TW200800553A - Energy ray curable resin injection molding machine and a method for manufacturing a molded article - Google Patents

Abstract

An energy ray curable resin injection molding machine for forming any 2-dimemsion fine shape on a surface of a film and so on and has excellent productivity is provided. The energy ray curable resin injection molding machine 1 of this invention includes: a mold 2, a countable injection mechanism 4 and an energy ray source 6. The countable injection mechanism 4 counts the amount of energy ray curable resin then injects into a cavity 8 of a mold. The energy ray source 6 is used for irradiating energy rays to the mold. The mold includes a window 16 which forms at least a portion of the cavity of the mold and lets the energy rays pass through therefrom. The energy rays are irradiated from the energy ray source through the window to the cavity of the mold.

Description

200800553 23891pif.doc IX. Description of the Invention: [Technical Field of the Invention] - The present invention relates to an energy ray-curable resin injection molding apparatus and a method of manufacturing a shaped article, and more particularly to the use of ultraviolet light and the like Injection molding apparatus for line-hardened resin and manufacture of molded article [Prior Art] A pnsm sheet, an anti-reflection film, and a viewing angle-restricting film used for a backlight of a liquid crystal shingling device are equal to a predetermined concave-convex shape of the surface. The film or sheet (film, etc.) is supplied to the door of the drum mold and the base film having the shape of the surface of the film by the surface of the film, and the surface shape of the roll mold Continuous transfer onto the substrate_. 3) The use of the drum mold of this conventional technology: the shape of the cylinder mold extending in the direction of rotation; = "the surface, but there is the problem that the following two-dimensional opening cannot be given to the binding surface, the above two-dimensional shape refers to the Temple of the Convent Table 2 ===:=Micro-shape printing is transferred to and there is also a problem that cannot be solved. [Summary of the two sides of the 于 浔驭 etc.] The present invention provides an energy line for solving such a problem. In the case of the hardened tree pond, the molded article is formed by the method of manufacturing a molded article, which is applied to the surface of a film or the like in a fine shape, and is in terms of productivity. The purpose of the invention is to provide a "line-hardening resin injection molding apparatus and a molded article which can impart a concave-convex shape to a crucible: according to the present invention, an injection molding apparatus is provided, which uses energy. The wire is hardened, and it is mixed with the source of the energy source, wherein the metering machine is metered and then metered into the cavity (_) of the mold to make a '3' line to the above mold. Energy line; _ two Included in the window, the window constitutes at least two of the cavity of the mold: two energy lines emitted through the energy line source, and the reading is read from the upper ship line to the above cavity. The mechanism includes an opening and closing mechanism, and the opening and closing mechanism mouth, the M-spring hardening Na is emitted to the mold cavity, and the dispensing mechanism has an end surface, and the end surface is #_the above-mentioned ejection opening-position is placed in the inner surface of the cavity On the same plane. According to this configuration, a film or the like having a p-shaped shape on the surface or a film having a concavo-convex shape on both surfaces can be continuously and industrially produced. According to this configuration, since the ejection opening is closed to the same deciduous soil as the inner surface of the cavity, it is possible to prevent the filling of the H-leaf amount ejection mechanism from the start of the supply path of the cavity when the energy ray is irradiated into the cavity. The energy line hardens ς = energy line to thicken or harden. Therefore, it is possible to prevent the removal of the molded article due to the thickening or hardening of the energy ray hardening tree, or the obstruction caused by the forming operation. The energy line hardening _ is used, and: the injection molding package-fat supply path, the second/, the administration includes: the mold, the first tree, the eleventh resin discharge path, and the second rod two tree raft supply a device, and an energy 竣, a cavity of the tenth discharge path and the resin discharge mold, and the first resin supply path is connected to the supply line of the brother-tree, and the first resin supply, and the six-way internal return. The second resin "1" is supplied to the second resin #1: 'the supply discharge path communicates with the cavity of the mold, and the second resin is reciprocated in the inside of the resin, and the second resin "Road and the second _== The discharge machine grease discharge device uses a *day non-exit junction=two energy line source for the above-mentioned two f including a window, the window constituting at least the second energy source of the above-mentioned mold cavity, and the energy line emitted by the source line source = The first two of the first rod, the teeth are irradiated into the cavity of the apron, and the second rod path and the second resin supply path are two) the first resin discharge path and the upper portion; the above (4) is located at the self-combining position Keeping away from the above-mentioned mold cavity, the upper surface is the same as the surface constituting the cavity of the above mold . Shangda (4) is located at almost 200800553 23891pif.doc = such a structure, when the energy line is irradiated, the resin supply path is excluded from the first-tree supply route. When the 1st line reaches the second one, there is no step difference between the surface of the so-called "almost the same plane" and the front end surface of the rod; =?' can be peeled off without damage to the molded product; . An under-edge line and an energy line source, wherein the metering mechanism measures the amount to be in a cavity of the mold, and the line source is used to irradiate the mold with an energy line; Mold = constituting at least a portion of the mold cavity from the window and for transmitting the energy line emitted from the line source, the mold being configured to illuminate the energy line from the line source through the window to the cavity of the mold; Further included is a pressurizing device that covers a surface of the window opposite to the cavity to form a sealed space, and the pressurizing device pressurizes the sealed space. According to this configuration, it is possible to continuously and industrially produce a film which is provided with a 隹 shape on the surface, or a film which is provided with an uneven shape on both surfaces. Further, according to this configuration, since the pressurizing means is provided, it is possible to apply pressure to the window by the pressurization = toward the cavity side. Thereby, at the time of injection molding, the outward pressure of the window can be compensated by the energy ray hardening resin injected into the cavity at a predetermined pressure, thereby reducing the load on the window. According to the present invention, there is provided an injection molding apparatus which uses an energy ray-hardening resin, characterized by comprising: a mold, a metering structure, and an energy source, wherein the mold is openable and closable a mold: a metering device, the energy line hardening resin is subjected to & ^, and then emitted into the mold cavity, the energy line source is used to irradiate the mold with energy lines; and the mold comprises f, the money is at least a portion of the cavity of the mold and is used to transmit energy rays through the energy line source, and the mold is configured to illuminate the energy line from the energy source source through the cavity of the mold; The above mold is configured such that when the mold is started to be opened, one of the mold portions is separated from the split surface from the other upper mold portion. ～ With such a configuration, it is possible to continuously and industrially produce a film having a two-dimensional surface or the like, or a film having a concavo-convex shape on both surfaces. Further, according to this configuration, since the mold portion is opened, the mold portion is separated from the side of the cut surface, so that one end portion of the two molded portions is sequentially turned to the other end portion. Leave. Therefore, =U is gradually touched, so that the molded article can be prevented from being damaged. = 'For example, Japanese Patent Laid-Open No. δ 295538, or Japanese Patent Laid-Open No. Hei-14418 #u discloses a ray-shaped shape that allows the secret surface of the mold to be separated from the heat by the master; 丄I 乂曰7 force Move to open the mold. The force of gravity, above the molded article, will be subjected to very large peeling resulting in; σ: / σ damage. In particular, for example, when the silk product is in the form of a thin plate, as described above, according to the present invention, according to the present invention, an injection molding apparatus is provided, and the injection molding apparatus 10 200800553 2389lpif>d〇5 : ^ tt *,, a line hardening core (four) line source, wherein the metering injection mechanism meters the energy energy line i, = and then emits it into a cavity of the mold, the window, 'illuminating the energy line to the mold; The mold includes: illuminating the cavity with the at least a portion of the cavity of the r mold and for arranging the energy line through the upper energy source source from the body nozzle mechanism to the reduced cavity; The limb ejection mechanism is configured to supply a gas between the molded article and the mold, and the mold, so that the molded article is peeled off from the mold, and the gas discharge port is included, and the gas discharge port is used for: The inner surface is calibrated with gas and a page-out mechanism is provided. In the two-dimensional shape, it is possible to continuously and exclusively produce a film which is imparted on the surface, and which has a concave-convex shape or the like on both sides. The structure of the body and the structure of the gas ejection mechanism can be ejected from the gas jet d to the different positions of the molded article and the private product. In the second == two: the part of the separation is different, so sometimes it will be two; ί and make it into one and more ΐ 构 可 狮 gas can be stripped from the mold and the moon bf easily and reliably discharged from the mold Molded product. Knife Other preferred embodiments in accordance with the present invention are used to remove y from the mold. ^ Molded product take-up machine Holds one side end of the above-mentioned molded product: The take-out mechanism holding portion is sequentially divided from the above-mentioned mold. The core (4) faces the other side end 200800553 23891pif.doc According to this structure, the molded product take-out mechanism removes the forming port from the side end i month to the other side end from the mold, (4) = the damage is When the molded article is taken out from the mold, if the entire -a property is obtained from the "戦", the molded article is peeled off from the mold, and the molded article is not subjected to excessive force. For example, when the molded article is a thin plate which is easy to break; = outer root: other preferred aspects of Kangming, the energy line is ultraviolet light or near infrared light, short wavelength (four) visible light, and laser light. ' Its: Introduce the cavity. Γ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, The above is better. One side, better = other preferred aspects of transparency. The surface of the window on the side of the cavity is made of resin as a polyester tree. According to the present invention, the above transparent 12 200800553 23891pif.doc grease 0 In other preferred embodiments of the present invention, the transparent resin is integrated with the quartz glass plate. According to another preferred aspect of the present invention, the window constitutes at least a portion of the cavity of the mold. The window is provided with a fine structure on a surface on the side of the cavity. According to another preferred aspect of the present invention, a gas ejecting mechanism is provided for ejecting a milk from the inner surface of the mold to peel the molded article from the mold. According to another preferred aspect of the present invention, an ultrasonic vibration device is provided for vibrating the mold to peel the molded article from the mold. According to another preferred aspect of the present invention, the metering and injection mechanism includes a discharge mechanism. The discharge mechanism includes an inkjet nozzle/head. According to another preferred aspect of the present invention, the discharge mechanism is a discharge mechanism using a gas (inert gas) pressure control or a piezoelectric element. According to another preferred aspect of the present invention, the ejection orifice or the nozzle tip of the energy ray-curable resin is disposed to face the opposite direction to the energy source. According to this configuration, the tip end of the nozzle is not irradiated with the energy ray, so that the energy line irradiated to the cavity can be prevented from causing the nozzle to be clogged due to the hardening of the energy ray hardening resin in the nozzle. According to other preferred aspects of the invention, a cleaning mechanism for cleaning the cavity of the mold is included. According to another preferred aspect of the present invention, the mold is a mold that opens and closes in the up-and-down direction, and the metering and injection mechanism is configured to inject the energy line from the direction of the mold opening and closing unit 13 200800553 23891pif.doc. of. Produce = such a structure, which can inhibit the opening of the mold due to resin injection, according to the present invention

