TW200826848A - Packaged non-tea beverage - Google Patents

Abstract

A non-tea drink packed in a container which contains a purified green tea extract, characterized by: (A) containing from 0.01 to 1.0% by mass of unpolymerized catechins; (B) the ratio of unepimerized compounds in the unpolymerized catechins being from 5 to 25% by mass; (C) the pH value being from 2.5 to 5.1; and (D) containing from 0.0001 to 20% by mass of at least one member selected from among fructose, glucose, sucrose, high fructose corn syrup (containing less than 50% of fructose) and high fructose corn syrup (containing 50 to 90% of fructose). Thus, it is possible to provide a non-tea drink packed in a container which contains the unpolymerized catechins at a high concentration, has both of relieved astringency and appropriate sweetness/sourness with no damage in the flavor and is suitable for prolonged storage, although it contains the sweetener.

Description

200826848 IX. Description of the invention: [Technical field to which the invention pertains] The invention relates to a container-packed non-tea beverage in which a high concentration of catechin is added by adding a purified green tea extract, and the flavor is balanced. The reduction and moderate sweetness and sourness, although containing sweeteners, are suitable for long-term preservation. i [Prior Art] As a physiological effect of catechins, effects of inhibiting the rise of cholesterol or blocking the activity of amylase have been reported (for example, refer to Patent Documents 2 and 2). In order to make the catechins exhibit the physiological effects as described above, adults need to drink 4 to 5 cups of tea per day. Therefore, in order to more easily ingest a large amount of catechins, the manufacturer desires to add a high concentration of catechins to the beverage. technology. As one of the methods, there is a method in which a catechin is added to a beverage in a dissolved state by using a concentrate of green tea extract (for example, refer to Patent Documents 3 to 5). However, if the concentrate of the commercially available green tea extract is used as it is, the warmth or bitterness is strong and the throat is bad due to the influence of the components contained in the Chinese abundance of the green tea extract. At present, in order to obtain the adaptability for long-term drinking for the physiological effect of catechin, and adding a sweetener to be able to drink for a long period of time, there is a stability of the non-polymer catechin itself at a high temperature. problem. [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document 5] Japanese Patent Laid-Open No. Hei 8-- [Japanese Patent Laid-Open Publication No. Hei No. Hei No. Hei No. 2005-58208 [Patent Document 7] Japanese Patent JP-A-2005-58209 [Patent Document 8] Japanese Laid-Open Patent Publication No. 2005-58210 [Patent Document 9] Japanese Patent Laid-Open No. 2005-5821 No. 1 (Invention) The present invention provides a container-packed non-tea a beverage to which a purified product of green tea extract is added, and (A) a non-polymer catechin is 〇·〇 uo mass%, and (B) a non-polymer catechin non-body ratio is 5 〜 25% by mass, (C) pH value of 2.5 to 5.1, containing 0.0001 to 20% by mass of (1) one or more selected from the group consisting of fructose, glucose, sucrose, glucose fructose liquid sugar, and fructose glucose liquid sugar. [Embodiment] The present invention provides a container-packed non-tea beverage in which a high concentration of catechin is contained by adding green (a purified extract of tea extract, and both a reduction in astringency and a moderate sweetness and sourness are considered. The present inventors have studied the flavor of a green tea beverage containing a high concentration of catechins, and found that the pH can be controlled by controlling the pH even though it contains a sweetener. Value and the non-body ratio of non-polymer catechins, and the addition of a certain amount of specific sweeteners, which is obtained by taking into account both the reduction of warmth and moderate sweetness and sourness, even if it contains sweeteners, even if it is preserved for a long time. A non-tea beverage that can hold a catechin content. 117620.doc 200826848 This rabbit's gluten-free non-tea beverage is used to control the non-body ratio of non-polymer catechins and adjust the pH and The sweetener is selected, thereby achieving both a reduction in warm taste and a moderate sweetness and sourness, and maintaining the catechin content even in the case of long-term storage, although it contains a sweetener. (A) non-polymer catechins, which are non-epidermal catechins such as catechins, gallocatechin, catechin gallate vinegar, gallic catechin gallate The general term for the classification of catechins such as tea catechins, epicatechins, epigallocatechin, epicatechin gallate, epigallocatechin, gallic acid and vinegar The concentration of the non-polymer catechins is defined based on the total of the above eight kinds. The container-packed non-tea beverages of the present invention contain Ο.