TW201011064A - Reactively processed, high heat resistant composition of polypropylene and an olefinic interpolymer - Google Patents

Reactively processed, high heat resistant composition of polypropylene and an olefinic interpolymer Download PDF

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Publication number
TW201011064A
TW201011064A TW098117449A TW98117449A TW201011064A TW 201011064 A TW201011064 A TW 201011064A TW 098117449 A TW098117449 A TW 098117449A TW 98117449 A TW98117449 A TW 98117449A TW 201011064 A TW201011064 A TW 201011064A
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TW
Taiwan
Prior art keywords
polymer
propylene
composition
olefin
ethylene
Prior art date
Application number
TW098117449A
Other languages
Chinese (zh)
Inventor
Jeffrey M Cogen
Robert Gowell
Ronald Wevers
Maarten W Aarts
Original Assignee
Dow Global Technologies Inc
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Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of TW201011064A publication Critical patent/TW201011064A/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/246—Intercrosslinking of at least two polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/005—Modified block copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Inorganic Insulating Materials (AREA)
  • Insulated Conductors (AREA)

Abstract

A propylene polymer is coupled with an olefinic interpolymer by a process comprising contacting under reactive processing conditions at least: A. 10 wt% of at least one propylene polymer; B. 10 wt% of at least one olefinic interpolymer; C. 35 wt% of at least one metal hydrate; and D. A coupling amount of a coupling agent, each weight percent based on the combined weight of the propylene polymer, olefinic interpolymer and metal hydrate. Wire and cable insulation sheaths made from compositions comprising the coupled polymer exhibit desirable heat resistance.

Description

201011064 六、發明說明： 【發明所屬之技術々貝域；j 相關申請案的交互參考 本申請案主張2008年6月6曰提出申請之美國專利申 請案序號第61/059,356號的優先權，其全部内容併入此處 作為參考。 發明領域 本發明關於一種包括聚丙稀聚合物及稀煙互聚物的組 ® 成物。於一態樣中，本發明關於一種包括經過反應性加工 之聚丙烯及烯烴互聚物的組成物，其顯示適用於導線及纜 線包覆的抗高熱特性。於另一態樣中，本發明關於一種包 - 括絕緣層的電纜線，於又一態樣中，本發明關於一種電纜 . 線其中絕緣層包括含有經過反應性加工之聚丙烯及稀烴互 聚物的組成物。 【先前技術3 發明背景 • 聚合組成物經常被用作導線及纜線的基本絕緣材料。 作為一種絕緣物，該組成物應該展現各種物理及電氣性 質，諸如抗熱性’對抗機械切割’對抗應力碎裂及介電性 失效。用於電導體的絕緣材料常常需要交聯以達到所欲的 抗熱性。 交聯可藉由數種機制被引入聚合物的不同分子鏈之 間，其中一個機制係將化學反應性化合物接枝至構成巨大 聚合物的個別聚合物主鏈或鏈上，以這種方式使得在一主 201011064 鍵上的接枝化合物接著可與另一主鏈上的類似接枝化合物 反應，由此形成交聯。這個方法的例示為"矽烷交聯”的方 法。 石夕&交聯方法利用交聯聚合物分子的含矽烷化合物。 在成形或模製操作之前或是成形或模製操作期間，藉由使 用適合數量的有機過氧化物或其他自由基啟始劑，矽烷可 被接枝至適合的聚合物。其他成份諸如穩定劑、色素、填 充劑、催化劑、加工助劑及相似物也可被包括在混合物中。 當使用妙烷-過氧化物摻合物於聚合物交聯時，在接枝 鲁 效率及加工效率，諸如饋出速率與進行次數之間必須取得 妥協。因為需要嚴格控制加工過程，所以很難以這種方式 形成可交聯材料。例如，若此方法在太高的溫度下執行， 聚合物會在加工裝置(例如饋出器）中部分交聯，致使其後難 以獲得品質一致的良好產品。由於需要從加工設備移除部 分交聯產品之故，因此也會發生加工遲延。於後續加熱進 行交聯過程期間也要特別地小心，以確保由聚合物製備的 物件依然保留其等的形狀。 ® 更且’當使用高度反應性矽烷·過氧化物摻合物時，會 發生膠狀物形成、螺紋產生及焦化現象。對於利用加工條 件及加工設備以在嚴格的熔化及混合狀況下於聚烯烴中產 生高剪應力的加工過程而言，上述問題係嚴重的。這些問 題通常來自於在最初熔化與均質化過程期間，過氧化物過 早’及最終完全的活化。傳統上，藉由使用較低反應性的 4 201011064 矽烷摻合物來處理這個問題，但是這種方法會降低交聯反 應的接枝效率。 另一個交聯方法係使用輻射。輻射交聯需要複雜的設 備，因此執行費用昂貴。更且，輻射會造成聚合物因氧化 及/或鏈剪切而降解，因而聚合物更需要特別的穩定化。更 且’就外套厚度與纜線的整體直徑兩者而言，可被商業輻 射設備操作的纜線大小是有限制的。當外套係非一致交聯 時，這種限制典型地更加明顯，並且造成纜線周緣或外套 Φ 材料壁内部之物理性質的變化結果。 另外的材料，諸如聚胺甲酸酯及氟化乙烯丙烯彈性 體，係昂貴的，且該等材料對水敏感。此外，對於使這些 - 材料得以對抗火焰而言，鹵素常常是必要的，這樣也使得 „ 這些化合物減少了許多吸引力。 所以，對於導線及纜線工業而言，其等依然需要及期 待一種聚烯烴組成物’該聚烯烴組成物可以不需要進一步 地交聯即被饋出，並且展現抗熱性與對抗著火及火焰散佈 Φ 的性質’更佳地，具有良好的撓性。 c發明内容3 發明概要 於一實施例中，本發明關於一種包括聚丙烯聚合物的 組成物，該聚丙烯聚合物以烯烴互聚物反應性加工，使得 該組成物展現抗熱性與對抗著火及火焰散佈的性質。此 外，該組成物也展現良好的撓性。 5 201011064 於本發明一實施例中’一種用於耦合丙烯聚合物及烯 烴互聚物的方法’該方法包括在反應性加工狀況下接觸至 少： A. 1 〇 wt%的至少一丙烯聚合物； B iOwt%的至少一烯烴互聚物； c 35 wt%的至少一金屬水合物；及 D _合數量的耦合劑， 各重量百分比係基於丙烯聚合物、烯烴互聚物及金屬水合 物的結合重量。典型地’該輕合劑係⑴具有乙烯基基團的 石夕烧，或者(U)聚（叠氮化物）。 聚丙烯聚合物可為均聚物或共聚物。烯烴互聚物包 括，但不限於，非常低密度聚乙烯(VLDPE)，均質分枝的、 線性乙稀/°6-烯烴共聚物’均質分枝的，實質線性乙烯/α-烯烴共聚物，線性中密度聚乙烯，線性低密度聚乙烯 (LLDPE)，超低密度聚乙烯(ULDPE)，及多嵌段烯烴聚合 物。用於本發明的金屬水合物包括，但不限於，氫氧化鋁 及氫氧化鎂。 於本發明一實施例中，一種包括絕緣層的纜線，該絕 緣層包括一種含有反應性加工聚丙烯聚合物、烯烴互聚物 及金屬水合物的組成物。 較佳實施例的詳細說明 本揭露的數字範圍係大致的，因此除非另有說明，否 則可以包括範圍之外的數值。假設在任一較低數值及任一 較高數值之間至少具有分離的兩單位的話，則數字範圍包 201011064 括以一單位方式增值之較低與較高數值在内的所有數值 舉例而言，若是組成、物理或其他性質，諸如，例如八子 量、黏度、融熔指數等等，係從100至1000，那麼所二個 別的數值，諸如100、101、102等等，以及次範圍，諸如 100至144、155至170、197至200等等，係被明白地列 舉。就含有少於一的數值或含有大於一的小數(例如^， 1.5等等）範圍而言，一單位被認為是〇 〇〇〇1、〇 〇〇1、〇 或0.1，依情形而定。就含有少於十的一位數(例如^至5) 的範圍而言，一單位典型上被認為是〇1。這些只是特別想 要的例子而已，例示的最低數值與最高數值之間所有可能 的數子數值組合也被5¾為為本揭露所明白表示。除了其他 情況之外，本揭露均提供相對於聚合物的抗樹劑數量、製 程狀況、添加劑數量及分子量的數字範圍。 “纜線”“電纜線”與類似術語意指在保護套或鞘之内 的至少一導線或光纖。典型上，纜線係黏結在一起的兩個 或多個導線或光纖，典型上在同一個保護套或鞘内。保護 套内的個別導線或光纖可以是裸線、具有覆蓋物或絕緣 物。組合纔線可含有電導線及光纖兩者。境線等等可投計 成用於低、中及高電壓。 聚合物"意指由聚合卓體（不管是相同或不同類型者) 製備的聚合化合物。此一般性術語聚合物因此含括術語均 聚物與術語共聚物，均聚物通常用於指稱由單一類型單體 製備的聚合物，共聚物定義於下。 201011064 "互聚物”、"共聚物”及類似術语意}曰由至少兩不同類裂 之單體的聚合反應而製備的聚合物。這些一般性術語指稱 由兩不同類型單體製備的聚合物，以及指稱由超過兩不同 類型之單體製備的聚合物，例如三聚物、四聚合物等等。 “聚烯烴”、“PO”及類似術語意指簡單烯烴衍生的聚合 物。許多聚烯烴是熱塑性的’且為本發明之故，可包括橡 膠相。代表性聚烤烴包括聚乙稀、聚丙婦、聚丁婦、聚異 戊二烯及其等的各種互聚物。 “摻合物”、“聚合物摻合物”及類似術語意指兩或多個 材料的混合物，例如兩或多個聚合物，至少一聚合物及至 少一抗水樹劑等等的的混合物。此種摻合物可以是互溶或 不互溶的。此種掺合物可以是相分離的或不是相分離的。 基於穿透電子光譜、光散射、X射線散射或任何習於此藝者 已知的方法，此種摻合物可以含有一或多個主要構形或不 具一或多個主要構形。 組成物，配方及類似術語意指兩種以上組份之掺 合物的混合。於用以製造缓線鞘或其他物件之材料的混合 或摻合物内部，該組成物包括所有混合的組份，例如，耦 合的丙烯聚合物及烯烴互聚物、金屬水合物、未耦合的聚 合物及辆合劑，與任何其他的添加劑(諸如加卫#1、抗氧化 劑等等）。 "分子熔化物4在室溫下至少—部分係非結晶型的 麵合劑（改質劑m抗氧化劑的摻合物，任意地也包含例如描 述於W〇2G()3/_229Al的其他聚合物添加劑。耦合劑及 201011064 抗氧化劑兩者至少部分包含於摻合物的非結晶相中。而 且，較佳地，耦合劑及抗氧化劑形成一錯合物，與單獨耦 合劑中形成氮烯基團之基團的拉曼光譜相較，該錯合物關 於形成51稀基團之基團的拉曼光譜(Raman Spectra)係偏移 的。 “耦合的”及類似術語意指以耦合劑將一聚合物鏈與另 一聚合物鏈結合。 "耗合劑”及類似術語意指含有至少兩個反應性基團的 化學化合物，各個反應性基團能夠形成可以插入聚合物鏈 CH、0¾或CH3基團（脂肪族及/或芳香族)之碳氫鍵結的碳 烯或氮烯基團。反應性基團可將聚合物键耦合或交聯在一 起。柄合劑在有效地麵合聚合物鏈之前需要以熱、聲波能 量、輻射或化學活化能來活化。 ‘‘輕合數量”及類似術語，於本發明内文中’意指在反 應性加工條件與金屬水合物存在下，足以耦合丙烯聚合物 及稀煙互聚物的耦合劑數量，如此使得呈纜線或導線絕緣 勒型式之組成物的抗熱性比由其他組成物製成之類似纜線 或導線絕緣鞘的抗熱性還要優良，該其他組成物除了丙烯 聚合物及烯烴互聚物係未耦合的之外，其餘方面與呈纜線 或導線絕緣鞘型式之組成物相同。 “氮烯基團”意指具有結構R-N的化合物，其中N係 能夠藉由插入聚合物鏈的CH、CH2或CH3基團（脂肪族及/ 或芳香族兩者）的碳氫鍵結而與聚合物鏈反應的氮。最佳之 9 201011064 插入碳氣鍵結的氮烯的氮具有兩孤立電子對。R係不會反 面干優播入上述碳-氫鍵結之氮的原子。 "峻烯基團"意指具有結構R-C-R，的化合物，其中c 係能夠藉著插入聚合物鏈之CH、CH2或CH3基團（脂肪族 及/或芳香族兩者)之碳氫鍵結而與聚合物鏈反應的碳。用於 插入碳氫鍵結之最佳的碳具有一孤立電子對。R及R，係不 會反面干擾插入上述碳-氫鍵結之碳的兩獨立原子。 “抗氧化劑"意指能夠被用於使加工聚合物期間產生之 氧化作用降至最低的各類型化學化合物。該術語也包括抗 氧化劑的化學衍生物。該術語更包括於稍後之抗氧化劑說 明中描述的化學化合物，這些化學化合物當與耦合劑適合 地結合時，會與耦合劑反應以形成錯合物。此錯合物相較 於單獨的耦合劑展現修飾過的拉曼光譜。 “反應性加工，，意指藉著混合聚合物組份而相容化 (compatibilization)或化學耦合聚合物之摻合物的方法，以 此種方式其等在原位彼此反應。組成物組份具有足 夠的反應性，如此反應可以越過熔化相邊界而發生。 “反應性加工狀況，，意指聚合物的摻合物進行（1)充分地 混合以達到外形組織所要的微細程度，及(2)使至少一些聚 合物分子彼此反應或耦合以在混合/磨碎過程期間形成共 價鍵。反應進行得相當地快，使得其等在饋出器或混合器 加工期間於合理時間内就已經反應完全。典型加工狀況包 括溫度100至280，更典型地150至250及最典型地180 至250 C。壓力典型地（至少一部分)係聚合物之摻合設備的 201011064 函數，但是典型地壓力範 7。/5雇Kit u, 固從—大氣壓到稍微正壓的狀 :=工狀況繼續持續直到典型地至少 地至少70、最典型地至少8 尺/、茧 或者，在魏輕合綱例子中，=的疊氮化物已經反應， m. „ . 〇Λ 、 至夕5〇、更典型地至少70、 最分比的過氧化物已經被消耗。201011064 VI. Description of the invention: [Technology of the invention belongs to the field of the present invention.] The present application claims the priority of US Patent Application Serial No. 61/059,356, filed on Jun. 6, 2008. The entire contents are incorporated herein by reference. FIELD OF THE INVENTION The present invention relates to a group of products comprising a polypropylene polymer and a dilute tobacco interpolymer. In one aspect, the invention is directed to a composition comprising reactively processed polypropylene and an olefin interpolymer which exhibits high thermal resistance properties for wire and cable coating. In another aspect, the invention relates to a cable comprising an insulating layer. In another aspect, the invention relates to a cable. The insulating layer comprises a reactively processed polypropylene and a dilute hydrocarbon. The composition of the polymer. [Prior Art 3 Background] Polymeric compositions are often used as a basic insulating material for wires and cables. As an insulator, the composition should exhibit various physical and electrical properties, such as heat resistance 'against mechanical cutting' against stress cracking and dielectric failure. Insulating materials for electrical conductors often require cross-linking to achieve the desired heat resistance. Crosslinking can be introduced between different molecular chains of a polymer by several mechanisms, one of which is to graft a chemically reactive compound onto an individual polymer backbone or chain that constitutes a macropolymer, in such a way The grafted compound on a primary 201011064 bond can then react with a similar grafting compound on the other backbone, thereby forming a crosslink. An example of this method is the method of "decane cross-linking." The Shixi & cross-linking process utilizes a decane-containing compound of a cross-linked polymer molecule, either prior to the forming or molding operation or during the forming or molding operation. The decane can be grafted to a suitable polymer using a suitable amount of an organic peroxide or other free radical initiator. Other ingredients such as stabilizers, pigments, fillers, catalysts, processing aids, and the like can also be included. In the mixture. When using the alkane-peroxide blend to crosslink the polymer, a compromise must be made between the grafting efficiency and the processing efficiency, such as the feed rate and the number of passes, because the process needs to be strictly controlled. Therefore, it is difficult to form a crosslinkable material in this way. For example, if the method is performed at too high a temperature, the polymer may partially crosslink in a processing device (for example, a feeder), making it difficult to obtain consistent quality afterwards. Good product. Due to the need to remove part of the cross-linked product from the processing equipment, processing delays may also occur. During the subsequent heating and cross-linking process Care must be taken to ensure that the articles made from the polymer retain their shape. ® and more, when using highly reactive decane-peroxide blends, gel formation, threading and coking occur. Phenomena. The above problems are serious in the processing of processing conditions and processing equipment to produce high shear stress in polyolefins under strict melting and mixing conditions. These problems usually arise from the initial melting and homogenization process. During this period, the peroxide is prematurely and eventually fully activated. Traditionally, this problem has been addressed by the use of a less reactive 4 201011064 decane blend, but this approach reduces the grafting efficiency of the cross-linking reaction. Another cross-linking method uses radiation. Radiation cross-linking requires complicated equipment and is therefore expensive to perform. Moreover, radiation causes degradation of the polymer due to oxidation and/or chain shear, so the polymer needs special stabilization. Moreover, 'the size of the cable that can be operated by commercial radiation equipment is limited in terms of both the thickness of the jacket and the overall diameter of the cable. This limitation is typically more pronounced when the jacket is non-uniformly crosslinked and results in changes in the physical properties of the cable perimeter or jacket Φ material wall interior. Additional materials such as polyurethane and fluorinated ethylene propylene Elastomers are expensive and the materials are sensitive to water. In addition, halogens are often necessary to make these materials resistant to flames, which also makes these compounds less attractive. Therefore, for the wire and cable industry, there is still a need and expectation of a polyolefin composition which can be fed out without further crosslinking and exhibits heat resistance against fire and flame spread. The nature of Φ is better, with good flexibility. BRIEF SUMMARY OF THE INVENTION In one embodiment, the present invention is directed to a composition comprising a polypropylene polymer reactively processed with an olefin interpolymer such that the composition exhibits heat resistance and resistance to ignition and The nature of the flame spread. In addition, the composition also exhibits good flexibility. 5 201011064 In one embodiment of the invention 'a method for coupling a propylene polymer and an olefin interpolymer', the method comprises contacting at least: A. 1 〇 wt% of at least one propylene polymer under reactive processing conditions; B iOwt% of at least one olefin interpolymer; c 35 wt% of at least one metal hydrate; and D _ total amount of couplant, each weight percentage based on a combination of propylene polymer, olefin interpolymer and metal hydrate weight. Typically, the light-binding agent (1) has a vinyl group, or (U) poly (azide). The polypropylene polymer can be a homopolymer or a copolymer. Olefin interpolymers include, but are not limited to, very low density polyethylene (VLDPE), homogeneously branched, linear ethylene/-6-olefin copolymer 'homogeneously branched, substantially linear ethylene/alpha-olefin copolymer, Linear medium density polyethylene, linear low density polyethylene (LLDPE), ultra low density polyethylene (ULDPE), and multi-block olefin polymers. Metal hydrates useful in the present invention include, but are not limited to, aluminum hydroxide and magnesium hydroxide. In one embodiment of the invention, a cable comprising an insulating layer comprising a composition comprising a reactive processed polypropylene polymer, an olefin interpolymer, and a metal hydrate. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT The numerical ranges of the present disclosure are broad and, therefore, may include values outside the range unless otherwise indicated. Assuming that there are at least two separate units between any lower value and any higher value, the numerical range package 201011064 includes all values including the lower and higher values added in one unit, for example. Composition, physical or other properties, such as, for example, eight-quantity, viscosity, melt index, etc., from 100 to 1000, then two individual values, such as 100, 101, 102, etc., and sub-ranges, such as 100 to 144, 155 to 170, 197 to 200, etc. are explicitly enumerated. In the case of a range containing less than one value or containing a fraction greater than one (e.g., 1.5, 1.5, etc.), a unit is considered to be 〇 〇 1, 〇 〇〇 1, 或 or 0.1, as the case may be. For a range containing a single digit of less than ten (e.g., ^ to 5), a unit is typically considered to be 〇1. These are only examples of what is particularly intended, and all combinations of possible numerical values between the lowest and highest values are also indicated by the disclosure. The present disclosure provides, among other things, a numerical range of the amount of anti-tree agent, process conditions, amount of additives, and molecular weight relative to the polymer. "Cable" "cable" and like terms mean at least one wire or fiber within a protective sheath or sheath. Typically, the cable is two or more wires or fibers that are bonded together, typically in the same protective sheath or sheath. Individual wires or fibers within the protective sleeve may be bare wires, have a covering or insulation. The combined cable can contain both electrical wires and fibers. Horizons and the like can be counted for low, medium and high voltages. "Polymer" means a polymeric compound prepared from a polymerized body, whether of the same or a different type. This general term polymer thus encompasses the term homopolymer and the term copolymer, which are commonly used to refer to polymers prepared from a single type of monomer, the copolymer being defined below. 201011064 "Interpolymer", "copolymer" and like terms mean a polymer prepared by the polymerization of at least two different types of cracked monomers. These general terms refer to polymers prepared from two different types of monomers, as well as polymers that are claimed to be prepared from more than two different types of monomers, such as terpolymers, tetrapolymers, and the like. "Polyolefin", "PO" and like terms mean a simple olefin derived polymer. Many polyolefins are thermoplastic' and, for the purposes of the present invention, may include a rubber phase. Representative poly-baked hydrocarbons include various interpolymers of polyethylene, polypropylene, polybutyrate, polyisoprene, and the like. "Blender", "polymer blend" and like terms mean a mixture of two or more materials, such as a mixture of two or more polymers, at least one polymer, and at least one water-resistant tree agent, and the like. Such blends may be miscible or immiscible. Such blends may be phase separated or not phase separated. Such blends may contain one or more primary configurations or no one or more primary configurations based on penetrating electron spectroscopy, light scattering, X-ray scattering, or any method known to those skilled in the art. The composition, formulation and like terms mean a mixture of a mixture of two or more components. Inside a mixture or blend of materials used to make a slow sheath or other article, the composition includes all mixed components, for example, coupled propylene polymers and olefin interpolymers, metal hydrates, uncoupled Polymer and vehicle mixture, and any other additives (such as Jiawei #1, antioxidants, etc.). "Molecular melt 4 at least a part of a non-crystalline type of surface agent at room temperature (blend of the modifier m antioxidant, optionally also including other polymerizations such as described in W〇2G() 3/_229Al The additive, the coupling agent and the 201011064 antioxidant are at least partially contained in the amorphous phase of the blend. Moreover, preferably, the coupling agent and the antioxidant form a complex and form a nitrogen-alkenyl group with the separate coupling agent. The Raman spectrum of the group of the group is offset by the Raman Spectra of the group forming the 51 dilute group. "Coupled" and similar terms mean that the coupling agent will A polymer chain is bonded to another polymer chain. "Consumer" and like terms mean a chemical compound containing at least two reactive groups, each reactive group capable of forming a polymer chain CH, 03⁄4 or a hydrocarbon-bonded carbene or a nitrogen-alkenyl group of a CH3 group (aliphatic and/or aromatic). The reactive group can bond or crosslink the polymer bonds together. Before the chain of things, you need heat, sonic energy, Radiation or chemical activation energy to activate. ''Light quantity' and similar terms, in the context of the present invention' means sufficient coupling of propylene polymer and dilute tobacco interpolymer in the presence of reactive processing conditions and metal hydrates. The amount of couplant, such that the heat resistance of the cable or wire-insulated composition is superior to the heat resistance of a similar cable or wire insulation sheath made of other compositions other than propylene polymer. And the olefin interpolymer is uncoupled, and the rest is the same as the composition of the cable or wire insulating sheath type. "Nylenyl group" means a compound having a structure RN, wherein N is capable of being inserted by polymerization Nitrogen-bonded nitrogen of the CH, CH2 or CH3 groups (both aliphatic and/or aromatic) of the chain and reacts with the polymer chain. Optimal 9 201011064 Insertion of carbon-bonded nitrogen-nitrogen nitrogen It has two isolated electron pairs. The R system does not interfere with the above-mentioned carbon-hydrogen bonded nitrogen atoms. "Squareen group" means a compound having a structural RCR, wherein the c system can be inserted by Polymer chain The carbon of the CH, CH2 or CH3 group (both aliphatic and/or aromatic) is bonded to the polymer chain. The carbon used for the insertion of hydrocarbon bonds has an isolated electron pair. R and R do not adversely interfere with the insertion of two separate atoms of the carbon-hydrogen bonded carbon. "Antioxidant" means various types of chemistry that can be used to minimize oxidation during processing of the polymer. The term also includes chemical derivatives of antioxidants. The term further includes chemical compounds described in later antioxidant descriptions that, when properly combined with a coupling agent, react with the coupling agent to form a fault. The complex exhibits a modified Raman spectrum compared to the couplant alone. "Reactive processing, means a method of compatibilization or blending of chemically coupled polymers by mixing polymer components, in such a manner that they react with each other in situ. Composition components Having sufficient reactivity, such a reaction can occur across the boundary of the melt phase. "Reactive processing conditions, meaning that the blend of polymers is (1) sufficiently mixed to achieve the desired degree of fineness of the shape structure, and (2) At least some of the polymer molecules are reacted or coupled to each other to form a covalent bond during the mixing/grinding process. The reaction proceeds fairly quickly so that it has reacted completely within a reasonable time during the processing of the feeder or mixer. Typical processing conditions include temperatures from 100 to 280, more typically from 150 to 250 and most typically from 180 to 250 C. The pressure is typically (at least a portion) the 201011064 function of the polymer blending device, but typically a pressure gauge of 7. /5 hire Kit u, solid-to-atmospheric to slightly positive pressure: = work condition continues until typically at least 70, most typically at least 8 feet /, 茧 or, in the case of Wei light, = The azide has been reacted, m. „ , 至 5 〇, more typically at least 70, the most proportionate peroxide has been consumed.

