200904832 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種氯乙嫦系樹脂用安定劑組成物，詳細 “’係關於含有硬脂醯基苯甲醯基甲燒之糊狀或液狀之 鼠乙烯樹脂用安定劑組成物，及含有該安定劑組成物之主 ^用作各種樹脂零件等之成形材料的氯乙㈣樹脂 物。 【先前技術】 氯乙烯系樹脂於進行加熱成形加工時，主要容易產生由 脫氯化氫51起之熱分解，並且會產生機械性質之劣化或色 狀惡化’因此添加—種或數種熱安㈣而進行使用。 ▲作，該氯乙婦系樹脂用安㈣組成物之—種，使用有色 疋化優異的万—二酮化合物’目前正廣泛使用二苯 甲基甲垸或硬賴基苯甲醯基甲燒（以下，稱作_。 尤其是上述SM’其係被FDA認可之衛生性優異的安定劑 成分’可使用於玩具等中。 另一方面’就操作性方面而言，正謀求一種糊狀或液狀 之文疋劑組成物。作為將粉末之安定劑成分或高黏度之安 定劑成分製成糊狀或液狀之安定劑組成物而使用的方 法，已知有：將環氧化植物油或鄰苯二甲酸二_2一乙基己 醋等以氯乙烯樹脂用安定劑或可塑劑所公知的液狀物，調 -、上述女疋“成刀中的方法。然而，如此而獲得之糊狀 或液狀之安定劑組成物，於長期保存時或於冬季時，存在 有產生机動!·生之心化、固化、成分之沉澱、相分離等問題。 97110772 200904832 尤其是，調配有SBM之糊狀安定劑有黏声斗上 々/又τρ向之倾Θ 因此，為了提高其流動性必須調配大量之環氧化大σ 等。使用如此而稀釋之安定劑來獲得充分之、安〜大，油 時，必須大量調配安定劑組成物，故而所獲得化效果 脂組成物的物性降低。因此，於防止物性降低而== 量時’存在有無法實現充分之色調安定化的問題。… 【發明内容】 (發明所欲解決之問題） 1因此，本發明之第丨目的在於提供一種氯乙 安定劑組成物，其操作性優異，並且色調安定化效=用 物本:::…的在於提供-種氯乙稀系二 物，其色调安定性優異，並且不會產生物性成 (解決問題之手段） - 本發明者等人為解決上抽;i I ^ M W田喊而進行潛心研究，結果 舍見·猎由调配特定之脂肪酸甲酉旨及少量之通，可獲得 而m八夜狀的虱乙烯系樹脂用安定劑組成物，從 而完成了本發明。 即，本發明係關於一猶翕 免X七4 —先 種玑乙烯系树脂用安定劑組成物、 及3有该女疋劑組成物而成氣 7 ^ ^ m ^ 风疋虱乙烯系樹脂組成物，該氯 乙席系树知用文定劑組成物 所旦取物之知被為··係由含有10〜80 貝里。石反’、子數為12〜30之脂肪酸曱 丨 量%之⑻硬脂醯基苯甲醯夂”曰及1 8貝 ., 基甲烷的糊狀或液狀組成物所 組成。 本么明中’上述(A)碳原子數為12〜加之脂肪酸曱酯的 97110772 200904832 含量較佳為20〜80質量％。又，作為上述（A)碳原子數 12〜30之脂肪酸曱酯，較佳的是使用植物油脂肪酸曱酯 特佳的是使用大豆油脂肪酸曱酯。 (發明效果） 本發明之氯乙烯系樹脂用安定劑組成物，係不僅含有具 有高色調改善效果且衛生性亦優異之SBM，於低溫時 〜10 C )亦具有優異之流動性，並且長期保存性優異，於 低溫保存後亦抑制固化或相分離等經時性變化的糊狀哎 液狀者，因此，可較佳地獲得製造適應性優異，並且物I .亦優異之氣乙烯系樹脂組成物。 【實施方式】 以下，對本發明之較佳的實施形態進行詳細說明。 本發明之糊狀或液狀氣乙烯系樹脂用安定劑組成物，立 係含有10〜80質量％、更佳為20〜8〇質量％之碳原子數為 12〜30之脂肪酸甲醋，及i〜8質量％之3隨作為必需成 (分，且使微細之固體粒子懸浮於液體中而成的組成物， 且具有流動性。 於上述脂肪酸甲酯之含量未滿1〇質量％時，流動性之改 善效果小，若含有大於80質量％，則對氯乙烯系樹脂之 塑化效果會變得過大，因此，會發生如下之不良狀況：戶° 獲得之氯乙烯系樹脂組成物的物性降低；或者於夏季t 溫環境下，製品之表面表現出黏著性等。尤其是於含= 20質量％以上時，流動性之改善效果大，故而較佳。又， 於上述硬脂醯基苯甲醯基甲烷之含量未滿丨質量％時，色 97110772 8 200904832 安定化政果小；若調配大於8質量％，則流動性會降 低，而使操作性變差。 作為構成本發明所使用之碳原子數為之脂肪酸 γ 土 S曰的月曰肪酸，例如可列舉：月桂酸、肉豆謹酸、掠搁 、、更月曰酉夂#硬脂酸、蓖麻油酸、亞麻油酸、次亞麻油 酉欠'由I、化生酸、山窬酸、芥酸等飽和或不飽和脂肪酸， 或：屬於水解天然油脂而獲得之脂肪酸之混合物的大豆 f :如肪I椰子油脂肪酸、桐油脂肪酸、菜籽油脂肪酸、 綿籽油脂肪酸、獸脂脂肪酸、魚油脂肪酸等。 本么月中’就谷g獲得及低溫時之流動性的觀點而言， 作為上述月曰肪酸甲醋，較佳的是使用於低溫時之流動性優 異之植物油脂肪酸的甲醋’特佳的是使用大豆油脂肪酸的 曱酯。 作為構成本發明之氣乙烯系樹脂用安定劑組成物的其 他成分，除至少使用通常用作氣乙烯系樹脂之安定劑的金 (屬系安定劑中的任-種以外，可進而使用可與通常金屬系 安定劑併用之各種添加劑。 作為上述金屬系安定劑，例如可列舉：鉛系安定劑、有 機酸金屬鹽、有機錫安定劑、及該等之複合安定劑等。 作為鉛系安定劑，例如可列舉：鉛白、鹼性矽酸鉛、鹼 性硫酸鉛、二鹼性硫酸鉛、三鹼性硫酸鉛、鹼性亞硫酸鉛、 二鹼性亞磷酸鉛、矽膠共沈澱矽酸鉛、二鹼性鄰苯二甲酸 鉛、三鹼性馬來酸鉛、水揚酸鉛、硬脂酸鉛、鹼性硬脂酸 鉛、二鹼性硬脂酸鉛、月桂酸鉛、辛酸鉛、12_羥基硬脂 97110772 9 200904832 酸錯、山荼酸鉛、環烧酸鉛等。 作為有機酸金屬鹽，可使用：羧酸、有機磷酸類或苯酚 類之金屬（Li、Na、K、Mg、Ca、Ba、Sr、Zn、Sn、A1 等） 鹽等，作為該叛酸’例如可列舉：己酸、辛酸、壬酸、2 一 乙基己基酸、癸酸、新癸酸、十一碳烯酸、月桂酸、肉豆 蔻酸、彳不櫚酸、硬脂酸、異硬脂酸、12 —經基硬脂酸、氯 硬知酸、12-酮硬脂酸、苯基硬脂酸、蓖麻油酸、亞麻油 p酸、次亞麻油酸、油酸、花生酸、山窬酸、芥酸、芸苔酸 及類似酸，以及獸脂脂肪酸、椰子油脂肪酸、桐油脂肪酸、 大旦油脂肪酸、采籽油脂肪酸及綿籽油脂肪酸等天然產生 之上述酸的混合物，苯甲酸、對第三丁基苯曱酸、乙基苯 甲酸、異丙基苯甲酸、甲苯甲酸、二甲苯甲酸、水揚酸、 5-第三辛基水揚酸 '環烷酸、環己甲酸等。 又，作為上述有機磷酸類，例如可列舉：單或二辛基磷 酸、單或二-十二烷基磷酸、單或二—十八烷基磷酸、單或 (一（壬基苯基）磷酸、膦酸壬基苯酯、膦酸硬脂酯等。作為 上述苯酉分類，可列舉：苯紛、甲紛、乙盼、環己紛、壬盼、 十二烷基苯酚等。 酸性鹽、驗性鹽或者過 該等有機酸金屬鹽，可為正鹽 驗性錯合物。 作為上述有機錫系安定劑，例如可列舉：甲基錫酸、丁 基錫酸、辛基錫酸、二甲基氧化錫、二丁基氧化錫、 ，氧化錫、二曱基硫化錫、二丁基硫化錫、二辛基硫化錫、 早丁基乳化/硫化錫、甲基硫錫酸、丁基硫錫酸、辛基硫 97110772 10 200904832 錫酸、二月桂酸二丁基錫、二硬脂酸二丁基錫、二油酸二 ，基錫、鹼性月桂酸二丁基錫、二巴豆酸二丁基锡、雙 氧基二乙二醇馬來酸酯）二丁基錫、$基/辛基/新戊二醇 馬來酸酉旨二丁基錫、異辛基/1>4一丁二醇馬來酸酉旨二丁基 錫、二f基丙烯酸二丁基錫、二肉桂酸二丁基錫、雙（馬 來酸油基酯）二辛基錫、雙（馬來酸硬脂基酯）二丁基錫、 伊康酸二丁基錫、馬來酸二辛基錫、二巴豆酸二甲基錫、 雙（馬來酸丁酯）二辛基錫、二甲氧化二丁基錫、二—十二 烷氧化二丁基錫、乙二醇化二辛基錫、季戊四醇/氧化二 :基錫縮合物、雙(月桂基硫醇)二丁基錫、雙(硬脂基硫 醇）二甲基錫、參（月桂基硫醇）單丁基錫、$ 一巯基丙酸二 丁基錫威基丙酸二辛基錫、巯基乙酸二丁基錫、參（巯 基乙酸異辛醋）、參（魏基乙酸2_乙基己醋）單辛基錫、雙 (巯基乙酸異辛酯）二丁基錫、雙（巯基乙酸異辛酯）二辛基 錫、雙（巯基乙酸2-乙基己酯）二辛基錫、雙（巯基乙酸異 辛酯）二甲基錫、雙（巯基丙酸異辛酯）二〒基錫、參（髄基 丙酸異辛酯）單丁基錫、硫化雙[單丁基二（異辛氧基羰基 亞甲基硫基）錫]、硫化雙[二丁基單（異辛氧基幾基亞甲基 硫基）錫]、雙（巯基丙酸異辛酯）單丁基單氯錫、雙（酼基 乙酸異辛酯）單丁基單氯錫、雙（月桂基硫醇）單丁基單氯 錫、雙（乙基賽聪蘇馬來酸酯）丁基錫、馬來酸雙（馬來酸 丁酯二辛基錫）、二硫化雙（二異辛基硫基乙醇酸甲基 錫）、二硫化雙（甲基/二曱基錫單/二異辛基硫基乙醇 酸）、二硫化雙（二異辛基硫基乙醇酸甲基錫）、三硫化雙 97110772 11 200904832 ^異辛基硫基乙醇酸丁基錫）、參(丁基硫基乙醇酸)2— 丁氧基 >厌基乙基錫等。 士=金屬系安定劑之含量’係於本發明之氣乙烯系樹脂 用女疋劑組成物中，較佳的是2G〜5G質量％、更佳的是 30〜40質量％。 本發明之氣乙烯系樹脂用安定·成物中，可於無損本 發明之效果的範圍内，適當使用通常氣乙稀系樹脂所使用 之^塑劑。作為上述可塑劑，例如可列舉：鄰苯二甲酸二 :酯二鄰笨二甲酸丁己酯、鄰苯二曱酸二庚酯、鄰苯二甲 ::辛；、鄰苯二甲酸二異壬醋、鄰苯二甲酸二異癸醋、 郤本一甲酸二月桂醋、鄰苯二甲酸二環己醋、對苯二甲酸 一辛醋等苯二甲酸系可塑劑；己二酸二辛醋、己二酸二異 壬I:己二酸二異癸醋、二(二乙二醇頂）己二酸醋等己 夂糸可塑劑；磷酸三苯醋、磷酸三甲苯S旨、磷酸醋三一 二：苯㈣酸三(異丙基苯基)醋、磷酸三乙㈣酸三 辛醋、磷酸三(丁氧基乙基)醋、磷酸辛基二 本基®曰㈣酸酯系可塑劑；使用乙二醇、二乙二醇、三乙 t 醇、丙二醇、U-丙二醇、1，3-丁二醇、1>4— 丁二 醇、1，5 -己二醇、1 β _己_ _ 使用草妒、兩_ /新戊二醇等作為多元醇， 1 一駄、琥珀酸、戊二酸、己二酸、庚二酸、 :,酸、壬二酸、癸二酸、鄰苯二甲酸、間苯二甲酸、對 ς甲酸等作為二元酸’且根據需要使用一元醇、單繞酸 ::終止劑的聚I系可塑劑；其他，四氫鄰苯二甲酸系可 塑劑、壬·一酸系可谢濟||、/欠_ A 2 '、 h 々一酸系可塑劑、硬脂酸系可塑 97110772 12 200904832 劑、檸檬酸系可塑劑、偏苯三甲酸系可 糸可塑劑、聯笼夕 句本四甲酸 含量，於本發明^酸系可塑劑等。添加上述可塑劑時之 〜8〇質量％、更稀系樹脂組成物中，較佳的是20 更佳的是30〜50質量％。 αΙ本發明之氣乙歸系樹脂用安定劑組成物+，於A損 =明之效果的範圍内，可進而添加通常用作氣己= 「'=系r化劑、水滑石化合物、環氧化合二: 安定二充二了。化合物、紫外線吸收劑、受阻胺系光 作為上述有機亞磷酸酯化合物，例如可列舉： =其亞_參(2,4—二第三丁基苯基)醋、亞餐參(： 土 @二、亞磷酸參（二壬基苯基）酯、亞磷酸參（單/二 混合壬基苯基）酉旨、酸式亞填酸二苯醋、亞鱗酸2 2 :基雙（4,6~二第三丁基苯基）辛基S旨、亞磷酸二苯基癸基 (自日亞^敲苯基二異癸基酯、亞磷酸三丁酯、亞磷酸三（2_ =f己基）酯、亞磷酸三癸酯、亞磷酸三月桂酯、酸式亞 ^ 丁酉曰、酉夂式亞磷駿二月桂酯、三硫代亞礙酸三月桂 酉曰#雙（新戊二醇）/〗，4-環己二甲基二亞磷酸酯、雙（2, 4~ 一第二丁基苯基）季戊四醇二亞磷酸酯、雙（2, 6_二第三丁 基一 4-曱基苯基）季戊四醇二亞磷酸酯、二硬脂基季戊四醇 二亞磷酸酯、苯基-4, 4，-異亞丙基二苯酚/季戊四醇二亞 磷=酯、四（C12〜15混合烷基）_4,4，_異亞丙基二苯基二 亞磷酸酯、氫化4, 4’-異亞丙基二苯酚多亞磷酸酯、雙（辛 97110772 13 200904832 基苯基）/雙[4, 4,-正亞丁基雙（2_第三丁基_5_甲基苯200904832 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to a stabilizer composition for a chlorinated ethylenic resin, and is detailed in the section "For a paste or liquid containing a stearyl benzoyl thioglycolate. A stabilizer composition for a rat vinyl resin, and a vinyl chloride (tetra) resin which is used as a molding material for various resin parts, etc., containing the stabilizer composition. [Prior Art] Vinyl chloride resin is subjected to heat forming