TW200946607A - Resin composition used to forming color filter by inkjet method, color filter and liquid crystal display device - Google Patents

Abstract

The present invention provides a resin composition used to forming a color filter by a inkjet method which can form a pixel with good flatness but without uncoating portion. The resin composition used for forming a color filter by inkjet method is characterized in comprising (A) colorant, (B) multifunctional monomer, (C) binder resin, (D) surfactant with HLB is 10 or less, (E) organic solvent; wherein the (E) organic solvent, based on the whole organic solvent, comprising more than 70% by mass of organic solvent whose boiling is higher than 180 DEG C at 1 atm.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a resin composition for preparing a color filter used in a color liquid crystal display device or a color image pickup device element or the like by an inkjet method, having an inkjet method A color filter of a pixel pattern formed of the resin composition, and a liquid crystal display device. [Prior Art] When preparing a color filter © used in a color liquid crystal display (LCD) or the like, it is known to generally adopt a method of forming a color on a substrate or a substrate on which a light shielding layer of a desired pattern is formed in advance. The film of the radiation-sensitive composition is irradiated with radiation (hereinafter referred to as "exposure") through a photomask having a desired pattern shape, and then developed, dissolved and removed, and then post-baked using a cleaning oven or a hot plate. Pixel patterns of respective colors are formed (Patent Document 1 and Patent Document 2). However, in these methods, the formation of the pixel pattern is complicated, and there are problems such as high cost. On the other hand, an ink jet method color filter preparation method including a step of forming a tantalum colored layer using a color filter of an ink jet head, and a resin composition for an ink jet type color filter are known (Patent Literature) 3~5). In addition, it is known that a specific solvent is contained in the resin composition for a color filter in order to improve the stability of the ink, the discharge property, and the like (Patent Document 6). However, if a pixel is formed in a narrow region distinguished by an interval formed on a transparent substrate by an inkjet method, the shape of the pixel is along or near the outer edge portion of the pixel due to the affinity of the ink to the spacer surface or the like. There is a problem that a portion having a thin film thickness and a maximum portion having a film thickness on the center side of the pixel or a surface having a concavo-convex shape or the like can easily form a pixel having a non-uniform film thickness in 200946607. In addition, due to the affinity between the ink and the transparent substrate or the size of the opening region divided by the interval, there is a possibility that the ink cannot be coated in the pixel to generate an uncoated portion (also referred to as pinhole, white, white defect, etc.). )The problem. Patent Document 1: Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. [Problem to be Solved by the Invention] An object of the present invention is to provide an excellent flatness and which does not occur. The resin composition of the color filter is formed by the inkjet method of the uncoated portion of the pixels. In the inventors of the present invention, the present inventors have conducted intensive studies on a resin composition for forming a color filter by an inkjet method, and as a result, it has been found that the resin composition contains HLB 10 of 10 or less. The surfactant and the organic solvent having a boiling point of more than 180 ° C at 1 atm can obtain a resin which can form a pixel excellent in flatness without occurrence of an uncoated portion, and can be used for forming a color filter by an ink jet method. The composition thus completed the present invention. That is, the present invention provides a resin composition for forming a color filter by an inkjet method, characterized in that the resin composition contains (A) a colorant, .200946607 (B) a polyfunctional monomer, (C) The binder resin, (D) HLB値 is an intercalating agent of less than 10 Å, and (E) an organic solvent, and (E) the organic solvent is an organic solvent having a boiling point of more than 180 ° C at one atmosphere in all organic solvents. It is contained in more than 70% by mass in all organic solvents. The present invention also provides a color filter having a pixel pattern formed by using the above resin composition by an ink jet method, and a liquid crystal display device including the color filter. Advantageous Effects of Invention φ According to the resin composition of the present invention, it is possible to form a pixel which is excellent in flatness and which does not cause an uncoated portion by the ink jet method. Therefore, the resin composition of the present invention is extremely useful for the production of various color filters and liquid crystal display devices typified by color filters for color liquid crystal display devices in the electronic industry. [Embodiment] Hereinafter, the present invention will be described in detail. Resin Composition 0 - (A) Colorant - The coloring agent of the present invention is not particularly limited, and may be any of an organic pigment and an inorganic pigment. Among them, organic pigments are preferred from the viewpoints of color development and heat resistance which require ruthenium purity and high permeability. As the above-mentioned organic pigment, for example, a compound classified as a pigment in a color index (CI; issued by The Society of Dyers and Colourists) may be mentioned, and specifically, the following coloring material index (CI〇 numbered compound may be mentioned. CI Pigment Yellow 12, CI Pigment Yellow 13, CI Pigment Yellow 14, C I. 200946607 Pigment Yellow 17, CI Pigment Yellow 20, CI Pigment Yellow 24, CI Pigment Yellow 31, CI Pigment Yellow 55, C.I_Pig Yellow 83 , Cl Pigment Yellow 93, CI Pigment Yellow 109, CI Pigment Yellow 11〇, C. ί. Pigment Yellow 138, CI Pigment Yellow 139, CI Pigment Yellow βο'ο. ϊ. Pigment Yellow 153, CI Pigment Yellow 154, CI Pigment Yellow 155, CI Pigment Yellow 166, CI Pigment Yellow 168, C. Pigment Yellow 1 80, CI Pigment Yellow 21 1 ; CI Pigment Orange 36, CI Pigment Orange 43, CI Pigment Orange 51, CI Pigment Orange 61 'CI Pigment Orange 71 ; 〇C·1·Pigment Red 9, CI Pigment Red 97, CI Pigment Red 122, CI Pigment Red 123, CI Pigment Red 149, C. I·Pigment Red 166, CI Pigment Red 168, CI Pigment Red 175'cr Pigment Red 176, c〗 Pigment Red 177, c. I, Pigment Red 180, c_I. Pigment Red 185, C. I·Yan Red 207, CI Pigment Red 208, C·Pigment Red 209, c. 〗 Pigment Red 215, c. 〗 Pigment Red 224, CI Pigment Red 242, C_I. Pigment Red 243, CI Pigment Red 254; C_I. Pigment Violet 19 , C. I·Pigment Violet 23, C. I·Pigment Violet 29; c·I·Pigment Blue 1 5, CI Pigment Blue 60, c·〗 Pigment Blue 丨 5:3, © C. L Pigment Blue 15:4 , CI Pigment Blue 15:6; c_I·Pigment Green 7, CI Pigment Green 36, CI Pigment Green 58, CI Pigment Green 136, CI Pigment Green 210: C···Pigment 23, C. I·Pigment Brown 25 The organic pigments may be used singly or in combination of two or more. In the present invention, the 'organic pigments' may be purified by recrystallization, reprecipitation, solvent washing, sublimation, vacuum heating or a combination thereof. The above inorganic pigments are, for example, titanium oxide, barium sulfate, calcium carbonate, fresh white, sulfuric acid boat, yellow bell, zinc yellow, iron oxide red [red iron oxide (ΙΠ)], 200946607 cadmium red, ultramarine blue, Prussian blue, chromium oxide Green, cobalt green, amber, titanium black, synthetic iron black, carbon black, etc. These inorganic pigments may be used singly or in combination of two or more. In the present invention, one or more dyes or natural pigments may be used in combination with the above pigments as the case may be. In the present invention, the pigment may be surface-modified with a polymer as needed. The polymer which modifies the particle surface of the pigment is, for example, a polymer described in Japanese Laid-Open Patent Publication No. Hei 8-259876, or a commercially available polymer or oligomer for dispersing various ruthenium pigments. When a pigment is used as the colorant, it is preferred to use the pigment together with a part of the component (C) to be described later, for example, with a dissolver or a rod in the presence of a dispersant and a dispersing aid added as needed in an organic solvent. A mill, a bead mill, a roll mill, or the like is pulverized, mixed, and dispersed to form a pigment dispersion liquid. The average particle diameter of the pigment in the pigment dispersion liquid thus obtained is preferably from 50 to 400 nm, more preferably from 50 to 150 nm. In order to form an image of the uncoated portion which is excellent in flatness and which does not cause an uncoated portion, it is preferred that the pigment dispersion liquid has a small reduction, preferably 200 mPa or less, more preferably 150 mPa or less. The reason may be as follows. After the resin composition is ejected into the region separated by the spacer by the ink-jet method, the droplets of the resin composition are volatilized by a heating step, and are coated while being concentrated. If the organic solvent is volatilized to some extent, but the concentration of the concentrated resin composition is small, even if the external force (gravity) is small, the droplets easily flow. As a result, the flatness is excellent and the uncoated portion is not formed. Pixels. The physical state of the resin composition which is volatilized and concentrated to some extent in the organic solvent is close to that of the pigment dispersion, so that the decrease in the pigment dispersion is reduced. 200946607 is associated with the desired effect described above. It should be noted that the enthalpy is determined by measuring the viscosity with different shear stress and using the formula of Cass on. The dispersing agent used in the preparation of the pigment dispersion liquid may be, for example, a cationic, anionic, nonionic or amphoteric dispersing agent. However, in view of obtaining a pigment dispersion having a small amount of reduced enthalpy, a polymer is preferred. Dispersant. Specific examples thereof include modified acrylate copolymers, acrylate copolymers, polyurethanes, polyesters, alkylammonium salts or phosphate salts of polymer copolymers, and cationic comb graft polymers. Here, the cationized ionic graft-shaped graft polymer refers to a structure in which a branched polymer of two or more molecules is graft-bonded to a main polymer having a plurality of basic groups (cationic functional groups) of one molecule. Examples of the polymer include a polymer composed of a polyethyleneimine having a main polymer portion and a ring-opening polymer having a branch polymer portion of ε-caprolactone. Among these dispersants, preferred are modified acrylate-based copolymers, polyurethanes, and cationic comb-shaped graft polymers. The above dispersants are commercially available. For example, modified acrylate copolymers are: Disperbyk-2000, Disperbyk-200 1 (above, prepared by BYK © Company), polyamine vinegar: Disperbyk-1 6 1 , Disperbyk- 1 62, Disperbyk-165, Disperbyk-167, Disperbyk-170,

