TW200535992A - Method for creating original disk for information recording medium, device for irradiating original disk for information recording medium, method for manufacturing information recording medium and information recording medium - Google Patents

Method for creating original disk for information recording medium, device for irradiating original disk for information recording medium, method for manufacturing information recording medium and information recording medium Download PDF

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TW200535992A
TW200535992A TW094109429A TW94109429A TW200535992A TW 200535992 A TW200535992 A TW 200535992A TW 094109429 A TW094109429 A TW 094109429A TW 94109429 A TW94109429 A TW 94109429A TW 200535992 A TW200535992 A TW 200535992A
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Taiwan
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electron beam
recording medium
information recording
range
mother
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TW094109429A
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Chinese (zh)
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Yuzuru Chika
Toshinori Sugiyama
Hiroshi Ido
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Hitachi Maxell
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Abstract

To provide a device for irradiating an original disk for an information recording medium of which the recording position accuracy is enhanced by electron irradiation. The original disk for information recording medium in which variation in groove width and noise levels of recording tracks of the whole original disk 21 are reduced is created by the device 100 for irradiating the original disk for the information recording medium equipped with an electron irradiation means for irradiating the original disk 21 having an electron sensitive resist thin film in which polarity change arises by the electron irradiation with electron beam 19 whose amount is fixed per unit time, a driving means for holding and rotating the original disk 21, a variation means for varying a relative position between the electron irradiation means and the original disk 21 in the horizontal direction and an original disk rotation control means for controlling the number of rotations of the original disk 21 based on the relative position in the case of irradiating the original disk 21 with the electron beam 19 by the electron irradiation means.

Description

200535992 (1) 九、發明說明 【發明所屬之技術領域】 本發明係有關資訊記錄媒體用母片作成方法等,詳細 來說,係有關提高了記錄位置精確度之電子束照射的,資 曰只§3錄媒體用母片作成方法等。 【先前技術】 β 近年來,伴隨被記錄之資料量增加,使所需之資訊記 錄媒體之記錄容量及記錄密度,進而被記錄之資訊的存取 速度上升成爲必要。故光碟片基板之窪(pit)大小或凹軌 (groove)寬度係逐年細微化,軌間距亦狹窄化。通常,預 先形成於光碟片基板之窪或凹軌等細微構造,係以使用了 雷射光之微影法來作成。故,可形成之窪或凹軌的最小尺 寸,係相關於由光源所射出之雷射光的波長,和聚光透鏡 之開口數(NA)。因曝光裝置之透鏡ΝΑ在0.9已經接近極 ^ 限,故使用先前之雷射光的母片曝光裝置,係以雷射光之 短波長化,來應對細微化之趨勢。具體來說,對於D V D 中,例如使用波長351nm之気雷射;而例如BluRay Disc( 藍光碟片)中,則使用了例如使用氬雷射之激振束之第2高 調波的,波長2 5 7 n m或2 4 4 n m之雷射光。 與光碟片相同地使用微影法來形成細微構造之半導體 製造處理中,係例如適用波長1 9nm之氬氟化物準分子雷 射光等波長更短之雷射光。但是此種脈衝雷射光源中,各 脈衝光之強度係有不一致,例如會損害窪尺寸之平均性, -5- 200535992 (2) 故對於非半導體製程所採用之面曝光方式的,直描方式之 光碟片製造工程,並不適用。對此,並未發現比使用氬雷 射之激振束之第2高調波的遠紫外線雷射,可更短波長且 連續激振,並作成更細微之窪或凹軌的雷射光源。故,更 加提高記錄密度之碟片的製造,係以電子束描繪裝置之適 用可能性爲高,並持續開發中。 然而,先前爲了於光碟片用母片作成螺旋狀之記錄軌 φ ,係大致分類有將曝光光束之光量及線速度保持一定,依 半徑位置而連續改變母片之旋轉數及滑動件之移動速度的 CL V (Constant Linear Velocity定線速度)方式;和將母片 之旋轉數及滑動件之移動速度保持一定,依半徑位置而連 續改變曝光光束之光量的CAV(Constant Angular Velocity 定角速度)方式2種。通常,重視記錄容量之在生專用媒體 或僅可記錄一次之追記媒體係以CLV方式,而重視存取 速度之電腦用途媒體則用CAV方式作成。例如,被看做 φ 光磁碟片般,將位址於正確的於特定位置局部存在化,可 使存取時間縮短。亦即,爲了於碟片上之特定位置來正確 記錄,必須是容易進行半徑方向之驅動控制和旋轉控制的 CA.V方式。 更且,近年來以飛躍性提高記錄密度爲目的,係提案 有僅調變少量位元之記錄位置的複値記錄方式,或以複數 位元列形成標誌之二維記錄;針對光碟片母片之提高記錄 位置精確度,係爲必須。 另一方面,被使用於電子束描繪裝置之電子束,並不 -6 - 200535992 (3) 存在如使用先前雷射光之母片曝光裝置之音響光學(A 0)元 件般,任意控制光束之透過率的元件;故係藉由調變通過 開口部之電子數量(電流値),來控制電子束照射量。然而 ,例如固定母片之旋轉數,於母片半徑20mm到60mm爲 止之範圍,形成螺旋狀之記錄軌時,於最內周和最外周, 電流値必須改變3倍左右。 又,要控制電子束中自基板之後方散射,或基板之充 φ 能(Charge up)量係有困難,其具有若變更由電子槍所放射 之電流値,則會變動電子束之軸等問題點;對固定母片之 旋轉數,配合半徑位置改變電流値之CAV照射方式並不 容易,而對於安定的光碟片母片製造,亦有相當障礙。 第10圖,係針對CLV方式,說明光碟片用母片之半 徑位置和旋轉數之關係的圖。第1 0圖之橫軸爲光碟片用母 片之半徑位置,縱軸爲旋轉數。曲線A,係表示針對C LV 方式,作爲光碟片用母片之目標的理想旋轉數之推導;其 φ 表示半徑位置大者(外周),旋轉數則小。如第1 〇圖所示, CLV方式中,仔細觀察之,係將光碟片用母片之旋轉數保 持一定,並以非常短之時間間隔(旋轉數更新之間隔C)來 階段性改變(誤差B)旋轉數地,進行數位控制。另一方面 ,係不會依旋轉之慣性力量而涮間改變母片旋轉數,通常 ,母片之旋轉係以曲線A,和將以數位控制所輸出之階段 狀指令値加以小幅度反覆的形式,來進行。 旋轉數更新之間隔C,係受到與控制裝置之通訊速度 或反應速度,和表示控制裝置之旋轉數之位元分解能的限 -7- 200535992 (4) 制。故,若表示旋轉數之位元數不足,沒有累積某程度之 誤差而無法檢測出與曲線A之差別的情況;或是控制裝 置之運算受到與其他輸出電路之通訊的限制之情況;又或 因資訊之輸入輸出之通訊失敗等,而旋轉數之更新被拖延 之情況’會產生巨大之旋轉控制誤差(誤差D)。 又,CLV驅動,因內周和外周之旋轉數不同,故旋轉 數大之內周側比起外周,其決定旋轉速度之脈衝頻率更新 φ 間隔,會變的鬆散。故於內周,更容易產生特定之應記錄 位置和實際照射電子束之位置的位置偏差。對此,若降低 內周之速度’則因碟片整體之照射時間會顯著拉長,故不 適合局始度化之碟片製造。更且,延長照射時間,會大幅 影響電子束之輸出變動,故對於安定地製造於母片作成時 ,預先記錄之資訊量飛躍性增加的高密度光碟片母片,係 有相當障礙。 另一方面,以開迴圈進行類比控制時,對指示旋轉速 φ 度之基準時脈,與片旋轉速度之旋轉編碼器的輸出相比較 ,則可準備特定之燈波形,故難以產生此種問題;但必須 配合旋轉速度之變動量而詳細設定增益之變更,通常並不 容易進行此種管理,故於轉軸及滑動件控制般單一方向驅 動的例子中,係以用閉迴圈進行數位控制者爲現行的主流 。故,CLV方式中’並不一定會進行理想之旋轉控制。從 而,爲了以極高精確度實現曝光位置,可想見將母片之旋 轉數和滑動件之移動速度保持一定的C A V方式,是爲理 想;例如,報告有針對C A V方式,將電子束之每單位面 200535992 (5) 積之照射量作爲一定的曝光方法(參考專利文件;1 ) β [專利文件1 ]日本特開2 0 0 0 - 〇 1 1 4 6 4號公報 【發明內容】 發明所欲解決之課題 但是,如專利文獻1所記載般,針對C A V方式,將電 子束之每單位面積之照射量作爲一定的方法中,旋轉速度 φ 不同之內周和外周,其由電子槍所放射之電流値必須大幅 改變,而有無法避免改變電子束之軸的問題。 又,如專利文獻1所記載般,將電子束加以脈衝調變 ,依脈衝之工作比來控制電子束之照射量的手法,通常電 子束之斷開(blanking)在確保偏向量之目的下,並非反應 速度快之靜電偏向,而是採用電磁偏向;故過渡性通過開 口部之電子數量會有變化,因而所形成之凹軌會有寬度平 均性不足的問題。亦即,爲了解決此問題,必須將旋轉數 φ 抑制爲低,而會延長碟片整體之照射時間,故不適合高密 度化之碟片的製造。即使採用靜電偏向之斷開,爲了進行 調變,亦必須增加電子束之偏向量;亦即,用於斷開之偏 向電極的電容會增加,而產生調變速度之限制。 本發明,係用以解決此種以電子束描繪裝置來曝光資 訊記錄媒體用母片時,會變成浮雕之技術性問題者。 亦即,本發明之目的,係提供一種記錄位置精確度被 提高之電子束照射下的,資訊記錄媒體用母片作成方法。 又,本發明之其他目的,係提供一種可進行提高記錄 -9- 200535992 (6) 位置精確度之電子束照射的,資訊記錄媒體用之母片照射 裝置。 更且本發明之其他目的,係提供一種記錄位置精確度 被提高之資訊記錄媒體之製造方法。 更且本發明之其他目的,係提供一種記錄位置精確度 被提高之資訊記錄媒體。 Ί 用以解決課題之手段 % 上述課題應被解決,而本發明係提案有一種資訊記錄 媒體用母片作成方法,係針對使用一種具備了對具有因電 子束照射而產生極性變化之電子束感應阻劑薄膜之母片, 照射電子束之電子束照射手段、和保持母片並加以旋轉之 驅動手段、和將電子束照射手段與母片改變其水平方向相 對位置之變動手段的,母片照射裝置,來照射電子束,而 形成螺旋狀或同心圓狀之軌的資訊記錄媒體用母片作成方 -Φ 法;其特徵係將照射電子束之範圍,區分爲於半徑方向被 分割爲同心圓狀之複數記錄範圍;將母片之照射電子束之 範圍中每單位時間之電子束照射量保持一定,而針對被區 分之各記錄範圍,使母片之旋轉數爲一定地加以控制。 藉由採用如此構成,以電子槍所放射之電流値會成爲 一定,故可抑制電子束之軸變動;又,因固定旋轉速度而 進行旋轉誤差少之旋轉控制,故可將照射電子束之資訊保 持高度位置精確度。 本發明中,將照射電子束之範圍於半徑方向被分割爲 -10- 200535992 (7) 同心圓狀之複數記錄範圍’係指特定裝置中可進行資訊之 記錄或再生的範圍;通常’與設置於母片內周之條碼所代 表般,記錄有母片管理資訊的範圍等’並不相同。 又,爲了形成於母片預先記錄特定資訊之窪,通常雖 採用以斷開來遮斷電子束的方法;但伴隨如此之控制,即 使於對母片照射之每單位時間之電子束照射量有變化時, 針對未進行電子束遮斷之時序’將對母片照射之每單位時 φ 間之電子束照射量作爲一定的資訊記錄媒體用母片作成方 法,亦在本發明之範圍內。 又,本發明中,若針對被區分之記錄範圍之邊界部, 自外周之被區分之記錄範圍,向著內周之被區分之記錄範 圍,使其階段性之增加旋轉數地加以控制,則會降低每單 位面積之電子束照射量的內外周差,而可更加大母片之電 子束照射面積。 又,針對被區分之記錄範圍之邊界部,自內周之被區 φ 分之記錄範圍,向著外周之被區分之記錄範圍,使其階段 性之增加旋轉數地加以控制,亦可得到相同之效果,而如 此之資訊記錄媒體用母片作成方法,亦在本發明之範圍內 〇 更且,採用越外周側之記錄範圍旋轉數越高的構成, 比起先前之CAV方式,係減少電子束之照射時間,而可 安定的進行資訊記錄媒體之製造。 更且,本發明中係針對旋轉的母片之被區分之記錄範 圍,將線速度之最大値和線速度之最小値的比,控制在 -11 - 200535992 (8) 1 . 3以下者爲佳;更且,針對旋轉的母片之被區分之各記 錄範圍間,將平均線速度之最大値和平均線速度之最小値 的比,控制在1 ·1以下者爲佳。 將旋轉的母片之記錄範圍中的線速度’和各記錄範圍 間之平均線速度及記錄範圍的寬度’置於上述之範圍內’ 則可針對各記錄範圍內’對具有因電子束照射而產生極性 變化之電子束感應阻劑薄膜之母片’進行特定顯影處理而 Φ 形成之凹軌之凹軌寬度的變動,調整在可接受之範圍內。 另外,針對電子束之照射面積少’而照射有電子束之所有 範圍,將旋轉之母片的旋轉數作爲一定’而可將線速度之 最大値和線速度之最小値的比’控制在1 ·3以下時’即可 使於半徑方向被分割爲同心圓狀之記錄範圍的數目作爲1 〇 更且,被設置於母片之內周側之被區分之記錄範圍的 寬度,係較被設置於母片之外周側之被區分之記錄範圍的 φ 寬度爲窄者爲佳;針對被設置於旋轉線速度之變化量大之 母片之內周側的記錄範圍’可更減低每單位面積之電子束 之照射量的內外周差。亦即,即使於被設置於旋轉線速度 之變化量大之母片之內周側的記錄範圍’亦可更降低因進 行特定顯影處理所形成之凹軌’其凹軌寬度的內外周差。 又,若依本發明,則提案有使用更具備了將電子束對 軌以幾乎垂直之方向加以振動之電子束彳扁向手段的母片照 射裝置,來照射電子束’而形成螺旋狀或同心圓狀之軌的 資訊記錄媒體用母片作成方法;其中針對被區分之各記錄 -12- 200535992 (9) 範圍,使電子束之偏向量自內周向外周增加地加以控制。 藉由採用此種構成,則會保持電子束照射之資訊的局 度位置精確度;進而可降低於照射電子束之範圍’進行特 定顯影處理所形成之凹軌’其凹軌寬度的內外周差。 更且,將各半徑位置r之線速度作爲V(r),不進行線 速度V(r)之電子束偏向,而是將進行特定顯影處理所形成 之凹軌的凹軌寬度作爲W(r),且將在旋轉之同時進行電 φ 子束之偏向所形成之凹軌的凹軌寬度作爲Wmax之情況下 ,使針對各半徑位置的電子束之偏向量成爲Wmax-W(r)地 ,加以控制者爲佳;如此,可使被區分之各記錄範圍中的 凹軌寬度爲平均。 更且,使電子束之偏向頻率在V(〇/W(r)以上地,將 電子束於對軌方向幾乎垂直的加以偏向者爲佳,此係可抑 制藉由進行特定顯影處理所形成之凹軌的蛇行。 其次,本發明係把握作一種資訊記錄媒體用之母片照 φ 射裝置,其特徵係具備對具有因電子束照射而產生極性變 化之電子束感應阻劑薄膜之母片,照射電子束之電子束照 射手段;和保持母片並加以旋轉之驅動手段;和將電子束 照射手段與母片改變其水平方向相對位置之變動手段;和 將母片之照射電子束之範圍,區分爲於半徑方向被分割爲 同心圓狀之複數記錄範圍,並將被區分之各記錄範圍中每 單位時間之電子束照射量保持一定,而針對被區分之各該 錄範圍,使母片之旋轉數爲一定地加以控制的控制手段。 藉由採用如此構成,可使自電子槍所放射之電流値爲 -13- 200535992 (ίο) 一定,故可抑制電子束之軸變動;又,因旋轉速度固定而 進行旋轉誤差少之旋轉控制,故可保持電子束所照射之資 訊的高度記錄位置精確度。 又,本發明若更具有係針對被區分之記錄範圍之邊界 部,自外周之被區分之記錄範圍,向著內周之被區分之記 錄範圍,使其階段性之增加旋轉數地加以控制的,控制手 段;則會降低每單位面積之電子束照射量之內外周差,進 ' φ 而可增加母片之電子束之照射面積。 ^ 又,針對本發明所適用之資訊記錄媒體用之母片照射 裝置,係對被區分之記錄範圍之邊界部,將母片之旋轉數 之變更,以1 0旋轉以下來進行者爲佳;因進行與記錄再生 無關之旋轉數變更,使過渡之遷移範圍之軌減少,故可防 止記錄容量減少。 又,本發明所適用之資訊記錄媒體用之母片照射裝置 中,母片照射裝置係更具備進行母片之旋轉控制,同時輸 .Φ 出旋轉之該母片之角度資訊的,旋轉角度資訊輸出手段者 爲佳;以此係可實施與用電子束記錄之訊號產生手段的再 同步,而將於半徑方向被複數區分爲同心圓狀之記錄範圍 ,其半徑方向所產生之旋轉數變更所造成的旋轉誤差,加 以修正。更且,針對於半徑方向被複數區分爲同心圓狀之 複數記錄範圍間,係可提高資訊之記錄位置精確度。 又,本發明所適用之資訊記錄媒體用之母片照射裝置 中,係更具備控制電子束之偏向量的偏向控制手段者爲佳 ;針對於半徑方向被區分之記錄範圍,由內周向外周,使 -14- 200535992 (11) 於對軌方向杂乎垂直之方向被偏向的電子束,其偏向量增 加地加以控制’而可更減低所形成之凹軌寬度的內外周差 。更且,電子束之偏向控制手段,係採用反應速度快之靜 電偏向者爲佳’此係可抑制藉由進行特定顯影處理所形成 之凹軌的蛇行。 又’本發明所適用之資訊記錄媒體用之母片照射裝置 中,係更且具備可藉由斷開來遮斷電子束之電子束的調變 Φ 控制手段者爲佳。 另一方面,本發明係把握一種資訊記錄媒體之製造方 法,其係一種具有特定螺旋狀或同心圓狀之軌的資訊記錄 媒體之製造方法,係針對具有形成包含特定凹軌之資訊記 錄媒體用母片的母片形成工程、和形成一個被轉印有被形 成之資訊記錄媒體用母片之凹軌的形狀之金屬鑄模的,鑄 模形成工程;並且母片工程,具備電子束照射手段、和變 動與母片之水平方向相對位置的變動手段、和使母片旋轉 Φ 之驅動手段的,特定之電子束照射裝置;其特徵係將因驅 動手段而旋轉之母片其表面的電子束感應阻劑薄膜,以電 子束照射手段來照射電子束,然後以變動手段來改變電子 束照射手段與母片之水平方向相對位置’以電子束照射手 段來照射電子束時,係將母片中被照射電子束之區域,區 分爲於半徑方向分割爲同心圓狀的複數記錄範圍,將母片 之照射電子束之範圍中每單位時間之電子束照射量保持一 定,然後使母片之旋轉數爲一定地來照射電子束。 更且,若依本發明,則提供一種資訊記錄媒體’係於 -15- 200535992 (12) 基板上形成有螺旋狀或同心圓狀之記錄用軌的資訊記錄媒 體;其特徵係具有於基板上以特定寬度被區分爲同心圓狀 之複數記錄範圍;和被設置於被區分之各記錄範圍之邊界 部,其基板之半徑方向之寬度爲1 0軌以下的遷移範圍。 將本發明所適用之資訊記錄媒體中之遷移範圍作爲10 軌以下,減少無關記錄再生之軌,可防止記錄容量之減少 。於遷移範圍或遷移範圍附近,係更具備可再同步之再同 Φ 步控制標誌者爲佳;而可在形成於半徑方向被複數區分爲 同心圓狀之記錄範圍時,將記錄範圍之邊界之半徑位置附 近所產生之旋轉數變更所造成的旋轉誤差’加以修正。 本發明所適用之資訊記錄媒體中’於基板上以特定寬 度被區分爲同心圓狀之各記錄範圍,其外周側之半徑位置 和內周側之半徑位置的比,係在1 ·3以下者爲佳。 更且,本發明所適用之資訊記錄媒體中’被設置於基 板之內周側之被區分之記錄範圍的寬度’係較被設置於基 Φ 板之外周側之被區分之記錄範圍的寬度爲窄者爲佳。 以上,若依本發明,則可提供一種使用提高了記錄位 置精確度之電子線照射的,資訊記錄媒體用母片作成方法 【實施方式】 以下,根據圖示,說明用以實施本發明之最佳方式( 以下簡稱實施方式)。 第1圖,係說明本實施方式所適用之母片照射裝置的 -16- 200535992 (13) 圖。第1圖所示之母片照射裝置1 00,係由收容電子光學系 來作爲電子束照射手段的鏡塔】0,和具備母片保存旋轉手 段的試料室20所構成。鏡塔10及試料室20,係以適合之真 空裝置(未圖示)保持在真空狀態。電子光學系,係被裝置 於鏡塔10之內部,並具備由特定施加電壓(例如5 OkV)而放 述電子束1 9的熱電子放射型電子槍1 1 ;和將被放射之電子 束1 9,加以聚光之電容透鏡1 2 ;和藉由以光束調變器1 8所 φ 調變之訊號源17之訊號,來進行電容透鏡12所聚光之電子 束1 9之調變的,斷開電極1 3 ;和將以斷開電極1 3所偏向之 電子束1 9,加以遮斷的孔徑1 4 ;和將電子束1 9之振幅,根 據控制器2 6之訊號加以偏向的偏向電極1 5 ;和將電子束1 9 聚光爲細微之光束徑,而照射於母片21上的物鏡16。 試料室20中,係具備保存母片2 1並加以旋轉的驅動手 段亦即旋轉台2 2,和將母片2 1於水平方向移動,使電子束 1 9與母片2 1之水平方向相對位置改變的變動手段,亦即移 φ 動台23 ;旋轉台22及移動台23,係經由導引螺旋24,而被 傳導有交流伺服馬達2 5之動力。 如第1圖所示,由電子槍1 1所放射之電子束1 9,係由 電容透鏡1 1 2來聚光。斷開電極1 3,係藉由訊號源1 7之訊 號被光束調變器1 8調變後的電場,將電子束1 9之行進方向 加以偏向,而調變電子束1 9其孔徑1 4之通過量。通過孔徑 1 4之電子束1 9,係由偏向電極1 5被偏向控制,由物鏡1 6再 次聚光後,被照射至母片2 1的表面。 偏向電極1 5,係將控制器2 6之振幅控制訊號所造成的 -17- 200535992 (14) 高頻振動之振幅加以控制,依此,來控制電子束1 9的偏向 量。控制器2 6,係根據照射於母片2 1之電子束1 9其在母片 2 1上的位置,和針對該位置母片2〗之旋轉數資訊,來進行 運算,而控制電子束1 9的偏向量。 又’控制器26,係藉由照射於母片21之電子束19與母 片2 1的水平方向相對位置之旋轉數控制訊號,來控制交流 伺服馬達2 5,而作爲控制母片2 1之旋轉數的母片旋轉控制 ^ 手段並產生功能。 其次,說明母片21。第2圖,係說明母片之記錄範圍 的圖。第2圖(a)係表示於半徑方向,被均等區分的複數記 錄範圍;第2圖(b),係表示具有不同寬度的複數記錄範圍 〇 如第2圖(a)所示,母片21a,係具有於半徑方向被均 等分割的複數記錄範圍(記錄範圍1 a〜記錄範圍3 a)。被分 割之各記錄範圍的寬度,雖無特別限定,但通常以 0 · 2〜0 · 5 m m,而理想爲〇 . 5〜5.0 m m的範圍。 於半徑方向被均等分割的複數記錄範圍(記錄範圍1 a〜 記錄範圍3 a)其半徑方向寬度,通常係如以下來決定。亦 即,在各記錄範圍內母片以一定旋轉數旋轉時,於半徑方 向被均等分割的複數記錄範圍內,最內周側之線速度和最 外周側之線速度的比(各記錄範圍之最外周線速度/各記錄 範圍之最內周線速度),通常爲1.3以下;理想上是在1.2以 下之範圍地,來預先設定各記錄範圍之寬度者爲佳。藉由 如此設定各記錄範圍之寬度,可將於半徑方向被均等分割 -18- 200535992 (15) 的複數記錄範圍內,每單位面積之電子束照射量之內外周 差更加降低。亦即,可降低藉由進行特定顯影處理所形成 的各記錄範圍內之凹軌,其凹軌寬度的內外周差。 如第2圖(b)所示,母片21b,係具有於半徑方向被以 特定寬度分割的複數記錄範圍(記錄範圍lb〜記錄範圍3b) 。複數記錄範圍(記錄範圍lb〜記錄範圍3b)之寬度,係被 設定爲在母片2 1 b之半徑方向,由內周側往外周側變大者 •。 如此,將母片2 1 b其於半徑方向被分割爲同心圓狀之 複數記錄範圍(記錄範圍lb〜記錄範圍3b)的寬度,使設於 內周側之記錄範圍寬度較外周側爲窄,則可將線速度變化 較大之內周側之記錄範圍內,其最內周側之線速度與最外 周側之線速度的比(各記錄範圍之最外周線速度/各記錄範 圍之最內周線速度)更加降低;結果,可針對線速度變化 較大之內周側之記錄範圍內,將每單位面積之電子束照射 φ 量之內外周差更加降低。亦即,可降低藉由進行特定顯影 處理所形成的內周側記錄範圍內之凹軌,其凹軌寬度的內 外周差。 又,於半徑方向被分割爲同心圓狀之各記錄範圍的旋 轉數,其各記錄範圍間平均線速度之最大値和最小値的比 (各記錄範圍整個平均線速度最大値/各記錄範圍整個平均 線速度最小値),通常是1.1以下;理想上是在1.05以下之 範圍地,來預先設定各記錄範圍之寬度者爲佳。如此設定 各記錄範圍之旋轉數,可將各整個記錄範圍中,每單位面 -19- 200535992 (16) 積之電子束照射量之差更加降低。亦即,亦可降 行特定顯影處理所形成的各整個記錄範圍內之凹 軌寬度的變動。又,將於半徑方向被分割爲同心 記錄範圍的旋轉數保持一定,可進行旋轉誤差少 制,而可保持電子束照射之資訊的高度位置精確 更且,母片21a及母片12b之旋轉數,係在 各記錄範圍(記錄範圍1 a〜記錄範圍3 a,記錄範園 φ 範圍3b)之邊界部,對應各記錄範圍之旋轉數的 再次整合訊號之同步的遷移範圍(未圖示),通常 軌左右。各記錄範圍間,旋轉數之變更通常係以 內,或是10msec以內的任一個短時間間隔,來 佳。 如本實施方式所適用之母片照射裝置1 〇〇般 持母片2 1之旋轉數爲一定,一邊照射電子束1 9時 射於電子束感應阻劑薄膜之電子束1 9,其每單位 φ 射量並非一定。故,形成於各記錄範圍之記錄軌 於各記錄範圍之最內周側和最外周側會有改變。 但是,即使如此般記錄軌之凹軌寬度變化的 亦可藉由將此等訊號相加來正規化,而可修正某 訊號強度。從而,使母片2 1中於半徑方向被分割 狀之複數記錄範圍,其寬度與母片2 1之旋轉數爲 加以預先設定,而可將各記錄範圍內之凹軌的凹 動,調整在可接受之範圍內。依此,可製造出母 之C/N比(載子位準/雜訊位準)被保持在容忍値 低藉由進 軌,其凹 圓狀之各 之旋轉控 度。 被分割之 H lb〜記錄 變化;故 係設置1 〇 10旋轉以 進行者爲 ,一邊保 ,通常照 面積之照 的寬度, 情況下, 個程度的 爲同心圓 適當地, 軌寬度變 片21整體 以內的, -20- 200535992 (17) 資訊記錄媒體用母片。 第3圖,係說明將電子束偏向於與軌幾乎垂 之型態的圖。第3圖係針對母片2 1其於半徑方向 同心圓狀之複數記錄範圍中的某一個範圍1,表 內周側之軌a(軌a、軌a+l、軌a + 2.··),設置於 之軌b (軌b、軌b + 1、軌b + 2…),設置於外周側 c、軌c + 1、軌c + 2···),其分別照射於各軌之電 頻振動。 • 第3 圖中,橫軸表示母片2 1之軌方向,縱 片2 1之半徑方向。如第3圖所示,使用使電子束 幾乎垂直之方向高頻振動的功能,實際的擴大照 2 1之電子束1 9的照射面積,而可將藉由進行特定 而形成於各記錄範圍之凹軌,其凹軌寬度加以增 更且,照射於母片2 1中於半徑方向以特定寬 複數記錄範圍的電子束1 9,其偏向量係對各個記 .φ 自母片2 1之內周側向著外周側增加者爲佳。亦同 所示,在於內周側之軌a(軌a、軌a+l、軌a + 2 周側相比因其線速度較慢,每單位面積之電子束 大,故將電子束1 9的偏向量控制爲少者爲佳;另 在於外周側之軌c(軌c、軌c+1、軌c + 2.·.),因 較快,每單位面積之電子束照射量爲小,故將電 偏向量控制爲大者爲佳。 亦即,如此於本實施方式中,若將電子束19 母片2 1之軌幾乎垂直之方向的手法,則通常配合 直之方向 被分割爲 示設置於 中周部分 之軌c (軌 子束的高 軸表示母 1 9於與軌 射於母片 顯影處理 加。 度分割之 錄範圍, 口如第3圖 ··.),與外 照射量爲 一方面, 其線速度 子束I 9的 偏向於與 母片2 1在 -21 - 200535992 (18) 特定半徑位置之線速度連續變化的,每單位面積之電子束 照射量,其造成之各記錄範圍內部凹軌寬度之內外周差’ 此種問題可藉由控制電子束1 9之偏向量’來對各記錄範圍 之每個保持一定旋轉數,並可時限於母片上形成平均之軌 的凹軌寬度。 如此,根據母片2 1之半徑方向位置資訊’和各記錄範 圍之旋轉速度資訊’則可賦予顫動(Warble)偏向’擴大各 9 φ 記錄範圍之電子束1 9的照射面積’而可減低所形成之凹軌 - 的凹軌寬度內外差。 在此,針對母片2 1之各半徑位置r的電子束1 9之偏向 量,係將各半徑位置r之線速度作爲V(r),不進行線速度 V(〇之電子束19的偏向,而是將進行特定顯影處理所形成 之凹軌的凹軌寬度 W(r),且在旋轉之同時進行電子束之 偏向所形成之凹軌的凹軌寬度爲Wmax之情況下,控制爲 \Vmax-W(〇者爲佳。又,使電子束19之偏向頻率在 .φ V(r)/W(r)以上地,將電子束19於對軌方向幾乎垂直的加以 偏向者爲佳。 如此,將偏向電及1 5造成電子束1 9之高頻顫動下的顫 動量之控制,加以組合,則針對母片2 1之特定記錄範圍內 ,配合線速度連續變化之每單位面積的電子束照射量變化 ,其所造成的記錄軌的凹軌寬度變動會被抵銷,而可保持 母片2 1之各記錄範圍之旋轉數爲一定,並將記錄軌之凹軌 寬度保持爲平均。亦即,根據被照射有電子束1 9之母片2 1 的位置資訊,和針對照射有電子束1 9之母片2 1上之位置的 -22- 200535992 (19) 旋轉數資訊,來進行運算,則可設定電子束1 9的偏向量, 更加減低各記錄範圍內部之記錄軌的凹軌寬度變動,而可 製造出母片21整體之C/N比(載子位準/雜訊位準)被降低 的資訊記錄媒體用母片。 其次,說明母片21之構成。母片21,係於適當之基板 上旋轉塗佈有電子束感應阻劑後,以加熱處理來去除多餘 溶劑,而形成有電子束感應阻劑薄膜。 作爲母片2 1之基板,例如可舉出矽晶圓、石英玻璃、 ^ 蘇打玻璃、表面形成有導電層之石英玻璃、表面形成有導 電層之蘇打玻璃等。此等之中,將矽晶圓充能(Charge up) 者亦多少適用。 電子束感應阻劑,通常係使用將酸產生劑和黏著樹脂 ,以溶解有鹽基性化合物而調整爲鹽基性的溶劑,來加以 稀釋者。 作爲酸產生劑,只要是藉由電子束之照射來改變化學 • · 構造,而產生酸性物質者則沒有特別限定,例如三氯磺酸 • 基三苯毓,九氟丁基磺酸三苯毓,三氯磺酸基二苯碘,九 氟丁基磺酸二苯碘,九氟丁基磺酸二苯p -甲氧基苯,九 氟丁基磺酸二苯P-乙基苯等鑰鹽類;1,8-萘二甲醯胺基甲 烷磺酸酯,1,8 -萘二甲醯胺基三氯磺酸酯,1,8 -萘二甲醯 胺基甲苯磺酸酯,安息香甲苯磺酸酯等磺酸酯類;二(苯 磺醯基)二偶氮甲烷,二(p-氯苯磺醯基)二偶氮甲烷,二( 環己基磺醯基)二偶氮甲烷等偶氮甲烷類。此等之中,係 以三氯磺酸基三苯毓等鑰鹽,可實現高感度而爲理想。酸 - 23- 200535992 (20) 產生劑之具體例如以下所示200535992 (1) IX. Description of the invention [Technical field to which the invention belongs] The present invention relates to a method for preparing a master film for an information recording medium, etc. In detail, it relates to an electron beam irradiation method that improves the accuracy of a recording position. §3 The method of making master films for recording media. [Prior art] In recent years, with the increase in the amount of data to be recorded, it becomes necessary to increase the recording capacity and recording density of the required information recording medium, and further increase the access speed of the recorded information. Therefore, the pit size or groove width of the substrate of the optical disc is gradually reduced year by year, and the track pitch is also narrowed. Generally, fine structures such as depressions or recessed tracks that are previously formed on the optical disc substrate are made by a lithography method using laser light. Therefore, the minimum size of a depression or recess that can be formed is related to the wavelength of the laser light emitted by the light source and the number of openings (NA) of the condenser lens. Because the lens NA of the exposure device is 0. 9 is close to the limit, so the previous master exposure device using laser light uses the shorter wavelength of laser light to cope with the trend of miniaturization. Specifically, for DVD, for example, a 気 laser having a wavelength of 351 nm is used; and for BluRay Disc, for example, a second high-frequency wave using an excitation beam of argon laser is used, with a wavelength of 2 5 Laser light of 7 nm or 2 4 4 nm. In the same manner as the optical disc, the lithography method is used to form a fine-structure semiconductor manufacturing process. For example, shorter wavelength laser light such as argon fluoride excimer laser light having a wavelength of 19 nm is used. However, in this pulsed laser light source, the intensity of each pulsed light is inconsistent, for example, the averageness of the pit size will be impaired. -5- 200535992 (2) Therefore, for the surface exposure method used in non-semiconductor processes, the direct drawing method The optical disc manufacturing process is not applicable. For this reason, it has not been found that the far-ultraviolet laser, which is the second highest modulation wave using the lasing beam of argon laser, can continuously excite with a shorter wavelength and create a more subtle depression or recessed laser light source. Therefore, the manufacturing of discs with a higher recording density is based on the high possibility of using an electron beam drawing device, and it is continuously being developed. However, in order to make a spiral recording track φ for a mother disc on an optical disc, it is roughly classified into keeping the light amount and linear velocity of the exposure beam constant, and continuously changing the number of rotations of the mother disc and the moving speed of the slider according to the radial position. CL V (Constant Linear Velocity) method; and CAV (Constant Angular Velocity) method that keeps the number of rotations of the mother film and the moving speed of the slider constant and continuously changes the light amount of the exposure beam according to the radial position 2 Species. In general, dedicated live media or recordable media that value recording capacity only uses the CLV method, while computer-use media that values access speed is created using the CAV method. For example, it can be regarded as a φ-optical disk, and the localization of the address at the correct specific location can shorten the access time. That is, in order to record correctly at a specific position on the disc, it must be a CA that is easy to perform drive control and rotation control in the radial direction. V way. In addition, in recent years, the purpose of dramatically improving the recording density is to propose a complex recording method that only adjusts the recording position of a small number of bits, or a two-dimensional recording that forms a mark with a plurality of bit rows; for optical disc masters It is necessary to improve the accuracy of the recording position. On the other hand, the electron beam used in the electron beam drawing device does not exist.-200535992 (3) The acoustic beam (A 0) element of the master exposure device using the previous laser light can be arbitrarily controlled. The device controls the amount of electron beam exposure by adjusting the number of electrons (current 値) passing through the opening. However, for example, when the number of rotations of the fixed mother sheet is within a range of 20 mm to 60 mm in the radius of the mother sheet and a spiral recording track is formed, the current 値 must be changed by about 3 times at the innermost and outermost periphery. In addition, it is difficult to control the scattering of electron beams from behind the substrate, or the amount of charge up of the substrate (Charge up), which has problems such as changing the axis of the electron beam if the current 値 emitted by the electron gun is changed. ; It is not easy to change the number of rotations of the fixed master with the CAV irradiation method of the current 配合 in accordance with the radial position, and there are also considerable obstacles to the manufacture of stable master discs. Fig. 10 is a diagram illustrating the relationship between the radial position and the number of rotations of the master disc for optical discs with respect to the CLV method. The horizontal axis of Fig. 10 is the radial position of the master disc for optical discs, and the vertical axis is the number of rotations. Curve A represents the derivation of the ideal rotation number for the C LV method as the target of the optical disc master; its φ represents the larger radius position (outer periphery), and the rotation number is smaller. As shown in Figure 10, in the CLV method, carefully observe that the number of rotations of the master disc for the optical disc is kept constant, and it is changed stepwise at a very short time interval (the interval C for the number of rotation updates) (error B) Rotate the digital ground for digital control. On the other hand, it does not change the number of rotations of the mother piece in accordance with the inertial force of the rotation. Generally, the rotation of the mother piece is in the form of curve A and the step-like instructions output by digital control are repeated in small amounts. , To proceed. The interval C for the rotation number update is limited by the communication speed or response speed with the control device and the bit resolution of the rotation number of the control device. -7- 200535992 (4). Therefore, if the number of bits indicating the number of rotations is insufficient, and there is no degree of error accumulated to detect the difference from curve A; or the operation of the control device is restricted by communication with other output circuits; or If the update of the rotation number is delayed due to communication failure of the input and output of information, etc., a huge rotation control error (error D) will occur. In addition, the CLV drive has different numbers of rotations on the inner and outer perimeters. Therefore, the inner frequency side with a larger number of rotations has a looser frequency update φ interval, which determines the rotation speed, than the outer perimeter. Therefore, in the inner periphery, it is easier to cause a positional deviation between a specific recording position and a position where the electron beam is actually irradiated. On the other hand, if the speed at the inner periphery is reduced, the irradiation time of the entire disc will be significantly prolonged, so it is not suitable for localized disc manufacturing. In addition, prolonging the irradiation time will greatly affect the output variation of the electron beam, so there is a considerable obstacle to high-density optical disc masters that are stably manufactured when the master film is made, and the amount of pre-recorded information has increased dramatically. On the other hand, when analog control is performed with an open loop, the reference clock indicating the rotation speed φ degree can be compared with the output of the rotary encoder of the slice rotation speed to prepare a specific lamp waveform, so it is difficult to produce such a waveform. Problem; however, it is necessary to set the gain change in detail in accordance with the amount of change in the rotation speed. This kind of management is usually not easy. Therefore, in the example of a single-direction drive such as the control of the rotating shaft and the slider, the closed loop is used for digital control. This is the current mainstream. Therefore, the CLV method does not necessarily perform ideal rotation control. Therefore, in order to realize the exposure position with extremely high accuracy, it is conceivable that the CAV method that keeps the number of rotations of the mother film and the moving speed of the slider is constant; for example, it is reported that for the CAV method, each Unit surface 200535992 (5) Product exposure as a certain exposure method (refer to patent documents; 1) β [Patent Document 1] Japanese Patent Laid-Open No. 2 0 0 0-〇 1 1 4 64 [Inventive Content] Problem to be solved However, as described in Patent Document 1, for the CAV method, the irradiation amount per unit area of the electron beam is regarded as a constant method. The inner and outer peripheries having different rotation speeds φ are radiated by the electron gun. The current 値 must be changed drastically, and there is a problem that the axis of the electron beam cannot be avoided. In addition, as described in Patent Document 1, the method of pulse-modulating the electron beam and controlling the irradiation amount of the electron beam according to the working ratio of the pulse is generally used to blank the electron beam in order to ensure the bias vector. It is not the electrostatic deflection that responds fast, but the electromagnetic deflection. Therefore, the number of electrons passing through the opening part will change, so the formed concave track will have a problem of insufficient width uniformity. That is, in order to solve this problem, it is necessary to suppress the rotation number φ to be low, and the irradiation time of the entire disc is prolonged, so it is not suitable for the manufacture of high-density discs. Even if electrostatic biased disconnection is used, in order to perform the modulation, the bias vector of the electron beam must be increased; that is, the capacitance of the biased electrode for disconnection will increase, resulting in a limitation of the modulation speed. The present invention is to solve the technical problem that such an electron beam drawing device will become a relief when the master for information recording media is exposed. That is, it is an object of the present invention to provide a method for forming a master film of an information recording medium under the irradiation of an electron beam having an improved recording position accuracy. Still another object of the present invention is to provide a mother sheet irradiation device for information recording media capable of performing electron beam irradiation for improving recording position accuracy. Furthermore, another object of the present invention is to provide a method for manufacturing an information recording medium with improved recording position accuracy. Furthermore, another object of the present invention is to provide an information recording medium with improved recording position accuracy.手段 Means to solve the problem% The above-mentioned problem should be solved, but the present invention proposes a method for creating a master film for an information recording medium, which aims at using an electron beam sensing device that has a change in polarity due to electron beam irradiation. Resistor film mother sheet, electron beam irradiation means for irradiating electron beams, driving means for holding and rotating the mother sheet, and means for changing the relative position of the electron beam irradiation means and the mother sheet in a horizontal direction, the mother sheet is irradiated The device is used to irradiate the electron beam, and the information recording medium forming a spiral or concentric circular track is made of a master-square method; the characteristic is that the range of the irradiated electron beam is divided into concentric circles divided in the radial direction. The multiple recording ranges of the state; the amount of electron beam irradiation per unit time in the range of the irradiated electron beams of the mother sheet is kept constant, and the number of rotations of the mother sheet is controlled to be constant for each of the distinguished recording ranges. By adopting such a structure, the current radiated by the electron gun becomes constant, so the axis variation of the electron beam can be suppressed; and the rotation control with a small rotation error due to a fixed rotation speed can be maintained, so the information of the irradiated electron beam can be maintained Height position accuracy. In the present invention, the range of the irradiated electron beam is divided into -10- 200535992 in the radial direction. (7) The concentric circle-shaped plural recording range 'refers to a range in which information can be recorded or reproduced in a specific device; usually' and settings As indicated by the barcode on the inner periphery of the master film, the scope of recording master film management information, etc. is not the same. In addition, in order to form a depression in which specific information is recorded in advance on the mother film, a method of interrupting the electron beam by disconnection is generally adopted; however, with such a control, the amount of electron beam irradiation per unit time is irradiated on the mother film. When changing, it is also within the scope of the present invention to use a method of making the mother film for a certain information recording medium for the timing when the electron beam is not cut off. In addition, in the present invention, if the boundary portion of the discriminated recording range is controlled from the discriminated recording range on the outer periphery to the discriminated recording range on the inner periphery in a stepwise manner, the number of rotations is controlled. The inner and outer peripheral difference of the amount of electron beam irradiation per unit area is reduced, and the electron beam irradiation area of the mother substrate can be made larger. In addition, for the boundary portion of the discriminated recording range, the recording range divided by φ from the inner periphery to the discriminated recording range from the outer periphery is controlled to increase the number of rotations in stages, and the same result can be obtained. Effect, and such an information recording medium using the method of making a master film is also within the scope of the present invention. Furthermore, it adopts a structure in which the number of rotations on the outer recording side is higher, and the electron beam is reduced compared with the previous CAV method. The irradiation time can be stably performed to manufacture the information recording medium. Moreover, in the present invention, the ratio of the maximum linear velocity and the minimum linear velocity is controlled to -11-200535992 (8) 1 for the differentiated recording range of the rotating mother film.  It is better to be less than 3; moreover, the ratio between the maximum 値 of the average linear velocity and the minimum 値 of the average linear velocity between the recorded ranges of the rotating mother film is preferably controlled to be less than 1.1. If the linear velocity in the recording range of the rotating master film, the average linear velocity between the recording ranges, and the width of the recording range are placed within the above-mentioned ranges, then for each recording range, the The variation of the width of the recessed track of the recessed track formed by the Φ of the mother sheet of the electron beam sensing resist film having a polarity change is adjusted within an acceptable range. In addition, for all areas where the electron beam is irradiated with a small area of the electron beam, the number of rotations of the rotating mother wafer is set to be a constant 'to control the ratio of the maximum linear velocity to the minimum linear velocity' to 1 · When 3 or less, the number of recording ranges that are divided into concentric circles in the radial direction can be set as 10, and the width of the divided recording range that is set on the inner peripheral side of the master film is set relatively. The narrower φ width of the recording range that is distinguished on the outer peripheral side of the mother film is better; for the recording range on the inner peripheral side of the mother film that is set to have a large change in the rotational linear velocity, the per-unit area can be further reduced. The difference between the inner and outer circumferences of the irradiation amount of the electron beam. In other words, even if the recording range is set on the inner peripheral side of the mother film having a large change in the rotational linear velocity, the inner and outer peripheral differences in the width of the recessed track of the recessed track formed by the specific development process can be further reduced. Furthermore, according to the present invention, it is proposed to use a mother wafer irradiation device further equipped with an electron beam and a flattening means for vibrating an electron beam to a rail in a nearly vertical direction to irradiate the electron beams to form a spiral or concentric shape. The information recording medium of the circular track is made of a master film; in which, for the range of each recorded record-12-200535992 (9), the bias vector of the electron beam is controlled to increase from the inner periphery to the outer periphery. By adopting such a structure, the local position accuracy of the information irradiated by the electron beam can be maintained; furthermore, it is possible to reduce the inner and outer peripheral differences of the width of the concave track within the range of the irradiated electron beam 'concave tracks formed by specific development processing' . Furthermore, let the linear velocity of each radial position r be V (r), and the electron beam deflection of the linear velocity V (r) is not performed, but the recessed track width of the recessed track formed by the specific development process is defined as W (r) ), And when the width of the recessed orbit formed by the deflection of the electric φ sub-beam while rotating is taken as Wmax, the bias vector of the electron beam for each radial position is Wmax-W (r) ground, It is better to control it; in this way, the width of the grooves in each of the divided recording ranges can be made even. Furthermore, it is better to make the deflection frequency of the electron beam above V (0 / W (r), and deflection the electron beam in a direction almost perpendicular to the orbital direction. This can suppress the formation by performing a specific development process. Second, the present invention grasps a φ-radiation device for a mother film used as an information recording medium, which is characterized by having a mother film having an electron beam sensing resist film having a polarity change due to electron beam irradiation. Electron beam irradiation means for irradiating the electron beam; and driving means for holding and rotating the mother sheet; and changing means for changing the relative position of the electron beam irradiation means and the mother sheet in the horizontal direction; and the range of the electron beam irradiation for the mother sheet, It is divided into a plurality of recording ranges that are divided into concentric circles in the radial direction, and the amount of electron beam exposure per unit time in each of the divided recording ranges is kept constant. The number of rotations is a control method for controlling the number of rotations. By adopting such a configuration, the current 値 emitted from the electron gun can be kept constant at -13- 200535992 (ίο), so it can be suppressed. The axis of the sub-beam fluctuates; and because the rotation speed is fixed, the rotation control with less rotation error is performed, so that the accuracy of the height recording position of the information irradiated by the electron beam can be maintained. Furthermore, if the present invention has a record for distinguishing The boundary part of the range is controlled from the outer recording range to the inner recording range, and the number of rotations is controlled step by step. The control means will reduce the electron beam irradiation per unit area. The difference between the internal and external perimeters can be increased by φ to increase the irradiation area of the electron beam of the mother film. ^ Furthermore, the mother film irradiation device for the information recording medium to which the present invention is applied is a boundary portion of the distinguished recording range. It is better to change the number of rotations of the mother film to 10 rotations or less; since the number of rotations that are not related to recording and reproduction is changed, the transition range of the transition range is reduced, so that the recording capacity can be prevented from decreasing. In the master film irradiating device used for the information recording medium to which the present invention is applied, the master film irradiating device is further equipped with a rotary control of the master film and simultaneously outputs. Φ The rotation angle information output means is preferred if the rotation angle information of the mother piece is output; in this way, resynchronization with the signal generation means recorded by the electron beam can be implemented, and the radial direction is divided into plural concentric circles. The recording range of the state is corrected by the rotation error caused by the change in the number of rotations in the radial direction. Furthermore, the accuracy of the recorded position of information can be improved for the plural recording ranges that are divided into concentric circles by plural numbers in the radial direction. In addition, in the mother film irradiation device for the information recording medium to which the present invention is applicable, it is better to have a bias control means for controlling the bias vector of the electron beam; for the recording range divided in the radial direction, from the inner periphery to the outer periphery In order to make -14-200535992 (11) the electron beam deviated in a direction perpendicular to the orbital direction, the deflection vector is controlled in an increased manner, and the difference between the inner and outer circumferences of the formed concave track width can be further reduced. Furthermore, the means for controlling the deflection of the electron beam is preferably a static deflector with a fast response speed. This is to suppress the meandering of the concave tracks formed by performing a specific development process. It is also preferable that the master film irradiation device for an information recording medium to which the present invention is applied is further provided with a modulation Φ control means capable of interrupting the electron beam by interrupting the electron beam. On the other hand, the present invention grasps a method for manufacturing an information recording medium, which is a method for manufacturing an information recording medium having a specific spiral or concentric circular track, and is directed to a method for forming an information recording medium including a specific concave track. A mother sheet forming process of the mother sheet and a metal mold forming the shape of a recessed track of the mother sheet for the information recording medium to be formed, the mold forming process; and the mother sheet process having an electron beam irradiation means, and A specific electron beam irradiating device for changing the relative position of the mother film in the horizontal direction and a driving method for rotating the mother film by Φ; its characteristic is the electron beam induction resistance of the surface of the mother film which is rotated by the driving method. Agent film, the electron beam is irradiated by the electron beam irradiation means, and then the horizontal position of the electron beam irradiation means and the mother sheet is changed by the changing means. When the electron beam is irradiated by the electron beam irradiation means, the mother sheet is irradiated The area of the electron beam is divided into a plurality of recording ranges that are divided into concentric circles in the radial direction, and the mother plate is irradiated with electrons. The amount of electron beam irradiation per unit time in the beam range is kept constant, and then the electron beam is irradiated with a constant number of rotations of the mother substrate. Furthermore, according to the present invention, an information recording medium is provided. The information recording medium is a -15-200535992 (12) information recording medium having a spiral or concentric circular recording track formed on a substrate; its characteristics are provided on the substrate A plurality of recording ranges that are divided into concentric circles with a specific width; and a migration range that is provided at a boundary portion of each of the separated recording ranges and has a width in the radial direction of the substrate of 10 tracks or less. The migration range in the information recording medium to which the present invention is applied is set to be less than 10 tracks, reducing the track of irrelevant recording and reproduction, and preventing the reduction of the recording capacity. It is better to have re-synchronous re-synchronous Φ step control marks near the migration range or migration range. When forming a recording range that is divided into multiple concentric circles in the radial direction, the boundary of the recording range The rotation error caused by the change in the number of rotations near the radial position is corrected. In the information recording medium to which the present invention is applied, each recording range that is divided into concentric circles with a specific width on the substrate, and the ratio between the radial position on the outer peripheral side and the radial position on the inner peripheral side is one of 1.3 or less. Better. Furthermore, in the information recording medium to which the present invention is applied, the 'width of the divided recording range provided on the inner peripheral side of the substrate' is larger than the width of the divided recording range provided on the outer peripheral side of the base Φ plate is Narrower is better. In the above, according to the present invention, a method for preparing a master for information recording media using an electron beam with improved recording position accuracy can be provided. [Embodiment] Hereinafter, the best method for implementing the present invention will be described with reference to the drawings. Best Mode (hereinafter referred to as the implementation mode). FIG. 1 is a -16-200535992 (13) diagram illustrating a mother film irradiation apparatus to which this embodiment is applied. The master wafer irradiating device 100 shown in Fig. 1 is composed of a mirror tower accommodating an electron optical system as an electron beam irradiation means], and a sample chamber 20 having a master wafer storage rotating means. The mirror tower 10 and the sample chamber 20 are maintained in a vacuum state by a suitable vacuum device (not shown). The electron optics system is installed inside the mirror tower 10 and includes a thermionic electron gun 1 1 that emits an electron beam 19 at a specific applied voltage (for example, 5 OkV); and an electron beam to be emitted 19 , The condenser lens 12 to which the light is focused; and the modulation of the electron beam 19 to the condenser lens 12 by the signal of the φ modulated signal source 17 by the beam modulator 18 Open electrode 1 3; and aperture 14 which will block the electron beam 19 biased by disconnect electrode 13; and a bias electrode which biases the amplitude of the electron beam 19 according to the signal from the controller 26 15; and the electron beam 19 is condensed to a fine beam diameter, and is irradiated onto the objective lens 16 on the mother substrate 21. The sample chamber 20 includes a rotary table 22, which is a driving means for holding and rotating the mother substrate 21, and moves the mother substrate 21 in a horizontal direction so that the electron beam 19 and the mother substrate 21 are horizontally opposed to each other. The means for changing the position, that is, moving the moving table 23; the rotating table 22 and the moving table 23 are transmitted with the power of the AC servo motor 25 through the guide screw 24. As shown in Fig. 1, the electron beam 19 emitted by the electron gun 11 is focused by a capacitive lens 1 12. Disconnecting the electrode 1 3 is to deflect the traveling direction of the electron beam 19 by the electric field modulated by the beam modulator 18 by the signal from the signal source 17 and modulate the electron beam 19's aperture 1 4 Whose throughput. The electron beam 19 passing through the aperture 14 is controlled by the deflection electrode 15 and is condensed again by the objective lens 16 to be irradiated onto the surface of the mother substrate 21. The deflection electrode 15 controls the amplitude of the high-frequency vibration caused by the amplitude control signal of the controller 26, and controls the deflection amount of the electron beam 19 accordingly. The controller 2 6 controls the electron beam 1 based on the position of the electron beam 1 9 on the mother film 21 and its position on the mother film 21 and the rotation number information of the mother film 2 at that position. Partial vector of 9. Also, the controller 26 controls the AC servo motor 25 by controlling the number of rotations of the relative position of the electron beam 19 irradiated on the mother film 21 and the mother film 21 in the horizontal direction, and controls the AC servo motor 25. The rotation number of the master rotation control means and generates a function. Next, the mother sheet 21 will be described. Fig. 2 is a diagram illustrating a recording range of a mother film. Figure 2 (a) shows the plural record ranges equally divided in the radial direction; Figure 2 (b) shows the plural record ranges with different widths. As shown in Figure 2 (a), the master piece 21a , Has a plurality of recording ranges (recording range 1 a to recording range 3 a) which are equally divided in the radial direction. Although the width of each of the divided recording ranges is not particularly limited, it is usually 0 · 2 ~ 0 · 5 m m, and is preferably 0.  5 ~ 5. 0 m m range. The plural recording ranges (recording range 1 a to recording range 3 a) which are equally divided in the radial direction are generally determined in the following manner in the radial direction width. That is, the ratio of the linear velocity on the innermost peripheral side to the linear velocity on the outermost peripheral side in the plural recording ranges that are equally divided in the radial direction when the mother film is rotated by a certain number of rotations in each recording range. Outer peripheral linear velocity / inner peripheral linear velocity of each recording range), usually 1. 3 or less; ideally 1. For the range below 2, it is better to set the width of each recording range in advance. By setting the width of each recording range in this way, it is possible to divide evenly the plural recording ranges of -18-200535992 (15) in the radial direction, and the peripheral difference between the irradiation amount of the electron beam per unit area is further reduced. That is, it is possible to reduce the difference between the inner and outer peripheries of the width of the concave tracks in each recording range formed by performing a specific development process. As shown in Fig. 2 (b), the mother film 21b has a plurality of recording ranges (recording range lb to recording range 3b) divided by a specific width in the radial direction. The width of the plural recording range (recording range lb to recording range 3b) is set to be larger in the radial direction of the mother film 2 1 b from the inner peripheral side to the outer peripheral side. In this way, the mother film 2 1 b is divided into a plurality of concentric circles with a plurality of concentric circles in the width of the recording range (recording range lb to recording range 3b), so that the width of the recording range provided on the inner peripheral side is narrower than the outer peripheral side. The ratio of the linear velocity at the innermost peripheral side to the linear velocity at the outermost peripheral side within the recording range of the inner peripheral side where the linear velocity changes greatly (the outermost peripheral linear velocity of each recording range / the innermost of each recording range) (Peripheral linear velocity) is further reduced; as a result, for the recording range on the inner peripheral side where the linear velocity changes greatly, the inner and outer peripheral differences of the amount of irradiation of the electron beam per unit area by φ can be further reduced. That is, it is possible to reduce the difference between the inner and outer peripheries of the concave track width within the recording range of the inner peripheral side formed by performing a specific development process. In addition, the number of rotations of each recording range divided into concentric circles in the radial direction is the ratio of the maximum 値 and the minimum 平均 of the average linear velocity between the recording ranges (the maximum average linear velocity of the entire recording range 値 / the entire recording range) The average linear velocity is the smallest 値), usually 1. 1 or less; ideally 1. For ranges below 05, it is better to set the width of each recording range in advance. By setting the number of rotations of each recording range in this way, the difference in the amount of electron beam exposure per unit area of -19- 200535992 (16) in each entire recording range can be further reduced. That is, it is also possible to reduce variations in the width of the groove tracks in each of the entire recording ranges formed by the specific development process. In addition, the number of rotations, which are divided into concentric recording ranges in the radial direction, is kept constant, and the rotation error can be reduced, and the height position of the information irradiated by the electron beam can be kept more accurate. The number of rotations of the mother film 21a and the mother film 12b , Is at the boundary of each recording range (recording range 1 a to recording range 3 a, recording range φ range 3 b), corresponding to the synchronous migration range (not shown) of the reintegration signal corresponding to the rotation number of each recording range, Usually around the rails. The change in the number of rotations between recording ranges is usually within a short interval of 10 msec or better. The number of rotations of the mother substrate 21, which is the same as that of the mother substrate irradiating device 100 applicable to this embodiment, is constant, while the electron beam 19 is irradiated on the electron beam sensing resist film when the electron beam 19 is irradiated. The φ shot is not constant. Therefore, the recording track formed in each recording range is changed on the innermost peripheral side and the outermost peripheral side of each recording range. However, even if the recessed track width of such a recording track is changed, the signal strength can be corrected by normalizing by adding these signals. Therefore, the plurality of recording ranges of the master 21 are divided in a radial direction, and the width and the number of rotations of the master 21 are set in advance, and the concave movement of the concave tracks in each recording range can be adjusted to Within acceptable range. Based on this, the mother's C / N ratio (carrier level / noise level) can be made tolerant 値 low rotation control of each concave shape of the circular track. The divided H lb ~ records the change; therefore, it is set to perform a rotation of 1010, while keeping the width of the area, usually in accordance with the width of the area. In this case, the degree is concentric circles. Within -20-200535992 (17) Masterpiece for information recording media. Fig. 3 is a diagram illustrating a state in which the electron beam is deflected to a position almost perpendicular to the orbit. FIG. 3 shows a range 1 of a plurality of recording ranges of a concentric circle in the radial direction for the mother film 21, and the track a (track a, track a + 1, track a + 2) on the inner peripheral side of the table. ··), installed on the rail b (rail b, rail b + 1, rail b + 2, etc.), installed on the outer peripheral side c, rail c + 1, rail c + 2 ...), which are irradiated to each Electric frequency vibration of the rail. • In Figure 3, the horizontal axis indicates the orbital direction of the mother film 21 and the radial direction of the vertical film 21. As shown in FIG. 3, using the function of making the electron beam vibrate in a direction almost vertical, the irradiation area of the electron beam 19 of the photo 2 1 is actually enlarged, and it can be formed in each recording range by specifying it. The concave track, the width of the concave track is increased, and the electron beam 19 is irradiated on the mother film 21 with a specific wide and complex recording range in the radial direction, and its bias vector is recorded for each. It is preferable that φ increases from the inner peripheral side toward the outer peripheral side of the mother sheet 21. Also shown, the orbit a on the inner peripheral side (orbit a, orbit a + 1, orbit a + 2) is slower than the peripheral side, and the electron beam per unit area is larger, so the electron beam is 1 9 The partial vector control is preferably the smaller; the other is the rail c on the outer side (rail c, rail c + 1, rail c + 2. ·. ), Because it is faster, the amount of electron beam irradiation per unit area is small, so it is better to control the bias vector to a large one. That is, in this embodiment, if the orbit of the electron beam 19 mother film 21 is almost perpendicular, it is usually divided into the orbit c (or the The high axis indicates the development of the mother 19 and the orbital shooting on the mother film. The divided recording range is as shown in Figure 3 ... ), And the external exposure is on the one hand, and its linear velocity sub-beam I 9 is biased toward the continuous linear velocity of the parent film 21 at -21-200535992 (18). The electron beam per unit area is irradiated. The internal and external perimeter difference of the width of the inner concave track of each recording range caused by this amount. This kind of problem can maintain a certain number of rotations for each recording range by controlling the bias vector of the electron beam 19, and can be limited to the mother time. The width of the recessed rails forming the average rail on the sheet. In this way, according to the position information of the radial direction of the mother film 21 and the rotation speed information of each recording range, warping can be given to 'expanding the irradiation area of the electron beam 19 of each 9 φ recording range', so that it can be reduced. The formation of the recessed rails-the width of the recessed rails is different inside and outside. Here, for the bias vector of the electron beam 19 at each radial position r of the mother substrate 21, the linear velocity of each radial position r is taken as V (r), and the bias of the electron beam 19 at the linear velocity V (0) is not performed. , But the width of the recessed track W (r) of the recessed track formed by the specific development process, and the width of the recessed track of the recessed track formed by the deflection of the electron beam while rotating is Wmax, control to \ Vmax-W (0 is better. Also, the deflection frequency of the electron beam 19 is at. Above φ V (r) / W (r), it is preferable to deflect the electron beam 19 almost perpendicular to the orbital direction. In this way, by combining the control of the amount of flutter under the high frequency flutter caused by the bias beam and the electron beam caused by the electron beam, the electrons per unit area with the continuous change of the linear velocity within the specific recording range of the mother film 21 are combined. The variation of the beam irradiation amount will offset the variation of the recessed track width of the recording track, and can keep the number of rotations of each recording range of the mother film 21 constant, and keep the recessed track width of the recording track average. That is, based on the positional information of the mother wafer 2 1 irradiated with the electron beam 19 and -22- 200535992 (19) rotation number information for the position on the mother wafer 2 1 irradiated with the electron beam 19 For calculation, the bias vector of the electron beam 19 can be set, which can further reduce the variation of the recessed track width of the recording track within each recording range, and can produce the overall C / N ratio (carrier level / noise level) of the mother film 21 (Standard) Masterpiece for reduced information recording media. Next, the structure of the mother substrate 21 will be described. The mother sheet 21 is formed on the appropriate substrate by spin-coating an electron beam sensing resist with a heat treatment to remove excess solvent to form an electron beam sensing resist film. Examples of the substrate of the mother substrate 21 include silicon wafers, quartz glass, soda glass, quartz glass with a conductive layer formed on the surface, and soda glass with a conductive layer formed on the surface. Among them, those who charge silicon wafers (Charge up) also apply to some extent. Electron beam sensing resists are usually diluted by using an acid generator and an adhesive resin to dissolve a salt-based compound into a salt-based solvent. As an acid generator, as long as the chemical structure is changed by irradiation with an electron beam, those that generate acidic substances are not particularly limited, such as trichlorosulfonic acid, triphenylsulfonic acid, and triphenylsulfonic acid nonafluorobutylsulfonic acid. , Trichlorosulfonic acid diphenyliodine, nonafluorobutylsulfonic acid diphenyliodine, nonafluorobutylsulfonic acid diphenyl p-methoxybenzene, nonafluorobutylsulfonic acid diphenyl P-ethylbenzene, etc. Salts; 1,8-naphthalenedimethylaminosulfonic acid ester, 1,8-naphthalenediamineaminotrichlorosulfonic acid ester, 1,8-naphthalenedimethylaminosulfonic acid tosylate, benzoin Tosylate such as tosylate; bis (benzenesulfonyl) diazomethane, bis (p-chlorobenzenesulfonyl) diazomethane, bis (cyclohexylsulfonyl) diazomethane, etc. Azomethanes. Among these, key salts such as trichlorosulfonic acid triphenylsulfonate are desirable because they can achieve high sensitivity. Acid-23- 200535992 (20) Specific examples of the generator are shown below

CFgSOgCFgSOg

N—0*~S—CH3 TPS-105 三氯磺酸基三苯銃N-0 * ~ S-CH3 TPS-105 Trichlorosulfonyl triphenylsulfonium

0 NAI-105 1,8-蔡二甲醯胺基三氯磺酸酯 ΝΑΙ -100 !,8-蔡二甲醯胺基甲烷磺酸酯0 NAI-105 1,8-Cyme dimethylamino chlorotrisulfonate ΝΑΙ-100 !, 8-Cyme dimethylamino sulfamate

N—Ο—S—CF3 Q_,^Q 〇Fas〇, DPM05 三氣礦酸基二苯碘 DPI-109 九氟丁基磺酸二苯碘 〇h3c~h〇- 九氟丁基磺酸三苯銃N—O—S—CF3 Q_, ^ Q 〇Fas〇, DPM05 Triazine acid diphenyl iodide DPI-109 nonafluorobutyl sulfonic acid diphenyl iodine 0h3c ~ h〇- nonafluorobutyl sulfonic acid triphenyl pistol

〇4FgS〇3〇4FgS〇3

NAI-101 1,8-萘二甲醯胺基甲苯磺酸酯 MDS-105 九氟丁基磺酸二苯p-甲氧基苯NAI-101 1,8-naphthalene dimethylamine tosylate MDS-105 Nonafluorobutylsulfonic acid diphenyl p-methoxybenzene

MDS-205 九氟丁基磺酸二苯P-乙基苯MDS-205 Nonafluorobutylsulfonic acid diphenyl P-ethylbenzene

DAM-102 二(環己基磺醯基)二偶氮甲烷 作爲黏著樹脂,只要是藉由以照射電子束使酸產生劑 起化學變化所產生的化學物質,於室溫或加熱狀況下會起 極性變化者,則無特別限定;但可舉出聚異丁烯酸甲酯 (PMMA),聚異丁烯酸乙酯,聚異丁烯酸丁酯,聚異丁烯 酸異酯’聚乙烯酸甲酯等(甲)聚乙烯酸酯類;聚羥基苯乙 -24 - 200535992 (21) 烯衍生物等。此等之中,亦以聚異丁烯酸甲基(PMMA), 其極性變化造成之顯影速度變化較大,而爲理想。又,使 聚異丁儲酸甲基(PMMA)之分子量分布變狹窄,係可減輕 電子束照射範圍之顯影殘像差,而爲理想。 溶劑’只要是可溶解酸產生劑及黏著樹脂者,則無特 別限定;但可舉出丙烯乙二醇-2-單甲基乙醚乙酸酯 (PGEMA),丙烯乙二醇單甲基乙醚(PE)等賽璐索芙類;2-^ φ 庚酮,甲基乙基酮(MEK)等酮類;乳酸乙酯(EL),醋酸丁 ‘ 酯(BA)等酯類;更且,此等混和溶媒等,係可提高旋轉塗 佈後之電子束感應薄膜的膜厚平均性,而爲理想。其中, 以丙烯乙二醇-2-單甲基乙醚乙酸酯(PGEΜA)和乳酸乙酯 (EL)之混和溶媒尤其理想。更且,藉由.將鹽基性化合物溶 解來調整爲鹽基性,可提高顯影後之凹軌寬度的平均性。 作爲鹽基性化合物,只要是可與以照射電子束使酸產 生劑起化學變化所產生的化學物質,產生中和反應者,則 .φ 無特別限定;但理想上例如有雙(2-羥基乙基)亞胺三(羥基 甲基)甲烷(Bis-Tfis),三異丙醇胺(ΤΙΡΑ)等,於旋轉圖佈 後’不會因熱處理而產生蒸發的非揮發性鹽基化合物爲佳 。其中,雙(2-羥基乙基)亞胺三(羥基甲基)甲烷(Bis-Tris) 於顯影後之電子束感應阻劑其側壁角爲陡峭,而爲理想。 鹽基性化合物之具體例如以下所示。 - 25- 200535992 (22)DAM-102 Di (cyclohexylsulfonyl) diazomethane as an adhesive resin, as long as it is a chemical substance produced by chemical change of an acid generator by irradiating an electron beam, it will become polar at room temperature or under heating The change is not particularly limited, but examples include (meth) polyethylene such as polymethyl methacrylate (PMMA), polyethyl methacrylate, polybutyl methacrylate, polyisobutyl methacrylate, 'polyvinyl methyl ester, and the like. Acid esters; polyhydroxyphenylethyl-24-200535992 (21) ene derivatives. Among these, polymethyl methacrylate (PMMA) is also preferred, and the development speed caused by the change in polarity is large. In addition, narrowing the molecular weight distribution of polyisobutyric acid methyl (PMMA) is preferable because it can reduce the development residual aberration in the electron beam irradiation range. The solvent is not particularly limited as long as it dissolves the acid generator and the adhesive resin; however, propylene glycol-2-monomethyl ether acetate (PGEMA), propylene glycol monomethyl ether ( PE) and other cellophanes; 2- ^ φ heptone, methyl ethyl ketone (MEK) and other ketones; ethyl lactate (EL), butyl acetate (BA) and other esters; moreover, this Equal mixing of solvents and the like is preferable because it can improve the film thickness averageness of the electron beam sensing film after spin coating. Among them, a mixed solvent of propylene glycol-2-monomethyl ether acetate (PGEMA) and ethyl lactate (EL) is particularly preferable. Furthermore, by dissolving the salt-based compound to adjust the salt-based property, the average of the width of the recessed track after development can be improved. The base compound is not particularly limited as long as it is a chemical substance that can be produced by chemically changing an acid generator by irradiating an electron beam. .Φ is not particularly limited; however, for example, bis (2-hydroxy Ethyl) imine tris (hydroxymethyl) methane (Bis-Tfis), triisopropanolamine (TIPA), etc., after rotating the cloth, non-volatile base compounds that do not evaporate due to heat treatment are preferred . Among them, the electron beam sensing resist of bis (2-hydroxyethyl) imine tris (hydroxymethyl) methane (Bis-Tris) after development has a steep sidewall angle, which is ideal. Specific examples of the basic compound are shown below. -25- 200535992 (22)

H2 H〇\H2 H〇 \

h2h2

HOH〆 I、CH2〇H ch2ohHOH〆 I, CH2〇H ch2oh

Bis-Tris 雙(2-院乙基)亞胺基三(經甲基)甲烷Bis-Tris bis (2-ethylethyl) iminotri (methane) methane

H3c. /OH CH〆 H2 I HO. /C、/CH2H3c. / OH CH〆 H2 I HO. / C, / CH2

CH〆、〆 I ICH〆, 〆 I I

CH3 H2C. /CH3 CHCH3 H2C. / CH3 CH

OHOH

TIPA 三異丙醇胺 又,爲了提高旋轉塗佈後之電子束感應薄膜的膜厚平 均性,係於溶劑中添加微量之介面活性劑爲佳。介面活性 劑,係以含有氟者,可抑制旋轉塗佈時之條痕產生,而爲 理想。 其次,說明由被母片照射裝置1 00照射電子束之母片 2 1,來製造資訊記錄媒體用母片的方法。 藉由電子束照射,而於電子束感應阻劑薄膜形成有特 定潛像的母片2 1,係以熱板由下面加熱,而改變電子束感 應阻劑薄膜中被照射了電子束1 9之範圍的極性。接著,將 產生極性變化後之電子束照射範圍,以鹼性顯像液溶解, 而得到阻劑圖案。 顯像液只要是可將產生極性變化後之電子束感應薄膜 加以溶解者,則無特別限定;但以十四甲基銨羥基氧化物 (TMAH)水溶液,氫氧化鈉(NaOH)水溶液,氫氧化鉀(KOH) -26 - 200535992 (23) 水溶液,磷酸緩衝液,及此等之混和物爲佳;其中,以十 四甲基銨羥基氧化物(TMAH)水溶液於顯影後之電子束感 應阻劑其側壁角爲陡峭,而爲理想。 於如此做成之電子束感應阻劑圖案的表面,形成導電 膜後,進行鎳電鍍;將鎳電鍍層由轉印有電子束感應阻劑 圖案資訊記錄媒體用母片剝除,則可得到資訊記錄媒體用 的壓模。 g 另外,本實施方式中,爲了得到目標之光束徑而必須 增加電子束1 9的加速電壓,但一般上提高加速電壓,則電 子束感應阻劑之感度則反而降低。如此之電子束感應阻劑 之感度降低,雖可藉由將形成於母片21上之電子束感應阻 劑薄膜的膜厚增加,來加以提高,但母片2 1上所形成之凹 軌的深度,和確保充分感度之電子束感應阻劑薄膜的膜厚 ,其必須成爲相同者係有困難。故,於此母片2 1上以電子 束感應阻劑薄膜所形成的阻劑圖案,作爲蝕刻遮罩,使反 φ 應性離子蝕刻等蝕刻方法。將以電子束感應阻劑薄膜所形 成之凹軌的形狀,轉印於母片2 1者爲佳。 用於反應性離子蝕刻之氣體,只要對應於電子束感應 阻劑之蝕刻速度的母片2 1之蝕刻速度,亦即蝕刻選擇比在 1 .0以上則無特別限定;但例如以CHF3、C2F6等碳化氟氣 體其選擇比大者爲佳;其中,以C2F6之蝕刻速度其面內 平均性良好,而尤其理想。 接著,去除殘留於母片2 1表面之電子束感應阻劑,而 完成光資訊記錄媒體用母片。電子束感應阻劑之去除方法 >27 - 200535992 (24) ,只要不會使轉印至母片2 1之形狀劣化者,則無特別限定 。具體來說,可使周氧電漿灰化,以有機溶劑溶解,以鹼 性水溶液溶解等。其中,使用矽晶圓作爲母片時,係以不 會引發矽晶圓之化學反應的氧電漿灰化爲佳。 如此做成之轉印有電子束感應阻劑圖案的資訊記錄媒 體用母片,其表面形成導電膜之後,係進行鎳電鍍;將鎳 電鍍層由轉印有電子束感應阻劑圖案資訊記錄媒體用母片 ϋ 剝除,則可得到資訊記錄媒體用的壓模。 資訊記錄媒體,通常係使用如此做成之光資訊記錄媒 體用壓模,例如進行聚碳酸樹脂等的射出成型,得到將電 子束感應阻劑所轉印之記錄軌形成於表面的基板,之後, 於此基板上層積記錄層等特定之各層而製造之。 以適用本實施方式之母片照射裝置100製造出資訊記 錄媒體用母片,用此母片所作成之資訊記錄媒體,係如上 述般,將電子束感應阻劑所轉印之螺旋狀或同心圓狀記錄 Φ 軌,形成於表面的基板,其上係具有以特定寬度被區分爲 同心圓狀之複數記錄範圍;而被區分之此等各記錄範圍的 邊界部,係設有基板之半徑方向之寬度在〗〇軌以下的遷移 範圍。 遷移範圍或遷移範圍之附近,係以更具備可同步之再 同步控制標誌者爲佳;此係對母片2 1照射電子束1 9,形成 於半徑方向被複數區分爲同心圓狀之記錄範圍時,其記錄 範圍之邊境之半徑位置附近所產生之旋轉數變更所造成的 旋轉誤差,加以修正。 -28- 200535992 (25) 將具有資訊記錄媒體之基板,其內周側所設置之被區 分的記錄範圍之寬度,係以較設置於基板外周側之被區分 的記錄範圍之寬度更小者爲佳。對各記錄範圍之寬度來說 ,設置於基板內周側之被區分的記錄範圍之寬度,係以較 設置於基板外周側之被區分的記錄範圍寬度更小者爲佳。 又,在基板上以特定寬度被區分爲同心圓狀之各記錄範圍 ,其外周側之半徑位置和內周側之半徑位置的比,係在 g 1 . 3以下者爲佳。 如此,若依本實施方式,母片2 1中照射電子束1 9之範 圍其每單位時間之電子束照射量可被保持爲一定,故可抑 制電子束1 9之軸變動;更且,藉由固定旋轉速度而進行旋 轉誤差少之旋If控制,可將照射電子束1 9之資訊保持高度 位置精確度。 又,使記錄位置精確度提高,則可控制相鄰軌間之串 音或顫動的相位干涉,而製造高密度記錄媒體。更且,可 φ 集中於碟片之特定角度,來記錄控制訊號及位址資訊,而 可製造存取速度較快之大容量資訊記錄媒體。 更且,將母片2 1區分爲於半徑方向被分割爲同心圓狀 的複數記錄範圍,採用越外周側之記錄範圍其旋轉數越提 高的構成,比起先前之CAV方式,係可減少電子束19之 照射時間,而製造安定之資訊記錄媒體。 實施例 以下,根據實施例更詳細說明本實施方式。另外,本 實施方式並不限定於實施例。 -29- 200535992 (26) (1 )資訊記錄媒體用母片之製造 (電子束感應阻劑薄膜) 將三氯磺酸基三苯毓200mg、針對數平均分子量其重 量平均分子量的比率在1.2以下,分子量分散爲少之聚異 丁嫌酸甲酯l〇g,溶解於丙烯乙二醇-2-單甲基乙醚乙酸酯 與乳酸乙酯的混和溶媒5 4 g,而作成溶液1之5 · 4 0 g ;和量 取(2-hydroxyethyl)iminotris(hydroxymethyl)0.79g,溶解 於乳酸乙酯l〇〇g而成的溶液2之0.22g;和量取住友3M公 司製造之FC-43 0有2g來作爲介面活性劑,並以丙烯乙二 醇-2-單甲基乙醚乙酸酯l〇〇g稀釋而成溶液3之0.029g,相 互混和,而調至電子束感應阻劑。將此電子束感應阻劑旋 轉塗佈於矽晶圓,用熱板以1 1 (TC加熱2分鐘,而得到矽晶 圓上形成有膜厚8 Onm電子束感應阻劑薄膜的母片。 由電子束照射裝置,以加速電壓50kV、聚光半角 9mrad、光束電流22 5 ιιΑ的條件,使每單位時間之電子束 照射量爲一定地,對形成於上述矽晶圓上之電子束感應阻 劑薄膜,以下述圖樣形成潛像。 亦即,如後述之第1表〜第4表所示,預先設定母片中 ,於半徑方向具有特定寬度之被區分爲同心圓狀的複數記 錄範圍,對各記錄範圍之每個以特定之一定旋轉數來旋轉 母片,使各記錄範圍具有一定之電子束照射量,而對應資 -30- 200535992 (27) 訊記錄媒體中具有特定凹軌寬度之軌的部分,進行電子束 照射。旋轉數,如第1表〜第4表所示,係於各記錄範圍之 每個成階段性變化。各記錄範圍於母片半徑方向之特定寬 度,在第1表及第4表中係5mm,而於第2表及第3表中,係 向著母片之外周方向而增加。又,針對第3表及第4表所示 之曝光條件,以高頻顫動來進行電子束照射,使資訊記錄 媒體之軌的凹軌寬度成爲一定地進行操作。另外,各記錄 ^ 範圍之邊界部分,係設置有遷移範圍(寬度約1 0軌左右), 其用以將藉由對各區域產生變化之旋轉數而變動之訊號, 其同步加以整合。 其次,將電子束照射結束之矽晶圓,以熱板由下面加 熱,使電子東感應阻劑薄膜中照射過電子束之範圍的極性 被改變。將此以顯影液(東京應化工業有限公司製·· NMD-3之稀釋溶液),將極性變化後之範圍溶解,而得到於形成 於矽晶圓上的阻劑圖案。接著,將電子束感應阻劑圖案作 φ 爲蝕刻遮罩,使用C2F6氣體來反應性離子蝕刻,將電子 束感應阻劑圖案轉印至母片。更且,藉由氧電漿灰化,去 除殘留之電子束感應阻劑,而得到矽晶圓製之光資訊記錄 媒體用母片。 (2)資訊記錄媒體之製造 (聚碳酸鹽基板) 對上述矽晶圓製之光資訊記錄媒體用母片,使用濺鍍 法形成鎳導電皮膜後,藉由電鍍而形成平均2 9 0 // m之鎳 -31 - 200535992 (28) 皮膜。之後,將砍晶圓和鎳皮膜分離,而得到光資訊記錄 媒體用壓模。更且藉由聚碳酸鹽樹脂之射出成型,而得到 表面形成有電子束感應阻劑圖案的聚碳酸鹽基板。 (資訊記錄媒體之層構造) 第4圖,係說明實施例所使用之資訊記錄媒體的圖。 第4圖所示之資訊記錄媒體400,係具有膜面射入型磁區擴 ^ φ 大媒體的模式化構造;其爲於透明基板4 1上,依序層積散 ^ 熱層42、和記錄層43、和常磁性層44、和觸發層45、和再 生層46及強化層47,而形成保護塗佈層48作爲最外層。 透明基板4 1,係使用由上述資訊記錄媒體用母片所製 造之壓模,以射出成行法所形成的聚碳酸酯基板。散熱層 4 2,係用以調整記錄再生時媒體熱感度的層;其係藉由使 用A1合金之靶的濺鍍裝置,製造爲膜厚40nm。記錄層43 ,係將資訊作爲磁化資訊而記錄的層;其係使用由室溫到 .φ 居里溫度爲止,具有過渡金屬優勢之垂直磁化的TbFeCo 所構成。記錄層4 3,係同時對T b、F e、C 〇的單體靶進行 濺鍍,具有補償溫度約2 5 t,而居里溫度2 5 〇 C之膜組成 ,其膜厚爲60nm。 常磁性層44係以Gb構成,係用以調整記錄層43與觸 發成4 5之靜磁性耦合例的層。觸發層4 5,係使用過渡金屬 優勢之T b F e所構成。觸發層4 5,係同時對τ b、F e的單 體靶進行濺鍍,具有補償溫度在室溫以下的膜構成,其膜 厚爲1 0 n m。再生層4 6係將由記錄層4 3所轉印之磁區,加 -32- 200535992 (29) 以擴大的層;其係使用由室溫到居里溫度爲止,具有稀土 類金屬優勢之垂直磁化的G d F e C 〇所構成。再生層4 6之成 膜,係同時對Gd、Fe、Co的單體靶進行濺鍍,藉由控制 對各靶之投入電力來調整膜組成。再生層4 6係垂直磁化膜 ’居里溫度約260 °C,使補償溫度在居里溫度以上地調整 膜組成,而膜厚作爲3 0 nm。強化層4 7,係用以於層內多 重干涉再生用光束,來實效性增加克爾(kerr)旋轉角的層 其係以SiN所構成。強化層47之成膜,係使用Si爲靶 材料,而於Ar及氮環境中進行成膜,膜厚爲35 nm。保護 塗佈層48,係於強化層47上塗佈丙烯酸樹脂系的紫外線硬 化型樹脂組成物,之後照射紫外線而硬化,形成爲膜厚1 5 // m 〇 (3)位元錯誤率之測定 根據以上述方法所製造之資訊記錄媒體4 0 0,其所形 • 成有軌之凹軌寬度,係以下述之手續測定了位元錯誤率( 針對全部總位元數的產生錯誤之位元數)。 第5圖,係說明位元錯誤率之測定裝置的圖。在此, 係使用了具有波長4 0 5 nm之雷射和開口率〇 . 8 5之物鏡的光 磁碟片驅動器。另外,省略了伺服電路及光學系等。第5 圖所不之位兀錯誤率測定裝置5 0 0,係具備輸出光磁性訊 號5 7之驅動光學頭5 1 ;和將擬似隨機圖案訊號5 3與同步於 擬似隨機圖案訊號5 3之雷射脈衝訊號5 4,分別輸出的位元 錯誤分析器5 2 ;和將擬似隨機圖案訊號5 3,加以轉換爲調 -33- 200535992 (30) 變磁場的線圈驅動器5 5 ;和將雷射脈衝訊號5 4,轉換微調 變雷射脈衝的雷射驅動器5 6 ;和將自驅動光學頭5 1輸出之 光磁性訊號5 7,加以處理的帶通濾波器5 8與等化器5 9。 其次,說明位元錯誤率測定裝置5 0 0之記錄動作。首 先由位元錯誤分析器52,輸出擬似隨機圖案訊號53,和適 當同步於擬似隨機圖案訊號53之雷射脈衝訊號54。此等訊 號,係藉由線圈驅動器5 5和雷射驅動器5 6,被分別轉換爲 調變磁場和調變雷射脈衝;以磁場與雷射作用於資訊記錄 ^ 媒體,使由位元錯誤分析器52所輸出之擬似隨機資料,作 爲磁區而被記錄於媒體。在此,係使用磁場之強度爲 3 000e,而雷射功率爲8mW的光脈衝磁場調變方式。 其次,說明此位元錯誤率測定裝置5 00之再生動作。 首先,使磁區擴大動作適當發生地,投入1.5mW〜2mW的 再生功率。自驅動光學頭5 1輸出之光磁性訊號5 7,係藉由 帶通濾波器58與等化器59,使被記錄之擬似隨機圖案訊號 .φ 53的錯誤盡量減少地加以控制。位元錯誤分析器52,係進 行光磁性訊號57之類比數位轉換,且對此類比數位轉換後 之再生訊號,與使用於記錄的擬似隨機圖案訊號5 3,進行 比較。依此,來測定使用於記錄之擬似隨機圖案訊號53的 位元錯誤率。 (實施例1) 如第1表所示,依上述之母片之電子束照射方法,設 置8個於半徑方向區分爲寬度5 mm之同心圓狀的記錄範圍 -34- 200535992 (31) :針對各記錄範圍,以第1表所示之旋轉數來旋轉母片, 而對以電子束照射所形成之資訊記憶媒體,測定其位元錯 誤率。 第6圖,係爲了得到實施例]之資訊記錄媒體,說明母 片之電子束照射條件的圖。第6圖中橫軸,係於砂晶圓上 形成有電子束感應阻劑薄膜之母片的半徑(圖中左方爲內 周);縱軸,係針對於半徑方向分別被區分爲寬度5mm之 記錄範圍,其旋轉數及線速度。 _ 如第1表所示,旋轉數在各記錄範圍之每個係成爲一 定,而被設定爲由母片之外周側向著內周側階段性增加。 各記錄範圍之平均線速度係1.767(記錄範圍4)〜1.814(記錄 範圍2),平均線速度之最大値與最小値的比爲1 .03,而被 設定爲幾乎一定値。又,針對於半徑方向被平均分割之各 記錄範圍,最內周側之線速度與最外周側之線速度的比( 各記錄範圍最外周之線速度/各記錄範圍最內周之線速度) ·· 係1.09(記錄範圍8)〜1.25(記錄範圍1)。更且於第1表,表 示有針對各記錄範圍中,包含內周側軌與外周側軌的複數 任意軌,所測定之位元錯誤率的算數平均値。 另外,第1表中內周半徑,係各記錄範圍中最內周之 半徑(單位:m m);外周半徑,係各記錄範圍中最外周之 半徑(單位:ni m);旋轉數,係各區分軸圍中的一疋旋轉 數(單位:rpm);內周線速度,係各記錄範圍之最內周線 速度(單位:m / s e c);外周線速度,係各記錄範圍之最外 周線速度(單位:m/sec);平均線速度,係針對於半徑方 -35- 200535992 (32) 向被平均分割之各記錄範圔內,最內周側線速度與最外周 側線速度的算數平均線速度(單位:m / s e c)。另外,之後 的第2表〜第4表中亦相同。 [第1表]TIPA Triisopropanolamine In order to improve the film thickness uniformity of the electron beam sensing film after spin coating, it is better to add a small amount of a surfactant to the solvent. The surface active agent is preferably one containing fluorine to suppress the occurrence of streaks during spin coating. Next, a method of manufacturing a mother substrate 21 for an information recording medium by irradiating the mother substrate 21 with an electron beam by the mother substrate irradiation apparatus 100 will be described. The mother substrate 21 having a specific latent image formed on the electron beam sensing resist film by electron beam irradiation is heated from below by a hot plate, and the electron beam sensing resist film is irradiated with the electron beam 19 The polarity of the range. Next, the electron beam irradiation range after the polarity change is dissolved in an alkaline developing solution to obtain a resist pattern. The developing solution is not particularly limited as long as it can dissolve the electron-beam sensing film that has undergone a change in polarity; however, a tetradecyl ammonium hydroxyoxide (TMAH) aqueous solution, a sodium hydroxide (NaOH) aqueous solution, and hydroxide Potassium (KOH) -26-200535992 (23) Aqueous solution, phosphate buffer, and mixtures thereof are preferred; among them, tetradecyl ammonium oxyhydroxide (TMAH) aqueous solution is used as an electron beam sensing resist after development Its side wall angles are steep and ideal. After the conductive film is formed on the surface of the thus-formed electron beam resist pattern, nickel plating is performed; the nickel plating layer is peeled off from the mother sheet with the electron beam resist pattern information recording medium transferred, and information can be obtained. Stamper for recording media. g In this embodiment, in order to obtain the target beam diameter, it is necessary to increase the acceleration voltage of the electron beam 19, but generally, if the acceleration voltage is increased, the sensitivity of the electron beam sensing resistor is reduced. The sensitivity of the electron beam sensing resist is reduced in this way. Although the thickness of the electron beam sensing resist film formed on the mother substrate 21 can be increased, the thickness of the recessed rail formed on the mother substrate 21 is increased. It is difficult to make the depth and the film thickness of the electron beam sensing resist film having sufficient sensitivity the same. Therefore, a resist pattern formed by the electron beam sensing resist film is used as an etching mask on the mother substrate 21 to perform an etching method such as reverse φ ion etching. The shape of the concave track formed by the electron beam sensing resist film is preferably transferred to the mother substrate 21. The gas used for reactive ion etching is not particularly limited as long as the etching speed of the mother substrate 21 corresponding to the etching speed of the electron beam sensing resist, that is, the etching selection ratio is 1.0 or more; however, for example, CHF3, C2F6 Isofluoride gas is preferably selected with a larger ratio; among them, the in-plane averageness at the etching rate of C2F6 is good, which is particularly desirable. Next, the electron beam sensing resist remaining on the surface of the mother substrate 21 is removed to complete a mother substrate for an optical information recording medium. Removal method of electron beam sensing resist > 27-200535992 (24) is not particularly limited as long as it does not deteriorate the shape transferred to the mother substrate 21. Specifically, the periplasmic plasma can be ashed, dissolved in an organic solvent, and dissolved in an alkaline aqueous solution. Among them, when a silicon wafer is used as the mother wafer, it is better to use an oxygen plasma ashing that does not cause chemical reactions on the silicon wafer. The mother sheet for the information recording medium with the electron beam sensing resist pattern transferred as described above is formed with a conductive film on the surface, and then nickel plating is performed; the nickel plating layer is transferred from the information recording medium transferring the electron beam sensing resist pattern. By using a mother film 母, a stamper for an information recording medium can be obtained. The information recording medium is usually a stamper for an optical information recording medium made in this way. For example, injection molding of polycarbonate resin is performed to obtain a substrate on which a recording track transferred by an electron beam sensing resist is formed on the surface. A specific layer such as a recording layer is laminated on this substrate and manufactured. A mother film for an information recording medium is manufactured by using the mother film irradiation device 100 to which this embodiment is applied. The information recording medium made with this mother film is spiral or concentric transferred by an electron beam sensing resist as described above. Circular recording Φ track. The substrate formed on the surface has a plurality of recording ranges divided into concentric circles with a specific width. The boundary portion of each of these recorded ranges is provided with the radius direction of the substrate. The width of the migration range is below 〖0. The migration range or the vicinity of the migration range is preferably the one with more synchronizable resynchronization control marks; this is the irradiation range of the mother film 21 with the electron beam 19, which is formed in the radial direction and is divided into multiple concentric circles. At that time, the rotation error caused by the change in the number of rotations near the radius position of the border of the recording range is corrected. -28- 200535992 (25) The width of the discriminated recording range set on the inner peripheral side of the substrate with the information recording medium will be smaller than the width of the discriminated recording range set on the outer peripheral side of the substrate. good. For the width of each recording range, the width of the divided recording range provided on the inner peripheral side of the substrate is preferably smaller than the width of the divided recording range provided on the outer peripheral side of the substrate. In addition, the ratio of the radial position on the outer peripheral side to the radial position on the inner peripheral side of each recording range divided into concentric circles with a specific width on the substrate is preferably g 1.3 or less. Thus, according to this embodiment, if the range of the electron beam 19 to be irradiated in the mother film 21 is maintained, the amount of electron beam irradiation per unit time can be kept constant, so the axis variation of the electron beam 19 can be suppressed; moreover, by The rotation If control with a small rotation error is performed by a fixed rotation speed, and the information of the irradiation electron beam 19 can be maintained at a high position accuracy. Furthermore, by increasing the accuracy of the recording position, it is possible to control the phase interference of the crosstalk or chattering between adjacent tracks to manufacture a high-density recording medium. In addition, φ can be concentrated on a specific angle of the disc to record control signals and address information, and a large-capacity information recording medium with faster access speed can be manufactured. In addition, the mother film 21 is divided into a plurality of recording ranges that are divided into concentric circles in the radial direction, and the more the recording range on the outer peripheral side is, the higher the number of rotations is. Compared with the previous CAV method, the number of electrons can be reduced. The irradiation time of the beam 19 makes a stable information recording medium. Examples Hereinafter, this embodiment will be described in more detail based on examples. The present embodiment is not limited to the examples. -29- 200535992 (26) (1) Manufacture of master sheet for information recording media (electron beam sensing resist film) 200 mg of trichlorosulfonyl triphenylsulfonate and the weight average molecular weight ratio of the number average molecular weight to 1.2 or less 10 g of polyisobutyric acid methyl ester with a small molecular weight dispersion, dissolved in 5 4 g of a mixed solvent of propylene glycol-2-monomethyl ether acetate and ethyl lactate, to prepare a solution of 5 of 1 · 40 g; and the amount of (2-hydroxyethyl) iminotris (hydroxymethyl) 0.79 g, 0.22 g of solution 2 dissolved in 100 g of ethyl lactate; and the amount of FC-43 0 manufactured by Sumitomo 3M Corporation There are 2g as a surface active agent, and 0.029g of solution 3 is diluted with 100g of propylene glycol-2-monomethyl ether acetate to be mixed with each other to adjust to an electron beam sensing resist. This electron beam sensing resist was spin-coated on a silicon wafer and heated on a hot plate at 1 1 (TC for 2 minutes) to obtain a mother wafer having a thickness of 8 Onm electron beam sensing resist film formed on the silicon wafer. The electron beam irradiation device, under the conditions of an acceleration voltage of 50 kV, a condensing half-angle of 9 mrad, and a beam current of 22 5 ιΑ, makes the amount of electron beam irradiation per unit time constant to the electron beam induction resist formed on the silicon wafer. The film forms a latent image in the following pattern. That is, as shown in Tables 1 to 4 described later, a plurality of recording ranges that are divided into concentric circles with a specific width in the radial direction are set in advance in the master film. Each recording range rotates the master by a specific number of rotations, so that each recording range has a certain amount of electron beam exposure, and the corresponding recording track has a specific recessed track width in the recording medium. The number of rotations, as shown in Tables 1 to 4, is changed stepwise for each of the recording ranges. Each recording range has a specific width in the radius direction of the master film, and is in the first range. Table and Table 4 It is 5mm, and in Tables 2 and 3, it increases toward the outer periphery of the mother film. For the exposure conditions shown in Tables 3 and 4, electron beam irradiation is performed with high frequency vibration, The width of the concave track of the track of the information recording medium is fixed. In addition, the boundary part of each recording ^ range is provided with a migration range (about 10 tracks in width), which is used to generate The signals that change with the change in the number of rotations are synchronized and integrated. Secondly, the silicon wafer on which the electron beam irradiation is completed is heated from below by a hot plate, so that the polarity of the range in which the electron beam is irradiated in the electron-sensitive resist film is This was changed with a developer (a diluted solution of NMD-3 manufactured by Tokyo Yingka Kogyo Co., Ltd.) to dissolve the polarized range to obtain a resist pattern formed on a silicon wafer. Next, the resist pattern was formed on a silicon wafer. The electron beam sensing resist pattern is used as φ as an etching mask, and C2F6 gas is used for reactive ion etching to transfer the electron beam sensing resist pattern to the mother substrate. Furthermore, the residual electrons are removed by ashing with an oxygen plasma. Beam sense (2) Manufacture of information recording medium (polycarbonate substrate) For the above-mentioned optical information recording medium master made of silicon wafer, sputtering is used. After the nickel conductive film is formed by electroplating, an nickel-31-200535992 (28) film with an average of 2 0 // // m is formed by electroplating. Then, the diced wafer and the nickel film are separated to obtain a stamper for an optical information recording medium. In addition, a polycarbonate substrate having an electron beam sensing resist pattern formed on the surface is obtained by injection molding of a polycarbonate resin. (Layer structure of an information recording medium) FIG. 4 illustrates the information used in the embodiment. The information recording medium 400 shown in FIG. 4 is a patterned structure of a large-area injection-type magnetic area expansion ^ φ large medium; it is sequentially layered on the transparent substrate 41 ^ The thermal layer 42, the recording layer 43, the normally magnetic layer 44, the trigger layer 45, and the reproduction layer 46 and the reinforcement layer 47 form a protective coating layer 48 as the outermost layer. The transparent substrate 41 is a polycarbonate substrate formed by an injection line method using a stamper made of the above-mentioned information recording medium master. The heat radiating layer 42 is a layer for adjusting the thermal sensitivity of the medium during recording and reproduction; it is manufactured to a thickness of 40 nm by a sputtering device using a target of an A1 alloy. The recording layer 43 is a layer in which information is recorded as magnetized information; it is composed of TbFeCo with perpendicular magnetization which has the advantage of a transition metal from room temperature to .φ Curie temperature. The recording layer 43 is formed by sputtering the monomer targets of T b, Fe, and C 0 at the same time, and has a film composition with a compensation temperature of about 25 t and a Curie temperature of 250 c. The film thickness is 60 nm. The normally magnetic layer 44 is composed of Gb, and is a layer for adjusting the example of the magnetostatic coupling between the recording layer 43 and the trigger. The trigger layer 45 is composed of T b F e with the advantage of transition metal. The trigger layer 45 is a sputtering target for a single target of τ b and Fe at the same time, and has a film structure with a compensation temperature below room temperature, and its film thickness is 10 nm. The reproduction layer 4 6 is a layer to be enlarged by adding the magnetic region transferred by the recording layer 4 3 to -32- 200535992 (29); it uses a vertical magnetization with the advantages of rare earth metals from room temperature to the Curie temperature. G d F e C 〇. The film formation of the regeneration layer 46 is performed by sputtering a single target of Gd, Fe, and Co at the same time, and the film composition is adjusted by controlling the power input to each target. The regeneration layer 4 6 is a vertical magnetized film with a Curie temperature of about 260 ° C. The film composition is adjusted so that the compensation temperature is above the Curie temperature, and the film thickness is 30 nm. The reinforcing layer 47 is a layer for effectively interfering with the regeneration beam in the layer to effectively increase the Kerr rotation angle. It is made of SiN. The enhancement layer 47 was formed by using Si as a target material, and the film was formed in an Ar and nitrogen environment with a film thickness of 35 nm. The protective coating layer 48 is a coating of an acrylic resin-based ultraviolet curable resin composition on the reinforcing layer 47, and then cured by irradiation with ultraviolet rays to form a film thickness of 1 5 // m 〇 (3) bit error rate measurement According to the information recording medium 4 0 0 manufactured by the above method, the width of the formed concave track is determined by the following procedures (bit error rate for all total bits) number). Fig. 5 is a diagram illustrating a device for measuring a bit error rate. Here, a magneto-optical disk drive using an objective lens with a wavelength of 4.05 nm and an aperture ratio of 0.85 is used. In addition, servo circuits, optical systems, and the like are omitted. The error rate measuring device 5 0, which is not shown in Fig. 5, is a driving optical head 5 1 which outputs a photomagnetic signal 5 7; and a lightning which synchronizes the pseudo-random pattern signal 5 3 and the pseudo-random pattern signal 5 3 The pulse signal 5 4 is a bit error analyzer 5 2 which is output respectively; and the pseudo-random pattern signal 5 3 is converted into a coil driver 5 5 of a modulation-33- 200535992 (30) variable magnetic field; and the laser pulse The signal 5 4 is a laser driver 5 6 which converts the laser pulses for fine adjustment and conversion; and the photomagnetic signal 5 7 output from the self-driving optical head 51 is processed by a band-pass filter 5 8 and an equalizer 5 9. Next, a recording operation of the bit error rate measuring device 500 will be described. First, the bit error analyzer 52 outputs a pseudo-random pattern signal 53 and a laser pulse signal 54 which is appropriately synchronized with the pseudo-random pattern signal 53. These signals are converted into a modulated magnetic field and a modulated laser pulse by the coil driver 55 and the laser driver 56 respectively; the magnetic field and the laser act on the information recording ^ media, and the bit error analysis The pseudo-random data output from the device 52 is recorded on the medium as a magnetic field. Here, a light pulse magnetic field modulation method with a magnetic field intensity of 3 000e and a laser power of 8 mW is used. Next, the reproduction operation of the bit error rate measuring device 500 will be described. First, the magnetic field expansion operation is appropriately performed, and a regeneration power of 1.5 mW to 2 mW is applied. The optical magnetic signal 5 7 output from the self-driving optical head 51 is controlled by the band-pass filter 58 and the equalizer 59 to minimize the errors of the recorded pseudo-random pattern signal .φ 53. The bit error analyzer 52 performs analog-to-digital conversion of the photomagnetic signal 57 and compares the reproduced signal after such analog-to-digital conversion with the pseudo-random pattern signal 5 3 used for recording. Based on this, the bit error rate of the pseudo-random pattern signal 53 used for recording is measured. (Example 1) As shown in Table 1, according to the electron beam irradiation method of the above-mentioned mother sheet, eight concentric circles with a width of 5 mm in the radial direction are set to a recording range of -34- 200535992 (31): For each recording range, the master is rotated by the number of rotations shown in Table 1, and the bit error rate of the information storage medium formed by irradiation with an electron beam is measured. Fig. 6 is a diagram for explaining an electron beam irradiation condition of a mother film in order to obtain an information recording medium according to the embodiment. The horizontal axis in FIG. 6 is the radius of the mother wafer on which the electron beam sensing resist film is formed on the sand wafer (the left side in the figure is the inner periphery); the vertical axis is divided into 5 mm widths for the radial direction. The recording range, its rotation number and linear speed. _ As shown in Table 1, the number of rotations is fixed for each system in each recording range, and is set to increase stepwise from the outer peripheral side to the inner peripheral side of the master. The average linear velocity of each recording range is 1.767 (recording range 4) to 1.814 (recording range 2), and the ratio of the maximum 値 to the minimum 平均 of the average linear velocity is 1.03, and is set to be almost constant. The ratio of the linear velocity at the innermost side to the linear velocity at the outermost side for each recording range that is evenly divided in the radial direction (linear velocity at the outermost periphery of each recording range / linear velocity at the innermost periphery of each recording range) ·· Departments range from 1.09 (recording range 8) to 1.25 (recording range 1). In addition, Table 1 shows the arithmetic mean of the bit error rate measured for each of the recording ranges, including the plural arbitrary orbits of the inner peripheral side rail and the outer peripheral side rail. In addition, the inner radius in the first table is the radius (unit: mm) of the innermost perimeter in each recording range; the outer radius is the radius (unit: ni m) of the outermost perimeter in each recording range; the number of rotations is each Differentiate the number of revolutions in a shaft (unit: rpm); the inner peripheral linear velocity is the innermost peripheral linear velocity of each recording range (unit: m / sec); the outer peripheral linear velocity is the outermost peripheral linear velocity of each recording range (Unit: m / sec); the average linear velocity refers to the radius of -35- 200535992 (32) The average linear velocity of the innermost linear velocity and the outermost linear velocity in each recording range that is evenly divided. (Unit: m / sec). The same applies to the following second to fourth tables. [Table 1]

記錄 內周 外周 旋轉數 內周線 外周線 平均線 位元錯 範圍 半徑 半徑 (rPm) 速度 速度 速度 誤率 (mm) (mm) (m / s e c) (m/sec) (m/sec) xl Ο5 1 20 25 1.602 2.002 1.802 3.15 2 25 3 0 ^_63j) 1.649 1.979 1.8 14 2.59 3 30 3 5 1.649 1.924 1.786 1.76 4 3 5 40 si5〇 1.649 1.884 1.767 1 .76 5 40 45 __4〇5 1.696 1.908 1.802 1.59 6 45 50 ^3^60 1.696 1.884 1.790 1.40 7 50 55 1.727 1.900 1.814 1.52 8 55 60 3〇〇 1.727 1.884 1.806 1.40 由弟1表所不之結果,各記錄範圍之線速度,係由內 周側向者外周側變大些許,目內周部之位元錯誤率,係較 外周部相封的1¾ ’而得知資訊記錄媒體之所有範圍都可被 抑制。 (實施例2) 如第2表所示’依上述之母片之電子束照射方法,使 -36- 200535992 (33) 各記錄範圍內最內周側線速度與最外周側之線速度的比( 各記錄範圍最外周之線速度/各記錄範圍最內周之線速度) 的比,被收縮在特定範圍內地,設置11個記錄範圍;針對 各記錄範圍,以第2表所示之旋轉數來旋轉,而對以電子 束照射所形成之資訊記憶媒體’測定其位元錯誤率。各記 錄範圍之半徑方向寬度,係被設定爲內周側比外周側部狹 窄〇 _ 第7圖,係爲了得到實施例2之資訊記錄媒體,說明母 片之電子束照射條件的圖。第7圖中橫軸,係於矽晶圓上 形成有電子束感應阻劑薄膜之母片的半徑(圖中左方爲內 周);縱軸,係針對於半徑方向分別被區分爲特定寬度之 記錄範圍,其旋轉數及線速度。 如第2表所示,旋轉數在各記錄範圍之每個係成爲一 定,而被設定爲由母片之內周側向著外周側減少。各記錄 範圍之平均線速度係1 · 7 6 9 (記錄範圍9 )〜1 . 8 2 5 (記錄範圍1 ) φ ,平均線速度之最大値與最小値的比爲1 · 0 3,而被設定爲 幾乎一定値。又,針對於半徑方向被平均分割之各記錄範 圍,最內周側之線速度與最外周側之線速度的比(各記錄 範圍最外周之線速度/各記錄範圍最內周之線速度)係1.1 〇 ( 記錄範圍1)〜1 · 1 1 (記錄範圍6等)。將位元錯誤率之測定結 果,以第2表來表示。 -37- 200535992 (34) Γ_- 記錄 內周 外周 旋轉 內周線 外周線 平均線 位元錯 範圍 半徑 半徑 數 速度 速度 速度 誤率 (mm) (m rn)j (m / s e c) (m/sec) (m/sec) xlO5 1 20 22一 」3〇 1.738 1.825 1.62 2 22 24.J_ _75〇_ 1.727 J^9〇〇_ 1.814 1.52 3 2 4 〇 6 7 5 1.710 1.880 1.795 1.37 4 26.6 2 9^3 __^— 1.713 1.800 1.41 5 29.3 3 2.j_ 1,702 1.787 1.3 1 6 32.2 1.719 1.805 1.44 7 35.4 1.723 1.899 1.811 1.5 1 8 39 4 ? 9 42 0 1.715 1.886 1.801 1.36 9 42.9 4 7 2 _371__ 1.684 1.853 1.769 1.34 10 47.2 5±,9_ 1.705 1.875 1.790 1.37 11 5 1.9 S 7 3 1 5 . 1.712 1.880 1.769 1.25 由 第2表 j / 所示之 結果’ 各區分範圍之半徑方向寬度’ 係設定爲內周側較外周側部狹窄’而向著半徑方向使寬度 增加者,來將旋轉數變化大之內周側之記錄範圍’其位元 錯誤率抑制的更低;結果,得知對於資訊記錄媒體之所有 範圍,位元錯誤率更加降低。 (實施例3) 如第3表所示,依上述之母片之電子束照射方法,使 -38- 200535992 (35) 各記錄範圍內最內周側線速度與最外周側之線速度的比( 各記錄範圍最外周之線速度/各記錄範圍最內周之線速度) 的比,被收縮在特定範圍內地,設置11個記錄範圍;針對 各記錄範圍,以第3表所示之旋轉數來旋轉,而對以電子 束照射所形成之資訊記憶媒體,測定其位元錯誤率。各記 錄範圍之半徑方向寬度,係被設定爲內周側比外周側部狹 窄。 本實施例中,使各記錄範圍中電子束的高頻振動振幅 (顫動頻率:47.9MHz),由內周向外周連續增加20nm的偏 向量,使母片整面之凹軌寬度幾乎保持一定。 第8圖,係爲了得到實施例3之資訊記錄媒體,說明母 片之電子束照射條件的圖。第8圖中横軸,係於矽晶圓上 形成有電子束感應阻劑薄膜之母片的半徑(圖中左方爲內 周);縱軸,係針對於半徑方向分別被區分爲特定寬度之 記錄範圍,其旋轉數、線速度及顫動振幅的偏向量。 如第3表所示,旋轉數在各記錄範圍之每個係成爲一 定,而被設定爲由母片之內周側向著外周側減少。各記錄 範圍之平均線速度係1 · 7 8 7 (記錄範圍5 )〜1 . 8 2 5 (記錄範圍1 ) ’平均線速度之最大値與最小値的比爲1 .02,而被設定爲 幾乎一定値。又,針對於半徑方向被平均分割之各記錄範 圍’最內周側之線速度與最外周側之線速度的比(各記錄 範圍最外周之線速度/各記錄範圍最內周之線速度)係1 .丨〇 ( I己錄範圍1〜記錄範圍1 1等)。將位元錯誤率之測定結果, 以第3表來表示。 -39- 200535992 (36)Record the number of rotations of the inner circumference and the outer circumference. The average line position error range of the inner circumference and outer radius. Radius (rPm) Speed velocity Speed error rate (mm) (mm) (m / sec) (m / sec) (m / sec) xl Ο5 1 20 25 1.602 2.002 1.802 3.15 2 25 3 0 ^ _63j) 1.649 1.979 1.8 14 2.59 3 30 3 5 1.649 1.924 1.786 1.76 4 3 5 40 si5〇1.649 1.884 1.767 1 .76 5 40 45 __4〇5 1.696 1.908 1.802 1.59 6 45 50 ^ 3 ^ 60 1.696 1.884 1.790 1.40 7 50 55 1.727 1.900 1.814 1.52 8 55 60 3〇〇1.727 1.884 1.806 1.40 According to the results of Table 1, the linear velocity of each recording range is from the inner peripheral side. The outer peripheral side is slightly larger, and the bit error rate of the inner peripheral portion is 1¾ ′ closer than the outer peripheral portion. It is learned that all ranges of the information recording medium can be suppressed. (Example 2) As shown in Table 2, according to the electron beam irradiation method of the above-mentioned mother film, the ratio of the linear velocity of the innermost peripheral side to the linear velocity of the outermost peripheral side in each recording range is -36-200535992 (33) The ratio of the linear velocity at the outermost periphery of each recording range / the linear velocity at the innermost periphery of each recording range is reduced to a specific range, and 11 recording ranges are set. For each recording range, the number of rotations shown in Table 2 is used to Rotate, and measure the bit error rate of the information memory medium formed by irradiation with an electron beam. The width in the radial direction of each recording range is set to be narrower on the inner peripheral side than on the outer peripheral side. Fig. 7 is a diagram illustrating the electron beam irradiation conditions of the master in order to obtain the information recording medium of Example 2. The horizontal axis in FIG. 7 is the radius of the mother wafer on which the electron beam sensing resist film is formed on the silicon wafer (the left side is the inner periphery); the vertical axis is divided into specific widths for the radial direction. The recording range, its rotation number and linear speed. As shown in Table 2, the number of rotations is fixed for each system in each recording range, and is set to decrease from the inner peripheral side toward the outer peripheral side of the mother film. The average linear velocity of each recording range is 1 · 7 6 9 (recording range 9) to 1. 8 2 5 (recording range 1) φ. The ratio of the maximum 値 to the minimum 平均 of the average linear velocity is 1 · 0 3, and is The setting is almost always 値. The ratio of the linear velocity of the innermost peripheral side to the linear velocity of each outermost recording range divided equally in the radial direction (linear velocity of the outermost periphery of each recording range / linear velocity of the innermost periphery of each recording range) System 1.1 〇 (recording range 1) to 1 · 1 1 (recording range 6 etc.). Table 2 shows the measurement results of the bit error rate. -37- 200535992 (34) Γ_- Record the inner circumference and outer circumference rotation of the inner circumference and the outer circumference. Average line bit error range radius radius number speed velocity speed error rate (mm) (m rn) j (m / sec) (m / sec ) (m / sec) xlO5 1 20 22 1 '' 3〇1.738 1.825 1.62 2 22 24.J_ _75〇_ 1.727 J ^ 9〇〇_ 1.814 1.52 3 2 4 〇6 7 5 1.710 1.880 1.795 1.37 4 26.6 2 9 ^ 3 __ ^ — 1.713 1.800 1.41 5 29.3 3 2.j_ 1,702 1.787 1.3 1 6 32.2 1.719 1.805 1.44 7 35.4 1.723 1.899 1.811 1.5 1 8 39 4? 9 42 0 1.715 1.886 1.801 1.36 9 42.9 4 7 2 _371__ 1.684 1.853 1.769 1.34 10 47.2 5 ±, 9_ 1.705 1.875 1.790 1.37 11 5 1.9 S 7 3 1 5. 1.712 1.880 1.769 1.25 According to the result shown in Table 2 /, 'radial width of each division range' is set to the inner peripheral side rather than the outer peripheral side If the side is narrow and the width is increased in the radial direction, the recording range on the inner peripheral side with a large change in the number of rotations will have a lower bit error rate. As a result, it is known that for all ranges of the information recording medium, the bit The meta error rate is further reduced. (Example 3) As shown in Table 3, the ratio of the linear velocity on the innermost side to the linear velocity on the outermost side in each recording range was -38-200535992 (35) according to the electron beam irradiation method of the above-mentioned mother film ( The ratio of the linear velocity at the outermost periphery of each recording range / the linear velocity at the innermost periphery of each recording range is reduced to a specific range, and 11 recording ranges are set. For each recording range, the number of rotations shown in Table 3 is used. Rotate and measure the bit error rate of the information storage medium formed by the irradiation of the electron beam. The radial width of each recording range is set to be narrower on the inner peripheral side than on the outer peripheral side. In this embodiment, the high-frequency vibration amplitude (vibration frequency: 47.9 MHz) of the electron beam in each recording range is continuously increased by an offset vector of 20 nm from the inner periphery to the outer periphery, so that the width of the concave track on the entire surface of the mother substrate is almost constant. Fig. 8 is a diagram for explaining the electron beam irradiation conditions of a mother substrate in order to obtain the information recording medium of the third embodiment. The horizontal axis in FIG. 8 is the radius of the mother wafer on which the electron beam sensing resist film is formed on the silicon wafer (the left side in the figure is the inner periphery); the vertical axis is divided into specific widths for the radial direction. The recording range is the partial vector of the number of rotations, linear velocity, and vibration amplitude. As shown in Table 3, the number of rotations is fixed for each system in each recording range, and is set to decrease from the inner peripheral side toward the outer peripheral side of the mother film. The average linear velocity of each recording range is 1. 7 8 7 (recording range 5) to 1. 8 2 5 (recording range 1). The ratio of the maximum 値 to the minimum 平均 of the average linear velocity is 1.02, and is set to Almost sure. The ratio of the linear velocity on the innermost peripheral side to the linear velocity on the outermost peripheral side of each recording range that is evenly divided in the radial direction (the linear velocity on the outermost periphery of each recording range / the linear velocity on the innermost periphery of each recording range) Department 1. 丨 0 (I have recorded range 1 ~ record range 1 1 etc.). Table 3 shows the measurement results of the bit error rate. -39- 200535992 (36)

[第3表] 記錄 內周 外周 旋轉數 內周線 外周線 平均線 位元錯 範圍 半徑 半徑 (rpm) 速度 速度 速度 誤率 (mm) (mm) (m / s e c) (m/sec) (m/sec) xlO5 1 20 22 855 1.738 1.912 1.825 1.06 2 22 24.2 780 1.727 1.900 1.814 1.07 3 24.2 26.6 705 1.710 1.880 1.795 1.06 4 26.6 29.3 645 1.713 1.886 1.800 1 .07 5 29.3 32.2 585 1.702 1.871 1.787 1.06 6 32.2 35.4 525 1.719 1.890 1.805 1.06 7 35.4 39 480 1.723 1.899 1.811 1 .06 8 39 42.9 435 1.715 1.886 1.801 1.06 9 42.9 47.2 405 1.684 1.853 1.769 1.11 10 47.2 5 1.9 360 1.705 1.875 1.790 1.06 11 5 1.9 57 330 1.712 1.880 1.796 1.06 由第3表所示之結果’各區分範圍之半徑方向寬度’ 係設定爲內周側較外周側部狹窄,而向著半徑方向使寬度 增加,並將各記錄範圔中電子束之高頻振動的振幅,由內 周向著外周增加2 0 n m的偏向量;結果,得知對於資訊記 錄媒體之所有範圍,位元錯誤率更加降低。 (實施例4) 如第4表所示,依上述之母片之電子束照射方法,設 200535992 (37) 置8個於半徑方向區分爲寬度5⑴ηι之同心圓狀的記錄範圍 ;針對各記錄範圍,以第4表所示之旋轉數來旋轉母片, 而對以電子束照射所形成之資訊記憶媒體,測定其位元錯 誤率。本實施例中,使各記錄範圍中電子束的高頻振動振 幅(顫動頻率:47.9MHz),由內周向外周連續增加偏向量 ,使母片整面之凹軌寬度幾乎保持一定。 第9圖,係爲了得到實施例4之資訊記錄媒體,說明母 φ 片之電子束照射條件的圖。第9圖中橫軸,係於矽晶圓上 形成有電子束感應阻劑薄膜之母片的半徑(圖中左方爲內 周);縱軸,係針對於半徑方向分別被區分爲寬度5mm之 記錄範圍,其旋轉數、線速度及偏向量。 如第4表所示,旋轉數在各記錄範圍之.每個係成爲一 定,而被設定爲由母片之內周側向著外周側減少。各記錄 範圍之平均線速度係1 · 9 7 9 (記錄範圍1 )〜1 · 8 6 5 (記錄範圍6 ) ,平均線速度之最大値與最小値的比爲丨·06,而被設定爲 φ 幾乎一定値。又,針對於半徑方向被平均分割之各記錄範 圍’最內周側之線速度與最外周側之線速度的比(各記錄 範圍最外周之線速度/各記錄範圍最內周之線速度)係1.25( 記錄範圍1 )〜1 · 0 9 (記錄範圍8 )。將位元錯誤率之測定結果 ,以第4表來表示。 - 41 - 200535992 (38) [第4表] 記錄 內周 外周 旋轉 內周線 外周線 平均線 位元錯 範圍 半徑 半徑 數 速度 速度 速度 誤率 (mm) (mm) (r p m) (m / s e c) (m/sec) (m/sec) xl〇5 1 20 25 840 1.759 2.199 1.979 1.06 2 25 30 675 1.767 2.120 1.943 1.06 3 30 35 570 1 .790 2.089 1.939 1.06 4 35 40 480 1.759 2.0 10 1.884 1 .06 5 40 45 420 1.759 1.979 1.869 1.06 6 45 50 3 75 1.767 1.963 1.865 1.06 7 50 55 345 1.806 1.987 1.896 1.08 8 55 60 3 15 1.814 1.979 1.896 1.10[Table 3] Record the number of rotations of the inner circumference and the outer circumference. The average line position error range of the inner circumference and outer radius. Radius (rpm). Speed Speed Speed Error Rate (mm) (mm) (m / sec) (m / sec) (m / sec) xlO5 1 20 22 855 1.738 1.912 1.825 1.06 2 22 24.2 780 1.727 1.900 1.814 1.07 3 24.2 26.6 705 1.710 1.880 1.795 1.06 4 26.6 29.3 645 1.713 1.886 1.800 1 .07 5 29.3 32.2 585 1.702 1.871 1.787 1.06 6 32.2 35.4 525 1.719 1.890 1.805 1.06 7 35.4 39 480 1.723 1.899 1.811 1 .06 8 39 42.9 435 1.715 1.886 1.801 1.06 9 42.9 47.2 405 1.684 1.853 1.769 1.11 10 47.2 5 1.9 360 1.705 1.875 1.790 1.06 11 5 1.9 57 330 1.712 1.880 1.796 1.06 by the first The result shown in Table 3, 'radial width of each division range', is set such that the inner peripheral side is narrower than the outer peripheral side, the width is increased toward the radial direction, and the amplitude of the high-frequency vibration of the electron beam in each recording range is set. The bias vector of 20 nm is increased from the inner periphery to the outer periphery; as a result, it is known that for all ranges of the information recording medium, the bit error rate is further reduced. (Example 4) As shown in Table 4, according to the electron beam irradiation method of the above-mentioned mother film, set 200535992 (37) to set 8 concentric circular recording ranges with a width of 5⑴η in the radial direction; for each recording range Rotate the master by the number of rotations shown in Table 4, and measure the bit error rate of the information storage medium formed by irradiation with an electron beam. In this embodiment, the high-frequency vibration amplitude (vibration frequency: 47.9 MHz) of the electron beam in each recording range is continuously increased from the inner periphery to the outer periphery so that the width of the recessed track on the entire surface of the mother substrate is almost constant. FIG. 9 is a diagram for explaining the electron beam irradiation conditions of the mother φ sheet in order to obtain the information recording medium of Example 4. FIG. The horizontal axis in FIG. 9 is the radius of the mother wafer on which the electron beam sensing resist film is formed on the silicon wafer (the left side in the figure is the inner periphery); the vertical axis is divided into 5 mm widths for the radial direction. The recording range, its number of rotations, linear velocity and bias vector. As shown in Table 4, the number of rotations is in each of the recording ranges. Each system becomes constant, and is set to decrease from the inner peripheral side toward the outer peripheral side of the mother film. The average linear velocity of each recording range is 1 · 9 7 9 (recording range 1) to 1 · 8 6 5 (recording range 6). The ratio of the maximum 値 to the minimum 平均 of the average linear velocity is 丨 · 06, and is set to φ is almost always 値. The ratio of the linear velocity on the innermost peripheral side to the linear velocity on the outermost peripheral side of each recording range that is evenly divided in the radial direction (the linear velocity on the outermost periphery of each recording range / the linear velocity on the innermost periphery of each recording range) The range is 1.25 (recording range 1) to 1 · 0 9 (recording range 8). Table 4 shows the measurement results of the bit error rate. -41-200535992 (38) [Table 4] Record the inner circumference and outer rotation, the inner circumference, the outer circumference, the average line bit error range, the radius, the speed, the speed, and the error rate (mm) (mm) (rpm) (m / sec) (m / sec) (m / sec) xl05 1 20 25 840 1.759 2.199 1.979 1.06 2 25 30 675 1.767 2.120 1.943 1.06 3 30 35 570 1 .790 2.089 1.939 1.06 4 35 40 480 1.759 2.0 10 1.884 1.06 5 40 45 420 1.759 1.979 1.869 1.06 6 45 50 3 75 1.767 1.963 1.865 1.06 7 50 55 345 1.806 1.987 1.896 1.08 8 55 60 3 15 1.814 1.979 1.896 1.10

由第4表所示之結果,將各記錄範圍中電子束之高頻 振動的振幅,由內周向著外周增加其偏向量,而得知對於 ® 資訊記錄媒體之所有範圍,位元錯誤率更加降低。 如此,若依本實施方式所適用之資訊記錄媒體用之母 片製造方法,則可抑制電子束之軸變動,並保持高度的資 訊記錄位置精確度;更且,藉由與電子束之偏向量控制的 組合,則可針對資訊記錄媒體之整面,謀求位元錯誤率的 降低。 【圖式簡單說明】 第1圖說明母片照射裝置的圖。 -42- 200535992 (39) 第2圖說明母片之記錄範圍的圖。第2圖(a)係表示於 半徑方向平均區分之複數記錄範圍;第2圖(b)係表示具有 不同寬度之複數記錄範圍。 第3圖說明使電子束偏向於與軌幾乎垂直之方向之型 態的圖。 第4圖說明實施例所使用之資訊記錄媒體的圖。 第5圖說明位元錯誤率測定裝置的圖。 第6圖係爲了得到實施例1之資訊記錄媒體,說明母片 之電子束照射條件的圖。 第7圖係爲了得到實施例2之資訊記錄媒體,說明母片 之電子束照射條件的圖。 第8圖係爲了得到實施例3之資訊記錄媒體’,說明母片 之電子束照射條件的圖。 第9圖係爲了得到實施例4之資訊記錄媒體,說明母片 之電子束照射條件的圖。 第10圖針對CLV方式,說明光碟片用母片其半徑位 置和旋轉數之關係的圖。 【主要元件符號說明】 1 〇 :鏡塔 1 1 :電子槍 1 2 :電容透鏡 1 3 :斷開電極 1 4 :孔徑 -43- 200535992 (40) 1 5 :偏向電極 1 6 :物鏡 1 7 :訊號源 18 :光束調變器 1 9 :電子束 2 0 :試料室 21、 21a、 21b :母片 g 22 :旋轉台 23 :移動台 24 :導引螺旋 2 5 :交流伺服器 2 6 :控制器 4 1 :透明基板 4 2 :散熱層 4 3 :記錄層 φ 44 :常磁性層 45 :觸發層 4 6 :再生層 4 7 :強化層 4 8 :保護塗佈層 5 1 :驅動光學頭 52:位元錯誤分析器 5 6 :雷射驅動器 5 7 :光磁性訊號 -44 - 200535992 (41) 58 :帶通濾波器 5 9 :等化器 1 0 0 :母片照射裝置 400 :資訊記錄媒體 5 00 :位元錯誤測定裝置From the results shown in Table 4, the amplitude of the high-frequency vibration of the electron beam in each recording range was increased from the inner periphery to the outer periphery, and it was found that for all ranges of the ® information recording medium, the bit error rate was even greater. reduce. In this way, according to the method for manufacturing a mother film for an information recording medium applicable to this embodiment, it is possible to suppress the axis variation of the electron beam and maintain a high degree of information recording position accuracy; moreover, by using a bias vector with the electron beam The combination of controls can reduce the bit error rate for the entire surface of the information recording medium. [Brief Description of the Drawings] FIG. 1 is a diagram illustrating a mother film irradiation device. -42- 200535992 (39) Figure 2 illustrates the recording range of the master film. Fig. 2 (a) shows the plural recording ranges divided evenly in the radial direction; Fig. 2 (b) shows the plural recording ranges with different widths. Fig. 3 is a diagram illustrating a state in which the electron beam is deflected in a direction almost perpendicular to the orbit. Fig. 4 is a diagram illustrating an information recording medium used in the embodiment. Fig. 5 is a diagram illustrating a bit error rate measuring device. Fig. 6 is a diagram for explaining the electron beam irradiation conditions of the mother substrate in order to obtain the information recording medium of the first embodiment. Fig. 7 is a diagram for explaining the electron beam irradiation conditions of the mother substrate in order to obtain the information recording medium of the second embodiment. Fig. 8 is a diagram for explaining the electron beam irradiation conditions of the mother substrate in order to obtain the information recording medium of the third embodiment. Fig. 9 is a diagram for explaining the electron beam irradiation conditions of the mother substrate in order to obtain the information recording medium of the fourth embodiment. Fig. 10 is a diagram illustrating the relationship between the radius position and the number of rotations of the master disc for optical discs for the CLV method. [Description of main component symbols] 1 〇: Mirror tower 1 1: Electron gun 1 2: Capacitive lens 1 3: Disconnect electrode 1 4: Aperture -43- 200535992 (40) 1 5: Deflecting electrode 16: Objective lens 1 7: Signal Source 18: Beam modulator 19: Electron beam 2 0: Sample chamber 21, 21a, 21b: Mother piece g 22: Rotary table 23: Mobile table 24: Guide screw 2 5: AC servo 2 6: Controller 4 1: Transparent substrate 4 2: Heat dissipation layer 4 3: Recording layer φ 44: Normal magnetic layer 45: Trigger layer 4 6: Regeneration layer 4 7: Reinforcement layer 4 8: Protective coating layer 5 1: Drive optical head 52: Bit error analyzer 5 6: Laser driver 5 7: Photomagnetic signal -44-200535992 (41) 58: Bandpass filter 5 9: Equalizer 1 0 0: Master film irradiation device 400: Information recording medium 5 00: Bit error measuring device

Claims (1)

200535992 (1) 十、申請專利範圍 1 · 一種資訊記錄媒體用母片作成方法,係針對使用一 種具備了對具有因電子束照射而產生極性變化之電子束感 應阻劑薄膜之母片,照射電子束之電子束照射手段、和保 持母片並加以旋轉之驅動手段、和將電子束照射手段與母 片改變其水平方向相對位置之變動手段的,母片照射裝置 ,來照射電子束,而形成螺旋狀或同心圓狀之軌的資訊記 Φ 錄媒體用母片作成方法;其特徵係 將照射上述電子束之範圍,區分爲於半徑方向被分割 爲同心圓狀之複數記錄範圍; 將上述母片之照射電子束之範圍中每單位時間之電子 束照射量保持一定,而針對被區分之各上述記錄範圍,使 上述母片之旋轉數爲一定地加以控制。 2 ·如申請專利範圍第1項所記載之資訊記錄媒體用母 片作成方法,其中,係針對被區分之上述記錄範圍之邊界 φ 部,自外周之被區分之上述記錄範圍,向著內周之被區分 之上述記錄範圍,使其階段性之增加旋轉數地加以控制者 〇 3 ·如申請專利範圍第1項或第2項所記載之資訊記錄媒 體用母片作成方法,其中,係針對旋轉的上述母片之被區 分之上述記錄範圍’將線速度之最大値和線速度之最小値 的比,控制在1 . 3以下者。 4 ·如申請專利範圍第1項至第3項之任一項所記載之資 訊記錄媒體用母片作成方法,其中,係針對旋轉的上述母 -46 - 200535992 (2) 片之被區分之各上述記錄範圍間,將平均線速度之最大値 和平均線速度之最小値的比,控制在1 · 1以下者。 5·如申請專利範圍第1項至第4項之任一項所記載之資 訊記錄媒體用母片作成方法,其中,被設置於上述母片之 內周側之被區分之上述記錄範圍的寬度,係較被設置於上 述母片之外周側之被區分之上述記錄範圍的寬度爲窄者。 6·如申請專利範圍第1項至第5項之任一項所記載之資 • 訊記錄媒體用母片作成方法,其中’係使用更具備了將電 • 子束對上述軌以幾乎垂直之方向加以振動之電子束偏向手 段的母片照射裝置,來照射電子束;針對被區分之各上述 記錄範圍,使上述電子束之偏向量自內周向外周增加地加 以控制者。 7·—種資訊記錄媒體用之母片照射裝置,其特徵係具 備 對具有因電子束照射而產生極性變化之電子束感應阻 ^ φ 劑薄膜之母片,照射電子束之電子束照射手段; 、和保持上述母片並加以旋轉之驅動手段; 和將電子束照射手段與母片改變其水平方向相對位置 之變動手段; 和將上述母片之照射上述電子束之範圍,區分爲於半 徑方向被分割爲同心圓狀之複數記錄範圍,並將被區分之 各上述記錄範圍中每單位時間之電子束照射量保持一定, 而針對被區分之各該上述錄範圍,使上述母片之旋轉數爲 一定地加以控制的控制手段。 -47- 200535992 (3) 8 ·如申請專利範圍第7項所記載之資訊記錄媒體用之 母片照射裝置,其中,係更具有係針對被區分之上述記錄 範圍之邊界部,自外周之被區分之上述記錄範圍,向著內 周之被區分之上述記錄範圍,使其階段性之增加旋轉數地 加以控制的,控制手殺者。 9 ·如申請專利範圍第7項或第8項所記載之資訊記錄媒 體用之母片照射裝置,其中,針對被區分之上述記錄範圍 ^ φ 之邊界部,將上述母片之旋轉數之變更,以10旋轉以下來 • 進行者。 10·如申請專利範圍第7項至第9項之任一項所記載之 資訊記錄媒體用之母片照射裝置,其中,係更具備進行上 述母片之旋轉控制,同時輸出旋轉之該母片之角度資訊的 ,旋轉角度資訊輸出手段者。 1 1 ·如申§靑專利朝圍第7項至第1 〇項之任一項所記載之 資訊記錄媒體用之母片照射裝置,其中,係更具備控制上 .φ 述電子束之偏向量的偏向控制手段者。 、 1 2 .如申請專利範圍第1 1項所記載之資訊記錄媒體用 之母片照射裝置,其中,電子束之上述偏向控制手段,係 採用靜電偏向者。 1 3 · —種資訊記錄媒體之製造方法,其係一種具有特 定螺旋狀或同心圓狀之軌的資訊記錄媒體之製造方法,係 針對具有形成包含特定凹軌之資訊記錄媒體用母片的母片 形成工程、和形成一個被轉印有被形成之上述資訊記錄媒 體用母片之凹軌的形狀之金屬鑄模的,鑄模形成工程;並 -48- 200535992 (4) 且上述母片工程,具備電子束照射手段、和變動與母片之 水平方向相對位置的變動手段、和使上述母片旋轉之驅動 手段的,特定之電子束照射裝置;其特徵係 將因上述驅動手段而旋轉之上述母片其表面的電子束 感應阻劑薄膜,以上電子束照射手段來照射電子束,然後 以上述變動手段來改變上述電子束照射手段與上述母片之 水平方向相對位置,以上述電子束照射手段來照射電子束 φ 時,係將上述母片中被照射上述電子束之區域,區分爲於 半徑方向分割爲同心圓狀的複數記錄範圍,將上述母片之 照射電子束之範圍中每單位時間之電子束照射量保持一定 ,然後使上述母片之上述旋轉數爲一定地來照射電子束。 14. 一種資訊記錄媒體,係於基板上形成有螺旋狀或 同心圓狀之記錄用軌的資訊記錄媒體;其特徵係具有 於上述基板上以特定寬度被區分爲同心圓狀之複數記 錄範圍, • 和被設置於被區分之各上述記錄範圍之邊界部,其上 述基板之半徑方向之寬度爲1 0軌以下的遷移範圍。 1 5 .如申請專利範圍第1 4項所記載之資訊記錄媒體, 其中,被區分之各上述記錄範圍,其外周側之半徑位置和 內周側之半徑位置的比,係在1 .3以下者。 ]6 .如申請專利範圍第1 4項或第1 5項所記載之資訊記 錄媒體,其中,被設置於該基板之內周側之被區分之上述 記錄範圍的寬度,係較被設置於該基板之外周側之被區分 之上述記錄範圍的寬度爲窄者。 -49-200535992 (1) 10. Scope of patent application1. A method for preparing a master sheet for information recording media is directed to the use of a master sheet provided with an electron beam sensing resist film having a polarity change due to electron beam irradiation to irradiate electrons The electron beam irradiating means for the beam, the driving means for holding and rotating the mother sheet, and the changing means for changing the relative position of the electron beam irradiating means and the mother sheet in a horizontal direction, the mother sheet irradiating device irradiates the electron beam to form Information recording of spiral or concentric tracks Φ The recording medium uses a master film; it is characterized by dividing the range of the above-mentioned electron beam into a plurality of recording ranges that are divided into concentric circles in the radial direction; The irradiation amount of the electron beam per unit time in the range of the irradiated electron beam of the sheet is kept constant, and the number of rotations of the above-mentioned mother sheet is controlled to be constant for each of the above-mentioned recording ranges that are distinguished. 2 · The method of making a master film for an information recording medium as described in item 1 of the scope of the patent application, wherein the boundary φ of the above-mentioned divided recording range is defined from the outer recording area to the inner recording area. Those who have distinguished the above-mentioned recording range to control the increase in the number of rotations in stages. 03. The method of creating a master film for the information recording medium as described in the first or second scope of the patent application. The above-mentioned recording range of the above-mentioned master film that is distinguished is to control the ratio of the maximum linear velocity to the minimum linear velocity to 1.3 or less. 4 · The method of making a master film for an information recording medium as described in any one of the items 1 to 3 of the scope of patent application, wherein the above-mentioned master-46-200535992 (2) films are distinguished for each of the rotations The ratio between the maximum 値 of the average linear velocity and the minimum 値 of the average linear velocity between the above recording ranges is controlled to be less than or equal to 1.1. 5. The method of making a master film for an information recording medium as described in any one of the scope of claims 1 to 4, wherein the width of the above-mentioned divided recording range is set on the inner peripheral side of the master film , Which is narrower than the width of the above-mentioned divided recording range provided on the outer peripheral side of the above-mentioned mother film. 6 · As described in any of items 1 to 5 of the scope of the patent application. • A method of making a master film for the information recording medium, in which 'system use is more equipped with the ability of the electron beam to be almost perpendicular to the above track. The mother plate irradiation device of the electron beam deflection means that vibrates in the direction irradiates the electron beam; for each of the above-mentioned recorded ranges, the deviation vector of the electron beam is increased and controlled from the inner periphery to the outer periphery. 7 · —A mother sheet irradiation device for an information recording medium, which is characterized by having an electron beam irradiation means for irradiating an electron beam with a film having a resistance change of the electron beam induced by the electron beam ^ φ agent film; And driving means for holding and rotating the mother sheet; and changing means for changing the relative position of the electron beam irradiation means and the mother sheet in a horizontal direction; and dividing the range of the mother sheet irradiating the electron beam into a radial direction Divided into concentric circular plural recording ranges, and keeping the amount of electron beam irradiation per unit time in each of the divided recording ranges fixed, and for each of the divided recording ranges, the number of rotations of the master film is made Control means for certain control. -47- 200535992 (3) 8 · The master film irradiation device for the information recording medium as described in item 7 of the scope of patent application, which further has a boundary portion for the above-mentioned recording range which is distinguished from the outer periphery. The division of the above-mentioned record range toward the inner range of the above-mentioned record range is controlled in stages to increase the number of rotations to control the hand killer. 9 · The parent piece irradiation device for the information recording medium as described in item 7 or item 8 of the patent application scope, wherein the number of rotations of the parent piece is changed for the boundary portion of the distinguished recording range ^ φ Come with 10 spins or less • Performer. 10. The master film irradiating device for the information recording medium as described in any one of items 7 to 9 of the scope of the patent application, wherein the master film irradiation device further includes a rotation control of the master film and outputs the rotated master film at the same time. For angle information, rotation angle information output means. 1 1 · As claimed in § 靑 Patent Chaowei, any of the items 7 to 10 described in the information recording medium for the master film irradiation device, which is more equipped with control. Φ said electron beam bias vector Control-oriented people. 12. The device for irradiating a mother sheet for an information recording medium as described in item 11 of the scope of patent application, wherein the above-mentioned deflection control means of the electron beam is an electrostatic deflection. 1 3 · A method for manufacturing an information recording medium, which is a method for manufacturing an information recording medium having a specific spiral or concentric circular track, and is directed to a master having a master sheet for forming an information recording medium including a specific concave track Sheet forming process and forming a metal mold having the shape of the concave rail of the mother sheet for the information recording medium formed thereon, a mold forming process; and -48- 200535992 (4) and the above-mentioned mother sheet project, having Electron beam irradiation means, and means for changing the relative position of the mother sheet in the horizontal direction, and driving means for rotating the mother sheet, specific electron beam irradiation devices; characterized in that the mother part is rotated by the driving means. The electron beam sensing resist film on the surface of the sheet is irradiated with the electron beam by the above electron beam irradiation means, and then the above-mentioned changing means is used to change the relative position of the electron beam irradiation means and the horizontal direction of the mother sheet, and the electron beam irradiation means is used to When the electron beam φ is irradiated, the area of the mother substrate to be irradiated with the electron beam is divided into radial directions. Cutting a plurality of concentric recording range, the range of electron beam irradiation of the master of the electron beam irradiation amount per unit of time remains constant, and so that the number of rotation of the master to be constant electron beam irradiation. 14. An information recording medium is an information recording medium on which a spiral or concentric circular recording track is formed on a substrate; it is characterized in that it has a plurality of recording ranges divided into concentric circles with a specific width on the substrate, • In the boundary part of each of the above-mentioned recording ranges, the width of the substrate in the radial direction is a migration range of 10 tracks or less. 15. The information recording medium described in item 14 of the scope of patent application, wherein the ratio of the radius position on the outer peripheral side to the radius position on the inner peripheral side of each of the above-mentioned recorded ranges is 1.3 or less. By. ] 6. The information recording medium described in item 14 or item 15 of the scope of patent application, wherein the width of the above-mentioned divided recording range provided on the inner peripheral side of the substrate is wider than that provided in the The width of the above-mentioned divided recording range on the outer peripheral side of the substrate is narrow. -49-
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