TW201016199A - Medical tape and medical products made therefrom - Google Patents

Medical tape and medical products made therefrom Download PDF

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Publication number
TW201016199A
TW201016199A TW97140422A TW97140422A TW201016199A TW 201016199 A TW201016199 A TW 201016199A TW 97140422 A TW97140422 A TW 97140422A TW 97140422 A TW97140422 A TW 97140422A TW 201016199 A TW201016199 A TW 201016199A
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Taiwan
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medical
tape
woven fabric
woven
medical tape
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TW97140422A
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Chinese (zh)
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Dun-Shen Zhu
shi-ming Zhou
Ting Fan
Youting Li
Dong Wu
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3M Innovative Properties Co
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Publication of TW201016199A publication Critical patent/TW201016199A/en

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Abstract

The present invention provides a medical tape, which includes: a Metallocene-PP copolymer nonwoven backing-lining, and a medical pressure sensitive adhesive coated on at least one face of the above-mentioned backing-lining. The present invention also provides a medical product, which includes medicament and the invented medical tape. The invention can be used to produce medical dressings, medical pastes, ok bonds, etc. and has the advantages of easy in processing, good resiliency, and good liquid barrier properties.

Description

201016199 六、發明說明: 【發明所屬之技術領域】 5 10 15 ❹ 20 、本發月係關於-種醫用膠帶及由其製成的醫用製品, 尤指-種以不織布爲背襯材料的醫用膠帶及由其製成的醫 用製品,例如醫用敫料、膏貼和創可貼等。 【先前技術】 在目剛的健康護理和個人護理領域中,不織布膠帶由 於其&優良、價格低廉和加卫方便等優點,得以廣泛應 用不織布膠帶的原材料包括人造絲、聚醋、人造絲/聚醋 混β物和聚丙烯等。例如,專利前案彼露了一 種醫用透氣膠帶,2包括纏帶圓筒,不織布的—面爲醫用 底膠,不織布的另一面爲黏合劑。黏合劑和不織布間有醫 用底膠。黏合劑採用醫用級丙烯酸壓敏膠,不織布採用常 規齊格勒-納塔聚丙稀不織布。但是,由上述原材料製成的 膠帶都存在如下兩個共同缺點:(1)缺乏彈性,不適合用於 關節等活動部位;(2)對液體的阻隔性差,因此不能防止外 來液體對施用部位的影響或内在藥液的滲出。 爲此’已經有一些發明力圖解決上述的部分問題。如 歐洲專利EP1097185介紹了一種茂金屬催化的聚乙烯(乙稀 和α-稀烴的共聚物)不織布,可作爲背襯材料用於敷料、 膏貼和膠帶等。但是,一般而言,聚乙烯粒子的結晶度高、 加工困難,尤其是茂金屬聚乙烯不能採用紡黏法製造不織 3 201016199 布。就算少數商品化用閃蒸法製成的聚乙烯不織布,由於 過於堅韌而缺乏彈性,難以拉伸。 因此,目前需要開發一種易於加工、具有良好彈性和 液體阻隔性的醫用膠帶及由其製成的醫用製品,例如不織 5 布膠帶。 ’ 【發明内容】 φ 本發明的目的是提供一種易於加工、具有良好彈性和 液體阻隔性的醫用膠帶。 10 作爲本發明的一方面,提供了一種醫用膠帶,其包括: (1) 茂金屬聚丙晞共聚物不織布背襯;以及 (2) 塗敷在所述背襯的至少一面上的醫用壓敏勝。 作爲本發明的另一方面,提供了一種醫用製品其包 括上述醫用膠帶和藥劑。 15 根據本發明的某些實施例,本發明的醫用膠帶及由其 製得的製品比起傳統的膠帶和製品來說更具有彈性,爲皮 • 冑提供一種更舒適的貼合感覺,而且適用於f曲的關節和 任何活動部位;背襯防水性強,可以完全阻止外來水分的 浸入,且可以減少内在液體的滲出對於短期阻隔尤爲有 20 效。 【實施方式】 下面結合附圊和實施例對本發明進行更詳細的描述。 需要指出,這些描述和實施例都是爲了使本發明便於理 4 5 ❿ 10 15 20 ,可包括敷料、膏 201016199 解,而非對本發明的限制。 所有的份數、百分比、比 ’除非特別指明, G例等含1都以重量爲某準。 本發明提供了-種醫用膠帶,其包括:-(〇 3金屬聚丙烯共聚物不織布背襯以及 本發明H在所述背襯的至少—面上的w㈣敏膠。 和藥劑。 醫用製…其包括上述醫用膠帶 本發明中使用的術語「製品」例如 貼和創可貼等。 根據某些實施例,本發明的膠帶中採用的茂金屬聚丙 烯共聚物不織布背襯具有如下特性:克重爲2(μ⑼g/m2;厚 度爲0.05-0.4 mm ;其縱向和橫向彈性回復率達⑽以上; 不織布的靜水壓值不低於25cm水柱。 本發明中’術語「茂金屬聚丙稀共聚物」是指採用茂 金屬催化劑進行婦烴聚合得到的聚㈣與至少—種其他α -稀烴的共聚物。本發明中’適用於與丙稀共聚的α稀煙包 括但不限於:乙稀、丁稀、戊烯、己烯、庚烯、辛稀、壬 烯、癸烯、十-烯、與十二烯。根據某些實施例,適用於 本發明的茂金屬聚丙烯共聚物的平均分子量爲 150000-250000,分子量分佈5,熔體流動速率爲 〇.5-35g/10min,結晶度爲 3-30%,拉伸強度爲 15 2 27 6 Μρ&, 伸長率爲100-1500% ’彈性回復率爲8〇_97% , 爲_2〇至 •30°C,T„^40-160°C。根據某些較佳的實施例,適用於本 5 201016199 發明的茂金屬聚丙稀共聚物中丙烯單元的莫耳(m〇le)份數 不低於65%,更佳為不低於70%。 5 ❹ 10 15 20 對於茂金屬催化的聚烯烴不織布,聚丙烯材料比起聚 乙烯材料具有以下幾方面的優點:(丨)具有更好的抗張強度 和耐磨性;(2)出現分層的概率大大降低;(3)加工視窗(溫度 範圍)寬。 烯烴聚合用茂金屬催化劑通常是由茂金屬化合物作爲 主催化劑和一個路易斯酸作爲助催化劑所組成的催化體 系。茂金屬化合物是指過渡金屬原子以茂環配位元形成的 有機金屬配位元化合物。因結構特殊,茂金屬作爲聚烯烴 催化劑時,具有使共聚單體分佈均勻,準確控制聚烯烴微 觀立體化學結構以及能製得結晶度較低的共聚物等優點。 利用茂金屬催化劑的這些特點可以製得彈性良好的聚烯烴 彈性體。茂金屬聚烯烴彈性體擁有價格低、彈性高、與其 他材料相容好等特性。 製備聚丙烯彈性體所用的茂金屬催化劑催化體系有橋 聯茂金屬催化體系、非橋茂金屬催化體系、單茂金屬催化 體系和茂金屬/硼化物催化體系等。例如,Exx〇nM〇bil公司 推出的Vistamaxx系列的特種丙烯一乙烯共聚物彈性體,其 申丙烯的莫耳份數可占65%以上,其較佳用於本發明的某些 實施例。關於茂金屬聚丙烯共聚物彈性體,例如,還可參 見美國專利US6476172 B1。US6476172 B1彼露了用茂金屬 催化的等規丙蝉和α-烯烴無規共聚物組成的彈性纖維及其 6 201016199 工藝,其全部内容並入本文作爲參考。關於茂金屬聚丙烯 共聚物彈性體,例如,還可參見:201016199 VI. Description of the invention: [Technical field to which the invention belongs] 5 10 15 ❹ 20 This is a medical tape and medical products made thereof, especially a non-woven fabric as a backing material. Medical tapes and medical articles made therefrom, such as medical enamels, plasters, and band-aids. [Prior Art] In the field of health care and personal care, non-woven tapes are widely used as raw materials for non-woven tapes, including rayon, polyester, rayon, due to their superiority, low price, and convenient addition. Polyacetate mixed with β and polypropylene. For example, the patent case discloses a medical breathable tape, 2 includes a wrap-around cylinder, the non-woven surface is a medical primer, and the other side of the non-woven fabric is a binder. There is a medical primer between the adhesive and the non-woven fabric. The adhesive is made of medical grade acrylic pressure sensitive adhesive, and the non-woven fabric is made of conventional Ziegler-Natta polypropylene non-woven fabric. However, the tape made of the above raw materials has the following two common disadvantages: (1) lack of elasticity, not suitable for use in joints such as joints; (2) poor barrier to liquid, and thus cannot prevent the influence of external liquid on the application site. Or the infiltration of the internal drug solution. To this end, there have been some inventions that seek to solve some of the above problems. For example, European Patent EP 1097185 describes a metallocene-catalyzed polyethylene (copolymer of ethylene and alpha-diuretic hydrocarbon) non-woven fabrics which can be used as a backing material for dressings, plasters and tapes. However, in general, polyethylene particles have high crystallinity and are difficult to process, and in particular, metallocene polyethylene cannot be produced by a spunbond method. Even a small number of commercially available polyethylene nonwoven fabrics made by flashing are too tough and inelastic, making them difficult to stretch. Therefore, there is a need to develop a medical tape which is easy to process, has good elasticity and liquid barrier properties, and a medical article made thereof, such as a non-woven cloth tape. SUMMARY OF THE INVENTION φ An object of the present invention is to provide a medical tape which is easy to process, has good elasticity and liquid barrier properties. 