:本發明的聚㈣(特別包括丙稀聚 ;互使用傳統聚烯”合技術，例如戚格勒納他 aw咖）、金屬茂或限制幾何催化劑而產生，當缺各 個技術適用於產生歧_刊聚馳。金屬茂及限制幾 何催化_〇包括與活化劑⑽，氧化铭溶膠 (—η6))結合的單環或雙糾二稀基1基絲基過渡 金屬（較佳地第4族)錯合物。美國專利第5,〇64,8〇2號、 而髓则4及WO9·526揭示限制幾何金屬錯合物以及 製備其等的方法。各種含有取代茚基的金屬錯合物教示於 WO95/14024 及 W098/49212 中。 一般而言，於習於此藝者熟知的戚格勒-納他或卡明斯 基-辛（Kaminsky-Sinn)型聚合反應的狀況下可以完成聚合 反應，亦即’在溫度0-250°C、較佳地30-200°C以及壓力 從大氣壓至 1〇,〇〇〇 大氣壓（1013 百萬帕斯 卡megaPascal(MPa))下可以完成聚合反應。依需要的狀 況，可使用懸浮液、溶液、泥漿、氣相、固態粉末聚合反 應或其他製程狀況。催化劑可為支撐或非支撐，支樓組成 物可以為各種型式。矽石、蓉土或聚合物（尤其是聚（四氟乙 11 201011064 烯）或聚烯烴）為代表性支撐物’而且當催化劑被用於氣相聚 合反應製程時’使用支撐物是所欲的。支撐物較佳的使用 數量係足以使得催化劑（基於金屬）對支撐物的重量比例落 在 1 : 1 : 100,000 至 1 : 10、更佳地 1 : 5〇,〇〇〇 至丨：2〇、 最佳地1 : 10,000至1 : 30的範圍。在大部分的聚合反應 中，催化劑對使用之可聚合化合物的莫耳比例從1〇-〗2 : i 至 10_1 : 1、更佳地從 10_9 : 1 至 10_5 : 1。 鈍性液體可作為合適的聚合反應溶劑。例子包括直鍵 及分枝的碳氫化合物（諸如異丁烷、丁烷、戊烷、己烧、庚 參 炫•、辛炫》及其專之混合物），ί衷狀及脂ί哀族碳氮化合物（諸如 環己烷、環庚烷、甲基環己烧、甲基環庚燒及這些材料的 兩種以上的混合物）；全氟化的碳氫化合物（諸如全氟化的 _ C4-1G烧類）；及芳香族與烧基取代的芳香族化合物（諸如 笨、甲苯、二甲苯及乙基苯）。 丙稀聚合物'· 用於實施本發明的丙烯聚合物（組成物的組份A)不是 稀烴互聚物（組成物的組份B)。丙烯聚合物可為丙烯均聚 〇 物，或丙烯與一或多個其他烯烴的共聚物，或兩種以上均 聚物或兩種以上共聚物的摻合物，或一或多個均聚物及一 或多個共聚物的掺合物。用於本組成物的丙烯聚合物可為 各種型式並包括例如實質上同排丙烯均聚物、隨機丙烯共 聚物與接枝或嵌段丙烯共聚物。 12 201011064 丙烯共聚物典型地包括9〇以上 _單元。丙歸共聚物中單元的其來自, 烴。 來自至少—CX-歸 丙烯共聚物的α_稀烴組份較佳 被認為是α·稀經)或C4-20線性、分枝^乙稀(為本發明目的 烴的例子包括K丁稀、4_甲基_ ^狀06烯煙。c4.20 0t,: The poly(tetra) of the present invention (especially including propylene polyglycols; the use of conventional polyenes, such as 戚Gerner), metallocene or limited geometry catalysts, when various technologies are suitable for producing _ Journal of Metallocene and Restricted Geometry Catalysts 单 include monocyclic or double ruthenyl 1 skyl transition metals in combination with activator (10), oxidized sol (—η6) (preferably Group 4) Complex compounds. U.S. Patent No. 5, No. 64,8,2, and M. 4 and WO 9·526 disclose methods for limiting geometric metal complexes and preparing them, etc. Various metal complex teachings containing substituted sulfhydryl groups In WO95/14024 and W098/49212. In general, the polymerization can be carried out under the conditions of the Ziegler-Natin or Kaminsky-Sinn type polymerization known to the art. That is, the polymerization can be completed at a temperature of 0-250 ° C, preferably 30-200 ° C and a pressure from atmospheric pressure to 1 Torr, at atmospheric pressure (1013 MPa Pascal megaPascal (MPa)). Condition, suspension, solution, slurry, gas phase, solid powder polymerization Other process conditions. The catalyst can be supported or unsupported, and the composition of the branch can be of various types. Vermiculite, Rong or polymer (especially poly(tetrafluoroethylene 11 201011064 ene) or polyolefin) is a representative support. 'And when the catalyst is used in a gas phase polymerization process, 'use of a support is desirable. The support is preferably used in an amount sufficient to cause the catalyst (based on metal) to support weight ratio to fall at 1: 1 : 100,000 To 1:10, more preferably 1:5〇, 〇〇〇 to 丨: 2〇, optimally 1: 10,000 to 1:30. In most polymerizations, the catalyst is used for the polymerizable compound. Mohr ratio from 1〇-〗 2: i to 10_1 : 1, more preferably from 10_9 : 1 to 10_5 : 1. A passive liquid can be used as a suitable polymerization solvent. Examples include direct bonds and branched hydrocarbons. Compounds (such as isobutane, butane, pentane, burned, Geng Shenxuan, Xin Xing) and their special mixtures), 衷 状 and fat 哀 碳 碳 carbon (such as cyclohexane, cycloglycan Alkanes, methylcyclohexane, methylcycloheptane and these materials a mixture of two or more; perfluorinated hydrocarbons (such as perfluorinated _ C4-1G); and aromatic and alkyl-substituted aromatic compounds (such as stupid, toluene, xylene, and ethyl) Benzene). Acryl polymer'· The propylene polymer (component A of the composition) used in the practice of the present invention is not a dilute hydrocarbon interpolymer (component B of the composition). The propylene polymer may be a homopolymer of propylene. Or a copolymer of propylene with one or more other olefins, or a blend of two or more homopolymers or two or more copolymers, or one or more homopolymers and one or more copolymers Compound. The propylene polymers used in the present compositions can be of various types and include, for example, substantially identical propylene homopolymers, random propylene copolymers, and graft or block propylene copolymers. 12 201011064 Propylene copolymers typically comprise more than 9 _ units. The unit of the propylene copolymer is derived from a hydrocarbon. The α-dilute hydrocarbon component derived from at least the CX-reductive propylene copolymer is preferably considered to be α·spare or C4-20 linear, branched ethylene (examples of hydrocarbons for the purpose of the present invention include K-butylene, 4_methyl_^06 olefin smoke. c4.20 0t,

癸稀、十二婦、1-十四稀、！_十六％ 1•己稀、κ辛烯、1-te也可含有觀結構，諸如環己料 十人歸。(X， 3-環己基·1·丙歸⑽丙基環己院 、元㈣成諸如 烴。雖然不是傳統意義地，了*環已烷的1烯 環烯烴’諸如冰片稀及相_烯烴，特^發5明之故，某些 片烯，也是α-烯烴且可被用來取代一些二::乙基1冰 煙。類似地，笨乙稀及其相關_(例如，述以卡 等)就本發明目的而言也是…稀煙。例示的聚丙等 括但不限於丙稀/乙烯、乙稀丁稀、乙稀己烯乙綠物包 稀及相似物。例示的三聚物包括乙寧丙稀λ•辛稀、乙1:辛 丙稀/1·丁稀及乙稀/丙稀/二稀單體(EPDM)。共聚物可= 隨機的或是喪段的。 & 以下是可用於本發明組成物之例示而非限制的丙烯聚 合物：丙烯衝擊共聚物包括但不限於D〇w聚丙烯 T702-12N ;丙烯均聚物包括但不限於DOW聚丙稀 H502-25RZ;及丙烯隨機共聚物包括但不限於DOW聚丙婦 R751_12N。上述的Dow丙烯聚合物典型地具有〇.9〇 g/cm3 的密度（以ASTMD792測定）。 13 201011064 更且，可以使用熔化流動指數0.5 dg/min(230°C/2.16kg) 及熔點164°C的分枝衝擊丙烯共聚物INSPIREtm D114 (也 可從陶氏化學公司（Dow Chemical Company)購得）。 此外’密度0.90 g/cc及MFR2 g/10 min的澄清丙烯共 聚物樹脂 PROFAXtm SR-256M，密度 0·90 g/cc 及 MFR 1.5 g/10min的衝擊丙烯共聚物樹脂PR〇FAXtm8623，以及 聚丙烯（均或共聚物）與一或多個丙烯-乙烯或乙烯-丙烯共 聚物的反應器内摻合物CATALLOYtm也可以使用（所有均 可從Basell，Elkton，MD購得）。其他丙烯聚合物包括Solvay 的KS 4005丙稀共聚物；及Solvay的KS 300丙稀三聚物。 稀烴互聚物\ 用於實施本發明的烯烴互聚物（組成物的組份B)不包 括上述的丙稀聚合物（組成物的組份A)。稀烴互聚物包括但 不限於聚烯烴彈性體、聚烯烴撓性體及聚烯烴塑性體。較 佳地，烯烴互聚物係乙烯互聚物，其基於烯烴互聚物的重 量包括至少10、較佳地至少50及更佳地至少80wt%之來 自乙烯的單元。 有用於實施本發明之烯烴互聚物的例子包括非常低密 度的聚乙烯(VLDPE)，均質分枝、線性的乙烯/α-烯烴共聚 物（例如Mitsui石油化學股份有限公司的TAFMER®及 DEXPlastomers的EXACT®)，與均質分枝、實質線性的乙 烯/α-烯烴聚合物(例如購自陶氏化學公司的AFFINITY®聚 烯烴彈性體及ENGAGE®聚烯烴彈性體）。實質線性的乙烯 201011064 共聚物於美國專利5,272,236、5,278,272及5,986,028有更 為全面的描述。 有用於實施本發明之其他烯烴互聚物包括異質分枝之 以乙烯為底的互聚物，其包括，但不限於，線性中密度聚 乙烯(LMDPE)，線性低密度聚乙烯(LLDPE)，及超低密度聚 乙烯（ULDPE)。商業聚合物包括DOWLEX™聚合物， ATTANE™聚合物及flEXOMER™聚合物（所有購自陶氏 化學公司），與ESCORENE™及EXCEED™聚合物（均購自 ExxonMobil化學公司）〇 另外的烯烴互聚物包括多嵌段或分段共聚物。這些共 聚物係兩種以上化性不同的區域或區段(稱作“嵌段”），較佳 地以線性方式，連接的聚合物，亦即，包括聚合乙烯官能 性以端對端方式（而不是以外接或接枝方式）連接之化性不 同單元的聚合物。在某些實施例中，嵌段具有不同的嵌入 共單體數f或類型、密度、結晶數量、組成此等組成物之 聚合物的結晶大小、立體化學性（同排或對排）的類型或程 度、位置規雜或位置不規雜、分枝數量（包括長鏈分枝 或高度分枝）、均質性或其他化學或物理性f。多嵌段共聚 物可藉由製ϋ絲物制特方輯產生關特乡分散性指 數分布(PDI < Μ我）、嵌段長度分布及/或嵌段數目分^ 的特徵而區別。更特別地，當以連續方法產生時，聚合物 的實施例可含有範圍從約口至約8的·在其他實施例 中’從約1，7至約3.5;在又一實施例中，從約丨7至約2 5 ·， 在再-實施例中，從約h8至約2 5或從約18至約21。 15 201011064 當以批次或半批次方法產生時，聚合物的實施例可含有PDI 的範圍係從約1.0至約2.9 ;在其他實施例中，從約1.3至 約2.5 ;在又一實施例中，從約1.4至約2.0 ;在再一實施 例中，從約1.4至約1.8。 乙烯/α-烯烴多嵌段互聚物包括乙烯及一或多個呈聚 合型式的共聚α-稀烴共單體，其特徵為含有兩個以上物化 性質不同之聚合單體單元的多個（即兩個以上）的嵌段或分 段（嵌段互聚物），較佳地為多嵌段互聚物。於一些實施例 中，多嵌段互聚物可以以下的化學式表示： (ΑΒ)η 其中η至少為1，較佳地大於1的整數，諸如2、3、 4 、 5 ' 10 ' 15 、 20 、 30 、 40 ' 50 ' 60 、 70 、 80 、 90 ' 100 或更高；“Α”代表硬嵌段或分段；“Β”代表軟嵌段或分段。 較佳地，Α及Β以線性方式連接，而不是以分枝或星狀方 式連接。“硬”分段意指聚合單元的嵌段，其中於一些實施 例中，乙烯出現的數量大於95重量百分比，及於其他實施 例中，乙烯出現的數量大於98重量百分比。換言之，於一 些實施例中，硬分段中共單體的含量少於5重量百分比， 於其他實施例中，硬分段中共單體的含量少於硬分段總重 的2重量百分比。於一些實施例中，硬分段包括所有或實 質上所有的乙烯。“軟”分段，於另一方面，指稱聚合單元 的嵌段，其中於一些實施例中，共單體的含量大於軟分段 總重的5重量百分比，在各種其他實施例中，大於軟分段 總重的8重量百分比、大於軟分段總重的10重量百分比 201011064 或大於軟分段總重的15重量百分比。於一些實施例中， 軟分段中共單體的含量可能大於20重量百分比，在各種其 他實施例中，大於25重量百分比、大於30重量百分比、 大於35重量百分比、大於40重量百分比、大於45重量 百分比、大於50重量百分比或大於60重量百分比。 有用於實施本發明的乙烯多嵌段共聚物，及其等的製 備與使用，更完整地描述於WO 2005/090427、 US2006/0199931、US2006/0199930、US2006/0199914、 US2006/0199912、US2006/0199911、US2006/0199910、 US2006/0199908 、美國專利第 7,355,089 號、 US2006/0199906、US2006/0199905、美國專利第 7,524,911 號、US2006/0199896、US2006/0199887、美國專利第 7,514,517 號、US2006/0199872、US2006/0199744、 US2006/0199030 、美國專利第 7,504,347 號及 US2006/0199983。代表性烯烴多嵌段互聚物包括由陶氏化 學公司製造及銷售的烯烴嵌段共聚物。 有用於本發明的乙烯互聚物包括乙烯/α-烯烴互聚 物，其具有α-烯烴的含量基於互聚物重量典型地係至少5、 更典型地至少15及最典型地至少約20wt%。這些互聚物具 有α-烯烴的含量基於互聚物重量典型地係少於90、更典型 地少於75及最典型地少於約50wt%。α-烯烴的含量以13C 核磁共振(NMR)光譜利用描述於尺311(1311(/?伙^/^<^〇/«〇/· C/zew· C2iY2<&3))的步驟測量。 17 201011064 α-嫦烴較佳地為C3·^線性、分枝或環狀α_烯烴。c3 2() α-烯烴的例子包括丙烯、丨_丁烯、4_曱基_丨_戊烯、丨己烯、 1-辛烯、1-癸烯、1-十二烯、丨_十四烯、丨_十六烯、及丨_十 八烯。α-烯烴也可含有環狀結構，諸如環己烷或環戊烷，而 形成諸如3-環己基-1-丙烯(烯丙基環己烷)及乙烯基環己烷 的α-烯烴。雖然不是傳統意義上的α_烯烴，為了本發明之 故，某些環烯烴，諸如冰片烯及相關的烯烴，特別是5_亞 乙基-2-冰片浠，也是α_浠烴且可被用來取代一些或所有的 上述α-烯烴。類似地，苯乙烯及其相關烯烴(例如，α_甲基 參 苯乙浠等等）就本發明目的而言也是…烯烴。例示的聚稀烴 共聚物包括乙烯/丙烯、乙烯/丁烯、乙烯/1_己烯、乙烯/丨_辛 烯、乙烯/苯乙烯及相似物。例示的三聚物包括乙烯/丙烯Α- 辛烯、乙烯/丙烯/丁烯、乙烯/丁烯/1-辛烯、乙烯/丙烯/二烯 單體(EPDM)及乙烯/丁烯/苯乙烯。共聚物可以是隨機的或是 嵌段的 其他有用於實施本發明的烯烴互聚物包括購自陶氏化 學公司的以VERSIFY®丙烯為基底的聚合物，及購自 ®Rare, twelve women, 1-fourteen,! _16% 1 • hexaploene, κ octene, 1-te may also contain a structure, such as a ring of ten people. (X, 3-cyclohexyl·1·propanol (10) propylcyclohexan, meta (tetra) to form a hydrocarbon such as a hydrocarbon. Although not conventionally, a cycloalkenyl 1-alkene olefin such as borneol and phase olefins, Some of the flakes are also alpha-olefins and can be used to replace some of the two: ethyl 1 ice smoke. Similarly, stupid ethylene and its related _ (for example, card, etc.) For the purposes of the present invention, it is also ... dilute smoke. Exemplary polypropylenes include, but are not limited to, propylene/ethylene, eththium butadiene, ethylene hexene chloroform, and the like. The exemplified terpolymer includes ethyl phthalate. Propylene λ•Silmine, B 1: Octane/1·Butyl and Ethylene/Propylene/Diluted Monomer (EPDM). Copolymer can be random or mourned. & Exemplary and non-limiting propylene polymers: propylene impact copolymers of the present invention include, but are not limited to, D〇w polypropylene T702-12N; propylene homopolymers include, but are not limited to, DOW polypropylene H502-25RZ; Copolymers include, but are not limited to, DOW polypropylene R751_12N. The above Dow propylene polymer typically has a density of 〇.9〇g/cm3 (as determined by ASTM D792). 13 2010 11064 Furthermore, a branched impact propylene copolymer INSPIETm D114 having a melt flow index of 0.5 dg/min (230 ° C / 2.16 kg) and a melting point of 164 ° C can be used (also available from the Dow Chemical Company). In addition, 'density propylene copolymer resin PROFAXtm SR-256M with density of 0.90 g/cc and MFR2 g/10 min, impact propylene copolymer resin PR〇FAXtm8623 with density of 0·90 g/cc and MFR 1.5 g/10 min, and An in-reactor blend of polypropylene (either homopolymer or copolymer) with one or more propylene-ethylene or ethylene-propylene copolymers, CATALLOYtm, can also be used (all available from Basell, Elkton, MD). Other propylene polymerizations Included in Solvay's KS 4005 propylene copolymer; and Solvay's KS 300 propylene terpolymer. Dilute hydrocarbon interpolymers \ olefin interpolymers (component B of the composition) used in the practice of the present invention do not include the above A propylene polymer (component A of the composition). The dilute hydrocarbon interpolymer includes, but is not limited to, a polyolefin elastomer, a polyolefin flexure, and a polyolefin plastomer. Preferably, the olefin interpolymer is ethylene interpolymer. And the weight of the olefin based interpolymer comprises at least 10, Preferably at least 50 and more preferably at least 80% by weight of units derived from ethylene. Examples of olefin interpolymers useful in the practice of the invention include very low density polyethylene (VLDPE), homogeneously branched, linear ethylene/α- Olefin copolymers (such as TAFMER® from Mitsui Petrochemical Co., Ltd. and EXACT® from DEXPlastomers), with homogeneous branched, substantially linear ethylene/α-olefin polymers (such as AFFINITY® polyolefin elastomers from Dow Chemical Company) Body and ENGAGE® Polyolefin Elastomer). Substantially linear ethylene 201011064 copolymers are more fully described in U.S. Patent Nos. 5,272,236, 5,278,272 and 5,986,028. Other olefin interpolymers useful in the practice of the invention include heterogeneous ethylene-based interpolymers including, but not limited to, linear medium density polyethylene (LMDPE), linear low density polyethylene (LLDPE), And ultra low density polyethylene (ULDPE). Commercial polymers include DOWLEXTM polymers, ATTANETM polymers and flEXOMERTM polymers (all from Dow Chemical Company), and ESCORENETM and EXCEEDTM polymers (both from ExxonMobil Chemical Company) for additional olefin interpolymerization The inclusions include multi-block or segmented copolymers. These copolymers are two or more different regions or segments (referred to as "blocks"), preferably in a linear manner, connected polymers, that is, including polymeric ethylene functionality in an end-to-end manner ( Instead of an external or grafting method, the polymers of different units are linked. In certain embodiments, the blocks have different numbers of embedded comonomers, f or type, density, number of crystals, crystal size, stereochemistry (same row or row) of the polymers that make up the compositions. Or degree, location, or location, number of branches (including long-chain branches or high-branched), homogeneity, or other chemical or physical properties. The multi-block copolymer can be distinguished by the characteristics of the Guan Texiang dispersibility index distribution (PDI < Μ me), block length distribution and/or block number distribution. More particularly, when produced in a continuous process, embodiments of the polymer may range from about from about 8 to about 8 in other embodiments 'from about 1, 7 to about 3.5; in yet another embodiment, from From about 7 to about 2 5 ·, in the re-embodiment, from about h8 to about 25 or from about 18 to about 21. 15 201011064 When produced in a batch or semi-batch process, embodiments of the polymer may contain PDI ranging from about 1.0 to about 2.9; in other embodiments, from about 1.3 to about 2.5; in yet another embodiment Medium, from about 1.4 to about 2.0; in still another embodiment, from about 1.4 to about 1.8. The ethylene/α-olefin multi-block interpolymer comprises ethylene and one or more copolymerized α-dilute co-monomers in a polymeric form, characterized by a plurality of polymerized monomer units having two or more different physicochemical properties ( That is, two or more blocks or segments (block interpolymers), preferably multi-block interpolymers. In some embodiments, the multi-block interpolymer can be represented by the following chemical formula: (ΑΒ)η where n is an integer of at least 1, preferably greater than 1, such as 2, 3, 4, 5' 10 '15, 20 , 30, 40 ' 50 ' 60 , 70 , 80 , 90 ' 100 or higher; "Α" stands for hard block or segment; "Β" stands for soft block or segment. Preferably, Α and Β are connected in a linear manner, rather than in a branched or star-like manner. "Hard" segmentation refers to a block of polymeric units wherein, in some embodiments, ethylene is present in an amount greater than 95 weight percent, and in other embodiments, ethylene is present in an amount greater than 98 weight percent. In other words, in some embodiments, the amount of comonomer in the hard segment is less than 5 weight percent, and in other embodiments, the amount of comonomer in the hard segment is less than 2 weight percent of the total weight of the hard segment. In some embodiments, the hard segments comprise all or substantially all of the ethylene. "Soft" segmentation, on the other hand, refers to a block of polymeric units, wherein in some embodiments, the amount of comonomer is greater than 5 weight percent of the total weight of the soft segment, in various other embodiments, greater than soft 8 weight percent of the total weight of the segment, 10 weight percent greater than the soft segment total weight 201011064 or greater than 15 weight percent of the soft segment total weight. In some embodiments, the content of comonomer in the soft segment may be greater than 20 weight percent, in various other embodiments greater than 25 weight percent, greater than 30 weight percent, greater than 35 weight percent, greater than 40 weight percent, greater than 45 weight percent Percentage, greater than 50 weight percent, or greater than 60 weight percent. There are ethylene multi-block copolymers useful in the practice of the present invention, and the preparation and use thereof, as described more fully in WO 2005/090427, US 2006/0199931, US 2006/0199930, US 2006/0199914, US 2006/0199912, US 2006/0199911 US2006/0199910, US2006/0199908, US Patent No. 7,355,089, US2006/0199906, US2006/0199905, US Patent No. 7,524,911, US2006/0199896, US2006/0199887, US Patent No. 7,514,517, US2006/0199872, US2006/0199744 US 2006/0199030, U.S. Patent No. 7,504,347 and US 2006/0199983. Representative olefin multi-block interpolymers include olefin block copolymers manufactured and sold by The Dow Chemical Company. Ethylene interpolymers useful in the present invention include ethylene/α-olefin interpolymers having an alpha olefin content typically at least 5, more typically at least 15 and most typically at least about 20 wt%, based on the weight of the interpolymer. . These interpolymers have an alpha-olefin content of typically less than 90, more typically less than 75 and most typically less than about 50 weight percent, based on the weight of the interpolymer. The content of the α-olefin was measured by 13 C nuclear magnetic resonance (NMR) spectroscopy using the procedure described in Rule 311 (1311 (/? ^^/^<^〇/«〇/·C/zew· C2iY2<& 3)) . 17 201011064 The alpha-anthracene is preferably a C3 linear, branched or cyclic alpha-olefin. Examples of c3 2() α-olefins include propylene, ruthenium-butene, 4-mercapto-non-pentene, decene, 1-octene, 1-decene, 1-dodecene, 丨_ten Tetraene, hydrazine-hexadecene, and hydrazine-octadecene. The α-olefin may also contain a cyclic structure such as cyclohexane or cyclopentane to form an α-olefin such as 3-cyclohexyl-1-propene (allyl cyclohexane) and vinylcyclohexane. Although not an alpha olefin in the conventional sense, certain cycloolefins, such as norbornene and related olefins, especially 5-ethylidene-2-borneol, are also alpha-anthracene hydrocarbons and are Used to replace some or all of the above alpha-olefins. Similarly, styrene and its related olefins (e.g., alpha-methyl phenyl acetophene, etc.) are also olefins for the purposes of the present invention. Exemplary polyalkylene copolymers include ethylene/propylene, ethylene/butene, ethylene/1-hexene, ethylene/non-octene, ethylene/styrene, and the like. Exemplary terpolymers include ethylene/propylene fluorene-octene, ethylene/propylene/butene, ethylene/butene/1-octene, ethylene/propylene/diene monomer (EPDM), and ethylene/butene/styrene . The copolymer may be random or block. Other olefin interpolymers useful in the practice of this invention include VERSIFY® propylene-based polymers available from The Dow Chemical Company, and are commercially available from ®

