TW200947142A - Surface shape measuring apparatus, exposure apparatus, and device manufacturing method - Google Patents

Surface shape measuring apparatus, exposure apparatus, and device manufacturing method Download PDF

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Publication number
TW200947142A
TW200947142A TW098106000A TW98106000A TW200947142A TW 200947142 A TW200947142 A TW 200947142A TW 098106000 A TW098106000 A TW 098106000A TW 98106000 A TW98106000 A TW 98106000A TW 200947142 A TW200947142 A TW 200947142A
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Taiwan
Prior art keywords
light
film
substrate
surface shape
reflected
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TW098106000A
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Chinese (zh)
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TWI416272B (en
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Wataru Yamaguchi
Takahiro Matsumoto
Hideki Ina
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Canon Kk
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/24Measuring arrangements characterised by the use of optical techniques for measuring contours or curvatures
    • G01B11/2441Measuring arrangements characterised by the use of optical techniques for measuring contours or curvatures using interferometry
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B11/00Measuring arrangements characterised by the use of optical techniques
    • G01B11/02Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness
    • G01B11/06Measuring arrangements characterised by the use of optical techniques for measuring length, width or thickness for measuring thickness ; e.g. of sheet material
    • G01B11/0608Height gauges
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B9/00Measuring instruments characterised by the use of optical techniques
    • G01B9/02Interferometers
    • G01B9/02055Reduction or prevention of errors; Testing; Calibration
    • G01B9/02062Active error reduction, i.e. varying with time
    • G01B9/02063Active error reduction, i.e. varying with time by particular alignment of focus position, e.g. dynamic focussing in optical coherence tomography
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B9/00Measuring instruments characterised by the use of optical techniques
    • G01B9/02Interferometers
    • G01B9/02055Reduction or prevention of errors; Testing; Calibration
    • G01B9/0207Error reduction by correction of the measurement signal based on independently determined error sources, e.g. using a reference interferometer
    • G01B9/02072Error reduction by correction of the measurement signal based on independently determined error sources, e.g. using a reference interferometer by calibration or testing of interferometer
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B9/00Measuring instruments characterised by the use of optical techniques
    • G01B9/02Interferometers
    • G01B9/0209Low-coherence interferometers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70483Information management; Active and passive control; Testing; Wafer monitoring, e.g. pattern monitoring
    • G03F7/70491Information management, e.g. software; Active and passive control, e.g. details of controlling exposure processes or exposure tool monitoring processes
    • G03F7/70516Calibration of components of the microlithographic apparatus, e.g. light sources, addressable masks or detectors
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/70Microphotolithographic exposure; Apparatus therefor
    • G03F7/70483Information management; Active and passive control; Testing; Wafer monitoring, e.g. pattern monitoring
    • G03F7/7055Exposure light control in all parts of the microlithographic apparatus, e.g. pulse length control or light interruption
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F9/00Registration or positioning of originals, masks, frames, photographic sheets or textured or patterned surfaces, e.g. automatically
    • G03F9/70Registration or positioning of originals, masks, frames, photographic sheets or textured or patterned surfaces, e.g. automatically for microlithography
    • G03F9/7003Alignment type or strategy, e.g. leveling, global alignment
    • G03F9/7023Aligning or positioning in direction perpendicular to substrate surface
    • G03F9/7026Focusing
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F9/00Registration or positioning of originals, masks, frames, photographic sheets or textured or patterned surfaces, e.g. automatically
    • G03F9/70Registration or positioning of originals, masks, frames, photographic sheets or textured or patterned surfaces, e.g. automatically for microlithography
    • G03F9/7049Technique, e.g. interferometric
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01BMEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
    • G01B2290/00Aspects of interferometers not specifically covered by any group under G01B9/02
    • G01B2290/70Using polarization in the interferometer

Abstract

A surface shape measuring apparatus includes an illumination system and a light receiving system. The illumination system splits wide-band light from a light source into measurement light and reference light, illuminates the measurement light to obliquely enter a surface of the film, and illuminates the reference light to obliquely enter a reference mirror. The light receiving system combines the measurement light reflected by the surface of the film and the reference light reflected by the reference mirror with each other and introduces the combined light to a photoelectric conversion element. An incident angle of the measurement light upon the surface of the film and an incident angle of the reference light upon the reference mirror are each larger than the Brewster's angle. S-polarized light and p-polarized light included in the measurement light entering a surface of the substrate have equal intensity on the photoelectric conversion element.

Description

200947142 六、發明說明: 【發明所屬之技術領域】 本發明係關於表面形狀量測設備以及曝光設備。 ~ 【先前技術】 - 說明相關於表面形狀量測設備及採用前者的曝光設備 之先前技術與需要高精確度表面形狀量測之半導體曝光設 ❹ 備。 當藉由使用光微影(印刷)技術而製造微結構半導體 裝置或液晶顯示裝置時,經由投影光學系統,使用投影曝 光設備以投影及轉移繪製於光罩(遮罩)上的電路圖案至 晶圓上。 於投影曝光設備中,較高封裝密度的半導體裝置造成 需要以較高解析功率投影光罩上的電路圖案至供曝光的晶 圓。投影曝光設備中可轉移的最小臨界尺寸(解析度)係 〇 成比例於曝光中所使用之光的波長,以及係反向成比例於 投影光學設備的數値孔徑(NA)。因此,設定曝光波長 . 爲較短値,獲得較高的解析功率。爲此緣故,近來已將投 影曝光設備中所使用的光源自超高壓水銀燈(即g線(波 長約436 nm)或i線(波長約365 nm))改變成KrF準 分子雷射(波長約248 nm)或ArF準分子雷射(波長約 193 nm),其發射較短波長的光。亦硏究浸潤曝光的實際 使用。另外,需要更加寬的曝光區域。 爲符合該等需要,主要曝光設備係由步進-及-重複形 -5- 200947142 式(亦稱爲“步進器”),其中藉由單次曝光以縮減尺寸於 晶圓上印刷實質上爲正方形的曝光區域,改變成步進_及· 掃描形式(亦稱爲“掃描器”),其中曝光區域具有矩形狹 縫形狀,以及可藉由以高速相對掃描光罩及晶圓而以較高 精確度曝光較大目標區域。 - 於掃描器中,於曝光期間,於晶圓上預定的位置到達 . 曝光狹縫區域之前,藉由呈光傾斜-入射系統形式之表面 位置偵測單元而量測於預定晶圓位置的晶圓表面位置(即 @ ,投影光學系統的光學軸之方向中的位置,亦稱爲焦點) 。根據量測結果,當曝光預定晶圓位置時,實施修正使得 晶圓表面對準供曝光的最佳焦點位置。 特別是,於曝光狹縫之縱長方向(與掃描方向垂直之 方向)的曝光狹縫區域中設定複數個量測點以不僅量測晶 圓表面位置的高度(焦點),並且量測晶圓表面傾斜。已 提出許多測量焦點及傾斜的方法。例如,日本專利公開第 06-260391號及美國專利第6,249,35 1號提出使用光學感 〇 測器作爲量測晶圓表面位置的方法。PCT國內公開第 2006-514744號提出使用組態的氣體線規感測器以噴灑空 - 氣至晶圓並且量測晶圓表面位置。亦提出另一使用靜電電 . 容感測器的方法。 然而,近年來因較短曝光光線波長及較大投影光學系 統NA的趨勢,焦點深度變得非常小,以及使待曝光的晶 圓表面與最佳焦點平面對準之精確度(即所謂的聚焦精確 度)的需求已提高至更高的水準。特別是’即便當量測錯 -6- 200947142 誤係晶圓上圖案的影響及晶圓上所塗覆之光阻的厚度變化 所引起時,不可忽略表面位置偵測單元的量測錯誤。 例如,因光阻厚度的變化,於接近周邊電路圖案處產 生對焦點量測爲明顯之程度的階梯狀高度差異及刻線’即 '使與焦點深度相較爲小。因此,光阻表面的傾斜角度增加 *,以及於藉由表面位置偵測單元所偵測的反射光中,於經 反射或折射之後,來自光阻後表面的反射光由鏡面反射角 Φ 偏移。另外,因晶圓上之圖案的密度差異,圖案緻密區域 與圖案粗糙區域間之反射率不同。因此,於藉由表面位置 偵測單元所偵測的經反射光中,來自光阻後表面之經反射 的光之反射角及反射強度改變,以及藉由偵測經反射的光 所獲得的波形變得不對稱以及產生量測錯誤。 圖19闡述對基材SB照射量測光MM的情況,於曰 本專利公開第06-260391號中所提出之光學感測器中,SB 於不同區域之反射率不同。於所閨述的情況中,量測光線 0 MM相對於不同反射率區域之間的邊界線處以A角度傾斜 ,使得於α ’所表示之方向中實施量測。圖20闡述於/3 ’ _ 所表示之方向中三個彼此分開的橫截面處,即橫截面ΑΑ’ ^ 、:ΒΒ’及CC’,之經反射的光之強度分佈。經反射的光於 橫截面ΑΑ’及CC’具有良好對稱。於包括不同反射率區域 的橫截面ΒΒ’處,經反射的光具有不對稱廓型。換句話說 ,經反射的光之重心(barycenter)自預定位置偏移,以 及產生量測錯誤。因此,藉由接收經反射的光所偵測的波 形信號變得不對稱以及所偵測之信號波形的對比顯著劣化 200947142 ,因此造成精確量測晶圓面位置的困難。此困難導致大的 失焦及晶片損壞。 如前述,取決於晶圓上的圖案經反射的光之強度因藉 由自光阻的前及後表面之經反射的光所產生的干涉而改變 。因此,於一些情況中,藉由接收經反射的光難以精確地 ' 偵測晶圓表面上的位置。 *200947142 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a surface shape measuring device and an exposure device. ~ [Prior Art] - Describes the prior art related to the surface shape measuring device and the exposure device using the former, and the semiconductor exposure device requiring high-accuracy surface shape measurement. When a microstructure semiconductor device or a liquid crystal display device is manufactured by using a photolithography (printing) technique, a projection exposure apparatus is used to project and transfer a circuit pattern drawn on a photomask (mask) to a crystal via a projection optical system. On the circle. In projection exposure apparatus, a semiconductor device of higher packing density results in the need to project a circuit pattern on the reticle to a wafer for exposure at a higher resolution power. The minimum critical dimension (resolution) that can be transferred in a projection exposure apparatus is proportional to the wavelength of the light used in the exposure, and is inversely proportional to the number of apertures (NA) of the projection optics. Therefore, set the exposure wavelength. For shorter turns, obtain higher resolution power. For this reason, the light source used in projection exposure equipment has recently been changed from ultra-high pressure mercury lamps (ie g-line (wavelength about 436 nm) or i-line (wavelength about 365 nm)) to KrF excimer laser (wavelength about 248). Nm) or ArF excimer laser (wavelength about 193 nm) that emits light of shorter wavelengths. Also consider the actual use of infiltration exposure. In addition, a wider exposure area is required. In order to meet these needs, the main exposure equipment consists of step-and-repeat type-5-200947142 (also known as "stepper"), in which a single exposure is used to reduce the size on the wafer. The squared exposed area is changed to a step_and-scan form (also referred to as a "scanner") in which the exposed area has a rectangular slit shape and can be compared by scanning the mask and the wafer at a high speed. Highly accurate exposure of large target areas. - in the scanner, during the exposure, at a predetermined position on the wafer, before the exposure slit region, the crystal at the predetermined wafer position is measured by the surface position detecting unit in the form of a light tilt-injection system The position of the circular surface (ie, the position in the direction of the optical axis of the projection optics, also known as the focus). Based on the measurement results, when the predetermined wafer position is exposed, a correction is made such that the wafer surface is aligned with the best focus position for exposure. In particular, a plurality of measurement points are set in the exposure slit region in the longitudinal direction of the exposure slit (the direction perpendicular to the scanning direction) to measure not only the height (focus) of the wafer surface position, but also the wafer. The surface is tilted. Many methods of measuring focus and tilt have been proposed. For example, Japanese Patent Publication No. 06-260391 and U.S. Patent No. 6,249,35, the disclosure of which is incorporated herein by reference. PCT Domestic Publication No. 2006-514744 proposes the use of a configured gas gauge sensor to spray air-to-wafer to the wafer and measure the wafer surface position. Another method of using an electrostatic capacitance sensor is also proposed. However, in recent years, due to the trend of shorter exposure light wavelengths and larger projection optical system NA, the depth of focus becomes very small, and the accuracy of aligning the surface of the wafer to be exposed with the best focal plane (so-called focusing) The need for precision has been raised to a higher level. In particular, even if the equivalent error measurement -6-200947142 is caused by the influence of the pattern on the wafer and the thickness variation of the photoresist applied on the wafer, the measurement error of the surface position detecting unit cannot be ignored. For example, due to the change in the thickness of the photoresist, a step height difference and a reticle 'i' which is close to the depth of focus are generated at a level close to the peripheral circuit pattern. Therefore, the tilt angle of the photoresist surface is increased by *, and in the reflected light detected by the surface position detecting unit, after being reflected or refracted, the reflected light from the rear surface of the photoresist is shifted by the specular reflection angle Φ . In addition, the reflectance between the dense region of the pattern and the rough region of the pattern is different due to the difference in density of the pattern on the wafer. Therefore, in the reflected light detected by the surface position detecting unit, the reflected angle and the reflected intensity of the reflected light from the rear surface of the photoresist are changed, and the waveform obtained by detecting the reflected light is detected. Become asymmetrical and produce measurement errors. Fig. 19 illustrates the case where the substrate SB is irradiated with the light metering MM. In the optical sensor proposed in Japanese Patent Laid-Open Publication No. 06-260391, the reflectance of the SB is different in different regions. In the case described, the measuring ray 0 MM is inclined at an A angle with respect to a boundary line between different reflectance regions, so that the measurement is performed in the direction indicated by α '. Figure 20 illustrates the intensity distribution of the reflected light at three mutually separated cross sections in the direction indicated by /3 ' _, i.e., the cross sections ΑΑ' ^ , : ΒΒ ' and CC'. The reflected light has good symmetry in the cross sections ΑΑ' and CC'. At a cross-section ΒΒ' comprising regions of different reflectivity, the reflected light has an asymmetrical profile. In other words, the barycenter of the reflected light is offset from the predetermined position and a measurement error is generated. Therefore, the waveform signal detected by receiving the reflected light becomes asymmetrical and the contrast of the detected signal waveform is significantly degraded 200947142, thus causing difficulty in accurately measuring the position of the wafer surface. This difficulty leads to large out-of-focus and wafer damage. As mentioned above, the intensity of the reflected light depending on the pattern on the wafer is altered by the interference caused by the reflected light from the front and back surfaces of the photoresist. Therefore, in some cases, it is difficult to accurately 'detect the position on the wafer surface by receiving the reflected light. *