Disperbyk-182 (prepared by BYK Corporation), cationic comb-shaped graft polymers are, for example, Solsperse 24000, Solsperse 37000, Solsperse 56000, Solsperse 7 6 5 0 0 (manufactured by Lubrizol Co., Ltd.), AJISPER PB821, AJISPER PB822, AJISPER PB 823, AJISPER PB824, AJISPER PB827, AJISPER PB880, AJISPER PB 8 81 (above, Ajiromoto Fine-Techno Co., Inc.) and the like. 200946607 The content of the dispersant in the preparation of the pigment dispersion liquid is usually 100 parts by mass or less, preferably 0.5 to 1 part by mass, per 100 parts by mass of the pigment, depending on the combination of the pigment and the dispersant to be used. The portion is further preferably from 1 to 70 parts by mass, particularly preferably from 10 to 60 parts by mass. At this time, if the content of the dispersing agent exceeds 100 parts by mass, the strength of the obtained pixel or the like may be impaired. In addition, the organic solvent to be used in the preparation of the pigment dispersion liquid is, for example, the same solvent as the organic solvent described later. © The content of the organic solvent in the preparation of the pigment dispersion liquid is usually 200 to 1,200 parts by mass based on 100 parts by mass of the pigment. Preferably, it is 300 to 1000 parts by mass. The dispersing aid used in the preparation of the above pigment dispersion liquid is, for example, a pigment derivative such as a copper phthalocyanine derivative. (B) Polyfunctional monomer - The polyfunctional monomer of the present invention is a monomer having two or more polymerizable unsaturated bonds. Examples of the polyfunctional monomer include di(meth)acrylates of alkylene glycols such as ethylene glycol and propylene glycol; di(meth)acrylates of polyalkylene glycols such as polyethylene glycol and polypropylene glycol. a poly(meth) acrylate of a ternary polyol such as glycerin, trimethylolpropane, pentaerythritol or dipentaerythritol or a dicarboxylic acid modified or alkylene oxide modified product thereof; polyester, epoxy resin Oligo(meth)acrylates such as urethane resins, alkyd resins, polyoxyl 1 resins, spiro resins, etc.; -10-.200946607 Poly-1,3-butane having hydroxyl groups at both ends a di(meth) acrylate having a polyisoprene having a hydroxyl group at both terminals and a polyhexyl vinegar having a terminal at both ends, and having a transradical polymer at both ends; or a reference [2-(methyl)] Acryloxyethyl]phosphate and the like. Among these polyfunctional monomers, poly(meth) acrylates of polyhydric alcohols having a ternary value of 3 or more, or dicarboxylic acid modified products or alkylene oxide modified products thereof, specifically, trishydroxyl is preferable. Methylpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, pentaerythritol penta(methyl) φ dipentaerythritol acrylate, dipentaerythritol hexa(meth)acrylate, The compound represented by the following formulas (1) to (4) and the like are particularly excellent in terms of strength and surface smoothness of the pixel, and it is difficult to cause turbidity and film residue on the unexposed portion of the substrate and the light shielding layer. Preferably, trimethylolpropane triacrylate, pentaerythritol triacrylate, dipentaerythritol hexaacrylate, all compounds of the following formula (1) wherein R is a hydrogen atom, and all of R in the following formula (2) are hydrogen atoms; The compound, a compound in which all X in the following formula (3) is an acryloyl group, and a compound in which all X in the following formula (4) is an acryloyl group. 〇 The above polyfunctional monomers may be used singly or in combination of two or more. 0 -11- 200946607

[In the formula (1) and the formula (2), R is each independently and represents a hydrogen atom or a methyl group]

