TW200827397A - Novel polyolefin-based resin composition and resin molded article thereof - Google Patents

Abstract

The present invention provides a polyolefin-based resin composition comprising 100 weight parts of a polyolefin-based resin, 0.01 to 1 weight part of a specific amide-based component (A), 0.005 to 1 weight part of at least one inorganic compound (B) selected from the group consisting of hydrotalcite, calcined hydrotalcite, talc, alkali aluminum double hydroxides, magnesium hydroxide, magnesium oxide, calcium carbonate and calcium oxide. The present invention also provides polyolefin-based resin molded articles with excellent crystallinity, rigidity and transparency; etc.

Description

[Technical Field] The present invention relates to a novel polyolefin-based resin composition and a method for producing the same, and a polyolefin-based resin obtained by molding the polyolefin-based resin composition A method for improving the transparency of a polyolefin resin, a method for increasing the rigidity of the polyolefin resin, and a nucleating agent composition for a polyolefin resin. [Prior Art] The polyolefin resin has excellent moldability, mechanical properties, electrical properties, and the like, and is used in various fields as materials for film formation, sheet molding, blow molding, and injection molding. However, the polyolefin-based resin generally has the above-mentioned excellent physical properties, but generally has problems of transparency, crystallinity, and low rigidity. In order to improve these problems, there has been a

A technique in which a compound or the like is used as a nucleating agent composition is proposed (Patent Documents 1 to 4). The polyolefin-based resin composition containing the amide-based compound has a very high crystallization rate, and when the composition is injection-molded, it contributes to shortening the cycle time. Further, the transparency and mechanical properties (stability, etc.) of the obtained molded body are improved. Further, in order to further improve the mechanical properties, a method of further blending a filler (filler) such as talc with a polyolefin-based resin composition containing an amine-based compound is known (Patent Documents 5 and 6). In general, the amount of the compound is 5 to 3 % by weight relative to 5 200827397 polyolefin resin, which is a large amount. In recent years, in order to meet the demand for diversification and high functionality of polyolefin-based resin molded articles, it is necessary to develop a transparency and mechanical strength of a poly-smoke-based resin molded article. It is a polyolefin resin composition such as rigidity. [Patent Document 1] Japanese Patent Laid-Open No. Hei 6-192496 [Patent Document 2] [Patent Document 3] [Patent Document 4] [Patent Document 5] [Patent Document 6]

曰 特 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 DISCLOSURE OF THE INVENTION Problem to be Solved by the Invention 15 An object of the present invention is to provide a polyolefin resin composition and

In the production method, the polyolefin resin molded article can have excellent crystallinity, rigidity, transparency, and the like. Another object of the present invention is to provide a polysoic 20 hydrocarbon resin molded article having excellent crystallinity, rigidity, transparency, and the like which is obtained by molding the polyolefin resin composition, and to improve transparency of the polyolefin resin. A method for improving the rigidity of a polyolefin resin and a nucleating agent composition for a polyolefin resin. Means for Solving the Problem In view of the above-mentioned status quo, the inventors of the present invention have studied in detail in order to solve the above-mentioned problems, and found that it is possible to significantly increase the concentration of polyamines by blending a specific amine-based compound with a specific inorganic compound in a polyolefin-based resin. The hydrocarbon resin has crystallity, rigidity and transparency, and can improve heat resistance. The present invention resides in the above-mentioned findings, and is further studied and transferred to the completion. The present invention can provide an invention of the following items. (1) A polyolefin resin composition comprising: a polyolefin resin; (at least) a guanamine compound represented by the formula (1), which is 100 parts by weight based on the polystyrene resin a 化合物1~1 part; and 10 (B) 0.005~1 parts by weight of an inorganic compound selected from the group consisting of hydrotalcite, calcined hydrotalcite, talc, alkali aluminum hydroxide, magnesium hydroxide, magnesium oxide , at least one of the group consisting of calcium carbonate and calcium oxide; [Chemical 1] • 15 r2 rHconh^jT )k (1) where k represents an integer of 3 or 4; R1 represents from 1, 2, 3 a residue obtained by removing all of the groups in propanetridecanoic acid, 1,2,3,4-butanetetracarboxylic acid or 1,3,5-benzenetricarboxylic acid; 3 or 4 R2 systems are each other The same or different each represents a hydrogen atom or a linear or branched alkyl group having 1 to 10 carbon atoms. (2) The polyolefin resin composition according to Item 1, wherein the component (A) and the component (B) 20 are (A) component: (B) component = 1: 0: 01 to 10 by weight ratio. use. (3) The polyolefin resin composition according to Item 1, wherein the (Α) component and the (Β) component are used in a weight ratio of (Α) component: (Β) component = 1: 0·1 to 3 . (Claim 4) A polyolefin-based resin molded article obtained by molding the polyolefin-based resin composition according to any one of the above items. (Claim 5) The polyolefin resin molded article according to item 4, wherein the molding method has a step of: completely melting the component (A) in the melt of the polyolefin resin (item 6) A method of transparency of a polyolefin-based resin, which comprises the step of containing the following substances in a weight fraction of the polyolefin resin, that is,

(Α) 0·01 to 1 part by weight of at least one hydrazine compound represented by the formula ;); and (Β) 0·005 to 1 part by weight of an inorganic compound selected from hydrotalcite and calcined At least one of the group consisting of hydrotalcite, talc, alkali dihydroxide, magnesium hydroxide, magnesium oxide disulfide, and oxidation #5;

R^CONH-O )k (1) wherein k represents an integer of 3 or 4; R1 represents from l5 2, propane tricarboxylic acid, 1,2, 3, 4-butane tetra- or 丨, 3, 5_Benzene_Removal of all residues after removal of all ruthenium, 3 or 4 R2 lines are the same or different, each represents a hydrogen atom or a linear or branched alkyl group having 1 to 10 carbon atoms base. (Item 7) A method for increasing the rigidity of a polyolefin-based resin, comprising the step of: (A) at least one of 0.0 W by weight of the polyolefin resin; An indole compound represented by the formula (1); and 8 200827397 (Β) 0·005 to 1 part by weight of an inorganic compound selected from the group consisting of Dianshi, Peihua hydrotalcite, talc, double hydroxide, and hydroxide At least one of a group consisting of money, gasification of Weiyue calcium carbonate and calcium oxide; Λ, 【化3】r4conh-〇)k (i)

10

Where k represents an integer of 3 or 4; Ri represents from! 'A 3-propane trisinic acid, U, 3,4-butadiene four _, 3,5_benzene three _ remove all; the residue obtained after the base; 3 or 4! ^ are mutually identical Or different, 峠 峠 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢In the respective table (item 8), a polyolefin-based resin composition fat composition contains: · agglomerated 'the poly-hydrocarbon-derived polyolefin-based resin; /A) to f, an amine-based compound represented by the formula (1), It is 〇〇1 to i parts by weight with respect to 100 parts by weight of the poly-smoke-based resin · ' ^ (8) Na ~! The inorganic compound of the weight fraction is selected from the group consisting of stone, smoldering hydrotalcite, talc, dihydrogen oxide, hydrogen oxyhydroxide, oxidized/month calcium carbonate and calcium oxide, at least _, Lizhen, [化4] '

RHcom^y)k (1) 20 wherein k represents an integer of 3 or 4; Ri represents octagonal 1,2,3-propanetricarboxylate 9 200827397 acid, 1,2,3,4·butane tetracarboxylic acid or! a residue obtained by removing all carboxyl groups in 3, 5-benzenetricarboxylic acid; 3 or 4 R2 systems are the same or different from each other, and each represents a hydrogen atom or a linear or branched carbon number of 1 to 1 Å. The dendritic alkyl group; however, the production method comprises a step of completely dissolving the component (A) in a melt of the polycarbonate-based resin. (Equation 9) A nucleating agent composition for a polyolefin resin having a uniform composition, comprising: (A) at least one guanamine compound represented by the formula (1), which is relative to the polyolefin resin 100 0.001 to 1 part by weight by weight; and 〇(B) 0·005 to 1 part by weight of an inorganic compound selected from the group consisting of hydrotalcite, calcined hydrotalcite, talc, alkali aluminum hydroxide, magnesium hydroxide, At least one of the group consisting of magnesium oxide, calcium carbonate, and calcium oxide;

