200804749 九、發明說明： 【發明所屬之技術領域】 -種熱交齡熱媒及錢用’尤細水液為級，配合熱交換器為具 有内壓，而能滿足轉載熱的強度，和明確解決環保課題。 【先前技術】 有關熱父換裝置，一般為工業用之恆溫維持裝置，或室内取暖之循環 •式油葉電暖器，其裡部轉載熱之媒體為由礦物油為之，雖然礦物油的比熱 較低而易於吸熱，但由於其油體本身黏滯係數高而不易流動，且油質受到 電加熱器的南溫鮮，常會形成統糊，而在加熱器表面形成一焦炭層 衫響發熱功率，且該油質易於劣化失去有效帶熱作用，一般使用約三年必 須重新更換，·業用者職至半年需錢換，更換後之廢關形成一大 污染問題，更容Μ漏油形成電氣短職晴物油造成火災導致人身及財 產損失。 藝 【發明内容】 本發明利財液為基材，混合改善娜為熱媒，其物理性質改善載熱 條件及相變溫度，實施於-具内壓之閉迴路式熱交換系路徑之中，更可擴 大水液相變溫度，而符合熱交換系之性能需求，並能轉載滿足熱的強度為 本發明主要目的。 本發明再-目的，係該水隸料填充有高解之餘粒子，藉由該 載熱粒子可獲得快速帶熱效果。 本發明第二目的為該閉迴路熱交換系統之路徑㈣為可接受一虔力 值，得是可產生較高内壓，而提升水液沸點溫度。 200804749 本發明第三目的為該閉迴路敏齡統之路徑空間為接受熱媒填入， 熱媒之容積比約70-85%，而預留有膨漲吸收空間。 本發月第四目的為该水液為了對抗低溫而可加熱防來劑，使降低其凝 結溫度。 依據本發明實施，可獲以下優點： 1 ·具有無污染及不燃性的安全特性。 2·拋棄時無環保回收問題。 _ 3 ·系統洩漏無環境污染問題。 4 ·因不可燃，茂漏後對於居家物品如地毯等不會有污染及助燃之 行為。 【實施方式】 *有關本發明之詳細說明，魏請參㈣！圖所示，本發明為應用在熱 父換系10 0，熱交換系10 0設有一吸熱端丄，經路徑丄〇而迴向結合 熱沉端2，熱媒3則填充於系統路徑i 〇之中’並串接吸熱端1A熱沉端 2 ’若實祕電子機ϋ冷卻系，則在熱沉端2的外端可彻風力馬達驅散 熱溫，而吸熱端1可親合發生廢熱之電子元件。 右熱交換系1〇 〇應用於室内取暖提升環境空氣溫度之加溫器，則利 用一加熱器4以對熱媒3產生熱作，加熱器4為電熱工作，由電熱裝置4 0發生熱電工作，外圍有導熱殼體41所包封。 熱父換系1〇 〇相關熱媒3填佈路徑，為具有一可抗拒内壓之容置空 間，利用其内壓對抗，則可提升水液沸點溫度，一般水液在吸熱到達1〇〇 t時則會產生相變氣化，其氣化會形成膨脹壓力，以危害到交換系統之結 構，相關水液由液態至氣態變化的一個主要條件，除溫度外，為一壓力與 沸點的關係，由克拉貝隆方程式△Ρ/7\Τ=λ/τ (V2_Vi)，其中入 6 200804749 為潛熱，丁是彿點，V2為氣態的容積比，^為液態的容積比，由此我們 了解壓力大的時候，其沸點會跟著提升，也就是在—壓力容器之下，其水 的彿點/皿度會與其壓力值的大小成正比，如是可提高上升水液的沸點溫度。 本發明實施以壓力容器之觀念，讓該水液之沸點可提升約到達l25<t， 其條件為交_統之關允許在〇· 15Mpa雜力值為前提，依據本發明實 驗’水性溶液在-大氣壓（常壓）下之沸點約⑽。C，利用密閉容器壓力為 〇· IMpa的時候’其〉弗點提★到達約12『c，而内塵設定為0· 15細，則濟點 了到達約125C ’又该彿點提尚在i25°C，則相同可受到國際安全標準见13〇 ❿C以下之規範，或歐洲IEC小於HGt以下規範，若配合歐洲之規袼，其壓 力相對可調降，使溫度在11(rc以下，該安全標準溫度為應用在室内取暖葉 片式電暖器的升溫規袼，利用該安全溫度，可適當轉載出電暖器熱量，而 緩和對室内溫度作加溫。 熱媒3填充於熱交換系1〇 〇的内部路徑空間之中，所填入之容積比 約70-85%為佳，使路徑空間預留有約15一3_靜態空間，該預留空間，則 可吸收熱媒3異常相變後膨張之體積，如環境溫度下降到其冰點以下使熱 媒3結冰時所發生之膨漲體積，或電加熱器異常工作使熱媒3溫超過沸點 Φ 相變後氣體漲壓之膨漲體積，得由該預留空間作前置性安全防護。 加熱器表面提供水液親合交遞熱能，在微小單位面積，若該點熱能集 中較高，且水液流速相對不足的情況下，親合該面積的水液會急速升溫氣 化，形成球狀氣泡，又該氣泡-切面為交割在加熱器表面而形成氣穴，本 案提供輔助解決方案如下： 水的比熱大於義油，㈣升溫慢，加熱H表面顯崎氣泡氣穴 現象。 解決方式： 1·水中加導熱粒子迅速將加熱器表面高溫帶走並加速氣泡麟速度消 200804749 除氣泡。 2·加熱器表面毛孔化，利用毛孔粗面凹凸落差結構及二點溫差，使生 成之氣泡無法穩定落置而驅離。 3·加熱器表面佈置網狀結構，糊網構線材桿身破壞氣泡結構而將之 破壞分解。 4.加熱器連動超音波震動裝置，利用震盪能量使氣泡與加熱器表面交 結部位切開位移，加上水壓及液體内聚力，而使氣泡脫離。 —般而言’加之熱交換祕，其目的為將加熱器之減快速往目 鲁的地帶放，其速率越高為佳，昔用利用礦物油有黏滯性的問題，使產生迴 流緩慢，和因緩慢可能造成管路之平流層，而中心之熱質無法與管壁或熱 沉端結構元件表面親合，失去交換功能作用。 本發明利用水液低黏滯性，則其循環速率可增加，由於速度增加，則 易於在路控中形成紊流，利用該棄流可讓管路中心之熱媒所運載熱質，易 於與週邊w合而親合管路壁面，達成管路内中心點及週邊之液體易於奮流 ’親合管壁而向外交換熱能。 • 本發明之熱媒為了改善其物理性質，在百分比的水液中，可填充約 15 5(U之改善劑’該改善劑為防腐劑或絕緣劑或乙二醇防;東劑，糊乙二 =防_可降低其凝結溫度約在_15—批，因此若應用在天寒地象的居 家環境的室内，則可避免熱媒因凍結而無法作動。 本發明進-步在熱媒3裡部填充有低比熱之健粒子，魏熱粒子為 金屬微粒或氧化物微粒，上述微粒可經奈米化使易於被水液載動，利用導 熱粒子低比熱之特性，而胁魏熱端吸熱，並藉由水液快速運送而在熱 沉端快速放送熱溫。 該奈米微粒藉由加入水溶性分散劑，從而達到使奈米微粒在水基液態 傳媒中均勻穩定分布。 200804749 熱媒3進-何姻齡為細，避錄纽可轉敎之物理性。 ’’’、乂換系1 G Q蝴熱媒3流佈之路徑為具有抗紐，在熱媒 前可操作為真空狀態或以熱態填充形成負麼，事後填佈熱媒以真空填充方 式或負職充，則可避免裡部域殘存，從而避免對熱交換器的雜、。 若如上述以真球充之實施，麵吸熱端i的㈣，需結合有一緩衝 櫃！！，該緩衝m i為吸收超額勤，避免加熱器4因電流不穩所產生 之異常狀況發生祕内㈣壓時，可作祕力之緩衝，形成異狀安全防護， 該緩衝櫃1 1進一步可設有釋壓閥i i 〇。 請再參閱第2圖所示，依據本發明實施可細在葉片式電暖器5，該 電暖器5係由多數葉片5 U排之後，上下端串通結合為分流側5工工及 集流側5 i 2 ’分流側5】丄裡部設有加熱器4，葉片導通分流側5工工 及集流側512之間，形成有管路5 2，該管路5 2為—長孔狀之截面， 設有長邊側52 1及短邊侧5 2 2 ’兩者之比例以大於等於6 :工為佳。 請再參閱第3圖所示’葉片式電暖器5係由多數葉片5 i上下結合分 流側511及集流側512所構成-循環迴路，在分流侧5 i i裡部設有 電熱作用之加熱器4 ’加熱H 4對裡部之熱媒3產生熱作，提升其溫度之 後，熱媒m經由葉片5 i所設管路5 2往上浮流，該伏流過程之動力為 由加熱II加溫作用’使物質熱應變產生伏流動態效應，藉由該伏流而達成 一冷熱循環迴流作動線。 由於水液為低黏滯性，因此在管路5 2裡部可快速通流，其快速通流 之流速則可讓路財之熱魅生紊流，錢狀Μ於接觸管路5 2之内壁 面’使該熱質與管路内壁面產生熱交換。 又路5 2 (睛參閱第2圖所示）其長邊側5 21及短邊側5 2 2 所以形成6 : 1的狀態’為_短邊側可拉近長邊_壁相對的距離，而 減低距離後’雜魏形絲流域4公絲财心说速仏内側距 200804749 離D/粘滯係數//所決定，其中若短邊侧之值較小，相對D值較小的時候， 則易於突破臨界雷諾數，使管内流易於形成紊流，依據本發明之實驗結果， 應用水液之黏滯係數相乘後，其管路截面長短邊之比為長邊側6短邊側1 (D值）為佳。 200804749 【圖式簡單說明】 第1圖係為熱交換系統圖。 第2圖係為本發明電暖器應用圖。 第3圖係為第2圖之側視圖。 【主要元件符號說明】 吸熱端·......... · · 1 路徑............10 熱交換系.........100 緩衝櫃···········11 釋壓閥··········110 熱沉端·......... · 2 熱媒.............3 加熱器............4 電熱裝置...........4 0 殼體············ 4 1 葉片式電暖器· · .......5 葉片·...........5 1 分流侧 集流側·········· 5 1 2 管路.....