TW200934862A - Emulsified petroleum product - Google Patents

Emulsified petroleum product

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Publication number
TW200934862A
TW200934862A TW97136151A TW97136151A TW200934862A TW 200934862 A TW200934862 A TW 200934862A TW 97136151 A TW97136151 A TW 97136151A TW 97136151 A TW97136151 A TW 97136151A TW 200934862 A TW200934862 A TW 200934862A
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TW
Taiwan
Prior art keywords
oil
water
petroleum product
volume ratio
volume
Prior art date
Application number
TW97136151A
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Chinese (zh)
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TWI470075B (en
Inventor
Toshiharu Fukai
Takaaki Fukai
Masatoshi Fukai
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Toshiharu Fukai
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Application filed by Toshiharu Fukai filed Critical Toshiharu Fukai
Publication of TW200934862A publication Critical patent/TW200934862A/en
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Publication of TWI470075B publication Critical patent/TWI470075B/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328Oil emulsions containing water or any other hydrophilic phase

Abstract

To provide an emulsified petroleum product which can sustain the emulsified state of various kinds of petroleum products with water over a long period of time without requiring a special apparatus. A petroleum product such as light gas oil, heavy fuel oil, a petroleum-based dry solvent, kerosene, gasoline, waste oil, coal tar, (molten) asphalt kerosene, gasoline or the like is mixed under stirring with water and a vegetable oil comprising at least one member selected from among castor oil, rapeseed oil, rice oil and sunflower oil. Thus, an emulsified petroleum product capable of sustaining the emulsified state over a long time can be produced.

Description

200934862 九、發明說明 【發明所屬之技術領域】 本發明係有關使輕油、重油、石油系乾洗溶劑、廢油 、煤焦油、瀝青(已溶融者)煤油、汽油等石油製品與 水乳化而成之石油製品乳化物。 【先前技術】 φ 自過去即已知油與水乳化後所成之乳劑燃料。以往製 作乳劑燃料之技術已提案於專利文件1。專利文件中所揭 示之以往的技術係自廢油中去除夾雜物後,將廢油與水及 界面活性劑置入裝置內,使廢油與水及界面活性劑於磁場 中以高速進行混合攪拌,而製作乳劑燃料。 混合廢油與水及界面活性劑而製作之乳劑燃料,其乳 化安定期間自數小時或最多至3天左右,保持乳化狀況有 其極限。因此,使用乳劑燃料時,於上次使用至下次使用 ❹ 間若有1〜2天未使用,燃料與水便會分離,而成爲使燃燒 器本體腐蝕的原因,並發生無法點火此一問題。因此,過 去即已知之乳劑燃料必須特別注意自製造開始至使用時之 使用期限,且必須於短期間的期限內使用完畢。 乳劑燃料混合物的一個例子爲油:水:界面活性劑=7 :2: 1,被極力宣傳爲加水的極限。自過去即極力宣傳因 水的比率之增加若在此標準以上,會提早乳化的分離,及 增大蒸發潛熱而不適於實際應用。然而,實際上水的比率 超過10%而未達15%之間之乳劑燃料,於常溫的空氣中, 200934862 存在燃燒器不易點火的缺點。 爲使乳劑燃料的點火順利,思考改良燃燒器及改良燃 燒方法。燃燒器之改良認爲係具備二流體噴嘴之燃燒器。 二流體噴嘴係具備噴射點火用燃料之噴嘴,與噴射乳劑燃 料之噴嘴此二個噴嘴,於點火用燃料噴嘴點裝置有導燃器 ,再以該導燃器使乳劑燃料點火。然而即便使用具備二流 體噴嘴之燃燒器,仍無法克服乳劑燃料不易點火的缺點。 φ 另外改良燃燒方法認爲有可預先使燃燒部升溫至800°C, 再將乳劑燃料噴射至該燃燒部之方法,及使燃燒環境之溫 度爲約1600 °C,再將乳劑燃料噴射至該燃燒環境中之方法 。然而使用該等方法,必須要有高溫的燃燒部及燃燒環境 之設備,有增大設備費用之缺點。 [專利文件1]專利第3 5 1 3 6 62號 【發明內容】 G [發明欲解決之課題] 於專利文件1之技術,爲了使廢油與水以界面活性劑 使廢油與水乳化,目的爲進行磁場形成與高速攪拌之設備 爲數千萬日圓,有價格高昂之缺點。另外爲使廢油與水乳 化,必須大量使用高價的界面活性劑,會有因使用界面活 性劑而使乳劑燃料成本增加之缺點。進而,廢油與水之乳 化狀態僅能維持3天,必須於3天內使用乳劑燃料,有不 適於實際應用之缺點。 做爲乳劑燃料乳化劑之界面活性劑,被認定爲環境荷 -6 - 200934862 劑燃料而產生 來水時,會使 境。 水(混合界面 化物質進行混 殊設備,可長 時使用爲燃料 物爲目的。 係將輕油、重 (已溶融者) 或米糠油或葵 混合攪拌使石 2種類間之容 3 0 %以上,同 品與該水之合 上。本發明之 時,該植物油 經處理使分子 使其含有溶解 爾蒙。因此’會有因燃燒含界面活性劑之乳 戴奧辛之缺點。進而’使用的水爲含氯之自 含氯之油產生戴奧辛及NOX,可能會破壞環 進而爲氧化物質之油,即便與經氧化之 活性劑之水)進行混合,因係氧化物質與氧 合,而無法達到削減C Ο 2。 本發明係解決上述缺點,以提供無需特 φ 時間保持各種石油製品與水之乳化狀態,同 時,可使其進行蒸汽般燃燒之石油製品乳化 [解決課題之手段] 與本發明有關之石油製品乳化物其特徵 油、石油系乾洗溶劑、廢油、煤焦油、瀝青 中任一種石油製品與水,及蓖麻油或菜好油 花油中之至少1種油所構成之植物油,進行 © 油製品與水乳化,其中使該石油製品與該水 積比率爲100%時,該石油製品之容積比爲 時該水之容積比爲70%以下,而使該石油製 計容積爲1〇〇時,該植物油之容積爲0.3以 特徵係該石油製品與該水之合計容積爲100 之容積爲1.5以上。本發明之特徵係該水係 團變小之水。本發明之特徵係該水係經處理 氧或活性氫中至少1個之水。 如申請專利範圍第1或2項之石油製品乳化物,其中 200934862 使該石油製品與該水2種類間之容積比率爲1 〇〇%時,該 石油製品之容積比爲50%以上,該水之容積比爲50%以下 〇 與本發明有關之石油製品乳化物其特徵係將煤油與汽 油中任一種石油製品與水,及蓖麻油或菜籽油或米糠油或 葵花油中混合至少2種以上的油所構成之植物油,進行混 合攪拌使石油製品與水乳化,其中使該石油製品與該水2 φ 種類間之容積比率爲1 〇〇%時,該石油製品之容積比爲 3 0%以上,同時該水之容積比爲70%以下,而使該石油製 品與該水之合計容積爲1〇〇時,該植物油之容積爲0.3以 上。本發明之特徵係該石油製品爲煤油時,使該煤油與該 水之合計容積爲100時,該植物油之容積爲1.5以上。本 發明之特徵係使該煤油與該水2種類間之容積比率爲 100%時,該煤油之容積比爲50%以上,該水之容積比爲 5 0%以下。本發明之特徵係該水係經處理使分子團變小之 〇 水。本發明之特徵係該水係經處理使其含有溶解氧或活性 氫中至少1個之水。本發明之特徵係於蓖麻油或菜籽油或 米糠油或葵花油中混合2種以上的油所構成之該植物油中 ,使混合之2種以上植物油之全體之容積比爲100%時, 混合植物油爲2種類時之其中一種油爲30%以上,而混合 植物油爲3種類或4種類時,較少的2種類的植物油之合 計爲3 0%以上。本發明之特徵係該石油製品爲汽油時,使 該汽油與該水之合計容積爲100時,該植物油之容積爲10 以上。本發明之特徵係使該汽油與該水2種類間之容積比 200934862 率爲100%時,該汽油之容積比爲50-75%,該水之容積比 爲25〜5 0%。本發明之特徵係該水係經處理使分子團變小 之水。本發明之特徵係該水係經處理使其含有溶解氧或活 性氫中至少1個之水。本發明之特徵係於蓖麻油或菜籽油 或米糠油或葵花油中混合2種以上的油所構成之該植物油 中,使混合之2種以上植物油之全體之容積比爲100%時 ,混合植物油爲2種類時之其中一種油爲3 0%以上,而混 〇 合植物油爲3種類或4種類時,較少的2種類的植物油之 合計爲3 0 %以上。 與本發明有關之石油製品乳化物其特徵係將輕油、重 油、石油系乾洗溶劑、廢油、煤焦油、瀝青(已溶融者) 中任一種石油製品與水,及蓖麻油或菜籽油或米糠油或葵 花油中之至少1種油所構成之植物油,進行混合攪拌使石 油製品與水乳化,其中使該石油製品與該水2種類間之容 積比率爲100%時,該石油製品之容積比爲30%以上,同 G 時該水之容積比爲70%以下,而於使該石油製品與該水之 合計容積爲100時之該植物油之容積爲〇·3以上之石油製 品乳化物中,相對於該石油製品乳化物之容積爲100 ’將 容積5以上之該石油製品與〇·〇ΐ以上之該植物油進行混 合而成。本發明之特徵係該石油製品與該水之合計容積爲 100時,該植物油之容積爲1.5以上。本發明之特徵係該 水係經處理使分子團變小之水。本發明之特徵係該水係經 處理使其含有溶解氧或活性氫中至少1個之水。本發明之 特徵係使該石油製品與該水2種類間之容積比率爲100 % 200934862 時,該石油製品之容積比爲50%以上,該水之容積比爲 50%以下。 與本發明有關之石油製品乳化物之特徵係將煤油與汽 油中任一種石油製品與水,及蓖麻油或菜籽油或米糠油或 葵花油中混合2種以上的油所構成之植物油,進行混合攪 拌使該石油製品與該水乳化,其中使該石油製品與該水2 種類間之容積比爲1 0 0 %時,該石油製品之容積比爲3 0 % ❹ 以上,同時該水之容積比爲70 %以下,而於使該石油製品 與該水之合計容積爲100時之該植物油之容積爲0.3以上 之石油製品乳化物中,相對於該石油製品乳化物之容積爲 100,將容積5以上之該石油製品與0.01以上之該植物油 進行混合而成。本發明之特徵係該石油製品爲煤油時,使 該煤油與該水之合計容積爲100時,該植物油之容積爲 1 · 5以上。本發明之特徵係該水係經處理使分子團變小之 水。本發明之特徵係該水係經處理使其含有溶解氧或活性 Ο 氫中至少1個之水。本發明之特徵係使該石油製品與該水 2種類間之容積比率爲1 00%時,該石油製品之容積比爲 50%以上,該水之容積比爲50%以下。本發明之特徵係該 石油製品爲汽油時’使該汽油與該水之合計容積爲100時 ,該植物油之容積爲10以上。本發明之特徵係該水係經 處理使分子團變小之水。本發明之特徵係該水係經處理使 其含有溶解氧或活性氫中至少1個之水。本發明之特徵係 使該石油製品與該水2種類間之容積比率爲1 〇〇%時,該 石油製品之容積比爲5〇〜75%,該水之容積比爲25〜5〇%0 -10- 200934862 本發明之特徵係於蓖麻油或菜籽油或米糠油或葵 合2種以上的油所構成之該植物油中,使混合之 植物油之全體之容積比爲100%時,混合植物油ί 時之其中一種油爲3 0%以上,而混合植物油爲3 種類時,較少的2種類的植物油之合計爲30%以.200934862 IX. Description of the Invention [Technical Fields According to the Invention] The present invention relates to emulsification of petroleum products such as light oil, heavy oil, petroleum dry cleaning solvent, waste oil, coal tar, asphalt (melted) kerosene, gasoline, and the like. Petroleum product emulsion. [Prior Art] φ An emulsion fuel obtained by emulsification of oil and water has been known since the past. Previous techniques for making emulsion fuels have been proposed in Patent Document 1. The prior art disclosed in the patent document removes inclusions from waste oil, and then puts waste oil, water and surfactant into the device, so that the waste oil and water and the surfactant are mixed at high speed in a magnetic field. And make emulsion fuel. The emulsion fuel prepared by mixing waste oil with water and a surfactant has a limit of emulsification from a few hours or up to about 3 days during the emulsification stabilization period. Therefore, when using emulsion fuel, if it is not used for 1 to 2 days between the last use and the next use, the fuel and water will separate, which will cause corrosion of the burner body, and the problem of failure to ignite occurs. . Therefore, emulsion fuels that have been known in the past must pay particular attention to the period of use from the time of manufacture to the time of use, and must be used within a short period of time. An example of an emulsion fuel mixture is oil: water: surfactant = 