TW201016922A - Method for atmospheric plasma-enhanced natural antibacterial and moisture transferring and quick drying modification of textiles - Google Patents

Abstract

A method of plasma-enhanced natural antibacterial and moisture transferring and quick drying modification of textiles at atmospheric pressure is provided. The method includes the following steps: plasma activation and coarsening of the textiles at atmospheric pressure, wherein the textiles are polyester or nylon; exposure of the textiles to the air; uniform coating of the antibacterial agent solution on the textiles, wherein the antibacterial agent solution is chitosan polymer solution or chitosan oligomer solution; low-temperature baking of the textiles and the antibacterial agent solution; activation and coarsening of the composite of the textiles and the antibacterial agent solution and fast graft polymerization and cross-linking of the composite; high-temperature baking and curing of the textiles and the antibacterial agent solution. The antibacterial efficiency and the washing fastness of the textiles can be enhanced greatly via the process described above.

Description

201016922 VI. Description of the Invention: [Technical Field] The present invention relates to a method for enhancing the graft polymerization and bonding of an antimicrobial agent by atmospheric electropolymerization of a textile, and particularly relates to a combination of a general low rate Chitosan graft polymerization and an innovative high-rate atmospheric plasma simultaneously activate the antibacterial agent solution and the textile antibacterial agent graft polymerization and bonding and cross-linking process such as antibacterial and moisture absorption and quick-drying modification method to achieve a large increase The natural antibacterial rate of textiles, the washing fastness and the requirements of environmentally friendly processes. [Prior Art] With the improvement of human living standards, the demand for safe, healthy and comfortable antibacterial and moisture-absorbing and quick-drying textiles is becoming more and more urgent. The antibacterial agents used in antibacterial textiles on the market are classified into organic and inorganic. Two. The inorganic antibacterial agent has the best antibacterial effect with nano silver, but its toxicity and cost are also the highest. Therefore, it is applied to clothing such as underwear, underwear, sportswear, vacation, socks, etc., and still uses organic natural antibacterial agents to meet the overall needs of health, comfort and safety. It is the best choice for Chitosan polymers and Chitosan oligomers with the dual function of moisture absorption and quick drying. Both chitosan and chitosan oligosaccharides have good biocompatibility, bioactivity, biodegradability, hygroscopicity and non-toxicity, while polyester fabrics and nylon-resistant fabrics are hydrophobic. The material, therefore, is grafted with a tens of nanometer-thickness of chitosan or a few polyester-coated polyester cloth or a long-lasting cloth which has the characteristics of moisture absorption and quick drying. And chitosan is second only to cellulose in natural production, and the supply is sufficient and the price is reasonable. 201016922 At present, the manufacturing method of antibacterial textiles is more competitive in the market because of the lower cost of chemical processing and processing. In addition to the antibacterial agent, the chemical agents required for the conventional chemical treatment of the grafting process require the following two indispensable chemical agents: (1) Acidic agents required for textile surface activation treatment such as h2〇2, K2S2〇 8 or an azo compound (Azocoinp〇unds), in order to produce an antibacterial agent and substrate graft polymerization initiator (p〇lymerizati〇n Initiators) such as peroxides (Peroxides); 〇 (2) to enhance the weaving of the fabric A small amount of a crosslinking agent (Cross-linking agent) or the like. With the addition of these two chemicals, antibacterial agents and hygroscopic agents, it is possible to manufacture functional textiles such as antibacterial and hygroscopic and quick-drying that meet some market needs. However, this traditional chemical processing process still has two major shortcomings. The first one is the processing of the normal concentration of chemical agents, the antibacterial rate and the washing fastness of the products are generally poor; the second is to use a higher concentration of chemical processing in order to improve the antibacterial rate and washing fastness, Its wastewater will cause serious pollution to the 0 environment. With the advancement of plasma technology, the aforementioned two types of chemical agents that pollute the environment can be replaced by environmentally friendly electricity. Since the electric beam is produced by using an inert gas (such as He or Ar) or clean and dry air or a reactive gas (such as ruthenium, osmium or iridium) under a strong electric field, the plasma contains electrons, ions, and free radicals. A number of highly active species with UV light. When the surface of the woven fabric is irradiated and struck by these highly active species, the molecular bonds on the surface are interrupted to produce an active radieais. These reactive groups can directly initiate the graft polymerization. On the one hand, after contact with oxygen, more peroxide can be produced, and then the subsequent antibacterial functional group graft polymerization can be initiated. Therefore, electricity can replace the acidic chemicals used in conventional activation. In order to mention the grafting rate of the antibacterial functional group, it is also important to have the activity of the microbial agent in addition to the surface of the woven fabric. Since chitosan is a highly molecular material, it is almost inactive, and chitin is also a low activity macromolecule, and its rate of grafting to activated textiles is very low. Therefore, in order to enhance the activity of the chitosan, the chitin polymerase solution is applied to the surface of the woven fabric, and the chitosan molecules are broken by the irradiation of the atmospheric plasma to improve the activity and On the other hand, the chitosan bond which has been graft polymerized onto the substrate is subjected to a crosslinking reaction. Therefore, it is also possible to replace the function of the chemical crosslinking agent by using an electropolymerization treatment as appropriate and in addition to increasing the grafting rate. According to the chemical characteristics of different substrates, the electrolysis treatment parameters can be adjusted to obtain the best antibacterial and hygroscopic quick-drying effects. Therefore, in addition to completely replacing the functions of the above chemical agents, the plasma can achieve better quality than the traditional chemical processing process under the environmental protection requirements. Although the plasma has the advantages described above, the most mature true φ air plasma or low-pressure plasma is developed because the required vacuum equipment and operating cost are quite south, and the processing conditions of the required vacuum chamber are also The size and yield of the substrate are limited. Therefore, vacuum (or low pressure) plasma does not have the competitiveness of industrial applications in the antibacterial modification of woven fabrics. Fortunately, the atmospheric plasma can be modified to cover the shortcomings of vacuum plasma. Its technology development has gradually reached a stage. Because it does not require expensive vacuum equipment, the substrate size is also unlimited. Therefore, atmospheric plasma is used in industry. On, has unlimited application potential. Internationally published literature on natural antibacterial modification of atmospheric plasma is: (1) 2006 North Carolina State University (N〇rth Car〇lina 6 201016922)

