TW200848507A - Liquid detergent composition for clothing - Google Patents

Abstract

The present invention provides a liquid detergent composition for clothing capable of preventing clothing from stiffness and recontamination while the clothing is washed. The liquid detergent composition containing: (A) nonionic surfactant, 10 to 50 mass%, (B) long chain tertiary amine and/or cationic surfactant, 0.1 to 10 mass%, and (C) a water soluble polymer having (c1) alkylene terephthalate unit and/or alkylene isophthalate unit and (c2) oxyalkylene unit and/or polyoxyalkylene unit, 0.01 to 10 mass%.

Description

200848507 • IX. OBJECTS OF THE INVENTION: 1. Field of the Invention The present invention relates to a liquid detergent composition and a product which can be used for cleaning clothes, and the like. . [Prior Art] In the past, in addition to cleaning and smudging, there is a proposal for a fabric cleaning agent (4) which is also intended to improve softness and the like. These softeners or surfactants contained in the "liquid detergent composition for soft clothes, in the detergent composition" are often attached to the laundry with the stains once removed from the laundry. Therefore, there is a variety of techniques for not only having a cleaning effect but also imparting a softening effect and preventing recontamination. For example, in order to maintain texture, it is investigated to contain a specific nonionic surfactant and In the detergent composition of the polyoxyl compound (Patent Document 2), and the effect of preventing re-contamination, the detergent composition containing a water-soluble polymer (Patent Documents 3 and 4) is examined. [Patent Document 1] JP-A-2002-249799 (Patent Document 3) JP-A-2006-63304 (Patent Document 4) 〇 2 — 18〇〇 92 公 [Summary of the invention] (Problems to be solved by the invention) ... and 'Even when using the technique as described above, the following problems may occur. 319968 5 200848507 In recent years, in the washing machine of In order to increase the size of the water and improve the water-saving effect, the large-capacity washing machine represented by the drum-type washing machine is gradually becoming more and more popular. Such a large-capacity washing machine is gradually becoming popular, and the fabrics can be aggregated after being smashed. In addition, the bath ratio is lowered due to the summary of washing or water-saving effects, and there is a disadvantage that the problem of fabric stiffness and re-contamination after washing is likely to occur. The material has become more serious with the increase of the polyester material or the blend with the cotton. In the detergent composition of the prior art, it is as large as the drum type washing machine. When the capacity washing machine cleans the fabric made of various fiber materials, it is difficult to avoid the above problems. In view of the above circumstances, the object of the present invention is to provide: especially in the texture of the laundry after washing, especially The composition of the night body detergent having excellent effect of suppressing the stiffness and preventing the effect of re-contamination. (Method for solving the problem)

As a result of intensive studies conducted by the inventors of the present invention, it has been found that the above problems can be solved by the use of the washing of the clothes and the preparation of the clothes, and the present invention can be achieved. That is, it contains: The present invention relates to a liquid detergent composition for clothing, (A) a nonionic surfactant, 1 to 5 % by mass; () a long chain, and, and an amine and/or a salt thereof And/or a cationic surfactant of a quaternary ammonium salt, 0.1 to 10% by mass; and (6) having an alkylene phthalate unit and/or an isophthalic acid acetal 319968 6 200848507 unit with oxygen A water-soluble polymer of an oxyalkylene unit and/or a polyoxyalkylene unit, 〇·〇1 to 1% by mass. Further, in the present invention, (C) is a water-soluble polymer represented by the following general formula (1) and/or (2): A-〇-(Rl〇)y- 〇Ο-R2〇_ Ο Ο 'C-{〇y&;-〇~ (R1〇)y_

B

X

(wherein, A and B are each independently a hydrogen atom or a methyl group, and Rl & r2 is a number of carbonization groups of 2 to 4, the number of yy to the number of cuts) A — 〇—(Rl〇) y·

Ο II C 〇 II C —〇 —R2〇

〇 1丨丨ΑΛ.X

〇II C—O —(R1〇)y—B (wherein A and B are independently chlorine or methyl, r1 and r2 are carbon 2 to 4, X is 〇 to 1 The number of 〇, 乂 is the number of i to 1〇〇). Further, the present invention is more preferably a ([)) sulfonium diacid having a % by weight of 〇〇1 to 1〇ff, and a hydrocarbon having 4 to 12 carbon atoms copolymerizable with the cis-butane diacid a copolymer of a limb and/or a copolymer of maleic acid and acrylic acid, and/or a salt thereof. (Effect of the Invention) By using the liquid detergent composition of the present invention, even in the case of a low bath ratio typified by a wave type washing machine, for example, the amount of water is 5 to 15 319 968 7 200848507 with respect to the cloth. When the clothing is washed, in addition to the detergency and the like, the performance required for the liquid detergent composition for clothing can be maintained, and the texture of the clothing such as wood can be imparted, and the object to be washed can be prevented. Pollution. [Embodiment] • Liquid detergent button The liquid detergent composition of the present invention may contain the components (A), (B) and (C) described below, and may be blended with the component (8) and/or Others get it. In addition, the effect of preventing the re-contamination of the liquid detergent composition for clothing of the present invention is further enhanced by the effect of the phase (9) and the phase of the component (6). Hereinafter, each component used in the present invention will be described. IA) ingredients