Wherein k represents an integer of 3 or 4; R1 represents from 1,2,3-propanetricarboxylic acid, 1,2,3,4-butanetetracarboxylic acid or hydrazine, 3,5-benzenetricarboxylic acid The residue obtained by removing all the carboxyl groups; the three or four R2 systems are the same or different from each other, and each represents a hydrogen atom or a linear or branched alkyl group having 1 to 10 carbon atoms. (Item 10) The nucleating agent composition for a polyolefin resin according to Item 9, wherein (a) 20 component and (B) component are (A) component: (B) component = 1: 0·01~ 1〇 weight ratio is used. EFFECTS OF THE INVENTION 200827397 The present invention provides a plant containing a polyolefin resin, a component (4), and (9) a hydrated olefin, and a resin composition, which can be formed by molding the fumarate resin composition. A polyolefin resin molded article having excellent crystallinity, rigidity, transparency, and heat resistance is obtained. Further, the present invention also provides a nucleating agent composition comprising the component (A) and the component (B). Since the nucleating agent composition containing the component (A) and the component (B) of the present invention is a powder having good fluidity, the transportability in the catheter is excellent, and workability can be improved. [Embodiment] The preferred embodiment of the present invention is a component of the present invention. Specifically, the following compounds are exemplified. <(A1): tridecylamine of propane tricarboxylic acid> 15 1,2, 3-propanetricarboxylic acid tricyclohexyldecylamine, 1,2,3-propanetricarboxylic acid tris(2-methylcyclohexylfluorene) Amine), 1,2,3-propanetricarboxylic acid tris(3-mercaptocyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(4-mercaptocyclohexyldecylamine), 1,2 , 3-propanetricarboxylic acid tris(2-ethylcyclohexyldecylamine), 20 1,2,3-propane tricarboxylic acid tris(3-ethylcyclohexyldecylamine), 1,2,3·propane III Tris(4-ethylcyclohexyldecylamine)carboxylate, 1,2,3-propane tricarboxylic acid tris(2-n-propylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tri 3-n-propylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(4-n-propylcyclohexyldecylamine), 11 200827397 1,2, 3-propanetricarboxylic acid tris(2-) Isopropylcyclohexylguanamine), 1,2,3-propanetricarboxylic acid tris(3-isopropylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(4-isopropylcyclo) Hexyl decylamine, 1,2,3-propane tricarboxylic acid tris(2-n-butylcyclohexyl decylamine), 5 1,2, 3-propane tricarboxylic acid tris(3-n-butylcyclohexyl decylamine , 1,2, 3-propane tricarboxylic acid tris(4-n-butylcyclohexyl decylamine) 1,2,3-propanetricarboxylic acid tris(2-isobutylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(3-isobutylcyclohexyldecylamine), 1,2 , 3-propanetricarboxylic acid tris(4-isobutylcyclohexyldecylamine), 10 1,2,3-propane tricarboxylic acid tris(2·t-butylcyclohexyldecylamine), 1,2, 3 - propane tricarboxylic acid tris(3-t-butylcyclohexyldecylamine), 1,2,3-propane tricarboxylic acid tris(4-t-butylcyclohexyldecylamine), 1,2,3-propane Tris(2-tert-butylcyclohexyldecylamine) tricarboxylate, tris(3-tert-butylcyclohexyldecylamine) 1,1,2,3-propane tricarboxylate Tris(4-t-butylcyclohexyldecylamine) carboxylic acid, 1,2,3-propane tricarboxylic acid tris(4-n-pentylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid (4-n-hexylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(4-n-heptylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(4-n-octyl) Cyclohexyl decylamine), 20 1,2,3·propane tricarboxylic acid tris[4-(2-ethylhexyl)cyclohexyl decylamine], 1, 2, 3-propane tricarboxylic acid tris(4-positive Mercaptocyclohexyl decylamine, 1,2,3-propane tricarboxylic acid tris(4-n-aryl) ring Baseline amine, 1,2,3-propane tricarboxylic acid tris(di-2-methylhexyl-mono-cyclohexyl)decylamine, 1,2,3-propane tricarboxylic acid tris(dicyclohexyl-2 -Methylcyclohexyl)guanamine. 12 200827397 <(A2) : Butane tetracarboxylic acid tetradecylamine> 1,2,3,4-butanetetracarboxylic acid tetracyclohexyldecylamine, 1,2,3,4-butanetetracarboxylic acid Tetrakis(2·methylcyclohexyldecylamine), 1,2,3,4-butadienyltetracarboxylic acid tetrakis(3·methylcyclohexyldecylamine), 5 1,2, 3, 4·butane tetracarboxylate Tetrakis(4-methylcyclohexyldecylamine), '1,2,3,4-butanetetracarboxylic acid tetrakis(2-ethylcyclohexyldecylamine)^ 1,2,3,4·butane IV Tetrakis(3-ethylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-ethylcyclohexyldecylamine), ® 1,2,3,4-butane Tetrakis(4-n-propylcyclohexyldecylamine) tetracarboxylate, tetrakis(3-n-propylcyclohexyldecylamine), 1,2,3,4, 4 1,2,3,4-butanetetracarboxylic acid 4-butane tetracarboxylic acid tetrakis(4-n-propylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(2-isopropylcyclohexyldecylamine), 1,2, 3 , 4-butane tetracarboxylic acid tetrakis(3-isopropylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-isopropylcyclohexyldecylamine), 15 1, 2, 3, 4·butane tetracarboxylic acid tetrakis(2-n-butylcyclohexyldecylamine), ^ 1,2,3,4-butanetetracarboxylic acid tetrakis(3-positive) Cyclohexyl decylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-n-butylcyclohexyl decylamine), 1,2,3,4-butanetetracarboxylic acid tetra (2 -isobutylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(3-isobutylcyclohexyldecylamine), 20 1,2,3,4-butanetetracarboxylic acid Tetrakis(4-isobutylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(2-t-butylcyclohexyldecylamine), 1, 2, 3, 4-butane Tetrakis(4,2-butylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-t-butylcyclohexyldecylamine), 1,2,3, 4-butane tetracarboxylic acid tetrakis(2-tert-butylcyclohexyl decylamine), 13 200827397 5 10 1,2, 3, 4-butane tetracarboxylic acid tetrakis(3-tert-butylcyclohexyl decylamine , 1,2,3,4-butanetetracarboxylic acid tetrakis(4-t-butylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-n-pentyl ring) Hexylguanidamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-n-hexylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-n-heptyl) Cyclohexyl decylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-n-octylcyclohexyl decylamine), 1,2, 3, 4- Tetrakis(4-ethylhexyl)cyclohexyldecylamine, 1,2,3,4-butanetetracarboxylic acid tetrakis(4-n-decylcyclohexyldecylamine), 1,2 , 3, 4·butane tetracarboxylic acid tetrakis(4-n-butylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(dicyclohexyl-di-2-methylcyclohexyl) ) guanamine. <(A3): Tridecylamine benzenetricarboxylic acid> 1,3,5-benzenetricarboxylic acid tricyclohexyldecylamine, 1,3,5-benzenetricarboxylic acid tris(2-methylcyclohexylfluorene) Amine), 1,3,5-benzenetricarboxylic acid tris(3-methylcyclohexyldecylamine), 15 1,3, 5-benzenetricarboxylic acid tris(4-methylcyclohexyldecylamine), • 1 , 3, 5-benzenetricarboxylic acid tris(2-ethylcyclohexyldecylamine), 1,3, 5-benzenetricarboxylic acid tris(3-ethylcyclohexyldecylamine), 1,3, 5-benzene Tris(3-ethylcyclohexyldecylamine) tricarboxylate, tris(2-n-propylcyclohexyldecylamine) 1,1,3,5-benzenetricarboxylic acid, 1,3,5-benzenetricarboxylic acid (3-n-propylcyclohexyldecylamine), 1,3,5-benzenetricarboxylic acid tris(4-n-propylcyclohexyldecylamine), 1,3, 5-benzenetricarboxylic acid tris(2-iso Propylcyclohexyldecylamine), 1,3,5-benzenetricarboxylic acid tris(3-isopropylcyclohexyldecylamine), 1,3,5-benzenetricarboxylic acid tris(4-isopropylcyclohexyl) Guanamine), 14 200827397 1,3, 3-(2-n-butylcyclohexyldecylamine) 5-benzenetricarboxylate, 1,3,5-benzenetricarboxylic acid tris(3-n-butylcyclohexyldecylamine , 1,3, 5-benzenetricarboxylic acid tris(4-n-butylcyclohexyldecylamine), 1,3, 5-benzenetricarboxylic acid tris(2-isobutylcyclohexyl) Amine), 5,3,5-benzenetricarboxylic acid tris(3-isobutylcyclohexyldecylamine), 1,3,5-benzenetricarboxylic acid tris(4-isobutylcyclohexyldecylamine), 1,3, 5-benzenetricarboxylic acid tris(2-t-butylcyclohexyldecylamine), 1,3, 5-benzenetricarboxylic acid tris(3-t-butylcyclohexyldecylamine) 1,3 , 5-benzenetricarboxylic acid tris(4-t-butylcyclohexyldecylamine), 10 1,3, 5-benzenetricarboxylic acid tris(2-t-butylcyclohexyldecylamine), 1, 3, Tris(3-t-butylcyclohexyldecylamine) 5-benzenetricarboxylate, tris(4-t-butylcyclohexyldecylamine) 1,3,5-benzenetricarboxylic acid, 1,3, 5- Tris(4-n-pentylcyclohexyldecylamine) benzenetricarboxylate, tris(4-n-hexylcyclohexyldecylamine) 1,1,3,5-benzenetricarboxylic acid Tris(4-n-heptylcyclohexyldecylamine), 1,3,5-benzenetricarboxylic acid tris(4-n-octylcyclohexyldecylamine), 1,3,5-benzenetricarboxylic acid tris[4- (2. ethylhexyl) cyclohexyl decylamine], 1,3, 5-benzenetricarboxylic acid tris(4-n-decylcyclohexyl decylamine), 1,3, 5-benzenetricarboxylic acid tris(4- N-arylcyclohexyl decylamine), 20 1,3,5-phthalic acid bis(di-2-decylhexyl-early-3⁄4 hexyl)-brown amine, and 1,3, 5-benzene Acid tri (dicyclohexyl-2-cyclohexyl Yue-yl) Amides like. Among the above-mentioned amide-based compounds, in view of nucleation, in particular, three or four R 2 in the formula (1) are each a hydrogen atom or a linear or branched carbon number of 1 to 4. A dendritic alkyl amide compound is preferred. Specifically, 15 200827397, a compound such as the following can be exemplified. <(AA1): trimethylamine of propane tricarboxylic acid> 1,2,3-propanetricarboxylic acid tricyclohexyldecylamine, 1,2,3-propanetricarboxylic acid tris(2-methylcyclohexylfluorene) Amine), 5 1,2, 3-propanetricarboxylic acid tris(3·methylcyclohexyldecylamine), ~ 1,2,3-propanetricarboxylic acid tris(4-methylcyclohexyldecylamine), - 1,2,3-propanetricarboxylic acid tris(2-ethylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(3-ethylcyclohexyldecylamine), 1,2,3· Propane tricarboxylic acid tris(4-ethylcyclohexyl decylamine), 10 1,2, 3-propane tricarboxylic acid tris(2-n-propylcyclohexyl decylamine), 1,2, 3-propane tricarboxylic acid Tris(3-propylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(4-n-propylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(2· Isopropylcyclohexylguanamine), 1,2,3-propanetricarboxylic acid tris(3-isopropylcyclohexyldecylamine), 15 1,2,3-propanetricarboxylic acid tris(4-isopropyl Cyclohexyl decylamine), ^ 1,2, 3-propanetricarboxylic acid tris(2-n-butylcyclohexyl decylamine), 1,2, 3-propane tricarboxylic acid tris(3-n-butylcyclohexyl fluorene Amine), _ 1,2, 3-propane tricarboxylic acid tris(4-n-butylcyclohexyl decylamine), 1,2,3-propanetricarboxylic acid tris(2-isobutylcyclohexyldecylamine), 20 1,2,3-propanetricarboxylic acid tris(3-isobutylcyclohexyldecylamine), 1,2 , 3-propanetricarboxylic acid tris(4.isobutylcyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(2-t-butylcyclohexyldecylamine), 1,2, 3- Propane tricarboxylic acid tris(3-tert-butylcyclohexyl decylamine), 1,2,3-propane tricarboxylic acid tris(4-t-butylcyclohexyl