processing. At the time, it is mainly prone to thermal decomposition by dehydrochlorination 51, and deterioration of mechanical properties or deterioration of color is caused, so that it is added by using one or several types of heat (4). Anthony (4), a kind of keto-dione compound which is excellent in coloring and deuteration, is currently widely used as diphenylmethylformamidine or lysylbenzamide (hereinafter referred to as _. Especially the above) SM' is a stimulant ingredient that is approved by the FDA and can be used in toys and the like. On the other hand, in terms of operability, a paste or liquid composition is being sought. A method for forming a stabilizer component of a powder or a stabilizer component of a high viscosity into a paste or liquid stabilizer composition, which is known to be an epoxidized vegetable oil or a di-tert-ethyl phthalate. a vinegar or the like which is a liquid substance known as a stabilizer or a plasticizer for a vinyl chloride resin, and a method of forming a knife or a liquid stabilizer which is obtained by the above method. In the long-term storage or in the winter, there are problems such as maneuvering, birth, solidification, precipitation of components, phase separation, etc. 97110772 200904832 In particular, the paste stabilizer with SBM is viscous. Therefore, τρ is inclined to it. Therefore, in order to improve its fluidity, a large amount of epoxidized large σ must be prepared. When such a diluted stabilizer is used to obtain sufficient ampere-and-large oil, it is necessary to mix a large amount of the stabilizer composition. Therefore, the physical properties of the obtained fat composition are lowered. Therefore, when the physical property is prevented from being lowered and the amount of == is reduced, there is a problem that sufficient color stability cannot be achieved.... [Summary of the Invention] Therefore, a third object of the present invention is to provide a composition of a vinyl chloride stabilizer which is excellent in handleability and has a stable color tone effect = use of a substance::: It has excellent color tone stability and does not produce physical properties (the means to solve the problem) - the inventors and others have solved the problem of solving the upper pumping; i I ^ MW field shouting, and the results show that hunting is based on the formulation of specific fatty acids. The present invention has been completed by the use of a stabilizer composition for a vinyl-based resin in the form of a m-night, and the present invention relates to a system of the invention. a stabilizer composition for a resin, and a composition of the female tanning agent to form a gas of 7 ^ ^ m ^ air-enthalpy vinyl resin composition, and the composition of the composition of the chloroform The knowledge is made up of 10 to 80 Berry. Stone anti-, the number of fatty acids in the number of 12 to 30% (8) stearyl benzoyl hydrazine 曰 and 18 lb., composed of a paste or liquid composition of methane. The content of the above-mentioned (A) having a carbon atom number of 12 to 12 and a fatty acid decyl ester is preferably from 20 to 80% by mass. Further, as the above (A) a fatty acid decyl ester having 12 to 30 carbon atoms, preferably It is particularly preferable to use a vegetable oil fatty acid oxime ester to use a soybean oil fatty acid oxime ester. (Effect of the invention) The stabilizer composition for a vinyl chloride resin of the present invention contains not only a SBM having a high color tone improving effect but also excellent hygienic properties. It has excellent fluidity at low temperature, and has excellent long-term storage stability, and also suppresses the change of the paste or the like which is temporally changed, such as curing or phase separation, after storage at a low temperature, and therefore, it is preferably obtained. A gas-based resin composition which is excellent in the flexibility of the production and is also excellent in the material. [Embodiment] Hereinafter, preferred embodiments of the present invention will be described in detail. The paste or liquid ethylene-based resin of the present invention is used. Stabilizer composition The base contains 10 to 80% by mass, more preferably 20 to 8% by mass of the fatty acid methyl ketone having 12 to 30 carbon atoms, and 3 to 3% by mass of the product is required to be formed (minute, and fine) a composition in which the solid particles are suspended in a liquid, and has fluidity. When the content of the fatty acid methyl ester is less than 1% by mass, the effect of improving the fluidity is small, and if it is more than 80% by mass, the vinyl chloride is contained. The plasticizing effect of the resin becomes too large, and therefore, the following disadvantages occur: the physical properties of the vinyl chloride resin composition obtained by the household are lowered; or the surface of the product exhibits adhesion in the summer t temperature environment. In particular, when the content is more than 20% by mass, the effect of improving the fluidity is large, so that it is preferable. Further, when the content of the above stearyl benzoylmethane methane is less than 5% by mass, the color is 97110772 8 200904832. If the amount is more than 8% by mass, the fluidity is lowered and the workability is deteriorated. As the fatty acid γ soil S曰 constituting