TW200837121A - Non-reactive, chlorine-free composition - Google Patents

Abstract

The present invention relates to non-reactive compositions comprising (A) amorphous poly-α-olefins which contain no organically bound chlorine and have an enthalpy of fusion in the range from 0 to 80 J/g, (B) ketone resins, ketone/aldehyde resins and/or urea/aldehyde resins and/or their hydrogenated derivatives, (C) solvents and (D) if desired auxiliaries and/or additives, and to their use as primers for promoting the adhesion of coating materials such as paints, varnishes, adhesives and sealants and also inks, including printing inks, for example, to plastics and glass.

Description

200837121 IX. INSTRUCTIONS OF THE INVENTION [Technical Field] The present invention relates to a non-reactive composition comprising A) an amorphous poly-α-olefin which does not contain organically bonded chlorine and has from 0 to 80 J a ketone resin, a ketone/aldehyde resin and/or a urea/aldehyde resin and/or a hydrogenated derivative thereof, a C) solvent and D) if necessary, an adjuvant and/or Additives; and the like as primers for promoting the adhesion of coating materials (such as paints, varnishes, adhesives and sealants) and inks (including, for example, printing inks) to plastics and glass. [Prior Art] It is known that a mixture of a ketone or a ketone reacts with an aldehyde to form a resinous product in the presence of a basic catalyst or an acid. For example, a mixture of cyclohexanone and methylcyclohexanone can be used to prepare a resin (Ullmann, Vol. 12, p. 551). The reaction of ketones and aldehydes usually yields hard resins which are commonly used in the coatings industry. At present, industrially important ketone-formaldehyde resins are conventionally prepared by using formaldehyde to prepare an anthrone-formaldehyde resin. The preparation methods are described, for example, in DE 102006009080.2 and the patents cited therein. The preparation is usually carried out by reacting a ketone with formaldehyde in the presence of a base. The oxime resin, the ketone/aldehyde resin and/or the urea/aldehyde resin and the hydrogenated derivatives thereof are applied to the coating material as, for example, a film formation. Additional components, to -5 - 37,710,121 to improve specific properties 'such as initial drying rate, gloss, hardness or scratch resistance. Due to their relatively low molecular weight, typical ketones, ketone/aldehydes and/or urea/aldehyde resins and/or their hydrogenated derivatives have low melt viscosity and solution viscosity and are therefore used in the coating material components. The film forms a functional 'sexual dip. As a result of, for example, sun exposure, the carbonyl group of the ketone/aldehyde resin will undergo a conventional degradation reaction (e.g., Norrish type I or II). φ Therefore it is not possible to use unmodified ketone/aldehyde resins or ketone resins for high quality applications in the outdoor field, such as where high resistance properties are required (especially for weathering and heat). These disadvantages can be improved by hydrogenating the carbonyl group. The conversion of a carbonyl group to a secondary alcohol by hydrogenation of a ketone-aldehyde resin has been used for a long time (DE 870 022). It is also possible to prepare a ketone-aldehyde resin based on carbonyl hydrogenation and cyclohydrogenation of a ketone containing an aromatic group. This type of resin is described in DE 1 02006026758.3 or DE 1 0 2 0 0 0 0 2 6 7 6 0.5. Φ Most of the amorphous poly-α-olefins are well known. Indeed, DE-A-1 442 83 1 describes a catalyst system consisting of a reaction product of a titanium trihalide with an aluminium compound on the one hand and an oxyhydrogen titanium on the other hand. An amorphous polyolefin copolymer can be obtained by using this catalyst system. It is known from DE-A-23 06 667 that most of the amorphous poly(1-butene) polymers can be prepared by a low pressure polymerization process, which contains, if necessary, other olefins at 40 to 1 2 (At the TC temperature, 1 -butene is polymerized in a solution using a mixed catalyst composed of TiCl3·nAlCl3 (n = 0.2 - 0.6) and an appropriate triterpene. -6 - 200837121 DE-A-29 30 In a similar manner, a mixed catalyst composed of TiCl3 • nAlCl3 (η = 0·3 — 0·35 ) and trialkylaluminum as a cocatalyst was used again to prepare a large portion having a high softening point. Amorphous 1-butene-propylene-ethylene terpolymer. DE-A-26 37 990 describes a terpolymer having an amount of propylene of at least 93.2% by weight and an ethylene fraction of not more than 1.9 % by weight. And no more than 4.9 % by weight of the 1-butene portion, wherein a TiCl 3 mixed catalyst called a "activator" and a catalytic catalyst are used. In these applications, no reference is made to poly-α. - olefin, and ketone resin, ketone / aldehyde resin and / or urea / aldehyde resin and / or their hydrogenated derivatives based primer group A product that imparts good adhesion to untreated plastics. For non-polar plastics, they are usually pretreated to give the coating a high enough adhesion to the plastic. For example, plastics containing polyolefins, such as Polyene (ΡΡ), modified polypropylene (such as polypropylene-ethylene copolymer), polyethylene (Ρ Ε ), modified ρ Ε, mixture (such as polypropylene / ethylene-propylene with low EPD Μ content -Diene blends (PP/EPDM), ruthenium/ruthenium blends or special polyesters) are pretreated by specific methods to cause the coating material to adhere to the plastic. Typical methods are flame treatment, corona Discharge, gas phase fluorination or plasma treatment. These methods cause partial oxidation of the plastic surface, so the surface tension is increased. This result can cause subsequent coatings or adhesives to form an intermolecular interaction with the matrix, thereby enhancing adhesion. The disadvantage of these methods is the high cost and in fact the effect of the pretreatment will decrease in a relatively short period of time (days to weeks). Moreover, the corona pretreated 200837121 plastic has a knot. Sexual tendency, so this pretreatment method can in principle only be applied on-line with a coating material. It is also possible to use, for example, other methods of adding an adjuvant during the manufacture of the plastic to promote adhesion. The disadvantages of these methods are considerable cost and In fact, 'lower molecular weight adjuvants can cause problems during the manufacture of plastics and can adversely affect physical properties such as mechanical strength. Another pretreatment option is to apply the primer before applying the coating material. US 2003/05 5 1 63 describes a binder composition comprising a chlorinated and COOH-containing polyolefin and a ketone resin. JP 46027878 likewise describes a composition in which the ketone resin likewise contains chlorinated polyolefin. Products containing organically bonded chlorine will release hydrochloric acid and, for example, highly toxic dioxin during combustion. As a result, such methods are not applicable based on occupational health care and environmental reasons. SUMMARY OF THE INVENTION One subject of the present invention is to find a composition based on a poly-α-olefin and a ketone, a ketone/aldehyde and/or a urea/aldehyde resin and/or a hydrogenated derivative thereof. The coating material is excellently adhered to the unpretreated plastic. The composition must be free of chlorine and must exhibit rapid initial drying and high anti-caking properties. The effect of the pretreatment must also be maintained for a long period of time, so it may be possible to selectively pretreat directly after the plastics manufacturer's location (offline) or directly before the application of the coating material (line 200837121). According to the patent application, it is surprising that the subject matter based on the present invention can be achieved by using poly-α-olefins and ketones, ketones/aldehydes and/or ureas before applying the coating material. The aldehyde resin and/or their hydrogenated derivative-based primer composition is applied to the plastic, and these compositions are described in more detail below. The composition of the present invention does not contain organically bonded chlorine relative to the previous case. They exhibit rapid initial drying and high anti-caking properties. The pretreatment effect can also be maintained constant over a long period of time. The compositions of the present invention are therefore particularly useful for promoting adhesion of coating materials to plastics. The present invention provides at least one non-reactive poly-α-olefin containing no organically bonded chlorine and substantially containing the non-reactive composition shown below A) by weight of 1% to 98% by weight, which does not contain an organic bond Chloride and having a fusion enthalpy in the range of 0 to 80 J/g, and B) 1% to 98% by weight of at least one ketone resin, ketone/aldehyde resin and/or urea/aldehyde resin and/or The hydrogenated derivatives 'and C) are from 1% to 98% by weight of at least one solvent 'and, if necessary, D', up to 7% by weight of at least one adjuvant or adjuvant, component A) to The total weight of D) is 100% by weight. It has been found that the following combination of compositions consisting of components A) to D) meets all required criteria. 200837121 Component A) The necessary component of the innovation, A), is used in an amount of from 1% to 98% by weight, preferably from 1% to 49%, more preferably from 1% to 40%. It is in principle suitable for all polyalpha_steams which are swellable and/or soluble in organic solvents. These poly-α-olefins may be non-reactive poly-α due to modification (for example, using maleic anhydride) carrying functional groups or most non-functional groups (pure hydrocarbon polymers) as component A) An olefin which does not contain organically bonded chlorine and which has a enthalpy of fusion in the range from 〇 to 80 J/g and is therefore mostly amorphous. The non-reactive and mostly amorphous poly-α-olefin may be a homopolymer or a copolymer, such as a miscellaneous polypropylene (ΑΡΡ), a miscellaneous polystyrene, or preferably having the following list Copolymers and/or terpolymers of body composition: a) from 0.5% to 100% by weight, preferably from 1% to 99%, more preferably from 10% to 98%, or from 4 to 20 Alpha-olefin of carbon atom, b) 1% to 99.5% by weight, preferably 1% to 99%, more preferably 2% to 90% propylene, and c) 〇% to 50% by weight Preferably from 0% to 20% of ethylene, the poly-α-olefin has: • a weight average molecular weight of from 2,000 to 500,000 g/mol, preferably from 5,000 to 300,000 g/mol, more preferably from 7,500 to 200,000 g/mol. ' -10- 200837121 • 2.0 to 60' is preferably 2.5 to 40, more preferably 2.5 to 30, more dispersible PD, • - 80 to 0 ° C, preferably -60 to 0 ° C, more preferably -55 to -1.