7:2: 1, which is strongly promoted as the limit of water addition. Since the past, it has been strongly promoted that the increase in the ratio of water, if it is above this standard, will result in the separation of early emulsification and the increase of latent heat of evaporation, which is not suitable for practical use. However, in fact, the ratio of water exceeds 10% and the emulsion fuel is less than 15%. In normal air, 200934862 has the disadvantage that the burner is not easy to ignite. In order to smooth the ignition of the emulsion fuel, consider improving the burner and improving the combustion method. The improvement of the burner is considered to be a burner with a two-fluid nozzle. The two-fluid nozzle is provided with a nozzle for injecting the fuel for ignition, and two nozzles for spraying the fuel of the emulsion, and a pilot burner is provided at the ignition nozzle point of the ignition, and the emulsion fuel is ignited by the pilot burner. However, even if a burner having a two-fluid nozzle is used, the disadvantage that the emulsion fuel is not easily ignited cannot be overcome. φ In addition, the improved combustion method considers that the combustion portion can be heated to 800 ° C in advance, the emulsion fuel is injected to the combustion portion, and the temperature of the combustion environment is about 1600 ° C, and the emulsion fuel is injected thereto. The method of burning the environment. However, the use of such methods requires the presence of a high-temperature combustion unit and a combustion environment, which has the disadvantage of increasing the cost of the equipment. [Patent Document 1] Patent No. 3 5 1 3 6 62 [Summary of the Invention] G [Problem to be Solved by the Invention] In the technique of Patent Document 1, in order to emulsifie waste oil and water with a surfactant by using waste oil and water, The purpose of the equipment for magnetic field formation and high-speed agitation is tens of millions of yen, which has the disadvantage of high price. Further, in order to emulsification of waste oil and water, it is necessary to use a large amount of a high-priced surfactant, and there is a disadvantage that the cost of the emulsion fuel is increased by the use of the interface active agent. Further, the emulsified state of the waste oil and water can only be maintained for 3 days, and the emulsion fuel must be used within 3 days, which has disadvantages that are not suitable for practical use. As a surfactant for emulsion fuel emulsifiers, it is considered to be environmentally charged when -6 - 200934862 fuel is produced. Water (mixed interface materials for mixing equipment, long-term use for fuel purposes. The light oil, heavy (melted) or rice bran oil or sunflower mixed to make the content of the stone 2 kinds of more than 30% The same product is combined with the water. At the time of the present invention, the vegetable oil is treated to cause the molecule to contain melamine. Therefore, there is a disadvantage of burning the dioxin-containing milk containing the surfactant. Chlorine-derived chlorine-containing oils produce dioxin and NOx, which may damage the ring and become an oxidizing substance oil, even if mixed with the oxidized active agent), because the oxidizing substance is oxygenated, it cannot be reduced. Ο 2. The present invention solves the above-mentioned drawbacks, and provides an emulsification of petroleum products which can be subjected to steam-like combustion without special φ time, and at the same time, emulsification of petroleum products which can be steam-likely burned [means for solving the problem] emulsification of petroleum products related to the present invention a vegetable oil composed of at least one of a characteristic oil, a petroleum-based dry cleaning solvent, a waste oil, a coal tar, a bitumen, and at least one oil of castor oil or vegetable oil, and is made of oil products and Water emulsification, wherein when the ratio of the petroleum product to the water product is 100%, the volume ratio of the petroleum product is 70% or less of the volume ratio of the water, and when the petroleum production volume is 1 Torr, The volume of the vegetable oil is 0.3, and the volume in which the total volume of the petroleum product and the water is 100 is 1.5 or more. The feature of the present invention is that the water system becomes smaller water. The invention is characterized in that the water system is treated with at least one of oxygen or active hydrogen. For example, in the petroleum product emulsion of claim 1 or 2, wherein the volume ratio of the petroleum product to the water 2 is 2009%, the volume ratio of the petroleum product is 50% or more, the water The volume ratio of the petroleum product is less than 50%. The petroleum product emulsion related to the present invention is characterized by mixing at least two kinds of petroleum products and water in kerosene and gasoline, and castor oil or rapeseed oil or rice bran oil or sunflower oil. The vegetable oil composed of the above oil is mixed and stirred to emulsify the petroleum product with water. When the volume ratio of the petroleum product to the water 2 φ species is 1%, the volume ratio of the petroleum product is 30%. In the above, the volume ratio of the water is 70% or less, and when the total volume of the petroleum product and the water is 1 Torr, the volume of the vegetable oil is 0.3 or more. The present invention is characterized in that, when the petroleum product is kerosene, when the total volume of the kerosene and the water is 100, the volume of the vegetable oil is 1.5 or more. According to a feature of the present invention, when the volume ratio between the kerosene and the water is 100%, the volume ratio of the kerosene is 50% or more, and the volume ratio of the water is 50% or less. The present invention is characterized in that the water system is treated to reduce the molecular weight of the hydrophobic water. The invention is characterized in that the water system is treated to contain at least one of dissolved oxygen or active hydrogen. The present invention is characterized in that the vegetable oil comprising two or more kinds of oils is mixed with castor oil or rapeseed oil or rice bran oil or sunflower oil, and the volume ratio of the whole of the two or more kinds of vegetable oils mixed is 100%, and the mixture is mixed. When one type of vegetable oil is 30% or more, and when the mixed vegetable oil is 3 types or 4 types, the total of the two types of vegetable oils is 30% or more. The present invention is characterized in that when the petroleum product is gasoline, when the total volume of the gasoline and the water is 100, the volume of the vegetable oil is 10 or more. The present invention is characterized in that when the volume ratio of the gasoline to the water 2 is 100%, the volume ratio of the gasoline is 50-75%, and the volume ratio of the water is 25 to 50%. A feature of the invention is that the water system is treated to reduce the molecular mass of the water. The invention is characterized in that the water system