In a plurality of sections, it is possible to efficiently produce a molded article by simultaneously projecting a plurality of formed knives to J = b kinds of structures. Surface ~ Other preferred aspects, the energy source is a UV lamp having a peak wavelength of illumination. The pulse is otherwise similar in that the energy line source is a short-acting hardenable resin that does not raise the temperature of the mold. He is better in setting up the optical system, the optics =:=; = energy line concentrating, diffusing or collimating. The machine pushes the % sample and sets the solid (four) structure, which is fixed on the surface. The substrate film having the fine structure is simply fixed to the other preferred embodiment of the mold, and the window constitutes the mold opening knive, and the fine structure is formed on the surface of the window on the cavity side and the inner surface of the window. . She has at least a part of the other difficulty in accordance with the present invention, which is formed on the surface of the above-mentioned window on the side of the cavity. ... Hai is,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, On the surface, the fine resin layer 'this fine structure is formed by thermal polymerization first casting polymerization. According to another preferred aspect of the present invention, at least a portion of the chamber is provided with a layer of energy-hardening transparent material that is fabricated on the surface of the window on the side of the cavity, the micro-transfer Come. ~Street error according to the core _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ According to this structure, when the mold is opened, the molded article is easy to produce. According to another preferred aspect of the present invention, the window constitutes the mold portion, and the transparent resin layer containing the release agent is formed on the surface of the window on the side of the cavity. . According to this configuration, when the mold is opened, the molded article is easily improved in productivity. In accordance with other preferred aspects of the present invention, the student includes a pair of electrodes configured to lose the mold cavity and to face the thickness of the cavity. In accordance with other preferred aspects of the invention, one of the electrodes is a transparent electrode disposed back to the window. According to other preferred aspects of the invention, a pair of electrodes are included to fit the cavity of the mold and to the width direction of the cavity. ...弋 15 200800553 23891pif.doc «In other preferred aspects of the month, the energy source is a UV lamp that produces a pre-ecologically ultraviolet light. Between the house and the king; or === the state of the above-mentioned energy line source and the edge of the window is better:! 'The above inkjet nozzle / nozzle - line hardening resin on the top (four) = _ look amount gradually coated The cloth energy metering includes a precision = two:;!;:, the mechanism-side moves relative to the mold, the cavity. ― Qian gradually coated energy line Wei resin in the above mold: ϊΐΐ, :: 1: can be used to continuously supply the energy ray hardening resin to the shape ϋ Γϋ I _ (4) 1 " ^ continuous line _ injection into the shape of the fine shape is good In the f3 dimension or on both sides, according to other aspects of the present invention, there is provided a mouth, a raw: "diffuse and extraction step, wherein the injection step is to harden the energy line by using (the above resin supply device) Ejecting in a cavity, the hardening step is an energy line that illuminates the fat toward the window to harden the energy line. The energy line is hardened. 16 200800553 23891pif.doc According to the fat injection molding device of the present invention having such a structure, the beer can be _A, According to the invention, the resin injection molding apparatus can harden the ft: seed energy line. The present invention is applied to both sides of the binding film or the like. [Embodiment] Hereinafter, the present invention will be described with reference to the accompanying drawings. The outline of the grease injection molding apparatus 1 is that the k-hardened tree is formed by forming a predetermined concave surface on the injection molding surface. An injection molding apparatus for injection molding apparatus 1 film or the like, a film or a sheet of a film (a film used for a thin backlight, an antifouling sheet, a film made of a liquid crystal display device, etc.) 1. an antireflection film, a viewing angle The injection molding apparatus 1 includes: a mold 2, a line source 6 , wherein the metering and injection mechanism 4 uses the machine f4 and performs counting to irradiate the energy line to the 2 shot reading hardening resin. The mold 2 is configured to include; :6: The fixed type and the reciprocating type which are made of metal to the mold 2 are made into a cavity 8 which can correspond to the fixed ❹ f. The forming and forming of the present embodiment can be formed. The shape-making light #, 、, j injection molding apparatus 1 is a garment for a thin plate shape, and the cavity 8 has a thickness of 30 _ to a surface _, that is, the thickness of the manufactured cavity 8 can be destroyed as follows. 17 200800553 23891pif.doc The thickness of the film is equal to or less than 200 _, or less than or equal to 1 〇 spleen, or less than or equal to 60 μπι. The metering injection mechanism 4 includes a runner 1 〇, and a spit out j 12" sump 10 is a way in which one end is connected to the cavity 8 In the tamping type 2a rain arrangement, the discharge device 12 is configured to supply a predetermined amount of energy line hardening tree lining to the other end of 1Q. Further, the injection device of the present embodiment is configured to The flow cell 1α is disposed in such a manner as to extend parallel to the moving direction of the movable pattern 2b, so that the energy line hardening is not emitted into the cavity 8 in a manner parallel to the movement and movement direction of the moving type. The month b reading source 6 is configured to be self-fixed. The opposite side of the type ^

