200905938 九、發明說明： 【發明所屬之技術領域】 本發明係關於-種有機太陽能電池 之有機太陽能電池。 種具有滤光層 【先前技術】 由於全球錢變遷、空氣污_題 以太陽能發電做為電力供應來源之可能性二、日趨⑽之故， ”年來以梦晶圓為主的太陽能電池市場快逮 矽晶圓為主的太陽能發電技術之成本畢 、’、 二=此太陽能電池之應用仍只能值於特定用途 ==’!界上主要的研究單位，均致力於投人太陽能 關技躺研究，祈求·出新的物質，崎低產品成本並 提升效能。 有機太陽能電池具有成本低、重餘、具可撓性 大面積等優勢。軸目前錢太電池絲電轉換效率== 未能㈣晶圓太陽能電池相比較。但是因為具備未來的成長性， 因此吸引越來越多人投入此項研究。 常見的有機太陽能電池有染料敏化太陽能電池、高分子有機 太陽能電⑨、小分子有機太陽能電池以及錢/無機奈米複合型有 機太陽能電池。 染料敏化太陽能電池主要是由玻璃或塑膠基板、導電薄膜 (TCO)、電子傳遞層、光敏化染料層、電解質層、導電薄膜、玻璃 或塑膠基板所形成。當光照射在染料敏化太陽能 電池時，吸附在 200905938 電子傳遞層上的光敏化逛 子注入到電子傳遞層+::二染料分子呢收光能後’釋敌出電 狀態的染料分子二入=;層中的電解液還原⑽ 路形成光電流，並由金屬負電極進入還原電解^錢，經料 有機尚分子太陽能電池與有機小分 破璃或塑穋基板、導電薄膜 *以〉也主要皆是由 基板所形成。當光照射在有、曰:¥電_ '破璃或塑勝 陽能電科，斷===機小分子太 洞對，而電子隨即注入導電薄膜桃放發，釋放電子電 有機/無機奈米_人心/ 外迴路形成光電流。 基板、導電薄膜、有機法機=太％能電池主要是由破璃或塑膠 板所形成。當光照射在有機電薄膜、破璃或_基 有機/無妓合縣t的_分子柄能電池時’ =而電子循著無機分子中的奈来棒或奈米二進^電子電洞 騰層，經由外迴路形成先電流。 <丁進亚>主入導電薄 材料與餘料斷改良，逐漸 換效率。但是錢太陽能電;切之 電池的光電轉 性，容易受到紫外線、水、空氣 才科文限於本身材質的特 C發明内容】 44的影響而劣化。 鑒於以上的問題，本發明提供一 之有機太陽能電池。 〃 ° 20慮特定波長範圍光線 ，據本發明所揭露之有機太陽能 第—電極層、有機層、第二電砂、篆/、Q有弟—基板、 ㈢ 基板和濾光層。其、垣成 6 200905938 依序為第-基板、第-電極層、有m、第二電極層、第二 Γ1的堆疊結構。濾'光層是形成於人射光線人射方向之有機二 月匕电池的基板表面上或是形成於基板愈電極芦 、 定波長之^紐。_層，Μ θ㈤，㈣過遽特 ^ ώ 有先電效應特性的材料，用以接 统綠麟化輕子電清4。第—顧 二基:广都是透明基板。用—線穿透= 膜的形式私，財鼓陽 部迴路連接。 負電極，亚與外 ^濾光層是由兩種或兩種以上材質以交 2太陽能電池上。對不同波長的光而言，入射同：= 牙透與吸收特性也不同，夢 、、- 式，可㈣、好ϋ 不同㈣多層堆疊的方 線選用τ 補•射光。因此可針對所要過滹之光 線忠用可以過濾掉雜定波 之先 太陽能電池上。 、乾圍先線的材貝’堆疊製作在有機 根據本發明所揭露之有機太陽能電池， 射光線中對有機太陽妒Φ 慮先層吸收入 機材料不合光線，使有機太陽能電池内的有 〜防講/ 的影響而劣解。此外軸層更可以當作 "曰’避免水、空氣進入有 電池中的光敏化材料劣化。 b / ’使有機太陽能 ^關本侧嶋W响輸例詳細說 【實施方式】 200905938 為達到本發明之目的，本發明設計 長範圍光線。 ^ u s，迻濾掉特定波 各月麥「第1圖」’係為本發明第— 示意圖，包含有第-基板10、第一電極太陽能電池 二電極層21、第二基板2。和細40。本實=3〇、第 第—美妬ln w ^ 尽戶'施例的組成依序為 土 電極層1卜有機膜層3〇、第二m 二基板20的堆疊結構。 一^ θ 21、弗 第-電極層U與第二電極層21是以導電薄膜的 用以當作有機太陽能電池 、、7工子 -雷㈣”” 並與外部迴路連接。第 紐、極層触f可以是但不健於是金、銀、翻 ，也可以是但不僅限於銦 化錫這些透明轉體氧化金屬。 並轉是具有光___，_接收入射光線 可=為電子制釋出。有賊層3Q可叹高分子有機材料，也 4小》子有機材料。第—基板10和/或第二基板20是透明基 明基^^翻透明玻璃或透膠，其中透明塑膠的材 貝疋來對苯一甲酸乙二醇酯_yethyl咖卿h_ate)、聚酯 ouster) > ^^I£S|(p〇lycarb〇nates) . ^^^StS|(p〇iyaciylates) 及來本乙烯(p〇lyStyrene)以及其他材質。 —濾光層40是由兩種或兩種以上之氧化物交替堆疊而成，能有 领止紫外絲㈣有機材财害之人射絲造成有機材料產生 =化。濾光層40可以是但不僅限於是Ti〇2/s】〇2、触趣朽、 吨娜、Ta2〇5/Sl〇2、Ti〇iySi〇2 或 Hf(vSi〇2。其中遽光層如 8 200905938 二層數至少是八層以上’越多層效果越好。在才 J七慮先層40的材質用以過麵彻麵以 本仏 並非用以限定本發明。 '歧之入射光，但 濾光層4〇是形成於入射光線入射面之有 、 基板表面。當第-紐K)為翻材_，濾也透明 射光線入射面之第—基板】G表面上，換句日形成於入 成於第一基板10之另一側。使得 第=、先層40是形 有機太陽能電池時，可阻止竿f旦線攸弟—基板10外入射 對有機材料有害 時’觀層4。是形成於人射先線人基= 20表面上，換句話今，、、者本爲」 弟一基板 、，換H慮先層4〇是形成於第二基板20之另—加 當然’第一基板10與第二基板 1。 入射光線可雜意鄕-紐料或/^=材質，因此 陽能電池，因此_4G可以如上所述，嫌:= =基板二基板—上，換句話說ST: 疋形成於第-基板1G之另—側與第二基板2g之另_側:曰 物「㈣」’輪靖：實败麵太 另一不思圖。其裝置結構與本發明第—實施例差別在於，二 基板10树明材科、射紐鄕—基板1Q外 能電池時，濾光層40是形成於第一基板K)與第-電極層 間。或以二基板20為透明材質時，入射光線從第二基板2 入射有機太陽能電崎，渡光層*是形成於第二基板如 電極層21之間。又或者是[基板1Q鮮二基板2q都是透叫 200905938 質’入射先線可以任意從第一基板10外或第二基板20外入射有 機太陽能電池，因此濾光層4〇是同時形成於第一基板1〇與第一 电極層11之間和與第二基板2〇與第二電極層21之間。 清茶照「第3圖」，係為本發明第三實施例之染料敏化太陽能 電池不意圖，包含有第一基板1〇〇、第一電極層1〇1、有機膜層 300、第二電極層層加、第二基板2⑻和濾'光層·。 本貫施例的組成依序為第一基板1〇〇、第一電極層im、有機 膜層300、第二電極層2〇1、第二基板200的堆疊結構。 *第-基板100和/或第二基板2〇〇是透明基板。用以使入射光 線牙透入賴敏化太陽能電池内與有機膜層3⑻仙。透明基板 可以選用透明玻赋透明塑膠，其中透明塑膠的材質為聚對笨二 甲酸乙二_旨”炭酸酯、聚丙稀酸酯及聚苯乙烯等其他 ^ ^極層101與第二電極層2〇1是以導電薄膜的形式存 第作有機'陽能電池之正、負電極，並與外部迴路連接。 nZ:、與H電極層201的材質可以是但不僅限於是 金銀翻或如些金屬材質，也可以是 或摻氣二氧倾透料導體氧化金屬。於銦錫乳化物 濾'光層糊是由兩種或兩種以上之氧化物交替堆 有效阻止紫外光線等對有機鉍 且而成，月b 的父替堆疊的層數至少杲R /、中4光層40 層以上’越多層可以得到越好的效 10 200905938 果。在本實施例中濾光層40的#質用以過遽掉4〇〇細以下光線 之入射光，但並非用以限定本發明。 濾、光層400是形成於入射光線入射面之染料敏化太陽能電池 透明基板表面。當第-基板⑽鱗明材料，讀光線從第一 •基板100夕卜入射染料敏化太陽能電池時，攄光層400是形成於入 :射光線入射面之第一基板100表面上，換句話說，濾光層是 形成於第-基板100之另-侧。使得入射光線從第一基板⑽外 /入射染料敏化太陽能電池時，可阻止料姐㈣錢 料有害之入射光造成有機膜層300的材料產生劣化。