decylamine), 16 200827397 1,2, 3- Propane tricarboxylic acid tris(2-t-butylcyclohexyl decylamine), 1,2,3-propane tricarboxylic acid tris(3-tert-butylcyclohexyl decylamine), and 1,2,3-propane Tris(3-tert-butylcyclohexyldecylamine) tricarboxylate. <(AA2) : Butanetetracarboxylic acid tetradecylamine> 5 1,2,3,4-butanetetracarboxylic acid tetra(cyclohexyldecylamine), • 1,2,3,4·butane tetracarboxylate Tetrakis(2-methylcyclohexyldecylamine), • 1,2,3,4-butanetetracarboxylic acid tetrakis(3-methylcyclohexyldecylamine), 1,2,3,4-butane IV Tetrakis(4-methylcyclohexyldecylamine), ® 1, 2, 3, 4-butanetetracarboxylic acid tetrakis(2-ethylcyclohexyldecylamine), 10 1,2, 3, 4-butyl Tetrakis(3-ethylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4·ethylcyclohexyldecylamine), 1,2,3,4-butyl Tetrakis(4-n-propylcyclohexyldecylamine), 1,2,3,4·butanetetracarboxylic acid tetrakis(3-n-propylcyclohexyldecylamine), 1,2, 3, 4 -butane tetracarboxylic acid tetrakis(4-n-propylcyclohexyldecylamine), 15 1,2,3,4-butanetetracarboxylic acid tetrakis(2-isopropylcyclohexyldecylamine), ^ 1,2 , 3, 4-butane tetracarboxylic acid tetrakis(3·isopropylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-isopropylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(2-n-butylcyclohexyldecylamine), 1,2,3,4·butanetetracarboxylic acid tetrakis(3-n-butyl) Cyclohexyl decylamine), 20 1,2,3,4-butanetetracarboxylic acid tetrakis(4-n-butylcyclohexyl decylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(2- Isobutylcyclohexyl decylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(3-isobutylcyclohexyl decylamine), 1,2,3,4-butanetetracarboxylic acid tetra ( 4-isobutylcyclohexyl decylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(2-t-butylcyclohexyl decylamine), 17 200827397 1,2, 3, 4-butane Tetrakis(4,2-butylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-t-butylcyclohexyldecylamine), 1,2,3, 4-butanetetracarboxylic acid tetrakis(2-tert-butylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(3-tert-butylcyclohexyldecylamine), 5 1 , 2, 3, 4·butane tetracarboxylic acid tetrakis(4·t-butylcyclohexyldecylamine). <(AA3): Triammonium benzenetricarboxylate> 1,3,5-benzenetricarboxylic acid tricyclohexyldecylamine, 1,3,5-benzenetricarboxylic acid tris(2-methylcyclohexyldecylamine , 1,3, 5-benzenetricarboxylic acid tris(3-methylcyclohexyldecylamine), 10 1,3, 5-benzenetricarboxylic acid tris(4-methylcyclohexyldecylamine), 1,3 , 3-(2-ethylcyclohexyldecylamine) 5-benzenetricarboxylate, tris(3-ethylcyclohexyldecylamine) 1,3,5-benzenetricarboxylate, 1,3,5-benzenetricarboxylate Tris(4-ethylcyclohexyldecylamine), 1,3,5-benzenetricarboxylic acid tris(2-n-propylcyclohexyldecylamine), 15 1,3, 5-benzenetricarboxylic acid tris(3) - n-propylcyclohexyl decylamine), 1,3,5-benzenetricarboxylic acid tris(4-n-propylcyclohexyl decylamine), 1,3, 5-benzenetricarboxylic acid tris(2-isopropyl Cyclohexyl decylamine), 1,3,5-benzenetricarboxylic acid tris(3-isopropylcyclohexyl decylamine), 1,3, 5-benzenetricarboxylic acid tris(4-isopropylcyclohexyl decylamine ), 20 1,3, 5-(2-n-butylcyclohexyldecylamine) 5-benzenetricarboxylate, 1,3,5-benzenetricarboxylic acid tris(3-n-butylcyclohexyldecylamine), 1 , 3, 5-benzenetricarboxylic acid tris(4-n-butylcyclohexyldecylamine), 1,3, 5-benzenetricarboxylic acid tris(2-isobutylcyclohexyldecylamine), 1,3, Tris(3-isobutylcyclohexyldecylamine) 5-phenyltricarboxylate, 18 200827397 5 • 10 1,3, 5-(4-isobutylcyclohexyldecylamine) 5-benzenetricarboxylate, 1,3 , 3-(2-butylcyclohexyldecylamine) 5-benzenetricarboxylate, tris(3-t-butylcyclohexyldecylamine) 1,3,5-benzenetricarboxylic acid, 1,3, 5 - tris(4-t-butylcyclohexyldecylamine) benzenetricarboxylate, tris(2-tert-butylcyclohexyldecylamine) 1,3,5-benzene, 1,3,5-benzenetricarboxylic acid Tris(3-t-butylcyclohexyldecylamine) tricarboxylate, tris(4-t-butylcyclohexyldecylamine) 1,3,5-benzenetricarboxylate, and the like. Among these preferred amide-based compounds, three or four R 2 in the general formula (1) are each a hydrogen atom or a viewpoint from the viewpoints of the balance between transparency and rigidity, and ease of obtaining raw materials. A guanamine compound is preferred. Specifically, for example, 1,2,3-propanetricarboxylic acid tricyclohexyldecylamine, 1,2,3-propanetricarboxylic acid tris(2-methylcyclohexyldecylamine), 1, 2, 3-propanetricarboxylic acid tris(3-methylcyclohexyldecylamine), 15 1, 2, 3-propane tricarboxylic acid tris(4-methylcyclohexyldecylamine), • 1, 2, 3, 4- Butane tetracarboxylic acid tetracyclohexyl decylamine, 1,2,3,4-butanetetracarboxylic acid tetrakis(2-methylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetra (3-methylcyclohexyldecylamine), 1,2,3,4-butanetetracarboxylic acid tetrakis(4-methylcyclohexyldecylamine), 20 1,3, 5-benzenetricarboxylic acid tricyclohexyl Indoleamine, 1,3,5-benzenetricarboxylic acid tris(2-methylcyclohexyldecylamine), 1,3,5-benzenetricarboxylic acid tris(3-methylcyclohexyldecylamine), 1,3 , tris(4-mercaptocyclohexyldecylamine) 5-benzenetricarboxylate, tris(di-2-decylhexyl-mono-cyclohexyl)decylamine 1,2,3-propanetricarboxylate, and 19 200827397 1,2,3·propane tricarboxylic acid tris(dicyclohexyl-2-methylcyclohexyl)decylamine or the like. Further, when the improvement effect of transparency is emphasized, R1 in the general formula (1) is obtained by removing all carboxyl groups from 1,2,3·propane tricarboxylic acid or 1,3,5-benzenetricarboxylic acid. Residual amine amine compounds are preferred. Specifically, for example, 1,2,3·propane tricarboxylic acid tricyclohexyl decylamine, 1,2,3-propane tricarboxylic acid tris(2-methylcyclohexyl decylamine), 1, 2, 3-propanetricarboxylic acid tris(3-mercaptocyclohexyldecylamine), 1,2,3-propanetricarboxylic acid tris(4-methylcyclohexyldecylamine), 10 1,3, 5-benzenetricarboxylate Tricyclohexyl decylamine and tris(2.methylcyclohexyl decylamine) 1,3,5-benzenetricarboxylate. The guanamine-based compound represented by the formula (1) may be used singly or in combination of two or more kinds as appropriate. The crystal form of the guanamine compound of the present invention is not particularly limited as long as the effect of the present invention can be obtained, and a crystalline form such as hexagonal crystal, monoclinic crystal or cubic crystal can be used. Such crystallization is conventional or can be made by conventional methods. The guanamine compound of the present invention is preferably one having a purity of 100%, but may be one containing a plurality of impurities. When the impurity is contained, the purity of the 20 amide compound is preferably 90% by weight or more, more preferably 95% by weight or more, particularly preferably 97% by weight or more. The impurity may, for example, be a monoamine dicarboxylic acid or an ester compound thereof derived from a reaction intermediate or an unreacted product, a dimethylamine monocarboxylic acid or an ester compound thereof, and a ruthenium imide compound derived from a side reaction. 20 200827397 The method for producing the acid amine compound of the present invention is not particularly limited, and only the desired amide compound can be obtained. For example, it can be obtained from a specific polycarboxylic acid component and a specific alicyclic monoamine component by a conventionally known method (e.g., JP-A-7-24261A). The aliphatic polycarboxylic acid component is exemplified as bismuth, 2,3-propane tricarboxylic acid, hydrazine, 2,3,4-butanetetracarboxylic acid, hydrazine, 3,5-benzene monocarboxylic acid, and the polycarboxylate. A ruthenium chloride and an acid anhydride, and a derivative of the polycarboxylic acid and an ester of a lower alcohol having 1 to 4 carbon atoms. These aliphatic polycarboxylic acid components may be subjected to amidation alone or in combination of two or more. The lipid monoamine component is selected from the group consisting of a cyclohexylamine and a linear or branched alkyl group substituted with a carbon number of 1 to 1 Torr (preferably 1 to 4 carbon atoms). At least one of the group consisting of hexylamines may be subjected to aromatization alone or in combination of two or more. Specific examples thereof include cyclohexylamine, 2-methylcyclohexylamine, 3-:cyclohexylamine, 4·methylcyclohexylamine, 2-ethylcyclohexylamine, 3-ethylhexylamine , 4-ethylcyclohexylamine, 2-n-propylcyclohexylamine, 2-isopropylhexylhexylamine, 2-n-butylcyclohexylamine, 2-isobutylcyclohexylamine, 2_second Base hexylamine, tert-butylcyclohexylamine, 2·n-hexylcyclohexylamine, n-octyl hexylamine, 2 • n-butylcyclohexylamine, 4—n-propylcyclohexyl-isopropylcyclohexyl Amine, 4-n-butylcyclohexylamine, 4-isobutylcyclohexylamine 4 first butylcyclohexylamine, 4-tert-butylcyclohexylamine, 4-n-hexylcyclohexylamine, 4 nn # 1 N-octylcyclohexylamine and 4-n-butylcyclohexylamine. The motor may be exemplified by cyclohexylamine, 2-methylcyclohexylamine, 3-methylcyclohexylamine, 4-methyl lysine 3 linylhexylamine, 2-ethylcyclohexylamine, 2-n-propyl Base ring hexylamine, 2-isopropylcyclohexylamine, 2-n-butylcyclohexylamine, 2-isobutyl ring 21 200827397 hexylamine, 2-t-butylcyclohexylamine and 2_third Cyclohexylamine and the like. The cyclohexyl base substituted by the county is a mixture of a cis tilt, a trans form, and a mixture of the stereoisomers. Preferably, the ratio of the trans isomer: the ratio of the trans form to the GLC area is 5 〇 : 5 〇 〇 : 1 〇〇 range, and more preferably 5 %: 65 〇 : just the range. Further, "GLC" means a gas-liquid phase analysis method. (3) The particle size of the brewable amine compound of the present invention is "unspecially limited" before the effect of the present invention can be obtained, and the particle size is determined from the viewpoint of the melting rate (or dissolution time) of the molten polyolefin resin. It may be small. When the measured value of the particle diameter is obtained by the diffraction 10 method (volume reference), the particle diameter of the amylose-based compound is preferably not more than m, more preferably 50 μm, and more preferably 50 μm. It is especially good to l〇#m. In the method of adjusting the maximum particle diameter within the above range, a conventional pulverizing apparatus is generally used in the technical field, and a conventional grading apparatus can be used as needed. Specifically, the pulverizing apparatus can be exemplified by a counter-jet mill 100AFG (trade name, manufactured by Hosokawa Micron Co., Ltd.) and a supersonic jet mill pJM_2 (trade name, manufactured by Sakamoto Pneumatic Co., Ltd.). And a disc type grinder (pin_mm), etc., and the sorting apparatus can be exemplified by a sieve classifier, a dry classifier (Cydone, a micro-isolator, etc.).