10 As an aspect of the invention, there is provided a medical tape comprising: (1) a metallocene polypropylene copolymer non-woven backing; and (2) a medical pressure applied to at least one side of the backing Min Sheng. As another aspect of the present invention, there is provided a medical article comprising the above medical tape and medicament. According to certain embodiments of the present invention, the medical tape of the present invention and articles made therefrom are more flexible than conventional tapes and articles, providing a more comfortable fit for the skin and Applicable to f-joint joints and any active parts; the backing is highly waterproof, can completely prevent the infiltration of external moisture, and can reduce the leakage of internal liquids, especially for short-term barriers. [Embodiment] The present invention will be described in more detail below with reference to the accompanying drawings and examples. It should be noted that these descriptions and examples are intended to facilitate the invention and may include a dressing, paste 201016199 solution, and are not limiting of the invention. All parts, percentages, ratios ‘ Unless otherwise specified, G, etc., all contain 1 by weight. The present invention provides a medical tape comprising: - (〇3 metal polypropylene copolymer nonwoven backing and w (four) sensitive glue of the invention H on at least the face of the backing. and a medicament. The above-mentioned medical tape includes the term "article" as used in the present invention such as a sticker and a band-aid, etc. According to some embodiments, the metallocene polypropylene copolymer nonwoven fabric backing used in the tape of the present invention has the following characteristics: It is 2 (μ(9) g/m2; thickness is 0.05-0.4 mm; its longitudinal and transverse elastic recovery rate is above (10); the hydrostatic pressure value of non-woven fabric is not less than 25 cm water column. In the present invention, the term 'metallocene polypropylene copolymer' It refers to a copolymer of poly(tetra) obtained by polymerization of a mother metal with a metallocene catalyst and at least one other α-dilute hydrocarbon. In the present invention, the alpha-smoke which is suitable for copolymerization with propylene includes but is not limited to: ethylene, butyl Dilute, pentene, hexene, heptene, octene, decene, decene, decaene, and dodecene. According to certain embodiments, the average molecular weight of the metallocene polypropylene copolymer suitable for use in the present invention is 150000-250000, molecular weight 5, the melt flow rate is 〇.5-35g/10min, crystallinity is 3-30%, tensile strength is 15 2 27 6 Μρ &, elongation is 100-1500% 'elastic recovery rate is 8〇_97 %, from _2 〇 to 30 ° C, T „40-160 ° C. According to certain preferred embodiments, the mer units of propylene units in the metallocene polypropylene copolymer of the invention of 2010 5 199 ( The number of parts is not less than 65%, more preferably not less than 70%. 5 ❹ 10 15 20 For metallocene-catalyzed polyolefin nonwovens, polypropylene materials have the following advantages over polyethylene materials: (丨) has better tensile strength and wear resistance; (2) the probability of delamination is greatly reduced; (3) processing window (temperature range) is wide. Metallocene catalysts for olefin polymerization are usually made of metallocene compounds. a catalytic system composed of a main catalyst and a Lewis acid as a cocatalyst. The metallocene compound refers to an organometallic coordination compound formed by a transition metal atom as a ring-ring coordination element. When the metallocene is used as a polyolefin catalyst due to a special structure, Has a uniform distribution of comonomers and accurate control The advantages of the microscopic stereochemical structure of olefins and the ability to obtain copolymers with low crystallinity. These characteristics of metallocene catalysts can be used to obtain polyolefin elastomers with good elasticity. Metallocene polyolefin elastomers have low price and high elasticity. It is compatible with other materials. The catalytic system of metallocene catalyst used in the preparation of polypropylene elastomers includes bridged metallocene catalyst system, non-bridged metal catalyst system, single metallocene catalyst system and metallocene/boride catalyst system. For example, the Vistamaxx series of specialty propylene-ethylene copolymer elastomers from Exx〇nM〇bil, which can account for more than 65% of the propylene, are preferred for use in certain embodiments of the present invention. For metallocene polypropylene copolymer elastomers, see, for example, U.S. Patent 6,472,172 B1. U.S. Patent 6,476,172 B1 discloses elastomeric fibers composed of metallocene-catalyzed isotactic propylene and alpha-olefin random copolymers and their processes. For metallocene polypropylene copolymer elastomers, for example, see also:

ChienJ等(Polymer Chemsitry,1991,28(1 1): 1603-1607) 用 rac-anti-Et(Me4C5)(Ind)TiCl2, 5 rac-anti-Et(Me4C5)(Ind)TiCl2 / rac-syn-Et (Me4C5)(Ind)TiCl2 等莫耳混合物和rac-anti-Et (Me4C5) (Ind) TiMe2非對稱橋聯 茂金屬催化劑合成出具有結晶-無定形立體多嵌段結構的 熱塑性PP彈性體; 攀 Gauthier W J 等(Macromolecules,1995, 28(11): 10 3779-3786)用 Me2C (Cp)(Ind)TiCl2, Me2C (Cp)(Ind)ZrCl2,ChienJ et al. (Polymer Chemsitry, 1991, 28(1 1): 1603-1607) using rac-anti-Et(Me4C5)(Ind)TiCl2, 5 rac-anti-Et(Me4C5)(Ind)TiCl2 / rac-syn- a thermoplastic PP elastomer having a crystalline-amorphous stereo multi-block structure is synthesized by a molar mixture of Et (Me4C5)(Ind)TiCl2 and a rac-anti-Et (Me4C5) (Ind) TiMe2 asymmetric bridged metallocene catalyst; Climbing Gauthier WJ et al. (Macromolecules, 1995, 28(11): 10 3779-3786) using Me2C (Cp)(Ind)TiCl2, Me2C (Cp)(Ind)ZrCl2,

Me2C (Cp)(Ind)HfCl2, Me2Si(Cp)(Ind)ZrCl2 和 Me2Si (Cp)(Ind)HfCl2茂金屬催化劑合成PP彈性體,其中Cp爲茂 基;Synthesis of PP elastomer by Me2C (Cp)(Ind)HfCl2, Me2Si(Cp)(Ind)ZrCl2 and Me2Si(Cp)(Ind)HfCl2 metallocene catalyst, wherein Cp is a metallocene;

Resconi L 等(Chemical Reviews, 2000, 100(4): 15 1253-1345)用 Me2Si(Flu)2 ZrCl2Me2Si(Flu)2ZrMe2C2v對稱無 掌性橋聯茂金屬催化劑合成出平均相對分子質量(Mw)高達 φ 10萬〜40萬、彈性和光學性能良好的完全非晶型PP彈性體;Resconi L et al. (Chemical Reviews, 2000, 100(4): 15 1253-1345) synthesized Me2Si(Flu)2 ZrCl2Me2Si(Flu)2ZrMe2C2v symmetric palm-free bridged metallocene catalyst to synthesize average molecular weight (Mw) up to φ 100,000 to 400,000 fully amorphous PP elastomers with good elasticity and optical properties;

Coates G(Chemical Reivews, 2000, 100(4): 1223-1252) 用(2-PhInd)2ZrCl2, (2-PhInd)2HfCl2,(2-PhInd)2Zr(CH2Ph)2 20 和(2-PhInd)2Hf(CH2Ph)2無橋振動茂金屬催化劑合成出PP 彈性體;Coates G (Chemical Reivews, 2000, 100(4): 1223-1252) using (2-PhInd)2ZrCl2, (2-PhInd)2HfCl2, (2-PhInd)2Zr(CH2Ph)2 20 and (2-PhInd)2Hf (CH2Ph)2 bridgeless viscoal metallocene catalyst to synthesize PP elastomer;

Collete J W 等(Macromolecules, 1989, 22(10): 385 1-3858)採用以三氧化二鋁爲載體的MR4茂金屬催化劑 合成出PP彈性體,Μ爲鈦、錯或铪;R爲CH2Ph,Me3CH2或 PhCMe2CH2 ; 7 25 201016199Collete JW et al. (Macromolecules, 1989, 22(10): 385 1-3858) synthesized PP elastomers using an MR4 metallocene catalyst supported on alumina, which is titanium, erbium or yttrium; R is CH2Ph, Me3CH2 Or PhCMe2CH2; 7 25 201016199

Tullock C W 等(Journal of Polymer Science. Part A.Tullock C W et al (Journal of Polymer Science. Part A.