State University ) Belen M. Perez Rivera's master thesis entitled "Plasma-aided antimicrobial and insect repellent finishing of cotton"; (2) US Patent Disclosure applied by Mohamed Abedehay Bourham et al., North Carolina State University, USA, 2007 No. 20070161308A1, the patent name is "Atmospheric pressure plasma-aided accessory finishing of textiles". In the first published literature, the process was as follows: after the textile was pretreated with He/02 large ❿ gas, the Glycidyl methacrylate (GMA) was grafted at a temperature of 80 ° C. -60 minutes, as a cross-linking agent for the subsequent grafting of antibacterial agents, and then grafting hydrogenated trimethyl-sulphate (N-(2-hydroxy propyl) 3-trimethylammonium chitosan chloride at 80 ° C , HTCC), which is a quaternary ammonium chitosan derivative having a higher antibacterial property than chitosan to complete the antibacterial process of textiles. Φ However, the disadvantage is that the graft polymerization of glycidyl methacrylate (GMA) takes 30 to 60 minutes, and the preparation of hydrogenated tridecylamine chlorinated chitosan (HTCC) takes up to about 24 hours. Therefore, it is not easy to mass produce. In the patent application disclosed in the second article of Bourham et al., although the process can dispense with the polymeric glycosyl glycidyl glycol (GMA) crosslinker which grafts the antibacterial agent, and activate the atmospheric plasma with the antibacterial agent. The branches are combined into a single process that is performed simultaneously. However, hydrogenated tridecylamine in the amine salt derivative type of quaternary amine chitosan is still used to vaporize chitosan (HTCC) as an antibacterial agent. Gasification of chitosan (HTCC) antibacterial agent by hydrogenated tridecylamine is 201016922 Chitosan and tridecylamine chloride glycidol