圖23闡述美國專利第6,249,3 5 1號中所揭露之表面 形狀量測設備的結構。所揭露的表面形狀量測設備包括光 Q 源101、透鏡103、光束分裂器105、參考鏡130、呈繞射 光柵形式之光束組合器17〇、透鏡171、透鏡173,以及 光電轉換元件175。於該表面形狀量測設備中,光係傾斜 地照射至樣本3 60,以及藉由光電轉換元件1 75所偵測的 干涉信號而決定樣本3 60的形狀。藉由光電轉換元件175 所接收的光包括自光阻的前表面所反射的光及自光阻的後 表面所反射的光。此提高了精確地量測光阻之前表面形狀 的難度。圖21闡述習知設備中所獲得的干涉信號,圖23 〇 闡述於垂直樣本表面的方向中藉由致動器3 97掃描樣本 3 60。當量測晶圓上無圖案的樣本時獲得圖2 1中之干涉信 , 號,以及當樣本上僅塗覆光阻時獲得圖22中所闡述者。 _ 因爲所接收的光不僅包括來自光阻的前表面之經反射的光 亦包括來自光阻的後表面之經反射的光,於此狀態下量測 形成的干涉信號使得藉由來自光阻的後表面之經反射的光 所產生的干涉以疊加方式影響藉由來自光阻的前表面之經 反射的光所產生的干涉。此導致僅使用來自光阻的前表面 -8 - 200947142 之經反射的光精確地偵測光阻前表面之高度資訊的難度。 爲於分開來自光阻的前及後表面之經反射的光同時量測干 涉信號,美國專利第6,249,3 5 1號提出一種藉由增加於基 材的入射角而增加光阻的前表面之反射率的方法。美國專 •利第6,249,35 1號說明,與來自光阻的後表面之經反射的 * 光相較,所提出的方法有效於相對地增強來自基材上之光 阻的前表面之經反射的光。 Q 然而,當基材由A1或Cu所構成且具有高反射率,光 阻的後表面(即光阻/基材介面)具高程度反射率使得無 法充分抑制來自光阻的後表面之經反射的光之影響,即便 當設定於基材上之光的入射角爲大的値之時。因此,錯誤 由量測光阻前表面形成的値所產生。 另外,當如PCT國內公開第2006-514744號中所述使 用氣體線規感測器時,發生氣體中所混合之細顆粒亦被噴 灑至晶圓上的特定問題,且不能於真空下操作之曝光設備 Q ,如使用超紫外光的EUV (超紫外光)曝光設備,中使 用氣體線規感測器,因爲真空度因經噴灑的氣體而下降。 _ 【發明內容】 根據本發明之一面向,表面形狀量測設備可高精確地 量測表面形狀而不會受到基材之反射率分佈及膜所引起之 干涉的影響。 本發明之另一面向,提供一種表面形狀量測設備,係 組態以量測基材上所形成之膜的表面形狀。表面形狀量測 -9- 200947142 設備包括照射系統,係配置以將來自光源的寬頻帶光分裂 成爲量測光及參考光,量測光係照射以傾斜地進入膜的表 面,參考光係照射以傾斜地進入參考鏡;光接收系統,係 配置以使藉由膜之表面所反射的量測光及藉由參考鏡所反 射的參考光彼此組合,以及將組合的光導至光電轉換元件 - ;以及處理單元,係組態以基於藉由光電轉換件所偵測的 . 干涉信號而計算膜之表面形狀。於膜之表面的量測光之入 射角及於參考鏡之參考光的入射角各者皆大於布魯斯特( qFigure 23 illustrates the structure of a surface shape measuring apparatus disclosed in U.S. Patent No. 6,249,315. The disclosed surface shape measuring apparatus includes a light Q source 101, a lens 103, a beam splitter 105, a reference mirror 130, a beam combiner 17 in the form of a diffraction grating, a lens 171, a lens 173, and a photoelectric conversion element 175. In the surface shape measuring apparatus, the light system is obliquely irradiated to the sample 3 60, and the shape of the sample 3 60 is determined by the interference signal detected by the photoelectric conversion element 175. The light received by the photoelectric conversion element 175 includes light reflected from the front surface of the photoresist and light reflected from the rear surface of the photoresist. This improves the difficulty of accurately measuring the shape of the surface before the photoresist. Figure 21 illustrates the interference signal obtained in a conventional device, and Figure 23 illustrates the scanning of sample 3 60 by actuator 3 97 in the direction of the vertical sample surface. The interference signal in Figure 21 is obtained when the unpatterned sample on the wafer is equivalently measured, and the one illustrated in Figure 22 is obtained when only the photoresist is applied to the sample. _ because the received light includes not only the reflected light from the front surface of the photoresist but also the reflected light from the back surface of the photoresist, and the interference signal formed in this state is measured by the light from the photoresist The interference produced by the reflected light from the back surface affects the interference produced by the reflected light from the front surface of the photoresist in a superimposed manner. This results in the difficulty of accurately detecting the height information of the front surface of the photoresist using only the reflected light from the front surface -8 - 200947142 of the photoresist. In order to simultaneously measure the interference signals from the reflected light from the front and back surfaces of the photoresist, U.S. Patent No. 6,249,315 proposes to increase the front surface of the photoresist by increasing the angle of incidence of the substrate. The method of reflectivity. U.S. Patent No. 6,249,35, the disclosure of which is directed to the relative enhancement of the front surface of the photoresist from the substrate as compared to the reflected light from the back surface of the photoresist. Light. Q However, when the substrate is composed of A1 or Cu and has high reflectivity, the rear surface of the photoresist (ie, the photoresist/substrate interface) has a high degree of reflectivity, which makes it impossible to sufficiently suppress the reflection from the rear surface of the photoresist. The effect of light, even when the incident angle of light set on the substrate is large. Therefore, the error is caused by the flaw formed by measuring the front surface of the photoresist. In addition, when a gas gauge sensor is used as described in PCT Domestic Publication No. 2006-514744, the specific problem that fine particles mixed in the gas are also sprayed onto the wafer occurs, and cannot be operated under vacuum. The exposure apparatus Q, such as an EUV (Ultraviolet Light) exposure apparatus using ultra-ultraviolet light, uses a gas gauge sensor because the degree of vacuum is lowered by the sprayed gas. SUMMARY OF THE INVENTION According to one aspect of the present invention, a surface shape measuring apparatus can measure a surface shape with high accuracy without being affected by a reflectance distribution of a substrate and interference caused by a film. Another aspect of the present invention provides a surface shape measuring apparatus configured to measure a surface shape of a film formed on a substrate. Surface Shape Measurement-9- 200947142 The apparatus includes an illumination system configured to split broadband light from the light source into measurement light and reference light, the measurement light system illuminates obliquely into the surface of the film, and the reference light system illuminates obliquely Entering a reference mirror; the light receiving system is configured to combine the measured light reflected by the surface of the film and the reference light reflected by the reference mirror with each other, and to direct the combined light to the photoelectric conversion element - and the processing unit The system is configured to calculate the surface shape of the film based on the interference signal detected by the photoelectric conversion member. The incident angle of the measured light on the surface of the film and the incident angle of the reference light to the reference mirror are larger than Brewster (q

Brewster)角。進入基材表面之量測光中所包括的s極化 光及P極化光對於光電轉換元件具有相同強度。 利用根據本發明之一面向的表面形狀量測設備,基於 當入射角大於布魯斯特角時P極化光之相位改變的性質, 藉由抑制藉由來自光阻(膜)的後表面所反射的光之影響 可減少光學量測中所產生的錯誤。因此,表面形狀量測設 備能夠精確地量測如設置光阻之膜的前表面位置。另外, 提供一種曝光設備,相關於小的焦點深度其可實現高焦點 ◎ 精確度,且其可增加良率。 參考隨附圖式,由以下例示性實施例之說明,本發明 _ 的其他特徵將顯而易見。 【實施方式】 於以下參考隨附圖式將說明本發明之例示性實施例。 要注意的是,於所有圖式中’以相同元件符號表示相同的 分量並省略重複的描述。 -10- 200947142 圖1爲根據本發明之第一例示性實施例之表面形狀量 測設備200的方塊圖。表面形狀量測設備200係組態以於 高度方向(Z方向)中偵測於基材3上之膜’即量測目標 於其表面具有膜,的表面位置之設備。更具體地’表面形 -狀量測設備200包括各發射寬頻帶光之如鹵素燈或LED ( -包括所謂的白光LED)的光源1、光束分裂器(BS) 2a, 係配置以分行光’以及表面夾頭CK,係配置以固持量測 φ 目標3。另外,表面量測設備200包括Z架台5、Y架台 6,以及X架台7,其係組態以對準量測目標的位置、參 考鏡4、光束分裂器(BS) 2b,係配置以將藉由參考鏡4 所反射的光及藉由基材3所反射的光彼此組合,以及影像 拾取裝置8,如CCD或CMOS感測器。於此例示性實施 例中,於基材3之表面上形成光阻作爲膜。 以下將說明各種分量的功能及實例。於圖1中,由光 源1所發射的光經光束分裂器2a分裂成兩個光束,其各 ❹ 具有實質上爲所發射光之一半的光量。兩個光束以相同的 入射角0分別進入基材3及參考鏡4。 .可設定光源1的波長頻帶以包含自400 nm至8 00 nm 的波長。然而,波長頻帶不受限於此範圍且設定波長頻帶 不低於1〇〇 nm係所欲者。當於基材3上形成光阻時,爲 防止光阻敏化的緣故,不應以波長不大於紫外光( 3 50 nm )之光照射基材3。 使用厚膜,如金屬膜或介電多層膜,作爲分裂膜,或 是由膜所形成之厚度爲約1/zm至5^111的膜(由SiC或 -11 - 200947142Brewster) Corner. The s-polarized light and the P-polarized light included in the measurement light entering the surface of the substrate have the same strength for the photoelectric conversion element. With the surface shape measuring device oriented according to one aspect of the present invention, based on the property of changing the phase of the P-polarized light when the incident angle is larger than the Brewster angle, by suppressing reflection by the rear surface from the photoresist (film) The effects of light can reduce errors in optical measurements. Therefore, the surface shape measuring device can accurately measure the position of the front surface of the film such as the photoresist. In addition, an exposure apparatus is provided which achieves high focus ◎ accuracy with respect to a small depth of focus, and which increases the yield. Further features of the present invention will become apparent from the following description of the exemplary embodiments. [Embodiment] Exemplary embodiments of the present invention will be described below with reference to the accompanying drawings. It is to be noted that the same components are denoted by the same reference numerals throughout the drawings and the repeated description is omitted. -10-200947142 Fig. 1 is a block diagram of a surface shape measuring apparatus 200 according to a first exemplary embodiment of the present invention. The surface shape measuring apparatus 200 is configured to detect a film on the substrate 3 in the height direction (Z direction), i.e., a device that measures the surface position of the film on its surface. More specifically, the 'surface shape-like measuring apparatus 200' includes a light source 1, a beam splitter (BS) 2a, each of which emits broadband light such as a halogen lamp or an LED (including a so-called white light LED), which is configured to branch light ' And the surface chuck CK is configured to hold the φ target 3 in a holding amount. In addition, the surface measuring apparatus 200 includes a Z gantry 5, a Y gantry 6, and an X gantry 7, which are configured to align the position of the measurement target, the reference mirror 4, the beam splitter (BS) 2b, and are configured to The light reflected by the reference mirror 4 and the light reflected by the substrate 3 are combined with each other, and an image pickup device 8, such as a CCD or CMOS sensor. In this exemplary embodiment, a photoresist is formed on the surface of the substrate 3 as a film. The functions and examples of the various components will be explained below. In Fig. 1, the light emitted by the light source 1 is split into two beams by a beam splitter 2a, each of which has a light amount which is substantially one-half of the emitted light. The two beams enter the substrate 3 and the reference mirror 4 at the same incident angle 0, respectively. The wavelength band of the light source 1 can be set to include wavelengths from 400 nm to 800 nm. However, the wavelength band is not limited to this range and the set wavelength band is not lower than 1 〇〇 nm. When a photoresist is formed on the substrate 3, the substrate 3 should not be irradiated with light having a wavelength of not more than ultraviolet light (3 50 nm) in order to prevent photoresist sensitization. A thick film such as a metal film or a dielectric multilayer film is used as a split film, or a film formed by a film having a thickness of about 1/zm to 5^111 (by SiC or -11 - 200947142)

SiN所構成)光束分裂器’光束分裂器2a係可形成爲立 方光束分裂器。 藉由光束分裂器2a分裂之量測光及參考光,量測光 係照射基材3並於藉由基材3所反射後進入光束分裂器 2b。另一方面,參考光係照射參考鏡4並於藉由參考鏡4 所反射之後進入光束分裂器2b。可由玻璃平面鏡形成參 考鏡4,其表面精確度爲約1〇 nm至20 nm。 經由光束分裂器2b,藉由基材3所反射的量測光及 藉由參考鏡4所反射的參考光彼此組合,以及被影像拾取 裝置8所接收。藉由疊加由基材3所反射的量測光與由參 考鏡4所反射的參考光所產生的干涉光進入影像拾取裝置 8的光接收表面。光束分裂器2b可與光束分裂器2a相同 〇 於此第一例示性實施例中,於基材3及參考鏡4的入 射角、參考鏡4的物理性質、光極化狀態三者爲抑制來自 基材上之膜的後表面之反射光影響的重要因素。將於以下 說明這些因素。 首先’於此第一例示性實施例中,係照射參考光及量 測光以大於布魯斯特角(亦稱爲極化角)之入射角進入參 考鏡4及基材3上之膜的前表面,反射光之p極化分量的 相位經反轉。參考圖2說明該特徵。圖2爲闡述相關於圖 3之結構中的入射角針對各s極化光及p極化光之反射率 大小改變之圖。於此’假設光阻的反射率(表示針對波長 爲550 nm的光之値)爲1>5。如圖2中所見,相關於光阻 200947142 之入射角0的完全改變,S極化光之反射率大小爲負。另 一方面,於入射角Θ爲約57度時p極化光之反射率大小 變爲〇,以及於更大入射角時其正負號由正變負。當p極 化光的反射率大小變爲0時之入射角係稱爲布魯斯特角或 •極化角。因此,當入射角大於布魯斯特角時,s極化光及 ^ P極化光兩者之反射率大小爲負且兩者同相。 圖4闡述由如A1或Cu所構成之高反射率基材的結構 @ 。術語“高反射率基材”所指不僅是基材本身具高反射率, 亦指其中於Si基材上形成之膜具高反射率的基材。圖5A 及5B爲闡述當高反射率基材具有圖4之結構時,反射的 光中所包括之s極化光及p極化光之相位改變的圖。由圖 5A可見,當光阻前表面的入射角θ大於布魯斯特角時, 來自光阻前表面之反射的光中之p極化分量的相位係反轉 ’以及s極化光及p極化光同相位。另一方面,根據史奈 爾定律(Snell’s law)因光阻中的折射角0 ’小於光阻前 〇 表面的入射角,於基材的入射角變爲小於布魯斯特角。因 此’如圖5B中可見,來自光阻後表面(即光阻/基材介面 .)之反射的光中所包括之s極化光分量與p極化光分量之 間產生約π的相位差。 如圖5Α中說明,光係以大於布魯斯特角之入射角進 入參考鏡4,使得反射光中所包括的s極化光分量與p極 化光分量兩者同相位。另外,考量干涉信號的對比,以特 定材料構成參考鏡4之基材及基材上所形成之膜係所欲者 。例如,可由折射率接近基材3上之光阻的折射率之材料 -13- 200947142 構成膜,諸如Si02、SiN或SiC。因爲供白光干涉之同調 長度僅數微米,由厚度不小於數微米之基材構成參考鏡4 係所欲者,以防止藉由來自參考鏡之後表面的反射光所引 起之干涉。替代地,可於參考鏡4之基材上形成折射率接 近量測目標基材上之光阻的折射率之厚度爲數微米或更厚 的膜。 圖6闡述當入射光以80度之入射角進入具圖4的結 構之基材時,所量測之干涉信號的模擬波形。於模擬中, 設定光阻的膜厚度爲2;zm,使得來自光阻前表面之反射 光所形成的干涉信號與來自光阻後表面之反射光所形成的 干涉信號彼此分開。因爲來自光阻前表面之反射光及自光 阻後表面之反射光同相位,來自光阻前表面之反射光所形 成的干涉信號之s極化光分量與p極化光分量之間無相移 。另一方面,因爲來自光阻後表面之反射光所形成的干涉 信號含有介於來自光阻後表面之反射光與來自參考鏡之反 射光之間的相位差π,針對s極化光分量及p極化光分量 之干涉信號的波形之相位彼此相反。因此,藉由實施調整 ,使得量測光及參考光包括相同強度的s極化光及ρ極化 光,來自光阻後表面之反射光的s極化光分量及ρ極化光_ 分量彼此相消。因而可降低來自光阻後表面之反射光的信 號強度。 因此,藉由滿足三個條件,即入射角0大於布魯斯特 角、參考鏡4使用折射率接近光阻折射率的材料,以及非 極化,可精確地量測基材表面的位置。 -14- 200947142 大致上,來自光源之光極化。於干涉儀中’即便當來 自光源之光所包括的S極化光及P極化光具相同強度’光 束分裂器對兩極化光之反射率及透射率不同。此造成難以 令來自光阻後表面之反射光所形成的干涉信號中之s極化 •光及P極化光完全相互匹配。換句話說,例如當導入非極 - 化狀態之光時,來自光阻後表面之反射光所形成的干涉信 號中的S極化光及P極化光不會完全彼此相消,並且於一 Φ 些情況中妨礙精確量測光阻前表面的位置。將於以下說明 根據本發明之第一例示性實施例之調整光極化狀態的方法 〇 製備具有厚度爲數微米之膜的基材,膜係相同於量測 目標基材上的膜(於此情況中爲光阻)或具有與膜之折射 率相等的折射率。放置所製備的基材於量測設備中,調整 S極化光對P極化光之強度比,使得來自光阻後表面之反 射的光所形成之干涉信號的影響最小化。用於調整S極化 〇 光對P極化光之強度比的基材需用實用於實際半導體製程 之材料而構成。具體爲,Si、A卜W及Cu爲目前使用的 • 材料。於本發明的例示性的實施例中,藉由使用S i基材 . 等以實施調整,當由目前半導體製程中所使用的材料構成 量測目標基材時’獲得本發明的優點。若將來於半導體製 程中使用不同於Si之基材材料,雖基材使用不同材料, 藉由實施調整可執行本發明。然而,當基材由不同於Si 之材料所構成時,經調整的s極化光對p極化光之強度比 例的狀態可能改變。於此情況中,經由配置兩個或多個可 -15- 200947142 選擇性改變的極化調整元件以及根據所使用之基材插入極 化調整元件之一者的步驟藉由調整強度比例可執行本發明 〇 雖未於圖1中說明,於光源1與光束分裂器2a之間 ,設置無色λ/2板作爲調整光源1所發射光之極化狀態的 - 單元。組合兩種具不同延遲特徵型態的結晶材料及兩者間 . 的空氣而形成之λ/2板,並且其用以於光源1之波長範圍 中的兩個正交極化光分量之間提供λ/2之相位差。無色 q λ/2板可爲市售板中的一種。此外,附接旋轉驅動單元( 未繪示)至無色λ/2板,使得藉由旋轉無色λ/2板而調整 來自光阻後表面之反射的光所形成之干涉信號中的s極化 光對Ρ極化光之強度比。以此調整方法,因使用具厚光阻 結構的基材,於傾斜入射白光干涉儀中可使來自光阻前表 面之反射的光所形成之干涉信號及來自光阻後表面之反射 的光所形成之干涉信號彼此分開。除設置基材,亦可藉由 製備具有膜之結構而調整光極化狀態,其中於晶圓台上所 © 設置的參考標記39(見圖13)上形成厚度爲數微米之膜 ,其反射率接近量測目標基材上之膜的反數率,以及利用 . 具有此結構之參考標記而調整光極化狀態。因此,藉由調 整上述分別之來自光阻後表面之反射的光所形成之干涉信 號的強度比,可抑制來自光阻後表面之反射的光所形成之 干涉信號的影響。當量測膜的表面形狀時’膜表面於較大 入射角下展現較高的反射率’因此’設定入射角爲儘可能 的大係所欲者。於實例中’設定入射角爲70度或更大。 -16- 200947142 然而,當入射角接近90度時,發生組裝光學系統的困難 〇 以下將說明獲得干涉信號的方法。於圖1中’藉由基 材夾頭固持基材3,並將基材3放置於Z架台5、Y架台 • 6及X架台7上。驅動Z架台5以影像拾取裝置8而獲得 - 干涉信號,於圖7中說明,以及於儲存器(未繪示)中儲 存對應於基材3上之反射點的影像時取裝置8之各像素的 @ 光強度。當改變基材3上的量測區域時,於藉由操作X 架台7或Y架台6而定位所欲量測區預對準影像拾取裝 置8的光接收區之後,實施上述量測。爲精確地控制X 架台、Y架台及Z架台的位置,針對五個軸,即X、Y及 Z軸三者及兩個傾斜軸ωχ及c〇y,之各者設置雷射干涉儀 。根據雷射干涉儀的輸出藉由執行封閉迴路控制,可實施 較高精確度之形狀量測。當藉由分割基材3成爲複數區域 而實施基材3整體的全面形狀量測時,藉由使用雷射干涉 〇 儀可實現更精確的形狀資料組織。 現在說明藉由處理已由影像拾取裝置8所獲得並儲存 . 於儲存器中之干涉信號而量測基材3之形狀的方法。圖7 . 闡述於特定像素藉由影像拾取裝置8所獲得的干涉信號。 所說明的干涉信號亦被稱爲干涉圖。於圖7的圖表中,水 平軸表示由Z軸線規干涉儀(或如靜電電容感測器之另一 種線規感測器)所量測的値(Z架台位置),以及垂直軸 表示影像拾取裝置8之輸出。藉由計算干涉信號之峰値的 位置’對應於信號峰値位置之藉由Z軸線規干涉儀所量測 -17- 200947142 之値提供於相關像素處之量測値的高度。可藉由量測影像 拾取裝置8之所有像素各者的高度而決定基材3的三維形 狀。根據信號峰値位置及前者周圍之數點所獲得的資料可 利用曲線近似法(如,使用曲線的二次函數)計算峰値的 位置。利用曲線近似法,於沿Z軸,即圖7之水平軸,用 1 /1 〇或更小的解析度之取樣間距Zp可計算峰値位置。可 藉由步階方式以恆定間距Zp實際驅動Z架台5,或藉由 以恆定速度驅動Z架台5以及考慮經過提供取樣間距Zp 的時序取樣之干涉信號,而設定取樣間距Zp。亦可使用 習知的FDZ法(美國專利第5,3 98,113號中說明)作爲量 測峰値位置的方法。根據FDA法,藉由使用傅立葉頻譜 之相位斜率而決定對比峰値位置。 於白光干涉方法中,影響解析度的關鍵因素爲位置( 其中介於參考光及量測光之間的光學路徑差爲〇)決定的 精確度。爲此,除FDA法以外,提出數種邊緣分析方法 作爲習知技術,包括藉由相移法或傅立葉轉換法獲得白光 干涉邊緣之包絡線以及自最大邊緣對比位置決定光路徑差 爲零之點的方法,以及相位交叉法。 以下將連同具有與第一例示性實施例不同結構之表面 形狀量測設備一起說明本發明的第二例示性實施例。圖8 爲根據本發明之第二例示性實施例之表面形狀量測設備 200的方塊圖。表面形狀量測設備200係組態以偵測基材 3,即量測目標,之表面的Z方向位置的設備。