TW200822287A - Method of fabricating semiconductor device having fine contact holes - Google Patents

Method of fabricating semiconductor device having fine contact holes Download PDF

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Publication number
TW200822287A
TW200822287A TW096139460A TW96139460A TW200822287A TW 200822287 A TW200822287 A TW 200822287A TW 096139460 A TW096139460 A TW 096139460A TW 96139460 A TW96139460 A TW 96139460A TW 200822287 A TW200822287 A TW 200822287A
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TW
Taiwan
Prior art keywords
layer
pattern
molding
forming
hard mask
Prior art date
Application number
TW096139460A
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Chinese (zh)
Inventor
Sung-Hyun Kwon
Jae-Hwang Sim
Dong-Hwa Kwak
Joo-Young Kim
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Samsung Electronics Co Ltd
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Publication date
Application filed by Samsung Electronics Co Ltd filed Critical Samsung Electronics Co Ltd
Publication of TW200822287A publication Critical patent/TW200822287A/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76802Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
    • H01L21/76816Aspects relating to the layout of the pattern or to the size of vias or trenches
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/027Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
    • H01L21/033Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
    • H01L21/0334Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
    • H01L21/0337Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31144Etching the insulating layers by chemical or physical means using masks
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76877Filling of holes, grooves or trenches, e.g. vias, with conductive material
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B41/00Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
    • H10B41/30Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
    • H10B41/35Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region with a cell select transistor, e.g. NAND

Abstract

A method for fabricating a semiconductor device having fine contact holes is exemplarily disclosed. The method includes forming an isolation layer defining active regions on a semiconductor substrate. An interlayer dielectric layer is formed on the semiconductor substrate having the isolation layer. First molding patterns are formed on the interlayer dielectric layer. Second molding patterns positioned between the first molding patterns and spaced apart therefrom are also formed. A mask pattern surrounding sidewalls of the first and second molding patterns is formed. Openings are formed by removing the first and second molding patterns. Contact holes are formed by etching the interlayer dielectric layer using the mask pattern as an etching mask.

Description

200822287 26022pif.doc 九、發明說明: 【發明所屬之技術領域】 制止本發明有關於製造半導體裝置的方法,特別是有關於 製造以模造圖案形成的罩幕圖案來形成細微接觸窗開口 (fine contact hole)的半導體裝置的方法。 【先前技術】 Ο 4j 半導體裝置包括分離裝置(discrete device),例如電晶 體、電阻器以及電容器。分離裝置經由形成於貫通絕緣層 的接觸窗開π内的接觸插塞或互連裝置,而彼此電性連 接^列如,NAND独閃記憶體包括與半導體基板内彼此 1P同的主動區域父叉延伸的字線,以及與字線相臨並與主 動區域父叉的選擇線。NAND型快閃記憶體還包括藉由層 間介電層而與字線和選擇線絕緣並與它們交叉的位元線: 位兀線分別經由接觸窗開口而電性連接到選擇線附近的主 動區域。接觸窗開口-般藉由圖案化製程形成。圖案化气 耘包括以黃光製程⑽__FQeess)在賴介上形 開孔的罩幕_,以及_經由開孔而暴露出的^ 間以電層。 曰 因為接觸窗開口的尺寸隨著半導體裝置的積集声 =變小,朗·的尺寸也顧小。“,難^制二 先衣程到所需要之縮小的開孔尺寸。例如,由於半 板上的佈局(topol〇gy)複雜,在黃光製程申, 、肢土 擇線和字線)產生漫反射(diffusereflecii〇n)。因而,歹,如造 各開孔的尺寸—致,仍有相當程度·制存在。因^確保 200822287 26022pif.doc 法確保填充於各接觸窗開口的接觸插塞都具有一致的慨 抗。故,半導體裝置的可靠性下降。 【發明内容】 因而,本申請所描述的實施例是有關於一種使用以模 造圖案所形成的罩幕圖案,來製造具有細微且實質上尺寸 一致均勻之接觸窗開口的半導體裝置的方法。 、 ο200822287 26022pif.doc IX. Description of the Invention: [Technical Field] The present invention relates to a method of fabricating a semiconductor device, and more particularly to manufacturing a mask pattern formed in a patterned pattern to form a fine contact hole (fine contact hole) A method of a semiconductor device. [Prior Art] The semiconductor device includes a discrete device such as an electric crystal, a resistor, and a capacitor. The separating device is electrically connected to each other via a contact plug or interconnecting device formed in the contact opening π of the through insulating layer. For example, the NAND flash memory includes an active area parent fork that is the same as each other in the semiconductor substrate. An extended word line, and a selection line that is adjacent to the word line and is parental to the active area. The NAND type flash memory further includes a bit line insulated from and intersecting with the word line and the selection line by an interlayer dielectric layer: the bit line is electrically connected to the active area near the selection line via the contact window opening, respectively . The contact window opening is generally formed by a patterning process. The patterned gas 耘 includes a mask _, which is formed by a yellow light process (10) __FQeess, and an electrical layer exposed by the opening.曰 Because the size of the contact window opening becomes smaller with the accumulated sound of the semiconductor device, the size of the lang is also small. “It’s difficult to make two first coats to the required opening size. For example, due to the complexity of the layout on the half plate (topol〇gy), the yellow light process, the soil selection and the word line) Diffuse reflection (diffusereflecii〇n). Therefore, 歹, such as the size of each opening, there is still a considerable degree of existence. Because ^ ensure that the 200822287 26022pif.doc method to ensure that the contact plugs filled in the opening of each contact window There is a consistent resistance. Therefore, the reliability of the semiconductor device is degraded. [Invention] Accordingly, the embodiments described in the present application relate to a mask pattern formed by using a pattern to be manufactured with subtle and substantial A method of a semiconductor device having a uniformly uniform contact opening. ο

本發明之一實施例提出一種製造半導體裝置的方法。 例,,方法包括先在半導體基板上形成定義出主動區域的 隔離層。然後,在具有隔離層的半導體基板上形成層間介 電^。接著,在層間介電層上形成第一模造圖案。還可二 在第一模造圖案之間形成與其具有間隔的第二模造圖案。 =成包圍第一和第二模造圖案的侧壁的罩幕圖案。以移除 和乐二模造圖案來形成開孔。以罩幕圖案為钱刻罩 幕’餞刻層間介電層以形成接觸窗開口。 【實施方式】 現在財照附圖在下文中更全面地描述本發明的實施 二實施例能夠以不同形式實現並且不應解釋為 。;本申睛明確闡述的實施例。更確切地,提供這 容透徹並完整,並向本領域熟= 員=者傳達本發明的範圍。在關中,為了清楚起見誇 了::區域的厚度。在整個說明書中相似的標號表示相 =料件(例如層、膜、區域或基板)被稱為 件;時,它可以直接位於其他元件上或者也可 曰几相反,當7°件被稱為直接位於另一元件 6 200822287 26022pif.doc 上時,則不存在中間元件。 圖1是根據一實施例的半導體裝置的平面圖。圖2A、 * 圖3A、圖4A、圖5A、圖6A、圖7A、圖8A、圖9A、圖 機 、圖11A、圖12A、圖13A以及圖14A是沿圖1的線 M’的截面圖,其為根據第一實施例的製造半導體裝置的方 法流程圖。圖2B、圖3B、圖4B、圖5B、圖6B、圖7B、 圖8B、圖9B、圖10B、圖11B、圖12B、圖13B以及圖 Ο 14B是沿圖1的線π-ιγ的截面圖,其為根據第一實施例的 製造半導體裝置的方法流程圖。 參知、圖1、圖2A和圖2B,提供半導體基板1〇〇。半 導體基板100可以是矽基板。半導體基板1〇〇的材質例如 疋SiC、SiGe或GaAs。墊層(pad layer)103形成於半導體 基板100上。墊層103包括熱氧化層 以及氮化石夕層(silicon nitride layer)中的至少一種。下硬罩 幕層(lowerhardmasklayer)l〇6形成於墊層103上。下硬罩 〇 幕層106包括氧j匕破(Silicon oxide)。在一實施例中,下硬 f幕層106包括氧化矽層。在一實施例中,不形成下/硬罩 幕層106(即,省略下硬罩幕層1〇6的形成)。 • 一參照圖1、圖3A以及圖3B,彼此間隔的第一上 幕圖案109形成於下硬罩幕層1〇6上。各第_上硬罩 、案109包括不同於下硬罩幕層1〇6的材質。例如,杳ς 罩幕層106包括氧化石夕時,第一上硬罩幕圖案多 晶矽(P〇ly_silion)或氮化矽(silicon nitride)。各第一上砸 | = 圖案卿成為線形。在一實施例中,藉由 200822287 26022pif.doc 弟-上硬罩幕11案Κ)9周1]的下硬罩幕層湯,以形成凹 陷區域10 7。 形成覆蓋於第-上硬罩幕圖案刚以及下硬罩幕層 106的凹陷區域的保角犧牲層(conformal sacrificial layer)112。因而,位於第一上硬罩幕圖案ι〇9之間的部份 犧牲層112可以定義為溝槽(gr〇ve)112a。藉由調整犧牲層 112的厚度,溝槽112a形成具有實質上與第-上硬罩幕圖 木109相同的n溝槽的底面可以 盘 第-上硬罩幕圖案⑽的底面為共平面。―貝。 2層m可以包括相對於[上硬罩幕圖案⑽的 才貝具 =刻選擇性的材質。例如,當第一上硬罩幕圖案 109匕括夕晶矽時,犧牲層112包括氧化矽。 $犧牲層112和下硬罩幕層106包括實質上相同 ^材貝。例如’犧牲層112和下硬罩 括氧化矽。 貝貝工刮匕 Ο 幕層1Q6時,犧牲層112形成為覆蓋 於弟一上硬罩幕圖案109的侧壁。 / 靜2圖1、圖4A和圖4B,在由犧牲層112所定義的 罩厚度實質上一致並且為線形的第二上硬 弟―上硬罩幕圖案115 ^置在第-上硬 罩秦圖案H)9之間且被犧牲層112所包圍。因此,第二上 硬罩綦圖案出的侧壁和底面都有犧牲層ιΐ2包圍。第二 上硬罩幕圖案115包括鱼第一 質。 U上硬罩幂圖案109相同的材 200822287 26022pif.doc 在一實施例中,第二上硬罩幕圖案115設置在盥第一 上硬罩幕圖案1〇9實質上相同的層 112的轉縣板上形缸硬轉材質層,並平1匕 上硬罩幕^貝yf,直至上硬罩幕材質層的頂面實質上與第 上:更罩幕@案109的頂面為共平面為止,以形成第二上One embodiment of the present invention provides a method of fabricating a semiconductor device. For example, the method includes first forming an isolation layer defining an active region on a semiconductor substrate. Then, an interlayer dielectric is formed on the semiconductor substrate having the isolation layer. Next, a first molding pattern is formed on the interlayer dielectric layer. Further, a second pattern having a space therebetween may be formed between the first pattern patterns. = a mask pattern enclosing the side walls of the first and second molding patterns. The openings are formed by removing and patterning. The mask is patterned to engrave the interlayer dielectric layer to form a contact opening. [Embodiment] The present invention will now be described more fully hereinafter with reference to the appended claims. The embodiment explicitly stated in the present application. Rather, it is provided to be thorough and complete, and to convey the scope of the invention to those skilled in the art. In Guanzhong, for the sake of clarity, it is exaggerated:: the thickness of the area. Throughout the specification, like reference numerals indicate that a material (such as a layer, a film, a region, or a substrate) is referred to as a member; when it is referred to as being directly on the other component, or vice versa, when the 7° member is referred to as When located directly on another component 6 200822287 26022pif.doc, there are no intermediate components. 1 is a plan view of a semiconductor device in accordance with an embodiment. 2A, 3A, 4A, 5A, 6A, 7A, 8A, 9A, 11A, 12A, 13A, and 14A are cross-sectional views taken along line M' of Fig. 1. It is a flowchart of a method of manufacturing a semiconductor device according to the first embodiment. 2B, 3B, 4B, 5B, 6B, 7B, 8B, 9B, 10B, 11B, 12B, 13B, and 14B are cross sections along the line π-ιγ of Fig. 1. Figure is a flow chart of a method of fabricating a semiconductor device in accordance with a first embodiment. Referring to Figures 1, 2A and 2B, a semiconductor substrate 1 is provided. The semiconductor substrate 100 may be a germanium substrate. The material of the semiconductor substrate 1 is, for example, SiC, SiGe or GaAs. A pad layer 103 is formed on the semiconductor substrate 100. The pad layer 103 includes at least one of a thermal oxide layer and a silicon nitride layer. A lower hard mask layer l6 is formed on the underlayer 103. The lower hard mask 〇 curtain layer 106 includes a silicon oxide. In one embodiment, the lower hard f curtain layer 106 comprises a hafnium oxide layer. In one embodiment, the lower/hard mask layer 106 is not formed (i.e., the formation of the lower hard mask layer 1 〇 6 is omitted). • Referring to Figures 1, 3A and 3B, first curtain patterns 109 spaced apart from one another are formed on the lower hard mask layer 1〇6. Each of the upper hard cover and the case 109 includes a material different from the lower hard mask layer 1〇6. For example, the ruthenium mask layer 106 includes oxidized stone, and the first upper hard mask pattern is polycrystalline silicon (P〇ly_silion) or silicon nitride. Each first captain | = The pattern is linear. In one embodiment, the lower hard mask layer soup of 9 weeks 1] is formed by the 200822287 26022 pif.doc-upper hard mask 11 case to form the recessed region 107. A conformal sacrificial layer 112 is formed overlying the recessed regions of the first-upper hard mask pattern and the lower hard mask layer 106. Thus, a portion of the sacrificial layer 112 located between the first upper hard mask patterns ι 9 can be defined as a trench 112a. By adjusting the thickness of the sacrificial layer 112, the trench 112a forms a bottom surface having substantially the same n-groove as the upper-top hard mask 109. The bottom surface of the disk-upper mask pattern (10) may be coplanar. -shell. The 2 layers m may include a material that is selective with respect to [the upper hard mask pattern (10). For example, when the first upper hard mask pattern 109 is etched, the sacrificial layer 112 includes yttrium oxide. The sacrificial layer 112 and the lower hard mask layer 106 comprise substantially the same material. For example, the sacrificial layer 112 and the lower hard cover include yttrium oxide. The sacrificial layer 112 is formed to cover the sidewall of the upper hard mask pattern 109 when the beaker is scraped 1 1Q6. / static 2 Figure 1, Figure 4A and Figure 4B, in the thickness of the cover defined by the sacrificial layer 112 is substantially uniform and linear, the second upper hard brother - upper hard mask pattern 115 ^ placed on the first - upper hard cover Qin Between the patterns H) 9 and surrounded by the sacrificial layer 112. Therefore, the side walls and the bottom surface of the second upper hard cover are surrounded by a sacrificial layer ι 2 . The second upper hard mask pattern 115 includes the first quality of the fish. U hard mask power pattern 109 the same material 200822287 26022pif.doc In one embodiment, the second upper hard mask pattern 115 is disposed in the first layer 112 of the first upper hard mask pattern 1〇9 The plate-shaped cylinder is hard-turned to the material layer, and the upper surface of the hard mask is flattened until the top surface of the upper hard mask material layer is substantially coplanar with the top surface of the upper cover: case 109 To form a second

