200903561 九、發明說明： 【相關申請案之交互參照】 本申請案係基於並主張日本專利申妹 優先權，此優先權案申請於2〇〇7年4 g 26 ^ 藉由參考文獻方式合併於此。平4月26日，其㈣揭露内容 【發明所屬之技術領域】 種具有優異啟動特 性的ifi祕關於-錢級，尤其係關於. ί 【先前技術】 冷陰極螢光燈、外部電極# μ 機、電腦轉讀晶顯轉摘料被制仙於電視 透光管中封入采與稀有氣;玻】部附近，於此 置的電極被設置在端！;紐技光管内所設 f m述冷陰極螢光燈與外部ί二螢 加通過電極時，存在於透亦其 i螢先燈中，虽電壓被施 _的稀有氣體被電極所吸;並弓 燈與外部雜顯;會發出料線。冷陰極螢光 的螢光。在此種螢“中，光體所發出 法立即點亮螢光燈。於電子發射’因而無 係藉由下列方式而達成=改，暗啟動特性的報告，其 合物的放射性材料施加在玻璃數之例如绝化 次電子，而在啟動時促使絶引起二 疋進放电的發生C曰本公開專利公報第 200903561 2001-15065 號）。 其，的報告包含：藉由使用放射性材料延長用於 藉由將驗土金料等的麵▲與稀 土金屬4 4的乳化物結合而製備（曰本公 2001-332212號）·，以及一種螢光燈，為τ防μ /報弟 的绝由於放電而附著於螢:體薄膜因::: 本發明之目的為提供—種具有優異黑暗啟動特性的榮光燈。 【發明内容】 本案發明人檢驗過許纽射性， 材料。因此，本案發明人發現：藉由使用離子結晶物質 ΪΐΪίΐ暗啟動特性的螢光燈。本案發明人最後基於此知識而 亦即’本發明係關於一種螢光燈，包含：透光管，於 u稀有氣體；螢光_，設置在透光管的内表面上二及二 或Ϊ極；子結晶物質所形成的放射性材料被設置在電 本發明之螢光燈具有優異的黑暗啟動特性。 【實施方式】 甘由光燈係—種包含下列元件的螢光燈：透光管，於 稀ϊίΐ;螢光體層，設置在透光管的内表面上： 置在電極離子結晶純卿成的放雜材料被設 置在％拉表面上或電極的附近。 燈的ίίί破ίίίί的ί綺可紐时朝財㈣之螢光 官可由任何材料所製成，只要此透光管係由 了見“柄的_所製請可。吾人可使用任何形狀的透光 200903561 ί型mi圓形斷面形狀或橢81形斷面形狀的直管型、彎曲型、 在於r透光管的稀有氣體會被存 料產生碰撞，此侧將作說明，而稀有 迻尤g之稀有虱體的罝可例如為30至100 torr。 ，人透光管絲經由輝級電而 所形成之二域子而引發，進而產生手' = 白ίί汽Ϊ點亮螢綱，封人透光f之汞的量可為例如！ ^光體層被設置在上述透光管_表面上。 =但較佳係即使在此種情況下織可;:== 的範例包含γ2〇3: Eu、γν〇4: Eu、L p〇 、，化。此種螢光體 ”、鳴。 二M^MPO抓.Eu。再者’螢光體層 ; 的紫外線所激發，並且含有用以發出位於 之可見光的適當螢光體组合，藉以吾人$ 色區帶 色彩表現上極域異的Μ。料靜趟層可發射在 30·。 層的厚度可例如為15至 上述螢光燈設有一對電極，以作為引發 =了引起從上述汞原子發射紫外線。 可被使用作為此種電極。前者的範例包含冷降!極兩者 彼此相對的方式將鎳、！目料所形成 中以開口 部之兩端部騎近。對於外部型電極 =U在透光管内 ，鋁、鐵及鎳等等的合 200903561 晶物 的結晶。離子結晶物質的範例為已= 含f 時所形成 質，其包含：無機酸鹽，例如硫酸鹽、子的離，、结晶物 化氫嫩鹽、硝酸鹽及 麵:b風例;臭 團所組成的陰離子為:ί 離 "W〇" ίί IS金屬離，二的團屬這ί : 化物i金ϊίί^4呈離子、^曰物質的範例包含金屬氧 ;^riv^ 鹽等等。再者=以：飾，例如羧酸鈣鹽及驗鎂 氧化U 了列舉.乳蝴、氧化鎂、氧化鋇、氧化鑭、氫 ，了從此種離子結日日日物質形成放射性材料 ，加液施加至透光管靠近 用於列可被提供作為塗膜。作為 料量可不招風乾燥塗膜。所使用的放射性材 積的方法，將放射極1mg。吾人亦可以例如熱倾及氣相沉 表面的内表面Γ。 置在電極表面上或在透光管靠近電極 舉例而言’吾人可藉由下财法製造此種螢光燈。製備含有 200903561 内Ϊ且以例如塗佈、浸潰及噴塗的方法將此液體施 忿材料層。在此之後，將連 j ^ 汞封入。 寺寺*于兩缒。在此之後，將稀有氣體與 概略極 =冷中極勞光燈的範例。卻之 所製造之玻赌22的兩端加以密^+玻;將^玻， 從1· 5至6· 0刪的範圍，較佳係^玻离吕22的外位可例如係 管22的内壁表面上，營光體層係24每的範圍。在玻璃 ?設置。在玻璃管22的内部“ 玻璃管的全， 塵力的數十分之―，並且將指定量^，降，至大氣 在玻璃管22的兩端附近，以開體及水導入此空間。 由鎳'銦等等所形成之具有〇 7 〇 f此相對的方式，設有各自 厚度的杯狀電極27。將導線29各自;^ ^以及〇. 05至1·— 焊接至電極27的底部，而將直另—二:歹3式加以設置：將-端 璃管22的外部。 碥牙過玻璃珠23並且拉出玻 含有上述放射性材料的透光瞢+ 玻璃管22靠近兩電極的内表面上。^ ^射層22a、22b被設置在 放電期間不容易受到稀有教俨雜。因為電子發射層22a、22b在 子發射緣、咖設射，所以將透光管電 料的電子發射層亦被設置在杯狀材料使用量範圍。相同材 層可被設置在杯狀電極的外側=彻的表面上。這些電子發射 射層27a、27b在放電期間不容易至:然而’因為電極電子發 層^，設置在杯狀電極-表=:¾ 200903561 層27a—、27b的厚度係例如每電極不超過㈣❸匕種放射性材料使 用量範圍。對於這些電子發射層而言，僅可設置透光管電子發射 層與電極電子發射層其中之-，僅可設置透光管電子發射層既、 22b其中之-’而同樣地僅可設置電極電子發射層27a、27b其中 ---- 圖2(a)與圖2(b)顯示本發明之螢光燈用於外部電極型 燈的範例。圖2(a)以及® 2(b)分職科部電極型螢光燈3 綱見圖以及概略，關、。此縣燈具有觸树璃所製造的玻 璃官32，此玻璃官的兩端被加以密封。玻璃管32的外徑可 從1. 5至6. 0麵的範圍，較佳係從L 5至5. 〇麵的範圍。」玻璃 官32的内壁表面上’螢光體層33實質上係 在玻璃管32的内部空間中，内部壓力被降低至 ’並且紋量的稀有氣體及汞被導人此空間。外部 置在玻璃管32之兩末端部的各自外表面上。作= 铭、鎳等等的金屬薄片接合至玻璃管32的外表面f = J ，’俾能覆蓋玻璃管32的整個末端。外部電極之 f 35mm °未顯示的導線被連接至外ί電極； 使電壓可經由導線施加至電極。 丨电征Μ 發射，含有上述放射性材料的電子 子發射層所騎的金屬放電期間從電 原珊光體層的附著而產生自勞; 少，所以較佳係以離螢光體層之端部的距離咸 管32 _表社。電子魏層鱗❹彳之玻璃 的此種放射性材料使用量範圍。 /、马母包極不超過lmg 在上述冷陰極f光燈與外部f 質所形成的放射性材料層被設置在電極=“=;晶: 200903561 0 壓之後’立即以二:欠電子引發輝光放電並且在 〇. 5秒的短時間内點亮螢光燈。 示範實施例 技術於示範實施例作更詳細的說明。細，本發明的 技術乾圍並不被這些示範實施例所限制。 示範實施例1 _ 3下製造圖1所示之冷陰極螢光燈。製備含有螢光 右=體’而_將此液體施加至透光管的内表面，此玻璃管係由呈 ϊ液厚度1卿玻顧製造，並且乾燥所‘ 將夺]所9·:八有汕咖厚度的螢光體層。在此之後，把藉由 =力r^1；杯狀電極的内表面，此電極係由具有in 的底所製造’將縣6連騎的導線連接至此電極 ’而製備電子發射層，俾能使離子 端氣、氖氣及汞封入，以以： 支數製造25支此種冷陰極螢光如可在吻内ί亮之 測試。 丁知耵層亚且同樣地貫施點亮 示範實施例2 燈。圖2(b)所社_極型榮光 上此玻璃官係由具有4. 0咖口徑及〇. 5mm厚度的卿^ 11 200903561 所製造。在此之後’把藉由將表1所示之離子結晶物質分散在水、 乙醇或其混合液中而製備的施加液施加至玻璃管的内表面，以 ^ l〇〇°C乾燥此施力^液，而製備電子發射層。