(Glycidyltrimethyl ammonium chloride, GTMAC) is synthesized in a neutral or alkaline solution at 80oC, and the process is still up to about 24 hours. Therefore, the above two processes are not easy to mass produce and have no basic requirements for industrial application value. From the above analysis, it shows that the published literature and the published patent due to the hydrogenation of trimethylamine chlorinated chitosan (HTCC) antibacterial agent synthesis process rate is too slow and costly, and can not meet the mass production of the textile industry With low to φ this demand. SUMMARY OF THE INVENTION In view of this, the main object of the present invention is to combine the general low-rate antibacterial agent graft polymerization process with an innovative and rapid antibacterial agent graft polymerization and bonding crosslinking process to greatly increase the connection of textile antibacterial agents. The branch rate and the strength of the graft bond achieve the goal of improving product quality. Specifically, the present invention directly uses the market-specific specifications of chitosan or chitinase as an antibacterial Φ agent, thereby eliminating the additional processing time and low cost of secondary processing, so as to achieve rapid process and large output. The goal of low cost. In the improvement of antibacterial efficiency, the present invention mainly uses atmospheric electropolymerization to simultaneously irradiate a few butyl lactic acid antibacterial solution and a textile substrate to improve the activity and purity of the antibacterial agent, and the crosslinking strength with the substrate. To achieve the antibacterial rate of demand on the market. The natural antibacterial agent to which the present invention is applied includes chitosan and chitosan, and the like, thereby expanding the range of antibacterial agents for applications such as natural anti-f modification of atmospheric electricity, and making the application of antibacterial modification of atmospheric plasma wider. 'And by its innovative antibacterial agent solution and textiles at the same time large 201016922 gas plasma activation, rapid grafting of artificial textiles antibacterial rate and washing fastness of the process of cross-linking, greatly improve the high quality of industrial applications, a large number of violations Improve product quality, so it meets the needs for the above or other purposes, cost, etc. The gas-electric device enhances the atmospheric glow or filament discharge of the large fabrics of natural anti-g and suction (four) textiles. The dual-function modification method, including the spinning polyester cloth and the resistant fabric, activates and coarsens the activated I, while the textile The free radicals and oxygen products produced for the fabric are exposed to the atmosphere'. The textiles of the textile are impregnated with natural anti-solubilizers, which will form a peroxidized cloth on the surface of the textile, and (4) low-speed ', 〇, to make pure liquid The uniform application of the antibacterial agent solution is a polymerization reaction of the chitin polymerase solution, and the natural rate graft polymerization of the natural antibacterial agent will be completed slowly so that the natural antibacterial agent on the textile is baked under the temperature: the glow and the filament Hybrid discharge capacity ' μ loves the conditions for the generation of life-saving electricity; the natural antibacterial agent solution that has been dried to the same level of dryness and textiles are simultaneously used as electric radiation to carry out natural antibacterial solution and textile The cross-linking of σ and graft bonds; and the full supply and hardening of the natural and rapid grafting temperature. The height of the solution and the product are easy to understand. The above and other objects, features and advantages can be more obvious. = The following is a description of the embodiment (4), and in conjunction with the closed type, the detailed description is given.

, macro flow diagram. Please refer to B 201016922. The process sequence of the present invention is as shown in the following steps S11 to S16. (511) Atmospheric plasma activation and coarsening of textiles, (512) Exposure of textiles to the atmosphere; (513) Antibacterial solution Uniform coating on textiles; (514) low temperature baking of antibacterial agent solution and textile; atmospheric plasma activation and (S15) antibacterial agent solution and textile combination roughening, rapid graft polymerization and bonding cross-linking; (S16 High temperature drying and hardening of antibacterial agent solution and textile;