玻璃 glass transition temperature Tg, • in the range from 〇 to 80 J / g, preferably in the range of 1 to 70 J / g •, more preferably in the range of 1 to 60 J / g The combination of enthalpy, and • the substantial solubility and/or swelling rate in a non-polar solvent. Φ The properties of these poly-olefins include all possible variations between the above numbers, such as 2.5 to 30 (minimum range) PD and -80 to 〇 °C (maximum range) Tg. For the α-olefin having 4 to 20 carbon atoms, it is preferred to use 1-butene, 1-pentene, 1-hexene, 1-octene, 1-octene, 1-12, alone or in combination. Can, 1 18 burning, 3-methyl-1-butyl, methylpentene (such as 4-methyl-1-pentene), methylhexene, or methylheptene. Φ Molecular weight and polydispersity can be determined via high temperature GP C. The assay was performed according to ASTM D6474-99, but at a higher temperature (replaces 140 °C with 16 (TC) and 150 μl instead of a smaller injection volume of 300 // 1. The solvent used was trichlorobenzene. The measurement is carried out at a column temperature of 1 60 ° C. The general calibration used in this method and used to evaluate the dissolution profile is carried out according to the polyolefin standard. The result is related to an unrelated polymer (eg polystyrene-based polymer) Calibration based on or not universally calibrated is incompatible because it is not possible to compare polymer structures and/or hydrodynamic radii in different three-dimensional spaces. Similarly, the solvent used is different from the solvent -11 - The measurement of 200837121 is also incomparable because different polymer structures and/or hydrodynamic radii in different solvents may result in different molecular weight measurements. Polydispersity PD is defined as number average versus weight average Mohr mass ratio, which is a measure of the width of the mass distribution of the molar mass, which is relatively related to the presence of polymerization characteristics and to the catalyst used. In addition to being a measure, it is also a low molecular mass fraction that can affect the adhesive properties of the polymer material. Within certain limits, the polydispersity is a combination of special catalyst/catalyst. Characteristics. Depending on the step used (eg 1, 2 or more agitation tanks or a combination of agitation tank and flow tube), the molar mass distribution and reaction mode (single or multiple of catalyst, cocatalyst and monomer) Quantitative) can be unimodal, bimodal or multimodal. Polydispersity has a considerable influence on the viscosity and adhesion of materials at room temperature. In addition, molecular weight and polydispersity are solution viscosity, mechanical properties and adhesion properties. One of the factors that have a large impact. The lower the molecular weight, the lower the viscosity of the solution. However, there may be a negative effect on the mechanical properties at low molecular weights. Therefore, for optimum properties, the weight average molecular weight of component A) is 2000 to Between 500000 g/m〇l, preferably between 5,000 and 300,000 g/moi, more preferably between 7,500 and 200,000 g/mol; and a polydispersity of between 2.0 and 60, preferably between 2.5 and 40 Between 2 and 5 to 3 0 Room. The crystalline enthalpy, glass transition temperature and melting range of the crystalline portion can be determined by differential thermal analysis (DSC) according to DIN 53 765 at a heating rate of 1 〇 K/min from the second heating curve. The bending point of this heat flow curve was evaluated as the glass transition temperature by -12·200837121. The glass transition temperature can be controlled in a conventional method via monomer composition and reaction conditions. In general, using a longer chain of monomers results in a lower glass transition temperature. Similarly, the reaction conditions for shorter chain polymers (e.g., at relatively high polymerization temperatures) can be formed, which can also result in a decrease in glass transition temperature in certain instances. The low glass transition temperature Tg can advantageously affect (low temperature) elasticity, but is not conducive to anti-caking and rapid initial drying rate (solvent residence time). Thus the Tg of component A) is selected to be between -80 and 0 ° c, preferably between -60 and Ot:, more preferably between -55 and -10 °C. The fusion enthalpy is a measure of the crystallinity of the polymer. The polymers of component A) have a relatively low crystallinity, i.e. they are not completely but mostly amorphous. A certain degree of crystallinity is important to the physical properties required. The crystalline region is detected over a wide temperature range extending from 〇 to 1 75 °C during melting, and the strength varies with position. The polymers of component A) are excellent in that their crystallinity is not only a single peak but also a double peak and a multiple peak melting peak, some of which are distinctly separated but others are bonded to each other. The fusion enthalpy of the polymer of these components A) (as a measure of overall crystallinity) is between 0 J/g and 80 J/g, preferably in the range of 1 to 70 J/g, more preferably 1 Up to 60 J/g. The low crystallinity on the one hand achieves high transparency and on the one hand, it is possible to specifically combine excellent physical properties. The degree of low crystallinity shows a relatively high surface tack (adhesion) at room temperature. This makes their mechanical work more flexible overall. However, the adhesion of such materials is quite low, so this is why such low crystallinity is usually not the norm. Higher crystallinity can achieve a special combination of excellent properties -13- 200837121. The polymer of the present invention has a relatively high crystallinity' such as a polybutene or butene copolymer containing a high butene moiety having, for example, very good tensile strength. At the same time, their surface viscosity is quite low. The solubility and/or swellability in a non-polar solvent is necessary so that component A) can be processed. In one aspect, component a) must be homogeneously miscible in combination with components B) to D), while on the other hand the composition consisting of components a) to D) must be readily available to conventional methods (eg spray, Application in printed, flow curtain, drawdown or sponge applications). Solubility was determined by dissolving component A) in a 10% or 50% dilution of the individual solvent or solvent mixture at agitation and reflux temperature, and then cooling the solution to room temperature. The solubility of component A) in xylene is between 80% and 99.9%, preferably between 85% and 99.5% and more preferably between 90% and 99.0%. Further, component A) is soluble in an aromatic solvent (for example, toluene, benzene, cresol, naphthalene, tetrahydronaphthalene) and/or an aliphatic solvent and a solvent mixture (for example, decahydronaphthalene or hexane, alone or in combination). Heptane, cyclohexyl, Kristalloel, white spirits, terpentines, sarcophagus. Typical preparation methods and compositions for the preparation of such non-reactive and mostly amorphous poly-α-olefins are described, for example, in DE 40 00 695, DE 00 3 1 293 and WO 2006/060648. The component Β) is used in an amount of from 1% to 98% by weight, preferably from 1% to 49%, more preferably from 1% to 40% by weight. -14 - 200837121 These products are particularly concerned with rapid initial drying rates (improved solvent retention) and high resistance to caking. In addition, the use of component B) improves the compatibility with subsequent coating materials in wet-to-wet applications and improves adhesion of subsequent coatings to primer coatings. In particular, component A) of the composition of the invention improves solubility by the presence of component B) and improves flow and solids. Suitably, component B) has a ketone resin, a ketone/aldehyde resin and/or a urea/aldehyde resin and/or a hydrogenated derivative thereof, alone or in combination. In general, it is possible to use all of the ketones indicated in the literature for the synthesis of ketones and ketone-aldehyde resins, generally all C_H-acid ketones. Suitable ketones for the preparation of ketones and ketone-aldehyde resins (component B) include all ketones, more particularly individual or mixed acetone, acetophenone, methyl ethyl ketone, tertiary butyl ketone, g. a mixture of 2-ketone, pento 3-ketone, methyl isobutyl ketone, cyclopentanone, cyclododecanone, 2,2,4- and 2,4,4-trimethylcyclopentanone, Cycloheptanone and cyclooctanone, cyclohexanone, and all alkyl-substituted cyclohexanones having one or more alkyl groups and having a total of from 1 to 8 carbon atoms. Examples of the alkyl-substituted cyclohexanone include: 4-tert-butylpentylcyclohexanone, 2-secondary butylcyclohexanone, 2-tributylbutylcyclohexanone, and 4-terternary butyl ring. Hexanone, 2-methylcyclohexanone and 3,3,5-trimethylcyclohexanone. Preferred ketone-aldehyde resins are based on the following ketones: acetophenone, cyclohexanone, 4-13 butylcyclohexanone, 3,3,5-trimethylcyclohexanone, alone or in combination Heptone, and a ketone resin based on cyclohexanone. Suitable aldehyde components of the ketone-aldehyde resin (component B) include, inter alia, non-branched -15-200837121 chains or branched aldehydes such as formaldehyde, acetaldehyde, n-butyraldehyde and/or isobutyraldehyde, valeraldehyde and Dodecaldehyde. It is generally possible to use all of the aldehydes indicated in the literature for the synthesis of ketone resins. However, it is preferred to use formaldehyde alone or in combination. The desired formaldehyde is typically an aqueous or alcoholic (e.g., methanol or butanol) solution having a strength of from about 20% to about 40% by weight. Other forms of formaldehyde may also be used, for example using paraformaldehyde or trioxane. However, in principle all formaldehyde donor compounds are suitable. An aromatic aldehyde (e.g., benzaldehyde) can likewise be present in the mixture with formaldehyde. Particularly preferred starting compounds for use as ketone-aldehyde resins are acetophenone, cyclohexanone, 4-13 butylcyclohexanone, 3,3,5-trimethylcyclohexanone and heptanone, alone or in combination. With the leaven. The molar ratio between the ketone and the aldehyde component is between 1:0.25 to 1:15, preferably between 1:0.9 and 1:5, and most preferably between 1:0.95 and 1: Between 4. Processes for the preparation of ketone-aldehyde resins are described, for example, in EP 1 486 520, DE 1 0200600907.9 and DE 1 02006009080.2, and the references cited therein. Also as component B) is a hydrogenated derivative of a resin formed from a ketone and an aldehyde. The above ketone-aldehyde resin is hydrogenated with hydrogen at a pressure of up to 300 bar in the presence of a catalyst. During this hydrogenation, the carbonyl group of the ketone-aldehyde resin is converted to a secondary hydroxyl group. Depending on the reaction conditions, some of the hydroxyl groups can be eliminated to give a methyl group. The following diagram is used to illustrate: -16- 200837121