當第二基板 200為透明材質時，人射光線從第二基板外人射有機太陽能 電池時，濾光層400是形成於入射光線入射面之第二基板2⑻表 面上，換句話說，濾光層400是形成於第二基板2〇〇之另一侧。 當然，第一基板100與第二基板200可以都是透明材質，因 此入射光線可以任意從第一基板100外或第二基板200外入射染 料敏化太陽能電池，因此濾光層400可以如上所述，形成於入射 * 光線入射面之第一基板100與第二基板200表面上，換句話說， 濾光層400是形成於第一基板100之另一側與第二基板2〇〇之另 一側0 有機膜層300是具有光電效應特性的材料，用以接收入射光 線並轉化為電子電洞釋出。在此實施例中，有機膜層3〇〇是染料 光敏化劑。 本實施例之染料敏化太陽能電池更包括有二氧化鈦薄膜1〇2 與電解質層202。二氧化鈦(Ti〇2)薄膜102形成於有機膜層3〇〇與 11 200905938 +電極層1〇1之間◦有機膜層300所使用的染料光敏化劑吸收 入射光後，電子會躍遷至激發態，但激發態非穩定狀態，因為有 機膜層300緊鄰二氧化鈦薄膜1〇2，電？得以在激發態時，注入 1氧化鈦的導電帶，經由第一電極層將電子導出。電解質 層=02形成於有機膜層3⑻與第一電極層2讥之間，用以供給電 子，。光敏化材料層，還原有機縣3⑻因光電效應而分解的 帶正電的分子。 #、明=、/ 4圖」，係為本發明第四實施例之染料敏化太陽能 也另不思圖。其裝置結構與本發明第三實施例差別在於，當 板⑽為透日爾時，人射光線從第—基板1⑻外入射有 池時’濾光層是形成於第一基板與第 =外為透_時，— 基板·與第二電極二光層4〇°是形成於第二 基板200都是B ☆者基板⑽與第二 或第—A板2GQ Γ 味射崎意從第—基板100外 及弟一基板200與第二雷托@ ^ηι 成有濾光層400。 —電極層201之間皆形 清蒼照「第5圖 乂么屯 複合型太陽能電池示意圖==例卿機奈米 80 有機/無機混合騎7〇、第二_ _51、 δπ 乐一基板60和濾光層 層5〗、有機/ 本實施觸組成依序騎—純50、第-電極 12 200905938 採機混合膜層70、第二電極層6…_ 第-基板舞/或第二基板⑽θ ==0的堆疊結構。 穿透入有魏獅複合刑板。㈣使入射光線 声70作用。土太^匕電池内，與有機/無機混合膜 基板可以翻翻麵或透 膠的材質為聚對笨二曱酸：1〜 明塑 s旨、聚苯乙烤以及其他材質。9 4 '聚碳_、聚丙烯酸 極層51與第：電極層61是以導電_的形式存在， 機太陽能電池之正、負電極，並與外部迴路連接。第 一電極層51與第：電極層61的材質可以是但不僅限於是金、銀 贱如齡肺質，也可叹料僅隨銦錫氧鱗或魏二 氧化錫這些透明半導體氧化金屬。 有機/無機混合膜層7Q是具有光電效應特性的材料，係由有 機分子與錢分子混合成的。有機分刊以接收人射光線並轉化 為電子電聊出，而無機分子具有良好的許傳遞雜，用以傳 遞有機分子所釋出的電子至外部迴路。 、 濾光層80是由兩種或兩種以上之氧化物交替堆疊而成，能有 触止紫外规精錢材料有害之人射光線造成有機材料產生 劣化。濾光層80可以是但不僅限於是Ti〇2/Si〇2、Sub2/MgF、 丁说助2、TaA/SK)2、⑽.7·2 或 Hf〇3/Sl〇2。其中濾光層 8〇 的交替堆疊的層數至少是8層以上，越多層可以得到越好:效 果。在本實施例中濾光層80的材質用以過濾掉400nm以下光線 之入射光，但並非用以限定本發明。 濾光層80是形成於入射光線入射面之有機/無機奈米複人型 13 200905938 太陽能電地透明基板表面。當第—基板50為透明材質日士 =第—基板50外入射有機，無機奈賴合型太陽能C射光 光層80是形成於入射水* 尾’也4，濾 ,,、、 先線人射面之第—基板5〇表面上，u :光層8。疋形成於第—基板％之另一侧。使得光: 弟一基板50外入射右嬙/ λ* + 对光線攸 兔機奈米複合型太陽能電池時m mi對有機光敏化材料有害二 膜層70的材料產生劣化。杏 …匕合 田弟—基板60為透明材質時，入射# 光权射麵/域奈频合社陽㈣池時，，、Ϊ ί曰、= 射光線入射面之第二基板60表面上，換j 5兄，80是形成於第二基_之另u。 人射:線可=ΐ:= t二基板6。可以都是透明材質，因此 合型太陽能電池，因此濾光層⑽可以如上所述，t t =線人射面之第—基板5Q與第二基板 ζ成於 2層⑽是形成於第-基板如之另—側與第二基板 請參照「第6圖丰 ^ 複合型太陽能電池另—干音H =弟六貫施例之有機/無機奈米 差別在於，當第—从;。其裝置結構與本發明第五實施例 或一::二::： 土板〇外入射有機太陽能 二私6。與第二__。又或者是=:::::: 14 200905938 板6〇都材質’人射光線可以任意從第-基板50外或第二 射有機太1%此電池，因此濾光層可以同時形成於 弟一基板5Q與第—電極層51之間和與第二基板60與第二電極層 61之間。 雖然本發似前述之較佳實施_露如上，然其並非用以限 定本=明’任何熟f相像技藝者，在不脫離本發明之精神和範圍 田可作—許之更動與潤飾，因此本發明之專梅 本說明書咖4料概_狀者鱗。 【圖式簡單說明】 ^圖係為本發明第-實施例之有機太陽能電池示意圖； 弟2圖係為本發明第二實施例之有機太陽能電池另一示意 圖； 弟3圖係林發明第三實關之_敏化太陽 能電池示意 意圖； 第4圖係林發明第四實施例之染料敏化太陽能電池另一 示 第5圖係為本發明第五實施例有 電池示意圖；A 制以無機奈未硬合型太陽能 t/無機奈米複合型太陽能 第6圖係為本發明第六實施例之有機/ 電池另一示意圖。 【主要元件符號說明】 10.........................第一基板 .................弟一電極層 15 200905938 20 .........................第二基板 21 .........................第二電極層 30.........................有機膜層 40.........................濾光層 50 .........................第一基板 51 .........................第一電極層 60 .........................第二基板 61 .........................第二電極層 70.........................有機/無機混合膜層 80.........................濾光層 100 .......................第一基板 101 .......................第一電極層 102 .......................二氧化鈦薄膜 200 .......................第二基板 201 .......................第二電極層 202 .......................電解質層 3⑻.......................有機膜層 400.......................