TW200914599A - Extraction of hydrocarbons from hydrocarbon-containing materials - Google Patents

Abstract

A method of extracting hydrocarbon-containing organic matter from a hydrocarbon-containing material includes the steps of providing a first liquid comprising a turpentine liquid; contacting the hydrocarbon-containing material with the turpentine liquid to form an extraction mixture; extracting the hydrocarbon material into the turpentine liquid; and separating the extracted hydrocarbon material from a residual material not extracted.

Description

200914599 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to the field of extracting hydrocarbons from hydrocarbon-containing materials. This application is a contiguous case of Cong 3,126, filed on July 16, 2008, filed in the U.S. Patent Application Serial No. 12/174,139, filed on March 21, 2008, and claimed to be September 2007. U.S. Provisional Application No. 60/973,964, filed on the 20th, each of which is hereby incorporated by reference in its entirety by reference to the prior art, the prior art fossil fuel, also known as hydrocarbon-containing organic matter, is solid. The liquefaction, dissolution, and/or take-up of semi-solid, highly viscous or viscous forms (hereinafter, individually and collectively referred to as fossil i, material) have proven to be extremely challenging and difficult. As used herein, such fossil fuels include, but are not limited to, hydrocarbon-containing organic materials in coal, oil shale, tar sands, and oil sands (hereinafter collectively referred to as tar sands), as well as crude oil and heavy crude oil. , coarse asphalt, mother-of-pearl natural dice and/or tallow. This difficulty can be attributed in part to the fact that these fossil fuels contain complex organic pores, which are often embedded in the matrix of inorganic compounds, by oxygen-sulfur bonds. There is a need to produce other liquid hydrocarbon feedstocks for the manufacture of liquids and gaseous fuels, and to produce a variety of chemicals, medical and engineering materials, due to the increased demand and consumption of hydrocarbon-based materials. Various techniques or methods have been developed to liquefy, dissolve and/or extract fossil fuels. However, the liquefaction, dissolution and extraction techniques of ρ ψ χ / 巳5 are not the first to be used in the liquefaction, dissolution and extraction techniques or the 134584 200914599 method. # ^ Commercialization is poor for all types of fossil fuels. This is due to the fact that the dissolution and development of the carbonaceous compound liquids that have been developed in the past: all the prior art techniques and methods are very important for the deployment and insertion system. ^卜冰„« Take the game ^, about hydrocarbon liquefaction, dissolution and / or extraction = ... methods and techniques may be difficult to control or control, because there is - Chi Xi you ^ F /5L, (2) in the extremely high two two Reasons for: (1) operation in an excessively high factory; to require expensive processing of containers and equipment at the pole k: w '(3), which requires the use of external, catalytic and/or accelerators under the well-known conditions. (4) Accepting two or more reagents and toxicity of the party, and neither the function of H nor the composition 'it is often the source of r, γ: 'can not be recycled; (5) need to supply special form lJ such as money shot; (6) long process time for partial liquefaction, dissolution =; (7) need extra fine particles, it is very difficult and expensive to not recover the disc; and (8) the reagents, catalysts and / / Or accelerators. Because of the increase in the recovery of materials, there is a need to provide other techniques: in the initial drilling operation, a method can be advantageously used... The organic substances that capture 3 anaerobic compounds dissolve and promote 1 movement, then they can be Recycling, € from entering /, moving into ^ Shi Yun 4 existing pressure The gradient forces the organic matter containing the carbonated hydride to be punctured. The heavy-disc hydrogenation system can be used to dissolve, and the initial drilling operation is often left in the storage tank. About the second and third phases or the work The positive oil recovery operation can be advantageously carried out in a cost-effective manner by using the method of 'enhancing the oil, the six agglomerates M m ^ / / solution to recover the hydrocarbon-containing organic matter in the storage tank. 134584 200914599 Although the effective method and composition exist in the oyster's period, it is difficult to compare with the value of the organic matter produced by the carbon bismuth compound, which is attributed to the operating expenses. BRIEF SUMMARY OF THE INVENTION According to one embodiment of the present invention, a method for drawing hydrocarbon-containing organic matter from a hydrocarbon-containing material includes the steps of providing a first liquid, including a turpentine liquid, and The hydrocarbon-containing material is contacted with the turpentine liquid to form an extraction mixture, and the substance. The extraction mixture contains at least a portion of the carbonaceous compound-containing organic shellfish and Matsubara oil The residual material contains insoluble matter derived from a hydrocarbon-containing material. The residual material may also contain a hydrogen-containing compound in the case where all such hydrocarbon-containing material has not been dissolved by the turpentine liquid and moved into the extraction mixture. a reduced portion of the organic compound of the compound. The residual material is then separated from the extraction mixture. The extraction mixture is further separated into a first portion and a second portion. The first portion of the extraction mixture comprises a stream of charcoal hydrogen products, 1 comprising at least a portion of a hydrocarbon-containing organic material extracted from a hydrocarbon-containing material: the second portion of the extraction mixture comprising at least a portion of the turpentine liquid. In one embodiment, substantially all of the turpentine fluid The system is recovered in a recycle stream. In another embodiment, substantially all of the hydrocarbon-containing elastomeric shellfish is drawn into the extraction mixture. In such a specific embodiment, the barrier shell is substantially free of oil and can be further used or disposed of, which can impact the environment. DETAILED DESCRIPTION OF THE INVENTION 134584 200914599 The present invention relates to an easily deployable composition for extracting, liquefying and/or dissolving coal tar shale, shale tar tar and from fossil fuel. Phase ~ < According to the specific embodiment, a method is provided, 1 comprising the following bovine, self-hydrocarbon-containing materials such as coal, oil shale, tar sands, containing heavy crude oil, crude oil, natural gas (which often a tank or a combination thereof in which crude oil and other fossil fuels coexist, liquefying, dissolving and/or extracting carbon-containing chlorine

Organic matter of the compound. Organic substances containing hydrocarbons include but not: heavy crude oil, crude oil, natural gas, and the like. The hydrocarbon-containing organic material may be in the form of a solid, a semi-solid, a liquid 'sludge, a viscous liquid, a liquid or a gas. Other materials for suitable hydrocarbon-containing materials to be treated using the process of the present invention include liquids and solids, including hydrocarbon-containing materials to form residual materials. Examples of hydrocarbon-containing materials may also include tank bottoms, oil pits or pond sludge and slurry mixtures, discarded food, manure-, sludge or municipal waste. Liquefaction, dissolution, and/or extraction of hydrocarbon-containing organic materials includes the steps of 'providing a turpentine liquid to bring a carbon-containing gas into contact with a turpentine liquid from the hydrocarbon-containing material: extracting at least one a portion of the hydrocarbon-containing organic material to the turpentine liquid to produce an extraction mixture, "containing a hydrocarbon-containing organic material and a turpentine liquid that has been removed from the hydrocarbon-containing material, and from any unextracted The residual material separates the extracted organic matter in the turpentine oil: The turpentine liquid may contain a quantity of terpineol. The naturally occurring turpentine oil liquid contains a quantity of terpene. In a specific embodiment, the pine knot 2 liquid comprises alpha-terpineol. 134584 200914599 Turpentine liquid to hydrocarbon-containing materials

The shellfish scale, the volume of the hydrocarbon-containing material can be measured more directly. In some embodiments, the ratio of the knots: is greater than or equal to about 1:2 and 4:1 or is specific to about 1:1, and in some specific. or equal to 2:1. In the specific embodiment, the organic matter contained in the hydrocarbon-containing material is greater than or equal to about i% by weight of the hydrocarbon-containing material, in other embodiments. , greater than or equal to about 10% by weight, and in still further embodiments, greater than or equal to about 14% by weight. In a particular embodiment of the invention, the liquefaction, dissolution or extraction reagent selected for the hydrocarbon-containing material is a natural, synthetic or mineral turpentine which may comprise terpineol or 〇! itself. In some embodiments, the liquefaction, dissolution, and/or extraction of fossil fuels or hydrocarbon-containing organic materials can be about 2. The crucible is carried out at a temperature in the range of about 30. In some embodiments, the organic material or material is contacted with the turpentine liquid at a temperature below about 3 Torr or below about 60 Torr. In other embodiments, the liquefaction, dissolution, and/or extraction temperatures may range from about 20 c to about 200 C. The pressure at which the fossil fuel is liquefied, dissolved, and/or extracted is typically employed. About i0xl04 Baska (01 atmosphere) to about 5.0X106 Baska (50.0 atmosphere). In some concrete examples 134584 -10- 200914599, m can be about 5_0χ104 Baska (〇·5 atm) ) to a pressure of between about 8 〇χΐ〇 5 kPa (8.0 atmosphere mill). In some other specific embodiments, it is intended to be liquefied and dissolved by immersion in or contact with a turpentine liquid. And/or the extracted fossil fuel or the organic substance containing the m-form may be in the form of particles of a fossil fuel, a sheet of strips or a slab bed, and the size thereof is in the range of about 0.74 millimeters to about 10 millimeters. Including one or more of the liquefaction, dissolution and/or extraction reagents a solution, a solution, or an extraction vessel (post-r, reactor). In some embodiments, the size, size, length, or plate of the fossil fuel is between about 149 mm (yellow mesh) to about In the range of millimeters. In some embodiments, the particles, sheets, strips or plate beds of fossil fuels are actuated by one or more liquefaction, dissolution and/or extraction reagents in liquid form. Form, by particle, tablet, strip or plate bed, by boiling the reagent or reagents. In some embodiments, the duration of liquefaction, dissolution, and/or extraction is from about 0.25 minutes to about 90 minutes. Between minutes, fossil fuels may be partially or fully liquefied, dissolved and/or extracted: the extent of liquefaction, dissolution and/or extraction may be controlled by operating conditions such as vessel pressure, intensity of the actuation and duration of operation. And/or adjust the type, relative amount and concentration of the reagents in the reactor - or a variety of liquefaction, dissolution or extraction reagents. The basis of this _ 丨 丨 is surprisingly found, when about 500 grams try 1 ^ Alcohol is added to the tray In the case of the approximately 25 gram 6 〇 'mesh coal sample from the Pittsburgh mine in the county, the color of the reagent changed almost immediately into a cyan black' and remained so after a few hours. This color change is not due to coal particles. a suspension, but an indicator of the extraction of organic matter from coal with carbonitrides 134584 200914599. Next, the 2:1 mixture of the 4 alcohols and the coal sample is transferred from the shallow pan to the capped and tightly sealed The jar, and at (about) 25 days under the environmental conditions of about 2 (TC and slightly less than about L〇lxl〇5 Baska (1 atm). The conversion rate of the coal sample (meaning the degree of liquefaction) After being washed, padded with ethanol, dried and weighed, it was determined to be (10)% by weight. The 71% by weight conversion is equivalent to almost all soluble tellable (organic matter) present in the coal sample, and the approximate analysis is · % by weight of water just received, 9.25% by weight Dry ash, (iv) % by weight of anhydrous volatiles and % by weight of dry fixed carbon. Using coal, as well as oil shale and tar sands, in a series of follow-up experiments under various operating conditions, 'the group of reagents that have been infused, including natural and/or synthetic turpentine, containing olefins, and dilute alcohols' means? Alcohol, which is used in liquefaction, dissolution and/or stroke of kerogen (organic matter), dicedar (organic matter) and/or in fossil fuels including oil shale, tar sands, heavy crude oil and/or crude oil. Or the application of cytoplasmic (organic matter) to non-赍 & ancient 4 ^. Aunts are not effective in lifting] without any catalyst or alkaline metal assist. These reagents, except for the mineral turpentine derived from petroleum, are recyclable and "green 丨', 咅Pl3 your main u for fossils...all: he:: relatively inexpensive, when there is, He knows that liquefaction, dissolution and/or extraction reagents are earlier than hydrazine, such as tetrahydroanthracene, - 物 々 quot 一 一 一 一 一 一 一 一 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及 及Is derived from petroleum mineral turpentine, hair: two I regeneration, but is relatively low toxicity and is not expensive. It has also been fueled, dissolved and / or extracted sample penetration or diffusion to the fossil::, pieces , in a plate or strip, at a rate that can be perceived, 'worked through its pores, so & the outpoor of the private worker to make this 4 particle H strip or plate connected 134584 • 12- 200914599 released = liquefiable, soluble or extractable excipients in these, often almost & even in far milder conditions, such as ambient temperature and pressure' compared to fossil fuels such as coal, oil shale, Liquefaction, dissolution and/or extraction of tar sands, crude oil and heavy crude oil Nearly the inventors of the present invention. Aspects of the present invention provide for the liquefaction, dissolution and/or extraction of fossil fuels or organic compounds of chelating compounds from hydrocarbon-containing materials such as coal, oil shale and tar sands. An ancient earth-, (four) shell method in which a portion of a solid or semi-solid fossil fuel is contacted with a turpentine liquid in an extraction mixture, which may be in an alkali metal, a catalyst, a gas (6) and/or a carbon oxide (co). In the absence of chlorine, CO and CO can be used as a mixture, but gamma, but the specific embodiment of the invention includes methods and compositions in the absence of hydrazine and CO. In some embodiments, turpentine The liquid system is selected from the group consisting of natural turpentine, tar oil, turpentine, pine oil, secret, sputum, pure product, polymer, and mixtures thereof. In other specific embodiments, the turpentine oil system is selected. Rare: Diterpene (p-book; ^ ^ ^ ...: -1'8--lean), Novo W, spinach, hydroperoxide 2_Peptane's-alcohol hydrate, 2_fall_ + Know one of the unscented alcohol (myCen〇i), the different dragons, the frequency of the special Alcohol, acetic acid p-menthion =, 7' dihydro citronellal 1 alcohol and mixtures thereof. In other turpentine oil system selected from ... brain, trans-p-methyl isopropyl i 3,7- dimethyl octane , wrong acid, different sour, basil, Lele, bellerolol, 2_methoxy 2 red methyl _7,8_ cyclazone, camphor, citric acid, 7-methoxy Gas_香茅骏,10_樟脑134584 -13- 200914599 Rhein, citronella, mint, and mixtures thereof. According to one aspect, solid or semi-solid sputum or other hydrocarbon-containing materials, Such as coal, oil shale, tar fly and heavy crude oil, or for example, oil tank bottom material, oil pit or pond sludge,, ^ ^ also discarded food, manure, sludge or municipal waste, can be provided in any size, touch ,, _ .. , , , helps to connect with turpentine liquid =. Fossil fuels or hydrocarbon-containing materials can be provided as large fragments or pieces of particles, such as coal or oil shale. Root f: Particle 2: Surface, fossil fuel or material containing carbon and chlorine compounds. According to the present invention, the particles of the fossil fuel or the hydrocarbon-containing material are present in a flat/'s mean particle size of from about _4 mm to about 约. In certain other embodiments, the particles of the fossil fuel have average particles. The size is from about 0,074 mm to about 25 mm. According to an aspect of the invention,

