TW200423209A - Wafer holder for semiconductor manufacturing device and semiconductor manufacturing device in which it is installed - Google Patents

Wafer holder for semiconductor manufacturing device and semiconductor manufacturing device in which it is installed Download PDF

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Publication number
TW200423209A
TW200423209A TW93105549A TW93105549A TW200423209A TW 200423209 A TW200423209 A TW 200423209A TW 93105549 A TW93105549 A TW 93105549A TW 93105549 A TW93105549 A TW 93105549A TW 200423209 A TW200423209 A TW 200423209A
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Taiwan
Prior art keywords
wafer
diameter
wafer carrier
semiconductor manufacturing
temperature
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TW93105549A
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Chinese (zh)
Inventor
Masuhiro Natsuhara
Hirohiko Nakata
Manabu Hashikura
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Sumitomo Electric Industries
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Publication of TW200423209A publication Critical patent/TW200423209A/en

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Abstract

The present invention provides a wafer holder for semiconductor manufacturing device, and a semiconductor manufacturing device in which it is installed, which can increase the thermal uniformity on the wafer holding surface for the wafer holder containing wafer loading surface. In the wafer loader containing wafer loading surface, the diameter a of the wafer holding surface for the wafer loader is set smaller than the diameter b of the surface on the opposite side of the wafer holding surface, and the temperature distribution on the wafer surface is set within ± 0.5%. Furthermore, if it is set as b-a ≥ 50 μ m, the temperature distribution is set within ± 0.4 %. The wafer loader is preferably the ceramic heater.

Description

200423209 玖、發明說明: 【發明所屬之技術領域】 本發明係關於使用於蝕刻裝置、濺鍍裝置、電漿cvd裝 置、低壓電漿CVD裝置、金屬CVD裝置、絕緣膜CVD裝置、 低介電率膜(Low—K)CVD裝置、M〇CVD裝置、釋放氣體裝 置、離子植入裝置、塗敷顯影機等之半導體製造裝置之晶 圓載具,進而裝載其之處理反應室、半導體製造裝置者。 【先前技術】 。先前,半導體之製程巾,對於被處理物即半導體基板(晶 圓)進行成膜處理或㈣處理等各種之處理。進行針對於如 此之半導體基板之處理之半導體製造裝置中,固定半導體 基板使用加熱半導體基板用之陶瓷加熱器。 如此.先别之陶瓷加熱器例如日本專利特開平4 — π〗%號 公報所揭示。特開平4— 78138號公報所揭示之陶亮加熱器: :::陶曼製之加熱器部,其埋設有電阻發熱體,設置於 谷益内’並設置有晶圓加熱面;凸狀支持部,其設置於該 力二熱:部之晶圓加熱面以外之面,與上述容器之間形成氣 畨性密封;以及雷搞,甘 /、連接至電阻發熱體,取出至容器 外以免實質性露出至容器之内部空間。 該發明中,雖可眚?目甘+二 、見八先W之加熱器即金屬製之加熱器 中可見之污染或執效率次^ 、θ "-、政旱免化之改善,但對於半導體基板之 &度为佈未能涉及。但是, … 疋半^體基板之溫度分佈進行上 =各種之處理時,由於與良率產生密切之關係因而非常重 要。此處’例如曰本專利特開細一 U8664號公報中,揭200423209 发明 Description of the invention: [Technical field to which the invention belongs] The present invention relates to an etching device, a sputtering device, a plasma cvd device, a low-voltage plasma CVD device, a metal CVD device, an insulating film CVD device, and a low dielectric. Low-K CVD equipment, MoCVD equipment, gas release equipment, ion implantation equipment, coating and development equipment, and other semiconductor manufacturing equipment wafer carriers, and then load the processing reaction chamber, semiconductor manufacturing equipment . [Prior art]. Previously, semiconductor process towels have been subjected to various processes, such as film formation treatment and sacrifice treatment, for semiconductor substrates (crystal wafers), which are the objects to be processed. In a semiconductor manufacturing apparatus for processing a semiconductor substrate as described above, a ceramic heater for heating the semiconductor substrate is used for fixing the semiconductor substrate. In this way, other ceramic heaters are disclosed in, for example, Japanese Patent Laid-Open No. 4-π〗%. The Tao Liang heater disclosed in Japanese Unexamined Patent Publication No. 4-78138: ::: a heater section made by Taumman, which is embedded with a resistance heating element and is installed in Guyi ', and is provided with a wafer heating surface; convex support The part is arranged on the second heat of the force: a surface other than the wafer heating surface of the part forms an air-tight seal between the container and the container; Sexually exposed to the inner space of the container. In this invention, though? Mugan + Second, see the pollution or enforcement efficiency visible in the heaters of the eighth W, that is, metal heaters ^, θ "-, improvement of exemption from drought and drought, but for semiconductor substrates Could not be involved. However, when the temperature distribution of the half-body substrate is subjected to various processes, it is very important because it is closely related to the yield. Here ’, for example, in Japanese Patent Laid-Open No. U8664,

O:\91\91658.DOC 200423209 化陶究基板之溫度之陶究加熱器。該發明中, 反面之最高溫度與最低溫度之溫度差若為數%以 内,可被認為耐用。 巧歎/0以 曰=,近年之半導體基板正在推進大型化。例如,綱 二1二推進自8:向12对之轉變。伴隨該半導體基板之 产八:、/匈瓷加熱器之半導體基板之加熱面(保持面)之溫 度刀佈被認可需要處於±1.0%以内,進而,期望為城祝以 内0 再者近年來,日日圓上形成之配線幅度更加微小化,盘此 相伴進-步提高對於晶圓表面溫度之均熱性之要求:、例 如’於晶圓上以自旋式塗敷等之方法塗敷抗餘劑膜,再使 其硬化,或者顯影抗㈣膜後,進行硬化之情形時,例如 以2〇〇°C進行熱處料,作為晶圓之溫度分佈要求±〇.3%以 内、更好的是士〇·1%以内之溫度分佈。 【專利文獻1】曰本專利特開平〇4一〇7813s號公報 【專利文獻2】日本專利特開2〇〇1 — 118664號公報 【發明内容】 (發明所欲解決之問題) 本發明係鑒於以上問題開發而成者。即,本發明之目的 在於提供—種半導體製造裝置用晶圓載具及裝載其之半導 體衣迨爰置,其可提高晶圓保持面之均熱性。 (解決問題之手段)本發明之半導體製造裝置用晶圓载 其特徵在於晶圓载具之晶圓保持面之直徑a小於與晶圓 載具之晶圓保持面相反側之面之直徑b。再者,上述直徑匕O: \ 91 \ 91658.DOC 200423209 Ceramic heater for temperature of ceramic substrate. In this invention, if the temperature difference between the highest temperature and the lowest temperature on the reverse side is within a few%, it can be considered durable. Qiao sigh / 0 = =, semiconductor substrates in recent years are advancing in size. For example, Twelve Twelve and Twelve have moved forward from 8:12 to 12 pairs. Along with the production of the semiconductor substrate, the temperature of the heating surface (holding surface) of the semiconductor substrate of the Hungarian porcelain heater is recognized to be within ± 1.0%, and furthermore, it is expected to be within the city wish. In recent years, The width of the wiring formed on the Japanese Yen is further miniaturized, and this is accompanied by a step-by-step increase in the requirement for the uniformity of the wafer surface temperature: for example, 'coating anti-remainder on the wafer by spin coating, etc. In the case where the film is hardened, or after the anti-knock film is developed, the hardening is performed, for example, heat treatment at 200 ° C, and the temperature distribution of the wafer is required to be within ± 0.3%, and more preferably Temperature distribution within ± 0.1%. [Patent Document 1] Japanese Patent Laid-Open Publication No. 041047813s [Patent Literature 2] Japanese Patent Laid-Open Publication No. 2001-118664 [Summary of Invention] (Problems to be Solved by the Invention) The present invention is made in view of Developed by the above issues. That is, an object of the present invention is to provide a wafer carrier for a semiconductor manufacturing device and a semiconductor garment set thereon, which can improve the uniformity of heat on a wafer holding surface. (Means for Solving the Problem) The wafer carrier for a semiconductor manufacturing device of the present invention is characterized in that the diameter a of the wafer holding surface of the wafer carrier is smaller than the diameter b of the surface opposite to the wafer holding surface of the wafer carrier. Moreover, the above diameter dagger