: k + m The process for preparing a hydrogenation product is described, for example, in DE 1 02006009079.9 and DE 102006009080.2. In the case of ketones containing aromatic structural elements, these structural elements can also be hydrogenated under hydrogenation conditions. Suitable resins are described, for example, in DE 1 02006026760, 5 and DE 1 0 2 0 0 6 0 2 6 7 5 8 · 3. In addition, when component B) is a urea-aldehyde resin, it uses urea of the formula (i)

(0 where X is oxygen or sulfur 'A is an alkylene group and n is 〇 to 3, and 1·9(η+1) to 2·2(η+1) mol of the general formula (丨丨) aldehyde

R2

Η (Η) -17- 200837121 wherein R and R2 represent a hydrocarbyl group of up to 20 carbon atoms in each case, such as a aryl group, an aryl group and/or a aryl group and/or formaldehyde. Suitable ureas of the general formula (i) are, for example, urea and thiourea at n = 0, methyldiurea, ethyldiurea, tetraamethylenediurea and/or six at n=l Methyl diurea and mixtures thereof. Preferred is urea. Suitable aldehydes of the formula (ii) are, for example, isobutyraldehyde, 2-methylpentanal, 2-ethylhexanal and 2-phenylpropanal, and mixtures thereof. Preferred is isobutyraldehyde. The formaldehyde used may be an aqueous form partially or wholly containing an alcohol such as methanol or ethanol, or trioxane and/or trioxane. Generally, all of the monomers mentioned in the literature for preparing urea-aldehyde resin B) are applicable. Particularly preferred are urea, isobutyraldehyde and formaldehyde. Typical modes of preparation and compositions are described, for example, in DE 27 57 220, DE-A 27 57 176 and EP 0 271 776. The commercial product is Laropal® A81 or Laropal® A 101 from BASF AG. The characteristics of component B) are: • between 0 and 450 mg KOH/g, preferably between 0 and 375 mg KOH/g, more preferably between 〇 and 305 mg KOH/g. '• Gardner color 値 between 50 and 5, preferably between 0 and 3 _ 0, more preferably between 0 and 2.0 (50% by weight in ethyl acetate), • Resin After exposure to heat (24h, 150 ° C) between 〇 to 1〇·〇, preferably between 〇 to 7.5, more preferably between 0 and 5.00. Judner-18-200837121 Color 値 (50% by weight in ethyl acetate), • 300 to 1 000 g/mol, preferably 400 to 50,000 g/mol, more preferably 400 to 3000 g/mol The molecular weight 'Μη, • is between 1.25 and 4.0, more preferably between 1.3 and 3 · 5 (Mw / Mn), • between 20 and 180 ° C, preferably between 30 and 14 ° ° Between C, more preferably between 40 and 130 ° C melting point / range, • solubility in non-polar organic solvents. These properties are also arbitrarily changed herein. Hydroxyl hydrazine is a measure of the polarity of the resin. Assuming that the resin properties are fixed parameters (e.g., carbonyl ruthenium, molecular weight), the higher the polarity, the higher the polarity. To be highly compatible with component A), the hydroxy oxime selected must be sufficiently low to be soluble in the non-polar solvent. On the other hand, the more extreme the primer, the better the adhesion of the subsequent coating to the primer coating. The optimized hydroxyindole is between 0 and 45 mg KOH/g, preferably between 0 and 3 75 mg KOH/g, more preferably between 〇3 and 350 mg KOH/g. The measurement is carried out in accordance with DIN 5 3 240-2 "Measurement of hydroxy oxime". During the measurement period, it should be confirmed that the actual 3-hour acetaminophen action time was observed. The Gardner color is a component B) measured in 5% by weight of ethyl acetate, according to DIN ISO 4630, and is a measure of the color of the resin. The lower the color, the closer the color is to the colorless. The color enthalpy after heat exposure is similarly measured in this manner. This method can also be used to obtain an indication of the heat resistance of component B). For this purpose, component B) was placed in an air atmosphere at 150 ° C for 24 h (see measurement of non-volatile fractions). The Giardner color is then -19-200837121. The thermally exposed resin is determined in accordance with DIN IS Ο 4 6 3 〇 in a 50% by weight solution of ethyl acetate. The lower the color, the better the heat resistance of the resin. The molecular weight and polydispersity of the component oxime) were measured by gel permeation chromatography in tetrahydrofuran using polystyrene as a standard. The polydispersity (Mw/Mn) is calculated from the ratio of the weight average (Mw) to the number average (Μη). The higher the molecular weight, the higher the melting range of the component 且) and the better the initial drying rate, but also the higher solution viscosity. For a given molecular weight (?n), the viscosity of the solution becomes higher as the dissolved polymer becomes less uniform (highly polydisperse). The desired number average molecular weight Μη is between 300 and 100,000 g/m〇l, preferably between 400 and 5000 g/mol, more preferably between 400 and 3000 g/mol, and polydispersity ( Mw/Mn) is between 1.25 and 4.0, more preferably between 1.3 and 3.5. In order to achieve, for example, initial drying of the composition of the invention and high hardness and anti-caking properties of the coating, it is necessary to maximize the melting range of component B). The assay uses a capillary melting point tester (Btichi B-545) in accordance with DIN 53 181. The preferred melting point/range of component B) is between 20 and 180 ° C, preferably between 30 and 140 ° C, more preferably between 40 and 130 ° C. Component B) can be dissolved in a typical organic solvent such as ethyl acetate, butyl acetate, acetone, methyl ethyl ketone or the like. In addition, component B) is soluble in a non-polar solvent. This is absolutely necessary because it is only necessary to homogeneously mix the very non-polar component A) with the component B). Component B) is soluble in -20-200837121 aromatic solvents (eg xylenes, toluene, benzene, cresols, naphthalenes, tetrahydronaphthalenes) and/or aliphatic solvents and solvent mixtures (eg separate or mixed ten) 10% and 50% by weight dilutions of hydrogen naphthalene, hexanthene, Gengyuan, (methyl)cyclohexyl, Kristalloel, mineral spirits, turpentine, and sarcophagus. Component C) The essential component of the innovation, C), is used in an amount of from 1% to 98% by weight, preferably from 2% to 98%, more preferably from 20% to 98%. In general, the appropriate component C) is all organic solvents used in the adhesive and coatings industries. Preferred are, for example, aromatic, aliphatic and/or cycloaliphatic solvents and solvent mixtures, such as xylenes, toluene, benzene, cresols, naphthalene, tetrahydronaphthalene, decalin, hexane, alone or in