ΟΙΗ.Ο% by mass, preferably 0.07 to 0.5% by mass. %, more preferably 〇·〇8~〇·3 mass%, most preferably 0.09~0.2% by mass of non-polymer catechins. If the content of non-polymer catechins is within this range, then A large amount of non-polymer catechins can be easily taken in. Thus, it is desirable to obtain physiological effects of non-polymer catechins. Further, when the content of non-polymer catechins is less than 0.01% by mass, it is not expected to be obtained. The physiological effect of non-polymer catechins. In addition, if the content of non-polymer catechins exceeds 1.0% by mass, the bitterness of the beverage The non-polymer catechins in the container-packed non-tea beverages of the present invention include: epigallocatechin gallate, epigallocatechin, epicatechin The body of gallic acid ester and epicatechin, and catechin gallate, gallocatechin gallate, gallocatechin, and catechin Non-epithelial. Non-epiforms are almost non-existent in nature. 'The system is formed by thermal denaturation of the surface. Further, by thermal denaturation, 117620.doc 200826848 converts non-polymer catechins into polymers. The catechins. Therefore, (A) non-polymeric non-polymer catechins (B) non-polymerizable in the container-packed non-tea catechus of the present invention, from the viewpoint of wind stability and storage stability. The ratio of the non-epitopic class of the genus ([(B)/(A)]xl〇〇)) is preferably $~Μ mass °/. More preferably, it is 8 to 20% by mass, and particularly preferably 1 to 15% by mass. In the non-polymer catechins in the non-tea beverages of the container of the present invention, the presence and absence of epigallocatechin gallate _, the eclipse (four), the table «gallic acid s §, and catechins are not: =^ gallate body, and non-gallate body containing epigallocatechin, gallic catechin, and non-gallate. (8) Non-polymer catechins in the non-polymer catechins which can be used in the container-packed non-tea beverages of the present invention, from the viewpoint of suppressing bitterness, because of the bitter taste of gallic acid steroids. The ratio of the tea gallate body (the ratio of gallate body, [(8) / (A)] xl 〇〇), preferably 5 to 5 % by mass, more preferably 10 to 46 quality%.疋

The container-packed non-tea beverage having a high concentration of non-polymer catechins in the present invention can be adjusted, for example, by adding a purified product of green tea extract to a concentration of non-polymer catechins. Specifically, a green tea extract may be added to the concentrate aqueous solution of the green tea extract or the concentrate of the green tea extract. Here, the so-called "concentration of green tea extract" refers to the purification of non-polymer catechins from the extract of the green tea leaves by hot water or a water-soluble organic solvent. . As for t', various forms such as solid, aqueous solution, and slurry can be cited. 117620.doc 200826848 As a purified product of green tea extract containing non-polymer catechins, it can be selected from the commercially available Mitsui Nonglin (share) r POLYPHENONE" , Ito Park (shares) ''THEA-FLAN', Sun Chemicals (shares)' SUNpHEN〇NE,, and so on. If the concentration of the non-polymer catechins is within the above range, those which have been purified may also be used. As a purification method, there is a method in which a precipitate or a purified product of 'anthraquinone tea extract' is suspended in water or a mixture of water and an organic solvent such as ethanol, and the precipitate formed is removed and then distilled. To dissolve the back J, it is also possible to use a method in which the extract extracted from the tea leaves by a water-soluble organic solvent such as hot water or ethanol is concentrated and re-purified or the extract is directly purified. 17 The ratio of gallic acid vinegar in the non-polymer catechins used in the present invention is lowered by subjecting the concentrate or purified product of the 4 tea extract to citrate treatment. In the case of the acetonitrile treatment, it is preferred to add the shoe vinegar enzyme in such a manner that the non-polymer catechins of the eucalyptus extract are in the range of 〜5 to 1% by mass. The temperature of the acid-reducing enzyme treatment is preferably 15~4 of the enzyme activity (rc' is better (9)~ thief. The acid is treated by the enzyme, preferably the enzyme is available. 