更具體地 ,表面形狀量測設備200包括光源1、第一極化器9a、經 200947142 配置以分行光的光束分裂器2a,以及經配置以固持量測 目標3的基材夾頭,以及經組態以對準量測目標位置之z 架台5、Y架台及X架台7。表面形狀量測設備進一步包 括參考鏡4、經配置以使由參考鏡4所反射的光與由基材 • 3所反射的光彼此疊加之光束分裂器2b、第二極化器9b -,以及影像拾取裝置8,如CCD或CMOS感測器。基材3 爲其表面上形成有光阻膜的晶圓。 @ 以下將說明各種組件之功能及實例。 於圖8中,由光源1所發射的光於進入基材3及參考 鏡4之前通過第一極化器9a。由光束分裂器2a所分裂的 兩個光束以相同的入射角Θ分別進入基材3及參考鏡4。 由基材3所反射的量測光及由參考鏡4所反射的參考光進 入光束分裂器2b。因光源1、入射角Θ、光束分裂器2a 及2b,以及參考鏡4均與第一例示性實施例中所使用者 相同,於此不再重複組件說明。光束分裂器2b可與光束 Q 分裂器2a相同。量測光及參考光於通過第二極化器9b之 後被影像時裝置8所接收。分別由基材3及參考鏡4所反 . 射之後,量測光及參考光經由光束分裂器2b彼此疊加, _ 以產生進入影像拾取裝置8之光接收表面的干涉光。 此用來自光源的光線獲得干涉信號之方法及處理干涉 信號的方法係相同於第一例示性實施例中所使用者。因此 ,於此不再重複說明方法。 第二例示性實施例與第一例示性實施例的差別在於極 化器9a及9b分別設置在基材3及參考鏡4之光學路徑的 -19- 200947142 上游及下游。以此配置’於來自光源1所發射的光之極化 狀態已改變爲線性極化之後’導致光以大於布魯斯特角之 入射角進入基材3及參考鏡4各者。由影像拾取裝置8接 收由基材3及參考鏡4所反射的光,其具與於基材3及參 考鏡4入射的極化光相同的線性極化狀態。 參考圖9,以下將說明由光源所發射之光直至爲此第 二例示性實施例中的影像拾取裝置8所接收期間之極化狀 態的改變。由光源1所發射光之極化狀態被第一極化器 9a改變。圖9闡述已爲光源1所發射並通過第一極化器 9a的光之極化狀態爲+45°方向線性極化的情況。 由基材3及參考鏡4所反射的光之相位相關於圖2、 5A及5B中說明的入射角而改變。因此,由膜前表面所反 射光之極化的方向沒有改變,以及反射光維持+45°方向線 性極化。另一方面,因爲由膜/基材介面所反射的光與由 參考鏡4所反射的光之間產生相位差π,由膜/基材介面所 反射的光改變成-45°方向線性極化。因此,由膜前表面及 膜/基材介面之反射的光所形成之干涉信號具有兩個正交 的(+45°方向及-45°方向)線性極化分量。因此,於由基 材3及參考鏡4所反射後,經由第二極化器9b僅擷取 + 45°方向線性極化之分量可單排除由膜/基材介面之反射 的光所形成之干涉信號的分量。同樣地,當已由光源1所 發射並通過第一極化器9a之光的極化狀態爲-45°方向線 性極化時,於由膜/基材介面所反射的光與由參考鏡4所 反射的光之間產生相位差π,且可僅排除由膜前表面之反 -20- 200947142 射的光所形成之干涉信號的分量。換句話說,藉採用上述 參考鏡4、設定入射角0大於布魯斯特角,以及照射呈線 性極化之極化狀態的入射光’可抑制由膜/基材介面之反 射的光所形成之干涉信號的影響。雖然因使用極化器而需 •要較第一例示性實施例爲大的光量,可有效地移除由光阻 - 後表面所反射光所形成的干涉信號,以及可精確地量測塗 覆於晶圓上之光阻的表面形狀。 φ 以下將說明於第二例示性實施中調整光極化狀態的方 法。 製備具有數微米厚之膜的基材,膜與量測目標基材上 的膜(於此情況中爲光阻)相同或其折射率與膜之折射率 相同。於量測設備中放置所製備的基材,以及調整s極化 光對P極化光的強度比使得由光阻後表面之反射光所形成 的干涉信號之影響最小化。附接旋轉驅動單元(未繪示) 至圖8中之極化器9a及9b各者,使得藉由旋轉極化器 9a及9b可調整上述由光阻後表面之反射光所形成的干涉 信號中的強度比。以此調整方法,因使用具有厚光阻結構 .的基材,於傾斜入射白光干涉儀中可使由光阻前表面之反 射光所形成的干涉信號與由光阻後表面之反射光所形成的 干涉信號彼此分開。除設置基材,亦可藉由製備具有膜之 結構而調整光極化狀態,其中於晶圓台上所設置的參考標 記39(見圖13)上形成厚度爲數微米之膜,其反射率接 近量測目標基材上之膜的反數率,以及利用具有此結構之 參考標記而調整光極化狀態。因此,藉由調整上述分別之 -21 - 200947142 來自光阻後表面之反射的光所形成之干涉信號的強度比, 可抑制來自光阻後表面之反射的光所形成之干涉信號的影 響。 除旋轉極化器,藉由配置λ/2板,包括極化器下游的 旋轉驅動單元及旋轉λ/2板,亦可調整來自光源之光的極 · 化狀態。於量測光阻前表面的位置時,由光阻前表面反射 · 的光所形成之干涉信號提供待量測的信號(S),以及由 光阻後表面反射的光所形成之干涉信號成爲雜訊(Ν) 。 υ 於較高S/N比例下,可實施較高精確度之光阻前表面的形 狀量測,依據形狀量測所需精確度而調整上述的強度比。 例如,調整強度比之値使S/N比不小於1 〇係所欲者。當 需要更精確的量測時,可設定S/N比不小於20或30。如 此一來,於此第二例示性實施例中,相對於+4 5°方向及 -45°方向,調整已通過極化器9a的線性極化光,使其落 於±1°之內。其原因爲,當線性極化光以不同於:L45°之角 度定向時,由膜前表面及膜/基材介面之反射的光所形成 © 之干涉信號不會彼此正交。因此,因存在之分量與由光阻 後表面所反射的光干涉,S/N比下降以及造成實施高精確 . 度表面形狀量測的困難。 例如,設定調整極化狀態的頻率使得遞送設備實施調 整後,僅當替換設備部件,如光源,時實施調整。另外’ 亦可於分開地取決量測目標基材而製備相當厚(數微米) 的膜以及藉由使用於其上形成有相當厚之膜的基材調整極 化狀態之後,量測量測表面基材的膜表面形狀。 -22- 200947142 即使未設置第二極化器9b,接收來自光阻前表面及 光阻後表面之反射光作爲兩個線性極化分量。於此情況下 ,當所接收的光爲兩個正交的線性極化分量時,可抑制由 光阻後表面之反射的光所形成之干涉信號的影像,因爲干 •涉僅由同相位之參考光及由光阻後表面之反射的光所產生 . 。就干涉信號的對比之觀點而言,所接收的光爲兩個正交 的線性極化分量係所欲者。然而,實際上,因光束分裂器 0 等之影響移動相位改變,以及不易獲得接收的光呈完全線 性極化狀態。爲此緣故,於第二例示性實施例中使用第二 極化器9b以進一步抑制來自光阻後表面之反射光的影響 〇 當於基材3上實施複數量測區域之形狀量測時,於晶 圓台已經移除以對準各預定區域之後,藉由驅動X架台 及Y架台,類似第一例示性實施例獲得干涉信得及處理 干涉信號。 〇 以下將連同具有與第一及第二例示性實施例不同結構 之表面形狀量測設備一起說明本發明的第三例示性實施例 .。圖1 0爲根據本發明之第三例示性實施例之表面形狀量 測設備200的方塊圖。表面形狀量測設備200係組態以偵 測基材3,即量測目標,之表面的Z方向位置的設備。更 具體地,表面形狀量測設備2 0 0包括光源1、第一極化器 9a、第一波長板l〇a、經配置以分行光的光束分裂器2a, 以及經配置以固持量測目標3的基材夾頭CK,以及經組 態以對準量測目標位置之Z架台5、Y架台及X架台7。 -23- 200947142 表面形狀量測設備進一步包括參考鏡4、經配置以使由參 考鏡4所反射的光與由基材3所反射的光彼此組合之光束 分裂器2b、第二極化器9b、第二波長板10b,以及影像 拾取裝置8,如CCD或CMOS感測器。 以下將說明各種組件之功能及實例。 - 於圖10中,由光源1所發射的光於進入基材3及參 _ 考鏡4之前通過第一極化器9a及第一波長板10a。由光 束分裂器2a所分裂的兩個光束以相同的入射角Θ分別進 &The beam splitter 'beam splitter 2a' can be formed as a vertical beam splitter. The light metering and reference light are split by the beam splitter 2a, and the measuring light irradiates the substrate 3 and is reflected by the substrate 3 to enter the beam splitter 2b. On the other hand, the reference light system illuminates the reference mirror 4 and enters the beam splitter 2b after being reflected by the reference mirror 4. The reference mirror 4 can be formed by a glass plane mirror having a surface accuracy of about 1 〇 nm to 20 nm. The light reflected by the substrate 3 and the reference light reflected by the reference mirror 4 are combined with each other via the beam splitter 2b, and received by the image pickup device 8. The interference light generated by superimposing the light reflected by the substrate 3 and the reference light reflected by the reference mirror 4 enters the light receiving surface of the image pickup device 8. The beam splitter 2b can be identical to the beam splitter 2a. In the first exemplary embodiment, the incident angles of the substrate 3 and the reference mirror 4, the physical properties of the reference mirror 4, and the optical polarization state are suppressed. An important factor in the effect of reflected light on the back surface of the film on the substrate. These factors will be explained below. First, in this first exemplary embodiment, the reference light and the measurement light are incident on the front surface of the film on the reference mirror 4 and the substrate 3 at an incident angle greater than the Brewster angle (also referred to as the polarization angle). The phase of the p-polarized component of the reflected light is inverted. This feature is explained with reference to FIG. 2. Fig. 2 is a view for explaining the change in the reflectance of each of the s-polarized light and the p-polarized light with respect to the incident angle in the structure of Fig. 3. Here, the reflectance of the photoresist (indicating that the light is 550 nm) is 1 > As seen in Fig. 2, the magnitude of the reflectance of the S-polarized light is negative with respect to the complete change of the incident angle 0 of the photoresist 200947142. On the other hand, the reflectance of the p-polarized light becomes 〇 at an incident angle Θ of about 57 degrees, and the positive and negative signs become positive and negative at a larger incident angle. The incident angle when the reflectance of the p-polarized light becomes 0 is called the Brewster angle or the polarization angle. Therefore, when the incident angle is larger than the Brewster angle, the reflectance of both the s-polarized light and the ^P-polarized light is negative and the two are in phase. Figure 4 illustrates the structure of a high reflectivity substrate composed of, for example, A1 or Cu. The term "high reflectivity substrate" means not only the substrate itself has a high reflectance, but also a substrate in which a film formed on a Si substrate has a high reflectance. 5A and 5B are views for explaining changes in the phase of s-polarized light and p-polarized light included in the reflected light when the high-reflectivity substrate has the structure of Fig. 4. As can be seen from FIG. 5A, when the incident angle θ of the front surface of the photoresist is larger than the Brewster angle, the phase of the p-polarized component in the reflected light from the front surface of the photoresist is inverted 'and the s-polarized light and the p-polarized The light is in phase. On the other hand, according to Snell's law, since the angle of refraction 0' in the photoresist is smaller than the incident angle of the front surface of the photoresist, the incident angle on the substrate becomes smaller than the Brewster angle. Therefore, as seen in FIG. 5B, a phase difference of about π is generated between the s-polarized light component and the p-polarized light component included in the light reflected from the rear surface of the photoresist (ie, the photoresist/substrate interface). . As illustrated in Fig. 5A, the light system enters the reference mirror 4 at an incident angle greater than the Brewster angle such that the s-polarized light component and the p-polarized light component included in the reflected light are in phase. In addition, considering the contrast of the interference signals, the substrate of the reference mirror 4 and the film formed on the substrate are formed of a specific material. For example, a film such as SiO 2 , SiN or SiC may be constituted by a material -13 - 200947142 having a refractive index close to that of the photoresist on the substrate 3. Since the coherence for white light interference is only a few micrometers in length, the reference mirror 4 is composed of a substrate having a thickness of not less than several micrometers to prevent interference caused by reflected light from the surface behind the reference mirror. Alternatively, a film having a refractive index close to the refractive index of the target substrate can be formed on the substrate of the reference mirror 4 to have a thickness of several micrometers or more. Figure 6 illustrates the simulated waveform of the interfering signal measured when incident light enters the substrate of the structure of Figure 4 at an angle of incidence of 80 degrees. In the simulation, the film thickness of the photoresist is set to 2; zm, so that the interference signal formed by the reflected light from the front surface of the photoresist and the interference signal formed by the reflected light from the rear surface of the photoresist are separated from each other. Since the reflected light from the front surface of the photoresist and the reflected light from the rear surface of the photoresist are in phase, there is no phase shift between the s-polarized light component and the p-polarized light component of the interference signal formed by the reflected light from the front surface of the photoresist. . On the other hand, since the interference signal formed by the reflected light from the back surface of the photoresist contains a phase difference π between the reflected light from the back surface of the photoresist and the reflected light from the reference mirror, the s-polarized light component is The phases of the waveforms of the interference signals of the p-polarized light components are opposite to each other. Therefore, by performing the adjustment, the measurement light and the reference light comprise s-polarized light and ρ-polarized light of the same intensity, and the s-polarized light component and the ρ-polarized light-component of the reflected light from the rear surface of the photoresist are mutually Destruction. Therefore, the signal intensity of the reflected light from the rear surface of the photoresist can be reduced. Therefore, by satisfying three conditions, that is, the incident angle 0 is larger than the Brewster angle, the reference mirror 4 uses a material whose refractive index is close to the refractive index of the resist, and the non-polarization, the position of the surface of the substrate can be accurately measured. -14- 200947142 Generally, the light from the light source is polarized. In the interferometer, 'S-polarized light and P-polarized light included in the light from the light source have the same intensity'. The beam splitter has different reflectance and transmittance for polarized light. This makes it difficult to polarize the s in the interference signal formed by the reflected light from the rear surface of the photoresist. The light and the P-polarized light completely match each other. In other words, for example, when light of a non-polarization state is introduced, S-polarized light and P-polarized light in the interference signal formed by the reflected light from the rear surface of the photoresist do not completely cancel each other, and Φ In some cases, it is impeded to accurately measure the position of the front surface of the photoresist. A method of adjusting a photopolarization state according to a first exemplary embodiment of the present invention will be described below. A substrate having a film having a thickness of several micrometers, which is the same as a film on a target substrate, is prepared. In the case of photoresist, or has a refractive index equal to the refractive index of the film. The prepared substrate is placed in a measuring device to adjust the intensity ratio of the S-polarized light to the P-polarized light to minimize the influence of the interference signal formed by the reflected light from the back surface of the photoresist. The substrate used to adjust the intensity ratio of S-polarized light to P-polarized light is constructed using materials that are used in actual semiconductor processes. Specifically, Si, A, and Cu are currently used materials. In an exemplary embodiment of the present invention, the advantages of the present invention are obtained by using an S i substrate or the like to carry out the adjustment, when the target substrate is composed of the materials used in the current semiconductor process. If a substrate material other than Si is used in a semiconductor process in the future, the present invention can be carried out by performing adjustments, although the substrate is made of different materials. However, when the substrate is composed of a material different from Si, the state of the intensity ratio of the adjusted s-polarized light to p-polarized light may vary. In this case, the step of adjusting the intensity ratio can be performed by configuring two or more polarization adjusting elements that can be selectively changed by -15-200947142 and inserting one of the polarization adjusting elements according to the substrate used. Although not illustrated in Fig. 1, between the light source 1 and the beam splitter 2a, a colorless λ/2 plate is provided as a unit for adjusting the polarization state of the light emitted from the light source 1. Combining two crystal materials having different retardation patterns and air between them to form a λ/2 plate, and for providing between two orthogonally polarized light components in the wavelength range of the light source 1 The phase difference of λ/2. The colorless q λ/2 plate can be one of commercially available plates. In addition, a rotary driving unit (not shown) is attached to the colorless λ/2 plate such that the s-polarized light in the interference signal formed by the reflected light from the rear surface of the photoresist is adjusted by rotating the colorless λ/2 plate. The intensity ratio of polarized light. With this adjustment method, the interference signal formed by the reflected light from the front surface of the photoresist and the light reflected from the rear surface of the photoresist can be made in the oblique incident white light interferometer by using the substrate with the thick photoresist structure. The resulting interference signals are separated from each other. In addition to providing a substrate, the polarization state of the light can also be adjusted by preparing a structure having a film on which a film having a thickness of several micrometers is formed on a reference mark 39 (see FIG. 13) provided on the wafer stage. The rate is close to measuring the inverse rate of the film on the target