combination. , heptane, (methyl)cyclohexane, Krista 11 〇e 1 , mineral spirits, turpentine, sarcophagus. Component D) Component D) is optionally present and is used in an amount of from 0% to 97% by weight. Suitable component D) is an adjuvant and an additive, such as an inhibitor, another organic solvent, water, a surface-reactive substance (for example, an antifoaming agent), a deaerator, a lubricant, a flow control agent, a matrix wetting agent, Anti-caking agents, oxygen scavengers, free radical scavengers, catalysts, light stabilizers, color brighteners, sensitizers, photoinitiators, rheological additives (eg, thixotropic agents and/or thickeners), Anti-skinning agent, antistatic agent, wetting agent, dispersing agent, crosslinking agent (such as block or non-block (poly) isocyanate), preservative (such as -21 - 200837121 fungicide and / or biocide) , thermoplastic additives, plasticizers, matting agents, flame retardants, internal mold release agents, foaming agents and / or dyes, pigments and / or dips. In addition, 'more than 40% by weight of other polymers may be present as component 〇) 'for example, polyurethane, polyacrylate, polyether, polyester, alkyd, polyamide, casein, fiber Ether, cellulose derivatives, polyvinyl alcohols and derivatives, polyvinyl acetate, polyvinylpyrrolidone, rubber, natural resin, hydrocarbon resin (such as coumarone resin, decyl resin, cyclopentadiene), terpene Resin, maleic acid resin, phenol resin, phenol/urea aldehyde resin, amine based resin (eg melamine resin, benzoguanamine resin), epoxy acrylate, epoxy resin, phthalate and alkali metal ruthenium An acid salt (such as water glass), a sand oxide resin, and/or a fluoropolymer. These binders may be externally crosslinked and/or self-crosslinked, air dried (physically dried) and/or oxidatively hardened. Compositions were prepared from components A) to D): The composition was prepared by thoroughly mixing the components at a temperature of 20 to 80 ° C ("Lehrbuch der Lacktechnologie", Th. Brock, M. Groteklaes, P. Mischke , ed. V. Zorll, Vince ntz Verlag, Hanover, 1 99 8, p. 229 ff.), if necessary in an inert atmosphere. This can be done by first introducing component C) and adding components A), B) and, if necessary, component D). The composition of the invention consisting of components A) to D) does not contain chlorine. Chlorine free means the use of chlorine-free products containing organically bonded chlorine, such as chlorinated rubber-22-200837121, chlorinated polyolefin or the like. On the other hand, inorganic chlorides (such as salts) may be present, but usually do not have any potential toxicity. The present invention also provides the use of the non-reactive composition as a primer composition to promote adhesion to plastics, more particularly unpretreated plastics, from the compositions of the present invention consisting of components A) to D) It can be used as a primer composition, which allows adhesives, sealants and/or coating materials to adhere to pre-treated plastics, eliminating the need for typical plastic pretreatment methods such as flame treatment. , corona discharge, plasma treatment or gas phase fluorination. It is sufficient to simply clean the substrate before using a typical cleaning agent such as isopropyl alcohol and/or n-hexane. The composition of the invention consisting of components A) to 0) is particularly suitable as a primer for promoting adhesion, sealant and/or coating material pairs having a lower than 40, preferably lower than 38, preferably lower Adhesion of unpretreated low energy plastic at a surface tension of 34 mN/m2. # Examples of low-energy plastics of this type that may be mentioned include polycondensation hydrocarbons such as polypropylene (PP), modified polypropylene such as polypropylene/ethylene copolymers (for example, block copolymers or random copolymers). , polyethylene (PE), modified PE, mixture (for example, polypropylene/ethylene with a low EPDM content - PP/EPDM), pp/PE, and rubber, Polyvinyl chloride and specific polyester. The plastic expansion can be a machined or shaped article, or a composite (e.g., a system in which paper and/or aluminum is laminated to a plastic or film, foil or sheet). Plastics can be used in the commodity sector (eg bottles, parcels, carrying bags, -23-200837121 tags or similar) or high-priced ( applications (eg in the electronics industry, automotive engineering or aircraft structures). The composition of the invention consisting of components A) to D) exhibits rapid initial drying and high anti-caking properties. The effect of the pretreatment can also be maintained for a long period of time, so it is possible to selectively pre-treat directly after the production of the plastic in the plastics manufacturer's location (offline) or directly before (online) the application of the coating material. Depending on the intended use, a subsequent adhesive, sealant or coating material can be applied to the primer coating of the present invention. This subsequent coating was applied directly to the primer coating as wet to wet, i.e., the solvent was not removed. The primer may also be first removed at room temperature or elevated temperature and the subsequent coating applied to a "dry" (i.e., solvent free) primer. The compositions of the present invention can be applied to a plastic substrate using typical methods. Examples include: (electrostatic) spray method, injection method, spin coating, flow curtain type, dip-coating type, roll type, over-ink type, drum type, wipe-on type, washing type, printing type, roller coating, scraping Painted and pressed. The thickness of the primer coating of the present invention after evaporation of volatile components (e.g., solvent) is between 〇·〇1 to l〇〇/zm, preferably between 0.1 and 1, more preferably 0. 2 Between 1 0 // m. Subsequent coating materials may use all coating materials, more particularly all solvent- or aqueous coating materials or solvent-free coating materials (for example, radiation-curable coating materials and/or powder coating materials), For example, enamel coating compounds, primers, primer materials, surface materials, printing inks, atomic pen pastes, inks, varnishes, pigmented paints, laminating systems, heat-sealing paints, US-24-200837121 makeup articles, sealants , an insulating agent or an adhesive. The flow of the composition of the present invention on the substrate, and the subsequent flow of the coating material on the composition of the present invention, is flawless and has no defects on the surface (e.g., potholes and deficiencies). The invention also provides an article made using the non-reactive composition