CH2—O-t-RiQ^X

X—(-0R1-^-0——CH2——C——CH2——O—(-R1〇-)^j-X

CH2 0—^R1〇-)—X (3) (4) 200946607

|H2—0—(-R10)-^-X CH2—0—(-R10)-jpX X—(ORL^O—ch2—c—ch2—o—ch2-c-CH2—0—(-R1〇 ·)»—x CHj—O—·(-R1Of--X CH2-O—(-R1〇-)x [In the formulas (3) and (4), 'R1 is independent, and represents a vinyl group or a propylene group. Each of X is independently represented by an acryl fluorenyl group or a methacryl fluorenyl group, and m is each independently, and represents an integer of 0 to 15, and the total of each m is 2 to 35, and η is independent, and represents an integer of 0 to 15, and each η The total amount of the polyfunctional monomer of the present invention is preferably from 5 to 1,000 parts by mass, more preferably from 20 to 300 parts by mass, per 100 parts by weight of the ruthenium pigment. In this case, when the content of the polyfunctional monomer is less than 5 parts by mass, the strength or surface smoothness of the pixel tends to be lowered, and when it exceeds 1,000 parts by mass, the pigment concentration is relatively lowered, so that it is difficult to achieve the film as a film. - (c) Binder resin - The binder resin of the present invention is not particularly limited as long as it functions as a binder with respect to the (Α) coloring agent, and is preferably an alkali-soluble resin having a carboxyl group. Tejia has one An ethylenically unsaturated monomer having a carboxyl group (hereinafter referred to as "carboxyl group-containing unsaturated monomer") and other ethylenically unsaturated monomer copolymerizable therewith (hereinafter referred to as "copolymerizable unsaturated monomer") Copolymer (hereinafter referred to as "carboxyl-containing copolymer"). The carboxyl group-containing unsaturated monomer is, for example, (meth)acrylic acid, crotonic acid, (unsaturated monocarboxylic acid such as X-chloroacrylic acid or cinnamic acid; Maleic acid, maleic anhydride, fumaric acid, itaconic acid, itaconic anhydride, lime-13- 200946607 Unsaturated dicarboxylic acid such as nornic acid, citraconic anhydride, mesaconic acid or its anhydride Saturated polycarboxylic acid or its anhydride; succinic acid mono [2-(methyl) propylene oxiranyl ethyl] ester, phthalic acid [2-(methyl) propylene methoxyethyl] ester, etc. 2 yuan The above polycarboxylic acid [(meth) propylene decyloxyalkyl] ester; ω-carboxy polycaprolactone mono (meth) acrylate, a mono(meth)acrylic acid having a polymer having a carboxyhydroxy group at both terminals An ester or the like. The carboxyl group-containing unsaturated monomer may be used singly or in combination of two or more. In the present invention, a carboxyl group-containing one is used. The saturated monomer is preferably (meth) propylene succinic acid mono [2-(methyl) propylene methoxyethyl ester], ω-carboxy polycaprol (meth) acrylate, etc., particularly preferably (meth)acrylic acid. Further, the copolymerizable unsaturated monomer is, for example, fluorene-phenyl maleimide, fluorene-o-hydroxyphenyl maleimide, hydrazine-m-hydroxyphenyl maleimide, Ν-p-hydroxyphenyl cis-diimine, Ν-benzyl maleimide, Ν-cyclohexyl succinimide, Ν-amber quinone imine-3-butylene Imine benzoate, peryleneimine-4-butyleneimine butyrate, hydrazine-succinimide: maleimide hexanoate, hydrazine-succinimide Anthracene-substituted cis-diimine such as benzyl-n-butylenediamine propionate or hydrazine-(acridinyl) maleimide; styrene, α-methylstyrene, o-ethylene Toluene, m-vinylbenzene, p-vinyl toluene, p-chlorostyrene, o-methoxystyrene, oxystyrene, p-methoxystyrene, o-vinylphenol, m-ethylphenol, p-vinylphenol, P-hydroxy-α-methylstyrene, o-ethylene acid Single mono- and mono-acids, esters, succinimide, succinimide, sulphate, -6-fluorenylene, butenyl, m-m-methyl benzyl benzyl-14- 200946607 methyl ether, m-vinyl benzyl methyl ether , an aromatic vinyl compound such as p-vinylbenzyl methyl ether, o-vinylbenzyl glycidyl ether, m-vinylbenzyl glycidyl ether, p-vinylbenzyl glycidyl ether; 茚, 1- Anthracene such as methyl hydrazine; methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, n-butyl (meth) acrylate, Isobutyl (meth)acrylate, butyl (meth)acrylate, butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, 2-hydroxyl (meth)acrylate Ethyl ethyl ester, 2-hydroxypropyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate, 2·hydroxybutyl (meth)acrylate, 3-hydroxybutyl (meth)acrylate, (A) 4-hydroxybutyl acrylate, allyl methacrylate, benzyl (meth) acrylate, (meth) acrylate Hexyl ester, phenyl (meth)acrylate, 2-methoxyethyl (meth)acrylate, 2-phenoxyethyl (meth)acrylate, polyethylene glycol (n = 2 to 100) methyl ether (Meth) acrylate, polypropylene glycol (n = 2 to 1 〇〇) methyl ether (meth) acrylate, polyethylene (meth) acrylate (n = 2 to 15) ester, mono (methyl) Acrylic polypropylene glycol (n = 2~15) ester, (meth) propylene isodecyl decanoate, trimethyl (meth) acrylate [5. 2. 1_02'6]decane-8-yl ester, dicyclopentenyl acrylate, 2-hydroxy-3-phenyloxypropyl (meth)acrylate, glycerol mono(meth)acrylate, (meth)acrylic acid 4-hydroxyphenyl ester, unsaturated carboxylic acid ester such as ethylene oxide modified (meth) acrylate of p-cumylphenol; 2-aminoethyl (meth)acrylate, (meth)acrylic acid 2-Dimethylaminoethyl ester, 2-aminopropyl (meth)acrylate, 2-dimethylaminopropyl (meth)acrylate, 3-aminopropyl (meth)acrylate, ( Aminoalkyl esters of unsaturated carboxylic acids such as 3-dimethylaminopropyl methacrylate; -15- 200946607 glycidyl esters of unsaturated carboxylic acid such as glycidyl (meth)acrylate; a cyanide vinyl compound such as acrylonitrile, α-chloroacrylonitrile or divinyl cyanoethylene; (meth) acrylamide, α-chloropropenylamine, hydrazine-2-hydroxyethyl (meth) acrylamide Isounsaturated amides; vinyl acetates such as vinyl acetate, vinyl propionate, vinyl butyrate, vinyl benzoate; U vinyl methyl ether, vinyl ethyl ether Unsaturated ethers such as allyl glycidyl ether; aliphatic conjugated dienes such as 1,3-butadiene, isoprene, chloroprene; polystyrene, poly(meth)acrylic acid A macromonomer having a mono(meth)acrylinyl group at the terminal of a polymer molecular chain such as an ester, a poly(meth)acrylic acid n-butyl ester or a polyoxyalkylene. These copolymerizable unsaturated monomers may be used singly or in combination of two or more. In the present invention, the copolymerizable unsaturated monomer is preferably a fluorene-substituted maleimide, an aromatic vinyl compound, an unsaturated carboxylic acid ester, or a polymer (Methyl) propylene fluorene at the end of the molecular chain. The macromonomer of the group, etc., particularly preferably Ν-phenyl-butyleneimine, fluorene-cyclohexylmethyleneimine, styrene, α-methylstyrene, p-hydroxy-α- Methylstyrene, methyl (meth)acrylate, n-butyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, (meth)acrylic acid Allyl ester, benzyl (meth) acrylate, polyethylene glycol (η = 2~10) methyl ether (meth) acrylate, polypropylene glycol (η = 2~1 〇) methyl ether (methyl) Acrylate, mono(meth)acrylic acid polyethylene-6-16-200946607 alcohol (n=2~10) ester, mono(meth)acrylic acid polypropylene glycol (n=2~i〇) vinegar, (meth)acrylic acid Cyclopentenyl ester, glycerol mono(meth)acrylate, 4-hydroxyphenyl (meth)acrylate, ethylene oxide modified (meth)acrylic acid of p-cumylphenol , Polystyrene macromonomer, polymethyl methacrylate macromolecular monomer. Preferred specific examples of the carboxyl group-containing copolymer are: (meth)acrylic acid/N-phenylmaleimide/styrene/benzyl (meth)acrylate copolymer, 0 (meth)acrylic acid /N-m-hydroxyphenyl maleimide / styrene / benzyl (meth) acrylate copolymer '(meth)acrylic acid / N-p-carboxyphenyl maleimide / benzene Ethylene/benzyl methacrylate copolymer '(meth)acrylic acid/N-cyclohexylmethyleneimine/styrene/benzyl methacrylate copolymer^(meth)acrylic acid /N-phenyl cis-butyl diimide imine methyl styrene / benzyl (meth) acrylate copolymer ' 〇 (meth) acrylate / Ν - phenyl cis butyl bis imimine / styrene / (Meth) n-butyl acrylate copolymer, (meth)acrylic acid / fluorene-phenyl-butylene iminoimide / styrene / 2-ethylhexyl (meth) acrylate copolymer '(methyl) Acrylic acid / fluorene-phenyl cis-butyl bis-imine / p-hydroxy-α-methyl styrene / benzyl (meth) acrylate _@ copolymer '(methyl) propylene sulphuric acid / Ν-phenyl cis-butyl Di-imine/styrene/(meth) n-butyl acrylate Polymer, (meth)acrylic acid/ΝPhenyl cis-butane diimide, phenylethyl phthalate/(methyl) -17- 200946607 2-ethylhexyl acrylate copolymer, (meth)acrylic acid /N-phenyl maleimide / styrene / (meth) 2-hydroxyethyl acrylate / benzyl (meth) acrylate copolymer, (meth) acrylic acid / N-phenyl butene Diimine/styrene/benzyl (meth)acrylate/glycerol mono(meth)acrylate, (meth)acrylic acid/N-p-hydroxyphenyl maleimide/styrene/ Benzyl (meth) acrylate / glycerol mono(meth)acrylate, (meth)acrylic acid / N-phenyl maleimide / styrene / phenyl acrylate acrylate / ( 2-hydroxyethyl methacrylate/polystyrene macromonomer copolymer, (meth)acrylic acid/N-phenylbutyleneimine/styrene/phenyl (meth)acrylate/( 2-Hydroxyethyl methacrylate/polymethyl methacrylate macromolecular copolymer, (meth)acrylic acid/N-phenyl maleimide/styrene/(methyl) benzyl acrylate Ester / n-butyl (meth)acrylate / 2-Hydroxyethyl (meth)acrylate copolymer, Ο (meth)acrylic acid / N-phenyl maleimide / styrene / benzyl (meth) citrate / (meth) acrylic acid N-butyl ester / glycerol mono(meth)acrylate copolymer, (meth)acrylic acid / N-phenyl maleimide / styrene / benzyl (meth) acrylate / (meth) acrylic acid 2 _Ethylhexyl ester / 2-hydroxyethyl (meth) acrylate copolymer, (meth) acrylate / N-phenyl maleimide / phenylethyl / (methyl) propylene acid vinegar /(Methyl)propionic acid 2 -ethylhexanoacetic acid / mono(methyl)propoxy glycerol glyceride copolymer, -18- 200946607 (methyl) propylene acid / N-phenyl maleic acid Amine/styrene/(meth)acrylic acid polyethylene glycol (n=2~1〇) methyl ether/dicyclopentenyl (meth)acrylate copolymer, (meth)acrylic acid/N-phenyl cis Butyleneimine / styrene / (meth) acrylic polypropylene glycol (n = 2 ~ 1 〇) methyl ether / (meth) acrylate dicyclopentene ester copolymer, (meth) acrylic acid / N- Phenyl maleimide / styrene / (meth) acrylic polyethylene glycol (n = 2 1〇) methyl ether / dicyclopentene oxime (meth) acrylate / glycerol mono (meth) acrylate, (meth) acrylate / N-phenyl maleimide / styrene /(Methyl)acrylic acid polypropylene glycol (n = 2~1〇) methyl ether / dicyclopentenyl (meth)acrylate / glycerol mono(meth)acrylate, (meth)acrylic acid / succinic acid Mono [2-(methyl) propylene methoxyethyl ester] / N-phenyl maleimide / styrene / benzyl (meth) acrylate copolymer, (meth) acrylic acid / succinic acid Mono [2-(methyl) propylene methoxyethyl ester] / N-p-hydroxyphenyl maleimide / styrene / benzyl (meth) acrylate φ copolymer, (meth) acrylic acid /Succinic acid mono [2-(methyl) propylene methoxyethyl ester] / N-phenyl maleimide / styrene / allyl (meth) acrylate copolymer, (meth) acrylic acid /Succinic acid mono [2-(methyl) propylene methoxyethyl ester] / N-cyclohexyl maleimide / styrene / allyl (meth) acrylate copolymer, (meth) acrylic acid /succinic mono[2-(methyl)acryloxyethyl ester]/N-cyclohexyl cis-butane Iridylimine/styrene/benzyl (meth)acrylate copolymer, -19- . 200946607 (Meth)acrylic acid / succinic acid mono [2_(methyl) propylene methoxy acetate / N-phenyl maleimide / styrene / (meth) acrylate butyl vinegar / (A 2-hydroxyethyl acrylate copolymer, (meth)acrylic acid / succinic acid mono [2-(methyl) propylene methoxy acetate] / N phenyl maleimide / styrene / ( N-butyl acrylate/mono(meth)acrylate copolymer, (meth)acrylic acid/succinic acid mono[2-(methyl)propenyloxyethyl]/N-phenyl cis-butyl 2醯imino/phenylethyl/(methyl)propionic acid 2-ethylhexanoic acid D/(2-)ethyl 2-hydroxyethyl acrylate copolymer, (meth)acrylic acid/succinic acid single [2-(A) Ethyl propylene ethoxylate _] / N phenyl butyl succinimide / styrene / 2-ethylhexyl (meth) acrylate / glycerol mono (meth) acrylate copolymer, (methyl Acrylic acid/mono(meth)acrylic acid ω-carboxypolycaprolactone/N_m-hydroxyphenyl maleimide/styrene/benzyl (meth)acrylate copolymer, (meth)acrylic acid/ Omega-carboxy polycaprolactone/N-p-hydroxyl group Benzene butylenediamine/styrene/benzyl (meth)acrylate copolymer, (meth)acrylic acid/mono(meth)acrylic acid ω-carboxypolycaprolactone/Ν-phenylhhenene醯imine/styrene/benzyl (meth)acrylate/glycerol mono(meth)acrylate, (meth)acrylic acid/mono(methyl)acrylic acid ω-carboxypolycaprolactone/Ν-p-hydroxyl Phenyl maleimide / styrene / benzyl (meth) acrylate / glycerol mono (meth) acrylate, (meth) acrylate / mono (meth) acrylate ω - carboxy poly Ester/Ν-benzene-20- 200946607 cis-butenylene diimide/styrene/n-butyl (meth)acrylate/2-hydroxyethyl (meth)acrylate copolymer, (meth)acrylic acid/single (meth)acrylic acid ω-carboxypolycaprolactone / N-phenyl maleimide / styrene / n-butyl (meth) acrylate / mono (meth) glyceryl acrylate copolymer, (a Acrylic acid/mono(meth)acrylic acid ω-carboxypolycaprolactone/Ν-phenyl maleimide/styrene/2-ethylhexyl (meth)acrylate/(meth)acrylic acid Hydroxyethyl ester Copolymer, Q (meth)acrylic acid / mono(meth)acrylic acid ω·carboxypolycaprolactone / fluorene-phenyl maleimide / styrene / 2-ethylhexyl (meth) acrylate /mono (meth) acrylate copolymer, and the like. The copolymerization ratio of the carboxyl group-containing unsaturated monomer in the carboxyl group-containing copolymer is usually 5 to 50% by mass, preferably 10 to 40% by mass. In the present invention, for example, a copolymer of an unsaturated isocyanate compound such as 2-(meth)acryloxyethyl isocyanate and an unsaturated compound having a hydroxyl group such as 2-hydroxyethyl (meth)acrylate may be copolymerized. The resin G is reacted to introduce a polymerizable unsaturated bond to the branch of the binder resin. The polystyrene-reduced weight average molecular weight (hereinafter referred to as "hei") measured by gel permeation chromatography (GPC, elution solvent: tetrahydrofuran) in the present invention is usually 3,000 to 300,000, preferably In the polystyrene-converted number average molecular weight (hereinafter referred to as "Μη") which is measured by gel permeation chromatography (GPC, elution solvent: tetrahydrofuran), the binder resin in the present invention is usually 5,000 to 100,000. The ratio of Mw to Μη (Mw/Mη) of the binder resin in the present invention is preferably from 1 to 5, and more preferably from 1 to 4», in the range of from 3,000 to 60,000, preferably from 5,000 to 25,000 〇-21 to 200946607. The resin can be, for example, in a suitable solvent, in 2,2,-azobisisobutyronitrile, 2,2'-azobis(2,4-dimethylvaleronitrile), 2,2,-azo It is prepared by polymerizing (meth)acrylic acid or the like in the presence of a radical polymerization initiator such as bis(4-methoxy-2,4-dimethylvaleronitrile). As described above, the binder resin can be subjected to radical polymerization of a polymerizable unsaturated compound, followed by purification by reprecipitation using two or more organic solvents having different polarities. That is, the solution in the good solvent after polymerization may be filtered or centrifuged as needed to remove insoluble impurities, and then injected into a large amount (usually 5 to 10 times the volume of the polymer solution) of a precipitant (weak In the solvent), the copolymer is prepared by reprecipitating. At this time, among the impurities remaining in the polymer solution, the impurities dissolved in the precipitant remain in the liquid phase, and are separated from the purified copolymer (C1) or the like. The combination of the good solvent/precipitant used in the reprecipitation method is, for example, diethylene glycol monomethyl ether acetate/n-hexane, methyl ethyl ketone/n-hexane, diethylene glycol monomethyl ether acetate. / n-heptane, methyl ethyl ketone / n-heptane, and the like. The binder resin can be, for example, 2,2 azobisisobutyronitrile, 2,2'-azobis(2,4-dimethylvaleronitrile), 2,2'-azobis(4-methoxyl). -2,4-Dimethylvaleronitrile) and other radical polymerization initiators, and pyrazole-1-dithiocarboxylic acid cyano (dimethyl)methyl ester, pyrazole-1-dithiocarboxylic acid Benzyl ester, tetraethyl thiuram disulfide, bis(pyrazole-1-ylthiocarbonyl) disulfide, bis(3-methyl-pyrazol-1-ylthiocarbonyl) disulfide, double (4 -methyl-pyrazol-1-ylthiocarbonyl)disulfide, bis(5-methyl-pyrazol-1-ylthiocarbonyl) disulfide, bis(3,4,5-trimethyl-pyridyl) In the presence of a molecular weight controlling agent which acts as an initiator, such as azole_1_ylthiocarbonyl)disulfide, bis(pyrrol-1-ylthiocarbonyl)disulfide, disulfide-22-200946607 benzamidine disulfide It is prepared by subjecting each unsaturated compound as a constituent component to free radical polymerization in an inert solvent at a reaction temperature of ～150 ° C, preferably 50 to 120 t. In the present invention, the binder resin may be used singly or in combination of two or more. In the present invention, the content of the binder resin is usually 10 to 1,000 parts by mass, preferably 20 to 500 parts by mass, per 1 part by mass of the (A) colorant. 0 At this time, the total content of the binder resin is less than 10 parts by mass, for example, the storage stability of the obtained resin composition may be lowered, and when it exceeds 1,000 parts by mass, the concentration of the colorant is relatively lowered, so that it is difficult to realize as a film. The target color density. - (D) The surfactant composition having an HLB 10 of 10 or less - The resin composition of the present invention contains an interface active agent having an HLB 10 of 10 or less (hereinafter referred to as "lipophilic surfactant"). By including the above-mentioned surfactant, it is possible to form a pixel which is excellent in flatness by the ink-jet method and which does not produce an uncoated portion. In the present invention, the HLB of the surfactant is preferably from 0 to 9, more preferably from 0 to 7. Among them, the HLB 使用 used in the present invention can be obtained by a known method. The lipophilic surfactant can form a pixel having a good flatness and an uncoated portion, and from this viewpoint, a polyoxymethylene-based surfactant is preferred. The polyoxo-based surfactants are, for example, branched-modified polydimethyl siloxane, two-terminal modified polydimethyl siloxane, one terminal-modified polydimethyl siloxane, and a branch. The polydimethylsiloxane or the like modified at both ends of the chain may be, for example, a polyoxyethylene group such as a polyoxyethylene group, a polyoxyethylene polyoxypropylene group or a polyglyceryl group. More preferred polyoxo-based surfactants are: polyether-modified polydimethyl siloxanes, and particularly preferred examples are polyoxyethylene-modified polydimethyl siloxane, polyoxyethylene polymerization. Oxypropylene modified polydimethyl oxime. The above surfactants are commercially available, for example, FZ-2122 (HLB 値 = 0), FZ-2110 (HLB = 0), FZ-7006 (HLB = 2), FZ-2166 (HLB = 3), FZ- 2 1 64 (HLB = 4) ' FZ-700 1 (HLB = 5 ), FZ - 2 1 2 0 ❻ (HLB = 6) ' SH8400 (HLB = 7), FZ-7002 (HLB = 8), FZ- 21 04 (HLB = 9) (above, prepared by Dow Corning Toray) and the like. In the present invention, the lipophilic surfactant may be used singly or in combination of two or more. In the present invention, other surfactants may be used in combination with the lipophilic surfactant. The other surfactants include various surfactants such as nonionic, cationic or anionic surfactants. The content ratio of the other surfactant is preferably from 0 to 75% by mass, more preferably from 5% to 50% by mass, based on the total amount of the lipophilic surfactant Q and other surfactants. The content of the lipophilic surfactant in the resin composition of the present invention is usually 〇, relative to 100 parts by mass of the solid component other than the organic solvent, from the viewpoint of preventing generation of the uncoated portion and prevention of raw sugar on the surface of the pixel. 〇 i 〜 3 parts by mass, preferably 0. 025~1 parts by mass, further preferably 〇〇5 〇. 5 parts by mass. - (E) Organic solvent - The organic solvent in the present invention contains more than 70 - 24 to 200946607 mass%, preferably more than 80% by mass to 100% by mass, particularly preferably more than 90% in all organic solvents. The organic solvent having a boiling point of more than 180 ° C at a pressure of 1 to 100% by mass at one atmosphere, preferably an organic solvent of more than 200 ° C but not more than 290 ° C, more preferably more than 220 ° C but 280 ° An organic solvent of C or less (hereinafter referred to as "high boiling point solvent"). When the content ratio of the high-boiling point solvent is 70% by mass or less, the resin composition is easily dried, so that the ink discharge property is deteriorated, and the balance between the homogenization speed and the drying speed of the resin composition is broken, and the flatness of the obtained pixel or the tree φ The spreadability of the lipid composition on the substrate also deteriorates. The above high-boiling solvent is, for example, a diacetate such as dipropylene glycol diacetate, cesium diacetate, 3, butylene glycol ester or 1,6-hexanediol diacetate, which has two acetate structures. Organic solvent; diethylene glycol monomethyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol mono-n-propyl ether acetate, diethylene glycol monoethyl ether acetate, diethylene glycol mono-n-butyl ether Acid ester, dipropylene glycol monomethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, propylene glycol butyl ether acetate, acetic acid 3-methyl Ο -3- An organic solvent having an acetate structure such as oxybutyl ester; ethylene glycol monoisoamyl ether, ethylene glycol monohexyl ether, ethylene glycol monophenyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether , diethylene glycol mono-n-propyl ether, diethylene glycol mono-n-butyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol mono-n-propyl ether, dipropylene glycol Mono-n-butyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether, benzyl ethyl ether, dihexyl ether, diethylene glycol diethyl ether, acetone acetone, different Buddha Ketone, caproic acid, caprylic acid, 1-octanol, 1-nonanol, benzyl acetate, ethyl benzoate, diethyl oxalate, diethyl maleate, γ-butyrolactone, ethylene carbonate, carbonic acid Propylene ester, Να- 200946607 methyl sterolone and the like. Among them, from the viewpoint of the viewpoint of the resin composition, it is preferably an organic solution of a glycolic acid ester having two acetate structures, further preferably an acid ester having 2 to 6 carbon atoms, particularly preferably diacetic acid 1,3. - Butylene glycol ester. The above hydrazine boiling point solvent may be used singly or in combination of two or more kinds: In the present invention, a solvent may be combined with a high boiling point solvent. Examples of the other organic solvents include: φ alcohols such as methanol, ethanol, and benzyl alcohol; ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol glycol mono-n-butyl ether, propylene glycol monomethyl ether, and propylene glycol monoethyl Glycol monoalkyl ether; ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether ethyl n-propyl ether acetate, propylene glycol monomethyl ether acetate, propionate, 3-methoxybutyl acetate (meth)alkylene acetate such as ester; G diglyme, diethylene glycol methyl ethyl ether, tetraether; methyl ethyl ketone, cyclohexanone, 2-heptanone, 3-heptanone hydroxy-4-methylpentan-2-one), 4-hydroxy-4-methylhex-2-broth methyl lactate, ethyl lactate and other alkyl lactate; ethyl acetate, acetic acid Ester isopropyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate, ethyl propionate, n-propyl butyrate, isopropyl butyrate, ethyl orthobutyrate, ethoxy acetic acid Ethyl ester, 3-methoxypropionic acid methyl-26-dispersion stability angle agent, more preferably diethylene glycol is used in combination. Other organic mono-n-propyl ether, diethyl ether (poly) alkylate, ethylene glycol glycol monoethyl ether glycol monoalkyl ether hydrogen furan, etc., other diacetone alcohols (4-anthracene and other ketones; acetic acid Butyl ester, n-butyl acid ester, butyl butyl ester, hydroxyethyl ester, 3-methoxy group 200946607 ethyl acetate propionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, methyl pyruvate , ethyl pyruvate, n-propyl pyruvate, methyl acetate, ethyl acetate, ethyl 2-hydroxy-2-methylpropionate, methyl 2-hydroxy-3-methylbutanoate, An ester such as ethyl 2-oxobutanoate; an aromatic hydrocarbon such as toluene-xylene; a guanamine such as dimethylformamide or N,N-dimethylacetamide; and the like; From the viewpoints of solubility, pigment dispersibility, etc., 'preferably benzyl alcohol, ethylene glycol mono-n-butyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, ethylene glycol monomethyl ether acetate, propylene glycol monomethyl Ether acetate, propylene glycol monoethyl ether acetate, 3-methoxybutyl acetate, diglyme, diethylene glycol methyl ethyl ether, cyclohexanone, 2 · heptanone, 3 g Ketone, acetic acid N-butyl ester, isobutyl acetate, n-amyl formate, isoamyl acetate, 3-methoxybutyl acetate, n-butyl propionate, ethyl butyrate, isopropyl butyrate, butyric acid Butyl ester, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethyl pyruvate, etc. The above other organic solvents may be used alone or in combination of two or more. The content of the organic solvent is preferably from 5 to 35% by mass, more preferably from 1% to 35% by mass, based on the ink ejectability and storage stability of the obtained resin composition. - (F) Photopolymerization Initiator - The resin composition of the present invention can impart radiation sensitivity by blending (F) a photopolymerization initiator. The photopolymerization initiator in the present invention is visible light, Exposure of radiation such as ultraviolet rays, far ultraviolet rays, electron beams, and X-rays can produce a compound which can initiate the polymerization of the above (B) polyfunctional monomer. -27- 200946607 The above photopolymerization initiator is, for example, acetophenone. Compounds, compounds, triterpenoids, 0 - a mercapto steroid compound, a benzophenone compound, an α-diketone compound, a xanthone compound, a diazo compound, etc. In the present invention, the photopolymerization initiator may be used alone. Or the photopolymerization initiator in the invention is preferably at least one selected from the group consisting of a benzene compound, a biimidazole compound, a tri-farming compound, and a 0-fluorenyl group. In the present invention, the general content of the photopolymerization initiator is used. Is a phasor (B) polyfunctional monomer is usually 0. 