substrate, and adjusting the polarization state of the light using the reference mark having this structure. Therefore, by adjusting the intensity ratio of the interference signals formed by the respective reflected light from the rear surface of the photoresist, the influence of the interference signal formed by the reflected light from the rear surface of the photoresist can be suppressed. When the surface shape of the film is equivalently measured, the film surface exhibits a high reflectance at a large incident angle. Therefore, the incident angle is set to be as large as possible. In the example, the incident angle was set to be 70 degrees or more. -16- 200947142 However, when the incident angle is close to 90 degrees, the difficulty of assembling the optical system occurs 〇 The method of obtaining the interference signal will be described below. In Fig. 1, the substrate 3 is held by a substrate chuck, and the substrate 3 is placed on the Z stand 5, the Y stand 6 and the X stand 7. Driving the Z gantry 5 to obtain an interference signal by the image pickup device 8, as illustrated in FIG. 7, and taking the pixels of the device 8 when storing an image corresponding to the reflection point on the substrate 3 in a memory (not shown) @光强度. When the measurement area on the substrate 3 is changed, the above measurement is performed after the light receiving area of the image pickup unit 8 is pre-aligned by positioning the X stage 7 or the Y stage 6 by operating the X stage 7 or the Y stage 6. In order to accurately control the positions of the X, Y, and Z stands, a laser interferometer is provided for each of the five axes, namely, the X, Y, and Z axes, and the two tilt axes ωχ and c〇y. By performing closed loop control based on the output of the laser interferometer, a more accurate shape measurement can be performed. When the overall shape measurement of the entire substrate 3 is performed by dividing the substrate 3 into a plurality of regions, a more accurate shape data organization can be realized by using a laser interference detector. A method of measuring the shape of the substrate 3 by processing the interference signal that has been obtained by the image pickup device 8 and stored in the memory will now be described. Fig. 7. Describes the interference signal obtained by the image pickup device 8 at a specific pixel. The illustrated interference signal is also referred to as an interferogram. In the graph of Figure 7, the horizontal axis represents the 値 (Z gantry position) measured by the Z-axis interferometer (or another gauge sensor such as a capacitive sensor), and the vertical axis represents image pickup. The output of device 8. The height of the measurement 値 provided at the relevant pixel is determined by the Z-axis interferometer by calculating the position of the peak 値 of the interference signal corresponding to the position of the signal peak -17-200947142. The three-dimensional shape of the substrate 3 can be determined by measuring the height of each of all the pixels of the image pickup device 8. Based on the information obtained from the peak position of the signal and the number of points around the former, the position of the peak can be calculated using a curve approximation (for example, using a quadratic function of the curve). Using the curve approximation, the peak position can be calculated with a sampling interval Zp of 1 / 1 〇 or less along the Z axis, that is, the horizontal axis of Fig. 7. The Z-mount 5 can be actually driven by the step method at a constant pitch Zp, or by the Z-frame 5 being driven at a constant speed and considering the interference signal sampled at a timing at which the sampling pitch Zp is supplied. A conventional FDZ method (described in U.S. Patent No. 5,3,98,113) can also be used as a method of measuring the position of the peak. According to the FDA law, the relative peak position is determined by using the phase slope of the Fourier spectrum. In the white light interference method, the key factor affecting the resolution is the accuracy determined by the position (where the optical path difference between the reference light and the measured light is 〇). To this end, in addition to the FDA method, several edge analysis methods are proposed as conventional techniques, including obtaining the envelope of the white light interference edge by the phase shift method or the Fourier transform method and determining that the light path difference is zero from the maximum edge contrast position. Method, as well as phase crossing method. A second exemplary embodiment of the present invention will be described below along with a surface shape measuring apparatus having a structure different from that of the first exemplary embodiment. Figure 8 is a block diagram of a surface shape measuring apparatus 200 in accordance with a second exemplary embodiment of the present invention. The surface shape measuring device 200 is configured to detect the substrate 3, i.e., the device that measures the Z-direction of the surface of the target. More specifically, the surface shape measuring apparatus 200 includes a light source 1, a first polarizer 9a, a beam splitter 2a configured to split light through 200947142, and a substrate chuck configured to hold the measurement target 3, and The configuration is to align the z-mount 5, Y-frame and X-frame 7 of the target position. The surface shape measuring apparatus further includes a reference mirror 4, a beam splitter 2b, a second polarizer 9b- configured to superimpose light reflected by the reference mirror 4 and light reflected by the substrate 3, and Image pickup device 8, such as a CCD or CMOS sensor. The substrate 3 is a wafer on which a photoresist film is formed. @ The following describes the functions and examples of the various components. In Fig. 8, the light emitted by the light source 1 passes through the first polarizer 9a before entering the substrate 3 and the reference mirror 4. The two beams split by the beam splitter 2a enter the substrate 3 and the reference mirror 4 at the same incident angle Θ, respectively. The light reflected by the substrate 3 and the reference light reflected by the reference mirror 4 enter the beam splitter 2b. Since the light source 1, the incident angle Θ, the beam splitters 2a and 2b, and the reference mirror 4 are the same as those of the first exemplary embodiment, the description of the components will not be repeated here. The beam splitter 2b can be identical to the beam Q splitter 2a. The measurement light and the reference light are received by the device 8 after being passed through the second polarizer 9b. After being irradiated by the substrate 3 and the reference mirror 4, respectively, the measurement light and the reference light are superimposed on each other via the beam splitter 2b to generate interference light entering the light receiving surface of the image pickup device 8. The method of obtaining an interference signal using light from a light source and the method of processing the interference signal are the same as those of the first exemplary embodiment. Therefore, the method will not be repeated here. The difference between the second exemplary embodiment and the first exemplary embodiment is that the polarizers 9a and 9b are disposed upstream and downstream of the optical path -19-200947142 of the substrate 3 and the reference mirror 4, respectively. With this configuration 'after the polarization state of the light emitted from the light source 1 has been changed to linear polarization', the light enters the substrate 3 and the reference mirror 4 at an incident angle greater than the Brewster angle. The light reflected by the substrate 3 and the reference mirror 4 is received by the image pickup device 8 in the same linear polarization state as the polarized light incident on the substrate 3 and the reference mirror 4. Referring to Fig. 9, the change of the polarization state of the light emitted by the light source until it is received by the image pickup device 8 in the second exemplary embodiment will be described below. The polarization state of the light emitted by the light source 1 is changed by the first polarizer 9a. Fig. 9 illustrates the case where the polarization state of the light which has been emitted by the light source 1 and passed through the first polarizer 9a is linearly polarized in the +45° direction. The phase of the light reflected by the substrate 3 and the reference mirror 4 changes in relation to the angle of incidence illustrated in Figures 2, 5A and 5B. Therefore, the direction of polarization of the light reflected from the front surface of the film is not changed, and the reflected light maintains a linear polarization of +45°. On the other hand, since the phase difference π is generated between the light reflected by the film/substrate interface and the light reflected by the reference mirror 4, the light reflected by the film/substrate interface is changed to linear polarization in the -45° direction. . Therefore, the interference signal formed by the light reflected from the front surface of the film and the film/substrate interface has two orthogonal (+45° direction and -45° direction) linear polarization components. Therefore, after being reflected by the substrate 3 and the reference mirror 4, only the component of the linear polarization in the +45° direction can be extracted through the second polarizer 9b, and the light reflected by the film/substrate interface can be excluded. The component of the interference signal. Similarly, when the polarization state of the light that has been emitted by the light source 1 and passed through the first polarizer 9a is linearly polarized in the -45 direction, the light reflected by the film/substrate interface is referenced by the reference mirror 4 A phase difference π is generated between the reflected light, and only the component of the interference signal formed by the light emitted by the inverse -20-200947142 of the front surface of the film can be excluded. In other words, by using the above reference mirror 4, setting the incident angle 0 to be greater than the Brewster angle, and illuminating the incident light of the linearly polarized polarization state, the interference formed by the light reflected by the film/substrate interface can be suppressed. The effect of the signal. Although it is necessary to use a polarizer for a large amount of light compared to the first exemplary embodiment, the interference signal formed by the light reflected by the photoresist-back surface can be effectively removed, and the coating can be accurately measured. The surface shape of the photoresist on the wafer. φ Hereinafter, a method of adjusting the polarization state of light in the second exemplary embodiment will be described. A substrate having a film having a thickness of several micrometers is prepared, the film being the same as the film on the measurement target substrate (in this case, the photoresist) or having the same refractive index as the refractive index of the film. The prepared substrate is placed in the measuring device, and the intensity ratio of the s-polarized light to the P-polarized light is adjusted to minimize the influence of the interference signal formed by the reflected light from the back surface of the photoresist. Attaching a rotary driving unit (not shown) to each of the polarizers 9a and 9b in FIG. 8 enables the interference signal formed by the reflected light from the rear surface of the photoresist to be adjusted by the rotary polarizers 9a and 9b Intensity ratio in . With this adjustment method, due to the use of a substrate having a thick photoresist structure, the interference signal formed by the reflected light from the front surface of the photoresist and the reflected light from the rear surface of the photoresist can be formed in the oblique incident white light interferometer. The interference signals are separated from each other. In addition to providing a substrate, the photopolarization state can also be adjusted by preparing a structure having a film in which a film having a thickness of several micrometers is formed on a reference mark 39 (see FIG. 13) provided on the wafer stage, and the reflectance thereof is obtained. The inverse ratio of the film on the target substrate is measured, and the photopolarization state is adjusted using the reference mark having this structure. Therefore, by adjusting the intensity ratio of the interference signals formed by the above -21 - 200947142 reflected light from the rear surface of the photoresist, the influence of the interference signal formed by the reflected light from the rear surface of the photoresist can be suppressed. In addition to the rotary polarizer, the polar state of the light from the light source can also be adjusted by arranging the λ/2 plate, including the rotary drive unit downstream of the polarizer and the rotating λ/2 plate. When measuring the position of the front surface of the photoresist, the interference signal formed by the light reflected from the front surface of the photoresist provides a signal (S) to be measured, and the interference signal formed by the light reflected by the surface of the photoresist becomes Noise (Ν).