When the above six processes are completed, the modification of the textiles is completed. It is worth noting that the atmospheric plasma source to which the present invention is applied includes Dieletric Barrier Discharge (DBD) atmospheric plasma, radio frequency plasma, microwave (Microwave) plasma and low temperature jet arc polymerization (Arc plasma jet). And the preferred atmospheric plasma continuous reforming process device can be as described in US Patent No. 12/124,685, issued to Mien-Win Wu et al., entitled "Apparatus and method for double-plasma graft polymerization at atmospheric. Pressure", wherein the patent application focuses on the equipment for the double-plasma modification process of polymer materials. In the process of step S11, the textile may be activated and roughened by atmospheric glow or filamentary discharge plasma to facilitate uniform coating and graft polymerization of the chitosan antibacterial wheat solution. Since the power density of the plasma and the increase of the oxygen concentration in the plasma gas affect the coarsening and activation of the textile, the oxygen (〇2) and the argon (Ar) (or helium (He) are more effective in the upgrading process. )) The flow ratio is 2 10%, and the plasma power density is 〇.9W/cm2. Under the operating parameters of the two atmospheric plasmas, the upgrading process can reach the processing speed required by the market. 201016922 In the process of step S12, the activated and roughened textile substrate is exposed to the atmosphere, and the radicals on the surface of the textile interact with oxygen 02 to convert into oxygen radicals, which then form a higher activity. Oxide, as a starting agent for graft polymerization of antibacterial agents. Since the surface of the activated textile is exposed to the atmosphere, on the one hand, a more active peroxide is produced, and on the one hand, the peroxide that has been produced will also disappear with the air of the environment, according to 2003, Chi-Yuan Huang et al. People in Surface and Coating

A research paper published in the Journal of Technology, entitled "Effect〇fplasma ❹ treatment on the AAc grafting percentage of high-density polyethylene", which uses a vacuum plasma to activate a substrate and is exposed to a large temperature of fluorine for 10 minutes to produce The most peroxide, and because this process only uses a plasma gas containing a small amount of oxygen (〇2), its exposure to the atmosphere can be reasonably shortened to 5-6 minutes to properly increase the processing speed. In the process of step S13, the chitosan antibacterial agent solution is uniformly coated on the peroxide-forming textile by impregnation or spraying to carry out slow rate chitosan graft polymerization. . If it is coated by impregnation, the appropriate impregnation time is set to 4~6 minutes, and the preferred impregnation time is about 5 minutes'. The contact time between the product and the grafting solution required for the slow grafting rate is required. The processing speed required to upgrade the process. In the process of step S14, the textile coated with the chitosan antibacterial agent solution is placed in an oven and baked at a temperature of 80 ° C to 10 ° C to reduce the moisture of the chitosan solution on the textile. content. This process does not use a higher temperature to avoid the grafting solution drying too fast, but rather shortens the grafting time (because the graft polymerization is carried out in the liquid 4), thereby reducing the grafting ratio of the grafting liquid to the textile. The optimum process is to first graft the textile at a lower temperature and then heat up to the temperature required for hardening at 201016922. In addition, 90% to 95%. In the process of step S15, the p-polymerization and the textile combination are further affected by the electric charge on the atmosphere, and the second step is: the mixture used in the three grafting liquids. n Atmospheric plasma is active species such as glow and silk and UV. At the same time, textile 3 is activated and roughened, and fast-talking is concentrated. (10) ▲ 4m of the liquid is the mouth and the key, and the reaction is carried out to enhance the eight-resistance. The grafting rate of the yield and the bonding strength of the water-washed graft. Since the axis of the product is _product and connected with ~10%) moisture, the use of the heart 3 has 乂祁/〇5 <n 7W/ 2 The power density of the large-rolled plasma can be moderately reduced - Cm, and the oxygen (〇) 盥 argon _) flow ratio in the plasma gas can be moderately reduced (Ar) (戍氦 rolling or arc discharge; Producing an excessive amount of filament-like discharge and discharging the mechanical strength of the textile fiber. In the process of step S16, the high-temperature drying is followed.

