TW200745214A - Siloxane compound containing photoreactive group, process for preparation and thermosetting resin composition thereof, and articles with cured coats thereof - Google Patents

Siloxane compound containing photoreactive group, process for preparation and thermosetting resin composition thereof, and articles with cured coats thereof

Info

Publication number
TW200745214A
TW200745214A TW096113509A TW96113509A TW200745214A TW 200745214 A TW200745214 A TW 200745214A TW 096113509 A TW096113509 A TW 096113509A TW 96113509 A TW96113509 A TW 96113509A TW 200745214 A TW200745214 A TW 200745214A
Authority
TW
Taiwan
Prior art keywords
photoreactive group
siloxane compound
articles
preparation
resin composition
Prior art date
Application number
TW096113509A
Other languages
Chinese (zh)
Other versions
TWI402297B (en
Inventor
Yuji Yoshikawa
Masaaki Yamaya
Original Assignee
Shinetsu Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinetsu Chemical Co filed Critical Shinetsu Chemical Co
Publication of TW200745214A publication Critical patent/TW200745214A/en
Application granted granted Critical
Publication of TWI402297B publication Critical patent/TWI402297B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/045—Polysiloxanes containing less than 25 silicon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
    • C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Silicon Polymers (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyethers (AREA)
  • Epoxy Resins (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

A photoreactive group-containing siloxane compound is obtained by subjecting a system comprising (a) a photoreactive group-containing alkoxysilane and (b) a hydrolyzable group end-capped dimethylsiloxane to hydrolytic condensation in the presence of a basic catalyst and with an amount of water greater than the amount necessary for hydrolytic condensation of all alkoxy groups. It forms on a substrate a coating having mar resistance, crack resistance, anti-staining effect, and marker ink wipe-off ability.
TW96113509A 2006-04-18 2007-04-17 A siloxane compound containing a photo-reactive group, a method for producing the same, and a photohardenable resin composition, an article having the hardened film TWI402297B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006114074 2006-04-18
JP2006192436A JP4868135B2 (en) 2006-04-18 2006-07-13 Photoreactive group-containing siloxane compound, method for producing the same, photocurable resin composition, and article having the cured film

Publications (2)

Publication Number Publication Date
TW200745214A true TW200745214A (en) 2007-12-16
TWI402297B TWI402297B (en) 2013-07-21

Family

ID=38605643

Family Applications (1)

Application Number Title Priority Date Filing Date
TW96113509A TWI402297B (en) 2006-04-18 2007-04-17 A siloxane compound containing a photo-reactive group, a method for producing the same, and a photohardenable resin composition, an article having the hardened film

Country Status (4)

Country Link
US (1) US7928179B2 (en)
JP (1) JP4868135B2 (en)
KR (1) KR101307142B1 (en)
TW (1) TWI402297B (en)

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WO2009090916A1 (en) * 2008-01-15 2009-07-23 Toagosei Co., Ltd. Organosilicon compounds which have oxetanyl groups, and a method for the production and curable compositions of the same
JP2010180375A (en) * 2009-02-09 2010-08-19 Shin-Etsu Chemical Co Ltd Photocurable coating composition, film forming method, and coated article
JP2013095817A (en) * 2011-10-31 2013-05-20 Dic Corp Alkoxysilane condensate and active energy ray-curable composition using the same
JP6269429B2 (en) 2013-10-24 2018-01-31 信越化学工業株式会社 Photo-curable paint, laminate and automotive headlamp covering sheet
CA2949412A1 (en) * 2014-05-20 2015-11-26 Centre National De La Recherche Scientifique (Cnrs) Novel process for obtaining superhydrophobic or superhydrophilic surfaces
US9359386B1 (en) * 2015-02-19 2016-06-07 Gelest Technologies, Inc. Silanes and silicones with distinct hydrophilic and oleophobic substitution
CN105542169A (en) * 2016-02-01 2016-05-04 江西省科学院应用化学研究所 Preparation method for alkoxy functionalized polysiloxane
EP3578612A1 (en) 2018-06-08 2019-12-11 3M Innovative Properties Company Polysiloxane-based protective coating composition for hard surfaces
JP7039718B2 (en) * 2018-08-24 2022-03-22 ワッカー ケミー アクチエンゲゼルシャフト Preparation method of branched organopolysiloxane
JP7231422B2 (en) * 2019-01-29 2023-03-01 三菱マテリアル電子化成株式会社 antifouling membrane

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FR2447386A1 (en) * 1979-01-24 1980-08-22 Rhone Poulenc Ind PHOTOPOLYMERIZABLE ORGANOPOLYSILOXANIC COMPOSITIONS
US4585670A (en) * 1985-01-03 1986-04-29 General Electric Company UV curable silicone block copolymers
JPS63295768A (en) * 1987-05-26 1988-12-02 東レ・ダウコーニング・シリコーン株式会社 Fiber treatment agent
US5188864A (en) * 1988-08-15 1993-02-23 Dow Corning Corporation Adhesion promoter for UV curable siloxane compositions and compositions containing same
US5663269A (en) * 1992-03-31 1997-09-02 Loctite Corporation Organosiloxane fluids prepared using organo-lithium reagents
JP2639286B2 (en) * 1992-07-14 1997-08-06 信越化学工業株式会社 Curable organopolysiloxane composition
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JP3209084B2 (en) * 1996-03-13 2001-09-17 信越化学工業株式会社 Resin composition, method for producing the same, and artificial marble
DE19725518A1 (en) * 1997-06-17 1998-12-24 Huels Silicone Gmbh Polyorganosiloxanes with dialkoxyorganosiloxy groups
JP3843575B2 (en) * 1998-01-13 2006-11-08 東亞合成株式会社 Photocationic curable resin composition
US6121342A (en) * 1998-01-13 2000-09-19 Toagosei Co., Ltd. Photocationically curable compositions and process for producing the same
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JP3572989B2 (en) 1999-04-01 2004-10-06 三菱マテリアル株式会社 Polyhedral organosilicon compounds having perfluoroalkyl groups
KR100722731B1 (en) * 1999-03-31 2007-05-29 미쓰비시 마테리알 가부시키가이샤 Polyhedral organosilicon compound and method for producing the same
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Also Published As

Publication number Publication date
JP2007308674A (en) 2007-11-29
KR101307142B1 (en) 2013-09-10
KR20070103306A (en) 2007-10-23
TWI402297B (en) 2013-07-21
US7928179B2 (en) 2011-04-19
US20070244250A1 (en) 2007-10-18
JP4868135B2 (en) 2012-02-01

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