[Examples] The following examples are intended to illustrate but not limit the scope of application of the present invention. I)) Preparation of polyolefins using crystalline form of titanium trichloride (TiCl3 • 0.3 3A1C13 ) from TiCl4 in aluminum-reduced form and a mixed catalyst composed of triisobutylaluminum (i: 4 by weight ratio), the monomer shown in Table 1 is in n-butane, and the temperature shown in Table 1 is in the laboratory hot pot. Polymerization in which hydrogen is used as a molar mass adjuster. The associated pressure is from 15 to 35 bar. The ethylene and propylene monomers were continuously measured during the 3-hour reaction time; the 1-butene monomer was added first. After 3 hours, isopropanol was added to the reaction mixture, and the addition stopped the reaction. Unreacted monomer and n-butane solvent were evaporated in an evaporator. The molten polyolefin is discharged at a temperature of about 1 90 °C. -25- 200837121 gas il, gt: touch} (four) 吆s 7 I Μ one - ι ® 褰镞 · ι撇 polydispersity ν 〇 suspension IS S 92000 34000 35000 sexual fusion 焓 [J / g] vn 戈 r4 r *H r-H Tg[°C] m cn oo (N Ό rn m H2 quantity [liter(stp)] oo 00 reaction ί reaction temperature rc] ο 〇▼-H o NMR content [% by weight] trv ν〇^ —^ 5 〇〇卜m Bu g 3 13C Monomer unit awards}^ Ν3 ΙΕ Dipropylene 1-butene K] K II Example 1 I ΗΗ (N HH cn ώ ώ Π舄孽 毖 归 归 归1 71 赖 - -26 - 200837121 π ·) Component B) 1. Preparation of ketone-aldehyde resin The preparation of the ketone-aldehyde resin is based on the example GL 254 of EP 1 486 520 A1. 2. Preparation of a hydrogenated ketone-aldehyde resin The preparation of a hydrogenated ketone-aldehyde resin is based on Example 2 of DE 1 02006026758.3. 3. Preparation of urea-aldehyde resin The preparation of the urea-aldehyde resin is based on Example 1 of DE 27 17 76. Table 2 below gives a description of the properties of the resins II-1 to II-3.

-27- 200837121 Table 2. Properties of Resin ΙΙ-l to II-3 棚 Π-1 Resin ΙΙ-2 棚 Π-3 Hydroxyl hydrazine [mgKOH/g] 7.6 16.0 19.4 Melting point [°c] 63 49 63 Non Volatile content (24h, 150〇C) [% by mass] 78.2 99.6 64.3 Jardner color (50% in ethyl acetate) 1.0 0.0 1.1 Jardena color (24h, after 150°C; in acetic acid 50% in ester) 3.9 0.2 3.2 Μη (GPCXg.mol·1 corrected by PS) 500 890 1150 Mw (GPCXg.mor1 corrected by PS) 670 1350 4640 Polydispersity 1.3 1.5 3.0 Solubility (10%/50%) Mineral oil clarification / clarification clarification / clarification clarification / clarification Isopar 8 澄清 clarification / clarification clarification / clarification clarification / clarification hexane turbidity / clarification clarification / clarification micro turbid / clarified xylene clarification / clarification clarification / clarification clarification / clarification The lacquer composition is shown in Table 3 below. The material is dissolved and homogenized by stirring. For this purpose, the individual solvent (component C) is first placed and the polyolefin I-1 and the individual resins Π-1 to II are placed. -3 is slowly added during stirring at room temperature. To accelerate dissolution, the solution is briefly heated to 60 ° C with stirring. After dissolution occurs, it will dissolve. Liquid filtration. -28- 200837121

Table 3. Comparative composition Cl and primers P1 to P8 (all figures in grams/g) C1 P1 P2 P3 Ρ4 Ρ5 Ρ6 Ρ7 Ρ8 Polyolefin 1-1 10.0 5.0 3.3 2 5.0 5.0 5.0 5.0 5.0 Resin II-1 • 5.0 6.7 8 5.0 5.0 5.0 Resin Π-2 • _ Solution 5.0 Employed Resin II-3 • • One 5.0 Xylene 90.0 90.0 90.0 90.0 Squash suspected 90.0 90.0 Solvesso 8 100 • • Face 90.0 靡1 • Mine Shellsol8D 40 • Suspected 90.0 _ Mineral oil - - Earn - • 90.0 - - All solutions are clear to slightly turbid, colorless to slightly yellow, and slightly water. The portion of the undissolved composition in the case of the comparative solution C1 was considerably higher than the compositions P1 to P8. This can be explained by the effect of the dissolving agent of the resins II-1 to II-3. The solutions C1 and P1 to P8 were applied to a film which had been previously cleaned with ethanol and n-hexane by a spatula applicator (2 // m wet film). After evaporation of the solvent (see Table 4 for various flash times), the printing ink was applied to the sheet with a spatula coating (2 V m wet film) and the films were solvent removed at room temperature. Adhesive properties are assessed using a tester known as wrinkle. After applying the printing ink for 24 hours, the coated sheet was "wrinkled". If the coating is not damaged, the adhesion is very good (丨). In the case of coating damage, the degree of damage was evaluated (2: micro spalling, ..., 6: complete delamination). In addition, the adhesion was estimated by an adhesive tape peeling method (tape test). After the different flashing times of the printing ink (5 min, lh, 24 h), the adhesive tape was adhered to the printing ink film and peeled off again. If the coating is not damaged, the adhesion is very good (1). In the case of coating damage, the damage is evaluated -29 - 200837121 (2: micro spalling, ..., 6: complete delamination). The printing ink used has the following composition: 39.0 g of ethanol 11.2 g of ethyl acetate 4 〇·Kurstharz 1201 Synthetic resin (Degussa AG) 7·2 gram of Hacolor blue 5 0423 (Hagedorn) All ingredients are stirred under the stated order Combine and homogenize. The film substrate (coating film) used is as follows:

Treofan NNA 40 (PP film), Hostaphan RN 50 (PET film), Genotherm EE 87 (PVC film) Tables 4-1 and 4-2 below show printing inks on individual primers P1 to P8 compared to printing inks. Adhesion test (wrinkle test, tape test) results on individual untreated films and comparative primer C1.

