TW201008752A - Method for producing injection-molded article - Google Patents

Method for producing injection-molded article Download PDF

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Publication number
TW201008752A
TW201008752A TW98117030A TW98117030A TW201008752A TW 201008752 A TW201008752 A TW 201008752A TW 98117030 A TW98117030 A TW 98117030A TW 98117030 A TW98117030 A TW 98117030A TW 201008752 A TW201008752 A TW 201008752A
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Taiwan
Prior art keywords
resin
molded article
injection
volume
retention
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TW98117030A
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Chinese (zh)
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TWI476091B (en
Inventor
Mineo Ohtake
Mitsuhiro Mochizuki
Kazufumi Watanabe
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Polyplastics Co
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Publication of TWI476091B publication Critical patent/TWI476091B/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/2669Moulds with means for removing excess material, e.g. with overflow cavities
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0025Preventing defects on the moulded article, e.g. weld lines, shrinkage marks
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0025Preventing defects on the moulded article, e.g. weld lines, shrinkage marks
    • B29C2045/0044Preventing defects on the moulded article, e.g. weld lines, shrinkage marks expelling moulding material outside the mould cavity at the weld line location

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

To provide a method for producing an injection molded product which can nearly fundamentally determine the best position of plastic reserving and the best volume of plastic reserving in a metal mold with a desired degree of improvement and also sufficiently improve the weld strength for a thin injection molded product. The method for producing the injection molded product uses the metal mold, in which a resin reservoir is arranged to project from the vicinity of a weld part excepting the weld part, in at least one side of diversion passages until the weld part formed by confluence of a plurality of molten resin flows in a cavity, wherein the resin reservoir of the metal mold is so arranged as to satisfy the following formula (I): (Vd/V)>-71.4(V0/V)<SP>3</SP>+47.8(V0/V)<SP>2</SP>-10.0(V0/V)+0.78, when the volume of the molded product from a gate central part to the weld part is V, the volume of the molded product from the weld part to a gate central part of the resin reservoir, of V, is V0, and the volume of the resin reservoir is Vd.

Description

201008752 六、發明說明: 【發明所屬之技術領域】 本發明係關於可以改善熔接部強度的射出成形品 造方法。 【先前技術】 就一般的射出成形加工而言,在採用多點澆口之場 合’必然會產生熔接現象。熔接會產生在成形體之表面上, 對應於從澆口射出至模具之模穴中的熔融樹脂於產生分岐 後,又再次合流而形成的合流部位置,即使便是採用單點 洗口’就例如在進行具有較大偏肉比之射出成形品或是設 置有埋入銷之射出成形品的射出成形時之場合亦然。亦即 所謂溶接是指熔融樹脂流在合流時所形成的合流界面出 現於成形體的表面而顯示其接合部位。 這種成形品上的熔接,大多是由於上述各種要因重合 後而發生,以現實上具有複雜形狀之成形品而言,要作出 不發生熔接的成形品是極為困難。在此類之熔接部上,不 僅因為產生線狀模樣的所謂溶接痕(Weld mark)而損及外 觀’就以溶融樹脂僅是單純的合流而融著形成一雜化來 說’亦可能無法讓樹脂形成均勻的混合,而產生只能得到 遠低於樹脂原本所應具有強度的重大問題。 針對熔接部強度低下問題的改善方法,就以經由流道 (Runner)再從複數個澆口而將熔融樹脂射出至模具之模穴 中,並於該模具之模穴内對應至由複數處熔融樹脂流合流 後之合流部的位置,而在成形體的表面形成熔接部的熱向 201008752 性(Thermo tropic)液晶聚合物之射出成形方法而言,為了 讓上述合流熔融樹脂流中之一處在上述合流部形成實質上 的合流之後,能保有可以繼續流動的容積而作出與上述模 具中模穴不同之另外的模穴’並將該模穴設置於上述複數 個澆口其中一個澆口近旁的流道部上的方法係已公開周知 (請參照專利文獻1)。 此外在使用的模具中,從射出之熔融充填樹脂的分流 點開始,至該分流樹脂於合流後形成熔接部為止的各分流 樹脂流路中至少一處,設置由成形品模穴中突出的樹脂滯 留部’並内藏有可以進退活動的活塞(pist〇n),而利用在 形成熔接之後但内部的樹脂仍維持有流動性之時,讓熔接 部中的樹脂產生移動,來打亂熔接部内樹脂或是充填劑的 配向等,而有效的改善熔接部強度等方法及所使用的模具 亦已公開周知(請參照專利文獻2)。 改善熔接部強度低下之另一種方法,就以經由流道再 從複數個澆口而將熔融樹脂射出至模具之模穴中,並於該 模具之模穴内對應至由複數處熔融樹脂流合流後之合流部 的位置,而在成形體上形成熔接部的熱可塑性樹脂組成物 之射出成形方法而言,為了讓上述合流熔融樹脂流中之一 處在上述合流部形成實質上的合流之後,能保有可以繼續 流動的容積而作出樹脂滯留部,並將該樹脂滯留部突出而 叹置於上述模具之模穴或是至少一處流道上的方法亦已公 開周知。 先前技術文獻(專利文獻): 201008752 專利文獻1 :特開平05 — 318517號公報 專利文獻2 :特開平06 - 〇08293號公報 專利文獻3.特開平Q5 — 285990號公報 【發明内容】 發明所欲解決的課題:201008752 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to an injection molding method capable of improving the strength of a welded portion. [Prior Art] In the case of a general injection molding process, a fusion phenomenon is inevitably caused by the use of a multi-point gate. The welding is produced on the surface of the molded body, corresponding to the position of the confluent portion formed by the molten resin which is ejected from the gate to the cavity of the mold, and then merged again, even if a single-point washing is used. For example, it is also possible to perform injection molding of an injection molded article having a large partial meat ratio or an injection molded article having a buried pin. That is, the term "melting" means that the merged interface formed by the flow of the molten resin at the time of joining appears on the surface of the molded body to show the joint portion. The welding on such a molded article is often caused by the above-mentioned various factors being superposed, and it is extremely difficult to form a molded article which does not cause welding in a molded article having a complicated shape in reality. In such a welded portion, not only the so-called weld mark (Weld mark) which causes the linear pattern is damaged, but the appearance of the melted resin is only a simple merge and melts to form a hybrid. The resin forms a uniform mixture, and produces only a major problem that is far below the strength that the resin should have. For the improvement of the problem of low strength of the welded portion, the molten resin is ejected from the plurality of gates through the runner to the cavity of the mold, and corresponding to the molten resin in the mold cavity of the mold The heat of the welded portion is formed on the surface of the molded body at the position of the merged portion after the flow, and the injection molding method of the 2010 tropic liquid crystal polymer is used to make one of the above-mentioned merged molten resin streams After the confluence portion forms a substantial confluence, a volume capable of continuing to flow can be maintained to make another cavity different from the cavity in the mold, and the cavity is disposed in the vicinity of one of the plurality of gates. The method on the road is well known (please refer to Patent Document 1). Further, in the mold to be used, at least one of each of the shunt resin flow paths until the shunt resin forms a welded portion after joining is formed from the branching point of the molten molten resin to be injected, and the resin protruding from the cavity of the molded product is provided. The retention portion ' contains a piston that can move forward and backward, and the resin in the welded portion is moved to break the inside of the welded portion when the resin is still maintained after the fusion is formed. A method of effectively improving the strength of the welded portion, and a mold to be used, such as the alignment of the resin or the filler, is also known (see Patent Document 2). Another method for improving the strength of the welded portion is to eject the molten resin from the plurality of gates through the flow path into the cavity of the mold, and corresponding to the flow of the molten resin in the cavity of the mold. In the injection molding method of the thermoplastic resin composition in which the welded portion is formed at the position of the merging portion, in order to allow one of the merged molten resin streams to form a substantial merging in the merging portion, A method of retaining a resin retention portion that can continue to flow, and projecting the resin retention portion to sigh on a cavity or at least one flow path of the mold is also known. CITATION LIST Patent Literature PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT Problem solved:

就專利文獻1之方法而言並無適用於厚度3mm以下, 而就專利文獻3之方法而言並無適用於厚度4min以下之薄 型成形品的先例。而專利文獻2中所記載方法在應用於薄 型成形品之場合’亦無法充分的改善熔接部強度。然而在 使用薄肉連接器(Connecter)等之薄型精密成形品進行嵌 合時就產生了破裂等的問題。再加上近年來各種元件都在 進行薄肉化,故改善薄型成形品在成形作業時熔接強度是 一被追求改善之技術。 此外專利文獻2、3之方法係關於在樹脂合流後使其再 繼續流動的技術,就模具而言,樹脂滞留部的位置及體積 是與樹脂之固化速度、成形品體積、另外亦和樹脂溫度、 模具溫度、射出壓力等成形條件相互關連,故難以確切的 來加以規定。因此能針對所期望的改善程度,能幾乎確切 的來設定最佳之樹脂滯留部位置’而簡單的作出高品質的 射出成形品來亦是一被追求之技術。 尤其是在採用專利文獻2之方法之場合,如將樹脂滞 留部之體積加大時’雖然可以讓較多的樹脂在溶接部中移 動,亦可以改善熔接強[但周大型的樹脂滞留部會讓樹 脂消耗量增多’並不符合實際需[故盡可能的利用小型 201008752 的樹脂淨留部來改善炫接強度亦是一被追求之技術。 本發明之目的是要提供一種射出成形品的製造方法, 來解決以上所述之課題,並針對所期望的改善程度,能近 乎確切的設定最佳之樹脂滯留部位置、樹脂滯留部體積, 即使是對於薄型射出成形品亦可以充分的改善其熔接強 用以解決課題的手段: 本發明者為了解決上述等之課題而不斷的進行銳意研 究。其結果、即是-種射出成形品之製造方法,在其所使 用模具之模穴内,位於由複數處㈣樹脂流合流而形成溶 接部之前的至處分流路上,於該溶接部之外而靠近溶 接部之位置設置突出的樹脂滞留部,並且在將洗口中央部 起至熔接部為止的成形品體積設為v,將前述¥之中自熔 :部至前述樹脂滞留部之注入口中央部為止的成形品體積 設為V。’將前述樹脂滞留部的體積設為^之場合,如果前 述樹脂滯留部是被配置成能符合下述公式⑴之時,以此種 射出成形品之製造方法即可找出以上的問題解決之道並 得以進一步達成本發明的成效。在本發明中並提供更具體 的說明如下。 ' 公式(I ): (Vd / V) &gt; - 71. 4(V〇 / V)3+ 47. 8(V〇 / V)2- 10. 〇(Vo / V) + 0. 78 ...(I ) (1) 一種射出成形品之製造方法,在其所使用模具之 模八内位於由複數處熔融樹脂流合流而形成溶接部之職「 201008752 的至少一處分流路上’於前述熔接部之外而靠近熔接部之 處設置突出的樹脂滞留部’並且在將澆口中央部起至溶接 部為止的成形品體積a^為ν’將前述v之中自溶接部至前 述樹脂滞留部之注入口中央部為止的成形品體積設為v。, 將前述樹脂滯留部的體積設為Vd之場合,讓前述樹脂滞留 部配置成能符合下述公式α)的射出成形品之製造方法。 公式(I ): (Vd/ Y)&gt; -71.4(V〇/ V)3+47.8(V〇/V)2-1〇.〇(V〇/ V ) + 0. 78 ...(I ) (2) —種射出成形品之製造方法,在其所使用模具之 模穴内,位於由複數處熔融樹脂流合流而形成炼接部之前The method of Patent Document 1 is not applicable to a thickness of 3 mm or less, and the method of Patent Document 3 does not have a precedent for a thin molded article having a thickness of 4 minutes or less. On the other hand, when the method described in Patent Document 2 is applied to a thin molded article, the strength of the welded portion cannot be sufficiently improved. However, when a thin precision molded article such as a thin connector is used for lamination, problems such as cracking occur. Further, in recent years, various components have been thinned, so that the improvement of the fusion strength of the thin molded article during the forming operation is a technique which is sought to be improved. Further, the methods of Patent Documents 2 and 3 relate to a technique of continuing the flow after the resin is joined. In the mold, the position and volume of the resin retention portion are the curing speed of the resin, the volume of the molded article, and the temperature of the resin. Forming conditions such as mold temperature and injection pressure are related to each other, so it is difficult to specify them precisely. Therefore, it is also a technique pursued to easily and accurately set a high-quality injection molded article in order to accurately set the desired resin retention portion position with respect to the desired degree of improvement. In particular, when the method of Patent Document 2 is used, if the volume of the resin retention portion is increased, 'there may be a large amount of the resin retention portion, although the resin can be moved in the fusion portion. Increasing the consumption of resin does not meet the actual needs [so it is a technology pursued to use the small resin of the 201008752 as much as possible to improve the splicing strength. An object of the present invention is to provide a method for producing an injection-molded article, which solves the above-described problems, and which can accurately set the position of the resin retention portion and the volume of the resin retention portion in an almost exact manner. In order to solve the above problems, the present inventors have made intensive studies to improve the welding strength of the thin injection molded article. As a result, the method for producing an injection molded article is located in a cavity of a mold to be used, and is located at a branching path before a plurality of (4) resin flows to form a welded portion, and is close to the molten portion. The resin storage portion is provided at the position of the fused portion, and the volume of the molded product from the center portion of the rinsing portion to the welded portion is v, and the center portion of the injection port from the self-melting portion to the resin retention portion is formed. The volume of the molded article up to this is set to V. When the volume of the resin retention portion is set to ^, if the resin retention portion is arranged to conform to the following formula (1), the above problem can be solved by the method for producing the injection molded article. And can further achieve the results of the present invention. A more specific description is provided in the present invention as follows. 'Formula (I): (Vd / V) &gt; - 71. 4(V〇/ V)3+ 47. 8(V〇/ V)2- 10. 〇(Vo / V) + 0. 78 .. (I) (1) A method for producing an injection-molded article, in which a plurality of molten resin flows in a plurality of molten molds to form a fusion portion, at least one branching path of 201008752 Outside the portion, the protruding resin retentate portion is provided near the welded portion, and the volume of the molded product a from the center portion of the gate to the welded portion is ν', and the self-dissolving portion of the v is added to the resin retention portion. In the case where the volume of the resin-retaining portion is Vd, the resin-retaining portion is disposed so as to conform to the method of producing an injection-molded article of the following formula α). Formula (I): (Vd/Y)&gt; -71.4(V〇/V)3+47.8(V〇/V)2-1〇.〇(V〇/ V ) + 0. 78 ...(I (2) A method for producing an injection molded article, which is located in a cavity of a mold to be used, before a molten resin flows in a plurality of places to form a refining portion