Kg) Ingredients: No 蜱彳h厶物1 (B) The ingredients are selected from the group consisting of hydrotalcite, calcined hydrotalcite, talc, alkali ahimimim double hydroxides, magnesium hydroxide, magnesium oxide. At least one of 22,227,397 inorganic compounds in the group consisting of calcium carbonate and calcium oxide. In the case of the hydrotalcite, it is also possible to use a commercially available product which is generally obtainable without impairing the effects of the present invention. For example, · 3·5Η2〇 (trade name “DHT-4A”, manufactured by Kyowa Chemical Industry Co., Ltd.), Mg4.5ΑΜΟΚ) i3C03 (made by Kokusai Co., Ltd., trade name “DHT-4A2”), Mg4.5Al2 ( OH) 13C03 • 3·5Η2〇 (manufactured by Kyowa Chemical Industry Co., Ltd., trade name “dht-6”). These commercial products are also subject to surface treatment, but may be chemically identical to those without surface treatment. The above-mentioned calcined hydrotalcite is an inorganic oxide obtained by calcining hydrotalcite by a conventional method (e.g., Table 10, 2006-511679, JP-A-2000-212272, JP-A-4-505449, etc.). The calcined product can also be used as a commercially available product which can be obtained without impairing the effects of the present invention. For example, MgojAlojOuX, Concord Chemical Industry Co., Ltd., trade name r Concord de 21〇〇)). The aforementioned talc system has the same meaning as a compound generally represented by Mg3Si4〇1G(〇H)2 or a compound referred to as a hydrous. The talc can be used without prejudice to the effects of the present invention, and commercially available products which are generally available can be used. For example, "MICROACEP-6" (trade name, manufactured by Sakamoto Shisha Co., Ltd.). Further, the talc may contain an impurity such as carbonic acid or other minerals depending on the place of production, but 20 is not particularly limited without impairing the effects of the present invention. The alkali aluminum hydroxide can be used without departing from the effects of the present invention, and a synthetic product or a commercially available product which can be generally obtained can be used. The "test" refers to alkali metals and alkaline earth metals, specifically, alkali metals such as lithium, sodium and potassium, and alkaline earth metals such as calcium, barium and strontium. For example, Li2Al4(〇H)12C03 23 200827397 • 3H2〇 (manufactured by Mizusawa Chemical Industry Co., Ltd., trade name "Miscar Karak") can be exemplified. Before the test, the oxidized sputum bag was double-listed to her Wei salt (such as special Kaiping 10-45411), hydrated calcium s (hydr〇calumite) and hydrocalumite carbonate (such as special Kaiping 9-241019). 5, the magnesium hydroxide, magnesium oxide, calcium carbonate and calcium oxide can be used, and commercially available products and reagents which are generally available can be used without impairing the effects of the present invention. For example, the commercially available product may, for example, be magnesium hydroxide (Kyowa Chemical Industry Co., Ltd., trade name "Magsharat F"). The inorganic compound may be surface-treated with a higher fatty acid such as stearic acid or oleic acid such as oleic acid, decyl citrate or oleic acid amide or the like, which may be exemplified as a coating method such as coating. By. The pH of the inorganic compound is preferably from 7.0 to 14.0, more preferably from 7.2 to 13.0, and still more preferably from 7.5 to 12.0. Further, the pH of the inorganic compound is measured by the method described in the examples below. 15 The particle size of the inorganic compound is not extracted before the effect of the present invention is obtained, but the particle size is only possible from the viewpoint of the dispersibility and refractive index of the molten and molten polyolefin resin. The small one is appropriate. When the particle diameter measured by the laser diffraction diffusion method is used, the particle diameter of the inorganic compound is preferably 5 μM or less, more preferably 丨 茁, and 20 is better than Ιμηι. The hydrocarbon-based resin of the present invention is exemplified by a polyethylene resin, a polypropylene resin, a polyfluorene fluorene resin, a polybutylene resin, and the like. Specifically, for example, high-density polyethylene, medium-density polyethylene, 24 200827397 linear polyethylene, acetonitrile copolymer having an ethylene content of 5 (% by weight or more), preferably 5% by weight or more, and propylene are exemplified. The homopolymer, the propylene content-% by weight of the propylene copolymer, preferably the butene homopolymer, and the butyl olefin are preferably 5% by weight or more (preferably 7). a butyl diene copolymer, a methyl pentene homopolymer, a methyl pentene content of 5 wt% or more (preferably 7 wt% or more), and a polybutylene Rare. The aforementioned copolymer may be a random copolymer or a block copolymer. When the resins have a stereoscopic ship, they may be in the same row (isGtaetie) or syndiotactic.