ExxonMobil化學公司的VISTAMAXX®丙稀聚合物，至少 那些VERSIFY®及VISTAMAXX®丙烯聚合物具有來自少 於85 mol%的丙烯單元含量。各類其他聚丙烯聚合物的討 論包含於現代塑膠百科全書/砂（尸/α扣 五卵），1988年，十月中期發行，第65卷，第 11期，第6-92頁。 18 201011064 若烯煙互聚物摻合物用於實施本發明，則換合物得以 反應器内或反應ϋ後製程來製作。反應_摻合製程較反 應器後摻合製程為佳，而且使用多數依序連接的反應器的 製程係較㈣反應器祕合製程。這些反應器可含有相同 的催化劑但在不同狀況下操作，例如不同反應物濃度、溫 度、壓力等等’或在相同狀況下操作但是添加不同的催化 劑。 金屬水合物\ 有用於實施本發明的金屬水合物包括，但不特別限制 於’例如具有經基或結晶水的化合物，諸如氫氧化銘及氣 氧化鎮。這些金屬水合物可以單獨使用或兩種以上結合使 用。 商業上了購传之虱氧化鎂的例子包括Matinswerk製 造的MAGNIFIN®。其他例子包括KISUMA 5、kisumaExxonMobil Chemical's VISTAMAXX® propylene polymer, at least those VERSIFY® and VISTAMAXX® propylene polymers have a propylene unit content of less than 85 mol%. A discussion of various other polypropylene polymers is included in Modern Plastic Encyclopedia/Sand (People/A-Bucking Five Eggs), 1988, Mid-October Issue, Vol. 65, No. 11, pp. 6-92. 18 201011064 If the olefinic interpolymer blend is used in the practice of the invention, the compound can be made in the reactor or in a post-reaction process. The reaction _ blending process is better than the reactor after the blending process, and the process of using most of the sequentially connected reactors is better than the (4) reactor splicing process. These reactors may contain the same catalyst but operate under different conditions, such as different reactant concentrations, temperatures, pressures, etc. or operate under the same conditions but with the addition of different catalysts. Metal Hydrate\ Metal hydrates useful in the practice of the invention include, but are not particularly limited to, for example, compounds having a trans- or crystallization water, such as oxyhydroxide and oxidized towns. These metal hydrates may be used singly or in combination of two or more. Examples of commercially available magnesium oxides include MAGNIFIN® manufactured by Matinswerk. Other examples include KISUMA 5, kisuma

5A、KISUMA 5B、KISUMA 5J、KISUMA 5LH 及 KISUMA 5PH(所有商;^及製造均來自KyGwa化學卫業股份有限公 司）。例子of商業上可購得之三（氫氧）化鋁包括 Matinswerk製造的martinal⑧及a—製造的 HYDRAL。 於推合進入組成物之前，金屬水合物可以表面處理劑 (典型上⑦烧表面處理劑）進行表减理，絲面未經處理的 金屬水合物可與表面處理劑—起被掺合進人組餘中以進 行原位的表面處理。添加之表面處理_合練量為足以 、金屬物所要之表面處理的數量。要被加入之表面 19 201011064 處理劑的典型上較佳數量為基於金屬水合物重量至 2.0 wt/0。可以使用任何習於此藝者所熟知的表面處理劑而 不必特別限制、然而’具有有機官能基團的石夕炫表面處理 劑’諸如胺基、異丁稀基、乙烯基、環氧基及疏基基團係 較佳的’並且就阻擋火勢及抗拉性f而言，具有乙稀基及/ 或環氧基的石夕烧表面處理劑是最佳的。 麵合劑： 如上所述，在本發明内文中，耦合劑為一種多官能的 化合物，亦即，一種包括兩種以上官能基團的化合物其 參 在合適的反應條件下能夠經由共價性鍵結連結將兩種以上 聚合物鏈結合在一起。聚（疊氮化物)耦合劑包括烷基及芳香 基疊氮化物、醯基疊氮化物、甲酸疊氮基酯、磷酸基疊氮 化物、膦酸基疊氮化物、矽基疊氮化物及聚(磺醯基疊氮化 物）。聚(磺醯基疊氮化物）為一種含有至少兩個與聚烯烴反 應之活性基團（磺醯基疊氮化物基團（_s〇2N3))的化合物。較 佳地，聚(磺醯基疊氮化物）具有結構X—R_x，其中各X 為-S〇2N3且R代表未取代的或鈍性取代的烴基，烴基醚 參 或含矽基團，較佳地具有足夠的碳、氧或矽，較佳地碳原 子，以充分地分離磺醯基疊氮化物基團來讓聚烯烴及磺醯 基疊氣化物之間進行溫和反應（facile reacti〇n)。可被鈍性取 代進入R的原子或基團的例子包括，但不限於，氟、脂肪 族醚或芳香族醚，矽氧類以及其中兩個以上的聚烯烴鏈連 結在一起的磺醯基疊氮化物基團。R係合適的芳香基、烷 基、烧基芳香基、芳香基炫基石夕烧 '石夕氧類或雜環、如上 20 201011064 述之純性且分離續醯基疊氮化物基團的基團及其他基團。 更佳地’ R包括在續醯基團之間的至少一個芳香基團，最 佳地’至少兩個芳香基團（諸如當尺是4,4，二苯基醚或4,4，_ 聯苯基時）。當R係一芳香基基團時，較佳地，該基團具有 超過一個環，如同在伸萘基雙(磺醯基疊氮化物）。聚(磺醯 基）疊氮化物包括但不限於下列化合物：如丨,5_戊烧雙(續醯 基疊氮化物）、1,8-辛烷雙(磺醯基疊氮化物）、癸烷雙(磺 醯基疊氮化物）、1，10-十八烷雙(磺醯基疊氮化物）、辛基 -2,4,6-笨三(磺醯基疊氮化物）、4,4，_二苯基醚雙(磺醯基疊氮 化物）、I，6·雙(4’績醯胺苯基）己烷、2,7_萘雙(確醯基疊氮化 物）’與每分子平均含有1至8個氣原子及約2至5個磺醯 基疊氮化物基團的氯化脂肪族碳氫化合物的混合的磺醯基 疊氮化物，以及兩種以上上述化合物的混合物。較佳聚(磺 醯基疊氮化物）包括氧-雙(4-磺醯基叠氮基苯）、2,7-萘雙(石黃 醯基疊氮化物）、4,4,雙(磺醯基疊氮基)聯苯基、4,4，-二苯基 醚雙(磺醯基疊氮化物)及雙(4_磺醯基疊氮基苯基）曱烷，與 兩種以上上述化合物的混合物。 矽烷耦合劑的例子包括乙烯基_三作_甲氧基乙氧基)矽 烷、乙烯基三乙氧基矽烷(VTES)、乙烯基三甲氧基矽烷 (VMTS)、γ-(曱基丙稀醯氧丙基)_三甲氧基石夕烷、γ_(曱基丙 烯醯氧丙基）甲基二曱氧基矽烷，γ_環氧丙氧丙基甲基-二乙 氧基矽烷及相似物。VTES及VTMS係較佳的矽烷耦合劑。 21 201011064 用於輕合的耗合劑數量，例如，典型上基於組成物的 結合重量（即聚丙烯、締煙互聚物及金屬水合物的結合重量） 為0·1至6’更典型地Q.l至5及最典型地G.2至3wt%。 添加劑 組成物可含有添加劑’其包括但不限於抗氧化劑、固 化劑、交聯共劑、助爆劑及阻滯劑、加工助劑、填充劑、紫 外線吸收劑或穩定劑、抗靜電劑、成核劑、滑動劑、塑化劑、 潤滑劑、黏度控制劑、增稠劑、抗阻塞劑、介面活性劑、稀 釋油、酸清除劑及金屬去活化劑。可使用之添加劑數量範圍 基於組成物重量從少於約〇 〇1至超過約1〇 wt%。 抗氧化劑的例子如下所示，但不限於此：阻礙酚類(諸如 四[亞甲基(3,5-二三級丁基_4_羥基氫_桂皮酸酯甲烷；雙 [(β-(3,5-二-三級丁基·4_羥基苄基)_甲基羧基乙基)]硫化物， 4,4-硫雙(2-甲基-6-三級丁基酚），4,4’-硫雙(2-三級丁基甲 基酚）’ 2,2’-硫雙(4-曱基_6_三級丁基酚），及硫二乙烯雙〇 ^ 一-二級丁基羥基）氫桂皮酸酯）；亞磷酸鹽及磷灰石（諸如= (2,4_一-二級丁基酚基）亞磷酸鹽及二-三級丁基酚基-磷夜 石），硫化合物(諸如二_十二基硫二丙酸鹽，二_十四基硫二丙 酸鹽，及二硬脂基硫二丙酸鹽）；各種矽烷；聚合的2,2,4-三 甲基_1，2_二氫喹啉，η，η，-雙(1,4-二曱基戊基-Ρ-伸苯基二胺）， 院基化二紛基胺類，4,4，_雙(α，α_二曱基苄基)二酚基胺，二驗 基-Ρ-伸笨基二胺，混合的二·芳香基_ρ_伸苯基二胺類，及其 他阻礙胺抗降解輯穩定劑。可使用的抗氧化讎量為基於 組成物重量約〇.1至約5 wt%。 、 22 201011064 固化劑的例子如下所示：過氧化二異丙基苯 ;雙(〇^-丁5A, KISUMA 5B, KISUMA 5J, KISUMA 5LH and KISUMA 5PH (all businesses; ^ and manufacturing are from KyGwa Chemical Vision Co., Ltd.). Examples of commercially available tris (aluminum hydroxide) include martinal 8 manufactured by Matinswerk and HYDRAL manufactured by a. Before the composition is pushed into the composition, the metal hydrate can be surface-reduced by a surface treatment agent (typically 7-burning surface treatment agent), and the untreated metal hydrate can be blended into the group with the surface treatment agent. The remainder is used for surface treatment in situ. The surface treatment to be added is a quantity sufficient for the surface treatment of the metal object. Surface to be added 19 201011064 A typical preferred amount of treating agent is based on the weight of the metal hydrate to 2.0 wt/0. Any surface treatment agent well known to those skilled in the art may be used without particular limitation, however, 'Shi Xi Xuan surface treatment agent having an organic functional group' such as an amine group, an isobutyl group, a vinyl group, an epoxy group, and The sulfhydryl group is preferred and the zeshi-sinter surface treatment agent having a vinyl group and/or an epoxy group is preferred in terms of blocking fire and tensile properties f. Face Mixing Agent: As described above, in the context of the present invention, the coupling agent is a polyfunctional compound, that is, a compound comprising two or more functional groups capable of undergoing covalent bonding under suitable reaction conditions. The link combines two or more polymer chains together. Poly(azide) couplants include alkyl and aryl azides, sulfhydryl azides, azide formates, phosphoric acid azides, phosphonic acid azides, sulfhydryl azides, and poly (sulfonyl azide). The poly(sulfonyl azide) is a compound containing at least two reactive groups (sulfonyl azide groups (_s〇2N3)) which react with the polyolefin. Preferably, the poly(sulfonyl azide) has the structure X-R_x, wherein each X is -S〇2N3 and R represents an unsubstituted or passively substituted hydrocarbyl group, a hydrocarbyl ether hydrazone or a hydrazine-containing group, Preferably, the carbon has sufficient carbon, oxygen or hydrazine, preferably a carbon atom, to sufficiently separate the sulfonyl azide group to allow a mild reaction between the polyolefin and the sulfonyl-based vaporization (facile reacti〇n ). Examples of atoms or groups that can be bluntly substituted into R include, but are not limited to, fluorine, aliphatic ethers or aromatic ethers, fluorenes, and sulfonyl stacks in which two or more polyolefin chains are linked together. Nitride group. R is a suitable aromatic group, an alkyl group, an alkyl group, an aryl group, a sulphur, or a heterocyclic ring, and a group which is pure and separates a fluorenyl azide group as described in 20 201011064 And other groups. More preferably, 'R includes at least one aromatic group between the hydrazine groups, optimally 'at least two aromatic groups (such as when the ruler is 4, 4, diphenyl ether or 4, 4, _ When phenyl). When R is an aryl group, preferably, the group has more than one ring, as in the case of a naphthyl bis(sulfonyl azide). Poly(sulfonyl) azides include, but are not limited to, the following compounds: ruthenium, 5-pentane bis (continuous decyl azide), 1,8-octane bis(sulfonyl azide), ruthenium Alkane bis(sulfonyl azide), 1,10-octadecane bis(sulfonyl azide), octyl-2,4,6-stupidyl (sulfonyl azide), 4, 4,_Diphenyl ether bis(sulfonyl azide), I,6·bis (4'-decylamine phenyl)hexane, 2,7-naphthalene (anthracene azide)' a mixed sulfonyl azide having a chlorinated aliphatic hydrocarbon having an average of 1 to 8 gas atoms and about 2 to 5 sulfonyl azide groups per molecule, and a mixture of two or more of the above compounds . Preferred poly(sulfonyl azide) includes oxy-bis(4-sulfonyl azide benzene), 2,7-naphthalene bis(sessinyl azide), 4,4, bis(sulfonyl) Azido)biphenyl, 4,4,-diphenyl ether bis(sulfonyl azide) and bis(4-sulfonylazidophenyl)decane, and two or more of the above compounds mixture. Examples of the decane coupling agent include vinyl _ trimethyl methoxyethoxy decane, vinyl triethoxy decane (VTES), vinyl trimethoxy decane (VMTS), γ-(mercapto acrylonitrile) Oxypropyl)-trimethoxy-infraline, γ-(mercapto propylene oxypropyl)methyl decyloxy decane, γ-glycidoxypropylmethyl-diethoxy decane and the like. VTES and VTMS are preferred decane coupling agents. 21 201011064 The amount of the consumable used for the light combination, for example, typically based on the combined weight of the composition (ie, the combined weight of polypropylene, smoky interpolymer and metal hydrate) is from 0. 1 to 6' more typically Ql Up to 5 and most typically G. 2 to 3 wt%. The additive composition may contain additives including, but not limited to, antioxidants, curing agents, crosslinking agents, boosters and retarders, processing aids, fillers, UV absorbers or stabilizers, antistatic agents, Nucleating agents, slip agents, plasticizers, lubricants, viscosity control agents, thickeners, anti-blocking agents, surfactants, diluent oils, acid scavengers, and metal deactivators. The range of additives that can be used ranges from less than about 〇1 to more than about 1% by weight based on the weight of the composition. Examples of antioxidants are shown below, but are not limited thereto: hindering phenols (such as tetrakis [methylene (3,5-di-tri-butyl-4-hydroxyhydro-cinnamic acid methane; double [(β-( 3,5-di-tertiary butyl 4-hydroxybenzyl)-methylcarboxyethyl)]sulfide, 4,4-thiobis(2-methyl-6-tertiary butylphenol), 4 , 4'-thiobis(2-tert-butylmethylphenol)' 2,2'-thiobis(4-mercapto-6-tertiary butylphenol), and thiodiethylene bismuth ^ one-second butyl Hydroxy citrate); phosphite and apatite (such as = (2,4_-di-butyl phenate) phosphite and di-tertiary butyl phenol-phosphorus night stone) , sulfur compounds (such as di-dodecylthiodipropionate, di-tetradecylthiodipropionate, and distearylthiodipropionate); various decane; polymerized 2,2,4- Trimethyl-1,2-dihydroquinoline, η,η,-bis(1,4-didecylpentyl-indole-phenylenediamine), dibasic amines, 4, 4, _bis(α,α-didecylbenzyl)diphenolylamine, di-quinone-oxime-extension base diamine, mixed di-aryl group _ρ_phenylene diamine, and others Blocks amine anti-degradation stabilizers. The amount of antimony oxide that can be used is from about 0.1 to about 5 wt% based on the weight of the composition. , 22 201011064 Examples of curing agents are as follows: diisopropylbenzene peroxide; double (〇^-丁

基-過氧基異丙基)笨；過氧化異丙基異丙基笨丁基；過氧 化t-丁基異丙基苯；過氧化二竹基；2,5-錄丁基過氧 基)-2,5-二甲基己院；2,5_雙卜丁基過氧基)_2,5二甲基己 快3 ’ 1,1雙(t-丁基過氧基)3,3,5_三曱基環己烷；過氧化異丙 基異丙基苯異丙基苯；過氧化二(異丙基異丙基苯）；或其等 的此σ物彳使用的過氧化物固化劑數量基於組成物重量為 4 G·1至5 Wt%。各種其他已知固化共劑、助關及阻滯劑 也可使用’諸如異三聚氰酸三稀丙基醋；乙氧基化的雙紛A 二甲基丙烯酸醋；α-甲基苯乙稀二聚物；及美國專利第 5’346’961及4,018,852號描述的其他共劑。 加工助劑的例子包括但不限於幾酸金屬鹽（諸如硬脂 酸酉曰鋅或硬月日酸醋舞）；脂肪酸(諸如硬脂酸、油酸或芬子 酸）；脂肪醯胺（諸如硬脂醯胺、油酿胺、芬子酿胺或η,η，_乙 稀又硬月曰醯胺），聚乙稀臘；氧化的聚乙稀職；氧化乙稀的 ❹ 聚合物；氧化乙歸及氧化㈣的共聚物；蔬菜臘：石油臘； 非離子介面活性劑；與聚石夕院。可以使用的加工共劑數量 基於組成物重量為約0.05至約5 wt0/〇。 填充劑的例子包括但不限於粘上、沉澱的氧化矽及矽 酸鹽壎化氧化♦碳酸弼、基礎礦物及算術平均顆粒大小 大於15奈米的碳黑。可使用的填充劑數量範圍基於組成物 重量為從少於約0.01至超過約50 wt%。 &成物\ 23 201011064 組成物組份的反應性加工會導致固態、高溫聚合物的 較佳外形。反應性耦合的聚丙烯組成物展現抗熱性、對抗 著火及火焰散佈及較佳地，撓性性質。反應性加工產生較 佳的外形包括，但不限於，聚丙稀及稀烴互聚物的_合。 使用的丙稀均聚物或共聚物可為任何的數量，只要當 組成物未接續交聯饋出時可展現抗熱性及對抗著火及火焰 散佈即可。基於組成物的重量，丙烯均聚物或共聚物可包 括至少10、較佳地至少15及更佳地至少20wt%。組成物 中丙烯均聚物或共聚物最大數量的唯一限制為經濟上、實 @ 施上(例如，減少性回復)及組成物其他組份所需最少數量， 但典型上通常最大量基於組成物的重量包括少於50、較佳 地少於45及更佳地少於40wt%。 ^ 使用的烯烴互聚物可為任何的數量，只要當组成物未 交聯饋出時可展現抗熱性及對抗著火及火焰散佈即可。豨 烴互聚物基於組成物的重量可包括至少10、較佳地至少15 及更佳地至少20wt%。組成物中稀烴互聚物之最大數量的 唯一限制為經濟上、實施上(例如，減少性回復）及組成物其 ® 他組份所需的最少數量，但典型上通常最大量基於組成物 的重量包括少於50、較佳地少於45及更佳地少於40wt%。 使用之金屬水合物可為任何的數量，只要當組成物未 接續交聯饋出時可展現抗熱性、撓性及對抗著火及火焰散 佈的性質即可。金屬水合物基於組成物的重量可包括至少 35、較佳地至少40及更佳地至少50 wt%。組成物中金屬 水合物之最大數量的唯一限制為經濟上、實施上及組成物 24 201011064 其他組份所需的最少數量，但典型上，通常最大量基於組 成物的重里包括少於75、較佳地少於70及更佳地少於 65wt% ° 組成物也可包括雙-磺醯基疊氮化物及抗氧化劑的耦 合套組，抗氧化劑包括但不限於IRGAN〇x@ 1〇1〇或 IRGANOX® MD 1024。此套組包括至少〇 〇5、較佳地至少 0.1及更佳地至少0.2wt%的組成物。組成物中套組之最大 數量的唯一限制為經濟上、實施上及組成物其他組份所需 最少數量’但典型上通常最大量基於組成物的重量包括少 於2、較佳地少於1及更佳地少於〇 5wt%。當組成物在饋 出器或其他混合裝置内以分子溶化物的型式存在時，套組 典型地加入至組成物中。 藉由習於此藝者所熟知的標準設備可達成纜線絕緣材 料的混合。混合設備的例子為内批式混合器，諸如 Banbury™或B〇mngTM内混合器。或者，可使用連續的單 一或雙重扭轉混合器，諸如FarrelTM連續混合器、Werner 及Pfleiderer™雙重扭轉混合器或Buss™揉捏連續饋出 機。使用之混合器類型以及混合器的操作狀況將會影響半 導性材料的性質，諸如黏度、體積電阻性及饋出表面的平 滑度 包括本發明組成物絕緣層的纜線可由各種類型饋出機 製備，例如單一或雙重扭轉型。傳統饋出機的描述記載於 美國專利第4,857,600號中。共饋出及饋出機的例子可在美 國專利第5,575,965號中找到。典型的饋出機在其上游端具 25 201011064 有漏斗且在其下游端具有模件。漏斗將物料注入含有螺旋 器的桶中。在下游端，在螺旋器端及模件之間，具有蒒箱 及打破盤。饋出機的螺热盟〜、1 的螺％1§部分被認為可分為三段，饋入 段、加壓段與計量段，及兩區，後加熱區及前加熱區段 與區沿著上游至下游。在另外例子中，沿著上游至下游的 軸線可具有多個(超過兩個）的加減。若具有超過—個桶， 則4等桶序列連結。各桶之長度對直徑的比例範圍係約 15 · 1至約30 ·卜在饋出之後為聚合絕緣之交聯的導線包 覆操作中’㈣常常立即穿進㈣模件下游的加熱魏 義 區。此加熱固化區的溫度範圍可維持在約2〇〇至約35〇 c、 較佳地、約170 約250 0此加熱區可以加壓蒸氣或是以傳 導加熱的加壓氮氣加熱。然而，藉著實施本發明，可以除 去饋出之後的交聯。 以下的例子說明各種本發明的實施例。除非另有說 明’所有的部分及百分比均以重量計。 特別實施例 六個樣本組成物的分析報告於第1表。三個樣本（比較 Θ 例（CEX)及例1及例3)包括以聚烯烴彈性體（密度 0.870 g/cm3(ASTM D792)的 AFFINITY™ EG 8200 且可由 陶氏化學公司購得）反應性加工的聚丙烯均聚物 (H502-25R)，以及由 Albemarle-Martinswerk 購得的 MAGNIFIN®H5 Mg(OH2)。兩樣本(例2及例4)包括以超低 密度聚乙烯(購自陶氏化學公司的ATTANE SC4107)反應性 加工的聚丙烯均聚物（H502-25R)，以及MAGNIFIN® H5 26 201011064Base-peroxyisopropyl) stupid; isopropylisopropyl butyl butyl peroxide; t-butyl cumene peroxide; diphenyl peroxide; 2,5-butyl peroxy )-2,5-dimethylhexyl; 2,5-di-dibutylperoxy)_2,5-dimethylhexyl 3' 1,1 bis(t-butylperoxy)3,3,5 _Trimethylcyclohexane; isopropyl cumyl isopropyl benzene peroxide; bis(isopropyl cumene) peroxide; or a peroxide curing agent for the sigma The amount is from 4 G·1 to 5 Wt% based on the weight of the composition. Various other known curing co-agents, assisting and retarding agents can also be used, such as tri-propyl propyl acetonate; ethoxylated bis-A methacrylate; α-methyl styrene Dilute dimer; and other co-agents described in U.S. Patent Nos. 5'346'961 and 4,018,852. Examples of processing aids include, but are not limited to, a few acid metal salts (such as zinc strontium stearate or hard vinegar dance); fatty acids (such as stearic acid, oleic acid or fenic acid); fatty guanamines (such as Stearylamine, oleoresin, fennel amine or η, η, _ ethylene and hard rutheniumamine, polyethylene; oxidized polyethylene; oxidized ethylene ❹ polymer; oxidation Copolymer of B and Oxidation (4); vegetable wax: petroleum wax; non-ionic surfactant; and Ju Shi Xi Yuan. The amount of processing co-agent that can be used is from about 0.05 to about 5 wt0/〇 based on the weight of the composition. Examples of fillers include, but are not limited to, cohesive, precipitated cerium oxide and strontium strontium oxide strontium carbonate, base minerals, and carbon black having an arithmetic mean particle size greater than 15 nanometers. The amount of filler that can be used ranges from less than about 0.01 to more than about 50 wt% based on the weight of the composition. & Objects\ 23 201011064 The reactive processing of the composition components results in a better shape of the solid, high temperature polymer. The reactively coupled polypropylene composition exhibits heat resistance, resistance to fire and flame spread, and, preferably, flexibility properties. Reactive processing yields better shapes including, but not limited to, polypropylene and dilute hydrocarbon interpolymers. The propylene homopolymer or copolymer used may be any amount as long as the composition exhibits heat resistance and resistance to ignition and flame spread when the composition is not continuously fed out. The propylene homopolymer or copolymer may comprise at least 10, preferably at least 15 and more preferably at least 20% by weight, based on the weight of the composition. The only limitation on the maximum amount of propylene homopolymer or copolymer in the composition is the minimum amount required for economical, practical (e.g., reduced recovery) and other components of the composition, but typically the maximum amount is typically based on the composition. The weight comprises less than 50, preferably less than 45 and more preferably less than 40% by weight. ^ The olefin interpolymer used may be any amount as long as the composition exhibits heat resistance and resistance to fire and flame spread when the composition is not cross-linked. The hydrocarbon cross-linking agent may comprise at least 10, preferably at least 15 and more preferably at least 20% by weight, based on the weight of the composition. The only limitation on the maximum amount of dilute hydrocarbon interpolymer in the composition is the minimum amount required for economics, implementation (eg, reduced recovery), and composition/components thereof, but typically the maximum amount is based on the composition. The weight comprises less than 50, preferably less than 45 and more preferably less than 40% by weight. The metal hydrate to be used may be any amount as long as the composition exhibits heat resistance, flexibility, and resistance to ignition and flame spread when the composition is not continuously fed out. The metal hydrate may comprise at least 35, preferably at least 40 and more preferably at least 50 wt%, based on the weight of the composition. The only limit on the maximum amount of metal hydrate in the composition is the minimum amount required for the economic, the implementation, and the other components of the composition 24 201011064, but typically the maximum amount is usually less than 75 based on the weight of the composition. Preferably, the composition may comprise less than 70 and more preferably less than 65% by weight. The composition may also comprise a coupling set of bis-sulfonyl azide and an antioxidant, including but not limited to IRGAN〇x@1〇1〇 or IRGANOX® MD 1024. The kit comprises at least 〇5, preferably at least 0.1 and more preferably at least 0.2% by weight of the composition. The only limitation on the maximum number of sets in a composition is the minimum amount required for economics, implementation, and other components of the composition' but typically the usual maximum amount includes less than 2, preferably less than 1, based on the weight of the composition. And more preferably less than 〇5wt%. When the composition is present in the form of a molecular melt in a feeder or other mixing device, the kit is typically added to the composition. The mixing of the cable insulation material can be achieved by standard equipment well known to those skilled in the art. An example of a mixing device is an internal batch mixer such as a BanburyTM or B〇mngTM internal mixer. Alternatively, a continuous single or double twist mixer can be used, such as a FarrelTM continuous mixer, a Werner and PfleidererTM double torsion mixer or a BussTM kneading continuous feeder. The type of mixer used and the operating conditions of the mixer will affect the properties of the semiconducting material, such as viscosity, volume resistivity, and smoothness of the feed surface. The cable comprising the insulating layer of the composition of the present invention can be used by various types of feeders. Prepared, for example, single or double twisted. A description of a conventional feeder is described in U.S. Patent No. 4,857,600. An example of a co-feedout and a feeder can be found in U.S. Patent No. 5,575,965. A typical feeder has a funnel at its upstream end 25 201011064 and has a module at its downstream end. The funnel injects material into the bucket containing the screw. At the downstream end, between the end of the screw and the module, there is a box and a breaking disk. The screw part of the feeder, the snail %1 § part of the screw is considered to be divided into three sections, the feed section, the pressurization section and the metering section, and the two zones, the rear heating zone and the front heating section and the zone edge From upstream to downstream. In another example, there may be multiple (more than two) additions and subtractions along the upstream to downstream axis. If there are more than one bucket, the four buckets are linked. The ratio of the length to the diameter of each barrel ranges from about 15 · 1 to about 30 · In the wire coating operation for the cross-linking of the polymeric insulation after the feeding out, '(4) often penetrates immediately (4) the heating Weiyi area downstream of the module . The heat curing zone can be maintained at a temperature in the range of from about 2 Torr to about 35 Torr c, preferably from about 170 to about 250. The heated zone can be pressurized with steam or heated with a pressurized heated pressurized nitrogen. However, by practicing the present invention, cross-linking after feeding out can be eliminated. The following examples illustrate various embodiments of the invention. Unless otherwise stated, all parts and percentages are by weight. Special Examples The analysis of the six sample compositions is reported in Table 1. Three samples (Comparative Examples (CEX) and Examples 1 and 3) included reactive processing with a polyolefin elastomer (AFFINITYTM EG 8200 at a density of 0.870 g/cm3 (ASTM D792) and available from The Dow Chemical Company). Polypropylene homopolymer (H502-25R), and MAGNIFIN® H5 Mg (OH2) available from Albemarle-Martinswerk. Two samples (Examples 2 and 4) included a polypropylene homopolymer (H502-25R) reactively processed with ultra low density polyethylene (ATTANE SC4107 from The Dow Chemical Company), and MAGNIFIN® H5 26 201011064