is treated to contain at least one of dissolved oxygen or active hydrogen. The present invention is characterized in that the vegetable oil comprising two or more kinds of oils is mixed with castor oil or rapeseed oil or rice bran oil or sunflower oil, and the volume ratio of the whole of the two or more vegetable oils mixed is 100%, and the mixture is mixed. When one type of vegetable oil is 30% or more, and when the mixed vegetable oil is 3 types or 4 types, the total of the two types of vegetable oils is 30% or more. The petroleum product emulsion related to the present invention is characterized in that it is any petroleum product and water of light oil, heavy oil, petroleum dry cleaning solvent, waste oil, coal tar, asphalt (melted), and castor oil or rapeseed oil. Or a vegetable oil comprising at least one oil of rice bran oil or sunflower oil, which is mixed and stirred to emulsify the petroleum product with water, wherein when the volume ratio of the petroleum product to the water type is 100%, the petroleum product The volume ratio is 30% or more, and the volume ratio of the water in the same G is 70% or less, and the volume of the vegetable oil having a volume of 100 or more of the petroleum product is 〇·3 or more. The petroleum product having a volume of 5 or more is mixed with the vegetable oil of 〇·〇ΐ or more with respect to the volume of the petroleum product emulsion. The present invention is characterized in that the volume of the vegetable oil is 1.5 or more when the total volume of the petroleum product and the water is 100. The invention is characterized in that the water system is treated to reduce the molecular mass of the water. The present invention is characterized in that the water system is treated to contain at least one of dissolved oxygen or active hydrogen. The present invention is characterized in that when the volume ratio of the petroleum product to the water type is 100% 200934862, the volume ratio of the petroleum product is 50% or more, and the volume ratio of the water is 50% or less. The petroleum product emulsion according to the present invention is characterized in that the vegetable oil consisting of any one of petroleum products and water in kerosene and gasoline, and castor oil or rapeseed oil or rice bran oil or sunflower oil is mixed. Mixing and stirring to emulsify the petroleum product with the water, wherein when the volume ratio of the petroleum product to the water type is 100%, the volume ratio of the petroleum product is more than 30% ,, and the volume of the water The ratio is 70% or less, and in the petroleum product emulsion in which the volume of the vegetable oil is 0.3 or more when the total volume of the petroleum product and the water is 100, the volume of the emulsion relative to the petroleum product is 100, and the volume is The petroleum product of 5 or more is mixed with the vegetable oil of 0.01 or more. The present invention is characterized in that, when the petroleum product is kerosene, when the total volume of the kerosene and the water is 100, the volume of the vegetable oil is 1.5 or more. A feature of the invention is that the water system is treated to reduce the molecular mass of the water. The invention is characterized in that the water system is treated to contain at least one of dissolved oxygen or active hydrogen. The present invention is characterized in that when the volume ratio of the petroleum product to the water type is 100%, the volume ratio of the petroleum product is 50% or more, and the volume ratio of the water is 50% or less. The present invention is characterized in that when the petroleum product is gasoline, when the total volume of the gasoline and the water is 100, the volume of the vegetable oil is 10 or more. The invention is characterized in that the water system is treated to reduce the molecular mass of the water. The invention is characterized in that the water system is treated to contain at least one of dissolved oxygen or active hydrogen. The present invention is characterized in that when the volume ratio of the petroleum product to the water type is 1%, the volume ratio of the petroleum product is 5 〇 to 75%, and the volume ratio of the water is 25 〜5 〇%. -10- 200934862 The present invention is characterized in that the vegetable oil is composed of castor oil or rapeseed oil or rice bran oil or two or more kinds of oils, and the vegetable oil is mixed when the volume ratio of the whole vegetable oil is 100%. One of the oils of ί is more than 30%, and when the mixed vegetable oil is 3, the total of the lesser two types of vegetable oil is 30%.

[發明的效果] © 根據與本發明有關之石油製品乳化物,因無 去爲必須之高價的界面活性劑,與過去的乳劑燃 可降低成本。另外,本發明之石油製品乳化物, 溫下可長時間保持乳化安定狀態之優點。本發明 僅利用使燃料等之石油製品與水及植物油進行混 而使燃料等之石油製品與水乳化,無須爲了乳化 場及高速攪拌裝置等特殊設備,而可低價地製造 乳化物。本發明之石油製品乳化物,因不如過去 〇 面活性劑,故不會有因燃燒而產生戴奧辛,可做 染環境之燃料。 本發明中石油製品乳化物係包含輕油、重油 汽油等各種燃料及石油系乾洗溶劑、廢油、煤焦 (已溶融者)中任一種。本發明係將爲液體之石 水(一般之水或加工水(針對加工水於後敘述) 麻油或菜籽油或米糠油或葵花油中之至少1種以 構成之植物油,進行混合攪拌而成之石油製品乳 由將液體石油製品與水及植物油進行混合攪拌, 花油中混 2種以上 ! 2種類 種類或4 需使用過 料相比, 具有於室 中,因可 合攪拌, 之形成磁 石油製品 般使用界 爲不會污 、煤油、 油、瀝青 油製品與 ),及蓖 上的油所 化物。藉 可成爲液 -11 - 200934862 體石油製品與水之乳化之石油製品乳化物,且該石油製品 乳化物可長時間保持其乳化狀態。 首先針對本發明所使用之植物油進行說明。本發明所 使用之植物油因石油製品而異,但爲蓖麻油或菜籽油或米 糠油或葵花油中之至少1種,或爲混合該等油之2種或3 種或4種者。本發明所使用之植物油其作用在於使燃料等 之液體石油製品與水乳化,且係爲了長時間維持該乳化狀 〇 態者。蓖麻油具有可長時間維持乳化狀態之優點,但爲黏 性較高者。反之菜籽油及米糠油及葵花油,與蓖麻油相比 爲黏性低者。於黏性提高時,點火溫度會變高,自燃燒器 的噴嘴的噴射速度會變慢,而成爲燃燒時的阻礙。且容易 發生燃燒器堵塞。植物油可藉由適當地選擇黏性較高的蓖 麻油與黏性較低之菜籽油或米糠油或葵花油,而可長時間 維持乳化狀態,及提升適合燃燒器之燃料的燃燒性。 進行各項實驗後,得知需因應液體石油製品之性質, © 分開使用植物油之蓖麻油或菜籽油或米糠油或葵花油。於 使用輕油、重油、石油系乾洗溶劑、廢油、煤焦油、瀝青 (已溶融者)時,可使用蓖麻油或菜籽油或米糠油或葵花 油之任何1種。亦可使用蓖麻油或菜籽油或米糠油或葵花 油中混合2種者,及可使用混合3種及4種者。另外,使 用煤油及汽油時’可使用蓖麻油或菜籽油或米糠油或葵花 油中混合任意2種者,或使用混合3種及4種者。混合蓖 麻油或菜籽油或米糠油或葵花油中2種至4種時,使混合 2種至4種所成之植物油之容積比爲100 %時,混合油爲2 -12- 200934862 種時其中一種油爲30%以上,且混合油爲3種或4種時, 較少的2種的油之合計爲3 0 %以上" 本發明中所使用之水可使用自來水等一般的水。然而 爲了助長燃燒,以使用經處理使其含有大量溶解氧(例如 接近飽和狀態値(8.4mg/l))之水爲佳。進而以使用經處 理使其含有大量活性氫(例如接近飽和狀態値(吸光度 3.0))之水爲佳。以含有大量溶解氧與活性氫者爲佳, 〇 但藉由至少含有其中之一,而可進行高效率之燃燒。 進而,該水以本身具界面活性力之水爲佳。藉由使水 之分子團變小,可使該水本身具有界面活性力。例如使水 通過由磁石產生之磁場,或使水通過電磁波,以及將超音 波導入水中,或以紫外線照射水及以遠紅外線照射水等等 ,可使水之分子團變小。使水之分子團變小之方法並未限 定於該等方法。加工水係指使分子團變小之水,及使其含 有溶解氧與活性氫等之水。本申請案中,「水」不僅爲自 ® 來水及井水等一般的水,亦包含加工水。 本申請案爲不使用界面活性劑者。水本身具界面活性 力之天然水,已知有法國的Lourdes及德國的Nordenau 之水(認爲係井水之一種),其他已知者爲與本申請案發 明者有關之專利第2889903號之水(「創生水」)。創生 水爲進而含有更多溶解氧(8_4mg/l以上),同時還含有 更多活性氫(吸光度3 · 0以上)者。使用界面活性劑時會 消滅水中所含之溶解氧,但如與本申請案同樣不使用界面 活性劑,而使用本身具界面活性力之水時,可使其大量含 -13- 200934862 有溶解氧’且可達成維持燃燒時之高溫及提升燃燒性。 【實施方式】 [實施例1] 輕油、重油、煤油、汽油、石油系乾洗溶劑、廢油、 煤焦油 '瀝青(已溶融者)等石油製品與水,及蓖麻油或 菜好油或米糠油或葵花油中之至少1種的油所構成之植物 〇 油之混合,係以依不同順序,將水與植物油加入石油製品 鐘後’再使三者進行混合攪拌爲佳。於石油製品中,加入 水或是植物油之任一種進行混合攪拌,之後,即便再加入 其他物質進行攪拌,會短暫地乳化,但乳化狀態在短時間 內便會分離。另外,一開始使水與植物油進行攪拌,即便 將該攪拌後所得者與石油製品進行混合,會短暫地乳化, 但乳化狀態在短時間內便會分離。 針對石油製品,首先說明「輕油」、「重油」、「石油 〇 系乾洗溶劑」。於輕油及重油及石油系乾洗溶劑中任一種 ,使該任一種之石油製品與水之2種類間之容積比爲 100%時,輕油及重油及石油系乾洗溶劑中任一種之石油製 品之容積比爲3 0 %以上,水之容積比爲7 0 %以下。而使石 油製品與水之合計容積爲100時,植物油之容積爲0.3以 上。石油製品爲輕油及重油及石油系乾洗溶劑時,植物油 可使用蓖麻油或菜籽油或米糠油或葵花油中任1種。或可 使用自該等4種油中混合2種以上所成的油。藉由使該等 石油製品與水及植物油進行攪拌’可製作石油製品與水進 -14- 200934862 行乳化後之石油製品乳化物。 輕油及重油與水間之容積比未達30%時,輕油及重油 變爲無法點火。而使用石油系乾洗溶劑時,與水間之容積 比未達30%時,使用於洗滌時不易洗去被洗滌物之污垢。 輕油及重油及石油系乾洗溶劑中任一種之石油製品與水間 之谷積比接近100%時,因使用水變爲無意義,而未揭示 上限之數値。