Can Wei. In the present embodiment, the energy ray source 6 uses an energy line having other illuminance =: and = or other energy lines with a U 2 T =: resin type or the like having an emission peak wavelength in the range of 35 (^ field: > nm) Source 2' has a laser, such as Α, sub-laser YAG laser (532 nm). _), =, energy line source 6 can also be a UV source that transmits short pulses. A system can also be provided between the energy source 6 and the mold 2 for enabling the energy source from the energy source source 6 to be on the energy line of the mold 2 to be placed on the opening. The quartz glass plate Ιδ, and is used to guide the energy line from the energy source source 6 to be solid. The quartz glass plate 16 forms part of the cavity. , the cavity 8 opening 14 of the " and the quartz glass plate 16 are set to π ^ to the following dimensional shape, that is, 18 200800553 23891pif.doc The energy line from the energy source 6 is emitted to the cavity 8 _ energy line stone! hardening. A fine structure transfer mold 18 is attached to the cavity 8 on the side of the fixed type 2a facing the quartz glass plate 16 described above. Fine structure transfer mold month = a fine structure spacer member is formed on the surface, and the sand structure has a shape in which the if = to the fine structure of the molded article is complementary; and the λ is finely formed toward the cavity g side. It is configured such that a plurality of waters are placed under the fine structure transfer mold 18, and the ceramics 2 are maintained at a predetermined temperature. Further, a shutter for opening and closing the end of the cavity 8 side is provided. Further, in the split surface of the solid jia and the movable type 2b, the straight through is less than or equal to 10 _ , and the Putian vent 24 〇 has the structure of the injection job i + , and the _ mold 2:: After the energy line hardening resin is injected into the apparatus from the metering and injection mechanism 4, the claw lamp of the line source 6 is activated for a predetermined time, and the energy line hardening resin in the = 8 is hardened to form a cavity δ shape. Product. Thereafter, the mold 2 is opened, and the molded product is taken out from the mold 2. In the same manner as in Fig. 1, the forming device of the forming device 6 is formed in the same manner as in Fig. 1, and the change of the injection molding device 1 of the first embodiment shown in Fig. 1 is shown. The structure of the injection molding device 26 is basically different from that of the injection molding device, and is different from the injection molding device i in that a fixed type such as a gas supply path 28 opening to the cavity 8 is formed. The diameter of the gas supply path % is preferably set to be less than 10 μη!. > Before the main energy line hardening resin, when the mold is opened from the gas supply path 28 to the cavity 19 200800553 23891pif.doc, the cavity 8 can be cleaned, and the body can be easily whitened. The gas supply path 28 supplies a gas such as an inert gas = self-solid & type 2 & Fig. 3 and Fig. 1 show a forming apparatus 30 in the same manner as in Fig. 1. The structure of the injection molding apparatus 1 according to the second embodiment of the present invention is basically the same as that of the moving type 2b. The difference from the injection molding apparatus 1 is that 10, the energy line hardening is orthogonal to the extension, and the flow channel is arranged to be ejected into the cavity 8 to be orthogonal to the moving direction of the movable type 2b. Injection molding agency. The Hrb end is provided with a tapered piston_mechanism as shown in Fig. 4, and the flow cell is the same as Fig. 1 before Fig. 5, and the figure 4 is a drawing of the forming device 34, and the injection molding of the third embodiment is not shown. The apparatus 1 is identical in construction, and the structure of the forming apparatus 34 is basically different from the injection of a plurality of sheets which can be simultaneously formed into a thin one, in that the mold 18 is transferred. The method consists of having a cavity 8 and a fine structure forming a snyr. 4 The injection molding apparatus 1 of the embodiment has a structure in which the transparent energy ray-hardening type is disposed substantially on the bottom surface of the cavity 8 of the ground soil and the solid cavity side opposite to the slanting plate. The inner side (the empty shape is given to the mold 42 and the like. The fine formation of the I 3 material layer is as shown in Fig. 6 and is configured as a fixed type in which the injection molding is performed. 20 200800553 23891pif.doc A plurality of openings are formed in the cavity 8 The suction passage 38 is connected to the suction device (not shown) to connect the transparent substrate 40 disposed on the bottom surface of the cavity 8 on the fixed type 2a · side to the cavity 8 . Further, in the injection molding device 36, the bottom surface of the cavity δ is not provided with the micro-fine structure transfer mold 18. Further, in the injection molding device 36, the cavity 8 of the quartz glass plate π constituting the window The side is provided with a fine shape imparting mold 42 made of a transparent resin. • The fine shape imparting mold 42 is made of a transparent material (for example, a crosslinkable resin material, PMMA (p〇lymeihyl Methacrylate) with respect to an energy line from an energy source. Formation of poly(mercapto methacrylate) and polyoxyalkylene a thin plate-shaped energy ray-curable transparent material layer having a thickness of about 1 mm to 2 mm, wherein the surface is processed into a concave-convex shape that is complementary to the shape imparted to the molded article, and the surface on which the uneven shape is formed faces the cavity 8 side , the glass plate 16 on the 〇, :: (4) 42 can be a fine structure on the transparent resin, or can be a transparent resin on the shape of the second ... or the casting of the fine structure formed by the light casting. 42 can also be hard-coated on the surface. After 2::,, _ set 36, first, in the open mold embedded t = on the bottom surface of the fixed lake, configure the self-suction bow dark road 38; ^ = 纟The transparent substrate is formed by the bottom surface. 'The transparent substrate 4 is adsorbed _ in the cavity δ, k and the work tool 2 is used, and a predetermined amount of energy ray hardening resin is self-calculated 21 200800553 23891pif.doc After the cavity 8 is injected, the lamp of the energy source 6 is operated for a predetermined time. At this time, since the fine shape attached to the quartz glass plate 16 imparts energy to the mode 4, the energy from the energy source 6 is transmitted. The wire will illuminate the energy line hardening resin in the cavity 8 so that the cavity 8 is inside The energy line is hardened and hardened to form a molded article conforming to the shape of (9) 8. Thereafter, the opening and lowering of the right holder 2' is stopped from the yam bow|fusible from the mold 2. The suction of the guide passage 38 causes the molded article to be formed by injection molding. In the molded article formed by the placing 36, a shape in which the concave-convex shape of the transparent tree-shaped providing die 42 is complementarily provided on the surface of the substrate 4〇3 φ is embedded in the same surface. The drawing of the first molding apparatus 44 of the present invention. The injection molding apparatus is different from the injection molding apparatus 1 in that the line source 6 of the movement penalty and the transparent female garment of the molded article are attracted by the attraction of energy. _ is set on the quartz panel ^6, the rigid 丨 passage 46 is the same as Fig. 1 and is a table forming device r. The _-shaped device 丄 6 is provided with a fine shape 2 on the surface on the cavity side. According to the injection molding die 18 having the above-described structure and the fine shape field 48 made of a transparent resin, the Shihwa glass plate is finely configured on both sides of the transfer product, so that the capsules 41 are disposed on the both surfaces to form a film 41, respectively. . "The molded article of the book structure (film diagram 9 and figure shows the transformation of the shape of the square) 22 200800553 23891pif.doc The pattern of the forming device 5G. The difference between the injection molding device and the shot is that A cavity 8 for holding the mold 2 is disposed, and an electrode is disposed. - As shown in FIG. 9, the surface of the quartz glass plate 16 on the side of the cavity 8 is connected to the DC power source 52 and serves as a towel. —Electrical=pole M, metal fine structure transfer mold attached to fixed Wa ^ ^ Power supply 52 is connected at the other end to form another electrode. Transparent electrode ^ / 丨 insulation edge member 55 is mounted on mobile type 2b Further, the fine green mold 18 is also attached to the fixed type jaws via the insulating member 55. Therefore, the injection molding apparatus 5〇t is provided with a cavity for holding the mold 2 and a thickness direction of the cavity 8 ((4) film A pair of electrodes 54 and 18 arranged in the thickness direction of f. According to the injection molding apparatus 50 having such a configuration, for example, (4) resin («树系列) has a large molecular weight line hardening tree as the energy Line hardening, after the energy beam is hardened to ^ 8 In the front or the _ process, an electric field is applied to the energy ray hardening resin in the space of 8 by the electrodes, whereby the energy molecules are aligned in the thickness direction of the film or the like as a molded article, and the product is scheduled to be opened. The optical performance of the present invention is the same as that of the eighth embodiment of the present invention. The injection molding apparatus % and the injection are the same, and the same is that the amount _ 6 and ; The polarizing film 58 is disposed in accordance with the injection molding device 56 having such a configuration, and is polarized by using a polar energy ray-curable resin such as a gas-based energy-hardening tree-shaped polarizing film 58 such as a gas-based tree 200800553 23891pif.doc. The energy line is applied to the energy line hardening tree wax-injection, which can make the molecular alignment of the energy line hardening resin to give J', , predetermined optical properties, etc. It can also be configured as a polarizing thinner. The ' ' 使 能量 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Forming device _ type. The difference between the molding apparatus 60 and the injection-out is the structure of the metering and injection mechanism of the energy ray-curable resin. As shown in Fig. 1, in the injection molding apparatus 6G, the metering-discharging apparatus is mounted on the movable type 11. The inkjet nozzle 64 is configured to supply the hardened resin supplied from the Uv hardened tree moon box to the cavity 8 of the right holder 2. The inkjet stomach 62 Μ 64 has a discharge mechanism, and the discharge is performed. The mechanism uses air pressure (for example; inert gas such as gas or nitrogen) or piezoelectric element. For example, in the injection molding device 60, the 喰 趣 ^ ^ is oriented in the opposite direction to the energy source 6 . The earth white and the mouth are provided at the ends, and in the injection molding device 60, the lens 68 is disposed between the ends. H7 and Mold 2 Figs. 12 and 13 are views showing the first device 69 of the present invention. The injection molding device 69 has a similar structure for injection molding, and the injection molding device 6Q and the injection molding device on the movable type 2b side of the injection molding device 60 are moved along the ==, that is, as shown in Fig. 12 As shown in the figure, the UV-curable resin case 70 and the crucible 74 which constitute the measuring device of the 200800553 23891pif.doc injection mechanism are moved along the fixed type 2a, and the amount is gradually fixed by the amount 2a. A precisely metered energy ray hardening resin 76 is applied to the surface. The energy line of the sewed cloth is hard-boiled 7 : After flat = expands. After the soil, the ten main land is the energy line hardening tree, which will be transferred and cut, and the mold will be moved (Fig. 13), and then the energy source source 6 = moon 匕 [line (10)) will be used to harden the cavity 8_ energy line hardening resin. . At this time, in order to prevent overflow from the mold, the viscosity of the energy-hardening resin is ~100°C, preferably 5 cp~5〇〇cp, and better early, ',, cp.疋10 cp~1〇〇 of the p text pair, the thickness of the energy ray hardening resin coating layer is less than or equal to, preferably less than or equal to 100, more preferably less than or equal to ^ _, and secondly, for the eleventh implementation The injection molding apparatus fT of the form. Figure Μ shows the U-th embodiment of the present invention (four); A plan view of a schematic structure of a mold or the like of 110, and a cross-sectional view taken along line -XV of Fig. 4 is shown. Further, Fig. 16 is a cross-sectional view taken along line XV of Fig. 14 and Xνι, and Fig. 17 is a cross-sectional view taken along line χνπ - χνιι green f V I in Fig. 14. The spoon-fixing & B injection molding apparatus 110 includes a mold 112, a metering and injection mechanism, a line source 116, and a gas supply mechanism 117, wherein the metering and injection floor 4 is used to measure the energy ray-hardening resin. This is configured in the mold ii2, and the energy source Πό has the same configuration as that of the first embodiment for the injection mold 112 to irradiate the energy ray, and the gas supply mechanism 117 is for supplying gas between the mold 200800553 23891pif.doc and the molded article. The mold 112 is composed of a pair of openable and closable metal-fixed type 118, and a neighboring knife. The mold-moving type m is relatively difficult to shape between the mold 118 and the movable type 120 as shown in FIGS. 16 and 171. The puller 112 is configured to be solid 122. The cavity corresponding to the shape of the 7-piece molded product is shown in Figure 15.