于 At a higher S/N ratio, a higher-precision shape measurement of the front surface of the photoresist can be performed, and the intensity ratio described above can be adjusted according to the accuracy required for the shape measurement. For example, adjusting the intensity ratio will make the S/N ratio not less than 1 〇. When more accurate measurements are required, the S/N ratio can be set to be no less than 20 or 30. As a result, in this second exemplary embodiment, the linearly polarized light that has passed through the polarizer 9a is adjusted to fall within ±1° with respect to the +4 5° direction and the -45° direction. The reason for this is that when the linearly polarized light is oriented at an angle different from: L45, the interference signals formed by the light reflected from the front surface of the film and the film/substrate interface are not orthogonal to each other. Therefore, the S/N ratio is lowered due to the interference of the component present and the light reflected by the rear surface of the photoresist, and the difficulty in performing highly accurate surface shape measurement is caused. For example, setting the frequency of adjusting the polarization state causes the delivery device to perform an adjustment, and the adjustment is performed only when the device component, such as a light source, is replaced. In addition, it is also possible to separately measure the target substrate to prepare a relatively thick (several micrometer) film and to measure the polarization state by using a substrate on which a relatively thick film is formed to adjust the polarization state. The film surface shape of the substrate. -22- 200947142 Even if the second polarizer 9b is not provided, the reflected light from the front surface of the photoresist and the rear surface of the photoresist is received as two linear polarization components. In this case, when the received light is two orthogonal linear polarization components, the image of the interference signal formed by the light reflected by the rear surface of the photoresist can be suppressed, because the interference is only in phase. The reference light and the light reflected by the back surface of the photoresist are generated. From the standpoint of the contrast of the interference signals, the received light is the desired of two orthogonal linear polarization components. However, in practice, the phase changes due to the influence of the beam splitter 0 and the like, and the light that is not easily received is completely linearly polarized. For this reason, the second polarizer 9b is used in the second exemplary embodiment to further suppress the influence of the reflected light from the rear surface of the photoresist. When the shape measurement of the complex measurement region is performed on the substrate 3, After the wafer stage has been removed to align each predetermined area, an interference signal and an interference signal are processed similarly to the first exemplary embodiment by driving the X stage and the Y stage. BRIEF DESCRIPTION OF THE PREFERRED EMBODIMENTS A third exemplary embodiment of the present invention will be described below along with a surface shape measuring apparatus having a structure different from that of the first and second exemplary embodiments. Figure 10 is a block diagram of a surface shape measuring apparatus 200 in accordance with a third exemplary embodiment of the present invention. The surface shape measuring device 200 is configured to detect the substrate 3, i.e., the device that measures the Z-direction of the surface of the target. More specifically, the surface shape measuring device 200 includes a light source 1, a first polarizer 9a, a first wavelength plate 10a, a beam splitter 2a configured to split light, and configured to hold a measurement target The substrate chuck CK of 3, and the Z gantry 5, the Y gantry, and the X gantry 7 configured to align the target position. -23- 200947142 The surface shape measuring device further comprises a reference mirror 4, a beam splitter 2b, a second polarizer 9b configured to combine the light reflected by the reference mirror 4 and the light reflected by the substrate 3 with each other The second wavelength plate 10b, and the image pickup device 8, such as a CCD or CMOS sensor. The functions and examples of the various components will be described below. - In Fig. 10, the light emitted by the light source 1 passes through the first polarizer 9a and the first wave plate 10a before entering the substrate 3 and the reference mirror 4. The two beams split by the beam splitter 2a are respectively injected at the same angle of incidence &

入基材3及參考鏡4。由基材3所反射的量測光及由參考 鏡4所反射的參考光進入光束分裂器2b。因光源1、入射 角Θ、光束分裂器2a及2b,以及參考鏡4均與第一例示 性實施例中所使用者相同,於此不再重複組件說明。光束 分裂器2b可與光束分裂器2a相同。量測光及參考光於通 過第二波長板10b及第二極化器9b之後被影像拾取裝置 8所接收。分別由基材3及參考鏡4所反射之後,量測光 及參考光於影像拾取裝置8之光接收表面上彼此疊加以產 Q 生光干涉。 由無色λ/4板形成波長板。組合兩種具有不同延遲特 徵的結晶材料及介於其間的空氣以形成無色λ /4板,以及 其用於提供寬頻帶中介於兩個正交極化光分量之Λ /4相位 差。可提供市售板作爲無色λ /4板。 使用獲得自光源之干涉信號的方法及處理干涉信號的 方法與第一例示性實施例中者相同。因此,於此不再重複 說明那些方法。 -24- 200947142 第三例示性實施例與第一實施例之差異在於分別於基 材3及參考鏡4之上游及下游的光學路徑中設置一組極化 器9a與波長板10a以及一組化器9b與波長板l〇b。以此 配置,於由光源所發射的光之極化狀態自線性極化(如P ' 極化光)經改變爲環狀極化之後,致使光以入射角0進入 - 基材3及參考鏡4各者。來自基材3及參考鏡4之反射光 ,僅以與上述線性極化相同方向震盪的光分量被影像拾取 Q 裝置8所接收。 以下參考圖11將說明此第三例示性實施例中光極化 狀態的改變。藉由極化器9a使發射自光源1的光之極化 狀態變爲線性極化,接著藉由波長板l〇a變爲環狀極化。 圖Π闡述當已由光源1所發射且已穿過極化器9a及波長 板l〇a的光之極化狀態爲右手環狀極化情況。 當使用參考鏡4時,由基材3及參考鏡4之反射光的 相位相關於如圖2、5A及5B所示之入射角而改變。因此 〇 ,來自膜前表面之反射光的旋轉極化方向不會改變,以及 反射光維持右手環狀極化。另一方面,因爲介於來自膜/ .基材介面之反射光與來自參考鏡4的反射光之間產生有相 位差π,來自膜/基材介面之反射光係變爲左手環狀極化。 因此,於經由波長板l〇b而使環狀極化光改變爲線性極化 光之後,可令來自膜前表面及膜/基材介面之反射光形成 的呈右手及左手環狀極化狀態之干涉信號被分別轉變成P 極化分量及s極化分量。因此,僅藉由經極化9b擷取p 極化分量可單去除來自膜前表面之反射光所形成之干涉信 -25- 200947142 號的分量。換句話說,藉由使用上述參考鏡4,於環狀極 化狀態中以大於布魯斯特角的入射角0照射入射光,經由 波長板轉變環狀極化成爲線性極化分量,以及經由極化器 擷取來自光阻前表面之反射光的分量,可抑制來自光阻後 表面之反射光所形成之干涉信號的影響。雖然因使用極化 - 器及波長板而較第一例示性實施例中需要更大的光量,可 .The substrate 3 and the reference mirror 4 are inserted. The light reflected by the substrate 3 and the reference light reflected by the reference mirror 4 enter the beam splitter 2b. Since the light source 1, the incident angle Θ, the beam splitters 2a and 2b, and the reference mirror 4 are the same as those of the first exemplary embodiment, the description of the components will not be repeated here. The beam splitter 2b can be identical to the beam splitter 2a. The measurement light and the reference light are received by the image pickup device 8 after passing through the second wave plate 10b and the second polarizer 9b. After being reflected by the substrate 3 and the reference mirror 4, respectively, the measurement light and the reference light are superimposed on each other on the light receiving surface of the image pickup device 8 to generate Q light interference. A wavelength plate is formed from a colorless λ/4 plate. Two crystal materials having different retardation characteristics and air interposed therebetween are combined to form a colorless λ /4 plate, and it is used to provide a Λ /4 phase difference between two orthogonally polarized light components in a wide frequency band. A commercially available board can be provided as a colorless λ /4 board. The method of using the interference signal obtained from the light source and the method of processing the interference signal are the same as those in the first exemplary embodiment. Therefore, those methods will not be repeated here. -24- 200947142 The difference between the third exemplary embodiment and the first embodiment is that a set of polarizers 9a and a wave plate 10a and a group of elements are disposed in the optical paths upstream and downstream of the substrate 3 and the reference mirror 4, respectively. The device 9b and the wavelength plate l〇b. With this configuration, after the polarization state of the light emitted by the light source is changed from linear polarization (such as P 'polarized light) to circular polarization, light is caused to enter at the incident angle 0 - the substrate 3 and the reference mirror 4 each. The reflected light from the substrate 3 and the reference mirror 4 is received by the image pickup Q device 8 only by the light component oscillating in the same direction as the linear polarization described above. The change of the photopolarization state in this third exemplary embodiment will be described below with reference to Fig. 11. The polarization state of the light emitted from the light source 1 is changed to linear polarization by the polarizer 9a, and then becomes circularly polarized by the wavelength plate 10a. The diagram illustrates the polarization state of light that has been emitted by the light source 1 and that has passed through the polarizer 9a and the wavelength plate 10a as a right-handed circular polarization. When the reference mirror 4 is used, the phase of the reflected light from the substrate 3 and the reference mirror 4 changes in relation to the incident angle as shown in Figs. 2, 5A and 5B. Therefore, the direction of rotational polarization of the reflected light from the front surface of the film does not change, and the reflected light maintains the right hand circular polarization. On the other hand, since a phase difference π is generated between the reflected light from the film/.substrate interface and the reflected light from the reference mirror 4, the reflected light from the film/substrate interface becomes left-handed circular polarization. . Therefore, after the circularly polarized light is changed to linearly polarized light via the wavelength plate 10b, the right-handed and left-handed circular polarization states formed from the reflected light from the front surface of the film and the film/substrate interface can be formed. The interference signals are converted into P polarization components and s polarization components, respectively. Therefore, the component of the interference signal -25-200947142 formed by the reflected light from the front surface of the film can be removed by simply extracting the p-polarized component by the polarization 9b. In other words, by using the above-described reference mirror 4, the incident light is irradiated at an incident angle 0 larger than the Brewster angle in the circular polarization state, the circular polarization is converted into a linear polarization component via the wavelength plate, and the polarization is obtained. The device extracts the component of the reflected light from the front surface of the photoresist, and suppresses the influence of the interference signal formed by the reflected light from the back surface of the photoresist. Although a larger amount of light is required in the first exemplary embodiment due to the use of the polarizer and the wavelength plate,

有效移除來自光阻後表面之反射光所形成的干涉信號,以 及可精確地量測晶圓上所塗覆之光阻的表面形狀。如連同 Q 圖6於上述說明者可實施調整方法,就由於基材上形成充 分厚膜,使前表面信號(即來自光阻前表面之反射光所形 成的干涉信號)與後表面信號(即來自光阻後表面之反射 光所形成的干涉信號)彼此分開,以及調整極化器9a及 9b與波長板10a及10b的相對角度,使得後表面信號相 關於前表面信號的相對強度最小化。 即便於此第三例示性實施例中未設置第二極化器9b ,接收來自光阻前表面及後表面之反射光作爲兩個正交線 ❹ 性地極化分量,以及僅藉由同相位的參考光及由光組前表 面所反射的光產生干涉。因此,可抑制由光阻後表面的反 . 射光所形成之干涉信號的影響。然而,實際上,因光束干 涉器等的影響相位改變被移動,且不易獲得呈完全線性極 化狀態的接收光。爲此緣故,於此第三例示性實施例中使 用第二極化器9b以進一步抑制來自光阻後表面之反射光 的干涉信號。 藉由附接旋轉驅動單元至極化器9a及9b或波長板 -26- 200947142 10a及1 Ob可用類似上述例示性實施例的方式實施調整極 化狀態。更具體地,製備具有數微米厚之膜的基材,膜與 量測目標基材上的膜(於此情況中爲光阻)相同或其折射 率與膜之折射率相同。於量測設備中放置所製備的基材。 ' 接著,調整s極化光對p極化光的強度比使得藉由旋轉極 - 化器9a及9b或波長板l〇a及10b,使得由光阻後表面之 反射光所形成的干涉信號之影響最小化。 0 當於基材3上複數量測區域實施形狀量測時,於藉由 驅動X架台及Y架台使晶圓台已被移動而對準各預定區 域之後,以類似於第一例示性實施例獲得及處理干涉信號 〇 上述已說明三個例示性實施例,爲簡便說明之故,例 示性實施例未使用透鏡等。圖12爲根據本發明之另一面 向之表面形狀量測設備200的方塊圖。以下參考圖12將 說明使用透鏡等所構成之光學系統的例示性實施例。藉由 0 聚光透鏡11聚集光源1所發射的光並使其通過透射狹縫 板30。經由包括透鏡12、透鏡42及孔徑止擋22的光學 .系統16,於藉由光束分裂器2a而分行爲兩光束後,經聚 集的光成像於基材3及參考鏡4之分別表面上。來自基材 3及參考鏡4的反射光經由光束分裂器2b彼此疊加並經 由包括透鏡52、透鏡62及孔徑止擋13的影像光學系統 24而成像於影像拾取裝置8上。因此’可使基材3的表 面成像於影像拾取裝置8上。使用透射狹縫板30以定義 量測區域。 -27- 200947142 雖前述已說明之三個例示性實施例係於基材3及參考 鏡4之入射角相同的情況,只要參考鏡4滿足上述條件’ 於基材3及參考鏡4之入射角不需要相同。另外’爲增加 干涉信號的對比,藉由調整於基材3及參考鏡4的入射角 可改變來自基材3及參考鏡4之反射光所形成的干涉圖案 之個別強度。 圖13爲根據本發明之第四例示性實施例之半導體曝 光設備的方塊圖,其包括表面形狀量測設備。如圖13中 所說明,曝光設備包括照射設備800、光罩3 1係放置於 其上的光罩台RS、投影光學系統32、晶圓3係放置於其 上的晶圓台WS,以及配置於晶圓台WS上的參考板(遮 罩)39。另外,曝光設備包括表面位置量測設備33、相 關於量測設備33之處理單元400、表面形狀量測設備200 ,以及相關於量測設備200的處理單元410。表面形狀量 測設備200可爲根據第一至第三例示性實施例中之設備的 一者。於此第四例示性實施例中,爲更清楚表示彼等功能 ,表面位置量測設備33及表面形狀量測設備200係分別 稱爲焦點量測設備33及聚焦校準設備200。電性連接至 照射設備8 00的控制單元包括CPU及記億體、光罩台RS 、晶圓台WS、焦點量測設備3 3,以及用以控制曝光設備 操作之焦點校準設備200。於此第四例示性實施例中,當 焦點量測設備3 3偵測晶圓3之表面位置時,控制單元 1 1 00進一步執行計算以及控制以校正量測的値。 照射設備800照射其上形成有待轉移之電路圖案的光 200947142 罩31。照射設備800包括光源單位800及照射光學系統 801。照射光學系統801具有均勻照射光罩31的功能以及 極化的照射功能。 光源單位800係例如奮射。雷射可爲如波長爲約1 93 • nm之ArF準分子雷射或波長爲約248 nm之KrF準分子雷 - 射。光源之類型並不受限於準分子雷射。更具體地,亦可 使用波長爲約157 nm之F2雷射或波長爲約20 nm或更短 0 的EUV (超紫外光)。 照射光學系統800爲經配置以藉由使用光源單位800 所發射之光束而照射照射光學表面之光學系統。於此第四 例示性實施例中,光束經由具供曝光之預定最適形狀之曝 光狹縫而成形’以及經成形的光束係照射至光罩3 1。此 照射光學系統801包括依序配置於照射光學系統801中之 透鏡、聚光透鏡、蠅眼透鏡、孔徑止擋、聚光透鏡、狹縫 ,以及成像光學系統。 〇 例如由石英構成光罩31,以及光罩31上形成有待轉 移的電路圖案。由光罩台RS支撐並驅動光罩31。來自光 .罩31的繞射光通過投影光學系統32以及投射至晶圓3。 . 配置光罩3 1及晶圓3使彼呈光學共軛關係。藉由以對應 於所欲縮減因數比之速度比掃描光罩31及晶圓3,將光 罩31上的電路圖案轉移至晶圓3上。曝光設備包括基於 光傾斜入射系統的光罩偵測單元(未繪示)。光罩31係 位於預定位置,而藉由光罩偵測單元來偵測光罩31的位 置。 -29- 200947142 光罩台RS經由光罩夾頭(未繪示)支撐光罩31以 及係連接至移動機構(未繪示)。移動機構係由線性馬達 所組成,以及於X軸方向、γ軸方向、z軸方向,以及繞 各此等軸旋轉的方向驅動光罩台RS,藉此移動光罩31。 投影光學系統32具有將來自目標平面的光束成像至 影像平面上的功能。於此第四例示性實施例中,投影光學 系統32自光罩31上所成的電路圖案將繞射光成像之晶圓 3上。投影光學系統32可例如作爲包括複數個透鏡元件 的光學系統、包括複數透鏡元件及至少一個凹透鏡的光學 系統(折反射系統),或包括複數個透鏡元件及至少一個 繞射光學元件如相全息的光學系統。 晶圓3爲處理目標且具光阻塗覆於基材上。於此第四 例示性實施例中,晶圓3亦爲偵測目標,藉由焦點量測設 備33及焦點校準設備200而偵測其表面位置。於另—例 示性實施例中,晶圓3爲液晶基材或其他處理目標之一者 〇 晶圓台WS經由晶圓夾頭(未繪示)支撐晶圓3。連 同光罩台RS,晶圓台WS藉利用線性馬達於X軸方向、γ 軸方向、Z軸方向’以及繞各彼等軸旋轉的方向移動晶圓 3。另外,藉由例如6-軸雷射干涉儀81監視光罩台rs的 位置及晶圓台WS的位置,並以恆定速度比驅動兩個台。 以下將說明量測晶圓3之量測表面位置的點(即焦點 )。於此第四例示性實施例中,藉由焦點量測設備3 3量 測晶圓表面形狀而同時於掃描方向(Y方向)之晶圓3的 -30- 200947142 全部區域上掃描晶圓台ws。而且晶圓台ws垂直於掃描 方向(X方向)的方向中步進AX。接著,藉於掃描方向 中重複量測晶圓表面位置的操作,於晶圓3的全部表面上 實施形狀量測。爲增加產出’藉使用複數焦點量測設備 ' 33可於相同時間量測晶圓3的不同表面位置。 . 焦點量測設備3 3使用光學高度量測系統。換句話說 ,焦點量測設備3 3利用大入射角將光導至晶圓以及藉由 @ 位置偵測器如CCD感測器偵測由晶圓表面所反射光之影 像移動的方法。尤其是,使光束進入晶圓上待量測的複數 點,以及由這些點之反射光係導至個別感測器已根據複數 不同點所獲得之高度量測資訊計算曝光目標表面之傾斜。 以下將說明焦點及傾斜偵測系統。首先,說明焦點量 測設備3 3之結構及操作。參照圖1 4,焦點量測裝置3 3 包括光源105、聚光透鏡106、具有複數相鄰配置之矩形 透射狹縫的圖案板107、透鏡108及111、晶圓103、晶 ❹ 圓台(WS) 104、鏡109及110,以及光偵測器112,諸 如CCD感測器。元件符號1 02表示縮小投影透鏡以投影 .光罩(未繪示)至供曝光的晶圓103上。藉由聚光透鏡 106而聚焦由光源105所發射的光及照射至圖案板107。 已通過圖案板107之狹縫的光係以預定角度經由透鏡108 及鏡109而照射至晶圓103。圖案板107及晶圓103相關 於透鏡108呈成像關係,以及圖案板107之各狹縫的空間 影像係形成於晶圓上。藉由CCD感測器112經鏡110及 透鏡Π1接收來自晶圓103的反射光。藉由透鏡111,晶 -31 - 200947142 圓103的狹縫影像重新成像於CCD感測器112上’以及 獲得如l〇7i所指出之對應於圖案板107之狹縫的狹縫影 像信號。藉由偵測CCD感測器1 1 2上之彼等信號的位置 移動,量測晶圓103之Z方向上的位置。假設入射角爲Θ 人,當於Z方向中晶圓表面由位置wl至w2而改變dz時 ,可藉由下式表示晶圓3於光軸上的移動量ml: - ml=2*dz*tan0 入 (1) ❹ 例如,假設入射角Θ入爲84度,則得到m 1 = 1 9 · dz。此 指出移位量爲晶圓移位量的1 9倍。藉相乘(1 )之値與光 學系統的放大率(即藉透鏡111之成像放大率)而獲得光 偵測器上的位移量。 以下將仔細說明使用上述根據本發明之第四例示性實 施例之曝光設備的曝光方法。圖15爲當使用根據本發明 之第四例示性實施例的曝光設備時,曝光方法之全部步驟 的流程圖。首先,於步驟S1中,載入晶圓3至設備中。 0 接著’於步驟S10中判定是否藉焦點量測設備33執行焦 點校準。根據如“相關晶圓是否爲批次中之頭件晶圓,,、“ 相關晶圓是否爲複數批次中之頭件晶圓”以及“相關晶圓是 否爲嚴格要求焦點精確度之製程中的晶圓”之資訊自動進 行判定。此資訊係由使用者於先前儲存於曝光設備中。若 步驟S 1 0中判定不需要焦點校準,程序流程進行到步驟 S 1 000,其中於晶圓上執行普通曝光順序。另—方面,若 於步驟S 1 〇判定須要焦點校準,則程序流程進行到步驟 -32- 200947142 SI 00中的焦點校準順序。 於步驟S100中’執行圖16中所說明的流程圖。首先 ’驅動晶圓台WS以恰當定位焦點量測設備33下方的參 考板39。參考板39係由玻璃板所形成,其具有高表面精 •確度’即所謂的光學扁平。參考板39的表面具有反射率 • 均句以預防由焦點量測設備33引起之量測錯誤的區域。 於該區域上實施量測。亦可設置參考板39作爲部分之包 φ 括於曝光設備所執行的其他校準(如供對準偵測系統及評 估投影光學系統)所需之各種校準標記的板。於步驟 S101中,藉由焦點量測設備33偵測參考板39之Z方向 上的位置’以及於步驟S102中儲存量測値於設備中。然 後’於步驟S 1 0 3中’驅動晶圓台w S以恰當定位參考板 39於焦點校準設備200下,以及由焦點校準設備200於 藉由焦點量測設備3 3所量測區域之參考板3 9上X γ平面 中相同位置處執行形狀量測。於步驟S 1 0 4中,儲存形狀 φ 量測資料Pm於設備中。於步驟S105中計算第一偏移1。 如圖1 7中所說明’得到偏移丨作爲介於焦點校準設備 . 2 00所量測値Pm與焦點量測設備3 3所量測値〇m之間的 差異。偏移1無焦點量測設備3 3的量測錯誤,因量測係 執行於參考板39之光學均勻表面上。因此,於理想狀況 中偏移1應爲零。然而,偏移1因如晶圓台WS之掃描方 向中的系統偏移及焦點量測設備33或焦點校準設備200 之長期漂移而產生。爲此緣故,基於週期基礎所量測的偏 移1係所欲者。 -33- 200947142 由上述步驟而完成使用參考板39的焦點校準順序 S100。於焦點校準順序S100之後,執行使用晶圓3之焦 點校準順序S200。於圖16之步驟S201中,驅動晶圓台 WS以於焦點量測設備3 3之量測位置恰當定位晶圓台3。 假設晶圓3上的(晶圓表面)量測位置Wp匹配以下描述 之曝光順序中的量測位置。另外,於步驟S201中藉由焦 點量測設備33偵測晶圓上量測位置Wp處之Z方向上位 置,以及於步驟S202中儲存量測値Ow於設備中。於步 驟S203,驅動晶圓台WS以於焦點校準設備200下方恰 當定位晶圓3,以及藉由焦點校準設備200執行晶圓3上 量測位置Wp處的形狀量測。於步驟S204中,儲存形狀 量測資料Pw於設備中。晶圓3上的量測位置可選自以下 各種模式,包括:如每晶圓一個點、每發射一個點、一發 射中所有點、複數發射中所有點,以及一晶圓中所有點。 於步驟S20 5中,計算第二偏移2。如圖17中所說明 ,計算偏移2之介於焦點校準設備200之量測値與作爲針 對晶圓3上各量測位置Wp的焦點量測設備3 3之量測値 〇w之間的差。 於步驟S206中’於晶圓3上每量測點計算介於偏移 2及偏移1之間的差。藉由下式(2)可得到晶圓3上之 量測點的偏移量Op : °P(i) = [Ow(i) - Pw(i)] - (Om - Pm) (2) 200947142 其中i表示代表晶圓3上量測位置的點數目。