TW200906985A - Inkjet ink for color filter, and color filter using the same - Google Patents

Abstract

The invention provides an inkjet ink for a color filter. The inkjet ink is ejected from a head and generates droplets spread over the entirety of an ink layer forming region. The inkjet ink has excellent curability and excellent adhesion to a substrate. The invention also provides a color filter manufactured by using the inkjet ink. The inkjet ink for a color filter includes (A) a compound that is cured by at least one of an acid and a radical, (B) a pigment, (C) a compound having, in the molecule, a group which has adhesiveness to a substrate, and (D) a solvent. The invention also provids a color filter manufactured by using the inkjet ink for a color filter.

Description

200906985 IX. Inventive description: [Technical field to which the invention pertains] Eight kinds of inkjet inks for forming a predetermined pattern film represented by a enamel knives (color layer) such as a _color filter film, and (10) inkjet inks The color filter produced first [prior art] 々巴应元膜 f

With the development of personal computers, especially the development of portable computers, the demand for liquid crystal displays, especially color liquid crystal displays, has become more and more important. However, due to the high price of the above-mentioned color liquid crystal display, people are demanding to reduce the cost and increase the production rate. The system is color filter and fine in terms of cost, and is required to reduce its cost and improve its efficiency and efficiency. . The color filter film generally has red (R), green (G), and blue (B) color patterns, and the electrodes corresponding to the respective elements of R, G, and B are turned "ON" and "off". (〇FF), the liquid crystal acts as a shutter (the role of "(4)" The light is displayed in color by the respective pixels of R, G, and B. As a method of manufacturing the conventional color filter film, a dyeing method is exemplified. In the dyeing method, first, a water-soluble polymer material as a dyeing material is formed on a glass substrate, and the polymer material is patterned into a desired shape by a lithography process, and then the obtained pattern is immersed in a dyeing bath to obtain a colored color. A pattern of R, G, and B color filter layers is formed by repeating the above dyeing method three times. Other methods include a pigment dispersion method in which a photosensitive resin layer in which a pigment is dispersed is first formed on a substrate by The photosensitive resin layer is patterned to obtain a monochromatic pattern, and the r, G, and B color luminescent film layers are formed by repeating the process twice. As another method of -5-200906985, pigments are further listed. Scattered in a thermohardening tree In the fat, R, G: B j ' is the method of thermally hardening the resin. However, in the above methods, the three colors of B must be repeated three times in the same process, and the::: The same cost of manufacturing

It has been mentioned that the above method has the effect of spraying ink on the surface of the substrate to form a second method (see, for example, Japanese Patent Laid-Open No. 59-75205). + In order to spray the ink on the correct pattern with the ink in the mouth, it is required to be straightforward and stable when ejecting ink from the nozzle. However, if the speed is too fast, the ink at the tip of the nozzle of the ejection head is f. The force of the water droplets is offset, and the interval-time is intermittent. The soil water (1) is clogged, and the ink cannot be ejected. = In addition, the ink is too fast when the ink is colored on the substrate, and the surface of the ink layer is _ undulation after squirting or = Π uniform, not enough. And the speed of silking is too slow, __ j ... process makes it completely dependent, or even if it can be sloppy but inefficient. Therefore, it can be difficult to dry only when shooting performance. The ink is so that the ink layer is completely dependent on it. It also needs moderate drying. It is used as a color filter for color filter films, but if the ink filter for color filter film is poorly dispersed, it is due to aggregation between pigment particles. The nozzle portion of the discharge is clogged. Therefore, when the article is used as (4), the dispersibility also affects the discharge performance of the ink. As a technique for suppressing clogging, a coloring agent is disclosed, -6-200906985A resin composition for a liquid-jet type enamel film having a boiling point of 2 or more at a normal pressure and a solvent having a boiling point of 2 or more thieves (for example, the nozzle tip of the ejection head is difficult to dry, and it is difficult to generate a t-based substrate. After the ink is ejected, the solvent in the drying process of the ink layer and the solvent of the high Buddha point remain until the end, and it is difficult to dry the king, and there is a problem in production efficiency.

The present inventors have proposed a color light-passing film: ink roller, which is characterized in that the ink ink is straightforward and stable when it is ejected from the nozzle, and the pattern of the uniform south is selected, and at the same time, it can be high. Efficiently dry the water... The water contains the binder component, the pigment and the solvent, and the relative: the total amount of the soil = agent is in the ratio of 90% by weight or more (wt%), and the point is: the shoe is fine. c. The vapor pressure at normal temperature is less than or equal to that of the main solvent (refer to the 喷 专利 专利 专利 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' 二 二 二 二 二 二 二 二 二 二Color filter and light film with better enamel. Ink, ρ The color filter film as described below is sprayed with a long time gold. It can be applied to the gap of the black matrix on the substrate for spray coating, and on the substrate. After the ϊ matrix ft water is dripped, the hardening shrinkage is suppressed, and the shape is stably and reproducibly maintained in the black &quot;knife region, and the hardening can be performed efficiently with -7-200906985; the black result A coloring pattern which can be applied by heating or exposure, "solvent contact, or treatment during use, or can not be peeled off from the substrate. Wind,,,, phase damage" SUMMARY OF THE INVENTION The first aspect of the invention is to provide an inkjet ink for color film film which is ejected from a nozzle and diffused into droplets of the entire ink layer. The corner is excellent in inkjet shape flatness and excellent in hard recording and compatibility. Another object of the present invention is to provide a color filter film which is produced by the above-described color filter of the present invention. In the case of a light film, it is obtained by ink, and it has a pixel portion which is excellent in curability and excellent in adhesion to a substrate, and which is not discolored and has high uniformity. The present inventors conducted intensive studies and found that by using a specific The compound having excellent substrate adhesion can solve the above problems, and the present invention has been completed. The method for solving the above problems is as follows: <1> An inkjet ink for a color filter film, characterized in that it contains at least. (Α) a compound which is cured by at least one of an acid and a radical; (Β) a pigment; (a compound containing a substrate-adhesive group in the molecule; and (D) a solvent. As described in the above &lt;1&gt; The inkjet ink for a color filter film further contains a compound which generates at least one of an acid and a radical. <3> The color described in the above &lt;丨&gt; or &lt;2&gt; Filter film Ink ink for color filter film according to any one of the above-mentioned items, wherein the above-mentioned (the above-mentioned) C) A compound having a substrate-adhesive group in the molecule is represented by the following formula (1): (〇R1)n L-Si (I) κ 3-n

In the formula (I), L represents a monovalent organic group, R1 and R2 each independently represent a hydrocarbon group, and η represents an integer of 1 to 3. (5) The inkjet ink for color filter film according to any one of the above-mentioned (1), wherein the compound (C) contains a substrate-adhesive group in the molecule, Formula (Π) indicates. (〇R1)n L'-si (I I)

V κ 3-n In the formula (Π), 'L' represents a monovalent organic group including a hydrophilic moiety, R1 and R2 each independently represent a hydrocarbon group, and η represents an integer of 1 to 3. &lt;6&gt; The color light-transmitting film described in the above-mentioned =1&gt;~&lt;3&gt;

(Α) -9- 200906985 In the general formula (A), M represents an organic linking group which represents an η+1 valence, and a part which runs J and 鲢, and the work η represents an integer of 卜5, "adhesion 圏, main The m is not an integer of 1 to 3. &lt;7&gt;-a kind of color filter medium, which is used in any of the readings &gt;~&lt;6&gt;, and is used as described above &lt; 1 color pattern. Money material ink formation / k The spray ==; for a color filter film with ink ink, ink (4) ink droplets emitted and dripped, diffused to the entire ink layer Each of the regions is excellent in adhesion to the base (4). (4) R-curing at R. In addition, the inkjet ink used in the color filter film of the present invention has a hardened wire and is excellent in adhesion of the silk sheet, and does not decolorize. The above-mentioned and other objects, features and advantages of the present invention will become more apparent. The preferred embodiments of the present invention will be described in detail below. The following are the following: [Embodiment] The following 'in this specification, 'light' contains wavelengths of visible and invisible areas. And electromagnetic radiation, including microwave radiation e.g., electron rays. That is, "light" specifically means "electromagnetic waves and electron beams having a wavelength of 5 μm or less". In the present invention, the term "(fluorenyl)acrylic group" means either or both of an acrylic group and a methacryl group, and the same "(meth)acrylate" means an acrylate. And any of the decyl acrylates or -10-200906985 olefinic group means propylene fluorenyl and fluorenyl propyl group hereinafter, the present invention will be described in detail. And the color filter inkjet ink comprises at least: (4) a compound which is hardened by at least one of acids; (8) a pigment; (6) a compound having a substrate-adhesive group; and (D) a solvent component sequentially Description. f ί I first 'describes a compound containing a thiol group in the molecule (C) which is a characteristic component of the present invention. &lt;(c) Compound containing a substrate-adhesive group in the molecule> The "combined person having a substrate-adhesive group in the molecule (hereinafter referred to as an "adhesive" as appropriate)" as used in the present invention is included in the molecule. The compound having a functional group excellent in the density of the substrate and soluble in the ink for inkjet ink is not particularly limited. The substrate-adhesive group means that it can be selected from a group consisting of a covalent bond, an ionic bond, a hydrogen bond, a polar interaction, and a valence interaction between the hard material table for the substrate. Any interaction group = specific examples include: ester groups derived from acid groups, acids, acid rust salts, ruthenium metal salts, substituents formed by hydrolysis to form stanol groups, rust groups, phenolic hydroxyl groups, zwitterions One or more partially structured groups selected from the group consisting of a chelating group and a chelating group. The inkjet ink of the present invention is used for forming a colored pattern of a color filter film, and the substrate for the color filter film may be an inorganic material such as glass or a ruthenium substrate, or cellulose diacetate, cellulose triacetate or propyl acetate. Acid cellulose, Ding Ί 1-200906985 Acidic cellulose, cellulose acetate butyrate, nitrocellulose, glycol vinegar, polyethylene, polystyrene, polypropylene, d: vine and other organic resin materials. Among the above substrates, the material of the plate or the material selected from the silk plate is particularly difficult to break the substrate or the stone base, the salt and the base of the base, and the base of the B. In the group consisting of substituents, 1: group is selected: ^ is preferably an ammonium group, which is hydrolyzed to form a thiol hydrazone substituent, a phosphonate group and an ester group thereof, and can be used as a (c) binder. The compound may be, for example, a compound containing a formazan group, and more specifically, an organodecane compound which is not represented by the formula (I). lr-S\ (〇R1)n (1) represents a group, and R1 and R2 are independently

In the general formula (I), the point L is considered to be: 1! ϊ: a group, but from the viewpoint of stability over time. ... ^ ‘its, ,,. The organic group which does not contain an ethylenic double bond in the structure is removed from the viewpoint of the hardenability of the curable composition of the present month at the time of photocuring, and the removal of the portion other than the hardened portion by a process such as development. In view of the above, the formula (1) is more preferably an organolithium compound represented by the formula (11), that is, a decane compound having a monovalent organic group including a hydrophilic moiety. J〇R1)n L'-Si (II) R23-n Independent = a monovalent organic group of a hydrophilic moiety, R1 and R2 each independently represent a hydrocarbon group, and η represents an integer of 1 to 3. - Description of the hydrophilic portion ~ The monovalent organic group 1 contains a hydrophilic moiety which represents a hydrophobic atomic group having a high affinity for a polar substance, for example, an atom such as m. Examples of the hydrophilic portion include a high-molecular substance represented by j, a dipole-polar interaction, a dipole-ion interaction, an ionic bond, a hydrogen bond, and the like. Examples of hydrophilic sites include: the polarity j or the dissociation group of oxygen, gas, sulfur, etc., the test (4), the hydrogen bond acceptor, the part containing a plurality of isolated electricity, and the aggregation of the hydrophilic field, etc. Examples thereof include a hydrophilic group such as a group, an amine group, a aryl group, a thiol group, a thiol group, an amine carbaryl group, an amine carbamide group, a urethane group, a urethane group, and a urethane group. Sulfur urinary tract, guanamine, ester, sulphur, vein, urea, oxy-oxyl, kegan, secondary amine, tertiary =, -(CH2CH2〇)a- A polyvalent hydrophilic moiety such as a hydrophilic portion of the polyoxyethylene moiety (where &amp; is larger than the number of impurities) and a partial structure represented by the following structural formula

COOM -SOM1 〇 0 H 1 -P-OM1 OM2 Divalent hydrophilic part 9 ——P-0— I ή OM1 Ο o-p^o 0. 0

II —s-ο—

II 0 - Valence hydrophilic part 〇

II -p-ο-

I 〇, each of the chains independently of a hydrogen atom, a valence metal atom or NR4+, and the hydrocarbon having the number of carbon atoms on the R-plane of the towel is the above-mentioned hydrophilic portion, and from the viewpoint of stability over time, it is more preferable The compound contained in the component (A) described below, that is, the structure in which the ethylenic double bond of the compound having an ethylenically unsaturated double bond is subjected to a Michael addition reaction, is considered to be a hydroxyl group or a carbonyl group. , thiocarbonyl, amine methyl sulfhydryl, amine methyl 'g care' is preferred _ gas base, amine methyl-14-200906985 thiol amine group, urinary burning site, thiourea site, guanamine site, sulfonate site, The urea site, the thiourea site, and the oxygenoxy group are known. a hydrazine, a hydrazine moiety, a polyethylene complex represented by -(CH2CH2〇)a-, an integer of three or more, and a partial structure represented by the following structural formula: a is a monovalent hydrophilic moiety Ο 〇 M2 0 —COOM —έ一OM1

II 〇 Divalent hydrophilic part 〇 〇 I! π s-o--p-ο- 儿 I i 〇 OM1

Trivalent hydrophilic site 〇 II ——-p?—

Ο II 〇 P 〇 〇 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 , , , , , , , , , , , , From the viewpoint of not easily inducing the above hydrolysis reaction, among the hydrophilic sites, preferred are a hydroxyl group, a carbonyl group, a thiocarbonyl group, a urethane 4 position, a sulfur-urea burned portion, a brewed amine portion, a S-site portion, a sulfur test site, and an amine group. -15- 200906985 A polyoxyl moiety represented by a mercapto group, an amine methyl methoxy group, an amine mercaptoamine group, a urea moiety, a thiourea moiety, a tertiary amine moiety, and -(CH2CH2〇)a- (where a More than or equal to 2); more preferred are hydroxyl, urethane, thiourethane, guanamine, sulfonamide, ester, urea, thiourea, secondary amine, -(CH2CH2 〇) a---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------聚乙烯) The polyethylene oxygen moiety shown by a_ (where a is an integer of 2 or more). In the molecule of the organodecane compound which can be used for the (C) binder, it is preferred to have at least one of the above hydrophilic sites, and more preferably a plurality of the above hydrophilic sites. When there are a plurality of hydrophilic sites in the molecule, these hydrophilic sites may be the same or different. In the above formula (1) and formula (Π), R1 and R2 each independently represent a hydrocarbon group having 1 to 6 carbon atoms, and the hydrocarbon group may have a substituent. Preferred among the above hydrocarbon groups are linear, branched or cyclic alkyl groups and the like. Preferred examples of R1 and R2 are: methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, hexyl, cyclohexyl, phenyl, wherein methyl, B are preferred. base. η represents an integer of 1 to 3, and from the viewpoint of stability, η is preferably 3. Further preferred examples of the specific organodecane compound which is suitable as the above (C) binder include a compound represented by the following formula (111) or formula (?). -16- 200906985 Corpse R1)n R2&quot;Six (III) 3·π R2 In the formula H (m), the F^R2 independently represents the number of carbon atoms R and R2 and the formula (1) or R1 and R2 in (11) are synonymous, and preferred examples are also the same. κ A hydrocarbon chain having 1 to 12 carbon atoms in the basin. It should be noted that R3 may have a ring structure or an unsaturated bond. In addition, the structure may also have a valence hydrophilic moiety. The second part is the leaf part t part, which is the part listed in the hydrophilic part of the upper rainbow and the middle part of the 朗2仏 hydrophilic part, and preferred examples are also the same. I is a hydrophilic part. Here, the hydrophilic portion refers to a portion of the (four) hydrophilic portion which is listed as a price-dependent portion. η is 3&quot; represents an integer of 1 to 3, which is preferable from the viewpoint of stability.