Polymer Chemistry, 1989,27(9): 3063-3081)採用以三氧化 二鋁爲載體的MAr2 [如Ti(C6H5CH3)2]茂金屬催化劑合成出 立體多嵌段PP彈性體。 5 採用已知的不織布生産技術可以容易地將“茂金屬聚 丙烯共聚物”製成不織布。 尤其適用於本發明的不織布,例如包括通過紡黏法生 産的Marnix彈性不織布(國橋實業有限公司,深圳市寶安 區觀瀾鎮觀光路國橋工業園)《Marnix是一種嶄新的不織 10 布産品’採用纺黏工藝,以ExxonMobil Chemical公司生産 的特種彈性體Vistamaxx (—種茂金屬丙稀一乙浠共聚物) 爲主要原料製得的。它結合了不織布與彈性布的優點,手 感柔軟,富有彈性,其伸長率可達200-500%,彈性回復率 可達90%以上。Vistamaxx的分子量爲150000-250000,分子 15 量分佈$2.5,熔體流動速率爲0.5-35 g/10min,結晶度爲3-30 %,拉伸強度爲15.2-27.6 MPa,伸長率爲100-1500%,彈性 回復率爲 80-97%,Tg 爲-20 至-30°C,1\„爲 40-160。〇。 Vistamaxx中丙烯的莫耳份數占65%以上。其靜水壓值可以 高達25-70cm,視不織布的具體厚度而有所不同。一般,不 20 織布越厚,靜水壓值越高。 根據某些實施例,本發明的膠帶中採用的醫用壓敏膠 爲丙烯酸酯或者橡膠基壓敏膠。根據某些實施例,塗布的 幹膠厚度爲10-100g/m2。 8 201016199 根據某些實施例,適用於本發明的壓敏膠的黏合力符 合如下要求:當採用25微米厚的PET薄膜作爲背襯測試其對 鋼板的黏合力a夺,該壓敏#的黏合力應大於〇谓腿。這是 5 10 15 因爲^發明中採用的不織布具有防水性且隨著不織布克 重升高即厚度增加,防水性越強。因此,踢黏劑需要大於 〇.lN/mm的最低鋼板剝離力才能和不織布表面很好地複合 製得膠帶。另外,在同樣塗佈克重的前提下,在不織布表 面複合從容易到困難的程度依次排序爲··溶劑型合成橡勝 膠黏劑 > 溶劑型丙烯酸酯膠黏劑 > 水性丙烯酸酯膠黏劑。 根據某些實施例,茂金屬聚丙烯不織布在使用前可以 «面處理以改變織物的表面性能,例如改善满濕性以提 高與黏合劑的介面結合性能。已知的表面處理方法都可用 於本發明。例子包括但不限於電暈處理、等離子處理和火 焰處理等。 本發明可通過以下工藝實施: 將壓敏膝水塗佈在離型紙上’放入烘箱中烘乾,再與 不織布背襯I確壓㈣助下複合,㈣膠層至不織布上。 本發明除了生産膠帶外,還可用於生産敷料、膏貼和 創可貼等産品。但是應當理解,本發明也可用於工業上需 要使用彈性防水膝帶的場合,如作爲工業膠帶應用於通信 電子領域等。 ^ 本發明首次採用茂金屬聚丙烯共聚物不織布作爲膠帶 背襯,配合醫用級壓敏膠,製得的醫用膠帶及由該基材製 得的醫用製品同時具有彈性、防水性和觸感舒適的優點, 20 201016199 且工藝過程簡單,更貼合人體皮膚,適用範圍更廣泛。根 據本發明的醫用製品,例如膠帶施用於活動關節時,與作 用部位可完全貼合而不緊繃,並且藥液不會穿透膠帶並污 染客戶的貼身衣物。此外,患者可以正常沖水洗澡而不會 5 影響膏貼上藥物的作用。 實施例 測試方法:Polymer Chemistry, 1989, 27(9): 3063-3081) A stereomultiblock PP elastomer was synthesized using a MAr2 [e.g., Ti(C6H5CH3)2] metallocene catalyst supported on alumina. 5 The "metallocene polypropylene copolymer" can be easily made into a nonwoven fabric by a known nonwoven fabric production technique. It is especially suitable for the non-woven fabric of the present invention, for example, Marnix elastic non-woven fabric produced by the spunbonding method (National Bridge Industrial Co., Ltd., Guoqiao Industrial Park, Guanlan Town, Bao'an District, Shenzhen) "Marnix is a brand new non-woven 10 cloth product. 'Using a spunbond process, the special elastomer Vistamaxx (-metallocene propylene-acetonitrile copolymer) produced by ExxonMobil Chemical Co., Ltd. was used as the main raw material. It combines the advantages of non-woven fabric and elastic cloth. It is soft and elastic, with an elongation of 200-500% and an elastic recovery rate of over 90%. Vistamaxx has a molecular weight of 150,000 to 250,000, a molecular weight distribution of $2.5, a melt flow rate of 0.5-35 g/10 min, a crystallinity of 3-30%, a tensile strength of 15.2-27.6 MPa, and an elongation of 100-1500%. The elastic recovery rate is 80-97%, the Tg is -20 to -30 °C, and the 1\„ is 40-160. Vista. The molar content of propylene in Vistamaxx accounts for more than 65%. The hydrostatic pressure can be as high as 25-70cm, depending on the specific thickness of the non-woven fabric. Generally, the thicker the 20-woven fabric, the higher the hydrostatic pressure value. According to some embodiments, the medical pressure-sensitive adhesive used in the adhesive tape of the present invention is acrylic. Ester or rubber based pressure sensitive adhesive. According to certain embodiments, the coated dry glue has a thickness of from 10 to 100 g/m 2. 8 201016199 According to certain embodiments, the adhesive force of the pressure sensitive adhesive suitable for use in the present invention meets the following requirements: Using a 25 micron thick PET film as a backing to test its adhesion to the steel plate, the pressure of the pressure sensitive # should be greater than that of the 〇. This is 5 10 15 because the non-woven fabric used in the invention is waterproof and The weight of the non-woven fabric is increased, that is, the thickness is increased, and the waterproofness is stronger. Therefore, the kicking agent needs to be larger than The minimum steel plate peeling force of .lN/mm can be well combined with the non-woven fabric surface to make the tape. In addition, under the premise of the same coating weight, the surface of the non-woven fabric is sorted from easy to difficult to solvent type. Synthetic Rubber Adhesives > Solvent-Based Acrylate Adhesives> Waterborne Acrylate Adhesives According to certain embodiments, metallocene polypropylene nonwovens can be surface treated to modify the surface properties of the fabric prior to use, for example The wettability is improved to improve the interface bonding property with the adhesive. Known surface treatment methods can be used in the present invention. Examples include, but are not limited to, corona treatment, plasma treatment, flame treatment, etc. The present invention can be carried out by the following processes: The pressure sensitive knee water is coated on the release paper, dried in an oven, and then combined with the non-woven fabric backing I (4) to assist the composite, (4) the rubber layer to the non-woven fabric. The invention can be used for production in addition to the production of tape. Products such as dressings, plasters and band-aids. However, it should be understood that the present invention can also be used in industrial applications where elastic waterproof knee straps are required, such as industrial tapes. It is used in the field of communication electronics, etc. ^ This invention is the first to use metallocene polypropylene copolymer non-woven fabric as a tape backing, with medical grade pressure sensitive adhesive, medical tape obtained and medical products made from the same. It has the advantages of elasticity, water resistance and comfortable touch, 20 201016199 and the process is simple, more suitable for human skin, and the scope of application is wider. The medical article according to the invention, for example, when the tape is applied to the movable joint, the action site can be It fits completely without tightening, and the liquid does not penetrate the tape and contaminate the customer's close-fitting clothing. In addition, the patient can wash the bath normally without affecting the effect of the drug on the plaster. Example Test method:

A 彈性回復率測試方法 10 遵循FZ/T 700〇6-2004標準。使用萬能電子拉力機 (Instron5569,英斯特朗公司,上海市南京西路819號中創大 廈1708室)。操作如下:(1)固定一條2 54cmxl〇cm的樣品在 Instron的爽具上;(2)施加in的力在樣品上,記錄此時的樣 品長度L〇 ; (3)開動lnstron拉伸樣品到固定的伸長量(在本發 15明中是20%伸長量),停留1分鐘,並記錄此時的樣品長度 L01 ; (4)撤去拉力,讓樣品回復到自然狀態’停留3分鐘; Φ (5)再施加1N拉力於樣品上,記錄此時的樣品長度L〇’。 測得的彈性回復率=(L〇丨-L〇’)/( L〇丨-L0)xl〇〇〇/0 20 靜水壓測試方法 遵循IS〇811:1981 1標準。使用YG825型織物靜水壓測 試儀(寧波纺織儀器廠,寧波市鄞州區高橋鎮高峰村三村路 75號水壓上升的速率爲60cm/min,且水溫爲20°C(標準大 氣壓)。操作如下:(1)截取大於l〇crnX l〇cm面積的樣品,在 25 測試儀上按要求夾緊(對於膠帶是膠面朝下夾緊);(2)選定 201016199 6〇cm/min的水壓上升速率;(3)按開始鍵水壓開始穩定升 南’記錄不織布表面開始冒第三滴水珠或出現第三處滲水 時的壓力’即爲靜水壓。 5 實施例1 :膠帶 塗佈幹膠克重爲30.0g/m2的ps_57E水性丙稀酸醋谬黏 劑(西安天韻實業有限公司,西安市高新區楓葉新都市 A1020 507至)於克重爲12〇g/m2的單面離型紙(寶燕工業科 技有限公司,上海市松江區新廟三路1222號)上放入洪箱 10中烘乾,並在碾壓輥的作用下與克重爲2〇g/m2且厚度爲 60μΐη的Marnix彈性不織布(國橋實業有限公司,深圳市寶安 區觀湖鎮觀光路國橋工業園)複合,轉移膠層至不織布上。 所得不織布膠帶對鋼板的剝離力爲G3un/_,靜水壓爲 31.2cm,縱向和橫向的彈性回復率分別爲”…❶/❶和 15 92.38%。製得的膠帶如圖1所示。此移帶包括兩層結構’從 上到下依次是:1是茂金屬聚丙烯共聚物不織布層,2是醫 ❹ 肖壓敏膠層°所得膠帶應用於肘關節或膝關節時,具有报 好的順應性和舒適性,不翹邊,且不會影響關節部位的正 常活動,沒有普通不織布膠帶的緊繃感。此膠帶可連續正 20常貼合7天以上時間,且在使用過程中可進行日常淋浴(每 次約30分鐘)。 實施例2 :膠帶 塗佈幹膠克重爲3〇.〇g/m2的PS-58E水性丙烯酸酯膠黏 25劑(西安天韻實業有限公司,西安市高新區楓葉新都市 201016199 A1020 507室)於克重爲120g/m2的單面離型紙(寶燕工業科 技有限公司,上海市松江區新廟三路1222號)上,放入烘箱 中烘乾,並在碾壓輥的作用下與克重爲40g/m2且厚度爲 117μηι的Marnix彈性不織布(國橋實業有限公司,深圳市寶 5 安區觀瀾鎮觀光路國橋工業園)複合,轉移膠層至不織布 上。所得不織布膠帶對鋼板的剝離力爲0.462N/mm,靜水壓 爲38.0cm,縱向和橫向的彈性回復率分別爲94.13%和 91.68%。 ❹ 10 實施例3 :膠帶 塗佈幹膠克重爲43.8g/m2的丙烯酸酯膠黏劑(根據 RE24960 (Ulrich)製備的95.5/4.5(重量比)的丙烯酸異辛酯 一丙烯酸共聚物黏合劑)於克重爲120g/m2的單面離型紙(寶 燕工業科技有限公司,上海市松江區新廟三路1222號)上, 15 放入烘箱中烘乾,並在碾壓輥的作用下與克重爲60g/m2且 厚度爲180μιη的Marnix彈性不織布(國橋實業有限公司,深 φ 圳市寶安區觀瀾鎮觀光路國橋工業園)複合,轉移膠層至不 織布上。所得不織布膠帶對鋼板的剝離力爲〇.240N/mm, 靜水壓爲57.0cm,縱向和橫向的彈性回復率分別爲93.55% 20 和 90.82%。 實施例4 :膠帶 塗佈幹膠克重爲38.4g/m2的合成橡膠膠黏劑(含約25% Kraton 1117 (Kraton LLC, Houston,Texas)聚苯乙稀-異戊二 25 烯-苯乙烯共聚物,約25%芳香族改性的C5樹脂增黏劑,約 12 201016199 5 φ 10 15 20 49%甲苯/庚烷混合溶劑和約0.1%抗氧劑)於克重爲120g/m2 的單面離型紙(寶燕工業科技有限公司,上海市松江區新 廟三路1222號)上,放入烘箱中烘乾,並在碾壓輥的作用 下與克重爲80g/m2且厚度爲245μπι的Marnix彈性不織布 (國橋實業有限公司,深圳市寶安區觀瀾鎮觀光路國橋工 業園)複合,轉移膠層至不織布上。所得不織布膠帶對鋼 板的剝離力爲1.14lN/mm,靜水壓爲64.5cm,縱向和橫向的 彈性回復率分別爲93.00%和88.02%。 實施例5 :膠帶 塗佈幹膠克重爲49.8g/m2的合成橡膠膠黏劑(含約25% Kraton 1117 (Kraton LLC,Houston, Texas)聚苯乙稀-異戊二 烯-苯乙烯共聚物,約25%芳香族改性的C5樹脂增黏劑,約 49%甲苯/庚烷混合溶劑和約0.1%抗氧劑))))))))於克重爲 120g/m2的單面離型紙(寶燕工業科技有限公司,上海市松江 區新廟三路1222號)上,放入烘箱中烘乾,並在碾壓輥的作 用下與克重爲l〇〇g/m2且厚度爲308μιη的Marnix彈性不織布 (國橋實業有限公司,深圳市寶安區觀瀾鎮觀光路國橋工業 園)複合,轉移膠層至不織布上。所得不織布膠帶對鋼板的 剝離力爲1.481 N/mm,靜水壓爲68.9cm,縱向和橫向的彈性 回復率分別爲91.00%和87.67%。 實施例6 :基於膠帶的敷料 本實施例中採用的材料如下: 13 201016199 邊框紙(克重爲125g/m2,耐恒紙業有限公司,廣州經 濟開發區東區北片蓮潭路7號); 彈性不織布、膠黏劑,棉墊(惠龍衛生材料有限公司, 上海市浦東新區唐鎮鎮新虹村);和 5 離型紙(克重爲1 〇〇g/m2 ’寶燕工業科技有限公司,上 海市松江區新廟三路1222號)。 用彈性防水不織布膠帶製得的敷料如圖2所示(左:截 φ 面圖,右:正視圖)。此敷料結構包括以下五層結構,從 上到下依次爲:3爲邊框紙層(包括切線8) ,4爲4〇g/m2彈 10性不織布層,5爲30g/m2 PS-57E水性丙烯酸酯膠黏劑層,6 爲棉墊層,7爲l〇〇g/m2單面離型紙層。 工藝工程如下:(1)塗佈製得不織布膠帶;(2)將其放置 在模切機的放卷輥上;(3)以4m/min的速率,將模切好形狀 的邊框紙和不織布表面在2〇〇〇c的熱報作用下熱複合在一 15 起’並剝離原有離型紙;(4)在膠面上添加棉墊,並附上産 品離型紙;(5)成品模切成最終形狀。 ® 所得敷料的邊框紙離型力爲3.2g/mm,膠面離型力爲 1.2g/mm,膠面對鋼板的剝離力爲〇.372N/mm。 20 實施例7:基於膠帶的奮貼 本實施例中採用的材料如下: 彈性不織布、膠黏劑、棉墊(惠龍衛生材料有限公司, 上海市浦東新區唐鎮鎮新虹村);和 離型紙(克重爲130g/m2,寶燕工業科技有限公司,上 25 海市松江區新廟三路1222號)。 201016199 用彈性防水不織布膠帶製得的膏貼如圖3所示(左:戴 面圖,右·正視圖)。 此膏貼結構包括以下四層,從上到下依次爲:9爲 80g/m2彈性不織布層,1〇爲30g/m2 AK2247合成橡膠膠黏 5 劑’ 6爲棉墊層,11爲130g/m2單面離型紙層。 工藝工程如下:(1)塗佈製得不織布膠帶;(2)將其放置 在模切機的放卷輥上;(3)剝離原有離型紙;(4)在膠面上添 加棉墊,並附上産品離型紙;(5)成品模切成最終形狀。 所得膏貼的離型力爲〇.7g/mm,膠面對鋼板的剝離力爲 10 1.1 ΙΟΝ/mm。 實施例8 :基於膠帶的創可貼 本實施例中採用的材料如下: 邊框紙(克重爲125g/m2,耐恒紙業有限公司,廣州經 15 濟開發區東區北片蓮潭路7號); 彈性不織布、膠黏劑、棉墊(惠龍衛生材料有限公司, 〇 上海市浦東新區唐鎮鎮新虹村);和 離型紙(克重爲100g/m2’寶燕工業科技有限公司,上 海市松江區新廟三路1222號)。 20 用彈性防水不織布膠帶製得的創可貼如圖4所示(左: 截面圖;右:正視圖)。此創可貼結構包括以下五層,從 上到下依次爲:3爲邊框紙層(包括切線8) ,4爲4〇§/1112彈 性不織布層,5爲30g/m2 PS-57E水性丙烯酸酯膠黏劑層,6 爲棉墊層’ 7爲l〇〇g/m2單面離型紙層。工藝工程如下:⑴ 25塗佈製得不織布膠帶;(2)將其放置在模切機的放卷輥上; 15 201016199 (3) 以4m/mm的速率,將模切好形狀的邊框紙和不織布表面 在200°C的熱輥作用下熱複合在一起,並剝離原有離型紙; (4) 在膠面上添加棉墊,並附上産品離型紙;(5)成品模切成 最終形狀。 5 ❹ 10 15 所得創可貼的邊框紙離型力爲3 .〇g/mm,膠面離型力爲 l.lg/mm,膠面對鋼板的剝離力爲〇3〇1N/mm。 【圖式簡單說明】 圖1係根據本發明一實施例的不織布單面膠帶的示意 圖。 、 圖2係根據本發明一實施例的不織布膠帶用作敷料的 示意圖(左:截面圖;右:正視圖)。 圖3係彈性防水不織布膠帶用作膏貼的示意圖(左:截 面圖;右:正視圖)。 圖4係彈性防水不織布用作創可貼的示意圖(左:截面 圖;右:正視圖)。 【主要元件符號說明】 1茂金屬聚丙烯共聚物不織布層 2 醫用壓敏膠層 3邊框紙層(包括切線8) 4 40g/m2彈性不織布層 5 30g/m2 PS-57E水性丙烯酸酯膠黏劑層 6 棉墊層 20 201016199A Elastic recovery rate test method 10 Follow the FZ/T 700〇6-2004 standard. Use universal electric pull machine (Instron 5569, Instron Company, Room 1708, Zhongchuang Building, No. 819 Nanjing West Road, Shanghai). The operation is as follows: (1) Fix a sample of 2 54cmxl〇cm on the Instron's coolness; (2) Apply the force of in on the sample, record the length of the sample at this time; (3) Start the lnstron to stretch the sample to The fixed elongation (20% elongation in the hairpin 15), stayed for 1 minute, and recorded the sample length L01 at this time; (4) Remove the pulling force and let the sample return to the natural state 'stay for 3 minutes; Φ ( 5) Apply a 1N pull force to the sample and record the sample length L〇' at this time. Measured elastic recovery rate = (L 〇丨 - L 〇 ') / ( L 〇丨 - L0) x l 〇〇〇 / 0 20 Hydrostatic pressure test method Follow IS 〇 811: 1981 1 standard. Use YG825 fabric hydrostatic pressure tester (Ningbo Textile Instrument Factory, No. 75, Sancun Road, Gaoqiao Town, Yinqiao District, Ningbo City, the water pressure rise rate is 60cm/min, and the water temperature is 20 °C (standard atmospheric pressure). As follows: (1) Cut a sample larger than l〇crnX l〇cm area, clamp it on the 25 tester as required (for the tape, the rubber surface is clamped downward); (2) Select 201016199 6〇cm/min water. (3) Press the start button water pressure to start stable and rise south 'record the non-woven surface to start the third drop of water or the pressure at the third place sees water' is the hydrostatic pressure. 