Mg(OH2)。例5包括丙烯衝擊共聚物(C705-44NAHP)及烯烴 互聚物(VERSIFY™ 3300, 12莫耳百分比的乙烯及88莫 耳百分比的丙烯，密度為0.866 g/ cm3及MFR為9.8g/10 min(230°C/21.6kg))，兩者皆購自陶氏化學公司。 除了上述組份之外，樣本也包括購自杜邦公司（E.I.du Pont de Nemours and Company)的 FUSABOND® 494，其係 一種順丁烯二酸酐接枝的聚乙烯（密度為0.87 g/cc)。樣本也 包括 IRGANOX MD 1024、IRGANOX PS 802DSDP 及 CHIMASSORB 944、IRGANOX MD 1024 係一種購自汽巴 (Ciba)特用品化學的金屬去活化劑及抗氧化劑，IRGAN〇x PS 802DSDP係一種用作與酚抗氧化劑（也購自汽巴特用品 化學）相結合的熱穩定劑，CHIMASSORB 944係一種受阻 胺的光穩定劑（也購自汽巴特用品化學）。例3、4及5也包 括IRGANOX 1010，其係一種抗氧化劑。例i_2及5與比 較例也包括Dow-Corning MB 50-001，其係一種含有分散於 聚丙烯均聚物中之50%超高分子量矽氧類聚合物的配方。 例1-2及5更包括雙磺醯基疊氮化物(BSA)及IRGANOX 1010的額外套組。EX 3及4更包括XL PEarl矽烷，其係 一種過氧化物、乙烯基三烷氧矽烷與矽烷去氫_縮合催化劑 的混合物。過氧化物在混合期間分解，造成乙烯基矽烷接 枝至聚合物鏈。在混合期間從金屬水合物釋出的少量濕氣 與去氫-縮合催化劑結合因而造成矽烧-接枝聚合物鏈的耗 合。 第1表 27 201011064 測試樣本的配方 比較 例 例1 例2 例3 例4 例5 PP(HP)H502-25R(°/〇) 15 15 15 14 14 C705-44NAHP(%) 15 AFFINITY EG8200(%) 32.3 32 31 ATTANE SC4107(%) 32 31 VERSIFY 3300.00(%) 32 FUSABOND 494(%) 2 2 2 2 2 2 MAGNIFIN® H5 MV(%) ~~50 50 50 50 50 50 IRGANOX MD 1024(%) 0.2 0.2 0.2 0.2 0.2 0.2 CHIMASSORB HALS 944(%) 0.2 — 0.2 0.2 0.2 0.2 0.2 IRGANOX 1010(%) 0.2 0.2 0.2 IRGANOX PS 802 DSTDP(%) 0.1 0.1 0.1 0.1 0.1 0.1 Dow-Corning MB 50-001(PP 為底 5 0%)(%) 0.2 0.2 0.2 0.2 含 IRGANOX 1010 的 BSA分子熔化體(％) 0.3 0.3 0.3 XI PEARL 矽烷(％) 2.3 2.3 總量(wt%) 100 100 100 100 100 100 多個樣本用於測試彎曲係數、熔化流動指數、熱機械 分析γγμα)、熱m性或熱灿及抗張性，其等係以下述方 法製備：在16代下於^i1(1.27 mm)模具中模製（來自混 合碗的材料)達Π)分鐘’接著在㈣料下固化6小時， 、製備冑板。多個狗骨狀物件(㈣如⑽)被切下且被 試以提供平均測試值。 201011064 依據ISO 178試驗彎曲性質並報告於第2表中。彎曲 試驗測量在3點載重的狀況下彎曲橫桿所需要的力量。彎 曲係數用於表示當材料撓屈時，材料的堅硬程度。 第2表 測試樣本依據IS0179的彎曲試驗結果（1 mm/min) 比較例 例1 例2 例3 例4 例5 (MPa)~~ 250.7 204.4 687.5 331.8 303.3 260.4Mg(OH2). Example 5 included propylene impact copolymer (C705-44NAHP) and olefin interpolymer (VERSIFYTM 3300, 12 mole percent ethylene and 88 mole percent propylene, density 0.866 g/cm3 and MFR 9.8 g/10 min) (230 ° C / 21.6 kg)), both purchased from The Dow Chemical Company. In addition to the above components, the samples also included FUSABOND® 494, available from E. I. du Pont de Nemours and Company, which is a maleic anhydride grafted polyethylene (density 0.87 g/cc). The samples also include IRGANOX MD 1024, IRGANOX PS 802DSDP and CHIMASSORB 944, IRGANOX MD 1024, a metal deactivator and antioxidant from Ciba special chemicals, and IRGAN〇x PS 802DSDP is used as a phenol resistant CHIMASSORB 944 is a light stabilizer for hindered amines (also purchased from Steamer Chemicals) as a heat stabilizer combined with oxidant (also purchased from Steamer Chemicals). Examples 3, 4 and 5 also included IRGANOX 1010, which is an antioxidant. Examples i_2 and 5 and Comparative Examples also include Dow-Corning MB 50-001, which is a formulation containing a 50% ultrahigh molecular weight oxime polymer dispersed in a polypropylene homopolymer. Examples 1-2 and 5 further include an additional set of disulfonyl azide (BSA) and IRGANOX 1010. EX 3 and 4 further include XL PEarl decane which is a mixture of a peroxide, a vinyl trialkoxysilane and a decane dehydrogenation-condensation catalyst. The peroxide decomposes during mixing, causing the vinyl decane to graft to the polymer chain. The small amount of moisture released from the metal hydrate during mixing combines with the dehydrogenation-condensation catalyst thus resulting in the consumption of the calcined-grafted polymer chain. Table 1 27 201011064 Formulation comparison of test samples Example 1 Example 2 Example 3 Example 4 Example 5 PP(HP)H502-25R(°/〇) 15 15 15 14 14 C705-44NAHP(%) 15 AFFINITY EG8200(%) 32.3 32 31 ATTANE SC4107 (%) 32 31 VERSIFY 3300.00 (%) 32 FUSABOND 494 (%) 2 2 2 2 2 2 MAGNIFIN® H5 MV (%) ~~50 50 50 50 50 50 IRGANOX MD 1024 (%) 0.2 0.2 0.2 0.2 0.2 0.2 CHIMASSORB HALS 944 (%) 0.2 — 0.2 0.2 0.2 0.2 0.2 IRGANOX 1010 (%) 0.2 0.2 0.2 IRGANOX PS 802 DSTDP (%) 0.1 0.1 0.1 0.1 0.1 0.1 Dow-Corning MB 50-001 (PP bottom 5 0%) (%) 0.2 0.2 0.2 0.2 BSA molecular melt (%) containing IRGANOX 1010 0.3 0.3 0.3 XI PEARL decane (%) 2.3 2.3 Total (wt%) 100 100 100 100 100 100 Multiple samples for testing Bending coefficient, melt flow index, thermomechanical analysis γγμα), thermal m or thermal and tensile properties, etc. were prepared by molding in a mold of ^i1 (1.27 mm) in 16 generations (from mixing) The material of the bowl) was Π) minutes and then cured under (4) for 6 hours to prepare a seesaw. A plurality of dog bone pieces ((iv) as (10)) were cut and tested to provide an average test value. 201011064 Test bending properties according to ISO 178 and reported in Table 2. The bending test measures the force required to bend the crossbar at a 3-point load. The bending coefficient is used to indicate how hard the material is when the material is flexed. Table 2 The test sample is based on the bending test results of IS0179 (1 mm/min). Comparative Example 1 Example 2 Example 3 Example 4 Example 5 (MPa)~~ 250.7 204.4 687.5 331.8 303.3 260.4

依據IS01133在230C試驗炼化流動指數並報告於第 3表中。三種特定的重量2·l6kg、5kg及21·6kg顯示於第 3表。 ^試樣本使用IS〇U33 ^230oC下的熔化流動指數 比較例 例1 例2 例3 例4 例5 2.16 kg 3.17 5 kg 0.52 21.6 kg 7.62 5.75 0.36 20.68 熱機械分析(TMA)係一種探針穿透試驗，其中以固定 速率加熱樣本並將穿透起始的溫度(軟化溫度)報告為TMA 溫度。六個樣本的TMA溫度報告於第4表中。 溫度(°C) 測試樣本的熱機械分析(在5»c/min的】mm穿透) 151.6 154.6 例5 229.9 144.2 第5表報告150。(：下測量六個樣本巾各個樣本的熱固 性結果。 29 201011064 第5表 測試樣本依據ΕΝ 60811-2-1在150°(：/20ΝΑΜη2下的熱固性試驗 比較例 例1 例2 例3 例4 例5 熱5i長（％) 破裂 115 47 61 7 215 放鬆延長(％) 63 25 32 1 204 第6表報告200°C下測量六個樣本中各個樣本的熱固 性結果。 第6表 測試樣本依據EN 60811-2-1在200°C/20N/cm2下的熱固性試驗 〇 比較 例 例1 例2 例3 例4 例5 熱延長(％) 破裂 破裂 >200 >200 15 未測 言式 放鬆延長(％) 34 第7表報告六個測試樣本的抗張性質。 第7表 測試樣本依據EN 60811-1-1在50mm/min下的抗張性質 比較例 例1 例2 例3 例4 例5 最終抗張強度(Mpa) 4.7 9.1 10.3 6.3 9.0 12.1 在破裂時的延長（％) 424 520 300 366 406 675 在上述的組成物中，以聚烯烴彈性體(AFFINITY®)或 超低密度聚乙烯(ATTANE®)或甚至是低乙烯含量的烯烴互 聚物(VERSIFYtm)反應性加工的丙烯均聚物，當未接續交聯 而饋出時，其展現（1)抗熱性、（2)對抗著火及火焰散佈及(3) 30 201011064 撓性。這些性質使得這些組成物適合於纜線應用，諸如 125°C等級的機動導線。 雖然本發明已經經由前述的說明詳盡地描述，但是如 此詳盡的說明只是為了說明的目的並不因此被解釋為對於 下述申請專利範圍的限制。所有引述的報告、參考文獻、 美國專利、獲准的美國專利申請案及美國專利申請公開案 均併入此處作為參考。 【圖式簡單說明】 ® (無） 【主要元件符號說明】 (無） 31The refining flow index was tested at 230C according to IS01133 and reported in Table 3. Three specific weights of 2·16 kg, 5 kg, and 21.6 kg are shown in Table 3. ^Sample used for comparison of melt flow index at IS〇U33 ^230oC Example 1 Case 2 Case 3 Case 4 Case 5 2.16 kg 3.17 5 kg 0.52 21.6 kg 7.62 5.75 0.36 20.68 Thermomechanical analysis (TMA) is a probe wear A test was conducted in which the sample was heated at a fixed rate and the temperature at which the penetration started (softening temperature) was reported as the TMA temperature. The TMA temperatures for the six samples are reported in Table 4. Temperature (°C) Thermomechanical analysis of the test specimen (mm penetration at 5»c/min) 151.6 154.6 Example 5 229.9 144.2 Table 5 Report 150. (: The thermosetting results of each sample of six sample towels are measured. 29 201011064 The test sample of the fifth table is based on the thermostat test of ΕΝ 60811-2-1 at 150° (:/20ΝΑΜη2). Comparative example 1 case 2 case 3 case 4 case 5 Heat 5i length (%) Rupture 115 47 61 7 215 Relaxation extension (%) 63 25 32 1 204 Table 6 reports the thermosetting results of each of the six samples measured at 200 ° C. Table 6 Test samples according to EN 60811 -2-1 Thermoelectricity test at 200 ° C / 20 N / cm 2 〇 Comparative Example 1 Example 2 Example 3 Example 4 Example 5 Thermal elongation (%) Rupture and rupture > 200 > 200 15 Untested relaxation relaxation ( %) 34 Table 7 reports the tensile properties of six test samples. Table 7 Test samples according to EN 60811-1-1 Tensile properties at 50 mm/min Comparative Example 1 Example 2 Example 3 Example 4 Example 5 Final Tensile strength (Mpa) 4.7 9.1 10.3 6.3 9.0 12.1 Extension at break (%) 424 520 300 366 406 675 In the above composition, polyolefin elastomer (AFFINITY®) or ultra low density polyethylene (ATTANE) ®) or even a low ethylene content olefin interpolymer (VERSIFYtm) reactively processed propylene homopolymer When fed out without cross-linking, it exhibits (1) heat resistance, (2) resistance to fire and flame spread, and (3) 30 201011064 flexibility. These properties make these compositions suitable for cable applications such as 125°. C-grade motorized wire. Although the invention has been described in detail above with the foregoing description, the detailed description is only for the purpose of illustration and is not construed as a limitation of the scope of the claims below. U.S. Patent, Approved U.S. Patent Application, and U.S. Patent Application Serial No. are hereby incorporated by reference.

Claims (1)