X'-R (〇R1)nq —Si (IV) 3-π 1~6 (4)) wherein f and ^ each independently represent a carbon atom of nn and R and a formula (1) or (π) R1 and R2

The preferred example of 冋 ’ is also the same. u and R -17- 200906985 each independently represent a single bond or a hydrocarbon chain having 1 to 12 carbon atoms. Here, when r4, r5, r6 &amp; r7 may have a ring structure or an unsaturated bond, the above hydrocarbon chain may have a substituent which may contain a valence hydrophilic moiety. certain. The sub-ordination may include a monovalent substitution of the hydrophilic moiety, and the divalent hydrophilicity of the i q value indicates that the divalent hydrophilic moiety is represented by the second strictivity toward the hydrophilic moiety. That is, when q is 1, the enthalpy is found on the ζ table, and when q is 2, ζ represents a trivalent hydrophilic portion. The hydrophilic portion of the 2222 bismuth and the above-described general formula (1) or (8) are exemplified as a divalent or trivalent hydrophilic moiety and represent an integer of 0 to 20, q represents 1 or 2, and Γ represents W3. The integer η represents an integer of 1 to 3. R3 in the above formula or R4, r5, and r6 in the formula (10) and the so-called "smoke bond" are preferably a chain, a square ring including a linear chain, a branched chain or a cyclic ring. _ may have a substituent, in the basin == substituents in the hydrocarbon chain, for example, an aliphatic group, an η group: a group, a halogen atom, a cyano group, a nitro group, an aliphatic oxy group, a galantinc A group, a heterocyclic oxy group, a hydrophilic group. Among them, an aliphatic group having a carbon number of 12, an aromatic group, a hetero ring = oxime = a cyano group, and a hydrophilic group. Preferable examples of the aliphatic steroid group having a carbon number of 12 include methyl group, ethyl group, propyl group, butyl group, isobutyl group, pentyl group, hexyl group, cyclohexyl group, octyl group, and the like. , its = more preferred is methyl, ethyl. Examples of the aromatic group include benzene &quot;18-200906985, a naphthyl group, an anthracenyl group, and more preferably a phenyl group. The heterocyclic ring may, for example, be morpholine, tetrahydroindenyl, pyrrolyl, furyl, phenylthio, benzopyrrolyl, benzofuranyl, benzophenylthio, pyrazolyl, isoxazolyl, Isothiazolyl, oxazolyl, benzisoxazolyl, benzisothiazolyl, imidazolyl, oxazole, thiazolyl, benzimidazolyl, benzoxazolyl, benzothiazolyl, ^pyridine , quinolyl, isoquinolyl, pyridazinyl, pyrimidinyl, pyridazinyl, porphyrin, pyridazinyl, quinazolinyl, quinoxalinyl, acridinyl, phenanthryl, pyridazinyl , carbazolyl, porphyrinyl, fluorenyl, triazolyl, oxadiazolyl, thiadiazolyl, more preferably morpholinyl, tetrahydroindenyl, pyridyl. A site having the same monovalent hydrophilic moiety, a specific group, a thiol group, an ammonium group, an amine carbenyl group, an amine group, and a substituent represented by the following structural formula. 〇—COOM —s~〇m1 Ο In the case where R3 in the above formula (III) or r4, r5, r6 and R7 in the formula (Iv) is a divalent hydrocarbon group, the valence hydrophilic moiety may be contained. It can be exemplified that specific examples of the hydrophilic moiety in the above formula (I) or (8) include a hydroxyl group, an amine amine methyl methoxy group, and an amine methyl amide group.

-19- 200906985

—COOM 9 Ο f-OM1 —P-OM1 〇OM2 In the above structural formula, 'Μ' Μ1 and M2 each independently represent a hydrogen atom, a valence metal, or an NR/', where the squaring indicates that the number of carbon atoms is 4 Smoke chain. When γΐ, γ2, ζ in the above formula (IV) is a divalent hydrophilic moiety, it can be exemplified by the fact that the hydrophilic portion of the above formula (1) or (π) towel is contained in Specific sites of the divalent hydrophilic moiety include, for example, a carbonyl group, a thiocarbonyl group, a urethane moiety, a thiourethane moiety, a guanamine moiety, an ester moiety f, a sulfur (tetra) moiety, a heteroamine moiety, a urea thief, and a thiourea moiety. A secondary amine oxime, a polyethylene oxygen moiety represented by -(CH2CH2〇)a· (wherein & greater than an integer), an oxygen slit base, and a partial structure represented by the following structural formula. 9 〇-S-〇--P-0- 0 6m1 monovalent metal atom or the above structural formula, 4, wherein R represents a cigarette bond having a carbon number of 1 to 4, and Z in the structure may be trivalent hydrophilic: For example: =仏1上上灿灿 or (π) towel material. The part of the slave item: = the same part, which can be exemplified by: the tertiary amine urea complex, the German miscellaneous money under the heterogeneous structure - the part shown Structure -20- 200906985, etc. 〇9 ~Ρ~〇-Ο-Ρ-ο- f] 〇\ R3 is preferably a methylene chain having 1 to 5 carbon atoms or may have a substituent in the chain The methylene chain of an oxygen atom may be included, and a methylene bond having a carbon number of 3 is more preferable. In the present invention, specific examples of the organodecane compound which can be suitably used as the (C) binder are as follows. The organodecane compound represented by the formula (1) may, for example, be β-(3,4-epoxycyclohexyl)ethyltrimethoxydecane or glycidoxypropyltrimethoxy.矽, γ-glycidoxypropyl triethoxy decane, decyl trimethoxy fluorene, dimethyl methyl diethoxy sulphur, ethylene triacetate acetaminophen, γ-chloropropyl monomethoxy base Alkane, vinyltrimethoxydecane, vinyltriethoxyalkane, Y-chloropropylmethyldimethoxyoxydecane, tridecylchlorodecane, 2_(3,4-, oxime%)B Further, preferred are exemplified by exemplified by trimethyl methoxy decane, diallyl tridecyl decane, ethoxy decane, bis(trimethoxymethoxymethyl sulfonyl) hexane, phenyl trimethoxy hydroxy, etc. An example is an organic decane compound of the general formula (11), (111) or (IV) [exemplary compound (1) to (62)] structure. &quot;21- 200906985 (1) h2n (3) (6) h2n (2) HS々^^ Si(〇Me)3 (4) 八, H2N/^/^Si(〇Me)3 17) /

Si(〇Et)3 (9) (10)

HS

i ^OEt Si OEt

Si(OMe): (11)

H2N

t , A^\z^sK〇Me)3

HO /SkOEt (14) \

(16) 〇(10) 9 u Kr^s/&quot;''^&quot;Si(〇Me)2 HC^^/\^^Si(〇Me)3 H2N

OH (IT) H〆 -22- (18)200906985

Si(OMe)3

(twenty one)

Si(OMe)3 (22)

N^-^Si(OEt)3 H (23)

Si(OEt)3 (24)

N^^^Si(OEt)3 H

Si(OEt)3 Η H -23- (25) 200906985 (26)

N’'x~^Si(OEt}3 Η (27)

N Η

Si(OEt)3

N^-^SKOEt), H 200906985 (34)

Ο

S^^^SiiOMe), (35), Si(OEt)3

(36) H2Nx/\n, H, Si(OEt)3 i (37) H2N, (38)

Ή' v, Si(OEt>3 H a

N ^Si(OEt)3 H (39) Λ (40)

S \^~Si(OMe)3 (41) (42) 〇OB)3 'N^Y^Si(OEt)3 (43) 〇 β人Ν' J Η 'Si(OEt)3 (44) HO_

OH -25- (45) 200906985

Η Η (46) Η

(48)

X NT ν, Si(OEt&gt;3 Η (49) ? (50) (Eto)3sr Κ OH 》>

-26- 200906985 (52)

ο A Ν Η

,Si(OMe)3 (54) 〇 (55)

Ο

V (5δ) NaO, |/\/Ck^( Ν Ο -SKOEth

Η, Si(OEt)3 (61) Fork Η ( (62) Ο, S'^^ Si(OMe)3 may be suitable as the (C) adhesive of the present invention, the specific organic decane compound -27-200906985 For example, the synthesis can be carried out in the following manner. Hereinafter, the above-exemplified compound (22) is exemplified, and a specific synthesis method can be given. Other specific organic stone-burning compounds which can be used in the present invention can also be synthesized in the same manner by using a raw material, a catalyst, and the like. It should be noted that the 'synthesis method is not limited to the following methods. To 5 g (0.373 mol) of diethylene glycol monoethyl ether, 1 ml of acetonitrile was added to dissolve it, and then 0.50 g of Neostan U-600 (made by Nitto Chemical Co., Ltd.) and 92.2 g (0.373 mol) were added. Triethoxy (3-propylisocyanohydrazide) decane was stirred at 50 C for 4 hours. After the reaction was completed, the reaction solution was cooled to room temperature, and then washed by adding 100 ml of n-hexane three times. The lower layer was collected, and the solvent was removed to obtain 142 g (0.373 mol) of the compound (22) (yield: 100%). Further preferred embodiments of the (C) adhesive in the present invention may be exemplified by intramolecular inclusion. a curable compound of a substrate-adhesive group, wherein the compound contains the above-mentioned substrate-adhesive group and contains at least one ethylenically unsaturated bond, which is hardened by forming a crosslinked structure using an initial species such as an acid or a radical. , V or hardening by a polymerization reaction. The above compound preferably has two or more dilute unsaturated bonds in the molecule 3, and more preferably contains three or more ethylenic bonds in the molecule. More preferably, the unsaturated bond contains four or more molecules in the molecule. The bond-unsaturated bond preferably contains five or more ethylenically unsaturated bonds in the molecule. From the viewpoint of the strength of the interaction, the hardening compound having an adhesive group Preferred are compounds containing a substituent capable of forming an ionic bond, a multi-point hydrogen bond, or a covalent bond; from the viewpoint of adhesion from a substrate having a strong interaction with a substrate of -28 to 200906985 degrees, and an unexposed portion From the viewpoint of developability and film strength of the exposed portion, it is preferred that the above compound contains a selected functional group composed of an ammonium group, a phosphonate group, a target group thereof, and a mesyl group. The compound represented by the following formula (A) is exemplified as the sclerosing compound of the group. In the above formula (A), Μ represents a moiety having an ethylenically unsaturated double bond, and L represents η+1彳. The organic linking group of bismuth, χ represents a hard material adhesion group. η represents an integer of 1 to 5, and m represents an integer of 1 to 3. The comparative examples of the structure shown by Μ are: unsaturated neon (for example, C Dilute acid, methacrylic acid, itaconic acid, crotonic acid, different Oleic acid, maleic acid, etc., vinegars, and amines. It is also possible to use an unsaturated phthalate ester containing an electrophilic substituent such as an isophthalic acid sulfonic acid group or an epoxy group, or a ruthenium and a ruthenium. Energy- or polyfunctional alcohols, amines, sulfur-addition reactions, and unsaturated neonates or S&amp; amines and monoluenes containing &quot;tetracycline groups or oxime oxygen (10) county substituents Or a structure formed by a substitution reaction of a polyfunctional alcohol, an amine, or a thiol. As another example, an unsaturated phosphonic acid, a styrene, an ethylene group, or the like may be used instead of the above-mentioned unsaturated compound group. Among them, preferred are (meth)acrylic acid group, styrene ethylene glycol, and ethyl ether structure. The step-in-step is a structure containing a (?-) propyl group. The above formula (A)t ' L represents an n+1 valent organic linking group determined by the number (8) of the partial structure containing an ethylenically unsaturated double bond, and the structure thereof contains a hydrocarbon ring nitrogen nitrogen of -29-200906985 ίο The number of sulfur atoms or carbon atoms is 3... bond, sulfur uranium bond group amine = urea ring group, halogen original, su and ^ 10,000 gansin, oxime, aromatic oxy, epoxy group N-type oxo-heterothio group, aliphatic hydrazine-based sulfonylthio group, oxy group, heart===^amine group, _ family bribe, ancestry group, heterocyclic bribe 'family continuation amine group , heterocyclic ring by amine scented aroma (4) A „^ silk Weiwei, aliphatic oxymethylwei group, heteroamine __ amine group, aromatic oxyamino group, : L' 曰 aliphatic thio-amine Aromatic thiolamine, heterocyclic ring - 々 册 疗 疗 疗 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Aromatic heterooxyoxy, heteroepoxy, fluorenyl, aliphatic sulfonyloxy, aromatic sulfonyloxy, azo-free azo, aromatic azo, heterocyclic azo A, Xiangmei yam, heterocyclic y == two sputum base 1 The scent of the scent of the scent of the scent of the compound of the scent of the scent of the compound of the scent of the compound of the scent of the compound The specific example of -30-200906985 [(MA-l)~(MA-ll)] is as follows, in the case where the olefinic double bond group is used as the propylene group in the Μ, 、, 吉However, the propylene fluorenyl group may be replaced with a substituent other than the above acryl fluorenyl group. Further, the structure represented by Μ may contain two or more dilute bonds different from each other. Double bond group -31- 200906985 (MA-l) (MA-2) o 0 (MA-3) °r°i

(MA-4) 0=

(MA-7) o o

o (MA-6) 〇=

'NT 'NT 0 o people νΛο o o

o °1 O 0

q p °1 °1 °1 -32- 200906985 (MA-9)

〇

OH

ο OH (MA-10)

T o 叉 f' f v 〇 0 o people ask people 〇 0^0 Λ

)&lt;^〇 O^fO

V (MA-11)

Preferably, in the above formula (A), when m is 1, X is selected from the group consisting of monovalent functional groups represented by the following formula. -33- 200906985 ο II ~Ρ-〇Μ 1

R 11 ΟΜ 2 -so3h so3m1 -n-r12 R13 X'

M1OOC M1OOC

COOM1 COOM2 In the above formula, 'R to R13 each independently represent an alkynyl group or an alkenyl group; Μ1 and Μ2 are each independently # + a gas 丞 丞 group; X· represents a counter anion. In the above formula (Α), when m is 2, X is selected from the group consisting of a mussel g group of the following formula.

9 〇 - s - o - ΟΜ 2 A x R12 occupies 12 0 R130 In the above formula, R12 to R13 are each independently an alkynyl group or a fluorenyl group; and M2 represents a hydrogen atom or a metal ion. I is an atom or an ammonium group; X· represents a trans-34-200906985. Preferably, in the above formula (4), when m is 3, X is a group consisting of divalent functional groups represented by the following: select. 〇 II -Ο—1^-〇—Ο

