TW200833734A - Method of producing flame retardant polyester polymer, polyester polymer produced therefrom and fiver produced using the polyester polymer - Google Patents

Method of producing flame retardant polyester polymer, polyester polymer produced therefrom and fiver produced using the polyester polymer

Info

Publication number
TW200833734A
TW200833734A TW096140660A TW96140660A TW200833734A TW 200833734 A TW200833734 A TW 200833734A TW 096140660 A TW096140660 A TW 096140660A TW 96140660 A TW96140660 A TW 96140660A TW 200833734 A TW200833734 A TW 200833734A
Authority
TW
Taiwan
Prior art keywords
polyester polymer
produced
flame retardant
polymer
fiver
Prior art date
Application number
TW096140660A
Other languages
Chinese (zh)
Other versions
TWI368625B (en
Inventor
Seung-Cheol Yang
Original Assignee
Hyosung Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hyosung Corp filed Critical Hyosung Corp
Publication of TW200833734A publication Critical patent/TW200833734A/en
Application granted granted Critical
Publication of TWI368625B publication Critical patent/TWI368625B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C09K21/12—Organic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
    • C08G63/6924—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6926—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/50—Physical properties
    • C08G2261/59—Stability
    • C08G2261/594—Stability against light, i.e. electromagnetic radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66—Substances characterised by their function in the composition
    • C08L2666/78—Stabilisers against oxidation, heat, light or ozone
    • C08L2666/82—Phosphorus-containing stabilizers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66—Substances characterised by their function in the composition
    • C08L2666/84—Flame-proofing or flame-retarding additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)

Abstract

Disclosed herein is a method of producing a flame retardant polymer by adding a phosphorus flame retardant, represented by Chemical Formula 1 below, to a first esterification reaction process such that the amount of phosphorus thereof relative to the amount of polymer is 500 to~ 50000 ppm, and then adding a manganese salt and a phosphorus compound, each of which is a UV stabilizer, in a second esterification process such that the amount of each of manganese and phosphorus thereof is 0.1 to 500 ppm, a polyester polymer produced using the method, and a polyester fiber produced using the polyester polymer. The polyester polymer and polyester fiber have permanent flame retardant properties and excellent UV stability.
TW096140660A 2006-11-22 2007-10-30 Method of producing flame retardant polyester polymer, polyester polymer produced therefrom and fiver produced using the polyester polymer TWI368625B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020060115769A KR100764378B1 (en) 2006-11-22 2006-11-22 Manufacturing method of flame retardant polyester polymer, polyester polymer and fiber therefrom

Publications (2)

Publication Number Publication Date
TW200833734A true TW200833734A (en) 2008-08-16
TWI368625B TWI368625B (en) 2012-07-21

Family

ID=39419389

Family Applications (1)

Application Number Title Priority Date Filing Date
TW096140660A TWI368625B (en) 2006-11-22 2007-10-30 Method of producing flame retardant polyester polymer, polyester polymer produced therefrom and fiver produced using the polyester polymer

Country Status (5)

Country Link
JP (1) JP5132271B2 (en)
KR (1) KR100764378B1 (en)
CN (1) CN101186689B (en)
DE (1) DE102007056179B4 (en)
TW (1) TWI368625B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101735578B (en) * 2008-11-24 2011-08-03 中国石油天然气股份有限公司 Flame-resistant and uvioresistant polyester composite material and method for preparing same
CN102691130B (en) * 2012-06-19 2014-10-29 福建经纬新纤科技实业有限公司 Process for manufacturing fire-retardant polyester fiber
CN102691131A (en) * 2012-06-19 2012-09-26 福建经纬新纤科技实业有限公司 Manufacturing equipment system of flame-retardant polyester fiber
CN104178838B (en) * 2013-05-23 2018-01-02 东丽纤维研究所（中国）有限公司 Flame retardant polyester false twist fibers and its manufacture method
CN105985514B (en) * 2015-03-03 2018-11-30 东丽纤维研究所（中国）有限公司 A kind of preparation method of flame-retardant polyester composition
CN105177754B (en) * 2015-10-21 2017-08-01 东华大学 A kind of preparation method of high-strength fire-retarding polyester filament
CN116515094B (en) * 2023-07-04 2023-09-29 中国天辰工程有限公司 Preparation method of flame-retardant degradable polyester and degradable copolymerized flame retardant

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2346787C3 (en) 1973-09-17 1980-05-08 Hoechst Ag, 6000 Frankfurt Flame retardant linear polyesters, processes for their manufacture and their use
JPS5128894A (en) 1974-09-06 1976-03-11 Teijin Ltd NANNENSEI HORIESUTERU NO SEIZOHO
JPS5247891A (en) 1975-10-14 1977-04-16 Toyobo Co Ltd Phosphorus-containing flame retarders
JPS5346398A (en) 1976-10-07 1978-04-25 Teijin Ltd Flame retardant copolyester and its preparation
JPS60124648A (en) * 1983-12-09 1985-07-03 Nippon Ester Co Ltd Flame-resistant polyester composition
JPS626912A (en) 1985-07-02 1987-01-13 Nippon Ester Co Ltd Flameproofing polyester fiber structure
JPH0813877B2 (en) * 1986-06-17 1996-02-14 東レ株式会社 Manufacturing method of flame retardant polyester
US5180793A (en) 1991-12-31 1993-01-19 Hoechst Celanese Corporation Flame resistant, low pilling polyester fiber
JP3169104B2 (en) * 1993-09-30 2001-05-21 東洋紡績株式会社 Flame retardant polyester fiber
US5399428A (en) 1994-03-11 1995-03-21 Monsanto Company Flame retardant polyester copolymers
JP3313019B2 (en) * 1996-03-14 2002-08-12 ポリプラスチックス株式会社 Flame retardant polyester resin composition
JP3300613B2 (en) * 1996-09-12 2002-07-08 三井化学株式会社 Method for producing polyethylene terephthalate
KR100449383B1 (en) * 1997-06-26 2004-11-26 주식회사 휴비스 Manufacturing method of fire retardant polyester fiber having excellent mechanical properties
JPH1135667A (en) * 1997-07-18 1999-02-09 Nippon Ester Co Ltd Production of flame-retardant polyester
KR100370274B1 (en) * 1999-06-26 2003-01-29 주식회사 효성 Manufacturing process of nonflammable polyester
JP2002161131A (en) * 2000-11-29 2002-06-04 Mitsubishi Chemicals Corp Flame retardant polyester resin
JP4595309B2 (en) * 2003-10-17 2010-12-08 東レ株式会社 Production method of flame retardant polyester
KR20050037854A (en) * 2003-10-20 2005-04-25 에스케이씨 주식회사 Flame-retardant polyester film
KR101083773B1 (en) * 2004-04-27 2011-11-18 코오롱인더스트리 주식회사 A flame retardant polyester with excellent color tone, and a process of preparing the same
KR100561083B1 (en) * 2004-05-10 2006-03-15 주식회사 효성 Cation Dyeable flame retardant polyester polymer and manufacturing method thereof, and copolyester fiber prepared from said copolyester copolymer
KR20050116537A (en) * 2004-06-08 2005-12-13 주식회사 코오롱 A conjugated fiber with excellent flame retardant composed two component

Also Published As

Publication number Publication date
CN101186689B (en) 2012-10-03
CN101186689A (en) 2008-05-28
TWI368625B (en) 2012-07-21
JP5132271B2 (en) 2013-01-30
DE102007056179B4 (en) 2017-11-09
JP2008127570A (en) 2008-06-05
KR100764378B1 (en) 2007-10-08
DE102007056179A1 (en) 2008-12-04

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