The component (A) in this month is a nonionic surfactant, and the liquid detergent composition for clothing is mainly formulated to impart a washing function. The nonionic surfactant used in the present invention is not particularly limited as long as it is used in the field of the detergent composition, and may be used singly or in combination of two kinds. the above. There are polyoxyalkylene type nonionics, examples of such nonionic surfactants, surfactants, and the like. The nonionic surfactant used in the present invention is particularly preferably used, for example, in the following formula (3). [(EO)ffi(p〇)n]-r4 (3) [wherein, R is a linear or branched alkyl or alkenyl group; is -〇一戋{〇〇-; R4 is hydrogen Atom or carbon number i to 3 yard base; EQ means epoxy B 319968 8 200848507 alkane, POj shows epoxy propylene 9; m, n respectively represent the molar number of the average addition]. When -Υ- is -〇_ in the general formula (3), (the magic component is an alcohol alkoxy compound (al(3)hoi alk0Xylate). In this case, the RS is from 1 to 22 carbon atoms. The carbon number is preferably from 1 to 2, and more preferably from 1 to a, and may be linear or branched, and may have an unsaturated bond, and R4 is preferably a hydrogen atom. § Y is C00-日守' (A) is a fatty acid ester type nonionic surfactant. In this case, R3 is a carbon number of 9 to 21, and preferably has a carbon number of u to 21. Straight or branched, and may also have an unsaturated bond. R4 at this time is preferably an alkyl group of 匕 to C3. E0 and P0 may also be added separately or in combination, and E 〇 and P0 groups. It may also be added as a block. Further, the order of addition of the ribs and p〇 may be as shown in the above formula (3), or may be the opposite. When the mixture is added to E0 and P0, the E0 group The mass ratio of the total amount in the peroxyalkylene group is preferably 60% by mass or more. The average addition molar number m of E0 is an integer of 3 to 2 (), and preferably 5 to 18, and 5 to 15 is better. The average addition of the p〇 is n. It is preferable to use 〇 to 3 to make it to 3 or less. By setting m to 20 or less, it is possible to suppress a decrease in the cleaning function due to the HLB value becoming too high, which is advantageous for washing sebum; It is possible to prevent deterioration of odor. By setting n to 6 or less, it is possible to suppress a decrease in the stability of the detergent composition at a high temperature. The addition of the molar distribution of E0 or P0 is based on the production of nonionic interfacial activity. The reaction method at the time of the agent (A) is not particularly limited. 319968 9 200848507 • ^ For example, when a general catalyst such as sodium hydroxide or potassium hydroxide is used, ethylene oxide or propylene oxide is added. In the case of the media, the addition of the Moir number distribution system is broader = • 6-; +5038 Al3+ . Ga3+ In3^;; ^ .^ H, La3+, ... and other metal ions of the oxide material specific burning = base ^ Catalyst, and the addition of epoxy Ethylene or Epoxy (4) tends to form a narrow distribution in the hydrophobic base material 4'." W: The specific example of the component (A) (hereinafter referred to as "CP" (P is Integer) means T, and the number of the table is not the meaning of p), for example, for the (6) company's trade name Saf〇l23 (C12/Cl3 mix) a synthetic alcohol obtained by a partial oxidation process, or a trade name (3) - (1) (C12/C14 mixture) manufactured by p&G, and a trade name c〇_m〇 (cl2 八i4 mixture) ), a natural alcohol such as the product name ((1)/(1) mixture) manufactured by Ec〇green 01eo Chemical, which is a 15 or 12 molar equivalent of epoxy enamel; and the name of the product made by New Japan Physicochemical Co., Ltd. C〇n〇1(ci2) and other natural alcohols are added to 9 moles of earthworms, and C13. i is obtained by subjecting C12 olefins obtained by trimerization of butyl women to carbonyl oxidation. Ear, addition 7 Moore (manufactured by BASF Corporation: trade name Lutensol Τ 07) or 1 molar molar equivalent of ethylene oxide (manufactured by BASF Corporation: trade name Lutens〇1 τ〇1〇); for lauric acid A cool addition of 15 molar equivalents of ethylene oxide; a C12 alcohol 1 mole obtained by subjecting hexanol to Guerbet reaction, adding 10 moles of epoxy B Alkane-derived ((3) rib EA company: trade name ISOFOL12-10EO); for C12 to C14 secondary alcohol, addition of 15 molar equivalents of ethylene oxide (manufactured by Sakamoto Co., Ltd.: quotient 31996810 200 848 507 embankment group name of catalyst, and the amount of propylene oxide added together by SOFTANOL150); for use of methyl laurate to 15 mole equivalents of ethylene oxide and the like when 3 mole. " In the above examples, in terms of the superiority of the detergency, the addition of 2 or 15 molar equivalents of ethylene oxide to ο or alcohol, or the addition of c12 or C12/14 natural alcohol纟 9, 125 Ge 15 Mo Er equivalent of epoxy Ethylene, for lauric acid " to add 15 moles of ethylene oxide is better. Moreover, the superiority of the appearance stability of the liquid detergent composition at a low temperature is obtained by adding 7 molar equivalents of ethylene bromide to a C13 branched type synthetic alcohol (manufactured by BASF Corporation: Product Name Lutensc) 1 (B) Component The component (8) of the present invention is a long-chain tertiary amine and/or a salt thereof, and/or a quaternary ammonium salt cationic surfactant, which is formulated in a detergent composition (8) The cloth which is washed by using the detergent composition can prevent or reduce the occurrence of stiffness. Here, the term "long-chain tertiary amine" means the following (4). The long-chain tertiary amine represented by the following formula (4) is suitable for use as a knife (B). R6 R7 In the above formula (4), the hydrocarbon group of the 'R-blocking number γ to 27 (wherein the hindrance does not include the substituent and the carbon number in the linking group) may be a straight chain or a bond, and may be saturated or It is unsaturated and can also be a substituent. In addition, R5 can also be 319968 11 200848507 疋Μ n K~ is a carbon 溆 5 5 々 straight or branched alkyl; W is a leg C 〇 〇〇 C - K1 〇, mountain to 23 hydrocarbon group, And 7 to 21 as 'carbon number', 1 soil, K is the stone inverse u-base, and 12 to 20 is better than H1G to 23 or not. The linear or branched chain may be a saturated R-based hydrocarbon group having 1 to 25 carbon atoms. Into the right ΓΓ straight chain or branch, can be saturated or not silk, and can also be 3 with a substituent. X n may be a linking group such as a chain: or an ether group. In the pot, a linear or branched alkyl group having a number of 1 to 4 and a straight or branched hydroxyalkyl group having an anisotropy of 17 to 4 is suitable. R series rabbit number 1 to 4 words 4 gold ~ +, rb # green 18 # A chain or branched red base, carbon number 1 to 4 linear or branched hydroxyalkyl, E 〇 addition. Any one of the polyoxyethylidene groups in the range of I to 25, in terms of carbon number

5 4 ή6 ^ Ai -V' i to 4 straight or branched alkyl, carbon number J to 4 straight or branched hydroxyalkyl is suitable. use. The long-chain tertiary amine represented by the following formula (5) in the formula (4) is more preferably R11 Z - R13_n R12 except that in the above formula (5), a chain or a branched alkyl group, or a carbon number _ *---- 5) 'R11 and R12 are a direct bond or a bond of a carbon number of 1 to 4 up to 4, respectively. 319968 12 200848507 is a linear or branched stretch base of 1 to 4 stone anomalies. Z is a group represented by the following formula (6) or (7). —NH— C —R14 II ......(6) A 0 — C —R16 I, ------(7)

