200844389 九、發明說明： 【發明所屬之技術領域】 本發明關於一種含鈦模製體，其製造方法及其應用。 本發明特別關於一種含鈦之模製體，例如呈磚塊、丸 粒、或壓製石形式者，還關於製造此模製物的方法，以及 其在冶金程序中的應用，特別是用於裝入初級、次級及三 級冶金的熔融爐或容器者。 本發明也關於一種方法，用以提高耐火外牆的保持性 以減少氧化氮及硫含量（特別是在鐵分析及廢氣中者）， 以及藉使用合成及/或天然鈦攜帶體減少熔融爐或豎道擴 中有害之循環物質者。 此外還提到一種方法，使用含鈦模製體當作熔渣形成 劑、熔渣保護劑、及合金劑。 【先前技術】 由於在環保方面要求日益高漲，在材料作溶煉 (Verhtittung，英：smelting )時，製造商往往要追加作費 成本的程序以減少污染環境的物質，這點使製造成本增 加，因此使一方法的經濟性受影響。因此發展出許多方法，曰 以將此複雜的解決方法儘量經濟地達成。在金屬作精煉 日守’也有使用既存的方法（例如將垃圾作溶融化 ,卜、一、 … 夕从减 夕 >可染環境的物質。這種垃圾的熔融物氣化的作業係使用 冶金方法技術。如此有以下優點： a)確保溫度，使礦物性及金屬性之廢料成分變成熔融 * 5 200844389 相且使有機與無機之有宝* 物一一如果不呈气辦 °物貝为解，在此產生的產 中及/或在液能入P^掉一在液悲熔渣 的方弋/〜孟蜀中並非結合成可分離（eluierbar ) 的方式。在此，熔涪 λλ - ^ —矛孟屬的作用有如整合在程序中 的有害物質沈降品。 b) 利用該還原性的大氣， # # & y* ^ a 了確保至屬氧化物還原。這點 係幵v成液體合金的前提。 c) 將廢物的物質作趙讲i 、 σ千句值的應用，由於剩餘廢物尋 以低（來自原氣清洗作業的塵、污泥、鹽）故可確 保這種利用。 化 匕卜由於產生—m查（它可作乾式或濕式顆粒 故製造的構造材料可認可，且可廣泛用於世界。因此， 如製或產生金屬合金，它可在鐵屑處理 (Schrotthandel)或直接在精煉機或鑄造廠（Giej3ereim) 減少。 在-人級冶金中，所用的合金劑也可用來的鐵鈦 (Ferrotitan)、鐵碳鈦（Ferr〇karb〇titan)及鋁熱製程來 的鈦鋁。這些合金劑，特別是鐵鈦很昂貴，鐵鈦的分析顯 示，它主要由20〜75重量％或更多的Ti，由2〜1〇重量 %或更多的Α1+Α12〇3 ’由0·2〜8重量％或更多的石夕，以及 由20〜65重量％或更多的Fe構成。舉例而言，一種鐵碳 紙可具以下主要分的組成·· Ti: 30〜40% ; C: 5〜8% ; Si : 3〜4% ; Al: 1〜2% ; Μη : 0.5 %。舉例而言，鈦|呂可具 有以下主成分的組成： 6 200844389200844389 IX. DESCRIPTION OF THE INVENTION: TECHNICAL FIELD The present invention relates to a titanium-containing molded body, a method for producing the same, and an application thereof. The invention relates in particular to a titanium-containing molded body, for example in the form of bricks, pellets, or pressed stone, as well as to a method of making the molded article, and its use in metallurgical procedures, in particular for loading Into the primary, secondary and tertiary metallurgical melting furnaces or vessels. The invention also relates to a method for improving the retention of a refractory exterior wall to reduce nitrogen oxides and sulfur content (especially in iron analysis and exhaust gases), and to reduce the melting furnace by using synthetic and/or natural titanium carriers or The vertical channel expands the harmful circulating substances. There is also mentioned a method of using a titanium-containing molded body as a slag forming agent, a slag protecting agent, and an alloying agent. [Prior Art] Due to the increasing demand for environmental protection, when materials are used for smelting (Verhtittung, smelting), manufacturers often have to add cost-cost procedures to reduce environmental pollution, which increases manufacturing costs. Therefore, the economics of a method are affected. So many methods have been developed to achieve this complex solution as economically as possible. In the metal refining day guards, there are also existing methods (such as melting the garbage, bu, one, ... eve from the eve of the eve of the environment). The waste gasification operation of this waste uses metallurgy. Method technology. This has the following advantages: a) to ensure the temperature, so that the mineral and metallic waste components become molten * 5 200844389 and make the organic and inorganic treasures * things one if one does not show the gas In the production produced here and / or in the liquid energy into the P ^ a liquid in the slag slag / ~ Meng Yu is not combined into a separable (eluierbar) way. Here, the fused λλ - ^ - genus acts as a sediment of harmful substances integrated into the program. b) Using the reducing atmosphere, # # & y* ^ a ensures that the oxide is reduced. This is the premise that 幵v becomes a liquid alloy. c) The application of the waste material to the value of sigma and sigma value can be ensured because the remaining waste is low (from the dust, sludge and salt of the raw gas cleaning operation). Since it can be used as a dry or wet granule, it can be recognized as a construction material and can be widely used in the world. Therefore, if it is made or produced, it can be treated in iron filings (Schrotthandel). Or directly reduced in the refiner or foundry (Giej3ereim). In the human-level metallurgy, the alloying agent used can also be used in Ferrotitan, Ferric-Kart (Tirr〇karb〇titan) and aluminum hot process. Titanium and aluminum. These alloying agents, especially iron and titanium, are very expensive. The analysis of iron and titanium shows that it is mainly composed of 20 to 75% by weight or more of Ti, and 2 to 1% by weight or more of Α1+Α12〇3. 'from 0. 2 to 8 wt% or more of Shi Xi, and from 20 to 65 wt% or more of Fe. For example, an iron carbon paper may have the following main composition·· Ti: 30 ~40%; C: 5~8%; Si: 3~4%; Al: 1~2%; Μη: 0.5%. For example, titanium|Lu can have the following composition of main components: 6 200844389
Ti : 5〜10%或50〜63%，其餘為a卜 這種合金劑利用高價材料取代可大大改善輻射線產生 的經濟性。 使用鈦在現代鋼及鑄鐵中的主要理由係將沃斯田式鉻 /鎳/鋼安定化以防形成裂縫以及將鑄鐵中石墨封入物的 情形細化。 由於在次級冶金的程序（往往持續很久，可達超過2 小時）因此盛桶（Pfanne )或容器的熔渣區域受到熔渣的 熱動力或運動作用很大的負荷。 盛桶須作早時之停工及高成本的修復。Ti: 5 to 10% or 50 to 63%, and the rest is a. This alloying agent is replaced by a high-priced material to greatly improve the economic efficiency of radiation generation. The main reason for using titanium in modern steel and cast iron is to stabilize the Vostian chromium/nickel/steel to prevent crack formation and to refine the graphite seal in the cast iron. Due to the secondary metallurgical process (which often lasts for more than 2 hours), the slag area of the Pfanne or vessel is heavily loaded by the thermal or kinetic action of the slag. The barrels must be used for early work stoppages and high cost repairs.
Kupol爐係一種豎道爐，金屬可在其中溶融，一般， Kupol爐用於製造金屬。在此，豎道爐由上送以焦炭（當 作能量攜帶物）、以及使用物料及附加物料。使用物料為 固體生鐵、循環材料、金屬片包裝及找出的金屬鋼屑 (Schrott )，各依生產目的而定。為了調整鐵分析的§丨含 量以及形成熔渣之有利的流動性質，故使用碳化矽、矽 (Kies )及石灰石製成的模製體當作附加物料。要將金屬 取出，須將爐略在其底上方之處放流，有一吸虹管接到放 流口，它有二個出口。在此，液體熔渣經上出口導入一捕 集谷态。鐵在熔渣下方經另一出口被壓通過，舉例而言， 可V入一個預保持爐中。由於在豎道爐有一些過壓力，故 吸虹器可發揮功能。 但熔融爐或豎道爐往往到了其極限，因此仍有急切需 要開發新賴的特別技術以應付冶金廢料的應用。 7 200844389 但在所有迄今用於處理廢物的習知方法，由冶金循環 物料（例如鋅、鈉、鉀、鉛、銅、釩等）造成的污染問題 仍存在。要處理的廢料越多，則這些不想要的物質量越多。 這點特別使用耐火的外牆材及骨材的耐久性（Haltharkeit ) 大大減少。 ^ ^ ^ …^八1 mp乃汰铞邗的豎迢爐中使 用製成的壓坯（Pressling )，其組成係由不同的廢料物質 構成，例如含鐵的灰塵、還原劑、熔渣形成劑、以及結合 劑，這種技術的目的使一般在高爐程序中進行的熔= (Verhiittung )程序能在個別壓製的模製體本身中進行。 因此塵狀的氧化鐵攜體（它們在所有的精煉程序總是再出 現者）可作較佳之處理，沒有這些技術，則可再使用的灰 塵的比例較少，因此需要再作一道污染環境的廢棄處理。 斤：：7使用的壓坯含有上述有害的金屬循環物料， 4外，當這些廢物作熱處理時， ^ (氮氧化物s〇2(i化〜t 廢㈣含N〇x 法中，有害的循環物料有辞、錯、納和卸。 ^ 由於鋅的熔點及沸點低， 在爐喉Wts⑽）中^ =—種不利性質’即會 入循環程序時，往往再;ΛΓ 時往往再重新進 們與固體耐火外牆接觸）备減?:::序。這種鋅粒子(它 虹管從去。，辛的負面作用變得無害，另外將鋅從吸 錯由於比重大 會造豎道爐的低作用 侵入外牆的孔 8 200844389 隙中並在該處造成破壞。 驗金屬如鈉與鉀由於需要酸性熔渣以從爐帶出，故會 妨生鐵的除硫作業，該除硫作業本身需要儘量鹼性的熔 產。XI些相反的需求大大妨礙高爐程序。此外，鹼金屬物 貝對於各防火的外牆有助熔劑（)的作用，這點 又對經濟性有很有不利的影響。 一些兀素：銅、鉻、鎳、釩近乎完全溶在液態生鐵中， j此它們即使在隨後的製鋼程序也不能除去，此處也要在 前場（Vorfeld)中將這些含量儘可能地減少。 ^ 所有的豎道爐使用焦炭當作能量攜帶體。在此，焦 炭的雜質還有不想要的硫。由 …、 文J瓜田於焦石反燃收，液態的鐵吸收 了—些硫成分，它對進一步的加 °加有干擾作用。因此鐵須 在初級及/或次級冶金的特 作除硫作業。 