硬罩幕圖f 115。平坦化上硬罩幕材質層的方法例如是回 蝕㈣back)和/或化學機械研磨法刪㈣^ pdishing,CMP)製程。當使用回_程來平坦化上硬罩幕 材質層時,侧上硬罩幕材制,使得第二上硬罩幕圖案 115的頂面實質上與第—上硬罩幕圖案1Q9的頂面為共平 面。當使CMP技術來平坦化上硬罩幕材制時坦 化上硬罩幕材質層,直到暴露出第—上硬罩幕應^ 丁f而。 參照圖卜圖5A和圖5B,蝕刻由第二上硬罩幕層115 所暴露出的部份犧牲層112。在_暴露㈣犧牲層曰ιΐ2 後,芦侧下硬罩幕層106和墊層1〇3。結果,依序堆疊 的第-墊圖案lG3a和第-下硬罩幕圖riQ6a,形成在第 =;硬Ϊ綦圖案1〇9下方。同時’依序堆疊的第二墊圖案 腿、弟二下硬罩幕圖案祕以及齡_⑽,也形 成在第二上硬罩幕圖案115下方。 參照圖1、目6A和圖6B,以第一和第二塾圖案1〇3a 和i03b、第一!0第二下硬罩幕圖案106aw _以及第一 和弟二上硬罩幕圖案1Q9和115為蝴轉, 基板100以形成溝渠117。因而,藉由半導體基板内 200822287 26022pif,doc 足義出主動區域118a 的溝渠 117 ______, ^ ^ " 〜 ^ ^ 布一工々文 罩幕圖案109和115形成為線形,故各主動區域118a定義 為線形,並沿半導體基板1〇〇的縱向方向延伸。 參照圖1、圖7A和圖7B,形成隔離層121以實質上 填充於溝渠117。隔離層121包括絕緣層,例如高密度電 聚氧化物(high density plasma oxide)。 Ο ο 左藉由形成填充於圖6A所示之溝渠117的絕緣層,並 隨後移除依序堆疊的第一和第二墊圖案1〇3&和1〇北、第 一^第二下硬罩幕圖案1〇如和1〇汕以及第一和第二上硬 罩幕圖案109和115,以形成隔離層121 Ό +曰參照圖卜圖U和圖8Β,於各主動區域U8a上形成 电曰曰體。電晶體包括形成於各主動區域118a上Hard mask picture f 115. The method of planarizing the upper hard mask material layer is, for example, etch back (4) back and/or chemical mechanical polishing method (4) ^ pdishing, CMP). When the upper hard mask material layer is planarized using the back process, the hard mask material is made on the side such that the top surface of the second upper hard mask pattern 115 is substantially the top surface of the first upper hard mask pattern 1Q9. For the coplanar. When the CMP technique is used to planarize the upper hard mask material, the hard mask material layer is flattened until the first hard mask is exposed. Referring to FIGS. 5A and 5B, a portion of the sacrificial layer 112 exposed by the second upper hard mask layer 115 is etched. After the (four) sacrificial layer 曰ιΐ2 is exposed, the hard mask layer 106 and the mat layer 1〇3 are lowered. As a result, the sequentially stacked first pad pattern 1G3a and the lower-lower mask pattern riQ6a are formed under the =; hard Ϊ綦 pattern 1 〇 9. At the same time, the second pad pattern legs, the second hard mask pattern and the age _(10) which are sequentially stacked are also formed under the second upper hard mask pattern 115. Referring to FIG. 1, FIG. 6A and FIG. 6B, the first and second 塾 patterns 1〇3a and i03b, the first "0" second lower hard mask pattern 106aw _, and the first and second hard mask patterns 1Q9 and 115 is a butterfly, and the substrate 100 is formed to form a trench 117. Therefore, by the semiconductor substrate 200822287 26022pif, doc is sufficient to form the trenches 117 ______ of the active region 118a, ^ ^ " ~ ^ ^ cloth mask patterns 109 and 115 are formed into a line shape, so the active regions 118a are defined It is linear and extends in the longitudinal direction of the semiconductor substrate 1〇〇. Referring to Figures 1, 7A and 7B, an isolation layer 121 is formed to substantially fill the trenches 117. The isolation layer 121 includes an insulating layer such as a high density plasma oxide. ο ο left by forming an insulating layer filled in the trench 117 shown in FIG. 6A, and then removing the first and second pad patterns 1 〇 3 & and 1 〇 north, first ^ second hard The mask patterns 1 and 1 and the first and second upper hard mask patterns 109 and 115 are formed to form an isolation layer 121 Ό + 曰 with reference to FIG. 5 and FIG. 8A, and electricity is formed on each active region U8a. Carcass. The transistor includes a formation on each active region 118a