濾光層 16200905938 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to an organic solar cell of an organic solar cell. Kind of filter layer [previous technology] Due to the global money change, air pollution _ the problem of solar power as a source of electricity supply, the second (10), "the dream wafer-based solar cell market is catching up The cost of silicon-based solar power generation technology is the same, ', two = the application of this solar cell can still be worth only for specific purposes =='! The main research units in the world are dedicated to investing in solar energy technology Pray for new materials, low product cost and improve efficiency. Organic solar cells have the advantages of low cost, heavy weight, and large flexibility. The current axis is too much battery wire conversion efficiency == failed (four) crystal Compared with round solar cells, but because of the future growth, it attracts more and more people to invest in this research. Common organic solar cells are dye-sensitized solar cells, high-molecular organic solar cells, and small-molecule organic solar cells. And money/inorganic nano composite organic solar cells. Dye-sensitized solar cells are mainly made of glass or plastic substrates and conductive films (TCO). , an electron transport layer, a photosensitizing dye layer, an electrolyte layer, a conductive film, a glass or a plastic substrate. When the light is irradiated on the dye-sensitized solar cell, the photosensitized wanderer adsorbed on the 200905938 electron transport layer is injected into the electron transport Layer +:: two dye molecules after the light-receiving energy's release of the dye molecules in the state of the power-off state =; the electrolyte in the layer is reduced (10) to form a photocurrent, and the metal negative electrode enters the reduction electrolysis Organic still molecular solar cells and organic small broken glass or plastic substrate, conductive film * are also mainly formed by the substrate. When the light is irradiated in, there is: 电: _ _ 'glass or plastic Shengyang Electric , === machine small molecules are too hole pairs, and the electrons are then injected into the conductive film peach to release, release the electronic electricity organic / inorganic nano _ human heart / outer loop to form photocurrent. Substrate, conductive film, organic machine = too% The energy battery is mainly formed by broken glass or plastic plate. When the light is irradiated on the organic electric film, the glass or the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Nai stick or nano Into the electronic hole layer, the first current is formed through the outer loop. <Ding Jinya> The main conductive thin material and the residual material are improved, and the efficiency is gradually changed. But the solar energy; the photoelectric conversion of the battery, It is easy to be affected by the influence of ultraviolet rays, water, and air, which is limited to the material of the invention. 44. In view of the above problems, the present invention provides an organic solar cell. 〃 ° 20 Considering a specific wavelength range of light, according to the present The organic solar first electrode layer, the organic layer, the second electric sand, the 篆/, Q have a brother-substrate, the (three) substrate and the filter layer disclosed by the invention. The 垣成6 200905938 sequentially is the first substrate, the first- An electrode layer having a stacking structure of m, a second electrode layer, and a second crucible 1. The filtering 'optical layer is formed on the surface of the substrate of the organic douterium battery in the direction in which the human light is emitted, or formed on the substrate. The constant wavelength of the button. _ layer, Μ θ (five), (d) over 遽 遽 ώ ώ ώ 先 先 先 先 ώ ώ ώ ώ ώ ώ ώ ώ ώ 。 