Cj J adds a liquid to the turpentine oil: ❹ According to one aspect of the invention, the second liquid may be selected from the group consisting of low carbon fats, hydrazines, yards, aromatics, aliphatic amines, aromatic amines, Disulfide 2 σ. Examples of mixtures include 'manufactured in petroleum refining', s siemen's analysis/supply, light cycle oil and petroleum brain, or solvents produced in dry coal and fractionated liquefied coal. The low-carbon aliphatic alcohol used in the group refers to the primary, secondary and tertiary mono-alcohols having between 2 and 12 carbon atoms. As used herein, the alkane is a straight chain and a branched alkane between 5 and 22 carbon atoms. The aromatic compound as used herein refers to a monocyclic, heterocyclic, and polycyclic compound. The aliphatic amines used herein are primary, secondary and tertiary amines, "having an alkyl substituent between 1 and 15 carbon atoms. In some embodiments 134584 -14- 200914599 2 is the use of the present invention or a combination thereof. In another specific embodiment, the low carbon aliphatic alcohol indicated above may be used. In the specific embodiment, the solvent is selected from the group consisting of ethanol, two alcohols, and different Propyl alcohol, butanol '戍 、, 庚 烧 burning: benzene: toluene: xylene, hydrazine, onion, four gas tea 'triethylamine, aniline, sulfonate and their mixture, can be operated to keep the solvent liquid The temperature and pressure of the form. In some embodiments, the ratio of the turpentine liquid to any other turpentine miscible solvent contained in the fluid is greater than or equal to 1:1, in a particular embodiment Greater than or equal to about 9: 4. In some embodiments 1, the ratio (four) is greater than or equal to (d). In still other embodiments, the beta ratio is greater than or equal to 4: 1. The fossil according to the present invention The fuel is contacted with the turpentine fluid system at a temperature of from about 2: to about. In some embodiments The fossil fuel/糸 is contacted by the loose oil liquid at a temperature lower than about the boot. According to the invention, the fossil fuel and the turpentine liquid 4 Bass atmospheric pressure) to about _6 Baska (9) atmospheric pressure. According to one aspect, the method is carried out at a pressure of from about 5 atmospheres to about 8 rolls. X. According to this & the method further comprises providing an extraction vessel, body or half The solid fossil fuel is in contact with the turpentine liquid. The mixing device is provided according to the extraction = 2, and the fossil fuel contained in the reactor or the turpentine liquid is mixed and stirred. = One aspect of the invention 'fossil fuel And turpentine liquid can be cultured in the holding to extend its contact time. According to the further step, liquefaction, 134584 -15- 200914599 The degree of dissolution and / or extraction is the time of contact with the turpentine liquid by solid or semi-solid fossil fuel The length and/or the temperature of the fossil fuel and the turpentine liquid mixture are controlled. According to the aspect of the invention, the fossil fuel system comprises a turpentine liquid and water as a stirring agent. Non-homogeneous liquid contact.

* In some embodiments, the ratio of turpentine fluid to water is greater than or equal to about 1:1 by volume to avoid slurry formation which can make separation of the extracted organic material in the fluid containing the turpentine liquid difficult. According to one aspect of the invention, the fossil fuel is contacted by a turpentine liquid in the presence of an energy input, the energy being selected from the group consisting of thermal energy, exceeding about 30 (TC, pressure over atmospheric pressure, microwave energy, ultrasonic energy, ionization (four) energy, mechanical Shear force and its mixing. According to an aspect of the invention, a liquefaction or dissolution catalyst is provided in a mixture of a fossil fuel and a turpentine liquid. According to the invention, the reaction or dissolution mixture is by adding a compound. It is supplemented with 'the compound is selected from the group consisting of hydrogen, carbon monoxide, metal oxides, metals and mixtures thereof. According to Ben Lumin's - the 'microbes' are added to the reaction or dissolved in the mixture. In fossil fuels and other hydrocarbon-containing materials In a hydrocarbon, a chemical bond selected, for example, a sulfur crosslink and an oxygen crosslink, are interrupted by biological treatment with a thermophilic type of the genus Geobacillus and a mineral nutrient microbial microorganism. The resulting single object, derived from the sulfur spring. These choices of chemical bond breaks will help fossil fuels and other The dissolution of the hydrocarbons in the material of the hydrocarbons. 134584 -16- 200914599 Still other aspects and advantages of the present invention will become apparent from the description of the present invention. The detailed description of the present invention is intended to be illustrative of the preferred embodiments of the invention. In the following, the present invention is intended to be illustrative, and not limiting. According to a specific embodiment of the present invention, a self-hydrocarbon-containing hydrocarbon is provided. A method of extracting a hydrocarbon-containing organic material comprising a viscous liquid, a liquid or a gas fossil fuel material. The method provides a first liquid, including a turpentine liquid, a turpentine oil system and a hydrocarbon-containing material, On-the-spot contact in a subterranean formation containing the fossil fuel material, thus forming an extraction mixture to extract hydrocarbon-containing compounds物物贝至》玄权为油液' and forming an extraction liquid. The extraction liquid is removed from the structure' wherein the extraction liquid comprises a turpentine liquid containing the extracted organic compound of the money-containing compound. The extracted hydrocarbon-containing compound The organic material is separated from the unextracted residual material. The method may further comprise separating the extracted hydrocarbon material from the turpentine liquid. The viscous liquid, liquid or gas fossil fuel material may be heavy crude oil, crude oil, natural gas or The underground structure may be, for example, a crude oil storage tank or a natural gas storage tank. The "Mingke Valley" is operated on the spot to directly liquefy and/or dissolve the fossil fuel in the middle, and from such a structure extracting plant. The liquid product formed. The extraction reagent of the present invention is a liquid having a strong physical and chemical affinity with the asphalt organic substance 134584 -17- 200914599, the substance including bidet, kerogen and/or tar, in the alpha body coal / by shale and tar sands. When the extracting agent of the present invention and the bituminous organic substance mainly containing a hydrocarbon are in direct contact with each other, the organic matter is dissolved in the extracting reagent of the present invention to liquefy the organic substance. At the time of contact, the hydrocarbon of the present invention and the extraction reagent rapidly form a homogeneous solution, i.e., a single phase liquid. The physicochemical affinity between the extraction reagent of the present invention and the telling material can be utilized to increase oil recovery from the oil sump under field conditions. Most of the prior art on-site recycling techniques that have been applied to oil tanks to date have appealed to so-called frontier replacements. This method is precisely controlled by special tests of multiphase fluid flow in a porous medium. It is easy to leave most of the C often overJona's original: from unrecovered, even if, good "low viscosity oil sump (4). The invention / stroke reagent will be overcome by overcoming the conditions on the spot The complex behavior of multiphase flow and the recovery of oil. The present invention utilizes the chemical affinity of the extremely strong substance S of the turpentine liquid. The method of the present month is to inject the extraction reagent of the present invention into the oil or natural gas storage tank through the injection well. The t system is dissolved in the extraction reagent of the present invention (when the two are in contact with the oil bath), thus producing a homogenous solution, that is, a single phase liquid. When the extraction agent of the present invention runs from the injection well to the production In the well, it is not only a replacement oil; the first trapping oil is dissolved in the extraction reagent of the present invention until the extraction reagent is completely saturated with the oil. Then, the extraction reagent becomes inactive during other oil recovery processes. And the single-phase liquid simply flows through the pores of the storage tank and finally reaches the production well. 134584 -18- 200914599 The following are three specific specific examples of the on-the-spot method for oil recovery of the present invention. In a first embodiment of the present invention, about three (10) to seven (10) pore volumes of the inventive extraction reagent are injected into an oil bath that has been submerged to residual oil saturation. (IV) Approximately 51% of the initial oil is produced in the storage tank. The injection of the reagent can surprisingly produce about 41% of the initial oil in the reservoir. This method is known to be effective in the experiment, as described in the above.

In the second embodiment of the present invention, C is about two (10) to five (10) of the aperture volume of the present day and month I % y 4, and the formula is known as the 'into the oil sump. Initially, the injection only causes the oil to be produced until about: the knives - (〇·3) to three-quarters (0.75) of the pores a, the extraction reagent of the present invention is injected; then the oil is dissolved And the invention of the extraction reagent system 'is produced. Most of the oil present can be recovered by injecting about one-half (1.5) to three and a half (reagents between 35 liters of space). This method surprisingly recovers the initial oil in the tank. This particular embodiment of the method has also been experimentally validated as described in Example 22 below. In a third embodiment of the field, the extraction reagent of the present invention is injected, from an oil bath containing a very viscous oil. When oil is used, for example, in the tank of "Orinoco oil belt" in venezuda. The use of the prior art recovery method has a very low 'range' of 15% of the initial oil in this tank. With the injection of the turpentine liquid of the present invention The extraction of the reagents, and the unexpected increase in the rate of the reservoirs, can be improved by the horizontal wells of the generators and injectors and the periodic steam soaking of such wells. 134584 -19- 200914599 The final recovery of natural gas from a large gas storage tank can be increased with the injection of the extraction reagent of the present invention into a storage tank. The gas production form of such a storage tank often causes a dangerous large-scale collapse on the surface of the gas field, example For example, in the Groemngen field in the Netherlands. Therefore, the tank pressure must be maintained by water injection. The water injected into the tank will capture about 30% of the gas at high pressure under high pressure, which is due to the flow of water and gas. Due to the low permeability reservoir, with the injection of the stroke reagent of the present invention, the captured gas system in the reservoir is dissolved in the f ° agent and flows to the production well. By separating the reagents on the surface Recovering the gas with the gas, recycling the reagents, and recycling the reagents. After Yu Fancheng one or more known methods to help oil production, such as c〇2 or natural gas injection and surfactant addition, the extraction of the present invention can be performed. DETAILED DESCRIPTION OF THE INVENTION Example of Carrying Out the Invention Coal In certain embodiments, anthracite or bituminous coal may be ground to a range of from about 0.841 house meters (2 inches mesh) to about 〇 149 mm (1 mesh) Size, and Q is dissolved and/or extracted by immersion in a turpentine liquid at a pressure in the range of about L0x105 Baska (1 atm) to about 2.0 x 105 Bass (2.0 atmosphere). liquefaction In certain other embodiments, the turpentine oil month A can be a natural, synthetic or mineral turpentine comprising up to about 50-70% by volume of alpha-terpineol, about 20-40% by volume of terpineol and About 1% by volume of other components. In some embodiments, the 'milled anthracite or bituminous coal bed can be at a temperature between 80 C and about 130. (or in the range of - or possibly up to the boiling point of the turpentine liquid, Stirring by passing the turpentine liquid. In some other specific embodiments, dissolution and/or extraction, meaning that the liquefaction continues between 134584 -20 and 200914599, may range from about 10 minutes to about 40 minutes. In some embodiments, the contact time of the hydrocarbon-containing organic material from the coal is 'less than 5 minutes. In some embodiments, lignite, brown coal or any other lower grade coal may be ground to a range of from about 419 mm (9) mesh to about MM.