RX' 1 I alkynyl p; == 立子 - When X of formula (8) contains a counter anion as a partial structure, = anti anion Χ · can be like: fluoride anion, chloride anion, filling anion = ion and other halogen anions; acetic acid Anion, three =: sulfate anion, hydrogen sulfate anion, methyl anion, tris-sulfate anion, perchlorate anion, tetrafluoroanion, hexa-acid anion, hexachloro-acid anion, hexafluoro-acid anion, etc. . And, in terms of compound hearing and stability (four) degree, it is better to use the scorpion, stone = touch ion, tetrafluoroborate anion and hexafluoro-Wean anion to test the separation point = two:; ==, from dense The viewpoint of the property of the second embodiment; the viewpoint of the property of improving the hardness, the adhesion of the portion 1:== group and the solid component of the inkjet ink of the present invention including the bond-bonding unsaturated double bond The content of the compound of the group is preferably wt%, preferably from 2 to 35 to 200906985 is from 0.05 to 20% by weight, further preferably (^ to 忉 wt%. It is to be noted that when an adhesion-containing group is used When the curable compound of the group is used as the component (C), the amount of addition is preferably 0.01 to 60% by weight, and further preferably 0.05 to 40% by weight. (A) using an acid and A compound which hardens at least one of the radicals &gt; (A) a compound which is hardened by at least one of an acid and a radical (hereinafter referred to as a curable compound as appropriate) as long as it is utilized by using an acid a compound such as a base that forms a crosslinked structure or undergoes a polymerization reaction, etc. The curable compound may be a cyclic ether such as a mercapto compound or an epoxy compound or an oxetane compound; a combination of a thiol compound and an ethylenically unsaturated double bond compound; a thiol or itaconic acid, crotonic acid, isocrotonic acid, maleic acid, a compound containing at least one ethylenically unsaturated double bond such as a (meth) acrylonitrile group or a (fluorenyl) acrylamide group, etc. In view of the hardenability and the stability, it is preferable that (meth)acrylic acid is used. In the case where a curable compound containing a substrate-adhesive group is used as the (C) adhesive, When sufficient hardenability is obtained by controlling the content thereof, since the component has a function of the component and the component (A), it is not necessary to add a hardening compound which is usually used without an adhesive group, but for control In the present invention, a curable compound (a curable compound not containing a substrate-adhesive group) which can be used in combination can be used in combination with the above-mentioned curable compound. A compound which is well known as a compound containing an ethylenically unsaturated double bond is used without particular limitation. The above compound includes, for example, a monomer, a prepolymer, that is, a dimer, a trimer-36-200906985, and oligomerization. Chemical substances such as a substance or a mixture thereof and a copolymer thereof. 'Examples of a monomer and a copolymer thereof may be exemplified by an unsaturated carboxylic acid (for example, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, or different). Crotonic acid, maleic acid, etc.) or its lysine, glutinous rice noodles are recorded as an axis of unsaturated tarenic acid and aliphatic 7-sterol compounds, unsaturated arsenic and no female polyamines.帛 帛 不 不 不 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛 帛Dehydration, vinegar or amine-derived dehydration condensation reaction with monofunctional or polyfunctional lining, and the like. Also suitable for use: an unsaturated carboxylic acid ester containing an electrophilic substituent such as an isocyanate group or an epoxy group or an addition of a monofunctional or polyfunctional alcohol, an amine, or a sulfur; and (4) Group or? A substituted carboxylic acid ester or a guanamine of a phenyl phenolic isocyanating substituent, and a monofunctional or polyfunctional alcohol, ugly, sulfur-reacting substituted reactant. As another example, a compound of a rib unsaturated phosphonic acid, a stupid, or a vinyl unsaturated carboxylic acid may be used. This is a monomer example of an ester of an aliphatic polyol compound and an unsaturated carboxylic acid. Examples of the acrylate include ethylene glycol diacrylate, triethylene glycol diacrylate, and U•butylene glycol diacrylate. Ester, diacrylate, propylene glycol acrylate, neopentyl glycol diacrylate, trimethylolpropane triacrylate, trishydroxypropyl propane tris(propylene oxypropyl) ether, trishydroxy thioacetate Acrylic vinegar, propylene glycol dipropylene acrylate, bismuth dicyclohexane-cyclohexanediol ester, tetraethylene glycol diacrylate, pentaerythritol diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, diacrylic acid Second season -37- 200906985 Pentaerythritol ester, dipentaerythritol hexaacrylate, sorbitol triacrylate, sorbitol tetraacrylate, sorbitol pentaacrylate, sorbitol hexaacrylate, tris (propylene oxypropylene) Base) isocyanurate, polyester acrylate oligomer, and the like. Further, an EO modified body or a PO modified body of the above compound may be mentioned. Examples of the mercapto acrylate include dimercapto acrylate, triethylene glycol dimercapto acrylate, neopentyl glycol dimercapto acrylate, trishydroxypropyl propane tridecyl acrylate, and trishydroxy ethane ethane. Tridecyl acrylate, ethylene glycol dimercaptoacrylate, 1,3-butylene glycol dimercaptoacrylate, hexanediol dimercaptoacrylate, pentaerythritol dimercaptoacrylate, pentaerythritol tridecyl acrylate , pentaerythritol tetramethacrylate, dipentaerythritol dimercaptoate, dipentaerythritol hexaacrylate, sorbitol tridecyl acrylate, sorbitol tetradecyl acrylate, bis[3-(yl) Propylene oxirane-2-hydroxypropyloxy)phenyl]dimercaptomethane, bis(p-(acrylonitrile methoxyethoxy)phenyl]dioxyl decane, etc. and their EO modified bodies , PO modified body. Examples of the itaconate include ethylene glycol diaconate, propylene glycol diitaconate, 1,3,butylene glycol diitaconate, and 1,4-butylene glycol diitaconate. Di-isoconate, pentaerythritol diisoconate, sorbitol tetracoconate, and the like. Examples of the crotonic acid ester include ethylene glycol dicrotonate, dicrotonate, pentaerythritol dicrotonate, and sorbitol tetradodetoic acid ester. Examples of the isocrotonate include ethylene glycol diisocrotonate, pentaerythritol diisocrotonate, and sorbitol tetraisocrotonate. The maleic acid ester may, for example, be ethylene glycol dimaleate, triethylene glycol dimaleate, pentaerythritol dimaleate or sorbitol tetramaleate. -38- 200906985 SI 47^ Other examples of the purpose, for example, are suitable for making Μ: Japanese patent special public 昭 vinegar (4), Japanese 3 Japanese special opening 57_196231 as described in the aliphatic alcohol outside the gamma 3 patent special opening 59 -5240, Japanese Patent Laid-Open Publication No. 2-226149, Japanese Patent Application Laid-Open No. Hei No. 2-226149--------------------------------------- It can also be used as a mixture. Specific examples of the monomer of the ruthenium amide compound and the unsaturated retinoic acid amide include methylene bis acrylamide, methylene bis decyl olefin amine, 1, 6 - hexamethylene bis propylene amide, 〗 6, 6 hexamethylene dimethyl propyl, acid amine, diethylene triamine propylene amide, benzyl dimethyl propylene amide, this dimethyl Bis-methyl methacrylamide and the like. Other preferred examples of the amide-based monomer The urethane oxime addition polymerizable compound produced by the addition reaction of an isocyanate and a hydroxyl group is also suitably used, and specific examples thereof are also suitable. The polyisocyanate compound containing two or more isocyanate groups in the molecule described in Japanese Patent Publication No. Sho 48-417 No. 8 is a hydroxy group-containing B represented by the following formula (2). A vinyl urethane compound containing two or more polymerizable vinyl groups in one molecule obtained by a dilute base monomer. CH2=C(R4)COOCH2CH(R5)OH (2) (wherein 'R4 and R5 represent Η or CH3.) In addition, as disclosed in Japanese Patent Laid-Open No. 51-37193, 曰本专利特公平2-32293, Japanese Patent The urethane acrylates described in Japanese Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Polyurethane compounds of the oxygen oxyphylline skeleton are also suitable. In addition, the addition of an amine-based structure or a sulfur-containing structure in the molecule described in Japanese Patent Laid-Open No. 1-1G5238, the Japanese Patent Publication No. Hei. A polymerizable compound can be used to form a curable composition having a very excellent photospeed. Other examples of η can be produced by a vinegar, vinegar, and epoxy resin as described in Japanese Patent Laid-Open No. 48-64183, Japanese Patent Publication No. Sho. No. 4,319, and Japanese Patent Publication No. Sho 52-30490. A polyfunctional acrylate or methacrylate such as epoxy acrylate or the like obtained by the reaction of methyl)acrylic acid. It is also possible to cite a specific unsaturated compound described in Japanese Patent Publication No. Sho-43946: Japanese Patent Publication No. 337, Japanese Patent Publication No. 1-3-40336; or Japanese Patent Special Open 2-2 Lake The TM structure of the all-gas syllabic group described in No. 61-22048, such as the ethylene-based phosphonic acid-based compound described in the above, is also applicable. You can also use Japan's next age vol. 20, Νο 7 Jie: Γ. Page (10) In the production, when adding other polymer compounds, it is sensitive from hardening: and the bond is contained in two or more olefinic bonds. Wherein 'preferably contains two or oleic acid vinegar structures, and the surface contains three or three (diyl group = acid vinegar structure, and most preferably contains four (four) _ or more 基 (base) ·; ) = -40- 200906985 Ester structure. Further, from the viewpoint of the curing sensitivity and the developability of the unexposed portion, it is preferable to contain the EO modified body. From the viewpoint of the curing sensitivity and the strength of the exposed portion, it is preferable to contain a urethane bond. From the above viewpoints, preferred examples include: Bishuang A diacrylate, bisphenol A diacrylate EO modified body, tri-propyl mercapto triacrylate, trimethylolpropane tris(propylene fluorene) Oxypropyl propyl sulphate, tris-methyl ethene succinimide, such as acid, succinic acid, tetraglycolic acid, quaternary tetradecyl diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, tetraacrylate Pentaerythritol ester, dipentaerythritol pentaacrylate, hexapropylene dipentaerythritol vinegar, sorbitol triacrylate g, sorbitol tetrapropyl acrylate, sorbitol pentaacrylate, sorbitol hexaacrylate g, three (Allyloxyethyl)isocyanurate, EO modified body of pentaerythritol tetraacrylate, EO modified body of dipentaerythritol hexaacrylate, and the like. As a commercial product, urethane oligomer UAS-10, UAB-140 (made by Shanyang National Policy Pulp Co., Ltd.), DPHA-40H (made by Sakamoto Chemical Co., Ltd.), UA-306H, UA-306T, UA- are preferred. 306I, AH-600, T-600, AI-600 (manufactured by Kyoeisha). More preferably, it is a bisphenol A diacrylate EO modified body, a triacetic acid pentaerythritol vinegar, a pentaerythritol tetraacrylate S, a dipentaerythritol pentaacrylate, a dipentaerythritol hexaacrylate, or a tris(propylene oxyethyl) Isocyanurate, EO modified pentaerythritol tetraacrylate, EO modified product of dipentaerythritol hexaacrylate, DPHA_40H (manufactured by Nippon Kayaku Co., Ltd.), UA-306H, UA-306T, UA-306I, AH-600, T-600, AI-600 (manufactured by Kyoei Co., Ltd.). The addition ratio of the monomer as the curable compound is usually from 〇 to 70% by weight based on the total solid content of the ink. Here, when the bis-trifunctional single-41-200906985 = body composition, / °, the ink may not be lightly plugged when the ink is not used by a single inkjet nozzle = == Na, adhesion, hardness is poor, may not be ' The polyfunctional monomer of the single i::=r is a di- or trifunctional ink, and the viscosity of the di- or trifunctional ink is not easily increased by the drying of the ink, so that the spray is stable, but the other layer is hardened by the ink layer. The film of the ruthenium layer was obtained, with respect to the base (four) mil. Therefore, by adding the above-mentioned di-trifunctional= or tetrafunctional or higher polyfunctional monomer or oligomer to the film of the human pre-hardened layer, the film strength and the dense tetrafunctional monomer and oligomer can be For example: tetrapropylene dipentaerythritol vinegar, pentaerythritol tetramethacrylate, pentapropylene tetrahexaacrylate dipentaerythritol, hexamethylene acrylate diquaternium i relative to the total solid content of the ink, usually: add, ί can Or, can be more than the official: another 3: = one & one energy monomer to stabilize the squirting and profit: = composition to balance the strength and tightness: two 篁 heavy injury one ~ two functional Sexual monomer, Siguantai t + A polyfunctional ingredients are usually added in proportion! ~5. The weight U = 士士 The above addition is equal to 2 parts by weight, and the upper limit of the force tear is 35 parts by weight or less. Here, when ί = -42 - 200906985 parts by weight of the above-mentioned di-trifunctional monomer, the addition ratio of the tetrafunctional polyfunctional component is less than 1 part by weight, and the hardness or solvent resistance cannot be sufficiently obtained. Sex and other characteristics. In the case of dihydrate, the above-mentioned addition ratio of the polyfunctional component may exceed the above; in the four senses, the curing speed and the processing speed of the treatment water may be slow. . In the case of a weight injury, the ink needs to be described. Preferably, the amount of the curable compound added is 5 to 8 G in the total amount of the hard-working compound. The ((:)-adhesive_, the second is the range of the hardening compound having the adhesive group and (A) the total amount of hardening is 7 to 85 wt%. Portion &lt;(B) Pigment &gt; As a pigment for the coloring agent of the inkjet ink of the present invention, it is possible to use an organic coloring agent and an inorganic coloring agent depending on the color required for the R, G, B or the like of the halogen (halogen component) or the black matrix layer. It is preferable to use an arbitrary coloring agent. The organic coloring agent may be, for example, a dye, an organic pigment, a natural pigment, or the like. For the inorganic coloring agent, for example, an inorganic pigment, an extender pigment, or the like can be used. Among them, the organic pigment has high color rendering property and heat resistance. The organic pigment is, for example, a compound classified as a pigment in a dye index (CI; issued by The Society of Dyers and Colourists), and specifically includes the following dye index (CI) number. Pigment. CI Pigment Yellow 1, CI Pigment Yellow 3, CI Pigment Yellow 12, CI Pigment Yellow 13, CI Pigment Yellow 14, CI Pigment Yellow 15, CI Pigment Yellow 16, CI Pigment Yellow 17, CI Pigment Yellow 20, CI Pigment Yellow 24, CI Pigment Yellow 31, CI Pigment Yellow 55, CI Pigment Yellow 60, CI Pigment Yellow 61, CI Pigment Yellow-43-200906985 65, CI Pigment Yellow 7 Bu CI·Pigment Yellow 73, CI Pigment Yellow 74, CI Pigment Yellow 81, CI Pigment Yellow 83, CI Pigment Yellow 93, CI·Pigment Yellow 95, CI Pigment Yellow 97, CI Pigment Yellow 98, CI Pigment Yellow 1〇〇, CI Pigment Yellow 101, CI Pigment Yellow 104, CI Pigment Yellow 106, CI Pigment Yellow 108, CI Pigment Yellow 109, CI Pigment Yellow 110, CI Pigment Yellow 113, CI Pigment Yellow 114, CI Pigment Yellow 116, CI Pigment Yellow 117, CI Pigment Yellow 119, CI Pigment Yellow 120, CI Pigment Yellow 126, CI Pigment Yellow 127, CI Pigment Yellow 128, CI Pigment Yellow 129, CI Pigment Yellow 138, CI Pigment Yellow 139, CI Pigment Yellow 150, CI Pigment Yellow 151, CI Pigment Yellow 152, CI Pigment Yellow 153, CI Pigment Yellow 154, CI Pigment Yellow 155, CI Pigment Yellow 156, CI Pigment Yellow 166, CI Pigment Yellow 16 8, CI Pigment Yellow 175; CI Pigment Dial 1, CI Pigment Orange 5, CI Pigment Orange 13, CI Pigment Orange 14, CI·Pigment Orange 16, CI Pigment Orange 17, CI Pigment Orange 24, CI Pigment Orange 34, CI Pigment Orange 36, CI Pigment Orange 38, CI Pigment Orange 40, CI Pigment Orange 43, CI Pigment Orange 46, CI Pigment Orange 49, CI Pigment Orange 51, CI Pigment Orange 61, CI Pigment Orange 63, CI Pigment Orange 64, CI Pigment Dial 71, CI Pigment Orange 73; CI Pigment Violet 1, CI Pigment Violet 19, CI Pigment Violet 23, CI Pigment Violet 29, CI Pigment Violet 32, CI·Pigment Violet 36, CI Pigment Violet 38; CI Pigment Red 1, C&gt ;1•Pigment Red 2, c〗 Pigment Red 3, c〗 Pigment Red 4, CI Pigment Red 5, CI Pigment Red 6, CI Pigment Red 7, CI Pigment Red 8, CL Pigment Red 9, CI Pigment Red 10, CI ·Pigment Red 11, C 丄 Pigment Red 12, CI Pigment Red 14, c ! Pigment Red 15, c 丄 Pigment Red 16, c 丄 Pigment Red 17, C.1. Pigment Red 18, CI Pigment Red 19, CI Pigment Red 21, CI Pigment Red 22, CL Pigment Red 23, c丄 Pigment Red 3〇, c丄 Pigment Red-44- 200906985 31, CI Pigment Red 32, CI·Pigment Red 37, CI Pigment Red 38 CI Pigment Red 40, CI Pigment Red 4 Bu CI Pigment Red 42, CI Pigment Red 48: Bu CI Pigment Red 48:2, CI Pigment Red 48:3, C.I_Pigment Red 48:4, CI Pigment Red 49: 1. CI·Pigment Red 49:2, CI Pigment Red 50:1, CI Pigment Red 52:1, CI Pigment Red 53:1, CI Pigment Red 57, CI·Pigment Red 57:1, CI Pigment Red 57:2 , CI·Pigment Red 58:2, CI Pigment Red 58:4, CI Pigment Red 60:1, CI Pigment Red 63:1, CI Pigment Red 63:2, CI Pigment Red 64:1, CI·Pigment Red 81: 1. CI Pigment Red 83, CI Pigment Red 88, CI Pigment Red 90:1, CI Pigment Red 97; CI Pigment Red 1〇1, CI Pigment Red 102, CI Pigment Red 104, CI Pigment Red 105, CI Pigment Red 106 , CI Pigment Red 108, CI Pigment Red 112, CI Pigment Red 113, CI Pigment Red 114, CI Pigment Red 122, CI Pigment Red 123, CI·Pigment Red 144, CI Pigment Red 146, CI Pigment Red 149, CI Pigment Red 150, CI Pigment Red 151, CI Pigment Red 166, CI Pigment Red 168, CI Pigment Red 170, CI Pigment Red 171, CI Pigment Red 172, CI Pigment Red 174, CI Pigment Red 175, CI Pigment Red 176, CI Pigment Red 177, C丄 Pigment Red 178, CI Pigment Red 179, CI Pigment Red 180, CI Pigment Red 185, CI Pigment Red 187, CI Pigment Red 188, CI Pigment Red 190, CI·Pigment Red 193, CI Pigment Red 194, CI Pigment Red 202, CI Pigment Red 206, CI Pigment Red 207, CI Pigment Red 208, CI Pigment Red 209, CI·Pigment Red 215, CI Pigment Red 216, CI Pigment Red 220, CI·Pigment Red 224, CI · Pigment Red 226, CI Pigment Red 242 'CI Pigment Red 243, CI Pigment Red 245, C_I. Pigment Red 254, CI Pigment Red 255, C.I_Pigment Red 264, CI Pigment Red 265; CI Pigment Blue 15, CI Pigment Blue 15:3, CI Pigment Blue 15:4, CI -45- 200906985 Pigment Blue 15:6, CI Pigment 趑. CI Pigment Brown 23, ci Pigment Pine, CJ. Pigment Green 7, CL Pigment Green 36, · Yi machine pigment #哲不' CL pigment black 1, pigment black 7. Titanium acid, sulfuric acid lock, charcoal dance quality: ^ can also be exemplified by: iron oxide (iron oxide red (III)), Zhenhong, =, sulfuric acid error: yellow wrong, zinc yellow, ramber (umber) , Titanium, human group, month, sweet blue, chrome oxide green, green, material can be used alone in the present invention, the use of the spray of the invention: two or more mixed use. In the case of the pattern of the color matrix layer, black material is formed on the substrate of the spray film; Black having high light-shielding property::====Coloring color = coloring agent, or cyanine black; :: using the ink of the ink of the present invention to form two of the following adhesives' and light-curing adhesive; However, it is also possible to harden by light by adjusting the ink layer or extending the exposure method. When the hard recording of the present invention is used as a color calender film, the pigment-secondary particle diameter is preferably 10 to 0 nm, more preferably 10 to 7 nm, from the viewpoint of color uniformity or contrast. Further, Preferably, 1〇~刈ηι» 'Best is 1〇~4〇nm. In the case of forming a pixel, the pigment is added in a ratio of usually =1 to +60 wt%, preferably 15 to 4 〇 plus %, based on the total solid content of the inkjet ink. If the amount of the pigment is too small, the transmission density may be insufficient when the inkjet ink is applied to a predetermined film thickness (usually αι 2·0 μηη). If the amount of the pigment is too large, the adhesion to the substrate when the inkjet ink is applied to the substrate and hardened, and the hard material of the cured film -46-200906985 can be insufficient. The second point of view considers 'better in this = its: polyphenolic acid and its salts, high molecular weight unsaturated, such as modified j:: modified polyester, poly-inspection, modified poly(meth)acrylic acid vinegar, (Methyl) propylene copolymer, acid-formed formalin condensate, and polyoxyethylene sulfonate-based acid vinegar, polyoxyethylene alkylamine, polyalcoholamine, pigment derivative, and the like. The molecular dispersant can be further classified according to its structure: a linear polymer = a terminal modified polymer, a graft polymer, and a block polymer. The knives and knives are adsorbed on the surface of the pigment to prevent re-aggregation. Therefore, the preferred structure can be exemplified by a terminal-modified polymer having a surface adhered to the surface of the pigment, a graft-type polymer, and a high-density type. =. On the other hand, the pigment derivative has an effect of promoting adsorption of the polymer dispersant by modifying the surface of the pigment.