-30- 200837121

睬煺(诚MIE醆,譃Μ _遛)Μ _ _ ?|^月13carboxy_起镒 镒赵q~松芨北尔_伥^菡袒尾dUI^镒To Too cut I d璲 inverted phase iis "®dml, inch tape test PVC 24h cn inch (Ν (N (N i-H (N r-^ (N vH (N (N rH 5 inch mm vH (N (N (M (N νH mm 5min VO Inch mmmm (NT—Hi m (N 1 ^—4 T—tm 可ΓΟrH PET 24h in >T) inch m 1—H r—^ ' m T—< m (N m ▼-H r H v 〇νο ι〇 inch (N mm TH inch m TH inch (NT-H TH 5min VO v〇νο VO v〇 inch rH VO f 4 m rH VO m tH 24h VO VO (Ν T—^ ^r> t—H m ^Η tH (N r—H \ov〇Γ^Ι (Ν (N t—H t—H m (N a • VO VD m cn (N v〇(N r—< (N v〇1 TH inch (N mv〇(N r^H (N wrap test PVC inch inch inch m ▼-H (T) (N (N m (N TH inch inch t-H PET VO VO (N i-H inch (NH Inch m (N rn CN Of Απί V£> VO ΓΛ (NV 〇 (N in T-H1 vo v〇t-1 v〇CN i-l primer drying conditions without primer (comparative) 0.5 min RT 1 Min RT 1 2 min RT 丨0.5 min RT 1 min RT 2 min RT 0.5 min RT 1 minRT 2 min RT 0.5 min RT 1 min RT 2 min RT 0.5 min RT 1 min RT 2 min RT Μ m 壊 cn Ph 2 -31 - 200837121

帐塘(Μ窸te酷<缄Μ镶瑠)_鎏^钖^月13录蝈#1镒丑尚T打笔This scraping ¥忉菡画}坩匡运镒Too just id carboxyl rffi&gt ;壊wii«f®s:.(N-inch tape test PVC 24h (M (M cn (N (N 1 < (N (N λ inch cn m cn 5min mm 'Τ·Η inch cn mmm PET 24h m (N t - H rH (NT - H m CN T - H 5 inch (N t - 1 inch (N rH (NH inch (N (N 5min T - H vo ¥ (N mm & 24h v〇t - H tH tn TH < H VO (N v〇H v〇(N rH i-H 5min VO (N CN rH v〇<N rH v〇(N f-H rH wrinkle test PVC j _1 inch inch) rH mm rH rH inch cn (N PET m ΓΛ (N rn (N ΟΊ (N CN—I l (N 1—H VO rn <N rH ▼—H vo (N r*H primer drying condition 0.5 min RT 1 min RT 2 min RT ] 0.5 min RT 1 min RT ! 2 min RT 0.5 min RT 0.5 min RT 1 min RT 2 min RT Sample 00 IX. II Fine=1Ή -32 - 200837121 When the primer coating is missing The printing ink has poor adhesion to individual plastics. This can be confirmed by the results of the wrinkle test and the tape test. Only on PVC (after 24h) Test 3) found minimal adhesion improvement. Comparative experiment C1 showed that the primer without component B) actually improved the adhesion substantially. However, considerable improvement was observed only after 2 minutes of flash time. And it is not at a very high degree. In contrast, the adhesion of the printing ink to the plastic substrate can be significantly improved by the primer coating of the present invention even after a short flashing time. After the steaming time, the higher component B) concentration (P1 to P3) is good for adhesion. Since all primer coatings are tack-free after 30 seconds, they are highly resistant to caking after a very short time. Examples P4 to P6 showed no significant difference compared to P1. The difference was in the accuracy region of the corresponding method. Therefore, the effect of the solvent (component C) used was small. Solutions C1 and P1 to P8 were applied to a polyethylene and polypropylene plate available from Kriippel by a medical spatula (2 v m wet film) which had been previously cleaned with ethanol and n-hexane. After the solvent was removed by evaporation, the printing ink was applied in a medical spatula (2 #m wet film) and the solvent was removed at room temperature. In addition, a standard commercial two-component polyurethane varnish was applied to the panel by spray coating and dried at 80 ° C for 30 minutes. The adhesive properties of the printing ink were evaluated by an adhesive tape peeling method (tape test). For this purpose, the printing ink adhered to the printing ink film and peeled off again after different flashing times (5 min, lh, 24 h). If the coating is not damaged, the adhesion is very good (1). In the case of coating damage -33- 200837121, the degree of damage is assessed (2: micro spalling, ... '6: complete delamination) 交叉 cross-hatching test of the applied coating material according to DIN EN ISO 2409 (GT 0 is Very good, GT 5 is completely delaminated). The results are shown in Table 5.

Table 5 • Two component varnish (cross hatch) and printing ink (tape test) on individual primers P1 to P8 compared to varnish/ink on individual untreated panels and comparative primer C 1 Adhesion test result sample primer drying condition cross i PE _ spring PP tape collar PE prison PP 5min lh 24h 5min lh 24h 4rrr m no primer (comparative) 5 5 6 6 6 6 6 6 Cl 5 min RT 5 5 6 6 6 2-3 2 2 30 min 100°C 5 5 4-5 3 3 4-5 2-3 2-3 PI 5 min RT 5 2 4 3-4 3-4 1 1 1 30 min 100°C 2 -3 0 1 1 1 1 1 1 P2 5 min RT 5 1 4-5 4 4 1 1 1 30 min 100°C 3 0-1 2 2 1-2 1 1 1 P3 5 min RT 5 2 5 4 4 1 1 1 30 min 100°C 3 1-2 2 2 1-2 1 1 1 P4 5 minRT 5 2 4-5 3 3-4 1 1 1 30 min 100°C 2-3 0 2 2 1 1 1 1 P5 5 minRT 5 2 4-5 3 3 1 1 1 30minl00°C 2 0-1 1 1 1 1 1 1 P6 5 min RT 5 2 4 3 3 1 1 1 30 min 100°C 2-3 0-1 1- 2 1 1 1 1 1 P7 5 minRT 5 3 4 4 4 1 1 1 30 min 100°C 4-5 2-3 2-3 2·3 2 1 1 1 P8 5 minRT 5 1-2 3 3 3 1 1 1 30 min 100°C 3 0 1-2 1 1 1 1 1 -34- 200837121 The two-component polyurethane is in the absence of a primer coating Varnishes poor adhesion of individual plastic. The same result was obtained when pretreated by comparative primer C1. In all cases there is no adhesion (cross hatch GT 5 ). When the primers P1 to P8 of the present invention are used for pretreatment on PE, the adhesion is not improved if the solvent of the primer is removed at room temperature. However, if the primers P1 to P8 of the present invention remove the solvent at an elevated temperature, the adhesion of the two-component varnish to PE is remarkably improved. The inventive primers P1 to P8 on PP produced a significant improvement in the adhesion of the varnish. However, here too, there is a tendency that the solvent will further improve in the adhesive property upon evaporating at an elevated temperature. The printing ink has the same adhesion to individual plastics when the primer coating is absent (tape test 6). Pretreatment with C1 on PE did not show improvement after evaporation of the solvent for 5 minutes at room temperature. A relatively slight improvement can be seen after the primer has been forced to dry. On the PP, some minor improvements can be seen in the pretreatment using C1. When the primer of the present invention removes the solvent at RT, the result for PE is that the adhesion properties of the printing ink on the individual primers are improved. In contrast, the results of forced drying of individual primers at 1 〇 ° C found that the printing inks had very good adhesion properties on the thus pretreated PE sheets. In the case of PP, there is excellent adhesion at any temperature during evaporation of the solvent. Again, Examples P4 through P6 did not show a difference with respect to P1. Therefore, the effect of the solvent (component C) used is very low. Primer P1 was applied to Treofan NNA 40 (pp film) -35-200837121 as described above. However, the printing ink was applied after 3 or 6 months of application of the primer. The adhesive properties were examined and showed no difference compared to the direct application of the printing ink. Therefore, it is exemplified that the adhesion promoting effect is maintained even in a long period of time (see Table 6). Table 6. Treofan NNA 40 after applying primer for 2 minutes and after 3 or 6 months