’以及在問結構134兩侧而形成於各主 C 的摻雜區域136。例如,細Η 巧㈣内 域。至小一带曰雕7 ㈣隹&域136包括源極與汲極區 ^ 电日日版可以是晶胞電晶體CT,並且至少一帝曰 ^姐可以是選擇電晶體ST。晶胞I曰Μ M 毛日日 :: 擇線串;:線SSL或地選 晶中•晶胞電晶體CT可以是快閃記憶體的 電層。第二介電層i〜124可以是穿遂介 疋阻“ ’丨電層。上述的穿遂介 10 200822287 26022pif.doc 笔層的至少-層例如是氧化石夕、氮氧化石夕(si0N)、氮 s,ilOgen-doped Si oxide)、高介電常數(h㈣)二 似物或者其組合的材質。高介電常數介電材質; 入口疋^ 1德、氧化給、氧化鑭或類似物或者发起 f) ο 5。貝㈣存層】27的至少—層包括氮氧切(s_、、氮 常數介電材質或_物或者其組合的材^ ,二d“層130的至少-層包括氧化石夕(例如,中溫氧化物 (—_ temperature oxide,MT0))、高介電常 或類似物或者其組合的材質。 电材貝 在一實施例中,資料儲存層127包括太半曰 (nan〇^^^ 〇 , ^^ a ^ 'ls(Mo)' ::二質:;實例中,奈米晶結構包括 人,⑺()或類似物的氧化物或者其电 :的材貝。在另—實例中,奈米晶結構包㈣、錯 1化石夕” t硼或類似物或者其組合的材質。 依序二胞電:"體CT的間_包括 接制、閘咖層以及控制閑極。 成声=電晶體ST和CT的半導體基板1⑽上形 139 1間介電層139例如是氧化石夕。於# 曰層139上形絲刻終止層142。飿刻終止層⑷ 142上形成緩衝層145。緩衝 i。例士 Λ對於姓刻終止層142具有_選擇性的材 、〇 @祕止層142為氮化石夕時,'緩衝層145為 200822287 26022pif.doc 氧化石夕等材質。 參照圖1、圖9A和圖9B,於緩衝層145上形成第一 * 模造層。第一模造層包括相對於緩衝層145具有钱刻選擇 , 性的材質。第一模造層例如是多晶矽等材質。接著,圖案 化第一模造層以形成線形的第一模造線148。可以使用微 影(photolithgraphy)和I虫刻製程來圖案化第一模造層。 在一實施例中,各第一模造線148形成為與主動區域 〇 118a内的奇數或偶數的主動區域重疊的形式。因此,第一 模造線148之間的間距P1大於用來圖案化第一模造層的 微影製程所能達到的最小解析度。如上文所述,第一模造 線148形成為線形。因而,第一模造線148具有實質上一 致的寬度。 藉由蝕刻位於第一模造線148之間的部份缓衝層 145,以形成凹陷區域147。於具有第一模造線148的半導 體基板100上形成保角間隔層151。間隔層151覆蓋第一 I) 模造線148的頂面和侧壁,以及定義出凹陷區域147的部 份缓衝層145。因此,間隔層151定義出位於第一模造線 148之間的缓衝層145上的線形溝槽151a。藉由調整間隔 層151的厚度,溝槽151a可以形成為具有與第一模造線 148實質上相同的寬度。溝槽151a的底面與第一模造線148 > 的底面實質上為共平面。在一實施例中,間隔層151包括 與緩衝層145實質上相同的材質。 參照圖1、圖10A以及圖10B,於具有間隔層151的 半導體基板100上形成第二模造層,以填充溝槽151a。第 12 200822287 26022pif.doc 一模造層包括與第一模造層貫質上相同的材質層。接著, 對第一模造層進行圖案化(例如,平坦化)製程,以形成填 • 充於溝槽151a的第二模造線154。因而,第二模造線154 • 的覓度貫質上是一致的且為線形,並且位於第一模造線 148之間的緩衝層145上。苐一模造線154設置在與第一 模造線148實質上相同的層位。例如,第二模造線154的 底面實質上與第一模造線148的底面為共平面。此外,第 二模造線154的寬度與第一模造線i4g的寬度實質上相 同。在一貫施例中,各弟一模造線148與奇數的主動區域 118a重登。因此,各第二模造線154與偶數的主動區域118a 重疊。因而,第一和第二模造線148和154的間距P2小 於第一模造線148之間的間距P1。 使用回蝕或CMP技術來平坦化第二模造層。當使用 回钱製程來平坦化第二模造層時,儀刻第二模造層’使得 第二模造線154的頂面與第一模造線148的頂面實質上為 〇 共平面。在使用cyp技術來平坦化第二模造層時,平坦 化第二模造層,直到暴露出第一模造線148的頂面。 於具有第二模造線154的半導體基板100上,形成交 • 叉於第一和第二模造線148和154上的線形光阻圖案 157。光阻圖案157形成為具有實質上一致的預定寬度。當 使用上述回蚀製程來平坦化第二模造層時,還玎以#刻設 置於第一模造線148上方的部份間隔層151,隨後,形成 光阻圖案157。在一實施例中,光阻圖案157形成為交叉 於部份主動區域118a上,使得選擇電晶體ST的串選擇線 13 200822287 26022pif.doc SSL水平位於光阻圖案157和晶胞電晶體CT的字線WL 之間。光阻圖案157實質上平行於串選擇線SSL。 一參照圖1、圖11A和圖11B,以光阻圖案157為蝕刻 罩幕,蝕刻由光阻圖案157暴露出的部份間隔層151以及 第一和第二模造線148和154,以形成第一和第二模造圖 案148&和154a。例如,使用對第一和第二模造線148二 ο ο 154具有蝕刻選擇性的蝕刻氣體,以乾蝕刻製程來蝕刻間 隔層151。隨後,對苐一和第二模造線148和154進行’ 韻刻。 根據一實施例,由於使用預定寬度的光阻圖案157來 ,案化線形第一和第二模造線148和154,第一和第二模 造圖案148a和15如分別形成為具有實質上一致的寬度, =’ g|為第二模造線W的寬度與第一模造線⑽的寬 二貫質目同’第—模造圖案術的寬度與第二模造圖幸 的寬度實質上相同。 、 ^接著除光阻圖案157(例如,使用灰化剝離職製程 為8。咖》。以第—和第二模造圖案14《和154a 罩秦’ _第一和第二模造圖案148M口 154a之門 ⑽份間隔層151,以形成位 @ ;,r52,同時由此暴露出部份緩= 份;二===第為幕,_的部 丨物。因而,依序堆疊的第一緩;二下二τ衝圖案 口木丨45a和弟一模造圖 14 200822287 26022pif.doc 案148a形成於蝕刻終止層142上。類似的,依序堆燊的第 一緩衝圖案145b、間隔圖案152和第二模造圖案i54a形 • 成於姓刻終止層142上。因而,依序堆疊的第_缓衡圖案 . l45a和第一模造圖案148a被稱為第一開孔模造圖案 155a,而依序堆疊的第二緩衝圖案Μ%、間隔圖案152和 第一模造圖案154a被稱為第二開孔模造圖案i55b。 在間隔層151和緩衝層145包括實質上相同材質的實 Ο 施例中,可以在同一蝕刻製程中,蝕刻間隔層151和緩衝 層 145 〇 以平面圖來看,第一和第二開孔模造圖案15兄和155b 形成為具有長軸(maj or axe)和短軸(minor axe)。第一和第二 開孔模ie圖案155a和155b的長軸沿著與主動區域H8a 的縱向方向實質上相同的方向延伸。 參照圖1、圖12A和圖12B,罩幕層形成於具有第一 和第二開孔模造圖案155a和155b的半導體基板1〇〇上。 〇 罩幕層声括相對於第一和第二模造圖案148a和154a、間 隔圖案152以及第一和第二緩衝圖案145a和145b具有|虫 刻選擇性的材質。例如,罩幕層包括有機材質,例如是光 • 阻抗餘齊彳、抗反射塗層(anti-reflective coating,ARC)、非晶 質碳(amorphous carbon)材質,或類似物或者其組合。 接著,圖案化罩幕層(例如,平面化)以形成罩幕圖案 160。在一實施例中,使用回蝕製程圖案化罩幕層,直到暴 露出第一和第二開孔模造圖案155a和155b的頂面。 之後,移除第一和第二開孔模造圖案155a和155b, 15 200822287 26022pif.doc 以在Ϊ幕圖案⑽中形成第-和第二開孔161Μϋ 16lb。 在貝細例中,藉由餘刻第一和第二模造圖案⑽a和 ,154a,並隨後餘刻間隔圖案152以及第一和第二緩衡圖尹 * l45a和145匕,而移除第一和第二開孔模造圖帛155a和 155b 口而第和第二開孔的間距 實質上平行於串選擇線SSI^的方向。 。耆 r, 參照圖卜® 13A和圖13B,以罩幕圖案160為餘刻 罩秦,侧朗終止層142和層間介電層139來形成暴霖 出與串選擇線SSL相鄰的主動區域U8a的第一和第二接 觸窗開口 163a和i63b。可用乾钱刻製程來侧姓刻終止 層142和層間介電層139。因而,第—和第二接觸窗開口 ^3a和163b形成為具有實f上—致的尺寸。儘管第—和 第=接觸窗開口 163&和祕的深寬比(aspectrati〇)很大, 但第一和第二接觸窗開口 163a和163b形成為具有實質上 一致的尺寸。 、、 J 如上所述,罩幕圖案160包括有機材質。因而,當乾 餘刻層間介電層139以形成第一和第’二接觸窗開口 163a =163b時,第一和第二接觸窗開口 16%和16北的侧壁塗 後有來自罩幕圖案160之有機材質的薄聚合體層。由於第 •和第一接觸窗開口 163a和163b的侧壁塗覆有薄聚合體 層,能防止第一和第二接觸窗開口 163&和163b的寬度增 力口到苐和弟一接觸窗開口 163a和163b能彼此連通的程 度。因而,第一和第二接觸窗開口 163&和163b形成為具 有貫質上豎直的侧壁或正傾斜(positively-inclined)的侧 16 200822287 26022pif.doc 壁。當第一和第二接觸窗開口 163a和163b具有正傾斜侧 壁時,各第一和第二接觸窗開口 163a和163b的寬度由其 上區域向其下區域的方向變小。 Ο 參照圖1、圖14A和圖14B,移除罩幕圖案16〇。之 後,移除蝕刻終止層142。於具有第一和第二接觸窗開口 163a和163b的半導體基板1〇〇上形成接觸導電層。在一 實施例中,接觸導電層包括摻雜多晶矽、金屬或類似物或 者其組合等材質。以CMP或回蝕製程平坦化接觸導電層, 直到暴露出層間介電層139的頂面為止,以形成填充於第 一和第二接觸窗開口 163a和163b的接觸插塞cn。接觸 插基CN包括分別填充於第一和第二接觸窗開口丨幻②和 163b的第一和第二接觸插塞166a和166b。 如圖11A和11B所述,第 ,〜个1 口弟—闭札模造圖案155a 和155b分別形成為具有長軸和短轴。因而 平面圖所看到的長軸和短軸,其中i 的長軸沿著與主祕,118_縱向方 : = 此,為了減小接觸插塞叫摻雜區 丨=^=^,训咖嶋⑶與推雜區域 重疊的第-導^丨^層139上’形成與第—接觸插塞166a 之間並與第二接觸插塞166b重疊:第電線169a 第一導電、線169a形成為重疊於 偶數的主動區域。各第二導電線心 200822287 26022pif.doc 位於第-導電線169a之間的主動區域118a 導電線169a和169b被稱為位元線BL。 弟一 . 形成第—和第二導電線職和祕的方法如下。首 .先:形成位於層間介電層I39上且與第-接觸插塞祕 重疊的第-導電線l69a,接著,形成覆蓋於第_導電線 職的侧壁的位元線間隔層(未圖示),然後,形成設置在 帛電線169a之間並具有接觸於位域間隔層的二侧 D 壁$第二導電線169b,以及移除位元線間隔層 '然而,在 只施例中,不移除位元線間隔層(例如,省略位元線間隔 層的移除)。因此,位元線間隔層保留在第一和第二導電線 169a和169b之間。 根據圖1到圖14B所描述的實施例,與以微影製程直 接於罩幕圖案16〇中形成開孔相比,第一和第二開孔161a 和161b分別形成為具有實質上一致的尺寸。因此,後續所 形成的第—和第二接觸窗開口 163a和163b,以截面圖和 Q 平面圖來看,都具有實/質上一致的尺寸。因此,分別填充 於第一和第二接觸窗開口 163a和163b的第一和第二接觸 插塞166a和l66b具有實質上一致的阻抗。 在下文中將參照圖1以及圖15A至圖20B以描述根據 第二實施例的製造半導體裝置的方法。And a doped region 136 formed on each side of the main structure C on both sides of the structure 134. For example, the fine (4) inner domain. The 至 曰 7 (4) 隹 & field 136 includes the source and the bungee area ^ The electric Japanese version can be a unit cell transistor CT, and at least one emperor can be a selective transistor ST. Cell I曰Μ M Hair Day :: Line Selection; Line SSL or Ground Selecting Crystal Cell CT can be the electrical layer of flash memory. The second dielectric layers i to 124 may be through the dielectric layer "'an electric layer. The above-mentioned layer 10 200822287 26022pif.doc pen layer at least - layer is, for example, oxidized stone eve, nitrogen oxynitride eve (si0N) , nitrogen s, ilOgen-doped Si oxide), high dielectric constant (h (four)) dimorphism or a combination of materials. High dielectric constant dielectric material; inlet 疋 ^ 1 de, oxidation, bismuth oxide or the like or Initiating f) ο 5. Bay (four) storage layer] 27 at least the layer comprises a oxynitride (s_, a nitrogen-constant dielectric material or a substance or a combination thereof), and two at least one layer of the layer 130 includes oxidation Material of Shi Xi (for example, medium temperature oxide (MT)), high dielectric or similar or a combination thereof. In one embodiment, the data storage layer 127 includes too much 曰 ( Nan〇^^^ 〇, ^^ a ^ 'ls(Mo)' ::Secondary: In the example, the nanocrystalline structure includes the oxide of human, (7) () or the like or its electric: material. In another example, the material of the nanocrystalline structure package (four), the wrong 1 fossil ” t boron or the like or a combination thereof. The sequential second cell electricity: " The gate layer and the control idle electrode. The semiconductor substrate 1 (10) on the sounding = transistor ST and CT has a shape 139. The dielectric layer 139 is, for example, an oxidized stone. The stop layer 142 is formed on the # 曰 layer 139. A buffer layer 145 is formed on the engraving stop layer (4) 142. Buffer i. For example, when the surname stop layer 142 has a _ selective material, the 〇@secret layer 142 is a nitride, and the buffer layer 145 is 200822287 26022pif. Doc oxidized stone material, etc. Referring to Fig. 1, Fig. 9A and Fig. 9B, a first *molding layer is formed on the buffer layer 145. The first molding layer includes a material having a selective selection and properties with respect to the buffer layer 145. The mold layer is, for example, a material such as polysilicon. Next, the first mold layer is patterned to form a linear first mold line 148. The first mold layer can be patterned using photolithography and I-etching processes. Each of the first molding lines 148 is formed in a form overlapping with an odd or even number of active regions in the active region 〇118a. Therefore, the pitch P1 between the first molding lines 148 is larger than the micro pattern used to pattern the first molding layer. Minimum resolution that can be achieved by the shadow process As described above, the first molding line 148 is formed in a line shape. Thus, the first molding line 148 has a substantially uniform width. By etching a portion of the buffer layer 145 between the first molding lines 148 to form A recessed region 147. A conformal spacer layer 151 is formed on the semiconductor substrate 100 having the first molding line 148. The spacer layer 151 covers the top and sidewalls of the first I) molding line 148, and defines a portion of the recessed region 147. Buffer layer 145. Therefore, the spacer layer 151 defines a linear groove 151a on the buffer layer 145 between the first molding lines 148. The groove 151a may be formed to have substantially the same width as the first molding line 148 by adjusting the thickness of the spacer layer 151. The bottom surface of the trench 151a is substantially coplanar with the bottom surface of the first molding line 148 >. In an embodiment, the spacer layer 151 comprises substantially the same material as the buffer layer 145. Referring to Figures 1, 10A and 10B, a second mold layer is formed on the semiconductor substrate 100 having the spacer layer 151 to fill the trench 151a. No. 12 200822287 26022pif.doc A molded layer includes a material layer that is the same as the first molded layer. Next, a patterning (e.g., planarization) process is performed on the first patterned layer to form a second molding line 154 that fills the trench 151a. Thus, the second molding line 154 is uniformly uniform in shape and linear, and is located on the buffer layer 145 between the first molding lines 148. The first mold line 154 is disposed at substantially the same level as the first mold line 148. For example, the bottom surface of the second molding line 154 is substantially coplanar with the bottom surface of the first molding line 148. Further, the width of the second molding line 154 is substantially the same as the width of the first molding line i4g. In the consistent application, each younger brother makes a line 148 and an odd active area 118a. Therefore, each of the second molding lines 154 overlaps with the even number of active regions 118a. Thus, the pitch P2 of the first and second molding lines 148 and 154 is smaller than the pitch P1 between the first molding lines 148. The second mold layer is planarized using etch back or CMP techniques. When the second molding layer is planarized using a return process, the second molding layer is inscribed such that the top surface of the second molding line 154 is substantially coplanar with the top surface of the first molding line 148. When the cyp technique is used to planarize the second mold layer, the second mold layer is planarized until the top surface of the first mold line 148 is exposed. On the semiconductor substrate 100 having the second molding line 154, a linear resist pattern 157 which is bonded to the first and second molding lines 148 and 154 is formed. The photoresist pattern 157 is formed to have a substantially uniform predetermined width. When the second etch layer is planarized using the etch back process described above, a portion of the spacer layer 151 placed over the first pattern line 148 is also patterned by #, and then a photoresist pattern 157 is formed. In one embodiment, the photoresist pattern 157 is formed to intersect the partial active region 118a such that the string selection line 13 of the transistor ST is selected. 200822287 26022pif.doc SSL level is located in the photoresist pattern 157 and the cell transistor CT Between lines WL. The photoresist pattern 157 is substantially parallel to the string selection line SSL. Referring to FIG. 1, FIG. 11A and FIG. 11B, a portion of the spacer layer 151 exposed by the photoresist pattern 157 and the first and second molding lines 148 and 154 are etched by using the photoresist pattern 157 as an etching mask to form a first One and second molding patterns 148 & and 154a. For example, the spacer layer 151 is etched by a dry etching process using an etching gas having an etch selectivity to the first and second molding lines 148 ο ο 154. Subsequently, the first and second molding lines 148 and 154 are rhymed. According to an embodiment, since the linear first and second molding lines 148 and 154 are patterned using the photoresist pattern 157 of a predetermined width, the first and second molding patterns 148a and 15 are formed to have substantially uniform widths, respectively. , =' g| is the width of the second molding line W and the width of the first molding line (10) is the same as the width of the second molding pattern. Then, in addition to the photoresist pattern 157 (for example, the use of the ashing stripping process is 8. Coffee). The first and second molding patterns 14 and 154a hood Qin _ first and second molding patterns 148M 154a The door (10) is spaced apart by a layer 151 to form a bit @;, r52, and thereby exposing a portion of the buffer; and the second === is the first curtain, the part of the _. Therefore, the first stack is sequentially stacked; The second and second τ punch patterns are formed on the etch stop layer 142. Similarly, the first buffer pattern 145b, the spacer pattern 152 and the second are sequentially stacked. The pattern i54a is formed on the end of the layer 142. Thus, the _thivation pattern 1-5a and the first pattern 148a are sequentially referred to as the first aperture pattern 155a, and sequentially stacked. The second buffer pattern Μ%, the spacer pattern 152, and the first pattern 154a are referred to as a second aperture pattern i55b. In the embodiment where the spacer layer 151 and the buffer layer 145 comprise substantially the same material, the same etching may be performed. In the process, the etch spacer layer 151 and the buffer layer 145 are viewed in plan view, the first sum The second aperture molding pattern 15 and 155b are formed to have a major axis (maj or axe) and a minor axis (minor axe). The long axes of the first and second aperture die patterns 155a and 155b are along the active region H8a. The longitudinal direction extends in substantially the same direction. Referring to Figures 1, 12A and 12B, a mask layer is formed on the semiconductor substrate 1 having the first and second aperture patterning patterns 155a and 155b. The sound includes a material having an insecticidal selectivity with respect to the first and second molding patterns 148a and 154a, the spacer pattern 152, and the first and second buffer patterns 145a and 145b. For example, the mask layer includes an organic material such as light. • Impedance, anti-reflective coating (ARC), amorphous carbon material, or the like, or a combination thereof. Next, the patterned mask layer (eg, planarization) is A mask pattern 160 is formed. In one embodiment, the mask layer is patterned using an etch back process until the top surfaces of the first and second aperture patterning patterns 155a and 155b are exposed. Thereafter, the first and second layers are removed. Opening patterning patterns 155a and 155b, 15 200822287 26022pif.doc to form the first and second openings 161 Μϋ 16 lb in the curtain pattern (10). In the case of the case, by patterning the first and second molding patterns (10) a and 154a, and then leaving the spacing pattern 152 And the first and second balance diagrams Yin*l45a and 145匕, and removing the first and second aperture molding patterns 155a and 155b, and the spacing between the second and second apertures is substantially parallel to the string selection line SSI The direction of ^. .耆r, referring to FIG. 13A and FIG. 13B, the mask pattern 160 is used as a mask, the lateral termination layer 142 and the interlayer dielectric layer 139 to form an active region U8a adjacent to the string selection line SSL. First and second contact window openings 163a and i63b. The layer 142 and the interlayer dielectric layer 139 may be terminated by a side-by-side process. Thus, the first and second contact opening openings ^3a and 163b are formed to have a size of the real f. Although the first and second contact opening 163a and 163b are formed to have substantially uniform dimensions, although the first and second contact opening 163& and the aspect ratio are large. , J As described above, the mask pattern 160 includes an organic material. Thus, when the interlayer dielectric layer 139 is left to form the first and second 'contact window openings 163a=163b, the sidewalls of the first and second contact opening 16% and 16 are coated with a mask pattern. 160 thin layer of organic material. Since the sidewalls of the first and first contact window openings 163a and 163b are coated with a thin polymer layer, the width of the first and second contact opening 163 & 163b can be prevented from increasing to the contact opening 163a. And the extent to which 163b can communicate with each other. Thus, the first and second contact opening 163 & 163 and 163b are formed to have a longitudinally vertical side wall or a positively-inclined side 16 200822287 26022 pif.doc wall. When the first and second contact opening 163a and 163b have positively inclined side walls, the widths of the respective first and second contact opening 163a and 163b become smaller from the upper region toward the lower region thereof.罩 Referring to Figures 1, 14A and 14B, the mask pattern 16 is removed. Thereafter, the etch stop layer 142 is removed. A contact conductive layer is formed on the semiconductor substrate 1A having the first and second contact opening 163a and 163b. In one embodiment, the contact conductive layer comprises a material such as doped polysilicon, metal or the like or a combination thereof. The contact conductive layer is planarized by a CMP or etch back process until the top surface of the interlayer dielectric layer 139 is exposed to form contact plugs cn filled in the first and second contact opening 163a and 163b. The contact interposer CN includes first and second contact plugs 166a and 166b that are filled in the first and second contact opening openings 2 and 163b, respectively. As shown in Figs. 11A and 11B, the first to the eleventh-closed patterning patterns 155a and 155b are formed to have a long axis and a short axis, respectively. Therefore, the long axis and the short axis seen in the plan view, where the long axis of i is along with the main secret, 118_longitudinal side: = this, in order to reduce the contact plug called doping area 丨 = ^ = ^, training curry (3) The first conductive layer 139 overlying the dummy region overlaps between the first contact plug 166a and the second contact plug 166b: the first conductive line 169a is formed to overlap the first conductive line 169a. Even number of active areas. Each of the second conductive cores 200822287 26022pif.doc The active regions 118a located between the first conductive lines 169a The conductive lines 169a and 169b are referred to as bit lines BL. Brother I. The method of forming the first and second conductive lines is as follows. First, first: forming a first conductive line l69a on the interlayer dielectric layer I39 and overlapping the first contact plug, and then forming a bit line spacer covering the sidewall of the first conductive line (not shown) And then, forming a two-side D wall $second conductive line 169b disposed between the turns of the wire 169a and having contact with the bit spacer layer, and removing the bit line spacer layer 'however, in the example only, The bit line spacer layer is not removed (eg, the removal of the bit line spacer layer is omitted). Therefore, the bit line spacer layer remains between the first and second conductive lines 169a and 169b. According to the embodiment depicted in FIGS. 1 through 14B, the first and second openings 161a and 161b are formed to have substantially uniform dimensions, respectively, as compared to forming the openings directly in the mask pattern 16A by the lithography process. . Therefore, the subsequently formed first and second contact opening 163a and 163b have a real/quality uniform size in both the sectional view and the Q plan view. Therefore, the first and second contact plugs 166a and 166b respectively filled in the first and second contact opening 163a and 163b have substantially uniform impedance. A method of manufacturing a semiconductor device according to a second embodiment will be described hereinafter with reference to Fig. 1 and Figs. 15A to 20B.