The end portion is slidably attached to the fixed type by the parallel/close-up (the contact surface of the type 12 )) of the inner side of the 112-port type 118 with respect to the mold. :? 4:;: A direction A heart soil u b Also, at the end of the fixed type 11 g on the other side, the upper and lower musk, the door - ^ screw inspection 125 is installed. An opening 126 is formed in the movable type 120 extending from the upper and lower sides, and a quartz glass plate 128 having the same structure as that of the first embodiment is attached to the opening (3), and the quartz glass plate 128 is formed to be used for The energy source and the 116# can be introduced into the window of the cavity 122. Second, on the surface of the fixed type 12G and the quartz glass plate 128 on the side of the cavity 122, the micro-machining of the shape complementary to the surface shape of the molded article is performed as needed. The cavity 122 includes a rectangular thin plate-shaped forming portion and a pair of flow groove portions 131, wherein the molding portion 130 has a shape corresponding to the shape of a molded article such as a cymbal sheet, and the pair of flow groove portions 131 communicate with the forming portion 130 and are thicker than the forming portion 13 The pair of flow groove portions 131 are arranged to extend along the total length of both sides of the rectangular shaped portion 13 (FIG. 16). 26 200800553 23891pif.doc As shown in FIG. 16, the metering and injection mechanism Π4 includes a resin supply device 115 and a resin supply. The road 132 and the discharge path 134, wherein the resin supply unit 1 = for supplying the energy line hardening tree into the cavity, and the resin supply path 132 is for connecting the resin supply device 115 and the cavity 122, and the discharge path A discharge device (not shown) for connecting the cavity m and the suction device. The tree, the supply path 132 has a substantially L shape, and is coupled with a horizontal portion 132a (second resin supply path) and a vertical portion 13 (first resin supply) In the second direction, the horizontal portion 132a extends from the second surface of the self-fixing type 118 in the horizontal direction, and the recording portion 132b extends upward from the end of the horizontal portion. The upper end of the vertical portion mb is formed with an exit pupil, and the ejection opening is opened to The center of the flow groove portion 131 is substantially in the longitudinal direction. The squirrel discharge 4 134 is roughly in the shape of a l-shape, and is combined with a horizontal portion 13 such as (second tree turn-out path) and a vertical portion (10) (first-resin discharge path horizontal portion 134a is The horizontally self-fixing type 118 (four)-side extension 'vertical portion 134b extends upward from the end of the horizontal portion. The upper end of the vertical portion 134b is formed with a discharge port 138 which opens substantially the center of the longitudinal direction of one of the launder portions 131. = = such a structure, when injection molding, first, to the thick-walled trough portion / two fat filling, and then, the self-flow trough portion 131 to the thin plate-shaped forming portion, so what is the general line of hardening tree The grease is quickly and evenly introduced into the seesaw shape forming portion 130. The through hole 14Q and the through hole are formed in the port 3L 118, and the extension line of the vertical portion 132b of the supply path 132 is formed, and the passhole hole 42 is on the discharge path 138. The extension of the vertical portion (10) 27 200800553 23891pif.doc The long line extends downward. The through holes 14Q and M2 are substantially the same inner diameters of the portions 132b and 134b., hundreds, and straight. "The rods 144, 146 are disposed in the through holes. The rod 144 and the tearing have the same as the fox UG, 142, and the like, and the movable surface can be moved between the upper green and the lower green by not shown. * The cup 144 is configured such that, in the upper position, the invading resin is supplied to the vertical portion (10) of the road to close the resin supply path 132, and the upper end surface 148 is in the basin.