The preferred dryness of this process is approximately !=. ? Cheng's antibacterial agent solution and textiles, and preferably the second degree > just c~150〇c, and the preferred roasting time is 2~3 minutes, so that the X-link hardening has not been completed yet. The material provides the conditions for cross-linking hardening, and avoids the textile and anti-g agent being damaged due to too high temperature and too long time. The whole process is designed to enhance the resistance of chitosan or chitosan oligosaccharides. The rate of grafting and grafting of the material to achieve the purpose of improving product quality, and the use of atmospheric plasma equipment can achieve a continuous production process to achieve mass production, reduce costs and meet environmental protection needs. The modification example of the side-butylase and the chitosan as the antibacterial agent, respectively, 12 201016922 modified polyester woven fabric and nylon woven fabric, indicating that the result of the modification is later. Fig. 2 and Fig. 3 are experimental data for the analysis of the chemical composition of the surface of the polyester fabric which has not been modified. Referring to FIG. 2 and FIG. 3, in the X-Ray PhotodeCtr〇n Spectroscopy (XPS) analysis, the polyester cloth which has not been modified by antibacterial contains only carbon (C) and oxygen (〇) elements. The polyester cloth which is antibacterially modified by chitosan has a nitrogen (N) element signal derived from a chitosan amine group. ^

* For a more detailed analysis, Figure 4 and Figure 5 respectively show that the nitrogen in the X-ray photoelectron spectroscopy (xps) has not been modified with antibacterial properties. Please refer to Fig. 4 and Fig. 5, wherein Fig. 4 shows that the nitrogen element (4) which is not modified is the background noise information, completely (N) transfer money, and the target 5 is clear. Seeing the obvious nitrogen (N) peak money 'more clearly prove that the polyester vinegar that has been modified by antibacterial modification has been grafted into several groups. Figure 6 and Figure 7 show the low-grafting speed of traditional atmospheric electropolymerization. Mingda pulping enhances the energy spectrum of the high resolution scan near the position of the MUNHC element of the dragon cloth. The reference to Fig. 6 and Fig. 2 shows that the process of the invention is resistant to dragon cloth. The nitrogen (9) yuan = the wire is even (10) the traditional atmospheric plasma is changed to the process. The analysis of the two energy can be as shown in Table 1, the process of the invention is resistant to the long cloth _) element twist is 4.4 / 0 ' than the traditional process The ice of the person is higher than the newspaper. © it Yarn analysis results Traditional antibacterial modification