01 to 120 parts by mass to 100 parts by mass. In a preferred photopolymerization initiator of the present invention, specific examples of acetophenone are: 2-hydroxy-2-methyl-1-phenylacetone-1, 2-methylthiophenyl)-2-morpholinylacetone -1, 2-benzyl-2-dimethyl|morpholinophenyl)butanone-1, 1-hydroxycyclohexyl phenyl ketone, 2,2-diphenylethyl ketone-1 and the like. G Among these acetophenones, 2-methyl-1-yl)-2-morpholinylacetone-1, 2-benzyl-2-dimethylamino-1-yl)butanone is particularly preferred -1 and so on. The above acetophenone compounds may be used singly or in combination of two or more. Specific examples of the above biimidazole compound are: 2,2 yl)-4,4',5,5'-indole (4-ethoxycarbonylphenyl phenylimido(2-bromophenyl)-4,4' ,5,5'-indole (4-ethoxycarbonylphenyl azole, 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2' -® -28-, biimidazole benzoin-like polynuclear steroids, mixed with ethyl ketone compounds, for 100-class, preferably class 1 compounds: · methyl-1-(4_I amine 1-(4-methoxy-1,2-(4-methylthiobenzene) (4-morpholinobenzene mixed above to make bis(2-chlorobenzo, 2,2'-bis)-1, 2 '-Limimidazole, 2,2'- 200946607 bis(2,4-dichlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2, 2'-bis(2,4,6-trichlorophenyl)-4,4',5,5,-tetraphenyl-1,2'-biimidazole, 2,2'-bis(2-bromobenzene) -4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2,2,-bis(2,4-dibromophenyl)-4,4',5,5 '-Tetraphenyl-1,2'-biimidazole, 2,2'-bis(2,4,6-tribromophenyl)-4,4',5,5'-tetraphenyl-1,2 '-Biimidazole, etc. Among these biimidazole compounds, one Preferred is 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2,2,-bis (2,4· Dichlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2,2'-bis(2,4,6-trichlorobenzoinyl)-4, 4',5,5'-tetraphenyl-1,2'-biimidazole, etc., particularly preferably 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl The above-mentioned biimidazole compound may be used alone or in combination of two or more. - Hydrogen donor · In the present invention, when a biimidazole compound is used as a photopolymerization initiator, it can be further improved. From the viewpoint of sensitivity, it is preferred to use a hydrogen donor as described below. ❹ "Hydrogen donor" means a compound which can supply a hydrogen atom to a radical generated by a biimidazole compound by exposure, preferably a thiol compound, An amine compound, etc. The thiol compound has a benzene ring or a heterocyclic ring as a nucleus, and has one or more, preferably 1 to 3, and more preferably 丨2 to 2 directly bonded to the mother nucleus. a compound of the base (hereinafter referred to as "thiol chloride to the stomach,"). a compound having one or more, preferably 1 to 3, and more preferably i to 2, amine groups directly bonded to the mother nucleus having a benzene ring or a hetero ring as a core (hereinafter referred to as "amine" Ammonia-like precursors -29- ° 200946607 It should be noted that these hydrogen donors may also have a sulfhydryl group and an amine group. These hydrogen donors are more specifically described below. The thiol-based hydrogen donor may have one or more benzene rings or heterocyclic rings, and may have both a benzene ring and a heterocyclic ring. When two or more of these rings are present, a fused ring may or may not be formed. Further, when the thiol-based hydrogen donor has two or more mercapto groups, as long as at least one free mercapto group remains, the remaining one or more mercapto groups may be substituted with an alkyl group, a φ aralkyl group or an aryl group, and further, At least one free thiol group may be left, that is, a structural unit having two sulfur atoms bonded via a divalent organic group such as an alkylene group or a structural unit in which two sulfur atoms are bonded in the form of a disulfide. Further, the 'thiol-based hydrogen donor may be substituted by a carboxyl group, an alkoxycarbonyl group, a substituted alkoxycarbonyl group, a phenoxycarbonyl group, a substituted phenoxycarbonyl group, a nitrile group or the like at a position other than the fluorenyl group. Specific examples of such thiol-based hydrogen donors are: 2-mercaptobenzothiazepine, 2-mercaptobenzoxazole, 2-nonylbenzimidazole, 2,5-dimercapto-purine, ι 唾 哩, 2-mercapto-2,5-dimethylaminopyridine, and the like. Among these thiol-based hydrogen donors, 'preferably 2-mercaptobenzothiazole and 2-mercaptobenzoxazole, particularly preferably 2-thiobenzene. And thiazolidine. The amine hydrogen donor may have one or more benzene rings or heterocycles, and may have both a benzene ring and a hetero ring. When there are two or more of these rings, a fused ring may or may not be formed. Further, 'one or more amine groups of the amine hydrogen donor may be substituted by an alkyl group or a group other than the amine group may be substituted with an alkoxycarbonyl group or a phenoxy group by a carboxyl group, an alkoxy group 30-200946607'. Substitution with a carbonyl group, a substituted phenoxycarbonyl group, a nitrile group or the like. Specific examples of such amine hydrogen donors are: 4,4,-bis(dimethylamino)benzophenone, 4,4,-bis(diethylamino)benzophenone, 4- Diethylaminoacetophenone, 4-dimethylaminopropiophenone, ethyl 4-dimethylaminobenzoate, 4-dimethylaminobenzoic acid, 4-dimethylaminobenzonitrile And, preferably, 4,4'-bis(dimethylamino)benzophenone, 4,4'-bis(diethylamino)benzophenone, particularly preferably 4,4'-double (Diethylamino)benzophenone. 〇 In the case of a photopolymerization initiator other than the biimidazole compound, the amine hydrogen donor also functions as a sensitizer. In the present invention, the hydrogen donor may be used singly or in combination of two or more. When one or more kinds of thiol-based hydrogen donors are used in combination with one or more kinds of amine-based hydrogen donors, the formed pixels are less likely to fall off from the substrate during development, and the pixel intensity and sensitivity are also high, which is preferable. Specific examples of preferred combinations of thiol-based hydrogen donors and amine-based hydrogen donors are: 2-mercaptobenzothiazole/4,4'-bis(dimethylamino)benzophenone, 2-mercapto Benzene Q-thiazole/4,4'-bis(diethylamino)benzophenone, 2-mercaptobenzoxazole/4,4,-bis(dimethylamino)benzophenone, Further preferred combination of 2-mercaptobenzoxazole/4,4'-bis(diethylamino)benzophenone, etc.: 2_mercaptobenzothiazole/4,4,-bis ( A particularly good combination of diethylamino)benzophenone, 2-mercaptobenzoxazole/4,4,-bis(diethylamino)benzophenone, etc.: 2·thiobenzene幷 哩 / 4,4 '-bis (diethylamino) benzophenone. In the combination of the mercaptan hydrogen donor and the amine hydrogen donor, the weight of the mercaptan hydrogen donor is preferably 1:1 to 1:4, more preferably 1:1 to - 31- 200946607 Specific examples of the above three tillage compounds are: 2,4,6-gin(trichloromethyl)-3-trimole, 2-methyl-4,6-bis(trichloromethyl)-3 - Three tillage, 2-[2-(5-methylfuran-2-yl)vinyl]-4,6-bis(trichloromethyl)-8-three tillage, 2_[2-(furan-2- Vinyl]-4,6-bis(trichloromethyl)-s-three tillage, 2-[2-(4-diethylamino-2-methylphenyl)vinyl]-4, 6-bis(trichloromethyl)-s-tripper, 2-[2-(3,4-dimethoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)-3- Tri-trap, 2-(4-methoxyphenyl)-4,6-bis(trichloromethyl)-s-triterpene, 2-(4-ethoxystyryl)-4,6-double (trichloromethyl)-s-tripper, 2-(4-n-butoxyphenyl Q-yl)-4,6-bis(trichloromethyl)-s-trisole, etc. Ploughing compounds. Among these three tillage compounds, particularly good 2-[2-(3,4-dimethoxyphenyl)vinyl]-4,6-bis(trichloromethyl)-s-three tillage. The above tritrap type compounds may be used singly or in combination of two or more. The specific example of the above 0-fluorenyl quinone compound is preferably 9. H. - an azole-based fluorene type polymerization initiator of the azole type, for example: 1-[9-ethyl-6-benzylidene -9. H. -oxazol-3-yl]-nonane-1,2-decane-2-indole-0-acetate, 1-[9-ethyl 〇-6-benzylidene-9. H. - oxazol-3-yl]-pentane-1,2-pentane-2-indole-0-acetate, 1-[9-ethyl-6-benzylidene-9. Hey. - oxazol-3-yl]-octane-1-one oxime-indole-acetate, ketene, 1-[9-ethyl-6-(2-methylbenzhydryl)-9 Hey. -oxazol-3-yl]-, 1-(0-acetamidine), ketene, 1-[9-ethyl-6-[2-methyl-4-(2,2-dimethyl-) 1,3-dioxolyl)methoxybenzylidene]-9. Hey. -oxazol-3-yl]-, 1-(0-acetamidine), 1-[9-ethyl-6-(1,3,5-trimethylbenzylidene)-9. Hey. -oxazol-3-yl]-ethane-1-one oxime-0-benzoate, 1-[9-butyl-6-(2-ethylbenzylidene)-9. Η·- oxazol-3-yl]-ethane-1-one oxime-0-benzoate, 1-[9-ethyl-6-(2-methyl-4-tetrahydropyranyl) Methoxybenzene-32- 200946607 醯基)-9. 11. -唠哩-3-yl]-B--1-keto-indole-acetate, 1_[9-ethyl-6-(2-methyl-4-tetrahydrofuranylmethoxybenzylidene) _9. Hey.  - oxazol-3-yl]-ethane-1-one oxime-0-acetate and the like. Among them, preferred ketene, 1-[9-ethyl-6-(2.methylbenzylidene)-9. Η··晴嗤-3-yl]-,l-(〇-乙 brewing), B-ketone, 1-[9-ethyl-6-[2-methyl- 4-(2,2-di Methyl-indole, 3-dioxolyl) methoxybenzimidyl]-9·Η·-carbazol-3-yl]-, 1-(〇_乙醯肟). The above-mentioned 0-fluorenyl hydrazine compound may be used alone or in combination of two or more. 〇 φ - Additive component - The resin composition in the present invention may contain various additive components as needed. The above additive components are, for example, vinyl trimethoxy decane, vinyl triethoxy decane, vinyl ginate (2-methoxyethoxy) decane, fluorenyl-(2-aminoethyl)-3-amine Propyl propyl dimethoxy decane, Ν-(2-aminoethyl)-3-aminopropyltrimethoxy decane, 3-aminopropyl triethoxy decane, 3-glycidoxy Propyltrimethoxydecane, 3-glycidoxypropylmethyldimethoxymethoxynonane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxydecane, 3·chloropropyl a adhesion promoter such as methyl dimethoxy decane, 3-chloropropyl trimethoxy decane, 3-methyl propylene methoxy propyl trimethoxy decane or 3-mercaptopropyl trimethoxy decane; Antioxidant such as 2-thiobis(4-methyl-6-tributylphenol) or 2,6-ditributylphenol; 2-(3-tert-butyl-5-methyl-2 Ultraviolet absorber such as -hydroxyphenyl)-5-chlorobenzotriazole or alkoxybenzophenone; anticoagulant such as sodium polyacrylate; -33- 200946607 1,1'-azo double (cyclohexene) Thermal radical generators such as alkyl-1-carbonitrile), 2-phenylazo-4-methoxy-2,4-dimethylvaleronitrile ; ink, performance stabilizers such as methanol, ethanol, isopropanol, n-butanol, glycerin, etc. The resin composition in the present invention may further contain a thermal acid generator or an acid crosslinking agent. The above thermal acid generator is a component which generates an acid by heating, and examples thereof include a phosphonium salt, a benzothiazole gun salt, an ammonium salt, a key salt and the like, and particularly preferably a phosphonium salt and an anthracene benzothiazole key salt. Specific examples of the above phosphonium salt are, for example, hexafluoroantimonate 4·acetamyl phenyl dimethyl hydrazine, hexafluoroarsenic acid 4-ethenyloxy phenyl dimethyl hydrazine, hexafluoroantimonic acid 4 benzyloxy group. Carbonyloxyphenyldimethylhydrazine, hexafluoroantimony 4-benzoyloxyphenyldimethylhydrazine, hexafluoroarsenic acid 4-benzylidyloxyphenyldimethylhydrazine, hexafluoro Dialkylsulfonium salts such as 3-chloro-4-ethenyloxyphenyldimethylhydrazine arsenate; 4-hydroxyphenylbenzylmethylsulfonium hexafluoroantimonate; 4·hydroxyphenylhydrazine hexafluorophosphate Benzylmethyl hydrazine, 4-ethenyloxyphenylbenzylmethyl hydrazine hexafluoroantimonate, 4-methoxyphenylbenzylmethyl hydrazine hexafluoroantimonate, 2·methyl hexafluoroantimonate 4-benzylphenylbenzylhydrazine, hexafluoroarsenic acid 3-chloro-4-hydroxyphenylbenzylmethylhydrazine and the like monobenzylphosphonium salts; hexafluoroantimonic acid 4-hydroxyphenyldibenzyl Bismuth, 4-hydroxyphenyldibenzylphosphonium hexafluorophosphate, 4-ethenyloxyphenyldibenzylhydrazine hexafluoroantimonate, 4-methoxyphenyldibenzylhydrazine hexafluoroantimonate, hexafluoro Dibenzyl sulfonium salt such as 3-chloro-4-hydroxyphenyldibenzylphosphonium arsenate or 3-methyl-4-hydroxy-5-tributylphenyldibenzylhydrazine hexafluoroantimonate ; -34- 200946607 4-hydroxyphenyl-4-methoxybenzylmethyl hydrazine hexafluorophosphate, 4-hydroxyphenyl 4-hydroxybenzyl hydrazine hexafluoroantimonate, hexafluoroantimonic acid 4- Hydroxyphenyl-4-nitro-glycolylmethyl hydrazine, 4-hydroxyphenyl-4-chlorobenzylmethyl hydrazine hexafluorophosphate, hexafluoroantimonic acid 3·methyl·4 hydroxyphenyl·4_nitrate Base benzyl methyl hydrazine, hexafluoroantimony 4-phenylphenyl-3, 5-dichlorobenzyl methyl hydrazine, hexafluoroantimonic acid 3 _ chloro-4- hydroxyphenyl _2 chlorobenzyl a substituted benzyl sulfonium salt such as a hydrazine, a 4-hydroxyphenylbenzyl-4-methoxybenzyl hydrazine hexafluorophosphate or the like. Specific examples of the above benzothiazole gun salt include a 3-benzylmercaptobenzothiazole hexafluoroantimonate, a 3-benzylbenzothiazole hexafluorophosphate, and a 3-benzylbenzoxazole hexafluoroborate. 3-(4-methoxybenzyl)benzothiazole hexafluoroantimonate, 3-benzyl-2-methylthiobenzothiazole hexafluoroantimonate, 3-benzyl-5 hexafluoroantimonate a benzyl benzothiazole key salt such as a chlorobenzothiazole gun. Among the above sulfonium salts and benzothiazole gun salts, 4-ethoxycarbonyl phenyl dimethyl hexafluoroarsenate, 4-hydroxyphenyl benzyl hydrazine hexafluoroantimonate, and hexafluoroantimonic acid 4 are preferred. -Ethyloxyphenylbenzylmethylhydrazine, 4-hydroxyphenyldibenzylhydrazine hexafluoroantimonate, 4-ethenyloxyphenyldibenzylhydrazine hexafluoroantimonate, hexafluoroantimonic acid 3- Benzyl benzothiazole gun and the like. Commercially available products of these compounds are San-Aid SI-L85, San-Aid SI-L110, San-Aid SI-L145, San-Aid SI-L150, San-Aid SI-L160 (above, Sanxin Chemical Industry ( Share) preparation). The above thermal acid generator may be used singly or in combination of two or more. The above acid crosslinking agent is preferably a compound having two or more monovalent organic groups (hereinafter, referred to as "hydroxyl (ether) group) represented by the following formula in one molecule, -CH2OR4 -35- 200946607 (wherein R4 represents a hydrogen atom or an alkyl group having usually 1 to 6, preferably 1 to 4 carbon atoms.) Further preferably, the compound having a monovalent organic group bonded to a nitrogen atom, i.e., having N a compound of -hydroxymethyl and/or N.alkoxymethyl. When the acid cross-linking agent has two or more hydroxymethyl (ether) groups in one molecule, each hydroxymethyl (ether) group may be the same or different from each other. The acid crosslinking agent is such that when the (C) binder resin has a carboxyl group, the hydroxymethyl (ether) group in the acid crosslinking agent is in the presence of an acid generated by the thermal acid generator, and the Φ (C) binder The carboxyl group in the resin reacts to form a component of the crosslinked structure. The above acid crosslinking agent is, for example, an alkoxymethylated melamine such as ruthenium, osmium, iridium, osmium, iridium, osmium hexa(alkoxymethyl)melamine, ruthenium, osmium, iridium, osmium-tetra (alkane). An alkoxymethylated glycoluril such as oxymethyl)glycoluril or the like. For the acid cross-linking agent other than the above, urea/formaldehyde resin, thiourea/formaldehyde resin, melamine/formaldehyde resin, guanamine/formaldehyde resin, benzoguanamine/formaldehyde resin, glycoluril/formaldehyde resin, polyvinyl phenol can be used. A compound obtained by introducing a hydroxymethyl (ether) group. φ These acid crosslinking agents may be used singly or in combination of two or more. Among the above acid crosslinking agents, alkoxymethylated melamines and alkoxymethylated glycolurils, and particularly preferred alkoxymethylated melamines are preferred. From the viewpoint of excellent balance of crosslinkability, heat resistance and solvent resistance, and a cured product having a low dielectric constant, it is particularly preferable to use alkoxymethylated melamine (α) and alkoxymethylation. The acid urea crosslinking agent (β) is obtained by mixing the obtained acid crosslinking agent in a ratio of mass ratio [(α)/(β)] of preferably 5/95 to 95/5, more preferably 10/90 to 90/10. - Method for Producing Resin Composition - 36-200946607 The method for producing the resin composition of the present invention is not particularly limited, and may be added by adding the above pigment dispersion liquid, (B) component, (c) component, and (D) component, and The (F) photopolymerization initiator to be added, and further an organic solvent are added, and they are prepared by mixing together in a usual manner. Color filter The color filter of the present invention is characterized by having a pixel pattern formed by an inkjet method using the resin composition of the present invention. The color filter of the present invention is extremely useful for color camera elements, color sensors, and the like, in addition to a transmissive or reflective color liquid crystal display device. The color filter of the present invention can be produced by using the resin composition of the present invention by a known ink jet method, for example, the method described in JP-A-2000-310706 or the like. Liquid crystal display 7K device The liquid crystal display device of the present invention comprises the color light-emitting sheet of the present invention. The liquid crystal display device of the present invention can adopt a suitable structure. For example, the color filter may be formed on a substrate different from the driving substrate on which the thin film transistor (TFT) is disposed, and the driving substrate and the substrate on which the color filter is formed sandwich the liquid crystal. The layer may be opposed to a structure in which a color filter is formed on the surface of the driving substrate on which the thin film transistor (TFT) is disposed, and the substrate is sandwiched between the substrate on which the ITO (indium oxide-doped indium oxide) electrode is formed. The liquid crystal layer is opposite. The latter structure has an advantage that the aperture ratio can be further improved to obtain a bright, high-definition liquid crystal display device. EXAMPLES Hereinafter, the embodiments of the present invention -37-200946607 will be further described in detail by way of examples. However, the invention is not limited by the following examples. Preparation of Colorant The following pigment dispersions (R1), (R2), (G1), (G2), (G3), (Bl), (B2), and (B3) were prepared as colorants. Modulation example 1 will be 13. 5 parts by mass as a pigment c. I. Pigment Red 254/C. I. Pigment Red 177/ C. I. Pigment Yellow 1 3 9 = 50/3 5/1 5 (mass ratio) mixture, 6. 0 parts by mass AJISPER PB821 as a dispersing agent (Aj irom〇to Fie-Techno O Co. , Inc modulation) and 80. 5 parts by mass of 1,3-butylene glycol diacetate as an organic solvent was treated with a bead mill to prepare a pigment dispersion (R1). For the obtained pigment dispersion (R1)', an E-type viscometer (made by Toki Sangyo Co., Ltd.) was used to produce RE80L at different levels of rotation (〇. 5, 1, 2, 2. 5, 4, 5, 10, 20 rpm) The viscosity was measured and the enthalpy was determined to be 128 mPa. Modulation example 2 will be 13. 5 parts by mass as a pigment c. l Pigment Red 254/c. i. Pigment Red 177/ C. I. Pigment Yellow 150 = 50/35/15 (mass ratio) mixture, 6. 0 parts by mass © Solsperse 73 500 (manufactured by Lubrizol) and 80. 5 parts by mass of diacetic acid 1,3-, butylene glycol ester as an organic solvent was treated with a bead mill to prepare a pigment dispersion liquid (R2). In the same manner as in Preparation Example 1, the enthalpy of enthalpy of the pigment dispersion (R2) was determined to be 161 mpa. Modulation example 3 will be 15. 0 parts by mass of C>1•Pigment Green 36/c. l Pigment yellow 1 50 = 50/50 (mass ratio) mixture, 6. AJISPER PB821 ( A j i ro mo t o F i e - Te c hn o C 〇 . , I nc modulation) and 79. 0 parts by mass of 13-butylene glycol diacetate as an organic solvent was treated with a bead mill -38-200946607 to prepare a pigment dispersion (G1). The deuterium enthalpy of the pigment dispersion liquid (G1) was determined in the same manner as in the preparation example, and was 86 mPa. Modulation example 4 will be 15. 0 parts by mass of CI pigment green 36/ci pigment yellow 15 〇 = 5 〇 / 5 〇 (mass ratio) mixture, 6 〇 parts by mass of Solsperse 56000 (Lubrizol) and 79 〇 mass as dispersant The 1,3 -butylene glycol diacetate as an organic solvent was treated with a bead mill to prepare a pigment dispersion (G2). With modulation examples! Similarly, the deuterium enthalpy of the pigment dispersion liquid (G2) 求出 was determined to be 1 18 mPa. Modulation example 5 will be 15. 0 parts by mass of C I•Pigment Green 36/C I Pigment Yellow 1 50 = 50/50 (mass ratio) mixture, 9 〇 parts by mass as a dispersant