的至少一處分流路上,於前述熔接部之外而靠近熔接部I 處設置突出的樹脂滯留部,並且在將澆口中央部起至熔接 部為止的成形品體積設為V,將前述V之中自熔接部至前 述榭脂滯留部之注入口中央部為止的成形品體積設為 將前述樹脂滞留部的體積設為L之場合,讓前述樹脂滞留 部配置成能符合下述公式(Π )的射出成形品之製造方法。 公式(Π ): V)+ 0. 66 CVd/Y)&gt;-35.6(V〇/V)3+27.〇(v〇/v)2_6/56(v〇 (Π ) (3) 當前述(W V)之值為〇· 1〇以上η 17 ” υ Μ上υ· 17以下時, (1)或是(2)中所記載的射出成形品之製造方法。 (4) 當前述(vd/v)之值為〇.10以上〇 25以下時, (1)至(3)中任何一項所記載的射出成形品之製造方法。’ 201008752 ⑸以液晶聚合物作為射出樹脂,當前述射出成形品 的厚度未達lmm時,在^ 至(4)中任何一項所記載的射出 成形品之製造方法。 發明效果: 利用本發明的射出成形品之製造方&amp;,在較用模具 ^模穴内,位於由複數處熔融樹脂流合流而形成熔接部之 則的至少一處分流路上,於前述熔接部之外而靠近熔接部 之位置設置突出的樹脂㈣部之方式,冑可以針對所期^ 的熔接強度之改善程度、而近乎確切的在所使用模具上設 定出举佳的樹脂滯留部位置、樹脂滯留部體積。 利用本發明,即使是對於未達lnm之極薄型射出成形 品亦可以充分的改善其熔接強度。 【實施方式】 以下係針對本發明之一種實施例來加以詳細的說明, 但本發明不應受以下實施例的限制,只要是在本發明之目 的的範圍内,可以適當的追加相關的變更而實施本發明。 本發明係關於一種射出成形品之製造方法,其特徵為 在其所使用模具之模穴内,位於由複數處熔融樹脂流合流 而形成溶接部之前的至少一處分流路上,於該熔接部之外 而靠近熔接部之處設置突出的特定樹脂滞留部。 【模具】 在本發明相關射出成形品之製造方法所使用的模具 中’是如上所述的保有樹脂滞留部。如果未作出樹脂滯留 部時,在熔接部中樹脂係被配向成與流動方向形成呈 201008752 的角度,故會因樹脂間交互糾纏等之相互作用較少,而造 成該部分強度低下之現象。在本發明中可經由樹脂流入樹 知滯留部之方式,即使在熔接部亦會讓樹脂產生樹脂流動 方向的配向’而得以改善熔接部之強度。此外在樹脂滯留 部之附近會呈現與樹脂流動方向呈垂直的角度的配向,亦 即產生朝向樹脂滞留部之注入口方向的配向,由於樹脂滯 留部係設置於熔接部之外而靠近熔接部之處,故可擾亂熔 • 接部中樹脂之配向,而得以增強樹脂間之相互作用、防止 溶接部之強度低下。 製造本發明相關射出成形品所使用的模具其特徵為, 在將自澆口中央部起至熔接部為止的成形品體積設為v, 將v之中自熔接部至上述樹脂滯留部之注入口中央部為止 的成形品體積設為v。’及上述樹脂滯留部的體積設為l之 場=,樹脂滯留部係被配置成能符合下述公式(】)。公式 )&quot;7以表示成’溶接部之彎曲強度達到其它部分之彎曲 強度的40%以上的領域。還有在產生熔接部而造成彎曲強 度之低下後’將殘餘彎曲強度的程度以保持率來表示,即 採用以(熔接部之彎曲強度/其它部分之彎曲強度)xl〇〇% 得之值例如·在下述公式(I )之場合是表示保持率為 40%以上的領域。 公式(I ): (Vd/ V)&gt; -71. 4(V〇/ Y)3+47.8(V〇/ V)2-1〇.〇(Vo/ V)+〇.78 ) 利用在模具中設置符合上述公式之樹脂滯留部的方 201008752 式,可確保熔接部之f曲強度達到其它部分之弯曲強度的 40%以上。本發明除了能如此大幅的改善熔接部之強度外, 同時亦可以針對所期望的改善程度’而近乎確切的來設定 使用模具中之最佳樹脂滯留部位置及樹脂滯留部體積。 熔接部f曲強度之測定方法是如後所述,並域用以 該方法測定所得之彎曲強度值。 此外當所使用之模具中樹脂滞留部位置被配置成符合 下述公式(m時’則所製造出之射出成形品其熔接部之彎 曲強度能達到其它部分之彎曲強度的5〇%以上。由於能進 _ 一步改善熔接部之強度,故為一理想的方法。與上述公式 (I )之場合同樣的’公式(Π)可以表示溶接部之弯曲強度 達到其它部分之彎曲強度的50%以上的領域。 公式(H ):At least one of the branching passages is provided with a protruding resin retaining portion near the welded portion I outside the welded portion, and the volume of the molded article from the central portion of the gate to the welded portion is set to V, and the aforementioned V When the volume of the molded article from the center of the injection port to the center of the injection port of the resin storage portion is set to be L, the resin retention portion is disposed so as to conform to the following formula (Π). A method of manufacturing an injection molded article. Formula (Π): V)+ 0. 66 CVd/Y)&gt;-35.6(V〇/V)3+27.〇(v〇/v)2_6/56(v〇(Π) (3) When the foregoing When the value of (WV) is 〇·1〇 or more η 17 υ Μ Μ υ 17 or less, the manufacturing method of the injection molded article described in (1) or (2). (4) When the above (vd/) When the value of v) is 〇.10 or more and 25 or less, the method for producing an injection-molded article according to any one of (1) to (3). 201008752 (5) using a liquid crystal polymer as an injection resin, and the injection molding described above When the thickness of the product is less than 1 mm, the method for producing an injection-molded article according to any one of the above-mentioned items, the effect of the invention is as follows: In the hole, at least one of the branching passages is formed by a plurality of molten resin flowing together to form a welded portion, and a protruding resin (four) portion is provided at a position close to the welded portion except the welded portion, and the 胄 can be used for the period of time The degree of improvement in the welding strength is almost exactly determined by setting the position of the resin retention portion and the volume of the resin retention portion on the mold to be used. The welding strength can be sufficiently improved even for an extremely thin injection molded article of less than 1 nm. [Embodiment] The following is a detailed description of an embodiment of the present invention, but the present invention should not be subjected to the following examples. The present invention is directed to a method for producing an injection molded article, which is characterized in that it is within the scope of the object of the present invention. At least one of the branching passages before the molten resin flows in a plurality of streams to form a welded portion, and a protruding specific resin retaining portion is provided outside the welded portion near the welded portion. [Mold] The injection molded article according to the present invention In the mold used in the production method, 'the resin retention portion is as described above. If the resin retention portion is not formed, the resin is aligned in the welded portion to form an angle of 201008752 with the flow direction, so The interaction of the interaction entanglement and the like is less, and the phenomenon of the strength is low. In the present invention, The manner in which the grease flows into the tree-retaining portion allows the resin to cause the direction of the flow direction of the resin in the welded portion to improve the strength of the welded portion. Further, the resin retains an angle perpendicular to the resin flow direction in the vicinity of the resin retention portion. The alignment, that is, the alignment toward the injection port of the resin retention portion, is provided in the resin retention portion outside the fusion portion and close to the fusion portion, thereby disturbing the alignment of the resin in the fusion portion and enhancing the resin The mold is used to prevent the strength of the melted portion from being lowered. The mold used for producing the injection molded article of the present invention is characterized in that the volume of the molded article from the center portion of the gate to the welded portion is v, and The volume of the molded article from the middle fusion portion to the center of the injection port of the resin retention portion is set to v. The volume of the resin retention portion is set to 1 field = and the resin retention portion is arranged to conform to the following formula ( )). The formula &quot;7 is expressed in the field where the bending strength of the molten portion reaches 40% or more of the bending strength of the other portion. Further, after the weld portion is produced to cause the bending strength to be lowered, the degree of the residual bending strength is expressed by the retention ratio, that is, the value obtained by (the bending strength of the welded portion / the bending strength of the other portion) x l 〇〇 % is used, for example. In the case of the following formula (I), it is a field indicating that the retention ratio is 40% or more. Formula (I): (Vd/V)&gt; -71. 4(V〇/Y)3+47.8(V〇/ V)2-1〇.〇(Vo/ V)+〇.78 ) Used in the mold In the formula 201008752 in which the resin retention portion conforming to the above formula is provided, it is ensured that the f-bending strength of the welded portion reaches 40% or more of the bending strength of the other portion. In addition to the fact that the strength of the welded portion can be greatly improved, the optimum resin retention portion position and the resin retention portion volume in the mold can be set almost exactly for the desired degree of improvement. The method of measuring the bending strength of the welded portion f is as described later, and the obtained bending strength value is measured by the method. Further, when the position of the resin retention portion in the mold to be used is arranged to conform to the following formula (when m is used, the bending strength of the welded portion of the injection molded article produced can reach 5 % or more of the bending strength of the other portion. It is an ideal method to improve the strength of the welded portion in one step. The same formula (Π) as in the case of the above formula (I) can mean that the bending strength of the welded portion reaches 50% or more of the bending strength of the other portion. Field. Formula (H):