the carbon atom used in the present invention, for example, List: lauric acid Nutmeg, scum, and more sputum # stearic acid, ricinoleic acid, linoleic acid, sub-linseed oil 酉 owed by I, meta-acid, behenic acid, erucic acid, etc. Saturated fatty acid, or: a mixture of fatty acids obtained by hydrolyzing natural oils and fats: such as fat I coconut oil fatty acid, tung oil fatty acid, rapeseed oil fatty acid, cottonseed oil fatty acid, tallow fatty acid, fish oil fatty acid, etc. From the viewpoint of obtaining the liquidity at the time of low temperature and the low-temperature fluidity, it is preferable to use the vegetable oil fatty acid methyl vinegar which is excellent in fluidity at a low temperature as the above-mentioned glutamic acid vinegar. The oxime ester of the soybean oil fatty acid. As the other component constituting the stabilizer composition for the gas-based resin of the present invention, at least one of the gold (genus stabilizer) which is usually used as a stabilizer for the gas-vinyl resin is used. In addition, various additives which can be used in combination with a usual metal stabilizer can be used. Examples of the metal-based stabilizer include a lead-based stabilizer, an organic acid metal salt, an organotin stabilizer, and the like. Examples of the lead-based stabilizer include lead white, basic lead citrate, basic lead sulfate, dibasic lead sulfate, tribasic lead sulfate, basic lead sulfite, lead alkaline phosphite, and tannin. Coprecipitation of lead citrate, lead alkaline phthalate, lead tribasic maleate, lead salicylate, lead stearate, basic lead stearate, lead alkaline stearate, lauric acid Lead, lead octoate, 12-hydroxystearyl 97110772 9 200904832 Acidic acid, lead behenate, lead acid lead and so on. As the organic acid metal salt, a metal such as a carboxylic acid, an organic phosphoric acid or a phenol (Li, Na, K, Mg, Ca, Ba, Sr, Zn, Sn, A1, etc.) salt or the like can be used as the tarenic acid. For example, hexanoic acid, octanoic acid, citric acid, 2-ethylhexyl acid, citric acid, neodecanoic acid, undecylenic acid, lauric acid, myristic acid, non-palmitic acid, stearic acid, and iso-hard Fatty acid, 12-base stearic acid, chlorinated acid, 12-keto stearic acid, phenyl stearic acid, ricinoleic acid, linseed oil p acid, linoleic acid, oleic acid, peanut acid, mountain Benzoic acid, erucic acid, canola acid and similar acids, and a mixture of the above-mentioned acids, such as tallow fatty acids, coconut oil fatty acids, tung oil fatty acids, large oil fatty acids, seed oil fatty acids and cottonseed oil fatty acids, benzoic acid , p-tert-butylphthalic acid, ethyl benzoic acid, isopropyl benzoic acid, toluic acid, xylenecarboxylic acid, salicylic acid, 5-trioctyl salicylic acid, naphthenic acid, cyclohexanecarboxylic acid, etc. . Further, examples of the organic phosphoric acid include mono- or dioctylphosphoric acid, mono- or di-dodecylphosphonic acid, mono- or di-octadecylphosphonic acid, and mono-(indolylphenyl)phosphoric acid. , decyl phenyl phosphonate, stearyl phosphonate, etc. As the above classification of benzoquinone, benzodiazepine, acesulfon, acetyl, hexidine, sulfonium, dodecyl phenol, etc. The test salt or the organic acid metal salt may be a positive salt complex. The organotin stabilizer may, for example, be methyl stannic acid, butyl stannic acid, octyl stannic acid or dimethyl group. Tin oxide, dibutyltin oxide, tin oxide, dimercaptosulfide tin, dibutyltin sulfide, dioctyltin sulfide, early butyl emulsifier/tin sulfide, methyl thiostannic acid, butyl sulphuric acid , octyl sulphur 9710772 10 200904832 stannic acid, dibutyltin dilaurate, dibutyltin distearate, dioleic acid, tin, basic dibutyltin laurate, dibutyltin dicrotonate, dioxydiethylene Alcohol maleate) dibutyltin, keto/octyl/neopentyl glycol maleate, dibutyltin, different Octyl/1>4-butanediol maleic acid, dibutyltin, dibutyltin di-butyltin, dibutyltin di-cinnamate, bis(oleyl maleate)dioctyltin, bis(maleic acid) Stearyl ester) dibutyltin, dibutyltin iconate, dioctyltin maleate, dimethyltin dicrotonate, bis(butyl maleate)dioctyltin, dibutyltin dimethoxide, two - dodecane oxide dibutyltin, ethylene glycol dioctyltin, pentaerythritol / oxidation two: base tin condensate, bis (lauryl mercaptan) dibutyl tin, bis (stearyl mercaptan) dimethyl tin, ginseng (Lauryl mercaptan) monobutyltin, dioctyltin dibutyltin propyl propionate, dibutyltin thioglycolate, thioglycolic acid isooctyl vinegar, ginseng (weilic acetic acid 2_ethylhexanoic vinegar) Monooctyltin, bis(isooctyl phthalate) dibutyltin, bis(isooctyl acetate) dioctyltin, bis(2-ethylhexyl acetate) dioctyltin, bis(mercaptoacetic acid) Isooctyl ester) dimethyltin, bis(isooctyl propionate) dinonyl tin, ginseng (isooctyl propionate) Tin, sulfurized bis[monobutylbis(isooctyloxycarbonylmethylenethio)tin], sulfurized bis[dibutylmono(isooctyloxymethylenesulfanyl)tin], bis(fluorenyl) Isooctyl propionate) monobutyl monochlorotin, bis(isooctyl thioglycolate) monobutyl monochlorotin, bis(lauryl mercaptan) monobutyl monochlorotin, bis (ethyl cersubsin) Maleate) butyltin, maleic acid bis(butyl butyl maleate dioctyltin), bis(diisooctylthioglycolate methyl tin) disulfide, disulfide di(methyl/difluorenyl) Tin/diisooctylthioglycolic acid), disulfide di(diisooctylthioglycolate methyltin), trisulfide double 97110772 11 200904832 ^isooctylthioglycolate butyltin), ginseng Thiothioglycolic acid) 2-butoxy> anaethylethyltin and the like. The content of the metal-based stabilizer is in the range of 2G to 5G% by mass, more preferably 30 to 40% by mass, based on the composition of the tanning agent for the ethylene-based resin of the present invention. In the stabilizer of the gas-based ethylene resin of the present invention, a plasticizer used in a general ethylene-based resin can be suitably used within the range in which the effects of the present invention are not impaired. As the above plasticizer, for example, phthalic acid di-ester: dibutyl phthalate, diheptyl phthalate, phthalic acid: octane; diisoindole phthalate; Vinegar, diisophthalic acid phthalic acid, butadiene vinegar, dicyclohexyl phthalate, terephthalic acid, phthalic acid, etc.; adipic acid dioctyl vinegar, Diisoindole adipic acid I: hexamidine plasticizer such as adipic acid diisohydrazine vinegar, di(diethylene glycol top) adipic acid vinegar, triphenyl vinegar phosphate, trimethyl phosphate trihydrate, triacetate Two: tris(isopropylphenyl) vinegar of benzene (tetra) acid, trioctyl vinegar of triethyl (tetra)phosphate, tris(butoxyethyl) vinegar phosphate, octyldiyl phthalate (tetra) phosphate plasticizer; Using ethylene glycol, diethylene glycol, triethyl t, propylene glycol, U-propylene glycol, 1,3-butylene glycol, 1> 4-butanediol, 1,5-hexanediol, 1β_hex_ _ using grass 妒, two _ / neopentyl glycol, etc. as polyol, 1 駄, succinic acid, glutaric acid, adipic acid, pimelic acid, :, acid, azelaic acid, sebacic acid, o-benzene Dicarboxylic acid, isophthalic acid, p-formic acid A poly-I-type plasticizer which is used as a dibasic acid and, if necessary, a monohydric alcohol, a mono-acid: a terminator; other, a tetrahydrophthalic acid-based plasticizer, a bismuth-acid system, a thank-you || / _ _ A 2 ', h 々 acid-based plasticizer, stearic acid-based plastic 97110772 12 200904832 agent, citric acid plasticizer, trimellitic acid-based plasticizer, conjugated tetracarboxylic acid content, In the present invention, an acid-based plasticizer or the like. When the above plasticizer is added, it is preferably 8% by mass or less, and more preferably 20 is more preferably 30 to 50% by mass. Ι Ι 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安 安2. The compound, the ultraviolet absorber, and the hindered amine light are used as the above-mentioned organic phosphite compound, and examples thereof include: = sub-parameter (2,4-di-tert-butylphenyl) vinegar, Asian ginseng (: earth @二, phosphite ginsyl (didecyl phenyl) ester, phosphite ginseng (single / di mixed decyl phenyl) hydrazine, acid sub-acid diphenyl vinegar, squaric acid 2 2: bis (4,6~di-t-butylphenyl)octyl S, diphenyl sulfenyl phosphite (from yttrium phenyl diisodecyl ester, tributyl phosphite, sub Tris(2_=f-hexyl) phosphate, tridecyl phosphite, trilauryl phosphite, acid yttrium, yttrium phosphite, dilauryl ester, trithio sulfite, laurel Bis(neopentyl glycol)/, 4-cyclohexanedimethyl diphosphite, bis(2,4~-dibutylphenyl)pentaerythritol diphosphite, double (2, 6_2 Tributyl- 4-mercaptobenzene Pentaerythritol diphosphite, distearyl pentaerythritol diphosphite, phenyl-4, 4,-isopropylidene diphenol / pentaerythritol diphosphorus = ester, tetra (C12 15 mixed alkyl) _4, 4, _isopropylidene diphenyl diphosphite, hydrogenated 4, 4'-isopropylidenediphenol polyphosphite, bis (Xin 97110772 13 200904832 phenyl) / double [4, 4,- n-Butyl bis(2_t-butyl-5-methylbenzene
齡）]/1/6:己二醇二亞鱗酸醋、四-十三烧基/4, 4，-亞丁基 雙（2-第二丁基-5—甲基苯酚）二亞磷酸酯、六（十三烷 基）/1’1’3-參（2-甲基一5_第三丁基+經基苯基）丁烷/三 亞磷酸醋、9, 10-二氫+氧雜，—磷雜菲，_氧化物、2_ 丁基-2-乙基丙二醇/2,4,6_三第三丁基苯紛單亞磷酸醋 等。於添加上述有機亞磷酸醋化合物時之含量，於本發明 之氯乙烯請脂用安定劑組成物中，較佳較5〜7〇質量 %、更佳的是1 0〜50質量％。Age)]/1/6: hexanediol di linoleic acid vinegar, tetra-tridecyl ketone / 4, 4,-butylene bis(2-second butyl-5-methylphenol) diphosphite , hexadecyltridecyl/1'1'3-cis (2-methyl-5-t-butyl+perphenyl)butane/triphosphoric acid citrate, 9, 10-dihydrogen + oxalate , - phosphaphenanthrene, _ oxide, 2 - butyl-2-ethyl propylene glycol / 2, 4, 6 - tri-tert-butyl benzene, phosphite, and the like. The content of the above-mentioned organic phosphite compound is preferably from 5 to 7 % by mass, more preferably from 10 to 50% by mass, based on the stabilizer composition of the vinyl chloride resin of the present invention.
作為上述本酌·系抗氧化劑，例如可舉：2 6 _二第r 基對曱酚、2,6-二笨基-4—十八烷氧基苯酚、（3,5_二第三 丁基-4-羥基苯基）丙酸硬脂酯、（3, 5_二第三丁基_4—羥基 爷基）膦酸二硬脂醋、雙[(3,5_二第三丁基_4_羥基苯基） 丙酸]硫代二乙二酯、4, 4, _硫代雙（6_第三丁基間甲酚）、 2辛基硫代-4, 6-二（3, 5-二第三丁基_4_羥基苯氧基）均 二讲、2, 2’ -亞曱基雙（4-曱基-6-第三丁基苯酚）、乙二醇 雙[3, 3-雙（4-羥基-3-第三丁基苯基）丁酸]酯、4, 4, _亞丁 基雙（6-第三丁基間曱酚）、2,2’_亞乙基雙（4,6_二第三丁 基苯酚）、1，1，3-參（2_曱基-4-羥基—5-第三丁基苯基）丁 烷、對苯二曱酸雙[2-第三丁基曱基_6_(2_羥基_3一第 三丁基-5-曱基苄基）苯基]酯、異氰尿酸13,5-參（2,6一 二曱基-3-羥基-4-第三丁基苄基）酯、異氰尿酸1，3, 5-參 (3, 5-二第三丁基-4-羥基苄基）酯、1，3, 5_參（3, 5-二第三 丁基-4-羥基苄基）-2, 4, 6-三曱基苯、異氰尿酸1，3, 5-參 97110772 14 200904832 5-二第三丁基—4_羥基笨基）丙醯氧基乙基]酯、肆[亞 甲，一3 (3, 5-一第二丁基_4_超基苯基）丙酸醋基]甲燒、 2第一丁 & 4甲基-6-(2-丙烯醯氧基一3-第三丁基_5 一甲 基节基）苯盼、3, 9-雙[1，卜二曱基-2-經基乙 基]-2:4’8’10-四氧雜螺[5, 5]十一烷-雙[厂(3-第三丁 基-4-羥基-5-丁基笨基）丙酸]、三乙二醇雙[点_(3-第三 丁基—4 一羥基—5〜曱基笨基）丙酸]等。 f 於，加上述本I系抗氧化劑時之含量，於本發明之氣乙 社糸樹月曰用女疋劑組成物中，較佳的〜⑼ 佳的是5〜1〇質量％。 又 上述硫系抗氧化劑，例如可列舉：硫代二丙酸之二 肉豆^旨、肉豆s基硬脂錢、二硬脂醋等硫 丙酉夂一燒基s旨類，乃毒# 二 ϋ ^ ^ ^ 、及季戊四醇四（召-十二烷基巯基丙 孚…基疏基丙酸醋類等。 夺樹;硫系抗氧化劑時之含量，於本發明之氣乙烯 =用：定劑組成物中，較佳的是卜： 的疋5〜1〇質量％。 