‘ 圖 15A、圖 16A、圖 17A、圖 18A、圖 19A 和圖 20A 是沿圖1的線I-Ι,的截面圖,其為根據第二實施例的製造 半導體裝置的方法流程圖。圖15B、圖16B、圖17B、圖 18B、圖19B和圖20B是沿圖1的線ΙΙ-ΙΓ的截面圖,其為 18 200822287 26022pif.doc 根據第二實施例的製造半導體裝置的方法流程圖。 參照圖1、圖15Α和圖15Β,根據上文對圖2Α至圖 7Α以及圖2Β至圖7Β所描述的方法來形成具有由隔離層 121所定義出之主動區城U8a的半導體基板1〇〇。 Ο ο 於各主動區域118a上形成電晶體。電晶體包括形成於 各主動區域l18a上的閘結構234以及形成於閘結構234 兩侧之各主動區域内的摻雜區域236。至少一電晶體是晶 胞電晶體ct並且至少〆電晶體是選擇電晶體ST。晶胞電 晶體CT的閘電極作為字線WL,並與主動區域n8a交叉 ^伸。選擇電晶體ST的蘭電極作為串選擇線SSL或者地 選擇線GSL,並與主動區域118a交叉延伸。 在一實施例中,晶胞電晶體ct的閘結構234包括依 序堆疊的閘介電層224、淨閘227、閘間介電層23〇以及控 =閘極233。浮閘227例如是多晶石夕。摻雜區域230可以 是源極與汲極區域。 在另一貫施,中,晶胞電晶體CT的閘結構234可以 匕括依序堆疊的第一介電層、資料儲存層、第二介電無 及閘電極。 曰 問人t具有電晶體ST和CT的半導體基板100上,形成層 曰電層239。層間介電層239例如是氧化矽。 θ 翏照圖1、圖16Α和圖16Β,於層間介電層239上 声xj、冬止層242。钱刻終止層242包括相對於層間介電 擇性的材質層°例如’當層間介電層239 夕日守,I虫刻終止層242可為氮化石夕等材質。 19 200822287 26022pif.doc 於姓刻終止層242上形成第一模造層。第一模造層包 括相對於蝕刻終止層242具有蝕刻選擇性的材質。例如, 當蝕刻終止層242包括氮化矽時,第_模造層包括多晶矽 等材貝。接著,圖案化第一模造層以形成線形的第一模造 線248。可使用微影和蝕刻製程來圖案化第一模造層,使 知第一模造線248具有實質上一致的寬度。 Ο ο 在一實施例中,各第一模造線248形成為與主動區域 中的奇數或偶數的主動區域重疊。 間隔層251形成為覆蓋於第一模造線对8的侧壁。藉 由在半導體基板1〇〇以及第一模造線248上,以保角的方 式形成一層相對於第一模造線248具有蝕刻選擇性的材質 層,接著以異向性蝕刻來蝕刻材質層,以形成間隔層251, 因此間隔層251在第一模造線248的侧壁上且有實質上一 致的寬度。 /、、、 =¾圖1 ’圖ΠΑ以及圖17B,於具有間隔層251的 =基板,上形成第二模造層。第二模造層包括實質 二Γ旦模造線248之間,形成寬度實質上一 致的弗二板造線254。第二模造線254也為線形。 使用回I虫和/或CMIM支術來平坦化第二模造芦 用回簡術來平坦化第二模造層時, 二:在使 得第二模造線254的頂面與第層,使 為共平面。在-實施例中=面實質上 20 200822287 26022pif.doc 的頂面。由於第一和第二模造線248包括貫質上相同的材 質,在過度蝕刻第二模造層的同時,也會钱刻到第一模造 ^ 線248。因而,第一和第二檬造線248的頂面實質上為共 平面。Fig. 15A, Fig. 16A, Fig. 17A, Fig. 18A, Fig. 19A and Fig. 20A are cross-sectional views taken along line I-Ι of Fig. 1, which is a flow chart of a method of manufacturing a semiconductor device according to a second embodiment. 15B, 16B, 17B, 18B, 19B, and 20B are cross-sectional views taken along line ΙΙ-ΙΓ of Fig. 1, which are 18 200822287 26022 pif. doc Flowchart of a method of manufacturing a semiconductor device according to a second embodiment . Referring to FIGS. 1, 15A and 15B, a semiconductor substrate 1 having an active region U8a defined by an isolation layer 121 is formed according to the methods described above with respect to FIGS. 2A to 7A and FIGS. 2A to 7B. . ο ο A transistor is formed on each active region 118a. The transistor includes a gate structure 234 formed on each active region 118a and a doped region 236 formed in each active region on both sides of the gate structure 234. At least one of the transistors is a cell transistor ct and at least the germanium transistor is a selective transistor ST. The gate electrode of the unit cell CT is used as the word line WL and intersects with the active region n8a. The blue electrode of the transistor ST is selected as the string selection line SSL or the ground selection line GSL, and extends across the active region 118a. In one embodiment, the gate structure 234 of the cell transistor ct includes a gate dielectric layer 224, a gate 227, a gate dielectric layer 23, and a gate electrode 233 stacked in sequence. The floating gate 227 is, for example, a polycrystalline stone. Doped region 230 can be a source and drain region. In another embodiment, the gate structure 234 of the cell transistor CT can include a first dielectric layer, a data storage layer, and a second dielectric gateless electrode stacked in sequence. On the semiconductor substrate 100 having the transistors ST and CT, a layer of tantalum layer 239 is formed. The interlayer dielectric layer 239 is, for example, hafnium oxide. θ Referring to FIG. 1, FIG. 16B and FIG. 16A, an acoustic layer xj and a winter stop layer 242 are formed on the interlayer dielectric layer 239. The engraved termination layer 242 includes a layer of dielectric material relative to the interlayer. For example, when the interlayer dielectric layer 239 is used, the engraved termination layer 242 may be a material such as nitride. 19 200822287 26022pif.doc A first mold layer is formed on the last stop layer 242. The first mold layer includes a material having an etch selectivity with respect to the etch stop layer 242. For example, when the etch stop layer 242 includes tantalum nitride, the first mold layer includes a polysilicon or the like. Next, the first mold layer is patterned to form a linear first mold line 248. The first mold layer can be patterned using lithography and etching processes to make the first mold line 248 have a substantially uniform width. In one embodiment, each of the first molding lines 248 is formed to overlap an odd or even number of active regions in the active region. The spacer layer 251 is formed to cover the sidewall of the first molding pair 8. Forming a layer of material having an etch selectivity with respect to the first molding line 248 on the semiconductor substrate 1 〇〇 and the first molding line 248 in a conformal manner, and then etching the material layer by anisotropic etching to The spacer layer 251 is formed such that the spacer layer 251 is on the sidewalls of the first molding line 248 and has a substantially uniform width. /, , , = 3⁄4 Fig. 1 ' and FIG. 17B, a second mold layer is formed on the = substrate having the spacer layer 251. The second molded layer includes substantially two-half damascene lines 248 forming a substantially two-layered wire 254 having a substantially uniform width. The second molding line 254 is also linear. When using the I-worm and/or CMIM branch to planarize the second mold-making back to flatten the second mold layer, two: making the top surface and the second layer of the second mold line 254 coplanar . In the embodiment - the surface of the surface is substantially 20 200822287 26022pif.doc. Since the first and second molding lines 248 comprise substantially the same material, the second molding layer is overetched and the first molding line 248 is also inscribed. Thus, the top surfaces of the first and second lemon lines 248 are substantially coplanar.