O:\91\91658.DOC 200423209 較佳為比上述直徑a大50 μηι以上。上述晶圓載具較佳為於 其内部或表面形成有電阻發熱體之陶瓷加熱器。 裝载上述之晶圓載具之半導體製造裝置,被處理物即晶 圓之溫度與先前之溫度相比變得均一化,因此可提高原材 料利用率製造半導體。 根據本發明,藉由晶圓保持面之直徑a設定為小於與晶圓 呆持面相反側之面之直徑b ’可提供均熱性優良之晶圓載具 :及半導體製造裝置。再者,藉由設定5〇 _,可進 步提馬均熱性。震載如此之晶圓載具之半導體製造裝置 /、先刖之衮置相tb ’晶圓載具之溫度分佈亦變得更均一 =α此可κ現半導體之特性或良率、可靠性或 從阿〇 【實施·方式】 务明者為將晶圓保持面之溫度分佈設定為边5%以内, ^1_所示,發現晶圓载具1之晶圓保持面之直徑a若設定為 小於其相反側之面之直徑b即可。 …、 晶圓載具藉由於其内部或晶圓保持面以外之表 电阻發熱體(未圖示) 之 是,4或卩 )…、日日®,對晶圓實施特定之處理。但 疋右為上述直徑a亦大於t计、古々u 逸量自晶圓保持面之外Γ ,發現熱之散 佈易變得不均—化。若曰门m ’晶圓保持面之溫度分 已裝載之晶圓之溫产二圓保持面之溫度部分性降低時, 成膜處理時形成之:二二:降低’因此例如對晶圓實施 、之尽度或性質#得;ί;始— 如蝕刻處理之情形瞎 、、-一化。又,例 7寺,蝕刻速度變得不均一化。O: \ 91 \ 91658.DOC 200423209 is preferably larger than the diameter a by 50 μηι or more. The wafer carrier is preferably a ceramic heater having a resistance heating element formed inside or on its surface. In the semiconductor manufacturing apparatus equipped with the above-mentioned wafer carrier, the temperature of the wafer, which is the object to be processed, becomes uniform compared to the previous temperature, so that the semiconductor can be manufactured by increasing the utilization rate of raw materials. According to the present invention, by setting the diameter a of the wafer holding surface to be smaller than the diameter b 'of the surface on the opposite side from the wafer holding surface, a wafer carrier and a semiconductor manufacturing apparatus having excellent heat uniformity can be provided. In addition, by setting 50 °, it is possible to further improve the horse uniformity. The semiconductor manufacturing device of the wafer carrier which is loaded with such a shock / the first phase of the wafer carrier tb 'The temperature distribution of the wafer carrier has also become more uniform = α This can show the characteristics or yield, reliability or reliability of the semiconductor. 〇 [Implementation] The temperature distribution of the wafer holding surface should be set to within 5% of the edge. As indicated by ^ 1_, if the diameter a of the wafer holding surface of the wafer carrier 1 is set to be smaller than The diameter b on the opposite side is sufficient. …, The wafer carrier uses a resistance heating element (not shown) inside the wafer or the wafer holding surface (4 or 卩), ... However, the right is that the diameter a is also greater than t, and the 々u escape from the wafer holding surface is Γ. It is found that the heat distribution is easy to become uneven. If the gate m 'temperature of the wafer holding surface is partially lower than the temperature of the wafer on which the wafer is mounted, the temperature of the two-circle holding surface is partially reduced, which is formed during the film formation process:之 尽 度 或 力量 # 得; ί; Beginning-as in the case of etching treatment, blind,-one. Moreover, in Example 7, the etching rate became non-uniform.

O:\91\91658.DOC 200423209 :二圓表面之溫度分佈雖越少越好,但是, 内皿^佈要求為w均熱性,進而要求為城戰 述亩斤 為獲付如此之均熱性,發現若為上 这直徑a小於上述直徑b之圖i或圖2即可。 藉由陶^加熱器發熱之熱不僅加熱晶圓保持面,亦向晶 0保持面以外之面散逸。此時, &一 圓保持面之直徑a如圖3 八斤::亦大於其相反側之面之直徑b時,晶圓保持面之溫度 =冒大’於圖1(a<b)或圖2(a叫之情形時,發現晶圓保 、之/皿度分佈改善,晶圓保持面之均熱性提高,其結果 已裝載之晶圓奉面之均熱性提高。 广晶圓載具中,具有來自其側面之散熱增大,晶圓外周 敎溫度降低之傾向,藉由晶圓保持面之直徑相對較小於 其相反.側之面之直徑,可縮小散熱面積,因此可進一步均 一化晶圓保持面之溫度分佈,可均_化晶圓表面之溫度分 佈。7 ’於晶圓保持面之外周部中,位於自電阻發熱體之 離最遇之位置’ j_散熱面積增大,因此處於溫度易於降 低之傾向。因此’藉由縮短自外周部之發熱體之距離,且 減少散熱面積,可改善均熱性。 若欲將晶圓表面之溫度分佈設定為±0.5%以内之均熱 1生’+則設定a$b即可。再者,若直徑b比直徑&大5〇 _以上, P右叹疋b-ag 50 μηι ’則晶圓表面之溫度分佈可達到士0.4 %以下之均熱性因而令人滿意。 為形成直徑b與直徑a之差,除了圖丨所示之方法之外’如 圖4所不’藉由於晶圓載具中設置階差,可提高均熱性。又O: \ 91 \ 91658.DOC 200423209: Although the smaller the temperature distribution of the two-round surface is, the better, but the inner plate ^ cloth needs to be w uniformity, and then it is required to pay for this uniformity. It is found that if the above diameter a is smaller than the above-mentioned diameter i or FIG. 2, it suffices. The heat generated by the ceramic heater not only heats the wafer holding surface, but also dissipates to surfaces other than the crystal 0 holding surface. At this time, the diameter a of the holding surface of a circle is as shown in FIG. 3. When the diameter b of the holding surface is also larger than the diameter b of the surface on the opposite side, the temperature of the holding surface of the wafer = swells as shown in FIG. 1 (a < b) or FIG. 2 (In the case of "a", it is found that the wafer security / distribution distribution is improved, and the uniformity of the wafer holding surface is improved. As a result, the uniformity of the loaded wafer is improved. As a result, the wide wafer carrier has The heat dissipation from the side surface increases, and the temperature of the outer periphery of the wafer tends to decrease. The diameter of the wafer holding surface is relatively smaller than the opposite. The diameter of the side surface can reduce the heat dissipation area, so the wafer can be further uniformized. The temperature distribution on the holding surface can equalize the temperature distribution on the wafer surface. 7 'In the outer periphery of the wafer holding surface, it is located at the position where the self-resistance heating element is most far away' j_ The heat dissipation area increases, so The temperature tends to be lowered. Therefore, by shortening the distance from the outer heating element and reducing the heat dissipation area, the uniformity can be improved. If the temperature distribution on the surface of the wafer is to be set within ± 0.5%, the uniform heat can be generated for 1 life. '+ Then set a $ b. Also, if the diameter b is more straight If the diameter & is larger than 50 ° and P is sighed b-ag 50 μη ′, the temperature distribution on the surface of the wafer can reach a uniformity of less than ± 0.4%, so it is satisfactory. In order to form the difference between the diameter b and the diameter a, except In addition to the method shown in Figure 丨 'not shown in Figure 4', by setting the step in the wafer carrier, the uniformity can be improved.

O:\91\91658.DOC 200423209 再者如圖5所示,亦可於晶圓載 斜,若吉,κ介e 日日㈣載具之側面之階差處形成傾 ’ 亦長於直徑a則闕於形狀並無特別限制。 如上述中所揭示,晶圓载具之侧面之形 B之差根據所要求之均熱性或要求成本、 ^ 形狀,適當選擇即可。作是,衣戟之裝置 穿載之日鬥夕古 ―疋日日圓保持面之直徑a之長度與 之藉此若直心 佈反而广’曰曰Η載具之外周部之溫度降低影響溫度分 布,反而均熱性降低因而無法令人滿意。 本發明之晶圓載具之材 時,由於存士… 竞。使用金屬之情形 立..、日日圓上附著微粒之問題因而無法令人滿O: \ 91 \ 91658.DOC 200423209 Furthermore, as shown in Fig. 5, it can also be tilted on the wafer. Ruoji, κ-e e-day sundial carrier's side step is inclined. It is also longer than the diameter a. There is no particular limitation on the shape. As disclosed above, the difference in the shape B of the side surface of the wafer carrier may be appropriately selected according to the required uniformity, required cost, and shape. As a matter of fact, on the day of the wearing of the halberd ’s device, the length of the diameter a of the holding surface of the Japanese yen and the length of the diameter a are widened. On the contrary, the soaking property is lowered and is not satisfactory. The material of the wafer carrier of the present invention is due to deposits ... The use of metal: The problem of particles adhering to the Japanese yen cannot be satisfied.