Specific examples of the pigment dispersant which can be used in the present invention include: Disperbyk-101 (polyamidodecanoate), 107 (barium carboxylate), 11 (acid-containing copolymer), and 13 manufactured by BYK Chemie. 〇 (polyamide), 161, 162, 163, 164, 165, 166, 170 (polymer copolymer), "ΒΥΚ_ρι〇4, Ρ105 (焉 molecular weight unsaturated polycarboxylic acid), EFKA4047, manufactured by EFKA) 4050, 4010, 4165 (polyurethane), EFKA 4330, 4340 (segment copolymer), 4400, 4402 (modified polyacrylate), 5〇1〇 (polyester decylamine), 5765 (high molecular weight polycarboxylate) ), 622〇 (fatty acid polyester), 6745 (酞花月 derivative), 6750 (azo pigment derivative), Ajinomoto-47- 200906985 FINE-TECHNO company "Ajispa PB821, PB822", co-prosperity "Fi〇wren tg-71〇 (polyurethane oligomer)", "P〇iyfl〇w No.5〇E, Νο·3〇〇 (acrylic copolymer)", manufactured by Kogyo Chemical Co., Ltd., "Nippon Chemical Co., Ltd." Disparon KS-860, 873SN, 874, #2150 (aliphatic polycarboxylic acid), #7004 (polyether ester), DA-703-50, DA-705, DA-725" Kaosha Co., Ltd. "DemorRN, N (formalin naphthalenesulfonate polycondensate), MS, C, SN-B (aromatic sulfonate fumarate polycondensate)", "h〇MOGENOL L-18 (polymeric polycarboxylic acid) ), "Emulgen 920, 930, 935, 985 (polyoxyethylene phenyl phenyl ether)", "ACETAMIN 86 (stearylamine acetate)",

Lubrizol "s〇lSperse5〇〇〇 (Eucalyptus derivative), 22000 (azo pigment derivative), 13240 (polyesteramine), 3000, 17000, 27000 (polymer with functional moiety at the end), 24000, 28000, 32000, 38500 (grafted polymer)", rnikk〇1^7 一士士, manufactured by Nikko Chemcal Co., Ltd.) T106 (polyoxyethylene sorbitan monooleate), MYS-IEX (polyoxygen) Ethylene monostearate) and the like. The above dispersing agents may be used singly or in combination of two or more kinds. In the present invention, it is particularly preferred to use a pigment derivative in combination with a high molecular dispersant. In the present invention, the content of the dispersant is preferably 疋!i°Wt/〇, more preferably 疋3 to 1〇〇Wt%, more preferably 5, specifically for the field. In the case of a molecular dispersant, the amount of use with respect to the molecular dispersant is preferably in the range of 5 to 100 w =: J10 to 80 wt%. When the pigment derivative is used, the amount of the above-mentioned pigment street organism is preferably from &quot;48-200906985, and more preferably in the range of 3 to 20% by weight, particularly preferably in the range of θ.疋5 to 15 wt% In the present invention, when used as a colorant from the viewpoint of hardening sensitivity and color density, the total solid content of the counterpart is 'the total content of the coloring agent and the dispersing agent is equal to - less than or equal to 90 wt. %, 22nd

Wt% and less than or equal to % swim. Preferably, the step-by-step is 2$^ at 4〇/〇 and less than or equal to 80 wt〇/〇. Greater than or equal to 50 wt / 〇 (D) solvent The solvent of this color filter film inkjet ink can be selected from white _. Examples of the solvent solvent which may be exemplified include ethylene glycol _t_4-tetraethyl ether ether such as ethylene glycol monool monomethyl ether acetate; ethylene di oligomer Dn, i type, monoethylene glycol single Methyl ether and other ethylene glycol low (four) secret class, diethylene glycol monomethyl bond acetic acid: aside; acetic acid, 2-ethylhexanoic acid, acid, alcohol, hiding, vinegar, acetic acid, ethyl acetate, S, stupid f, acid, ke Its sour liver; vinegar and other two New Zealand two (four); fragrant noodles; diethyl iodide New Zealand; Chlorine, dichloroacetic acid and other bacteria _ ^ fat such as diethyl hydrazine, 1 propanol and other alkoxy _ ; diglycol 1 ', 2 2 base ethanol, h methoxy group; 2-diethylamine 7 醴 - propylene dipropylene glycol and other diol oligomers, such as r amine, diethanolamine and other amine alcohols ; 2 · alkoxy alcohol esters such as ethoxylated ethyl acetate, dioxyethyl n-ethyl phenanthrene, benzene fine; isoaliphatic or aromatic amines = diamylamine, the amine 荨 - Τ Ethyl amide Ν, Ν-dimethylmethyl-49- 200906985 amides such as aldehydes, N-methylpyrrolidone and pyrrolidone; sulphites such as dimethyl hydrazine, hexane, octane, Dioxane, heptene, 3,4-dimethyl burned, one-burned and the like. The above solvent may be used singly or in combination, but in order to suppress the change in the concentration over time and the solidification at the coating site during coating, or to prevent the hardenability and the drying retardation, it is preferred that at least one solvent is used at a boiling point under normal pressure. ^ is equal to 150 ° C and less than or equal to 300 χ; preferably, a solvent equal to or greater than 16 = C and less than or equal to 25 CTC. Specifically, from the viewpoints of the stability of the pigment dispersion liquid, the drying property after coating, and the like, the solvent is more preferably: diethylene glycol monobutyl ketone acetic acid, diethylene glycol monomethyl lang, etc. Low ether vinegar; alkoxy alcohols such as 2-ethoxyethanol, methoxy-2-propanol; glycol oligomers such as propylene glycol; ethylene glycol monomethyl acetate Ethylene glycol ether vinegar. The above solvent is usually used in a ratio of 40 to 95 with respect to the total amount of the ink including the above solvent to prepare a discharged ink. If 乂, the ink viscosity is high and it is difficult to eject from the ink jet head. When it melts, the film of the ink-receiving portion (the portion where the ink layer is formed) is broken, and the ink which is widely distributed in the wettability change portion is nearly wet: the light portion overflows, and the moisture spreads. To the neighbor, from the library, the ink layer is formed. In other words, it is not possible to obtain a sufficient penetrating knives. The remaining film thickness is too thin, except in the inkjet ink of the present invention, as long as the essential components of the present invention are not damaged in July. The effect 'A variety of-50-200906985 compounds can be used depending on the purpose. For example, in order to improve the film properties of the formed coloring pattern, (E) an acid generating compound or (F) a binder polymer may be added. Hereinafter, preferred components for use will be described. &lt; (E) A compound which generates at least one of an acid and a radical > f. A compound which generates at least one of an acid and a radical in the present invention (hereinafter referred to as an acid/radical generating agent as appropriate) means A compound which produces at least one of an acid and a radical by light or heat after application of the ink. By using the above-mentioned compound in combination, an acid, a radical, or the like generated by the compound acts as a starting species, and (A) curing is performed by at least one of an acid and a radical, and the curing reaction of the compound is started and carried out. promote. When the component (E) is a compound which generates an acid, the acid produced as the compound is carboxylic acid, sulfonic acid, phosphoric acid, phosphoric acid ester, sulfuric acid, sulfuric acid disulfinic acid, hydrochloric acid, nitric acid, boric acid, or the like. A substance such as fluoroboric acid, a boron complex, a living organism, or a hexafluorophosphoric acid which is produced by using light and/or heat in the droplets after application can be used to produce a substance of succinic acid or Lewis acid. Specific examples of the acid/radical generating agent include the following compounds known as photopolymerization initiators: (8) organohalogen compounds; (8) oxadiazole compounds; (4) 2 compounds S' (4) a diacid compound; (4) a compound; a hydrazine salt δ '(g) carbonyl compound; (h) a ketal compound; (i) a benzoin compound; - hydrazine, 1 substance, (1) an organic peroxide; m) an even I compound; (n) a fragrant compound; (G) a money compound; a (ruthenium) metallocene compound; (q) a hexammine-flavor compound; a W-mercaptophosphine (oxidation) compound. (8) Specific examples of the organic i-based compound include, for example, "B讪em. Soc Japan" 42, 2924 (1969), and U.S. Patent No. 3,905,815-51-200906985, f. Japanese Patent Special Publication 46〇5Mon 48- 362SI, Japan's special __ 55 2 special, Zhao Zhao _9736, Japanese Patent Special Open 6 61_169837, Japanese Patent Special Open 62= 曰 曰 = 62 〇 〇 1, 曰 专利 特 昭 ” ” ” ” 〇 2: ^ Ben, Kai Zhao 63_29_, Μ· R Hutt "Joumal 〇f ZTTc (5) This Qing" 1 (No3), (1970)" and other materials described in the article, especially listed: tridentate methyl substitution The compound of the shot. Monomethyl as a 2 s-triazine compound, more suitable is an s-triazine derivative in which at least one monodentate, dihalogen or dentate substituted thiol group is bonded to the s-triazine ring, and specific examples thereof are as follows: 2,4,6_tris(monochloromethyl)_s_triazine, '2,4,6_tris(dichloromethyl)-S-triazine, 2,4,6-tris(trichloroindenyl) _s_Triazine, 2-methyl-j,6-bis(dichloroindenyl)_s_triazine, 2-n-propyl-4,6-bis(trichloroindenyl)triterpenoid, 2-(α ,α,β_trichloroethyl)_4,6_bis(trimethylmethyl)triazine, 2-phenyl-4,6-bis(trichloromethyl)_s_triazine, 2_(p. Phenyl group 4,6-bis(trichloroindenyl)_S-triazine, 2-(3,4.epoxyphenyl)-4,6-bis(trimethylsulfonyl)_s_triazine, 2_(p-chlorophenyl M,6-bis(trichloromethyl)-s-triazine, 2-[1-(p-oxooxy)-2,4.butadienyl]_4,6_double (trichloroindolyl)_s_triazine, anthracenyl-4^6-bis(trichloromethyl)+triazine, 2_(p-oxyl stupidyl)_4,6_bis(trichloromethane) -S-triazine, 2_(p-isopropoxystyryl)_4,6-bis(trichloro)-s-triazine, 2_(p-phenylene)_4,6_double (three Chloromethyl)_s_triazine, 2_(4_naphthyloxynaphthyl K6-bis(trichloromethyl)-S·triazine 2·Phenylthio_4,6-bis(trichloromethyl)-s-triazine, 2-benzylthio_4,6-bis(trichloromethyl)_s_triazine, 2,4,6_ One (one wide methyl) _s_ triazine, 2,4,6-tris(trimomethyl)-s-triazine, 2·methyl-52- 200906985 -4,6-bis(tribromofluorenyl) ) _8_ triazine, 2 triazine, etc. Τ milk base - double (triple methyl group > s_ (b) oxadiazole compounds can be listed as: 2_three two '34" dioxin vomit, 2 three gas Base _5_(cyanobenzene U-azole, 2-trichloromethyl-5-(naphthalene-work-based 沁' 嗓 ^2^3,4,4-phenethyl fluorenyl) stupid vinyl-1, 3,4·Noise, two saliva, etc. ··曱鼠曱-5-(4-(0 Specific examples of organic borate compounds = Zhao-_, 曰本专利特二=号, Japanese Patent Special Kaiping 9 Kaiping 9-face 6 〇-131837, Japanese Patent Japan, Japanese Patent, Japanese Patent, Special Open Patent, Special Patent 2, 07716, Japanese Temple No. 2764769, and Japanese Patent 2__31.

Kunz, Martinc&lt;Rad Tech5 98 Pr^ 矹寻谷 a

Chicago^ t 98· ^ceechng April 19-22, 1998, == newspaper, 曰本 patent special opening...55= Patent special Kaiping 6-175561 韶胼 韶胼 畨&gt; each... Root "Feng or organic Wei sulphur镔 合物 合物 专 ^ ^ 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利由 曰 曰 专利 专利 、 日本 日本 日本 日本 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 065 065 065 065 065 065 065 065 065 065 065 065 065 065 065 065 065 065 065 065 61. For example, the patents such as the Japanese Patent Laid-Open No. A, and the Japanese Patent No. 2〇〇1_132318, etc. -53-200906985, etc. (e) The oxime ester compound can be exemplified by: jcs Perkin II (1979) 1653-1660 &gt; JCS Perkin II (1979) 156-162 &gt; Journal of Photopolymer Science and Technology Π9〇5^202-71? &gt; n yfc The compound described in the Japanese Patent Laid-Open Publication No. 2000-80068, and the compound described in Japanese Patent Application Laid-Open No. Hei. (f) The rust salt compound can be exemplified by sj Schlesinger, ph〇t〇gr Sci. Eng. 18, 387 (1974), TS Bal P〇lymer, 21, 423 (1980); Patent No. 4, _, g55, Japanese lion Kaiping 4_36, and the rust salt described in each specification of US Patent No. 4, _, G55, and 4, G69, G56; Patent No. 104,143, U.S. Patent No. 339, No. 49, No. No., No. 4, No. 2, No. 2, No.

View: im month, the bismuth salt is a diaryl hard sulfonium salt, which is substituted from a stable group. More preferably, it is replaced by three = one. Further, it is preferable to take it by four or more alkoxy groups, and to correct the silk hardenability of the pure material, and at least one diaryl group is formed at a part of the core: one (four). Alternatively, the functional group having an absorption of 3 Å as a substituent is equal to or greater than the sulfa-correction salt which is applicable to the present invention, and is exemplified by: European Patent No. -54-200906985, No. 370,693, No. 390,214, and 233,567 No. 297,443, 297,442, U.S. Patent No. 4,933,377, 161,811, 410,201, 339,049, 4,760,013, 4,734,444, 2,833,827, German Patent 2,9,4,626 The sulfonium salt described in each specification of No. 3,604,580 and No. 3,604,581 is preferably substituted with an electron-withdrawing group in view of sensitivity to stability. Preferably, the Hammett value of the electron withdrawing group is greater than zero. Preferred examples of the electron-withdrawing group include a halogen atom, a carboxylic acid, and the like: other preferred sulfur rust from the viewpoints of thermal decomposition property, stability balance, and photocurability at the time of use in combination with a sensitizer or the like. The salt is a triarylsulfide salt. Preferably, it has at least one electron-withdrawing group such as a halogen atom or a carboxyl group; further preferably a di- or bi- or more substitution; an optimum substitution or a tri- or higher substitution. — The form of other preferred sulphur salts can be exemplified by the fact that the substituent of the triaryl sulfonium has a coumarin, an oxime and a thione having an absorption of greater than or equal to that of the second. As the triarylthione salt of other preferred sulphur salts, at least one triaryl group is formed at a chromophore--portion having an absorption of greater than or equal to nm. Alternatively, a triarylsulfide salt containing a functional group having an absorption of 300 mn or more as a substituent is recorded. As the rust salt compound, it is also exemplified by: j v. Crivdl〇, etc., moleucules, 10 (6), 1307 (1977); v Crivdl〇 et al.