However, in the above formula (8), ri4 is a nicotine group having 7 to 23 carbon atoms, preferably having a carbon number of 7 to 21; in the above formula (7), R15 is a carbon number of u to a white hydrocarbon group, and has a carbon number of 12 Preferably, it is 20; and f may be linear or branched and may be saturated or unsaturated. Preferred examples of the long-chain tertiary amine compound as the (Β) component include, for example, octyl hydrazide 1⁄4 amine propyl monomethylamine, decyl propyl dimethyl amide, and decyl decanoate. Propyl dimethylamine, decylaminopropyl melamine, hexadecyl H-propyl propyl decylamine, decyl propyl dimethyl methacrylate, 22 (acid guanamine) Long-chain fatty arylamine-based tertiary amines such as bis-decylamine and decyl propyl decylamine oleate; hexadecanoate propyl decylamine, octadecyl propyl monomethyl An aliphatic ester-based tertiary amine such as an amine; a decyl propyl propyl hexadecane diethanolamine or a decyl propyl decyl hydroxydiethanolamine; these compounds may be used singly or in combination of two or more. Amidoxime dimethyl decylamine, decyl propyl dimethyl amide, decyl propyl decyl decylamine, decyl propyl decyl decyl amide, decyl citrate Di-decylamine, decylaminopropyl decylamine octadecylamine, decylaminopropyl decylamine behenate, decyl propyl decylamine oleate 13 319968 200848507 Used alone or in combination for Preferably, it is more preferred to use a combination of hexadecanoic acid and amidoxime dimethyl octadecyl octadecyl dimethylamine. At this time, decyl propyl hexamethylene dimethylamine··18 Acid amidamine dimethylamine = .1 〇 · · 90 to 50 · · 50, and preferably 20: 80 to 40: 60. By using at a ratio of ♦, excellent stability is obtained. Further, a composition having high rigidity is suppressed. As a specific example of the production of the component (B), for example, when a "long-chain aliphatic guanamine alkyl tertiary amine" is produced, a fatty acid or a fatty acid lower alkyl ester, an animal or plant is used. After condensation reaction of a fatty acid derivative such as a fat or oil with a dialkyl (or alkanol) aminoalkylamine, the unreacted dialkyl (or ani alcohol) amine amide is sent by depressurization or nitrogen gas. In this case, as the above-mentioned fatty acid or fatty acid derivative, specifically, for example, caprylic acid, capric acid, dodecanoic acid, tetradecanoic acid, palmitic acid, octadecanoic acid, oleic acid, and behenic acid may be mentioned. , mustard acid, [2-hydroxystearic acid, coconut oil fatty acid, cottonseed oil fatty acid, corn oil fatty acid, tallow fatty acid Palmitic oil fatty acid, soybean oil fatty acid, linseed oil fatty acid, castor oil fatty acid, eucalyptus oil fatty acid and other vegetable oils or animal oil fatty acids, or oxime esters, ethyl esters, glycerides of these fatty acids, etc., among them, especially octanoic acid, Tannic acid, tetra-acid, tetradecanoic acid, hexadecanoic acid, octadecanoic acid, oleic acid, and behenic acid are the best. These fatty acids or fatty acid derivatives may be used alone or in combination of two or more. Dialkyl (or alkanol) aminoalkylamines, specifically, for example, dimethylaminopropylamine, dimethylaminoethylamine, diethylaminopropylamine, diethyl Aminoethylamine, etc., and preferably dimethylaminopropylamine. 319968 14 200848507 , Dialkyl (or alkanol)amine in the manufacture of long chain aliphatic guanamine alkyl tertiary amines The alkylalkylamine is preferably used in an amount of from 0.9 to 2.0 times moles relative to the fatty acid or a derivative thereof, and is preferably from 丨·〇 to 丨·5 times mole. • The reaction temperature is usually 100 to 220 ° C and preferably 150 to 200 ° C. By setting the reaction temperature to l (above TC, the reaction rate can be kept moderate; by setting the reaction temperature to 220 ° C or lower, the coloring of the obtained tertiary amine compound can be prevented or reduced. In the esterification reaction in the case of a tertiary amine, the amount of the dialkylf-amino alcohol used is preferably 5·丨 to 5 〇 moles relative to the fatty acid or its derivative, and is 〇·3 to 3· 0 times Moule is preferred, preferably 〇·9 to 2·〇倍莫耳, and preferably from 1·0 to 1.5 times Mo. The reaction temperature is usually from 1〇〇 to 220°C. It is preferably from 120 to 180 ° C. If the reaction temperature is less than 100 (3, the reaction becomes too slow, and when it exceeds ° C, there is a fear that the obtained tertiary amine is significantly colored, so In addition to the above conditions, the conditions for preparing the long-chain aliphatic guanamine-based tertiary amine may be appropriately changed depending on the type of the raw materials to be used, for example, the pressure during the reaction may be normal pressure or reduced pressure, and the reaction may be carried out. It is also possible to introduce an inert gas such as nitrogen by blowing. /8, and 'by using sulfuric acid, p-toluene yellow when using fatty acid When an acid catalyst is used, or when a fatty acid derivative is used, an alkali catalyst such as sodium decoxide, caustic potash or caustic soda can be used, and the reaction can be carried out efficiently at a low reaction temperature in a short time. When the tertiary amine compound is a long-chain amine having a high melting point, in order to improve handleability, it is preferably formed into a flake shape or a small 319968 15 200848507 pellet shape after the reaction, or is dissolved in ethanol. Other organic solvents are preferred to form a liquid. Other preferred examples of the component (β) include, for example, dodecyldimethylamine, tetradecyldimethylamine, coconut alkyldimethylamine, and ten. Hexamethylamine, tallow alkyl bis-f-amine, hardened tallow alkyl decylamine, octadecyldimethylamine, octadecyldiethanolamine, polyoxyethylidene hardened tallow alkylamine (Lion The product name of the Akzo (stock): ΕΤΗ〇ΜΕΕΝ 14 /14, etc.) The salt of the long-chain tertiary amine, for example, an acid salt formed by neutralizing the above-mentioned amine compound with an acid, etc. The acid to be used may, for example, be hydrochloric acid, sulfuric acid, nitric acid, lithic acid, glycolic acid. Lactic acid, citric acid, polyacrylic acid, p-toluenesulfonic acid, cumenesulfonic acid, etc. These acids may be used singly or in combination of two or more. In addition, another (β) component is a quaternary ammonium salt cation. The surfactant, the cationic surfactant is not particularly limited, and the effect of imparting softening to the wood or the formation of the (c) component of the liquid detergent composition may be agglomerated. The superiority of the stability is that the quaternary ammonium salt represented by the following general formula (8) is suitable. I R18~n~r 19