另外,相對於石油製品與水之合計容積爲 〇 100’植物油之容積未達0.3時無法乳化。進而,大量混 合植物油時可使乳化安定,但大量使用植物油不利於經濟 性。將植物油之數値訂爲〇·3係因使用高價且性能佳之乳 化用混合機時,相對於石油製品與水之合計容積爲1 00, 即便植物油之容積爲0.3亦可進行乳化。 因此,使輕油及重油及石油系乾洗溶劑中任一種石油 製品(與水之2種類間之容積比例爲1 00%時之容積比爲 30%以上),與水(與石油製品之2種類間之容積比例爲 〇 100%時之容積比爲70%以下),及植物油(石油製品與水 之合計容積爲時,植物油之容積爲〇·3以上)進行混 合攪拌,石油製品與水乳化而成爲石油製品乳化物。該石 油製品乳化物可於室溫下保持約3天之乳化狀態。因可確 保3天之乳化狀態而充分適用於實際應用。 石油製品與水之合計容積爲100時之植物油之容積爲 1.5以上時,可確保3 0天之乳化狀態。且當石油製品與水 之2種類間之容積比例爲1 〇〇%時’使石油製品之容積比 爲5 0%以上,水之容積比爲50%以下時,石油製品與水及 -15- 200934862 植物油(石油製品與水之合計容積爲100時,該植物油之 容積爲0.3以上)進行混合攪拌所成之石油製品乳化物, 即便經過3 0天亦可保持安定的乳化狀態。 於本發明中,重油係指重油中混合有煤油,且重油含 量較煤油爲多者。此乃因於寒冷地區使用重油時,藉由於 重油中添加煤油,可防止重油結凍的同時,可使於寒冷地 區重油之燃燒更順利進行。同樣地於本發明中,使用混合 φ 複數種類石油製品者時,將其視爲其含量中最大容積之石 油製品。 另外,石油製品使用廢油、煤焦油、瀝青(已溶融者 ),與水(與石油製品之2種類間之容積比例爲1 00%時 之容積比爲70%以下),及植物油(石油製品與水之合計 容積爲1〇〇時,植物油之容積爲〇·3以上)進行混合攪拌 時,石油製品與水乳化而成爲石油製品乳化物。該石油製 品乳化物可於室溫下保持約3天之乳化狀態。因可確保3 〇 天之乳化狀態而充分適用於實際應用。 [實施例2] 其次針對石油製品中之「煤油」加以說明。使煤油與 水之2種類間之容積比爲100%時,煤油之容積比爲30% 以上,水之容積比爲70%以下。而使煤油與水之合計容積 爲100時,植物油之容積爲0.3以上。此時植物油可使用 混合蓖麻油或菜籽油或米糠油或葵花油中任何2種以上者 。混合蓖麻油或菜籽油或米糠油或葵花油中2種或3種時 -16- 200934862 ,使混合2種以上所成之植物油之容積比爲100%時,所 混合之油爲2種時其中一種油爲3 0%以上,所混合之油爲 3種以上時較少的2種的油合計爲3 0%以上。然而混合之 油爲2種時,以相同量(50% : 50% ),或是其差異爲 10%左右(45~5 5% : 5 5〜45% )爲佳,混合之油爲3種以上 時,以相同量(3 3 % : 3 3 % : 3 3 % ),或是其差異爲1 0 %左 右(3 0-3 6% : 3 0~3 6% : 3 0〜3 6%)爲佳。 φ 煤油與水間之容積比未達30%時,煤油變爲無法點火 。煤油與水間之容積比接近1 〇〇%時,因使用水變爲無意 義,而未揭示上限之數値。相對於煤油與水之合計容積爲 100,植物油之容積未達0.3時無法乳化。進而,大量混 合植物油時可使乳化安定,但大量使用植物油不利於經濟 性。 因此,使煤油(與水之2種類間之容積比例爲1 〇〇% 時之容積比爲3 0%以上),與水(與煤油之2種類間之容 〇 積比例爲100%時之容積比爲70%以下),及植物油(煤 油與水之合計容積爲100時,植物油之容積爲0.3以上) 進行混合攪拌,煤油與水乳化而成爲煤油乳化物。該煤油 乳化物可於室溫下保持約3天之乳化狀態。因可確保3天 之乳化狀態而充分適用於實際應用。 石油製品與水之合計容積爲1〇〇時之植物油之容積爲 1.5以上時,即便經過3天亦可保持安定的乳化狀態。且 當煤油與水之2種類間之容積比例爲1 00%時,使煤油之 容積比爲50%以上,水之容積比爲50%以下時,煤油與水 200934862 及植物油(石油製品與水之合計容積爲丨〇〇時’該植物油 之容積爲〇. 3以上)進行混合攪拌所成之石油製品乳化物 ,可確保即使經過3 0天亦能保持安定的乳化狀態。 [實施例3] 針對石油製品中之「汽油」之實驗結果加以說明。使 汽油與水之2種類間之容積比爲100%時’汽油之容積比 0 爲30%以上,水之容積比爲70%以下。而使汽油與水之合 計容積爲100時,植物油之容積爲〇.3以上。此時植物油 可使用混合蓖麻油或菜籽油或米糠油或葵花油中任何2種 或3種以上者。使混合所成之植物油全體之容積比爲 100%時,蓖麻油或菜籽油或米糠油或葵花油中之2種或3 種以上之混合比,與煤油相同。藉由使該等汽油與水及植 物油進行混合攪拌,汽油與水乳化而可製作石油製品乳化 物(汽油乳化物)。 G 汽油與水間之容積比未達30%時,汽油變爲無法點火 。汽油與水間之容積比接近100%時,因使用水變爲無意 義,而未揭示上限之數値。相對於汽油與水之合計容積爲 100,植物油之容積未達0.3時無法乳化。進而’大量混 合植物油時可使乳化安定,但大量使用植物油不利於經濟 性。 因此,使汽油(與水之2種類間之容積比例爲100% 時之容積比爲3 0%以上)’與水(與汽油之2種類間之容 積比例爲1 〇 〇 %時之容積比爲7 0 %以下)’及植物油(汽 -18- 200934862 油與水之合計容積爲100時,植物油之容積爲0·3以 進行混合攪拌,汽油與水乳化而成爲汽油乳化物。該 乳化物可於室溫下保持約3天之乳化狀態。因可確保 之乳化狀態而充分適用於實際應用。 汽油與水之合計容積爲100時之植物油之容積f 以上時,可確保60天之乳化狀態。且當汽油與水之 類間之容積比例爲100°/。時,使汽油之容積比爲5〇%_ © ,水之容積比爲25〜50%時,汽油與水及植物油(汽 水之合計容積爲100時,植物油之容積爲10以上) 混合攪拌所成之汽油乳化物,即使經過8 0天亦能保 定的乳化狀態。 [實施例4] 自實施例1至實施例3所達成之石油製品乳化 OW型乳劑,或OWO型乳劑。其次,針對將該OW型 〇 或OWO型乳劑,以WO型乳劑或WOW型乳劑取代 法進行說明。例如針對輕油進行說明。將輕油與水及 油進行攪拌後所製造之石油製品乳化物(輕油乳化物 OW型乳劑或OWO型乳劑。相對於該將輕油與水及 油進行攪拌後所製造之輕油乳化物之容積爲100,以 上之輕油,與稀少(例如〇. 〇 1以上)之植物油進行 攪拌。藉此可獲得WO型乳劑或WOW型乳劑之輕油 物。 經以輕油爲例進行說明,重油、石油系乾洗溶劑 上) 汽油 3天 I 10 2種 -75% 油與 進行 持安 物係 乳劑 之方 植物 )係 植物 5以 混合 乳化 、煤 -19- 200934862 油、汽油亦可同樣地,相對 1 〇 0,以5以上之石油製品, 合攪拌。藉此可獲得WO型( 品乳化物。 t石油製品乳化物之容積爲 $ 0.01以上之植物油進行混 劑或WOW型乳劑之石油製[Effects of the Invention] © According to the petroleum product emulsion according to the present invention, since the expensive surfactant is not necessary, the cost can be reduced by burning with the past emulsion. In addition, the petroleum product emulsion of the present invention has the advantage of maintaining an emulsified stable state for a long period of time. In the present invention, a petroleum product such as a fuel is mixed with water and vegetable oil to emulsify a petroleum product such as a fuel and water, and it is not necessary to manufacture an emulsion at a low cost without special equipment such as an emulsifying field or a high-speed stirring device. Since the petroleum product emulsion of the present invention is inferior to the surfactant in the past, it does not cause dioxin due to combustion, and can be used as a fuel for the environment. The petroleum product emulsion of the present invention comprises any of various fuels such as light oil and heavy oil gasoline, and petroleum-based dry cleaning solvents, waste oil, and coal char (already melted). The present invention relates to a vegetable oil composed of at least one of sesame oil or rapeseed oil or rice bran oil or sunflower oil, which is a mixture of liquid water (generally water or processed water (described later for processing water)). The petroleum product milk is prepared by mixing liquid petroleum products with water and vegetable oil, and mixing two or more kinds of flower oils; 2 kinds of types or 4 need to use materials, compared with the use of materials, in the room, because of the agitation, the formation of magnetic oil The product-like use is not contaminated, kerosene, oil, bitumen oil products and), and oil on the raft. It can be used as a emulsified petroleum product emulsion of liquid petroleum products and water, and the petroleum product emulsion can maintain its emulsified state for a long time. First, the vegetable oil used in the present invention will be described. The vegetable oil to be used in the present invention varies depending on the petroleum product, but is at least one of castor oil or rapeseed oil or rice bran oil or sunflower oil, or two or three or four kinds of these oils. The vegetable oil used in the present invention functions to emulsify a liquid petroleum product such as a fuel with water, and to maintain the emulsified state for a long period of time. Castor oil has the advantage of maintaining an emulsified state for a long period of time, but is highly viscous. Conversely, rapeseed oil, rice bran oil and sunflower oil are less sticky than castor oil. When the viscosity is increased, the ignition temperature is increased, and the ejection speed of the nozzle from the burner is slowed, which is an obstacle to combustion. And the burner is prone to blockage. The vegetable oil can maintain the emulsified state for a long period of time and improve the flammability of the fuel suitable for the burner by appropriately selecting the viscous ricin oil and the less viscous rapeseed oil or rice bran oil or sunflower oil. After conducting various experiments, it was learned that depending on the nature of the liquid petroleum products, © separate use of vegetable oil in castor oil or rapeseed oil or rice bran oil or sunflower oil. When using light oil, heavy oil, petroleum-based dry cleaning solvent, waste oil, coal tar, or asphalt (melted), you can use either castor oil or rapeseed oil or rice bran oil or sunflower oil. You can also use castor oil or rapeseed oil or rice bran oil or sunflower oil to mix two kinds, and you can use three or four kinds. In addition, when using kerosene and gasoline, you can use either castor oil or rapeseed oil, rice bran oil or sunflower oil, or mix 3 or 4 types. When two or four kinds of castor oil or rapeseed oil or rice bran oil or sunflower oil are mixed, when the volume ratio of the mixed vegetable oil of 2 to 4 is 100%, when the mixed oil is 2 -12- 200934862 When one of the oils is 30% or more, and the mixed oil is three or four types, the total of the two less oils is more than 30%. The water used in the present invention may be water such as tap