The bottom surface of each of the launder portions 131 is a _ surface, and the trowel which forms the inner surface of the cavity 122 is placed at a lower position. As shown in Fig. 16, the upper end surface 148 is located at the lower end of the vertical portion 132b of the resin supply path 132. Therefore, the rod 144 is movable between the upper position and the lower position, which is almost the same plane as the inner surface of the cavity 122, and the lower position is the merged position of the horizontal portion 132a and the vertical portion 132b. Further, the rod 146 is configured to enter the portion 134b of the discharge path 134 at an upper position to close the discharge path 134, and the upper end surface 149 and the bottom surface of the other flow port 131 are formed as one surface, and constitute a part of the inner surface of the cavity 122. In the lower position, as shown in Fig. 16, the upper end surface 149 is located at the lower end of the vertical portion 13 of the discharge path 1/4. Therefore, the rod 146 can reciprocate between the upper position and the lower position, the upper position is almost the same plane as the inner surface of the cavity 122, and the lower position is the confluence position of the horizontal portion 134a and the vertical portion 134b. Furthermore, the lower positions of the rods 144, 146 are not limited to the confluence positions of the horizontal portions 132 =, 134a and the vertical portions mb, mb, and only the horizontal portions i32a, 134a and the vertical portions 132b, 134b 28 200800553 23891pif. Doc (4) 吉 =, so for example, the upper end faces 148, 149 are located at the lower end of the vertical portions mb, 134b of the rudder, further away from the cavity 122. The air supply mechanism 117 is configured to pick up the self-fixing type 118, and to recognize that α and 々 are easily taken out from the mouthpiece, and the molded product is hardened and then supplied to the fixed type 118; As shown in Fig. 17, the gas supply means u7 is supplied to the supply path 15A, and the gas supply path 15G is for connecting the breast supply device (not shown) and the cavity 122. (4) The supply path 15Q has a substantially L-characteristic position including a horizontal portion. The two straight portions are 15Gb. The horizontal portion l5Ga is self-fixed in the horizontal direction. The second side is extended. The vertical portion is 15% from the end of the horizontal portion toward 1°5]. 15% of the vertical portion is formed with a gas outlet gas blowing π 151 opening at a substantially center in the longitudinal direction of the flow channel portion 131. As shown in Fig. 14, the gas supply device 11 of the present configuration is provided on each flow groove portion m. 4 gases are blown out "51 openings. The preparation gas supply mechanism 117 further includes a 1 154, wherein the ejector valve 152 is disposed in the ejector pin W 罝 乳 乳 乳 乳 供给 b 150b, and the ejector pin 154 is disposed on the top 屮 R 1 ς〇 AA, The lower portion of the outlet valve 152 is used to push the ejection valve 152 up into the cavity 122. The head of the ejector valve I52 is housed in a head housing formed in the upper portion of the gas supply port, and the shaft portion is housed in a shaft passage 158 disposed below the head accommodating portion 156. i 隹 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石 石The surface of the trough portion 29 200800553 23891pif.doc becomes a surface, and the upper position is that the head protrudes into the trough portion 131. By the self-disposing the compressed spiral elastic 153 between the ash outlet valve 152 and the fixed type 118 The ejector valve 152 is pressed downward. The groove on the outer circumference of the 1d2 shaft portion extending in the axial direction is formed so that gas can flow between the shaft passage 158 and the shaft portion. The operation of the injection molding apparatus n〇 of the present embodiment will be described. Fig. 18 to Fig. 23 are diagrams showing the operation φ of the injection molding apparatus 11Q of the present embodiment. First, as shown in Fig. 18, the fixing of the mold 112 is closed. The rods 144 and 146 of the type 118 and the movable type 120' metering injection mechanism Π4 are disposed at the lower position. Therefore, the resin supply path 32 and the discharge path 134 are opened, and the cavity 122 communicates with the resin supply device 115 and the discharge device. Each ejector valve 152 is also disposed below In this state, the energy ray hardening resin is supplied from the resin supply device 115. The energy ray-curable resin enters the cavity 122 through the resin supply path 132. The inside of the cavity 122 is sealed, and while the discharge device is actuated, The energy nematomycin hardening resin is supplied into the cavity 122. The supplied energy ray hardening resin first fills one of the launder portions 131' and then flows into the forming portion 130. The cavity 122 is filled with the energy ray hardening resin, followed by the cavity 122 The inside air or the release gas or the like is discharged from the cavity 122 via the #出路路134 by the extrusion of the energy ray-curing resin and the suction of the discharge device. When the entire cavity 122 is filled with the energy ray hardening resin, such as Figure 19 shows 'moving the discharge side rod 146 to the upper position to close the vertical portion 134b of the discharge passage 134 30 200800553 23891pif.doc. At this time, the upper end surface of the rod 146 !49 and the other flow/groove portion 131 The bottom surface becomes a face, constituting a part of the inner surface of the cavity 122. Further, the resin supply device 115 continuously supplies the inner wire to the cavity 122 until the pressure in the cavity 122 reaches When the energy line hardening resin in the cavity 122 reaches a predetermined pressure, the supply of the energy ray hardening resin is ended, as shown in Fig. 20, the resin supply path side is moved to the upper position to close the resin. The supply path 132. At this time, the upper end surface 148 of the rod μ# • and the bottom surface of one of the flow groove portions 131 become one surface, constituting a part of the inner surface of the cavity 122. Then, the energy source 116 is actuated to pass through the quartz glass plate 128. The energy ray hardening resin is irradiated with an energy ray to harden the energy ray hardening resin, and a molded article ln having a shape corresponding to the shape of the cavity 122 is obtained. The molded article ln is composed of a thick portion ΠΙΑ and a thin plate portion 1ΠΒ, and the thick portion niA is formed by the flow groove portion 131, and the thin plate portion 111B is formed by the formed portion 13〇. Before the irradiation of the energy ray, the energy ray hardening resin in the vertical portion 132b of the resin supply path 132 and the vertical portion 134b of the discharge path 134 has been removed by the rods 144, 146, so that the energy line is not sufficient after the irradiation of the energy ray. Unhardened energy ray hardening resin remains in the arriving vertical portions 132b, 134b. Further, since the injection port 136 is closed by the upper end surface 148, it is possible to prevent the energy rays from entering the resin supply path 132. As a result, it is possible to prevent the uncured energy ray hardening resin remaining in the vertical portions 132b and 134b from being viscous or hardened, which hinders the removal operation of the molded article and the next injection molding operation. When the hardening of the molded article 111 is completed, the mold is opened. Specifically, 31 200800553 23891pif.doc pushes the front end of the bolt 125 of the fixed type 118 upward so that the shifting is centered, and the moving type m is reversed with respect to the solid (four) 118 = the shaft 124 120. Therefore, when the mold is started to be opened, the movement: 12; the 吏 moving type cutting plane - the side slanting - the side is separated from the fixed type 118. ▲ With respect to the result, the one end side of the shaping 118 is sequentially performed in the operation of opening the mold in this manner. Basin, self-solid 122 Π1: away. Therefore, in comparison with the case where the movable type 12 〇 is moved in the seat =: ? and the mold is opened in order, the force on the square of the face can be large. Therefore, it can be added to the molded product 111 m in the Dianchi. In the process of arranging the warfare, the sheet-shaped forming is not broken. The above-mentioned structure is not limited to the movement type relative to the fixed type, and the following structure is used: only the moving type material is -, 4', for example, may also be plucked, and then the moving type is moved to the upper predetermined high-motion type with respect to the mode division, and the modulo*splitting*orthogonal (four) field=slope 'below' is shifted out. * When the mold opening is completed, the molded article Ul is taken from the fixed type ι 8 first, and the gas is supplied between the groups (10) by the gas supply mechanism H7. Specifically, the product (1) and the stationary gas are actuated via the gas supply path 15 body supply means to counteract the pressure, and the pressing force of the coil spring 153 pushes up the groove of the shaft portion 152. Thereby, the heads of the top _ 152_ and _ 152 form a gap between the 丨/ and the port type 118, and the gas is supplied from the gap to the flow groove portion 131 of the molded article u. Therefore, the gas;; = self-fixed type 118 is peeled off and floated. As shown in Fig. 22, the gas is continuously supplied to the ejector pin 154, and the ejector valve 152 is moved to the upper position. Thereby, the head of the ejector valve is further protruded to the cavity 122, so that the molded article (1) = the soil port F 111 Α is completely peeled off from the fixed type 118. In this case, since the gas is continuously supplied from the gas supply path 15〇, the thick portion 111Α is not peeled off. Here, the discharge of the gas and the pushing of the ejector valve 2 are performed on the back surface of the molded article (1) mA. Therefore, the supply of the gas and the squirting of the valve 152 cause the molded article i i 1 to be broken. After the thick portion 111A of the molded article 111 is peeled off from the fixed type 118, the molded article is taken out from the fixed type 118 by the molded article carrying mechanism 160 provided in the injection molding device 12 as shown in FIG. The molded product feeding mechanism 160 includes a plurality of adsorption pads 162, and the adsorption pads 162 are arranged at predetermined intervals along the longitudinal direction of the cavity m flow groove portion 131. In the molded article transport mechanism 160, one of the molded articles lu is sucked, and the adsorption pad 162 of the wall portion 111A is gradually moved upward, whereby the thin plate portion 111B of the molded article 111 is peeled off from the surface of the fixed type 118 from the end portion in order. The molded article ill is taken out from the fixed type 118. When the molded article 111 is taken out from the fixing type 118, the molded article 111 is peeled off from one end to the other end in the same manner as the open mold. Therefore, the force applied to the molded product lu can be prevented from being large to prevent the molding. The thin plate portion 111B of the product 33 200800553 23891pif.doc ill is damaged. In addition, the molded product conveyor; ^ cover; fr both ends. In this case, the two f at both ends are held by the molded article m, and the molded article is moved toward the mechanism from the respective end portions, and finally the center portion is peeled off. The end portions on the opposite sides of the X 2 are peeled off in order, and the end portion of the product phase = the removal port formed by the above method can be taken out and transferred. The molded article of the desired shape is cut into a lower portion, and the man is cut. The human is used to describe the injection white color of the embodiment of the present invention. Fig. 24 is a view schematically showing a side cross section of the forming device 164 according to the twelfth embodiment of the present invention. As shown in Fig. 24, the radiation, the opposite side of the cavity, and the movable rock pressure have the same configuration as that of the third embodiment. In the following, I will tell you how to do it. In the injection molding apparatus 164, a pressurizing chamber is formed on the rear side of the movable type 12 (on the side opposite to the cavity 122). That is, as shown in Fig. 24, the box-shaped sleeve 166 is connected to the rear side of the movable type (0 (opposite side to the cavity 122), and a privileged space 168 is formed therein, and the sleeve 166 covers the quartz glass plate 128. The end face on the opposite side of the cavity 122. In the sealed space 168, the inside is pressurized to become a pressurizing chamber, i.e., the gas supply pipe 170 attached to the casing is supplied with pressurized gas from an external pressurized gas supply device. In the present embodiment, the energy ray source 116 is housed in a sealed space (pressurizing chamber) 168. This structure is added to the quartz glass plate 34 200800553 23891pif.doc 128 from the back side (opposite to the cavity), so that the pressure of the resin in the cavity 22 can be connected according to this structure. Again, point. Here, when using the heart = more vermiculite central glass (four) plate 128 and other excellent flexibility 1 using the #128 ·, quartz glass will produce 128 to the side of the light source to bend:, in the seventh, give the resin, make quartz glass (4) (4) Corresponding to the supply amount of the molded product of the hard line (can) of the energy ray hardening tree, the amount of the product of the hard line can be obtained after the hardening, and the second t-shaped injection of the present invention is obtained. In the form of forming a f-shape, the needle forming device is used. In the above description, a film or the like which is a molded article of the present invention manufactured by the injection molding apparatus of the above-described fourth embodiment will be described. The shape f 25 of the crucible is a partial plan view manufactured by the injection molding apparatus of the embodiment, and FIG. 26 is a thin section of the film having a thickness of several lines, and the film 78 is a checkerboard pattern. Μΐη~〇] The interval between wide 0 is about 10 arrays ~ 〇.05 _, preferably 5 _ 'better is 1 μηι~〇·2 μπι. In the injection molding apparatus of the solid surface 11, the above-mentioned _78 burial is manufactured by mutual production, that is, the fine structure transfer mold 18 which is provided with a fine structure by using TM, or a fine shape can be used because the downward refractive index is gradually increased. The characteristics of the reflective film. Moreover, since the surface is hard to adhere to dirt, it can also be used as a water repellency _ ϋ film to improve water repellency and antifouling properties. w卄中3 has a rat resin, - the work is the root of the money _ (four) Cheng Qing set the report as a molded article, another example of the film 82 part of the stand clothing - 1 as shown in Figure 27, fresh The film 82 has a regular shape or a square pyramid with a pitch of 1 μm to 100 μπι. .i shouted the secret film. The projection assumes that the apex angle of the quadrangular frustum of the projection 84 is 40 degrees to 2 G degrees, more preferably Q 3 Q degrees to 25 degrees. 5 () degrees ' rare 乂 rainbow tablets. The film 82 can be used as a backlight mechanism for a liquid crystal display device or the like, and by making the inclined surface of the protrusion 84 a rough surface, it is also possible to limit the use of _. The surface roughening method can be made by the H method or the like: the pre-neuro fine structure transfer mold 18 or the fine nucleus 41 is roughened corresponding to the surface of the inclined surface.纽 28 28 is a part of the plan view of the other example 稜鏡 . 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 86 As shown in Fig. 30, the cymbal piece 86 is arranged side by side on the entire back surface: a triangular columnar cymbal 88 extending in the direction of the mouth opening, and its end side portion in the longitudinal direction of the surface is arranged side by side from the end to the other side. The two-pointed pyramid 9 0 is extended. It is preferable that the side surface or the valley portion of the protrusion 90 or the side surface or the valley portion of the crucible 88 located below the protrusion 9〇 has a surface roughness 36 200800553 23891pif.doc By applying surface roughening, the protrusion 9 is稜鏡片弘表. Boundary and other illegible, can be made in the backlight high quality 稜鏡 . · _ 〇 〇 〇 〇 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好 较好And then better is 80 degrees ~ 100 degrees, the best is the twist. Also, the apex angle of -稜鏡88 is preferably 40 degrees to 90 degrees, and more preferably "shirt sound' 70 degrees.疋 〜~ In order to avoid the interference with the liquid crystal panel (m〇ire) and to achieve φ 溥 ,, the spacing of the 稜鏡 (or protrusion) is preferably 1 μΐϊ1~6〇μ®, better It is 1〇μιη~30 μπι, the best is 15 and ~2〇 Tao. When the cymbal piece 86 is used as a cymbal of a backlight mechanism such as a liquid crystal display device, the projections 90 are directed upward, and the LED light source is disposed on the side where the projections 9 are provided. Next, the energy ray-curable resin used in the injection molding apparatus of the above embodiment will be described. In order to improve the performance of the mold, it is preferred to suitably contain a release agent in the energy ray-hardening resin. As a raw material of the energy ray-hardening resin, the following materials are mentioned, for example. ^ Resin material 1, which is a rigid component, is represented by Chemical Formula 1. [Chemical 1] ch2=chcoch2