201011064 七、申請專利範圍： 1. 一種用於耦合丙稀聚合物及烯烴互聚物的方法，該方法 包括在反應性加工狀況下接觸至少： A. 10 wt%的至少一丙烯聚合物； B. 10 wt%的至少一晞烴互聚物； C. 35 wt%的至少一金屬水合物； D. 耦合數量的耦合劑；及 E. 任意地，一或多個添加劑。 2. 如申請專利範圍第1項的方法，其中該耦合劑係聚(磺醯 基)疊氮化物及含有乙稀基基團之矽烷的至少一者。 3. 如申請專利範圍第1-2項中任一項的方法，其中該耦合 劑存在的數量係基於該丙烯聚合物、烯烴互聚物及金屬 水合物之結合重量的0.1至6重量百分比。 4. 如申請專利範圍第1-3項中任一項的方法，其中該反應 性加工狀況包括150至280°C的溫度。 5. 如申請專利範圍第1-4項中任一項的方法，其中該烯烴 互聚物為非常低密度聚乙烯；均質分枝的、線性乙烯/V-烯烴共聚物；均質分枝的、實質線性乙烯/V-烯烴聚合 物；線性中密度聚乙烯、線性低密度聚乙烯、超低密度 聚乙烯及烯烴多嵌段共聚物的至少一者。 6. 如申請專利範圍第1-5項中任一項的方法，其中該烯烴 互聚物係均質分枝的、實質線性乙稀/V-稀烴聚合物，其 單元含量中來自乙烯單元的含量係至少80 wt°/〇及密度 係至少 0.870 g/cm3。 201011064 7. 如申請專利範圍第4項的方法，其中該金屬水合物係氫 氧化鋁及氫氧化鎂的至少一者。 8. 如申請專利範圍第1-7項中任一項的方法，其中一抗氧 化劑存在的數量係基於該丙烯聚合物、烯烴互聚物及金 屬水合物之結合重量的0.01至10 wt%。 9. 一種由申請專利範圍第1-8項中任一項的方法製成的組 成物。 10. 如申請專利範圍第9項的組成物，其呈現導線或纜線絕 緣鞠的型式。201011064 VII. Patent Application Range: 1. A method for coupling an acryl polymer and an olefin interpolymer, the method comprising contacting at least: A. 10 wt% of at least one propylene polymer under reactive processing conditions; 10 wt% of at least one anthracene hydrocarbon interpolymer; C. 35 wt% of at least one metal hydrate; D. a coupling amount of a coupling agent; and E. optionally, one or more additives. 2. The method of claim 1, wherein the coupling agent is at least one of a poly(sulfonyl) azide and a decane containing a vinyl group. 3. The method of any one of claims 1-2, wherein the coupling agent is present in an amount of from 0.1 to 6 weight percent based on the combined weight of the propylene polymer, olefin interpolymer, and metal hydrate. 4. The method of any one of claims 1-3, wherein the reactive processing condition comprises a temperature of from 150 to 280 °C. 5. The method of any one of claims 1-4, wherein the olefin interpolymer is a very low density polyethylene; a homogeneous branched, linear ethylene/V-olefin copolymer; homogeneously branched, Substantially linear ethylene/V-olefin polymer; at least one of linear medium density polyethylene, linear low density polyethylene, ultra low density polyethylene, and olefin multi-block copolymer. 6. The method of any one of claims 1-5, wherein the olefin interpolymer is a homogeneously branched, substantially linear ethylene/V-dilute hydrocarbon polymer having a unit content derived from an ethylene unit. The content is at least 80 wt ° / 〇 and the density is at least 0.870 g / cm 3 . The method of claim 4, wherein the metal hydrate is at least one of aluminum hydroxide and magnesium hydroxide. 8. The method of any one of claims 1-7, wherein an antioxidant is present in an amount of from 0.01 to 10% by weight based on the combined weight of the propylene polymer, the olefin interpolymer, and the metal hydrate. 9. A composition made by the method of any one of claims 1-8. 10. The composition of claim 9 of the patent application, which presents a pattern of wire or cable insulation. 33 201011064 四、指定代表圖： (一) 本案指定代表圖為：第（ ）圖。（無) (二) 本代表圖之元件符號簡單說明： 五、本案若有化學式時，請揭示最能顯示發明特徵的化學式： 201011064 發明專利說明書 細胸 '(本說明書格式、順序，請勿任意更動，※記號部分請勿填寫—-— -— ※申請案號：？个？ ※申請曰： 分類： 一、 發明名稱：（中文/英文） 經反應性加工之具有聚丙烯及烯烴互聚物的抗高熱組成物 REACTIVELY PROCESSED, HIGH HEAT RESISTANT COMPOSITION OF POLYPROPYLENE AND AN OLEFINIC INTERPOLYMER 二、 中文發明摘要： 一種丙烯聚合物耦合烯烴互聚物的方法，包括於反應性加工狀況 攀下至少接觸： A. 10 wt%的至少一丙稀聚合物； B. 10 wt%的至少一烯烴互聚物； C. 35 wt%的至少一金屬水合物；及 D. 柄合數量的耗合劑， 各重量百分比基於該丙烯聚合物、烯烴互聚物及金屬水合物的結合重 η 量。由包括該耦合之聚合物的組成物製造的導線及纜線絕緣鞘展現所 欲的抗熱性質。33 201011064 IV. Designation of representative drawings: (1) The representative representative of the case is: ( ). (None) (2) A brief description of the symbol of the representative figure: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 201011064 Patent description of the invention is a thin chest '(The format and order of this manual, please do not Change, ※Do not fill in the mark----- ※Application number:?? ※Application曰: Classification: I. Name of the invention: (Chinese/English) Reactively processed with polypropylene and olefin interpolymer The anti-high heat composition REACTIVELY PROCESSED, HIGH HEAT RESISTANT COMPOSITION OF POLYPROPYLENE AND AN OLEFINIC INTERPOLYMER II. Abstract: A method for coupling olefin polymer to olefin interpolymer, including at least contact with reactive processing conditions: A. 10 a wt% of at least one propylene polymer; B. 10 wt% of at least one olefin interpolymer; C. 35 wt% of at least one metal hydrate; and D. a handle amount of the consumable, each weight percentage based on a combined weight η of a propylene polymer, an olefin interpolymer, and a metal hydrate. Manufactured from a composition comprising the coupled polymer Wire and cable insulation sheaths exhibit desirable thermal properties. 三、英文發明摘要： A propylene polymer is coupled with an olefinic interpolymer by a process comprising contacting under reactive processing conditions at least: A. 10 wt% of at least one propylene polymer; B. 10 wt% of at least one olefinic interpolymer; C. 35 wt% of at least one metal hydrate; and D. A coupling amount of a coupling agent, each weight percent based on the combined weight of the propylene polymer, olefinic interpolymer and metal hydrate. Wire and cable insulation sheaths made from compositions comprising the coupled polymer exhibit desirable heat resistance. 1 201011064 六、發明說明： 【明所屬々貝^^ J 相關申請案的交互參考 本申請案主張2008年6月6日提出申請之美國專利申 請案序號第61/059,356號的優先權，其全部内容併入此處 作為參考。 發明領域 本發明關於一種包括聚丙浠聚合物及稀烴互聚物的組 ® 成物。於一態樣中，本發明關於一種包括經過反應性加工 之聚丙烯及烯烴互聚物的組成物，其顯示適用於導線及境 線包覆的抗南熱特性。於另一態樣中，本發明關於一種包 括絕緣層的電纜線，於又一態樣中，本發明關於一種電境 * 線其中絕緣層包括含有經過反應性加工之聚丙烯及烯烴互 - 聚物的組成物。 發明背景 聚合組成物經常被用作導線及纜線的基本絕緣材料。 作為一種絕緣物，該組成物應該展現各種物理及電氣性 質，諸如抗熱性，對抗機械切割，對抗應力碎裂及介電性 失效。用於電導體的絕緣材料常常需要交聯以達到所欲的 抗熱性。 交聯可藉由數種機制被引入聚合物的不同分子鏈之 間，其中一個機制係將化學反應性化合物接枝至構成巨大 聚合物的個別聚合物主鏈或鏈上，以這種方式使得在一主 3 201011064 鏈上的接枝化合物接著可與另一主鏈上的類似接枝化合物 反應，由此形成交聯。這個方法的例示為&quot;石夕烧交聯&quot;的方 法。 矽烷交聯方法利用交聯聚合物分子的含矽烷化合物。 在成形或模製操作之前或是成形或模製操作期間，藉由使 用適合數量的有機過氧化物或其他自由基啟始劑，石夕燒可 被接枝至適合的聚合物。其他成份諸如穩定劑、色素、填 充劑、催化劑、加工助劑及相似物也可被包括在混合物中。 當使用♦烧-過氧化物摻合物於聚合物交聯時，在接枝 效率及加工效率，諸如饋出速率與進行次數之間必須取得 妥協。因為需要嚴格控制加工過程，所以很難以這種方式 形成可交聯材料。例如，若此方法在太高的溫度下執行， 聚合物會在加工裝置(例如饋出器）中部分交聯，致使其後難 以獲得品質一致的良好產品。由於需要從加工設備移除部 分父聯產品之故，因此也會發生加工遲延。於後續加熱進 行父聯過程期間也要特別地小心，以確保由聚合物製備的 物件依然保留其等的形狀。 更且，當使用高度反應性矽烷·過氧化物摻合物時，會 發生膠狀物形成、螺紋產生及焦化現象。對於利用加工條 件及加工設備以在嚴格的熔化及混合狀況下於聚烯烴中產 生高剪應力的加工過程而言，上述問題係嚴重的。這些問 題通常來自於在最初熔化與均質化過程期間，過氧化物過 早，及最終完全的活化。傳統上，藉由使用較低反應性的 201011064 矽烷摻合物來處理這個問題，但是這種方法會降低交聯反 應的接枝效率。 另一個交聯方法係使用輻射。輻射交聯需要複雜的設 備，因此執行費用昂貴。更且，輻射會造成聚合物因氧化 及/或鏈剪切而降解，因而聚合物更需要特別的穩定化。更 且，就外套厚度與纜線的整體直徑兩者而言，可被商業輻 射設備操作的纜線大小是有限制的。當外套係非一致交聯 時，这種限制典型地更加明顯，並且造成纜線周緣或外套 φ 材料壁内部之物理性質的變化結果。 另外的材料，諸如聚胺甲酸酯及氟化乙烯丙烯彈性 體，係昂貝的，且该等材料對水敏感。此外，對於使這些 材料得以對抗火焰而言，由素常常是必要的，這樣也使得 - 這些化合物減少了許多吸引力。 - 所以，對於導線及纜線工業而言，其等依然需要及期 待一種聚烯烴組成物，該聚烯烴組成物可以不需要進一步 地交聯即被饋出，並且展現抗熱性與對抗著火及火焰散佈 Φ 的性質，更佳地’具有良好的撓性。 c發明内容1 發明概要 於一實施例中，本發明關於一種包括聚丙烯聚合物的 耝成物，該聚丙烯聚合物以烯烴互聚物反應性加工，使得 該组成物展現抗熱性與對抗著火及火焰散佈的性質。此 外，該組成物也展現良好的撓性。 201011064 於本發明-實施例中…细於耗合丙稀聚合物及稀烴 互聚物的方法，财法包括在反賴加域況下接觸至少： A. 10 wt°/。的至少一丙烯聚合物； B. 10 wt%的至少一烯烴互聚物； C· 35 wt%的至少一金屬水合物；及 D.耗合數量的輕合劑， 各重量百分比係基於丙烯聚合物、烯烴互聚物及金屬水合 物的結合重量。典型地’該耦合劑係⑴具有乙烯基基團的 矽烷，或者(ii)聚(疊氮化物）。 聚丙稀聚合物可為均聚物或共聚物。烯烴互聚物包 括’但不限於，非常低密度聚乙烯(VLDPE)，均質分枝的、 線性乙烯/α-烯烴共聚物，均質分枝的，實質線性乙烯/(χ_ 稀煙共聚物，線性中密度聚乙烯，線性低密度聚乙烯 (LLDPE) ’超低密度聚乙烯(ULDPE)，及多嵌段烯烴聚合 物。用於本發明的金屬水合物包括，但不限於，氫氧化鋁 及氫氧化鎂。 於本發明一實施例中，一種包括絕緣層的纜線，該絕 緣層包括一種含有反應性加工聚丙烯聚合物、烯烴互聚物 及金屬水合物的組成物。 t貧施方式】 較佳實施例的詳細說明 本揭露的數字範圍係大致的，因此除非另有說明，否 則可以包括範圍之外的數值。假設在任一較低數值及任一 較高數值之間至少具有分離的兩單位的話，則數字範圍包 201011064 括以一單位方式增值之較低與較高數值在内的所有數值。 舉例而言，若是組成、物理或其他性質，諸如，例如分子 量、黏度、融熔指數等等，係從100至1000，那麼所有個 別的數值，諸如100、101、102等等，以及次範圍，諸如 100至144、155至170、197至200等等，係被明白地列 舉。就含有少於一的數值或含有大於一的小數(例如1.1， 1.5等等）範圍而言，一單位被認為是0.0001、0.001、0.01 或0.1，依情形而定。就含有少於十的一位數(例如1至5) 的範圍而言，一單位典型上被認為是0.1。這些只是特別想 要的例子而已，例示的最低數值與最高數值之間所有可能 的數字數值組合也被認為為本揭露所明白表示。除了其他 情況之外，本揭露均提供相對於聚合物的抗樹劑數量、製 程狀況、添加劑數量及分子量的數字範圍。 “纜線”“電纜線”與類似術語意指在保護套或鞘之内 的至少一導線或光纖。典型上，纜線係黏結在一起的兩個 或多個導線或光纖，典型上在同一個保護套或鞘内。保護 套内的個別導線或光纖可以是裸線、具有覆蓋物或絕緣 物。組合纜線可含有電導線及光纖兩者。纜線等等可設計 成用於低、中及高電壓。 &quot;聚合物”意指由聚合單體（不管是相同或不同類型者) 製備的聚合化合物。此一般性術語聚合物因此含括術語均 聚物與術語共聚物，均聚物通常用於指稱由單一類型單體 製備的聚合物，共聚物定義於下。 201011064 &quot;互聚物&quot;、&quot;共聚物”及類似術語意指由至少兩不同類髮 之單體的聚合反應而製備的聚合物。這些一般性術語指稱 由兩不同類型單體製備的聚合物，以及指稱由超過兩不同 類型之單體製備的聚合物，例如三聚物、四聚合物等等。 “聚烯烴”、“p〇”及類似術語意指簡單烯烴衍生的聚合 物。許多聚烯烴是熱塑性的，且為本發明之故，可包括橡 膠相。代表性聚烯烴包括聚乙烯、聚丙烯、聚丁稀、聚異 戊一缔及其等的各種互聚物。 “摻合物”、“聚合物摻合物”及類似術語意指兩或多個 材料的混合物，例如兩或多個聚合物，至少—聚合物及至 少—抗水樹劑等等的的混合物。此種摻合物可以是互溶戋 不互溶的。此種摻合物可以是相分離的或不是相分離的。 基於穿透電子光譜、光散射、X射線散射或任何習於此藝者 已知的方法，此種摻合物可以含有一或多個主要構形或不 具—或多個主要構形。 组成物 I乃次類似術語意指兩種以上組份之摻 合物的混合。於用以製魏_或其他物件之材料的混合 或摻合物内部，該組成物包括所有混合的組份，例如，辆 合的丙烯聚合物及烯煙互聚物、金屬水合物'未_合的聚 合物及耦合劑，與任何其他的添加劑(諸如加工：化 劑等等）。 ^ &quot;分子溶化物&quot;意指在室溫下至少—部分係非結晶型的 耗合劑（改質劑)及抗氧化劑的摻合物，任意地也包含例如描 述於W〇2()〇3/_229 A1的其他聚合物添加。 201011064 抗氧化劑兩者至少部分包含於摻合物的非結晶相中。而 且，較佳地，耦合劑及抗氧化劑形成一錯合物，與單獨耦 合劑中形成氮烯基團之基團的拉曼光譜相較，該錯合物關 於形成氮烯基團之基團的拉曼光譜(Raman spectra)係偏移 的。 麵合的及類似術語意指以麵合劑將一聚合物鍵與另 一聚合物鏈結合。 &quot;耦合劑”及類似術語意指含有至少兩個反應性基團的 化學化合物，各個反應性基團能夠形成可以插入聚合物鏈 CH、CH2或CH3基團（脂肪族及/或芳香族）之碳氫鍵結的碳 烯或氮烯基團。反應性基團可將聚合物鏈耦合或交聯在一 起。耗合劑在有效地柄合聚合物鍵之前需要以熱、聲波能 量、輕射或化學活化能來活化。 “耦合數量”及類似術語，於本發明内文中，意指在反 應性加工條件與金屬水合物存在下，足以耦合丙烯聚合物 及烯烴互聚物的耦合劑數量，如此使得呈纜線或導線絕緣 鞘型式之組成物的抗熱性比由其他組成物製成之類似纜線 或導線絕緣鞘的抗熱性還要優良，該其他組成物除了丙烯 聚合物及烯烴互聚物係未耦合的之外，其餘方面與呈纜線 或導線絕緣勒型式之組成物相同。 “氮烯基團&quot;意指具有結構R—N的化合物，其中N係 能夠藉由插入聚合物鏈的CH、CH2或CH3基團（脂肪族及/ 或芳香族兩者）的碳氫鍵結而與聚合物鏈反應的氮。最佳之 9 201011064 插入碳氫鍵結的氮烯的氮具有兩孤立電子對。R係不會反 面干擾插入上述碳-氫鍵結之氮的原子。 &quot;碳烯基團&quot;意指具有結構R-C-R，的化合物，其中c 係能夠藉著插入聚合物鏈之CH、CH2或CH3基團（脂肪族 及/或芳香族兩者）之碳氫鍵結而與聚合物鏈反應的碳。用於 插入碳氫鍵結之最佳的碳具有一孤立電子對。尺及尺，係不 會反面干擾插入上述碳-氫鍵結之碳的兩獨立原子。 “抗氧化劑”意指能夠被用於使加工聚合物期間產生之 氧化作用降至最低的各類型化學化合物。該術語也包括抗 氧化劑的化學衍生物。該術語更包括於稍後之抗氧化劑說 明中描述的化學化合物，這些化學化合物當與耦合劑適合 地結合時，會與耦合劑反應以形成錯合物。此錯合物相較 於單獨的耦合劑展現修飾過的拉曼光譜。 “反應性加工”意指藉著混合聚合物組份而相容化 (compatibilization)或化學耦合聚合物之摻合物的方法，以 此種方式其#在社㈤叫彼狀應。組成物組份具有足 夠的反應性，如此反應可以越過熔化相邊界而發生。 “反應性加讀m旨聚合物的摻合物進行⑴充分地 混合以達到外形組織所要的I細程度，及(2)使至少一些聚 合物分子彼此反應或輕合以在混合/磨碎過程期間形成共 價鍵。反應進行得相當地快，使得其等在•器或混合器 加工期狀合理時間内就已經反應完全。典型加工狀況包 括溫度100至280，更典型地15〇至25〇及最典型地18〇 至250。〇壓力典型地(至少_部分)絲合物之摻合設備的 201011064 函數，但是典型地壓力範圍從一大氣壓到稍微正壓的狀 況。反應性加工狀況繼續持續直到典型地至少5〇、更血型 地至少70、最典型地至少80百分比的疊氮化物已經反應， 或者，在矽烷耦合劑的例子中，至少5〇、更典型地至少7〇、 最典型地至少80百分比的過氧化物已經被消耗。 聚烯烴合成 用於實施本發明的聚烯烴（特別包括丙烯聚合物及烯 烴互聚物）使用傳統聚烯烴聚合技術，例如戚格勒_纟内他 (Ziegler-Natta)、金屬茂或限制幾何催化劑而產生，當然各 個技術適用於產生感興趣的不同聚烯烴。金屬茂及限制幾 何催化劑（CGC)包括與活化劑（例如，氡化鋁溶膠 (alumoxane))結合的單環或雙環戊二烯基、茚基或第基過渡 金屬（較佳地第4族)錯合物。美國專利第5,064,802號、 WO93/19104及W095/00526揭示限制幾何金屬錯合物以及 製備其等的方法。各種含有取代節基的金屬錯合物教示於 WO95/14024 及 W098/49212 中。 一般而言，於習於此藝者熟知的戚格勒-納他或卡明斯 基-辛（Kaminsky-Sinn)型聚合反應的狀況下可以完成聚合 反應’亦即，在溫度0-250°C、較佳地30-200。(：以及壓力 從大氣壓至1〇,〇〇〇大氣壓（1013百萬帕斯 卡megaPascal(MPa))下可以完成聚合反應。依需要的狀 況，可使用懸浮液、溶液、泥衆、氣相、固態粉末聚合反 應或其他製程狀況。催化劑可為支撐或非支樓，支撑組成 物可以為各種型式。石夕石、瘃土或聚合物（尤其是聚（四氟乙 201011064 烯）或聚稀烴)為代表性支擇物，而且當催化劑被用於氣相聚 合反應製程時，使用支撐物是所欲的。支撐物較佳的使用 數量係足以使得催化劑（基於金屬）對支揮物的重量比例落 在 1 · 1 . 100,000 至 1 : 1〇、更佳地 1 : 5〇,〇〇〇 至 1 : 2〇、 最佳地1 : 10,000至i : 30的範圍。在大部分的聚合反應 中，催化劑對使用之可聚合化合物的莫耳比例從1〇-!2 : i 至 10·1 : 1、更佳地從 1〇-9 : 1 至 1〇·5 : 1。 鈍性液體可作為合適的聚合反應溶劑。例子包括直鏈 及分枝的碳氫化合物（諸如異丁烷、丁烷、戊烷、己烷、庚 參 烷、辛烷及其等之混合物）；環狀及脂環族碳氫化合物（諸如 環己炫、環庚烧、甲基環己烧、甲基環庚烧及這些材料的 兩種以上的混合物）；全氟化的碳氫化合物（諸如全IU匕的 C^o烷類）·’及芳香族與烷基取代的芳香族化合物（諸如 苯、甲苯、二曱笨及乙基苯）。 丙烯聚合物 用於實施本發明的丙烯聚合物（組成物的組份 A)不是 稀烴及聚物（組成物的崎B)。丙_合物可為丙_聚 % 物’或丙烯與-或多個其他烯烴的共聚物，或兩種以上均 聚物或兩種以上共聚物的掺合物，或_或多個均聚物及一 或多個共聚物的摻合物。用於本組成物的丙稀聚合物可為 各種型式並包括例如實質上同排丙烯均聚物、隨機丙稀共 聚物與接枝或嵌段丙烯共聚物。 12 201011064 比之來自丙 至少—α-烯 丙烯共聚物典型地包括90以上莫耳百分 烯的單元。丙料輯巾單元的其餘部分來: 烴。 稀共聚物的α-稀烴組份較佳地為乙稀(為本發明目 被認為是α_烯煙)或^線性、分枝或環狀…烯^月目的 煙的例子包括丨·丁晞、4_曱基-1-戊稀、i-己烯、^^ 癸烯、二稀、十四稀十六稀、及L十八歸 烴也可含树狀結構，諸如環己料環姐，㈣成諸如 3_環己基-1·丙稀(浠丙基環己烧)及乙烯基環己烧的α-稀 經。雖然不是傳統意義上__烯烴，為了本發明之故，某些 環烯烴，諸如冰片烯及相關的烯烴，特別是5_亞乙基_2_冰 片烯，也是(X-烯烴且可被用來取代一些或所有的上述…烯 烴。類似地，笨乙烯及其相關烯烴(例如，α_甲基笨乙烯等 等）就本發明目的而言也是α-烯烴。例示的聚丙烴共聚物包III. English Abstract: A propylene polymer is coupled with an olefinic interpolymer by a process comprising contacting under reactive processing conditions at least: A. 10 wt% of at least one propylene polymer; B. 10 wt% of at least one olefinic interpolymer C. 35 wt% of at least one metal hydrate; and D. A coupling amount of a coupling agent, each weight percent based on the combined weight of the propylene polymer, olefinic interpolymer and metal hydrate. Wire and cable insulation sheaths made from 1 201011064 VI. Description of the invention: [Make the mussels of the invention ^^ J Related application cross-references This application claims the US patent application number filed on June 6, 2008 The priority of 61/059,356, the entire contents of which is incorporated herein by reference. FIELD OF THE INVENTION The present invention relates to a group of products comprising a polypropylene polymer and a dilute hydrocarbon interpolymer. In one aspect, the invention is directed to a composition comprising reactively processed polypropylene and an olefin interpolymer which exhibits anti-Southern thermal properties suitable for use in wire and ambient coating. In another aspect, the present invention is directed to a cable including an insulating layer. In yet another aspect, the present invention is directed to an electrical field wherein the insulating layer comprises a reactively processed polypropylene and olefin interpolymerized. The composition of the object. BACKGROUND OF THE INVENTION Polymeric compositions are often used as a basic insulating material for wires and cables. As an insulator, the composition should exhibit various physical and electrical properties, such as heat resistance, resistance to mechanical cutting, resistance to stress cracking, and dielectric failure. Insulating materials for electrical conductors often require cross-linking to achieve the desired heat resistance. Crosslinking can be introduced between different molecular chains of a polymer by several mechanisms, one of which is to graft a chemically reactive compound onto an individual polymer backbone or chain that constitutes a macropolymer, in such a way The grafted compound on a major 3 201011064 chain can then react with a similar grafting compound on the other backbone, thereby forming a crosslink. An example of this method is the method of &quot;Shi Xi Burn Crosslink&quot;. The decane crosslinking method utilizes a decane-containing compound that crosslinks a polymer molecule. The smelting can be grafted to a suitable polymer by using a suitable amount of an organic peroxide or other free radical initiator prior to the forming or molding operation or during the forming or molding operation. Other ingredients such as stabilizers, pigments, fillers, catalysts, processing aids and the like may also be included in the mixture. When a ♦ burn-peroxide blend is used to crosslink the polymer, a compromise must be made between grafting efficiency and processing efficiency, such as feed rate and number of passes. Because of the need to strictly control the processing, it is difficult to form crosslinkable materials in this manner. For example, if the process is carried out at too high a temperature, the polymer will partially crosslink in a processing device (e.g., a feeder), making it difficult to obtain a good product of consistent quality afterwards. Processing delays can also occur due to the need to remove some of the parent products from the processing equipment. Special care should also be taken during the subsequent heating of the parent process to ensure that the articles prepared from the polymer retain their shape. Further, when a highly reactive decane-peroxide blend is used, gel formation, thread generation, and coking occur. The above problems are severe for processes that utilize processing conditions and processing equipment to produce high shear stress in polyolefins under stringent melting and mixing conditions. These problems typically result from premature, and ultimately complete, activation of the peroxide during the initial melting and homogenization process. Traditionally, this problem has been addressed by using a less reactive 201011064 decane blend, but this approach reduces the grafting efficiency of the cross-linking reaction. Another method of crosslinking uses radiation. Radiation cross-linking requires complex equipment and is therefore expensive to implement. Moreover, the radiation causes the polymer to degrade due to oxidation and/or chain shear, and thus the polymer needs to be particularly stabilized. Moreover, the size of the cable that can be operated by commercial radiation equipment is limited in terms of both the thickness of the jacket and the overall diameter of the cable. This limitation is typically more pronounced when the jacket is non-uniformly crosslinked and results in a change in the physical properties of the cable perimeter or the interior of the jacket φ material wall. Additional materials, such as polyurethanes and fluorinated ethylene propylene elastomers, are Amber's and are sensitive to water. In addition, it is often necessary to make these materials resistant to flames, which also makes these compounds less attractive. - Therefore, for the wire and cable industry, there is still a need and expectation of a polyolefin composition which can be fed out without further crosslinking and exhibits heat resistance against fire and flame. Spread the properties of Φ, better 'have good flexibility. BRIEF SUMMARY OF THE INVENTION In one embodiment, the present invention is directed to a composition comprising a polypropylene polymer reactive with an olefin interpolymer such that the composition exhibits heat resistance and resistance to fire And the nature of the flame spread. In addition, the composition also exhibits good flexibility. 201011064 In the present invention - an embodiment ... a method of consuming a propylene polymer and a dilute hydrocarbon interpolymer, the method comprising contacting at least in a reversed state: A. 10 wt ° /. At least one propylene polymer; B. 10 wt% of at least one olefin interpolymer; C·35 wt% of at least one metal hydrate; and D. a depleted amount of light mixture, each weight percentage based on propylene polymer The combined weight of the olefin interpolymer and the metal hydrate. Typically the coupling agent (1) has a vinyl group of decane or (ii) a poly(azide). The polypropylene polymer can be a homopolymer or a copolymer. Olefin interpolymers include, but are not limited to, very low density polyethylene (VLDPE), homogeneously branched, linear ethylene/α-olefin copolymers, homogeneously branched, substantially linear ethylene/(χ_ smoky copolymer, linear Medium density polyethylene, linear low density polyethylene (LLDPE) 'ultra low density polyethylene (ULDPE), and multi-block olefin polymer. Metal hydrates useful in the present invention include, but are not limited to, aluminum hydroxide and hydrogen Magnesium oxide. In one embodiment of the invention, a cable comprising an insulating layer comprising a composition comprising a reactive processed polypropylene polymer, an olefin interpolymer, and a metal hydrate. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT The numerical ranges of the present disclosure are broad, and thus may include values outside the range unless otherwise indicated. It is assumed that there are at least two separate values between any lower value and any higher value. In the case of a unit, the numerical range 201011064 includes all values that are added in lower value and higher value in a unit. For example, if it is composition, physics or other properties, For example, such as molecular weight, viscosity, melt index, etc., from 100 to 1000, then all individual values, such as 100, 101, 102, etc., and sub-ranges, such as 100 to 144, 155 to 170, 197 to 200 Etc., are explicitly enumerated. For a range containing less than one value or containing a fraction greater than one (eg, 1.1, 1.5, etc.), a unit is considered to be 0.0001, 0.001, 0.01, or 0.1, depending on the situation. For a range of one-digit numbers (eg, 1 to 5) containing less than ten, one unit is typically considered to be 0.1. These are only examples of what is specifically desired, and between the lowest and highest values exemplified. Combinations of possible numerical values are also considered to be clear to the disclosure. The disclosure provides, among other things, numerical ranges relative to the amount of anti-tree agent, process conditions, amount of additives, and molecular weight of the polymer. "Cable line" and like terms mean at least one wire or fiber within a protective sheath or sheath. Typically, the cable is two or more wires or fibers bonded together, typically in the same warranty The individual wires or fibers in the protective sleeve may be bare wires, have a covering or an insulator. The combined cable may contain both electrical wires and optical fibers. Cables and the like may be designed for low, medium and &quot;Polymer&quot; means a polymeric compound prepared from a polymerized monomer, whether of the same or a different type. This general term polymer thus encompasses the term homopolymer and the term copolymer, which is usually a homopolymer. Used to refer to a polymer prepared from a single type of monomer, the copolymer is defined below. 