-------52 長邊側....... · · · 5 2 1 短邊侧· · · · ......5 2 2 11200804749 IX. Description of the invention: [Technical field to which the invention belongs] - The thermal ageing heat medium and the money use 'Ultra-fine water liquid as the grade, combined with the heat exchanger to have internal pressure, and can meet the intensity of the transfer heat, and clear Solve environmental issues. [Prior Art] The hot-family-changing device is generally a thermostatic maintenance device for industrial use, or a circulating oil heater for indoor heating. The media for transferring heat inside is made of mineral oil, although mineral oil The specific heat is low and it is easy to absorb heat. However, because the oil body itself has a high viscosity coefficient and is not easy to flow, and the oil quality is affected by the south temperature of the electric heater, the paste is often formed, and a coke layer is formed on the surface of the heater. Power, and the oil quality is prone to deterioration and loses effective heat. Generally, it must be replaced after about three years. · The user needs to change the money for half a year. The replacement after the replacement forms a big pollution problem, and even more leaks. The formation of electrical short-term clearing oil causes fire and personal and property damage. [Invention] The invention is made of a liquid substrate, which is mixed with a heat medium, and the physical properties thereof improve the heat carrying condition and the phase transition temperature, and are implemented in a closed loop heat exchange system path with internal pressure. It is also possible to expand the temperature of the liquid phase to the temperature, and to meet the performance requirements of the heat exchange system, and to transfer the heat to meet the heat intensity is the main purpose of the invention. According to still another aspect of the present invention, the water-based material is filled with a high-solution residual particle, and the heat-carrying particle can obtain a rapid heating effect. A second object of the present invention is that the path (4) of the closed loop heat exchange system is such that a pressure value is acceptable, so that a higher internal pressure can be generated and the boiling temperature of the water liquid can be raised. 200804749 The third object of the present invention is that the path space of the closed loop sensitive system is filled with heat medium, and the volume ratio of the heat medium is about 70-85%, and the swelling absorption space is reserved. The fourth object of this month is to prevent the condensation temperature by lowering the condensation temperature of the aqueous solution in order to combat low temperatures. According to the practice of the present invention, the following advantages can be obtained: 1) It has safety features of no pollution and non-combustibility. 2. There is no environmental recycling problem when abandoning. _ 3 · System leakage has no environmental pollution problems. 4 · Because it is non-flammable, there will be no pollution or combustion-supporting behavior for household items such as carpets after the leak. [Embodiment] * For a detailed description of the present invention, Wei please refer to (4)! As shown in the figure, the present invention is applied to the hot parent system 100, and the heat exchange system 10 is provided with a heat absorbing end 丄, which is returned to the heat sink end 2 via the path ,, and the heat medium 3 is filled in the system path i 〇 In the middle of the 'end heat sink end 1A heat sink