Polymer Sci. Polymer Chem. Ed. 17, 1 石 石石盐; C S. Wen et al, The, Pr〇c. c〇nf Rad Asu (10), recorded in Tokyo, Oct (1988) Rust salt, such as bell salt. ' (g) a group of compounds can be exemplified by: diphenyl f ketone, Michelin, 2 - A - 55 - 200906985 benzophenone, 3-methyl benzophenone, 4 - fluorenyl benzophenone , benzophenone derivatives such as 2-chlorobenzophenone, 4-bromodibenzophenone, 2-carboxybenzophenone, 2,2-dimethoxy-2-phenylacetophenone, 2 ,2-diethoxyacetophenone, ι_hydroxycyclohexylpropiophenone, α-hydroxy-2-methylpropiophenone, hydroxy-丨-mercaptoethyl-(p-isopropylphenyl)one, 1 · mercapto (p-dodecylphenyl) ketone, 2-mercapto-(4'-(indolyl)phenyl)_2·morpholinylacetone, trichloroindolyl-(p-butylphenyl) Ethyl ketone derivatives such as ketone, 2-benzyl-2-dimethylamino 4-morpholinopropyl phenylformamidine (butyrophenone); oxime ketone, 2-ethyl sulphate, 2- Isopropyl thioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone, 2,4-ethylpyridone, 2,4-diisopropylpyridone, etc. Derivatives; benzoic acid ester derivatives such as p-dimethylaminobenzoic acid ethyl ester, p-diethylaminobenzoic acid ethyl ester, and the like. The (h) ketal compound may, for example, be a benzyl methyl ketal or a benzyl _p_ methoxyethyl ethyl acetal. (1) The benzoin compound may, for example, be benzoin isopropyl ether, benzoin isobutyl ether, benzoin oxime ether or methyl orthophenyl benzoate. The ten bite compound may, for example, be a 9-phenyl alpha bite or a 1,7-bis (9-fluorene) gargene. (1) The organic peroxide may, for example, be trimethylcyclohexanone peroxide, acetamidine acetone peroxide, 191_bis (third-stage butyl per 3 5 -trimethylcyclohexane, 1, 1_ bis (third-order butyl peroxy) cyclohexane, 2, 2 bis (th-butyl peroxy) butane, tertiary τ-hydroperoxy (tetra), diisopropyl benzene hydrogen Oxide, bismuth oxime, 5 _ 2 : compound, 1,1,3,3·tetradecyl butyl hydroperoxide, tertiary butyl cumyl peroxide, dicumene Base peroxide, 2,5-diindenyl _25 _ (second-56-200906985 grade based peroxygen) hexagram, 2,5-〇axn〇yl per- ruthenium, peroxy sulphate Benzoe, 2,4·dichlorophenylhydrazine peroxide, diisopropylperoxy-monohydrate, acid vinegar, di-2-ethylhexylperoxydicarbonate, di-2-ethoxyethyl , monocarbonate, dimethoxy isopropyl peroxycarbonate, bis(3-hydrazino-3 methoxybutyl) peroxydicarbonate, third butyl peroxyacetate, Third, Ding, peroxyvaleric acid vinegar, third-grade butyl peroxy neodecanoic acid vinegar, third-grade butadiene peroxyoctanoate, second-grade butyl peroxygen Sour vinegar, third-grade carbonate r (two pavilions (four) coffee with ^ four (10) tri-butyl peroxy dioxo-diphenyl with 4 Λ, 3,3,4,4 _ four (second-stage hexyl peroxycarbonyl) Benzophenone, (^ flute: 1/4 i to isopropyl isopropyloxyperoxy)diphenyl-, M-based ϋ 过 peroxydi- phthalate _), carbonyl II (third-grade hexyl emulsifiable mono- phthalate), etc. Section VIII compounds can be clearly stated as a Japanese paste, and the azo compound contained in the S. County such as _2_yl)amino)·3_phenylcoumarin oxime 5Amino|monomethylamino)-3·phenyl coumarin, /butylethylamine ♦ triazine_2_yl) Base)·3·phenyl coumarin and the like. ...-Methylamino I triazin-2-yl)amine Menque (8) can be exemplified by: U.S. Patent No. 28_No. Nitrogen-Ethyl-cyclohexyl compound,-bis(tetra)(P)metallocene compound Ice (5) 396, 曰^如·曰f Patent special open Zhaoben patent special open Zhao 63 marriage, Japanese present A newspaper, 曰本 patent special Kaiping "Suppression number -57- 200906985 bulletin, 曰本专利特开平2·47各种5 5 韵 号 所 各种 各种 各种 各种 各种 各种 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 韵 本 本 本 韵 韵 韵 = = = = = % pentyl alkenyl difluorobenzene I bis-2,4,6-trifluorobenzene+yl, mono-l-alkenyl | a thiol-dipentadienyl-Ti·difluorobenzene+yl, two Methylcyclopentadienyl H2,3 4 5 6 曰 专利 专利 专利 彻 彻 彻 彻 彻 彻 彻 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 (q) The hexaaryl-based bismuth compound can be exemplified by various compounds described in Japanese Patent No. 3,479, 185, and 4, 3iij = (4) 4, 622, 286. :2,2,·Bis(o-chlorophenyl)_4,4,,5,5,-tetraphenyldimethicone &gt;odor phenyl))-4,4',5,5'-tetraphenyl 2,2,2-bis(o-, p-chlorophenyl)_4,4',5,5'-tetraphenyldiimidazole, 2,2,_bis(o-chlorobenzene f)- M:,5,5,-tetrakis (metamethoxyphenyl) dimiso, 2,2,_bis(o-, o-, _dichlorobenzene)-4,4'di 5,5'-tetraphenyl Base dimi, 2,2,_bis(o-nitrophenyl)_4,4,5,5,_tetraphenyldiimidazole, 2,2,_bis(o-nonylphenyl)-4, 4,5,5,-tetraphenyldiimidazole, 2,2'-bis(o-trifluorophenyl)-4,4,5,5,-tetraphenyldiimidazole, and the like. (Γ) mercaptophosphine (peroxidation) compounds can be exemplified by: Ciba Specialty

Irgaracure8i9, Darocure 4265, Darocure TPO, etc. manufactured by Chemicals. As the (E) acid/radical generating agent used in the present invention, from the viewpoint of exposure sensitivity &quot;58-200906985 degrees, it is preferred from a trihalomethyltriazine compound, benzyldimethylketal a compound, an α-hydroxyketone compound, an α-aminoketone compound, an acid-based scaly compound, a phosphine oxide-based compound, a metallocene compound, an anthraquinone compound, a triallyl imidazole dimer, a radium compound, a benzothiazole Compound, benzophenone compound, acetophenone compound and its derivative, cyclodecadiene-benzene-iron complex and its salt, methyl oxadiazole compound and 3-aryl substituted coumarin A compound selected from the group consisting of compounds. The above-mentioned (Ε) compound which generates at least one of an acid and a radical is appropriately selected by considering the relationship with the compound which hardens by at least one of an acid and a radical, and can implement higher. Sensitivity. When the (Ε) acid/radical generating agent is used in combination with the curable composition of the present invention, the content of the acid/radical generating agent is preferably (1) 丨~sun relative to the total solid content contained in the inkjet ink. 'More preferably 〇5~25 wt%, especially good is 1~2〇wt. /. . When the content of the (Ε) acid/radical generating agent is within this range, a better sensitivity and a strong hardened portion can be formed. The above (E) compound which produces at least one of an acid and a radical may be used singly or in combination of two or more kinds. &lt;(F)Binder Polymer&gt; In the present invention, in order to improve the hardenability at the time of hardening of a droplet which is applied onto a substrate by an inkjet method and form an image, and to improve the strength after curing, adhesion to the substrate Sex, you can add a binder. As the binder component, a binder component which is composed only of a resin which does not have polymerization property itself and which is only dried and solidified can be used. However, in order to impart sufficient strength, durability, and adhesion to the coating film, it is preferred to use the inkjet method to form a pattern of the ink layer (coating film) on the substrate, and then the polymerization can be carried out by using -59-200906985 polymerization. As the binder component to which the ink layer is cured, for example, a curable binder component which can be polymerized and cured by light-heating such as visible light, ultraviolet light, electron beam or infrared light can be used. In the present invention, it is also suitable to use a binder containing a functional group reactive with an oxabutyl group in the presence of an acid. The curable adhesive component may contain a curable resin which can be polymerized and cured by light or heat such as visible light, purple wire, electron beam or infrared light, and may further contain (iv) acid and base by heat and/or according to S. a compound such as a test, a photosensitizer, or a low molecular compound containing at least one curable radical polymerizable ring-based property of the sclerosing resin, etc., in order to impart film formability and hardness Relative to the conformity, the preferred enthalpy includes a higher molecular weight. The higher the molecular weight, the higher the molecular weight than the 留 留 留 々 可以 可以 可以 可以 可以 可以 可以 可以 可以 可以 可以 可以The molecular weight, as the ancient times greater than #5, is the standard. As a molecule: a polymer that can be used without polymerization itself or two or two ==polymerizable polymer' can also be used as a binder polymer a polymer which can be based on, for example, a monomer group as shown below; (7) a binder polymer which can be used in the present invention, which is used to serve (1) 2-hydroxyethyl acrylate and acrylic acid 4 - by Ding Yu, ^ 酸酸 2 力丙酉, C Dilute acid 3_ propyl acrylate, hydroxypropyl acrylate, methacrylic acid / 3 hydroxy hydroxyethyl acrylate, methacrylic acid 2- ~ == A:; =: _, etc. -60- 200906985 (2) Ester, ethyl acrylate, propyl acrylate, butyl acrylate, isobutyl acrylate, amyl acrylate, hexyl acrylate, 2-ethylhexyl acrylate, octyl acrylate, benzyl acrylate, ethyl acrylate, acrylic acid shrinkage Glyceride, 3,4-epoxycyclohexyl methacrylate, vinyl acrylate, 2-phenylvinyl acrylate, propyl acrylate, allyl acrylate, 2-allyloxyethyl acrylate, Acrylic acid alkyl acrylate such as propyl acrylate. (3) decyl methacrylate, ethyl methacrylate, propyl methacrylate, (butyl methacrylate, isobutyl methacrylate, amyl methacrylate) , hexyl methacrylate, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, benzyl methacrylate, 2-chloroethyl methacrylate, glycidyl methacrylate, A 3,4-Epoxycyclohexylmethyl acrylate, vinyl methacrylate, mercaptopropyl Alkyl methacrylate such as 2-phenylvinyl acrylate, 1-propenyl methacrylate, allyl methacrylate, 2-allyloxyethyl methacrylate, and propargyl methacrylate. (4) acrylamide, mercapto acrylamide, N-hydroxydecyl acrylamide, N-ethyl acrylamide, N-hexyl methacrylamide, N-cyclohexyl acrylamide, N- ί Hydroxyethyl acrylamide, fluorene-phenyl acrylamide, hydrazine-nitrophenyl acrylamide, hydrazine-ethyl-hydrazine-phenyl acrylamide, vinyl acrylamide, vinyl methacrylate Acrylamide or methyl group such as amine, hydrazine, hydrazine-diallyl acrylamide, hydrazine, hydrazine-diallyl methacrylamide, allyl acrylamide, allyl acryl decylamine Acrylamide. (5) Ethyl vinyl ether, 2-chloroethyl vinyl ether, hydroxyethyl vinyl ether, propyl vinyl ether, butyl vinyl ether, octyl vinyl ether, phenyl vinyl Vinyl ethers such as ethers. -61- 200906985 (6) Vinyl esters such as vinyl acetate, vinyl chloroacetate, vinyl butyrate, and vinyl benzoate. (7) Styrene, α-mercaptostyrene, methyl styrene, chlorophenyl styrene, p-ethoxylated styrene, p-carboxystyrene and other styrenes. (8) Vinyl ketones such as methyl ketone ketone, ethyl vinyl _, propyl vinyl, and phenyl vinyl ketone. (9) B knows rare hydrocarbons such as r, propylene, isobutylene, butylene, and isoprene. (10) N-vinyl V» pyrrolidone, acrylonitrile, methacrylonitrile, and the like. (11) Maleic imine, N-propylene acrylamide, N-ethyl methacrylamide, N-propyl decyl acrylamide, N_(p-benzophenone) An unsaturated quinone imine such as acrylamide. (12) A methacrylic monomer having a hetero atom bonded to the α-position. For example, the compounds described in the specification of Japanese Patent Application No. 200-15595, and the specification of Japanese Patent Application No. 2001-115598 can be cited.

(13) Methyl acrylate, acrylic acid, itaconic acid, maleic acid, fumaric acid, I methacryloxyethyl succinic acid, 2-propenyloxyethyl succinic acid, 2-methyl Propylene oxiranyl ethyl hexahydrophthalic acid, 2-methyl propylene terephthalate ethyl phthalic acid, 2-propenyl guanamine-2-mercapto-1-propane sulfonic acid, 3-sulfonyl hydrazine A monomer containing a acid or a salt thereof, such as a potassium acrylate. In order to improve the hardenability, it is preferred that the side chain contains an allyl group or a glycidyl group or a (meth)acrylic acid group, a styryl group or the like, and a reactive group resin® side chain contains an allyl group. Or a vinyl ester group and a carboxyl group (mercapto) acrylic resin, and an alkali-soluble resin having a double bond in a side chain described in JP-A-2002-62698, JP-A-2002-62698-62-200906985 The side chain described in the publication contains an excellent balance of ruthenium sensitivity, and is suitable for use as a film strength of an alkali-soluble resin of the amine group of JP-A-2001-242612. The mouth does not find Lit Kung Kwan 7_12〇〇4, Japanese Patent Special Fair 7-120041, Japanese Patent Special Fair 7_12〇〇42, Japanese Patent Special: Ping 8-12424, Japanese Patent Special Open 63-287944 No., Japanese Patent Laid-Open No. Sho 63-287947, Japanese Patent Laid-Open (2) Coffee No., Japan No. 2: 1:116232, etc., an acid-containing polyurethane-based viscous δ agent or a Japanese patent system. The side-chain 3 described in the first aspect of the invention has a high-strength polymer of the binder of the side-bonding member 3 and the double-bonding agent. Therefore, it is advantageous in use. European Patent No. 993966, European Patent No. 12G4_, Japanese Patent Laid-Open No. 2001-318463, etc. The acid-containing acid-modified polyethylene-based binder containing the acid group is excellent in the polymerization of __degree and hard-recorded, so it is suitable to use 1 = external water; ^ linear organic polymer 'polyethylene sputum Or polyethylene oxide _. In order to improve the degree of hardening film (four), alcohol soluble = nylon or 2, 2 bis (4 · fresh base) propylene and epoxy chloropropene condensed bonds, etc. can also be used in the present invention The binder polymer, whose weight average molecular weight is preferably 5 or more, is preferably 10,000 to 3 Torr. Preferably, the number average molecular weight is greater than or equal to 〖, _, and is in the range of 2'_~250,000; and its polydispersity (average in the weight average molecule) is preferably greater than It is more preferably 1, more preferably in the range of u to 10. The above binder polymer may be any of a random polymer, a block polymer, a -63-200906985 graft polymer, etc., which can be used in the present invention. The binder polymer can be synthesized by a method. When the synthesis is carried out, the solvent can be as follows: = gasified ethylene, cyclohexanone, methyl ethyl ketone, propyl ketone, methanol, ethanol Ί early A shout, ethylene glycol single B Sediment, 2-methoxyacetic acid, diethylene glycol 1, dimethoxy-1-propanol, r-methoxy-2-propionic acid, t-formamide, bis-indenyl hydrazine Amine, toluene, ethyl acetate, methacrylate, lactic acid, dimercapto, water, etc. The above two or more kinds of solvents are used in combination. Λ Early or synthetic adhesives usable in the present invention The polymer base time polymerization starts to be heard: a conventional compound such as a money-based initiator, etc. mm start (photo-curing adhesive) Agent polymer) It is also possible to add a monofunctional monomer or oligomer to the photohard binder having the preferred characteristics as described above. As the monofunctional perfume, for example, styrene, vinyl acetate, etc. may be exemplified. Monofunctional such as hexamethylene hexanoic acid or phenoxy acetoacetate, which uses only the following epoxy compounds in the range of the effect of the present invention, which can improve the hardenability by heat, the heat generating acid or the test. The character 3 (4) is fine, and the molecular weight of the finished towel is higher than that of the (4) polyfunctional epoxy dioxime:: the epoxy group is replenished in the curable resin composition, and the concentration of the epoxy group is increased, and the crosslinking can be improved. Density: In the functional epoxy compound, 'in order to improve; later, preferably, an epoxy compound containing four or more ί-64-200906985 oxy groups in the molecule. In particular, when the present invention is used in an inkjet manner, in order to increase the weight average of the r-bonding epoxy compound on the inkjet to be equal to 1 Å, the strength of the cured resin layer or The hardness is likely to be lowered. Therefore, it is preferable to add the above-described tetrafunctional or higher polyfunctional epoxy compound to the curable resin composition to sufficiently increase the crosslinking density. The polyfunctional epoxy compound is an epoxy compound contained in one molecule. The compound of the group may be, and is not particularly limited, and for example, it may be a bismuth A type epoxy, a Weixian touch, a (five) = fat, a double W type resin, a diphenyl fine oxy resin, a 31% oxygen resin, a #type ring Oxygen resin, biphenyl type ring grease, bismuth type, fat: benzene secret varnish Wei oxygen resin, adjacent sclerosing varnish type epoxy resin, bismuth-based styrofoam epoxy resin, trifunctional epoxy resin, four Benzene (7 work = -", PhenylGl) E-epoxy resin, dicyclopentadiene riding ring = fat, hydrogenation (tetra) A-type epoxy resin, biguanide A containing nuclear transformation epoxy ί 曰, polypropylene-alcohol Type of oxygen resin, glycidol g type epoxy resin, glycerol amine type epoxy resin, ethylene-2 ring Resins, alicyclic resins, heterocyclic type epoxy resins and the like. m F can be specifically described as a product such as EpiC〇at 828 (made by Oily She11 Epoxy Co., Ltd.) and other types of A-type epoxy resin; the trade name ydf_i7 is made into a chemical system), etc. Brominated (tetra) A-type epoxy resin such as YDB·(East =, manufactured by Seiko Co., Ltd.); trade name EpicL (10) (Daily Ink Chemical Industry Co., Ltd.) and other double 酴 s type epoxy tree =, trade name YDC-1312 (Dongdu Huacheng Hydrogen-based epoxy resin; product name: EPICLON EXA4032 (manufactured by Dainippon Ink Chemical Industry Co., Ltd.), etc. -65- 200906985 Naphthalene type epoxy resin; trade name Epicoat YX4000H (manufactured by Oily Shell Epoxy Co., Ltd.) Epoxy resin; bisphenol A type novolac epoxy resin such as Epicoat 157S70 (manufactured by Oiled Shell Epoxy Co., Ltd.); trade name Epicoat 154 (manufactured by Oily Shell Epoxy Co., Ltd.), trade name YDPN-638 (Dongdu Chemical Industry Co., Ltd.) A novolac type epoxy resin, such as YPCN_7〇1 (manufactured by Tohto Kasei Co., Ltd.); a non-phenolic varnish-type epoxy resin; a product name: EPICLON HP-7200 (manufactured by Dainippon Ink Chemical Industry Co., Ltd.) Lean acid type epoxy resin; trade name Epicoat 1032H60 (oiled shell Triphenyl epoxide type epoxy resin such as Epoxy Co., Ltd.; trade name: VG3101M80 (manufactured by Mitsui Chemicals, Inc.), etc.; and tetraphenyl benzene (product name: Epicoat 1031S (manufactured by Oil Chemical Shell Epoxy Co., Ltd.)) Λ Two - ('phenylol) ethane type epoxy resin; trade name Denac〇1 εχ_411 (Nagase Chemical Industry Co., Ltd.) and other four-functional epoxy resin; trade name ST-3000 (made by Dongdu Chemical Industry Co., Ltd.) A product of a glyco-alcohol type epoxy resin such as a product of the product name: YH-434 (manufactured by Tohto Kasei Co., Ltd.) Glyoxal type epoxy resin such as YDG-414 (manufactured by Tohto Kasei Co., Ltd.); alicyclic polyfunctional epoxy compound such as Epolide GT-401 (manufactured by DA1CEL Chemical Co., Ltd.); triglycidyl isocyanate (TGIC) A type epoxy resin, etc., may be added as an epoxy reactive diluent, etc., as needed. The above-mentioned polyfunctional epoxy compound + Jiayi merchant name EpieGat 157S7q ( Oiling

Epoxy Co., Ltd., etc. A type of _ varnish-based epoxy resin and the trade name YDCN- (made by Tohto Kasei Co., Ltd.) and other varnish-type epoxidized-66-200906985 as a polymer having a relatively high molecular weight As the epoxy compound "), a polymer composed of at least a constituent unit represented by the following formula (1) and a constituent unit represented by the following formula (2) and containing two or more glycidyl groups can be used.