(V,/ V)&gt;-35.6(V〇/ V)3+27.〇(Vo/ V)2-6.56(V V) + 0. 66 .“(Π) 強度 經由上述公式,就可以針對所期望達到的熔接部彎曲 ,而輕易的來設定樹脂滯留部之位置(V, / V) &gt; -35.6 (V 〇 / V) 3 + 27. 〇 (Vo / V) 2-6.56 (VV) + 0. 66 . "(Π) Intensity can be targeted by the above formula It is desired to achieve the bending of the welded portion, and it is easy to set the position of the resin retention portion.

樹脂滯留部之 體積。且又可以如後所述的,經由將樹脂滯留部之位 體積予以最佳化之方式,而抑制額外不需要的樹脂 量,並獲得所期望的熔接部強度改善之效果。 置、 消耗 在本發明相關射出成形品之製造方法中,V()/V之範圍 通常可視其所期望的射出成形品之熔接強度改善程度而 適當的予以變更。例如、在成形品之溶接部強度的保持率 必須達到40%以上之場合,只要符合上述公式(】),則製 10 201008752 造者可以自由的設定樹脂滞留部之位置、樹脂滞留部之體 積。就以此而言,v。/v之範圍是以0.1〇以上〇.17以下為 佳。雖然是如眾所周知的,相較於射出 樹脂滞留部之體積愈大之時,則樹脂的移動量愈多 擾亂樹脂配向,而熔接部之強度亦愈容易改善,但如參照 第4、5圖則可明白的看出,當Vc/V是位於上述範圍時, 可以在抑制樹脂滯留部體積的同時,又達成高熔接部強度 •改善之效果。此外由第5圖而明白的看出,如欲達成4〇% 以上的保持率時,Vd/v之範圍應是在〇 〇65以上。同樣的、 由第5圖可得知,能達成50%以上的保持率之ν。/ v範圍應 是在0. 085以上。此外還可由第4、5圏可明白的看出,當 V。/ V之範圍是在上述之〇· 10以上〇. 17以下時,因保持率 達至! 40%以上、50%以上的領域寬廣,能達成以上、 以上保持率的可能性高而甚為理想。 在本發明相關射出成形品之製造方法中,vd / V之範 •圍通常雖可視其所期望之熔接強度的改善程度,而適當的 予以變更,但以〇1〇以上0.25以下為佳。又雖然相較於 射出成形品之體積,當樹脂滯留部之體積愈大之時,則會 如上所述的愈容易改善熔接部之強度,但如樹脂滯留部之 體積較大時,會額外消耗較多的樹脂,而產生不利的費用 增加。 ¥ V〇/V之範圍是在〇.1〇以上0.15以下,而Vd/V之 範圍是在0· 10以上0.25以下時,因能得到非常高的熔接 部強度改善之效果,而且可抑制額外不需要的樹脂消耗 11 201008752 量,故甚為理想。 雖然樹月曰滯留部之設置位置是根據與樹脂滞留部間之 體積的關係而決疋,但當自溶接部起算至樹脂滞留部之距 離太長時#由樹脂滞留部來擾亂樹脂配向的效果就會因 距離關係而難以影響至熔接部’就會產生必須將樹脂滞留 部體積作成非常大的不利現象。又當自溶接部起算至樹脂 滞留部之距離太短時,亦即v。/ v是小於〇·呢之時,則 沿著溶接部之樹脂流動會受到擾乳,而難以產生與溶接部 呈垂直方向之配向故亦為不佳。又所謂「樹脂滞留部之距φ 離」是指自樹脂滯留部之注入口中央部至溶接部為止的距 離。 在本發明所使用之模具中,亦可以設置複數個樹脂滞 留部。在設置複數個樹脂滯留部之時,雖然能夠設置於兩 f的分流樹料而進行複雜的樹m人,但儘可能的仍 疋又在4的女流回路上並沿著熔接部來設置為佳。 對於連結模具及樹月旨滞留部之注入口的厚度雖然無特 別的限制,但注入口的厚度是在能讓樹脂保持流動的範圍 内’以較薄者為佳。緊縮注入口的厚度時,會在樹脂滯留 部内部之壓力與模穴内之堡力間產生較大的壓力差,讓樹 脂更容易流入,而較易在熔接部產生樹脂流動方向的配 向’然後又會在樹脂滯留部之附近擾亂樹脂的配向,加強 樹脂間的相互作用,來達成提高熔接強度改善的效果。 如上所述本發明所使用之模具,可以適用於眾所周知 的各種熱可塑性樹狀射以形,尤其是對於利習知 12 201008752 成形方法會造成在溶接部的強度急劇低下之物品 的效果。例如:結晶性樹脂、料是在如^別 行液晶性聚合物之成形時,去進 VL - ^ ^ , 奶石冷丧部之兩側分子县 &gt;。著熔接枝配向,故會在熔接部產生較其它部 低的強度,但如採用本發明之成形方法及模具時 在溶接部之配向能有效率的受到㈣,而可以充分的= 強:。此外在使用無機充填刺'特別是使用纖維狀 之‘,.'可塑性樹脂之時,無機充填劑、特別 填 會沿著溶接部而配向故容易產生同樣的_,而本= f形方法及模具,對於該等樹脂組成物之成形亦極 【射出成形品] 利用本發明之製造方法所能製造出之射出成形品的形 狀等並未特別受到限制,本發明之製造方法可以適用於各 種形狀之射出成形品的成形。 ❿ 以上述專利文獻i中所記截之方法等,在射出成形品 之厚度是極薄之場合就無法得到改善溶接強度的效果但 如利用本發明的射出成形品之製造方法時,即使是不到_ 厚度之薄型射出成形品’亦可以改善其熔接強度。並更進 -步可以改善不到0.5mm厚度之射出成形品的熔接強度。 而本發明之特徵之-’就是此種即便是薄型射出成形品亦 可以達成溶接強度之改善。 利用本發明之製造方法所獲得的射出成形品,可以讓 熔接部的強度大幅改善。相較於未設置樹脂滞留部之場 合,使用本發明4時可以達&amp; 3 #以上的炼接強度之改 201008752 體積等的設 善。又可能進一步再經由樹脂滯留部的位置 定,而達成4倍以上的熔接強度之改善。 本發明之製造方法,雖然是如上所述的可以適用於使 用各種樹脂之射出成形品的製造,但特別是適用於強度較 弱’在嵌合時易產生破裂等問題之薄肉連接器(c〇nnec=d 等的精密成形品上為佳。此外在如上所述之使用液晶性聚 合物的薄肉連接器i ’亦可以達纽接強度之改善,故可 以良好的適用本發明之製造方法。The volume of the resin retention. Further, as will be described later, the amount of the resin which is additionally unnecessary is suppressed by optimizing the volume of the resin retention portion, and the desired effect of improving the strength of the welded portion is obtained. In the method for producing an injection-molded article according to the present invention, the range of V()/V is usually changed as appropriate depending on the degree of improvement of the fusion strength of the injection-molded article desired. For example, when the retention ratio of the strength of the joint portion of the molded article must be 40% or more, the manufacturer of the resin retention portion and the volume of the resin retention portion can be freely set as long as the above formula (]) is satisfied. In this way, v. The range of /v is preferably 0.1 〇 or more 〇.17 or less. Although it is well known that the larger the volume of the resin-retaining portion is, the more the amount of movement of the resin disturbs the resin alignment, and the strength of the welded portion is more easily improved, but as shown in Figs. 4 and 5 It can be clearly seen that when Vc/V is in the above range, the effect of the strength and improvement of the high-welding portion can be achieved while suppressing the volume of the resin retention portion. Further, as apparent from Fig. 5, in order to achieve a retention ratio of 4% or more, the range of Vd/v should be 〇 65 or more. Similarly, as can be seen from Fig. 5, ν of 50% or more can be achieved. The range of / v should be above 0. 085. It can also be seen clearly by the 4th and 5th, when V. The range of /V is more than the above 〇·10 or more 17. 17 or less, because the retention rate is up to 40% or more, 50% or more is broad, and it is highly desirable to achieve the above or above retention rate. . In the method for producing an injection-molded article according to the present invention, the range of vd / V is usually appropriately changed depending on the degree of improvement of the desired weld strength, but it is preferably 〇1 or more and 0.25 or less. Further, although the volume of the resin retaining portion is larger as compared with the volume of the injection molded article, the strength of the welded portion is more easily improved as described above, but if the volume of the resin retaining portion is large, additional consumption is caused. More resin, resulting in an unfavorable cost increase. ¥ V〇/V is in the range of 〇.1〇 or more and 0.15 or less, and Vd/V is in the range of 0·10 or more and 0.25 or less, because it can obtain a very high weld joint strength improvement effect, and can suppress the extra Unwanted resin consumption is 11 201008752, so it is