Adhesion test of printing ink on the primer P 1 (creping test, tape test) result sample primer drying condition wrinkle test glue 5 min ί test lh 24h P1 2min RT 1 1-2 1 1 3 months RT 0 1 1 1 6 months RT 0 1 1 1

-36-

Claims (1)

200837121 X. Patent Application No. 1 · A non-reactive composition containing no organically bonded A) at least one non-reactive-olefin by weight of 1% to 98%, which does not contain organically bonded chlorine and Having a enthalpy of from 0 to 80 J/g, and B) from 1% to 98% by weight of at least one ketone resin 887 and/or urea/aldehyde resin and/or their hydrogenated derivative C) by weight 1% to 98% of at least one solvent, at which D) up to 97% by weight of at least one adjuvant or adjuvant component A) to D) total weight is 1% by weight < 2. The non-reactive agglomerate A) which is soluble or swellable in an organic solvent is used according to the non-reactive composition of the first application of the patent. # 3. According to the non-reactive composition of the application patent, the non-reactive composition uses miscellaneous polypropylene and/or polybutene-1 as a component A) 4. According to any one of the patent applications 1 to 3 a composition in which substantially the non-reactive polycondensation group shown below is used as the component A): a) 0.5% to 100% by weight, preferably 1% to preferably 10% to 98% by weight or more a ketone/aldehyde tree having from 4 to 20 carbon atoms, b) from 1% to 99.5% by weight, preferably from 1% to chlorine and substantially in the range of agglomerated alpha, and, if necessary, an olefin As a substance, wherein 〇% non-reactive-α-dissimilar hydrocarbon 99%, more α-99%, more -37-200837121 preferably 2% to 90% propylene' and c) 〇% to 50% by weight The non-reactive composition according to any one of claims 1 to 3, wherein a non-reactive poly-α-olefin having the following characteristics is used as a group Part A): • 2000 to 500000 g/mol, preferably 5,000 to 300,000 H g/mol, more preferably 7500 to 200,000 g/mol weight average molecular weight, • 2.0 to 60, preferably 2.5 to 40, more Good for 2·5 to 30 dispersive PD, • - 8 0 to 0 ° C, preferably -6 0 to 0 ° C, more preferably -5 5 to -1 0 ° C glass transition temperature Tg, • In the range of from 0 to 80 J/g, preferably in the range of from 1 to 70 J/g, more preferably in the range of from 1 to 6 J/g, and Substantial solubility and/or swelling ratio in polar solvents. The non-reactive composition according to any one of claims 1 to 3, wherein 1-butene, 1-pentene, 1-hexene, 1-octene, alone or in the mixture, is used. 1-decene, 1-dodecene, 1-octadecene, 3-methyl-1-butene, methylpentene such as 4-methyl-1-pentene, methylhexene or methylglycol The alkene is an α-olefin having 4 to 20 carbon atoms as component A). 7. The non-reactive composition according to any one of claims 1 to 3, wherein the amount used is from 1% to 98% by weight, preferably from 1% to 49%, more preferably! From 100% to 40% of at least one non-reactive poly-α-38 - 200837121 monoolefin as component A). The non-reactive composition according to any one of claims 1 to 3, wherein a C-H-acid ketone is used to prepare a ketone resin and/or a ketone-aldehyde resin (component B). The non-reactive composition according to any one of claims 1 to 3, wherein a ketone resin and/or a ketone is prepared by using a ketone selected from the group consisting of ketones as shown below or in a mixture as a starting compound. Aldehyde resin (component B)): acetone, acetophenone, methyl ethyl ketone, tertiary butyl methyl ketone, heptyl 2-ketone, pent-3-enketone, methyl isobutyl ketone, cyclopentanone, a mixture of cyclododecanone, 2,2,4 and 2,4,4-trimethylcyclopentanone, cycloheptanone, cyclooctanone, cyclohexanone, 4-tripentylcyclohexanone, 2 - 2,4-butylcyclohexanone, 2 -tributylbutanone, 4 -tributylbutanone, 2 -methylcyclohexanone, 3,3,5-trimethylcyclohexanone . The non-reactive composition according to any one of claims 1 to 3, wherein acetophenone, cyclohexanone, 4-tert-butylcyclohexanone or the like is used alone or in a mixture. , 3,5-trimethylcyclohexanone and heptanone to prepare a ketone-aldehyde resin (component B)). 1 1 . The non-reactive composition according to any one of claims 1 to 3 wherein cyclohexanone is used to prepare a ketone resin (component B). 1 2 - A non-reactive composition according to any one of claims 1 to 3, wherein an aldehyde is used to prepare a ketone-aldehyde resin (component B). 1 3 . The non-reactive composition according to any one of claims 1 to 3, wherein formaldehyde, acetaldehyde, n-butyl ketone and/or isobutyraldehyde, valeraldehyde, and ten are used alone or in the mixture. Dialdehyde to prepare ketone-aldehyde resin (component B-39- 200837121 1 4 · A non-reverse composition according to any one of claims 1 to 3, wherein formaldehyde and/or trioxane and/or trioxal aldehyde components are used to prepare a ketone-aldehyde resin (component) B)). The non-reverse composition according to any one of claims 1 to 3, wherein acetophenone, ketone, 4-13 butylcyclohexanone, 3, used alone or in a mixture, is used. A resin of 3,5-trimethylcyclohexanone, heptane and formaldehyde is used as component B). The non-reverse composition according to any one of claims 1 to 3, wherein the resin according to any one of the fifteenth patents of the patent application after the preparation is used as the component B). The non-reverse composition according to any one of claims 1 to 3, wherein acetophenone, ring, 4-13 butylcyclohexanone, 3, 3 are used alone or in a mixture. a hydrogenated derivative of a resin composed of 5-trimethylcyclohexanone or heptanone as component B). 18. The non-reverse composition according to any one of claims 1 to 3, wherein the urea of the formula (i) is used as the cyclohexanone, and the hexahexanone m ψ Sex n+l wherein X is oxygen or sulfur, A is an alkyl group and η is 0 to 3' and 1·9) to 2.2 (n+l) mol of the formula (ii) aldehyde -40- 200837121 (Η) wherein R! and R2 represent a hydrocarbyl group of up to 20 carbon atoms in each case and/or a urea-aldehyde resin prepared from formaldehyde as a component Β). 1 9 · A non-reactive composition according to any one of claims 1 to 3 wherein urea, thiourea, methyldiurea, ethyldiurea, tetraamethylenediurea and / or hexamethylenediurea or a mixture of the same as the urea-aldehyde resin prepared as a component Β). The non-reactive composition according to any one of claims 1 to 3, wherein isobutyraldehyde, formaldehyde, 2-methylpentanal, 2-ethylhexanal and 2-phenylpropene are used. An aldehyde or a mixture of them as a component Β). The non-reactive composition according to any one of claims 1 to 3, wherein a urea-aldehyde resin prepared from urea, isobutyraldehyde and formaldehyde is used as the component Β). The non-reactive composition according to any one of claims 1 to 3, wherein at least one of a ketone resin, a ketone/aldehyde resin, a urea/aldehyde resin and/or the like is used. Derivatives as component Β): • 〇 between 450 mg KOH/g, preferably between 0 and 3 75 mg KOH/g, more preferably between 〇 and 305 mg KOH/g Number, • Gardner color 在 between 0 and 5, preferably between 0 and 3.0, more preferably between 0 and 2.0 (50-41 - 200837121% in ethyl acetate) ), • After the resin is exposed to heat (24h, 150°C) between 〇 and 1〇·〇, preferably between 〇 and 7.5, more preferably between 0 and 5.0, Gardner color値 (50% by weight in ethyl acetate), • 300 to 10000 g/mol, preferably 400 to 5000 g/mol', more preferably 400 to 3000 g/rnol, number average molecular weight Μη, • 1.25 to 4.0 More preferably, the polydispersity (Mw/Mn) between 1. 