束…“重視溫度分佈之均-性,較佳為執傳導 率南之氮化紹或碳切 *''' # V 高強度,且高_1_ 由於氮化矽具有 為氧化鋁。 局-#重視成本,則較佳 即便该荨之陶曼中,— 導率高、耐紅 右考慮性能與成本之均衡,熱傳 於主、性亦優良之氮化鋁(A1N)較為適合。 於使用A1N之愔形由_ 以下, 法。 /中,坪細表述本發明之晶圓载具之製造方 趨之原料粉末,比表面積較佳為2 〇 面積未滿2.〇m2/ > & m /g#。比表 超出5.04日士 ^ ’氮化銘之燒結性降低。又,若 再者,原料^ 粉末之凝聚性料強因而難於使用。 旦;、π末中所含之氧氣量較佳為2 wt%以下。若氧今 置超出2 wt%睹 ../? 右乳虱 所含之銘以外之二“體之熱傳導率降低。又,原料粉末中 卜之金屬雜質量較佳為2000 ppm以下。金屬雜Beam… "The importance of uniformity of temperature distribution is preferred, and the best conductivity is the nitride or carbon cut * '# V high strength, and high _1_ because silicon nitride has alumina. Bureau-# It is better to pay attention to cost. Even in the Taoman of this net, aluminum nitride (A1N), which has high conductivity, high red resistance, and performance and cost balance, heat transfer to the main, and excellent performance, is more suitable. The shape of the shape is as follows: / 中, Ping expresses the raw material powder of the wafer carrier manufacturing method of the present invention, and the specific surface area is preferably 20 area less than 2.0 m2 / > & m / g #. More than 5.04 days than the table ^ 'Nitrided Ming's sinterability is reduced. Moreover, if the raw material ^ powder has strong cohesiveness and is difficult to use. Once, the amount of oxygen contained in π is better It is less than 2 wt%. If the oxygen content is more than 2 wt%, the heat conductivity of the body is reduced. The amount of metal impurities in the raw material powder is preferably 2000 ppm or less. Metal Miscellaneous

O:\91\91658.DOC 200423209 質量若超出該範圍時,燒結體之熱傳導率降低。尤其,作 為金屬雜質’ Si等之IV族元素、或Fe等之鐵族元素具有較 高之使燒結體之熱傳導率降低之作用,因此含有量各自= 佳為500 ppm以下。O: \ 91 \ 91658.DOC 200423209 If the mass exceeds this range, the thermal conductivity of the sintered body will decrease. In particular, as a metal impurity such as Si, a group IV element or an iron group element such as Fe has a relatively high effect of reducing the thermal conductivity of the sintered body, and therefore each content is preferably 500 ppm or less.

AiM為不易燒結性材料,因此較佳於A1N原料粉末中添加 燒結助劑。戶斤添加之燒結助劑較佳為#土類元素化合$ : 稀土類元素化合物於燒結中與氮化鋁粉末粒子之表2中存 在之銘氧化物或銘氧氮化物進行反應,亦具有促進氮化: 之細緻化,並且除去造成降低氮化㈣結體之熱傳導率之 原因的氧氣的作用,因此可提高氮化銘燒結體之熱傳導率。 稀土類元素化合物較佳為除去氧氣之作用尤為顯著之紀 化合物。添加量較佳為0.01〜5wt%。若未滿〇〇1咖時, 難以獲得細緻之燒結體’並且燒結體之熱傳導率降低。又, 若超出5 wt%時,氮化Is燒結體之日日日粒界面存在有斧’ 劑,因此於腐餘性環境中使用之情形時,餘刻存在^晶 粒界面之燒結助劑,成為產生脫粒或微粒之原因。再::曰 較好的是燒結助劑之添加量為}械%以 , 口士 右馬1 wt%以下 守,於晶粒界面之3重點處亦未存在有斧 耐腐钱性。 mi助劑,因此提高 以二=類元素化合物可使用氧化物、氮化物、氟化物、 而令人二“广。其中,氧化物因價格便宜易於獲得 :人:…,硬脂酸化合物與有機溶劑之親 , ^此以有機溶㈣合氮化㈣料粉末與燒結 性增強因而尤其適合。 寸此合AiM is a material that is not easily sintered. Therefore, it is preferable to add a sintering aid to the A1N raw material powder. The sintering additive added by households is preferably # 土 类 合 合 $: The rare earth element compound reacts with the indium oxide or indium oxynitride present in Table 2 of the aluminum nitride powder particles during sintering, and also has the promotion Nitriding: Refinement and removal of oxygen, which reduces the thermal conductivity of the hafnium nitride structure, can improve the thermal conductivity of the nitrided sintered body. The rare earth element compound is preferably a compound having a particularly significant effect of removing oxygen. The added amount is preferably 0.01 to 5 wt%. If it is less than 0.001, it is difficult to obtain a fine sintered body 'and the thermal conductivity of the sintered body is reduced. In addition, if it exceeds 5 wt%, there is an axe agent at the daily grain interface of the nitrided sintered body. Therefore, when used in a corrosive environment, a sintering aid at the grain interface exists at a moment. It is the cause of threshing or fine particles. Re :: It is better that the additive amount of sintering aid is ≧ machine% and less than 1% by weight, and there is no axe corrosion resistance at the 3 points of the grain interface. Mi additives, so to improve the use of two types of element compounds can be oxides, nitrides, fluorides, which makes the two "wide. Among them, oxides are easy to obtain because of low prices: people: ..., stearic acid compounds and organic The affinity of the solvent, it is especially suitable for the organic solvent-coated nitride powder and enhanced sinterability.

O:\91\91658.DOC 200423209 特料粉末或燒結助劑粉末中,添加 錢進行混合。混合方法可為藉由球磨機混合或 -合等。藉由如此之混合,可獲得原料漿料。 藉由將所彳^料進行成形錢結,可獲 體。此方法中,可使用〕 “ 之2種方法。 二=後金屬化法進行說明。將上述裝料藉由噴 —、,去作成顆粒。將該顆粒插入特定之金屬模 -’貫施壓製成形。此時,壓機壓力較佳為98奶以上。、 未滿9.8略之壓力時,多數無法充分獲得成形體之強产, 而於操作等中易於破損。 強度 成形.體之密度雖依黏合劑之含有量或燒結助劑之添加量 而不同’但是較佳為h5 g/cm3以上。若未滿1.5 g/cm3時’ 原料叔末粒子間之距離相對增大,因此難以進行燒結。又, 成㈣进度較佳為2·5 g/cm3以下。若超出2.5 gW時,於 下-步驟之脫脂處理中難以充分除去成形體内之黏合劑。 因此’如上述所示’難以獲得細緻之燒結體。 其-入,將上述成形體於非氧化性環境中加熱,進行脫脂 王审。友妨: ^ 、二虱荨之氧化性環境中進行脫脂處理時,A1N 1末之表面被氧化’目此燒結體之熱傳導率p条低。作為非 乳化性%境氣體,m為氮或氬。脫脂處理之加 佳為5001以卜1ΛΛ。 … 、 上、100〇C以下。50(TC未滿之溫度中,無法 充刀除去黏合劑,因此脫脂處理後之疊層體中碳殘存過O: \ 91 \ 91658.DOC 200423209 Special material powder or sintering aid powder, add money to mix. The mixing method may be mixing by a ball mill or -combining. By such mixing, a raw material slurry can be obtained. The obtained material can be obtained by shaping the material. In this method, you can use [] two methods. Two = post metallization method to explain. The above charge is sprayed to form granules. The granules are inserted into a specific metal mold-'continuous pressing. Forming. At this time, the pressure of the press is preferably 98 milk or more. When the pressure is less than 9.8, most of the strong output of the formed body cannot be obtained, and it is easy to break in operation and so on. Strength forming. The density of the body depends on The content of the binder or the addition amount of the sintering aid varies, but it is preferably h5 g / cm3 or more. If it is less than 1.5 g / cm3, the distance between the raw material tertiary particles is relatively increased, and it is difficult to perform sintering. In addition, it is preferable that the progress of the lamination is 2.5 g / cm3 or less. If it exceeds 2.5 gW, it is difficult to sufficiently remove the adhesive in the molded body in the next step of the degreasing treatment. Therefore, it is difficult to obtain fineness as shown above. The sintered body is obtained by heating the above-mentioned formed body in a non-oxidizing environment to perform a degreasing test. You may: ^ When the degreasing treatment is performed in the oxidizing environment of Dixie net, the surface of A1N 1 is oxidized. 'The thermal conductivity of the sintered body is low. As a non-emulsifying% ambient gas, m is nitrogen or argon. The degreasing treatment is preferably 5001 to 1 ΛΛ.…, Up to 100 ° C. At temperatures below 50 ° C, the adhesive cannot be removed with a knife. Therefore, carbon remains in the laminate after degreasing.