的特殊-備中化大成本且很麻煩地The Kupol furnace is a vertical furnace in which metal can be melted. Generally, a Kupol furnace is used to make metal. Here, the vertical furnace is supplied with coke (as an energy carrier), as well as materials and additional materials. The materials used are solid pig iron, recycled materials, sheet metal packaging and metal scraps (Schrott), depending on the purpose of the production. In order to adjust the § 丨 content of the iron analysis and the favorable flow properties of the slag, molded bodies made of tantalum carbide, kies and limestone were used as additional materials. To remove the metal, the furnace must be discharged slightly above the bottom, and a suction tube is connected to the discharge port, which has two outlets. Here, the liquid slag is introduced into a trapped valley state via the upper outlet. The iron is forced under the slag through another outlet, for example, into a pre-retaining furnace. The suction absorber can function because there is some overpressure in the vertical furnace. However, melting furnaces or vertical furnaces often reach their limits, so there is still an urgent need to develop new technologies to cope with the application of metallurgical waste. 7 200844389 However, in all the conventional methods used to treat waste, pollution problems caused by metallurgical recycling materials (such as zinc, sodium, potassium, lead, copper, vanadium, etc.) still exist. The more waste you have to deal with, the more the quality of these unwanted items. This is particularly the use of refractory exterior wall and the durability of the aggregate (Haltharkeit) is greatly reduced. ^ ^ ^ ...^八1 mp is used in the kiln of the kiln, which is made of different waste materials, such as iron-containing dust, reducing agent, slag forming agent. As well as binders, the purpose of this technique is to enable the Veriittung process, which is typically performed in blast furnace processes, to be carried out in individual pressed molded bodies themselves. Therefore, dusty iron oxide carriers (which are always reappearing in all refining processes) can be better treated. Without these techniques, the proportion of reusable dust is small, so it is necessary to make another environmental pollution. Dispose of.斤::7 The compact used contains the above-mentioned harmful metal circulating materials, 4, when these wastes are heat treated, ^ (nitrogen oxide s〇2 (i ̄~t waste (d) containing N 〇 x method, harmful Circulating materials have words, errors, nano and unloading. ^ Due to the low melting point and boiling point of zinc, in the throat Wts (10)) ^ = - an unfavorable property 'will enter the cycle program, often again; 往往 often re-enter Contact with solid refractory exterior wall)?::: Preface. This kind of zinc particles (it's a rainbow tube from the go., the negative effect of Xin becomes harmless, and the zinc is intruded from the hole in the hole 8 200844389 due to the low effect of the specific gravity of the assembly of the vertical furnace and is caused there. Destruction. Metals such as sodium and potassium require acid slag to be taken out of the furnace, so it will hinder the desulfurization of iron. The desulfurization operation itself needs to be as alkaline as possible. Some of the opposite requirements greatly hinder the blast furnace program. In addition, the alkali metal shell has a flux () effect on the fireproof outer wall, which has a