The size of the mesh, and then dissolved and/or dissolved in the turpentine liquid at a pressure in the range of about 1Όχ5〇5 Bass (1 atm) to about 2 fine 5 Bass (2.0 atmospheres) Extraction, meaning liquefaction. In certain other embodiments, the 'turpentine oil' may be a natural, synthetic or mineral turpentine comprising from about 70 to 90% by volume of 4 oral alcohols, from about 5% to about 5% by volume of reduced alcohol, and about 5% by volume of the other Ingredients. In other embodiments, the ground lignite, brown coal, or any other lower grade coal bed may be at a temperature of between about 8 (rc and about 13 (r), or possibly up to the boiling point of the turpentine liquid. The turpentine liquid is agitated by passage. In some other specific embodiments, dissolution and/or stroke, meaning liquefaction, may range from about 2 minutes to about 6 minutes. In some embodiments, from coal The contact time for extracting the hydrocarbon-containing organic material is less than 5 minutes. Oil Shale In some embodiments, the oil shale can be ground to a range of about 419 mm (40 mesh) to 0.074 mm (200 mesh). Size, and then dissolved and/or extracted by immersion in a turpentine liquid at a pressure in the range of about 1.00 x 10 5 Bass (1 atmosphere) to about 2.0 x 105 Bass (2.0 atmospheres) In other embodiments, the turpentine liquid may be a natural, synthetic or mineral turpentine comprising about 70-9% by volume of terpineol, about 5-25% by volume of terpineol, and about 5% by volume of the other. Ingredients. In a certain 134584 -21 · 200914599 In other specific examples, the ground oil shale bed may be in the range of about 8 〇 between 〇 and about i3〇c, or may be as high as the boiling point of the turpentine liquid, by making the turpentine The liquid is agitated by the passage of the liquid. In other embodiments, the dissolution and/or extraction, that is, liquefaction, may be in the range of from about 3 G minutes to about 6 G minutes. In a second embodiment, the hydrocarbon-bearing shale is extracted from the hydrocarbon-bearing shale. The contact time of the organic substance of the compound is less than 5 minutes.

In a specific embodiment, the tar sand can be broken into a size ranging from about mm σ mesh to 4.76 mA (4 mesh), and then in about ι 〇χΐ〇 5 cards (1 atmospheric dust) to Under the force of about 2 〇χΐ〇 5 Baska (2 〇 atmospheric pressure), the straw is dissolved and/or extracted by immersion in the turpentine liquid, meaning that night smelting is in other specific examples, turpentine The liquid may be natural, synthetic or mineral, and it contains about % by volume of _ of the alcohol, about 30-50% by volume of pure alcohol, 5% by volume of "and / ❹ spinach and about 5% by volume of the other Ingredients. In another embodiment, the ground oil shale bed may be agitated by passing the turpentine liquid within a range of between about 9 Torr or possibly up to the turpentine liquid freezing point. In the present embodiment, dissolution and/or extraction, which is intended to be specific, can be carried out within (four) minutes (four) within two minutes. In some embodiments, the contact time of the organic material from the tar sands to extract the carbonaceous gasification is less than 5 minutes. Crude oil In some embodiments, (1.0) to about five (50) pore volumes are removed from the underground storage tank for initial light and medium crude oils to be produced on the spot by injecting about one turpentine liquid. That is, 'two or three phases of recycling. In other embodiments 134584-22 - 200914599, turpentine liquid between about two (2.0) and about four (4 〇) pore volumes can be injected. In certain embodiments, the turpentine liquid can be a natural, synthetic or mineral turpentine comprising from about 40% to about 70% by volume of terpineol, from about 30% to about 40% by volume of 3-terpineol, and from 1% by volume. α and/or bed terpene and about 1% by volume of other components. In some embodiments, the injection of the turpentine liquid can then be submerged with water in the range of from about one (1.0) to about three (3·0) pore volumes.

In some embodiments, heavy and extra heavy crude oil can be produced on the spot by injecting about one (1.0) to about five (5.0) pore volumes of turpentine liquid, meaning to be removed from the underground storage tank for initial , second or third phase of recycling. In other embodiments, a turpentine liquid between about two (10) and about four (4 Torr) pore volumes can be injected. In certain embodiments, the turpentine liquid can be a natural, synthetic or mineral turpentine comprising about 5 〇 7 7% by volume of alpha-terpineol, about 2 〇 _ 35 vol% of pure alcohol, 1 ( The volume and / or the recorded olefin and about 5% by volume of other components 'may be combined with steam injection. Referring to Figure 1', a device for recovering hydrocarbon-containing organic matter from tar sands is provided. Apparatus 100 includes a turpentine liquid supply 1〇2, which may optionally be coupled to pump 1G4' to supply turpentine liquid to contact vessel or extraction vessel 110. In some embodiments, the turpentine liquid supply can include a setting of a twisted turpentine liquid. In some embodiments, the contact container can be a tilting rotary filter or back (four). The tar sand sample 106' is supplied to the conveyor or similar feeding device to supply the tar sand to the inlet of the contact vessel 11 送. The delivery machine should optionally include a transition net or similar separation device to prevent the large: sub-introduction into the process. . The contact volume includes at least one population for the introduction of L oil liquid and contact with tar sands. The contact container (10) can be 134 584 -23- 200914599. The plurality (4) or the blade 114 ′ is designed to keep the tar sand in contact with the container for a certain amount of time (4), and to increase or contact the oil sand particles with the turpentine body door. In some embodiments, the contact container can be a tilting rotation benefit. The extraction mixture comprising the extraction liquid and the hydrocarbon-containing organic material extracted from the tar sands is removed from the contact vessel 110 via an outlet 116, which may include filtration Is 118 ' to prevent removal of the carbon-containing chloride containing the extracted carbonaceous A solid of the extraction mixture of organic matter. The pump 12A can be coupled to the outlet 116 to assist in supplying the extraction mixture to the holding tank 122. Line 124 can be coupled to holding tank 112 to supply the extraction mixture for further processing. After extraction with hydrocarbon-containing organic materials, inorganic solids and other materials that are insoluble in the turpentine liquid can be removed from the contact vessel via a second conveyor. - Some turpentine liquids include, but are not limited to, liquids containing pure alcohol and /5-terpineol. Referring now to Figure 2, a device 2 is provided for recovering hydrocarbon-containing organic shells from oil shale and other settled rock structures containing recoverable hydrocarbon materials. The oil shale sample 2〇2 is supplied to a grinder or crusher 204 to reduce the size of the oil shale. Preferably, the grinder or crusher 2 4 reduces the oil shale to between about 074 074 and 〇 42 mm in diameter. The crushed oil shale can be supplied to the filter depending on the condition of It to ensure uniformity and/or suitable particle size. The first conveyor 206 provides particles from the grinder or crusher 2 to contact 208. Contact container 208 is coupled to turpentine liquid supply 21A, which may optionally be coupled to a pump, and which supplies turpentine liquid to at least one inlet 212 that is coupled to contact vessel 208. In some embodiments, the loose oil liquid supply can include an arrangement for heating the turpentine liquid. 134584 200914599 The contact container 208 can include a plurality of shallow trays or vanes 214 designed to maintain tar sand in contact with the container for a specified amount of time and to increase or control contact between the tar sand particles and the turpentine liquid. In some embodiments, the contact container can be a tilting rotary or swirling screen. The extract mixture stream comprising the turpentine liquid and the hydrocarbon-containing organic material recovered from the oil shale is 216 collected and supplied to the holding tank 220. The pump 218 is attached to the ... to help supply the extraction mixture to the holding tank r 220. The draw mixture stream can be coupled to line 222 to supply the extracted mixed stream for further processing. The second conveyor 224 will assist in the removal of inorganic or insoluble materials from the contact container. Turpentine liquids may include, but are not limited to, < terpineol and/5-terpineol. Referring now to Figure 3, a means is provided for recovering hydrocarbon-containing organic materials from coal. The coal sample 3〇2 is supplied to a grinder or crusher 3〇4 to reduce the size of the coal. The grinder or crusher is preferably between about ca and mm in diameter, depending on the quality of the coal sample. In some specific embodiments, the grinder or crusher 3〇4 may be a wet mill. The crushed coal may be supplied to the filter, as appropriate, to ensure that the hooks and/or the particles are large, and that the crushed coal system is supplied to the first contact container. The first contact container 306 is also coupled to the turpentine liquid supply to be thinned, coupled to the pump 310, and is supplied to the shore, 1 11 糸仏 糸仏 # 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印 印In some embodiments, the 'turpentine liquid supply may include an arrangement for heating the turpentine liquid. The first contact vessel 3〇6 comprises a mixing arrangement for phase-acting the solid coal particles with the turpentine liquid and for improving or controlling the contact therebetween. Containing turpentine liquid and recovered from oil shale; 134584 -25- 200914599 The benzene θ θ of the hydrocarbon organic matter is collected via the first contact volume outlet 313 and supplied „ ^ .w ^ ^ 罘 - contact container 310. Pump 314

Optionally, it is coupled to outlet 313, which is like A, n^ _ σ to help supply the extraction mixture to the second contact bar 316. The second contact volume ”” Anzhengyi 316 may include a series of platters or blades 318 ′ designed to increase the separation of the sub-control solids from the turpentine liquid. The two contact containers 316 may optionally be tilted rotary filters or rotary screens. Extract

The mixture stream can be collected from a second contact vessel outlet port, which can optionally be coupled to pump 322 to assist in the flow of the draw mixture to the holding tank in the holding tank 324. The liquid coal present and any turpentine liquid may be supplied to the liquid coal refining unit or other processing steps via the official line 326. Conveyor 328 can be coupled to a second contact vessel 316 for removing the disc to recover solids' as a by-product of the process. The turpentine liquid may comprise two to the alpha-terpineol and the terpineol.奘 Oil page ^ 4 set 3〇0 can also be used to handle high and low levels. Referring now to Figure 4, the process of strengthening the recovery of hydrocarbon-containing organic substances from the subsurface structure containing hydrocarbons is provided. The hydrocarbon containing reservoir 404 is shown below the surface. Production wells are already in operation. An injection well 408 is provided for injecting turpentine liquid via a line. The turpentine fluid aids in the liquefaction, dissolution, and/or extraction of hydrocarbon-containing organic materials present in the tank, as well as providing a driving force to push the organic carbonaceous material in the structure toward the production well. A hydrocarbon product stream comprising the injected turpentine oil 2 is collected via line 412. Pine contains but not limited to (four) alcohol and pure alcohol. The liquid package, in some embodiments, is provided to increase the amount of oil 134584 -26· 200914599 oil produced from the oil well, which comprises at least 30% by volume oil, mineral turpentine, pine oil, —; 】 口口口私, r-帖醇醇, terpene resin, 仏佑^ 苴,, 日人私>#邱尽烯,7-pinene or eight of this mouth. In other embodiments, the y is less than 1 and the private liquid is 30 volumes.

% of geranium, 3-(tetra), dipentane (p-mental J (nopol), decane 'hydroperoxide 2 decane, / _ ^ - hydrate hydrate ' 2- sterol, :虱:: Alcohol (-_, isoborneol, trans-alcohol, acetic acid f, hydrazine, citronellol, acetic acid versus peppermint _8_ ki-7. ta human 7 & citronella light, cover alcohol or one #. In still other embodiments, the turpentine oil tank contains a large amount of carbonic acid to the Gulf of China; p-methyl isopropyl stupid, bacteriophage, 3,7-monomethyl*octadiene, cesium acetate ' basilene, bellele, bellerolol' 2-methoxy-2,6-dimercapto_7 8 stomach 4 ^ — , 8 decyl octane, camphor, 楝 楝, 7_f oxygen Base: Hydrogen acid, 1 () _ camphor (IV) ketone or a mixture thereof. Spear Road 4 In some embodiments, the turpentine liquid comprises about 4% by volume of terpineol. In other embodiments, 'turpentine oil The liquid comprises at least about (iv) antimony alcohol. In still other embodiments, the turpentine liquid package = at least about 40% by volume of alpha-terpineol and at least about 25% by volume of terpineol. In other embodiments' Turpentine liquid contains at least about 5〇% shout The alcohol/and in some embodiments' also includes terpineol. In certain embodiments, the turpentine liquid comprises at least 20% by volume of the sterol alcohol. In certain embodiments, the turpentine liquid comprises about 〇 〇 〇 〇 〇 〇 萜 萜 萜 及 及 及 及 及 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 A method of producing a subterranean hydrocarbon-containing sump comprising 'injecting turpentine liquid into a sump through an injection well to stimulate production of a chlorocarbon-containing material. The turpentine liquid may comprise at least one compound selected from the group consisting of turpentine , the synthesis of turpentine 'mineral turpentine, pine oil, secret thin 'Zhao thin: alcohol di-alcohol, chocolate alcohol, dilute resin, (tetra) ene, fine, r- ene and mixtures thereof. In other embodiments , the pine liquid may comprise at least one compound selected from the group consisting of geraniol, xylenol, dipentaquinone-menthol from dilute), nopo-), falling down, hydroperoxide 2_blocking, = leaven hydrate, 2 rhyme, dihydromyristyl alcohol («, Dragon brain, p-/he 8-alcohol, glycol acetate, citronellol, acetic acid, dimethoate, capitol, and mixtures thereof. In other specific two!: turpentine liquid may contain at least one compound, From the big scented brain, cans, p-methyl cumene's window scent, 3,7-dimethyl oxadipine, bismuth citrate, basil, allo-olene, belle basil Enols, 2-methoxy-2,6-monomethyl-7,8-epoxyoctane, camphor, citral, 'methoxydi: she, camphor, acid (4), menthone And the mixture thereof contains a pine eucalyptus oil liquid and a household tongtong 攸山 $ /, and "the hydrocarbon compound of the organic compound / /, the L system is recovered from the production well combined with the hydrocarbon-containing storage tank. The hydrocarbon-containing organic matter is temporarily +, and the production can be separated into the recovered hydrocarbon, the stream and the turpentine liquid circulating stream. In some embodiments, the alternative method further entails the step of injecting a stream of loose oily liquid into the injection well from a. On the other hand, it provides a method for carrying out enhanced recovery operations to increase the structure of hydrocarbons under the surface of carbon-containing gas compounds. This 134584 -28 ‘ 200914599 = includes: the step of injecting the turpentine liquid into the construction through the injection well. In a specific implementation example, Matsutake Sacher s (, at least 40% by volume of the product