The comonomer of the copolymer may be specifically exemplified by carbon such as ethylene, propylene, butylene, pentene, hexene, heptene, octene, decene, dilute, undecene and dodecene. a bicyclic monomer such as an atomic number of 2 to U, a bicyclo type monomer such as 1,4-endomethylenecyclohexene, a methyl ketone (meth)acrylate, or a (meth) propyl (meth) acrylate Dilute ester and ethyl acetate vinegar. 15 Suitable for the manufacture of catalysts for the aforementioned polymers, generally used

The Ziegler-Natta catalyst is self-evident, and it is also possible to use a catalyst (the catalyst system is used to carry excessive metal compounds (such as titanium trioxide, titanium tetrachloride, etc.) to the town of chlorination town 4 A catalyst for a 20-component system in which a carrier of a main component is combined with an alkyl aluminum compound (tetraethylaluminum, vaporized diethylaluminum or the like) may also be used as a metalocene catalyst. The flow rate of the t-ruthenium resin in the present invention (hereinafter, abbreviated as "MFR". JIS K 7210-1995) can be appropriately selected according to the molding method to which it is applied, but it is usually 〇·〇1 to 2 〇〇g/i 〇, and preferably 0.05 to 100 g/10 minutes. 25 200827397

The polyolefin-based resin may contain the above-mentioned (A) component, (B) component, and the following "other additives" (such as a modifier for a polyolefin resin) as described above to obtain the polyolefin system of the present invention. Resin composition. 5 The method for producing the polyolefin-based resin composition of the present invention is exemplified by the following methods: (1) preparing a polyolefin-based resin (a form such as a powder, a granule, a thin sheet or a pellet) according to a desired composition ratio, (A) ) component, (B) component and "other additives" as needed, followed by powder mixing (dry mixing) using a conventional mixer (such as a Henschel mixer, a belt mixer, a V-shaped mixer, etc.) a dry mixed type of a polyolefin resin composition; and a conventional mixed type mixer (such as a uniaxial or biaxial extruder), the above dry mixed type polyolefin resin The composition is melt-stirred in a general temperature of 160 to 30 (TC (preferably 180 to 280 ° C, more preferably 2 ° C to 260 ° C), and then the extruded strands are cooled, and Cutting the obtained strands, and producing a pellet-shaped polyolefin resin composition. Further, the method of forming the pellets also comprises preparing the component (A) in an amount of 1 to 20% by weight ( A method of high-concentration masterbatch pellet poly- and olefin-based resin composition of 2 to 15% by weight. The masterbatch pellet polyether 20 resin composition can be appropriately diluted with a polyolefin resin to a desired composition ratio and then supplied to a molding step. To more effectively obtain the effect of the present invention, the melt contained in the above (ii) In the stirring step, a step of completely melting the component (A) in the molten polyolefin resin is further provided. In particular, the polyolefin resin composition 26 200827397 of the present invention is used in the case of focusing on the polystyrene resin molded body. In the case of the use of transparency, it will be an important step. In order to completely dissolve as described above, it is preferred to heat the mixture to a temperature higher than the temperature of the (4) component (iv) poly-based resin, and to melt the pot. In other words, the temperature can be confirmed by the following method. First, the pellet of the polyolefin resin composition is experimentally prepared. Then, using a fine micromirror with a heating stage, the temperature rise rate is _. Under the condition, the pellet was observed. While the temperature-increasing towel was observed to be present in the small-sized (A)-age crystal, the heating was carried out, and the melting of the (A) component crystal in the smelting 10 polyolefin-based resin was determined by visual observation. In the present invention, as in the method exemplified in the above (ii), the method for producing a polyolefin-based lunar composition is also provided as follows. That is, the present invention provides an improvement of a polyolefin-based resin. The method of rigidity and transparency is characterized in that the polyfluorene-based resin contains 1 part by weight of 15 parts (A) and 0.005 to 1 part by weight of the component (B). Further, a method for producing a polyolefin-based resin composition comprising (A) a component of 0. 01 to 1 part by weight and (8) a component (10) of still more than 1 part by weight per part by weight of the polyolefin-based resin is provided. And the manufacturing method is provided with a step of completely melting the (Α) component to the molten polyolefin-based resin. The content of the (Α) component of the present invention is 0.01 to 1 part by weight based on 100 parts by weight of the polyolefin resin, and preferably 2 to 0.5 part by weight, more preferably 0.03 to 0.3 part by weight. Further, the content of the (Β) component of the present invention is 0.005 to 1 part by weight, and preferably 0. 01 to 〇·8 parts by weight, particularly 0.02 to 0.5, based on the weight of the polyolefin resin 1〇〇27 200827397. Parts by weight. In addition, in the prior art, the inorganic compound of the (Β) component is used as a filler (filler), and is 5 parts by weight to 5 parts by weight of the polyolefin resin, and the amount is 5 parts by weight. many. Moreover, fillers are considered to be unhelpful of transparency. However, the inventors of the present invention found that the use of (Α) ingredients and a small amount of (Β) ingredients can achieve an amazing effect of improving transparency. This insight is the first discoverer of the inventor of this case. Further, the composition ratio (weight ratio) of the (Α) component to the (Β) component of the present invention is preferably (Α) component: (Β) component = 1: 〇·〇1 to 10, preferably i: 0.05~ 5, more preferably 1: 0·1 to 3, and especially i: (u~2 is suitable. The effect of the present invention is markedly improved. The polyolefin resin of the present invention is polypropylene. In the case of a random copolymer, the transparency and crystallinity of the effect of the present invention tend to be improved, and the balance of transparency, crystallinity, heat resistance and rigidity is excellent in the case of a polypropylene 15-polymer. In the case of a polypropylene block polymer, the crystallinity, heat resistance and rigidity of the effect of the present invention tend to be improved. Further, the present invention also provides a nucleating agent composition for a polyolefin resin. When the polyolefin resin composition is produced, the component (A) and the component (B) may be mixed in advance (preferably uniformly mixed), and then the nucleating agent composition may be blended as a olefinic resin. That is, the present invention provides a polyolefin resin having a uniform composition containing the components (A) and (B). Further, the present invention also provides that the weight ratio of the component (A) to the component (B) is preferably (A) becomes (B) component = 1 ·· 〇~ι〇 (preferably 1 ·· 〇 〇5~$, more preferably 1: 28 200827397 0.1~3, and in particular! : 〇. Bu 2) The nucleating agent composition for the above polyalkylene-based resin. (4) Containing (8) 妓 (8) In the method of preparing a nucleating agent composition according to the fifth aspect of the invention, it is recommended to use a dry mixing method and an organic solvent as a dispersion medium. For the purpose of uniform mixing, the urethane resin composition of the present invention may be used in addition to the above (Α) component and (Β) component, and may be used in accordance with the purpose and use thereof. In the range of effect 10, "other additives" such as a modifier for polyolefin may be appropriately blended. The modifier for polyolefin may be referred to as "Positive-list additive" in a health agreement such as polyene smoke (2002) The various additives described. More specifically, it can be exemplified by: stabilizer (metal) Compound, epoxidized 15 compound, nitrogen compound, phosphorus compound, sulfur compound, etc.), ultraviolet absorber (monobenzophenone compound, benzotriazole compound, etc. antioxidant (phenolic compound, phosphite system) a compound, a sulfur compound, etc.), a surfactant, a lubricant (an aliphatic hydrocarbon such as paraffin or wax, a high-grade fatty acid having a carbon number of 8 to 22, and a south fatty acid metal salt having a reverse atomic number of 8 to 22; Ai, Ca, Mg, Zn), a southerly aliphatic alcohol having a carbon number of 8 to 22, a polyhydric alcohol, an aliphatic fatty acid having 4 to 22 carbon atoms, and an aliphatic monovalent alcohol having 4 to 18 carbon atoms In addition to esters, fatty acid amines having a carbon number of 8 to 22, decylamine, oxime oil, rosin derivatives, foaming agents, foaming aids and polymer additives, there are still plasticizers (phthalic acid II). Marrying, /, hydrogen ortho-dicarboxylic acid, second vinegar, etc.), cross-linking agent, cross-linking accelerator, 29 200827397 Charge inhibitor, dispersant, organic pigment, processing auxiliary and other nucleating agents And other additives. The amount of addition can be appropriately selected within the range