Z.. (8) ^ In the above formula (8), R18 is a hydrocarbon group having 8 to 25 carbon atoms, which may be linear or branched, may be saturated or unsaturated, and may also contain In addition, a hydrocarbon group or the like may also be a binder having a mercapto group or an ester group [-c(o)-〇-] 319968 16 200848507 or an ether group [-〇-] in its chain. It is suitable to use a hydrocarbon group having a broad number of 8 to 25 (which may be linear or branched, and may be "saturated"), and preferably has a carbon number of 16 to (ii). In addition, 16 has a bond in the bond. The ester group (10) is preferred. Or the two R17 are independently a hydrocarbon group having 1 to 25 carbon atoms, which may be a linear chain substituent. Alternatively, it may be saturated or unsaturated, and may also contain a hydrocarbon group. η ·! can;, in its bond with an acid amine group, ester group C (8)-〇-] or sulfhydryl [-0-] and other linking groups. ϋ Add 莫 0 to the molar number! A stone mountain 1 A straight or branched chain of 1 to 4 is preferably a linear or branched lysine which is burned to 4, and is preferably a hydrogen atom, preferably: and has a vine group in the bond [_c(9)_〇_ Any one of the alkyl groups of the antimony of 1 to 3 of the chlorine atom or the polyoxyalkylene group of the E0 addition mo =. Among them, the chlorine atom: to 3 alkane The hydroxyalkyl group having a carbon number of up to 3 is preferred, and a hydrogen atom or a methyl group is more suitable. ^ represents an anion specifically, for example, an ion such as a gas ion, a desert ion or an ionic ion, or a general formula d%, r2. is a carbon number ι to 3 == base (methyl, ethyl, An ion oxime represented by a methyl group, and a methyl group is particularly preferred. Among them, a chloride ion is preferred. 具体iC A specific example of the cationic surfactant represented by the formula (8) may be, for example, a ten-based base. a ceto Stearyl trimethyl ammonium chloride, an octadecyl-methylammonium sulphate, a succinyl ammonium sulphate, a monoester ammonium salt, two Ester 319968 17 200848507 Alkanolamine ester quaternary salt of ammonium salt, diester ammonium salt or the like or a mixture of these. Among them, a mixture of octadecyldimethylammonium chloride, behenyltrimethylammonium chloride, and an alkanolamine quaternary salt is preferred. (B) The above-mentioned long-chain tertiary amine and/or its cationic surfactant may be used singly or in combination of two or more. In particular, by using long-chain secondary amines and/or their hydrazine alone, hydrazine is more effective in preventing stiffness.

The component Cc) and the component (c) in the present invention have a alkylene terephthalate unit and an ortho-dicarboxylic acid-terminated ester unit (cl #元) and an oxygen-expanding unit and/or oxygen A water-soluble polymer of L-based single A (g2 | 兀). By formulating the component (6) in the detergent composition of the present invention, it is possible to prevent the darkening of the clothing in the washing, and to have the effect of preventing recontamination.

In the following, in the case of the stearic acid extension, R21 means a lower stretching base, and for example, a carbon number of 4 2 to 4 is particularly preferred. For the alkylene terephthalate unit, specifically, 319968 18 200848507 ethyl vinegar unit, terephthalic acid is a continuous propylene vinegar unit, and terephthalic acid is a butyl vinegar single: 甲广异伸丙早70 pairs One of the second butyl ester units of citric acid, the pair of stupid _ one and one S 1S one rong * rb this one ^ 曱酉夂 二 伸 伸 伸 酉曰 酉曰 酉曰 酉曰 酉曰 酉曰 酉曰 酉曰 酉曰 一种 一种 一种 一种 一种 一种 一种 一种Diformation of dicarboxylic acid (4) is preferred. In the middle, the para-phenylene isophthalate unit is represented by the following formula. 0

In the formula, R22 means a lower alkyl group, and for example, 2 to 4 is particularly preferred. J, such as the number of 44 or less, and c-alkylene phthalate unit, with pomelo 7 final--B day #工J enumerated, such as meta-xylene, acetaminophen, bismuth diacetate Single, + one 匕--e day + daytime dicarboxylic acid is stretching 酉曰 early 兀, m-dicarboxylic acid second butyl ester single dry 7 ^ 本 二 罗 笫 # # # # # 单元 单元 单元 , Separately or in combination to make a worry. In the present invention, a straight propyl isopropyl ester unit is preferred. / (c 1) of the present invention, which can be used, used, and used from the above-mentioned alkylene terephthalate and alkylene isophthalate units. J alone or in combination of two or more units (c2) units are oxygen stretching units and/or polyoxyalkylene units. The oxygen-extension base unit and/or the polyoxyalkylene unit can be represented by the formula - (Peak - 319968 19 200848507, that is, the oxygen-extended alkyl unitary unit system is more than 2, and is 1). In the case, the polyoxyalkylene carbon number is, for example, 4: wherein R23 is a lower alkyl group, and the oxygen is extended to the unit 2;: is an integer of the above. Upper (preferably 5 to 15) 〇, a more basic unit, which is preferably a polyoxyalkylene-based unit with s of 1 and an oxygen-extended (four) unit or an ethyl unit; an oxygen-extended propyl unit or an oxy-e-ethyl unit Or polyoxynized polyoxy-extension propyl unit, etc., and oxygen #propyl 7, · polyoxy-extension ethyl is preferred. The base 70 or polyoxy-extension ethyl unit in the monoterpene component 'may also contain The (C) component of the (10) unit is preferably a polymerized mash early (c2) monopolymer obtained by polymerizing the upper, the element, or the block. The compound is preferably, in particular, a block: a unit of a polymerization initiator, a polymerization inhibitor, or the like, or other groups of poly(5), but it is preferable to use (cl) or more. 9% molar % On a plus. 70 > 80 Mo = The specific structure of the component (6) which can be desirably made in the invention is exemplified by the following formula. In addition, although the following general formula shows the use of the formula (1) and the use of the meta-dicarboxylic acid for the use of the formula (1), the present invention is not limited to the following form. For example, the structure may be a 319968 20 200848507 unit in which a unit of terephthalic acid and a unit of isophthalic acid are mixed. The component (c) in the present invention has the structure of the following formula (1) and/or formula (2): A - 〇-(R1〇)y_ ? Ο 〇

- 〇-叫4^^一〇_ (R1〇)y_B

X (wherein A and B are each independently a hydrogen atom or a fluorenyl group, and both are preferably a methyl group; R1 and R2 are a C 2 to 4 alkyl group, and have a carbon number of 2 to 3; It is better; X is 〇 to 1〇, preferably 〇·5 to 5, and 〇·5 to 2. 5 is especially good, y is 1 to 100, preferably 1 to 8 ,, 1 to 5 〇 Preferably, it is preferably from 10 to 50, and particularly preferably from 20 to 30.) A~〇-(Rl〇)y·