Ο 咖 均 均 醇 醇 醇 醇The turpentine liquid is self-structuring to dissolve, draw, and/or replace the hydrocarbon-containing material, which is then recovered from the production well from a structure having a turpentine liquid. In some embodiments, the method further comprises separating the hydrocarbon from the turpentine liquid. In a further embodiment of the invention, the method further comprises re-circulating the turpentine liquid to the injection well. In some embodiments, the _ sterol is present in an amount between about 10,000 vol. In certain other embodiments, the m alcohol is present in an amount of at least 70% by volume. In still other embodiments, the desired alcohol is present in between about 10 discs, 40 Wei, and 5% by volume. In other embodiments, the 'turpentine liquid further comprises up to about 1 volume of terpineol. In other embodiments, the turpentine liquid may comprise up to about 25% by volume of the organic solvent' selected from the group consisting of methanol, ethanol, propanol, A stupid and xylene. This method can be used to recover hydrocarbon-containing organic materials during initial, second and third recovery operations, including after flooding/recycling operations. Providing a turpentine liquid for recovering hydrocarbon-containing organic matter from tar sands. In a specific embodiment, the fuel-saving liquid comprises at least about 30% by volume of α-terpineol and at least about 25% by volume of less than In another embodiment, the turpentine liquid comprises between about 3 and 7 volume percent of a-terpineol, between about 25 and 55 volume percent of terpineol, up to about 10 volume percent of terpenes. And up to about 1% by volume of decene. In another aspect, a turpentine liquid for recovering 3 stone antihydrogen organic substances from a high-grade coal source such as anthracite or smoke 134584 -29- 200914599 is provided. In this embodiment, the turpentine liquid comprises at least about 5% by volume of tetrahydrin and at least (four) vol% of pure alcohol. In another embodiment, the turpentine liquid comprises between about 45 and 80 vol% of the alcohol, About 15% by volume of milk, 至 萜 、 、 、 、 、 至 约 约 约 约 约 约 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' A turpentine liquid of an organic material. In one embodiment, the turpentine 2 body comprises at least about 60% by volume of tetrahydrin and up to about 30% by volume of pure alcohol. In another embodiment, the turpentine liquid comprises about 6品 and 95% by volume of "decyl alcohol, up to about 3% by volume of sterols, up to about 5% by volume of alpha-pinene and up to about 5% by volume of decene. On the other hand, a turpentine liquid for recovering organic substances containing chlorocarbons from oil shale is provided. As used herein, oil shale generally refers to any settled rock with asphaltic material. In one embodiment, the liquid comprises at least about 6 vol% by volume of the alcohol and up to about 5% by volume of the plaque. . alcohol. In another embodiment, the 'turpentine oil liquid comprises between about 95% by volume of "terraol, up to about 3{) by volume of alcohol, to about 5% by volume of decene and up to about 5% by volume. Terpene. In another aspect, a turpentine liquid is provided for recovering hydrocarbon-containing organic materials from light and medium crude oil. In one embodiment, the loose oil liquid comprises at least about 40 and 70% by volume. In another embodiment, the turpentine liquid comprises between about 40 and 70% by volume of the alcohol, about 3 〇 and 4 〇 _ 134584 -30- 200914599. f pure alcohol, up to about % pure olefin and up to (four) volume 萜 decene. fi in another - 'provides a turpentine liquid for the weight and heavy oil recovery of hydrocarbon-containing organic matter. In a specific embodiment, the loose oil liquid comprises at least about 50 and 70% by volume of serool and at least about 30% by volume of pure alcohol. In another embodiment, a turpentine liquid of 3 scoops 50 and 70 Between the volume % of α_terpineol, about 3〇 and vol% Alcohol, (iv) a high volume% and a high of about _ alkenyl 1〇 lean volume. Dryer regard 'to provide a system recovery from the tar sands with a hydrocarbon-containing donor short-tailed, H method. This method comprises the tar sands mining enriched configured to provide

In sand: Sample: The tar sand sample contains a recyclable hydrocarbon-containing pool to the residual inorganic or insoluble matter. The tar sand sample is supplied to the contact valley state, and the entrance of the CIB anchor body is used for the supply of turpentine oil and the turpentine liquid in a small amount, and the self-squeeze oil (4) is made of the eight-type material. Produce & extract 3 % bismuth compound organic: =::rw machine = · compound product stream and loose "The step of recycling the example to the contact vessel. In other specific product stream tray two mixture can be separated by steaming, To produce a hydrocarbon peach sap, that is, an oil liquid circulating stream. wherein 'the turpentine liquid may comprise one. In the sputum, the turpentine liquid may comprise at least about 40% by volume 仏 134584 31 200914599 帖 醇 Η and 重量) and 40% by weight Pure alcohol. In some embodiments, the turpentine fluid system between α5 and 4 equivalents is used to bring the tar sand into contact with the recovered hydrocarbons. In some embodiments, at 〇5 ”" The turpentine oil system between the quantities is used to combine the tar sand with the recovered carbon gas: contact. On the other hand, a method for recovering hydrocarbon-containing organic substances from t-hydrocarbon-containing oil shale is provided. The method includes mining a rock comprising a hydrocarbon-containing organic material to produce a hydrocarbon-containing oil shale comprising a recoverable hydrocarbon material and an inorganic or insoluble material. The oil shale is ground to produce crushed carbonaceous compound oil shale. After the iron, the crushed carbonaceous compound oil shale is filtered through the I mesh to prevent or control the supply of excessive particles to the extraction process. Crushed Carbon-Containing Compounds Oil shale systems are proud of contact vessels, where the contact vessel includes at least one inlet for the supply of turpentine liquid for the recovery of hydrocarbons from the crushed hydrocarbon-containing oil shale. Lime-containing hydrocarbon shale system and pine knot Ο liquid contact 卩 self-crushing hydrocarbon-containing oil shale extracts organic matter containing hydrocarbons to produce inorganic solids and contains turpentine liquid: Extract the mixture. The inorganic or insoluble material is removed from the mixture, and the recovered hydrocarbon is separated from the turpentine liquid to produce a hydrogen hydride product stream and a turpentine liquid recycle stream. In a specific embodiment, the turpentine liquid recycle stream is recycled to the contact. In other embodiments, the crushed chlorocarbon-containing oil shale has an average particle size of less than about a 42 mm diameter. In other specific embodiments of the method of recovering hydrocarbon-containing organic matter from oil shale, the pine 134584 - 32 · 200914599 oil liquid comprises at least one compound selected from the group consisting of: ..., private oil, synthetic private oil, mineral turpentine, Pine oil, α_pinene, current private repellent, α-terpineol, no-product fermented 'r-label alcohol, terpene resin, α_萜 coal, jinsusuene, γ-yi, knee-, Its mixture. In other specific embodiments, the turpentine liquid comprises at least: a compound selected from the group consisting of geraniol, diced, dipentene (p-nopol, decane, hydroperoxide 2 decane, > - alcohol hydrate, 2 alcohol, dihydromyristin (mycen〇l), isoborneol, - / &a>, -8-8-ol, a-glycol acetate, citronellol, Acetic acid on _ peppermint _8 ^ a few citronellal, k-alcohol and mixtures thereof. In other embodiments, the turpentine liquid is encapsulated: a small-type compound selected from the group consisting of a large scented brain, a terpene; Isopropylbenzene 3, @香醛,3J-dimethyl·octadiene's acetic acid,, basil, bellerol, bellerol, 2·曱oxyquinone H-alkylene oxide , camphor, citric acid, 7-methodamine - 夭 夭 讲 豕跄 豕跄 豕跄 豕跄 豕跄 豕跄 豕跄 豕跄 豕跄 T 虱 虱 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 - citronellal, 1 〇 樟 樟 碏 、 、 香In some embodiments, the turpentine liquid may comprise a pure alcohol. In other embodiments, the turpentine liquid may comprise at least about 40% by volume of alpha alcohol; and 1% to 4% by weight of the polyol. In some embodiments, the turpentine fluid system between 5 and 4 equivalents is used to contact the oil shale with the recovered hydrocarbon-containing organic material. In some embodiments, between α5 and 2.0 equivalents The turpentine oil system is used to bring the oil shale into contact with the recovered hydrocarbons. Another aspect is a method for recovering hydrocarbon-containing organic matter from a coal-rich subsurface structure. The method includes mining the subsurface structure. k to produce coal, wherein the coal contains organic matter and inorganic or insoluble matter that can recover hydrocarbons. The coal is ground to produce crushed coal, and 134584 33- 200914599 over = provide uniform or desired size of the sample The crushed coal system is proudly contacted, wherein the contact vessel includes at least one inlet for the supply of turpentine liquid for recovering hydrocarbons from the crushed coal, and with the turpentine liquid, extracted from the coal of the crushed coal. Hydrocarbons to produce inorganic solids and extracts. The extract mixture contains turpentine liquid and recovered hydrocarbons: mouthwash. Self-extraction of inorganic or insoluble solids The composition is separated and the hydrazine compound is separated from the turpentine liquid to produce a liquid coal product turpentine liquid recycle stream. In certain embodiments, the method further comprises recycling the turpentine liquid recycle stream to the contacting In other embodiments, the liquid coal product (IV) is supplied to the domain body coal refining unit. In some embodiments, the coal sample comprises low rank coal having an average = sub-size of less than about (four) millimeters. In a specific embodiment, the coal sample, including the same grade coal, has an average particle size of less than about _ mm. The method of recovering hydrocarbon-containing organic matter from coal is further potted and the body = the order of the turpentine liquid contains at least a compound selected from the group consisting of Tiansong Songlang^, synthetic turpentine, mineral turpentine, pine oil, shouting, thinning, alcohol, pure alcohol, (4) alcohol, (4) resin, 4 thin, bed = Erzhuang or a mixture thereof . In other specific embodiments, the turpentine; the body comprises at least one compound selected from the group consisting of geraniol, dipentane (towed diene), nopo (n_, obtained oxime, hydroperoxide 2, Su Wide object, called dihydromyristyl (four) ce_, isoborneol, p-menthol,: acetic acid shunt vinegar, citronellol, acetic acid--mint vinegar', 7-::oxy citronella red, drunk and In other embodiments, A Lang/containing at least one compound from a liquid, έ έ & & 回 134 134 崁 134 ; ; ; ; ; ; 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 134 , 3j-two