。 。 。 。 。 。 。 。 。 。 。 The first - Gu two base: widely transparent substrates. With the line penetration = the form of the film private, the financial drum is connected with the circuit. Negative electrode, sub-and external ^ filter layer is made of two or more materials to cross the solar cell. For different wavelengths of light, the incidence is the same as: = the tooth penetration and absorption characteristics are different, dream, - - type, can be (four), good ϋ different (four) multi-layer stacking square line select τ complement • light. Therefore, it is possible to use the first solar cell that can filter out the fixed wave for the light to be used. The organic solar cell according to the present invention is organically produced in accordance with the present invention, and the organic solar 妒 Φ is absorbed into the organic material in the light, so that the organic solar cell has an anti-light. Speak / the impact of inferiority. In addition, the shaft layer can be used as "曰' to prevent water and air from entering the photosensitive material in the battery from deteriorating. b / 'The organic solar energy is turned on. The embodiment is detailed. [Embodiment] 200905938 In order to achieve the object of the present invention, the present invention designs a long range of light. ^ u s, Filtering off a specific wave Each month, "Fig. 1" is a schematic view of the present invention, and includes a first substrate 10, a first electrode solar cell second electrode layer 21, and a second substrate 2. And fine 40. The composition of the embodiment of the present invention is the stacking structure of the organic electrode layer 1 and the second m substrate 20 in the order of the soil electrode layer 1 . A ^ θ 21, the electrode-electrode layer U and the second electrode layer 21 are made of a conductive film for use as an organic solar cell, 7 workers - Ray (4)" and connected to an external circuit. The first and last layer touches f may be, but are not, gold, silver, or flip, or may be, but not limited to, transparent tin oxide metal such as indium tin oxide. And the turn is light ___, _ receiving incident light can be = electronically released. There are thief layer 3Q sighable polymer organic materials, also 4 small "sub-organic materials. The first substrate 10 and/or the second substrate 20 is a transparent base glass transparent transparent glass or a transparent plastic, wherein the transparent plastic material is bismuth benzoic acid phthalate (_yethyl caiqing h_ate), polyester ouster ) > ^^I£S|(p〇lycarb〇nates) . ^^^StS|(p〇iyaciylates) and p〇lyStyrene and other materials. - The filter layer 40 is formed by alternately stacking two or more kinds of oxides, and can cause the organic material to be produced by the human hair which leads to the ultraviolet fiber (4) organic material. The filter layer 40 can be, but is not limited to, Ti 〇 2 / s 〇 2, touch fun, T. Na, Ta 2 〇 5 / Sl 〇 2, Ti 〇 i y 〇 2 or Hf (vSi 〇 2. For example, 8 200905938 The number of two layers is at least eight layers or more. The more the multi-layer effect is, the better. The material of the first layer 40 is used to pass the surface and is not intended to limit the invention. However, the filter layer 4〇 is formed on the incident surface of the incident light, and the surface of the substrate. When the first-new K) is the material _, the filter is also