4~6 of activity, more preferably 4.5~6, especially 5~6. In this month, the hair of the month is loaded with non-life drink, (F) cockroach (A) non-polymer catechin The mass ratio of the class [[F) caffeine / (A) non-polymer catechin Τ ' is better G.GGQ1 ~ G], better 〇. _ ~ 0.09, better 疋 0.01 ~ G.G8, especially G G4~G Q7. If the ratio of caffeine to non-poly-catechin catechins is less than G. coffee 1, then it is not good in terms of flavor balance. The ratio of caffeine to non-polymer catechins 117620.doc 200826848 exceeds 〇·ι, which will impair the original appearance of the beverage. It is not harmful. Caffeine can be used as a raw material for green tea extracts and spices. , juice and other caffeine in the presence of Zhongtian Ba, 丨, can also be added to the newly added caffeine. In this t-barley non-tea beverage, the flavor and storage stability ^ (C) pH value The range of 2.5~5·1. The range of (c)p;H value is preferably from 3_0 to 4·5, particularly preferably from 3.8 to 4.2. That is, if the pH is less than 2.5, the acidity becomes strong, and in long-term storage, Reacts with the carbohydrates used in combination to reduce the non-polymer catechins. Further, if the pH exceeds 51, it will react with the carbonaceous a-forms used in combination for long-term storage. The non-polymer catechins can be reduced. The pH can be adjusted by using ascorbic acid or a salt thereof or citric acid. In the container-packed non-tea beverage, (D) contains self-fructose, glucose, sugar, glucose and fructose solution. One or more selected from the sugar and fructose glucose liquid sugars. The content of the sweeteners in the container-packed non-tea beverage of the present invention is preferably from 0.0001 to 20% by mass, more preferably 〇〇〇. 1 to 15% by mass is particularly preferably 0 01 to 10% by mass. Further, the sweeteners also include the sweetener in the tea extract. In the container-packed non-tea beverage of the present invention, if the sweetener is too small, Almost no sweetness, so you can't get a balance with sour and salty taste, so sweet in sugar When it is 1, the sweetness is 2 or more, and it is preferable that it is 2 to 7 (Reference: JISZ8144, Functional Evaluation Analysis - Terminology, No. 3〇11, Sweetness, JISZ9080 'Functional Evaluation Analysis_Method, Test Method ; beverage term dictionary 4-2 sweetness classification, information n (Beverage 邛 (10) company); characteristic grade test mAG test, IS0 6564_1985 (E), "Sens〇ry 117620.doc 200826848

Meth〇d〇l〇gy_FlavourProfilemeth〇dn, etc.). On the other hand, if the sweetness is 8 or more, the throat is strong due to being too sweet, and the throat is lowered.

The glucose content in the container-packed non-tea beverage of the present invention is preferably 0.0001 to 20 mass. /. More preferably, 〇 〇〇 1 to 15% by mass, particularly preferably 0_01 to 10% by mass. The fructose content in the container-packed non-tea beverage of the present invention is preferably 0.0001 to 20% by mass, more preferably 1 to 15% by mass, particularly preferably 0.01 to 10% by mass. The mixed liquid sugar of the fructose glucose liquid sugar, the glucose fructose liquid sugar system, etc., the content thereof is preferably 7% by mass: more preferably G.1 to 6% by mass, particularly preferably 1 () to 5 ft. %. When the total amount is 20% by mass or more, coloring due to browning occurs during storage of the beverage. As a form of sucrose, there are granulated sugar, liquid sugar, cotton white sugar, etc., and any of: The sucrose content in the container-packed non-tea beverage of the present invention is preferably 0.001 to 20% by mass, more preferably 1 to 15% by mass, particularly preferably 〇 1 to 10% by mass. In the non-tea-based beverages of the present invention, in addition to the above-mentioned sweeteners, glycerols, multi-drugs, sugar alcohols, artificial sweeteners, and the like can be used. Compound car: Another example is maltodextrin. The glycerol type can be used, for example, in the present invention: 〜1 to 15% by mass, preferably 〇.2 〜1 〇, in the non-conservative beverage of the present invention. Use sugar alcohol, can be listed with · · 廿 Τ Τ 作为 作为 作为 作为 ' ' 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛 牛Sugar, mannitol, etc. Among these, it is 疋..., calories (calories) of erythritol. The content of these sugar alcohols is preferably 0.0001 to 20% by mass as compared with 117620.doc -12 to 200826848. The amount of the carbohydrate used in the container-packed non-tea beverage of the present invention is preferably 0001·0001 to 2% by mass based on the total mass. The total amount of