只 人κExamples of the above-mentioned preferred antioxidants include: 2 6 _di-r-p-p-nonylphenol, 2,6-di-p-styl-4-octadecyloxyphenol, and (3,5-di-3:3) Stearyl 4-hydroxyphenyl)propionate, (3,5-di-tert-butyl-4-hydroxy-hydroxy)phosphonic acid distearin, bis[(3,5-di-t-butyl) _4_hydroxyphenyl) propionic acid] thiodiethylene diester, 4, 4, _ thiobis (6_t-butyl m-cresol), 2 octyl thio-4, 6-di (3 , 5-di-tert-butyl-4-ylhydroxyphenoxy) bis, 2, 2'-fluorenylene bis(4-mercapto-6-tert-butylphenol), ethylene glycol double [3 , 3-bis(4-hydroxy-3-t-butylphenyl)butyrate], 4, 4, _butylene bis(6-tert-butyl-m-nonylphenol), 2,2'-Asian Bis (4,6-di-tert-butylphenol), 1,1,3-parade (2- mercapto-4-hydroxy-5-t-butylphenyl)butane, terephthalic acid double [2-Tertibutylindenyl_6_(2-hydroxy-3-tert-butyl-5-fluorenylbenzyl)phenyl]ester, isocyanuric acid 13,5-gin (2,6-12) 3-hydroxy-4-tert-butylbenzyl ester, isocyanuric acid 1,3,5-(3,5-di-t-butyl-4-hydroxybenzyl) ester, 1 3, 5_ ginseng (3, 5-di-t-butyl-4-hydroxybenzyl)-2,4,6-trimercaptobenzene, isocyanuric acid 1,3, 5-parameter 97110772 14 200904832 5-two Tertiary butyl-4-hydroxyphenyl)propenyloxyethyl]ester, hydrazine [methylene, a 3 (3,5-di-tert-butyl 4-methylphenyl) propionate] Methane, 2 first butyl & 4 methyl-6-(2-propenyloxy-l-tert-butyl-5 monomethyl) phenyl, 3, 9-double [1, 卜二Mercapto-2-ylethylethyl]-2:4'8'10-tetraoxaspiro[5,5]undecane-bis[factory(3-tert-butyl-4-hydroxy-5-butyl) Propionate], triethylene glycol bis [dot-(3-tert-butyl-4-hydroxy-5-fluorenyl) propionic acid] and the like. f, the content of the above-mentioned I-based antioxidant is preferably 5 to 1% by mass in the composition of the female medicinal preparation of the eucalyptus eucalyptus. Further, the above-mentioned sulfur-based antioxidant may, for example, be a thiodipropionic acid, a vegan, a sulphur, a sulphur, a sulphur, a sulphur, a sulphur, a sulphur, a sulphur, and the like. Dimensional ^ ^ ^ , and pentaerythritol IV (call - dodecyl fluorenyl propyl propyl propyl acetonate vinegar, etc.. seized trees; sulfur-based antioxidant content, in the invention of ethylene ethylene = use: In the composition of the agent, it is preferably 疋5 to 1〇% by mass of the 疋: only κ
MgxiZnx2Al 表===化it較佳地使用以下述通式⑴ 亦可為脫去結晶水者:者鋅、鎂及銘之複鹽化合物。該等 (0H) 2(xl + x2) + 4 (C 0 3 ) 1 - y / 2 ( C 1 0 4 ) y · ΙΠ Η 2 0 式中之xl、X2及 八 件的數，m矣_ n y刀別表不滿足以下述式所表示之條 ^ 111衣不0式紅土丄^ ^ 思之 2數。〇Sx2/xl< 10、2S (χΐ 97110772 15 200904832 + x2) < 20、〇 s y s 2。 上述水滑石化合物可為天然:物，亦可為合成品。作為該 合成品之合成方法，可例示：於日本專利特公昭46-228〇 號公報、曰本專利特公昭5〇_3〇〇39號公報、曰本專 公昭51-29129號公報、日本專利特公平^撕⑽號公報、 及曰本專利㈣昭6卜1 7427()號公報等所揭示之習知方 本卷月中’可不文上述水滑石化合物之結晶構造、 結晶粒徑等限制地使用水滑石化合物。 又’作為上述水滑石化合物，可使用以如硬脂酸之高級 脂肪酸、如油酸驗金屬鹽之高級脂肪酸金屬鹽、如十二尸 基苯石黃酸驗金屬鹽之有機確酸金屬鹽、高級脂肪酿胺、= 級脂肪酸酯或蠟等被覆其表面而成者。 二:ic滑石化合物之含量’於本發明之氣乙烯系樹脂用 女疋劑組成物中，較佳的是1〜20質量％、更佳的是卜 =士量％。若水滑石化合物之量超過2()質量％，則於長期 保存％可能會產生相分離，故而不佳。 产作為上述環氧化合物，例如可列舉··環氧化大豆油、環 ，化亞麻籽油、環氧化桐油、環氧化魚油、環氧化牛脂油、 :乳化％麻油、環氧化紅花油等環氧化動植物油， =酸？醋、環氧化硬脂酸丁醋、環氧化硬賴2-乙基 ά乳化硬脂酸硬脂醋、環氧化聚丁二婦、異氛尿酸 參（環氧基丙基）醋、環負仆古、Α /、 ., 衣巩化间油脂肪酸酯、環氧化亞麻籽 =肪酸醋、雙苯μ二環氧丙基鱗、二環氧化乙嫦基環 稀、二環氧化二環己稀、3士環氧基環己基f基環氧基 97110772 16 200904832 環己甲酸酯等環氧化合物等。 ’於本發明之氣乙烯系 質量％、更佳的是1〜 於添加上述環氧化合物時之含量 樹脂組成物中，較佳的是0.5〜2〇 1 〇質量％。 二==合物’例如可列舉:聯基丙坑、 季戍一四醇或泰 四醇、二季戊四醇、聚季戊四醇、 己一醅两匕史力曰馱+酯、雙（二季戊四醇） 甘油、異氰尿酸三（2-絲乙基）醋等。 j添加上述多元醇化合物時之含量，於本發明之氯乙烯 糸樹脂用安定劑組成物中， θ 的是5〜30質量%。 較佳的疋1〜5。質量%、更佳 作為上述万-二酮化合物，例如，乙酿丙綱、 Ζ、2,4, 6_庚三剩、丁酿基乙酿基甲烧、月桂酿編 基甲烷、軟脂醯基乙醯基甲烷、硬脂醯基乙醯基曱烷、苯 基乙醯基乙醯基甲貌、二環己基幾基甲烧、苯甲酿基甲醯 基甲烷、苯曱醯基乙醯基曱烷、二苯甲醯基甲烷、辛基苯 甲酿基曱烧、雙（4~辛基苯曱醯基）曱烧、苯甲醯基二乙醢 基曱烷、4-曱氧基苯曱醯基苯曱醯基曱烷、雙羧基曱 基苯曱醯基）甲烷、2-羧曱基苯曱醯基乙醯基辛基曱烷、 去氫醋酸、1，3-環己二酮、3, 6-二曱基-2, 4-二氧基環己 烷-1曱酸甲酯、2-乙醯基環己酮、雙曱酮、2_笨曱醯基 環己烧等。 又，本發明中，亦可使用該等二酮化合物之金屬鹽。 作為可提供該沒-二酮金屬鹽之金屬種類，例如可列舉： 97110772 17 200904832 鋰、鈉及鉀等鹼金屬；鎂、 銨、錫、烷基錫等。 （及鋇等鹼土金屬；辞、 於添加上述/9 -二g同化合物時旦 烯系樹脂用安定劑組成物中 S里’於本發明之氯乙 更佳的是卜5質量％。 較佳的是〇·5〜10質量％、 作為上述紫外線吸收劑，例如 f酮、2-羥基—4-甲氧基二 ：“ 一工基-本 甲酮、5, 5，-亞甲基雙°里基一4-辛軋基二苯 f基雙(2~麵基+甲氧基二苯甲酮)等之 Γ; "fri；2'(2^ 基苯基)笨并三…-趣… :5二Λ Λ:氣苯并三。坐、2_(2-羥基+第三丁基 土本基）5 -氯本并三唾、2_(2_辨其q 美芏其、贫诠- ,。 z ^羧基-3, 5-二異丙苯 基本基）本开二唑、2, 2，-亞甲基雙（4一第二 唾基)苯酚、2-(2-羥基_3—第f 一辛基+本开三 社丞d弟二丁基—5 —羧基 唑之聚乙二醇酯等2 — (2 —羥基 本土）本开二 …間本二朌單苯甲酸醋、3, 5 —二第三丁基+ : ?夂2, 4-一弟二丁基苯酯、3, 5~二第三丁基+羥基苯甲 酸十六酯等苯甲酸S旨類；2_乙基-2，_乙氧基草酿替苯胺、 ^氧基1，A十二貌基草酿替苯胺等經取代之草醯替苯 月女類，α-氰基-万，万—二苯基丙烯酸乙酯、2〜氰美 基-3-(對甲氧基苯基）丙稀酸甲醋等氰基丙烯酸^ 於添加上述紫外線吸收劑時之含量，於本發明祕 系樹脂用安定劑組成物中，較佳的是〇. 5〜所旦ς 、 佳的是1〜5質量％。 周更 97110772 18 200904832 作為上述受阻胺系井忠^ ^ ’例如可㈣：硬脂酸 T 土兮辰定黯、硬脂酸 哌啶酯、苯甲酸2,2 6 R I 2’2, 6, 6-五曱基-4- au，6—四甲基―“底’二四J广4~㈣_、癸二酸雙 五甲基-4十定基）酯、丁尸土)=癸二酸雙（U，2,6,6-㈣)，、丁烧四曱酸丁肆 四曱基-4- _、1，2,3,4-丁烧四甲酸上’2;69,6w 基)/二(十三烧基)醋、2—二’2，’6,6-五曱基-4-派咬 基苄基）丙二酸雙（1 2 2 土 （，5-一第三丁基-4 —羥 H2-經基乙基）-22’66’6,6'五甲基—4-娘咬基）酉旨、 酉旨縮聚物、U-雙（2 2 6 6四甲基—4十定醇/破站酸二乙 二漠乙_勿、u」雙^ 己烧 /2, 4-二氣-6-二: au，6-四曱基辰二:二二°井縮聚物、U-雙 辛美扩萁 土月女基）己烷/2, 4-二氣-6-第三 ‘2:2二 聚物、U，8，12,2,4-雙(Ν-丁基 基1-1，5，: 19四:基.^ Π定基）胺基）均三°井+ Ϊα Ν。’”四氮雜十二烷、1,5,8，12-肆[2,4-雙(Ν- ‘ 5I,丨,6_五甲基如底咬基)胺基)均三讲. —土]- 5812-四氮雜十二燒、u’i參[2,4，(ν_丁基 十-S ’二基一底⑽ 十烷 U，ll-參[2,4-雙（N-H(12 ::==一基胺基卜 ，於添加上述受阻胺系光安定劑時之含量，於本發明 乳乙婦糸樹脂用安定劑組成物中，較佳的是〇·5〜W質 97110772 19 200904832 i%、更佳的是1〜5質量％。 氫1=述咖之Λ體例，可列舉:碳酸約、氧化約、 〇 氧化鋅、氫氧化鋅、碳酸鋅、硫化鋅、氧化鎂、 風氧化鎂、碳酸鎂、氧介&# 乳化鋇 、 虱氣化銘、梦銘酸納、水滑 屬鹽=土 於於七 m 黏土、鐵丹、石棉、三氧化銻等。 用安：二Γ填劑時之含量’於本發明之氯乙烯系樹脂The MgxiZnx2Al table====it is preferably used in the following formula (1) or in the case of decrystallization water: zinc, magnesium and the compound double salt compound. (0H) 2(xl + x2) + 4 (C 0 3 ) 1 - y / 2 ( C 1 0 4 ) y · ΙΠ Η 2 0 where xl, X2 and the number of eight pieces, m矣_ Ny knives do not satisfy the ones represented by the following formula ^ 111 clothes not 0 type red clay 丄 ^ ^ 2 of the number. 