negative impact on the economy. Some alizarins: copper, chromium, nickel, vanadium are almost completely dissolved in the liquid state. In pig iron, j, they cannot be removed even in the subsequent steelmaking process, and these contents are also reduced as much as possible in the front field (Vorfeld). ^ All vertical furnaces use coke as an energy carrier. The coke impurities also have unwanted sulfur. By..., J. Guatian is defogged in coke, and the liquid iron absorbs some sulfur components, which interferes with further addition of °. Therefore, iron whiskers are at the primary level. And/or secondary smelting Special Patent for sulfur removal operations - Preparation of the large cost and cumbersome to
L赞明内容J 本發明的目的在於將先前技術的缺點克服 用3成及/或天然的鈦載體以將上…寺别使 伴隨物料的含量以及鐵中 、、循環物料或 备# Mn 的與^的含量減少（兮f盥石山 曰使ΝΟχ的形成作用減少 ^亥虱與石厌 本發明另一目的在於 、保4 % i兄。 高。 將耐火外牆與骨材的耐久性提 出手忍料地’這也b曰// 點達成。 的可㈣巾請專利範圍主項的特 200844389 样-本^明’忒含鈦之模製體含有合成及/或天然的鈦 :::體。在此「鈦攜帶體」-詞指-些物料，它們含有鈦， 二：呈元素鈇、化合物的鈦、及/或鹽的成分。該合成 及(或天 <然的鈦攜帶體與其他物料均句混合，然後利用— 逼賦形程序（例如做成隹余 成木塊石、磚塊、丸粒或壓製石形式） 力口 〇 依本發明也可使用主斤 八▲ 要由二氧化鈦或其化合物構成的 含鈦模製體。 本發明的含鈦模製體令古Μ ^ 聪3有的丁1(^2為0.5〜100重量％， 且且1〜90重量％，尤宜1〜 曰 80重I %，特宜3〜70重量 4，更宜4〜65重量％，尤^ 尤其疋4〜50重量％，最宜5〜30 重里％ (係由總鈦含量計管、 田 、 T开），依本發明，此模製體特別 於初級、次級及三級冶金領域在熔融爐及置道爐中。 來在化千工業之合成原料利用不同的化學結合劑丸粒 ί，或在燒結程序中成形成可充料的鈦攜帶體，且在次級 化金的各程序充料到液體介f，如金屬液或溶潰。 S使用者的各設備系續右古 予、、死有充分的吹入設備時，也可將 合成之鈦攜帶體吹入當作合金劑。 t種量各配合需求以及拌合（Gattierung)的計算。 、适些合成之鈦攜帶體溶在液態金屬或溶逢中，且各依 需求增加各欽含量。 依本發明’合成之鈦攜體有45〜55%，80〜90%，以 及1〇〇%的ίπο2可用。 當Tl〇2的氧含量係不利者時（例如在真空設備外）， 10 200844389 使可使用以TiCN、氮化鈦或碳化鈦為基礎的合成之鈦攜帶 體’可各依需求而定有變通性。 如果原料呈模製體形式，則對於熔融爐或豎道爐的送 料很有利。如此，舉例而言，可使用磚塊形式的碳化矽^ 乍p〇i爐（KuP〇ifen)的送料。依先前技術，這些模體 =>可以用工業上要作廢棄處理的「使用物料」為基礎而製 斤用之工業使用物料」的例子有煤炭及炭泥、含碳 化矽的殘餘物、爐喉及鋼廠灰塵以及鋼廠污染及其他物 該爐喉（Gicht)及鋼廠灰塵及污泥含有很多塊，但如 果它們呈集塊的固體形式充入豎坑爐，則只能由它們製得 ^鐵。為此開發出一些方法，藉之從灰塵利用結合劑製造 「所謂的集塊石」。在該固體壓製過程之前，將各種要作 廢棄處理的及要熔煉（verhiuten)的使用物料和熔渣形成 劑、結合劑以及以碳為基礎的還原劑混合。 【實施方式】 要製造本發明之含鈦的模製體，使用的含鈦材料由以 下之物遥出· Λ然鈦礦、富含二氧化鈦的熔渣、以及合成 之含鈦材料，或至少二種這些材料的混合物。 -成之έ 氧化鈇的材料，依本發明係由以下所述之 材料或其混合物選出： --來自二氧化鈇製程的中間產物、_合產物及/或完工 產物在此這些材料係可來自依硫酸鹽方法的製程的 11 200844389 二氧化鈦以及來自依氣化物 切方法的製程的二氧化鈦， 中間產物和耦合產物可從進 疋仃中之Τι〇2生產流程抽 出。 ——製造二氧化鈦製程的殘餘 ^ 在此，這些材料可來自 依硫酸篮法的二氧化鍅 欽氣造（採掘殘餘物） (Aufschluflrlickstand)以及爽白价友 久木自依虱化物方法的二氧 化欽製程的產餘物；如果有必 要 δ亥材料在當作助炫 劑使用前作預處理，例如利 不』用中和、清洗、及/或預 乾燥。 一一來自化學工的殘餘物，例如夾 u水自含Τι〇2的催化劑，例 如來自DENOX催化劑者。 --來自硫酸生產的產餘物，所謂的燃渣（杨⑻）， 它們在過遽器鹽（硫酸鐵）以分解時產生，除了含氧 化鐵外還含二氧化鈦。 本發明的含鈦模製體的製造可藉著將天然鈦礦混合及 /或加入而製&，天然鈦礦的例子有褐鐵礦砂及/或索瑞 耳（Sorell)丈谷〉查、富含—童於j士 a 田a —虱化鈦的熔渣、及/或合成之 含二氧化鈦的材料。 如有必要，可在這些含鈦材料中加入其他材料例如 工業要作廢棄處理的使用物料及，或還原齊卜例如以碳為 基礎者，如含碳化矽的殘餘物、碳與碳泥、爐喉、及鋼廠 灰塵及污泥以及其他物料。 要製造本發明的含鈦模製體，係在利用壓製、壓磚、 壓丸粒而賦形之前，蔣_ 4圭斗、金冬括μ、+、 J财種或數種上述之細粒含鈦材料加 12 200844389 到、、、田粒之使用材料」構成的混合物。如此所得的混合物 利用結合劑壓製成本發明的模製體。 用於製造本發明的含鈦模製體所用的鈦礦石及富含二 ，化鈦的熔渣所含Ti〇2為15〜90重量％，且宜25〜85重 1% (由總鈦含量計算）。鈦礦石可以不作純化而使用或 在將雜貝除去且將製造助溶劑的礦皮（脈石）（Gangart， 英：gangue)除去後使用。 r 製造本發明的含鈦模製體所用的合成之合鈦材料所含 之Ti02為5〜10〇重量％，且宜ι〇〜ι〇〇重量％，尤宜 1〇〇重$ % (由總鈦含量計算）。 此外本發明的標的還有： 利用本毛明的含鈦模製體以提高耐火系統的使用壽命， φ ^本發明的含鈦模製體以減少氮氧化物及硫， 才本毛月的含鈦模製體以減少在氮氧化物程序時的不 2要的伴隨物質，例如在初級冶金領域熔融爐或豎道 中的程序， 夏 使用本發明的含欽模製體當作㈣防護劑及合金劑。 利用本發明可提供： 一種含鈦模製體以 級口金私$ 4 寺別是用於熔融或初 、及—人級、三級冶金的爐體， 命 種3鈦枳製體以加入豎道爐以提高爐外 牆的使用壽 ===::=:::=二 13 200844389 •種3鈦^製體以加人豎道、爐中以及溶融爐中，例如初 、 、及一級冶金的爐體，以提高各耐火外牆的使用 壽命。 當本發明的此含二氧化鈦的模製體裝入豎道爐中時， 該模製體在冶金的精煉程序時加熱。在模製體巾含的還原 劑將豎道的氧化性成分還原。這點係發生到氧化鐵及先前 混到石材料的鈦化合物上。在此，模製體中的還原劑在有 天然礦鈦存在時〔例如褐鐵礦（在褐鐵磺中，鈦呈鈦酸鐵 形式存在）〕在第一步驟還原成反應性的Ti〇2，然後，所 得之Tl〇2作最終還原成co及金屬鈦。 在合成欽攜帶體的場合這種反應係立刻達成，因為鈦 主要呈Ti〇2形式存在。