end 2 ' If the solid electronic machine ϋ cooling system, at the outer end of the heat sink end 2, the wind motor can drive the heat dissipation temperature, and the heat absorbing end 1 can be in contact with the waste heat. Electronic component. The right heat exchange system 1〇〇 is applied to a heater for indoor heating to raise the ambient air temperature, and a heater 4 is used to generate heat to the heat medium 3, and the heater 4 is operated by electric heating, and the thermoelectric operation is performed by the electric heating device 40. The periphery is surrounded by a heat-conductive housing 41. The hot father replaces the 1热 related heat medium 3 filling path, which has a space for resisting internal pressure. With its internal pressure, it can raise the boiling temperature of the water. Generally, the water reaches 1 in the heat absorption. When t, phase change gasification will occur, and gasification will form expansion pressure, which will damage the structure of the exchange system. The main condition of the liquid water changes from liquid to gas, except for temperature, is the relationship between pressure and boiling point. By the Krablon equation △ Ρ / 7 \ Τ = λ / τ (V2_Vi), which enters 6 200804749 for latent heat, D is the Buddha point, V2 is the volume ratio of the gas state, ^ is the volume ratio of the liquid, from which we understand When the pressure is high, the boiling point will increase, that is, under the pressure vessel, the water point/diffness of the water will be proportional to the pressure value, and the boiling temperature of the rising water liquid can be increased. The invention implements the concept of a pressure vessel, so that the boiling point of the water liquid can be raised to about l25<t, and the condition is that the balance of the water system is allowed to be based on the 〇15 Mpa heterogeneity value, and the experimental aqueous solution is in accordance with the invention. - The boiling point at atmospheric pressure (atmospheric pressure) is about (10). C, when the pressure of the closed container is 〇·IMpa, the 'French' ★ reaches about 12 『c, and the internal dust is set to 0·15 fine, then the point is about 125C, and the Buddha’s point is still I25 ° C, the same can be subject to international safety standards see 13 〇❿ C or less, or European IEC is less than HGt below specifications, if combined with European regulations, the pressure is relatively adjustable, so that the temperature is below 11 (rc, the The safety standard temperature is the temperature rise regulation applied to the indoor heating blade type electric heater. With this safe temperature, the heat of the electric heater can be appropriately transferred, and the indoor temperature is moderated. The heat medium 3 is filled in the heat exchange system 1 Among the internal path spaces of the crucible, the volume filled is preferably about 70-85%, so that the path space is reserved with about 15_3_ static space, and the reserved space can absorb the abnormal phase of the heat medium 3. The volume of expansion after the change, such as the swelling volume that occurs when the ambient temperature drops below its freezing point to cause the heat medium 3 to freeze, or the abnormal operation of the electric heater causes the temperature of the heat medium 3 to exceed the boiling point Φ. The volume is up, and the reserved space is used for pre-security protection. The surface of the heater provides water and liquid affinity to transfer heat. In the case of a small unit area, if the concentration of heat energy is high and the flow rate of the water is relatively insufficient, the water that is in contact with the area will rapidly heat up and form a ball. The bubble, and the bubble-cut surface is formed on the surface of the heater to form air pockets. The auxiliary solution provided in this case is as follows: The specific heat of water is greater than that of the oil, (4) The temperature rises slowly, and the air surface of the H surface is heated. 