transparent on the incident surface of the light-substrate surface G, on the surface of the sentence The other side of the first substrate 10 is formed. When the first and first layers 40 are shaped as organic solar cells, it is possible to prevent the external layer of the substrate 10 from being incident on the substrate 10 when it is harmful to the organic material. It is formed on the surface of the human first line of the person base = 20, in other words, the original is a substrate, and the change of the first layer 4 is formed on the second substrate 20. The first substrate 10 and the second substrate 1. The incident light can be miscellaneous - neon or / ^ = material, so the solar battery, so _4G can be as described above, ignoring: = = substrate two substrates - on, in other words ST: 疋 formed on the first substrate 1G The other side of the other side and the second substrate 2g: the object "(four)" 'rounding the Jing: the real face is too different. The difference between the device structure and the first embodiment of the present invention is that the filter layer 40 is formed between the first substrate K) and the first electrode layer when the second substrate 10 is a tree material or a substrate 1Q external battery. Or, when the two substrates 20 are made of a transparent material, the incident light rays enter the organic solar electric yoke from the second substrate 2, and the light permeable layer* is formed between the second substrate such as the electrode layer 21. Or the [substrate 1Q fresh two substrate 2q is transparent 200905938 quality incident axis can be arbitrarily incident from the outside of the first substrate 10 or the second substrate 20, so the filter layer 4 同时 is formed at the same time A substrate 1 〇 is interposed between the first electrode layer 11 and the second substrate 2 〇 and the second electrode layer 21. "Dye 3" is a dye-sensitized solar cell according to a third embodiment of the present invention, and includes a first substrate 1 , a first electrode layer 1 , an organic film layer 300 , and a second electrode. Layer layer addition, second substrate 2 (8) and filter 'light layer ·. The composition of the present embodiment is a stacking structure of the first substrate 1A, the first electrode layer im, the organic film layer 300, the second electrode layer 2〇1, and the second substrate 200. * The first substrate 100 and/or the second substrate 2A are transparent substrates. It is used to penetrate the incident light into the sensitized solar cell and the organic film layer 3 (8). The transparent substrate can be made of transparent glass transparent plastic, wherein the transparent plastic material is poly-p-formic acid, and the other electrode layer 101 and the second electrode layer 2 are carbonic acid ester, polyacrylic acid ester and polystyrene. 〇1 is the positive and negative electrode of the organic 'positive battery' in the form of a conductive film, and is connected to the external circuit. The material of the nZ: and H electrode layer 201 may be but not limited to gold or silver or some metal. The material may also be a oxidized metal of a gas-doped dioxate material. The indium-tin emulsion filter is a mixture of two or more oxides effective to prevent ultraviolet light and the like. In the present embodiment, the number of layers of the parent stack is at least /R /, and the middle 4 layers are