ideal. Although the position of the stagnant stagnation portion is determined according to the relationship with the volume between the resin retention portions, when the distance from the self-dissolving portion to the resin retention portion is too long, the effect of the resin aligning portion is disturbed by the resin retention portion. If it is difficult to influence the welded portion due to the distance relationship, there is a disadvantage that the volume of the resin retaining portion must be made very large. Further, when the distance from the dissolution joint to the resin retention portion is too short, that is, v. When /v is less than 〇·, the flow of the resin along the fusion portion is disturbed by the flow of the resin, and it is difficult to produce an alignment perpendicular to the fusion portion. The term "distance of the resin retention portion" means the distance from the center portion of the injection port of the resin retention portion to the fusion portion. In the mold used in the present invention, a plurality of resin retention portions may be provided. When a plurality of resin retention portions are provided, although it is possible to provide a complicated tree in the split tree of two f, it is preferable to set it on the female flow circuit of 4 and along the welded portion as much as possible. . The thickness of the injection port for the connection mold and the tree-shaped retention portion is not particularly limited, but the thickness of the injection port is preferably in a range in which the resin can be kept flowing. When the thickness of the injection port is tightened, a large pressure difference is generated between the pressure inside the resin retention portion and the fortification force in the cavity, so that the resin is more likely to flow, and the alignment of the resin flow direction is more likely to occur in the welded portion. The alignment of the resin is disturbed in the vicinity of the resin retention portion, and the interaction between the resins is enhanced to achieve an effect of improving the weld strength. The mold used in the present invention as described above can be applied to various known thermoplastic plastic tree shapes, and in particular, it is effective for the article in which the molding method causes a sharp decrease in the strength of the welded portion. For example, the crystalline resin and the material are subjected to VL - ^ ^ in the formation of the liquid crystalline polymer, and the molecular counties of both sides of the cold stone portion of the milk stone are &gt;. Since the fusion grafting is performed, the strength of the welded portion is lower than that of the other portions. However, when the molding method and the mold of the present invention are used, the alignment in the fusion portion can be efficiently obtained (4), and sufficient = strong:. In addition, when an inorganic filler thorn is used, in particular, when a fibrous "," plastic resin is used, the inorganic filler, particularly filled along the fusion portion, tends to produce the same _, and the present f-method and mold The molding of the resin composition is extremely excellent [injection molded article] The shape and the like of the injection molded article which can be produced by the production method of the present invention are not particularly limited, and the production method of the present invention can be applied to various shapes. The molding of the molded article is injected. ❿ In the method described in the above-mentioned Patent Document i, when the thickness of the injection molded article is extremely thin, the effect of improving the welding strength cannot be obtained. However, when the method for producing the injection molded article of the present invention is used, even if it is not The thin injection molded article of _ thickness can also improve the welding strength. Further, the step can improve the welding strength of the injection molded article having a thickness of less than 0.5 mm. Further, the feature of the present invention is that such an improvement in the bonding strength can be achieved even in the case of a thin injection molded article. According to the injection-molded article obtained by the production method of the present invention, the strength of the welded portion can be greatly improved. Compared with the case where the resin retention portion is not provided, the use of the present invention 4 can achieve the improvement of the refining strength of &amp; 3 # or more, and the design of the volume of 201008752. Further, it is possible to further improve the welding strength by four times or more via the position of the resin retention portion. The production method of the present invention is applicable to the production of an injection molded article using various resins as described above, but is particularly suitable for a thin meat connector which is weak in strength and which is liable to cause cracking during fitting (c〇). It is preferable to use a fine molded article such as nnec = d. Further, the thin meat connector i' using the liquid crystalline polymer as described above can also improve the bonding strength, so that the production method of the present invention can be suitably applied.