Beverage vinegar, basilene, allo-olene 1,6-octadiene, acetic acid iso-pro-Ville ############################################################################ LAM aldehyde, 7-▼ oxygen melamine A \10-camphorsulfonic acid, citronellal, mint soil-wind-citronella, y, , ,, /fcti compound. In some cases of sinus sinus, in her case, the turpentine liquid contains at least ^ eighteen denier 舻 volume % 1 tilster. In some financial terms, (4) the oil liquid contains at least an aggregate product of at least about 5% by volume of the tableting alcohol. In the other embodiments, the loose oil liquid contains at least 60% by volume 忒σ 〜 ^ Product "Typical alcohol and about 30% by volume of the highest to do mouth mouth yeast. In some implementations Ρ ^ between 0.5 and 4 equivalents of the liquid system is used to bring the oil shale into contact with the returned 3 hurricane* compound organic matter. In a second embodiment, the turpentine liquid between 〇5 and 2 〇 is used to contact the oil shale with the hydrocarbon-containing organic matter. In addition, a system for recovering hydrocarbon-containing organic substances from tar sands is provided. The tar sand recovery system includes a bilge and contact vessel for supplying turpentine liquid, wherein the contact vessel includes at least one inlet for introducing the turpentine I body and at least one outlet for recovering the extraction mixture from the contact vessel. The second system also includes the first conveyor for supplying tar sands to the contact vessel. A holding tank is provided which includes connecting the holding tank to the contact volume line, wherein the line connecting the contact container and the holding tank includes a filter to prevent solids from passing to the holding tank. The system also includes a second conveyor for recycling and transporting solids. In one embodiment, the contact vessel is a rotary tilt filter that includes a series of vanes or trays for separating and/or controlling the tar sands. In another embodiment, a blade or tray is provided to increase or control the contact time between the oil 134584 - 35 - 200914599 oil sand and the turpentine liquid. In certain embodiments, the turpentine liquid can comprise alpha, a terpineol. In other embodiments, the turpentine liquid may comprise between (4) the alcohol and between about 55% by weight of the terpineol. In another aspect, a system for recovering hydrocarbon-containing organic shale from oil shale is provided. The system includes a tank for the supply of turpentine liquid and a grinder that pulverizes the shale into a reduced particle size. Provided is an outlet comprising at least one inlet for introducing a turpentine liquid, at least one inlet for crushed oil shale, at least one outlet for recovering solids from the contact vessel, and at least one outlet for recovering the extraction mixture from the contact vessel. Provide the first (four) delivery machine, poetry supply (four) broken oil f rock domain touch container. This system is in the holding tank 'where the holding tank includes the holding tank to which it is connected! Line 'where the line includes a filter to prevent solids from passing through to:, 曰 barrels, two conveyors for recycling solids. In some specific examples, the line advancement includes supplying hydrocarbons containing the collected hydrocarbons, and the initial primary bar is wrapped for further separation. In some implementations, the turpentine liquid may comprise (9) two volumes. In two specific embodiments, the turpentine liquid may comprise an alcohol. In the case of potting it is 1 alcohol and up to about 3% by weight of the pure volume ratio, the 'turpentine liquid can contain about 90% to 2% of the alcohol and about 5% to 25% by weight. Pure alcohol. The quality of Li Tongfang provides a kind of grinder that recovers the charcoal-containing organic matter from coal and reduces it into a tank containing a turpentine liquid, and a pulverized coal of a low-sized pulverized material. Providing contact 134584 -36- 200914599 The trough includes at least one inlet for introducing a turpentine liquid and at least one self-contacting container for recovering solids and liquids. The contact vessel also includes agitation 6 for adequate mixing of the turpentine liquid and the pulverized coal. A separator is provided for separating the solids from the liquid, wherein the separator includes an inlet, an outlet, and a line connecting the separator inlet to the outlet of the contacting vessel. The system also includes a holding tank, wherein the holding tank includes a line connecting the holding tank to the separator, wherein the line may include a filter to prevent solids from passing to the holding tank. In some embodiments, the system further includes a filter for selectively preventing particles having an average diameter greater than about 085 mm from being introduced into the contact vessel. In certain other embodiments, the system further includes a line for supplying liquid coal product to the refining unit for further processing. In some embodiments, the system further includes a first conveyor for supplying crushed coal to the contact vessel. In other embodiments, the system further includes a second conveyor for removing solids from the separator. In certain embodiments, the turpentine liquid can comprise terpineol. In a specific embodiment for recovering hydrocarbons from higher coal, the turpentine liquid may comprise between about 45% and 80% by volume of noristol and between about 15% and 45% by weight of the terpineol. In a specific embodiment for recovering hydrocarbons from lower grade coals, the turpentine liquid may comprise between about 6% and 95% by volume of the sterols and between about 0% and 30% by weight of the terpineol. On the other hand, there is provided a method for optimizing the extraction of a turpentine liquid containing a hydrocarbon organic substance from a hydrocarbon-containing substance. In general, the method includes providing a sample of a hydrocarbon-containing material and analyzing the hydrocarbon material' to determine the type of hydrocarbon to be extracted, <34584> A formulation for extracting a hydrocarbon-containing organic shell from a hydrocarbon material is provided, wherein the § ‧ weekly formulation is a function of the construction type and the size of the particulate hydrocarbon material. In general, the formulation comprises at least about, for example, a volume of shod alcohol and at least about (four) a percent of pure alcohol. Then, the amount of pure alcohol and pure alcohol in the formulation is adjusted based on the parameters indicated above. In general, although the methods indicated above provide a good starting point for determining the desired formulation for the extraction of various hydrocarbon-containing materials, for other hydrocarbon-containing (IV), and under certain operating conditions, The most suitable composition for the determination of liquid turpentine can be performed either as a series of statistically designed experiments or as a series of experiments based on optimization methods. t As shown in Table 1, the specific formulation used to extract, liquefy, and/or dissolve carbonaceous organic compounds from tar sands varies based on particle size. In some embodiments, a method for extracting a turpentine liquid containing a hydrocarbon organic material from tar sands, comprising adjusting the blending: the amount of the 4 alcohols and the reduced alcohols as the extracted carbon-rich A function of the size of the solid particles of the gas compound. In other embodiments, if the hydrocarbon-containing organic particulate matter comprises low grade coal or oil? Rock, in the pine knot: the amount of alcohol in the liquid is increased, and the amount of /3-propanol in the turpentine liquid is reduced. In other embodiments, if the organic particulate matter of the human Shishan gas compound includes tar sands, the amount of alcohol in the turpentine oil is reduced, and the amount of pure alcohol in the turpentine liquid is increased. In other embodiments, if the hydrocarbon-containing organic particulate matter comprises tar sands and the average diameter of the particulate matter is less than about 4.76 meters, the amount of spur alcohol in the turpentine liquid is reduced, and 134584 - 38- 200914599 The amount of eucalyptus alcohol in turpentine liquids is increased. In other embodiments, if the hydrocarbon-containing organic particulate matter comprises tar sands, and the average diameter of the 2 microparticulate matter is greater than about 丨 吋 (1 mesh), the amount of terpineol in the turpentine liquid is Reduced, while the amount of sulphuric acid in the turpentine liquid is increased. Particle size (mesh/mm diameter) Phytosterol/3-Supinol a-/hetero-- <4 mesh (4.76 mm) 30-50% volume 35-55% volume 10% volume 1 mesh (1 inch II Inch) -4 mesh (4.76 mm) 40-60% volume 30-50% volume 10% volume>1 mesh (1 Yingyu) "50-70% volume 25-45% volume 10% volume 仏 仏 Exing" As shown in Figure A, the formulation for the extraction, liquefaction and/or dissolution of coal is dependent on both the particle size and quality of the extracted coal. In the preparation of a turpentine liquid for the extraction of organic matter containing hydrocarbons In a specific embodiment, if the carbonaceous compound-containing material comprises anthracite, bituminous coal or other higher-grade coal, and the micro-material has an average diameter of less than about 15 mm, it is in the turpentine liquid. The amount of alcohol in the turpentine oil is increased. In other embodiments, the hydrocarbon-rich micro-materials include anthracite, bituminous coal or other high-grade coal, and the microparticles have a diameter of more than about 0.84 mm. , in the turpentine liquid, the shouting alcohol is reduced, while in the pine The amount of alcohol in the oil liquid is increased. = 134584 • 39- 200914599 Another specific implementation, if the hydrocarbon-rich particulate matter includes low-grade coal, and the average diameter of the particulate matter f is less than about mm Then, the amount of alcohol in the turpentine liquid is reduced, and the amount of pure alcohol in the turpentine liquid is increased. In another embodiment, if the hydrocarbon-rich microparticle material comprises a lower grade, and the microparticle material has a diameter of more than about 〇42 mm, the amount of the beneficial alcohol in the turpentine liquid is It is reduced 'and the amount of terpineol in the turpentine liquid is increased. Table 2, formulation for j-grade coal extraction, particle size based particle size (mesh/mm diameter) α-terpineol/5-supleol (X-/β- 稀稀^' < 100 mesh (0.149 mm) 45-65% volume 35-45% volume 10% volume h---- 〇% volume 20 mesh (0.841 mm) _ 100 mesh (0-149 mm) 50-70% volume 20-40 % 10% by volume 〇% by volume> 20 mesh (0·841 mm) 60-80% by volume 15-35% by volume 10% by volume 〇% by volume Table 3. Formulation for low-grade coal extraction based on particle size Particle size (mesh/mm diameter) α-terpinelite-3⁄4 alcoholene other <200 mesh (0.074 mm) 60-80% volume 10-30% volume 5% volume 0% volume 40 mesh (0.420 mm) _ 200 mesh (0.074 mm) 70-90% volume 5-25% body ^^ 5% volume 〇% volume

134584 -40- 200914599 > 40 mesh (0.420 mm) 75-95% by volume 0-20% by volume 5% by volume 〇% volume similar to the above for the extraction of tar sands, as shown in Table 4, for oil The composition of the stroke, liquefaction and/or dissolution of the shale is based on the particle size. In a specific embodiment of the method for preparing a composition for extracting a hydrocarbon-containing organic material, if the particulate matter of the rich compound comprises oil shale and the average diameter of the particulate matter is less than about 〇 mm, then The amount of saponin in the turpentine liquid is reduced, and the amount of pure alcohol in the turpentine liquid is increased. In another embodiment, if the hydrocarbon-rich microparticle material comprises oil shale, and the microparticle material has a diameter greater than about 0.42 mm, the 仏 品 罝 在 in the turpentine liquid is reduced. The amount of terpineol in the turpentine liquid is increased. Table 4· for oil sheet Wu Gai 夕 夕 铺 约 约 约 约 约 约 约 约 品 品 品 品 品 - - - - - - - - - - - - - 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 200 % volume 10-30% volume 5% volume 体积% volume 40 mesh (0.420 mm) _ 200 mesh (0.074 mm) 70-90% volume 5% volume 〇% volume > 40 mesh (0.420 mm) 75-95% volume 0-20% by volume 5% by volume 〇% by volume — The extraction of crude oil is likewise dependent on the type of crude oil being extracted, liquefied and/or dissolved. As shown in Table 5, the formulation for extraction, liquefaction and/or dissolution of crude oil is the letter between the particle size and density quality of the extracted crude oil. 134584 -41 - 200914599

number. The method comprises providing a turpentine liquid formulation comprising at least 50% by volume of alpha-sterol and at least 20% by volume of /5-terpineol; adjusting alpha-terpineol and /9-terpineol in a turpentine liquid formulation The amount is based on the temperature of the liquid hydrocarbon being extracted. In one embodiment, the API gravity of the extracted liquid hydrocarbon is greater than about 22. The amount of α-terpineol in the turpentine liquid is reduced, and the amount of alcohol in the turpentine liquid is increased. In another embodiment, if the extracted liquid hydrocarbon has a gravitational gravity of less than about 22, the amount of α-terpineol in the turpentine liquid is increased, and the ginseng liquid is added to the turpentine liquid. The amount of alcohol is reduced. As used herein, light oil has a enthalpy of at least about 31 Torr and a medium crude oil has an API of about 22. With about 31. Between the heavy oils has a Αρι between about 1〇0 and about 220, and the extra heavy oil has a Αρ〗 of less than about 1〇0. Table 5. Formulations for crude oil extraction based on API density Crude oil type CK-feol alcoholic alcohol alpha-/々-pinene Other light/medium crude oil (API greater than 22°) 40-70% by volume 30- 40% volume 10% volume 10% by volume weight / extra heavy crude oil (API less than 22 °) 50-70% volume Eo-35% volume - ___ - 10% volume 5% by volume in another - aspect, provide - A method for enhancing the recovery of a turpentine liquid from a liquid hydrocarbon-containing organic material from a subsurface structure is prepared. This side includes providing a formulation comprising at least 50% by volume of α, terpineol and at least % by volume of "_" alcohol, and adjusting the amount of pure alcohol and pure alcohol in the formulation to the geological characteristics of the subsurface structure Based on the other side, the Department provides a 4-day human, and & substance for the self-contained liquid hydrocarbons "Do not remove and/or recover hydrocarbons, where the composition contains 134584 -42 - 200914599 > - a compound selected from natural turpentine, synthetic turpentine, mineral pine, 1, oil, 4 thin, pure dilute "" alcohol, pure alcohol, (four) alcohol, terpene resin, shoddy, minus Dilute, r_(d) or a mixture thereof. In the specific embodiment, it is used to remove and/or recover a hydrocarbon package: at least one compound... geraniol, qing, dipenta-4 Heyi 8-diene, Nopo (n〇p〇1), decane, hydroperoxide 2- decane, hydrazine dihydrate hydrate, 2-nonanol, dihydromyristin (mycen〇1), isoborneol, p- Peppermint '8-alcohol, 1 decyl acetate, citronellol, p-menthyl acetate, 'hydroxydihydro citronellal' sterol and mixtures thereof. In still other embodiments, the composition for scavenging and/or recovering hydrocarbons comprises at least one compound selected from the group consisting of aniseed brain and terpenes; p-methylisopropyl stupid, anisaldehyde, 3'7- Methyl-1,6-octanoyl, isoindole acetate|ester, basil, bellerol, bellerol, 2-methoxy-2,6-dimethyl-7,8_epoxy Base octane, camphor, lemon road, 7-decyloxydihydro-citronellal '10_camphorsulfonic acid, citronella dish, menthone, and mixtures thereof. In one embodiment 'this composition contains at least A compound derived from alpha-pinene, terpenes, alpha-terpineol, and stone nominal alcohol. In another specific embodiment, the composition comprises at least 25% by volume alpha-terpineol or rash Terpineol. In another aspect, a method of removing and/or recovering hydrocarbons from a container containing liquid hydrocarbons is provided. The method includes contacting the interior of the container with a hydrocarbon scavenging composition, the composition Included in at least one compound selected from the group consisting of alpha-pinene,/5-pinene, alpha-terpineol, and terpineol to produce a mixture' The intermediate mixture comprises a liquid hydrocarbon residue and a hydrocarbon scavenging composition. The mixture is recovered and removed from the vessel. In a particular embodiment 134584 - 43 · 200914599, the scavenging composition comprises at least 25% by volume __品品醇或/3-terpineol. In certain other embodiments, the scavenging composition comprises at least 25% by volume of terpineol and at least 25% by volume of terpineol. Example 1. In this example, the 'system is made from the Pittsburgh deposit (Washington)