〇Sx2/xl< 10, 2S (χΐ 97110772 15 200904832 + x2) < 20, 〇 s y s 2. The hydrotalcite compound may be a natural substance or a synthetic product. As a method of synthesizing the synthetic product, Japanese Patent Publication No. Sho 46-228A, Japanese Patent Publication No. Sho. No. 5, No. 39, No. 39, Sakamoto No. 51-29129, Japanese Patent In the conventional method disclosed in the Japanese Patent Publication No. 4, No. 4,427, and the like, the crystal structure and crystal grain size of the hydrotalcite compound are not limited. A hydrotalcite compound is used. Further, as the hydrotalcite compound, a higher fatty acid such as a stearic acid, a higher fatty acid metal salt such as an oleic acid metal salt, or an organic acid metal salt such as a 12-carved phenylphosphinic acid metal salt can be used. A high-grade fatty amine, a fatty acid ester or a wax is coated on the surface. The content of the ic talc compound is preferably from 1 to 20% by mass, more preferably from 0% by weight, based on the composition of the oxime agent for the ethylene-based resin of the present invention. If the amount of the hydrotalcite compound exceeds 2 (% by mass), phase separation may occur in the long-term storage %, which is not preferable. Examples of the epoxy compound to be produced include epoxidized soybean oil, ring, linseed oil, epoxidized tung oil, epoxidized fish oil, epoxidized tallow oil, emulsified% sesame oil, and epoxidized safflower oil. Oil, = acid? Vinegar, epoxidized butyl succinate, epoxidized hard lysine 2-ethyl hydrazine emulsified stearic acid stearin, epoxidized polybutanin, anaerobic uric acid (epoxypropyl) vinegar, ring servant Ancient, Α /, ., yixianghua oil fatty acid ester, epoxidized flaxseed = fatty acid vinegar, bisbenzene μ diepoxypropyl scale, dicyclohexamethylene oxide ring, dicyclohexyl dicyclohexyl Dilute, 3 epoxide cyclohexyl f-epoxy group 97110772 16 200904832 Epoxide compounds such as cyclohexanecarboxylate. The amount of the gas ethylene in the present invention is more preferably from 1 to 2% by mass in the resin composition when the epoxy compound is added. The two == compound can be exemplified by: a thiophene pit, a tetradecyl alcohol or a tetraethylene alcohol, a dipentaerythritol, a polypentaerythritol, a diterpene, a bismuth diester, a bis (dipentaerythritol) glycerin, Isocyanuric acid tris(2-silylethyl) vinegar and the like. When the content of the above polyol compound is added, in the stabilizer composition for a vinyl chloride resin of the present invention, θ is 5 to 30% by mass. Preferably, 疋1~5. % by mass, more preferably as the above-mentioned 10,000-diketone compound, for example, acetylene, hydrazine, 2, 4, 6-g, butyl, butyl ketone, laurel, methane, soft glutinous Ethyl ethane methane, stearyl decyl decane, phenyl ethane hydrazide methyl form, dicyclohexyl ke group, benzoyl mercapto methane, benzoyl hydrazine Base decane, benzoylmethane, octyl benzoyl oxime, bis(4-octylphenylhydrazino) oxime, benzhydryldiethoxydecane, 4-decyloxy Phenylnonyl phenyl decane, biscarboxymethylphenyl hydrazino) methane, 2-carboxymethylphenyl fluorenyl octyl decane, dehydroacetic acid, 1,3-cyclohexane Ketone, 3,6-dimercapto-2,4-dioxycyclohexane-1 decanoic acid methyl ester, 2-ethyl fluorenylcyclohexanone, bis-fluorenone, 2 _ 曱醯 曱醯 环 己 等, etc. . Further, in the present invention, a metal salt of these diketone compounds can also be used. Examples of the metal species which can provide the metal salt of the bis-diketone include, for example, 97110772 17 200904832 alkali metals such as lithium, sodium and potassium; magnesium, ammonium, tin, alkyl tin and the like. (And an alkaline earth metal such as hydrazine; in the case of adding the above-mentioned /9 - di-g-compound compound, the stabilizer composition of the denier-based resin is preferably 5% by mass in the present invention. 〇·5 to 10% by mass, as the above ultraviolet absorber, for example, f ketone, 2-hydroxy-4-methoxydi: "mono- ketone, ketone, 5, 5, -methylene bis Ricky-4-octane-rolled diphenyl-f-bis(2-butyl-based+methoxybenzophenone) and the like; "fri;2'(2^-phenyl) stupid... ... :5二Λ Λ: gas benzotriene. Sit, 2_(2-hydroxy + tert-butyl soil base) 5-chloro-p- and three-salt, 2_(2_ distinguish its q beauty, its poor interpretation - , z ^carboxy-3, 5-diisopropylphenylcarbenyl), the present open diazole, 2, 2,-methylenebis(4-carbosyl)phenol, 2-(2-hydroxy-3- The first f-octyl group + the original open three community 丞d di-dibutyl-5-carboxyxazole polyethylene glycol ester, etc. 2 - (2 - hydroxy local) this open two ... between the two diphenyl benzoic acid vinegar, 3 , 5 - di-tert-butyl + : ? 夂 2, 4-di-dibutyl phenyl ester, 3, 5 - di-tert-butyl + hydroxybenzoic acid hexadecyl ester and other benzoic acid S; 2_B Base-2 _ ethoxylated phenyl aniline, ^ oxy 1, A 12-formyl turpentine, substituted oxalic acid, phenylene, female, α-cyano-wan, 10,000-diphenyl acrylate And the content of the cyanoacrylic acid such as 2% cyanome-3-(p-methoxyphenyl)acrylic acid methyl ketone in the addition of the above ultraviolet absorber, in the stabilizer composition for the secret resin of the present invention, Preferably, it is 〇. 5~本旦ς, preferably 1~5质量%. 