1. Adding heat-conducting particles in water quickly removes the high temperature of the heater surface and accelerates the bubble lining speed to eliminate the bubble. 2008.047. The pores of the heater surface are magnified, and the pores of the rough surface of the pores and the temperature difference between the two points are used to make the generated bubbles unstable. 3. The heater is placed on the surface of the heater. The surface of the heater is arranged with a mesh structure. The wire mesh body destroys the bubble structure and destroys it. 4. The heater is connected with the ultrasonic vibration device, and the shock energy is used to make the bubble and the heater surface. The cross-section of the junction is cut, coupled with water pressure and liquid cohesion, which causes the bubble to detach. - Generally speaking, 'the heat exchange is secret, the purpose is to heat the heater Decrease the speed to the location of the target, the higher the rate is better, the use of mineral oil has the problem of viscosity, so that the reflux is slow, and the slowness may cause the stratosphere of the pipeline, but the heat of the center can not be It has a function of affinity with the surface of the pipe wall or the heat sinking end structural element, and loses the function of exchange. The invention utilizes the low viscosity of water and liquid, and the circulation rate thereof can be increased, and the turbulent flow is easily formed in the road control due to the increase of the speed. The abandonment flow allows the heat medium in the center of the pipeline to carry the thermal mass, and is easy to be combined with the surrounding wand to the wall surface of the pipeline, so that the liquid at the center point and the surrounding area of the pipeline is easy to flow, and the outer wall is exchanged. Thermal energy. In order to improve its physical properties, the heat medium of the present invention can be filled with about 15 5 in a percentage of water (U-improving agent' is a preservative or an insulating agent or ethylene glycol; Paste B = Anti- _ can reduce the condensation temperature of about _15 - batch, so if it is applied indoors in the home environment of the cold map, it can prevent the heat medium from being unable to move due to freezing. According to the invention, the heat medium 3 is filled with the low specific heat particles, and the Wei heat particles are the metal particles or the oxide particles, and the particles can be easily transported by the water liquid through the nanometer, and the heat transfer particles are low in specific heat. The characteristics, while the hot end of the heat is absorbed by the hot end, and the hot water is quickly delivered at the end of the heat sink. The nanoparticles are uniformly and stably distributed in the water-based liquid medium by adding a water-soluble dispersant. 