water. However, in order to promote combustion, it is preferred to use water which has been treated to contain a large amount of dissolved oxygen (e.g., near saturated state 8.4 (8.4 mg/l)). Further, it is preferred to use water which is treated to contain a large amount of active hydrogen (e.g., near saturation 値 (absorbance 3.0)). It is preferred to contain a large amount of dissolved oxygen and active hydrogen, but by containing at least one of them, high-efficiency combustion can be performed. Further, the water is preferably water having an interface active force. By making the molecular group of water smaller, the water itself can have an interfacial activity. For example, water can be made smaller by passing water through a magnetic field generated by a magnet, or passing water through an electromagnetic wave, and introducing ultrasonic waves into water, or irradiating water with ultraviolet rays and irradiating water with far infrared rays. The method of making the molecular group of water smaller is not limited to these methods. The process water refers to water which makes the molecular group smaller, and contains water such as dissolved oxygen and active hydrogen. In the present application, "water" is not only general water such as water and well water, but also processed water. This application is for those who do not use a surfactant. Water itself is a natural water with an interfacial activity, known as Lourdes in France and Nordenau in Germany (a type of well water), and other known as patent No. 2889903 related to the inventor of the present application. Water ("Creation Water"). The water for creation is further containing more dissolved oxygen (8_4mg/l or more) and more active hydrogen (absorbance of 3 · 0 or more). When the surfactant is used, the dissolved oxygen contained in the water is eliminated, but if the surfactant is not used as in the present application, when the water having the surfactant is used, the large amount of dissolved oxygen can be contained in the range of -13 to 200934862. 'It is also possible to maintain the high temperature during combustion and improve the flammability. [Embodiment] [Example 1] Petroleum products and water such as light oil, heavy oil, kerosene, gasoline, petroleum-based dry cleaning solvent, waste oil, coal tar 'asphalt (already melted), and castor oil or vegetable oil or rice bran The mixing of the plant eucalyptus oil composed of at least one of the oil or the sunflower oil is preferably carried out by adding the water and the vegetable oil to the petroleum product clock in a different order. In the petroleum product, water or vegetable oil is added and mixed, and then, even if other substances are added and stirred, the emulsion is temporarily emulsified, but the emulsified state is separated in a short time. Further, the water and the vegetable oil are initially stirred, and even if the obtained product is mixed with the petroleum product, the mixture is temporarily emulsified, but the emulsified state is separated in a short time. For petroleum products, first explain "light oil", "heavy oil", and "oil dry cleaning solvent". Any one of light oil, heavy oil and petroleum-based dry cleaning solvents, such as light oil and heavy oil and petroleum-based dry cleaning solvent, when the volume ratio between the petroleum product and the water is 100%. The volume ratio is more than 30%, and the volume ratio of water is 70% or less. When the total volume of the petroleum product and the water is 100, the volume of the vegetable oil is 0.3 or more. When petroleum products are light oil and heavy oil and petroleum-based dry cleaning solvents, vegetable oil may be either castor oil or rapeseed oil or rice bran oil or sunflower oil. Alternatively, an oil obtained by mixing two or more kinds of these four kinds of oils may be used. By emulating the petroleum products with water and vegetable oils, it is possible to produce petroleum products and water-incorporated emulsified petroleum product emulsions. When the volume ratio of light oil and heavy oil to water is less than 30%, light oil and heavy oil become impossible to ignite. When a petroleum-based dry cleaning solvent is used, when the volume ratio to water is less than 30%, it is difficult to wash off the dirt of the laundry during washing. When the ratio of petroleum products to water in any one of light oil and heavy oil and petroleum dry cleaning solvents is close to 100%, the use of water becomes meaningless, and the upper limit is not revealed. Further, the total volume of the petroleum product and the water is 〇100'. When the volume of the vegetable oil is less than 0.3, the emulsification cannot be achieved. Further, when a large amount of vegetable oil is mixed, the emulsion can be stabilized, but the use of vegetable oil in a large amount is not economically advantageous. When the amount of the vegetable oil is 〇·3, the total volume of the petroleum product and the water is 100%, and the volume of the vegetable oil is 0.3, and the emulsification can be performed even if the volume of the vegetable oil is 0.3. Therefore, the petroleum product (the volume ratio of the light oil and the petroleum-based dry cleaning solvent is 30% or more when the volume ratio between the two types of water is 100%), and the water (with 2 types of petroleum products). When the volume ratio of the volume is 〇100%, the volume ratio is 70% or less), and the vegetable oil (when the total volume of the petroleum product and the water is ,·3 or more), the petroleum product and the water are emulsified. Become a petroleum product emulsion. The petroleum product emulsion can be maintained in an emulsified state for about 3 days at room temperature. It is fully suitable for practical use because it can ensure the emulsified state for 3 days. When the volume of the vegetable oil having a total volume of petroleum products and water of 100 is 1.5 or more, the emulsified state for 30 days can be ensured. And when the volume ratio between the petroleum product and the water type is 1%%, 'when the volume ratio of the petroleum product is more than 50%, and the volume ratio of water is 50% or less, the petroleum product and water and -15- 200934862 Vegetable oil (when the total volume of petroleum products and water is 100, the volume of the vegetable oil is 0.3 or more) The petroleum product emulsion obtained by mixing and stirring can maintain a stable emulsified state even after 30 days. In the present invention, heavy oil means that kerosene is mixed with heavy oil, and the content of heavy oil is more than that of kerosene. This is due to the fact that when heavy oil is used in cold areas, the addition of kerosene to heavy oil prevents heavy oil from freezing and allows heavy oil to burn more smoothly in cold regions. Also in the present invention, when a mixture of φ plural kinds of petroleum products is used, it is regarded as the largest volume of petroleum product in its content. In addition, petroleum products use waste oil, coal tar, asphalt (melted), and water (volume ratio of 70% or less when the volume ratio