carbohydrates 'includes a charcoal hydrate derived from fruit juice or tea extract. In the sweetener used in the container-packed non-tea beverage of the present invention, examples of the artificial sweetener include aspartame, sucralose, saccharin, cyclohexylamine (CyClamate), and vinegar. Potassium lactone (Acesulfame_ K), L-aspartate-methacrylic acid phenylalanine lower alkyl ester, aspartame-D-alanine guanamine, l-aspartame thiol amide Amino, L-aspartame-hydroxymethyl alkanoguanamine, L•aspartame-indenyl-hydroxyethyl decylamine, sucralose and other high-sweet sweeteners, glycyrrhizin, synthesis An alkoxy aromatic compound or the like. The content of the artificial sweeteners is preferably from 0.0001 to 20% by mass. You can also use thaumatin, stevi〇side and other natural sweeteners. In the container-packed non-tea beverage of the present invention, a sour material can be used. The sour material in the present invention is preferably selected from the group consisting of ascorbic acid, citric acid, gluconic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, phosphoric acid, malic acid, adipic acid and the like; More than one species. Further, in order to obtain a moderate acidity, it is preferred to combine the above (4) with a salt thereof. Specific examples thereof include: trisodium citrate, monopotassium citrate, trisuccinate, glucosamine, sodium gluconate, sodium tartrate, trisodium tartrate, potassium hydrogen tartrate, sodium lactate, potassium lactate, Rich (tetra) sodium and so on. As other sour materials, 117620.doc -13· 200826848 can be used to extract juices from natural ingredients. The content of the whole soaking sour material in the container-packed non-tea beverage of the present invention is preferably G.G1 to U% by mass, particularly preferably G.G2 to 0.6% by mass. When the concentration of the sour material is less than 质量1% by mass, the pain can be suppressed, but the acidity is too weak. On the other hand, when the concentration of the sour material exceeds 0.7% by mass, the sour taste becomes strong, but the bitterness or the degree of twist also becomes strong. Inorganic acids and inorganic acid salts can also be used. Examples of the inorganic acid or the inorganic acid salt include ammonium hydrogen hydride, ammonium dihydrogen phosphate, chlorine chloride: unloading, linal acid SI: sodium, sodium dihydrogen phosphate, tri-nanoic acid tris-phosphate, and phosphoric acid tri-loading. The inorganic acid or inorganic acid salt such as β hai is preferably 疋G.G1 to G.5 mass% in a container-packed non-tea beverage, and particularly preferably G G2 〇 3 mass%. In order to improve the preference, a flavor or fruit juiee may be added to the container-packed non-tea beverage of the present invention. Natural or synthetic flavors or juices can be used. Δ海, etc., can be selected from a mixture of fruit juice, fruit flavor (fruit), C-i flavor, or the like. Particularly preferred are juices and tea flavors, especially in combination with green tea or black tea flavors. Juice, preferably #果, pear, lemon, lime, citrus, grapefruit, cranberry, orange, strawberry, grape, kiwi, pineapple, passion fruit, mango, porridge, tree! Cherry juice. It is best to use sweet orange juice, preferably grapefruit, orange, diced, fee, mandarin and mango, passion fruit and fruit juice, or a mixture thereof. Better natural spices, such as jasmine, western yam =, sage, mint, hawthorn, chrysanthemum, Xue Qi, Gan Yan, Zhang Zhi, bamboo 荀 4. The content of the juice in the beverage of the present invention is preferably 0. Xie~20 weight 117620.doc -14- 200826848 % 'better 0.002~10% by weight. Particularly good spices are sweet orange flavors containing spices, lemon flavors, lime flavors and grape sleeves. In combination with the above-mentioned orange flavors, various other fruit flavors such as fructose, grape flavor, tree per flavor, cranberry flavor, cherry flavor, pineapple flavor, and the like can be used. Spices such as Hai can be extracted from the natural sources of juices and sesame oils, or also in the S 7 material, which contains a mixture of various spices, such as lemon and sour grapefruit spices, citrus and selected spices ( Typical is cola soft drink flav〇r). The fragrance as described above may be added in an amount of 0.0001 to 5% by weight in the beverage of the present invention, and the amount of the car is preferably from 1 to 3% by weight. The container-packed non-tea beverage of the present invention may further contain vitamins. Preferably, vitamin A, vitamin B and vitamins are added. Also, other vitamins such as vitamin D may be added. As vitamin B, examples include: inositol, thiamine (vitamin B1) hydrochloride, thiamine