〇 II C 〇 II , C~〇-R2〇

〇II C—O—(Ri〇)y—b—one (1) (wherein A and B are independently 氲 or 曱, respectively, and both are preferably methyl, R and R2 a carbonization number of 2 to 4, and preferably 2 to 3 carbon atoms; X is 0 to 1 Torr, preferably 〇 5 to 5, and preferably 〇 5 to 2 · 5; It is preferably 1 to 80, preferably 1 to 5, more preferably 10 to 50, and more preferably 2 to 30. In the above formulas (1) and (2), the ratio of X to y is preferably X: y = 1 : 5 to 1 · 20, and more preferably 1: 8 to (: 18). When X, y are in such a range The medium can be easily decontaminated (soi 1 release) performance can be improved and can improve 21 319968 200848507 • solubility in water, and better. In terms of washing effect, (c) component is mass average The molecular weight is preferably 500 or more, more preferably 800 or more, and preferably 1,000 or more. On the other hand, from the viewpoint of solubility and dispersibility of water, ^ mass average molecular weight The upper limit value is preferably 8.0 or less. In addition, from the viewpoint of maintaining the performance in storage, it is preferably 5,000 or less, and preferably 4,000 or less. Here, by GPC (condensation) When the mass average molecular weight is determined by using a THF (tetramethylene furan) as a solvent, PEG (polyethylene glycol) can be used as a calibration curve and then converted. For example, in the present invention ( The C) component is applicable by adding 10 g of the component (C) to 1,000 g of water and then using a stirrer at a temperature of 40 ° C ( 8 mm, length 50 mm, 1 liter beaker) can be dissolved after stirring for 12 hours at 200 rpm. (C) The components can be used commercially, or by various methods, etc. For the commercial product, for example, the product name TexCare SRN-100 (manufactured by Clari ant, mass average molecular weight 3,000) (hereinafter referred to as SRN-100) and the trade name TexCare SRN-300 (traded by Clariant Co., Ltd.) are commercially available. The mass average molecular weight is 7,000) (hereinafter referred to as SRN-300). It is particularly preferable to use TexCare SRN-100 (manufactured by Clariant Co., Ltd.) because the solubility in water is high and the cleaning performance after storage is small. For the methods disclosed in the literature, for example, Journal of Polymer Science, Vol. 3, pp. 609-630 (1948), Journal 22 319968 200848507 of Polymer Science, vol. g, pp. 61- In the method of No. 21, 8699, the method of the method is cracked. From 1 to 22 pages (1951), the method of the present invention can also be used in addition to the above, in the present invention, the system of the above-mentioned SRN-1 0 〇 (D) Ingredients especially TexCareSWM70 (Clariant 70% aqueous solution) Applicable. Male (8) knives of cis-butan acid-polymer, cis-butanic acid, maleic acid copolymerized carbon number 4 /, -. Resistant number 4 phantom 2 of the co-polymer And/or a copolymer of maleic acid and acrylic acid, and/or a salt thereof. Since the detergent composition 曰 3 of the present invention has the component (D), it can exhibit the synergistic effect with the (C) knife, and can further reduce the effect of contamination. More "preventing the blackening effect of washing" (in the maleic acid-based copolymer, it can be copolymerized with cis-butanic acid: body 1 as long as it is a number of charcoal copolymerizable with cis-butanic acid It is 4 to 12·., and is a monomer and/or acrylic acid, that is, unless otherwise specified. 』To the general-purpose tobacco system which can be copolymerized with maleic acid to J, and processed as a raw material. & inverse number 4 ^ M heart king 丨 king to 3, 疋 石 石 石 4 4 4 4 4 4 4 。 。 。 。 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外 另外The co-polymer and the agent of the sputum are neutralized by the slow-acting base. The hydrazine-based copolymer salt is suitable. The hydrocarbon-based hetero-organism used in the present invention. In the use of a dilute flue series in the use of a dilute flakes, when the m-butyl diacid is copolymerized with an olefin-based monomer, it can be combined with a butylene 319968 23 200848507::::: hydrocarbon monomer, with a carbon number of 4 to The olefin-based monomer of 12 is more preferably an inverse number of 4 to 8. By making the carbon number 4 or more, the effect of dyeing is further improved. On the other hand, the raw material can be made by making the carbon number below 12: The handling becomes good. '胄丁丁二The average mass of the copolymer of the hydrocarbon-based monomer = the thiophene-converted gel permeation chromatograph - 〇〇0 or more, which can improve the effect of preventing re-contamination, another

By making the mass average molecular weight at 1 〇〇, the stability of the composition is achieved.叨"杈N "In the preparation of a copolymer of cis-butanic acid and acrylic acid (hereinafter referred to as 2: C: 1 polymer), maleic acid and propylene ^ 65 · 5〇, and 30 ·· 70 to 50 ·· 50 is better, and 35 ·· 65 to 45 ·· 55 is better. Regarding the ratio of (iv) acid:;; the molar ratio of acrylic acid becomes - down, and the increase = the second substance: the decomposition ability of the powdered compound, and then becomes full 50: Bu: by making cis / azelaic acid The molar ratio of propionic acid becomes 5 〇: that is, the valley is easy to prepare a highly polymerizable acrylic copolymer. Further, the measured value of the copolymerization tester of maleic acid and dienoic acid is preferably from early morning to early onset, and from 5 to _ to 5 Å, more preferably. The effect of preventing recontamination can be improved by making the fruit and the knives 5' 〇〇 0 or more'. In addition, the mass average molecular weight is 1 Å. , _ below, and the stability of the composition and composition. 319968 24 200848507 In the present invention, since synthetic fiber (for example, polyester) and sky iron fiber (for example, cotton) can simultaneously exert the effect of preventing recontamination, copolymerization using a maleic acid and a hydrocarbon monomer is used. Better. In the (D) component of the present invention, the above-mentioned ones, such as a copolymerized salt of cis-butenedioic acid and an olefin, may be used, and Quinfl〇W manufactured by ZeZn Co., Ltd., Japan may be used. 540 (sodium salt, molecular weight: 8, hydrazine, pH: 1 〇), Quinfi〇w 542 (sodium salt, molecular weight: 8, hydrazine, pH: 8), Quinfi〇w 543 (ammonium salt, pH · · 6. 8), Quinfi〇w 64〇 (sodium salt, pH: 8), etc., or S〇kalanCP9 (sodium salt, molecular weight: 12, 〇〇〇, pH: 11) manufactured by BASF Co., Ltd. Name) and so on. Further, a copolymer of cis-succinic acid and acrylic acid and/or a salt thereof can be prepared using Sokalan CP7 (sodium salt, molecular weight: 50,000, pH: 8) manufactured by BASF Corporation, and Nippon Shokubai Co., Ltd. Cut Xian 11 (: a few - 4 〇〇 (molecular weight: 50,000), Aqualic TL - 5 〇〇 (molecular weight: 1 〇, 〇〇〇), Aqualic TL-37 (molecular weight: 5000) (all trade names), etc. The components of the detergent composition of the present invention may also be formulated with other components than the above components, such as enzymes (protease, lipase, cellulase, etc.), ampoules (sodium benzoate, citric acid). , sodium citrate, polyol, polyethylene glycol alkyl ether, polypropylene glycol alkyl ether, p-toluenesulfonic acid, polyethylidene terephthalate alkyl ether, polyethylidene (propylene) glycol benzene Phenylene (propylene) phenylether, polypropylene glycol phenyl ether, polyethyl propylene glycol phenyl ether, etc., texture enhancer such as polyfluorene, pH adjuster (sulfuric acid, sodium hydroxide, hydrogen) Potassium oxide, alkanolamine, etc.), preservative, 25 319968 200848507 Shigu back Khydr〇i: r〇pe), fluorescent agent Anti-inking agent, pearl, antioxidant, coloring agent: Acid Red 138, Direct Blue 86, Polar Red RLS, Acid Yellow 203, Acid Blue 9, Blue No. 1, Blue No. 205, Turquoise (tUrqUcnse) PGR ( All of them are trade names, pigments, pigments, flavoring agents, additives, and solvents such as water and alcohols, but are not limited to extensions. Further, the selection and the amount of the components can be arbitrarily selected as long as they are not within the scope of the object of the present invention. ('The preparation of each component is the washing of the month, and the amount of the (Α) component in the composition of the composition is 1 to 5% by mass in the total amount of the washed product. It is preferable to use 15 to 40% of the quality. The amount of the (Α) component can be increased by more than or equal to '% by mass'; by adjusting the amount of the (Α) component to 5 〇, 质^ i^ prevents, the viscosity of the composition is excessively increased, and the amount of the component (B) in the detergent composition of the invention is ο.1 to 1 相对 with respect to the total amount of the detergent: % by mass, especially containing yttrium; (to 5% by mass is optimal. By adjusting the amount of the component (8) above 〇 旦 · 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 In addition to the stability of the composition, the amount of the component (6) in the present invention may be 〇.G1 to 1G with respect to the total amount of the composition of the present invention. The amount of f is preferably in an amount of: % by weight, and the amount of the component (6) is adjusted to _ mass to 5, thereby improving the prevention of the detergent composition of the present invention. In addition to the effect stability of wood, it is economically advantageous, and the compounding amount is 319968 26 200848507. In the present invention, the content of (D) component is arbitrarily formulated. With respect to the total amount of the detergent composition of the present invention, it is 0.01 to 10% by mass, and preferably contains .5 to 5% by mass. By formulating the amount of the component (D) in a shell More than % can exert the effect of preventing re-contamination; by adjusting the amount of preparation to 10 masses, the effect of preventing re-contamination can be sufficiently obtained, and it is also advantageous in the warp. Further, if the detergent is to be used in the present invention In the composition, the composition has a multiplication effect, and the component (6): (8) has a mass ratio of 9:1 to 1:9, and is preferably within a range of 7:3 to 3:7. By making the blending amount of the component (8) with respect to the component (C) in the periphery, the effect of preventing the re-treatment of the detergent composition of the present invention can be further improved. When the (C) component of the detergent composition and (9) = the second component of the detergent composition, the s blending amount of the (6) component fine-formed knife is preferably U to 15 ft: More preferably, even if the amount of the above-mentioned blending amount is more than 15% by mass, the effect of the second = out = expected, and the tendency of the laundry to be stiffened *, and the effect of adding these components. It is not easy to show a combination of the examples of the detergent composition of the present invention:

(^) Component··R3 is a non-dissociated R mass % of the formula (3) of a carbon number of 1 () to 16 (4), (4) to a heart η-0 to 3, and R4={{ Ionic surfactant: 15 to 40 319968 27 200848507 1 (B) Composition: K, R is a linear alkyl group having 1 to 4 carbon atoms, and R13 is a straight 4# | hard alkyl group having 1 to 4 carbon atoms. Z is a filament of the formula (6) having a hydrocarbon chain R14 having 7 to 21 carbon atoms - an under bond secondary amine · · 5 · 5 to 5 % by mass - (C) component · · AD 1 1 9 Α, β are sulfhydryl groups, R and R2 are a 2 to 3 carbon alkyls, a group, X is a water-soluble polymer of the formula (1) wherein the stone is β 2 main, and the y is 20 to 30. And / or 伯 Λ Λ Β Β Β Β , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , Water-soluble polymer: 〇.〇5 to 5% by mass (D) Ingredient······································ The bulk copolymer: 0.05 to 5% by mass. The x month detergent composition can be produced by a method generally used in the production of a liquid lotion. For example, the 1 liter scale of the Levi, the =Vo cup uses a magnetic stirrer (MITAMURA RIKEN KOGYO INC.), the second ", the next order. The component (A) is dissolved in ethanol, and after the water is added thereto, the component (8) previously dissolved in ethanol is added, and after stirring, the component (c) and the component (c) are added, and then the mixture is stirred. The pH adjuster has a value of 7 in the vicinity of: The detergent composition of the present invention is selected from the composition of the net sword at a temperature of 25 ° C, and has a pH value of 5 and 5 The pH value of 8 is good. By making the value of Qi in the dry circumference, the storage property of the detergent composition can be improved. If the pH value of the substance is 2, the pH adjustment can be used.剤 以 以 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 319 The viscosity is 500, the ease of measurement, etc., and the applicability to the shampoo, and the composition of the bottle is not good. The following is a detailed description of the application, and the T AA — ,, The composition of the detergent composition. The following examples do not limit the target circumference of the present invention. In addition, the following [1:7], respectively "% by mass" and "parts by mass" f. Ingredients used in component (A) - E〇12 molar addition of Safol 23 alcohol from asol (R3 = C12 / C13 alkyl (as raw material) C12/C13 alcohol mass ratio = 6/4), Y = 〇, branching rate (A-1 synthesis method)