本發明的射出成形品之製造方法中,如果是採用如上 所述之配備著樹脂滯留部的模具時,並不會對樹脂之固化 速度、成形品容量’及樹脂溫度、模具溫度&amp;出壓力等 之成形條件等產生特別的限制。 【實施例】 、以下就透過具體的實施例來針對本發明再予以詳細的 說明,但本發明並不受限於該等實施例之限制。 〈材料〉 液晶性樹脂(PoiyPlastic公司產品「VectraE 13〇i」) 〈成形方法〉 」 下述評鏗例中之射出成形品,是利用第1圖中所示之模 具、成形機(SodickPlustech公司製造之「TR1〇〇EH」),並 按照以下的條件進行成形。所獲致之成形品的尺寸為50職x 5讓(下述表中顯示之厚度)。又在變更成形品之厚度時,是 以更換第1圓中所示之「蓋品·流道」的方式,在變更樹脂 滞留部之位置時,是以更換第i圖中所示之「樹腊滞留部」门 14 201008752 的方式’在變更樹脂滯留部之體積時,是以更換該當部之頂 出銷(Eject Pin)的長度,而變更樹脂滯留部深度的方式來 進行°此外關於熔接部之位置,則是經由未作出樹脂滞留部 之模具而取得射出成形品後,來加以確認。 〈成形條件〉 成形溫度:350。(:In the method for producing an injection-molded article of the present invention, when the mold having the resin retention portion as described above is used, the curing speed of the resin, the molded product capacity, and the resin temperature, the mold temperature, and the discharge pressure are not obtained. The forming conditions and the like are particularly limited. EXAMPLES The present invention will be further illustrated by the following examples, but the present invention is not limited by the examples. <Materials> Liquid crystal resin ("VectraE 13〇i", product of PoiyPlastic Co., Ltd.) <Forming method> The injection molded article in the following evaluation example is manufactured by Sodick Plustech Co., Ltd. using the mold and molding machine shown in Fig. 1 "TR1〇〇EH"), and formed according to the following conditions. The size of the obtained molded article was 50 jobs x 5 (the thickness shown in the table below). When the thickness of the molded article is changed, the "cover product and the flow path" shown in the first circle are replaced, and when the position of the resin retention portion is changed, the "tree" shown in the first figure is replaced. In the case of changing the volume of the resin retention portion, the length of the resin retention portion is changed by changing the length of the eject pin of the portion, and the depth of the resin retention portion is changed. In the position, the molded article is obtained by a mold in which the resin staying portion is not obtained, and is confirmed. <Forming conditions> Forming temperature: 350. (:

射出速度.:lOOnjm/ sec 模具溫度:70*t 週期時間:14秒 樹脂滞留部之位置與v。/ V間的關係,及樹脂滞留部 之深度與Vd / V間的關係,分別顯示於表i、表2中。 表1 :Injection speed: lOOnjm / sec Mold temperature: 70 * t Cycle time: 14 seconds The position of the resin retention part and v. The relationship between /V and the relationship between the depth of the resin retention portion and Vd / V are shown in Tables i and 2, respectively. Table 1 :

成形品厚度1.5咖t 0150 咖3) 成形品厚度0. 8咖t 080 咖3) 成形品厚度0.2iiinrt fV=20 Μη3) 樹腊滯留部位置 Vo (mm3) v〇/v V〇 (mm3) v〇/v V„ (mm3) V〇/V 1咖 7.5 0.05 4 0.05 1 0.05 2咖 15 0.10 8 0.10 2 0.10 3mm 22.5 0.15 12 0.15 3 0.15 5mm 37.5 0.25__ 20 0.25 5 0.25 表2 : 成形品厚度1. 5_t 成形品厚度0. 8mit 成形品厚度〇. 2wnnt 樹脂滯留部深度 Vd (mm3) (v=l&amp;mm3) ^=§0 mm3) (V=20 nun8) Va/V Vd/V Vd/V 1咖 7.065 〇. 0471 〇. 0883 0. 3533 2mm 14.13 〇· 0942 〇. 1766 0. 7065 3咖 21.195 〇-1413 〇· 2649 1.0598 15 201008752 〈實施例l &gt; 利用表3中所示的模具,製造出實施例及比較例之射 出成形品。並利用以下所示的方法測定出彎曲強度。測定 結果顯示於表3中。 〔彎曲強度之測定〕 利用第2圖中所示之彎曲試驗機(orieNTEC公司製造 「TENSILON RTA — 250」):試驗速度為 1 mm / min、跨距(Span) 為20mm、支點R為2. Omm,並採用第3圖中所示之荷重治 具(第3圖中所記載之尺寸是使用分釐卡尺(Micrometer) ® 測定所得’單位為mm),來針對實施例及比較例試驗片中 的熔接部彎曲強度,及熔接部以外部分之彎曲強度加以測 定。然後再經由上述之記算方法算出保持率。彎曲強度、 保持率則是顯示於表3中。 表3 : — 棋具 熔接部 弩曲強度 (MPa) 其它部分彎 曲強度 (MPa) 保持率 (¾) '-- 成形品厚度 (nun) 樹脂滯留部 深度(咖1) 樹脂滯留部 位置(咖) 注入口厚度 (mm) 例 1 0.2. 3 3 0.2 132.9 249.9 53.2 0.8 __3___ 0.1 116.3 186.1 62.5 例 3 1.5 3 3 0.1 92.5 170.9 54.1 0.2 39.5 249.9 15.8 i^-J2 0.8 未設置樹脂滯留部 27.6 186.1 14.8 1.5 27.4 170.9 16.0 於表3中為了能清楚明瞭,是在特定位置設置具有特 定體積之樹脂滞留部’並確認已獲得提高熔接部強度之改 善致果。此外並也確認了改善前(比較例)之保持率及改善 16 201008752 後(實施例)之保持率, 〈實施例2〉 党成形品厚度的影響。 _利用表4中所示之各種不同wv、Vd/V的模具’ 經由測定熔接部之彎 ' 、,Molded product thickness 1.5 coffee t 0150 coffee 3) molded product thickness 0. 8 coffee t 080 coffee 3) molded product thickness 0.2iiinrt fV=20 Μη3) tree wax retention position Vo (mm3) v〇/v V〇 (mm3) V〇/v V„ (mm3) V〇/V 1 coffee 7.5 0.05 4 0.05 1 0.05 2 coffee 15 0.10 8 0.10 2 0.10 3mm 22.5 0.15 12 0.15 3 0.15 5mm 37.5 0.25__ 20 0.25 5 0.25 Table 2 : Thickness of the molded article 1. 5_t Forming product thickness 0. 8mit Forming product thickness 〇. 2wnnt Resin retention depth Vd (mm3) (v=l&amp;mm3) ^=§0 mm3) (V=20 nun8) Va/V Vd/V Vd/ V 1 coffee 7.065 〇. 0471 〇. 0883 0. 3533 2mm 14.13 〇· 0942 〇. 1766 0. 7065 3 coffee 21.195 〇-1413 〇· 2649 1.0598 15 201008752 <Example l &gt; Using the mold shown in Table 3 The injection molded articles of the examples and the comparative examples were produced, and the bending strength was measured by the method described below. The measurement results are shown in Table 3. [Measurement of Bending Strength] Using the bending tester shown in Fig. 2 (OrieNTEC manufactures "TENSILON RTA - 250"): test speed is 1 mm / min, span (Span) is 20 mm, fulcrum R is 2. Omm, and Figure 3 is used. The load fixture shown in the figure (the size shown in Fig. 3 is measured by using a caliper (Micrometer) ® to measure the bending strength of the welded portion in the test piece of the embodiment and the comparative example, and the welding The bending strength of the portion other than the portion was measured. Then, the retention ratio is calculated by the above-described calculation method. The bending strength and retention ratio are shown in Table 3. Table 3: — Chess weld joint bending strength (MPa) Other part bending strength (MPa) Retention rate (3⁄4) '-- Forming product thickness (nun) Resin retention depth (Caf 1) Resin retention position (Caf) Note Inlet thickness (mm) Example 1 0.2. 3 3 0.2 132.9 249.9 53.2 0.8 __3___ 0.1 116.3 186.1 62.5 Example 3 1.5 3 3 0.1 92.5 170.9 54.1 0.2 39.5 249.9 15.8 i^-J2 0.8 Resin retention unit 27.6 186.1 14.8 1.5 27.4 170.9 16.0 In Table 3, in order to be clear, it is a case where a resin retaining portion having a specific volume is provided at a specific position and it is confirmed that an improvement in the strength of the welded portion is obtained. In addition, the retention rate before the improvement (comparative example) and the retention rate after the improvement (Example) were improved. <Example 2> The influence of the thickness of the party molded article. Using the various molds of different wv and Vd/V shown in Table 4, by measuring the bend of the welded portion,