between the two types of petroleum products is 100%), and vegetable oil (petroleum products) When the total volume of water is 1 ,, the volume of the vegetable oil is 〇·3 or more. When mixing and stirring, the petroleum product is emulsified with water to become an emulsion of petroleum products. The petroleum product emulsion can be maintained in an emulsified state for about 3 days at room temperature. It is fully applicable to practical applications because it ensures an emulsified state of 3 days. [Example 2] Next, the "kerosene" in petroleum products will be described. When the volume ratio between the two types of kerosene and water is 100%, the volume ratio of kerosene is 30% or more, and the volume ratio of water is 70% or less. When the total volume of kerosene and water is 100, the volume of the vegetable oil is 0.3 or more. At this time, vegetable oil may be used in any combination of castor oil or rapeseed oil or rice bran oil or sunflower oil. When two or three kinds of castor oil or rapeseed oil or rice bran oil or sunflower oil are mixed, 16-200934862, when the volume ratio of the vegetable oil mixed with two or more kinds is 100%, when the mixed oil is two kinds One of the oils is 30% or more, and when the oil to be mixed is three or more types, the total of the two types of oils is 30% or more. However, when the mixed oil is two kinds, the same amount (50%: 50%), or the difference is about 10% (45~5 5%: 5 5~45%), and the mixed oil is three kinds. Above, the same amount (3 3 % : 3 3 % : 3 3 % ), or the difference is about 10% (3 0-3 6% : 3 0~3 6% : 3 0~3 6% ) is better. When the volume ratio of φ kerosene to water is less than 30%, kerosene becomes unfired. When the volume ratio between kerosene and water is close to 1%, the use of water becomes meaningless, and the upper limit is not revealed. The total volume of kerosene and water is 100, and the volume of vegetable oil is less than 0.3 and cannot be emulsified. Further, when a large amount of vegetable oil is mixed, the emulsion can be stabilized, but the use of vegetable oil in a large amount is not economically advantageous. Therefore, the volume ratio of kerosene (volume ratio when the volume ratio between the two types of water is 1%% is 30% or more), and the volume when the volume of water (the volume ratio between the two types of kerosene is 100%) is 100%. When the ratio is 70% or less, and the vegetable oil (the total volume of the kerosene and water is 100, the volume of the vegetable oil is 0.3 or more), the mixture is stirred and the kerosene and the water are emulsified to form a kerosene emulsion. The kerosene emulsion can be maintained in an emulsified state for about 3 days at room temperature. It is fully suitable for practical use because it ensures an emulsified state for 3 days. When the volume of the vegetable oil when the total volume of the petroleum product and the water is 1 is 1.5 or more, the stable emulsified state can be maintained even after 3 days. And when the volume ratio between the two types of kerosene and water is 100%, the volume ratio of kerosene is 50% or more, and when the volume ratio of water is 50% or less, kerosene and water 200934862 and vegetable oil (petroleum products and water) When the total volume is 丨〇〇, the volume of the vegetable oil is 〇. 3 or more, and the petroleum product emulsion obtained by mixing and stirring can ensure a stable emulsified state even after 30 days. [Example 3] The experimental results of "petrol" in petroleum products are explained. When the volume ratio between the two types of gasoline and water is 100%, the volume ratio of gasoline is 0% or more, and the volume ratio of water is 70% or less. When the combined volume of gasoline and water is 100, the volume of the vegetable oil is 〇.3 or more. At this time, any two or more of the mixed oil of castor oil or rapeseed oil or rice bran oil or sunflower oil may be used as the vegetable oil. When the volume ratio of the whole vegetable oil to be mixed is 100%, the mixing ratio of two or more kinds of castor oil or rapeseed oil or rice bran oil or sunflower oil is the same as that of kerosene. By blending and stirring the gasoline with water and vegetable oil, the gasoline and water are emulsified to produce a petroleum product emulsion (gasoline emulsion). G When the volume ratio of gasoline to water is less than 30%, the gasoline becomes unfired. When the volume ratio between gasoline and water is close to 100%, the use of water becomes meaningless, and the upper limit is not revealed. The total volume of gasoline and water is 100. When the volume of vegetable oil is less than 0.3, it cannot be emulsified. Further, when a large amount of vegetable oil is mixed, the emulsion can be stabilized, but the use of vegetable oil in a large amount is not economical. Therefore, when the volume ratio of gasoline (the volume ratio of the volume ratio between the two types of water is 100% is 30% or more) and the volume ratio of water to the volume of the two types of gasoline is 1%, the volume ratio is 70% or less) and vegetable oil (Vapor 18-200934862 When the total volume of oil and water is 100, the volume of vegetable oil is 0.3% for mixing and stirring, and gasoline and water are emulsified to become a gasoline emulsion. The emulsion can be It is kept in an emulsified state at room temperature for about 3 days, and is sufficiently suitable for practical use because it can be ensured in an emulsified state. When the volume of vegetable oil of the total volume of gasoline and water is 100 or more, the emulsified state for 60 days can be ensured. And when the volume ratio between gasoline and water is 100 ° /, when the volume ratio of gasoline is 5% _ _, the volume ratio of water is 25 to 50%, the total of gasoline and water and vegetable oil (soda When the volume is 100, the volume of the vegetable oil is 10 or more. The gasoline emulsion obtained by mixing and stirring can be in an emulsified state even after 80 days. [Example 4] The oil obtained from Examples 1 to 3 Emulsified OW emulsion, or OWO emulsion. Next, the OW type 〇 or OOW type emulsion is described by a WO type emulsion or a WOW type emulsion replacement method. For example, the light oil is described. The petroleum product emulsion obtained by stirring the light oil with water and oil (Light oil emulsion OW type emulsion or OOW type emulsion. The light oil emulsion produced by mixing light oil with water and oil has a volume of 100 or more, and is light (for example, 〇. 〇 The vegetable oil of 1 or more is stirred, thereby obtaining a light oil of WO type emulsion or WOW type emulsion. The light oil is taken as an example, heavy oil, petroleum type dry cleaning solvent) Gasoline 3 days I 10 2 kinds-75 % oil and plant-based emulsion plant 5) mixed emulsified, coal -19-200934862 oil, gasoline, similarly, with 1 〇 0, with 5 or more petroleum products, stirred. In this way, a WO type (product emulsion) can be obtained. The vegetable oil of a volume of the petroleum product emulsion of more than 0.01 is used as a mixture or a petroleum compound of WOW type emulsion.