nitrate, riboflavin (vitamin B2), riboflavin 5, sodium phosphate, nicotinic acid ( Vitamin pp), nicotinamide, calcium pantothenate, pyridoxine (vitamin B6) hydrochloride, and vitamin B group selected from cyanocobalamin (vitamin B12), may also use folic acid in the beverage of the present invention, Biotin. The content of the vitamins is preferably at least 1% by mass or more per one of the beverages required in the beverage (US RDI standard: us 2〇〇5/〇〇〇3〇68, US Reference DailyIntake) . The container-packed non-tea beverage of the present invention may further contain minerals. The better minerals are calcium, chromium, copper, strontium, iodine, iron, magnesium, manganese, phosphorus, selenium, tellurium, molybdenum and zinc. Particularly good minerals are magnesium, phosphorus and iron. In the container-packed non-tea beverage of the present invention, cyclodextrin can be used in combination to suppress the bitter taste of non-polymer catechins. For cyclodextrin, exemplified by & cyclodextrin 117620.doc -15- 200826848 refined, β-cyclodextrin, γ-cyclodextrin. The cyclodextrin is preferably added in an amount of 0.005 to 0.5 mass in the green tea beverage of the container of the present invention. /◦, more preferably 0.02~0.3% by mass, especially preferably 〇·05~0.25 mass 0/〇. Each of the non-tea-based beverages of the present invention may contain 〇〇〇1 to 〇5 mass% sodium and 0.001 to 0.2 mass% potassium. Here, when the sodium and potassium concentrations are less than 0.001% by mass, there is a tendency that the taste is insufficient depending on the place of drinking. On the other hand, if it exceeds 0.5% by mass, there is a tendency that the salt itself has a strong taste and is disadvantageous for long-term drinking. As the sodium, in addition to the sodium citrate used in the present invention, a mixture such as sodium carbonate, sodium carbonate, sodium hydrogencarbonate, sodium phosphate, sodium hydrogen phosphate, sodium tartrate, sodium benzoate or the like can be easily obtained. The sodium salt also contains ingredients derived from the juice or tea added. The higher the sodium concentration, the higher the discoloration of the beverage. Further, the sodium content in the container-packed non-tea beverage of the present invention is preferably from 0.001 to 0.5% by mass, more preferably from 0. 002 to 0. 4, from the viewpoint of physiological effects and stability. The mass% is more preferably 0.003 to 0.2% by mass. As potassium, in addition to potassium citrate used in the present invention, for example, potassium hydride, potassium carbonate, potassium sulfate, potassium acetate, potassium hydrogencarbonate, potassium phosphate, potassium hydrogen phosphate, potassium tartrate, potassium ascorbate or the like may be added or The potassium salt of such a mixture also includes those derived from the ingredients of the juice or tea added. Compared with the sodium agronosity, the potassium concentration has a greater influence on the color tone of the sputum temperature during long-term storage. From the viewpoint of stability, the potassium content in the container-packed non-tea beverage of the present invention is preferably 0.001 to 0.2% by mass, more preferably 〇〇〇2 to 〇15% by mass, more preferably It is 0.003 to 0.12% by mass. 117620.doc -16 - 200826848 In addition to sodium and potassium, it may preferably contain 0.001 to 0.5% by mass, more preferably 〇J疋υ·〇〇2~〇, in the private sputum drink of the present invention. _4% by mass, particularly 妤 is 0.003 to 0.3% by mass of chloride ions. The negative milk ion component can be added as a salt of sodium chloride or potassium chloride. For example, if chlorine (tetra) is added, the amount of sodium and the amount of chloride ion may be included in the total amount of each ion corresponding thereto. In the non-tea-based beverage of the container of the present invention, the combination of the ingredients derived from the tea may be used alone or in combination with the addition of an anti-oxidant emulsifier, various esters, organic acids,