率。伴持強度,㈣度之保持 v持率則是顯不於表4中。又第4圓是以橫軸為W /縱轴為Vd/V之方式而以圖形表^記載於點緣⑺… 部刀之數字為保持率。然後再將其連結後以圖形顯示保持 率為4(U以上,及保持率為5〇%以上的回歸曲線。rate. The holding strength, (four) degree retention, the holding rate is not shown in Table 4. Further, the fourth circle is such that the horizontal axis is W and the vertical axis is Vd/V, and is represented by a graph in the point edge (7). The number of the knife is the retention ratio. Then, after connecting them, the graph shows a regression curve with a retention rate of 4 (U or more and a retention ratio of 5% or more.

17 201008752 P 一- 比較例9 0.15 0. 094 IHIi 實施例22 0.15 0.18 57 實施例23 0.16 0.11 40 實施例24 0.16 0.16 50 實施例25 0.18 0.15 50 實施例26 0.18 0.11 40 實施例27 0.20 0.11 40 實施例28 0.20 0.15 50 實施例29 0.22 0.15 50 實施例30 0.22 0.11 40 實施例31 0.23 0.12 40 實施例32 0.23 0.15 50 實施例33 0.25 0.12 40 實施例34 ' 0.25 0.15 50 比較例10 0.25 0. 047 .. 17 實施例35 0.25 0.14 42 比較例11 0.25 0.094 30 比較例12 0.25 0.047 27 實施例36 0.27 0.13 40 實施例37 0.27 0.16 50 實施例38 0.30 0.14 40 實施例39 0.30 0.17 一 50 Φ 經由將表4予以圖形化而轉換成第4圖後,就清楚的 顯示了保持率為40%以上領域的近似曲線,及顯示了保持 率為50%以上的的近似曲線。還有圖形中之數字為保持率。 第5圖是以表4中所示之數據為基礎, 瞻⑽公司生產之 顯不了利用 率在m以上、_上體麵£6」所計算求得保持_ 上、3扣以上、4fllv l 60%以上、7⑽以上、8〇%以上 40化上、50%以上、 示之數字為保持率,而仅、9〇%以上的領域。圓形中顯 該領域令之佯捭查妒农 實線上方之領械 B * 保待率較實線所顧_ 心領域,是表示在 本發明是以第4圖二不之保持率還高。 不之回歸曲線來如 果界疋。在該第 參 18 201008752 · 圓中所顯不的’代表保持率為4〇%以上之回歸曲線及代表 保持率為50%以上之回歸曲線,與第5囷中所顯示的,代 ”持率為4(U以上之回歸曲線及代表保持率為5⑽以上 ^回歸曲線,嚴密的說並不相同,但如以第4、5圖中所顯 示的範圍而言,是對等的。 從回歸曲線就可以清楚的加以確認’當v&quot;v位於〇1 到。.17之範圍内時’可以一方面抑制樹脂滯留部的體積同 ❹時又改善了熔接強度。並又可確認當樹脂滯留部的體積愈 大時,就具有愈高的熔接強度改善效果。 〈實施例3〉 使用表5所顯示的具有不同厚度之注入口的模具並 製造出射出成形品。然後將各成形品之彎曲強度的保持率 顯示於表5中。 表5 : -------- 棋具 V〇/V WV 保持率 成形品厚度 (nan) 樹脂滞留部 深度(咖) 樹脂滯留部 位置(咖1) 注入口厚度 (晒) 實施例40 1.5 2 3 0.1 0.1 0.14 Cl 7 實施例41 1.5 2 3 0.4 0.1 0.14 〇1· { ΑΛ Ο 比較例13 1.5 2 3 0.75 0.1 〇. 14 41. 〇 實施例42 0.8 2 3 0.1 39.5 0.26 33. 8 實施例43 0.8 2 3 — _0,4 27.6 0.26 OU. 1 46. 5 比較例14 0.8 2 3 0.75 27.4 0.26 U 1 由表5之結果就可以清楚的加以確認,當注入口的厚 度愈薄時,就具有愈大的熔接強度改善效果。 [圖式簡單說明】 19 201008752 第1圖係實施本發明時所使用模具之圖式,(a)為正面 圖、(b)為A—A線剖面示意圖。 第2圖係評鑑成形品強度時使用的彎曲試驗機。 第3圖係評鑑成形品強度時使用的荷重治具。 第4圖係顯示(Vc&gt;/V)及(Vd/V)及保持率間相互關係 的圖表。 第5圖係經由計算所得之(Vc/V)及(Vd/V)及保持率 間相互關係的圖表。 【主要元件符號說明】17 201008752 P I - Comparative Example 9 0.15 0. 094 IHIi Example 22 0.15 0.18 57 Example 23 0.16 0.11 40 Example 24 0.16 0.16 50 Example 25 0.18 0.15 50 Example 26 0.18 0.11 40 Example 27 0.20 0.11 40 Implementation Example 28 0.20 0.15 50 Example 29 0.22 0.15 50 Example 30 0.22 0.11 40 Example 31 0.23 0.12 40 Example 32 0.23 0.15 50 Example 33 0.25 0.12 40 Example 34 '0.25 0.15 50 Comparative Example 10 0.25 0. 047 . 17 Example 0.25 0.14 42 Comparative Example 11 0.25 0.094 30 Comparative Example 12 0.25 0.047 27 Example 36 0.27 0.13 40 Example 37 0.27 0.16 50 Example 38 0.30 0.14 40 Example 39 0.30 0.17 a 50 Φ Via Table 4 After being converted into the fourth graph, it is clearly shown that the retention curve is in the range of 40% or more, and the approximate curve showing the retention ratio of 50% or more. Also the number in the graph is the retention rate. Figure 5 is based on the data shown in Table 4, and the production utilization rate of the company (10) is not calculated above m, _ upper body is £6, which is calculated and maintained _ up, 3 buckles, 4fllv l 60 % or more, 7 (10) or more, 8〇% or more, 40% or more, and the number shown is the retention rate, and only the area of 9% or more. The circular field shows that the field is the top of the line of the farmer's line B*. The guarantee rate is higher than the solid line. _ The heart area indicates that the present invention is still high in the fourth figure. . If the regression curve is not the same as the boundary. In the reference No. 18 201008752 · the regression curve of the representative retention rate of 4% or more and the regression curve representing the retention rate of 50% or more, and the retention rate shown in the fifth paragraph The regression curve of 4 (U and above) and the representative retention rate of 5 (10) or more are not strictly the same, but are equivalent to the range shown in Figures 4 and 5. From the regression curve It can be clearly confirmed that when the v&quot;v is in the range of 〇1 to .17, the weld strength can be improved while suppressing the volume of the resin retention portion on the one hand, and the resin retention portion can be confirmed. The larger the volume, the higher the welding strength improvement effect. <Example 3> The injection molded articles were produced using the molds having the injection ports of different thicknesses shown in Table 5. Then, the bending strength of each molded article was The retention ratio is shown in Table 5. Table 5: -------- Chess V〇/V WV Retention ratio Product thickness (nan) Resin retention depth (coffee) Resin retention position (Caf 1) Thickness (sun) Example 40 1.5 2 3 0.1 0.1 0.14 Cl 7 Example 41 1.5 2 3 0.4 0.1 0.14 〇1· { ΑΛ Ο Comparative Example 13 1.5 2 3 0.75 0.1 〇. 14 41. 〇 Example 42 0.8 2 3 0.1 39.5 0.26 33. 8 Example 43 0.8 2 3 — _0, 4 27.6 0.26 OU. 1 46. 5 Comparative Example 14 0.8 2 3 0.75 27.4 0.26 U 1 From the results of Table 5, it can be clearly confirmed that the thinner the thickness of the injection port, the greater the weld strength improvement effect. [Description of Schematic] 19 201008752 Fig. 1 is a diagram of a mold used in the practice of the present invention, (a) is a front view, (b) is a cross-sectional view taken along line A-A. Fig. 2 is a review of a molded article Bending tester used for strength. Fig. 3 is a load jig for evaluating the strength of a molded article. Fig. 4 is a graph showing the relationship between (Vc &gt;/V) and (Vd/V) and retention. Fig. 5 is a graph showing the relationship between (Vc/V) and (Vd/V) and retention ratios obtained by calculation.