The coal of County, Permsy Wania) is liquefied with the reagent α_terpineol. Coal sample is obtained from

The Coal Bank of Pennsylvania State University provides the following approximate analysis of coal samples; 2.00% by weight of water just received, 9.25% by weight of dry ash, 38.63% by weight of anhydrous volatiles and 5〇12 % by weight dry fixed carbon. The coal sample has a particle size of about 60 mesh. About 6 grams of terpineol was gently added to about 3 gram of coal sample that had been placed in the extraction vessel, thus giving a reagent-to-sample ratio of 2 to 1. The extracted but not tightly sealed extraction vessel containing the formed terpineol and coal mixture is maintained at about 96. Under constant temperature, it is constantly being mixed. Without boiling the alcohol, the pressure in the extraction vessel is still maintained at a pressure slightly below about χ1χ1〇5 Baska (1 atm). About 3G points! Thereafter, the mixture was filtered, and the coal particles remaining on the reactor were washed with ethanol' and dried to constant weight. Based on the weight loss, the conversion rate of the coal sample, i.e., the degree of liquefaction, was determined to be about 68% by weight. Example 2. This example is identical to Example 1 in all aspects of Jiugu & 仏4·m & only Wii, except for two. After the temperature was maintained at about 96 ° C, such as eight pulls, a card, and a force for 30 minutes, as in Example 1, a coal sample and terpineol were contained. T knows that the pawn is about 135. (The temperature in the extraction vessel is maintained for another 30 minutes at the temperature remains 134584 200914599 at an environmental pressure slightly lower than about 1. 〇lxl 〇 5 Bass (1 atm). Conversion rate of coal sample 'The degree of liquefaction is determined to be about 70% by weight. Example 3 · The coal samples used were obtained from the same source and have the same approximate analysis as used in the previous two examples. About 31 grams Terpineol was added to about 31 grams of coal sample in the extraction vessel. The mixture was held for about 3 minutes at an ambient pressure of about 96. Torr slightly below about L01 x 105 Baska (1 atmosphere). The conversion rate of the sample, meaning the degree of liquefaction, after f' filtration, washing and drying, as carried out in the two previous examples, was determined by weighing the sample to be about 71% by weight. Example 4. This example was identical to Example 3 except that about 3% by weight of α-terpineol was replaced with hexane to provide an agent comprising 70% by weight of α-terpineol and 3% by weight of hexane. This will reduce the conversion rate, which means the degree of liquefaction, to About 1.3% by weight. Example 5 · The source and approximate analysis of the coal sample of this example, and the experimental conditions of temperature, pressure and reagent-to-sample ratio, the same as the actual (J. However, extraction The duration is reduced from about 3. minutes to about 2 knives. In addition, about 30% by weight of 1% terpineol is replaced by 丨-butanol, provided. Contains 70% by weight of terpineol and 3 〇 weight %1_ Butanol reagent. The amount of coal liquefied is only about 〇3 gram, which is equivalent to about 1.0% by weight of conversion. Example 6. This example uses the source and approximate analysis of the coal sample and the temperature of the extraction, The pressure and the duration of the day are the same as in Example 3. However, the amount of coal sample used is about 25 grams, and the reagent contains _gram (10% by weight) of stilbene alcohol and about 6 grams (20% by weight). The liquefied coal containing 7 ounces of sucrose and 3 ounces of xylene is about diced, phase 134584 • 45 · 200914599 is about 40% by weight of conversion. Example 7. In this example, the coal from the Wyodak deposit (Campbe U C_ty, Wyoming) is liquefied with reagent genidol The coal sample was obtained from (10) the coal bank of the State University of California, which provided the following approximate analysis of the coal sample. '2630% of the water just received, 7.57% by weight of dry ash ^44.86% by weight Anhydrous volatiles and 47.57% by weight of dry fixed carbon. ", the particle size of the sample is about 2 mesh. About (6) grams of terpineol is gently added to about 3 gram of coal sample that has been placed in the extraction vessel. The ratio of the reagent to the sample is about 2 to 1. The capped, but not tightly sealed, extraction vessel containing the mixture of the stomatol and the coal is maintained at a temperature of about 96. And constantly mixing. Do not make α_; ^ alcohol alcohol Fo Teng, the pressure in the extraction container is still maintained at an environmental pressure slightly lower than about 1Ό1χ1〇5 Baska (1 atmosphere), · 'spoon 30 knife know, will draw the container The mixture was filtered and the coal particles remaining on the filter were washed with ethanol and dried to constant weight. Based on the weight loss, the conversion rate of the coal sample, meaning the degree of liquefaction, is

The enthalpy was measured to be 75% by weight. Example 8. The experiments in this example were carried out under the same conditions as the previous examples except for one. About 15 g of α-terpineol, instead of about 6 g, was added to about 3 g of coal sample as described in the example of W, so that the ratio of reagent-to-coal was 〇·5 to 1 . The conversion of the obtained coal sample, i.e., the degree of liquefaction, was reduced from about % by weight obtained in the foregoing examples to about 69% by weight. Example 9. In this example, about 3 grams of oil shale from the Green River area of Colorado was dissolved in about 9 grams of alpha-terpineol, thus obtaining reagents - 134584 -46- 200914599

The sample ratio is 3 to 1' to extract kerogen (organic matter) and/or dicedar (organic matter) therefrom. The organic carbon content, including both volatility and R carbon, was determined to be about 22.66% by weight by a certified analytical company. Two experiments using an oil shale sample with a particle size of 6G mesh were ordered at ambient temperature "4 force individually at about 25 ° C and slightly below about Ι. ΟΙχΙΟ 5 Baska atmosphere house." The weight loss is measured after weighing, washing with ethanol and drying = after ', by weighing. These losses are about 9 weight percent after about 30 minutes and about 17 weights after about 45 minutes. %. From this weight loss, the organic matter means the conversion of kerogen and/or centrifugation, meaning that the degree of extraction is estimated to be about 4% by weight for the former and about 5% by weight for the latter. Example 10. This example is repeated for the previous example except for a single experiment lasting about 15 minutes at a temperature of about 96. (:, instead of about 25 ° C. The reset loss of the oil shale sample is about 12% by weight. Corresponding to the conversion rate of kerogen (organic matter), meaning that the degree of extraction is about 53% by weight. Example 11. In this example, the asphalt (organic matter) in the tar sand of Canada Alberta is dissolved. And extracted with commercial grade synthetic turpentine. The tar sand sample was obtained from Albe. The rta study meeting provided the following approximate knife analysis for the sample, 84.4 weights of 1% anhydrous solids, 116% by weight of anhydrous bitumen, and 4.0 reset% of water just received. About 3 grams of synthesis The turpentine is gently added to about 15 grams of tar stone in the treated but not tightly sealed extraction vessel. The sample is used in a ratio of about 2 to i by weight of the reagent to the sample. The resulting extraction vessel of the synthetic turpentine and tar sand mixture is maintained at a constant temperature of about 96 C and continuously stirred. Without boiling the synthetic turpentine, the pressure in the extraction vessel is still slightly lower than about 134584 -47 - 200914599. At ambient pressure of 101 χ 1 〇 5 巴斯 ^ 大 大 大 大 大 。 。 。 。 。 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约 约Based on the weight loss, the conversion of the bitumen obtained from the tar sand sample, that is, the degree of extraction, was determined to be about 1% by weight.

Example 12. In this example, about 60 grams of a tar sand sample from the same source having the same approximate analysis as the actual T described above, by substituting an a-terpineol Commercial grade synthetic turpentine extraction. The resulting reagent-to-sample ratio is Ubl instead of 1 as in the previous examples. The test is carried out at a temperature of about 96 ° C for about 3 minutes at an ambient pressure slightly below about 1. Glxl G5 Baska (1 roll). The conversion of the bitumen (organic matter) in the tar sand sample, i.e., the degree of extraction, is determined to be about % by weight. ^ In this example, about (8) grams of tar sands sample, II from about the same source, having the same approximate analysis as the previous two: examples, is about 60 grams. Use, and σ into loose oil extraction. Therefore, the ratio of the reagent_pair to sample formed is about 1g, and the experimental system is at about the temperature of the order, and about 3g minutes under the environmental waste force of less than w1〇5=card (1 atm). . The conversion rate of bidet (with broadcast) in the tar sand sample, that is, the degree of extraction, is about 70% by weight. Example . This silver accounted for the experiment, but the reagent-to-^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^^ 1. There will be:: Extracted by about 3 grams of commercial grade synthetic turpentine.沥月(有机物质) 卞# Conversion rate, meaning the degree of extraction, is about (10) wt% reduction in weight percent obtained from Example 9 134584 -48- 200914599. Example 15 j- • The experiment in this example was repeated for the previous example using a test of terpineol m I拗 to make the commercial grade turpentine. In the tar sand sample, the full case ", conversion rate, that is, the degree of extraction, is about 70% by weight in the case of the previous violation." Spoon Ge Yue, J describes the example 16 as in this example The experiment is slightly below about 1 (),

Card: 1 atmosphere) at ambient pressure, with the same approximate analysis of the tar sand sample from the same source: = tar oil sand, 2 = gram commercial grade synthetic turpentine added to about 6 gram tar sand sample In the case, the ratio of Insson to Na is about 1 to 1. The sample was maintained at about 651 for about 3 minutes with commercial grade Δ, i.e., followed by a force of about 5 minutes at about 5 minutes. The tar sand sample is filtered, washed, dried, and t heavy. Based on the weight loss, the conversion of the pitch (organic shell) in the tar sand sample, that is, the degree of extraction, was determined to be about 70% by weight. The experiment in this example was repeated with the previous example experiment using 1 terpineol instead of commercial grade synthetic turpentine. The conversion rate of the bitumen (organic matter), i.e., the degree of extraction, is increased from about 7% by weight to about 90% by weight of the foregoing examples.曰〇 Example 18. In this example, a weight of about 30 grams, obtained from the same source, having the same approximate analysis of tar sands as in Examples 11 to ,, at a temperature of about 96 c, at a slightly lower temperature It was extracted with a liquid containing about 20 g (80% by weight) of α-formol and about 5 g (2% by weight of toluene) under an ambient pressure of about 1〇1χ5〇5 kPa (1 atm). The duration of the experiment (reaction or extraction time) was about 30 minutes. The weight loss of the sample was about 1 〇 2 g. From this weight loss, the conversion rate of 134584 - 49 - 200914599 (organic material shell), which means the degree of extraction, is estimated to be about 33% by weight. Example 19. All three tar sand samples, all from the same source, have the same approximate analysis as used in all of the previous examples using tar sands at a temperature of about 15 C, at slightly less than about 1 〇 1 χ 1 〇5 Baska atmospheric pressure) % i brother pressure, by containing different amounts of α_terpineol and ethanol extraction. The duration of each test (reaction or extraction time) is 15 knives for each tar sand sample. The first sample was subjected to a mixture comprising about 0 g (% by weight) of α-terpineol and about 15 g (1% by weight) of ethanol, i.e., extracted with pure ethanol. The second sample was extracted as a mixture comprising about 7.5 grams (50% by weight) of terpineol and about 75 grams (9) by weight of 1% ethanol. A third sample was extracted with a mixture comprising about grams (% by weight) of terpineol and about 3 grams (20% by weight) of ethanol. The weight loss of the telling (organic matter) in the three samples, and the estimated conversion rate, that is, the degree of extraction, is about 0.2 g (1.0% by weight) for the first, second and third samples. ), 0.6 g (3. % by weight) and 〇 · 9 g (4.5 weight. Example 20) Dissolving irregular shaped particles of commercial grade asphalt having an average size of about 15 mm, and The alcohol is extracted under an ambient pressure of about 22 in its environment at a pressure of slightly less than about 1.0 llO5 Baska (1 atm). The first sample having a weight of about 20 g is dissolved and about牝 萜 萜 萜 萜 醇 萃取 萃取 , , 萜 萜 萜 萜 萜 萜 萜 萜 萜 萜 萜 萜 萜 萜 萜 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种 第二种The experiment was conducted to simulate the dissolution and extraction of heavy crude oil, which has a tendency to contain asphaltenes, just like asphalt. Example 21. In this example, the system is made from the same source, as used in all 134584 -50- 200914599 : bitumen in the tar sand of the same approximate analysis used in the previous examples of oil sands The substance is dissolved and taken up with two vegetable oils, soybean oil and corn oil. The vegetable oil can be completely miscible with the turpentine liquid. In the first experiment, a tar oil sample weighing about 15 grams is about 5%. At a temperature of about less than about 〇lxl 〇5 kPa (1 atm), blend with about gram of soybean oil and continue to stir for about 20 minutes. The weight loss is about 5 grams. From the weight loss, the conversion rate of the asphalt in the sample, that is, the degree of extraction, is estimated to be about 3.3% by weight. In the first experiment, a tar sand sample having a weight of about 5% is about 175. At a temperature of about 〇ΐχΐ〇5 巴斯5 Bass (1 atm), blend with about 60 grams of corn oil and stir for about 30 minutes. The weight loss is about 4.8.克, from the weight loss 'the conversion rate of indigo in the sample', that is, the degree of extraction is estimated to be about 12% by weight. Example 22. Two tests were carried out on Berea sand and gravel core samples. To determine the effect of reagent injection on the recovery of oil from the sand core. After 6 to determine the oil recovery from the oil field has been subjected to water inundation to the limit, due to 〇; - sterol sterling caused by the incremental oil recovery. The selected sand core contains 9 force 1 ml laboratory oil simulation crude oil. Submerged with water containing 3.0% potassium chloride solution will produce 4.6 liters of oil. Five (3) pore volumes of α_terpineol injection will produce an additional 3.61 liters of oil, thus leaving the core less than 8 〇% The oil is left in the original volume. The second test is designed to represent the increased recovery and is predictable from the unused reservoirs injected with alpha-best alcohol. The selected sand core contains 8 85 hair liters. The oil is simulated to simulate crude oil. The oil production begins after about 5 pore volumes of α_youpin, which lasts until 3-5 pore volumes; 134584 -51- 200914599 volume of terpineol after injection 'Therefore the sand core is low but 'most oils are recovered in only 2.5 pores. A total of 7.94 ml of laboratory oil was recovered and left in the original volume at 7.5% oil. In the -test, various ratios of turpentine liquid to sputum oil sand samples were tested. The turpentine oil system of each experiment provided below has the same formulation' wherein the composition comprises about 60% by volume of alpha terpineol, about 邡% by volume of reduced alcohol, and about 20% by volume of terpineol. Tar sands are from Carja