3 and 3 · 5, • between 20 and 180 ° C, preferably between 30 and 140 ° C, more preferably 40 Melting point/range to 130 ° C, and The non-polar organic solvent solubility. The non-reactive composition according to any one of claims 1 to 3, wherein the amount used is from 1% to 98% by weight, preferably from 1% to 49%, more preferably from 1% to 40% of at least one ketone resin, ketone/aldehyde resin, urea/aldehyde resin and/or their hydrogenated derivatives as component B) ° 24. According to any one of claims 1 to 3 of the patent application A reactive composition in which an organic solvent is used as component C). The non-reactive composition according to any one of claims 1 to 3, wherein an aromatic, aliphatic and/or cycloaliphatic solvent selected from the group consisting of the following, or a mixture, is used as a group. Part C): xylene, toluene 'benzene, cresol, naphthalene, tetrahydronaphthalene, decahydronaphthalene, hexane, heptane, (methyl) cyclohexyl, Kristalolels, specific boiling point spirits, mineral oil White spirits, tertentines, paraffin. The non-reactive composition according to any one of claims 1 to 3, wherein the component C) in the composition is present in an amount of from 1% to 98% by weight, preferably from 1% to 98%. 2% to 98%, more preferably 20% to 98% ° 2 7. The non-reactive composition according to any one of claims 1 to 3, wherein an auxiliary agent and an additive are used as the component D) The non-reactive composition according to any one of claims 1 to 3, wherein an auxiliary agent and an additive selected from the group consisting of the following are used alone or in a mixture as component D): an inhibitor, In addition, organic solvents, water, surface-reactive substances, defoamers, deaerators, lubricants, flow control agents, matrix wetting agents, anti-stick agents, oxygen scavengers, free radical scavengers, catalysts, light stabilization Agent, color brightener, sensitizer, photoinitiator, rheological additive (thixotropic agent and/or thickener), anti-skinning agent, antistatic agent, wetting agent, dispersing agent, cross-linking agent Segment or non-block (poly)isocyanate), preservatives (fungicides and/or biocides), thermoplastic additives, plasticizing Agent, matt agent, flame retardant, (internal) release agent, foaming agent, dye, pigment, dip, polyurethane, polyacrylate, polyether, polyester, alkyd, poly Indamine, casein, cellulose ether, cellulose derivatives, polyvinyl alcohols and polyvinyl alcohol derivatives, polyvinyl acetate, polyethylene ketones, rubber, natural resins, hydrocarbon resins (coumarone, And cyclopentadiene resin), terpene resin, maleic acid resin, phenol resin, phenol/urea-aldehyde resin, amine-based resin (for example, melamine resin, benzoguanamine resin), epoxy acrylate , epoxy resins, phthalates and alkali metal phthalates (eg water glass), decane resins, fluoropolymers. 2 9 · The non-reactive -43-200837121 composition according to any one of the patent applications 丨 丨 to 3, which is characterized by rapid initial drying and high anti-caking property. A method of preparing a non-reactive composition according to any one of claims 1 to 3, wherein the composition substantially contains A) at least one non-reactive by weight of from 1% to 98% by weight. a poly-α·olefin having no organically bonded chlorine and having a fusion enthalpy in the range of 0 to 80 J/g, and B) at least one ketone resin, ketone/aldehyde tree by weight of 1% to 98% by weight φ lipid and/or urea/aldehyde resin and/or their hydrogenated derivatives, and C) from 1% to 98% by weight of at least one solvent, and if necessary D) up to 97% by weight, at least An adjuvant or adjuvant, the total weight of the components A) to D) is 1% by weight, and is thoroughly mixed and homogenized by stirring and/or dispersing at a temperature of +20 to +80 °C. For components A) to D), the component C) is first introduced, then the components A), B) and, if necessary, D) are added. Φ 3 1 . — A non-reactive composition according to any one of claims 1 to 3 of the patent application as a primer composition for promoting adhesion to plastics 〇3 2. Use of the non-reactive composition of any of items 1 to 3 as a primer composition to promote adhesion to unpretreated plastics. 3 3 . The use of a non-reactive composition according to any one of claims 1 to 3 as a primer composition for promoting adhesion to a non-pretreated low-energy plastic, the plastic having a low At 40, preferably lower than 38-44 to 200837121, more preferably lower than 34 mN/m2. 34. The use of a non-reactive composition according to any one of claims 1 to 3 as a primer composition to promote adhesion to a non-pretreated low-energy plastic. From polypropene (pp), modified polypropylene (such as polypropylene-acetamide copolymer (such as block copolymer or random copolymer)), polyethylene (PE), modified PE, with low £? 1>1^ content of polypropylene/ethylene-propylene-diene blend (PP/EPDM), PP/PE blend, rubber, polyvinyl chloride and specific polyester. 3 5 · Use of a non-reactive composition according to any one of claims 1 to 3 as a primer composition to promote adhesion to glass 〇 3 6 · — based on the patent application Use of the non-reactive composition of any one of the three items as a primer composition, characterized in that it is directly after the production of the plastic in the plastics manufacturer's location (offline), or directly before the application of the coating material (online) Selective pretreatment. The use of the non-reactive composition according to any one of claims 1 to 3 as a primer composition, characterized in that the composition is by (electrostatic) spraying method, injection method, Application to the plastic substrate by spin coating, flow curtain, dip, roll, overfill, drum, wipe, wash, print, roller coating, knife coating or compression '3 8 · Use of a non-reactive composition according to any one of claims 1 to 3 as a primer composition, characterized by a subsequent adhesive, sealant and/or coating material Apply to the primer coating. -45- 200837121 3 9. Use of a non-reactive composition according to any one of claims 1 to 3 as a primer composition, characterized in that the subsequent coating is directly wet-to-wet Apply to the primer coating, or the primer removes the volatile component at room temperature or elevated temperature and then applies the subsequent coating to "dry" - that is, solvent free - primer. 40. Use of a non-reactive composition according to any one of claims 1 to 3 as a primer composition, characterized in that after the volatile component is evaporated, the thickness of the primer coating is Between 0.01 and 100/zm, preferably between 〇·1 and 3 0 // m, more preferably between 2. 2 to 1 〇# m 4 1 . According to the patent application section 1 to 3 Use of a non-reactive composition as a primer composition, characterized by the use of a solvent- and/or aqueous system and/or a solvent-free system (for example, a radiation hardenable adhesive, a sealant and a coating material) The sealant, adhesive and coating material of the powder coating material are used as a subsequent system. 42. Use of a non-reactive composition according to any one of claims 1 to 3 as a primer composition, characterized by using a sealant, an adhesive and a coating material selected from the group consisting of As a subsequent system: solvent- and/or aqueous systems and/or solvent-free systems (eg radiation hardenable adhesives, sealants and coating materials and/or powder coating materials), such as enamel coating compounds, primers, Bottom materials, surface materials, printing inks, atomic pen pastes, inks, varnishes, pigmented paints, enamel laminating films, heat-sealing paints, cosmetic articles, sealants and insulating agents are also bonded. Any of the items used in the paragraph 4 3 - an article made according to the patent pending 46 to 46 5-% 200837121 non-reactive composition. 200837121 VII. Designated representative map: (1) The representative representative of the case is: None (2), the representative symbol of the representative figure is a simple description··No 8. If there is a chemical formula in this case, please reveal the chemical formula that best shows the characteristics of the invention: none -4-