如此還原成金屬鈦的元素在最後 的步驟反應成極高耐火的碳化鈦、氮化鈦、及/或氮化碳 鈦。此外，形成高度耐火之具有鋁、鎂、鈣的化合物，例 如鈦酸鋁、鈦酸鍈及鈦酸鈣。此外還形成含鈦的金屬氧化 物尖晶石（Spinelle)。然後，該模製體在熔煉程序的過程 反應’且溶解’形成一種細的鐵熔渣混合物。在此，乳化 在其中的碳化鈦、氮化鈦、氮化碳鈦或鈦酸金屬鹽和尖晶 石在那些液體與耐火外牆接觸的地方沈積。當這些超細粒 子沈積在所要保護的表面上時，形成極耐火且較厚的層， 由氮化碳鈦、鈦酸金屬鹽和尖晶石構成。此沈積的層可修 補有缺陷的位置以及無缺陷的區域以防止液體如鐵或熔渣 穿透，且因而使得使用壽命大大提高，保護作用特別也到 達暨道爐内部，例如在放流通道或吸虹管構造内。 14 200844389 當使用本發明的含鈦模製體當作熔渣防護劑時，可藉 加入鈦攜帶體（宜加入合成之鈦攜帶體）到鐵與鋼工業的 不同的次級及三級熔渣，以將盛鋼桶的熔渣區域中之快速 的磨損減少或完全防止。 此程序用以下方式實現：將該液體系統藉著吹入或充 入和粒結合物（由合成鈦攜帶體構成）與熔渣内存在之由 锅及/或㉟及/或！s及/或鎂構成的化合物形成不同之高 度而ί火的欽酸鹽。 用於利用冶金的沖刷程序，使溶潰與金屬作大幅運動， 因此該含鈦酸鹽的m該盛桶中的熔渣區域的快速磨損 的區域作永久性接觸。如此該高度耐火的鋇-鈣-鎂及或鋁 的鈦酸鹽沈積在各接觸區域，且減少或防止—盛鋼桶的重 要區域的磨損。 該不同之鈦攜帶物的保護功能的這種變更方式的優點 在於：即使在氧化性的系、统，炼融爐的所要保護之耐火外 牆的耐火牆度由於各種鈦酸鹽或鈦化合物而提高。 不想要的伴隨物質，例如鋅、錯、納、鉀等，藉用含 鈦之攜帶體而結合成鈦酸金屬鹽，且因此可呈熔渣成分的 方式從豎道爐除去。 文到二乳化鈦之催化活性影響，以及受鈦容易與氮作 用形成氮化碳鈦的傾向影響，—方面，產生的氧化氣可受 催化還原成氮另方面有利於形成而彳高溫的氮化鈦、氣化 碳鈦及/或氧氮化鈦’這點有一好處，即有害的氧化氮可 從廢氣除去。 15 200844389 此外，存在鐵中的硫與鈦形成各種不 們隨後呈熔渣成分從豎坑爐除去。 所用天然鈦攜帶體宜為褐鎮礦及/或 熔渣，所用合成之含鈦攜帶體為鈦化合物 鈦。此外，依本發明可將依硫酸鹽方法或 得的二氧化鈦的殘餘物。依發明也可將， 料’如來自DENOX設備的催化劑或來自 加以利用。 【圖式簡單說明】 益 【主要元件符號說明】 益 同的硫化鈦，它 索瑞耳（Sorell ) ，特別是二氧化 氯化物方法製程 &二氧化鈦的廢 化學工業的廢料 16L. Appropriate Content J The purpose of the present invention is to overcome the disadvantages of the prior art by overcoming the use of a 30% and/or natural titanium carrier to increase the content of accompanying materials and the presence of iron, recycled materials or Mn. The content of ^ is reduced (兮f盥石曰曰 reduces the formation of ΝΟχ ^ ^ 虱 虱 石 石 石 石 石 石 石 石 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一 另一The material 'this is also b曰 / / point reached. The four (4) towel please patent section of the main item of special 200844389 sample - this ^ Ming '忒 titanium containing molded body containing synthetic and / or natural titanium ::: body. Herein, "titanium carrier" - the term refers to a material which contains titanium, two: a component of elemental cerium, a compound of titanium, and/or a salt. The synthesis and (or day < The materials are mixed and then used - forcing the shape of the program (for example, in the form of slabs of slabs, bricks, pellets or pressed stones), or according to the invention, it is also possible to use TB or ▲ The titanium-containing molded body is composed of the titanium-containing molded body of the present invention. D (1) is 0.5 to 100% by weight, and 1 to 90% by weight, particularly preferably 1 to 曰80% by weight, particularly preferably 3 to 70% by weight, more preferably 4 to 65% by weight, especially ^ 4 to 50% by weight, most preferably 5 to 30% by weight (based on the total titanium content of the tube, Tian, T open), according to the invention, the molded body is particularly in the primary, secondary and tertiary metallurgical fields in the melting furnace And the furnace in the furnace. The synthetic raw materials used in the chemical industry use different chemical binders, or form a rechargeable titanium carrier in the sintering process, and fill the various procedures in the secondary gold. To the liquid medium f, such as molten metal or molten. The equipment of the S user can continue to be blown into the equipment, and the synthetic titanium carrier can be blown into the alloy. According to the invention, the synthetic titanium carrier has 45~55%, 80~90%, and 1%% ίπο2 available. When the oxygen content of Tl〇2 is unfavorable (for example, outside the vacuum equipment) , 10 200844389 