Different mixtures of Alberta ore have a bitumen content of about wt% and a water content of about 4.5 wt%. All experiments were carried out at atmospheric temperatures. As shown in Table 6 below, traversing all the ratios provided below (meaning that the proportion of turpentine liquid tar sands ranges from 1:2 to 2:1), the recovery of hydrocarbons from tar sands results in good hydrocarbons. Recycling and almost no discernible difference. Regarding the temperature under extraction, the optimum temperature for the extraction, dissolution and/or liquefaction of hydrocarbons from tar sands is 65t:. As indicated in this table, the amount of hydrocarbon recovered is reduced at about 130 °C. However, it should be noted that increasing the temperature of the extraction solvent for certain solids from which it is particularly difficult to recover hydrocarbons increases the amount of hydrocarbons recovered. Finally, it was confirmed that the exposure time had almost no effect on the amount of material to be extracted. a & Because the minimum extraction time was 20 minutes, it was considered that the hydrocarbon extraction system for the self-tar sands exceeded the appropriate amount. 134584 -52- 200914599 Table 6 Weight of tar sand, weight of extractable HC, weight of extracting solvent, ratio of tar to solvent, amount of HC extracted, gram of extracted HC percentage temperature, °C exposure time, minute 15 2.0 30.0 1:2 3.2 161 96 20 60 7.8 120.0 1:2 5.4 69 96 30 60 7.8 31.6 2:1 9.6 123 96 30 60 7.8 60.0 1:1 7.6 97 65 30 60 7.8 60.0 1:1 4.0 51 130 30 60 7.8 60.0 1:1 6.3 80 65 30 Other experiments used an alternative solvent means ethanol and corn oil, which contained about 60% by volume of α-terpineol, about 20% by volume /3-terpineol and about 20 volumes. Comparison of % 7-terpineol compositions. As indicated in Table 7 provided below, the performance of ethanol and corn oil was surprisingly substantially lower than comprising 60% by volume of alpha-terpineol, about 20% by volume of terpineol and about 20% by volume. - a composition of terpineol. For example, although this terpineol composition achieves complete or nearly complete extraction of extractable hydrocarbons, ethanol produces only 10% recyclable hydrogen compounds, while heated corn oil produces only 33% recoverable hydrogen compounds. . Table 7 Chemical tar sand weight, gram extractable HC weight, gram extraction solvent weight tar sand to solvent ratio extracted HC amount, gram extracted HC percentage temperature, °C exposure time, minute ethanol 15 2.0 15.0 1 :1 0.2 10 15 15 Corn oil 30 3.9 60.0 2:1 1.3 33 175 30 60/20/20 Terpineol 60 7.8 60.0 1:1 7.6 97 65 30 60/20/20 Terpineol 60 7.8 31.6 2:1 9.6 123 96 30 As shown in Table 8 below, the performance of various turpentine liquid formulations is provided. 134584 -53- 200914599 includes turpentine liquid containing only alpha-terpineol and containing terpineol in combination with various known organic solvents. Formulation. The first three compositions set forth in the table include alpha-terpineol, /3-terpineol, and r-terpineol. For example, the first composition comprises about 60% by volume of terpineol, about 30% by volume of 3-terpineol, and about 10% by volume of r-piperol. These results surprisingly show that when the concentration of the alcohol increases, the performance of the turpentine liquid increases until the turpentine liquid contains approximately 70% alpha-terpineol, achieving complete extraction of the hydrocarbon material from the tar sand sample. The point. The second set of data was presented for the extraction of tar sands with hydrocarbons from pure terpineol. As shown, achieving greater than 100% extraction may be due to inconsistencies in the hydrocarbon content of the sample. However, these results generally confirm the surprising result that alpha-terpineol can extract substantially all recoverable hydrocarbons from the tar sands sample. Finally, the last data provided in Table 8 illustrates the effectiveness of a hybrid system of alpha-terpineol with known organic solvents. As shown, the substantially complete recovery of the recoverable hydrocarbon is achieved by a composition comprising a ratio of alpha-terpineol to ethanol in a 1:1 ratio. This is surprising because pure ethanol removes only about 10% of the total recoverable hydrogen absorbing compounds. In addition, a blend system containing alpha-terpineol versus terpene, whether in a ratio of 1:1 or 3:1, still results in 77% and 92% recovery of the total recoverable hydrocarbon. This is an unexpected result. Table 8 Chemical composition tar sand weight, gram extractable HC weight, gram solvent weight tar sand to solvent ratio The amount of HC extracted, gram of extracted HC percentage temperature, °C exposure time, minute 60/30/10 萜Alcohol 60 2.0 60.0 1:1 7.1 91 96 30 134584 -54- 200914599

40/30/20 60 7.8 60.0 [Ϊ1^ R-1 Terpineol--1 60 96 30 70/20/10 60 7.8 60.0 Terpineol TM"------** 101 30 100/ 0/0 60 7.8 60.0 ίΐΤ- Terpineol 128 96 30 100/0/0 60 7.8 120.0 — 1:2 ~8J^~ Not intoxicating ITT 96 30 100/0/0 "60 7.8 31.0 — Yi Pin Alcohol Y.6 123 96 30 50% a - 15 2.0 15.0 ~~ Terpineol/50% Ethanol 103 65 30 80% a - 15 2.0 15.0 1:1 Box alcohol/20% Ethanol---- 62 Ί? 15 75% a - 30 3.9 25.0 ττ^τ Zhuang Pinenol/25% Toluene 92 Is 15 50% a - 30 3.9 26.0 —1:0.9 Phytosterol/50% Benzene — 77 96 30 50% a - 30 3.9 26.0 — Ti〇9 Phytosterol/50% Diphenylbenzene**********—~ 61 30 L------ In this patent specification, and especially in ^--- It is surprising that the self-structuring of the carbon-containing material in the carbon-extracting example is the result of the nine-oxygen compound organic matter, in order to uniquely identify the component, rather than the second term of the sound sleeve should be sorted. Any of the components of the 1345S4 •55- 200914599 As used herein, the terms about and the terms should be interpreted as any numerical value within 5% of the numerical value. Again, the description of the terms in the numerical range should be interpreted as both. When used in this context, the explanation For the unique identification of components, and what is specifically ordered. The terms first, second, third, etc., which are included in the upper and lower limits of the range of the approximate and large inclusions, should be used to mean not to limit the components or steps.

DETAILED DESCRIPTION OF THE INVENTION Although the invention has been shown or described in some specific embodiments thereof, it should be understood by those skilled in the art that it is not so limited, and Various changes are readily accepted without departing from the scope of the invention.疋 [Simplified description of the drawings] Fig. 1 is a schematic view showing an example of the recovery of hydrocarbons from tar sands. Figure 2 is a schematic illustration of an embodiment of the recovery of hydrocarbons from oil shale. Figure 3 is a schematic illustration of one of the hydrocarbon recovery units from coal. Figure 4 shows the enhanced recovery of hydrocarbons from subsurface storage tanks. σ initial indication [main component symbol description] 100 rupture 102 turpentine liquid supply 104 pump 106 tar sand sample 108 round 134584 -56- 200914599 110 contact container or extraction container 112 holding the tank 114 multiple platters or Blade 116 outlet 118 filter 120 pump 122 holding tank 124 line 126 second conveyor 200 unit 202 oil shale sample 204 grinder or crusher 206 first conveyor 208 contact vessel 210 turpentine liquid supply 212 inlet 214 Multiple Shallow Discs or Blades 216 Outlet 218 Pump 220 Hold Tank 222 Line 224 Second Conveyor 300 Unit 302 Coal Sample 134584 -57- 200914599 304 Grinder or Crusher 306 First Contact Vessel 308 Turpentine Liquid Supply At 310 Pump 312 Mixing Setup 313 First Contact Vessel Exit 314 Pump 316 Second Contact Vessel 318 A Series of Shallow Discs or Blades 320 Contact Container Outlet 322 Pump 324 Hold Tank 326 Line 328 Conveyor 400 Process 402 Surface 404 Containing 竣Hydrogen storage tank 406 production well 408 injection well 410 line 412 line 134584 -58-

Claims (1)