not impairing the effects of the present invention. For example, it is preferable to blend the high-grade 5 and the known (tetra) metal (4) in the poly-dish resin composition of the present invention, and the polyolefin-based resin molded body of the present invention (especially in the case where the linonic resin is a polypropylene random copolymer) The transparency of time) has a tendency to improve. The additive may, for example, be a higher fatty acid metal salt having 8 to 22 carbon atoms, and is preferably a stearic acid or the like. The amount of the additive to be used is preferably from about 0.2 part by weight to about 2 parts by weight, and preferably from 10 0.005 to 0.1 part by weight. The polyolefin-based resin composition of the present invention produced by the illusion 1 is a useful polyolefin-based resin molded article having excellent crystallinity, heat resistance, rigidity and transparency. The polyolefin-based resin composition of the present invention can be molded by a conventional molding method which is used in the art to obtain the polyolefin-based resin molded article of the present invention. Specifically, molding methods such as injection molding, extrusion molding, blow molding, air compression molding, rotational molding, sheet molding, film formation, and heating into a 20 shape can be exemplified. The aforementioned molding conditions can be appropriately selected from a wide range of conventionally employed conditions. In the method of forming the polyolefin-based resin composition of the present invention, when the polyolefin-based resin composition of the present invention is molded, the (Α) component is completely dissolved in the molten polyolefin-based resin. Resin composition 30 200827397 Forming. In particular, when the polyolefin-based resin composition of the present invention is used in an application in which the transparency of the polyolefin-based resin molded article is emphasized, it is an important step. The molding temperature (resin temperature) is usually 160 to 30 (TC, preferably 5 to 180 to 280 ° C, and particularly preferably 200 to 260 ° C. The polyolefin resin molded body of the present invention thus obtained is crystallized. It is excellent in properties, transparency, rigidity, and heat resistance. Even in the past, it has been used as a smouldering resin composition containing a metal nucleating agent such as a metal phosphate, a metal carboxylate or a benzyl sorbitol. In the field, it can be used in the same way. 10 Specifically, it is suitable for use as: disposable syringes; packaging materials for foods and plants; various boxes for clothes boxes and clothes storage containers; Cups, packaging containers for conditioning foods; containers for microwaves; containers for beverages, cosmetics, pharmaceuticals, shampoos, etc.; containers and covers for seasonings such as miso and oyster sauce ; food containers and containers such as water, 15 m, bread and frustration; miscellaneous goods such as refrigerators; stationery; electrical and mechanical parts; and automotive parts, etc. The polyolefin resin molded body of the present invention Having the invention In addition, since the amide-based compound of the component (A) itself has excellent thermal stability, substantially no odor or odor is caused by the amide-based compound. Therefore, the molded body is important in odor. It is particularly useful for the use of odor stains (food packaging materials, beverage cans, cosmetic containers, etc.) EXAMPLES Hereinafter, the present invention will be described in detail by way of examples and comparative examples, but the present invention is not limited by the examples. 31 200827397 The pH value and the particle size of the inorganic compound of the present invention are measured by the following methods (1) and (the magical loading method. Further, the crystallinity, rigidity, heat resistance and transparency of the polyolefin resin molded body are as follows ( 3) Evaluation of the method of (6) (1) pH ft 5 After adding 5 ° of aqueous ethanol solution to a 1 〇 flask, the inorganic compound lg was added, and the inorganic compound was dispersed at a constant temperature of 25 ° C. Using a pH meter (manufactured by Horiba, Ltd.), the pH of the dispersion was measured immediately after the inorganic compound was applied for 10 minutes, and the particle size of the dispersion was measured. (10 (2) Particle size (body essence standard) Using a surfactant to make the inorganic compound The dispersion was uniformly dispersed in water to prepare a dispersion of the inorganic compound, and the median diameter of the obtained dispersion was measured by a laser diffraction/diffusion type particle size distribution measuring apparatus (model name "LA-910", manufactured by Horiba, Ltd.). Μηι). The smaller the value obtained, the smaller the particle size. 15 (3) Crystallinity Using a differential scanning calorimeter (model name "Diamond DSC", manufactured by Parkinyema Co., Ltd.), the heat peak was determined based on JIS K 7121. The peak of the obtained heat-generating peak is the crystallization temperature (it). The higher the crystallization temperature, the more excellent the crystallinity. In addition, the increase in crystallization temperature means that the crystallization rate becomes faster, which is beneficial to shorten the molding cycle time during injection molding. ί£ϊΜΜ. The bending elastic modulus (MPa) was measured using an Instron universal testing machine (model name "instron", manufactured by Instr〇n-Japan Company Limited) in accordance with JIS K 7203 (1982). In addition, the test temperature was 25. 〇, the test speed is l〇mm/ 32 200827397 points. The greater the value of the bending elastic modulus, the better the rigidity. Further, in the examples and the comparative examples, the test piece for measuring the bending modulus was 90 mm in length, 10 mm in width, and 4 mm in height. (5) Resistance to heat • 5 The HDT test apparatus (model name "HDT TESTER 3M-2", manufactured by Toyo Seiki Co., Ltd.) was used, and the deflection temperature (°C) of the load was measured in accordance with ASTM D648. In addition, the edge stress method was used to make the bending stress 〇45 MPa. The higher the temperature of the φ heavy deflection, the better the heat resistance. Further, in the examples and the comparative examples, the test piece for the deflection temperature of the load was 110 mm in length, 13 mm in width, and 40 mm in height and 40 mm in height. (6) Transparency The haze value (%, thickness lmm) was measured using a haze meter (model name "Hitzjad", manufactured by Toyo Seiki Co., Ltd.) based on ASTM D1003. The smaller the value obtained, the better the transparency. 15 Production Example 11 • 9.7 g (0.055 m) of 1,2,3-propanetricarboxylic acid and N-, a scale in a 500 ml four-necked flask equipped with a stirrer, a thermometer, a cooling tube, and a gas inlet. 100 g of pyridine-2-pyrrolidone was completely dissolved in 1,2,3-propanetricarboxylic acid while stirring at room temperature under a nitrogen atmosphere. 20 Next, 2·methylcyclohexylamine (trans isomer: cis isomer = 74.3: 25·7; GLC area%) 20.5 g (0.1815 mol), triphenyl phosphite citrate 56.3 g (0.1815 mol) was added. The bite was 14.48 (0.1815 mol) and the sulfhydryl group 2 - oxime ketone 50 g, and the mixture was stirred for 1 hour in a nitrogen atmosphere while stirring for 1 hour. After cooling, the reaction solution was gradually poured into a mixed solution of isopropyl alcohol 5 〇〇mi and water 5 〇〇 ml 33 200827397, and stirred at about 40 ° C for 1 hour, and then the precipitated white precipitate was filtered off. Further, the obtained white solid was washed twice with 500 ml of isopropyl alcohol at about 40 ° C, and then dried at 100 ° C and 133 Pa for 6 hours. The obtained dried product was pulverized in a mortar and passed through a standard sieve 5 (JIS Ζ-8801 specification) of a mesh of 1 〇 6 μηι to obtain a 1,2-, 3-propanetricarboxylic acid tris(2-methylcyclohexylfluorene) of the present invention. Amine) (hereinafter, abbreviated as "PTC-2MeCHA") 18.8 g (yield 74%). Production Example 21 The same procedure as in Production Example 1 was carried out except that cyclohexylamine (0.1815 mol) was used instead of 2-methylcyclohexylamine 10 (0.1815 mol), and 1, 2, and 3 of the present invention were obtained. Propane tricarboxylic acid tricyclohexyl decylamine (hereinafter abbreviated as "PTC-CHA") was 20.3 g (yield 80%). Production Example 31 Using 2-methylcyclohexylamine (trans isomer: cis isomer = 100:0; GLC 15 area%, 0.1815 mol) was substituted for 2-methylcyclohexylamine (trans form: cis form) = 74.3: 25.7; GLC area%, 0J815 mol), and in the same manner as in Production Example 1, the 1,2,3-propanetricarboxylic acid tris(2.methylcyclohexyldecylamine) of the present invention was obtained. (trans form; hereinafter referred to as "PTC-2MeCHA (100)") 17.3 g (yield 75%). 20 "Production Example 41 each uses 1,3,5-benzenetricarboxylic acid (0.055 mol) and cyclohexylamine (0.1815 mol) to replace 1,2,3-propanetricarboxylic acid (0.055 mol) and 2 - mercaptocyclohexylamine (0.1815 mol), which was carried out in the same manner as in Production Example 1, to obtain tricyclohexyldecylamine 1,3,5-benzenetricarboxylate of the present invention (hereinafter, abbreviated as 34 200827397 " TM-CHA") 19.4 g (yield 78%). Manufacturing Example 51