more than 40 layers. The more layers can be obtained, the better the effect is. 10 200905938. In the present embodiment, the color of the filter layer 40 is used. The incident light of the light below 4 〇〇 is removed, but is not intended to limit the invention. The filter and light layer 400 is formed on the transparent substrate surface of the dye-sensitized solar cell on the incident surface of the incident light. When the first substrate (10) is smeared Material, reading light from the first • substrate 100 When the dye-sensitized solar cell is incident, the calender layer 400 is formed on the surface of the first substrate 100 on the incident surface of the incident light, in other words, the filter layer is formed on the other side of the first substrate 100. When the light is emitted from the outside of the first substrate (10)/into the dye-sensitized solar cell, the material of the organic film layer 300 is prevented from being deteriorated by the incident light which is harmful to the material (4). When the second substrate 200 is a transparent material, the human light is emitted. When the organic solar cell is externally emitted from the second substrate, the filter layer 400 is formed on the surface of the second substrate 2 (8) on the incident surface of the incident light. In other words, the filter layer 400 is formed on the second substrate 2 Of course, the first substrate 100 and the second substrate 200 may both be transparent materials, so the incident light may be arbitrarily incident from the outside of the first substrate 100 or the outside of the second substrate 200, so the filter layer 400 may be as above. The filter layer 400 is formed on the other side of the first substrate 100 and the second substrate 2 on the surface of the first substrate 100 and the second substrate 200 incident on the incident surface of the incident light. Another The side 0 organic film layer 300 is a material having photoelectric effect characteristics for receiving incident light and converting it into electron hole release. In this embodiment, the organic film layer 3 is a dye photosensitizer. The dye-sensitized solar cell further includes a titanium dioxide film 1〇2 and an electrolyte layer 202. A titanium dioxide (Ti〇2) film 102 is formed between the organic film layers 3〇〇 and 11 200905938 + electrode layer 1〇1, the organic film layer 300 After the dye photosensitizer used absorbs the incident light, the electrons will transition to the excited state, but the excited state is unstable, because the organic film layer 300 is adjacent to the titanium dioxide film 1〇2, and the electricity is injected into the titanium oxide in the excited state. The conductive strip leads the electrons through the first electrode layer. An electrolyte layer = 02 is formed between the organic film layer 3 (8) and the first electrode layer 2? for supplying electrons. The photosensitive material layer reduces the positively charged molecules decomposed by the photoelectric effect in the organic county 3 (8). #,明=, / 4图", the dye-sensitized solar energy of the fourth embodiment of the present invention is also not considered. The difference between the device structure and the third embodiment of the present invention is that when the plate (10) is transparent, when the human light is incident from the outside of the first substrate 1 (8), the filter layer is formed on