Diterpenes (1) 〇〆 R2 (R1 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R2 represents a hydrocarbon group having 1 to 12 carbon atoms.) -fCH2-c4-=〇(2) 9 ch2 (R3 represents a hydrogen atom or an alkyl group having 1 to 10 carbon atoms.) The structural unit represented by the formula (1) is derived from a monomer represented by the following formula (3).

Ch2=c rO-R2 (3) (R1 and R2 are synonymous with the formula (1).) -67- 200906985 Composition = =, the monomer represented by = is used as a hardened coating film of a conjugated epoxy compound - by the hardening of the present invention The transparency of the formation of the resin composition. In the formula (3), R2 represents a carbon atom number which is a linear aliphatic group, an alicyclic type, an aromatic group = a 2=, and further includes an addition structure such as a double bond, a side chain of a hydrocarbon group, and a side of a snail %. Chains, cyclic crosslinks of hydrocarbon groups, and the like. Specific examples of the monomer represented by rr on the rr include: (meth)acrylic acid methyl = (methyl) propyl ethyl acetoacetate, (methyl) propyl isopropyl vinegar, (methyl) propylene = positive vinegar, (meth)acrylic acid isobutyl vinegar, (meth)acrylic acid n-butyl vinegar, (meth)acrylic acid third butyl ester, (methyl) acrylic acid 2 · ethyl hexanoic acid, (methyl ), hexyl enoate, (meth) propyl vinegar vinegar, (methyl) propyl lauric acid, vinegar (meth) acrylate, (meth) acrylate, third butyl hexane vinegar, (Iso-norbornene) (meth)acrylate, (meth)acrylate, (cyclohexyl)(cyclohexyl)acrylate, phenyl (meth)propionate, and the like. In the formula (3), R1 is preferably hydrogen or a methyl group; and R2 is preferably a group having 1 to 12 carbon atoms, and particularly preferably an anthracenyl group and a cyclohexyl group. Among the monomers represented by the above formula (3), preferred examples of the monomer include decyl methacrylate (MMA) and cyclohexyl methacrylate (CHMA). The constituent unit represented by the formula (2) in the fluorene polymer is derived from the early bamboo represented by the following formula (4). 22=c R3 &gt;-〇- (4) 〇 (R3 is synonymous with formula (2).) -68- 200906985 Formula (5) (4) Lai secret polymerization leader Wei Ke (epoxy anti-η: the polymer The storage stability of the curable resin composition is excellent. The viscosity is not easily increased during storage and during the discharge operation. It is presumed that the reason is - the formula is the formula or the formula (the epoxy group in the sentence is a glycidyl group. Using the alicyclic ί instead of the formula) When the monomer is represented by (4), the viscosity of the curable resin composition tends to increase. In the formula (4), the r3 is hydrogen or a methyl group: the monomer may specifically be a glycidyl (meth) acrylate. Specially known as 疋glycidyl methacrylate ((31^8). The above d 5 can be a random copolymer or a separate one, as long as it can determine the details of the color filter film, such as hardness and The above-mentioned polymer may be referred to as a formula (1) or a bond-constituting unit. The above-mentioned monomer may specifically exemplify the constituent unit of the formula (1) and the formula (7) and He Sheng of the compound of acrylonitrile and benzene. The composition of the formula (7) breaks the monomer filler monomer: the derivative (2 disintegration) table tree, recorded as the track circumference of ^ίΓο. When the formula (1) When the amount of the unit exceeds the above ratio, the chest hardening reaction point becomes less, and the crosslinking density may become lower. On the other hand, the amount of the constituent unit of =, (2) exceeds the above ratio 9 〇: 1 〇 when j becomes less, hardening The shrinkage is likely to become large. The accumulation of the moon frame when the weight average molecular weight of the above-mentioned adhesive epoxy compound is converted into a weight average molecular weight table, preferably large, especially greater than or equal to 4, _. Ring 3 Oxygen = He-69-200906985 The molecular weight of the substance is much less than 3, _, as: _ =::; ==;,] When the above τ ^ knife amount is repeated in polystyrene:: molecular weight 'It is preferable to be less than equal = f, to wait for ri5, _. This is because when the molecular weight is stable, the second degree of the valley is easy to rise, the amount of discharge or the straightness of the direction of the fairy may change. Poor, or long-term bismuth may be deteriorated., heterozygous Wei compound, _ Jiayu, using polyphenyl = different weight average molecular weight (Mw) for the above _ methyl propyl glycidyl glycoside (GMA ) / methyl propyl riding vinegar (MMA) copolymer. It should be noted that as long as the GMA / MMA silk _ reach For the purpose of the invention, other monomer components may be contained. ^ The synthesis of the above-mentioned adhesive epoxy compound is as follows: in a four-necked flask equipped with a condenser, a scrambler, and a dropping funnel, The solvent is heated to 12 Gt while the lion is used. The cation containing no warp group is used to avoid decomposition of the epoxy group during the synthesis reaction. However, the above formula is combined by a constant dropping method from a dropping funnel for 2 hours. (3) The indicated single, _ the monomer represented by the above formula (4) and the composition of the other monomer required" ^ δ mixture of the initiator (dropping component). After the completion of the dropwise addition, the temperature is lowered to 120 C. The catalyst was added and allowed to react for 3 hours, and then the temperature was raised to 丨3〇. Thereafter, the reaction was terminated for 2 hours to obtain the above-mentioned adhesive epoxy compound. In the thermosetting adhesive component used in the present invention, it is preferred to add -70 to 200906985 - an epoxy compound having two or more epoxy groups in the molecule and having a molecular weight smaller than that of the adhesive epoxy compound. (Here, __ "Multiple = polystyrene equivalent weight of polyfunctional epoxy compound Ϊ 2 222 分子量 and the molecular weight of the adhesive epoxy compound combined therewith, preferably 疋 is less than or equal to 4, coffee, particularly preferably less than Is equal to 3, _. It should be noted that the epoxy compound polystyrene conversion weight

The molecular weight y is determined by GPC (_ osmotic chromatography), for example, using tetrahydrofuran as a developing solution 'using HLC-8〇29 (T〇sh〇(股)). (Hardware) In the photocurable adhesive component or the thermosetting adhesive component which can be used in the present invention, a curing agent may be added in combination as needed. The hardener is, for example, a plurality of 7 carboxylic anhydrides or polycarboxylic acids. Specific examples of the polycarboxylic acid anhydride include o-dopic anhydride, itaconic anhydride, benzoic acid anhydride, methyl maleic anhydride, dodecenyl succinic anhydride, propylene tricarboxylic anhydride, maleic anhydride, and hexahydrophthalic acid. An aliphatic or alicyclic dicarboxylic anhydride such as dicarboxylic anhydride, dimethyltetrahydrophthalic anhydride, Himie ^hydride or Nacjic anhydride; An aliphatic polybasic dianhydride such as an alkyltetracarboxylic dianhydride or a cyclopentane tetracarboxylic dianhydride; an aromatic polyphthalic anhydride such as pyromellitic anhydride, trimellitic anhydride or benzophenone tetraphthalic anhydride; An acid group-containing acid anhydride such as an acid ester or glyceryl trimellitate is particularly preferably an aromatic polycarboxylic acid anhydride. Further, a commercially available epoxy resin hardener containing a carboxylic acid anhydride is also suitable for use. Specific examples of the polycarboxylic acid used as the hardener in the present invention include -71-200906985 soil: aliphatic polybasic acid such as arsine, glutaric acid, adipic acid, butane tetracarboxylic acid, and benzal acid; O-dibenzoic acid dicarboxylic acid, 1,2,4·cyclohexane triterpenic acid, ring sister tetradecanoic acid fat = calcined carboxylic acid; and o-arsic acid, m-decanoic acid, p-benzoic acid Yuqi: Yuanbenic acid, M, 5,8 naphthalenetetracarboxylic acid, dibenzoic acid tetracarboxylic acid = fragrant polycarboxylic acid, preferably an aromatic polycarboxylic acid. Acid Monomer The above polycarboxylic acid anhydride and polybasic acid can be used singly or in combination of two or more. It is also possible to add the amount of the hardener used in the present invention to the range of the weight of the tree and the amount of the hardening agent in the range of the weighting agent of the present invention. The effect of the hardenability can form a tough coating film: the adhesion of the substrate of the blade or the uniformity of the coating film, the smoothness = :! = more preferably 5 to 50 parts by weight. If the amount of the hardener added is too large, it is difficult to obtain an effect of effectively improving the hardenability. In the second invention, in order to improve the hardness and the hardness of the hardened tree, a catalyst which promotes the reaction between the acid-epoxy group and the oxime reaction is added to the sclerosing binder component. As the above catalyst, an initiator which is inactive at the time of heat curing can be used. It is preferable to use the cassia sulfhydryl group or the maleic imide group, the dimethyl group, or the combination of the above-mentioned compounds in the functional group containing = first dimerization. Things. • 72-200906985 &lt;Other components&gt; An additive which can be used for the inkjet ink of the present invention other than the above (E) acid/radical generator and (F) binder polymer which are preferred components for combination . (Sensitizer) In the binder component, in order to increase the decomposition efficiency of the initiator and to achieve a long wavelength of the photosensitive wavelength, a sensitizer may be used as needed. As a material which can be used in the present invention, the above-mentioned photopolymerization initiator is sensitized by an electron transfer or energy transfer mechanism. It can be used in the present invention to make the compounds listed separately and respond to the increase in light required for visible light, ultraviolet rays, electron rays, and infrared rays. Examples of preferred additions are: those belonging to the class of compounds and ranging from 330 nm to 450 nm to a gentleman. Sensitization with absorption wavelength in the circumference - the above sensitization: the agent can be: polynuclear aromatics (such as phenanthrene, anthracene, bismuth benzene, anthracene, 9-sodium di-oxylated oxime), eosin, green Worker, Ruo Danming, Bangladesh Rose = staff (isopropyl ketone, diethyl _, chlorine = thiocarbocyanine, oxacarbocene), phthalocyanine _ such as phthalocyanine, carbon phthalocyanine = class, thiazides (such as thioindigo, yttrium blue, blue) indigo such as acridine orange, chlorferrin, acridine yellow), 蒽 roller type 吖 吖 类 (eg squalium) &gt; ^ 曱Ketocoumarin, ketocumarin, phenotype, phenotype, base benzene, azo compound, diphenyl decane, = φ di-vinyl-based decane, di-p-vinyl-73- 200906985 Benzene, ^ get 11 sitting class, intimidation, spiro compounds, sputum. Ketone ketone, disperse blue, styryl pyrylium compound, pyrromethene compound, D-salt triterpene compound, benzoxanthene compound, barbituric acid derivative, thiobar A heterocyclic compound such as an aromatic acid ketone compound such as a benzoic acid derivative, an acetophenone, a diphenylmethylnet, a peptone or an amino ketone or an N-aryl oxazolidinone. Further, it is described in the specification of the European Patent No. 568,993, the specification of the U.S. Patent No. 4,5,8,811, the specification of the Japanese Patent No. 5,227,227, the Japanese Patent Laid-Open Publication No. Hei. No. Hei. Compounds and the like. (Common Sensitizer) Among the binder components, it is preferred to contain a co-sensitizer. In the present invention, the co-sensitizer further enhances the sensitivity of the sensitizing dye or the initiator to the active radiation or the polymerization inhibition of the polymerizable compound produced by the inhibition.

Examples of the above-mentioned co-sensitizers are amines, for example, MR Sander et al. Journal of P〇lymer Society j % 10 4 3173 f (1972) &gt; g rhyme 89, 曰本专利专开昭 51 side report, 曰本Patent 曰 〇 号 号 号 公 、 、 、 、 、 、 、 、 R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R R , 日本Other examples of the sensitizer include mercaptans and sulfurs, for example, *74-200906985 5, 5: two specializations, and thiol compounds of 镜_^^; Japanese Patent Publication No. 5-142772 Compounds, etc., can be =?::===7 :: one base is stupid, ... base-class surface = other examples of co-sensitizers can be cited as N-phenylgan test, etc.; The compound (for example, tributyltin acetate or the like) 曰 = the nitrogen donor described in the Japanese Patent Publication No. 4U; the sulfur-containing compound described in the publication No. 7 (for example, trisulfide) Equilibrium of transfer to increase the hardening speed = Speaking of the 'relative to the total solid content of the hardenable composition, the above /, the sensitizer's content is better Range of ι~3Gwt%, more preferably in the range ι ~25Wt% 'into - further preferred that G 5~2 () w (polymerization agent barrier) solid