V 當使用CMP技術來平坦化第二模造層時,第二模造 線254的頂面實質上與第一模造線248和間隔層251的頂 面為共平面。因而,第二模造線254設置在實質上與第一 D 模造線248相同的層位。當各第一模造線248形成為與奇 數的主動區域重疊時,各第二模造線254形成為與偶數的 主動區域重疊。 於具有第二模造線254的半導體基板上形成與第 一和第二模造線248和254交叉的線形光阻圖案257。光 阻圖案257形成為具有實質上一致的預定寬度。 在一實施例中,光阻圖案257形成為交叉於部份主動 區域118a,使得選擇電晶體ST的串選擇線SSL水平位於 〇 光阻_案257和晶胞電晶體CT的字線WL之間。光阻圖 案257實質上平行於串選擇線SSL。 - 參照圖1,圖18A和圖18B,以光阻圖案257為蝕刻 • 罩幕’ I虫刻第一和第二模造線248和254,以形成第一和 第二開孔模造圖案248a和254a。隨後,移除光阻圖案257。 接著’移除間隔層251 (例如,|虫刻)。因此,第一和第二模 4圖案248a和254a保留在I虫刻終止層242上。 ^根據一實施例,由於以具有預定寬度的光阻圖案257 來圖案化為線形的第一和第二模造線248和254,第一和 21 200822287 26022pif.doc 第一開孔模造圖幸94¾¾ 度。此外,第-和第二 =2地分別具有實質上一致的寬 有長軸和短軸。第孔模造圖案2術和254a分別具 長軸fm 和乐二開孔模造圖案248a和254a的 動區:或_的縱向方向實質上相同的方向 Ο Ο 度以及光阻圖^5^^和第二_'線248和254的寬 248a和254a。 $見度,以形成第一和第二模造圖案 模造圖安9“固 和圖19Β,於具有第一和第二開孔 罩幕層L相的ί導體基板1〇0上形成罩幕層。 具有_選擇性的:和= 和· 阻抗钱劑、ARr db、罩綦層包括有歸貝,例如是光 著,圖安各罢-、非晶質碳材質或類似物或者其組合。接 出第n ㈣程來平坦化罩幕層,直到暴露 乐一開孔杈造圖案248a和254a的頂面。 以於罩幕Pit除第—和第二開孔模气圖案248a和254a, 因此罩j圖二,形成第—和第二開孔26ia和祕。 線_彳t二=仙和鳩沿著實質上與串選擇 罩幕^^ 1、圖2GA和圖施,以罩幕圖案26G為钱刻 終止層242和層間介電層辦,二: 接觸窗n廷擇線飢相鄰的主動區域118a的第-和第丄 如而:㈣和13— 、 而後,移除蝕刻終止層242。藉由填充第 22 200822287 26022pif.doc 和第一接觸窗開口,以形成接觸插塞CN(例如,如圖14A 和圖14B戶斤;、+、m 冰一 :知迷的)。接觸插塞CN包括分別填充於第一和 ’ 第一接觸1^開口的第一和第二接觸插塞266a和266b。之 ,,_於^間介電層239上形成與第一接觸插塞266a重疊的 f ^ =線269a(例如,如圖14A和圖14B所描述的)。於 二&笔、、复%9a之間’形成與第二接觸插塞266b重疊的 帛了導電線26%。第—和第二導電線269a和26%被稱為 ’ 位元線BL。各第—導電線269a形成為重疊於主動區域 118a内的奇數或偶數的主動區域。各第二導電線269b形 成為重璺於水平上位於第一導電線269a之間的主動區域 118a。 根據上文描述的實施例,藉由圖案化線形的第一和第 一模ie線,以形成第一和第二模造圖案。沿著第一和第二 模造圖案所形成的罩幕圖案開孔具有實質上一致的尺寸。 因此,後續所形成的接觸窗開口具有實質上一致的尺寸並 Ο" 且填充於接觸窗開口的接觸插塞具有實質上一致的阻抗。 因此,上述方法能增加半導體贏置的矸靠性。 因而’根據本文所描述的一實施例之一種製造半導體 • t置的方法,其包括在半導體基板中形成定義出主動區域 的隔離層。層間介電層形成於具有降離層的半導體基板 上。第一模造圖案形成於層間介電層上。形成位於第一模 造圖案之間並與其具有間隔的第二模造_案。形成包圍第 一和第二模造圖案的侧壁的罩幕圖案。藉由移除第一和第 二模造圖案形成開孔。以罩幕圖案為蝕刻罩幕,蝕刻層間 23 200822287 26022pif.doc 介電層以形成接觸窗開口。 在一實施例中,形成第一模造圖案和第二模造圖案的 . 方法包括:在層間介電層上形成第一模造線,在層間介電 層上形成第二模造線,且第二模造線設置於第一模造線之 赛 間並與第一模造線具有間隔,然後,圖案化第一模造線以 形成第一模造圖案以及圖案化第二模造線以形成第二模造 圖案。 〇 在一實施例中,至少一部份的第一和第二模造線實質 上共平面。 在一實施例中,第一和第二模造圖案形成為具有相同 的尺寸。 在一實施例中,由平面圖來看,第一和第二模造圖案 形成為具有長軸和短轴。在一實施例中,第一和第二模造 圖案的長軸具有與第一和第二模造線的縱向方向為相同的 方向。 } 在一實施例中,在形/成第一模造線之前,在半導體基 板上形成緩衝層。在另一實施例中,在形成第一模造線之 後,藉由蝕刻部分設置於第一模造線兩侧的緩衝層,以形 成凹陷區域。 在一實施例中,形成第二模造線包括先形成覆蓋於第 一模造線以及覆蓋於具有凹陷區域的缓衝層的保角間隔 層,接著在具有間隔層的半導體基板上形成模造層,然後 平坦化模造層,使得第二模造線的頂面與第一模造線的頂 面位於相同的層位上。 24 200822287 26022pif.doc 在一實施例中,形成第一和弟一模造圖案包括先在間 隔層上以及第二模造線上形成與第一和第二模造線交又的 . 光阻圖案,接著以光阻圖案為蝕刻罩幕,蝕刻間隔層及第 • 一和第二模造線以形成第一和第二模造圖案,而後移除光 阻圖案,然後以第一和第二模造圖案為蝕刻罩幕,蝕刻第 一和第二模造圖案周圍的間隔層和緩衝層。 在一實施例中,形成第二模造線的方法包栝先在具有 ❹ 第一模造線的半導體基板上形成覆蓋於第一模造線的間隔 層,接著在具有間隔層層的半導體基板上形成模造層,以 及平坦化模造層,使得模造層保留在第一模造線之間。 在一實施例中,形成第一和第二模造圖案包括先在具 有第一模造線的半導體基板上形成與第一和第二模造線交 叉的光阻圖案,接著以光阻圖案為蝕刻罩幕,蝕刻第一和 第一模造線以形成第一和第二模造圖案,而後移除光阻圖 案,接著蝕刻間隔層,以暴露出第一和第二模造圖案的侧 U 壁。 在一貫施例中,多個主動區域藉由隔離層而彼此^間 隔’且各主動區域藉由隔離層定義為線形。 • 、在一實施例中,各第一模造線形成與主動區域内的奇 、 I或偶制主動區域重疊,並且纟第二模造線形成為與主 動區域内位於第一模造線之間的主動區域重疊。 在二實施例中,主動區域的定義包括先在半導體基板 上形成第一硬罩幕圖案,在第一硬罩幕圖案之間形成第二 硬罩幕圖案,接著蝕刻位於第一和第二硬罩幕圖案之間的 25 200822287 26022pif.doc 半導體基板,以形成綠,紐形成填充 並移除第-和第二硬罩幕圖案。 冑—層, 形成ί;:施:在;動區域的定義包括先在半導體基板 域,繼之:成周圍的緩衝層,以形成凹陷區 ^ 、七之形成復盍於第一硬罩慕圖安w g曰‘ Ο ο 緩衝層的保角犧牲層,而後形成分別由被:於 «之間的犧牲層所包_第二硬罩幕圖案,、= 硬罩幕圖案上以及位於第一和第二;昂 ,第一和第二硬罩幕圖而 半導體基板以形成溝渠,接著形成填5 y恭路出的 實施例中’主定==案。 上形成第-硬罩幕圖案,然後形成覆蓋η半導體基板 之侧壁的犧牲,,接著形成位於第硬罩幕圖案 有與犧牲層接觸之二侧壁的第二 案’間並具 牲層,以第—和第二硬罩翔案為_^ 1後移除犧 板而形成溝渠,繼之,形成埴 蝕刻導體基 硬罩幕圖案。 m的轉層,以及移除 在一實施例中,在形成層間介電芦 二主動區域上,並且於閘結構“結構形成 區域。 勡區域内形成摻雜 在-實施例中,各閘結構包括依序堆疊的第一介電 26 200822287 26022pif.doc 層 位於閘極 、貧料儲存層、第二介電層以及㈣極。在另—實 ,各閘結構包括依序堆疊的·電層、相、、1 間的介電層以及控制閘極。 在-^施例中,罩幕圖案由有機材質層形成。 ^-實_中,製造半導體裝置的方法更包括 拳圖案並形成填充接觸窗開口的接觸插塞。 示卓V. When the CMP technique is used to planarize the second mold layer, the top surface of the second mold line 254 is substantially coplanar with the top surfaces of the first mold line 248 and the spacer layer 251. Thus, the second molding line 254 is disposed in substantially the same level as the first D molding line 248. When each of the first molding lines 248 is formed to overlap with the odd active regions, each of the second molding lines 254 is formed to overlap with the even number of active regions. A linear resist pattern 257 crossing the first and second molding lines 248 and 254 is formed on the semiconductor substrate having the second molding line 254. The photoresist pattern 257 is formed to have a substantially uniform predetermined width. In one embodiment, the photoresist pattern 257 is formed to intersect the partial active region 118a such that the string select line SSL level of the select transistor ST is between the photoresist 257 and the word line WL of the unit cell CT. . The photoresist pattern 257 is substantially parallel to the string selection line SSL. Referring to FIG. 1, FIG. 18A and FIG. 18B, the first and second molding lines 248 and 254 are inscribed by the photoresist pattern 257 as an etch mask to form first and second aperture patterning patterns 248a and 254a. . Subsequently, the photoresist pattern 257 is removed. The spacer layer 251 is then removed (e.g., | insect). Therefore, the first and second dies 4 patterns 248a and 254a remain on the I-terminating stop layer 242. According to an embodiment, since the first and second molding lines 248 and 254 are patterned in a linear shape with a photoresist pattern 257 having a predetermined width, the first and 21 200822287 26022 pif.doc first aperture molding is fortunately 943⁄43⁄4 degrees . Further, the first and second = 2 grounds respectively have substantially uniform widths of a major axis and a minor axis. The first hole molding pattern 2 and the 254a respectively have a long axis fm and a moving area of the second aperture molding patterns 248a and 254a: or the longitudinal direction of the _ is substantially the same direction Ο 以及 degree and the photoresist pattern ^5^^ and The widths 248a and 254a of the two _' lines 248 and 254. The visibility is formed to form the first and second molding patterns to form a mask layer on the ί conductor substrate 1〇0 having the first and second aperture mask layer L phases. _ Selective: and = and · Impedance, ARr db, cover layer including return, such as light, Illustrated - amorphous carbon material or the like or a combination thereof. The nth (fourth) process is to planarize the mask layer until the top surface of the opening pattern 248a and 254a is exposed. The mask Pit removes the first and second aperture pattern patterns 248a and 254a, so the mask j Figure 2, forming the first and second openings 26ia and secret. Line _彳t two = xian and 鸠 along the line with the selection of the cover ^ ^ 1, Figure 2GA and Figure, with the cover pattern 26G for money The etch stop layer 242 and the interlayer dielectric layer are disposed, and the contact openings 242 are adjacent to the first and the third regions of the active region 118a: (4) and 13-, and then the etch stop layer 242 is removed. Filling the 22nd 200822287 26022pif.doc and the first contact window opening to form the contact plug CN (for example, as shown in Fig. 14A and Fig. 14B; +, m ice one: knowing). The plug CN includes first and second contact plugs 266a and 266b respectively filled in the first and 'first contact openings'. The first and second contact plugs 266a and 266b are formed on the dielectric layer 239 and the first contact plug 266a. Overlapping f ^ = line 269a (eg, as depicted in Figures 14A and 14B). Between the second & pen, complex %9a 'formed with the second contact plug 266b overlapped the conductive line 26% The first and second conductive lines 269a and 26% are referred to as 'bit lines BL. Each of the first conductive lines 269a is formed to overlap an odd or even number of active regions within the active region 118a. Each of the second conductive lines 269b is formed. To focus on the active area 118a between the first conductive lines 269a in a horizontal direction. According to the embodiment described above, the first and second molded patterns are patterned by patterning the first and first modes. The mask pattern openings formed along the first and second molding patterns have substantially uniform dimensions. Therefore, the subsequently formed contact window openings have substantially uniform dimensions and are filled in the contact window openings. The contact plug has a substantially uniform impedance. Therefore, the upper The method can increase the reliability of semiconductor wins. Thus, a method of fabricating a semiconductor device according to an embodiment described herein includes forming an isolation layer defining an active region in a semiconductor substrate. Formed on the semiconductor substrate having the falling layer. The first molding pattern is formed on the interlayer dielectric layer, and a second molding method is formed between and spaced apart from the first molding pattern to form the surrounding first and second moldings. A mask pattern of the sidewalls of the pattern. The openings are formed by removing the first and second mold patterns. Using a mask pattern as an etch mask, the interlayer is etched to form a contact opening. In one embodiment, the first molding pattern and the second molding pattern are formed. The method includes: forming a first molding line on the interlayer dielectric layer, forming a second molding line on the interlayer dielectric layer, and forming a second molding line The first molding line is disposed between the first molding line and spaced apart from the first molding line, and then the first molding line is patterned to form a first molding pattern and the second molding line is patterned to form a second molding pattern.一 In one embodiment, at least a portion of the first and second molding lines are substantially coplanar. In an embodiment, the first and second molding patterns are formed to have the same size. In an embodiment, the first and second molding patterns are formed to have a long axis and a short axis as viewed in plan. In an embodiment, the major axes of the first and second molding patterns have the same direction as the longitudinal directions of the first and second molding lines. } In one embodiment, a buffer layer is formed on the semiconductor substrate prior to forming/forming the first molding line. In another embodiment, after the first molding line is formed, the buffer layer is disposed on both sides of the first molding line by etching to form a recessed region. In one embodiment, forming the second molding line includes first forming a conformal spacer layer covering the first molding line and covering the buffer layer having the recessed region, and then forming a molding layer on the semiconductor substrate having the spacer layer, and then forming The molding layer is planarized such that the top surface of the second molding line is at the same level as the top surface of the first molding line. 24 200822287 26022pif.doc In one embodiment, forming the first and second patterned patterns includes first forming a photoresist pattern on the spacer layer and the second molding line, and then bonding the light to the first and second molding lines. The resist pattern is an etch mask, etching the spacer layer and the first and second molding lines to form the first and second molding patterns, and then removing the photoresist pattern, and then using the first and second molding patterns as an etching mask, A spacer layer and a buffer layer around the first and second mold patterns are etched. In one embodiment, the method of forming the second molding line comprises first forming a spacer layer covering the first molding line on the semiconductor substrate having the first molding line, and then forming the molding on the semiconductor substrate having the spacer layer. The layer, and the planarized molding layer, such that the molded layer remains between the first molding lines. In one embodiment, forming the first and second mold patterns comprises first forming a photoresist pattern crossing the first and second molding lines on the semiconductor substrate having the first molding line, and then using the photoresist pattern as an etching mask The first and first molding lines are etched to form the first and second molding patterns, and then the photoresist pattern is removed, followed by etching the spacer layer to expose the side U walls of the first and second molding patterns. In a consistent embodiment, a plurality of active regions are separated from each other by an isolation layer and each active region is defined as a line by an isolation layer. • In one embodiment, each of the first molding lines is formed to overlap an odd, one, or even active region in the active region, and the second molding line is formed to be an active region between the first molding line and the active region. overlapping. In two embodiments, the definition of the active region includes first forming a first hard mask pattern on the semiconductor substrate, forming a second hard mask pattern between the first hard mask patterns, and then etching the first and second hard portions. A mask pattern between the 25 200822287 26022pif.doc semiconductor substrate to form a green, neon fill fill and remove the first and second hard mask patterns.胄—layer, forming ί;: Shi: in; the definition of the moving region includes first in the semiconductor substrate domain, followed by: forming a surrounding buffer layer to form a recessed region ^, and the formation of the seventh is repeated in the first hard mask. An wg曰' Ο ο the sagittal layer of the sacrificial layer of the buffer layer, and then formed by the: sacrificial layer between the _ second hard mask pattern, = hard mask pattern and located in the first and the Second, the first and second hard masks are used to form the trenches, and then the formation is filled in. Forming a first-hard mask pattern thereon, then forming a sacrificial covering the sidewalls of the n-semiconductor substrate, and then forming a second layer between the second sidewall of the second hard mask pattern having contact with the sacrificial layer After the first and second hard cover cases are _^1, the sacrificial plates are removed to form a ditch, and then a ruthenium-etched conductor-based hard mask pattern is formed. The layer of m, and removed, in one embodiment, on the formation of the interlayer dielectric reed active region, and in the gate structure "structure formation region. Doping in the germanium region - in the embodiment, each gate structure includes The first dielectric layer 262222287 26022pif.doc layer stacked in sequence is located at the gate, the lean storage layer, the second dielectric layer, and the (four) pole. In another, the gate structure includes the electric layer and phase stacked in sequence. , a dielectric layer and a control gate. In the embodiment, the mask pattern is formed by an organic material layer. In the actual method, the method for manufacturing the semiconductor device further includes a punch pattern and forms a filling contact opening. Contact plug.