the first substrate and the outer surface is transparent. _, - the substrate and the second electrode two-layer 4 〇 ° are formed on the second substrate 200 are both B ☆ substrate (10) and the second or -A plate 2GQ 味 味 崎 意 意 from the first substrate 100 The second substrate 200 and the second Leito @^ηι are provided with a filter layer 400. - The electrode layer 201 is clear and clear. "Figure 5: 乂 屯 屯 composite solar cell schematic == 例 庆 machine nano 80 organic / inorganic hybrid ride 7 〇, second _ _51, δπ Le one substrate 60 and Filter layer 5, organic / present embodiment of the composition of the ride - pure 50, the first electrode 12 200905938 mining machine mixed film layer 70, the second electrode layer 6 ... _ the first substrate dance / or the second substrate (10) θ = The stacking structure of =0. Penetrate into the composite pen of Wei Shi. (4) Make the incident light 70 function. In the soil too, the organic/inorganic hybrid film substrate can be turned over or the material of the transparent material is a pair. Stupid acid: 1~ Ming plastic s, polystyrene baking and other materials. 9 4 'Polycarbon _, polyacrylic electrode layer 51 and the first: electrode layer 61 is in the form of conductive _, solar cell The positive electrode and the negative electrode are connected to the external circuit. The material of the first electrode layer 51 and the first electrode layer 61 may be, but not limited to, gold, silver, or the like, or may be sighed only with indium tin oxide scale or Transparent tin oxide metal such as Wei tin dioxide. Organic/inorganic hybrid film layer 7Q is photoelectrically active. The material is a mixture of organic molecules and money molecules. The organic publications receive light from humans and are converted into electronic electricity. The inorganic molecules have good transfer impurities to transfer electrons released by organic molecules. The external circuit. The filter layer 80 is formed by alternately stacking two or more kinds of oxides, which can cause deterioration of the organic material caused by the light emitted by the person who is harmful to the ultraviolet gauge material. The filter layer 80 can be However, it is not limited to Ti〇2/Si〇2, Sub2/MgF, Dingsuke 2, TaA/SK)2, (10).7·2 or Hf〇3/Sl〇2, in which alternating layers of filter layers 8〇 are stacked. The number of layers is at least 8 layers or more, and the more layers can be obtained: the effect. In the present embodiment, the material of the filter layer 80 is used to filter out incident light of light below 400 nm, but is not intended to limit the present invention. The layer 80 is an organic/inorganic nano-replica 13 200905938 solar-electric transparent substrate surface formed on the incident surface of the incident light. When the first substrate 50 is a transparent material, the Japanese material is replaced by the organic substrate, and the inorganic substrate is infiltrated. The solar C light beam layer 80 is formed at the end of the incident water* Also 4, filter,,,, the front of the front surface of the substrate - the surface of the substrate 5, u: the light layer 8. The crucible is formed on the other side of the first substrate, so that the light: the other substrate 50 is incident on the right side嫱 / λ* + When the light is twisted on the rabbit nano-composite solar cell, m mi degrades the material of the harmful photosensitive layer 