201011064 &quot;Interpolymer&quot;, &quot;copolymer&quot; and like terms mean polymerization of monomers derived from at least two different types. The polymer was prepared. These general terms refer to polymers prepared from two different types of monomers, as well as polymers that are claimed to be prepared from more than two different types of monomers, such as terpolymers, tetrapolymers, and the like. "Polyolefin", "p" and the like mean a simple olefin-derived polymer. Many polyolefins are thermoplastic and, for the purposes of the present invention, may include a rubber phase. Representative polyolefins include various interpolymers of polyethylene, polypropylene, polybutylene, polyisoprene, and the like. "Blend", "polymer blend" and like terms mean a mixture of two or more materials, such as a mixture of two or more polymers, at least - a polymer and at least - a water tree resistant agent, and the like. Such blends may be miscible and immiscible. Such blends may be phase separated or not phase separated. Such blends may contain one or more primary configurations or no-or multiple primary configurations based on penetrating electron spectroscopy, light scattering, X-ray scattering, or any method known to those skilled in the art. Composition I is a similar term meaning a mixture of a mixture of two or more components. Inside a mixture or blend of materials used to make Wei or other articles, the composition includes all mixed components, for example, a mixed propylene polymer and an olefinic interpolymer, a metal hydrate 'not _ Combined polymers and coupling agents, with any other additives (such as processing: chemicals, etc.). ^ &quot;Molecular melts&quot; means a blend of at least a portion of a non-crystalline type of depleting agent (modifier) and an antioxidant at room temperature, optionally including, for example, W〇2()〇 3/_229 A1's other polymer additions. 201011064 Both antioxidants are at least partially contained in the amorphous phase of the blend. Moreover, preferably, the coupling agent and the antioxidant form a complex which is related to the group forming the nitrogen-alkenyl group compared to the Raman spectrum of the group forming the nitrogen-alkenyl group in the separate coupling agent. The Raman spectra are offset. By face and like terms is meant a bond of a polymer bond to another polymer chain. &quot;Coupling agent&quot; and like terms mean a chemical compound containing at least two reactive groups, each reactive group capable of forming a CH, CH2 or CH3 group (aliphatic and/or aromatic) which can be inserted into the polymer chain. a hydrocarbon-bonded carbene or a nitrogen-alkenyl group. The reactive group can couple or crosslink the polymer chains together. The consumable agent needs heat, sonic energy, and light shot before effectively tying the polymer bond. Or chemical activation energy to activate. "Coupling amount" and like terms, in the context of the present invention, means the amount of coupling agent sufficient to couple a propylene polymer and an olefin interpolymer in the presence of reactive processing conditions and metal hydrate. Thus, the heat resistance of the cable or wire insulating sheath type composition is superior to that of a similar cable or wire insulating sheath made of other compositions other than propylene polymer and olefin interpolymer. The system is uncoupled, and the rest is the same as the composition of the cable or wire insulation type. "N-alkenyl group" means a compound having the structure R-N, wherein the N system can borrow Nitrogen that reacts with the polymer chain by carbon-hydrogen bonding of CH, CH2 or CH3 groups (both aliphatic and/or aromatic) inserted into the polymer chain. Best 9 201011064 The nitrogen of the nitrogen-bonded nitrogen olefin has two isolated electron pairs. The R system does not adversely interfere with the insertion of the above-mentioned carbon-hydrogen bonded nitrogen atoms. &quot;Carbonyl group&quot; means a compound having a structural RCR, wherein c is capable of being bonded to a carbon, hydrogen bond of a CH, CH2 or CH3 group (both aliphatic and/or aromatic) of a polymer chain. The carbon that reacts with the polymer chain. The best carbon for inserting hydrocarbon bonds has an isolated pair of electrons. The ruler and ruler do not interfere with the insertion of two independent atoms of the carbon-hydrogen bonded carbon. "Antioxidant" means various types of chemical compounds that can be used to minimize oxidation during processing of the polymer. The term also includes chemical derivatives of antioxidants. The term further encompasses the chemical compounds described in later antioxidant descriptions which, when suitably combined with a couplant, react with the couplant to form a complex. This complex exhibits a modified Raman spectrum compared to a separate coupling agent. "Reactive processing" means a method of compatibilization or chemically coupling a blend of polymers by mixing a polymer component, in such a way that it is called in the society. The composition component is sufficiently reactive that such a reaction can occur across the boundaries of the melt phase. "Reactive plus read polymer blends are (1) thoroughly mixed to achieve the desired fineness of the profile structure, and (2) at least some of the polymer molecules are reacted or lightly coupled to each other during the mixing/grinding process. Covalent bonds are formed during the reaction. The reaction proceeds fairly quickly, allowing it to react completely within a reasonable period of time during the processing of the vessel or mixer. Typical processing conditions include temperatures of 100 to 280, more typically 15 to 25 Torr. And most typically from 18 to 250. The pressure is typically (at least - part) of the 201011064 function of the blending device of the filament, but typically the pressure ranges from one atmosphere to a slightly positive pressure. The reactive processing continues Until at least 5 〇, more at least 70, more typically at least 80 percent of the azide has been reacted, or, in the case of a decane couplant, at least 5 〇, more typically at least 7 〇, most typically At least 80% of the peroxide has been consumed. Polyolefin Synthesis Polyolefins (particularly including propylene polymers and olefin interpolymers) used in the practice of the invention use conventional polyolefin polymerization Technology, such as Ziegler-Natta, metallocene or limited geometry catalysts, of course, each technique is suitable for producing different polyolefins of interest. Metallocene and Restricted Geometry Catalysts (CGC) include An activator (e.g., an alumoxane) bound monocyclic or biscyclopentadienyl, fluorenyl or base transition metal (preferably Group 4) complex. U.S. Patent No. 5,064,802, WO93 /19104 and W095/00526 disclose methods for limiting geometric metal complexes, and preparing them, etc. Various metal complexes containing substituted substituents are taught in WO 95/14024 and W098/49212. The polymerization can be carried out under the conditions of the well-known polymerization of the 戚Geller-Natin or Kaminsky-Sinn type, that is, at a temperature of 0 to 250 ° C, preferably 30 to 200. (: and the pressure can be completed from atmospheric pressure to 1 〇, 〇〇〇 atmospheric pressure (1013 megapascals megaPascal (MPa)). Suspension, solution, mud, gas phase, solid powder can be used as needed. Polymerization or other processes The catalyst may be a supporting or non-supporting structure, and the supporting composition may be of various types. The stone stone, alumina or polymer (especially poly(tetrafluoroethylene 201011064 ene) or poly-hydrocarbon) is a representative support. And when the catalyst is used in a gas phase polymerization process, it is desirable to use a support. The support is preferably used in an amount sufficient to cause the weight ratio of the catalyst (based on metal) to the support to fall by 1.1. 100,000 to 1: 1 〇, more preferably 1: 5 〇, 〇〇〇 to 1: 2 〇, optimally 1: 10,000 to i: 30 range. In most polymerizations, the molar ratio of the catalyst to the polymerizable compound used is from 1 〇 -! 2 : i to 10 · 1 : 1, more preferably from 1 〇 -9 : 1 to 1 〇 5 : 1. A passive liquid can be used as a suitable polymerization solvent. Examples include linear and branched hydrocarbons (such as isobutane, butane, pentane, hexane, heptane, octane, and the like); cyclic and alicyclic hydrocarbons (such as Cyclohexyl, cycloheptane, methylcyclohexane, methylcycloheptane and mixtures of two or more of these materials; perfluorinated hydrocarbons (such as C oi alkane of all IU )) 'and aromatic and alkyl substituted aromatic compounds (such as benzene, toluene, diterpene and ethylbenzene). Propylene Polymer The propylene polymer (component A of the composition) used in the practice of the present invention is not a dilute hydrocarbon and a polymer (saturation B of the composition). The propylene compound may be a copolymer of propylene/poly% or a copolymer of propylene and/or a plurality of other olefins, or a blend of two or more homopolymers or two or more copolymers, or _ or a plurality of homopolymers. And a blend of one or more copolymers. The propylene polymers used in the present compositions can be of various forms and include, for example, substantially identical propylene homopolymers, random propylene copolymers, and graft or block propylene copolymers. 12 201011064 is more than a unit derived from C. At least the ?-olefin propylene copolymer typically comprises more than 90 mole percent olefins. The rest of the propylene material unit comes: hydrocarbon. The α-thin hydrocarbon component of the dilute copolymer is preferably ethylene (which is considered to be α-olefin in the present invention) or is linear, branched or cyclic.晞, 4_mercapto-1-pentazone, i-hexene, ^^ decene, dilute, tetradecene hexadecane, and L octahydrocarbon may also contain a tree structure, such as a cyclohexane ring Sister, (iv) is a-sparse such as 3-cyclohexyl-1·acrylic (fluorenylcyclohexene) and vinylcyclohexane. Although not in the conventional sense, certain cyclic olefins, such as norbornene and related olefins, especially 5-ethylidene-2-norbornene, are also (X-olefins and can be used for the purposes of the present invention). To replace some or all of the above-mentioned olefins. Similarly, stupid ethylene and its related olefins (e.g., alpha-methyl styrene, etc.) are also alpha-olefins for purposes of the present invention. Exemplary polypropane copolymer packages 括但不限於丙烯/乙烯、乙烯/1-丁烯、乙烯/丨_己烯、乙烯辛 烯及相似物。例示的三聚物包括乙烯/丙烯/u辛烯、乙烯/ 丙烯/1-丁烯及乙烯/丙烯/二烯單體(EPDM)。共聚物可以是 隨機的或是嵌段的。 以下是可用於本發明組成物之例示而非限制的丙稀聚 合物：丙稀衝擊共聚物包括但不限於DOW聚丙稀 T702-12N ;丙烯均聚物包括但不限於DOW聚丙烯 H502-25RZ ;及丙烯隨機共聚物包括但不限於DOW聚丙烯 R751-12N。上述的Dow丙烯聚合物典型地具有〇 9〇 g/cm3 的密度（以ASTM D792測定）。 13 201011064 更且’可以使用熔化流動指數〇·5 dg/min(230°C/2.16kg) 及熔點164°C的分枝衝擊丙烯共聚物INSPIRE1&quot;1 D114 (也 可從陶氏化學公司（Dow Chemical Company)購得）。 此外，密度0·90 g/cc及MFR 2 g/10 min的澄清丙烯共 聚物樹脂 PROFAXtm SR-256M，密度 0·90 g/cc 及 MFR 1.5 g/10 min的衝擊丙烯共聚物樹脂pROFAxtm8623，以及 聚丙烯（均或共聚物）與一或多個丙烯-乙稀或乙烯-丙烯共 聚物的反應器内摻合物CATALLOYtm也可以使用（所有均 可從Basell，Elkton, MD購得）。其他丙烯聚合物包括Solvay 的KS 4005丙烯共聚物；及Solvay的KS 300丙烯三聚物。 稀烴互聚物 用於實施本發明的烯烴互聚物（組成物的組份B)不包 括上述的丙烯聚合物（組成物的組份A)。烯烴互聚物包括但 不限於聚烯烴彈性體、聚烯烴撓性體及聚烯烴塑性體。較 佳地，烯烴互聚物係乙烯互聚物，其基於烯烴互聚物的重 量包括至少10、較佳地至少50及更佳地至少80wt%之來 自乙烯的單元。 有用於實施本發明之烯烴互聚物的例子包括非常低密 度的聚乙烯(VLDPE)，均質分枝、線性的乙烯/α-烯烴共聚 物（例如Mitsui石油化學股份有限公司的TAFMER®及 DEXPlastomers的EXACT®)，與均質分枝、實質線性的乙 烯/α-烯烴聚合物(例如購自陶氏化學公司的AFFINITY®聚 烯烴彈性體及ENGAGE®聚烯烴彈性體）。實質線性的乙烯 201011064 共聚物於美國專利5,272,236、5,278,272及5,986,028有更 為全面的描述。 有用於實施本發明之其他烯烴互聚物包括異質分枝之 以乙烯為底的互聚物，其包括，但不限於，線性中密度聚 乙烯(LMDPE)，線性低密度聚乙烯(LLDPE)，及超低密度聚 乙烯（ULDPE)。商業聚合物包括DOWLEX™聚合物， ATTANE™聚合物及FLEXOMER™聚合物（所有購自陶氏 化學公司），與ESCORENE™及EXCEED™聚合物（均購自 Exxon Mobil化學公司）。 另外的烯烴互聚物包括多嵌段或分段共聚物。這些共 聚物係兩種以上化性不同的區域或區段(稱作“嵌段”），較佳 地以線性方式，連接的聚合物，亦即，包括聚合乙稀官能 性以端對端方式（而不是以外接或接枝方式）連接之化性不 同單元的聚合物。在某些實施例中，嵌段具有不同的嵌入 共單體數量或類型、密度、結晶數量、組成此等組成物之 聚合物的結晶大小、立體化學性（同排或對排）的類型或程 度、位置規則性或位置不規則性、分枝數量（包括長鏈分枝 或高度分枝）、均質性或其他化學或物理性質。多嵌段共聚 物可藉由製造共聚物枝獨特方法所產生的獨特多分散性指 數分布(PDI或Mw/Mn)、欲段長度分布及/或喪段數目分布 的特徵而區別。更特別地，當以連續方法產生時，聚合物 的實施例可含有範圍從約1.7至約8的PDI;在其他實施例 中，從約1.7至約3.5 ;在又一實施例中，從約1.7至約2.5 ; 在再一實施例中’從約1.8至約2.5或從約至約21。 15 201011064 當以批次或半批次方法產生時，聚合物的實施例可含有PDI 的範圍係從約1.0至約2.9 ;在其他實施例中，從約1.3至 約2.5 ;在又一實施例中，從約1.4至約2.0 ;在再一實施 例中，從約1.4至約1.8。 乙烯/α-烯烴多嵌段互聚物包括乙烯及一或多個呈聚 合型式的共聚α-烯烴共單體，其特徵為含有兩個以上物化 性質不同之聚合單體單元的多個（即兩個以上）的嵌段或分 段（嵌段互聚物），較佳地為多嵌段互聚物。於一些實施例 中，多嵌段互聚物可以以下的化學式表示： (ΑΒ)η 其中η至少為1，較佳地大於1的整數，諸如2、3、 4 、 5 、 10 、 15 、 20 、 30 、 40 、 50 、 60 、 70 、 80 、 90 、 100 或更高；“Α”代表硬嵌段或分段；“Β”代表軟嵌段或分段。 較佳地，Α及Β以線性方式連接，而不是以分枝或星狀方 式連接。“硬”分段意指聚合單元的嵌段，其中於一些實施 例中，乙烯出現的數量大於95重量百分比，及於其他實施 例中，乙烯出現的數量大於98重量百分比。換言之，於一 些實施例中，硬分段中共單體的含量少於5重量百分比， 於其他實施例中，硬分段中共單體的含量少於硬分段總重 的2重量百分比。於一些實施例中，硬分段包括所有或實 質上所有的乙烯。“軟”分段，於另一方面，指稱聚合單元 的嵌段，其中於一些實施例中，共單體的含量大於軟分段 總重的5重量百分比，在各種其他實施例中，大於軟分段 總重的8重量百分比、大於軟分段總重的10重量百分比 201011064 - 或大於軟分段總重的15重量百分比。於一些實施例中， 軟分段中共單體的含量可能大於20重量百分比，在各種其 他實施例中，大於25重量百分比、大於30重量百分比、 大於35重量百分比、大於40重量百分比、大於45重量 百分比、大於50重量百分比或大於60重量百分比。 有用於實施本發明的乙烯多嵌段共聚物，及其等的製 備與使用，更完整地描述於 WO 2005/090427、 US2006/0199931、US2006/0199930、US2006/0199914、 ® US2006/0199912、US2006/0199911、US2006/0199910、 US2006/0199908 、美國專利第 7,355,089 號、 US2006/0199906、US2006/0199905、美國專利第 7,524,911 號、US2006/0199896、US2006/0199887、美國專利第 7,514,517 號、US2006/0199872、US2006/0199744、 US2006/0199030 、美國專利第 7,5〇4,347 號及 US2006/0199983。代表性烯烴多嵌段互聚物包括由陶氏化 學公司製造及銷售的烯烴嵌段共聚物。 有用於本發明的乙烯互聚物包括乙烯/α-烯烴互聚 物，其具有α-烯烴的含量基於互聚物重量典型地係至少5、 更典型地至少15及最典型地至少約20wt%。這些互聚物具 有α-烯烴的含量基於互聚物重量典型地係少於90、更典型 地少於75及最典型地少於約50wt%。α-烯烴的含量以13C 核磁共振(NMR)光譜利用描述於1^1^&amp;11(及伙似〇^〇所〇/· C/zem. P/zj·?·，C2iY2&lt;&amp;3))的步驟測量。 17 201011064 α-烯烴較佳地為線性、分枝或環狀α_烯烴。 α-烯烴的例子包括丙烯、丨_丁烯、4_曱基戊烯、己烯、 1-辛烯、1-癸烯、1-十二烯、丨_十四烯、κ十六烯、及丨_十 八烯。α-烯烴也可含有環狀結構，諸如環己烷或環戊烷，而 形成諸如3-環己基-1·丙烯（烯丙基環己烷)及乙烯基環己烷 的α-稀煙。雖然不是傳統意義上的α_浠烴，為了本發明之 故，某些環烯烴，諸如冰片烯及相關的烯烴，特別是5_亞 乙基-2-冰片烯，也是α_烯烴且可被用來取代一些或所有的 上述α-烯烴。類似地，苯乙烯及其相關烯烴(例如，α_甲基 〇 苯乙稀等等）就本發明目的而言也是α_稀烴。例示的聚浠烴 共聚物包括乙烯/丙烯、乙烯/丁烯、乙烯/1_己烯、乙烯八_辛 烯、乙烯/苯乙烯及相似物。例示的三聚物包括乙烯/丙烯71_ 辛烯、乙烯/丙烯/丁烯、乙烯/丁烯/1-辛烯、乙烯/丙烯/二烯 - 單體(EPDM)及乙烯/ 丁烯/苯乙烯。共聚物可以是隨機的或是 - 嵌段的 其他有用於實施本發明的烯烴互聚物包括購自陶氏化 學公司的以VERSIFY®丙烯為基底的聚合物，及購自 ® ExxonMobil化學公司的VISTAMAXX®丙烯聚合物，至少 那些VERSIFY®及VISTAMAXX®丙烯聚合物具有來自少 於85 mol%的丙烯單元含量。各類其他聚丙烯聚合物的討 論 包含於現代塑膝百科全書/5P( P/aWci 五，1988年，十月中期發行，第65卷，第 11期，第6-92頁。 18 201011064 若烯烴互聚物摻合物用於實施本發明，則掺合物得以 反應器内或反應器後製程來製作。反應器内摻合製程較反 應器後摻合製程為佳，而且使用多數依序連接的反應器的 製程係較佳的反應器内掺合製程。這些反應器可含有相同 的催化劑但在不同狀況下操作，例如不同反應物濃度、溫 度、壓力等等，或在相同狀況下操作但是添加不同的催化 劑0 金屬水合物’· 有用於實施本發明的金屬水合物包括，但不特別限制 於，例如具有經基或結晶水的化合物，諸如氫氧化銘及氫 氧化鎮。這些金屬水合物可以單獨使用或兩種以上結合使 用。 商業上可購得之氫氧化鎂的例子包括Matinswerk製 造的MAGNIFIN®。其他例子包括KISUMA 5、KISUMA 5A、KISUMA 5B、KISUMA 5J、KISUMA 5LH 及 KISUMA 5PH(所有商標及製造均來自Kyowa化學工業股份有限公 司）。例子〇f商業上可購得之三（氫氧）化鋁包括 Matinswerk 製造的 MARTINAL® 及 Alamatis 製造的 HYDRAL。 於換合進入組成物之前，金屬水合物可以表面處理劑 (典型上矽烷表面處理劑）進行表面處理，或表面未經處理的 金屬Κδ物了與表面處理劑一起被摻合進入組成物中以進 行原4的表面處理。添加之表面處理劑的合適數量為足以 提供金屬水合物所要之表面處理的數量。要被加入之表面 19 201011064 處理劑的典型上較佳數量為基於金屬水合物重量0.1至 2 · 0 wt %。可以使用任何習於此藝者所熟知的表面處理劑而 不必特別限制。然而，具有有機官能基團的矽烷表面處理 劑，諸如胺基、異丁烯基、乙烯基、環氧基及酼基基團係 較佳的，並且就阻擋火勢及抗拉性質而言，具有乙烯基及/ 或環氧基的矽烷表面處理劑是最佳的。 麵合劑： 如上所述，在本發明内文中，耦合劑為一種多官能的 化合物，亦即，一種包括兩種以上官能基團的化合物，其 鲁 在合適的反應條件下能夠經由共價性鍵結連結將兩種以上 聚合物鏈結合在一起。聚（疊氮化物)耦合劑包括烷基及芳香 基疊氮化物、醯基疊氮化物、甲酸疊氮基酯、磷酸基疊氮 化物、膦酸基疊氮化物、石夕基疊氮化物及聚(績醯基疊氮化 _ 物）。聚(磺醯基疊氮化物）為一種含有至少兩個與聚烯烴反 應之活性基團（磺醯基疊氮化物基團（―s〇2N3))的化合物。較 佳地，聚(磺醯基疊氮化物）具有結構X — R_X ,其中各χ 為-S〇2N3且R代表未取代的或鈍性取代的烴基，烴基醚 參 或含矽基團，較佳地具有足夠的碳、氧或矽，較佳地碳原 子，以充分地分離磺醯基疊氮化物基團來讓聚烯烴及磺醯 基叠化物之間進行溫和反應（facile reaction)。可被純性取 代進入R的原子或基團的例子包括，但不限於，氟、脂肪 族醚或芳香族醚，矽氧類以及其中兩個以上的聚烯烴鏈連 結在一起的磺醯基疊氮化物基團。R係合適的芳香基、烷 基、烷基芳香基、芳香基烷基矽烷、矽氧類或雜環、如上 20 201011064 述之鈍性且分離磺醯基疊氮化物基團的基團及其他基團。 更佳地，R包括在磺醯基團之間的至少一個芳香基團，最 佳地’至少兩個^香基團（諸如當r是4,4'二苯基_或4,4'_ 聯苯基時）。當R係一芳香基基團時，較佳地，該基團具有 超過一個環，如同在伸萘基雙(磺醯基疊氮化物）。聚(磺醯 基）疊氮化物包括但不限於下列化合物：如丨，5_戊烷雙(磺醯 基豐氮化物）、1，8-辛烷雙(磺醯基疊氮化物）、丨,1〇_癸烷雙(磺 醯基疊氮化物）、1，10-十八烷雙(磺醯基疊氮化物）、丨_辛基 _2,4,6_苯二(磺醯基疊氮化物）、4,4，_二苯基醚雙(磺醯基疊氮 化物）、1，6-雙(4'磺醯胺苯基）己烷、2,7_萘雙(磺醯基疊氮化 物）’與每分子平均含有1至8個氯原子及約2至5個磺醯 基疊氮化物基團的氣化脂肪族碳氫化合物的混合的磺醯基 豐氮化物，以及兩種以上上述化合物的混合物。較佳聚(續 醯基疊氮化物）包括氧-雙(4-續醯基疊氮基苯）、2,7-萘雙(續 醯基疊氮化物）、4,4,雙(磺醯基疊氮基)聯苯基、4,4，_二苯基 醚雙(磺醯基疊氮化物)及雙(4_磺醯基疊氮基苯基）甲烷，與 兩種以上上述化合物的混合物。 矽烷耦合劑的例子包括乙烯基_三(卜甲氧基乙氧基)矽 烷、乙烯基三乙氧基矽烷(VTES)、乙烯基三甲氧基矽烷 (VMTS)、γ-(曱基丙烯醯氧丙基)_三甲氧基矽烷、γ_(甲基丙 稀酿氧丙基）曱基二甲氧基矽烷，7_環氧丙氧丙基甲基二乙 氧基矽烷及相似物。VTES及VTMs係較佳的矽烷耦合劑。 21 201011064 用於麵合的耦合劑數量，例如，典型上基於組成物的 結合重量（即聚丙烯、烯烴互聚物及金屬水合物的結合重量） 為0.1至6，更典型地0.1至5及最典型地0.2至3wt%。 添加劑These include, but are not limited to, propylene/ethylene, ethylene/1-butene, ethylene/non-hexene, ethylene octene, and the like. Exemplary terpolymers include ethylene/propylene/u octene, ethylene/propylene/1-butene, and ethylene/propylene/diene monomer (EPDM). The copolymer can be random or block. The following are exemplary and non-limiting propylene polymers useful in the compositions of the present invention: acryl impact copolymers including, but not limited to, DOW polypropylene T702-12N; propylene homopolymers including, but not limited to, DOW polypropylene H502-25RZ; And propylene random copolymers include, but are not limited to, DOW polypropylene R751-12N. The above Dow propylene polymer typically has a density of 〇 9 〇 g/cm 3 (as determined by ASTM D792). 13 201011064 and more can be used to melt the flow index 〇·5 dg/min (230 ° C / 2.16 kg) and the melting point of 164 ° C of branched impact propylene copolymer INSPIRE1 &quot; 1 D114 (also available from The Dow Chemical Company ( Dow Chemical Company). Further, a clear propylene copolymer resin PROFAXtm SR-256M having a density of 0·90 g/cc and an MFR of 2 g/10 min, an impact propylene copolymer resin pROFAxtm8623 having a density of 0·90 g/cc and an MFR of 1.5 g/10 min, and An in-reactor blend of one or more propylene-ethylene or ethylene-propylene copolymers, CATALLOYtm, can also be used (all available from Basell, Elkton, MD). Other propylene polymers include Solvay's KS 4005 propylene copolymer; and Solvay's KS 300 propylene terpolymer. Dilute Hydrocarbon Interpolymer The olefin interpolymer (component B of the composition) used in the practice of the present invention does not include the above propylene polymer (component A of the composition). Olefin interpolymers include, but are not limited to, polyolefin elastomers, polyolefin flexures, and polyolefin plastomers. Preferably, the olefin interpolymer is an ethylene interpolymer comprising at least 10, preferably at least 50 and more preferably at least 80% by weight of units derived from ethylene based on the weight of the olefin interpolymer. Examples of olefin interpolymers useful in the practice of this invention include very low density polyethylene (VLDPE), homogeneous branched, linear ethylene/alpha-olefin copolymers (e.g., TAFMER® and DEXPlastomers of Mitsui Petrochemical Co., Ltd.). EXACT®), with homogeneously branched, substantially linear ethylene/α-olefin polymers (such as AFFINITY® Polyolefin Elastomers and ENGAGE® Polyolefin Elastomers from Dow Chemical Company). Substantially linear ethylene 201011064 copolymers are more fully described in U.S. Patent Nos. 5,272,236, 5,278,272 and 5,986,028. Other olefin interpolymers useful in the practice of the invention include heterogeneous ethylene-based interpolymers including, but not limited to, linear medium density polyethylene (LMDPE), linear low density polyethylene (LLDPE), And ultra low density polyethylene (ULDPE). Commercial polymers include DOWLEXTM polymers, ATTANETM polymers and FLEXOMERTM polymers (all from Dow Chemical Company), and ESCORENETM and EXCEEDTM polymers (both from Exxon Mobil Chemical Company). Additional olefin interpolymers include multi-block or segmented copolymers. These copolymers are two or more different regions or segments (referred to as "blocks"), preferably in a linear manner, linked polymers, ie, including polymeric ethylene functionality in an end-to-end manner (Instead of external or grafting) polymers that are linked to different units. In certain embodiments, the blocks have different numbers or types of embedded comonomers, density, number of crystals, crystal size, stereochemistry (same row or row) of the polymers that make up the compositions, or Degree, positional regularity or positional irregularity, number of branches (including long-chain branches or high-branched), homogeneity or other chemical or physical properties. The multi-block copolymers can be distinguished by the unique polydispersity index distribution (PDI or Mw/Mn), the length distribution of the segments, and/or the distribution of the number of segments. More particularly, when produced in a continuous process, embodiments of the polymer may contain PDI ranging from about 1.7 to about 8; in other embodiments, from about 1.7 to about 3.5; in yet another embodiment, from about 1.7 to about 2.5; in still another embodiment 'from about 1.8 to about 2.5 or from about to about 21. 