Organic acid salts, inorganic salts, chromophore _ y M Ba I 颏, ritualizing agents, preservatives, seasonings, vegetable extracts, nectar 茬 茬 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽 虽Additives such as agents. Examples of the non-tea-based beverages and beverages in the container of the present invention include carbonated beverages, non-carbonated beverages, enriched water, rice-filled water, sports drinks, beverages, water-like beverages, and the like. Pressed beverages, low osmotic pressure beverages, high-permeability beverages, functional (four) and other forms. Yamaguchi's gluten-free non-tea-based carbonated beverage 'can suppress the bitterness of non-polymer catechins by having moderate foaming due to oxidizing gas, and can continue to impart a soft feeling to the beverage. And a cool feeling. The calories (calories) of the non-life-selling beverages in this month's milk are calculated by the glucose, fructose, and sucrose contained in iW = _, erythritol, 1 g, 0 Keal. Here, the container of the present invention is a non-tea drink = 'better than 4 calories/calories of calories (4 calories), more preferably 2 to 35 kcal/240 ml or less 'especially good 3~ 3〇kcal/24〇ml or less. The container of the invention, the container which can be used in the non-tea beverage, can be provided in the following general form: the polyethylene terephthalate is mainly composed of 117620.doc -17-200826848 shaped container (so-called PET bottle), life into η, made of paper containers, bottles, etc., or plastic film composite 4t. Here, the so-called container-packed non-tea beverages will be drinkable without dilution. In addition, the container of the present invention is not a touch, and the beverage is used, for example, after being filled into a bar of a metal can, and when it can be heat-sterilized, the regulations can be used. The sputum is the food hygiene law): applicable system, raw orphan, and the order of ~ 囷 囷 。. For the acid bottle, paper container can not be steamed (4) Use: pre-supplement with the same sterilization conditions as above For example, a flat-plate rail exchanger or the like is used for high-temperature short-time sterilization, followed by cooling to a certain container, etc. Further, other components may be added to the filling container under the Γ" It can be heat-sterilized under acidic conditions, and then the pH is restored to neutral under aseptic conditions; or heat sterilization under neutral conditions, followed by operation to restore the positive value to acidity under aseptic conditions. [Examples] The non-polymer catechins and the caffeine were measured by a membrane filtration li (G.8 _ 进行 遽 遽 遽 遽 遽 遽 遽 遽 遽 遽 遽 遽 performance performance performance performance performance performance performance performance performance performance performance performance performance performance performance performance performance performance performance performance performance performance Mat〇graph) (type SCL l〇Avp), installation of octadecyl-introduced liquid chromatography with packed column L_column TM 〇DS (4.6mn^x250 mm: manufactured by the Chemicals Evaluation Research Institute) The measurement is carried out according to the gradient method at a column temperature of 35 ° C. The measurement is carried out in the mobile phase A liquid is a distilled aqueous solution containing 0·1 m〇l / L acetic acid, and the b liquid is containing 0.1 mol / L acetic acid. The acetonitrile solution, the injection volume is 2〇μ1, and the uv detector wavelength is 280 nm (usually the concentration of catechins and caffeine 117620.doc -18 - 200826848 is in mass/vol% (%[ w/v]) indicates that the content in the examples is expressed by mass by multiplying the concentration by the amount of liquid.) Evaluation of flavor The drinking test was conducted by five functional inspectors. The method of measuring sweetness was 1 to 10% of sugar. The aqueous solution was adjusted to a level of 5%, and the sweetness was set to 1.0 to 10.0, and the sensory evaluation was performed at room temperature, and the sweetness was expressed at intervals of 01 (the classification of the beverage term 4-2 sweetness). , Information 11). Preservation test The prepared beverage was stored at 5 rc for 2 weeks and was observed by 5 functional inspectors. Before and after the change of the color of the beverage, the grade was determined according to the following criteria. The content of the non-polymer catechins was determined. A · No change, B: slight change, c: change, d: large change Example 1 Dissolve 100 g of the commercially available green tea extract purified product (Mitsui Nonglin (share) "P〇LYPHEN〇NE HG") in _g of 90.0% by mass of ethanol, and mature into 3 〇m paper and hole_ filter paper After filtration, 200 ml of water was added and concentrated under reduced pressure, whereby a purified product was obtained. The ratio of the non-polymer catechins in the obtained purified product was 15 2% by mass. The ratio of the non-polymer catechin gallate was 581% by mass to 75.0 g. The tea-based composition was put into a non-recorded steel container - 'The total amount was set to 1 〇〇〇 with ion-exchanged water, and a 5 4 4% 4% aqueous solution of hydrogencarbonate was added to adjust the pH to 5.5. Then, under the stirring condition of 117620.doc -19- 200826848 22 ° C, 150 r / min, added in 1 〇 7 g ion exchange water dissolved in 0. 27 g (compared to non-polymer catechins is 2.4 %) Kikkoman Tannase KTFH (industrial grade, 500 U/g or more)