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Claims (1)

200934862 十、申請專利範圍 1. 一種石油製品乳化物,其特徵係將輕油、重油、石 油系乾洗溶劑、廢油、煤焦油、瀝青(已溶融者)中任一 種石油製品與水,及蓖麻油或菜籽油或米糠油或葵花油中 之至少1種油所構成之植物油,進行混合攪拌使石油製品 與水乳化,其中使該石油製品與該水2種類間之容積比率 爲100%時,該石油製品之容積比爲30%以上,同時該水 〇 之容積比爲70%以下,而使該石油製品與該水之合計容積 爲100時,該植物油之容積爲0.3以上。 2 .如申請專利範圍第1項之石油製品乳化物,其中使 該石油製品與該水之合計容積爲100時,該植物油之容積 爲1 . 5以上。 3 .如申請專利範圍第1或2項之石油製品乳化物,其 中該水係經處理使分子團變小之水。 4. 如申請專利範圍第1或2項之石油製品乳化物,其 Ο 中該水係經處理使其含有溶解氧或活性氫中至少1個之水 〇 5. 如申請專利範圍第1或2項之石油製品乳化物,其 中使該石油製品與該水2種類間之容積比率爲1 〇〇%時, 該石油製品之容積比爲50%以上’該水之容積比爲50%以 下。 6. —種石油製品乳化物’其特徵係將煤油與汽油中任 1種石油製品與水,及蓖麻油或菜籽油或米糠油或葵花油 中混合2種以上的油所構成之植物油’進行混合攪拌使該 200934862 石油製品與水乳化,其中使該石油製品與該水2種類間之 容積比率爲100%時,該石油製品之容積比爲30%以上’ 同時該水之容積比爲70 %以下,而使該石油製品與該水之 合計容積爲時,該植物油之容積爲0.3以上。 7.如申請專利範圍第6項之石油製品乳化物,其中該 石油製品爲煤油時,使該煤油與該水之合計容積爲100時 ,該植物油之容積爲1.5以上。 © 8.如申請專利範圍第7項之石油製品乳化物,其中使 該煤油與該水2種類間之容積比率爲1 00%時,該煤油之 容積比爲50%以上,該水之容積比爲50%以下。 9.如申請專利範圍第7或8項之石油製品乳化物,其 中該水係經處理使分子團變小之水。 1 〇 .如申請專利範圍第7或8項之石油製品乳化物, 其中該水係經處理使其含有溶解氧或活性氫中至少1個之 水。 〇 1 1 .如申請專利範圍第7或至8項之石油製品乳化物 ,其中於蓖麻油或菜籽油或米糠油或葵花油中混合2種以 上的油所構成之該植物油中,使混合2種以上植物油之全 體之容積比爲100%時,混合植物油爲2種類時之其中1 種油爲30%以上,而混合植物油爲3種類或4種類時’較 少的2種類的植物油之合計爲30%以上。 12.如申請專利範圍第6項之石油製品乳化物’其中 該石油製品爲汽油時,使該汽油與該水之合計容積爲 時,該植物油之容積爲1〇以上。 -22- 200934862 1 3 .如申請專利範圍第1 2項之石油製品乳化物’其中 使該汽油與該水2種類間之容積比率爲100%時’該汽油 之容積比爲50〜75%,該水之容積比爲25〜50%。 1 4.如申請專利範圍第1 2或1 3項之石油製品乳化物 ,其中該水係經處理使分子團變小之水。 1 5 .如申請專利範圍第1 2或1 3項之石油製品乳化物 ,其中該水係經處理使其含有溶解氧或活性氫中至少1個 ❹ 之水。 1 6 .如申請專利範圍第1 2或至1 3項之石油製品乳化 物,其中於蓖麻油或菜籽油或米糠油或葵花油中混合2種 以上的油所構成之該植物油中,使混合2種以上植物油之 全體之容積比爲100%時,混合植物油爲2種類時之其中 一種油爲30%以上,而混合植物油爲3種類或4種類時’ 較少的2種類的植物油之合計爲30%以上。 17.—種石油製品乳化物,其特徵係將輕油、重油、 〇 石油系乾洗溶劑、廢油、煤焦油、瀝青(已溶融者)中任 一種石油製品與水,及蓖麻油或菜籽油或米糠油或葵花油 中之至少1種的油所構成之植物油,進行混合攪拌使石油 製品與水乳化,其中使該石油製品與該水2種類間之容積 比率爲100%時,該石油製品之容積比爲30%以上’同時 該水之容積比爲70%以下’而於使該石油製品與該水之合 計容積爲1〇〇時之該植物油之容積爲〇.3以上之石油製品 乳化物中,相對於該石油製品乳化物之容積爲1 0 〇,將容 積5以上之該石油製品與0.01以上之該植物油進行混合 -23- 200934862 而成。 18. 如申請專利範圍第17項之石油製品乳化物,其中 使該石油製品與該水之合計容積爲100時,該植物油之容 積爲1 .5以上。 19. 如申請專利範圍第17或18項之石油製品乳化物 ,其中該水係經處理使分子團變小之水。 20. 如申請專利範圍第17或18項之石油製品乳化物 〇 ’其中該水係經處理使其含有溶解氧或活性氫中至少1個 之水。 21. 如申請專利範圍第17或18項之石油製品乳化物 ,其中使該石油製品與該水2種類間之容積比率爲1 00% 時,該石油製品之容積比爲5 0%以上,該水之容積比爲 5 0 %以下。 22. —種石油製品乳化物,其特徵係將煤油與汽油中 任一種石油製品與水,及蓖麻油或菜籽油或米糠油或葵花 Ο 油中混合2種以上的油所構成之植物油,進行混合攪拌使 該石油製品與該水乳化,其中使該石油製品與該水2種類 間之容積比率爲100%時,該石油製品之容積比爲30%以 上,同時該水之容積比爲70%以下,而於使該石油製品與 該水之合計容積爲100時之該植物油之容積爲0.3以上之 石油製品乳化物中,相對於該石油製品乳化物之容積爲 100,將容積5以上之該石油製品與0.01以上之該植物油 進行混合而成。 23. 如申請專利範圍第22項之石油製品乳化物,其中 -24 - 200934862 該石油製品爲煤油時’使該煤油與該水之合計容積爲100 時,該植物油之容積爲1.5以上。 24. 如申請專利範圍第22或23項之石油製品乳化物 ,其中該水係經處理使分子團變小之水。 25. 如申請專利範圍第22或23項之石油製品乳化物 ,其中該水係經處理使其含有溶解氧或活性氫中至少1個 之水。 〇 26.如申請專利範圍第22或23項之石油製品乳化物 ,其中使該石油製品與該水2種類間之容積比率爲1〇〇% 時,該石油製品之容積比爲5 0 %以上,該水之容積比爲 50%以下。 27. 如申請專利範圍第22項之石油製品乳化物,其中 該石油製品爲汽油時,使該汽油與該水之合計容積爲1 00 時,該植物油之容積爲10以上。 28. 如申請專利範圍第22或27項之石油製品乳化物 ® ,其中該水係經處理使分子團變小之水。 29. 如申請專利範圍第22或27項之石油製品乳化物 ,其中該水係經處理使其含有溶解氧或活性氫中至少1個 之水。 3 0.如申請專利範圍第22或27項之石油製品乳化物 ,其中使該石油製品與該水2種類間之容積比率爲1 00% 時,該石油製品之容積比爲50〜75%,該水之容積比爲 25~50% ° 3 1.如申請專利範圍第22或27項之石油製品乳化物 -25- 200934862 ,其中於蓖麻油或菜籽油或米糠油或葵衣 上的油所構成之該植物油中,使混合之: 全體之容積比爲100%時,混合植物油爲 —種油爲30%以上,而混合植物油爲3| 較少的2種類的植物油之合計爲30%以J: 油中混合2種以 種以上植物油之 2種類時之其中 類或4種類時,200934862 X. Patent application scope 1. An oil product emulsion characterized by any petroleum product and water, such as light oil, heavy oil, petroleum dry cleaning solvent, waste oil, coal tar, asphalt (melted), and a vegetable oil composed of sesame oil or rapeseed oil or at least one of rice bran oil or sunflower oil, which is mixed and stirred to emulsify the petroleum product with water, wherein when the volume ratio of the petroleum product to the water is 100% The volume ratio of the petroleum product is 30% or more, and the volume ratio of the water is 70% or less. When the total volume of the petroleum product and the water is 100, the volume of the vegetable oil is 0.3 or more. 2. The oil product emulsion according to claim 1, wherein the vegetable oil has a volume of 1.5 or more when the total volume of the petroleum product and the water is 100. 3. The petroleum product emulsion according to claim 1 or 2, wherein the water is treated to make the molecular group smaller. 4. In the case of the petroleum product emulsion of claim 1 or 2, wherein the water is treated to contain at least one of dissolved oxygen or active hydrogen. 5. Claim No. 1 or 2 In the petroleum product emulsion, when the volume ratio of the petroleum product to the water type is 1%, the volume ratio of the petroleum product is 50% or more, and the volume ratio of the water is 50% or less. 6. A kind of petroleum product emulsion 'characteristic is a vegetable oil composed of kerosene and any petroleum product and water in gasoline, and castor oil or rapeseed oil or rice bran oil or sunflower oil mixed with two or more kinds of oil' Mixing and stirring to make the 200934862 petroleum product emulsify with water, wherein when the volume ratio of the petroleum product to the water type is 100%, the volume ratio of the petroleum product is 30% or more 'at the same time, the volume ratio of the water is 70%. When the volume of the petroleum product and the water is the same, the volume of the vegetable oil is 0.3 or more. 7. The petroleum product emulsion according to claim 6, wherein the petroleum product is kerosene, and when the total volume of the kerosene and the water is 100, the volume of the vegetable oil is 1.5 or more. 8. The oil product emulsion according to claim 7, wherein the volume ratio of the kerosene to the volume ratio of the kerosene is 100% or more, and the volume ratio of the water is It is 50% or less. 9. The petroleum product emulsion of claim 7 or 8, wherein the water is treated to reduce the molecular mass of the water. 1 . The petroleum product emulsion of claim 7 or 8, wherein the water is treated to contain at least one of dissolved oxygen or active hydrogen. 〇1 1 . The petroleum product emulsion of claim 7 or 8 wherein the vegetable oil consisting of castor oil or rapeseed oil or rice bran oil or sunflower oil is mixed with two or more kinds of oil to make a mixture When the volume ratio of the whole of the two or more vegetable oils is 100%, one of the two types of vegetable oils is 30% or more, and when the mixed vegetable oil is three or four types, the total of the two types of vegetable oils is less. More than 30%. 