〇 II ch2=ghcoch2c- ch2o-c-n-ch CH3 CH3

Ch2〇cch=ch2 〇 li CH2=CHCOCH2

I! ! 〇H N——C- I ii H〇

〇II och2~ c- ch2occh=ch2 ch2〇cch=ch2 Resin raw material 2 'is a rigid component, represented by chemical formula 2 2008 200800553 23891pif.doc [Chemical 2] ch3 chv h3 N- CO- CHCH2OCOCH=CH2 CH3 CH3 CH2- N-co-chch2ococh=ch2 The resin material 3 is a softening component, and is represented by Chemical Formula 3. [Chemical Formula 3] CH3 ch3 ch2 = ccoo (c4h8o) 9coc = ch2 The resin material 4 is a softening component and is represented by Chemical Formula 4. Cnno

3 y 3 Η - Η CICIC Η 1 (〇C2H4)nOci=CH2 〇 mtn^io The resin material 5 is a soft component and is represented by Chemical Formula 5.化 9H3 CH2=Cf〇(C2H4〇)m-

CH3 — (〇C2H4)n〇ci=CH2 〇 mtn=io Resin material 6, which is a soft component, is represented by Chemical Formula 6 [Chem. 6] 38 200800553 23891pif.doc

OC2H4OCOCH=CH; The polymerization initiator 7 for uv hardening is represented by Chemical Formula 7. [Chemistry 7]

Resin raw material 8, represented by chemical formula 8 [Chemical 8]

The EO adduct diacrylate of bisphenol A The resin material 9 is a rigid component and has a structure in which hydrogen is added to the aromatic ring of the resin material 5. The resin material 10 is a rigid component and is an urethane acrylate mixture containing the following A component and a knife-forming urethane carboxylic acid. A component: Hexamethylene diisocyanate + terpolymer of hexamethylene diisocyanate B component: hydroxypropyl acrylate acid (hy droxypropyl aery late ) + pentaerythritol triacrylate S ( Pentaerythritol triacrylate ) 39 200800553 23891pif.doc In the present invention, the polymer glass has a transition temperature (Tg) of 40 ° C or more, preferably 60 ° C or more, more preferably - 80 ° C ° or more. For the raw material for producing such a polymer, for example, the raw materials represented by the above Chemical Formula 8 and the following Chemical Formulas 9 to 25 can be mentioned. [Chemistry 9]

m=n=2 EO modified (n=2) dipropylene roastate of double A [Chemical 10] 〇

HOHoCH^C^ .CH9〇HnOCOCH=CH〇

‘ / Ή〆 ‘‘ ‘

I CH2CH2OCOCH=OH2 isocyanuric acid EO modified diacrylate [Chemical 11]

HO j-l2〇=C—C—(OC^Hg'Js—0C0CH=CH2 40 200800553 23891pif.doc tripropylene glycol diacrylate [^b 12] Η Ο H2C=C—c—(oc2h4 ) 4—ococh=ch2 triethylene glycol diacrylate n#4 [Chem. 13]

(CH2=CHCOOCH273- CCH2〇H

Pentaerythritol triacrylate [C14] (Cn2=CHCOOCH273-CCH 2CH 3 trimethylol propane triacrylate [Chemical 15] ch2=chco—(-〇〇3Ηβ ^-οοη|^-〇〇η2οη3 11=1 Three-modified mercapto-propene PO modified (η = 1) triacrylate [Chemical 16] 0

Iso-cyanuric acid EO modified triacrylate 41 200800553 23891pif.doc [Chemical 17] CH2=CHC0—f〇C3HB )—OCH: η cch2ch3 n-2 tri-sulfanyl-propyl-propene P〇 modified (n = 2) Triacrylate [Chemical 18] -cch9ch. CH2=CHCO-f 〇C2H4)-OCH: 11=2 Hydroxyl propyl EO modified (n = 2) tripropylene acid I [Chemistry 19] (ch2=chcooch^—coc:

.CH^OR \(CH2OOCCH=CH2)2 R :H or -c〇-CH= CH2

Dipentaerythritol five and six acrylates [Chem. 20]

(CH2=CHCOOCH2l4~C pentaerythritol tetraacrylate vinegar

[Chem. 21] OCX 42 200800553 23891pif.doc [ 22 22 ] { Μ — K — A : Acrylic acid Μ : Divalent alcohol Ν : Dibasic acid [Chem. 23]

• Α-^Χ—Y-j—X—A 11 A : Acrylic acid X: Polyvalent alcohol Y: Polybasic acid η : 1 ～1 0 [Chem. 24]

Trimethylolpropane acrylate phthalate 43 200800553 23891pif.doc

[Chem. 25]

Further, as the energy ray-curable resin component, at least the polymer has a glass transition temperature (Tg) of not more than or equal to, preferably more than or equal to. 70C, better than 9〇. 〇, the best is greater than or equal to the fat Tg, and at least the use of difunctional acrylate vinegar as the energy line hardening tree. If the sclerosing reaction is accelerated, the stiffness of the film will increase and it will increase.