13 201016922 ~~~—. I. Antibacterial modification of the invention 84.8 10.8 4.4 Table 2 is the low-grafting speed modification of the traditional atmospheric plasma and the antibacterial effect of the E. coli tested by the airborne electropolymerization enhanced antibacterial modification of the present invention. . Please refer to Table 2. The data in Table 2 is based on Taiwan's sGSTX61631/2007/LITest Report' and the batch of antibacterial test is based on the JIS L1902 test and calculation method determined by the Japan Industrial Standards Association. In the antibacterial test of this batch of woven fabrics, the initial amount of E. coli on the Nylon weaving fabrics of different antibacterial modification processes _ are 8·3χ107 colony forming units/gram (CFU/g) (:col〇ny_F〇rming Unit , CFU) 'The colony forming unit/gram (CFU/g) after the antibacterial test time specified by JIS L1902 and its bacteriostatic rate are shown in Table 2, indicating that the bacteriostatic rate of the process of the present invention is much higher than that of the dragon cloth. The conventional atmospheric plasma induces the grafting process, and under the condition of 2 minutes of atmospheric plasma activation and coarsening, the antibacterial modification of the anti-loning cloth of the invention is as high as 99.97%, which is in line with the market demand of antibacterial textiles. specification. • Table 2: Antibacterial effect of traditional and antibacterial modified Nylon cloth on Escherichia coli Process activation time CFU/g Reduction rate (%) Traditional antibacterial modification 1 minute 3.2χ107 61.45 Antibacterial modification of the present invention 1 minute 3.9χ106 95.30 2 minutes 2.5χ104 99.97 Figure 8 is the test result of the moisture absorption and quick-drying characteristics of the antibacterial modified Nylon oligo of the present invention. Please refer to Figure 8, the water droplets of the modified Nylon woven fabric 201016922 contact angle It is 3〇: and the surface water droplets are absorbed and diffused and disappeared for a short time ^ w seconds' means that the modified Nylon weave has the quick moisture absorption = 】: 本: 本本上:月:丁丁The sugar antibacterial modified polyester woven fabric is washed with water. The test result - refer to Fig. 9', which indicates that the plasma activation time is a few seconds, and the water is washed more than 5 times. The examples of i test the properties of modified polyester woven fabric and nylon woven fabric and moisture absorption and quick drying respectively, and prove that the method of the invention is to strengthen the natural antibacterial and moisture absorption and quick dry reforming method. Quality = fruit can be well received anti-g and hydrophilic, and has a good washed cattle. The method for enhancing the natural antibacterial and moisture absorbing and quick-drying modification of the atmospheric plasma of the textile of the present invention has at least the following characteristics: The present month effectively improves the low-rate graft polymerization modification process of the conventional atmospheric plasma, and can avoid adopting The disadvantages of secondary low-rate processing and high cost are required. 2. The invention can achieve a large increase in the antibacterial rate and the washing fastness, and can greatly reduce the production of the crucible, and can achieve the goal of continuous treatment and improvement of the yield. 2. The present invention replaces the conventional chemically acidic activating agent and the bonding agent with a non-toxic atmospheric plasma to meet the requirements of an environmentally friendly process. Although the present invention has been disclosed in the preferred embodiments above, it is not intended to limit the present invention. The simple changes and modifications made in the scope of the patent application and the contents of the present invention are still within the scope of the present invention. [Simplified Description] 15 201016922 FIG. 1 is a textile according to an embodiment of the present invention. A schematic diagram of the process of strengthening the antibacterial and moisture absorption and quick-drying dual-function modification method of atmospheric plasma. Figure 2 and Figure 3 respectively show that the antibacterial and antibacterial changes have been made. Analysis of the chemical composition of the surface of the polyester cloth. Figure 4 and Figure 5 show the high resolution near the position of the nitrogen (N) element in the X-ray photoelectron spectroscopy (XPS) of the polyester fabric which has not been modified with antibacterial. Scanning energy spectrum.

Figure 6 and Figure 7 show the high resolution of the low-grafting rate of the conventional atmospheric plasma and the high-resolution near the position of the nitrogen (N) element of the surface spectrum (XPS) of the invented atmospheric plasma enhanced antimicrobial modification. Figure 8 is an antibacterial modification of chitosan oligosaccharide of the present invention:: test results of dryness characteristics. The moisture absorption test of the dragon weaving cloth = the antibacterial effect of the chitosan oligosaccharide of the invention: the water washing of the modified dragon woven fabric [Description of the main components] S11~S16: Step

Claims (1)