5 Example 1: Tape coating ps_57E water-based acrylic acid vinegar adhesive with a dry weight of 30.0g/m2 (Xi'an Tianyun Industrial Co., Ltd., A1020 507, Maple New City, Xi'an High-tech Zone), with a single surface of 12〇g/m2 Release paper (Baoyan Industrial Technology Co., Ltd., No. 1222, Xinmiao 3rd Road, Songjiang District, Shanghai) is placed in the box 10 for drying, and under the action of the roller, the weight is 2〇g/m2 and the thickness is Marnix elastic non-woven fabric of 60μΐη (Guoqiao Industrial Co., Ltd., Bao’an District, Shenzhen The town sightseeing road Guoqiao Industrial Park) composites and transfers the rubber layer to the non-woven fabric. The peeling force of the obtained non-woven tape on the steel plate is G3un/_, the hydrostatic pressure is 31.2cm, and the elastic recovery rates in the longitudinal and transverse directions are respectively... ❶ and 15 92.38%. The obtained tape is shown in Figure 1. This transfer belt consists of two layers of structure 'from top to bottom: 1 is a metallocene polypropylene copolymer non-woven layer, 2 is a medical ❹ 压 pressure sensitive adhesive When the tape obtained in the layer is applied to the elbow joint or the knee joint, it has good compliance and comfort, does not warp, and does not affect the normal movement of the joint part, and has no tight feeling of the ordinary non-woven tape. Positive 20 is often applied for more than 7 days, and daily shower can be carried out during use (about 30 minutes each time). Example 2: Tape coated dry glue weight is 3〇.〇g/m2 PS-58E Waterborne Acrylate Adhesive 25 Agent (Xi'an Tianyun Industrial Co., Ltd., Maple New City 201016199 A1020 Room 507, Xi'an High-tech Zone) Yuke Heavy 120g/m2 Single-sided Release Paper (Baoyan Industrial Technology Co., Ltd., Songjiang, Shanghai) District, Xinmiao 3rd Road, No. 1222) Drying in an oven, and under the action of roller compactor, Marnix elastic non-woven fabric with a weight of 40g/m2 and a thickness of 117μηι (Guoqiao Industrial Co., Ltd., Guobao Industrial Park, Guanlan Town, Shenzhen Bao 5 An District) The composite adhesive layer was transferred to the non-woven fabric. The peeling force of the obtained non-woven fabric tape on the steel sheet was 0.462 N/mm, the hydrostatic pressure was 38.0 cm, and the elastic recovery rates in the longitudinal and transverse directions were 94.13% and 91.68%, respectively. ❹ 10 Example 3 : Tape coated dry adhesive with an acrylate adhesive weight of 43.8 g/m 2 (95.5/4.5 (by weight) of isooctyl acrylate-acrylic acid copolymer binder prepared according to RE24960 (Ulrich)) 120g/m2 single-sided release paper (Baoyan Industrial Technology Co., Ltd., No. 1222, Xinmiao 3rd Road, Songjiang District, Shanghai), 15 is placed in an oven for drying, and the weight is 60g under the action of the roller Marmix elastic non-woven fabric with /m2 and thickness of 180μιη (Guoqiao Industrial Co., Ltd., deep φ Guoqiao Industrial Park, Guanlan Town, Guan'an Town, Bao'an District, Shenzhen) is compounded and transferred to non-woven fabric. The peeling force of the obtained non-woven tape on the steel sheet was 240240 N/mm, the hydrostatic pressure was 57.0 cm, and the elastic recovery rates in the longitudinal and transverse directions were 93.55% 20 and 90.82%, respectively. Example 4: Tape coated dry rubber with a weight of 38.4 g/m2 of synthetic rubber adhesive (containing about 25% Kraton 1117 (Kraton LLC, Houston, Texas) polystyrene-isoprene 25-styrene Copolymer, about 25% aromatic modified C5 resin tackifier, about 12 201016199 5 φ 10 15 20 49% toluene / heptane mixed solvent and about 0.1% antioxidant) in a weight of 120g / m2 Surface release paper (Baoyan Industrial Technology Co., Ltd., No. 1222, Xinmiao 3rd Road, Songjiang District, Shanghai), dried in an oven, and with a weight of 80g/m2 and a thickness of 245μπι under the action of a roller. The Marnix elastic non-woven fabric (Guoqiao Industrial Co., Ltd., Guoqiao Industrial Park, Guanlan Town, Guanlan Town, Bao'an District, Shenzhen) is compounded and transferred to the non-woven fabric. The obtained non-woven tape had a peeling force of 1.14 lN/mm for the steel plate, a hydrostatic pressure of 64.5 cm, and elastic recovery rates of longitudinal and transverse directions of 93.00% and 88.02%, respectively. Example 5: Tape coated dry rubber with a weight of 49.8 g/m2 of synthetic rubber adhesive (containing about 25% of Kraton 1117 (Kraton LLC, Houston, Texas) polystyrene-isoprene-styrene copolymerization , about 25% aromatic modified C5 resin tackifier, about 49% toluene / heptane mixed solvent and about 0.1% antioxidant))))))))) on a single side with a weight of 120g / m2 Release paper (Baoyan Industrial Technology Co., Ltd., No. 1222, Xinmiao 3rd Road, Songjiang District, Shanghai), put it in an oven for drying, and under the action of roller compactor, the weight is l〇〇g/m2 and the thickness The 308μιη Marnix elastic non-woven fabric (Guoqiao Industrial Co., Ltd., Guoqiao Industrial Park, Guanlan Town, Bao'an District, Shenzhen) is compounded and transferred to the non-woven fabric. The obtained non-woven tape had a peeling force of 1.481 N/mm for the steel sheet and a static water pressure of 68.9 cm, and the elastic recovery rates of the longitudinal and transverse directions