在此之後，密封玻璃 苢的兩Μ，並且將氩氣、氖氣及汞封入，藉以製造外部電極型 光燈。 表1顯示製造25支此種外部電極型螢光燈而可在〇. 5秒内點 亮之支數的結果。 … 作為比較範例’以如同示範實施例2之相同方式製造外 極，螢光燈，其差異在於沒有設置電子發，並且 點亮測試。 、 表1 離子結晶物質 ---- Na.2S〇4 K2SO4 ------- MgS〇4 CaS〇4 BaS〇4 了 V η、 示車&貫施例1 20 25 ------ 17 18 15 6 ----___ 4 示範實施例2 — 「23 「24 ---— 20 16 16 【圖式簡單說明】 ’此勞光燈為本發明之螢 圖1係冷陰極螢光燈的概略剖 光燈的應用範例；及 匈圖 剖關，======圖及概略 【主要元件符號說明】 20開口 21冷陰極螢光燈 22 玻璃透光管 22a透光管電子發射層 22b透光管電子發射層 12 200903561 23玻璃珠 24螢光體層 25内部空間 27杯狀電極 27a電極電子發射層 27b電極電子發射層 29導線 31外部電極型螢光燈 32玻璃透光管 32a電子發射層 33螢光體層 34 外部電極200903561 IX. Invention Description: [Reciprocal Reference of Related Applications] This application is based on and claims the priority of Japanese patent applicants. This priority application was filed in 2〇〇7 years by 4 g 26 ^ by reference. this. On April 26th, the (4) disclosure content [the technical field to which the invention belongs] is a kind of ifi secret with excellent starting characteristics, especially related to . ί [Prior Art] Cold cathode fluorescent lamp, external electrode # μ machine The computer is transferred to the crystal display and the material is sealed in the TV light pipe and sealed in the rare gas; near the glass part, the electrode placed here is set at the end! In the Newtech light pipe, the fm is described as the cold cathode fluorescent lamp and the external ί 二 加 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过 通过The lamp is mixed with the outside; a feed line is issued. Fluorescence of cold cathode fluorescent light. In this type of firefly, the method of emitting light immediately illuminates the fluorescent lamp. In the case of electron emission, it is not achieved by the following means, the dark start characteristic is reported, and the radioactive material of the compound is applied to the glass. For example, the annihilation of the sub-electron, and at the start-up, causes the occurrence of the occurrence of the two-injection discharge. C. The publication of the Japanese Patent Publication No. 200003561 2001-15065). The report of the present invention includes: extending the use of the radioactive material for borrowing It is prepared by combining the surface ▲ of the earth-receiving gold material and the emulsion of the rare earth metal 4 4 (曰本公 2001-332212), and a fluorescent lamp, which is a discharge of the τ-anti-μ Attachment to Fluorescent: Body Film::: The object of the present invention is to provide a glory lamp having excellent dark start characteristics. [Invention] The inventor of the present invention has examined the properties and materials. Therefore, the inventor of the present invention found that: The fluorescent lamp of the present invention is based on the use of an ionic crystal material, and the present invention is based on the knowledge that the present invention relates to a fluorescent lamp comprising: a light-transmitting tube, a rare gas in u; , disposed on the inner surface of the light-transmitting tube, two or two or a drain; the radioactive material formed by the sub-crystalline material is disposed on the fluorescent lamp of the present invention to have excellent dark start characteristics. [Embodiment] A fluorescent lamp comprising the following components: a light-transmissive tube, in a thin layer; a phosphor layer disposed on the inner