〇1 · According to the low-energy fuel cell stack test device described in claim 1, wherein the control interface can be a computer screen with a mouse and a key touch screen. 2 0. According to the low-energy fuel cell stack test described in claim 1, wherein the burner and the rear heat exchanger are further connected to a plurality of check valves, each check valve Each is connected to a flow controller, and each flow controller is controlled by a plurality of solenoid valves. Class computer pollution section, human machine monitor, or pollution section, reorganization, one step, corresponding connection 2929
TW097141809A 2008-10-30 2008-10-30 Low emission and energy saving apparatus for performance testing of fuel cells TWI372953B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110177408A1 (en) * 2010-01-19 2011-07-21 Atomic Energy Council-Institute Of Nuclear Energy Research Environmentally Friendly, Energy-Economic System for Testing Fuel Cell Stacks
TWI451622B (en) * 2010-12-07 2014-09-01 Fuel cell power supply with high-low pressure hydrogen flow control
TWI451621B (en) * 2010-12-07 2014-09-01 Ta Hwa University Of Science And Technology Dual chamber fuel cell power supply
TWI557390B (en) * 2014-09-04 2016-11-11 臺灣塑膠工業股份有限公司 Control system for controlling a power plant system
TWI580104B (en) * 2012-12-26 2017-04-21 國立交通大學 Fuel cell system and method of heat recovery thereof
CN110531273A (en) * 2019-09-30 2019-12-03 中国华能集团清洁能源技术研究院有限公司 A kind of high-temperature fuel cell test macro

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110177408A1 (en) * 2010-01-19 2011-07-21 Atomic Energy Council-Institute Of Nuclear Energy Research Environmentally Friendly, Energy-Economic System for Testing Fuel Cell Stacks
US8333125B2 (en) * 2010-01-19 2012-12-18 Atomic Energy Council—Institute of Nuclear Energy Research Environmentally friendly, energy-economic system for testing fuel cell stacks
TWI451622B (en) * 2010-12-07 2014-09-01 Fuel cell power supply with high-low pressure hydrogen flow control
TWI451621B (en) * 2010-12-07 2014-09-01 Ta Hwa University Of Science And Technology Dual chamber fuel cell power supply
TWI580104B (en) * 2012-12-26 2017-04-21 國立交通大學 Fuel cell system and method of heat recovery thereof
TWI557390B (en) * 2014-09-04 2016-11-11 臺灣塑膠工業股份有限公司 Control system for controlling a power plant system
CN110531273A (en) * 2019-09-30 2019-12-03 中国华能集团清洁能源技术研究院有限公司 A kind of high-temperature fuel cell test macro

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