DisperbykJOOl (manufactured by BYK) and 1,3-butylene glycol diacetate / propylene glycol monomethyl ether acetate as an organic solvent = 280 / 480 parts by mass treated with a bead mill 'Preparation of pigment dispersion ((}3) The precipitation enthalpy of the pigment dispersion liquid (G3) was determined to be 156 mPa in the same manner as in Preparation Example 1. 调制 Preparation Example 6 12.0 parts by mass of cI blue as a pigment 15:6/CI Pigment Violet = 90/10 (mass ratio) a mixture, 6.0 parts by mass of ajiSPER PB821 (Ajiromoto Fie-Techno Co., Inc.) as a dispersing agent, and 82.0 parts by mass of 1,3 - butanediol diacetate as an organic solvent were treated with a bead mill to prepare a pigment dispersion (B1) The precipitation enthalpy of the pigment dispersion liquid (B1) was determined to be 1 43 mPa in the same manner as in Preparation Example 1. Preparation Example 7 12.0 parts by mass of cI blue as a pigment 15:6/CI Pigment Violet-39-200946607 = 90/10 (mass ratio) mixture, 6.0 parts by mass of AJISPER PB821 (prepared by Ajiromoto Fie-Techno Co., Inc.) as a dispersing agent, and 1,3 - butanediol diacetate / propylene glycol monomethyl ether as an organic solvent Acetate = 61.0/21.0 parts by mass treated with a bead mill to prepare pigments Solution (B2) "in the same manner as in Preparation Example 1 to obtain a pigment dispersion (B2) is Zhi yield, is 164 m P a square Preparation Example 8