O:\91\91658.DOC -12- 200423209 剩,因而妨礙此後之燒結步料之燒結。又,於超出麵t Z度中1殘务之碳之量過量減少,因此除去細粉末表面 俾、减覆盍膜之氧氣的能力降低,並使燒結體之熱 傳導率降低。 以 細 又,脫脂處理後之成形體中殘存之碳量, 下。若殘存超出hOwt%之碳日寺,妨礙燒結 緻之燒結體。 車交佳為1 ·〇 wt% 因而無法獲得 ”次,進行燒結。於氮或氬等之非氧化性環境中,以⑽ 〜2嗔之溫度進行燒結。此時,於使用之氮 體中所含有之水分,較佳為露點賓€以下。含有其以上= 水分=情料’燒結時A1N與環境氣體中之水分進行反應並 形成氧氮化物,因此出現熱傳導率降低之可能性。又,環 境氣體.t之氧氣量較佳^細德以下。若氧氣量多時, A1N之表面氧化,出現熱傳導率降低之可能性。 再者’燒結時使用之夾具適合為氮化领(bn)成形體。該 BN成形體對於上述燒結溫度具有充分之耐熱性,並且於其 表面存在有固體潤滑性,因此燒結時可減小疊層體收縮時 之夾具與豐層體之間的摩擦,可獲得畸變較少之燒結體。 所得之燒結體根據需要實施加工。網版印刷下—步驟之 導電糊膠時’吾人期望燒結體之表面粗度以Ra單位為5 _ 以下。若超出5 μηι時,藉由網版印刷進行I電路形成時,易於 產生圖案滲出或針孔等之缺陷。表面粗度若以Ra單位為1 pm 以下則更加適合。 Μ 研磨加工上述表面粗度時,於燒結體之兩面進行網版印O: \ 91 \ 91658.DOC -12- 200423209 left, thus hindering the sintering of subsequent sintering steps. In addition, the amount of carbon of 1 residue in the excess surface t Z degree is excessively reduced, so that the ability to remove the oxygen on the surface of the fine powder and reduce the oxygen on the film is reduced, and the thermal conductivity of the sintered body is reduced. The amount of carbon remaining in the formed body after the degreasing treatment is reduced, as follows. If carbon monoxide remains exceeding hOwt%, sintered body caused by sintering will be hindered. Che Jiao Jia is 1.0% by weight, so it cannot be obtained "times, and sintering is performed. In a non-oxidizing environment such as nitrogen or argon, sintering is performed at a temperature of ⑽ ~ 2 嗔. At this time, the The moisture content is preferably less than the dew point. When it is more than = moisture content = love material, A1N reacts with moisture in the ambient gas to form oxynitride during sintering, so there is a possibility that the thermal conductivity will decrease. Also, the environment The amount of oxygen in gas .t is preferably less than ^. If the amount of oxygen is large, the surface of A1N will oxidize, which may reduce the thermal conductivity. Furthermore, the fixture used during sintering is suitable for nitrided collar (bn) formed body The BN formed body has sufficient heat resistance to the above sintering temperature, and there is solid lubricity on the surface, so the friction between the clamp and the layered body when the laminate shrinks during sintering can be reduced, and distortion can be obtained. Fewer sintered bodies. The obtained sintered bodies are processed as required. When screen printing is carried out-the conductive paste of the step "I expect the surface roughness of the sintered body to be 5 _ or less in Ra units. If it exceeds 5 μm, When the I circuit is formed by screen printing, defects such as pattern bleedout and pinholes are liable to occur. The surface roughness is more suitable if the unit of Ra is 1 pm or less. Μ Grinding the surface roughness on both sides of the sintered body Screen printing

O:\91\91658.DOC -13- 200423209 刷=情形係理所當然,但即便僅於單面實施網版印刷之情 开::,進行網版印刷之面以及相反側之面亦實施研磨加工 車“:僅研磨加工進行網版印刷之面之情形時,於網版印 刷日守,以未進行研磨加工之面支援燒結體。此時,於未進 ::研磨加工之面存在有突起或異物,因此燒結體之固定變 仟不%疋,因為以網版印刷無法完善描繪電路圖案。 ―又’此時,兩加工面之平行度較佳為〇 5賴以下。若平 卜超出〇·5 mm時,於網版印刷時導電糊膠之厚度之不均 =性增大。若平行度為Q1麵以下則尤其適合。再者,進 、,版P刷之面之平面度較佳為〇 5 _以下。超丨0.5 _ 之平面度之情形時,亦會出現導電糊膠之厚度之不均一性 立曰大。右平面度亦為〇1 mm以下則尤其適合。 、一:磨加工之燒結體中藉由網版印刷塗敷導電糊膠, 氣電路之形成。導電糊勝藉由混合金屬粉末、根據 :要氧化物粉末、黏合劑與溶劑而可獲得。金屬粉末出於 ’、陶瓷之熱膨脹係數之匹配,較佳為鎢、鉬或鈕。 又’為提高與讀之緊密強度,亦可添加氧化物粉末。氧 :㈣末較佳為⑽元素細a族元素之氧化物或AM〗、 立 1〇7箄^其’氧化紀對於Α1Ν之漂濕性非常良好因而令人滿 思。之氧化物之添加量 之情形時,會使所开,成”广"°wt%。未滿°.lwt% # /成之电軋電路即金屬層與A1N之緊密強 又-又右超出30竭時,電氣電路即金 阻值增高。 曰 电乳私 “糊膠之厚度係乾燥後之厚度,較佳為5 _以上、_O: \ 91 \ 91658.DOC -13- 200423209 Brush = situation is a matter of course, but even if the screen printing is performed on one side only: The grinding screen is also implemented on the screen printing side and the opposite side. ": In the case where only the screen-printed surface is ground, the sintered body is supported by the surface without screen grinding on the screen printing day guard. At this time, there are protrusions or foreign matter on the surface that is not advanced: Therefore, the fixation of the sintered body does not change, because the circuit pattern cannot be perfectly described by screen printing. ―At this time, the parallelism of the two processed surfaces is preferably less than or equal to 0.55. If the flatness exceeds 0.5 When the thickness is mm, the unevenness of the thickness of the conductive paste during screen printing is increased. It is particularly suitable if the parallelism is less than the Q1 surface. Furthermore, the flatness of the surface of the P brush is preferably 0. 5 _ below. In the case of flatness exceeding 0.5 _, the unevenness of the thickness of the conductive paste will also appear to be large. The right flatness is also particularly suitable for 0 1 mm or less. Conductive paste is applied to the sintered body by screen printing to form a gas circuit. The conductive paste can be obtained by mixing metal powder, according to: oxide powder, binder and solvent. The metal powder is preferably tungsten, molybdenum or button because of the matching of the thermal expansion coefficient of ceramics. It is also possible to add oxide powder with the tightness of the reading. Oxygen: Plutonium is preferably the oxide or AM of the element 细 of the fine group A element, and its oxidizing age is very wettable to Α1Ν. Good and convincing. When the amount of oxide is added, it will make the opening "wide" ° wt%. Less than ° .lwt% # / Cheng of the electric rolling circuit, that is, the metal layer and A1N are tight and strong-when the right exceeds 30 hours, the electrical circuit, the metal resistance value increases. "The thickness of the paste is the thickness after drying, preferably 5 _ or more, _

O:\91\91658.DOC -14- 200423209 μιη以下。厚度未滿5 μηΐ2情形時,電氣電阻值過量增高, 並且緊密強度亦降低。又,超出〗〇〇 μπι之情形時,緊密強 度亦降低。 又,形成之電路圖案為加熱器電路(發熱體電路)之情形 時,圖案之間隔較佳設定為〇1顏以上。未滿〇 ι _之間 ^中’於電流流進發熱體時,會因施加電麼以及溫度而產 生浅漏電流並發生短路。尤其,於5〇(rc以上之溫度使用之 情形時,圖案間隔較佳設定為lmm以上,若3匪以上則更 好0 其次,將導電糊膠進行脫脂後,進行燒製。脫脂於氮或 氬等之非氧化性%境中進行。脫脂溫度較佳為·。匚以上。 未滿500。。時,導電糊膠中之黏合劑之去除為不充分因而於 、€内殘邊石反’於燒製時形成金屬之碳化物,因此金屬 層之電氣電阻值增高。 燒製於氣或氬等之非氧化性環境巾、15〇m之溫度 、_為、13於1500 c未滿之溫度中,未進行導電糊膠 ::屬粉末之粒成長,因此燒製後之金屬層之電氣電阻 !過:増高。又’燒製溫度以未超出陶竟之燒結溫度為好。 出陶莞之燒結溢度之溫度燒製導電糊膠時,陶竟中 屬2之燒結助料㈣揮發,進蚊料電糊膠中之金 屬::之粒成長,陶变與金屬層之緊密強度降低。 升;成:=:保形成之金屬層之絕緣性,於金屬層之上可 化成纟巴緣性塗敷屏。 應性小,並與細之性塗敷層之材質與電氣電路之反 /、 …、如脹係數差若為5·〇χ1〇-6/Κ以下則並O: \ 91 \ 91658.DOC -14- 200423209 μιη. When the thickness is less than 5 μηΐ2, the electrical resistance value is excessively increased, and the compact strength is also reduced. In addition, when it exceeds 〖〇〇μπι, the compaction strength also decreases. In the case where the circuit pattern to be formed is a heater circuit (heating body circuit), the interval between the patterns is preferably set to 0 or more colors. Less than 〇 ι _ between ^ ’When a current flows into the heating element, a shallow leakage current will occur due to the application of electricity and temperature, and a short circuit will occur. In particular, when used at a temperature of 50 ° C or more, the pattern interval is preferably set to 1 mm or more, and more preferably 3 mm or more. 0 Second, the conductive paste is degreased and then fired. The fat is degreased in nitrogen or Argon and other non-oxidizing conditions are carried out. Degreasing temperature is preferably above 匚. When it is less than 500…, the removal of the adhesive in the conductive paste is insufficient, so the residual stone in the inner side will be reversed. Carbides of metal are formed during firing, so the electrical resistance value of the metal layer is increased. Non-oxidizing environmental towels fired in gas or argon, a temperature of 150 m, a temperature of 13 to 1500 c In the process, the conductive paste is not grown: it is a grain growth of the powder, so the electrical resistance of the metal layer after firing! Over: high. Also, the firing temperature is preferably not exceeding the sintering temperature of ceramics. When the conductive paste is fired at the temperature of the overflow degree, the sintering aid 陶 of Tao Jingzhong 2 volatilizes, and the metal in the mosquito paste paste increases: the grain grows, and the tightness of the ceramic change and the metal layer decreases. Liter; Formation: =: Guarantees the insulation of the formed metal layer, and can be formed on the metal layer Bar coating edge of the screen should be small, and the fine material and anti layers of coating electrical circuits /, ..., if the difference in the coefficient of expansion as 5.3 〇χ1〇-6 / Κ is less and