Each uses 1,2,3, 4-butane, four acids (〇·〇55 moles), 2-methylcyclohexylamine (0.242 moles), triphenyl phosphite (0.242 moles), and a pyridine bite. (0.242 5 moles) to replace 1,2,3-propanetricarboxylic acid (0.055 mol), 2-methylcyclohexylamine (0.1815 mol), triphenyl phosphite (0J815 mol) and pyridinium (0·18ΐ5 莫耳)' was also carried out in the same manner as in Production Example 1, to obtain 1,2,3,4-butyring tetracarboxylic acid tetrakis(2-methylcyclohexyl decylamine) of the present invention (hereinafter, Slightly referred to as "btC-2MeCHA") 21.3 g (yield 63%). 1 制造 "Manufacturing Example 61 uses 1,2,3,4-butadiene tetracarboxylic acid (0.055 mol), cyclohexylamine (0.242 mol), quaternary acid vinegar (0.242 mol) and 121^ 0^(0.242 mol) to replace 1,2,3-propanetricarboxylic acid (0.055 mol), 2-methylcyclohexylamine (0.1815 mol), triphenyl phosphite (〇·ΐ815 mol· And pyridine (〇1815, 15 mil), and the same procedure as in Production Example 1, to obtain 20.0 g of the present invention - tetrabutylidene tetracarboxylic acid tetracyclohexyl decylamine (hereinafter abbreviated as "BTC_CH") Yield 66%). [Example 11 20] PTC prepared by the production example i used as the component (4) in the same-order polypropylene resin (MFR = 30 g / 1 〇 *, hereinafter abbreviated as "h-PP") u) 〇 by weight -2MeCHA 0.15 parts by weight and water-slip as component (B): l (Mg4.5Al2(0H)i3C03 · 3·5Η20, manufactured by Kyowa Chemical Industry Co., Ltd., "DHT-4A") 0.05 parts by weight, Adding other additives ^肆[亚;基-3-(3,5-di-t-butyl 4-predyl)-propionate]] (Chiba Special 35 200827397 Chemical company, trade name " IRGANOX1010") 0.05 parts by weight and bismuth subarsenate (2,4-di-t-butylphenyl) ester (trade name "IRGAFOS168", manufactured by Chiba Specialty Chemicals Co., Ltd.) 0.05 parts by weight, using Henschel The stirrer was dry-mixed at 1,000 rpm for 5 minutes to obtain a dry mixed type poly 5 olefin resin composition of the present invention. Next, the dry-mixed polyolefin-based resin composition was melt-stirred at a resin temperature of 240 C using a uniaxial extruder having a diameter of 20 mm, and then the extruded strands were water-cooled, and the obtained strands were cut. A pellet-type polyolefin resin composition of the present invention was obtained. Further, it was confirmed in advance that the above-mentioned added amount of the component (A) was soluble in the molten polypropylene resin at 240 °C. In the following examples, as in Example 1, a polarizing microscope with a heating stage was used to visually confirm that the amount of the component (A) contained in each table was melted in the contained polypropylene resin. Then, the obtained pellets of the present invention were injection-molded at a resin temperature of 250 ° C and a mold temperature of 4 (TC) to obtain a polyolefin-based resin molded article of the present invention (test piece). Crystallization temperature, flexural modulus, load deflection temperature and haze value, and inorganic compound ipH value and particle size, and 'the specific results are shown in Table 1. Example 2~ηι 2〇(A) component or The type or amount of the component (B) was changed to the type or addition amount shown in Table 1, and the polyolefin resin molded article (test piece) of the present invention was obtained in the same manner as in Example 。. The crystallization temperature, flexural modulus, load deflection temperature and haze value of the test piece, and the pH value and particle diameter of the inorganic compound used were not shown in Table 1 and Table 2. The comparative example 1 ~101

The type or addition amount of the component (A) or the component (B) was changed to the type or addition amount shown in Table 3, and the same procedure as in Example 1 was carried out to obtain a polyolefin resin other than the category of the present invention. Molded body (test piece). The crystallization temperature, the flexural modulus, the deflection temperature and the haze value of the obtained test piece, and the pH value and particle diameter of the inorganic compound used were measured, and the results of the measurements are shown in Table 3. Further, the activated clay system is described in the column (B) of Table 3, but is different from the component (B). 10 [Table 1] Polyolefin-based resin (A) Component: Amidoxime-based compound ____________ (B) Component: Inorganic compound Polyolefin-based resin molded article Type, addition amount, type, addition amount, pH, particle size, crystallization temperature, bending modulus, load Flexural temperature haze value (parts by weight) (parts by weight) (μιη) CC) (MPa) CC) (%) Example 1 h-PP PTC-2MeCHA 0.15 hydrotalcite 1 Mg4.5Al2(OH)13C〇3 · 3.5H20 0.05 8.6 0.43 132 1960 123 17 Example 2 h-PP PTC-2MeCHA 0.15 hydrotalcite 2 Mg45Al2(OH)nCO, 0.05 9.3 0.44 131 1950 123 15 Example 3 h-PP PTC-2MeCHA 0.15 Double Hydroxide Li2Al4(〇H)12C03 · 3H20 0.05 9.8 0.52 131 1940 122 17 Example 4 h-PP PTC-2MeCHA 0.15 hydrotalcite 3 Mg4.5Al2(OH)13C〇3 · 3.5H20 0.05 8.5 0.56 131 1950 122 15 Example 5 h-PP PTC-2MeCHA 0.15 calcined hydrotalcite MgojAlo 3〇1.15 0.05 11.4 8.6 131 1950 122 20 Example 6 h-PP PTC-2MeCHA 0.15 talc Mg3Si4〇i〇(OH), 0.05 9.0 5.5 127 1940 121 23 Example 7 h-PP PTC-2MeCHA 0.15 Mg(OH)2 0.05 9.7 6.9 131 1960 121 16 37 200827397 [Table 2] Polyolefin Resin (A) component: Hydrazine compound (9) Component: Inorganic compound Polyolefin resin molded article Type of addition amount (parts by weight) Type addition amount PH Particle size Crystallization temperature Bending elastic modulus load deflection temperature haze value ( Parts by weight (μιη) (°C) (MPa) ΓΟ (%) Example 8 h-PP PTC-2MeCHA 0.05 Hydrotalcite 1 Mg4.5Al2(〇H)13C03 · 3.5H20 0.1 8.6 0.43 130 1710 121 39 Example 9 h-PP PTC-CHA 0.15 hydrotalcite 1 Mg4.5Al2(OH)13C〇3 · 3.5H20 0.05 8.6 0.43 130 1900 121 29 Example 10 h-PP PTC-2MeCHA (100) 0.05 Hydrotalcite 1 Mg4.5Al2 ( OH) BC 〇 3 · 3.5H20 0.05 8.6 0.43 129 1810 120 33 Example 11 h-PP TM-CHA 0.05 Hydrotalcite 1 Mg4.5Al 2 (〇H) 13C03 · 3.5H20 0.05 8.6 0.43 126 1880 119 43 Example 12 h -PP BTC-2MeCHA 0.02 Hydrotalcite 1 Mg4.5Al2(0H)13C03 · 3.5H20 0.05 8.6 0.43 127 1850 119 38 Example 13 h-PP BTC-CHA 0.02 Hydrotalcite 1 Mg4.5Al2(OH)13C〇3 · 3.5 H20 0.05 8.6 0.43 128 1860 120 41