In order to prevent thermal polymerization which is required for the polymerization of the curable composition during storage or storage, it is desirable to add a small amount of the thermal polymerization inhibitor to the binder component. Examples of the thermal polymerization preventing agent which can be used in the present invention include hydroquinone, p-methoxyphenol, di-terternary butyl-p-cresol, pyrogallol, third-grade butyl catechol, benzoquinone, and 4 , 4,-thiobis(3-methyl.6_tertiary butylphenol), 2,2-methylenebis(4_methyl_6_third-butyl phenyl), N _Nitrosophenylhydroxylamine trivalent sulfonium salt and the like. -75- 200906985 The amount of the thermal polymerization inhibitor added is preferably "about 0.01 wt% to about 5 wt%" with respect to the total weight of the composition. In addition, in order to prevent the polymerization blockage of the raw material, it is necessary to add a high-grade fat such as yam or yamamine, etc., and to dry it through the drying process after the cloth is applied to the photosensitive layer. The amount of the derivative added is preferably from about 5% by weight to about 1% by weight of the total composition. (Other Additives) In the present invention, in order to improve the physical properties of the hardened film, it is possible to further add: ',, machine filler or (4); 2,2_thiobis...methyl-6 third-butylphenol) , 2,6-di-tertiary butyl phenol and other antioxidants; 2_(3_tert-butyl 5 methyl-2-hydroxyphenyl)_5·chlorobenzotriazole, alkoxybenzophenone A conventional additive such as an ultraviolet ray and a collecting agent, a sodium polyacrylate or a polymerization inhibitor such as various surfactants. Examples of the bismuth plasticizer include: dioctyl phthalate, lauric acid lauric acid, triethylene glycol octoate, phthalic acid ester, acid trimethyl vinegar, acid dioxin,癸二m, triethyl glycerin, etc. The adhesive θ Β ' can be added with an adhesive of 10 wt% or less relative to the total of the compound containing an ethylenically unsaturated double bond and the binder. The curable composition of the present invention described above is hardened with high sensitivity and has good storage stability. Further, it has high adhesion to the surface of a hard material such as a substrate on which the composition is applied. Therefore, the curable composition of the present invention can be preferably used in the fields of image forming materials, ink coatings, adhesives, coating agents and the like. ~76-200906985 (Manufacturing method of ink) It is possible to introduce each component into the inkjet ink for coloring the filter film. When the pigment is mixed, the solid component is dissolved or dispersed. However, in the agent, the domain is divided into groups to reduce the total amount of the solution. Therefore, in this case, the pigment is not sufficiently dispersed in the solvent, and the dispersibility of the pigment and the dispersion speed of the dispersion are well-distributed, such as a full-dispersion agent, which is invested in it, and is used in general. In the granule containing the main cultivator and the most medicinal agent, the inkjet ink of the present invention can be prepared by a high-speed disperser or the like, and the inkjet ink of the present invention can be prepared in a large sigma alcohol solvent. Or the inkjet ink of the present invention can be prepared by using a solvent-added calcination solvent containing only the main solvent, and the above-mentioned rhyme dispersion and "two-mixing and dissolving" other than the pigment can be made into a high-speed dispersing machine. 1) The color filter film of the present invention of the present invention forms a color light-emitting film having a pixel or a black matrix or the like as an inkjet ink formed by the inkjet ink of the present invention, and can display health and the like. a color filter film used in an image input device such as a color light film or a body image sensor used in an image output device. <Color filter film and method for producing the same>, color filter of the present invention Membrane manufacturer It is characterized in that droplets of the ink of the present invention -77-200906985 are ink-jet-formed to form a pixel by a concave portion surrounded by a partition wall formed on a substrate. Up ===== includes: Hunting is performed by irradiating an active energy ray to form a hardening process in which red is hardened or in a process of forming all the halogens in a desired color tone. A baking process or the like may be provided as needed: the upper shape is formed, and the partition wall is formed before the halogen forming process The details of the method of forming the wall in advance of the substrate 4 = will be described later. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ^Operation 'used to form a pixel (for example, P5 fflM, the inkjet ink of the pattern is immersed to form a concave portion on the substrate) to make a plurality of pixels of two or more colors constitute a pair of inks 2 == two : a method of thermally hardening an ink; a shadow layer: a shape of a duck formed on a plate on which a droplet is sprayed is not particularly limited, and may be a strip shape of a black matrix=two, or may be a lattice shape, or may be -78-200906985 Ink and by various methods: continuous spraying a method of spraying charged inkjet ink; a method of intermittently ejecting a piezoelectric element, and the like, and heating 4 water and intermittently performing ejection, and measuring the ink passage f from the perspective of the emulsion The viscosity is high, so the viscosity of the second temperature varies greatly. The viscosity change directly affects the speed of the droplets, which is easy to cause 4f degradation, because the temperature of the inkjet ink is kept constant in the ia. i Inkjet nozzle ( Hereinafter, the ink jet head can be used as well as a conventional ink jet head, and a continuous type and a dot-on-demand type can be used. In the dot print type, in a thermal head For example, European Patent No. A277,703, European Patent No. A 278, 590, for example, in the type of the squid head with the operating valve for the discharge described in the Japanese Patent Publication No. Hei 9-323420. No. Among them, piezoelectric nozzles are more preferable from the viewpoint of reducing the influence of heat on the inkjet ink and the wide selection of organic solvents that can be used. The nozzle is preferably a temperature control function for the nozzle to manage the temperature of the ink. Preferably, the injection temperature is set at a viscosity of 5 to 25 mPa·s when irradiated, and the ink temperature is controlled so that the viscosity variation range is within ±5%. Preferably, the operation is performed at a driving frequency of 1 to 500 kHz. The nozzle shape is not necessarily required to be circular, and is not limited to an elliptical shape or a rectangular shape. The nozzle diameter is preferably in the range of 1 〇 to 1 〇〇 μι». It is to be noted that the opening portion of the nozzle itself is not necessarily limited to -79-200906985^, and in this case, the nozzle diameter refers to a diameter of a circle which is assumed to be equal to the area of the opening. In the color filter film of the present invention, a RGB three-color ink is sprayed on the surface to form a group of three color-colored layers. In the present invention, the time of the removal of the (four) towel is dissolved in the ink residue by using a process for irradiating the ink residue to the active energy ray (hereinafter, sometimes referred to as a first-hardening process) and/or heating the above. Ink: It is sometimes referred to as the second hardening, and the ink residue may be formed into a shape. The temperature at which the thermal polymerization of the ink residue is started is diced to the core. The organic solvent contained in the drip sheet forms an ink residue, and then the ink residue is polymerized by a process of irradiating the ink residue to the active energy ray and/or heating the ink residue at a temperature equal to or higher than rc to form a halogen. Hereinafter, the first hardening process and the second hardening process will be described. The first hardening process 1 may be provided with a process in which the halogen energy of at least one color formed by the above pixel forming process is irradiated to the active energy ray to perform hardening (first hardening process). In the first-hardening process, the hardened enamel can be formed by hardening the ink of the present invention including red (R), green (G), and color Φ:). It is possible to perform hardening after forming a halogen of one color or hardening after forming a color of a halogen. The hardening of the ink of the present invention, such as R, G, B, etc., can be carried out by using an energy source that emits an active energy ray of a wavelength range of the photosensitive wavelength of the ink, which is used to promote polymerization hardening. . b As the source, for example, an external ultraviolet light of 400 to 200 nm, g-line, h-line, i-line, KrF excimer laser light, = excimer f-light, electron beam, x-ray, molecular ray can be appropriately selected and used. Or the energy source of the ionization of the above-mentioned polymerization initiation of the ion beam temple. Specifically, it is possible to use a light source that emits an activity of a wavelength range of φ 5 450 nm, preferably 365 Å 2 〇 nm, such as LD, LED (light emitting diode), fluorescent lamp, low dust south pressure mercury lamp , metal toothed lamp, carbon arc lamp, gas lamp, chemical, and, and appropriate. Preferred light sources include: led, high pressure mercury lamps, and metal toothed lamps. The irradiation time of the Γίί line can be appropriately set depending on the monomer and the polymerization initiator, and a can be set, for example, to 1 to 3 sec. A second hardening process - In the method for producing a color filter or a light film of the present invention, a process for hardening a substance including red (8), green (G), and blue (9) by using two may be provided (second hardening) Process). As described above, the hardening process can be hardened by the second hardening process by providing the second hardening process at the same time as the set-hardening process. Further, it is also possible to perform heat hardening by heat only in the present process, after forming the desired color tone and performing the first hardening process, and further performing the baking treatment. In other words, it is possible to perform heating (heating and heating) by heating or irradiating an infrared lamp with a substrate that is subjected to photopolymerization and a substrate of the partition wall in a light-inverting furnace or a dryer. The heating coffee depends on the composition and thickness of the inkjet ink. Generally, from the point of view of sufficient solvent-resistant, hybrid and ultraviolet absorbance, the recording is about 10 minutes to about 120 minutes. * ^ Exposure A/Mixing treatment with a color filter film without poor ink for the polymerization of the pixel and heating process. The heating temperature in the preheating process is not, and the rc and pixel portions are not polymerized. Temperature, two = ^ and 5 =, in the material just. 0, the inversion - 岐 岐 is greater than or equal to 60C and less than or equal to 9 (rc. By introducing the organic solvent in the ink, the % ink method gives m (four) = Promote 'can efficiently produce the viscosity of the ruthenium filter membrane ϋ ink residue to a higher fluidity, can be obtained and there are half (four) ancient two so that the 遽 遽 。 。 。 奸 奸 奸 奸 奸 奸Ink of the ink residue of the present invention Then, the i=heat process is effective not only for the ink that is polymerized by the heat in the pixel portion, but also for the ink with f:===. When the temperature is T, the temperature T at which the thermal polymerization starts is the photopolymerization, which is specifically due to heat. The temperature at which the polymerization reaction is decomposed and starts to be decomposed and the hoofing reaction is carried out. (4) The time during which the preheating process is itself due to heat is not particularly limited, and preferably 1 to 5 - 82 - 200906985 The temperature τ can be obtained as follows Heating. The polymerization of the ink is started by heating to observe the heating temperature of ^3* as Τ. In the method of manufacturing the color light film of the ink of the present invention, the above-mentioned halogen is performed at a lower temperature (d). Forming process ~ pre-passing process, first-hardening process and second hardening process; more = above, further preferably, at 6 hours = ====== into ~ final hardening type of binder, etc. It is possible to increase the aggregation of the paint or each of the partitions. In the present invention, a droplet of the ink of the present invention is ink-jet-formed on the substrate to form a booklet == an arbitrary partition, but in the production of fine light Membrane time ratio = with a function of... It is the same as the conventional black enamel film with the same black matrix; :==. It can be exemplified by the 特 〜 专利 专利 专利 〇〇 〇〇 _ _ _ _ _ _ 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶Black matrix, or Japanese paragraph 2___ bulletin paragraph 5] ~ Tao] or day ===Curry Gang ~ Qingqi-83- 200906985 In addition, 'in the inkjet ink of the present invention' preparation using shading component as In the case of the ink of the coloring agent, the ink may be used as a black matrix. In the above-described conventional production method, it is preferable to use a photosensitive resin transfer material from the viewpoint of cost reduction. The material is a material in which at least a light-blocking tree layer is provided on the dummy support, and the material is twisted. The light-shielding resin layer can be transferred onto the substrate on the substrate. The photosensitive resin transfer material is preferably formed of a photosensitive resin transfer material described in Japanese Laid-Open Patent Publication No. Hei. The _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ When it is light-shielding, it is also called "the color of the resin having a light-shielding property is also called "colored resin layer") / the protective film is squeaky, and the 仮 support of the s-type resin transfer material The method for producing the body, the thermoplastic tree η, and the transfer material is a method described in Japanese Patent Laid-Open No. Hei-5- No. [0066]. &amp; ^'3] In addition, it is possible to apply an ink-repellent treatment to the partition walls and to mix colors of ink. Regarding the ink-repellent treatment, a method in which an ink substance is mixed into a partition wall. (1) The anti-indoor number bulletin); (7) Re-set === Patent special 2 According to this patent, the special patent is opened. (No. 11 bulletin); (3) Using Fu-84-200906985 According to the method of Japanese Patent Specializing in the application of anti-ink materials (for example, the reference method), the side wall of the soil plate is treated with anti-inking treatment in order to form After the alizarin and the next wall are used to make the color film (4), the film can be transferred to cover the surface and the whole surface is used to form the coating layer.

The overcoat protects R, G, B = from flattening the surface. However, it is better to increase the number of processes without setting the coating layer. The coating layer may be composed of a resin (OC agent), and the resin (〇c is exemplified by: __tree silk, epoxy resin composition, poly retinal resin composition, etc.), wherein the _ acid resin composition The coloring material is excellent in transparency in the visible light region, and the resin component of the inkjet ink is usually a propylene-based resin as a main component, and the acrylic acid pure fat composition is excellent in adhesion. Therefore, it is preferable. There is a paragraph number [〇〇18] of the Japanese Patent Laid-Open Publication No. 2003-287618~ a coating layer, and a commercially available OPTOMERSS 6699G as a coating agent. The color filter film of the present invention utilizes the color filter of the present invention described above. The production method of the optical film can be applied to, for example, a television, a personal computer, a liquid crystal projector, a portable device, a mobile phone, or the like, a digital camera, a car navigation, etc., without any particular limitation. In the light film, at least 200,906,985 colors (8), green (G), and blue inks of the present invention are formed in the red-85-blue (B) color chromogen. <Display device> One can utilize the present invention Display device only May be, it is not particularly limited, and may be displayed on the display device,;. EL display device display the like curse j gold

As long as the color filter film of the present invention is provided, a display device such as a liquid crystal display device, a plasma h device, or a CRT display device can be cited. The display device of the present invention is preferably a liquid crystal resident. Female

A liquid crystal display device of various types described in the "43 Shengfei Second Generation Liquid Crystal Display Technology" of the "News of the Toray Survey Center". In the above display device, the present invention is effective for the liquid TFT method. There is a liquid (four) display device of the _gTFT type, which is described in "Color TFT Liquid Crystal Display (Kyoritsu Publishing Co., Ltd., 1996)". The present invention is of course applicable to a liquid crystal display device having a wide viewing angle such as a horizontal electric driving method such as IPS or a pixel division method such as MVA. The above method is described, for example, in "EL, PDP, LCD display technology, and the most color-removing filter film on the market. The liquid crystal display device is also made of an electrode substrate, a film, a backlight, a gap control material, and a viewing angle compensation thickness. For the above-mentioned materials, for example, "94, liquid crystal display peripheral materials and chemicals market (Ichishima Health Co., Ltd., &gt; -工's issued in 1994)", "2003 LCD related market The current situation and the future prospects (volume) (in the case of the Fujitsu Chimera Research Institute in 2003). The display device of the present invention can adopt electrically controlled birefringence (ECB), twisted nematic (TN), in-plane switching (ips), ferroelectric liquid crystal (Ferroelectric Liquid Crysta Bu FLC), Optically Compensatory Bend (OCB), Supper Twisted Nematic (STN), Vertically Aligned 'VA', Hybrid Aligned Nematic (HAN), Host-Guest Effect (Guest) Various display modes such as Host, GH). The display device of the present invention is characterized in that it has the color filter film described above, and thus has no display unevenness when mounted on a television or a monitor, and has a wide color reproduction area and a high contrast ratio, and is used in a notebook computer display. The display device of the present invention is also suitably used in a display device of a large screen such as a television monitor. EXAMPLES Hereinafter, the present invention will be specifically described by examples, but the following examples are not intended to limit the invention. It should be noted that "%" and "part" are quality standards unless otherwise specified. [Examples 1 to 4, Comparative Example 1] -87-200906985 [Preparation of dark composition κι for forming a partition wall] The dark composition Κ1 can be obtained as follows: First, the amount of the ruthenium pigment dispersed in the amount shown in Table 1 is measured. 1 'propanediol monoterpene ether acetate, mixed at a temperature of 24 ° C (± 2 ° C), stirred at 150 rpm for 1 〇 minutes, and then stirred to measure the amount of methyl ethyl ketone shown in Table 1, Adhesive 2, hydroquinone single shout, DPHA liquid, 2,4-bis(dichloroindenyl)_6-[4'-(N,N-bisethoxymethyl)amino-3'-benzene Base]-s-triazine, surfactant 1 and at a temperature of 25. (3 (±2. 〇 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依 依

Propylene glycol monomethyl ether oxime Xi Xiao Ding _

2,4·bis(dimethylmethyl)_6_[4,_(n,n_bisethoxycarbonyl----boxing)aminobromophenyl]_s-triazine surfactant 1 0.16 0.044 solution and Bulk adhesive 2, _ • 88- 200906985 &lt; κ pigment dispersion ι&gt; • Carbon black (Nipex 35 manufactured by Degussa Co., Ltd.) 13.1% • Dispersant (Compound 1 below) 0.65% • Polymer (methyl acetoacetate) Benzyl ester / methyl acrylate = 72/28 random copolymer of molar ratio, molecular weight 37,000) 6.72% • Propylene glycol monoterpenoid acetonitrile is 79.53%

Compound 1 &lt;Binder 2&gt; • Polymer (benzyl methacrylate/mercaptoacrylic acid = 78/22 27% random copolymer of molar ratio, molecular weight of 38,000) • Propylene glycol monomethyl ether acetate Ester 73% &lt;DPHA liquid&gt; • Dipentaerythritol hexaacrylate (MEHQ containing 5 〇〇ppm, manufactured by 曰本化制药股份有限公司, trade name: KAYARAD DPHA) 76% • Propylene glycol monomethyl Ether acetate 24% -89- 200906985 &lt;Interfacial active agent ι&gt; • The following fluorine-based surfactant 1 30% • Butanone 70% Fluorinated surfactant 1 - (CH2-CH) 4 〇 - ( CH2-CH)x—o=co=c OCH2CH2CnF2n+1 0(P0)7H (n=6, x=55, y=5, Mw=33940^ Mw/Mn=2.55 PO: propylene oxide; EO: ring Oxyethane-(CH2_CH)y-

〇=C

〇 (E〇) 7H (formation of the partition walls) The alkali-free glass substrate was washed with a UV washing device, then brushed with a detergent, and ultrasonically washed with ultrapure water. Place the substrate at 12 〇. The underarm heat treatment for 3 minutes was used to stabilize the surface state. The substrate was cooled, and the temperature was adjusted to 23 ° C. Then, the dark composition K1 prepared above was applied using a glass substrate applicator (manufactured by FAS Asia, trade name: MH-1600) having a slit nozzle. Then, a part of the solvent-dried layer was not pre-baked with vcd (straight-air age bee dream, manufactured by Tokyo Ohka Kogyo Co., Ltd.), and then pre-baked for 3 minutes at 12 Torr to obtain a dark composition layer κι having a film thickness of 2.3 μm. . Using a proximity exposure machine (manufactured by Hitachi, Ltd.) with a super-pressure mercury lamp, between the substrate and the reticle (with the image image standing upright, between the exposure mask surface and the dark layer first layer K1) The distance is set to _, in the nitrogen environment to -90- 200906985

Under the shower development for 80 seconds, a patterned image was obtained. The exposure of the pattern was 300 mJ/cm2 and the gap width was 100 μηι.