因而完成使 用晶圓3之焦點校準順序S2000。 以下將說明於完成焦點校準順序S100及S200兩者後 所執行之曝光順序S1000。圖18爲詳細說明曝光順序 - S 1 000的流程圖。參照圖18,於步驟S1010中執行晶圓對 . 準。由晶圓上偵測標記位置,藉由對準視野(未繪示)及 相關曝光設備對準XY平面中的晶圓而執行晶圓對準。於 ϋ 步驟S 1 0 1 1中’藉由焦點量測設備3 3量測晶圓3上預定 位置的表面位置。預定位置包括藉使用晶圓3之校準順序 所量測的點。因此,藉由校正根據式(2 )所計算之偏移 量Op ( i )的各量測値而量測全部晶圓表面的形狀。校正 後的晶圓表面形狀資料係儲存於曝光設備中。於步驟 S 1012中,針對第一次曝光照射,藉由晶圓台WS將晶圓 3自焦點量測設備33下方的位置移動至投射透鏡102下 方的曝光位置。同時,根據晶圓3之表面形狀資料,相關 ❹ 於曝光設備的處理單元預備供第一曝光照射的表面形狀資 料,以及計算自曝光成像平面之偏移量。然後,根據所計 .算之自曝光成像平面的偏移量,於Z方向及傾斜方向驅動 晶圓台,以實施於高度方向中、實質上以曝光狹縫爲單位 的匹配晶圓表面形狀之操作。於步驟S1013中,於Y方 向中實施曝光及掃描晶圓台WS。以此方式完成第一曝光 照射後,於步驟S1014判定是否有仍未執行曝光存在。若 仍未執行曝光存在,則返回步驟S1012。接下來,如第一 曝光照射,準備供下一曝光照射的表面形狀資料,以及於 -35- 200947142 Z方向及傾斜方向驅動晶圓台時實施曝光,以實施於高度 方向中、實質上以曝光狹縫爲單位的匹配晶圓表面形狀之 操作。於步驟S1014中,再次判定待執行曝光照射(即仍 未執行曝光)是否存在。接著,重複上述操作直到無仍未 執行曝光存在。於完成所有曝光照射後,於步驟81015中 · 自設備取出晶圓3以及結束曝光順序。 . 於此第四例示性實施例中,恰於各曝光照射之前,準 備供相關曝光照射的表面形狀資料以及計算自曝光成像平 @ 面的移動量以判定晶圓台之待驅動量。然而,在第一次曝 光照射之前可修正個別步驟的時序,而準備供所有曝光照 射的表面形狀資料,以及計算自曝光成像平面的移動量以 判定晶圓台之待驅動量。 另外’晶圓台WS並不受限於單一台。例如,其亦可 由所謂的包括兩個台,即曝光中所使用的曝光台及用以實 施晶圓對準及量測表面形狀的量測台,之雙台所組成。於 後者的情況中,安裝焦點量測設備3 3及焦點校準設備 0 200於量測台上。 以下將說明如此第四例示性實施例中,當安裝表面形 | 狀量測設備200於曝光設備中,調整表面形狀量測設備( 焦點校準設備)200中之光極化狀態的方法。雖如上述 第二例示性實施例中所說明者,藉由使用塗覆有數微米之 厚光阻可調整光極化狀態,以下說明的例示性實施例中係 基於曝光設備中所使用之曝光光線的極化實施調整方法。 曝光設備的照射光學系統8 0 1通常包括極化照射單元以指 -36- 200947142 定照射至光罩之光的極化狀態。因此,當遞送曝光設備時 ,基於曝光光線的極化而調整表面形狀量測設備200中的 光極化狀態。更具體地,首先,藉由使用供曝光光線之照 射光學系統80 1中的照射單元而形成呈預定狀態(如p極 ' 化光)的線性極化光。接著,致使呈預定線性極化狀態的 . 曝光光線垂直地進入包括旋轉驅動單元的極化器。另外, 旋轉極化器以判定透射率最大或最小的位置。此導致使用 φ 對應於P或S極化光的極化狀態作爲曝光光線。隨後,安 裝極化器使得來自焦點校準設備200中之光源的光垂直地 進入極化器。當根據圖8中所說明之第二例示性實施例而 應用此調整方法於表面形狀量測設備時,藉由利用旋轉驅 動單元將極化器旋轉45度而完成調整。因此,藉由使用 曝光設備而不用準備特殊基材可實施極化狀態的調整。 當遞送曝光設備時基於曝光光線之極化,於表面形狀 量測設備中調整極化狀態之後,藉由製備具有厚光阻的基 ❹ 材及使用根據待處理的晶圓結構的旋轉驅動單元可微調極 化狀態。 . 因爲晶圓,即待藉由半導體曝光設備量測且處理的基 材,尙存在的複雜電路圖案、劃線等,反射率分佈、局部 傾斜等發生的機率相當高。因此,本發明極有效於減少由 反射率分佈、局部傾斜等所引起的量測錯誤。較精確的晶 圓表面位置量測改善最佳曝光表面與晶圓表面之精確焦點 對準,因此增進半導體裝置的表現及增加產率。 例如經由曝光塗覆有光阻之基材(諸如晶圓或玻璃板 -37- 200947142 )的步驟、藉使用根據上述例示性實施例之一者的曝光設 備、顯影曝光的基材之步驟,以及先前技術已知的其他步 驟,可製造裝置(諸如半導體積體電路裝置或液晶顯示器 裝置)。 雖本發明已參考例示性實施例進行說明,應了解的是 本發明並不受限於所揭露的例示性實施例。以下申請專利 範圍係最廣義解釋以包含所有修飾以及均等結構及功能。 【圖式簡單說明】 圖1爲根據本發明之第一例示性實施例的表面形狀量 測設備之方塊圖。 圖2爲闌述改變相關於入射角反射率(即菲涅耳( Fresnel)關係)大小之圖。 圖3闡述圖2中所說明之模擬中所使用的模型。 圖4闡述圖5A及5B中所說明之模擬中所使用的模 型。 圖5A爲闡述相關於入射角,由光阻的前表面(即空 氣/光阻介面)所反射的光之相位改變的圖。 圖5B爲闡述相關於入射角,由光阻的後表面(即光 阻/A1介面)所反射的光之相位改變的圖。 圖6爲闡述各由光阻之前及後表面所反射的光形成之 干涉信號的圖。 圖7爲閩述本發明之第一實施例中所獲得之干涉信號 的圖。 -38- 200947142 圖8爲根據本發明之第二例示性實施例之表面形狀量 測設備的方塊圖。 圖9闡述根據本發明之第二例示性實施例之表面形狀 量測設備中各個不同點之極化狀態。 •圖1 0爲根據本發明之第三例示性實施例之表面形狀 - 量測設備的方塊圖。 圖1 1闡述根據本發明之第三例示性實施例之表面形 〇 狀量測設備中各個不同點之極化狀態。 圖12爲根據本發明之另一面向之表面形狀量測設備 的方塊圖。 圖13爲根據本發明之第四例示性實施例之半導體曝 光設備的方塊圖,半導體曝光設備包括表面形狀量測設備 〇 圖14爲本發明之第四例示性實施例中所使用的表面 位置量測設備之方塊圖。 ® 圖15爲本發明之第四例示性實施例中曝光順序的流 程圖。 圖16爲本發明之第四例示性實施例中之校正方法的 - 流程圖。 圖17爲闡述本發明之第四例示性實施例中之校正方 法的說明視圖》 圖18爲本發明之第四例示性實施例中之曝光方法的 流程圖。 圖1 9爲用以解釋習知表面位置量測設備的問題之說 -39- 200947142 明。 圖20爲闡述以圖丨9之習知表面位置量測設備所量測 的信號檔案之實例的圖。 圖21爲用以解釋習知表面形狀量測設備的問題之說 明。 _ 圖22爲用以解釋習知表面形狀量測設備的問題之說 明。 圖23爲習知表面形狀量測設備的方塊圖。 _ 【主要元件符號說明】 1 :光源 2a :光束分裂器 2b :光束分裂器 3 :基材 4 :參考鏡The interference signal formed by the reflected light from the rear surface of the photoresist is effectively removed, and the surface shape of the photoresist coated on the wafer can be accurately measured. If the adjustment method can be implemented as described above with reference to Q FIG. 6, the front surface signal (ie, the interference signal formed by the reflected light from the front surface of the photoresist) and the back surface signal are formed due to the formation of a sufficiently thick film on the substrate. The interference signals formed by the reflected light from the rear surface of the photoresist are separated from each other, and the relative angles of the polarizers 9a and 9b with the wave plates 10a and 10b are adjusted such that the relative intensity of the back surface signal with respect to the front surface signal is minimized. Even if the second polarizer 9b is not provided in the third exemplary embodiment, the reflected light from the front surface and the rear surface of the photoresist is received as a polar component of the two orthogonal lines, and only by the same phase. The reference light and the light reflected by the front surface of the light group interfere. Therefore, the influence of the interference signal formed by the opposite light of the surface of the photoresist can be suppressed. However, actually, the phase change is moved due to the influence of the beam interferer or the like, and it is difficult to obtain the received light in a completely linearly polarized state. For this reason, the second polarizer 9b is used in the third exemplary embodiment to further suppress the interference signal of the reflected light from the rear surface of the photoresist. The adjustment of the polarization state can be carried out by attaching the rotary drive unit to the polarizers 9a and 9b or the wavelength plates -26-200947142 10a and 1 Ob in a manner similar to the above-described exemplary embodiment. More specifically, a substrate having a film having a thickness of several micrometers is prepared, the film being the same as the film on the measurement target substrate (in this case, the photoresist) or having the same refractive index as that of the film. The prepared substrate is placed in a measuring device. ' Next, the intensity ratio of the s-polarized light to the p-polarized light is adjusted such that the interference signal formed by the reflected light from the rear surface of the photoresist is made by the polar-polarizers 9a and 9b or the wavelength plates 10a and 10b. The impact is minimized. 0 When the shape measurement is performed on the complex measurement area on the substrate 3, after the wafer stage has been moved to be aligned with each predetermined area by driving the X stage and the Y stage, similar to the first exemplary embodiment Obtaining and Processing Interference Signals Three exemplary embodiments have been described above, and for ease of illustration, the exemplary embodiments do not use lenses or the like. Figure 12 is a block diagram of another surface shape measuring apparatus 200 in accordance with the present invention. An exemplary embodiment of an optical system constructed using a lens or the like will be described below with reference to Fig. 12 . The light emitted from the light source 1 is collected by the condensing lens 11 and passed through the transmission slit plate 30. Through the optical system 16 including the lens 12, the lens 42 and the aperture stop 22, after the two beams are split by the beam splitter 2a, the collected light is imaged on the respective surfaces of the substrate 3 and the reference mirror 4. The reflected light from the substrate 3 and the reference mirror 4 is superimposed on each other via the beam splitter 2b and imaged on the image pickup device 8 via the image optical system 24 including the lens 52, the lens 62, and the aperture stop 13. Therefore, the surface of the substrate 3 can be imaged on the image pickup device 8. A transmission slit plate 30 is used to define the measurement area. -27- 200947142 Although the three exemplary embodiments described above are in the case where the incident angles of the substrate 3 and the reference mirror 4 are the same, as long as the reference mirror 4 satisfies the above conditions, the incident angles of the substrate 3 and the reference mirror 4 No need to be the same. Further, in order to increase the contrast of the interference signals, the individual intensity of the interference pattern formed by the reflected light from the substrate 3 and the reference mirror 4 can be changed by adjusting the incident angles of the substrate 3 and the reference mirror 4. Figure 13 is a block diagram of a semiconductor exposure apparatus according to a fourth exemplary embodiment of the present invention, including a surface shape measuring apparatus. As illustrated in FIG. 13, the exposure apparatus includes an illumination apparatus 800, a mask stage RS on which the mask 31 is placed, a projection optical system 32, a wafer stage WS on which the wafer 3 is placed, and a configuration A reference plate (mask) 39 on the wafer table WS. Further, the exposure apparatus includes a surface position measuring device 33, a processing unit 400 relating to the measuring device 33, a surface shape measuring device 200, and a processing unit 410 related to the measuring device 200. The surface shape measuring device 200 may be one of the devices according to the first to third exemplary embodiments. In the fourth exemplary embodiment, in order to more clearly show their functions, the surface position measuring device 33 and the surface shape measuring device 200 are referred to as a focus measuring device 33 and a focus calibration device 200, respectively. The control unit electrically connected to the illumination device 800 includes a CPU and a body, a mask table RS, a wafer table WS, a focus measuring device 33, and a focus calibration device 200 for controlling the operation of the exposure device. In the fourth exemplary embodiment, when the focus measuring device 3 3 detects the surface position of the wafer 3, the control unit 1 100 further performs calculation and control to correct the measured 値. The illuminating device 800 illuminates the light 200947142 cover 31 on which the circuit pattern to be transferred is formed. The illumination device 800 includes a light source unit 800 and an illumination optical system 801. The illuminating optical system 801 has a function of uniformly illuminating the reticle 31 and an illuminating function of polarization. The light source unit 800 is for example a shot. The laser can be an ArF excimer laser having a wavelength of about 1 93 • nm or a KrF excimer laser having a wavelength of about 248 nm. The type of light source is not limited to excimer lasers. More specifically, an F2 laser having a wavelength of about 157 nm or an EUV (ultraviolet light) having a wavelength of about 20 nm or less can also be used. Illumination optics 800 is an optical system configured to illuminate an illuminating optical surface by using a beam of light emitted by source unit 800. In the fourth exemplary embodiment, the light beam is shaped via an exposure slit having a predetermined optimum shape for exposure, and the shaped beam system is irradiated to the reticle 31. This illumination optical system 801 includes a lens, a collecting lens, a fly's eye lens, an aperture stop, a collecting lens, a slit, and an imaging optical system which are sequentially disposed in the illumination optical system 801.光 For example, the reticle 31 is made of quartz, and the circuit pattern to be transferred is formed on the reticle 31. The reticle 31 is supported and driven by the reticle stage RS. The diffracted light from the light cover 31 passes through the projection optical system 32 and is projected onto the wafer 3. The reticle 31 and the wafer 3 are arranged to be optically conjugated. The circuit pattern on the mask 31 is transferred onto the wafer 3 by scanning the mask 31 and the wafer 3 at a speed ratio corresponding to the desired reduction factor. The exposure apparatus includes a mask detection unit (not shown) based on a light oblique incidence system. The reticle 31 is located at a predetermined position, and the position of the reticle 31 is detected by the reticle detecting unit. -29- 200947142 The mask table RS supports the reticle 31 via a reticle holder (not shown) and is connected to a moving mechanism (not shown). The moving mechanism is composed of a linear motor, and drives the mask table RS in the X-axis direction, the γ-axis direction, the z-axis direction, and the direction in which the respective axes rotate, thereby moving the mask 31. The projection optical system 32 has a function of imaging a light beam from a target plane onto an image plane. In the fourth exemplary embodiment, the circuit pattern formed by the projection optical system 32 from the photomask 31 will be on the wafer 3 on which the light is imaged. Projection optics 32 can be, for example, an optical system including a plurality of lens elements, an optical system (a catadioptric system) including a plurality of lens elements and at least one concave lens, or a plurality of lens elements and at least one diffractive optical element such as a phase hologram Optical system. Wafer 3 is a processing target and is photoresist coated onto the substrate. In the fourth exemplary embodiment, the wafer 3 is also a detection target, and the surface position is detected by the focus measuring device 33 and the focus calibration device 200. In another exemplary embodiment, the wafer 3 is one of a liquid crystal substrate or other processing target. The wafer table WS supports the wafer 3 via a wafer chuck (not shown). Together with the mask stage RS, the wafer table WS moves the wafer 3 by the linear motor in the X-axis direction, the γ-axis direction, the Z-axis direction, and the direction in which the respective axes rotate. Further, the position of the mask table rs and the position of the wafer table WS are monitored by, for example, a 6-axis laser interferometer 81, and the two stages are driven at a constant speed ratio. The point at which the measurement surface position of the wafer 3 is measured (i.e., the focus) will be described below. In the fourth exemplary embodiment, the wafer surface shape is measured by the focus measuring device 3 3 while scanning the wafer table ws on the entire area of the wafer 3 of the -30-200947142 in the scanning direction (Y direction). . Further, the wafer table ws is stepped AX in the direction perpendicular to the scanning direction (X direction). Next, shape measurement is performed on the entire surface of the wafer 3 by repeatedly measuring the position of the wafer surface in the scanning direction. To increase the output 'by using the complex focus measuring device' 33, the different surface positions of the wafer 3 can be measured at the same time. The focus measuring device 3 3 uses an optical height measuring system. In other words, the focus measuring device 33 uses a large angle of incidence to direct light to the wafer and a method of detecting the movement of the image reflected by the surface of the wafer by a @ position detector such as a CCD sensor. In particular, the beam is directed to a plurality of points to be measured on the wafer, and the reflected light from the points is directed to an individual sensor that has calculated the tilt of the exposure target surface based on the height measurement information obtained at the different points. The focus and tilt detection system will be explained below. First, the structure and operation of the focus measuring device 33 will be explained. Referring to FIG. 14, the focus measuring device 3 3 includes a light source 105, a collecting lens 106, a pattern plate 107 having a plurality of rectangular transmission slits arranged adjacent to each other, lenses 108 and 111, a wafer 103, and a wafer round table (WS). 