surface of the light-transmitting tube: a dopant material placed on the electrode ion crystals is disposed on the %-drawing surface Or the vicinity of the electrode. The light of the light can be made of any material, as long as the light pipe is made of "handle". We can use any shape of light-transmissive 200903561 ί-type mi circular cross-sectional shape or elliptical 81-section shape of the straight tube type, curved type, the rare gas in the r-transparent tube will be collided by the storage, this side will For illustration, the rare 虱 of the rare 虱 can be, for example, 30 to 100 torr. The human light-transmitting tube filament is triggered by the two-domain formed by the glow electric power, and the hand is generated by the white light, and the amount of mercury that seals the human light can be, for example,! The photo body layer is disposed on the surface of the light-transmitting tube. = but preferably even if it is woven in this case; the example of === contains γ2〇3: Eu, γν〇4: Eu, L p〇 , and . This kind of phosphor", Ming. Two M^MPO catches.Eu. In addition, the 'fluorescent layer; the ultraviolet light is excited, and contains the appropriate phosphor combination to emit visible light, so that the US color zone The color is expressed in a polar region. The static layer can be emitted at 30. The thickness of the layer can be, for example, 15 to the above-mentioned fluorescent lamp, and a pair of electrodes are provided as the trigger = causing ultraviolet rays to be emitted from the above mercury atoms. It is used as such an electrode. The former example includes a cold drop! The poles are placed opposite each other in such a way that the nickel and the target are formed by the two ends of the opening. For the external type electrode = U is in the light transmission tube Crystallization of a mixture of aluminum, iron, nickel, etc. 200903561. An example of an ionic crystalline material is a material that has been formed when f is contained, and contains: a mineral acid salt such as sulfate, a sulphate, a crystalline hydrogen hydride. Tender salt, nitrate and noodles: b wind example; the anion composed of odor group is: ί away from "W〇" ίί IS metal away, the second group belongs to this ί : ii金ϊ ίί^4 is ion, ^ Examples of bismuth substances include metal oxygen; ^riv^ salt, etc. Again = to: Decorations, such as calcium carboxylate salts and magnesium oxides, are listed. Milk, magnesium oxide, strontium oxide, strontium oxide, hydrogen, and radioactive materials are formed from the daytime material of this ion, and the liquid is applied to the light-transmissive tube. The column can be provided as a coating film. As a material amount, the coating film can be dried without drying. The method of using the radioactive volume is 1 mg of the emitter. For example, we can also thermally pour the inner surface of the surface of the vapor deposition surface. On the surface of the electrode or in the vicinity of the electrode of the light-transmitting tube, for example, we can manufacture such a fluorescent lamp by the following method. The liquid is prepared by the method of coating, impregnating and spraying, for example, containing 200903561.