were 91.00% and 87.67%, respectively. Example 6: Tape-based dressing The materials used in this example are as follows: 13 201016199 Border paper (gram weight is 125g/m2, Naiheng Paper Co., Ltd., No. 7 Liantan Road, North Section, Eastern District, Guangzhou Economic Development Zone); Elastic non-woven fabric, adhesive, cotton pad (Huilong Sanitary Materials Co., Ltd., Xinhong Village, Tangzhen Town, Pudong New Area, Shanghai); and 5 release paper (gram weight is 1 〇〇g/m2 'Baoyan Industrial Technology Co., Ltd. , No. 1222, Xinmiao 3rd Road, Songjiang District, Shanghai, China). The dressing made of elastic waterproof non-woven tape is shown in Figure 2 (left: cut φ face, right: front view). The dressing structure comprises the following five-layer structure, from top to bottom: 3 is the border paper layer (including the tangent 8), 4 is the 4〇g/m2 elastic 10 non-woven layer, and 5 is 30g/m2 PS-57E water-based acrylic. The ester adhesive layer, 6 is a cotton mat layer, and 7 is a l〇〇g/m2 single-sided release paper layer. The process engineering is as follows: (1) coating the non-woven tape; (2) placing it on the unwinding roll of the die-cutting machine; (3) cutting the shape of the border paper and non-woven fabric at a rate of 4 m/min The surface is thermally composited under a heat of 2〇〇〇c in a 15' and peeled off the original release paper; (4) a cotton pad is added on the rubber surface, and the product release paper is attached; (5) the finished die-cutting Into the final shape. ® The resulting dressing has a frame release force of 3.2g/mm, a rubber release force of 1.2g/mm, and a peeling force of the rubber facing the steel plate of 372.372N/mm. 20 Example 7: Tape-based stickers The materials used in this embodiment are as follows: elastic non-woven fabric, adhesive, cotton pad (Huilong Sanitary Materials Co., Ltd., Xinhong Village, Tangzhen Town, Pudong New Area, Shanghai); Type paper (gram weight is 130g/m2, Baoyan Industrial Technology Co., Ltd., No. 1222, Xinmiao 3rd Road, Songjiang District, Shanghai 25). 201016199 The paste made of elastic waterproof non-woven tape is shown in Figure 3 (left: wear side view, right front view). The paste structure comprises the following four layers, from top to bottom: 9 is 80g/m2 elastic non-woven layer, 1〇 is 30g/m2 AK2247 synthetic rubber adhesive 5 agent '6 is cotton pad, 11 is 130g/m2 Single-sided release paper layer. The process engineering is as follows: (1) coating the non-woven tape; (2) placing it on the unwinding roller of the die-cutting machine; (3) peeling off the original release paper; (4) adding a cotton pad on the rubber surface, And attach the product release paper; (5) the finished product is cut into the final shape. The release force of the obtained paste was 〇.7 g/mm, and the peeling force of the rubber facing the steel plate was 10 1.1 ΙΟΝ/mm. Example 8: Tape-based band-aid The materials used in this embodiment are as follows: Border paper (gram weight is 125g/m2, Naiheng Paper Co., Ltd., No. 7 Liantan Road, North Section, East District, Guangzhou Economic Development Zone, Guangzhou); Elastic non-woven fabric, adhesive, cotton pad (Huilong Sanitary Materials Co., Ltd., Xinhong Village, Tangzhen Town, Pudong New Area, Shanghai); and release paper (gram weight is 100g/m2' Baoyan Industrial Technology Co., Ltd., Shanghai No. 1222, Xinmiao 3rd Road, Songjiang District). 20 A band-aid made of elastic waterproof non-woven tape is shown in Figure 4 (left: cross-section; right: front view). The band-aid structure comprises the following five layers, from top to bottom: 3 is the border paper layer (including the tangent 8), 4 is the 4〇§/1112 elastic non-woven layer, and 5 is the 30g/m2 PS-57E water-based acrylate adhesive. The agent layer, 6 is a cotton mat layer '7 is a l〇〇g/m2 single-sided release paper layer. The process engineering is as follows: (1) 25 coating to obtain a non-woven tape; (2) placing it on the unwinding roller of the die-cutting machine; 15 201016199 (3) cutting the shape of the border paper at a rate of 4 m/mm The surface of the non-woven fabric is thermally compounded under the action of a hot roller at 200 ° C, and the original release paper is peeled off; (4) a cotton pad is added on the rubber surface, and a release paper is attached; (5) the finished product is cut into a final shape. . 5 ❹ 10 15 The band-aid force of the band-aid of the band-aid is 3. 〇g/mm, the release force of the rubber surface is l.lg/mm, and the peeling force of the rubber facing the steel plate is 〇3〇1N/mm. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view of a non-woven single-sided tape according to an embodiment of the present invention. Fig. 2 is a schematic view showing a nonwoven fabric tape used as a dressing according to an embodiment of the present invention (left: sectional view; right: front view). Fig. 3 is a schematic view showing the use of an elastic waterproof non-woven tape as a paste (left: cross-sectional view; right: front view). Figure 4 is a schematic view of a flexible waterproof non-woven fabric used as a band-aid (left: cross-sectional view; right: front view). [Main component symbol description] 1 metallocene polypropylene copolymer non-woven layer 2 medical pressure sensitive adhesive layer 3 border paper layer (including tangent 8) 4 40g/m2 elastic non-woven layer 5 30g/m2 PS-57E waterborne acrylate adhesive Agent layer 6 cotton pad layer 20 201016199