周更97110772 18 200904832 As the above-mentioned hindered amine system 忠忠^ ^ ', for example, (4): stearic acid T 兮 黯 黯 黯, Piperidinyl stearate, 2,2 6 RI 2'2, 6, 6-pentamethyl-4- au, 6-tetramethyl-"bottom" quaternary J J 4~(tetra) _, azelaic acid Bis-pentamethyl-4 decyl) ester, butyl cadaverine = bis(U,2,6,6-(tetra)), butyrate tetrabutyl phthalate-4- _, 1, 2,3,4-butadiene tetracarboxylic acid on '2; 69,6w base) / bis(trityl) vinegar, 2-bi'2, '6,6-pentamethyl-4-pyrimidinyl benzyl Bisylmalonic acid bis(1 2 2 soil (,5-monobutyl-4-hydroxy-H2-transethyl)-22'66'6,6'pentamethyl-4-Nylon base) Decree Polymer, U-double (2 2 6 6 tetramethyl- 4 decyl alcohol / sclerosing acid sulphur dioxide _ _, u" double ^ hexane 2 / 4- gas -6 - 2: au , 6-四曱基辰二: 二二°well polycondensate, U-双辛美萁土土女基)hexane/2, 4-digas-6-third '2:2 dimer, U , 8, 12, 2, 4-bis (Ν-butyl 1-1, 5,: 19: base: Π 基) amino group) all three wells + Ϊα Ν. ''Tetraazadodecan, 1,5,8,12-anthracene [2,4-bis(Ν-'5I,丨,6_pentamethyl)) is said to be three. Soil]- 5812-tetraazadodecane, u'i gin [2,4,(ν_butyl-10-S'diyl-based (10) decaline U,ll-para [2,4-double (NH (12:===--amino-amino group, the content of the above-mentioned hindered amine-based light stabilizer is preferably 〇·5~W in the stabilizer composition for the milk-fed ointment resin of the present invention. 97110772 19 200904832 I%, more preferably 1~5 mass%. Hydrogen 1 = 咖 Λ , , , 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸 碳酸, wind magnesium oxide, magnesium carbonate, oxygen medium &# emulsified 钡, 虱 gasification Ming, Meng Ming acid, water slide salt = soil in seven m clay, iron, asbestos, antimony trioxide, etc. : content of the second filling agent 'in the vinyl chloride resin of the invention
〜30質量%。 #佳的疋5〜5°質量%、更佳的是W 又’本發明之氯乙烯系樹脂 損本發明之效果的範圍内，添加：;用齊]二=，無 安定化助劑。作以日Μ — 吊用於氣乙烯糸樹脂之 妒其ρ主 關安定化助劑，例如可列舉.1其 硫基尿素、苯胺基二硫 + . 一本基 酸、對第三丁基苯甲^胺、苯甲酸、桂皮 # , 甲 /弗石、過氯酸鹽等。 -他，本發明之氯乙烯系樹脂 無損本發明之效果的範圍内，成物中，可於 乙稀系樹脂之添加劑，例如交聯劑 抗模垢劑、表面處理劑、潤悧、防霧劑、 劑、科玆十丨々 阻从劑、螢光劑、狄徽· 杈固劑、發泡劑m 货w防檄 助劑、抗氧化劑、光安定劑等/㈣叫、顏料、加工 又’本發明之氣乙烯系樹脂用 氣乙婦系樹脂之加工方法之影 ’、'成物’可於不受 用於:輕加工、擠出成型加工:：二用延：如可較佳地應 工等。 熔融，现延法、加壓成型加 97110772 20 200904832 =月之么脂用安定劑組成物，其低溫時 〜10 C)之流動性、及於低溫狀態下長 良好，無固化或相分離。當然，於高二_^之流動性 存時，亦無固化或相分離。 ^狀恕下進行長期保 添加有本發明之氯乙稀系樹脂用安定 明之氣乙烯系樹脂組成物’例如可使用於如：：： 壁材、地板材、窗框、壁紙等建材；電線被覆:气 。車用内外裝飾材；溫室、隨道式溫室等農業用資材；伴:; 膜、盤等食品包裝材；塗料、軟管、其 貝柯，保4 雜貨/日用品；衛生材料等。尤其“本發 樹脂用安定劑組成物使用無毒之大豆油時；^ 食品/衛生用途或玩具、日用品等。 、 又 於 以下，根據實施例對本發明進行進—步說明，本發明並 不受該等實施例之限制。 χ 再者’實施例表示本發明之糊狀氯乙烯系樹 及其等之評價、以及含有該氯乙糊脂用 女疋劑組成物之氣乙烯系樹脂組成物之調製及直等之呷 rrtr表示比較氯乙婦系樹脂用安定劑組成物之調製 及含有該比較氣乙稀系樹脂用安定劑組成物 之比較乳乙細糸樹脂組成物之調製及其評價。又，實施例 中之「份」及「％」係基於質量標準者。 [實施例1〜3、比較例1 ] 根據表i所示之組成，調製本發明之糊狀氯乙稀系樹脂 用安定劑組成物及比較氯乙烯系樹脂用安m组成物。 97110772 21 200904832 針對所獲得之安定劑組成物，測定於25°C下之黏度， 將評價流動性之結果示於表1。 進而將含有上述安定劑組成物之氯乙烯系樹脂組成 ，以如下方式進行調配，而進行調製。 〈配方〉 100質量份 40質量份 3質量份 之配方的標準為質量份）1. 5 氯乙烯樹脂（聚合度7〇〇) 鄰苯二甲酸二辛酯 環氧化大豆油 安定劑組成物（表1 ··表 質量份 ;7 0 C下對°亥氯乙烯系樹脂組成物進行麼光加， 而製作〇.7咖厚之片材。將該片材置於職之^心 培箱中’而測定黑化時間（分鐘）。又，將〇7mm厚之^ 述片材相貼合’於18Gt下進行5分鐘或3()分鐘之壓製 加工’分別製作2mm厚之片材。針對所獲得之該等片材， =黃度an、’而作為壓製著色性。由於使安定劑組成 :勿中之粉末成为的比率一致’故而Ca/Zn系 sbm之合計量固定為安定劑組成物之43 2質量％。將結果 不於表1。 97110772 22 200904832 [表1 ] 實施伤 比較例 1 2 3 1 2 3 4 Ca/Zn系粉末安定劑 37. 2 37.2 37.2 37.2 37.2 33.2 42. 7 大豆油脂肪酸甲酯 56.8 28.4 14.2 0 7. 1 28.4 56.8 環氧化大豆油 0 28.4 ~42：61 56.8 49. 7 28.4 0 SBM B 6 6 6 6 10 0. 5 黏度（mPa. s/25°C) 2500 7000 23500 36300 32300 11000 1500 樹脂組成物之評價 190°C黑化時間（分鐘） 60 60 60 60 60 45 ^ 75 壓製著色（5分鐘後） 10.1 9.9 10.8 10. 6 12.4 19.4 壓製著色（30分鐘德） 94.1 88.8 89.4」 98.0 95. 8 98. 5 105. 6 於實施例1、2、3中，由於黏度為25, 〇〇〇以下，故而 可作為糊狀使用；於比較例1、2中，由於黏度超過 30, 000，而缺乏流動性，無法作為糊狀之安定劑而使用。 由上述情況可明瞭：藉由調配作為液狀成分之本發明之特 疋月a肪k曱酯，可獲得流動性優異之糊狀安定劑。又，根 據實施例2與比較例3之比較，可知，若液狀成分與本發 明相同之安定劑組成物之SBM的調配量增加，則流動性會 急遽降低，於該情況下，樹脂組成物於19(rc下之黑化時 間短，壓製著色評價亦遜於本發明。進而，根據實施例1 與=較例4之比較可明瞭：若SBM之使用量過少，則著色 «平知會降低。由該等實施例及比較例可明瞭：僅在以本發 明之特定範圍的調配量使用SM，且調配一定量之特定脂 肪酸甲酯的情況下，可獲得具有優異之流動性及著色改良 效果之糊狀氯乙烯系樹脂用安定劑組成物。 再者，丙酸f酯等低分子量化合物，於樹脂之加熱加工 97110772 23 200904832 法進行比較實驗， 以通用之環氧化大 作為 豆油 時會揮發而成為氣體，故而尤其無 糊狀安定劑組成物之液狀成分，僅 作為比較對象。 (產業上之可利用性） 本發明之氯乙烯系樹脂用安定劑組成物， 改善效果，於低瓜日车Γ , 1Λ〇^ , 糸八有咼色調 於低/皿時（一5〜10 C)具有優里 且長期保存性優異， /、 ”動性，並 經時性變化的Γ 抑制固化或相分離等 適應性優里，廿了較佳地獲得製造 、並且物性亦優異之氯乙烯系樹脂組成物。 97110772 24~30% by mass. Preferably, it is 5 to 5 % by mass, more preferably W, and the vinyl chloride resin of the present invention is added to the range of the effects of the present invention, and is added: For the purpose of Μ 用于 用于 气 气 ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ ρ Methylamine, benzoic acid, cinnamon #, A/Furstone, perchlorate, etc. - In the range in which the vinyl chloride resin of the present invention does not impair the effects of the present invention, an additive which can be used in an ethylene resin, such as a crosslinking agent anti-fouling agent, a surface treatment agent, moisturizing, anti-fogging Agent, agent, Koz Tenshi obstruction agent, fluorescent agent, Dihui · tamping agent, foaming agent m cargo w anti-mite auxiliaries, antioxidants, light stabilizers, etc. / (4) called, pigment, processing and 'The shadow of the processing method of the gas-based resin for the ethylene-based resin of the present invention', 'the product' can be used for: light processing, extrusion molding processing: two-use extension: as preferably Work and so on. Melting, rolling method, pressure forming and adding 97110772 20 200904832 = Moon's grease stabilizer composition, its low temperature at ~10 C), and good at low temperature, no curing or phase separation. Of course, there is no solidification or phase separation in the presence of high fluidity. For the long-term maintenance, the ethylene-based resin