It is possible to use a synthetic titanium carrier based on TiCN, titanium nitride or titanium carbide, which can be modified according to requirements. If the raw material is in the form of a molded body, it is used for a melting furnace or a vertical furnace. The feeding is advantageous. Thus, for example, a feed of a carbide 形式p〇i furnace (KuP〇ifen) in the form of a brick can be used. According to the prior art, these phantoms can be discarded industrially. Examples of industrial use materials based on the "use of materials" used are coal and charcoal, residues containing niobium carbide, dust from steel and steel mills, and pollution from steel mills and other materials (Gicht) And the steel mill dust and sludge contain a lot of pieces, but if they are filled into the vertical pit furnace in the form of solid blocks, they can only be made of iron. To this end, some methods have been developed to make "so-called agglomerates" from dust-using binders. Prior to the solid pressing process, various waste materials to be disposed of and to be smelted are mixed with a slag forming agent, a binder, and a carbon-based reducing agent. [Embodiment] To manufacture the titanium-containing molded body of the present invention, the titanium-containing material used is remotely removed from the following materials: cuminite, titanium dioxide-rich slag, and synthetic titanium-containing material, or at least two A mixture of these materials. - 成 έ 鈇 鈇 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的The process according to the sulphate process 11 200844389 Titanium dioxide and the titanium dioxide from the process of the gas-cutting process, the intermediate product and the coupling product can be extracted from the Τι〇2 production process in the mash. - Residues in the manufacture of titanium dioxide processes. Here, these materials can be obtained from the sulphur dioxide basket method of sulphur dioxide (Excavation Residues) (Aufschluflrlickstand) and the whitening process of the sapphire method. The remainder of the product; if necessary, the δ hai material is pretreated before use as a stimulant, such as neutralization, cleaning, and/or pre-drying. Residues from chemical workers, such as those containing water from Τι〇2, such as those from DENOX catalysts. - Residues from the production of sulphuric acid, so-called slag (Yang (8)), which are produced when the sulphuric acid salt (ferric sulphate) is decomposed, and contains titanium dioxide in addition to iron oxide. The titanium-containing molded body of the present invention can be produced by mixing and/or adding natural titanium ore. Examples of natural titanium ore are limonite ore and/or Sorell. It is rich in children's slag, and/or synthetic titanium dioxide-containing materials. If necessary, other materials may be added to these titanium-containing materials, such as materials used in industrial waste disposal, or reduced, such as carbon-based, such as residues containing cerium carbide, carbon and carbon sludge, furnaces. Throat, and steel mill dust and sludge and other materials. In order to manufacture the titanium-containing molded body of the present invention, before the forming is performed by pressing, pressing, and pressing pellets, the above-mentioned fine particles include titanium. Material plus 12 200844389 A mixture of materials used in, , and