ϋ 的,=中1所Α開的貝貝内容應認為是示意性而非限制性 内的請專利·意圖覆蓋落在本發明的精神和範圍 的最^飾、改進以及其他實施例。因而,以法律允許 大乾圍,本發明的範圍藉由後射請專利範圍及 最大允許解釋較,並不應侷限於上料細描述、。 L圖式簡單說明】 圖1是根據一實施例的半導體裝置的平面圖。 圖2A、圖3A、圖4A、圖5A、圖6A、圖7A、圖8A、 :A、圖10A、圖UA、圖以、圖以及圖1仏是 的線w’的截㈣,其為根據第-實施例的製造半 置的方法流程圖。 4 圖2B、圖3B、圖4B、圖5B、圖6B、圖7B、圖8B、 ^ B、® 10B、圖11B、圖12B、圖13B以及圖14B是沿。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Therefore, the scope of the present invention is allowed by the law to allow for the scope of the patent, and the maximum allowable interpretation is not limited to the detailed description. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a plan view of a semiconductor device in accordance with an embodiment. 2A, 3A, 4A, 5A, 6A, 7A, 8A, A, 10A, UA, Fig. 1, and Fig. 1A are cuts (4) of the line w', which are based on A flow chart of a method of manufacturing a half-set of the first embodiment. 4 Figure 2B, Figure 3B, Figure 4B, Figure 5B, Figure 6B, Figure 7B, Figure 8B, ^B, ® 10B, Figure 11B, Figure 12B, Figure 13B and Figure 14B are along