70 of the organic photosensitizing material. Apricot... When the substrate 60 is a transparent material, the incident #光When the weight surface/domain is in the middle of the cell (4), the surface of the second substrate 60 on the incident surface of the light is changed, and the other is formed on the second base. Human shot: line can = ΐ: = t two substrates 6. It can be a transparent material, so the solar cell is combined, so the filter layer (10) can be as described above, the first substrate of the tt = line of the human face - the substrate 5Q and the second substrate are formed in two layers (10) formed on the first substrate. For the other side and the second substrate, please refer to "6th Figure Feng ^ Composite Solar Cell Another - Dry Tone H = The Sixth Embodiment of the Organic/Inorganic Nano Difference Between: When - The Device Structure and The fifth embodiment or one of the present invention:: two::: the earth plate is externally incident on the organic solar energy two private 6. and the second __. or is =:::::: 14 200905938 board 6 〇 both materials 'people The light can be arbitrarily removed from the first substrate 50 or the second organic solvent is too much 1% of the battery, so the filter layer can be simultaneously formed between the substrate 5Q and the first electrode layer 51 and the second substrate 60 and the second substrate Between the electrode layers 61. Although the preferred embodiment of the present invention is as described above, it is not intended to limit the skill of the present invention, and may be used without departing from the spirit and scope of the present invention. The change and retouching of the present invention, therefore, the special specification of the present invention is as follows: [Simplified illustration] ^ The figure is a schematic diagram of the organic solar cell of the first embodiment of the present invention; the second drawing is another schematic diagram of the organic solar cell of the second embodiment of the present invention; the younger brother of the third embodiment of the invention is the sensitized solar cell 4 is a dye-sensitized solar cell of a fourth embodiment of the invention. FIG. 5 is a schematic view of a battery according to a fifth embodiment of the present invention; Fig. 6 is a schematic view showing another example of the organic/battery of the sixth embodiment of the present invention. [Description of main components] 10.................... .....first substrate.................di-electrode layer 15 200905938 20 .................. .......the second substrate 21........................the second electrode layer 30......... ................ Organic film layer 40......................... Filter layer 50. ........................first substrate 51 ...................... ...first electrode layer 60.........................second substrate 61 ............. ............Second electrode layer 70.........................organic/inorganic hybrid film Layer 80.........................Filter layer 100........................ ....first substrate 101 .................first electrode layer 102 .............. .........titanium dioxide film 200 .......................the second substrate 201 ........... ............Second electrode layer 202 ....................... electrolyte layer 3 (8)....... ................Organic film layer 400..........................Filter layer 16