O:\91\91658.DOC -15 - 200423209 無特別限制。例如,可使用結晶化玻璃或A1N等。將該等之 =料作成例如糊膠狀,進行特定之厚度之網版印刷,根據 而要進行脫脂後,可藉由以特定之溫度燒製而形成。 此時,添加之燒結助劑量較佳為001wt%以上。未滿〇〇iwt% 時’絕緣性塗敷層無法細緻化,難以確保金屬層之絕緣性。 又,燒結助量較佳為不超出20 wt%。若超出2〇糾%時,過 7之燒結助劑浸透於金屬層中’因此金屬層之電氣電阻值 毛生欠化:對於塗敷之厚度並無特別限制,但較佳為5 μηι 以上。其係因未滿5 μηι時難以確保絕緣性。 =,作為導電糊膠,亦可使用銀或把、白金等之混合物 1。金。該等之金屬相對於銀之含有量藉由添加鈀或白金 體之體積電阻率,故而若根據電路圖案調整其添加 =Ρ可.亥等之添加物具有防止電路圖案間之遷移之效 果’因此對於moo重量份較佳為添純丨重量份以上。 全屬粉末中’為確保與A1N之緊密性,較佳為添加 硼减物。例如可添加氧㈣或氧切、氧化銅、氧化 ==、氧化錯、稀土類氧化物、過渡金屬元素氧化:、 以及驗性土類金屬氧化 以上50 wt%以下。若旦。於添加量,較佳為0·1游。 降低因而無法令人滿二里'於其時’與氮化銘之緊密性 八,, 又’右含有量多於其時,妨礙銀 專之金屬成分之燒結因而無法令人滿意。 將’’、、機物之粉末與該等金屬粉末進行混合,進而六 :_或黏合劑,作成糊膠狀並可藉由上:同 電路形成。此情形時,對於已形成之電路圖案,於O: \ 91 \ 91658.DOC -15-200423209 No particular limitation. For example, crystallized glass or A1N can be used. These materials are made into a paste form, for example, and screen-printed to a specific thickness. After degreasing according to the conditions, they can be formed by firing at a specific temperature. At this time, the amount of the sintering assistant added is preferably 001 wt% or more. When the content is less than 〇iwt%, the insulating coating layer cannot be refined and it is difficult to ensure the insulation of the metal layer. The sintering assist amount is preferably not more than 20 wt%. If it exceeds 20%, the sintering aid over 7 is saturated in the metal layer, so the electrical resistance value of the metal layer is reduced: There is no particular limitation on the thickness of the coating, but it is preferably 5 μm or more. This is because it is difficult to ensure insulation properties when the thickness is less than 5 μm. =, As conductive paste, you can also use a mixture of silver, platinum, platinum, etc. 1. gold. The content of these metals relative to silver is added by the volume resistivity of palladium or platinum, so if the addition is adjusted according to the circuit pattern = P can be added. Additions such as Hai have the effect of preventing migration between circuit patterns'. For moo parts by weight, it is preferable to add pure 丨 parts by weight or more. In all powders, to ensure tightness with A1N, it is preferable to add boron subtractives. For example, you can add oxygen or oxygen cutting, copper oxide, oxidation ==, oxidation oxidation, rare earth oxides, transition metal element oxidation :, and oxidative earth metal oxidation above 50 wt%. Jordan. As for the addition amount, it is preferably 0.1 tour. The lowering cannot make people feel the tightness between 'at that time' and the nitride nitride, and the 'right' content is more than that, which hinders the sintering of the metallic component of silver, which is unsatisfactory. The powder of '', organic matter is mixed with these metal powders, and then six: or adhesives are made into a paste and can be formed by the same circuit as above. In this case, for the formed circuit pattern, in

O:\91\91658.DOC -16 - 200423209 氮等之惰性氣體環境中或空氣中以7〇〇〇c至1〇〇〇它之溫产 範圍進行燒製^ '孤又 再者此情形時,為確保電路間之絕緣,可藉由塗敷結晶 化玻璃或上釉玻璃、有機樹脂等’並燒製或硬化而形:: 緣層。至於玻璃之種類可使用卿酸玻璃、氧化錯、氧化 鋅、氧化銘以及氧化石夕等。於該等粉末中添加有機溶劑或 黏合劑,作成糊膠狀,藉由網版印刷進行塗敷。對於塗敷 之厚度並無特別限制,但較佳為5 μπ1以上。未滿5 _時, =為難以確保絕緣性。又至於燒製溫度,吾人期望與上述 路=成%之舰度相比為低溫。若以與上述電路燒製時相 匕為冋之/皿度燒製時’電路圖案之電阻值會增大 法令人滿意。 …、 其次.,根據需要可進而疊層陶瓷基板。疊層介由接合劑 進行則可。接合劑於氧化㈣末或氮Μ粉末中添加⑽ 疋素化合物或ma族元素化合物以及黏合劑或溶劑,將糊膠 :者以網版印刷等之方法塗敷於接合面。對於塗敷之接合 刮之厚度並無特別限制,但較佳為5 μιη以上。於5 _未滿 之厚度時,於接合層上f於產生針孔或接合 缺陷。 f心按口 將塗敷有接合劑之陶莞基板於非氧化性環境中,以50(rc :上之溫度進行脫脂。此後,將疊層之陶:是基板相互重疊, =特定之負冑,藉由於非氧化性環境中進行加熱,將陶 免土板相互接合。負載較佳為5 kpa以上。於5 kPa未滿之負 载時’無法獲得充分之接合強度或易於產生上述接合缺陷、。O: \ 91 \ 91658.DOC -16-200423209 In an inert gas environment such as nitrogen or in the air, it is fired at a temperature range of 7000c to 10,000. In order to ensure the insulation between circuits, it can be shaped by firing or hardening by coating crystallized glass or glazed glass, organic resin, etc. :: edge layer. As for the type of glass, acid glass, oxidized glass, zinc oxide, oxidized oxide, and oxidized stone can be used. An organic solvent or a binder is added to these powders to form a paste, and the coating is performed by screen printing. There is no particular limitation on the thickness of the coating, but it is preferably 5 μπ1 or more. When it is less than 5 mm, it is difficult to ensure insulation. As for the firing temperature, we expect the temperature to be lower than that of the above-mentioned road = %%. The method of increasing the resistance value of the circuit pattern at the time of firing with the above-mentioned circuit firing phase / during firing is satisfactory. …, Secondly, a ceramic substrate may be further laminated as necessary. The lamination may be performed via a bonding agent. The bonding agent adds a halogen compound or a ma group element compound and a binder or a solvent to the hafnium oxide or nitrogen M powder, and applies paste to the bonding surface by screen printing or the like. There is no particular limitation on the thickness of the applied bonding blade, but it is preferably 5 μm or more. When the thickness is less than 5 mm, pinholes or bonding defects are generated on the bonding layer. In the center, the ceramic substrate coated with the bonding agent is degreased in a non-oxidizing environment at a temperature of 50 (rc :). After that, the laminated ceramic: the substrates are overlapped with each other, = specific negative 胄Due to heating in a non-oxidizing environment, the ceramic-free soil plates are bonded to each other. The load is preferably 5 kpa or more. When the load is less than 5 kPa, 'the sufficient bonding strength cannot be obtained or the above-mentioned bonding defects are liable to occur.'