After the 55 minutes, the enzyme reaction was terminated at a time when the pH was lowered to 4.24. Then, the stainless steel container was immersed in 95. In a warm water bath, keep ίο minutes at 9 (rc) to completely lose the enzyme activity, then cool to 25 and then concentrate. After the phthalate esterase treatment, the non-polymeric green tea extract is purified. The ratio of the caffeines was 15% by mass, and the ratio of the non-polymer catechins was 45.1% by mass. 8.5 g of the purified product, 1 g of citric anhydride, and 1.2 g of trisodium citrate were dissolved in Next, the anhydrous crystalline fructose 36.6 g, erythritol, ascorbic acid, and lemon lime flavor were added, and the total amount was set to 1,000 g. After the addition, UHT sterilization was carried out and filled in a crucible bottle. The non-polymer catechin content of the sports drink is 0128% by mass, the non-epis ratio is 15.0% by mass, and the non-polymer gallate body rate is 5.2% by mass, caffeine/non-polymer The ratio of the caffeines was 0.052. The results of composition and flavor evaluation are shown in Tables 1 and 2. Examples 2 to 12 In the same manner as in Example ,, a container-packed non-tea beverage was prepared. Composition, flavor evaluation and preservation. The results of the test are shown in Tables 1 and 2. Comparative Example 1 In addition to Example 1 A container-packed non-tea beverage was prepared in the same manner as in Example ^ except that the citric acid was changed to 丨.0 g, trisodium citrate was changed to 15.0 g, and the pH was set to 6 Torr. The evaluation and the results of the test are shown in Tables 1 and 2. /, 4 411720.doc 20- 200826848 1:3⁄4 Comparative Example 1 0.85 3.66 1 1 1 0.75 1 r—^ 0.05 f remaining amount 1 〇Example 12 0.85 1 1 1 1 1 0.001 1 0.05 The remaining amount 〇 Example 11 0.85 1 1 1 3.66 1 1 0.38 0.05 The remaining amount ο Example 10 0.85 1 1 1 3.66 1 1 0.12 0.05 rH The remaining amount ο Example 9 0.85 1 1 4.88 1 1 1 0.12 0.05 rH remaining amount 实施 Example 8 0.85 1 3.66 1 1 1 1 fH 0.12 0.05 remaining amount ο Example 7 0.85 1 3.66 1 1 1 1 0.38 0.05 rH remaining amount ο Example 6 0.85 1 3.66 1 1 0.75喔rH 0.12 0.05 Γ remaining amount 实施 Example 5 0.85 3.66 1 1 1 0.75 1 l - Η 0.36 0.05 The remaining amount ο Example 4 0.85 3.66 1 1 1 1 1 0.12 0.05 The remaining amount 1 ο Example 3 0.85 3.66 1 1 1 0.75 1 1 丨0.05 The remaining amount ο Example 2 0.85 3.66 1 1 1 0.75 1 0.39 0.05 The remaining amount ο ν-Η Example 1 0.85 3.66 1 I .1 0.75 1 0.12 0.05 The remaining amount ο η - 骤 掩 ^ ^ & ^ ¥ $ ♦ swallow (D) fructose (% by mass) (D) glucose (quality %) (D) fructose glucose liquid sugar (% by mass) (9) granulated sugar (% by mass) (D) erythritol (% by mass) (D) thaumatin (% by mass) citric acid (% by mass) trisodium citrate (% by mass) Ascorbic acid (% by mass) Citric acid orange flavor (% by mass) Deionized water (% by mass) Total amount 117620.doc -21 - 200826848

^<] Comparative Example 1 〇〇0.127 τ-Η jo 0.052 inch rH o vd Q 0.011 ^r> m Example 12 〇cn 0.127 〇uS r-^ rH jn 0.052 (N ro < N r^i CQ r 0.096 ο Example...11.——...1 t> cn 0.127 Ο (N 1—H jrl 1 0.052 τ-Η o wS PQ 0.123 cn Example 10 ΓΟ 0.127 〇ui jri 0.052 (N r—H inch · ffl 丨! 0.127 i_ Example: 1 ο cn 0.127 o ώ jr> 0.052 (N s inch · PQ 0.125 CO Example 8 (N 0.127 o ui rH jn 0.052 ri < N s PQ 0.127 Example 7 〇cn 0.127 a\ jn 0.052 CN (N r*H o vS PQ 1 0.120 cn Example 6 o cn 0.127 o JO jr> 0.052 (N CN inch·0Q 1 0.124 m Example 5 00 0.127 oo JT> 0.052 in PQ I 0.098 jm Example 4 00 - 0.127 o jn TH JO 0.052 i - ^ S inch · PQ 1 0.119 m Example 3 m 0.127 o - r - H 1 - ^ jr > 0.052 (N CO CQ 0.114 Example 2 cn wS 0.127 OO JO 0.052 iH s uS ω 1- 0.095 m Example 1 cn IO 0.127 o uS JO 0.052 inch PQ I- 0.121 m (8) Non-polymer catechins (% by mass) (B) Non-epitopic ratio (% by mass) ( E) ratio of gallate body (% by mass) (F) caffeine / (A) (-) sourness, sweetness 2) (C) after storage of pH (55 ° C, 2 weeks) ) Non-polymer catechins (% by mass) after storage (55 ° C, 2 weeks) Calories (Kcal/240ml) JJ$4<锑杷:α:3- and 翱杷薬v : ^哞雄ε ::^71rw^Benzene 铢嗲韶 鹌 fe ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ :二蟀^ The spider $^-^benzene, ^8 s^.. ^, ,^ϊιφ - ^ ^ ^ -22- 117620.doc 200826848 It can be understood from Table 1 and Table 2 that the container of the present invention is not The tea-based beverage, in the case of not impairing the flavor, takes into consideration the reduction of the astringency and the moderate sweetness and sourness, and is suitable for long-term preservation even though it contains a sweetener.