104, mirrors 109 and 110, and photodetector 112, such as a CCD sensor. The symbol 012 indicates that the projection lens is reduced to project a reticle (not shown) onto the wafer 103 for exposure. The light emitted from the light source 105 is focused by the condensing lens 106 and irradiated onto the pattern plate 107. The light having passed through the slit of the pattern plate 107 is irradiated to the wafer 103 via the lens 108 and the mirror 109 at a predetermined angle. The pattern plate 107 and the wafer 103 are in an imaging relationship with respect to the lens 108, and the spatial image of each slit of the pattern plate 107 is formed on the wafer. The reflected light from the wafer 103 is received by the CCD sensor 112 via the mirror 110 and the lens Π1. By the lens 111, the slit image of the crystal -31 - 200947142 circle 103 is re-imaged on the CCD sensor 112' and the slit image signal corresponding to the slit of the pattern plate 107 as indicated by l〇7i is obtained. The position of the wafer 103 in the Z direction is measured by detecting the positional shift of the signals on the CCD sensor 112. Assuming that the incident angle is Θ, when the wafer surface changes dz from the position w1 to w2 in the Z direction, the amount of movement of the wafer 3 on the optical axis can be expressed by the following formula: - ml=2*dz* Tan0 In (1) ❹ For example, assuming an incident angle of 84 degrees, m 1 = 1 9 · dz is obtained. This indicates that the shift amount is 19 times the wafer shift amount. The amount of displacement on the photodetector is obtained by multiplying (1) and the magnification of the optical system (i.e., by the imaging magnification of the lens 111). The exposure method using the above-described exposure apparatus according to the fourth exemplary embodiment of the present invention will be described in detail below. Figure 15 is a flow chart showing the overall steps of the exposure method when the exposure apparatus according to the fourth exemplary embodiment of the present invention is used. First, in step S1, the wafer 3 is loaded into the device. 0 Next, it is determined in step S10 whether or not the focus measurement device 33 performs the focus point calibration. According to, for example, "whether the relevant wafer is the wafer of the header in the batch, "whether the relevant wafer is the wafer of the header in the plurality of batches" and "whether the relevant wafer is in the process of strictly demanding focus accuracy" The information of the wafer is automatically determined. This information is previously stored by the user in the exposure device. If it is determined in step S10 that the focus calibration is not required, the program flow proceeds to step S1 000, where on the wafer. Performing the normal exposure sequence. On the other hand, if it is determined in step S1 that the focus calibration is required, the program flow proceeds to the focus calibration sequence in step-32-200947142 SI 00. In step S100, 'execution illustrated in FIG. 16 is performed. Flowchart. First, the wafer table WS is driven to properly position the reference plate 39 under the focus measuring device 33. The reference plate 39 is formed of a glass plate having a high surface precision, a so-called optical flat. The surface of 39 has a reflectance • a uniform sentence to prevent an area of measurement error caused by the focus measuring device 33. The measurement is performed on the area. The reference plate 39 can also be set as a partial package φ A board of various calibration marks required for other calibrations performed by the exposure apparatus (such as for the alignment detection system and evaluation of the projection optical system). In step S101, the focus measurement device 33 detects the Z of the reference plate 39. The position in the direction 'and the stored amount in the device in step S102. Then 'in step S 1 0 3' drive the wafer table w S to properly position the reference plate 39 under the focus calibration device 200, and by focus The calibration apparatus 200 performs shape measurement at the same position in the X γ plane on the reference plate 39 of the measurement area of the focus measurement device 33. In step S1 0 4, the shape φ measurement data Pm is stored. In the device, the first offset 1 is calculated in step S105. As shown in Fig. 17, the offset is obtained as the focus calibration device. The measurement of the measurement unit Pm and the focus measurement device 3 3 The difference between 値〇m. Offset 1 is a measurement error of the focusless measuring device 3 3 because the measurement system is performed on the optically uniform surface of the reference plate 39. Therefore, in the ideal case, the offset 1 should be zero. However, the offset 1 is due to the system in the scanning direction of the wafer table WS. The shift is generated by the long-term drift of the focus measuring device 33 or the focus calibration device 200. For this reason, the offset 1 measured based on the cycle basis is desired. -33- 200947142 The reference plate 39 is completed by the above steps. The focus calibration sequence S100. After the focus calibration sequence S100, the focus calibration sequence S200 using the wafer 3 is performed. In step S201 of Fig. 16, the wafer table WS is driven so that the measurement position of the focus measuring device 3 3 is appropriate. Positioning the wafer table 3. It is assumed that the (wafer surface) measurement position Wp on the wafer 3 matches the measurement position in the exposure sequence described below. In addition, the wafer is detected by the focus measurement device 33 in step S201. The position in the Z direction at the position Wp is measured, and the measurement amount Ow is stored in the device in step S202. In step S203, the wafer table WS is driven to properly position the wafer 3 under the focus calibration apparatus 200, and the shape measurement at the measurement position Wp on the wafer 3 is performed by the focus calibration apparatus 200. In step S204, the shape measurement data Pw is stored in the device. The measurement locations on wafer 3 can be selected from the following modes, including: one dot per wafer, one spot per shot, all points in one emission, all points in a complex transmission, and all points in a wafer. In step S20 5, the second offset 2 is calculated. As illustrated in FIG. 17, the offset 2 is calculated between the measurement of the focus calibration apparatus 200 and the measurement of the focus measurement device 3 3 for each measurement position Wp on the wafer 3. difference. The difference between offset 2 and offset 1 is calculated for each measurement point on the wafer 3 in step S206. The offset of the measurement point on the wafer 3 can be obtained by the following formula (2): °P(i) = [Ow(i) - Pw(i)] - (Om - Pm) (2) 200947142 Where i represents the number of points representing the measurement position on the wafer 3. Thus, the focus calibration sequence S2000 using the wafer 3 is completed. The exposure sequence S1000 performed after completion of both the focus calibration sequences S100 and S200 will be described below. Figure 18 is a flow chart detailing the exposure sequence - S 1 000. Referring to Fig. 18, the wafer alignment is performed in step S1010. Wafer alignment is performed by detecting the marked locations on the wafer by aligning the fields of view (not shown) and associated exposure equipment to the wafers in the XY plane. In step S1 0 1 1, the surface position of the predetermined position on the wafer 3 is measured by the focus measuring device 3 3 . The predetermined location includes points measured by the calibration sequence using wafer 3. Therefore, the shape of the entire wafer surface is measured by correcting the respective amounts of the offsets Op (i) calculated according to the equation (2). The corrected wafer surface shape data is stored in the exposure apparatus. In step S1012, for the first exposure illumination, the wafer 3 is moved from the position below the focus measuring device 33 to the exposure position below the projection lens 102 by the wafer table WS. At the same time, according to the surface shape data of the wafer 3, the processing unit associated with the exposure apparatus prepares the surface shape information for the first exposure illumination, and calculates the offset from the exposure imaging plane. Then, according to the calculated offset from the exposure imaging plane, the wafer stage is driven in the Z direction and the oblique direction to perform the matching wafer surface shape in the height direction substantially in the exposure slit unit. operating. In step S1013, the exposure and scanning wafer stage WS is performed in the Y direction. After the first exposure irradiation is completed in this manner, it is determined in step S1014 whether or not the exposure is still not performed. If the exposure is still not performed, the process returns to step S1012. Next, as the first exposure illumination, the surface shape data for the next exposure illumination is prepared, and the exposure is performed when the wafer stage is driven in the -35-200947142 Z direction and the oblique direction to perform the exposure in the height direction, substantially exposing The operation of matching the surface shape of the wafer in units of slits. In step S1014, it is determined again whether or not the exposure illumination to be performed (i.e., the exposure has not been performed) is present. Then, the above operation is repeated until no exposure is still performed. After all exposure exposures are completed, in step 81015, the wafer 3 is taken out of the apparatus and the exposure sequence is ended. In the fourth exemplary embodiment, the surface shape data for the relevant exposure illumination and the amount of movement from the exposure imaging plane are prepared to determine the amount to be driven of the wafer table just before each exposure illumination. However, the timing of the individual steps can be corrected before the first exposure, while the surface shape data for all exposures is prepared, and the amount of movement from the exposure imaging plane is calculated to determine the amount of wafer to be driven. In addition, the wafer table WS is not limited to a single station. For example, it may be composed of so-called two stages, that is, an exposure stage used in exposure, and a measuring stage for performing wafer alignment and measuring the shape of the surface. In the latter case, the focus measuring device 3 3 and the focus calibration device 0 200 are mounted on the measuring station. In the fourth exemplary embodiment as described above, a method of adjusting the polarization state of light in the surface shape measuring device (focus calibration device) 200 when the surface measuring device 200 is mounted in the exposure device will be explained. Although the photopolarization state can be adjusted by using a photoresist coated with a thickness of several micrometers as described in the above second exemplary embodiment, the exemplary embodiment described below is based on the exposure light used in the exposure apparatus. Polarization implementation adjustment method. The illumination optical system 810 of the exposure apparatus generally includes a polarization state in which the polarization illumination unit is directed to -36-200947142 to illuminate the light of the reticle. Therefore, when the exposure apparatus is delivered, the polarization state of the light in the surface shape measuring apparatus 200 is adjusted based on the polarization of the exposure light. More specifically, first, linearly polarized light in a predetermined state (e.g., p-polarized light) is formed by using an illuminating unit in the illuminating optical system 80 1 for exposing light. Next, the exposure light in a predetermined linear polarization state is caused to enter vertically into the polarizer including the rotary driving unit. In addition, the polarizer is rotated to determine the position at which the transmittance is the largest or smallest. This results in the use of φ as the exposure light corresponding to the polarization state of the P or S polarized light. Subsequently, the polarizer is mounted such that light from the source in the focus calibration device 200 enters the polarizer vertically. When this adjustment method is applied to the surface shape measuring apparatus according to the second exemplary embodiment illustrated in Fig. 8, the adjustment is completed by rotating the polarizer by 45 degrees using the rotation driving unit. Therefore, the adjustment of the polarization state can be performed by using an exposure apparatus without preparing a special substrate. After the exposure device is delivered, based on the polarization of the exposure light, after the polarization state is adjusted in the surface shape measuring device, the base material having a thick photoresist can be prepared and the rotary driving unit according to the wafer structure to be processed can be used. Fine-tune the polarization state. Because of the wafers, the substrates to be measured and processed by the semiconductor exposure equipment, the complex circuit patterns, scribe lines, etc., the probability of occurrence of reflectance distribution, local tilt, etc., is quite high. Therefore, the present invention is extremely effective in reducing measurement errors caused by reflectance distribution, local tilt, and the like. More accurate wafer surface position measurement improves the precise focus alignment of the optimal exposed surface to the wafer surface, thereby enhancing the performance of the semiconductor device and increasing yield. For example, a step of exposing a substrate coated with a photoresist (such as a wafer or a glass plate - 37 - 200947142), a step of using an exposure apparatus according to one of the above exemplary embodiments, developing a substrate for exposure, and Other steps known in the prior art may be fabricated into devices such as semiconductor integrated circuit devices or liquid crystal display devices. While the invention has been described with reference to the exemplary embodiments, it is understood that the invention is not limited to the disclosed embodiments. The scope of the following patent application is to be