In the case of stone knives, the propylene sulfhydryl group is greater than or equal to two, preferably three to six acrylate monomers, whereby the polymerization hardening reaction is accelerated, and the rigidity and Tg are improved. In the case of a boat, if the molecule contains an alicyclic difunctional acrylic acid, the film straightness and Tg will increase. ^ If a large amount of acrylate containing a polar group is contained, the optical anisotropy of the film can be imparted. ^ The ultrafine cellulose atom containing fluorine atom can be made by optically hardening the ruthenium film by applying the same π to the film and photohardening it, thereby producing an optical film having an optical orientation of 各 44 200800553 23891 pif. Also, there is a lack of compatibility with metal or other transparent window resin, and it is easy to peel off from the mold. When epoxy acrylate is contained, it is hard to suppress oxygen at the time of hardening, and it is excellent in adhesiveness to metal. When the polymer is placed in the metal mold, it is difficult to adhere to the glass/transparent resin when the cookware is opened, and the peeling direction is always the mold surface, which is preferable. Peeling from the metal surface by blowing.

Acryl acrylate and acid imine acrylic acid as a diluent thereof can also be used. Acryl amic acid containing (dihydroxydihexyl diisocyanate/diisocyanate hexamethylene terephthalate mixture) and/or (hydroxypropyl acrylate/pentaerythritol triacrylate ruthenium mixture) component may also be used. Ester mixture. As for the photopolymerization initiator, it is preferred to use a polymerization starter J for UV hardening, and it is also possible to use a sensitizer to polymerize it by an energy sensitization reaction. The wavelength of the light is extended to increase the degree of hardening in the deep. For example, hydrazine (2_fluorenyl[4_(methylthio)phenyl]_2•morpholinylpropane ketone) and irgacure 907 initiator (manufactured by Ciba Specialty Chemicals Co., Ltd.) can be used in combination. . When a photopolymerization initiator having a peak of absorption and a long wavelength in a wavelength range of 360 nm or more is used as a polymerization initiator for uv hardening, the wavelength will be extended to increase the degree of hardening in the deep portion. , heart " For example, ΒΑΡα{双(2A6.三f-based benzoyl emulsified phosphine}, MBAK) {2,4,6_trimethylmethylmethanyl. Diphenyl oxidized lining}, several If a photopolymerization initiator having photofading property is used as a polymerization initiator for UV stone |, the absorption band of the polymerization initiator accompanying the photoreaction claw hardening disappears, and the light will reach deeper until The hardening reaction takes place in the depth. For example, there are decylphosphine oxide such as MBAP0 (2,4,6-trimethylbenzylidene-diphenylphosphine oxide), bis(η5-2,4-cyclopentadienyl-1-yl)-bis (2,6-Difluoro-Μ1Η j-pyrrolidyl)-phenyl) Titanium-based initiators such as titanium, 〇χΕ{ΐ, 2-octyl-, Η4-(phenylthio)(0-benzene曱醯肟)]} 肟 肟 ester. If using photopolymerization that can be utilized when irradiated by visible light energy rays

In the case of the initiator, the polymerization can be started by irradiation with visible light, so that a laser can be used as the energy source. For example, there are a titano-based initiator such as bis(η5_2,4-cyclopentadienyl)-bis(2,6-dioxane (1Η^pyrrole+yl)-phenyl). ^ As a specific example of the composition of the energy ray-curing resin, for example, the following examples exist. Example 1 is a hardening of a mixture of resin raw material 1 (40 wt%), resin raw material 2 (20 wt%), resin raw material 3 (40 wt%) > and UV curing polymerization initiation, "17 (1.2) Tg=i2 (hardened material under Tc. Example 2 Resin raw material ll (45 wt%), resin raw material

The tree, (2) wt%), and the mixture of uv hardening polymerization ^ Wt%) are hardened, and the smear agent 7 (U obtains Tg == 7 (hardened material under TC). The present invention is not limited to the above implementation county, in the money Various modifications are made within the scope of the invention, which are also included in the range of == 46 200800553 23891pifdoc. - Opposite;: Forming device 5. In the case of a cavity 8 and opposite to the empty thickness 2) Emperor Dong can also be injection molded as shown in Fig. 31; =:: 94, 96, a pair of electrodes 94, =; and opposite to the width direction of the cavity 8. ^ ^ 8 2 2: The transparent conductive film of the f-current power supply 98 is placed under the two ends of the Shiyang glass plate 16 , and the incoming edge member 100 is respectively connected to the movable type 2b. / The energy ray-curable resin u having a large polarity of 7 knives imparts predetermined optical properties to the molded article. The mechanism 02 can also use the precise discharge shown in Fig. 32 for the discharge mechanism, and the dense discharge mechanism 1 〇 2 is configured as By the controller ι 〇 4 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ In order to increase the amount of discharge, it is preferred to supply the energy line hardening tree using a nozzle of a plurality of nozzles arranged in /, or quasi- or two-dimensionally, especially as shown in FIGS. 12 and 13 . In the method, in order to uniformly apply the material of the energy ray-curing resin to the inside of the mold in a uniform manner for a short time, it is preferable to twist the nozzle.

It is also possible to use a transparent resin plate such as polyester or acrylic to form a window or all of the window. In this case, a translucent plate may be used instead of the quartz glass plate I6 or a plate in which the bismuth quartz glass plate and the transparent resin plate may be integrated. In the case where the transparent resin sheet and the quartz sheet are formed, it is preferable that the surface of the window on the cavity side is formed of a transparent resin. Further, the thickness of the transparent resin is, for example, 〇面〜10 mm, preferably 〇·5匪~5 mm> H A is 1 mm 〜2 mm. Ultrasonic vibration can also be used to connect the mold to the mold in order to facilitate the removal of the molded product from the mold. [Simplified description of the drawings] The formation of the shots; =: The shot formation of the second embodiment is the same as that of the second embodiment, and the injection opening and closing of the second embodiment of the present invention is followed by the formation of the m-shaped piston. The injection of FIG. 6 of the third embodiment of the present invention is the same as that of FIG. 1, and is a view showing a fourth embodiment of the present invention 48 200800553 23891 pif.doc forming apparatus. Figure 7 is a view similar to Figure 1 of a forming apparatus. 7" The injection of the fifth embodiment of the present invention is shown in Fig. 8 and Fig. 1 . The output of the sixth embodiment of the present invention is the same as that of Fig. 1, and is a view showing the molding apparatus of the present invention. Fig. 10 is a view similar to Fig. 1 and shows a drawing of the first forming apparatus of the present invention.氪月氪弟8 贝(四)Sorrowful ejection Fig. 1 is the same as Fig. 1 and shows the drawing of the first forming apparatus of the present invention. The center of the core 9 is a plan view of the present invention. The drawing η is a first embodiment of the present invention. The drawing is shown in FIG. The injection molding assembly 15 of the second embodiment of the invention is a cross-sectional view taken along the line xv - xv in Fig. 14. Figure 16 is a cross-sectional view taken along line XVI-XVI' of Figure 14. Figure π is a cross-sectional view taken along line χνπ-χνιι in Figure 14. Fig. 18 is a view showing an operation of an injection device i according to an eleventh embodiment of the present invention, and Fig. 19 is a view showing a shooting operation of an nth embodiment of the present invention. Fig. 20 is a view showing an eleventh embodiment of the present invention. A diagram of the operation of the injection device. Fig. 21 is a view showing the operation of the injection device according to the eleventh embodiment of the present invention. Fig. 22 is a view showing the operation of the injection device according to the eleventh embodiment of the present invention. Fig. 23 is a view showing the operation of the injection device according to the eleventh embodiment of the present invention. Fig. 24 is a view showing the operation of the injection device according to the twelfth embodiment of the present invention. Fig. 25 is a plan view showing a part of a film which is an example of a molded article produced by the injection molding apparatus according to the embodiment of the present invention. Figure 26 is a side view of the film of Figure 14. Fig. 27 is a partial perspective view of a film which is another example of a molded article manufactured by the injection molding apparatus according to the embodiment of the present invention. Fig. 28 is a plan view showing a part of a cymbal sheet which is another example of a molded article manufactured by the injection molding apparatus according to the embodiment of the present invention. Figure 29 is a side elevational view of the crotch panel of Figure 17. Figure 30 is a front elevational view of the cymbal of Figure 17. Fig. 31 is a view similar to Fig. 1 showing a modification of the injection molding apparatus of the seventh embodiment. Fig. 32 is a view showing the configuration of a precision discharge mechanism using a syringe. 50 200800553 23891pif.doc [Main component symbol description.] 卜26, 30, 34, 36, 44, 48, 50, 56, 60, 69, 92, ^ 110, 164: injection molding device • - 2, 112: mold 2a, 118: fixed type 2b, 120 · · mobile type 4, 114: metering injection mechanism _ 6, 116: energy line source 8, 122: cavity 10, 131: flow channel 12 · · discharge device 14, 126: opening 16 : quartz glass 18 : fine structure transfer mold 20 · water pipe, 22 : baffle _ 24 : air vent 28 , 150 : gas supply path 32 : tapered piston opening and closing mechanism 38 , 46 · • suction path 40 : transparent base Materials 41, 42: Fine shape imparting molds 52, 98: DC power supply 54: Transparent electrode 51 200800553 23891pif.doc