200914599 Patent Application Range: 1. A method for extracting hydrocarbon-containing materials from a hydrocarbon-containing material, comprising the steps of: providing a first liquid, comprising a turpentine liquid; and a hydrocarbon-containing material, The turpentine liquid connection, the mixture 'and the residual material' extraction extract - the hydrocarbon-containing organic retention material comprises at least - part of the hydrocarbon-containing residue, which is insoluble in the turpentine liquid; The ridge causes the extraction mixture to separate from the residual material; and the extraction mixture is mixed. The first part and the second part, the extraction, and the first part of the character are ordered to take the part... A product stream comprising at least a second metal compound, and the extract 2 comprising at least a portion of a turpentine liquid. * — 2· For example, the method of platinum claim 1, 1 Lj oil-saving, synthetic turpentine, “;:= the oil system is selected from the group consisting of natural pine pure alcohol, heart alcohol: rr: oil, pine oil, coffee, Qing, (d), r- (four) and mixtures thereof "alcohol, (four) resin, (tetra) alkene, according to the method of claim 1, the alcohol, 3-pungene, dipentene (the turpentine oil system is selected from the group consisting of fragrant hydrogen 2-decane peroxide, 萜/广何义 8-diene, nopo (n〇P〇1), decane, (myceno), sterol hydrate, 2-nonanol, dihydromethane Xian alcohol, 艉驷, 、, thin matter: alcohol, acetic acid, - mint,;: ', acetic acid (tetra) diol brewing, lemongrass ' ' search dihydro citronellal, capitol and its mixture 134584 200914599 4 · such as The method of the requester, wherein the turpentine oil system is selected from the group consisting of Baoyue®, decene; p-menthenyl cumene, anisaldehyde, 37-back fragrant, acetic acid iso- vinegar, basilene, and bile rare... Oxy-2,6-dimethyl-7,8-epoxyoctane, rod/class, 2_one early % 'citrate, 7-methyl-one-anthraquinone-citronellal, 10-camphor Sulfonic acid 'citronella 1'. Japanese lanceone, ketone ketone and its mixture 5. According to the method of the requester, wherein the 栌忐φ η π cut < organic substance is a solid f L · body or a + solid, wherein the hydrocarbon-containing material枓 contains many particles, and δ hai particles have an average particle diameter. 6. As requested in item 5, 25 of them. The method of the ninth liquid system is selected from the group consisting of about 0.74 mm to about 7. The method further comprises the step of adding the second liquid to the loose oil liquid. The second liquid system is selected from the group consisting of low carbon fat. A mixture of a group of alcohols, low carbons, low carbon aromatics, aliphatic amines, aromatic amines. 8. The method of claim 7, wherein the second liquid system is selected from the group consisting of ethanol, propane, isopropanol, butanol, pentylene, Gengyuan, hexane, benzene, toluene, and dimethyl strepene 4 , tetrahydronaphthalene, triethylamine, aniline and mixtures thereof. 9. The method of claim 8, wherein the step of contacting the carbonaceous compound material with the turpentine liquid comprises the step of adding water to the temperature of the water point. 10. The method of claim i, further comprising the step of heating the turpentine liquid to a temperature above ambient temperature to about 20 (TC point) prior to contacting the turpentine liquid with the hydrocarbon-containing material. 134584 200914599 n If the request item i is too, the 乂 method, /, the hydrocarbon-containing material 舆 the turpentine oil system in about 50 psi (0.1 atm) to about 5. 〇 xi 〇 6 Baska ( Contact at a pressure of 50.0 atmospheres. 12. The method of claim 1, wherein the method further comprises supplying at least a portion of the second portion of the extraction mixture to the contacting step. The method of C mj, the method of The step includes the steps of: providing an organic substance for X-hydrogenating the port and the turpentine liquid, contacting the underground structure in the organic structure containing the hydrocarbon-containing organic substance, and extracting the carbon-containing material by using the lower structure 14. The method of claim 1, wherein the material of the /, 〒3 slave compound is contacted by the turpentine liquid at a temperature of less than about 300. (: at the temperature. The method of 1, and the materials of the ruthenium compound are contacted by the turpentine liquid at a temperature of less than about 6 〇 t. c 16. The method of the request, wherein the hydrocarbon-containing material is The contact between the hydrocarbon-containing material and the turpentine liquid in the subterranean formation occurs in the subterranean formation; and further includes the step of recovering the extraction mixture through a production well in fluid communication with the subterranean formation, the residual material The spot remains in the subterranean formation. 17. The method of claim 16 which further comprises the step of re-injecting the turtle stream into the injection well during the dry process for further extraction of the hydrocarbon material. [Step 18. The method of claim 16] In the method of claim 1, wherein the turpentine oil comprises at least about 30% by volume of α-terpineol and at least about 5% of the body of the turpentine oil. I5% /3-terpineol. 134584 200914599 20. The method of claim i, wherein the turpentine liquid packaged alcohol is at least 20% by volume with at least 〇3 5 vol% α-萜Between alcohols and alcohols. 21. As requested by the method, turpentine is introduced into the olefin, ton or r_(iv). π3 at least - pure; such as the method of the monthly solution 1 '纟中松油油醇醇,装# α- The ratio of the alcohol to the alcohol is at least about 13:1. ° month, the method of item 1, wherein the turpentine liquid «醢* ® contains the alcohol and the alcohol The method of extracting a chlorocarbon-containing organic material from a material containing a carbon-gas compound, the material of the money compound includes tar sand, including The contact of the hydrocarbon material with the turpentine liquid comprises the steps of supplying the tar sand to the inner portion of the extraction vessel and supplying the turpentine liquid to the inner portion of the extraction vessel for a period of time from the self-contained hydrocarbon The period during which the material extracts a substantial portion of the hydrocarbon-containing organic material. 25. If the method of extracting a hydrocarbon-containing organic matter from a hydrocarbon-containing material, the hydrocarbon material comprises oil shale, the method further comprising the steps of: placing an organic substance containing a hydrocarbon Grinding to produce a plurality of particles that define an average diameter ranging from 4.8 mm to 25 mm to cause the plurality of particles to contact the turpentine liquid. 26. A method of extracting a hydrocarbon-containing organic material from a hydrocarbon-containing material as claimed in the claims; 5; the hydrocarbon material comprising coal, the method further comprising the steps of: 134584 200914599 comprising a hydrocarbon The organic material is ground to produce a plurality of particles that define an average diameter ranging from 0.8 millimeters to _ millimeters such that the plurality of particles are in contact with the turpentine liquid. A composition for extracting a hydrocarbon-containing organic material, the composition comprising at least about 3% by volume of cardol and at least about K) by volume of sterol. %. The composition of claim (10), wherein the composition comprises between (4) and (4) (iv) and a mixture of about 2% and 5% by volume of pure alcohol. 29. The composition of claim 27, which also comprises up to 2 steroidal saponin. 3. The composition of claim 27, which also comprises at least as high as 5% by volume - a species selected from the group consisting of natural turpentine, synthetic turpentine, mineral turpentine '4 ene, pure dilute, pure olefin, pure olefin And (4) to conclude. 31. The composition of Γ Γ 27 27 '' also contains at least one compound selected from the group consisting of t-cut, 3. (four), dipentene, and Niang II. Novo (4) 01), a, 虱peroxidation 2, b alcohol Hydrate, 2 shop, dichloromethane === isoborneol, p. mint, acetic acid pure dicimolol, acetic acid p-menthyl_8_ base mixture. 7 citronella dish, capitol and its 32: the composition of claim 27, which also comprises at least one compound selected from the group consisting of large scented brain, scorpion, p-methyl isopropyl benzene, mi mr_si, Basil, Benedict, 'Leh, 曱, 曱, 曱, | | 氡 氡 氡 氡 氡 樟 樟 樟 樟 樟 樟 樟 樟 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香 香Menthone and its mixtures. j 134584 200914599 33. The composition of claim 27, which also comprises up to about 1% by volume of gemene and up to about 10% by volume of /5-decene. 34. The composition of claim 27, wherein the composition further comprises between about 3 and 7 volume percent of alpha-terpineol and between about 25 and 55 volume percent of terpineol. 35. The composition of claim 27, wherein the composition further comprises between about 45 and rib volume % of alpha-terpineol and between about 15 and 45 volume percent of terpineol. 36. The composition of claim 27, wherein the composition further comprises between about 4% and % by volume of alpha-terpineol and between about 3 and about 4% by volume of terpineol. 37. The composition of claim 27, wherein the composition further comprises between about 5 and 7 volume percent of π terpineol and between about 30 and 4 volume percent of terpineol. 38. The composition of claim 27, which further comprises up to about 5% by volume 4 (four) up to about 5% by volume. 39. The composition of claim 27, wherein the composition further comprises between about -4% by weight of alpha-terpineol and up to about 3% by volume of terpineol. 40. The composition of claim 27, wherein the composition of the group of beans comprises "Ming, Τ, σ, and σ also comprises between about 60 and 95 vol% of alpha-terpineol and up to about 3% by volume of the sputum product. 41. A method for extracting a carbon-nitrogen-containing organic material from a material containing a stone-containing compound, the method comprising the steps of: providing a first liquid comprising a turpentine liquid, the turpentine liquid comprising π-terpineol; The hydrocarbon material is contacted with the turpentine liquid such that an extraction mixture is formed and a residual material is formed. The extraction mixture comprises to a portion of the hydrocarbon-containing organic material and the turpentine liquid, and the residual material comprises at least a portion of the Insoluble in shale gas compound material 134584 200914599 A substance which is insoluble in turpentine liquid; and separates the extraction mixture from the residual material. 42. The method of claim 41, further comprising the step of separating the extraction mixture into carbon a hydrogen product stream and a recycle stream, the hydrocarbon product stream comprising at least a portion of the hydrocarbon-containing organic material, the recycle stream containing A portion of the turpentine liquid. 43. The method of claim 42, further comprising the step of recycling the recycle stream to contact the hydrogen-containing compound material. 44. Recycling a material from a solid or semi-solid hydrocarbon-containing material A hydrocarbon-containing organic substance device comprising: a turpentine liquid supply, comprising a turpentine liquid containing a beneficial alcohol, an organic substance for extracting a hydrocarbon-containing material from a hydrocarbon-containing material; a contact container, the contact container Having a first inlet through the first inlet in fluid communication with a turpentine liquid supply, the contact vessel being operable to receive a hydrocarbon-containing material in the interior portion through the second inlet, contacting The container is operable to retain the hydrocarbon-containing material and the turpentine liquid in an interior portion of the contact vessel for a predetermined amount of time operable to form the extraction mixture and the residual material, the extraction mixture comprising at least a portion of the carbonaceous material An organic substance of a hydrogen compound and a turpentine liquid, the residual substance comprising at least a part derived from carbon An insoluble material of a bismuth compound material that is insoluble in the turpentine liquid; the contact vessel includes a first outlet for recovering the extraction mixture from the contact vessel, and a residual outlet for recovering the residue from the contact vessel 134584 200914599 second outlet of the substance 'contact Stirring; the hand' is operable to allow the mechanical retention of the tank, the holding tank is connected through the body, wherein the tank is kept, the I, and the extraction mixture of the contact vessel, the coffin is made to receive from the contact τ official line bag cup, gold over to keep the tank; and the German 'to prevent solids collection, for collection. Material. Residue of the second exit of each unit 45. As requested in item 44, Further, the separation container is a mixture of an organic substance that receives the extraction mixture and a turpentine liquid to hydrogenate the carbon. 46. The apparatus of claim 44 is further advanced. Spoon. The circulating flow of the turpentine liquid, $: includes a turpentine liquid for receiving the return contact volume from the separation vessel. The flow is operable to bring the separation capacity 47. The device of claim 44 is _^~' for repetition use. Designed to reduce hydrocarbon-containing hydrogenation/composites = including a grinder that is contacted with liquid turpentine. The size of the bucket is the same as that of the contact vessel. 48. The apparatus of claim 44, wherein the step further comprises a plurality of containers being a rotary tilt filter, and the contact time M of the composite material controls the turpentine liquid With a charcoal-containing hydrogen 49 such as a tea slice or a plate. The apparatus of claim 44, wherein the setting of the contact vessel comprises transporting the hydrocarbon-containing material to the apparatus of claim 44, wherein the material of the hydrocarbon is loosened with 松. The touch container advance step includes a setting for mixing P' from the liquid. 134584 200914599 Where the second contact container of the device of claim 44, the dragon is connected to the first contact Rongsong: the entry of the oil liquid and the material: use: pick, take the first _ out of the mixture; v Partial extraction - Λη. Used to remove the second outlet A from the mixed volume to + ritual residue at least the first contact container and the middle two contact container line 52. If requested The devices are connected to them. Entrance. V ^ includes a filter, a method for recovering a hydrocarbon-containing material including a V-containing substance from a tar sand in a contact vessel, which method obtains a tar sand, which can provide an organic substance for collecting hydrocarbons耠 耠 - 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 种 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触 接触The entrance; make the tar sand sample disc private, 丄, six g / oil liquid contact in the contact container, and ..., oil π sample and turpentine night t t shape stir, resulting in the formation of extract mixed characters, And forming a residual substance, the extract, the β D " compound contains at least a part of the person. The organic substance and the turpentine liquid, the residual substance comprises at least a part of π, - ω & 八 八不洛 substance derived from 隹石石, which is insoluble in the oily liquid, the inlet of the contact container oil liquid L is included to supply the pine knot to separate the extraction mixture from the residual material; to separate the extraction mixture into a hydrocarbon product stream and a turpentine liquid 134584 200914599 Circulating flow 'The hydrocarbon product stream contains at least one Qi θ y °卩And a hydrocarbon-containing organic material obtained from the tar sand; and recycling at least a portion of the turpentine liquid recycle stream to the contacting step; wherein the turpentine liquid comprises terpineol and terpineol. • a method for recovering hydrocarbon-containing organic matter from a pulverized hydrocarbon-bearing oil shale, the method comprising: providing a pulverized hydrocarbon-bearing oil shale; Providing a first liquid 'containing a turpentine liquid; filtering the pulverized hydrocarbon-containing oil shale; feeding the crushed hydrocarbon-containing oil shale into a contact vessel, the contact vessel comprising at least one for supplying a turpentine liquid To the inlet of the contact container; °. The pulverized: hydrocarbon oil shale is contacted with the turpentine liquid to form an extraction mixture and form a residual material, the extraction mixture comprising at least a portion of the hydrocarbon-containing organic material and the turpentine oil; and the residual material comprises at least a portion The insoluble matter derived from the oil shale is not in the turpentine liquid, separating the extraction mixture from the residual material; and the organic substance containing the hydrocarbon in the extraction mixture and the turpentine =: 'to produce hydrocarbons The product stream and the turpentine liquid-based compound product stream comprise at least a portion of the carbonaceous organic compound derived from the powdered and "anti-wind compound oil shale." A small portion of the turpentine liquid recycle stream is recycled to the contacting step -10- 200914599 55. A method for enriching a peptide organic material rich in hydrocarbon-containing coal, the method comprising: (4) collecting carbonitriding to obtain coal, the coal comprising recyclable containing human genus & Organic matter; grinding coal to produce crushed coal; filtering crushed coal; In the crying, ^•4 4 & invading the current „, the contact container includes at least one for supplying turpentine liquid to the skin to meet the turpentine liquid contact two: two extraction _, and the formation of residual substances, extraction The mixture comprises at least a portion of a hydrocarbon-containing organic material and a turpentine liquid, the residual material comprising at least a portion of the insoluble matter derived from coal, which is soluble in the turpentine liquid; separating the residual material from the extraction mixture; The organic material of the hydrocarbon is separated from the turpentine liquid to produce a hydrocarbon product stream and a turpentine liquid recycle stream, the hydrocarbon product stream comprising at least a portion of the organic matter from the coal-containing carbon-nitrogen compound; The J/邛 turpentine liquid recycle stream is recycled to the contacting step. 56. A method of recovering a hydrocarbon-containing organic material from a production well coupled to a hydrocarbon-containing surface under construction, the subsurface construction comprising a hydrocarbon-containing material, the method comprising: providing an injection well, the injection The system is in fluid communication with the subsurface structure; a first liquid is provided, the first liquid comprises a turpentine liquid containing terpineol; 134584 200914599 After injection, and th ΑΛ _ 耵 左 左 松 松 松 松 松 松 松 松 松 松 松 松 松 松• • 八 卞 卞 卞 卞 卞 松 松 卞 液体 形成 形成 形成 形成 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八 八The substance and at least a portion of the turpentine liquid; the extraction mixture from the structure is recovered through the production well; and the extraction mixture is separated to produce a hydrocarbon product stream and a turpentine stream. 134584 -12-