12.0 parts by mass of cI blue 15:6/CI pigment violet 0=9〇/1〇 (mass ratio) mixture as a pigment, 2.5 parts by mass of AnSPER PB821 (Ajiromoto Fie-Techno Co., Inc.) as a dispersing agent, and 85.5 parts by mass of 1,3-butylene glycol diacetate as an organic solvent was treated with a bead mill to prepare a pigment dispersion (B3). The deuterium enthalpy of the pigment dispersion liquid (B 3 ) was determined in the same manner as in Preparation Example 1 and found to be 268 mPa. Synthesis of binder resin To a flask equipped with a condenser and a stirrer, 3 parts by weight of 2,2'-azobisisobutyronitrile and 200 parts by weight of diethylene glycol monoethyl ether acetate were added, followed by ❹10. Parts by weight of methacrylic acid, 25 parts by weight of N-phenyl maleimide, 15 parts by weight of styrene, 40 parts by weight of diethylene glycol methyl ether methacrylate (manufactured by Oyster Oil Co., Ltd., trade name :BLEMMERr PME-10 0), 10 parts by weight of dicyclopentene acrylate and 5 parts by weight of α-methylstyrene dimer as a molecular weight modifier, and nitrogen substitution. Then, the reaction solution was heated to 80 ° C while stirring slowly, and the temperature was maintained for 5 hours to carry out polymerization to obtain a resin solution (solid content concentration = 3 1.2%). The obtained resin had Mw = 8,400 and Mn = 4,700. This resin solution was referred to as "resin solution 1". -40-200946607 Example 1 5,450 parts by mass of a pigment dispersion liquid (R1) as a coloring agent (A), and 19 parts by mass (calculated as a solid component) as a resin solution of (C) binder resin, 78 parts by mass Mixture of dipentaerythritol pentaacrylate and monoester of succinic acid, dipentaerythritol hexaacrylate and dipentaerythritol pentaacrylate as (B) polyfunctional monomer (East Asian synthesis), trade name: TO-1 3 82), 0.6 parts by mass of a polyfluorene-based surfactant FZ-2122 (manufactured by Dow Corning Toray Co., Ltd.) as component (D), and 310 parts by mass of diacetic acid as a (E) organic solvent, 1,3 - butyl The diol ester was mixed to prepare a resin composition (IJ-1). The composition is shown in Table 1. Next, the obtained resin composition was evaluated in the following manner. The evaluation results are shown in Table 2. Evaluation of viscosity The viscosity (25 ° C) of the resin composition was measured using an ELD type viscometer prepared by Tokyo Keiki Co., Ltd. Evaluation of surface tension 表面 The surface tension of the resin composition was measured using a Dynometer (manufactured by BYK-Gardner Gmb Co., Ltd.). In the glass plate, the coating and unwinding member was used to hold the resin composition and the head at 23 ° C using an ink jet apparatus Nanoprinter-1 500S (manufactured by Microjet Co., Ltd.), and was set to 25 pi per drop of ink on the glass substrate. One drop of the resin composition was sprayed on. Then, vacuum drying was carried out with 〇.2 Torr', then pre-baked on a hot plate at 9 ° C for 5 minutes, and then baked at 230 ° C for 30 minutes in a cleaning oven, thereby allowing the resin to be combined. Drying. The diameter of the droplet after drying was measured by an optical microscope ECLIPSE L200 (manufactured by Nikon Co., Ltd. - 41946060607). As a result, when the diameter was 110 pm or more, the evaluation was ◎, and when it was 85 // m or more but less than 10 10 pm, it was evaluated as 〇, and when it was 75 or more but less than 85 /im, it was evaluated as Δ, and when it was less than 75 /im, it was evaluated as Δ. X. Evaluation of the pixel flat member Using the ink jet apparatus Nanoprinter-1500S (manufactured by Microjet Co., Ltd.), the resin composition was ejected in a space of 2.0 mm, 500 mm long, and 150 pm wide, and the pixel center was dried. The nearby film thickness ❹ is 2.0 pm. The film thickness at the central portion of the pixel was measured in the width direction using α-step IQ (manufactured by KLA Tencor Co., Ltd.). Fig. 1 is a view of the pixel seen from above, and the film thickness is measured for the arrow portion of the wavy line. In this case, the maximum 値 of the film thickness is A, the film thickness at both ends of the pixel is B, C, and when A-(B + C)/2 is less than 0.25/m, it is evaluated as ◎, and is 0.25/zm or more but low. When it was 0.35, it was evaluated as 〇, and when it was 0.35 or more but less than 0.45 //m, it was evaluated as Δ, and when it was 0.45 //m or more, it was evaluated as X. Evaluation of the ink ejection member 〇 The resin composition and the head were held at 23 t using an ink jet apparatus Nanoprinter-1500S (manufactured by Microjet Co., Ltd.), and the ink ejection property was evaluated to be 25 pPa per ink. After discharging 200 parts of the resin composition, the samples were taken at intervals of 60 seconds, repeated 10 times, and then images of flying droplets during the ejection of 20,000 drops of the resin composition were obtained at a rate of 20 frames per second. Observe the image processed by the droplet image analysis system. As a result, it was evaluated as ◎ when no defective nozzle was observed in all of the 128 heads, 〇 was observed when 1 to 5 heads were observed, and Δ was observed when 6 to 10 heads were observed. In the case of 11 or more nozzles, -42-200946607 is evaluated as X» when it comes to a defective nozzle. Here, the defective nozzle refers to a case where the nozzle is clogged, the ink cannot be ejected, or the droplet splitting or the like does not fly well. Example 2 to 1-5 and Comparative Examples 1 to 7 A resin composition (IJ-2) was prepared in the same manner as in Example 1 except that the type and amount of the constituent components were changed as shown in Table 1. - (IJ-22) - Composition is shown in Table 1 respectively. Next, evaluation was carried out in the same manner as in Example 1 except that the resin composition (IJ-2)-(IJ-22) was used instead of the resin composition. . The evaluation results of Examples 2 to 15 are shown in Table 2. The evaluation results of Comparative Examples 1 to 7 are shown in Table 3. The components in Table 1 are as follows. Organic solvent 1,3-BGDA: 1,3-butylene glycol diacetate BCTAC: diethylene glycol mono-n-butyl ether acetate DPMA: dipropylene glycol monomethyl ether acetate 〇 PGMEA: propylene glycol monomethyl ether Acetate polyfunctional monomer TO- 1 3 82 : a mixture of dipentaerythritol pentaacrylate and monoester of succinic acid, dipentaerythritol hexaacrylate and dipentaerythritol pentaacetate DPHA: dipentaerythritol hexaacrylate ester surfactant FZ - 2 1 2 2 : D 〇w C 〇rning T 〇ray company's polyfluorene-based surfactant (HLB = 0) -43- .200946607 FZ-21 1 0 : Dow Corning Toray's modulated polyfluorene Oxygen surfactant (hlb = 0) L-7001 : 0〇 (:〇1'11丨1^1'〇^7 company prepared polyoxo-based surfactant (HLB=5) SH8400: Dow Corning Toray Polyurethane Surfactant (HLB = 7) FZ-2104 : Dow Corning Toray Modulated Polyoxonated Surfactant (HLB = 9) ^ FZ-7006: Dow Corning Toray Modulated Polymer Sand Oxygen Surfactant (HLB = 2) FZ-2166: Dow Corning Toray Modulated Sand Oxygen System Surfactant (HLB = 3) L-7604 : Polysilicate Surfactant Prepared by Dow CorningToray (HLB = 13) F475: Fluoride-based surfactant FZ-77 prepared by Dainippon Ink Company: Dow Corning Toray Company Polychlorinated interface Ο Active agent (HLB=11) SH 3 746: Dow Corning Toray's polysilicate surfactant (HLB=12) -44- 200946607