忿Material layer. After that, it will be sealed with j ^ mercury. Temple Temple * in two 缒. After that, the rare gas and the rough pole = cold medium extreme light lamp example. But the glass gambling 22 The two ends are densely combined with + glass; the range of the glass is from 1. 5 to 6.0, preferably the outer position of the glass 22 can be, for example, the inner wall surface of the tube 22, the camping layer 24 per range. Set in the glass. Inside the glass tube 22 "full of glass tubes Dust force several tenths -, ^ and the prescribed amount, down to the atmosphere in the vicinity of both ends of the glass tube 22 to the body and open water into the space. A cup electrode 27 having a thickness of 〇 7 〇 f formed by nickel 'indium or the like is provided. Each of the wires 29; ^^ and 〇. 05 to 1·- is welded to the bottom of the electrode 27, and the straight-to-two: 歹3 type is set: the outside of the --tube tube 22. The teeth pass through the glass beads 23 and are pulled out of the glass. The light-transmissive enamel + glass tube 22 containing the above-mentioned radioactive material is placed on the inner surface of the two electrodes. ^ The shot layers 22a, 22b are set to be less susceptible to rare teaching during discharge. Since the electron-emitting layers 22a, 22b are disposed at the edge of the emitter, the electron-emitting layer of the light-transmitting tube electrode is also disposed in the range of the amount of the cup-shaped material used. The same layer of material can be placed on the outside of the cup electrode = the surface. These electron emission layers 27a, 27b are not easily accessible during discharge: however, 'because the electrode electron emission layer is disposed on the cup electrode-table=:3⁄4 200903561, the thickness of the layer 27a-, 27b is, for example, not more than (four) per electrode. A range of radioactive materials used. For these electron-emitting layers, only the light-transmitting tube electron-emitting layer and the electrode-electron-emitting layer can be disposed, and only the light-transmitting tube electron-emitting layer can be provided, and 22b of the same can be provided. Emissive layers 27a, 27b - Figure 2 (a) and Figure 2 (b) show an example of a fluorescent lamp of the present invention for an external electrode type lamp. Figure 2 (a) and ® 2 (b) The divisional electrode type fluorescent lamp 3 is shown in the figure and is schematic, off. The county lamp has a glass door 32 made of glass, and the ends of the glass are sealed. The outer diameter of the glass tube 32 may range from 1.5 to 6.0, preferably from the range of L 5 to 5. On the inner wall surface of the glass member 32, the phosphor layer 33 is substantially in the inner space of the glass tube 32, the internal pressure is lowered to 'and the amount of rare gas and mercury are guided into the space. The outer portions are placed on the respective outer surfaces of both end portions of the glass tube 32. A metal foil such as imprint, nickel, or the like is bonded to the outer surface f = J of the glass tube 32, and the entire end of the glass tube 32 can be covered. The outer electrode f 35 mm ° unshown wire is connected to the outer electrode; the voltage can be applied to the electrode via the wire.