7 100g/m2單面離型紙層 9 80g/m2彈性不織布層 1 0 30g/m2 AK2247合成橡膠膠黏劑 1 1 130g/m2單面離型紙層 177 100g/m2 single-sided release paper layer 9 80g/m2 elastic non-woven fabric layer 1 0 30g/m2 AK2247 synthetic rubber adhesive 1 1 130g/m2 single-sided release paper layer 17

Claims (1)

201016199 七、申請專利範圍: 1. 一種醫用膠帶,其包括: (1) 茂金屬聚丙烯共聚物不織布背襯;以及 (2) 塗敷在所述背襯的至少一面上的醫用壓敏膠。 5 # 10 15 ❹ 2. 如申請專利範圍第1項所述之醫用膠帶,其中不織 布背襯具有如下特性:克重爲20-100g/m2 ;厚度爲0.05-0.4 mm,不織布的靜水壓值不低於25cm水柱。 3·如申請專利範圍第2項所述之醫用膠帶,其中不織 布背襯的縱向和橫向彈性回復率達85%以上。 4. 如申請專利範圍第1項所述之醫用膠帶,其中聚丙 烯的平均分子量爲150000-250000,分子量分佈$2.5,熔體 流動速率爲〇.5-35g/10min ’結晶度爲3-30%,拉伸強度爲 15·2·27.6 MPa,伸長率爲100-1500%,彈性回復率爲8〇_97 % ’ 1爲-20至-30°C,1\„爲40-160。(:。 5. 如申請專利範圍第1項所述之醫用膠帶,其中聚丙 稀中丙烯單元的莫耳份數爲65%以上。 6. 如申請專利範圍第1項所述之醫用膠帶,其中聚丙 稀不織布係通過紡黏法製備的不織布。 7. 如申請專利範圍第1項所述之醫用膠帶,其中聚丙 烯不織布經選自電暈處理、等離子處理、和火焰處理表面 處理方法處理。 8. —種醫用製品,其包括如申請專利範圍第1至7項中 任一項的醫用膠帶和藥劑。 20 201016199 9.如申請專利範圍第8項所述之製品,其中該製品爲 敷料、膏貼或創可貼形式。201016199 VII. Patent Application Range: 1. A medical tape comprising: (1) a metallocene polypropylene copolymer nonwoven backing; and (2) medical pressure sensitive applied to at least one side of the backing gum. 5 # 10 15 ❹ 2. The medical tape according to claim 1, wherein the non-woven backing has the following characteristics: a weight of 20-100 g/m2; a thickness of 0.05-0.4 mm; a hydrostatic pressure of the non-woven fabric The value is not less than 25 cm water column. 3. The medical tape of claim 2, wherein the non-woven backing has a longitudinal and lateral elastic recovery rate of more than 85%. 4. The medical tape according to claim 1, wherein the polypropylene has an average molecular weight of 150,000 to 250,000, a molecular weight distribution of 2.5, a melt flow rate of 5.5 to 35 g/10 min, and a crystallinity of 3 to 30. %, tensile strength is 15·2·27.6 MPa, elongation is 100-1500%, elastic recovery is 8〇_97% '1 is -20 to -30 °C, 1\„ is 40-160. 5. The medical tape of claim 1, wherein the propylene unit in the polypropylene has a molar fraction of 65% or more. 6. The medical tape according to claim 1 of the patent application, The non-woven fabric prepared by the spunbonding method, wherein the polypropylene non-woven fabric is treated by a corona treatment, a plasma treatment, and a flame treatment surface treatment method. 8. A medical article comprising a medical tape and a medicament according to any one of claims 1 to 7 wherein the article of claim 8 is the product of claim 8 wherein the article It is in the form of a dressing, plaster or band-aid. ❹ 19❹ 19
TW97140422A 2008-10-22 2008-10-22 Medical tape and medical products made therefrom TW201016199A (en)

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