O:\91\91658.DOC -17- 200423209 接合用之加熱溫度若為介由接合層將陶£基板相互充分 緊密接合之溫度則並無特別限制,但較佳為15崎以上。 未滿15〇代時,難以獲得充分之接合強度並易於產生接人 ^陷笼上述脫脂以及接合時之非氧化性環境較佳為使用: 或氫等。 如上,可獲得成為晶圓载具之陶瓷疊層燒結體。再者, 電氣電路未使用導電糊膠,例如若為加熱器電路,於銷線 (線圈)、靜電吸附用電極或灯電極等之情形時,亦可使用 鉑或鎢之網格(網狀體)。 “清^ T於料粉末中内藏上述翻線圈或網格,可 精:熱壓法作成。M之溫度或環境_只要按照上述A1N 之m度、環境即可’但是熱壓壓力較佳為施加0.98MPa 以上。.未滿0.98 MPa時,翻線圈或網格與A1N之間產生間 隔,因此無法顯現加熱器之性能。 其次,關於〕7 7τ —、、土 法進仃况明。將上述之原料漿 枓猎由刮板法進行薄腺忐 — ^ 、 乂。關於潯膜成形並無特別限 ’但溥膜之厚度於乾燥後較佳 度超出3 一,漿料之乾烊二7下。若缚膜之厚 龜裂之機率增高。 收里增大,因此薄膜中產生 糟由以網版印刷等之方法塗敷導電糊谬而於上述之薄膜 上形成成為特定形狀之带5帝、 包軋电路之至屬層。導電糊膠可使 Ύ〜、後金屬化法中說明者相同者。但是,根據 :法’導電糊膠中即便未添加氧化物粉末亦無妨礙。 …欠,豐層進行電路形成之薄膜以及未進行電路形成之O: \ 91 \ 91658.DOC -17- 200423209 The heating temperature for bonding is not particularly limited if the ceramic substrate is sufficiently tightly bonded to each other through the bonding layer, but preferably 15 or more. When it is less than 150 generations, it is difficult to obtain sufficient bonding strength and it is easy to produce a trapping cage. The above degreasing and non-oxidizing environment during bonding are preferably used: or hydrogen. As described above, a ceramic laminated sintered body to be a wafer carrier can be obtained. In addition, the electrical circuit does not use conductive paste. For example, if it is a heater circuit, in the case of a pin (coil), an electrode for electrostatic adsorption, or a lamp electrode, a grid of platinum or tungsten (mesh) ). "Qing ^ T contains the above-mentioned turning coils or grids in the material powder, which can be prepared by hot pressing. The temperature or environment of M _ as long as the m1 and environment of the above A1N, but the hot pressing pressure is preferably Applying 0.98MPa or more. When the pressure is less than 0.98 MPa, there is a gap between the turning coil or grid and A1N, so the performance of the heater cannot be displayed. Second, about 7 7τ —, the state of the civil law is clear. The raw material pulp hunting is carried out by the scraper method for thin gland 忐 —, 乂. There is no particular limitation on the formation of the 浔 film, but the thickness of the 溥 film after drying is better than 31, and the dryness of the slurry is 27. If the thickness of the film is increased, the probability of cracking is increased. As the retraction is increased, a thin film is produced by applying a conductive paste by screen printing or the like to form a specific shape on the film. The outer layer of the rolled circuit. The conductive paste can be the same as described in the post-metallization method. However, according to the method, the conductive paste does not hinder even if no oxide powder is added. Thin film for circuit formation and non-circuit formation

O:\91\91658.DOC -18 - 200423209 薄膜。疊層之方法將各薄膜放置於特定之位置並相互重 疊。此時,根據需要於各薄膜間事先塗敷溶劑。處於相互 重@之狀態中,根據需要進行加熱。進行加熱時,加敎溫 度較佳為以下。若以超出其之溫度進行加熱時,‘已'疊 層之薄膜會嚴重變形。而且,對於相互重疊之薄膜施加壓力 成為一體化。施加之壓力較佳為丨〜丨㈧“以之範圍。於iMpa 未滿之壓力時,薄膜無法充分一體化,於此後之步驟中會 造成剝離。X,若施加超出100MPa之壓力時,薄膜之變形 量會過量增大。 將該疊層體與上述之熱後金屬化法同樣進行脫脂處理以 及燒結。脫脂處理或燒結之溫度、碳量等與熱後金屬化法 相同。將上述之導電糊膠印刷至薄膜時,於複數個薄膜上 ”印.刷加熱器電路或靜電吸附用電極等,藉由將該等進 订:層/亦可易於製成含有複數個電氣電路之通電發熱加 ,、、、益如此,可獲得成為加熱器之陶竟疊層燒結體。 再者’發熱體電路等之電氣電路形成於陶瓷疊層體之最 外層之情形時,為確保電氣電路之保護以及絕緣性,與上 2之後金屬化法同樣’於電氣電路之上可形成絕緣性塗敷 所:于,陶瓷疊層燒結體根據需要實施加工 :之狀態中,多數無法達到以半導體製造裝置所要= 度。加工精度,例如被處理物裝載面之平/、 …進,好的是。.二==5Γ 時,被處理物與陶“熱器之間易於產生間隙=:O: \ 91 \ 91658.DOC -18-200423209 film. The lamination method places the films at specific positions and overlaps each other. In this case, a solvent is applied in advance between the respective films as necessary. In the state of mutual weight @, heat as needed. When heating, the heating temperature is preferably as follows. When heated above this temperature, the 'laminated' film can be severely deformed. In addition, pressure is applied to the films that overlap each other to be integrated. The applied pressure is preferably within the range of 丨 ~ 丨 ㈧. When the pressure of iMpa is not full, the film cannot be fully integrated, and it will cause peeling in the subsequent steps. X, if a pressure exceeding 100MPa is applied, The amount of deformation increases excessively. This laminate is subjected to degreasing treatment and sintering in the same way as the above-mentioned thermal post-metallization method. The temperature and carbon content of the degreasing treatment or sintering are the same as those in the thermal-post metallization method. When the glue is printed on the film, it is printed on a plurality of films. Brush the heater circuit or the electrode for electrostatic adsorption, etc., by ordering them: layer / can also be easily made into the electric heating with a plurality of electrical circuits, Therefore, it is possible to obtain a ceramic laminated sintered body that becomes a heater. In addition, when an electrical circuit such as a heating element circuit is formed on the outermost layer of a ceramic laminate, in order to ensure the protection and insulation of the electrical circuit, the insulation can be formed on the electrical circuit in the same way as in the metallization method after 2. In the coating state: In most cases, the ceramic laminated sintered body is processed as required: In most cases, it cannot reach the degree required by a semiconductor manufacturing apparatus. Processing accuracy, such as level of loading surface of the object to be processed, etc., is good. . 二 == 5Γ, the gap between the object to be treated and the "heater" is easy to produce =:

O:\91\91658.DOC -19- 200423209 器之熱無法均一化傳導至被處理物,易於產生被處理物之 溫度不均。 又,晶圓保持面之面粗度以Ra單位較佳為5 以下。若 以Ra單位超出5 μηι時,藉由晶圓載具與晶圓之摩擦,八取 之脫粒增多。此時,已脫粒之粒子成為微粒,對於向晶圓 上之成膜或蝕刻等之處理造成惡劣影響。再者,表面粗戶 若以Ra單位為1 μιη以下則適合。 又 如上,可製造晶圓載具本體。再者,於該晶圓載具上安 裝機械軸。機械軸之材質若為與晶圓载具之陶瓷之熱膨脹 係數相差*大之熱膨脹係數者則並無㈣限制,但與晶圓 載具之熱膨脹係數之差較佳為5><1〇_6/尺以下。 曰貝 熱膨脹係數之差若超出5χ10·6/κ時,安裝時於晶圓載具以 及機械,軸之接合部附近產生龜料,於接合時即便 龜裂,但於反複使时於接合部加±熱循環,會產生 或龜裂。例如’晶圓載具為Α1Ν之情形時,機械軸之材質最 適合為Am,但可❹氮切、碳切或富以柱、 Α1Γ^Γ接合層進行接合。接合層之成分較佳為包含 Α1Ν以及Al2_及稀域氧化物。料之成分 或機械軸之材料細等之m祕良好,因1接 較高,又亦易於獲得接合面之氣密性,因而令人滿音口。又 所接合之機械軸以及晶圓載具 〜 佳為0.5 mm以下。若超出其時,之接/面之平面度較 雖择得呈右 ^ 面處易於產生間隙, “性之接合。平面度為 更加適&°再者,峨具,_响狀^O: \ 91 \ 91658.DOC -19- 200423209 The heat of the device cannot be uniformly transmitted to the object to be treated, and it is easy to cause uneven temperature of the object to be treated. The surface roughness of the wafer holding surface is preferably 5 or less in Ra units. When the Ra unit exceeds 5 μηι, the fetching of eight fetches increases due to the friction between the wafer carrier and the wafer. At this time, the particles that have been threshed become fine particles, which adversely affects processing such as film formation or etching on the wafer. The rough surface is suitable if the Ra unit is 1 μm or less. In the same manner, the wafer carrier body can be manufactured. Furthermore, a mechanical shaft is mounted on the wafer carrier. If the material of the mechanical shaft is different from the thermal expansion coefficient of the ceramic of the wafer carrier, the maximum thermal expansion coefficient is not limited, but the difference from the thermal expansion coefficient of the wafer carrier is preferably 5 > < 1〇_6 / Foot below. If the difference between the thermal expansion coefficients exceeds 5 × 10 · 6 / κ, torture occurs near the wafer carrier and the machine, and the joints of the shaft during the installation. Even if the joints are cracked during the joint, the joints are repeatedly ± Thermal cycling can cause or crack. For example, when the 'wafer carrier is A1N, the material of the mechanical shaft is most suitable for Am, but it can be bonded by nitrogen cutting, carbon cutting or enriched with pillars and A1Γ ^ Γ bonding layer. The composition of the bonding layer preferably includes A1N, Al2_, and a rare-area oxide. The composition of the material or the fineness of the material of the mechanical shaft is good. Because the connection is high, it is easy to obtain the airtightness of the joint surface, so it is full of mouth. The mechanical axis and wafer carrier to be joined are preferably 0.5 mm or less. If it exceeds this time, the flatness of the joint / surface is easier to produce a gap at the right side, although the “sexual joint. The flatness is more suitable &