藏__ ο IQ 〇ο \〇· c5 ο vq ο \q Ο s ο soos vn oo vq sosoov〇o 〇ss ο soo from mm CS CS »·Η 8 CN CN ο so vo oso 8 gv〇m 8 s 8 o r- _ Jn s Erzhi SP; ilm> gt〇 r r r r r r r r r r r r r r r Oo oo oo oo CS oo 〇\ α\ Hall 酹CN OO CS 茺«—H CS οο cs oo s CS oo s CS OO CS oo CO <N oo sss id ΓΟ _ m ι i cn m ro 2 ro CO 2 CO ΓΟ 1 1 1 < 1 < 1 1 < 1 < 1 1 <: <: 1 i < 1 < 1 <; 怔mo 〇ο o 〇o rn 〇£ oosoo K o K 〇K 飨Η o HHQHH CLh H Ph Q Φ Peng painting sg pulse m 鲰m wear <π _ a\ CN ΟΝ 2 as CS wear a\ 〇\ ON RF i 艺璨发 S m 璨»—Η m ι im ι—H Weichai B 璨T—H 冢»-H m 搂m ι H 铤t—H mi ι—H Block 1—^ Flame I rub mmm 铤mmm骏mmmmmmm total mm Interest m key 鼷m ΠΕ3 um tm ^Jtn tm uni taa UQZ tXQ m Laxz lithium lithium lithium lithium Mm uxt m txrt lithium lithium m DEC Luo ss lithium fltn S5 Dm P mmmmmmm MMM whole M mmum M mmm _ o ο cn o cn v〇cn cn <3\ v〇cn i2 cn s C^is cn cn CS v〇cn s CO CS mo CO o cn o CO v〇cn S5 CN s CO <N CO mm C &lt ; <<<<<<<<<<<<<<<<<<<<<<<><<<><<>><8> 8 8 RQ n R 8 < Q 〇 RR 8 Q 〇RQ 〇骏 PQ PQ PQ PQ PQ H PQ PQ PQ PQ PQ PQ s CQ PQ PQ PQ cA PQ m PQ CQ waist 1 CO ro ro ro ro C·*) CQ CO ro ro ro ro s ro CO Ro S ro rn ro CO m _ V") v〇l〇l〇in v〇CO w-> so cn uo Sn v〇CO W"> V*i ξ 5 CS vn w-> Γ-* Wi运Wi S r- 狮φ Gong charm m *Λγ\ limit ίβ 1-( i-< CM r-( ϊ-Η o CM 〇(M 〇rH o il 〇τ—1 mt—H DQ iH CQ rH CQ CM PQ 00 CQ i—\ TH οά 1-( Pi: y—{ 〇CO 〇rH CQ ι—1 CQ 4π o rH CO CO LO CO 00 OD O iH CO 0^3 CO t>* G5 t—H iH rH rH tH t—4 τ—Η iH ϊ-Η CO U\J Cv] 1 1 1 1 1 I 1 1 1 1 1 I 1 1 1 1 m hH k—( HH ►—1 Hi tH h—( 1-3⁄4 t-^ lH ·—» 1-^ *—5 VH hH I—> »—1 * —> Hl *-> *—t Η—i »—> lH »—>>—H IH CS cn i VT) r— oo 〇\ 〇1 ( CN CO inch t〇CN i \〇 Im 匡mmii 匡 闺 闺 闺 辑 辑 辑 闺 镒镒镒镒镒镒镒Ιϋ 镒镒镒镒镒镒镒Ιϋ 镒镒镒镒镒镒镒Ιϋ 镒镒镒镒镒镒镒Ιϋ 镒镒镒镒镒镒镒Ιϋ 镒镒镒镒镒镒镒Ιϋ 镒镒镒镒镒镒镒Ιϋ 舾 舾 舾 mm face K m JJ JJ Jj aa 200946607