granules. The mixture thus obtained was pressed with a binder to the molded body of the invention. The titanium ore used in the manufacture of the titanium-containing molded body of the present invention and the titanium-rich slag containing Ti2 are 15 to 90% by weight, and preferably 25 to 85% by weight (by total titanium content). Calculation). The titanium ore may be used without purification or after removing the miscellaneous shells and removing the ore (gangue) (Gangart) from which the cosolvent is produced. r The synthetic titanium material used for producing the titanium-containing molded body of the present invention contains TiO 2 in an amount of 5 to 10% by weight, and preferably 〇 〇 to 〇〇 〇〇 by weight, particularly preferably 1 〇〇 by weight %. Total titanium content is calculated). In addition, the subject matter of the present invention is as follows: the titanium-containing molded body of the present invention is used to improve the service life of the refractory system, and the titanium-containing molded body of the present invention is used to reduce nitrogen oxides and sulfur, and is included in the present invention. Titanium molded body to reduce the accompanying substances in the oxynitride process, for example, in the melting furnace or vertical path of the primary metallurgical field, and the use of the molded body of the present invention as the (four) protective agent and alloy in summer Agent. The invention can provide: a titanium-containing molded body with a grade of gold private $4 Temple is used for melting or primary, and - human-grade, tertiary metallurgical furnace body, life 3 titanium tantalum body to join the vertical Furnace to improve the service life of the furnace wall ===::=:::=2 13 200844389 • Kind of 3 titanium ^ body to add people in the vertical, furnace and melting furnace, such as primary, and primary metallurgical Furnace body to improve the service life of each refractory exterior wall. When the titania-containing molded body of the present invention is placed in a vertical furnace, the molded body is heated during a metallurgical refining process. The reducing agent contained in the molded body towel reduces the oxidizing component of the vertical channel. This occurs on the iron oxide and the titanium compound previously mixed into the stone material. Here, the reducing agent in the molded body is reduced to a reactive Ti〇2 in the first step in the presence of natural ore in the presence of titanium (for example, limonite (in the form of iron ferric oxide, titanium is present in the form of iron titanate)] Then, the obtained Tl〇2 is finally reduced to co and titanium metal. This reaction is achieved immediately in the case of the synthesis of the carrier, since titanium is mainly present in the form of Ti〇2. The element thus reduced to titanium metal is reacted in the final step into extremely high fire resistant titanium carbide, titanium nitride, and/or titanium carbonitride. Further, a highly refractory compound having aluminum, magnesium, and calcium, such as aluminum titanate, barium titanate, and calcium titanate, is formed. In addition, a titanium-containing metal oxide spinel (Spinelle) is formed. The molded body then reacts & dissolves during the smelting process to form a fine iron slag mixture. Here, the titanium carbide, titanium nitride, titanium