200804749 Heat media 3 - He is a finer, avoiding the physicality of the New Zealand. ''', 乂换系1 GQ butterfly heat medium 3 flow cloth path has anti-news, can be operated in a vacuum state before the heat medium or filled with a hot state to form a negative, after the filling of the heat medium to vacuum filling or negative The job charge can avoid the residual of the inner domain, thus avoiding the miscellaneous heat exchanger. If the above is carried out with the real ball, the (4) of the surface endothermic end i must be combined with a buffer cabinet! ! The buffering mi is for absorbing excess duty, and avoids the abnormal situation caused by the unstable current of the heater 4. When the pressure is generated within the secret (four) pressure, it can be used as a buffer for the secret force to form an abnormal safety protection, and the buffer cabinet 1 can be further set. There is a pressure relief valve ii 〇. Referring to FIG. 2 again, in accordance with the present invention, the blade type electric heater 5 can be thinned. The electric heater 5 is arranged by a plurality of blades 5 U, and the upper and lower ends are serially coupled to the split side 5 for work and collection. The side 5 i 2 'split side 5 is provided with a heater 4 in the inner portion of the crucible, and the vane is connected between the diverting side 5 and the collecting side 512, and a pipe 5 2 is formed. The pipe 52 is a long hole. In the cross section, the ratio of the long side 52 1 and the short side 5 2 2 ' is preferably 6 or more. Referring to Fig. 3 again, the 'blade heater 5 is composed of a plurality of blades 5 i combined with the split side 511 and the collecting side 512 - a circulation loop, and an electric heating is provided on the split side 5 ii. The heater 4 'heats H 4 to generate heat for the heat medium 3 in the inner portion, and after raising the temperature, the heat medium m floats upward through the pipe 5 2 provided by the blade 5 i , and the power of the flow process is heated by the heating II The role of 'the thermal strain of the material produces a dynamic effect of the voltaic flow, by which a cold-heat cycle recirculation actuation line is achieved. Because the water is low-viscosity, it can be quickly circulated in the inner part of the pipeline 52, and the flow velocity of the rapid flow can make the turbulent heat of the road, and the money is in contact with the pipeline. The inner wall surface 'heats the heat mass with the inner wall surface of the pipe. Further, the road 5 2 (see the second figure) has a long side 5 21 and a short side 5 2 2 so that a state of 6:1 is formed, and the short side can be pulled closer to the long side _ the wall. After reducing the distance, the 'Wei Wei-shaped silk watershed 4 male silk coin said that the inner side of the speed 2008 2008 200804749 is determined by the D / viscosity coefficient / /, if the value of the short side is small, the relative D value is small, Therefore, it is easy to break through the critical Reynolds number, so that the flow in the tube is easy to form turbulent flow. According to the experimental result of the present invention, after the viscosity coefficient of the water liquid is multiplied, the ratio of the length of the pipeline section is the short side of the long side 6 (D value) is preferred. 200804749 [Simple description of the diagram] Figure 1 is a diagram of the heat exchange system. Figure 2 is a diagram of the application of the electric heater of the present invention. Figure 3 is a side view of Figure 2. [Explanation of main component symbols] Endothermic end ·......... · · 1 path............10 Heat exchange system.........100 buffer cabinet ···········11 Pressure relief valve··········110 Heat sink end.......... 2 Heat medium....... ......3 Heater............4 Electric heating device...........4 0 Housing············ · 4 1 Blade type electric heater · · .......5 blade ·...........5 1 Split-side collector side························ 2 Piping.....-------52 Long side.... · · · 5 2 1 Short side · · · · ......5 2 2 11