55, 100: insulating member 58: polarizing film 62, 72: ink jet head 64, 74: ink jet nozzle 66, 70: UV hardened resin case 68: lens 76: energy ray hardening resin 78: film 80, 84, 90: Projection 82: Optical film 86: cymbal 88: 稜鏡94, 96: Electrode 102 • Discharge mechanism 104: Controller 106: Discharge valve 108: Auxiliary box 111: Molded product 111A: Thick portion 111B: Thin plate portion 115: Resin supply device 117: gas supply mechanism 124 • shaft 125: bolt 52 200800553 23891pif.doc 128 : quartz glass plate 130 : forming portion ' 132 · resin supply path ' 132a, 134a, 150a · horizontal portions 132b, 134b, 150b: vertical portion 134: discharge path 136: injection port 眷 13S: discharge port 140, 142: through hole - N - 144, 146: rod 148, 149: upper end surface 151: gas discharge port 152: ejection valve 153: compression Coil spring 154: ejection pin '156: head housing portion 158: shaft passage 160: molded product conveying mechanism 162: adsorption pad, 166: box-shaped sleeve 168: sealed space 170: gas supply tube 53

Claims (1)

200800553 23891pif.doc X. Patent application scope: The stellite wire-shaped device has a line-hardening resin, which is characterized by: a mold; a source for illuminating the energy line to the above mold, and The window constitutes at least one of the energy source of the mold cavity, and the opening and closing mechanism is opened to the air-closing of the mold through the window, and the opening and closing mechanism is used for opening, and the surface is closed when the injection is closed. . , the hand "the same plane on the inner surface of the cavity. The tree i: ί the injection molding device uses a fine mold; = the way to 'connect the cavity of the mold; = cup, in the above-mentioned - resin supply path _ back; The second resin supply path, the Jinshang Chengwang resin supply device, is supplied to the second resin supply chamber first-resin discharge path by the road day, and communicates with the mold 54 200800553 23891pif.doc The second rod is discharged from the above-mentioned first resin a second resin discharge path merges with the first resin discharge path; a resin discharge device for causing self-discharge; and a T energy source for irradiating the mold with an energy ray; and The mold includes a window constituting at least one portion 2 of the mold cavity and passing through an energy line emitted from the energy line source, wherein the mold is n-spring from the upper 逑 91 _ through the window to the above-mentioned mold The inside end of the rod can be reciprocated between (a) and (1); the front end surface of the second rod can be reciprocated to and from the following resin supply path and the upper road U1 or the self-combining flow position a position away from the cavity of the mold; a surface; the above (8) (4) is almost the same as the surface constituting the cavity of the mold; (2) is located at the first resin discharge path and the second resin circuit = a new or self-combining position Keep away from the upper (4) position of the upper dragon; face. hd 'stands in the same flattened tree month as the face constituting the above-mentioned mold cavity: ^The forming device' uses the energy line hard eucalyptus, its characteristics Including the mold, the US, 'for measuring the energy ray hardening resin, and then ejecting it into the cavity of the cookware and 55 200800553 23891pif.doc 铌 踝 踝 用 用 用 用 向 向 向 向 向 向And the above-mentioned mold ♦ includes a window, the window constituting at least a part of the upper Wei-chat cavity and for igniting the energy emitted from the energy line source, and setting the energy to the upper frequency _ "sending into the cavity; and supplying * further includes a sleeve and a pressing device, the sleeve f covering the surface of the window panel to form a sealed space, and the pressing device uses energy for the sealed tree to form the injection molding device a wire hard mold composed of a plurality of mold parts that can be opened and closed; a measuring mechanism for measuring the energy ray hardening resin to be ejected into the cavity of the cookware; and an energy line source for The mold illuminates the energy line; and the upper trap includes a window constituting at least one of the mold cavities of the mold cavity and configured to pass the energy line from the energy line source through the t Inside the cavity; 7, 3 〇 irradiated to the above mold, the above mold is configured to start opening and smashing the tree; then she deletes the energy line hard mold; 56 200800553 23891pif.doc Τ里! The source 'is used to illuminate the above-mentioned mold with an energy line; and at least one portion of the mold cavity constituting the above-mentioned mold cavity is configured as an energy line source (four) energy line, in the above-mentioned mold; and 'the inside line source is irradiated to the mold through the window The cavity and 』=== are used to supply gas to the above-mentioned molded product μ, +, ;: 7 between the two faces so that the molded article is peeled off from the mold; the gas is formed: the discharge port, the gas The ejection outlet is provided with an ejection mechanism. _ gas, and the gas discharge port = towel, please turn over the injection of the item described in item 5, wherein ί: = extraction mechanism, the molded article take-out mechanism holds the molded article from the above-mentioned molded article take-out mechanism to maintain the above In the molded product, the mold is separated, and the molded article is sequentially oriented toward the other end-contact portion, and the mold (four) surface-shaped (four) sand and the pair are described in the above-mentioned items. The injection molding apparatus of the seventh aspect of the invention, wherein the permeate side surface is formed with a fine structure and contains a release agent. The injection molding apparatus disclosed in claim 7 is wherein 57 200800553 23891pif.doc, a fixing mechanism for adsorbing and fixing the thin film on the surface of the fine structure on the surface of the mold. The squirrel-shaped device according to any one of claims 4 to 4, further comprising a gas ejecting mechanism for separating gas from the inside of the cavity In order to peel the molded article from the mold 屮 η ! ! ° ° ! ! ! ! ! ! ! ° ° ° ° ° ° ° ° ° ° η η η η η η η η η η 田 田 田 田 田 田 田 田 田 田 田 田 田 田 田 田 田 田 田The molded article was peeled off from the mold. 12. The injection molding apparatus according to any one of the third aspect of the invention, wherein the metering injection mechanism comprises a discharge mechanism, and the discharge mechanism comprises an inkjet nozzle/head. The clothing line of any one of the first to sixth items of the Yuming patent circumference is the one in which the energy source of the upper sputum is the uv light head that sends the short pulse (4) to the sixth item. Above, twelve 1 /, includes a pair of electrodes configured to sandwich the cavity of the seven cookware and opposite to the thickness direction of the cavity. The pair of electrodes referred to in item 6 of the sixth item includes a pair of electrodes configured as a cavity of the holder and facing the width direction of the cavity. The UV lamp described in any one of the items 1 to 6. The above-mentioned energy source source is a polarized state ultraviolet light 17 as described in any of the above-mentioned patent scopes i to 6 2008 200800553 23891 pif.doc: between the above energy line source and the window or The above-mentioned window is equipped with the injection molding device described in claim 12, wherein the mechanism mechanism includes the amount of fine material discharged from the nozzle of the new nozzle: the movement of the mold, - The hardened resin is applied to the above mold cavity with the desired ruthenium and the inner line. The manufacturing method includes 1, 3, 4, and (4), and uses an injection molding apparatus as described in the Patent Application No., the Chinese Patent Application, which is characterized in that the resin is hardened by the above-mentioned energy ray θ = The enamel is irradiated toward the window to harden the energy ray hardening resin hard resin to shape the Hit | line, and the energy ray in the cavity is hardened into a molded article and 2022: 'hardened forming from the mold cavity Take out the product. The above-mentioned method of making the shots is such that the patented scope of the patent is first made into a garment, and is characterized in that it includes: a tree_upper IS: a fat supply device that hardens the energy line. The irradiation of the above-mentioned window causes the energy ray-hardening resin hard-molded article to harden the energy ray-curable resin in the cavity, and the shape-extracting step takes out the cured molded article from the mold cavity. 59