二壯的線11_11,的截關,其為根據第—實施綱製造半導 版衣置的方法流程圖。 甘、圖15A、圖16A、圖17A、圖18A、圖19A和圖20A ::圖1的線H,的截面圖,其為根據第二實施例的製造 ^體裝置的方法流程圖。 200822287 26022pif.doc 圖 15B、圖 16B、圖 17B、圖 18B、圖 19B 和圖 20B 是沿圖1的線ΙΙ-ΙΓ的截面圖,其為根據第二實施例的製造 . 半導體裝置的方法流程圖。 【主要元件符號說明】 100 :半導體基板 103 :墊層 103a :第一墊圖案 〇 103b :第二墊圖案 106 :下硬罩幕層 106a :第一下硬罩幕圖案 106b :第二下硬罩幕圖案 10 7 ·凹陷區域 109 :第一上硬罩幕圖案 112 :犧牲層 112a :溝槽 ) / 112b:犧牲圖案 / i 115 :第二上硬罩幕圖案 117 :溝渠 118 a ·主動區域 121 ··隔離層 124 :第一介電層 127 :資料儲存層 130 :第二介電層 133 :閘電極 28 200822287 26022pif.doc 134 閘結構 136 掺雜區域 139 層間介電層 142 1虫刻終止層 145 緩衝層 145a :第一缓衝圖案 145b :第二緩衝圖案 () 147 :凹陷區域 148 :第一模造線 148a :第一模造圖案 151 :保角間隔層 151a :線形溝槽 152 :間隔圖案 154 :第二模造線 154a :第二模造圖案 ^ 155a :第一開孔模造圖案 155b :第二開孔模造圖案 157 :光阻圖案 160 :罩幕圖案 ‘ 161a :第一開孔 161b ··第二開孔 163a :第一接觸窗開口 163b :第二接觸窗開口 166a :第一接觸插塞 29 200822287 26022pif.doc 166b :第二接觸插塞 169a :第一導電線 . 169b :第二導電線 224 :第二導電線 227 :浮閘 230 :閘間介電層 233 :控制閘極 〇 234 :閘結構 236 :摻雜區域 239 :層間介電層 242 :蝕刻終止層 248 :第一模造線 248a :第一開孔模造圖案 251 :間隔層 254 :第二模造線 - 254a :第二開孔模造圖案 257 :光阻圖案 260 :罩幕圖案 261a ··第一開孔 261b :第二開孔 266a :第一接觸插塞 266b :第二接觸插塞 269a :第一導電線 269b ··第二導電線 30 200822287 26022pif.doc BL :位元線 GSL :地選擇線 . WL :字線 SSL :串選擇線 CN :接觸插塞 ST :選擇電晶體 CT :晶胞電晶體 P1 :間距 P2 :間距 Ι-Γ :線 ΙΙ-ΙΓ :線The interception of the two strong lines 11_11, which is a flow chart of a method for manufacturing a semi-guided garment according to the first embodiment. Figs. 15A, 16A, 17A, 18A, 19A and 20A: a cross-sectional view of line H of Fig. 1, which is a flow chart of a method of manufacturing a body device according to the second embodiment. 200822287 26022pif.doc FIGS. 15B, 16B, 17B, 18B, 19B, and 20B are cross-sectional views taken along line ΙΙ-ΙΓ of FIG. 1, which are flowcharts of a method of fabricating a semiconductor device according to a second embodiment. . [Main component symbol description] 100: semiconductor substrate 103: pad layer 103a: first pad pattern 〇103b: second pad pattern 106: lower hard mask layer 106a: first lower hard mask pattern 106b: second lower hard mask Curtain pattern 10 7 · recessed area 109: first upper hard mask pattern 112: sacrificial layer 112a: trench) / 112b: sacrificial pattern / i 115 : second upper hard mask pattern 117 : trench 118 a · active area 121 · Isolation layer 124: First dielectric layer 127: Data storage layer 130: Second dielectric layer 133: Gate electrode 28 200822287 26022pif.doc 134 Gate structure 136 Doped region 139 Interlayer dielectric layer 142 1 Insect termination layer 145 buffer layer 145a: first buffer pattern 145b: second buffer pattern () 147: recessed region 148: first molding line 148a: first molding pattern 151: conformal spacer layer 151a: linear groove 152: spacer pattern 154 The second molding line 154a: the second molding pattern ^ 155a: the first opening pattern 155b: the second opening pattern 157: the photoresist pattern 160: the mask pattern '161a: the first opening 161b · · the second Opening 163a: first contact opening 163b: second contact opening 16 6a: first contact plug 29 200822287 26022pif.doc 166b: second contact plug 169a: first conductive line. 169b: second conductive line 224: second conductive line 227: floating gate 230: inter-gate dielectric layer 233 : Control gate 〇 234 : gate structure 236 : doped region 239 : interlayer dielectric layer 242 : etch stop layer 248 : first molding line 248a : first aperture molding pattern 251 : spacer layer 254 : second molding line - 254a: second aperture molding pattern 257: photoresist pattern 260: mask pattern 261a · first opening 261b: second opening 266a: first contact plug 266b: second contact plug 269a: first conductive Line 269b ··Second conductive line 30 200822287 26022pif.doc BL : Bit line GSL : Ground selection line. WL : Word line SSL : String selection line CN : Contact plug ST : Select transistor CT : Cell transistor P1 : Spacing P2: Spacing Ι-Γ : Line ΙΙ-ΙΓ : Line

Claims (1)