composition of the vinylidene-based resin of the present invention can be used for, for example,::: wall materials, flooring materials, window frames, wallpapers, and the like; :gas. Interior and exterior decorative materials for vehicles; agricultural materials for greenhouses, turf greenhouses, etc.; with: packaging materials for membranes, plates, etc.; coatings, hoses, bekeke, Bao 4 groceries/commodities; sanitary materials. In particular, "when the non-toxic soybean oil is used as the stabilizer composition for the present invention; ^ food/hygienic use or toys, daily necessities, etc., and the following is a description of the present invention based on the examples, and the present invention is not subject to the Further, the examples show the preparation of the paste-like vinyl chloride tree of the present invention and the like, and the preparation of the ethylene-based resin composition containing the composition of the female tanning agent for the chloroacetin. And 直rrtr indicate the preparation of the stabilizer composition for the vinyl chloride resin and the preparation and evaluation of the comparative composition of the styrene resin containing the stabilizer composition for the comparative ethylene resin. The "parts" and "%" in the examples are based on quality standards. [Examples 1 to 3, Comparative Example 1] The stabilizer composition for the paste-like vinyl chloride resin of the present invention and the amper composition for the comparative vinyl chloride resin were prepared according to the composition shown in Table i. 97110772 21 200904832 The viscosity at 25 ° C was measured for the stabilizer composition obtained, and the results of evaluating the fluidity are shown in Table 1. Further, the composition of the vinyl chloride resin containing the stabilizer composition described above was prepared by blending as follows. <Recipe> 100 parts by mass of 40 parts by mass of the formulation of 3 parts by mass is in parts by mass) 1. 5 Vinyl chloride resin (degree of polymerization 7 〇〇) Dioctyl phthalate epoxidized soybean oil stabilizer composition (Table 1 ··表质量份; 70 ° C under the ° hexyl chloride resin composition of the light to add, and the production of 〇.7 coffee thick sheet. The sheet is placed in the heart of the box The blackening time (minutes) was measured, and the sheet of 7 mm thick was bonded to each other for 5 minutes or 3 (minutes) at 18 Gt to produce a 2 mm thick sheet. The sheets are = yellowness an, 'as the coloring property of the press. Since the stabilizer composition is the same as the ratio of the powder in the powder, the total amount of the Ca/Zn system sbm is fixed as the stabilizer composition. 2% by mass. The results are not shown in Table 1. 97110772 22 200904832 [Table 1] Injury Comparative Example 1 2 3 1 2 3 4 Ca/Zn-based powder stabilizer 3. 2 37.2 37.2 37.2 37.2 33.2 42. 7 Soybean oil fatty acid Methyl ester 56.8 28.4 14.2 0 7. 1 28.4 56.8 Epoxidized soybean oil 0 28.4 ~ 42:61 56.8 49. 7 28.4 0 SBM B 6 6 6 6 10 0. 5 Viscosity (mPa. s/25°C) 2500 7000 23500 36300 32300 11000 1500 Evaluation of resin composition 190 ° C blackening time (minutes) 60 60 60 60 60 45 ^ 75 Pressing coloring ( After 5 minutes) 10.1 9.9 10.8 10. 6 12.4 19.4 Pressing and coloring (30 minutes) 94.1 88.8 89.4" 98.0 95. 8 98. 5 105. 6 In Examples 1, 2 and 3, since the viscosity is 25, 〇〇 In the following, it can be used as a paste; in Comparative Examples 1 and 2, since the viscosity exceeds 30,000, it lacks fluidity and cannot be used as a paste stabilizer. From the above, it is clear that: The liquid component of the present invention is a paste-like stabilizer which is excellent in fluidity. Further, according to the comparison between Example 2 and Comparative Example 3, it is understood that the liquid component is the same as the present invention. When the amount of the SBM of the stabilizer composition is increased, the fluidity is drastically lowered. In this case, the blackening time of the resin composition at 19 (rc) is short, and the evaluation of the coloring of the press is also inferior to the present invention. Further, The comparison between Example 1 and = Comparative Example 4 is clear: if SBM is made If the amount is too small, the coloring will be lowered. It is clear from the examples and the comparative examples that only when SM is used in a specific range of the present invention and a certain amount of a specific fatty acid methyl ester is formulated, it is obtained. A stabilizer composition for a paste-like vinyl chloride resin having excellent fluidity and color improving effect. Further, a low molecular weight compound such as propionic acid f-ester is subjected to a comparative experiment in a heat treatment of a resin of 97110772 23 200904832, and a general epoxidation is used as a soybean oil to volatilize and become a gas, so that a paste-free stabilizer composition is particularly preferable. The liquid component is only used as a comparison object. (Industrial Applicability) The stabilizer composition for the vinyl chloride resin of the present invention has an effect of improving the effect of the low guay, the Λ〇 , , , 糸 咼 于 于 一 一 一 一 一 一 一 一 一 一 一 一 一 一C) 适应 氯 具有 具有 Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ Γ 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯 氯Composition. 97110772 24