O:\91\91658.DOC -20- 200423209 T下則更加適合。又,各自之接合面之面粗度以Ra單位較 =為5 μηι以下&超出其之面粗度之情形時’同樣於接合面 处易產生間隙。面粗度以Ra單位為i卿以下則更加適合。 、:、人⑨曰曰圓載具上安裝電極。安裝可以眾所周知之方 々進仃一例如,自晶圓載具之晶圓保持面以及相反側至電 氣電路實施繞線加工,對於電氣電路實施金屬化或以非全 屬化使用直接活性金屬桿料,連接銦或鶴等之電極即可。 此後根據需要於電極上實施電鍵’可提高耐氧化性。如此, 可製造半導體製造裝置用晶圓載具。 又,將本發明之晶圓載具裝入半導體裝置,可處理半導 體晶圓。本發明之晶圓載具中晶圓保持面之溫度為均一 化,、因而晶圓之溫度分佈與先前相比亦均一化,因此對於 形成之膜或熱處理等,可獲得穩定之特性。 (實施例1) 將99重量份之氮化㈣末與丨重量份之他粉末進行混人, 分別將聚乙稀丁駿作為黏合劑1〇重量份,將苯二子酸二丁酉旨作 為〜|!5重里h,進行混合,以刮板法成形直捏伽贿、厚度 1.0 mm之綠色薄膜。再者,氮化銘粉末使用平均粒徑u卿、 比表面積3.4 mVg者。又,將平均粒徑為2〇叫之|粉末為 p重量份、Y2〇3M重量份、5重量份之黏合劑即乙燒纖维 素、作為溶劑使用丁基卡必醇並製成w糊膠。混合時使用 罐磨機以及三支輥子。以網版印刷該W糊膠,於上述綠色 薄膜上形成加熱器電路圖案。 於印刷加熱器電路之綠色薄膜上,疊層複數個各自為1〇酿O: \ 91 \ 91658.DOC -20- 200423209 T is more suitable. In addition, when the surface roughness of each of the joint surfaces is 5 μm or less in Ra units, and the surface roughness is exceeded, a gap is easily generated at the joint surface. The surface roughness is more suitable if the unit of Ra is i or less. ::, The electrode is installed on the round carrier. The installation can be performed in a well-known way. For example, from the wafer holding surface and the opposite side of the wafer carrier to the electrical circuit to perform the winding process, the electrical circuit is metallized or the direct active metal rod is used for de-alloying. An electrode such as indium or crane is sufficient. Thereafter, if necessary, an electric bond is applied to the electrode to improve the oxidation resistance. In this way, a wafer carrier for a semiconductor manufacturing apparatus can be manufactured. In addition, the wafer carrier of the present invention is mounted in a semiconductor device, and semiconductor wafers can be processed. The temperature of the wafer holding surface in the wafer carrier of the present invention is uniform, so that the temperature distribution of the wafer is also uniform compared to the previous one. Therefore, stable characteristics can be obtained for the formed film or heat treatment. (Example 1) 99 parts by weight of osmium nitride powder and 丨 parts by weight of other powders were mixed, and polyethylene butylene was used as a binder, 10 parts by weight, and dibutyl phthalate was used as ~ | ! 5 mils, mix, and use a doctor blade method to form a green film with a thickness of 1.0 mm. In addition, as the nitride powder, an average particle diameter U and a specific surface area of 3.4 mVg were used. Also, an average particle diameter of 20 is called | powder is p parts by weight, Y203M parts by weight, and 5 parts by weight of ethyl cellulose, which is a binder, and butylcarbitol is used as a solvent to make w paste. . A pot mill and three rollers are used for mixing. This W paste was printed on a screen to form a heater circuit pattern on the green film. On the green film of the printed heater circuit, a plurality of layers are each laminated.

O:\91\91658.DOC -21 - 200423209 厚之綠色薄膜,製成疊層體。於模型中重疊薄膜進行設置, 藉由於壓力機中以5(TC加熱,並且以10 MPa之壓力熱壓接2 分鐘進行疊層。此後,於氮環境中以600°C進行脫脂,於氮 環境中以1800°C、3小時之條件進行燒結,製成晶圓載具。再 者,燒結後,實施研磨加工以使晶圓保持面以,Ra單位為1 μηι 以下,且機械軸接合面以Ra單位為5 μπι以下。又,外徑亦 進行完成加工。加工後之晶圓載具之尺寸如表1所示。再 者,厚度為20 mm。 自晶圓保持面之相反側之面至上述加熱器電路進行繞線 加工,將加熱器電路露出一部分。露出之加熱器電路部中 使用、活性金屬焊料直接接合Mo製造之電極。該電極中藉由 通電加熱晶圓載具,並測定均熱性。 均熱,性之測定係將直徑300 mm之晶圓溫度計裝載於晶圓 保持面,並測定其溫度分佈。再者,調整供給電力以使晶 圓溫度計之中心部之溫度成為550°C。其結果如表1所示。 O:\91\91658.DOC -22- 表1O: \ 91 \ 91658.DOC -21-200423209 thick green film, made of laminated body. Laminate the film in the model and set it. Laminated by heating at 5 ° C in a press and thermocompression bonding at 10 MPa for 2 minutes. Thereafter, degreasing was performed at 600 ° C in a nitrogen environment and in a nitrogen environment. The wafer was sintered at 1800 ° C for 3 hours to produce a wafer carrier. After sintering, grinding was performed so that the wafer holding surface had a Ra unit of 1 μη or less and the mechanical shaft joint surface was Ra. The unit is 5 μm or less. In addition, the outer diameter is also processed. The dimensions of the wafer carrier after processing are shown in Table 1. Furthermore, the thickness is 20 mm. From the side opposite to the wafer holding surface to the above heating The heater circuit is wound to expose a part of the heater circuit. The exposed heater circuit part is used to directly connect an electrode made of Mo to an active metal solder. In this electrode, a wafer carrier is heated by applying electricity and the uniformity is measured. The measurement of heat and temperature is carried out by mounting a wafer thermometer with a diameter of 300 mm on the wafer holding surface and measuring its temperature distribution. Furthermore, the power supply is adjusted so that the temperature at the center of the wafer thermometer becomes 550 ° C. . Results shown in Table 1. O: \ 91 \ 91658.DOC -22- TABLE 1

No 直徑这 (mm) 直徑b (mm) b-a (μπι) 均熱性(%) 1 340.20 340.00 — 200 ±0.60 2 340.15 340.00 -150 ±0.59 3 340.12 340.00 — 120 ±0.58 4 340.10 340.00 -100 士 0.57 5 340.07 340.00 -70 ±0.55 6 340.06 340.00 -60 士 0.54 7 340.04 340.00 -40 ±0.53 8 340.02 340.00 -20 ±0.51 9 340.00 340.00 0 ±0.50 10 339.98 340.00 20 ±0.46 11 339.97 340.00 30 士 0.43 12 339.95 340.00 50 ±0.40 13 339.93 340.00 70 ±0.38 14 339.90 340.00 100 土 0.37 15 339.85 340.00 150 ±0.35 16 339.80 340.00 200 ±0.33 17 339.50 340.00 0.5 ,士 0.32 18 339.00 340.00 1.0 ±0.30 19 338.00 340.00 2.0 ±0.28 20 337.00 340.00 3.0 ±0.26 21 336.00 340.00 4.0 土 0.24 22 335.00 340.00 5.0 士 0.23 23 330.00 340.00 10.0 土 0.20 24 325.00 340.00 15.0 土 0.17 25 320.00 340.00 20.0 土 0.15 26 310.00 340.00 30.0 ±0.13 27 305.00 340.00 35.0 ±0.28 28 300.00 340.00 40.0 士 1.40 200423209 如自表1判斷,藉由直徑b設定為大於直徑a,可將晶圓表 面之溫度分佈設定為士0.5%以内。再者,若直徑b與直徑a 相比大於5 0 μηι以上’可將晶圓表面之溫度分佈設定為土0 · 4 %以内。 (實施例2) 將表1之各晶圓載具裝入半導體製造裝置,於直徑12吋之 Si晶圓之上,形成TiN膜。使用No· 1〜8之晶圓載具之情形 O:\91\91658.DOC -23- 200423209 時,TiN之膜厚之不均一性大於1 5%,使用其以外之晶圓載 具之情形時,膜厚之不均一性小於10%以下,可形成良好 之TiN膜。 (實施例3) 與實施例1同樣,製成厚度20 mm之晶圓載具。其次,如 圖4所示,於晶圓載具上形成階差,以與實施例1同樣之方 法測定均熱性。其結果示於表2。 表2No Diameter (mm) Diameter b (mm) ba (μπι) Soaking (%) 1 340.20 340.00 — 200 ± 0.60 2 340.15 340.00 -150 ± 0.59 3 340.12 340.00 — 120 ± 0.58 4 340.10 340.00 -100 ± 0.57 5 340.07 340.00 -70 ± 0.55 6 340.06 340.00 -60 ± 0.54 7 340.04 340.00 -40 ± 0.53 8 340.02 340.00 -20 ± 0.51 9 340.00 340.00 0 ± 0.50 10 339.98 340.00 20 ± 0.46 11 339.97 340.00 30 ± 0.43 12 339.95 340.00 50 ± 0.40 13 339.93 340.00 70 ± 0.38 14 339.90 340.00 100 soil 0.37 15 339.85 340.00 150 ± 0.35 16 339.80 340.00 200 ± 0.33 17 339.50 340.00 0.5, plus 0.32 18 339.00 340.00 1.0 ± 0.30 19 338.00 340.00 2.0 ± 0.28 20 337.00 340.00 3.0 ± 0.26 21 336.00 340.00 4.0 soil 0.24 22 335.00 340.00 5.0 ± 0.23 23 330.00 340.00 10.0 soil 0.20 24 325.00 340.00 15.0 soil 0.17 25 320.00 340.00 20.0 soil 0.15 26 310.00 340.00 30.0 ± 0.13 27 305.00 340.00 35.0 ± 0.28 28 300.00 340.00 40.0 ± 1.40 200423209 as Table 1 judges that by setting the diameter b to be larger than the diameter a, the temperature distribution on the wafer surface can be determined. Within disabilities as 0.5%. In addition, if the diameter b is larger than 50 μm compared to the diameter a ', the temperature distribution on the surface of the wafer can be set to within 0. 4%. (Example 2) Each wafer carrier of Table 1 was loaded into a semiconductor manufacturing apparatus, and a TiN film was formed on a Si wafer having a diameter of 12 inches. When using a wafer carrier of No. 1 ~ 8 O: \ 91 \ 91658.DOC -23- 200423209, the non-uniformity of the film thickness of TiN is greater than 15%, and when using other wafer carriers, The non-uniformity of film thickness is less than 10%, which can form a good TiN film. (Example 3) A wafer carrier having a thickness of 20 mm was fabricated in the same manner as in Example 1. Next, as shown in Fig. 4, a step was formed on the wafer carrier, and the soaking property was measured in the same manner as in Example 1. The results are shown in Table 2. Table 2

No 直徑a (mm) 直徑b (mm) b,a (mm) 均熱性(%) 29 338.00 340.00 2.0 ±0.27 30 335.00 340.00 5.0 ±0.22 31 330.00 340.00 10.0 ±0.20 32 325.00 340.00 15.0 士 0.16 33 320.00 340.00 20.0 士 0·15 34 310.00 340.00 30.0 ±0.13 35 305.00 340.00 35.0 ±0.33 36 300.00 340.00 40.0 士 1·40 如自表2判斷,即便於形成階差之情形時,藉由設定直徑 b大於直徑a,可將晶圓表面之溫度分佈設定為±0.5%以 内。再者,若直徑b與直徑a相比大於5 0 μηι以上,則可將晶 圓表面之溫度分佈設定為土0.4%以内。 (產業上之可利用性) 根據本發明,藉由晶圓保持面之直徑a設定為小於與晶圓 保持面相反側之面之直徑b,可提供均熱性優良之晶圓載具 以及半導體製造裝置。藉由設定b-a-50 μηι,可進一步提 高均熱性。裝載如此之晶圓載具之半導體製造裝置與先前 O:\91\91658.DOC -24- 200423209 之裝置相t匕,加熱器之溫度分佈亦更加均一化,因此可實 2導體之特性或原材料利用率、可靠性或集成度、圖像 品質之提高。 【圖式簡單說明】 圖係表不本發明之晶圓載具之剖面構造(4)之圖。 圖2係表不本發明之晶圓載具之剖面構造(a=b)之圖。 圖3係表示本發明以外之晶圓載具之剖面構造(a〉b)之圖。 圖係表示本發明之晶圓載具之剖面構造(a<b)之其他例 之圖。 圖5係表不本發明之晶圓載具之剖面構造(a<b)之其他例 之圖。 【圖式代表符號說明】 1 •晶圓載具 2 晶圓 a 晶圓保持面之直徑 b與晶圓保持面相反側之面之直徑No Diameter a (mm) Diameter b (mm) b, a (mm) Soaking (%) 29 338.00 340.00 2.0 ± 0.27 30 335.00 340.00 5.0 ± 0.22 31 330.00 340.00 10.0 ± 0.20 32 325.00 340.00 15.0 ± 0.16 33 320.00 340.00 20.0 00 · 15 34 310.00 340.00 30.0 ± 0.13 35 305.00 340.00 35.0 ± 0.33 36 300.00 340.00 40.0 11 · 40 As judged from Table 2, even when a step is formed, by setting the diameter b to be larger than the diameter a, the The temperature distribution on the wafer surface is set within ± 0.5%. Furthermore, if the diameter b is larger than 50 μm compared to the diameter a, the temperature distribution on the surface of the wafer can be set to within 0.4%. (Industrial Applicability) According to the present invention, by setting the diameter a of the wafer holding surface to be smaller than the diameter b of the surface opposite to the wafer holding surface, it is possible to provide a wafer carrier and a semiconductor manufacturing apparatus having excellent heat uniformity. . By setting b-a-50 μηι, the soaking performance can be further improved. The semiconductor manufacturing device with such a wafer carrier is similar to the previous device of O: \ 91 \ 91658.DOC -24- 200423209, and the temperature distribution of the heater is more uniform, so the characteristics of the 2 conductors or the use of raw materials can be realized. Rate, reliability or integration, and image quality. [Brief description of the drawing] The drawing is a drawing showing the cross-sectional structure (4) of the wafer carrier of the present invention. FIG. 2 is a diagram showing a cross-sectional structure (a = b) of the wafer carrier of the present invention. FIG. 3 is a view showing a cross-sectional structure (a> b) of a wafer carrier other than the present invention. It is a figure which shows the other example of the cross-sectional structure (a < b) of the wafer carrier of this invention. Fig. 5 is a view showing another example of the cross-sectional structure (a < b) of the wafer carrier of the present invention. [Illustration of Symbols] 1 • Wafer carrier 2 Wafer a Wafer diameter of wafer holding surface b Diameter of the surface opposite to wafer holding surface

O:\91\91658.DOC -25-O: \ 91 \ 91658.DOC -25-

Claims (1)

200423209 拾、申請專利範圍: 1. 一種半導體製.造裝置用晶圓載具,其係具有晶圓保持面 者’其特徵在^:上述晶圓載具之晶圓保持面之直徑a小 於與晶圓載具之晶圓保持面相反側之面之直徑b。 2·如申請專利範圍第丨項之半導體製造裝置用晶圓載具,其 中上述直徑b比上述直徑a大5 〇 μιη以上。 3·如申请專利範圍第1或2項之半導體製造裝置用晶圓載 具,其中上述晶圓載具係於其内部或表面形成電阻發熱 體之陶瓷加熱器。 4· 一種半導體製造裝置,其特徵在於··裝載有申請專利範 圍第1至3項中任一項之晶圓載具。 O:\91\91658.DOC200423209 Scope of patent application: 1. A wafer carrier for semiconductor manufacturing equipment, which has a wafer holding surface, which is characterized in that the diameter a of the wafer holding surface of the wafer carrier is smaller than that of the wafer carrier. The diameter b of the surface on the opposite side of the wafer holding surface. 2. If the wafer carrier for a semiconductor manufacturing device according to item 丨 of the patent application, wherein the diameter b is larger than the diameter a by 50 μm or more. 3. The wafer carrier for a semiconductor manufacturing device as set forth in claim 1 or 2, wherein the wafer carrier is a ceramic heater that forms a resistance heating element inside or on its surface. 4. A semiconductor manufacturing device, characterized in that it is equipped with a wafer carrier according to any one of patent application scopes 1 to 3. O: \ 91 \ 91658.DOC
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