丨 丨 Μ 发射 发射 , , , , , , , , , 发射 发射 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属 金属Salt tube 32 _ Table Society. The range of such radioactive materials used in the glass of the electronic layer. /, the mother-in-law package does not exceed lmg. The layer of radioactive material formed by the above-mentioned cold cathode f-light and external material is placed at the electrode = "=; crystal: 200903561 0 pressure" immediately after two: under-electron induced glow discharge And the fluorescent lamp is lit for a short time of 5 seconds. The exemplary embodiment techniques are explained in more detail in the exemplary embodiments. The technical practice of the present invention is not limited by these exemplary embodiments. Example 1 _ 3, the cold cathode fluorescent lamp shown in Fig. 1 was produced. The preparation contained the fluorescent right = body ' and the liquid was applied to the inner surface of the light-transmitting tube. The glass is manufactured, and the drying station 'will be won't be the 9:: the phosphor layer with the thickness of the coffee. After that, by the = force r ^ 1; the inner surface of the cup electrode, this electrode has The bottom of the in-made 'connects the wire of the county 6-seater to the electrode' to prepare an electron-emitting layer, which can enclose the ion-end gas, helium gas and mercury to make 25 such cold cathode fluorescent lamps with: Such as the test within the kiss. Ding Zhiyi layer and the same implementation of lighting demonstration 2 lights. Figure 2 (b) of the company _ polar glory on the glass official system is made of 4. 0 coffee caliber and 〇. 5mm thickness of the Qing ^ 11 200903561. After that, 'by the table 1 An application liquid prepared by dispersing an ionic crystalline substance in water, ethanol or a mixture thereof is applied to the inner surface of the glass tube, and the application liquid is dried at a temperature of 〇〇 ° C to prepare an electron emission layer. Thereafter, two turns of the glass crucible were sealed, and argon gas, helium gas, and mercury were sealed to prepare an external electrode type light lamp. Table 1 shows that 25 such external electrode type fluorescent lamps were manufactured and can be used within 5 seconds. The result of the count of lighting. As a comparative example, an external pole, a fluorescent lamp, was fabricated in the same manner as in Exemplary Embodiment 2, except that no electron emission was set and the lighting test was performed. Table 1 Ionic Crystalline Substance - --- Na.2S〇4 K2SO4 ------- MgS〇4 CaS〇4 BaS〇4 V η, Show & Example 1 20 25 ------ 17 18 15 6 - ---___ 4 Demonstration Example 2 - "23 "24 --- 20 16 16 [Simple description of the diagram] 'This light lamp is the 1st cold cathode firefly of the present invention Example of the application of the general light-cut lamp of the lamp; and the cut-off of the Hungarian map, ======Fig. and the outline [Description of the main components] 20 openings 21 cold cathode fluorescent lamp 22 glass transparent tube 22a light-transmitting tube electron emission Layer 22b light-transmitting tube electron-emitting layer 12 200903561 23 glass beads 24 phosphor layer 25 internal space 27 cup electrode 27a electrode electron-emitting layer 27b electrode electron-emitting layer 29 wire 31 external electrode type fluorescent lamp 32 glass light-transmitting tube 32a electron Emissive layer 33 phosphor layer 34 external electrode