117620.doc -23·

Claims (1)

200826848 X. Patent application scope: l A variety of gluten-based non-tea beverages, which are purified by adding green tea extract and containing 〜·〇1~1.0% by mass of (eight) non-polymer catechins, ( Β) Non-polymer catechins have a non-epis ratio of 5 to 25% by mass, (C) a pH of 2.5 to 5.1, "containing 〇·000!~2〇% by mass (0) from fructose, glucose The sugar, the fructose fructose liquid sugar and the fructose glucose liquid sugar are selected from the above-mentioned species. The long-term item 1 of the barn I non-steroidal beverage, which contains ~ mass two (D) self-fructose, glucose, sucrose, glucose The fructose liquid sugar and the fructose glucose liquid sugar are selected from the above. 3. The non-polymer catechin gallate body ratio of the non-polymer catechin gallate is 5~5 according to the item 1 or 2 of the invention. 〇质量〇/0. 4. The non-tea beverage according to any one of claims 1 to 3, wherein (?) caffeine and (Α) non-polymer catechins have a mass ratio [(F / (A)] is 0.0001 to 0.1 〇 5. The container-packed non-tea beverage according to any one of claims 1 to 4, which further contains The container-packed non-tea-based beverage according to any one of claims 1 to 5, further comprising a manual sweetener, wherein the container is a non-tea beverage according to any one of claims 1 to 6, wherein More than one selected from the group consisting of ascorbic acid, citric acid, gluconic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, linic acid, anaphoric acid, and the like. 117620.doc 200826848 8, as requested The container-packed non-tea beverage according to any one of 1 to 7, wherein each of the squid drinks further contains 10% by mass or more of the inositol, thiamine hydrochloride, thiamine nitrate , riboflavin, riboflavin 5, sodium phosphatidate, final acid, valeramine, pantothenic acid, 0 sterol hydrochloride and cyanosine selected vitamin 3 group, folic acid and biotin 9. The container of the non-tea-based beverage according to any one of claims 1 to 8, which is a carbonated beverage. The container-packed non-tea beverage according to any one of claims 1 to 8. , which is an enhanced water. 11. A non-tea beverage in a container according to any one of claims 1 to 8. The present invention is a non-tea based beverage according to any one of claims 1 to 8, wherein the container is a non-tea beverage. A non-tea-based beverage, which is a non-tea based beverage according to any one of claims 1 to 8, which is a non-tea beverage according to any one of claims 1 to 8. A near-water beverage. The container-packed non-tea beverage according to any one of claims 1 to 8 is an osmotic pressure beverage. 17. The container-packed non-tea beverage according to any one of claims 1 to 8, which is a hypotonic osmotic beverage. 117620.doc -2- 200826848 1 8 The container-packed non-tea beverage according to any one of claims 1 to 8, which is a hypertonic permeable beverage. 19. The container-packed non-tea beverage according to any one of claims 1 to 18, wherein the calorie does not reach 40 Kcal/240 m 117620.doc 200826848 VII. Designated representative map: (1) The representative representative of the case is: ( (2) A brief description of the symbol of the representative figure: 8. If there is a chemical formula in this case, please reveal the chemical formula that best shows the characteristics of the invention: (none) 117620.doc