[Table 3] ^ --Γ Polyolefin-based resin (A) Component: Amidoxime-based compound (B) Component: Inorganic compound Polyolefin-based resin molded article Type of addition amount Kind addition amount PH Particle size Crystallization temperature Bending elastic modulus Load deflection temperature haze value (parts by weight) 0.15 (parts by weight) (μιη) ΓΟ (MPa) CC) (%) 1 -= 24 Comparative Example 1 h-PP PTC-2MeCHA I — — — 125 1910 118 Comparative Example 2 h-PP — — Hydrotalcite 1 Mg4.5Al2(OH)i3C〇3 · 3·5Η20 0.05 8.6 0.43 114 1260 98 74 Comparative Example 3 h-PP PTC-2MeCHA 0.15 Activated clay 0.05 5.6 31.4 122 1900 119 25 Comparative Example 4 h-PP PTC-2MeCHA 0.05 — — — — 124 1650 119 48 Comparative Example 5 h-PP PTC-CHA 0.15 — — — — 124 1860 119 40 Comparative Example 6 h-PP — — — — — — 114 1240 97 67 Comparative Example 7 h-PP PTC-2MeCHA (100) 0.05 — — — 125 1750 118 46 Comparative Example 8 h-PP TM-CHA 0.05 — — — — 123 1850 116 50 Comparative Example 9 h-PP BTC-2MeCHA 0.02 — — — — 123 1790 114 46 Comparative Example 10 -- h-PP BTC-CHA 0.02 — — — — 125 1810 115 47 38 200827397 In the above Tables 1 to 3 and Tables 4 and 5 below: "Hydrophyll 1" is Mg4.5Al2 (0H) 13C03 · 3·5Η20, manufactured by Kyowa Chemical Industry Co., Ltd., trade name "DHT-4A"; 2" is Mg4.5Al2(0H)13C03, Kyowa Chemical Industry Co., Ltd. 5, trade name "DHT-4A2"; "Lithium aluminum hydroxide" is Li2Al4(0H)12C03 · 3H20, manufactured by Mizusawa Chemical Industry Co., Ltd. "Mis Karak L"; "Hydrate Talc 3" is Mg4.5Al2(0H)13C03 · 3·5Η20, manufactured by Kyowa Chemical Industry Co., Ltd. under the trade name "DHT-6"; 10 "Boiled Hydrotalcite" is Mg〇 .7Al().3〇i.l5 'Concord Chemical Industry Co., Ltd., trade name "Kyowa De 2100"; "Talc" is Mg3Si401G (0H) 2, manufactured by Sakamoto Shisha Co., Ltd., trade name "MICRO ACEP-6"; "Mg(OH)2" is manufactured by Kyowa Chemical Industry Co., Ltd. under the trade name "Magsha 15 Lat F". f. Example 141 A polypropylene block copolymer (MFR = 18 g/10 min, hereinafter abbreviated as "b-PP") having an ethylene content of 9.5% by weight was changed, and the same procedure as in Example 1 was carried out. The polyolefin resin molded article of the present invention (20 sheets of test) was obtained. The crystallization temperature, the bending elastic modulus, the load deflection temperature, and the pH and particle diameter of the inorganic compound used were measured, and the results of the measurements are shown in Table 4. [Example 151] The type of the component (B) was changed to the type described in Table 4, and the polyolefin resin molded article (test piece) of the present invention was obtained in the same manner as in Example 14 of 200827397. The crystallization temperature, the bending elastic modulus, the load deflection temperature, and the pH and particle diameter of the inorganic compound used were measured, and the results of the measurements are shown in Table 4. [Comparative Examples 11 to 13] The type or amount of the component (A) or the component (B) was changed to the type or amount of the component described in Table 4, and the same procedure as in Example 14 was carried out to obtain the outside of the scope of the present invention. A polyolefin resin molded body (test piece). The crystallization temperature, the bending elastic modulus and the load deflection temperature of the obtained test piece were measured, and the results of the above 10 measurements are shown in Table 4. [Table 4] Polyolefin-based resin (A) component: guanamine-based compound----- 1 - (B) Component: Inorganic compound Polyolefin-based resin molded article Type, addition amount, type, addition amount, pH, particle size, crystallization temperature Flexural modulus load deflection temperature (parts by weight) (parts by weight) (μιη) ΓΟ (MPa) CC) Example 14 b-PP PTC-2MeCHA 0.15 hydrotalcite 1 Mg4.5Al2(OH)13C〇3 · 3.5H20 0.05 8.6 0.43 129 1280 104 Example 15 b-PP PTC-2MeCHA 0.15 talc Mg3Si4〇i〇(〇H)2 0.05 9.0 5.5 127 1260 103 Comparative Example 11 b-PP PTC-2MeCHA 0.15 — — — — 124 1220 101 Comparative Example 12 b-PP — monohydrate talc 1 Mg4_5Al2(OH)13C〇3 · 3.5H20 0.05 8.6 0.43 112 1030 85 Comparative Example 13 b-PP — I — — — a 112 1020 84 ΓExample 161 Change h-PP to A polypropylene-based random copolymer of the present invention (MFR = 20 gA0, hereinafter abbreviated as "Γ-ΡΡ"), and the same procedure as in Example 1 15 to obtain a polyolefin-based resin molded article of the present invention ( Test piece). The crystallization temperature, the flexural modulus, the deflection temperature and the haze value of the obtained test piece, and the pH value and particle diameter of the inorganic compound used were measured, and the results of the measurements were shown in Table 5. f is more than the example 14 to jjl. The type or addition amount of the component (A) or the component (B) is changed to the type or addition amount described in Table 5, and the same as in the case of Example 16, the invention is made outside the scope of the present invention. A polyolefin resin molded body (test piece). The crystallization temperature, flexural modulus, load deflection temperature and haze value of the obtained test piece were measured, and the results of the measurements are shown in Table 5. [Table 5] Polyolefin-based resin (A) Component: guanamine-based compound (B) Component: Inorganic compound The type of polyolefin-based resin molded article of the present invention is added in the amount of hydrotalcite 1 Mg4_5Al2(0H)13C03 · 3.5H20 Amount PH particle size crystallization temperature bending elastic modulus load deflection temperature haze value (parts by weight) 0.15 g parts) (μπι) CC) (MPa) 1340 1310 (°〇101 99 9 ======= ==3⁄4 12 ----- 59 Example 16 r-PP PTC-2MeCHA 0.05 8.6 0.43 123 116 Comparative Example 14 r-PP PTC-2MeCHA 0.15 — — — Comparative Example 15 r-PP — — Hydrotalcite 1 Mg4. 5Al2(〇H)i3C〇3 · 3.5H20 0.05 8.6 0.43 109 1040 87 丨Comparative Example 16 r-PP — — — — — 109 1030 87 58 Industrial Applicability 10 The polyolefin resin composition of the present invention can be The resin molded article obtained by molding the polyolefin resin composition has excellent crystallinity and rigidity, and is suitable for injection molding, film molding, blow molding, extrusion molding, heat molding, and the like. Heat resistance and transparency, so it can be used as medical equipment, food and plants Materials such as packaging materials, various boxes, food packaging containers, electronic microwave containers, groceries, stationery, electronic mechanical parts, and automotive parts are used. [Simple diagram 2 41 200827397 (none) [ Main component symbol description] (none)

42

Claims (1)

200827397, the scope of application of the patent: a poly-smoke-based resin composition containing a polysulfonate-based resin; (A) at least one amide-based compound represented by the formula (〗), relative to the polyolefin-based resin 100 parts by weight of 〇(1)~丨 by weight; and ', (Β)0·〇〇5~1 parts by weight of an inorganic compound selected from the group consisting of hydrotalcite, hydrotalcite, talc, and double hydroxide !S, magnesium hydroxide, 15 2. 3_ 4. In the group consisting of magnesium oxide, calcium carbonate and calcium oxide, [Chemical 1] ’ RLfCONH^COk (1) where k represents an integer of 3 or 4; R1 represents from ruthenium, 2,3-propane tricarboxylic acid, 1,2,3,4-butanetetracarboxylic acid or gramin, 3,5-benzene The residue obtained by removing all the carboxyl groups in the tricarboxylic acid; the three or four R2 groups are the same or different from each other, and each represents a hydrogen atom or a linear or branched alkyl group having 1 to 1 ring of carbon atoms. For example, the composition of the fine soot resin of the first item of the patent scope, wherein the ratio of the component (A) to the component (B) is (A): (b) component = ι : 0·01 to 10 use. A polyolefin-based resin composition according to the first aspect of the invention, wherein the (Α) component and the (Β) component are used in a ratio of (Α) component: (Β) component = 1: 0.1 to 3 by weight. A polyolefin-based resin molded article obtained by molding a polyolefin-based resin composition according to any one of claims 4 to 20, 2008, 297, 397 to 1-3. A method for improving the transparency of a polyolefin-based resin, comprising the step of: (100) parts by weight of at least one part by weight of the polyolefin resin; The amine compound 5 compound represented by the formula (1); and (Β) 0·005 to 1 weight! And an inorganic compound selected from the group consisting of hydrotalcite, hydrotalcite, talc, bismuth hydroxide, oxyhydrin, magnesium oxide, calcium carbonate and calcium oxide; 2] rHconh-O )k (1) where 'k represents an integer of 3 or 4; R1 represents 1,2,3-propane tricarboxylic acid, 1,2,3,4-butanic acid or! , 3, 5_Benzene triester acid, the residue obtained after removing the full-time base; 3 or 4 her 2 series are the same or different, • 纟 represents the nitrogen atom or the linear or branched shape of the atomic number Burn 15 bases. • Six methods for increasing the rigidity of the polyolefin-based resin, comprising the step of: - (A_~1 part by weight of at least one type of formula (1)) of 100 parts by weight of the poly-hydrocarbon (10) ester The amine compound according to the formula; and 20 (8) 0.005 parts by weight of the inorganic compound selected from the group consisting of hydrotalcite, calcined hydrotalcite, talc, hydrogen peroxide reduction, hydroxide cone, magnesium oxide, carbonic acid 1 At least one of a group of bows and oxidized dances. 44 200827397 [Chemical 3] rHconh-O^|k (!) where k represents an integer of 3 or 4; R1 represents a propane from 1, 2, 3· Residues obtained by removing all five carboxyl groups from tricarboxylic acid, 1,2,3,4-butanetetracarboxylic acid or 1,3,5-benzenetricarboxylic acid; three or four R2 systems are identical to each other Or different, each represents a hydrogen atom or a linear or branched alkyl group having 1 to 10 carbon atoms. 7. A method for producing a polyolefin resin composition comprising: 10 polyolefin (Α) at least one guanamine compound represented by the formula (1), which is 0.01 to 1 part by weight based on 100 parts by weight of the polyolefin resin; and (Β) 0.005 to 1 part by weight of an inorganic compound selected from the group consisting of hydrotalcite, calcined hydrotalcite, talc, alkali aluminum hydroxide, magnesium hydroxide, magnesium oxide, calcium carbonate and calcium oxide. One; [Chemical 4] R: rHconhXjT )k (1) where k represents an integer of 3 or 4; R1 represents 1,2,3-propanetricarboxylic acid, 1,2,3,4-butane Residues obtained by removing all 20 carboxyl groups from tetracarboxylic acid or 1,3,5-benzenetricarboxylic acid; 3 or 4 R2 systems are the same or different from each other, 45 200827397 each represents a hydrogen atom or a carbon atom A linear or branched burnt base of ～10; and the production method includes a step of completely dissolving the component (A) in a melt of the polyolefin resin. 8. A nucleating agent composition for a polyolefin resin, comprising: # (A) at least one acid-amine compound represented by the formula (1), which is 〇〇1 to 1 part by weight based on 100 parts by weight of the poly-based resin; and (Β) 0·005 to 1 part by weight An inorganic compound selected from the group consisting of hydrotalcite, calcined hydrotalcite, talc, alkali aluminum hydride, magnesium hydroxide, magnesium oxide, calcium carbonate, and calcium oxide; 】 RLfCONH^jT)k (1) wherein k represents an integer of 3 or 4; Ri represents 丨, 2, 3-propane tricarboxylic acid, 1,2,3,4-butanetetracarboxylic acid or hydrazine, 3 a residue obtained by removing all carboxyl groups in the terephthalic acid; 3 or 4 R2 groups are the same or different from each other, each represents a hydrogen atom or a linear or branched alkyl group having 1 to 10 carbon atoms; . 46 200827397 VII. Designation of representative representatives: (1) The representative representative of the case is: (No). (2) A brief description of the symbol of the representative figure: (none) 8. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: