TW200524B - - Google Patents

Description

^ 00524 ^ 00524 Printed A6 ____ B6_ by the Employee Consumer Cooperative of Biyangyi, Ministry of Economic Affairs. V. Description of the invention (1) Zangjiejie The present invention is concerned with the preparation of sister compounds including condensed detergent particles. The compound of the invention Beibei Granule Detergent has been prepared in principle by drying in open fog so far. In the mist-drying process, detergent components, such as surfactants and rib cleaners, are mixed with up to 35-50% water, and κ forms a slurry. The obtained slurry is heated and the mist is dried, which is an expensive method. However, a good agglomeration method will be a cheaper method. Spray drying needs to remove 30-40% by weight of water. The equipment used for spray drying is expensive. The granules obtained have good solubility, but low bulk density, so the package is large. Moreover, the flow properties of the granules obtained by spraying S stemene are adversely affected by the irregularities of the large surface | therefore, the granulated products have a bad appearance. Granular detergents prepared by spray dry castellation have other known disadvantages. There are many non-standard methods for manufacturing detergent particles. They also have disadvantages. Most require a mixer on K and a separate granulation operation. Others require the use of acid form surfactants. Some others require pyrolysis of the starting material Shao. Because of its viscosity relationship, high-activity surfactant pastes are avoided in these methods. European A-1 110 731, published on August 13, 1984, is shown to dry without any evaporation »forming a solid" * The box is made by mixing the surfactant solution in a deep phase * mixed with rib lotion powder Method of detergent powder. Describe the process of solid «strips or rubs for rolling; but there is no teaching etc." Attached-3-This paper scale uses the Chinese "Home #Bi (CNS) 〒 4 specifications (210X297 mm) 81. 5. 20,000 ( H) (Please read the precautions on the back before filling in this page) 装 · 线 _ 200524 B6 V. Description of invention (2) The printing and aggregation function of the Employee Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs, directly forming high activity from paste conditioning grain. European Patent No. A-〇345 090, published on December 6, 1989, shows the preparation method of the micro-barrel detergent compound, which includes connecting the detergent acid with the neutralizer, and removing the B agent Acid and particulate bark neutralizer or detergent salt and carrier, in contact with the absorption belt, provide particulates. European Patent No. A-〇349 201, published on January 3, 1990, discloses that the finely divided dry decontamination rib lotion and the highly active interfacial active agent are placed in a uniform slurry, after cooling and Use finely dispersed granules to form uniform free-flowing granulated particles to produce condensed detergent particles. European Patent-0 390 251, published on October 3, 1990, shows a continuous manufacturing method of granular detergents or sister compounds. It includes first the particulate starter of the detergent surfactant and the builder The agent is processed in a high-speed mixer, followed by a medium-speed granulator / thickener • The third is processed in a dry grain / cooling device, added in the second step or between the first and second steps Powder * to reduce the amount of large particles encountered. A. Davidsohn and B. M. Mi ldwidskv. In Synthetic Dpt, ergpnt. S, John Wiley & Sons 1978, 6th edition, show the general decontamination professor, including the manufacture of manufactured detergent products. High-shear and cold mixing methods are well-known methods, but they require additional grinding steps or some other functions. For example, some use the acid form surfactant mixed with sodium carbonate to dry "neutralization technology. Please refer to Brooks' American No. 4,515.707 II issued on May 7, 1985; Kao 8E Soap Company's Japanese Patent Grant Public Publication No. -4- issued on September 30, 1983 (please read the back Please pay attention to this page and then fill in this page). Ί, turn _ This paper is used in the "Home" standard (CNS) A 4 specifications (210x297 mm) 81. 5. 20,000 (Η) V. Description of the invention (3) A 6 B6 The Ministry of Economic Affairs, Pyongyang Bureau of Industry and Commerce Co., Ltd. printed 183540/1983; and June 5, 1986 Lion K.1C. Japanese application Sho. 6 Bu 1 1 8500. Typically, excess carbonate (2-20 moles) is required to ensure a reasonable conversion of surfactant acid. The amount of carbonates unfavorably raises the pH of the wash water to a very alkaline range, which is particularly unsuitable for some low phosphate formulations. The use of surfactant acids generally requires immediate use or storage at cooling temperature, because highly reactive acids such as alkyl sulfate acids will degrade unless cooled *, and they tend to hydrolyze during storage and form free sulfuric acid and leaven during storage. It is practically stated that this prior art method requires a close combination of surfactant acid generation and granulation that requires additional capital investment. The second way is well known in this range and described in the patent literature, which is anionic surfactant acid and caustic solution (for example: 50% sodium hydroxide) or caustic powder (for example: carbon carbonate), in Just before or during granulation step test • Neutralize in situ. In this case, care should be taken to ensure the complete neutralization of the acid to avoid undesirable effects on the thorny interface and active agent base during storage and / or washing. The resulting particles are highly thick particles that can be combined with human particles and decontamination agents. When this second channel uses lower temperatures and & less deep shearing conditions than agitating and spraying, it has many limitations. On the one hand, it is necessary to perform a chemical reaction (neutralization) during the granulation step a or just before granulation, which is quite restrictive and can be used (temperature chemicals, etc.). In addition to ionic interface activity_acid of very low pH · prevent sensitive to these acidic conditions! ® = incorporation. Especially for the chemically unstable or deionized surfactants in acid form. This method requires a bowl (please read the precautions on the back before filling the nest page).--Order-Line-_ — 5 — The size of this paper is used in the "Home-like Chia (CNS) A 4 specifications (210X297 g *) '81. 5. 20.000 (H) 200 lectures A6 ____ B6 5. Description of the invention (4) Chemical unit and neutralization / granulation Step by step, close integration. This leads to the ease of logistics and / or design of these methods that are quite limited and it is important to increase the complexity and sleepiness of the control system of the entire method. Printed by the Beiyang Purification Bureau Beigong Xiaozhi Cooperative of the Ministry of Economic Affairs The present invention solves the above-mentioned difficulties and provides a more flexible and flexible approach to the processing of granular detergents. The present invention is based on an agglomeration / granulation step, which is not at all combined with the sulfation / sulfonation method. M obtains a surfactant which greatly increases the surfactant activity of the agglomerates, and the present invention can increase the ratio of the period to the powder capable of forming brittle particles. This can be achieved by chemical and / or physical construction of the paste, such as adding special chemical construction agents and / or removing moisture, and temperature control. The basis of the present invention is to introduce anionic surfactants into their salts, preferably the hydration of their sodium salts, and highly concentrated solutions. These high-activity (low-moisture) surfactant pastes are high-viscosity pastes, but they can still be pumped at a stable temperature of the surfactant. This guarantees that the chemicals can be transported and transferred from the manufacturing site to the granulation site and before the particles are formed, it can facilitate the storage of the dang. In those cases, sulfation / sulfonation are immediately before the granulation step, which provides the possibility of installing intermediate flushing barrels, simplifying the control of the entire unit. For some anionic surfactants or mixtures thereof, where the phase stagnate stagnate liquid crystal phase occurs, this process requires the formation of a lower stagnate phase (eg, clean phase (neat phases)) or the use of some viscosity Modified clams (for example: hydro tropes). The invention also describes a method of paste conditioning. It has been found that the addition of chemical rate-building agents, temperature control, and / or removal of water from the paste, the physical property is Μ 踺 • For example: fusion bonding and viscosity, which in turn determines the mixture of pastes / or granules. Characteristics of decontamination particles. It is found that this paste is very effective in conditioning 81. 5. 20,000 (H) (please read the precautions on the back before filling in this page). This paper uses the Chinese National Sample (CNS) A4 specification (210x297 *) A 6 __B6 V. Description of the invention (5) The printing method of the Employee Consumer Cooperative of the Central Committee of the Ministry of Economic Affairs is the use of an extruder. An important object of the present invention is to produce thickened and concentrated detergent particles by an agglomeration method contrary to the Ogushi-Dai method. Other objects of the present invention will be apparent from the following. Invention The invention is an economical method for manufacturing a thickened, concentrated detergent particle product, and in particular a sister compound that includes highly active condensed detergent particles, wherein the aforementioned method includes a high-activity paste agglomeration step, Chemical treatment of the paste obtained by Cong Tong. The invention is particularly applicable to all neutralizing AS hydrated pastes. It can be proved that it can be used for various surfactants. The invention is a method for manufacturing a free-flowing granular bark detergent, which includes: an effective amount of a chemical builder and an effective amount of a hydrated surfactant having at least 40% detersive activity Bundle mixing; from the aforementioned mixture, at a paste temperature of 20 ~ 90t • A uniform thick paste is quickly formed: the aforementioned paste is granulated when mixed with a dry detergent * wherein the aforementioned surfactant paste is composed of at least one Anionic surfactants are successful, and if there are any other surfactants, they include anionic, non-ionic, zwitterionic, amphoteric, and isolating surfactants and their mixture. In a preferred method, the aforementioned chemical constructing agent is added by the above method. The present invention is based on the method of making a high-activity surfactant paste. • It has agglomeration / granulation steps, which are completely separated from the acid-sulfurizing and sulfonating processes. Page) Binding · Binding-Thread. _-7-_ This paper is used in the "Chinese home standard (CNS) A 4 specifications (210x297 mm) 81. 5. 20.000 (H)

Printed by the β-Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs. Also includes chemical conditioning of the paste produced by the aforementioned method to obtain highly active particles. The conditioning of paste means that its physical properties are modified to form higher active agglomerates, which are not easily obtained by other methods under normal operating conditions. The present invention is particularly applicable to all hydrating pastes that are neutralized. It can be proved to be applicable to various surfactants (for example: Coco, Tallovr, etc.). In a specific embodiment of the present invention, an anionic surfactant is introduced into its salt, preferably a highly splashed aqueous solution of its sodium salt. These high-activity (and preferably low-moisture) surface-active pastes are high-viscosity pastes, but they remain pumpable at a temperature where the surfactant is stable. In other specific examples of the present invention, the anionic surfactant or mixture includes at least one anionic surfactant, in which a highly viscous liquid crystalline phase occurs, which requires the formation of a lower viscosity phase or the use of some viscosity modifier. In a more preferred embodiment, organic and / or inorganic compounds that change the physical structure and / or physical properties of the surfactant paste are added to the pomelo. It was found that this addition reduced the viscosity of the paste to the surfactant bundle * increased its viscosity and increased its softening point. This allows more paste to be added during the agglomeration process, thus resulting in higher active agglomerates, i.e. more than 50%. The processing method of this surfactant paste | can be batch and continuous • preferably continuously. In a preferred embodiment of the present invention, an extruder is used to condition the paste. This squeeze is a multi-purpose device that can mix 2 or more pastes and / or add this chemical building clam to this viscosity period and mix with the viscous paste. Moreover, it can remove water under Xingkong and control the temperature of the paste. As defined in this article, the conditioning of the bale means: a) the viscosity of the surface cascade · b) the effective viscosity of the poca-coa, c) the "hardness" and d) of the poca-paa (please read the back (Notes and then fill out this page) Binding · Order-This paper is used in the standard BB home sample standard (CNS) A 4 specifications (210x297 g *) 81. 5. 20.000 (H)

Kt 005 A6 B6 V. Description of the invention (7) Printed by the Beigong Consumer Cooperative of the Central Bureau of Economics of the Ministry of Economic Affairs to reduce the viscosity of the particles formed. The hardness and softness of the bale can be measured by a softness penetration meter according to ASTM 217-IP50 or ISO 2137. In this way, the paste hardness should be less than 2 cm, preferably less than 1 cm. This paste can be conditioned by i) cooling, ii) refining, cursing) adding a build agent (usually an electrolyte) during the period of highly active detergent. A paste useful in the present invention will consist of at least 40% by weight of anionic surfactant salts. The paste has a viscosity of at least 10 poises when measured at 701C and a shear rate of 25 seconds. Huayin Caizhi A viscous chemical builder, when added to a surfactant paste, will wait for the chemical and / or physical properties of the paste to be modified. M will form highly active agglomerates. These agents can be in solid, liquid or solution form, depending on their special chemical properties. Examples of agents useful in the present invention include 50% aqueous sodium hydroxide solution, 50% aqueous potassium hydroxide solution, sodium phthalate, silicate, silica, starch, polymer and copolymer • Nonionic interface Active agent and urea. The above agents can be used separately or mixed with each other according to their coordination properties. I The bundle used in the present invention is preferably one or a variety of different deionizing surfactants, "Hydrated paste * is preferably anionic interface active salt period. In the preferred embodiment, the anionic surfactant is preferably as shrinkable as possible (that is, it has the lowest possible moisture content • it is allowed to flow in a liquid way) * to keep it at a stable temperature Pumper. The different pure or mixed surfactants used in granulation are well known, because the present invention is used in industry and is equivalent to the physical properties of granular decontamination -9- (please first Read the precautions on the back and fill in this page.)-Line · This paper is used in the standard «Home Sample Standard (CNS) A 4 specifications (210x297 mm) 81. 5. 20.000 (H) 〇〇〇0 ^ 3 ^ A 6 B6 V. Description of the invention (8) The printed particles of anionic surfactant must be part of the bundle of the printed particles of the Beigong Xiaozhi Cooperative of the Central Acquisition Bureau of the Ministry of Economic Affairs. Its concentration is higher than 10%, preferably 10- 95%, better 20-95% · best 40-95¾. It is best to keep the moisture in the surfactant hydrated paste as low as possible, while maintaining the fluidity of the paste, because low moisture will cause a higher concentration of surfactant in the particles produced. Preferably, the paste contains 5-40% moisture, more preferably 5-30% moisture, and most preferably 5% -20% moisture. A relatively attractive operation to reduce the moisture content of the paste. It has a high viscosity before entering the agglomeration machine but there is no problem because the outlet is connected to the air or vacuum rapid drying machine on the agglomeration. It is best to use a high-activity surfactant paste to minimize the moisture content in the system during mixing * granulation and drying. The lower moisture content allows: ⑴ higher ratio of active surfactant to builder • eg 1: 1; (2) higher concentration of other liquids in the formula without causing paste or particle stickiness; ⑶ Less cooling due to a higher allowable granulation temperature; and ⑷ Less granule drying to meet the final moisture limit. Two important parameters of this surfactant paste | which can affect the mixing and granulation step is the paste temperature and viscosity. The viscosity is a function of concentration and temperature. In this application range, the viscosity is from about 1,000 to 10,000,000 cps. Preferably, the viscosity of arsenic into the human system is about 20,000 to about 100,000 cps, and more preferably about 30.000 to about 70,000 cps. The catfish degree of the paste of the present invention is set at 70 * 0. In this period, the initial temperature can be between its softening point (usually within the temperature range of 40-60t) and its decomposition point (depending on the chemical characteristics of 梱) • For example: acid-repellent (please read the precautions on the back before filling in this Page) Pack · Order ·

1 1 0 — This paper is used in the «Home» Standard (CNS) Grade 4 Specification (210x297 mm) 81. 5. 20 (〇〇〇W V. Description of the invention (9) Central Bureau of Economic Development When the alkyl ester paste printed by the industrial and consumer cooperatives is higher than 75-85¾, it tends to degrade) and is introduced into the mixer. High temperatures reduce the viscosity and simplify the pumping of the paste, but will result in lower active agglomerates. However, the use of a moisture reduction step in the pipeline (for example: quick drying) requires the use of a higher temperature (above 100tn. In the present invention, due to the elimination of moisture, high agglomerate activity can be maintained. Paste introduction The mixer can be carried out in many ways. Before it enters the mixing hump, it can be simply dumped to the end of the tube and pumped through a small hole at high pressure. All of these methods can produce agglomerates with good physical properties. In a preferred embodiment, the extrusion of the paste leads to a better distribution in the kneader, which improves the production of particles of the expected size. Before entering the mixture • Use high pumping pressure • Equally increase the final agglomerate Activity. Thin by mixing the two actions, and making the pores too small to allow holes (squeeze) to allow the expected flow rate, but maintaining the pumping force in the system to the maximum feasibility will achieve quite favorable results. Bottom layer and fertile side are thin. The activity of this hydrated surfactant paste is at least 30% and can be as high as about 95%; the preferred activities are: 50-80% and 65-75%. The balance of the paste is mainly water but can be included Including processing rib agents such as non-ionic surfactants. At higher activity levels, a little or no builder is required for the cold granulation of the paste. The resulting condensed surfactant particles can be added to dry Rib lotion or powder or use conventional agglomerates. This hydrated surfactant contains a kind of surfactant, which is selected from deionized, zwitterionic, amphoteric and cationic surfactants. And their mixtures. Anionic surfactants are preferred, and nonionic surfactants are used as the second type of surfactant (please read the precautions on the back and then fill out this page) ---- —11 — This paper is for standard use In the "National Sample Rate (CNS) A 4 specifications (210x297 g *) 81 5. 20,000 (H) V. Description of invention (ίο) A6 B 6

The printing agent M or the processing rib agent of the 8th Industrial Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs is not included in this article as a "" active" surfactant. Useful interface activities for this article are listed in 197 Norris US Patent No. 3,664,961 published on May 23, 197; and US Patent No. 3,919,678 issued on December 30, 1975 by 1 ^ 1 ^ 111 丨 〇 et al. . Useful positive ionic surfactants also include those in Cockrell U.S. Patent No. 4,222,905 issued September 16, 1980, and Murphy's U.S. Patent No. 4,239.659 issued December 16, 1980. However, cationic surfactants and the aluminosilicate materials herein are generally less coordinated. Therefore, since they are used in the composition of the present invention, they are preferably used at low concentrations. The following are representative examples of interface active surfaces useful in this compound. The water-soluble salts of higher fatty acids, namely "soap", is a yin type surfactant in the sister composition of this article. This includes gold-like soaps such as sodium, potassium, ammonium, and alkylammonium salts of higher carbon fatty acids containing from about 8 to about 24 carbon atoms, preferably from about 12 to about 18 carbon atoms. Soap can be made by direct saponification of lipids and oils or by neutralization of free fatty acids. Particularly useful are the sodium and potassium salts * of fatty acid mixtures derived from coconut oil and tallow, namely sodium or potassium fat and coconut soap. Useful anionic surfactants also include water-soluble salts, preferably gold-extracted organic reaction products of telluric acid, ammonium and alkyl clamp salts. In their molecular structure, the alkyl group contains about 10 to about 20 Å carbon atoms and "Acid or sulfuric acid bases (including the alkyl part of the acyl group in the term Λalkyl) a. Examples of the purchase of this group of synthetic surfactants are sodium alkyl acid and potassium, especially those High-Carbon Number Fermentation (Ce-Cie Carbon Atom) Benzoic Acid Surface Finishing Winners • Such as made of sugar lipids or -12- (please read the precautions on the back before filling out this page) Binding-Order &Line; This paper size Using Chinese National #quasi (CNS) f 4 specifications (210 x 297 mm) 81. 5. 20.000 (H)

(JK A 6 B6 V. Description of Invention (LI) Ministry of Economic Affairs + Central Bureau of Standards and Practitioners Employee Consumer Cooperative Printed Coconut Oil's Glyceryl Ester Glyceryl Ester in a straight bond or branch: those described in US patents. Special In the alkyl part of the carbon-Ci3 LAS. Other anions in this article are especially those made from tallow oil fatty acid monoglyceride 10 units oxyethylene and phenol ethylene oxide silver carp sulfate 10 units ethylene oxide and ethylene oxide ether sulfate Other useful materials in this article contain about 6-20 carbon atoms alpha-sulfonated fatty acids with 9 carbon atoms and a milling atom in the oxy-alkane 1-20 ton, and about 12-24 carbon atoms 1-3 A carbon atom and an alkoxy bond alkane sulfonic acid, but this acid is preferably obtained by neutralization of the ion-exchange; and the alkyl group contains about 9 to about 1, No. 2,220,099. The average number of straight bonds is about 11. The surfactant is derived from alkane and coconut oil compared to sodium sulfonate and sodium sulfate; wherein the alkyl group contains about 8-sodium salt or potassium salt; and the alkyl group contains about 10- Sodium salt or potassium salt. Anionic interface activator and ester contained in ester group The soluble salt of the alkyl part contains about 9 to about 1 sulfonic acid water. The soluble salt 1 to 30 moles of ethylene oxide olefin sulfonic acid water can contain about 8 esters in the "alkane part. Although this acid formula" can be The subdivided mixed step surfactant paste is its sodium and potassium benzenesulfonate. • Among them, the 15th carbon atom, for example, and the No. 2,477,383 middle alkyl benzene sulfonate, whose -13 is written as Cii Sodium glyceryl ether sulfonate, a high-carbon yeast chain; coconuts contain about 1 to about 12 carbon atoms per molecule of alkyl group. Each molecule contains about 1 to about 20 carbon atoms. Approximately 1-10 carbon atoms in the base; 2-anhydride containing approximately 2-23 carbon atoms in the base; alkyl ether sulfate containing approximately 10-alkanes in the alkyl group; soluble salts: and alkyl The base contains about — about 20 carbon atoms is typically used by discussion friends «part of it. The base has 10 — 16 carbon atoms 13- (please read the precautions on the back before filling out this page) · Line. This paper uses the standard "Home" Bi (MS) A 4 specifications (210 x 297 g; St) 81. 5. 20.000 (H) A6 ___B6 V. The straight media or points of the invention description (12) A mixture of alkylbenzene sulfonates and alkyl sulfates with 10-18® alkyl carbon atoms. These pastes are usually composed of liquid organic substances that react with sulfur trioxide to produce sulfonic acid and sulfuric acid, and then neutralize the acid, It is made with a salt that produces the acid. This salt is discussed throughout this document as a M surfactant paste. Na is preferred because of the final efficiency benefits and costs of sodium hydroxide for other neutralizers. Other agents that can be used are such as: potassium hydroxide. Water-soluble non-ionic surfactant _ in the composition of the present invention can also be used as a second surfactant. In fact, the preferred method is to use anionic / nonionic blends. Particularly preferred pastes include blends of nonionic and anionic surfactants, the ratio of which is about 0.01: 1 to about 1.1, more preferably about 0.05: 1. The nonionic type can use up to the same amount of the first surfactant. Such non-ionic substances include those produced by the condensation of alkyleneoxy groups (hydrophilic properties) and hydrophobic compounds that can be aliphatic or alkylaromatic properties. The length of the polyalkyleneoxy group with any specific hydrophobic group can be easily adjusted. K produces water-soluble compounds with a desired degree of balance between the hydrophilic and hydrophobic components. The non-ionic surfactants printed by the Beigong Consumer Cooperative of the Ministry of Economic Affairs of the People ’s Republic of China. Suitable non-ionic surfactants include polyphenol condensates of alkyl phenols. The condensation product of the branched configuration of alkylphenols has about 4 to 25 oz of gaseous ethane per alkyl phenol. The preferred non-sickle type is a water-soluble condensation product of an aliphatic leaven containing 8 to 22 carbon atoms, straight or branched configuration, and 4 to 25 mg per ear of drunken ear. Particular preference is given to alkyl groups containing about 9 to 15 carbon atoms. • Each molar enzyme has 4 to 25 molar ethylene oxide fermentation products; and malonylase and ethylene oxide—1 4 to 81. 5 . 20.000 (H) (Please read the precautions on the back before filling in this page) This paper is used in the "Home Sample Bi (CNS) A 4 specifications (210x297 g *) _B6 V. Invention description (13) Condensation of alkanes product. Semi-polar nonionic surfactants include water-soluble amine oxides containing an alkyl group of about 10-1δ carbon atoms and 2 parts selected from alkyl and hydroxyalkyl groups containing 1 to about 3 carbon atoms; The water-soluble phosphine oxide contains an alkyl moiety of about 10-18 carbon atoms and 2 moieties selected from those including alkyl and hydroxyalkyl containing about 1-3 carbon atoms; An alkyl portion and a portion of about 10 to 18 carbon atoms are selected from alkyl and hydroxyalkyl portions including about 1 to 3 carbon atoms. Amphoteric surfactants include aliphatic derivatives and aliphatic derivatives of secondary and tertiary amines, wherein the aliphatic portion may be a straight bond or a branched branch and one of the aliphatic substituents contains about 8-18 carbon atoms And at least one aliphatic substituent contains an anionic water solubilizing group. Zwitterionic surfactants include derivatives of quaternary quaternary ammonium compounds of the family and derivatives, and one of the aliphatic substituents contains about 8 to 18 carbon atoms. Printed by the Ministry of Economic Affairs of the Central Ministry of Economic Cooperation and Consumer Cooperatives. Specific preferred surfactants include linear alkylbenzene sulfonates with alkyl groups containing about 11 to 14 carbon atoms; tallow alkyl sulfates; coconut alkyl groups Glyceryl ether sulfonate; alkyl ether sulfate, in which the alkyl portion contains about 14-18 carbon atoms and wherein the average degree of hydroxyethylation is about 1 to 4: alkene or sulfonate contains about 14- Those with 16 carbon atoms; alkyl dimethylamine oxides, where the alkyl group contains about U-16 mineral atoms: alkyl dimethyl ammonium propane sulfonate and alkyl dimethyl ammonium hydroxypropane sulfonate The base contains about 14 to 18 carbon atoms; soaps containing high carbon number fatty acids of about 12-18 carbon atoms; Ce-Cie leaven and about 3 to 8 round earrings gas ethane combined products, and mixtures. — 15 — 81. 5. 20,000 (Η) (please read the notes on the back before filling in this page) This paper uses the Chinese «National« China (CNS) A 4 specifications (210X297) *) Ministry of Economic Affairs Quasi-bureau β-work dissipation co-production duo printing 〇〇〇〇 ^ 4 A 6 _B6 V. Description of the invention (14> useful cationic surfactants include RdsReRvfTX-type * where R4 is 10-20, preferably 12-18 Carbon atoms, and RB, 1 ^ and! 7 are each h-Cy alkyl * preferably methyl; X-is an anion, for example: chloride water-soluble quaternary ammonium compound. Examples of such trimethylammonium compounds Including C12-C14 alkyl trimethyl ammonium chloride and coconut alkyl trimethyl ammonium methosulfate. The particularly preferred surfactants used in this article include: linear Cu-C13 sodium alkylbenzene sulfonate; alpha-olefin sulfonic acid Ester; Triethylammonium Cu—C13 alkylbenzene sulfonate; alkyl sulfate (tallow • coconut • brown ffi * synthetic origin, for example: C45, etc.); sodium alkyl sulfate; MES; coconut alkyl glycerin Sodium ether ether sulfonate; sodium salt of animal lipase and sulfated condensation product of about 4 moles of ethylene oxide; coconut lipase and about 6 moles of epoxy Condensation products of alkanes; Condensation products of tallow fat and about 11 moles of ethylene oxide; Condensates of lipase containing about 14 to about 15 carbon atoms and about 7 moles of ethylene oxide; C12-C13 fatty alcohols Condensation products with about 3 moles of ethylene oxide; 3- (N, N-dimethyl-N-coconut alkyl ammonium) -2-hydroxypropane-1 monosulfonate; 3- (N, N— Dimethyl-N-coconut alkylammonium) -propane-1 monosulfonate; 6- (N-dodecylbenzyl-N, N-dimethylammonium) hexanoate; + dialkyldi Methylamine oxide; Coconut alkyl dimethylamine oxide; and the water-soluble sodium and potassium salts of coconut and tallow fatty acids. As used herein, the term '" surface active agent 〃 unless otherwise specifically indicated otherwise Its meaning means that there is no non-ionic surfactant. The interfacial agent activity (excluding non-ionic) on dry "detergent detergent rib lotion or powder ratio range 0.005-19: 1, preferably 0.05-10: 1 .Better 0.1: 1 ____ ~ 1 6 ~ _ This paper is in use "National Standard (CHS) Yu 4 Specification (210x297 Commonweed) 81. 5. 20.000 (H) (please first Read the precautions on the back and then fill out this page) Binding-Order V. Description of invention 〇 · 5) A 6 B6 Printed by Beigong Consumer Cooperative, Central Central Bureau of Economic Affairs

One 5: 1. Even more preferably, the ratio of the aforementioned surface-active surfactant to builders is 0.15: 1-1: 1; and 0.2: 1-0.5: 1). The platform pressure maintains the function of pumping and mixing viscous surfactants on the basis of a continuous mine. A basic extruder consists of a barrel and a smooth inner cylindrical surface. Inside this bucket is equipped with squeeze and knead. When the spin rotates, it causes the coral to move along the length of the barrel, which is the entrance of the highly active paste. The exquisite design of the extrusion base allows it to perform various functions. First of all, there are additional entrances in the barrel, which can accommodate other components, including the chemically constructed striated ribs added directly to the barrel. The sealing ring of the second vacuum pump and the mirror shaft of the rotating mirror • enables it to be evacuated, which reduces the moisture content. Third, heating or cooling tools * can be installed on the wall of the barrel for temperature control. Fourth, squeeze and squeeze the design of the spiral child to promote the mixing of the paste itself and other additives. The preferred extruder is a double screw extruder. This type of extruder has 2 spirals installed in parallel in the same barrel, which makes it possible to rotate in the same direction (co-rotation) or in the opposite direction (reverse rotation). · The co-rotating double spiral extruder is the best equipment used in the present invention. Extrusion is particularly useful in the present invention because by adding liquid nitrogen or solid-liquid carbon dioxide to the barrel, the paste can be effectively cooled (this may be considered surprising because of the stagnation of shear force • The result of mechanical energy input, which usually leads to excerpts heating the contents) • Simultaneously pumping increased viscosity (colder) paste out of the squeeze envelope and into mixed / agglomerated envelope occurrence or granulation. The Tongyi Shuangrong rotary presses used in the present invention include those made of: APV (please read the precautions on the back before filling the nest page). Installation &Order; Line-1 1 7-This paper size is not in use •• Home «Precision (CNS) A 4 specifications (210x297 mm) 81. 5. 20,000 (H) ^ j00〇S4 A 6 B6 Printed by the Central Consumer ’s Bureau of the Ministry of Economic Affairs Employee Consumer Cooperative V. Invention Instructions (L6) Baker (Article CP); Werner and Pfleiderer. (Continual column); Wenger (TF Shito column); Leistritz (ZSE series); and Buss (LR series) providers. This 掳 ® machine allows confusing by reducing the density and temperature. Moisture can be removed in a vacuum, preferably between 0 «mHg (pressure gauge) and a 55« mHg (pressure gauge) (0-7,3 thousand bar at atmospheric pressure M). The temperature can be reduced by adding solid carbon dioxide or liquid nitrogen directly during extrusion. The liquid is preferably used in an amount of up to 30% by weight of the paste. Powdered fuze Although preferred specific examples of the method of the present invention include the introduction of anionic interface active clam into the paste according to the above method *, there may be a certain amount of powdery bark flow, for example, in the form of a powdery powder. In these specific examples, the viscosity and moisture of the powder stream must be kept low * to prevent the increase of anionic surfactant, load, and therefore, agglomerates with too high surfactant concentration . The liquid agglomeration method of the preferred agglomeration method can also be used to introduce other surfactants and / or polymers. This can be implemented or pre-mixed by premixing the surfactant into a liquid stream, by introducing various streams in the agglomerator. These two examples of gambling methods can produce particles of different sexes (dispensing, coagulation, dissolution rate, etc.), especially if the mixed surfactant is allowed to form before the particles are formed. Then these differences can take advantage of the application of each preferred method. By using the techniques described so far, it has also been observed that in the final formulation, the concentration of certain chemicals that may be incorporated (for example: non-ionic • after-acid) is higher than that of any other known processing The way is higher * and for this base one 18 one (please read the precautions on the back before filling the nest page). Binding · Thread · The paper standard "Chinese sati« quasi (CHS) A 4 specifications (210x297 Mm) 81. 5. 20.000 (H) 200524 A 6 B6 V. Description of invention Ο · 7) Some of the bond properties of the central government ’s Ministry of Economic Affairs, ijA, industrial and consumer cooperation, Du Yin, and no harmful effects (agglomeration, κ 实, etc.) 〇The oil ageing Min will be good as I ». The term" fine dispersion and / or granulation "as used in this article means that it is in a subdivision mixer, unless otherwise specified. Otherwise, it refers to mixing and / or granulating the above mixture at a speed of about 5 meters / second to about 50 meters / second at the tip of the tablet. The end of the mixing and granulation process is preferably in the order of 0.1-10 points, more preferably 0.1-5. The best 0.2-4 points. Better mixing and granulation tip speeds are about 10-45 meters / second, and about 15-40 meters / second. The ratio of the bale to the powder should be selected Κ so that it remains visible to the naked eye at all stages of the method, eliminating particles. These particles can be glued at higher temperatures, but must be substantially free-flowing, so that the mixing and granulation steps can be performed at the same time, or Lu Ji can be carried out immediately, without causing blockage of the mixer / granulator. Any device, plant, or component that is suitable for surfactant processing can be used for curing the method according to the present invention. Suitable devices include, for example, falling film sulfonation reactors, digestion tanks, esterification reactors and the like. For mixing / agglomeration, any of the Thousand Mixer / Agglomerator can be used. In a preferred embodiment, the method of the present invention is continuously performed. Particularly preferred is the FukaeR FS-G series mixer manufactured by Japan Fukae Powtech Kogyo; this device is in the form of a bowl-shaped container. It can be accessed through the top entrance • close to its base, with a high quality The vertical sleeve of the mixer, and all the knives are located on the side wall. The seed mixer and cutter can be separated from each other, and work under the speed of the sub-gate change. This container can be filled with a cooling sleeve 19- (please read the note on the back side and fill in this page first). Order · Thread-This paper size 4 is used in the Zhongzhijia «Bi (CNS) A 4 specifications (210 x297 Public *) 81. 5. 20.000 (H) Printed by the Central Ministry of Economic Affairs ^ s Industrial and Consumer Cooperatives 〇〇〇〇S ^ A 6 ____B_6 V. Description of invention 〇_8) or 'If necessary, you can weigh and have a low temperature sister Pieces. In the method of the present invention, other types of mixers commonly used include DiosnaR V e: {Article Pharna Matrix * ex of TK Filder, UK). Other mixers believed to be used in the method of the present invention are the PujiR VG-Cex series from Fuji Sangyo of Japan; and the RotoR ex of Zanchetta & Co srl of Italy.

Other preferred Tongyi equipment may include EirichR, RV series manufactured by Gustau Eirich Hardheim, Germany; LodigeR, FM series manufactured by Lodige Machinenbau GmbH, Paderborn, Germany, for batch mixing; Baud Ο series for continuous mixing / agglomeration; German painting DraisR Τ160 series made by Drais Werke GmbH of Mannkein; and WinkworthR RT25 series made by Winkworth Machinery in Bershire, England.

Littleford mixer, model JIFM-130-D-12, with in-cut chips and C u ί s ί na "t F ο 〇d processor, It DCX-P 1 us model, 7. 7 5 hours (19.7 cm ) The blade is an example of 2 suitable mixers. Any other mixer has subdivision mixing / granulation ability and the residence time is in the range of 0.1-10 points. It can be used on the rotating shaft. Several "float wheels" of "float wheel" are preferred. The present invention can be divided into batches or continuous mines. Method S Application 0 Broadcasting of hemp is preferred. The temperature of bare work should also be as low as possible. This will result in a higher surfactant splash in the particles made. It is better to reduce the temperature during the agglomeration by one to 20. — This paper scale is not used in the “National Sample (CHS) Specification (210x297 *) 81. 5. 20.000 (H) (please read the precautions on the back before filling in the nest page) 装-线 · A 6 __B_6 5. Description of the invention (19) died at 100, preferably 10-901C, the best It is preferably between 20 and 80¾. The lower operating temperature useful in the present invention can be achieved by different methods known in the art, such as Cooling, the cooling water jacket of the equipment, the addition of solid carbon dioxide, etc .; the preferred method is solid carbon dioxide, the best method is liquid nitrogen cooling. In the preferred embodiment of the present invention is accompanied by a highly attractive accessory, to further Increasing the interfacial activity in the final granules is a liquid flow containing deionized surfactants and / or other surfactants. The addition leads to an increase in the viscosity and / or melting point of the paste and / or to eliminate the viscosity of the paste Other factors of the nature. In a preferred embodiment of the method of the present invention, when the paste is pumped into the agglomerator, some elements can be added in the pipeline. Examples of these elements can be various powders, It will be described in more detail in this article. Printed by the Black Baht Attachment Ministry of Economy Central Central Standards ^ 1¾ Industrial and Consumer Cooperatives (please read the precautions on the back before filling the nest) This invention is made for use in detergent High-density particles of the compound. The preferred sister compound for the final agglomerate to be incorporated into the granular detergent has a high surfactant level. It is produced by the present invention by increasing the degree of surfactant Particles / attached Agglomerates are more suitable for various formulations. These high surfactants containing granular agglomerates require less finishing technology to reach the final agglomerates. Therefore, a large amount of detergent is eliminated in the entire detergent manufacturing process (chant) It can be used in other processing steps (such as dry powder, powder removal, etc.) processing ribs (powder powder, etc.). The particles prepared according to the present invention are large, low in powder and free flowing. Preferably, it is about 0.4- The bulk density of about 1.2 g / «liter, more preferably about 0.6 _ about 0.8 g / ml. The weight of the grain of the present invention is the most average particle size of about 200 a 2 1 — the paper size is easy to use CNS) A4 specifications (210x297 mm) 81. 5. 20,000 (H) 2005: A 6 B6 V. Description of invention (20) Printed by the Ministry of Economic Affairs + Central Standards Bureau Beigong Poverty Alleviation Cooperative

-About 1000 microns. The preferred size of the particles thus formed is 200-1000 microns. The particle size range of the better granules thus formed is 200-2000 microns. The better granulation temperature range is about 10C to about 60¾, and the best is about 20 * C to about 50t :. Dryness The expected moisture content of the free-flowing particles of the present invention can be adjusted to a degree suitable for the intended application by drying in conventional powder drying equipment such as fluidized bed dryers. If you use a hot air fluidized bed dryer * you must use it with a small mind * to avoid decomposition of the heat sensitive parts of the particles. It is also advisable to have a cooling step before storing large-scale chess. This step can also be carried out in a conventional fluidized bed with cooling air. Drying / cooling of agglomerates can also be carried out in any other equipment such as rotary dryers, etc., which are used for powder drying. For detergent applications, the final moisture content of the agglomerates must be kept below the level where the agglomerates can be stored and buried in large quantities. The correct moisture content depends on the agglomeration of the agglomerate, but it is typically 1 to 8% of the free state water (that is, water does not form any crystalline form in the agglomerate), and the most typical is 2 to 4 % ° Decontamination Lattices "powders can be used in any of the coordinated decontamination rib lotions or builders or powders can be used in the method and composition of the present invention. The detergent compound in this article may contain some crystalline aluminic acid phase ion exchangers Naz 〔(Al〇2) z · (SiQa) y〕 with the following formula: XHaO (please read the notes on the back first Matters refill on this page) Binding · Order-f-line · Wooden paper size used in the home sample standard (CHS) A 4 specifications (210x297 mm) 81. 5. 20,000 (H) -22-; 〇〇δ ^ A 6 B6 V. Description of the invention (2+) where z and y are at least about 6, the molar ratio of z y is about _ about 0.4 and ζ is about 10 to about 264. The amorphous hydrated group silicate material useful herein has the following formula Mζ (ζΑ10〇 · ySi〇2) where M is sodium, potassium, ammonium or substituted ammonium, z is about 0.5-2 and 7 is 1. Magnesium ion exchange capacity of the aforementioned substances * At least about 50¾ grams of calcium carbonate hardness per gram of anhydrous silicate. The particle size of sodium hydrated zeolite A is preferably about 1-10 microns. The aluminosilicate "Ion Exchange Builder Substance is a hydrated form, if crystalline, it contains about 10 to about 28% by weight of the most water, if there is no The setting even contains potentially higher amounts of water. The highly preferred crystalline aluminosilicate ion exchange material contains about 18% to about 22% water in its crystalline matrix. This crystalline lithium aluminum silicate ion exchange substance is further characterized by a particle size diameter of 0.1 micrometer to about 10 micrometers. Amorphous materials are usually small, for example, less than about 0.01 microns. Preferably, the particle size of the ion exchanger is about 0.2 microns to about 4 microns in diameter. In this paper, the particle size diameter 〃 represents a given scorpion exchange flute according to conventional analysis techniques, such as: the measurement of Gu Weidymium using the scanning Leizi Gu Weijing, and the measured amount of scant is larger than the average particle size diameter. The crystalline aluminosilicate ion exchangers in this article are usually further characterized by their most exchangeable capacity. Calculated on the basis of anhydrous * * At least 2 () () of each aluminosilicate; Hardness, its general range is about 300 23 81. 5. 20.000 (H) (please read the notes on the back of the page before spitting this page) This paper is used in the B home sample standard (CNS) A 4 specifications ( 210x297; Jt), 〇0 dip A 6 B6 V. Description of the invention (22) Printed by Beigongxiaot Cooperative, Central Bureau of Economic Affairs, Ministry of Economic Affairs

/ G to about 352 huo equivalents / g. | S silicate ion exchange material This article further specializes in its calcium ion exchange rate, based on calcium ion hardness, at least about 2 grains of Ca — / gallon / min / g / gallon aluminosilicate (anhydrous basis), It is generally between about 2 capsules / gallon / minute / gram / gallon and about 6 capsules / gallon / minute / gram / gallon. The most common aluminosilicate for builder purposes shows a calcium ion exchange rate of at least about 4 tablets / gallon / minute / gram / gallon. Amorphous Aluminosilicate Ion Exchange Material Common Mg "exchange at least about 50¾ grams when suspended CaC03 / g (12 mg Mg-/ g) denier Mg-exchange at least about 1 capsule / gallon / minute / gram / gallon. When "In the examination of copper (Cu) radiation (1.54A units), the amorphous material did not show an observable diffraction case. The aluminosilicate ion exchange material useful in the practice of the present invention is available on the market. Ilusilicates useful in the invention can be crystalline or amorphous in structure and can be naturally-occurring aluminosilicates or synthetically derived. The method of manufacturing aluminosilicate ion exchange materials was discussed in 1976 Patent No. 3,985,669 of Krumnel et al.'S beautiful painting issued on October 12, and is hereby incorporated by reference. The preferred synthetic crystalline IS silicate ion exchange materials useful in this article are Zeolite A · Zeolite B, and Zeolite X It is available under the name. In the particularly preferred case "The Case • This crystalline aluminosilicate ion exchanger S has the following chemical formula Haia [(A10z) i2 (Si〇2) i2] · XH2O (please read the back Matters needing attention on this page) Pack · Order _ Line · One 2 4 — The BB home sample rod (CNS) A4 specification (210x297 g *) for this paper standard for ease of use 81. 5. 20,000 (H) A 6 B6 V. Description of the invention (23) where X is about 20 to about 30 , Especially about 27, and the particle size is generally less than about 5 microns. The granular detergent of the present invention may contain a neutral or swan salt whose pH in the solution is 7 or greater, and may be organic or inorganic Characteristic. The detergent builder provides the expected density and swelling of the detergent particles in this article. Some of the salts are plum. Many of them are also used as detergent ribs in the irrigation and irrigation solution. The role of noodles. Examples of neutral water-soluble compounds include Sickle King, ammonium or substituted ammonium chlorides, fluorides and sulfates. The above-mentioned salts are made of metal, especially sodium salts. Sodium sulfate is It is typically used by users in decontaminated steel particles and is a specific preferred salt. Citric acid and generally any other citric acid or citric acid, as long as it is chemically compatible with the remaining agglomerate compounds, can be combined It is included in the granular detergent of the present invention. Other useful water-soluble salts include compounds commonly known as detergent builders. The rib lotion is generally selected from a variety of different water-soluble * ammonium bromide * ammonium or substituted ammonium phosphates, polyphosphates, phosphonates, polyphosphonates, carbonates, silicates, boron 蘧 and Polyhydroxysulfonate. The above-mentioned compound is preferably Ml gold "salt, especially salt. The Central Ministry of Economic Affairs and the Beigong Xiaozhi Cooperative Society printed inorganic" special examples of acid salt rib lotion "is the degree of polymerization 6-21 tripolyphosphate, sodium pyrophosphate, polymeric metaphosphoric acid, sodium and potassium orthophosphate. Examples of polyphosphoric acid builders are sodium and potassium ethanediphosphonate, ethane 1 monohydroxy 1 1, 1 One or two sodium naphthalene and salt salts of acetic acid • Ethane 1 · 1, 2, 2-triphosphonic acid sodium and potassium arsenic * Other phosphorus rib lotion compounds are shown in US Patent 3.159,581; 3,213,030: 3,422.021: 3.422.137 ; 1 2 5 — 81. 5. 20,000 (H) (Please read the precautions on the back before filling in this page) This paper uses the National Standards (CNS) Grade 4 specifications (210x297 mm) of the paper. 〇〇 0〇 ^^ A6 ________B_6 V. Description of the invention (2, 3, 400, 176 and 3, 400, 148, and for reference herein. Examples of non-phosphorus, non-condensing builders are sodium and potassium carbonate, sodium bicarbonate and potassium • bi sodium and potassium bicarbonate, sodium and potassium tetraborate decahydrate, and the molar ratio of Si〇2 to gold oxide oxide The ratio is about 0.5 to about 4.0, preferably about 1.0 to about 2.4 silicate. The composition prepared by the method of the present invention does not require carbonates for mildew processing, and preferably does not contain more than 2% finely divided as disclosed in Clarke et al.'S Mirabi Case No. 4,196,093 published on April 1, 1980. Calcium carbonate, and preferably does not contain the latter. As mentioned above, powders such as zeolites, carbonates, silicas, silicates, citrates, citrates, phosphates, borates, etc. and processing acids such as starch can be used for detergents. The preferred embodiment of the present invention depends on the example. Printed by the Ministry of Economy, Ministry of Economics, Biyang Purin ^ s Industrial and Consumer Cooperative (please read the precautions on the back before filling the nest page). Different polymers are also useful, some of which can also be used as rib lotion, Μ Change Bodhisattva decontamination. Among such polymers that can be included, there may be mentioned carboxylated low-carbon alkyl cellulose sodium, low-carbon alkyl chain vitamins and hydroxy-low-carbon alkyl cellulose nano such as carboxymethyl cellulose Vesna, methylcellulose and hydroxypropylcellulose, polyvinyl yeast (which usually also includes some polyvinyl acetate), polyacrylamide, polyacrylate and different copolymers, such as Copolymers of acrylic acid and acrylic acid. The molecular weight of this polymer is broadly praised, but most of them are in the range of 2,000-100,000. "Polycarbonate" rib lotion describes Diehl's beauty of 3.308.067 published on March 7, 1967. Such substances include aliphatic 'post-acids such as maleic acid, itaconic acid, itaconic acid, mesaconic acid, fumaric acid, and aconitic acid. One 2 6 — This paper is used for free "B Family Samples (CNS) A 4 specifications (210x297 degrees) 81. 5. 20.000 (H) A 6 ------- ---------- B 6 V. Description of Invention ¢ 5) The Ministry of Economic Affairs, Central Hokkaido Industry Cooperative Consumer Cooperative printed the water-soluble salts of homopolymers and copolymers of citraconic acid and malonic acid. Supplement I Other ingredients commonly used in detergent compositions can be included in the composition of the present invention. These include flow aids, stains, bleach and bleach activators. Soap water boosters (Auds boosters) or foam inhibitors (suds Auppressors), anti-embroidering agents and anti-corrosion agents, soil suspending agents, soil release agents, dyes, filling surfaces, brighteners, fungicides, pH adjusters * Non-rib lotion_sexual source, water-soluble rib growth agent • enzyme • enzyme stabilizer, chelating agent and ingredients. The detergent particles of the present invention are particularly useful in a bag-shaped fully-through-the-wash product. Like sodium perborate tetrahydrate and monohydrate, may be included as part of the granular B-removing agent of the present invention. The bag-shaped full-automatic washing products disclosed in this technique are, for example, those specified in the US Patent No. 4,740,326 published in Ho'tel et al. On April 26, 1988. Another useful bag has at least one of its walls The first is composed of fine-pore polymerized kets. The terms "LAS" and "AS" as used in this article mean ", + dialkyl sodium sulfonate" and "alkyl sulfate w", respectively. "MES" means sodium methylsulfonate. Like,, C4S "-words Unless otherwise specified, otherwise the meaning is C i 4 and C t s alkyl. T AS meaning is tallow fatty acid alkyl ester. The following non-limiting examples will better understand the present invention. Percentage before doing it. Unless otherwise specified, it is based on Mengli. The following table has additional processing reveals. 1 2 7-The standard of this paper is "B Jia Yu Bi (CNS) T4 specification (210X297 public *) 81. 5_ 20,000 (H) (please read the precautions on the back before filling in this page) Packing-Threading · 5 2. Description of the invention (26) A 6B6 The Central Ministry of Economic Affairs and A Industrial Consumer Cooperative printed a rich bottle Example 1 This example describes an intermediate factory-scale high-shear mixer, Ei "ich RV02, in batch mode Method. The mixer is first filled with the powder mixture to be used, in this particular case the ratio of Zeol Ue A to finely divided carbonate or Zeolite A to finely divided citrate is 2: 1. The surfactant is 78% removed B active C4S AS hydrated paste * 13% moisture content. In this example, before starting to granulate, add 50% sodium hydroxide solution (0.6 kg) to the mixer (Ei "ich RV02) Paste (3 kg). During mixing, the paste solidifies and grinds at 2500 rpm with a mixer. After this process is stopped, add powder (1.050 kg). Use as a mixer until granulation occurs. Then stop this process The agglomerates were dried in a fluidized bed and classified through a screen. The polymer has a decontamination activity of 60% and a density of 600 g / L. They show excellent physical properties. G. Kuai 2 This example is similar to Example 1. The powdery mixture is the ratio of Zeolite A to finely divided carbonate. 2: Mixture of 1. Surfactant is a hydrated paste of C4BAS with 78% detersive activity and a moisture content of 13%. In this example, both powder (1.05 kg) and paste (3 kg) start to form Add the pellets to the mixer (E i "ich RV 0 2) ° before the mixer also add some of the most (2 kg) of dry ice, Μ lower the temperature to 151CK. The mixer is then 1600 (2500) rpra Speed start. Firstly, when the temperature is low, the mixture is in the form of fine powder. Use as a mixer until the temperature rises to the point where granulation occurs (121C). Then stop the process, the agglomerates are in the fluidized bed (please read first Note on the back and fill in this page) •.-28-This paper is used in the "National« China (CNS) A 4 specifications (210x297 ;;: :) 81. 5. 20.000 (H) Economy # Printed by Office for Consumer Cooperative of Central Bureau of Standards, Office 200, A6 _____B_6 V. Description of invention ¢ 27) Shangganjing It also meets the sieve classification. The agglomerates obtained have 60% decontamination activity, and their density is 625 g / l. They show excellent physical properties. Fenlunli 3 This example is described in the laboratory. In a high-shear mixer (food processor), a horizontal batch method. The mixer is first filled with the powder mixture to be used. In this particular case, the ratio of Zeolite A to finely divided sodium carbonate is 2: 1 . The surfactant is a hydrated paste of C 45 AS with a decontamination activity of 72% and a water content of 24%. In this example, silica powder (40 g) was added to the paste (400 g) in the mixer before starting granulation. The process was stopped and the powder (105 g) was added to the paste (335 g). It is used as a mixer until granulation occurs. The process is stopped and the agglomerates are dried on the fluidized bed and classified through a screen. The decontamination activity of the agglomerates obtained is 55-60%, and the density is 650 g / L. They show excellent physical properties. Cylinder CF4. This example describes a continuous performance, a double worm squeeze in an intermediate factory, Werner and Pfleiderer C58 has a bucket in part 6, where the paste is conditioned The method is that after the bundling is removed from the press, it is immediately granulated in a laboratory high-shear mixer. The surfactant is a 78% decontamination activity, a moisturizing alkyl benzene containing 18% mandarin. Sodium sulfonate (NaL AS) paste. The paste is introduced into the picking machine at a temperature of 70t; and the flow rate is 150 kg / hour. The paste is in a high shear mixer of «Laboratory regulations, zeolite A vs. finely divided H carbonate powder M2: 1 is the most important, and agglomerates when it is out of pressure. This paste is added to the powder bed until it is obtained The average particle size of the polymer is between 400 and 800 microns __- 29 -_ This paper is used again _ National Sample (CNS) A 4 specifications (210X297 g *) 81. 5. 20,000 (H) (please Read the precautions on the back first and then fill out this page) Binding · Order · Printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs __Β6 5. Description of the invention (28). Then the agglomerates dry on the fluidized bed And analyze its LAS content (this article describes the activity). This paste is operated between 100 and 120ΓΡΠΙ, and is simply pumped through the squeeze. When the paste exits the extruder, it remains at 70¾ * The activity of the resulting agglomerate is 32¾ ° g Example 5 The same equipment and weight ratio as described in Example 4 were used to produce agglomerates. In this example, Yu Qianyou used 2 parts before the barrel to cool the coil with 15C tap water and four after the barrel. Partially cooled with -20 υ ethylene glycol * pumped through the extruder. The outlet temperature of the paste in a steady state is 30 =, and the activity of the resulting agglomerate is 45%. Cell 4 produces the agglomerate with the same equipment and proportion as described in Example 4. In this example, maleic acid and propylene The solid powder of the copolymer is added to the paste at the entrance of the extruder. Without any cooling, the temperature of the paste exiting the extrusion is 681C, and the activity of the resulting agglomerate is 38%. When it is in the extrusion barrel With cooling, it is cooled in the same manner as described in Example 5 Example 5. The paste outlet temperature is 30 t, and the activity of the resulting agglomerate is 54%. Use the same equipment and suspension ratio as described in Example 4. Manufacture of agglomerates. However, in this ff example, NaUS was replaced by a surfactant paste containing 60% of the most sodium alkyl sulfate. C " one Cie carbon ranunculus and 25% water ° The inlet temperature was again maintained at 70t . This paste is simply pumped through the squeeze and exits the squeeze machine at a temperature of 70 °-3 0-This paper standard is used in the "« Home «Bi (CNS) A 4 specifications (210x297 mm> 81.5 . 20,000 (H) (Please read the precautions on the back before filling in this page) 装-线-A 6 B 6 2〇0 From V. Description of invention (29) The activity of the agglomerates obtained is 36%. 8 The agglomerates were manufactured using the same equipment and weight ratio as described in Example 7 and also using the alkyl sulfate paste of this example. However, in this example, a vacuum valve was used Use a vacuum pump that can deliver a vacuum of 70 mbar to apply vacuum. At the same time, the inner spiral tube in the extruder uses ethylene glycol and cools in all parts of the barrel at one 20t. 72% of the paste exits the extruder Activity, water content 22%, temperature 25¾. The agglomerates prepared with this paste have 60% alkyl sulfate activity. Cellar Example 9 The same equipment and weight ratio as described in Example 7 were used. Example of alkyl sulfate paste to produce agglomerates. In this example, the paste is made by passing -2〇υ ethylene glycol through cooling In addition, liquid nitrogen is injected into the fourth part of the barrel at a rate of 15 kg / hour for cooling. The paste is extruded at a temperature of 151, and the resulting agglomerate has 65% alkyl sulfate activity. (Please read first Note on the back and then fill out this page) Central Government Department of Economic Affairs: Printed by Consumer Cooperatives 3 1 — 81. 5. 20.000 (H) This paper scale is free of China National Standards (CNS) Grade 4 (210x297 Gongjie)

Claims (1)

6. Patent application Fanyuan B7 C7 D7 Gong Tongben 2 A method for manufacturing a concentrated granular detergent compound, which features the following steps: (i) obtained by neutralizing the anionic surfactant acid through 1 test High activity (at least 40% by weight anionic surfactant) "8 * when measured at 70 TC and a shear rate of 25 seconds" The viscosity of the aforementioned paste is at least 10 bar • sec (Pa.s), (Π) conditioning the aforementioned paste ; (Mt in the presence of effective detergent powder * in the high-shear mixer / granulation to form highly active detergent particles. 'According to the method of patent patent application No. 1, the steps (ii ) Includes pumping and / or water reduction * and / or cooling and / or adding a chemical builder to the aforementioned high-activity paste.It is characterized by the use of extrusion (please read the precautions on the back before filling this page). Printed and printed by the Central Government Bureau of Economic Affairs 3. According to the patent application drawing No. 2 4〇 · 〇_8〇υ temperature and air space (lower than atmospheric pressure) 4. According to the application of the No. 2 One or more input ports, and then mix them in the machine a One or more of the input port, and then mix in the extruder a. According to the application method of the second part of the application of the fan, the mixing part of the extrusion, under 0-7.3, enter the method of squeezing * Allow addition The method of item 0 of the powder allows the addition of powder. The barrel of any one of item 5 is borrowed as the characteristic of the paste is the entrance to the true pressure of thousands of kPa (kPa). And / or extra paste. Its special feature is a method of stabbing at the end and / or extra paste *. • What is the special tool for tool cooling, _hit · • thread · ——I —— f 4 (210X297 male (Guangzhou) 2〇〇 冰 告 本 g I .......................... VI. Patent application Fan® This cooling tool is included in the extrusion Directly add up to 30% by weight of solid carbon dioxide or liquid nitrogen to the paste. 7. According to the method of any one of items 2 to 5 of the patent application. The special purpose is that the compressor is a double worm extruder. a According to the method of item 1 of the application for patent application, its special emblem is in the form of powder. (Please read the precautions on the back before filling this page) · Line · Printed Armor of the Central Bureau of Standards of the Ministry of Economic Affairs 4 (210X297; ¥)