After placing 224.4 g of Sasol Safol 23 alcohol and 2.0 g of a 30% Na〇H G aqueous solution in a pressure-resistant reaction vessel, nitrogen substitution was carried out in the vessel. Then, after 30 minutes of dehydration at a temperature of loot: and a pressure of 2.0 kPa or less, the temperature was raised to 16 〇 ° C. The alcohol was mixed, and 610.7 g of ethylene oxide (gaseous state) was gradually added to the alcohol solution while adjusting the addition rate without causing the reaction temperature to exceed 18 Torr by using a blowing tube. After the completion of the calcination, the mixture was aged at a temperature of 180 ° C and a pressure of 3 3 MPa for 30 minutes, and then the unreacted epoxy bake was left at a temperature of 180 T: and a pressure of L kPa or less for 1 minute. After the temperature is below 100 ° C, 70% p-toluene 319968 29 200848507 is added to neutralize it to obtain A-; 1. The solution of the aqueous solution of the reactant is about 1 莫 1 with a branched type of Moore knife The so-called branching ratio is the ratio of the number of moles of _ 烧 in the raw material alcohol, and the ratio of the number of moles to the number of 。 ? 12 12 12 12 12 咖 咖 咖 咖 咖 咖 咖 咖 咖 咖 咖 咖 咖 咖 咖 咖(only 3 / C13 alkyl (mass ratio of C12 / C13 alcohol as raw material. Y = 〇, branching rate = 50%, R4 = H, m = l5, n = = 〇) (A-2 Synthetic method) 224.4 g of a commercial product Saf〇1 23 alcohol manufactured by Sasol and 763.4 g of ethylene bromide were used, and the same procedure as in A-1 was carried out to synthesize two A_-3: E〇15 Moer addition product of the trade name c〇_1214 alcohol manufactured by P&G company = C12/C14 alkyl group (mass ratio of C12/C14 alcohol as raw material is 2 u /29), Y=〇, Branching ratio, r4=h, m=15, n=〇) (Synthesis method of A-3) 224·4g of P-amp;G company's trade name CO-1214 alcohol and 759·5g of ethylene oxide were used. (Gaseous), the other steps are carried out in the same manner as A-i. A-4: E0 7 molar addition of C13 alcohol obtained by synthesizing butene trimer by carbonyl oxygen method (R3=C13 alkane) Base, Y=0, branching ratio 100%, R4 ηη, n=〇) (trade name: BATENZOL Τ07) (B) Component B-1: C16C18 amideamine · Long chain Fatty acid dimethylamino propyl amide (mass ratio of stearic acid (C18) / palmitic acid (C16) = 7/3), 30 319968 200848507 4 Product name · CATINAL MPAS-R (manufactured by Toho Chemical Co., Ltd.) B -2 : C16C18 proline amine synthetic product · Long-chain fatty acid dimethylamino propylamine (mass ratio of stearic acid (C18) / palmitic acid (C16) = 7/3). (Synthesis of B-2 Method) • Load 252g of stearic acid (molecular weight 284) in a 1 liter four-burner #watt with a reflux cooler. 108g palmitic acid (molecular weight 256), heated to cause melting 8 0 ° C stearate. After performing nitrogen substitution twice, the temperature was raised to 150 ° C, and dimercaptopropylpropylamine (molecular weight 1 〇 2) was obtained in 1 hour (127 g (mole ratio relative to mixed fatty acid was 〇·95). After dropping for 1 hour at 150 to 160 ° C, the temperature was raised to 185 ° C over 1 hour, and 47 g of dimethyl mercaptopropylamine was dropped over 1 hour. After the dropwise addition, it was kept at 185. At 190 ° C, after 7 hours of aging, the water produced by the by-product was distilled out to the outside of the system, and then kept at 170 to 190 ° C for decompression (4·OkPa), and after leaving for 1 hour, it was distilled off. Reaction of dimethylaminopropylamine. (B-3: C18 guanamine synthesis product: didecylaminopropyl decylamine stearate (synthesis method of B-3) 1 liter in refrigerated cooling In a four-necked flask, '600g of stearic acid (molecular weight 284) was charged and heated to 80 ° C to melt the stearic acid. After two times of nitrogen substitution, the temperature was raised to 15 Torr. The dimercaptopropylpropylamine (molecular weight 102) of i23g (mole ratio of stearic acid to 〇95) was dropped. Then, after maintaining at 150 to 160 ° C for 1 hour, for 1 hour. Warm up to 18 5. (:, 45 g of dimercaptopropylamine was added dropwise in 1 hour. After the completion of the dropwise addition, it was maintained at 185 to 丨90. In the sputum, after 7 hours 31 319968 200848507 1 The water was distilled off to the outside of the system, and depressurized (4·OkPa) was maintained at 1 to 70 ° C. After standing for 1 hour, the unreacted dimethylaminopropylamine was removed. B — 4 ·· cl 〇醯 胺 合成 · · 二 二 二 二 ( ( ( ( ( ( 合成 合成 合成 合成 合成 合成 合成 合成 合成 合成 合成 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 260 9 g of methyl decanoate (Paster Μ-40, manufactured by Lion Chemical Co., Ltd., molecular weight 186), after two times of nitrogen substitution at 60 ° C, the temperature was raised to 150 ° C, and 186 g was made in 1.5 hours ( The monomethyl propylamine (molecular weight 1 〇 2 ) with a molar ratio of mixed fatty acid of 丨·3〇) was dropped, and after completion of the dropwise addition, it was maintained at 185 to 190 C for 7 hours of aging. The conversion ratio of the mixed fatty acid calculated by the acid value was 97.2%. B-5: octadecyltrimethylammonium chloride, trade name Arquad T-8〇〇 (manufactured by Li〇n Akz Co., Ltd.) (C)

IC-1 · Water-soluble polymer, manufactured by Clariant, trade name TEXCARE SRN-170 (mass average molecular weight: 2, 〇〇〇 to 3,000, 70% aqueous solution of TEXCARE SRN-100) C-2 · Water-soluble polymer, Manufactured by ciariant, trade name TEXCARE SRN-300 (mass average molecular weight: 7, 〇〇〇) (D) Component D-1 · Sodium salt of maleic acid/olefin-based copolymer, made by the company, Trade name Sokalan CP9 (molecular weight 12,000) D-2 · Sodium salt of acrylic acid/maleic acid copolymer, manufactured by Basf, Inc. 32 319968 200848507 1 Product name SokalanCP7 (molecular weight 50,000, acrylic acid / maleic acid Mohr ratio 60/40) Common ingredients. Sodium benzoate: East Asian synthetic (stock) system, trade name: sodium benzoate, citric acid: Fusang Chemical Industry Co., Ltd., trade name: liquid citric acid 95% Ethanol: Japanese alcohol sales (shares), trade name: specific alcohol 95 degrees synthetic p-toluenesulfonic acid: Concord Fermentation Industry (shares)