Film Electronics Materials (#): The flat nozzle pressure is 0.04 MPa. Then, using the ultra-high pressure washing f ^ mouth to give RM MPa _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The mixture was heated in an oven at 24 (rc for 5 〇 minutes to obtain a strip-shaped partition wall having a film thickness of 2.0 μm, an optical density of 4.0, and an opening having a width of 1 μm. [Anti-inking plasma treatment] Using cathode consumption The parallel plate type plasma processing apparatus of the "cathode coupling" method performs the ink-proof plasma treatment on the substrate on which the partition wall is formed. (Gas used: CF4 gas flow rate: 80 seem Pressure: 40 Pa

RF power: 50 W Processing time: 30 seconds (Preparation of blue inkjet ink for color filter film) (1) Preparation of pigment dispersion Each pigment, pigment dispersant and organic solvent were mixed in the following ratios, and added to 500 Oxide-91-200906985 bismuth beads with a diameter of 0.3 mm were dispersed for 4 hours using a paint mixer (manufactured by Asada Steel Co., Ltd.) to prepare PB15:6 (CI Pigment Blue 15:6) pigment dispersion and pv23 (CI Pigment Violet 23) Pigment Dispersion. [Composition of Pigment Dispersion] • Each pigment (PB15: 6 or PV23) 10 parts by weight • Pigment Dispersant (Disperbykl61 (manufactured by BYK Chemie Japan) (solid content of solvent BCA: 30 wt%)) 10 parts by weight • Pigment dispersion Additive (N_phenylmaleimide/benzyl methacrylate copolymer (30% by weight solids in solvent BCA)) 10 parts by weight • Diethylene glycol monobutyl ether acetate (BCA) 70 parts by weight - Preparation of Blue Ink for Color Filter Film &lt;Monomer Solution (Bl)&gt; The solvent mixture, monomer, binder, and surfactant component were at 25 in the following composition. (: After stirring for 30 minutes, it was confirmed that there was no insoluble matter, and a monomer solution (B1) was prepared. -92- 200906985 • Diethylene glycol monobutyl ether acetate (BCA) [(D) component] 4.6 g • Tripropylene glycol n-butyl Ether (TPNB) [(D) component] 40.2 g • Compound which is hardened by acid or radical [(A) component: the compound of Table 2] 5.5 g • Adhesive agent [(C) component: the compound of Table 2] 0.7 g • A compound which produces at least one of an acid and a radical [(E) component: the compound of Table 2] (referred to as "(E) acid / radical generator" in the table) 0.2 g • benzyl methacrylate Ester/mercaptoacrylic acid = 78/22 molar ratio of random copolymer 'molecular weight is 38,000 [(F): binder] 1. 〇g • surfactant [fluorine-based surfactant 1, above structure] 〇.〇2g • Solsperse 20000 (manufactured by Avecia) ι 〇2 46.5 parts by weight of the above-prepared pB15:6 pigment dispersion, 35 parts by weight of PV23 pigment dispersion, and 30 parts by weight of monomer solution (B1) In the case of the filling, the (A) component, the (〇 component, and the (E) component are respectively used in the color light of the first to fourth embodiments using the object described in Table 2; Blue inkjet ink was used. The blue inkjet ink for color filter film of Comparative Example 1 was obtained in the same manner as in Example 2 except that the (C) adhesive was not added. -93- 200906985: Table 2] (C) Adhesive (Ε) acid/radical generator Example 1 Μ-1 S-1 Example 2 Μ·2 S-2 Example 3 Μ-3 S-3 〜 Example 4 Μ-4 S-4 Comparative Example 1 No S-2 ~

By means of the above-mentioned Table 2, "κ_2/κ 4 equivalent amounts of Κ-2 and Κ_4' in Example 3 and the total addition amount is $$. (c) Adhesive (4) used in the Example) ~g ( The details of the M compound and the (E) acid generator are shown in D. ^^v^〇'v^\^Si(〇CH3)3 0

Μ-2 ο

Si(OCH2CH3)3 Μ4-94-200906985 - (A) hardening compound-Kl: dipentaerythritol pentaacrylate K-2: pentaerythritol triacrylate K-3: 1,3-butylene glycol diacrylate K -4 : Epicoat 828 (resin made by Oiled Shell Epoxy) s \ CI Bisphenol A type

[Evaluation of the inkjet ink for the color light-transmissive film] [1. Evaluation of the hardenability] Using the SE_丨28 manufactured by Dimatix Co., Ltd. as the device Apollon manufactured by Dimatix Co., Ltd., the blue inkjet and the discharge control were used to mount the inkjet head. Automatic two-dimensional movement, water. KS211-200Ί!,Bian狡# Shuang 1 0 (·Jun) can fine the mechanism to make a predetermined corner of the ink. The entire area of the binding and clothing is -95- 200906985 Here, the R ink 1 described above is filled in the nozzle. Controlled by the mouth-out control device to drip the ink to a predetermined position. After dripping, it is dried at atmospheric pressure at 90 ° C for 2 minutes, then heated at 24 ° t for 30 minutes, and then immersed in N_decylpyrrolidone solvent. In the middle, the time until the peeling from the substrate was measured. The longer the peeling time, the more excellent the curability, and the time was 5 minutes or more, and the curing property was evaluated as good. The results are summarized in Table 2. As is apparent from Table 2, the present invention The inkjet ink was excellent in adhesion to the substrate. Comparative Example i in which the (C) adhesive was not contained i ^ The inkjet ink could not sufficiently obtain adhesion to the substrate. [2. Evaluation of flatness of the pixel portion] The contact surface shape measuring device New View 0K CZygQ, manufactured by observing the shape of the above-mentioned element portion, calculates the contour of the surface shape. Taking the second part ί as A and the highest part as B, the height difference (B-A) is measured to be 0.03 μπι, and the second is to pass to the very good picture part of the flat chick. It is necessary to determine that the level of high and low is _Α) ’ The results are summarized in the table (evaluation criteria for flatness) ◎ · Β·Α&lt; 0.1 μιη ° · 0.1^ BA &lt; 0.2 μιη Δ · 0.2^Β-Α&lt; 0.4 μηι χ : 0.4 μιη^Β-Α Diffusion to the substrate formed on the substrate without being included (the comparative example of the Q-adhesive agent: -96·200906985 is insufficient in diffusibility, and the flatness of the formed halogen portion is poor. [Examples 5 to 6 and Comparative Examples] 2] (Preparation of red inkjet ink for color filter film) The pigment dispersion was prepared by mixing each pigment, pigment dispersant, and agent in the following ratio, and adding 500 parts by weight of a gas diameter of 〇3. The wrong beads were dispersed for 4 hours using a paint mixer (manufactured by Asada Steel Co., Ltd.) to prepare PR254 (CI Pigment Red 254) pigment dispersion and PR177 (CI Pigment Red 177) pigment dispersion. [Composition of Pigment Dispersion] Each pigment (PR254 or PR177) 10 parts by weight • Pigment dispersant (Dkperbykl61 (manufactured by BYK Chemie Japan) (solid content of solvent BCA is 30 wt%)) i〇 parts by weight • Pigment dispersing aid (N-phenyl Malay醯imine / benzyl methacrylate copolymer (solvent BCA solid content is 30 wt%)) 10 parts by weight • Diethylene glycol monobutyl ether acetate (BCA) 70 parts by weight—Preparation of a red color ink for a color filter film &lt;Monomer solution (Rl)&gt; The monomer, the binder, and the surfactant component were stirred at 25 ° C for 30 minutes to confirm that there was no insoluble matter, and the monomer solution (R1) was prepared. -97- 200906985 4.6 g 40.2 g 5.5 g 0.7 g 0.2 g • Glycol monobutyl ether acetate (BCA) [(D) component] • Tripropylene glycol n-butyl ether (TPNB) [(D) component] • Compound that hardens with acid or free radicals [(A) Component: Table 3 Documented compound] • Adhesive agent [(C) component: Compound described in Table 3] • Acid/radical generator [(E) component: Compound described in Table 3] • Benzyl methacrylate/methyl methacrylate/ Methacrylic acid =: 1.0 g 0.02 g 1.0 g 50/28/22 molar ratio random copolymer, molecular weight 450,000 [(F): binder] • surfactant [fluorine-based surfactant i, above Structure] • Solsperse 20000 (manufactured by Avecia) Disperse 68.85 parts by weight of the above-prepared pR254 pigment dispersion and 6.15 heavy-duty PR177 pigment The liquid and 50 parts by weight of the binder composition were sufficiently mixed, and the materials described in Table 3 were used for each of the component (A), the component (C) and the component (E), and red inkjets for the color filter films of Examples 5 to 6 were obtained. ink. The red inkjet ink for a color filter film of Comparative Example 2 was obtained in the same manner as in Example 6 except that the (C) adhesive was not added. [Table 3] * -----1-- __

(c) Adhesive (E) Acid/Free Radical Generator (A) Curable Compound Curable Alizarin Part Sheep + Daily Material Example 5 M-5 S-2 K-1 Greater than or equal to 10 minutes Dings SL J Soil ◎ Example 6 ~· ^ M-6 S-4 K-2 -------.. 8 minutes 〇Comparative Example 2 S-4 K-1 4 points X -98- 200906985 Used in the examples ( C) Adhesive (M-5),

/\^Si(〇CH2CH3)3 M-5 [Evaluation of inkjet ink for color filter film] [1. Evaluation of hardenability] The inkjet head uses SE-128 manufactured by Dimatix Co., Ltd., and the discharge control device uses Dimatix. Apollo II. The ink jet head was mounted on an automatic two-dimensional moving stage (Junhejing Mechanism KS211-200), and a predetermined amount of ink was ejected from the head by the discharge control device while moving the stage to the gap between the above-mentioned produced partition walls. Here, the above-described red ink-jet ink is filled in the head, and is controlled by the discharge control device to cause the ink to drip at a predetermined position. After 21 drops, dry at normal pressure for 2 minutes at 9 (TC), then use a proximity exposure machine with ultra-high pressure mercury lamp, expose with an exposure of 500 mJ/cm2, and then immerse in N-mercaptopyrrolidone solvent. The measurement was carried out until the time of peeling from the substrate. The longer the peeling time, the more excellent the curability, and the time was 5 minutes or more, and the curing property was evaluated as good. The results are summarized in Table 3. The inkjet of the present invention is excellent in adhesion to the substrate. The inkjet ink of Comparative Example 2 does not sufficiently obtain adhesion to the substrate. [2. Evaluation of flatness of the halogen component] -99-200906985 In the case of the shape of the same portion as in the first to fourth embodiments, in the fifth embodiment, the pixel portion is formed to have a high degree of flatness, and the pixel portion 3 which is extremely excellent in flatness is obtained. In the case of the example 6 and the comparative example 2, The evaluation is carried out in accordance with the actual situation. The green color is always in Table 3. The ink of the phase R is flattened by the ink = the diffusion of the two (four) inks on the substrate is not filled with the knife, and the flat portion of the formed element is flat. [Examples 7 to 8, Comparative Example 3] (Green inkjet ink for color filter film) Preparation of the pigment dispersion liquid is to use a paint mixer (Asada Iron and Steel Co., Ltd.) in which each pigment, pigment dispersant, and zirconia beads having a diameter of Q 3 _ are mixed in the following ratios. Disperse for 4 hours, prepare PG36 (CI Pigment Green 36) pigment dispersion, pa (c ! Pigment Green 7) pigment dispersion, PY138 (CI Pigment Yellow 138) pigment dispersion and p^'15〇 (CL pigment yellow 150) Pigment Dispersion [Composition of Pigment Dispersion] • Each pigment (PG36, PG7, PY138 or PY150) 1 part by weight • Pigment Dispersant (Disperbykl61 (manufactured by BYK Chemie Japan) (Solvent BCA has a solid content of 30 wt %)) 10 parts by weight • Pigment dispersing aid (N-phenylmaleimide/benzyl methacrylate copolymer (solid content of solvent BCA 30 wt%)) 1 part by weight • diethylene glycol single Butyl Ether Acetate (BCA) 70 parts by weight - 100 - 200906985 - Preparation of Green Ink for Color Filter Films &lt;Monomer Solution (Gl)&gt; Composition of mixed solvent, monomer, binder, interfacial activity The monomer component 'g was stirred at 25 ° C for 30 minutes, and it was confirmed that there was no insoluble matter, and the monomer solution (G1) was prepared. Diethylene glycol monobutyl ether acetate (BCA) [(D) component] 4.6 g • Tripropylene glycol n-butyl ether (TPNB) [(D) component] 40.2 g • Compound hardened by acid or free radical [A Component: Table 4 Description of the compound] 5 5 g • Adhesive agent [(C) component: the compound of Table 4] 〇7 g • Acid/radical generator [(E) component: Compound of Table 4] ο g • Benzyl methacrylate/hydroxyethyl methacrylate/mercaptoacrylic acid = 50/28/22 molar ratio random copolymer, molecular weight 32,000 [(ρ): binder], Λ 1·0 g • Surfactant [Fluorine-based surfactant i, the above-mentioned structure] 002 g • Solsperse 20000 (manufactured by Avecia Co., Ltd.) 19.25 parts by weight of the 6 pigment liquid and 13.65 parts by weight of the PG7 pigment dispersion prepared as described above. 24 64 parts by weight of the p pigment dispersion liquid and 12.46 parts by weight of the PY15G pigment dispersion liquid, and the parts of the monomer yarn are sufficiently aged. Thereafter, 5 parts by weight of the positive twelfth product: color = color ratio shown in Example 7 was added, except that the coloring light 2 of Example 7 was used, and the adhesion was changed except for the use of $1® in the present invention. The green inkjet ink of Comparative Example 3 was obtained in the same manner as in Example 7 except that the compound of the sigma-like agent (Η-1) -101-200906985 was added. 4] _

(C) Adhesive (E) acid/radical generator (A) Curable compound curable element flatness Example 7 M-1 S-2 K-5 10 or more ◎ Example 8 M-7 S-3 K-6/K-7 is greater than or equal to 10 minutes ◎ Comparative Example 3 H-1 S-2 K-5 3 points X In the above Table 4, the meaning of "K-6/K-7" in Example 8 means It means adding equal amounts of K-6 and K-7 with a total addition of 5.5 g. The details of the (A) curable compound, (E) acid generator, (C) binder (M-7) and comparative compound (H-1) used in Table 4 are as follows. K-5: dipentaerythritol hexaacrylate K-6: nodal glycidyl bond K-7: neopentyl glycol diglycidyl

u&gt;^〇^-^sj(〇CH3)3 ο ο Μ-7 Η-1 [1. Evaluation of hardenability] The inkjet head uses SE-128 manufactured by Dimatix Co., Ltd., and the discharge control device uses Apollo II manufactured by Dimatix. The ink jet head was mounted on an automatic two-dimensional moving stage (Junhejing Mechanism KS211-200), and a predetermined amount of ink was ejected from the head by the discharge control device while moving the stage to the gap between the above-mentioned produced partition walls. -102- 200906985 Here, the green inkjet ink is filled in the head, and is controlled by the discharge control device to cause the ink to drip at a predetermined position. After the ink droplets were left behind, they were heated at 200 t for 2 minutes under normal pressure, and then immersed in an N-methyl scale solvent to measure the time until peeling from the substrate. The longer the peeling time, the more excellent the curability, and when the time is 5 minutes or more, the curing property is evaluated to be good. The above results are summarized in Table 4. As is clear from Table 4, the ink jet substrate of the present invention is excellent in kneading property. Including the comparative σ outside the scope of the present invention as the adhesion improving agent, the ink of the nozzle of Comparative Example 3 was adhered to the substrate.垄 &amp;,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, It is to be noted that the flatness ink is the same as that of the first embodiment: === m The ink has insufficient diffusibility on the substrate, and the formed element portion is flat. Although the present invention has been disclosed in the preferred embodiment, The invention is not intended to be used in any way, and the scope of the invention may be reduced without departing from the spirit of the invention (4). The scope of the present invention is -103-200906985. The scope of the patent application is subject to change. [Simple description of the diagram] None [Key component symbol description] None -104-

Claims (1)

200906985 X. Patent application garden: 1. An inkjet ink for color filter film, which comprises: (A) a compound which is hardened by using at least one of an acid and a radical; (8) a pigment; (C) a compound comprising a substrate-adhesive group in the molecule; and (D) a solvent. 2. The inkjet ink for a color filter film according to the above aspect of the invention, which further comprises (E) a compound which produces at least one of an acid and a radical. 3. In the case of the application of the paste, the color film is inkjet ink, which further contains (F) binder. 4. The inkjet ink for color filter film according to the invention of claim 2, wherein the compound (C) comprising a substrate-adhesive group in the molecule is represented by the following formula (I): j〇R1) n L—gas (I) R23-n In the formula (1), 'L represents a monovalent organic group; R1 and R2 each independently represent a hydrocarbon group; and η represents an integer of 1 to 3. 5. The inkjet ink for a color filter film according to Item 1, wherein the compound (C) having a substrate-adhesive group in the molecule has the following formula (II): -105- 200906985 l (ID Water, wherein the above (c) molecule comprises a substrate in close proximity, wherein the compound of the formula (A) represents: a compound of a group of the following: in the formula (A), Μ represents a moiety including an ethylenically unsaturated double bond; An n+1 valent organic linking group; χ represents a hard f material adhesive group; n represents an integer of 1 to 5; and m represents an integer of 1 to 3. A color filter film comprising a coloring formed by an inkjet ink for a color light-passing film according to any one of the first to sixth aspects of the invention, which is a color filter film. pattern. -106- 200906985 VII. Designated representative map: (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: None 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None