Claims (1)

201008752 七、申請專利範圍: 1. 一種射出成形品之製造方法,在其中所使用模具之 模穴内,位於由複數處熔融樹脂流合流而形成熔接部之前 的至少一處分流路上,於前述熔接部之外而靠近熔接部之 位置設置突出的樹脂滯留部,並且在將澆口中央部起至溶 接部為止的成形品體積設為V,在前述V之中將自溶接部 至前述樹脂滯留部之注入口中央部為止的成形品體積設為 % v。’將前述樹脂滞留部的體積設為vd之場合,讓前述樹脂 滯留部配置成符合下述公式(I ): (Vd / V) &gt; - 71.4 (Vo / V)3+47.8(V〇/V)2-10.0(v〇/ V)+0.78 …(I)。 2. —種射出成形品之製造方法,在其中所使用模具之 模穴内’位於由複數處熔融樹脂流合流雨形成熔接部之前 的至少一處分流路上,於前述溶接部之外而靠近溶接部之 位置設置突出的樹脂滯留部,並且在將澆口中央部起至落 接部為止的成形品體積設為V,在前述V之中將自熔接部 至前述樹脂滯留部之注入口中央部為止的成形品體積設為 V。’將前述樹脂滯留部的體積設為Vd之場合,讓前述樹脂 滞留部配置成符合下述公式(Π ): (Vd / V)&gt; — 35. 6(V〇/ Y)3+27. 0(V〇/ Υ)2 — 6.56(V〇/ V) + 0. 66 …(Π )。 3. 如申請專利範圍第1項所述的射出成形品之製造 方法,其中前述(V。/ V)是0. 10以上0. Π以下。 4. 如申請專利範圍第1項所述的射出成形品之製造 21 201008752 方法,其中前述(Vd/V)是0.10以上0. 25以下。 5.如申請專利範圍第1項所述的射出成形品之製造 方法,其中前述射出成形品之厚度為不足1mm,且使用的 射出樹脂為液晶聚合物。201008752 VII. Patent application scope: 1. A method for manufacturing an injection molded article, wherein at least one branching path before the molten resin is merged to form a welded portion in a cavity of a mold used therein, in the welded portion In addition, a protruding resin retaining portion is provided at a position close to the welded portion, and a volume of the molded article from the center portion of the gate to the welded portion is V, and the self-melting portion is transferred to the resin retaining portion among the V portions. The volume of the molded product up to the center of the inlet is set to % v. When the volume of the resin retention portion is set to vd, the resin retention portion is arranged to conform to the following formula (I): (Vd / V) &gt; - 71.4 (Vo / V) 3 + 47.8 (V〇 / V) 2-10.0 (v 〇 / V) + 0.78 (I). 2. A method for producing an injection-molded article, wherein at least one of the manifolds in the cavity of the mold to be used is located at a plurality of branches before the molten resin flows and forms a welded portion, and is adjacent to the fusion portion outside the fusion portion The protruding resin retaining portion is provided at a position, and the volume of the molded product from the center portion of the gate to the reaching portion is V, and the self-welding portion is at the center of the injection port of the resin retaining portion. The molded article volume is set to V. When the volume of the resin retention portion is Vd, the resin retention portion is arranged to conform to the following formula (Π): (Vd / V) &gt; - 35. 6 (V〇 / Y) 3 + 27. 0(V〇/ Υ)2 — 6.56(V〇/ V) + 0. 66 ...(Π ). 3. The method for producing an injection-molded article according to the first aspect of the invention, wherein the above (V./V) is 0.10 or more. 4. The method of manufacturing an injection-molded article according to claim 1, wherein the (Vd/V) is 0.10 or more and 0.25 or less. 5. The method of producing an injection-molded article according to claim 1, wherein the thickness of the injection-molded article is less than 1 mm, and the injection resin used is a liquid crystal polymer. 22twenty two
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