12. The petroleum product emulsion according to claim 6 wherein the petroleum product is gasoline, and the volume of the vegetable oil is 1 Torr or more when the total volume of the gasoline and the water is the same. -22- 200934862 1 3. If the volume ratio of the petroleum product to the type 2 of the water is 100%, the volume ratio of the gasoline is 50 to 75%. The volume ratio of the water is 25 to 50%. 1 4. The petroleum product emulsion of claim 12 or 13 wherein the water is treated to reduce the molecular mass of the water. A pharmaceutical product emulsion according to claim 12 or 13 wherein the water is treated to contain at least one of dissolved oxygen or active hydrogen. 1 6 . The petroleum product emulsion according to claim 12 or 13 wherein the vegetable oil comprises two or more oils mixed with castor oil or rapeseed oil or rice bran oil or sunflower oil, so that When the volume ratio of the whole of the two or more types of vegetable oil is 100%, the total amount of the vegetable oil in which the mixed vegetable oil is two types is 30% or more, and when the mixed vegetable oil is three or four types, the total of the two types of vegetable oil is less. More than 30%. 17. An oil product emulsion characterized by any one of petroleum products and water, and castor oil or rapeseed, which are light oil, heavy oil, petroleum oil dry cleaning solvent, waste oil, coal tar, asphalt (melted) a vegetable oil composed of oil or at least one of rice bran oil or sunflower oil, which is mixed and stirred to emulsify the petroleum product with water, wherein the petroleum product and the water are in a volume ratio of 100%, the petroleum The volume ratio of the product is 30% or more 'at the same time, the volume ratio of the water is 70% or less', and the petroleum product having a volume of the vegetable oil of 〇.3 or more when the total volume of the petroleum product and the water is 1 〇〇 In the emulsion, the volume of the petroleum product emulsion is 10 〇, and the petroleum product having a volume of 5 or more is mixed with 0.01 or more of the vegetable oil -23-200934862. 18. The petroleum product emulsion according to claim 17, wherein the vegetable oil has a volume of 1.5 or more when the total volume of the petroleum product and the water is 100. 19. The petroleum product emulsion of claim 17 or 18 wherein the water is treated to reduce the molecular mass of the water. 20. The petroleum product emulsion 〇' of claim 17 or 18 wherein the water is treated to contain at least one of dissolved oxygen or active hydrogen. 21. The oil product emulsion according to claim 17 or 18, wherein the volume ratio of the petroleum product to the water type is 100%, the volume ratio of the petroleum product is more than 50%, The volume ratio of water is below 50%. 22. An oil product emulsion characterized by mixing vegetable oil of any one of kerosene and gasoline with water, and castor oil or rapeseed oil or rice bran oil or sunflower oil, or a vegetable oil composed of two or more kinds of oil. Mixing and stirring to emulsifie the petroleum product with the water, wherein when the volume ratio of the petroleum product to the water type is 100%, the volume ratio of the petroleum product is 30% or more, and the volume ratio of the water is 70%. % or less, and in the petroleum product emulsion in which the volume of the vegetable oil is 0.3 or more when the total volume of the petroleum product and the water is 100, the volume of the emulsion of the petroleum product is 100, and the volume is 5 or more. The petroleum product is mixed with 0.01 or more of the vegetable oil. 23. The petroleum product emulsion according to claim 22, wherein -24 - 200934862 when the petroleum product is kerosene, the volume of the vegetable oil is 1.5 or more when the total volume of the kerosene and the water is 100. 24. The petroleum product emulsion of claim 22 or 23 wherein the water is treated to reduce the molecular mass of the water. 25. The petroleum product emulsion of claim 22, wherein the water is treated to contain at least one of dissolved oxygen or active hydrogen. 〇26. The petroleum product emulsion of claim 22 or 23, wherein the volume ratio of the petroleum product to the water type is 1%, the volume ratio of the petroleum product is more than 50% The volume ratio of the water is 50% or less. 27. The petroleum product emulsion according to claim 22, wherein the petroleum product is gasoline, and when the total volume of the gasoline and the water is 100, the volume of the vegetable oil is 10 or more. 28. The petroleum product emulsion of claim 22 or 27, wherein the water is treated to reduce the molecular mass of the water. 29. The petroleum product emulsion of claim 22 or 27, wherein the water is treated to contain at least one of dissolved oxygen or active hydrogen. 3. The oil product emulsion according to claim 22 or 27, wherein the volume ratio of the petroleum product to the water type is 100%, the volume ratio of the petroleum product is 50 to 75%, The volume ratio of the water is 25 to 50% ° 3 1. For example, the petroleum product emulsion 25-200934862 of claim 22 or 27, wherein the oil is in castor oil or rapeseed oil or rice bran oil or sunflower oil. In the vegetable oil to be mixed, when the volume ratio of the whole is 100%, the mixed vegetable oil is 30% or more, and the mixed vegetable oil is 3%, and the total of the two types of vegetable oil is 30%. J: When two or more types of two types of vegetable oils are mixed in the oil, 〇 -26- 200934862 七、指定代表圖 (一) 、本案指定代表圖為:無 (二) 、本代表圖之元件代表符號簡單說明:無〇 -26- 200934862 VII. Designation of Representative Representatives (1) The representative representative of this case is: None (2), the symbol of the representative figure of this representative figure is simple: None 八、本案若有化學式時,請揭示最能顯示發明特徵的化學 式:8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention:
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