carbonitride or titanate metal salt and spinel emulsified therein are deposited where those liquids come into contact with the refractory outer wall. When these ultrafine particles are deposited on the surface to be protected, a very refractory and thick layer is formed which is composed of titanium carbonitride, a metal titanate and a spinel. The deposited layer repairs defective locations as well as defect-free areas to prevent penetration of liquids such as iron or slag, and thus greatly increases the service life, particularly in the interior of the kiln, such as in the discharge channel or suction Inside the rainbow tube structure. 14 200844389 When using the titanium-containing molded body of the present invention as a slag protectant, it is possible to add a titanium carrier (preferably a synthetic titanium carrier) to different secondary and tertiary slags in the iron and steel industry. To reduce or completely prevent rapid wear in the slag area of the ladle. This procedure is accomplished by infusing or filling the liquid system by means of a blown or filled granule (consisting of a synthetic titanium carrier) with slag and/or 35 and/or! Compounds composed of s and/or magnesium form different high-degree sulphuric acid salts. For the use of a metallurgical flushing procedure to cause a large movement of the melt with the metal, the titanate-containing m is in permanent contact with the rapidly worn areas of the slag zone in the tub. Thus, the highly refractory strontium-calcium-magnesium and/or aluminum titanate are deposited in the various contact areas and reduce or prevent the wear of important areas of the ladle. The advantage of this modification of the protective function of the different titanium carrier is that even in the oxidizing system, the refractory wall of the refractory outer wall to be protected by the smelting furnace is due to various titanates or titanium compounds. improve. Unwanted concomitant substances, such as zinc, argon, sodium, potassium, etc., are combined into a titanate metal salt by means of a titanium-containing carrier, and thus can be removed from the vertical furnace in a slag composition. The influence of the catalytic activity of the second emulsified titanium and the tendency of titanium to easily form a carbonitride titanium with nitrogen, in which the generated oxidizing gas can be catalytically reduced to nitrogen and further facilitated formation and high temperature nitriding. Titanium, vaporized carbon titanium and/or titanium oxynitride have the advantage that harmful nitrogen oxides can be removed from the exhaust gases. 15 200844389 In addition, there is a variety of sulfur and titanium in the iron that are subsequently removed from the pit furnace. The natural titanium carrier used is preferably brown mineral and/or slag, and the synthetic titanium-containing carrier used is titanium compound titanium. Further, residues of titanium dioxide obtained by the sulfate method or according to the present invention may be used. It is also possible, depending on the invention, to use a catalyst such as from a DENOX plant or to utilize it. [Simple description of the diagram] Benefits [Description of main component symbols] Advantages of titanium sulfide, it is Sorell, especially the process of chlorine dioxide process & titanium dioxide waste Chemical industry waste 16