Example 12.3 29.5 〇〇 ◎ 10.8 26.7 〇〇Ο CO 25.5 ◎ ◎ ◎ 14.2 29.6 〇〇〇 11.2 29.4 〇 ◎ ◎ om 27.1 〇 ◎ ◎ ON 10.1 26.1 〇 <1 ◎ 00 10.3 25.7 ◎ ◎ ◎ 〇 od 29.5 〇〇〇VO 11.2 29.6 〇◎ ◎ 10.2 27.3 〇◎ ◎ inch 12.6 26.2 〇〇◎ CO ?··η o 25.5 ◎ 〇 ◎ (N 15.3 29.6 〇 ◎ 〇iH 12.5 27.0 〇 ◎ ◎ Viscosity (mPa. s) Surface Tension (mN/m) Coating spreadability on the glass surface Flatness inkjet ejection property _9 inch_200946607 ο [s] Comparative Example 7 10.8 24.9 XX < Comparative Example 6 11.1 29.8 <] < 〇Comparative Example 5 00 26.1 << X Comparative Example 4 10.5 30.1 < 3 〇 Comparative Example 3 10.5 26.1 << X Comparative Example 2 12.3 25.6 XX < Comparative Example 1 12.4 30.2 << 〇 Viscosity (mPa s) Surface tension (mN/m) Coating spreadability on the glass surface. Flatness inkjet discharge property 200946607 is 10%. It is excellent in Table 2 and Table 3. The interface composition contains HLB値 or less. And high boiling point solvent A resin composition for forming a color filter by a liquid-jet method of a pixel having a coating spreadability, an inkjet ejection property, and a pixel flatness on a glass-shaped surface. [Illustration of the Drawing] FIG. 1 shows that the pixel is flat. The evaluation position of the character. Fig. 2 shows the cross section of the pixel. @ [Description of main component symbols] None.

-48-

Claims (1)

200946607 VII. Patent Application Range: 1. A resin composition for forming a color filter by an inkjet method, characterized in that the resin composition contains (A) a colorant, (B) a polyfunctional single (C) binder resin, (D) an organic surfactant having a HLB 10 of 10 or less, and (E) an organic solvent, and (E) an organic solvent having a boiling point of more than 180 ° C at one atmosphere in an organic solvent More than 70% by mass is contained in all organic solvents. 2. The resin composition according to claim 1, wherein the (D) surfactant having an HLB Φ 値 of 10 or less is a polyoxynoxy surfactant. 3. The resin composition according to claim 1 or 2, wherein the organic solvent having a boiling point of more than 180 ° C at one atmosphere is an organic solvent having two acetate structures. The resin composition according to any one of claims 1 to 3, wherein (A) the colorant is dispersed by a mixture containing a pigment, an organic solvent and a dispersing agent to prepare a pigment dispersion liquid. The morphology of the pigment dispersion is less than 200 mPa. A color filter comprising a pixel pattern formed by an ink jet method using the resin composition according to any one of claims 1 to 4. A liquid crystal display device comprising a color filter as in claim 5 of the patent application. -49-