15 201011064 When produced in a batch or semi-batch process, embodiments of the polymer may contain PDI ranging from about 1.0 to about 2.9; in other embodiments, from about 1.3 to about 2.5; in yet another embodiment Medium, from about 1.4 to about 2.0; in still another embodiment, from about 1.4 to about 1.8. The ethylene/α-olefin multi-block interpolymer comprises ethylene and one or more copolymerized α-olefin comonomers in a polymeric form characterized by a plurality of more than two polymerized monomer units having different physicochemical properties (ie, Two or more blocks or segments (block interpolymers), preferably multi-block interpolymers. In some embodiments, the multi-block interpolymer can be represented by the following chemical formula: (ΑΒ)η where n is an integer of at least 1, preferably greater than 1, such as 2, 3, 4, 5, 10, 15, 20 , 30, 40, 50, 60, 70, 80, 90, 100 or higher; “Α” stands for hard block or segment; “Β” stands for soft block or segment. Preferably, Α and Β are connected in a linear manner, rather than in a branched or star-like manner. "Hard" segmentation refers to a block of polymeric units wherein, in some embodiments, ethylene is present in an amount greater than 95 weight percent, and in other embodiments, ethylene is present in an amount greater than 98 weight percent. In other words, in some embodiments, the amount of comonomer in the hard segment is less than 5 weight percent, and in other embodiments, the amount of comonomer in the hard segment is less than 2 weight percent of the total weight of the hard segment. In some embodiments, the hard segments comprise all or substantially all of the ethylene. "Soft" segmentation, on the other hand, refers to a block of polymeric units, wherein in some embodiments, the amount of comonomer is greater than 5 weight percent of the total weight of the soft segment, in various other embodiments, greater than soft 8 weight percent of the total weight of the segment, 10 weight percent greater than the total weight of the soft segment 201011064 - or greater than 15 weight percent of the total weight of the soft segment. In some embodiments, the content of comonomer in the soft segment may be greater than 20 weight percent, in various other embodiments greater than 25 weight percent, greater than 30 weight percent, greater than 35 weight percent, greater than 40 weight percent, greater than 45 weight percent Percentage, greater than 50 weight percent, or greater than 60 weight percent. Ethylene multi-block copolymers useful in the practice of the invention, and the preparation and use thereof, are more fully described in WO 2005/090427, US 2006/0199931, US 2006/0199930, US 2006/0199914, ® US 2006/0199912, US 2006/ 0199911, US2006/0199910, US2006/0199908, US Patent No. 7,355,089, US2006/0199906, US2006/0199905, US Patent No. 7,524,911, US2006/0199896, US2006/0199887, US Patent No. 7,514,517, US2006/0199872, US2006/ 0199744, US 2006/0199030, U.S. Patent No. 7,5,4,347 and US 2006/0199983. Representative olefin multi-block interpolymers include olefin block copolymers manufactured and sold by The Dow Chemical Company. Ethylene interpolymers useful in the present invention include ethylene/α-olefin interpolymers having an alpha olefin content typically at least 5, more typically at least 15 and most typically at least about 20 wt%, based on the weight of the interpolymer. . These interpolymers have an alpha-olefin content of typically less than 90, more typically less than 75 and most typically less than about 50 weight percent, based on the weight of the interpolymer. The content of α-olefins is described by 13C nuclear magnetic resonance (NMR) spectroscopy as described in 1^1^&amp;11 (and 伙^〇^〇/·C/zem. P/zj·?·, C2iY2&lt;&amp;3 )) Step measurement. 17 201011064 The alpha-olefin is preferably a linear, branched or cyclic alpha-olefin. Examples of the α-olefin include propylene, fluorene-butene, 4-decylpentene, hexene, 1-octene, 1-decene, 1-dodecene, fluorene-tetradecene, κhexadecene, And 丨 octadecene. The α-olefin may also contain a cyclic structure such as cyclohexane or cyclopentane to form α-lean smoke such as 3-cyclohexyl-1·propylene (allyl cyclohexane) and vinylcyclohexane. Although not a conventional alpha hydrazine hydrocarbon, certain cyclic olefins, such as norbornene and related olefins, especially 5-ethylidene-2-bornene, are also alpha olefins and may be Used to replace some or all of the above alpha-olefins. Similarly, styrene and its related olefins (e.g., alpha-methyl phenyl styrene, etc.) are also alpha-dilute hydrocarbons for purposes of the present invention. Exemplary polyalkylene copolymers include ethylene/propylene, ethylene/butene, ethylene/1-hexene, ethylene octa-octene, ethylene/styrene, and the like. Exemplary terpolymers include ethylene/propylene 71_octene, ethylene/propylene/butene, ethylene/butene/1-octene, ethylene/propylene/diene-monomer (EPDM), and ethylene/butene/styrene . The copolymer may be random or - other olefin interpolymers useful in the practice of the invention include VERSIFY® propylene-based polymers available from The Dow Chemical Company, and VISTAMAXX from® ExxonMobil Chemical Company. ® propylene polymers, at least those of VERSIFY® and VISTAMAXX® propylene polymers have a propylene unit content of less than 85 mol%. A discussion of various other polypropylene polymers is included in the Modern Plastic Knee Encyclopedia/5P (P/aWci V., 1988, Mid-October Issue, Vol. 65, No. 11, pp. 6-92. 18 201011064 olefins The interpolymer blend is used in the practice of the present invention, and the blend is prepared in the reactor or in the post-reactor process. The in-reactor blending process is better than the post-reactor blending process, and most of the sequential connections are used. The reactor process is a preferred in-reactor blending process. These reactors may contain the same catalyst but operate under different conditions, such as different reactant concentrations, temperatures, pressures, etc., or operate under the same conditions but Addition of different catalysts 0 metal hydrates'· Metal hydrates useful in the practice of the invention include, but are not particularly limited to, for example, compounds having a trans group or water of crystallization, such as hydrazine and hydrazine. These metal hydrates They may be used singly or in combination of two or more. Examples of commercially available magnesium hydroxide include MAGNIFIN® manufactured by Matinswerk. Other examples include KISUMA 5, KI SUMA 5A, KISUMA 5B, KISUMA 5J, KISUMA 5LH and KISUMA 5PH (all trademarks and manufactures are from Kyowa Chemical Industries, Ltd.). Examples 商业f commercially available tris (hydrogen oxy) aluminum including MARTINAL manufactured by Matinswerk ® and HYDRAL manufactured by Alamatis. Before hydrating into the composition, the metal hydrate can be surface treated with a surface treatment agent (typically a decane surface treatment agent), or the surface untreated metal Κδ is combined with the surface treatment agent. Blending into the composition for surface treatment of the original 4. The appropriate amount of surface treatment agent added is an amount sufficient to provide the desired surface treatment of the metal hydrate. Surface to be added 19 201011064 Typical preferred amount of treatment agent It is 0.1 to 2.0% by weight based on the weight of the metal hydrate. Any surface treatment agent well known to those skilled in the art may be used without particular limitation. However, a decane surface treatment agent having an organic functional group such as an amine group, Isobutenyl, vinyl, epoxy and sulfhydryl groups are preferred and block fire and tensile properties In particular, a decane surface treatment agent having a vinyl group and/or an epoxy group is preferred. Face Agent: As described above, in the context of the present invention, the coupling agent is a polyfunctional compound, that is, one includes two types. A compound of the above functional group capable of binding two or more polymer chains together via covalent bonding under suitable reaction conditions. Poly(azide) coupling agents include alkyl and aryl azides Compound, sulfhydryl azide, azide formate, phosphoric acid azide, phosphonic acid azide, agglomerate azide, and poly(p-azide azide). The poly(sulfonyl azide) is a compound containing at least two reactive groups (sulfonyl azide groups (-s〇2N3)) which react with the polyolefin. Preferably, the poly(sulfonyl azide) has the structure X - R_X wherein each χ is -S〇2N3 and R represents an unsubstituted or passively substituted hydrocarbyl group, a hydrocarbyl ether hydrazone or a hydrazine-containing group, Preferably, the carbon has sufficient carbon, oxygen or hydrazine, preferably carbon atoms, to sufficiently separate the sulfonyl azide group for a facile reaction between the polyolefin and the sulfonium sulfonate. Examples of atoms or groups which may be substituted by substitution into R include, but are not limited to, fluorine, aliphatic ethers or aromatic ethers, oxime and sulfonyl stacks in which two or more polyolefin chains are linked together. Nitride group. R is a suitable aryl group, alkyl group, alkyl aryl group, arylalkyl decane, oxime or heterocyclic ring, a group which is blunt and separates a sulfonyl azide group as described in 20 201011064, and others Group. More preferably, R comprises at least one aromatic group between the sulfonyl groups, optimally 'at least two scent groups (such as when r is 4,4' diphenyl _ or 4, 4' _ When biphenyl is used). When R is an aryl group, preferably, the group has more than one ring, as in the case of a naphthyl bis(sulfonyl azide). Poly(sulfonyl) azides include, but are not limited to, the following compounds: ruthenium, 5-pentane bis(sulfonyl azide), 1,8-octane bis(sulfonyl azide), ruthenium , 1〇-decane bis(sulfonyl azide), 1,10-octadecane bis(sulfonyl azide), 丨-octyl-2,4,6-benzenedi(sulfonyl) Azide), 4,4,-diphenyl ether bis(sulfonyl azide), 1,6-bis(4'sulfonamide phenyl)hexane, 2,7-naphthalene bis (sulfonate) Base azide) 'a mixture of sulfonyl azide with a gasified aliphatic hydrocarbon having an average of 1 to 8 chlorine atoms and about 2 to 5 sulfonyl azide groups per molecule, and A mixture of two or more of the above compounds. Preferred poly(continuous sulfhydryl azides) include oxy-bis(4-continuous fluorenyl azide), 2,7-naphthalene bis (continuous decyl azide), 4,4, bis(sulfonate) Azidophenyl, 4,4,-diphenyl ether bis(sulfonyl azide) and bis(4-sulfonyl azidophenyl)methane, and two or more of the above compounds mixture. Examples of the decane coupling agent include vinyl-tris(p-methoxyethoxy)decane, vinyltriethoxydecane (VTES), vinyltrimethoxydecane (VMTS), γ-(mercaptopropene oxime) Propyl)-trimethoxydecane, γ-(methylpropoxyethoxypropyl)decyldimethoxydecane, 7-glycidoxypropylmethyldiethoxydecane and the like. VTES and VTMs are preferred decane coupling agents. 21 201011064 The amount of couplant used for the face-to-face, for example, typically based on the combined weight of the composition (ie, the combined weight of polypropylene, olefin interpolymer, and metal hydrate) is from 0.1 to 6, more typically from 0.1 to 5 and Most typically 0.2 to 3 wt%. additive 組成物可含有添加劑，其包括但不限於抗氧化劑、固 化劑、交聯共劑、助爆劑及阻滯劑、加工助劑、填充劑、紫 外線吸收劑或穩定劑、抗靜電劑、成核劑、滑動劑、塑化劑、 满滑劑、黏度控制劑、增稠劑、抗阻塞劑、介面活性劑、稀 釋油、酸清除劑及金屬去活化劑。可使用之添加劑數量範圍 基於組成物重量從少於約0.01至超過約10 wt%。The composition may contain additives including, but not limited to, antioxidants, curing agents, crosslinking agents, boosters and retarders, processing aids, fillers, UV absorbers or stabilizers, antistatic agents, nucleation Agents, slip agents, plasticizers, slip agents, viscosity control agents, thickeners, anti-blocking agents, surfactants, diluent oils, acid scavengers and metal deactivators. The amount of additive that can be used ranges from less than about 0.01 to over 10 wt% based on the weight of the composition. 抗氧化劑的例子如下所示，但不限於此：阻礙盼類(諸如 四[亞曱基(3,5-二-三級丁基-4-羥基氫-桂皮酸酯）]甲烷；雙 [(β-(3,5-二-三級丁基_4_羥基苄基)-甲基羧基乙基)]硫化物， 4,4·-硫雙(2-甲基-6-三級丁基酚），4,4，-硫雙(2-三級丁基·5_甲 基盼）’ 2,2’-硫雙(4-曱基-6-三級丁基盼）’及硫二乙稀雙(3 $ 二-三級丁基-4-羥基）氫桂皮酸酯）；亞磷酸鹽及磷灰石（諸如= (2,4-二-三級丁基酚基）亞磷酸鹽及二_三級丁基酚基-碟灰 石），硫化合物(諸如二-十二基硫二丙酸鹽，二_十四基硫_内 酸鹽’及二硬脂基硫二丙酸鹽）；各種矽烷；聚合的2,24_ = 甲基-1，2-二氫喹啉，η，η'-雙(1,4-二甲基戊基_ρ_伸笨基二胺）， 烷基化二酚基胺類，4,4，-雙(α，α-二甲基节基)二酚基胺，— 基-P-伸苯基二胺，混合的二-芳香基U申苯基二胺類，及其 他阻礙胺抗降解劑或穩定劑。可使用的抗氧化劑數量為某於 組成物重量約0.1至約5 wt%。 22 201011064 固化劑的例子如下所示：過氧化二異丙基苯；雙“丁 基-過氧基異丙基)苯；過氧化異丙基異丙絲t_丁基；過氧 化t-丁基異丙基苯；過氧化二何基；2,5_雙士丁基過氧 基)-2,5-二甲基己烷；2,5，t-丁基過氧基)_2,5_二甲基己 炔-3 ; 1，1-雙(t-丁基過氧基)3,3,5_三甲基環己燒；過氧化異丙 基異丙基苯異丙基苯；過氧化二(異丙基異丙基苯）；或其等 的混合物。可使用的過氧化物固化劑數量基於組成物重量為 ”’勺0.1至5 wt/〇各種其他已知固化共劑、助爆劑及阻滞^ 也可使用’諸如異三聚肢三稀丙基s| ;乙氧基化的雙盼A 二甲基丙烯α_甲基苯乙稀二聚物；及美國專利第 5,346,961及4,018,852號描述的其他共劑。 加工助劑的例子包括但不限於羧酸金屬鹽（諸如硬脂 酸酯辞或硬脂酸酯鈣）；脂肪酸（諸如硬脂酸、油酸或芥子 酸）；脂肪醯胺（諸如硬脂醯胺、油醯胺、芥子醯胺或η〆—乙 烯雙硬脂醯胺”聚乙烯臘；氧化的聚乙烯臘；氧化乙烯的 聚合物，氧化乙烯及氧化丙烯的共聚物；蔬菜臘；石油臘； 非離子介面活性劑；與聚矽烷。可以使用的加工共劑數量 基於組成物重量為約0.05至約5 wt%。 填充劑的例子包括但不限於粘上、沉澱的氧化矽及矽 酸鹽、燻化氧化石夕碳酸約、基礎礦物及算術平均顆粒大小 大於15奈米的碳黑。可使用的填充劑數量範圍基於組成物 重量為從少於約〇.〇1至超過約5〇 wt〇/〇。 組成物 23 201011064 組成物組份的反應性加工會導致固態、高溫聚合物的 較佳外形。反應性輕合的聚丙稀組成物展現抗熱性、對抗 著火及火焰散佈及較佳地’撓性性質。反應性加工產生較 佳的外形包括，但不限於，聚丙烯及烯烴互聚物的耦合。 使用的丙烯均聚物或共聚物可為任何的數量，只要當 纪成物未接續交聯饋出時可展現抗熱性及對抗著火及火焰 散佈即可。基於組成物的重量，丙烯均聚物或共聚物可包 括至少10、較佳地至少15及更佳地至少20wt%。組成物 中丙稀均聚物或共聚物最大數量的唯一限制為經濟上、實 馨 施上(例如，減少性回復)及組成物其他組份所需最少數量， 但典型上通常最大量基於組成物的重量包括少於5〇、較佳 地少於45及更佳地少於40wt%。 使用的烯烴互聚物可為任何的數量，只要當組成物未 交聯饋出時可展現抗熱性及對抗著火及火焰散佈即可。稀 烴互聚物基於組成物的重量可包括至少1〇、較佳地至少15 及更佳地至少20wt%。組成物中烯烴互聚物之最大數量的 唯一限制為經濟上、實施上(例如，減少性回復)及組成物其 魯 他組份所需的最少數量，但典型上通常最大量基於組成物 的重量包括少於50、較佳地少於45及更佳地少於40wt%。 使用之金屬水合物可為任何的數量，只要當組成物未 接續交聯饋出時可展現抗熱性、撓性及對抗著火及火焰散 佈的性質即可。金屬水合物基於組成物的重量可包括至少 35、較佳地至少40及更佳地至少5〇 wt%。組成物中金屬 水合物之最大數量的唯一限制為經濟上、實施上及組成物 24 201011064 其他組份所需的最少數量，但典型上，通常最大量基於組 成物的重量包括少於75、較佳地少於70及更佳地少於 65wt%。Examples of the antioxidant are shown below, but are not limited thereto: hindering the expectant class (such as tetrakis[-fluorenyl (3,5-di-tri-butyl-4-hydroxyhydro-cinnamate)] methane; double [( --(3,5-di-tert-butyl-4-ylhydroxybenzyl)-methylcarboxyethyl)]sulfide, 4,4·-thiobis(2-methyl-6-tributyl) Phenol), 4,4,-thiobis(2-tert-butyl-5-methyl-pan)' 2,2'-thiobis(4-mercapto-6-triphenyl) and sulphur Ethylene bis (3 $ di-tert-butyl-4-hydroxy)hydrocinnamate); phosphite and apatite (such as = (2,4-di-tertiary butyl phenolate) phosphite And bis-tertiary butyl phenol-disc limestone, sulfur compounds (such as di-dodecylthiodipropionate, di-tetradecylthio-lactone) and distearyl thiodipropionate Salt); various decane; polymerized 2,24_ = methyl-1,2-dihydroquinoline, η,η'-bis(1,4-dimethylpentyl_ρ_extended base diamine), Alkylation of diphenolic amines, 4,4,-bis(α,α-dimethylbenzyl)diphenolylamine, —P-P-phenylenediamine, mixed di-aromatic U Shen Phenyldiamines, and other barrier amine antidegradants or stabilizers. The amount of antioxidant that can be used is from about 0.1 to about 5 wt% of the weight of the composition. 22 201011064 Examples of curing agents are as follows: diisopropylbenzene peroxide; bis-butyl-peroxyisopropylbenzene; isopropylisopropylisopropoxide t-butyl; peroxidized t-butyl Isopropylbenzene; hexyl peroxide; 2,5-bis-butylperoxy)-2,5-dimethylhexane; 2,5,t-butylperoxy)_2,5 _Dimethylhexyne-3; 1,1-bis(t-butylperoxy) 3,3,5-trimethylcyclohexan; isopropylisopropyl phenyl isopropyl benzene; a mixture of di(isopropyl cumene) peroxide; or a mixture thereof, etc. The amount of peroxide curing agent that can be used is "0.1 to 5 wt / 〇 of various other known curing agents based on the weight of the composition. Boosters and Blocks ^ can also be used 'such as isotrimer tri-propyl s|; ethoxylated bis-A dimethyl propylene α-methyl phenylethylene dimer; and US patent Other co-agents described in 5,346,961 and 4,018,852. Examples of processing aids include, but are not limited to, metal carboxylates (such as stearate or calcium stearate); fatty acids (such as stearic acid, oleic acid or sinapic acid); fatty guanamines (such as stearin) Amine, oil amide, mustard amide or η〆-ethylene bis-lipid amide amine polyethylene wax; oxidized polyethylene wax; ethylene oxide polymer, copolymer of ethylene oxide and propylene oxide; vegetable wax; petroleum wax Nonionic surfactant; with polydecane. The amount of processing co-agent that can be used is from about 0.05 to about 5 wt% based on the weight of the composition. Examples of fillers include, but are not limited to, sticky, precipitated cerium oxide and ceric acid salts. , fumed oxidized olivine carbonate, base minerals, and carbon black having an arithmetic mean particle size greater than 15 nanometers. The amount of filler that can be used ranges from less than about 〇.〇1 to more than about 5 〇wt. 〇/〇. Composition 23 201011064 The reactive processing of the composition component results in a better appearance of the solid, high temperature polymer. The reactive lightly condensed polypropylene composition exhibits heat resistance, resistance to ignition and flame spread, and preferably 'Flexible properties. Reactive processing yields preferred shapes including, but not limited to, coupling of polypropylene and olefin interpolymers. The propylene homopolymer or copolymer used can be any amount as long as the product is not The heat resistance and resistance to ignition and flame spread may be exhibited upon subsequent crosslinking and feeding. The propylene homopolymer or copolymer may comprise at least 10, preferably at least 15 and more preferably at least 20% by weight, based on the weight of the composition. The only limitation on the maximum amount of propylene homopolymer or copolymer in the composition is the minimum amount required for economical, practical application (e.g., reduced recovery) and other components of the composition, but typically the maximum amount is usually based on the composition. The weight of the substance includes less than 5 Å, preferably less than 45 and more preferably less than 40% by weight. The olefin interpolymer used may be any amount as long as the composition exhibits heat resistance when it is not crosslinked and fed out. And against fire and flame spread. The dilute hydrocarbon interpolymer may comprise at least 1 Torr, preferably at least 15 and more preferably at least 20 wt%, based on the weight of the composition. The maximum number of olefin interpolymers in the composition is unique Limited to economy The minimum amount required to perform, for example, reduce the recovery, and the composition of the ruthenium component, but typically the maximum amount generally comprises less than 50, preferably less than 45 and more preferably based on the weight of the composition. The amount of the metal hydrate to be used may be any amount as long as the composition exhibits heat resistance, flexibility, and resistance to ignition and flame spread when the composition is not continuously fed out. The metal hydrate is based on The weight of the composition may include at least 35, preferably at least 40 and more preferably at least 5% by weight. The only limitation of the maximum amount of metal hydrate in the composition is economic, implementation and composition 24 201011064 Other components The minimum amount required, but typically the maximum amount generally comprises less than 75, preferably less than 70 and more preferably less than 65 wt%, based on the weight of the composition. ❹ 組成物也可包括雙-磺醯基疊氮化物及抗氧化劑的耦 合套組，抗氧化劑包括但不限於IRGan〇X® 1010或 IRGANOX® MD 1024。此套組包括至少〇 〇5、較佳地至少 〇_1及更佳地至少〇.2wt%的組成物。組成物中套組之最大 數量的唯一限制為經濟上、實施上及組成物其他組份所需 最少數量，但典型上通常最大量基於組成物的重量包括少 於2、較佳地少於i及更佳地少於〇 5加％。當組成物在饋 出器或其他混合裝置内以分子熔化物的型式存在時，套組 典型地加入至組成物中。 藉由習於此藝者所熟知的標準設備可達成纜線絕緣材 料的混合。混合設備的例子為内批式混合器，諸如 Banbury或BollingTM内混合器。或者，可使用連續的單 -或雙重扭轉混合^，諸如F_1TM連續混合器、I吻 及Pfleiderer雙重扭轉混合器或BussTM揉捏連續饋出 機。使用之混合器_叹混合器的操作狀況將會影 導性材料的性質，諸如黏度、體積電阻性及饋出表面的平 包括本發明組成物絕緣層的纜線可由各種類型饋出機 製備’例如單-或雙重扭轉型。傳統饋出機的描述記載於 美國專利第4’857’刚號中。共饋出及饋出機的例子可在美 國專利第5,575,965號中找到。典型的饋出機在其上游端具 25 201011064 有漏斗且在其下游端具有模件。漏斗將物料注入含有螺旋 器的桶中。在下游端，在螺旋器端及模件之間，i有篩r 及打破盤。饋域的《器部分被認為可分為三段，饋I 段、加壓段與計量段，及兩區，後加熱區及前加熱區，段 與區沿著上游至下游。在另外例子中’沿著上游至下游= 軸線可具有多個(超過兩個）的加熱區。若具有超過—個桶， 則該等桶序列連結。各桶之長度對直徑的比例範圍係約 15: 1至約3G:卜在饋出之後為聚合絕緣之交聯的導線包 覆操作中，_常常立即穿進饋出模件下游的加熱硫化 參 區。此加熱固化區的溫度範圍可維持在約2〇〇至約35〇^、 較佳地約Π0至約25〇〇此加熱區可以加麼蒸氣或是以傳 導加熱的加壓氮氣加熱。然而，藉著實施本發明，可以除 去饋出之後的交聯。 . 以下的例子說明各種本發明的實施例❶除非另有說 明’所有的部分及百分比均以重量計。 特別實施例 六個樣本組成物的分析報告於第1表。三個樣本（比較 參 例（CEX)及例1及例3)包括以聚烯烴彈性體（密度 0.870 g/cm3(ASTM D792)的 AFFINITY™ EG 8200 且可由 陶氏化學公司購得）反應性加工的聚丙烯均聚物 (H502-25R) ’ 以及由 Albemarle-Martinswerk 購得的 MAGNIFIN®H5 Mg(OH2)。兩樣本(例2及例4)包括以超低 密度聚乙烯(購自陶氏化學公司的ATTANE SC4107)反應性 加工的聚丙烯均聚物（H502-25R)，以及MAGNIFIN® H5 26 201011064 ’ Mg(OH2)。例5包括丙烯衝擊共聚物（C705-44NAHP)及烯烴 互聚物(VERSIFY™ 3300，12莫耳百分比的乙烯及88莫 耳百分比的丙烯，密度為0.866 g/ cm3及MFR為9.8 g/10 min(230°C/21.6kg))，兩者皆購自陶氏化學公司。 