construed in a broadest sense as the BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a block diagram of a surface shape measuring apparatus according to a first exemplary embodiment of the present invention. Figure 2 is a graph of the change in the reflectance (i.e., Fresnel relationship) associated with the incident angle. Figure 3 illustrates the model used in the simulation illustrated in Figure 2. Figure 4 illustrates the model used in the simulation illustrated in Figures 5A and 5B. Figure 5A is a diagram illustrating the phase change of light reflected by the front surface of the photoresist (i.e., the air/photoresist interface) with respect to the angle of incidence. Figure 5B is a diagram illustrating the phase change of light reflected by the back surface of the photoresist (i.e., the photoresist/A1 interface) with respect to the angle of incidence. Fig. 6 is a view for explaining interference signals formed by respective lights reflected by the front and rear surfaces of the photoresist. Fig. 7 is a view for explaining an interference signal obtained in the first embodiment of the present invention. -38- 200947142 Fig. 8 is a block diagram of a surface shape measuring apparatus according to a second exemplary embodiment of the present invention. Figure 9 illustrates the polarization states of various points in the surface shape measuring apparatus according to the second exemplary embodiment of the present invention. Figure 10 is a block diagram of a surface shape-measuring apparatus in accordance with a third exemplary embodiment of the present invention. Fig. 11 illustrates the polarization states of various points in the surface shape measuring apparatus according to the third exemplary embodiment of the present invention. Figure 12 is a block diagram of another surface-facing measuring apparatus according to the present invention. Figure 13 is a block diagram of a semiconductor exposure apparatus including a surface shape measuring apparatus according to a fourth exemplary embodiment of the present invention. Figure 14 is a surface position amount used in a fourth exemplary embodiment of the present invention. A block diagram of the test equipment. ® Figure 15 is a flow chart showing the exposure sequence in the fourth exemplary embodiment of the present invention. Figure 16 is a flow chart of a method of correction in a fourth exemplary embodiment of the present invention. Figure 17 is an explanatory view for explaining a correction method in a fourth exemplary embodiment of the present invention. Figure 18 is a flow chart showing an exposure method in a fourth exemplary embodiment of the present invention. Figure 19 is a diagram for explaining the problem of the conventional surface position measuring device -39-200947142. Fig. 20 is a view for explaining an example of a signal file measured by the conventional surface position measuring device of Fig. 9. Fig. 21 is a view for explaining the problem of the conventional surface shape measuring device. Fig. 22 is a view for explaining a problem of the conventional surface shape measuring device. Figure 23 is a block diagram of a conventional surface shape measuring apparatus. _ [Main component symbol description] 1 : Light source 2a : Beam splitter 2b : Beam splitter 3 : Substrate 4 : Reference mirror

5 : Z架台 U 6 : Y架台 7 : X架台 8 :影像拾取裝置 9a :第一極化器 9b :第二極化器 10a :第一波長板 1 〇 b :第二波長板 1 1 :聚光透鏡 -40- 200947142 12 : 透鏡 13: 孔徑止擋 16: 光學系統 22 : 孔徑止擋 - 24 : 成像光學系統 . 30 : 透射狹縫板 3 1: 光罩 a 32: 投影光學系統 33 : 表面位置量測設備 39 : 參考板 4 2 : 透鏡 52 : 透鏡 62 : 透鏡 81 : 雷射干涉儀 10 1 :光源 〇 102 ’·縮小投影透鏡 103 :透鏡 1 04 :晶圓台 105 :光束分裂器 106 :聚光透鏡 107 :圖案板 l〇7i :影像信號 108 :透鏡 109 :鏡 -41 200947142 1 1 0 :鏡 111 :透鏡 1 1 2 :光偵測器 130 :參考鏡 1 7 0 :光束組合器 1 7 1 :透鏡 173 :透鏡 1 7 5 :光電轉換元件 200 :表面形狀量測設備 3 6 0 :樣本 397 :致動器 400 :處理單元 410 :處理單元 8 0 0 :照射設備 8 0 1 :照射光學系統 1 1 0 0 :控制單元 -425 : Z gantry U 6 : Y gantry 7 : X gantry 8 : Image pickup device 9 a : First polarizer 9 b : Second polarizer 10 a : First wavelength plate 1 〇 b : Second wavelength plate 1 1 : Poly Optical Lens-40- 200947142 12 : Lens 13: Aperture Stop 16: Optical System 22: Aperture Stop - 24: Imaging Optical System. 30: Transmission Slit Plate 3 1: Mask a 32: Projection Optical System 33: Surface Position measuring device 39: reference plate 4 2 : lens 52 : lens 62 : lens 81 : laser interferometer 10 1 : light source 〇 102 '·reduced projection lens 103 : lens 1 04 : wafer table 105 : beam splitter 106 : concentrating lens 107 : pattern plate l 〇 7i : image signal 108 : lens 109 : mirror - 41 200947142 1 1 0 : mirror 111 : lens 1 1 2 : photodetector 130 : reference mirror 1 7 0 : beam combiner 1 7 1 : Lens 173 : Lens 1 7 5 : Photoelectric conversion element 200 : Surface shape measuring device 3 6 0 : Sample 397 : Actuator 400 : Processing unit 410 : Processing unit 8 0 0 : Irradiation device 8 0 1 : Illumination optical system 1 1 0 0 : Control unit -42

Claims (1)

200947142 七、申請專利範圍: 1 · 一種表面形狀量測設備,係組態以量測一基材上 所形成之一膜的一表面形狀,該設備包括: 一照射系統,係配置以使來自一光源之寬頻帶的光分 ' 裂成爲量測光及參考光,該量測光係經照射以傾斜地進入 - 該膜的一表面,該參考光係經照射以傾斜地進入一參考鏡 0 一光接收系統,係配置以使藉由該膜之該表面所反射 的該量測光以及藉由該參考鏡所反射的該參考光彼此組合 ’以及將該組合的光導至一光電轉換元件;以及 一處理單元,係組態以根據藉由該光電轉換元件所偵 測的一干涉信號而計算該膜的該表面形狀, 其中於該膜之該表面的該量測光之一入射角以及於該 參考鏡之該參考光的一入射角各者皆大於布魯斯特( Brewster)角,以及 〇 進入該基材之一表面的該量測光中所包括的S極化光 以及P極化光對於該光電轉換元件具有相同的強度。 . 2 ·如申請專利範圍第1項所述之表面形狀量測設備 ,進一步包括: 一極化調整單元,係組態以調整來自該光源之該寬頻 帶之光中所包括的s極化光與p極化光間的一強度比例, 其中該極化調整單元調整該強度比例使得進入該基材 表面的該量測光中所包括的該S極化光以及該p極化光具 有相同的強度。 -43- 200947142 3 .如申請專利範圍第2項所述之表面形狀量測設備 ,其中該照射系統包括一極化器及一相位板中的至少一者 該極化調整單元包括一驅動單元,係組態以旋轉該極 化器及該相位板中的至少一者’並且以該驅動單元而藉由 旋轉該極化器及該相位板中的至少一者調整該強度比例。 4. 一種表面形狀量測設備,係組態以量測一基材上 所形成之一膜的一表面形狀,該設備包括: 一照射系統,係配置以使來自一光源之寬頻帶的光分 裂成爲量測光及參考光,該量測光係經照射以傾斜地進入 該膜的一表面,該參考光係經照射以傾斜地進入一參考鏡 t 一光接收系統,係配置以使藉由該膜之該表面所反射 的該量測光以及藉由該參考鏡所反射的該參考光彼此組合 ,以及將該組合的光導至一光電轉換元件;以及 一處理單元,係組態以根據藉由該光電轉換元件所偵 測的一干涉信號而計算該膜的該表面形狀, 其中於該膜之該表面的該量測光之一入射角以及於該 參考鏡之該參考光的一入射角各者皆大於布魯斯特角, 該照射系統包括一第一極化器,允許呈一預定方向之 線性極化光通過,該線性極化光係包括於來自該光源的該 寬頻帶光中,以及 該光接收系統包括一第二極化器,允許呈該預定方向 之線性極化光通過,該線性極化光係包括於藉由該膜之該 -44- 200947142 表面所反射的該量測光、藉由該基材之一表面所反射的該 量測光,以及藉由該參考鏡所反射的該參考光之至少一者 中, 呈該預定方向之該線性極化光包括s極化光以及P極 - 化光。 - 5.如申請專利範圍第4項所述之表面形狀量測設備 ,其中該預定方向爲+4 5°方向或- 45°方向。 〇 6. 一種表面形狀量測設備,係組態以量測一基材上 所形成之一膜的一表面形狀,該設備包括: 一照射系統,係配置以使來自一光源之寬頻帶的光分 裂成爲量測光及參考光,該量測光係經照射以傾斜地進入 該膜的一表面,該參考光係經照射以傾斜地進入一參考鏡 t 一光接收系統,係配置以使藉由該膜之該表面所反射 的該量測光以及藉由該參考鏡所反射的該參考光彼此組合 〇 ,以及將該組合的光導至一光電轉換元件;以及 一處理單元,係組態以根據藉由該光電轉換元件所偵 -測的一干涉信號而計算該膜的該表面形狀, . 其中於該膜之該表面的該量測光之一入射角以及於該 參考鏡之該參考光的一入射角各者皆大於布魯斯特角, 該照射系統包括一第一極化器及一第一波長板,該第 一極化器允許呈一預定方向之線性極化光通過,該線性極 化光係包括於來自該光源的該寬頻帶光中,以及該第一波 長板允許已通過該第一極化器的光通過,以及 -45- 200947142 該光接收系統包括一第二波長板,允許呈該預定方向 之線性極化光通過,該線性極化光係包括於藉由該膜之該 表面所反射的該量測光、藉由該基材之一表面所反射的該 量測光,以及藉由該參考鏡所反射的該參考光之至少一者 中〇 7. 如申請專利範圍第6項所述之表面形狀量測設備 ,其中該光接收系統包括一第二極化器,允許呈該預定方 向之線性極化光通過,該線性極化光係包括於已通過該第 二波長板的光中。 8. 如申請專利範圍第6項所述之表面形狀量測設備 ,其中該第一波長板爲一 λ/4-板。 9 .如申請專利範圍第1項所述之表面形狀量測設備 ,其中相關於來自該光源之該寬頻帶光’該參考鏡之折射 率不小於1.4,但小於2.5。 10. —種曝光設備,係組態以透過一原版上的一圖案 而曝光一基材,該曝光設備包括根據申請專利範圍第1至 9項中任一項之表面形狀量測設備。 11. 一種曝光設備,係組態以透過一原版上的一圖案 而曝光一基材,該曝光設備包括·’ 一第一表面形狀量測單元,係組態以藉由照射光使其 傾斜地進入一膜之一表面以及藉由偵測來自該膜之該表面 之反射光的一位置而量測該基材上所形成之該膜的一表面 形狀;以及 根據申請專利範圍第1至9項中任一項之表面形狀量 -46 - 200947142 測設備,作爲一第二表面形狀量測單元, 該第一表面量測單元之一量測的結果係基於該第二表 面量測單元之一量測的結果而經校正。 12. —種裝置製造方法,包括: 藉由使用根據申請專利範圍第10項之曝光設備曝光 一基材;以及 顯影該曝光的基材。200947142 VII. Patent Application Range: 1 · A surface shape measuring device configured to measure a surface shape of a film formed on a substrate, the device comprising: an illumination system configured to The light-band of the broad band of the light source splits into a metering light and a reference light that is irradiated to obliquely enter a surface of the film that is irradiated to obliquely enter a reference mirror. a system configured to combine the measured light reflected by the surface of the film and the reference light reflected by the reference mirror with each other' and combine the combined light to a photoelectric conversion element; and a process a unit configured to calculate the surface shape of the film according to an interference signal detected by the photoelectric conversion element, wherein an incident angle of the measurement light on the surface of the film and the reference mirror An incident angle of the reference light is greater than a Brewster angle, and the S-polarized light and the P-polarized light included in the measurement light entering the surface of the substrate The photoelectric conversion elements have the same intensity. 2. The surface shape measuring apparatus according to claim 1, further comprising: a polarization adjusting unit configured to adjust s-polarized light included in the broadband light from the light source An intensity ratio between the p-polarized light, wherein the polarization adjustment unit adjusts the intensity ratio such that the S-polarized light and the p-polarized light included in the measurement light entering the surface of the substrate have the same strength. The surface shape measuring device according to claim 2, wherein the illumination system comprises at least one of a polarizer and a phase plate, the polarization adjusting unit comprises a driving unit, The system is configured to rotate at least one of the polarizer and the phase plate and to adjust the intensity ratio by rotating the polarizer and at least one of the phase plates with the drive unit. 4. A surface shape measuring device configured to measure a surface shape of a film formed on a substrate, the apparatus comprising: an illumination system configured to split a broad band of light from a source Forming the measurement light and the reference light, the measurement light is irradiated to obliquely enter a surface of the film, the reference light is irradiated to obliquely enter a reference mirror t-light receiving system, configured to be made by the film The measurement light reflected by the surface and the reference light reflected by the reference mirror are combined with each other, and the combined light is guided to a photoelectric conversion element; and a processing unit is configured to Calculating the surface shape of the film by an interference signal detected by the photoelectric conversion element, wherein an incident angle of the measurement light on the surface of the film and an incident angle of the reference light of the reference mirror Both are greater than the Brewster angle, and the illumination system includes a first polarizer that allows linearly polarized light in a predetermined direction to pass, the linearly polarized light system being included in the broadband light from the light source, And the light receiving system includes a second polarizer that allows linearly polarized light in the predetermined direction to pass, the linearly polarized light system including the measurement reflected by the surface of the film - 44- 200947142 The linearly polarized light in the predetermined direction, including s polarization, in at least one of light, the amount of light reflected by a surface of the substrate, and the reference light reflected by the reference mirror Light and P pole - light. 5. The surface shape measuring device according to claim 4, wherein the predetermined direction is a +45 direction or a -45 direction. 〇6. A surface shape measuring device configured to measure a surface shape of a film formed on a substrate, the apparatus comprising: an illumination system configured to light a broadband band from a light source Splitting into measuring light and reference light, the measuring light is irradiated to obliquely enter a surface of the film, the reference light is irradiated to obliquely enter a reference mirror t-light receiving system, configured to The light meter reflected by the surface of the film and the reference light reflected by the reference mirror are combined with each other, and the combined light is guided to a photoelectric conversion element; and a processing unit is configured to Calculating the surface shape of the film by an interference signal detected by the photoelectric conversion element, wherein an incident angle of the measurement light on the surface of the film and a reference light of the reference mirror Each of the incident angles is greater than a Brewster angle, and the illumination system includes a first polarizer and a first wavelength plate, the first polarizer allowing linearly polarized light in a predetermined direction to pass, the linear polarization Included in the broadband light from the light source, and the first wavelength plate allows light that has passed through the first polarizer to pass, and -45-200947142 the light receiving system includes a second wavelength plate, allowing Passing linearly polarized light of the predetermined direction, the linearly polarized light system comprising the metering light reflected by the surface of the film, the metering light reflected by a surface of the substrate, and The surface shape measuring device according to claim 6, wherein the light receiving system comprises a second polarizer, allowing the present invention to be present in at least one of the reference light reflected by the reference mirror. The linearly polarized light of the predetermined direction passes, and the linearly polarized light is included in the light that has passed through the second wavelength plate. 8. The surface shape measuring device according to claim 6, wherein the first wavelength plate is a λ/4-plate. 9. The surface shape measuring apparatus according to claim 1, wherein the refractive index of the reference mirror associated with the broadband light from the light source is not less than 1.4 but less than 2.5. 10. An exposure apparatus configured to expose a substrate through a pattern on an original plate, the exposure apparatus comprising the surface shape measuring apparatus according to any one of claims 1 to 9. 11. An exposure apparatus configured to expose a substrate through a pattern on an original plate, the exposure apparatus comprising: a first surface shape measuring unit configured to obliquely enter by illuminating light Measuring a surface shape of the film formed on the substrate by detecting a surface of a film and detecting a position of the reflected light from the surface of the film; and according to claims 1 to 9 of the patent application Any of the surface shape quantities -46 - 200947142, as a second surface shape measuring unit, the result of measuring one of the first surface measuring units is measured based on one of the second surface measuring units The result is corrected. 12. A device manufacturing method comprising: exposing a substrate by using an exposure apparatus according to claim 10; and developing the exposed substrate. -47--47-
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