200822287 26022pif.doc 十、申請專利範圍: 1·一種製造半導體裝置的方法,包括: • 在半導體基板上形成隔離層,所述隔離層在所述半導 . 體基板内定義出主動區域; 在所述半導體基板上形成層間介電層, 在所述層間介電層上形成第/模造圖案; 在所述層間介電層上形成第二模造圖案,所述第二模 Θ 造圖案設置在所述第一模造圖案之間並與所述第一模造圖 案具有間隔; 形成包圍所述第一模造圖案的侧壁以及所述第二模造 圖案的侧壁的罩幕圖案; 移除所述第一模造圖案和所述第二模造圖案,以在所 述罩幕圖案内形成開孔;以及 以所述罩幕圖案作為蝕刻罩幕,蝕刻所述層間介電層 以形成接觸窗開口。 〇 2·如申請專範圍第1項所述的製造半導體裝-的方 法,其中形成所述第〜模造圖案和所述第二模造圖案包括: 在所述層間介電層上形成第一模造線; ♦ 在所述層間介電層上形成第二模造線,所述第二模造 線設置在所述第一楔造線之間並與所述第一模造線具有間 ' 隔; 圖案化所述第〜模造線以形成第/模造圖案;以及 圖案化所述第二模造線以形成第二模造圖案。 3·如申請專利範圍第2項所述的製造半導體裝置的方 32 200822287 26022pif.doc 法,其中一所述第一模造線的至少一部份實質上與/所述 第二模造線的至少一部份共平面。 4·如申請專利範圍第1項所述的製造半導體裝ί的方 法,其中一所述第一模造圖案的寬度貫質上與一戶斤述弟一* 模造圖案的寬度相同。 Ο200822287 26022pif.doc X. Patent Application Range: 1. A method of manufacturing a semiconductor device, comprising: • forming an isolation layer on a semiconductor substrate, the isolation layer defining an active region in the semiconductor substrate; Forming an interlayer dielectric layer on the semiconductor substrate, forming a first/mold pattern on the interlayer dielectric layer; forming a second molding pattern on the interlayer dielectric layer, the second mold pattern being disposed on Between the first molding patterns and the first molding pattern; forming a mask pattern surrounding the sidewalls of the first molding pattern and the sidewalls of the second molding pattern; removing the first molding And patterning the second mold pattern to form an opening in the mask pattern; and etching the interlayer dielectric layer to form a contact window opening using the mask pattern as an etch mask. The method of manufacturing a semiconductor package according to the above item 1, wherein the forming the first molding pattern and the second molding pattern comprises: forming a first molding line on the interlayer dielectric layer ♦ forming a second molding line on the interlayer dielectric layer, the second molding line being disposed between the first wedge lines and having a gap with the first molding line; patterning the Forming a first/mold pattern; and patterning the second mold line to form a second mold pattern. 3. The method of manufacturing a semiconductor device according to claim 2, wherein the at least one portion of the first molding line is substantially at least one of/the second molding line. Partially coplanar. 4. The method of manufacturing a semiconductor device according to claim 1, wherein the width of one of the first molding patterns is the same as the width of a pattern of the one mold. Ο 5·如申請專利範圍第1項所述的製造半導體裝置的方 法,其中以平面圖來看,至少一所述第一模造圖案和至少 一所述第二模造圖案具有長軸和短軸。 6·如申請專利範圍第5項所述的製造半導體裝置的方 法,其中所述主動區域沿縱向方向廷伸過所述半導體基 板,並且所述至少一第一模造圖案的所述長軸以及所述至 少一第二模造圖案的所述長轴沿與所述縱向方向實質上以 相同的方向延伸。 7·如申請專利範圍第2項所述的製造半導體裝置的方 法,更包括在形成所述第一模造線之前,在所述 層上形成緩衝層。 兒 導'體裂置的方 8·如申請專利範圍第7項所述的製造半 法’更包括: 在所述緩衝層上方形成所述第一模造線, 第一模 形成四 述緩衝層相鄰於至少_所述第-模造線的相對側^份所 、生在形成所述第一模造線之後,在與所述至少一,以及 ^所述相對侧面相鄰的所述緩衝層的各部份内 9·如申請專利範圍第8項所述的製造半導體壯 |夏的方 33 200822287 26022pif.doc 法,其中形成所述第二模造線包括: 保角 在所述第一模造線上以及各所述凹陷區域内 ” • 的形式形成間隔層; • 在所述間隔層上形成模造層;以及 頂 圖案化所述模造層,使得至少一所述第二模^备、 面實質上與至少一所述第一模造線的頂面共平面。 10·如申請專利範圍第9項所述的製造半導踱衣,^ 方法,其中形成所述第一模造圖案和所述第二模產圖济υ 括: 在所述間隔層和所述第二模造線上形成光阻圖案’所 述光阻圖案與所述第一模造線和所述第二模造線父叉’ 以光阻圖案為蝕刻罩幕,蝕刻所述第一模造線上的部 份所述間隔層; 以光阻圖案為蝕刻罩幕,蝕刻部份所述第一模造線以 及部份所述第二模造線; 移除所述光阻圖案;以及 以所述第一模造圖案和所述第二模4造圖案為蝕刻罩 幕,钱刻保留在所述第一模造線和所述第二模造線之間的 • 部份所述間隔層, . 〜以所述第—模造圖案和所述第二模造圖案為蝕刻罩 幕,蝕刻暴露於所述凹陷區域内的部份所述缓衡層。 11·如申請專利範圍第2項所述的製造半導體裝置的 方法,其中形成所述第二模造線包括: 在所述第—模造線上方形成間隔層; 34 200822287 26022pif.doc Ο ο 在所述間隔層上形成模造層;以及 、留在所 圖案化所述模造層,使得一部份所述模造層保 述相鄰的第一模造線對之間。 .,辦_£的 12. 如申請專利範圍第π項所述的製造半^ = ^案包 方法,其中形成所述第一模造圖案和所述第二模&,f 括: 。汽,所 在所述間隔層和所述第二模造線上形成光11旦圖^ 述光阻圖案交又所述第一模造線和所述第二模遠二丄模造 以所述光阻圖案為蝕刻罩幕,蝕刻部份所述弟 線和所述第二模造線; 移除所述光阻圖案;以及 &、十、兹一媒造線和所 蝕刻部份所述間隔層,以暴露出所处弟、 述第二模造線的㈣。 ㈣制造半導體装置的 13. 如申請專利範圍第!頊所述υ二炎直 ππ離層彼此間降 > 方法,其中所述主動區域藉由戶斤 /π宗義成線形。 其中所述隔離層將各所述主動處*气装置的 14. 如申請專利範圍第1頊戶斤述的:°:=動匾威 方法,其中各所述第一模造圖案、 勒内威, 鳴於橥二多個主動^ 並且其中各所述第二模造圖案重參I' W丈 、所述第z 其中所述第二多個主動區域的彡動區域毛、於 多個主動區域的主動區域之間σ 15·如申請專利範圍第1頊戶斤 方法,其中形成所述隔離層包括: 在所述半導體基板上形成第/ 述的製造半導' 硬罩幕圖案 .装ί白勺 35 200822287 26022pif.doc 在所述第一硬罩幕圖案之間形成弟4有間t、所 述第二硬罩幕圖案與所述第一破罩秦圖二 以所述第一硬罩幕圖安和所述第二破軍狄囷木為蝕刻 罩幕,姓刻位於所述第—二罩暮_和=衫二硬罩幕圖 案之間的部份所述半導體基板以形成溝秦, 硬罩幕 案 移除所述第一硬罩幕圖案------ 16·如申請專利範圍第丨項所述的製&半‘體裴置白( 用絕緣材質填充所述溝渠;以及 /一...... 丨和所述第5. The method of manufacturing a semiconductor device according to claim 1, wherein at least one of the first molding pattern and the at least one of the second molding patterns has a major axis and a minor axis in plan view. 6. The method of fabricating a semiconductor device according to claim 5, wherein the active region extends through the semiconductor substrate in a longitudinal direction, and the long axis of the at least one first patterned pattern and The long axis of at least one second molding pattern extends substantially in the same direction as the longitudinal direction. The method of manufacturing a semiconductor device according to claim 2, further comprising forming a buffer layer on the layer before forming the first molding line. The method of manufacturing a semi-method as described in claim 7 further includes: forming the first molding line above the buffer layer, the first mold forming four buffer layer phases Adjacent to at least the opposite side of the first molding line, after the formation of the first molding line, each of the buffer layers adjacent to the at least one and the opposite side The method of manufacturing a semiconductor according to claim 8 of the invention, wherein the forming the second molding line comprises: conformal on the first molding line and each Forming a spacer layer in the recessed area; forming a molding layer on the spacer layer; and top patterning the molding layer such that at least one of the second molds, the surface substantially and at least one The top surface of the first molding line is coplanar. The method of manufacturing a semi-conductive garment according to claim 9, wherein the first molding pattern and the second molding product are formed. Included in: the spacer layer and the second Forming a photoresist pattern on the line, the photoresist pattern and the first molding line and the second molding line parent fork' using a photoresist pattern as an etching mask, etching the portion of the first molding line a spacer layer; an etching mask as an etching mask, etching a portion of the first molding line and a portion of the second molding line; removing the photoresist pattern; and the first molding pattern and the The second mold 4 is patterned as an etching mask, and the portion of the spacer layer between the first molding line and the second molding line is retained, and the pattern and the pattern are The second molding pattern is an etching mask, and a portion of the retardation layer exposed in the recessed region is etched. The method of manufacturing a semiconductor device according to claim 2, wherein the The second molding line includes: forming a spacer layer over the first molding line; 34 200822287 26022 pif.doc ο ο forming a molding layer on the spacer layer; and leaving the patterned layer to be patterned such that a portion The molding layer maintains an adjacent Between the pair of moldings, the method of manufacturing the semi-^^^ package according to the πth aspect of the patent application, wherein the first molding pattern and the second mold & And f include: a vapor on which the spacer layer and the second molding line are formed. The photoresist pattern is further described, and the first molding line and the second mold are formed by the second mold. The photoresist pattern is an etching mask, etching part of the young line and the second molding line; removing the photoresist pattern; and &, ten, a dielectric line and the portion of the etched portion Layer to expose the younger brother, the second molding line (4). (4) Manufacturing semiconductor devices 13. As claimed in the scope of patents!顼 υ 炎 炎 直 离 离 离 离 离 离 离 离 & & & & & & & & & & & & & & & & & & & & & & & Wherein the isolation layer is to be used by each of the active gas units. 14. As claimed in the patent application, the first: the first molding pattern, the Le Neville,鸣 橥 多个 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二Between the regions σ 15 · The method of claim 1 wherein the forming the isolation layer comprises: forming a semi-conductive hard mask pattern on the semiconductor substrate. 200822287 26022pif.doc forming a second between the first hard mask pattern, the second hard mask pattern and the first mask, and the first hard mask And the second ruthenium sapphire is an etched mask, the portion of the semiconductor substrate between the first and second hoods and the second hard mask pattern is formed to form a groove, a hard cover The screen removes the first hard mask pattern ------ 16 · The system described in the third paragraph of the patent application & Pei body facing white (filling the trench with an insulating material; and / and the second one ...... Shu Ο 方法,其中形成所述隔離層包栝: 在所述半導體基板上形成缓衡層; 在所述緩衝層上形成第一硬罩幕圖案,使得部份所述 第一硬罩幕層相鄰於至少一所述第^硬罩幕圖案的相對侧 面; 在形成所述第一硬罩幕圖案之後,在與所述至少一第 一硬罩幕圖案的所述相對侧面相鄰的所述緩衝層的各部份 内形成凹陷區域, 形成覆蓋於所述第一硬^幕圖案的侧壁且設置在各所 述凹陷區域内的犧牲層; 在所述犧牲層上以及在所述第〆硬罩幕圖案之間形成 弟~^硬罩幕圖案, 钱刻所述第一硬罩幕圖案上方的部份所述犧牲層; I虫刻戶斤述第一硬罩幕圖案和所述苐二硬罩幕圖案之間 的部份所述犧牲層,以在所述第二硬罩幕圖案下方形成犧 牲圖案; 36 200822287 26022pif.doc ϋ罩幕圖案為蝕刻 以所述第一硬罩幕圖案和所述弟一 π第二硬罩幕圖 罩幕,触刻位於所述第—硬罩幕®案和戶 ; 案之間的部份所述半導體基板,以形成溝尔, 以絕緣材質填充所述溝渠; 移除所述第一硬罩幕圖案和所述第 .破罩幕 案 以 Ο ο 及 移除所述犧牲硬罩幕圖案。 炎卓導體裝置的 17.如申請專利範圍第1項所述的製' 方法,其中形成所述隔離層包括·· 安· 在所述半導體基板上形成第一硬罩暮牲廣; 形成覆蓋所述第一硬罩幕圖案的侧璧的I幕^案,其 在所述第一硬罩幕圖案之間形成第二破覃^ 中各所述第二硬罩幕圖案的侧壁接觸於所述犧 " 移除所述犧牲層; ^ i内安為蝕刻 以所述第一硬罩幕圖案和所述第二破罩秦圖:墓幕圖 罩幕,蝕刻位於所述第一硬罩幕圖案和所述第/石 案之間的部份所述半導/體基板,以形成溝渠; 以絕緣材質填充所述溝渠;以及 一 移除所述第-硬罩幕圖案和所述第〉硬罩幕圖案。 I8·如申請專利範m第1項所述的製造半導體裝置的 法,更包括在形成所述層間介電層之前,在所述主動區 域上形成閘結構;以及 在所述問結構的相對側面的所述主動區域内形成摻雜 區域。 200822287 26022pif.doc 19. 如申請專利範圍第18項所述的製造半導體裝置的 方法,其中至少一所述閘結構包括第一介電層、資料儲存 . 層、第二介電層以及閘電極。 20. 如申請專利範圍第18項所述的製造半導體裝置的 ^ 方法,其中至少一所述閘結構包括閘介電層、浮閘、閘間 介電層以及控制閘極。 21. 如申請專利範圍第1項所述的製造半導體裝置的 〇 方法,其中所述罩幕圖案包括有機材質。 22. 如申請專利範圍第1項所述的製造半導體裝置的 方法,更包括: 移除所述罩幕圖案;以及 形成填充所述接觸窗開口的接觸插塞。 23. 如申請專利範圍第2項所述的製造半導體裝置的 方法,更包括在形成所述第一模造線之後,形成所述第二 模造線。 U 38The method of forming the spacer layer: forming a retardation layer on the semiconductor substrate; forming a first hard mask pattern on the buffer layer such that a portion of the first hard mask layer is adjacent And opposite sides of at least one of the first hard mask patterns; after the forming the first hard mask pattern, the buffer adjacent to the opposite side of the at least one first hard mask pattern Forming a recessed region in each portion of the layer, forming a sacrificial layer covering the sidewall of the first hard mask pattern and disposed in each of the recessed regions; on the sacrificial layer and in the third crucible Forming a hard mask pattern between the mask patterns, the portion of the sacrificial layer above the first hard mask pattern is engraved; and the first hard mask pattern and the second layer are described a portion of the sacrificial layer between the hard mask patterns to form a sacrificial pattern under the second hard mask pattern; 36 200822287 26022 pif.doc ϋ a mask pattern is etched with the first hard mask pattern and The brother-π second hard mask mask mask, the tentacles are located in the a first hard mask method and a household; The mask case is Ο ο and the sacrificial hard mask pattern is removed. 17. The method of claim 1, wherein the forming the isolation layer comprises: forming an first hard mask on the semiconductor substrate; forming a cover a side curtain of the first hard mask pattern, which forms a second break between the first hard mask patterns and a sidewall of each of the second hard mask patterns contacts the Sacrificing " removing the sacrificial layer; ^ i internal is etched with the first hard mask pattern and the second mask: a tomb mask mask, etched in the first hard mask a portion of the semiconducting/body substrate between the curtain pattern and the first/stone case to form a trench; filling the trench with an insulating material; and removing the first-hard mask pattern and the first 〉 Hard mask pattern. The method of manufacturing a semiconductor device according to claim 1, further comprising forming a gate structure on the active region before forming the interlayer dielectric layer; and on opposite sides of the structure A doped region is formed in the active region. The method of fabricating a semiconductor device according to claim 18, wherein at least one of the gate structures comprises a first dielectric layer, a data storage layer, a second dielectric layer, and a gate electrode. 20. The method of fabricating a semiconductor device according to claim 18, wherein at least one of the gate structures comprises a gate dielectric layer, a floating gate, a gate dielectric layer, and a control gate. 21. The method of fabricating a semiconductor device according to claim 1, wherein the mask pattern comprises an organic material. 22. The method of fabricating a semiconductor device of claim 1, further comprising: removing the mask pattern; and forming a contact plug filling the contact opening. 23. The method of fabricating a semiconductor device of claim 2, further comprising forming the second molding line after forming the first molding line. U 38
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