除了上述組份之外，樣本也包括購自杜邦公司（E.I.du Pont de Nemours and Company)的 FUSABOND® 494，其係 一種順丁烯二酸酐接枝的聚乙烯（密度為0.87 g/cc)。樣本也 包括 IRGANOX MD 1024、IRGANOX PS 802DSDP 及 ® CHIMASSORB 944、IRGANOX MD 1024 係一種購自汽巴 (Ciba)特用品化學的金屬去活化劑及抗氧化劑，〗rgANOX PS 802DSDP係一種用作與酚抗氧化劑（也購自汽巴特用品 化學)相結合的熱穩定劑，CHIMASSORB 944係一種受阻 ‘ 胺的光穩定劑（也購自汽巴特用品化學）。例3、4及5也包 ' 括1RGANOX 1010，其係一種抗氧化劑。例i_2及5與比 較例也包括Dow-Corning MB 50-001，其係一種含有分散於 Ο 聚丙烯均聚物中之50%超高分子量矽氧類聚合物的配方。 例1-2及5更包括雙磺醯基疊氮化物(BSA)及IRGANOX 1010的額外套組。EX 3及4更包括XL PEarl矽烷，其係 一種過氧化物、乙烯基三烷氧矽烷與矽烷去氫_縮合催化劑 的混合物。過氧化物在混合期間分解，造成乙烯基矽烷接 枝至聚合物鏈。在混合期間從金屬水合物釋出的少量濕氣 與去氫··縮合催化劑結合因而造成石夕燒-接枝聚合物鏈的麵 合0 第1表 27 201011064 測3式樣本的配方 比較 例 例1 例2 例3 例4 例5 PP(HP)H502-25R(%) 15 15 15 14 14 C705-44NAHP(%) 15 AFFINITY EG8200(%) 32.3 32 31 ATTANE SC4107(%) 32 31 VERSIFY 3300.00(%) 32 FUSABOND 494(%) 2 2 2 2 2 2 MAGNIFIN® H5 MV(°/〇) 50 50 50 50 50 50 IRGANOX MD 1024(%) 0.2 0.2 0.2 0.2 0.2 0.2 CHIMASSORB HALS 944(%) 0.2 0.2 0.2 0.2 0.2 0.2 IRGANOX 1010(%) 0.2 0.2 0.2 IRGANOX PS 802 DSTDP(%) 0.1 0.1 0.1 0.1 0.1 0.1 Dow-Corning MB 50-001(PP 為底 5 0%)(%) 0.2」 0.2 0.2 0.2 含 IRGANOX 1010 的 BSA分子熔化體(％) 0.3 0.3 0.3 XI PEARL 矽烷(％) 2.3 2.3 總量（Wt〇/o) 100 —&quot; 100 100 100 100 100 多個樣本用於測試彎曲係數、熔化流動指數、熱機械 分析(TMA)、熱固性或熱蠕動及抗張性，其等係以下述方 法製備：在160。(：下於5〇mii(1 27mm)模具中模製（來自混 合碗的材料)達10分鐘，接著在9〇c&gt;C水浴下固化6小時， 以製備一薄板。多個狗骨狀物件(d〇g_b〇nes)被切下且被測 试以提供平均測試值。 28 201011064 依據ISO 178試驗彎曲性質並報告於第2表中。彎曲 試驗測量在3點載重的狀況下彎曲橫桿所需要的力量。彎 曲係數用於表示當材料撓屈時，材料的堅硬程度。 第2表 測試樣本依據IS0179的彎曲試驗結果（1 mm/min) 比較例 例1 例2 例3 例4 例5 (MPa) 250.7 204.4 687.5 331.8 303.3 260.4❹ The composition may also include a coupling set of bis-sulfonyl azide and an antioxidant including, but not limited to, IRGan〇X® 1010 or IRGANOX® MD 1024. The kit comprises at least 〇5, preferably at least 〇_1 and more preferably at least 22% by weight of the composition. The only limit on the maximum number of kits in a composition is the minimum amount required for economics, implementation, and other components of the composition, but typically the maximum amount typically comprises less than 2, preferably less than i, based on the weight of the composition. And more preferably less than 〇5 plus%. When the composition is present in the form of a molecular melt in a feeder or other mixing device, the kit is typically added to the composition. The mixing of the cable insulation material can be achieved by standard equipment well known to those skilled in the art. An example of a mixing device is an internal batch mixer such as a Banbury or BollingTM internal mixer. Alternatively, a continuous single- or double twist mixing can be used, such as an F_1TM continuous mixer, a kiss and Pfleiderer double torsion mixer or a BussTM kneading continuous feeder. The operating conditions of the mixer used in the sigh mixer will be such that the properties of the photoconductive material, such as viscosity, volume resistivity, and the flattening of the surface including the insulating layer of the composition of the present invention can be prepared by various types of feeders. For example, single- or double-twisted type. A description of a conventional feeder is described in U.S. Patent No. 4'857'. An example of a co-feedout and a feeder can be found in U.S. Patent No. 5,575,965. A typical feeder has a funnel at its upstream end 25 201011064 and has a module at its downstream end. The funnel injects material into the bucket containing the screw. At the downstream end, between the end of the screw and the module, i has a screen r and a break disk. The feeder section of the feed zone is considered to be divided into three sections, the I section, the pressurization section and the metering section, and the two zones, the post heating zone and the front heating zone, and the section and zone along the upstream to the downstream. In another example, there may be multiple (more than two) heating zones along the upstream to downstream = axis. If there are more than one bucket, the bucket sequences are linked. The ratio of the length to the diameter of each barrel ranges from about 15:1 to about 3G: in the wire coating operation for cross-linking of the polymeric insulation after feeding, _ often immediately penetrates the heated vulcanized ginseng downstream of the feeding module Area. The heat curing zone can be maintained at a temperature in the range of from about 2 Torr to about 35 Torr, preferably from about Π0 to about 25 Torr. This heating zone can be heated by steam or by pressurized nitrogen gas which is heated by conduction. However, by practicing the present invention, cross-linking after feeding out can be eliminated. The following examples illustrate various embodiments of the invention, unless otherwise indicated, and all parts and percentages are by weight. Special Examples The analysis of the six sample compositions is reported in Table 1. Three samples (Comparative Examples (CEX) and Examples 1 and 3) included reactive processing with a polyolefin elastomer (AFFINITYTM EG 8200 at a density of 0.870 g/cm3 (ASTM D792) and available from The Dow Chemical Company) Polypropylene homopolymer (H502-25R)' and MAGNIFIN® H5 Mg(OH2) available from Albemarle-Martinswerk. Two samples (Examples 2 and 4) included a polypropylene homopolymer (H502-25R) reactively processed with ultra low density polyethylene (ATTANE SC4107 from The Dow Chemical Company), and MAGNIFIN® H5 26 201011064 'Mg (OH2). Example 5 included propylene impact copolymer (C705-44NAHP) and olefin interpolymer (VERSIFYTM 3300, 12 mole percent ethylene and 88 mole percent propylene, density 0.866 g/cm3 and MFR 9.8 g/10 min) (230 ° C / 21.6 kg)), both purchased from The Dow Chemical Company. In addition to the above components, the samples also included FUSABOND® 494, available from E. I. du Pont de Nemours and Company, which is a maleic anhydride grafted polyethylene (density 0.87 g/cc). The sample also includes IRGANOX MD 1024, IRGANOX PS 802DSDP and ® CHIMASSORB 944, IRGANOX MD 1024, a metal deactivator and antioxidant from Ciba special chemistry, rgANOX PS 802DSDP is used as a phenol resistant CHIMASSORB 944 is a heat stabilizer for oxidizing agents (also purchased from Steamer Chemicals), a hindered 'amine light stabilizer (also purchased from Steamer Chemicals). Examples 3, 4, and 5 also include 1RGANOX 1010, which is an antioxidant. Examples i_2 and 5 and Comparative Examples also include Dow-Corning MB 50-001, which is a formulation containing 50% ultrahigh molecular weight oxime polymer dispersed in a ruthenium polypropylene homopolymer. Examples 1-2 and 5 further include an additional set of disulfonyl azide (BSA) and IRGANOX 1010. EX 3 and 4 further include XL PEarl decane which is a mixture of a peroxide, a vinyl trialkoxysilane and a decane dehydrogenation-condensation catalyst. The peroxide decomposes during mixing, causing the vinyl decane to graft to the polymer chain. The small amount of moisture released from the metal hydrate during the mixing is combined with the dehydrogenation·condensation catalyst, thereby causing the surface of the Shixi-grafted polymer chain to be 0. Table 1 201011064 Comparison of formulas of the sample type 3 1 case 2 case 3 case 4 case 5 PP(HP)H502-25R(%) 15 15 15 14 14 C705-44NAHP(%) 15 AFFINITY EG8200(%) 32.3 32 31 ATTANE SC4107(%) 32 31 VERSIFY 3300.00 (% 32 FUSABOND 494(%) 2 2 2 2 2 2 MAGNIFIN® H5 MV(°/〇) 50 50 50 50 50 50 IRGANOX MD 1024(%) 0.2 0.2 0.2 0.2 0.2 0.2 CHIMASSORB HALS 944(%) 0.2 0.2 0.2 0.2 0.2 0.2 IRGANOX 1010 (%) 0.2 0.2 0.2 IRGANOX PS 802 DSTDP (%) 0.1 0.1 0.1 0.1 0.1 0.1 Dow-Corning MB 50-001 (PP bottom 50%) (%) 0.2" 0.2 0.2 0.2 IRGANOX 1010 BSA molecular melt (%) 0.3 0.3 0.3 XI PEARL decane (%) 2.3 2.3 Total (Wt〇/o) 100 —&quot; 100 100 100 100 100 Multiple samples for testing bending coefficient, melt flow index, thermomechanical Analysis (TMA), thermoset or thermal creep and tensile properties, etc. Said side Preparation Method: 160. (: molded in a 5 〇 mii (1 27 mm) mold (material from the mixing bowl) for 10 minutes, followed by curing in a 9 〇c &gt; C water bath for 6 hours to prepare a thin plate. (d〇g_b〇nes) was cut and tested to provide an average test value. 28 201011064 The bending properties were tested according to ISO 178 and reported in Table 2. The bending test measures the bending of the crossbar at a 3-point load. The required force. The bending coefficient is used to indicate the hardness of the material when the material is flexed. The test results of Table 2 are based on the bending test results of IS0179 (1 mm/min). Comparative Example 1 Example 2 Example 3 Example 4 Example 5 ( MPa) 250.7 204.4 687.5 331.8 303.3 260.4 依據IS01133在230C試驗熔化流動指數並報告於第 3表中。三種特定的重量2.16 kg、5 kg及21.6 kg顯示於第 3表。 第3表 測試樣本使用IS01133在230°C下的熔化流動指數 比較例 例1 例2 例3 例4 例5 2.16 kg 3.17 5 kg 0.52 21.6 kg 7.62 5.75 0.36 20.68 熱機械分析(TMA)係一種探針穿透試驗，其中以固定 速率加熱樣本並將穿透起始的溫度(軟化溫度)報告為tma 溫度。六個樣本的TMA溫度報告於第4表中。 罘4表The melt flow index was tested at 230 C according to IS01133 and reported in Table 3. Three specific weights of 2.16 kg, 5 kg and 21.6 kg are shown in Table 3. Table 3 Test sample using IS01133 Melt Flow Index at 230 ° C Comparative Example 1 Example 2 Example 3 Example 4 Example 5 2.16 kg 3.17 5 kg 0.52 21.6 kg 7.62 5.75 0.36 20.68 Thermomechanical Analysis (TMA) is a type of probe A penetration test in which the sample was heated at a fixed rate and the temperature at which the penetration started (softening temperature) was reported as the tma temperature. The TMA temperatures for the six samples are reported in Table 4.罘4 table 第5表報告150〇c下測量六個樣本中各個樣本的轨固 性結果。 ^ 29 201011064 第5表 測試樣本依據ΕΝ 60811-2-1在150°C/20N/cm2下的熱固性試驗 比較例 例1 例2 例3 例4 例5 熱延長（％) 破裂 115 47 61 7 215 放鬆延長(％) 63 25 32 — 1 204 第6表報告200°C下測量六個樣本中各個樣本的熱固 性結果。 第6表 測試樣本依據EN60811-2-1在200°C/20N/cm2下的熱固性試驗 〇 比較 例 例1 例2 例3 例4 例5 熱延長(％) 破裂 破裂 &gt;200 &gt;200 15 未測 放鬆延長(％) 34 第7表報告六個測試樣本的抗張性質。 第7表 測試樣本依據EN 60811-1-1在50mm/min下的抗張性質 比較例 例1 例2 例3 例4 例5 最終抗張強度(Mpa) 4.7 9.1 10.3 6.3 9.0 12.1 在破裂時的延長（％) 424 520 300 366 406 675 在上述的組成物中，以聚烯烴彈性體(AFFINITY®)或 超低密度聚乙烯(ATTANE®)或甚至是低乙烯含量的烯烴互 聚物(VERSIFYtm)反應性加工的丙烯均聚物，當未接續交聯 而饋出時，其展現(1)抗熱性、（2)對抗著火及火焰散佈及(3) 30 201011064 撓性。這些性質使得這些組成物適合於纜線應用，諸如 125°C等級的機動導線。 雖然本發明已經經由前述的說明詳盡地描述，但是如 此詳盡的說明只是為了說明的目的並不因此被解釋為對於 下述申請專利範圍的限制。所有引述的報告、參考文獻、 美國專利、獲准的美國專利申請案及美國專利申請公開案 均併入此處作為參考。 C圖式簡單說明3 (無） 【主要元件符號說明】 (無）Table 5 reports the results of the rail-solidity of each of the six samples measured at 150〇c. ^ 29 201011064 The test sample of the fifth table is based on the thermosetting test of ΕΝ 60811-2-1 at 150 ° C / 20 N / cm 2. Comparative Example 1 Example 2 Example 3 Example 4 Example 5 Thermal elongation (%) Rupture 115 47 61 7 215 Relaxation extension (%) 63 25 32 — 1 204 Table 6 reports the thermoset results of each of the six samples measured at 200 °C. Table 6 Test sample according to EN60811-2-1 thermosetting test at 200 ° C / 20 N / cm 2 〇 Comparative Example 1 Example 2 Example 3 Example 4 Example 5 Thermal elongation (%) Rupture and rupture > 200 &gt; 200 15 Untested relaxation extension (%) 34 Table 7 reports the tensile properties of the six test specimens. Comparison of Tensile Properties of Test Samples of Table 7 in accordance with EN 60811-1-1 at 50 mm/min Example 1 Example 2 Example 3 Example 4 Example 5 Final Tensile Strength (Mpa) 4.7 9.1 10.3 6.3 9.0 12.1 At the time of rupture Extension (%) 424 520 300 366 406 675 In the above composition, a polyolefin elastomer (AFFINITY®) or ultra low density polyethylene (ATTANE®) or even a low ethylene content olefin interpolymer (VERSIFYtm) Reactively processed propylene homopolymers exhibit (1) heat resistance, (2) resistance to fire and flame spread, and (3) 30 201011064 flexibility when fed without subsequent crosslinking. These properties make these compositions suitable for cable applications, such as motorized conductors of the 125 °C rating. While the invention has been described in detail by the foregoing description, the claims All cited reports, references, U.S. patents, issued U.S. patent applications, and U.S. patent application are hereby incorporated by reference. Simple description of C pattern 3 (none) [Explanation of main component symbols] (none) 31 201011064 發明專利說明書 細胸 '(本說明書格式、順序，請勿任意更動，※記號部分請勿填寫—-— -— ※申請案號：？个？ ※申請曰： 分類： 一、 發明名稱：（中文/英文） 經反應性加工之具有聚丙烯及烯烴互聚物的抗高熱組成物 REACTIVELY PROCESSED, HIGH HEAT RESISTANT COMPOSITION OF POLYPROPYLENE AND AN OLEFINIC INTERPOLYMER 二、 中文發明摘要： 一種丙烯聚合物耦合烯烴互聚物的方法，包括於反應性加工狀況 攀下至少接觸： A. 10 wt%的至少一丙稀聚合物； B. 10 wt%的至少一烯烴互聚物； C. 35 wt%的至少一金屬水合物；及 D. 柄合數量的耗合劑， 各重量百分比基於該丙烯聚合物、烯烴互聚物及金屬水合物的結合重 η 量。由包括該耦合之聚合物的組成物製造的導線及纜線絕緣鞘展現所 欲的抗熱性質。31 201011064 Invention patent specification thin chest '(The format and order of this manual, please do not change it arbitrarily, please do not fill in the ※ part of the mark----- ※Application number:?? ※Application曰: Classification: 1. Name of the invention: (Chinese/English) Reactively processed high thermal resistance composition with polypropylene and olefin interpolymer REACTIVELY PROCESSED, HIGH HEAT RESISTANT COMPOSITION OF POLYPROPYLENE AND AN OLEFINIC INTERPOLYMER II. Abstract: A propylene polymer coupled olefin interpolymer And a method comprising: climbing at least contact in a reactive processing condition: A. 10 wt% of at least one propylene polymer; B. 10 wt% of at least one olefin interpolymer; C. 35 wt% of at least one metal a hydrate; and D. a handle amount of the binder, each weight percentage based on the combined weight η of the propylene polymer, the olefin interpolymer, and the metal hydrate. The wire made of the composition including the coupled polymer and The cable insulation sheath exhibits the desired thermal resistance. 三、英文發明摘要： A propylene polymer is coupled with an olefinic interpolymer by a process comprising contacting under reactive processing conditions at least: A. 10 wt% of at least one propylene polymer; B. 10 wt% of at least one olefinic interpolymer; C. 35 wt% of at least one metal hydrate; and D. A coupling amount of a coupling agent, each weight percent based on the combined weight of the propylene polymer, olefinic interpolymer and metal hydrate. Wire and cable insulation sheaths made from compositions comprising the coupled polymer exhibit desirable heat resistance. 1 雙面影印 201011064 • 第98117449號專利申請案申請專利範圍修正本 七、申請專利範圍： 1. 一種用於耦合丙烯聚合物及烯烴互聚物的方法，該方法 包括在反應性加工狀況下接觸至少： Α. 10 wt%的至少一丙烯聚合物； B. 10 wt%的至少一稀烴互聚物； C. 35 wt%的至少一金屬水合物； D. 耦合數量的耦合劑；及 E. 任意地，一或多個添加劑。 2. 如申請專利範圍第1項的方法，其中該耦合劑係聚(磺醯 基)疊氮化物及含有乙烯基基團之矽烷的至少一者。 3. 如申請專利範圍第1項的方法，其中該耦合劑存在的數 量係基於該丙稀聚合物、浠烴互聚物及金屬水合物之結 合重量的0.1至6重量百分比。 4. 如申請專利範圍第1項的方法，其中該反應性加工狀況 包括150至280°C的溫度。 5. 如申請專利範圍第1項的方法，其中該烯烴互聚物為非 常低密度聚乙烯；均質分枝的、線性乙烯/α-烯烴共聚 物；均質分枝的、實質線性乙烯/ex-烯烴聚合物；線性中 密度聚乙烯、線性低密度聚乙烯、超低密度聚乙烯及烯 烴多嵌段共聚物的至少一者。 6. 如申請專利範圍第1項的方法，其中該烯烴互聚物係均 質分枝的、實質線性乙烯Αχ-烯烴聚合物，其單元含量中 來自乙烯單元的含量係至少80 wt%及密度係至少 0.870 g/cm3。 32 201011064 溏 七、申請專利範圍： 1. 一種用於耦合丙烯聚合物及烯烴互聚物的方法，該方法 包括在反應性加工狀況下接觸至少： A. 10 wt%的至少一丙烯聚合物； B. 10 wt%的至少一烯烴互聚物； C. 35 wt°/。的至少一金屬水合物； D. 耦合數量的耦合劑；及 E. 任意地，一或多個添加劑。 A 2. 如申請專利範圍第1項的方法，其中該耦合劑係聚(磺醯 基）疊氮化物及含有乙烯基基團之矽烷的至少一者。 3. 如申請專利範圍第1-2項中任一項的方法，其中該耦合 劑存在的數量係基於該丙烯聚合物、烯烴互聚物及金屬 水合物之結合重量的0.1至6重量百分比。 ‘ 4. 如申請專利範圍第1-3項中任一項的方法，其中該反應 ' 性加工狀況包括150至280°C的溫度。 5. 如申請專利範圍第1-4項中任一項的方法，其中該烯烴 互聚物為非常低密度聚乙烯；均質分枝的、線性乙烯/V-烯烴共聚物；均質分枝的、實質線性乙烯/V-烯烴聚合 物；線性中密度聚乙烯、線性低密度聚乙烯、超低密度 聚乙烯及烯烴多嵌段共聚物的至少一者。 6. 如申請專利範圍第1-5項中任一項的方法，其中該烯烴 互聚物係均質分枝的、實質線性乙烯/V-烯烴聚合物，其 單元含量中來自乙烯單元的含量係至少80 wt%及密度 係至少 0.870 g/cm3。 32 201011064 7. 如申請專利範圍第4項的方法，其中該金屬水合物係氫 氧化鋁及氫氧化鎂的至少一者。 8. 如申請專利範圍第1項的方法，其中一抗氧化劑存在的 數量係基於該丙烯聚合物、烯烴互聚物及金屬水合物之 結合重量的0.01至10 wt°/〇。 9. 一種由申請專利範圍第1-8項中任一項的方法製成的組 成物。 10. 如申請專利範圍第9項的組成物，其呈現導線或纜線絕 緣鞘的型式。III. English Abstract: A propylene polymer is coupled with an olefinic interpolymer by a process comprising contacting under reactive processing conditions at least: A. 10 wt% of at least one propylene polymer; B. 10 wt% of at least one olefinic interpolymer C. 35 wt% of at least one metal hydrate; and D. A coupling amount of a coupling agent, each weight percent based on the combined weight of the propylene polymer, olefinic interpolymer and metal hydrate. Wire and cable insulation sheaths made from 1 double-sided photocopying 201011064 • Patent application No. 98117449, the scope of patent application is amended. 7. Patent application scope: 1. A method for coupling a propylene polymer and an olefin interpolymer, The method comprises contacting at least: 10 wt% of at least one propylene polymer; B. 10 wt% of at least one dilute hydrocarbon interpolymer; C. 35 wt% of at least one metal hydrate; D. a coupled amount of coupling agent; and E. Optionally, one or more additives. 2. The method of claim 1, wherein the coupling agent is at least one of a poly(sulfonyl) azide and a vinyl group-containing decane. 3. The method of claim 1, wherein the couplant is present in an amount of from 0.1 to 6 weight percent based on the combined weight of the propylene polymer, the fluorene hydrocarbon interpolymer, and the metal hydrate. 4. The method of claim 1, wherein the reactive processing condition comprises a temperature of from 150 to 280 °C. 5. The method of claim 1, wherein the olefin interpolymer is a very low density polyethylene; a homogeneous branched, linear ethylene/α-olefin copolymer; homogeneously branched, substantially linear ethylene/ex- An olefin polymer; at least one of a linear medium density polyethylene, a linear low density polyethylene, an ultra low density polyethylene, and an olefin multi-block copolymer. 6. The method of claim 1, wherein the olefin interpolymer is a homogeneous, substantially linear ethylene sulfonium-olefin polymer having a content of ethylene units in a unit content of at least 80 wt% and a density system. At least 0.870 g/cm3. 32 201011064 溏 VII, the scope of the patent application: 1. A method for coupling a propylene polymer and an olefin interpolymer, the method comprising contacting at least: A. 10 wt% of at least one propylene polymer under reactive processing conditions; B. 10 wt% of at least one olefin interpolymer; C. 35 wt ° /. At least one metal hydrate; D. a coupling amount of a coupling agent; and E. optionally, one or more additives. A. The method of claim 1, wherein the coupling agent is at least one of a poly(sulfonyl) azide and a vinyl group-containing decane. 3. The method of any one of claims 1-2, wherein the coupling agent is present in an amount of from 0.1 to 6 weight percent based on the combined weight of the propylene polymer, olefin interpolymer, and metal hydrate. </ RTI> The method of any one of claims 1-3, wherein the reaction condition comprises a temperature of from 150 to 280 °C. 5. The method of any one of claims 1-4, wherein the olefin interpolymer is a very low density polyethylene; a homogeneous branched, linear ethylene/V-olefin copolymer; homogeneously branched, Substantially linear ethylene/V-olefin polymer; at least one of linear medium density polyethylene, linear low density polyethylene, ultra low density polyethylene, and olefin multi-block copolymer. 6. The method of any one of claims 1-5, wherein the olefin interpolymer is a homogeneous, substantially linear ethylene/V-olefin polymer having a unit content derived from ethylene units. At least 80 wt% and a density of at least 0.870 g/cm3. The method of claim 4, wherein the metal hydrate is at least one of aluminum hydroxide and magnesium hydroxide. 8. The method of claim 1, wherein the antioxidant is present in an amount of from 0.01 to 10 wt/min based on the combined weight of the propylene polymer, the olefin interpolymer, and the metal hydrate. 9. A composition made by the method of any one of claims 1-8. 10. The composition of claim 9, which presents the form of a wire or cable insulating sheath. 33 201011064 7. 如申請專利範圍第4項的方法，其中該金屬水合物係氫 氧化紹及氫氧化鎂的至少一者。 8. 如申請專利範圍第1-7項中任一項的方法，其中一抗氧 化劑存在的數量係基於該丙烯聚合物、烯烴互聚物及金 屬水合物之結合重量的0.01至10 wt°/〇。 9. 一種由申請專利範圍第1-8項中任一項的方法製成的組 成物。 10. 如申請專利範圍第9項的組成物，其呈現導線或纜線絕 緣鞘的型式。 33 201011064 四、指定代表圖： (一) 本案指定代表圖為：第（ ）圖。（無) (二) 本代表圖之元件符號簡單說明：The method of claim 4, wherein the metal hydrate is at least one of hydrogen oxidation and magnesium hydroxide. 8. The method of any one of claims 1 to 7, wherein an antioxidant is present in an amount of from 0.01 to 10 wt% based on the combined weight of the propylene polymer, the olefin interpolymer, and the metal hydrate. Hey. 9. A composition made by the method of any one of claims 1-8. 10. The composition of claim 9, which presents the form of a wire or cable insulating sheath. 33 201011064 IV. Designation of representative drawings: (1) The representative representative of the case is: ( ). (none) (2) A brief description of the symbol of the representative figure: 五、本案若有化學式時，請揭示最能顯示發明特徵的化學式： (無)5. If there is a chemical formula in this case, please reveal the chemical formula that best shows the characteristics of the invention: (none) 22
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