201016922 VII. Patent application scope: 1. A method for strengthening the natural antibacterial and moisture absorption and quick-drying dual-function modification of textile atmospheric plasma, including: activation or coarsening of textile atmospheric glow or filament discharge plasma, and textiles are gathered Ester cloth and nylon cloth; exposing the activated textile to the atmosphere, causing the free radicals generated by the textile to form a peroxide; and impregnating the peroxide-forming textile into the natural antibacterial agent solution Φ to make the connection The branch liquid is uniformly coated on the surface of the textile and subjected to low-rate graft polymerization, and the natural antibacterial agent solution is a chitosan solution or a chitosan solution; a natural antibacterial agent which has been subjected to slow rate graft polymerization The solution and the textile are baked at a low temperature to dry the natural antibacterial agent solution on the textile to the required dryness to meet the conditions of the atmospheric glow and the filamentary mixed discharge; it will be dried to the desired dryness The natural antibacterial agent solution and the textile are simultaneously used as atmospheric plasma irradiation to carry out the living Φ, rapid graft polymerization and connection of the natural antibacterial agent solution and the textile. Cross-linking of the branches; and the natural drying and hardening of the natural antibacterial solution and the high temperature of the textile. 2. The method for enhancing the natural antibacterial and hygroscopic quick-drying dual-function modification of the atmospheric plasma of the textile according to claim 1 of the patent application, wherein the step of activating or roughening the atmospheric glow or filament discharge plasma in the textile The plasma gas used is a mixed gas of oxygen (〇2) and argon (Ar), and the flow ratio of oxygen (02) to argon Ar is 210%. 3. For the atmospheric plasma of the textiles mentioned in the first paragraph of the patent application, the natural antibacterial and hygroscopic quick-drying dual-function upgrading method, wherein in the textile 17 201016922 atmospheric glow or filamentary discharge plasma activation and coarsening In the step, the plasma gas used is a mixed gas of oxygen (〇2) and helium (He), and the flow ratio of oxygen (〇2) to helium (He) is > 10%. 4. The atmospheric plasma of the textile according to claim 2 or 3 of the patent application, which enhances the natural antibacterial and hygroscopic quick-drying dual-function upgrading method, wherein the plasma power density used is > 9 W/cm 2 . 5. The atmospheric plasma enhanced natural antibacterial and hygroscopic quick-drying dual-function upgrading method of the textile according to claim 1, wherein the activated φ textile is exposed to the atmosphere for 5 to 6 minutes. 6. The atmospheric plasma of the textile according to claim 1 of the invention claims to strengthen the natural antibacterial and hygroscopic quick-drying dual-function upgrading method, wherein the time for impregnating the peroxide-forming textile into the natural antibacterial agent solution is 4 to 6 minutes. 7. The method for enhancing the natural antibacterial and hygroscopic quick-drying dual-function modification of the atmospheric plasma of the textile according to claim 6 of the patent application, wherein the time during which the peroxide-forming textile is impregnated into the natural antibacterial agent solution is 5 minutes ❿ clock. 8. The method for enhancing the natural antibacterial and moisture absorption and quick-drying dual-function modification of the atmospheric plasma of the textile according to the first aspect of the patent application, wherein the natural antibacterial agent solution and the textile which have been subjected to slow rate graft polymerization are at a low temperature. In the lower baking step, the temperature of the low-temperature baking is between 80 ° C and 100 ° C. 9. The method of applying the atmospheric plasma of the textile according to item 8 of the patent application to strengthen the natural antibacterial and moisture absorption quick-drying dual-function modification method, wherein the natural antibacterial agent solution on the textile is dried to a required dryness of 90%. ~95% between. 10. For the atmospheric plasma of textiles mentioned in the first paragraph of the patent application plus 201016922 strong natural antibacterial and hygroscopic quick-drying dual-function modification method, in which the activation and rapid graft polymerization of natural antibacterial agent solution and textile are carried out. In the crosslinking of the graft bond, the plasma gas used is a mixed gas of oxygen (02) and argon (Ar), and the flow ratio of oxygen (02) to argon (Ar) is S3%. 11. The method for enhancing the natural antibacterial and hygroscopic quick-drying dual-function modification of the atmospheric plasma of the textile according to the first aspect of the patent application, wherein the natural antibacterial agent solution and the textile are activated, rapidly graft polymerized and grafted. In the cross-linking of the bond, the plasma gas used is a mixed gas of oxygen (02) and helium (He), and the flow ratio of oxygen (〇2) to helium (He) is < 3%. 12. The atmospheric plasma of the textile of claim 10 or 11 enhances the natural antibacterial and hygroscopic quick-drying dual-function upgrading method, wherein the plasma power density used is less than or equal to 77 W/cm2. 13. The method of applying the atmospheric plasma of the textile according to item 1 of the patent application to strengthen the natural antibacterial and moisture absorption quick-drying dual-function modification method, wherein the high temperature is completely dried and hardened in the natural anti-agent solution and the textile, the high temperature The drying temperature is between 140 ° C and 150 ° C. Φ 14. The atmospheric plasma of the textile according to claim 13 of the patent application reinforced the natural antibacterial and moisture absorption quick-drying dual-function modification method, wherein the high-temperature drying time is 2 to 3 minutes. 19