Spices: Tables 11 to 18 of JP-A-2002-146399, the preparation of a liquid detergent composition for clothing A (1) The ethanol in the following common component a is added to a 300 mL beaker. After the component (A), the mixture was thoroughly stirred by a magnetic stirrer (MITAMURA RIKEN KOGYO INC). (2) After adding water to the common component a which has been heated to 40 degrees in (1), the component (B) which has been previously dissolved in ethanol is added and dissolved sufficiently. (3) Further, after adding the component (C) and the component (D) to (2), the mixture is sufficiently stirred. \ (4) After adding the common component a and stirring it sufficiently, it becomes a liquid detergent composition for clothing. Moreover, the common component a in the table means the following composition. <Common ingredient a > Sodium benzoate 0.5% by mass Trisodium citrate 0.2% by mass 95% ethanol 5. 0% by mass Benzene sulfonic acid 2. 〇% by mass 33 319968 200848507 Perfume pH adjuster楠 丄 丄 ι ι ι 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 〜 ( ( 〜 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( i and table 2. (1) Evaluation of inhibition of stiffness effect <washing treatment method> Commercially available cotton towel (cotton 100%) 12 shirts were put into the cotton lining for Toshiba Adding force side 2 1 _, after washing, cleaning, and forming the product at a ratio of 25 mL, 'I will follow the standard washing process. i. Water and water volume, it is the dry day of the operation (4), cleaning, de-evaluation method> The settings of the first clothes _ standard washing process have not been adjusted. dry. The cotton towel _ 12 hours, let it dry, and then use this as a feed temperature and humidity chamber for 2 days, after using a non-ionic non-rigid test cloth. The evaluation was carried out with the comparison of the cloth and the two reservoirs of the interface active sword [after the oxygenation of the average cloth: after the evaluation of the functional evaluation of the two experts, according to the following benchmark 319968 200848507 10) And find the average of the special points. The higher the score, the less stiff. Bay η (assessment basis): 2 / min or more is a pass range of 1 point · · Same as or below the control cloth 2 points: Compared with the control cloth, the degree of stiffness is slightly suppressed by 3 points · compared to the control cloth, The degree of stiffness was suppressed by 4 points: the degree of stiffness was very suppressed compared to the control cloth (2) The evaluation of the prevention of recontamination was carried out in the 79J Terg-°-T〇mt-^NITED STATED TESTING CO., INC. 7243S type) In the bath, add 9 〇〇w knife eight yuUmL tap water, 0. 8mL washing level attack 'after stirring at 12Grpm for 3 minutes, put 5 pieces of red earth dirt cloth (3 x 4cm), 5 pieces of oil $1 cloth (5x5em) 2 pieces of white polyester cloth (5) $ (5), 2 pieces of cotton shirt cloth (5x5cm), wash for 1 minute (25. 〇. Remove the cleaning solution in the sputum, and test the dewatering tank of the double-tank washing machine 1 dehydration of cloth = 2 and then add 900 mL of tap water to the Terg-〇-T (10) ter bath for cleaning. 3 Detach the test cloth in a dewatering tank of a double-tank washing machine for 1 minute, after repeating 2 times. , measuring the reflectance of the white cloth, and calculating the difference between the reflectance of the white cloth and the washing degree as the degree of recontamination (Δ z) The reflectance is based on the color meter SE2000 (NIPPON DENSH0KU). (Evaluation basis): The results of the passing condition are as shown in the following Tables and 2s. 35 319968 200848507 [Table 1] 00 ΙΛ CM ΙΛ & o <β ο UD UD CO 4Λ LO CM inch d in d io o «0 100 5:5 to csi o ο €〇«5 CNJ 04 00 00 ce Ο ΙΩ ΙΑ l〇oa o Ο 2 Iff C4 0.03 0.03 AS Ο ♦•Η u> LO 0. 06 e>3 to OO ΙΑ S IA CM 0.2 00 o CO ο 00 ei — 00 CO 04 VO Life 2 to c^i CA 00 o ca o Ο — όο iM oo 00 CO »-ί S3 to CQ moo ο ▼Ή tA to ip-4 00 CO CSI co 00 IA oa CQ m 〇· IO o ce ο — ΙΑ «5 »—t to ca O CD “ ο LO 03 IA d IA o GO ο ο ΙΑ in (4) inch CO o CO cn tn <r^ 03 in d IA 〇os ο »-ί U5 LO CO o CO csi 00 IA CSJ IA o IA 〇0 ο i〇to «〇<Q o eg IA 05 IO o iO oa ο ir> ud CD OO o CM c〇tn it^ 04 IA 〇to o A ο LO in rK but o 00 Csj 1ί> 4Λ CM IA 〇to o ¢9 ο tc U) tH CO CO o 卜1—< inch in C4 CN3 o in om ο Η to in rH CO eo o 00 *m4 IA OJ C>i to o ΙΛ O' tH ο τ-4 UD to ^-4 to CO o OO tH cvj U3 04 CM ♦H a ο rH 1 1 QO CO CO — IA CSJ Λ ο 1 1 oo CO ψ^4 o CO Example 1 < n 1 < CO 1 < I lH 1 PQ (N 1 m CO 1 CQ 呀1 PQ m 1 CQ rH 1 υ CQ I υ rH 1 P c>i 1 Q | Common component 1 total Q (C) + (D) Total amount (% by mass) | Suppressing stiffness | Preventing cotton blackening effect | Preventing polyester blackening effect CQ u 5 36 319968 200848507 4 [Table 2] ΙΟ OQ CO 1 1 o Ο) to i〇CSJ CO in CS3 CS3 10 I 1 o ¥ ο Ο) OJ 05 CV3 LO es5 CO 1 f <N CQ — o 〇· ID OQ 03 CQ 1 1 CM to ο c6 o 00 镕iJ rH 1 < 1 r-· 1 o rH 1 Q (N 1 PQM 3 _ . 提 te te te te Μ : : 绿 绿 绿 : : : : : : : : 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在 在Liquid detergent composition in the circumference Suppresses the effect of stiffness and the effect of blackening. Further, in the comparison of Examples 3 to 16 in combination with the fresh ingredients of (6), and Examples i and 2 and (4), it is known that the liquid in the scope of the present invention is further ' 仫 门 门 门The prevention and the lack of the fruit are caused by the combination of the (C) component and the (F) blackening 3 to play the synergistic effect of the (6) component and the (8) component. More ", and can be [industry available] By using the liquid helium of the present invention, a large-sized washing machine represented by a tubular type washing machine, and being stiffened by the use of the material for rolling, and not being washed away when the cloth is washed. Re-contamination. The texture of the fabric can also be prevented. [Simple description of the drawing] Drumstick 319968 37 200848507 [Main component symbol description] No 0 38 319968

Claims (1)

200848507 X. Patent application scope: 1 · Liquid detergent composition for planting materials, containing (A) nonionic surfactant, 1 〇 to 5 〇 mass%; female long chain tertiary amine and / or a cationic surfactant of a salt, and/or a quaternary ammonium salt, 〇·1 to 10% by mass; and (c) having a (cl) alkylene terephthalate unit and/or a alkylene isophthalate The unit and the (C2) oxyalkyiene unit and the water-soluble polymer of the f/ or polyoxyalky lene unit, 〇· 01 to 1% by mass. (2) The liquid detergent composition for clothing of the first aspect of the invention, wherein (C) is a water-soluble polymer represented by the following general formula (1) and/or (2): Ο 〇 (R' ODy-一〇— R2〇·〇〇〇-(R*lO)yB X \ (wherein A and B are independently hydrogen or sulfhydryl groups, and Ri and R2 are 2 to 4 alkyls. Base, X is 〇 to 10, y is 1 to 1 〇〇) A- e〇—(R10)y- O II C ο Ο II Ί 丨1 C-〇-R2〇--C-<〇V ο II C〇—(Ri〇)y—BX 1-1(2) (wherein A and B are each independently a hydrogen atom or a fluorenyl group, and Ri and R2 are an alkylene group having an inverse number of 2 to 4 , X is 〇 to 1 〇, y is 1 to 1 〇〇). Composition of liquid detergent for clothing according to item 1 or 2 of the patent application section 319968 39 200848507 [, έ有·〇· 〇1 to 10% by mass (D) succinic acid and i =, butyl succinic acid copolymerized with a carbon number of 4 to 12 of the tobacco monomer and / or a copolymer of maleic acid and acrylic acid , and / or its salt. • Liquid detergent composition for clothing according to item 3 of the patent scope, where '(C) The mass ratio of the component (D) to the component (D) is from 9:1 to 1:9, and the amount of the mixture of the component (6) and the component (8) is from 0.1 to 15% by mass relative to the total amount of the composition. 319968 40 200848507 r VII. Designated representative diagram · This case has no schema. (1) The representative representative of the case is: (). (2) The symbol of the representative figure is a simple description: VIII. If there is a chemical formula, please reveal the chemical formula A which best shows the characteristics of the invention - ΡΡΟ - (ΡΡΟ) > τ Α - Ο - (R10) y. Ο Ο II / ~ λ II 0 C-{〇) - C-0 -R20 Ο II 〇C-0-R20 4 ο ο 0—(R10)y—Β X Ο II ChQhC-O-(R*»0)y- B (1) X 一-—(2) 319968