200417605 ⑴ 玖、發明說明 (發明說明應敘明：發明所屬之技術領域、先前技術、内容、實施方式及圖式簡單說曰 發明領域 本發明係關於清潔劑組合物。特定言之，本發明係關於 具有優異清潔力及較低皮膚刺激性之衣物清潔劑組合物。 先前技術 目如市面上已有多種清洗衣物之清潔劑產品，包括傳統 洗衣粉、；辰縮洗衣粉、洗衣精、皂絲等。由於各種產品所 含的配方’例如界面活性劑之種類及含量有所不同，使得 各種清潔劑產品具有不同之清潔效果。為達到較為優異之 清潔效果，可於清潔劑中添加較多量之界面活性劑，但由 於界面活性劑受硬水影響及對皮膚具有刺激性，且基於成 本上之考量，往往侷限了界面活性劑種類及含量之使用， 也因此限制了清潔劑之清潔效果。 因此，目前市場上仍亟尋求具有優異清潔效果且可缓和 對皮膚刺激性之衣物清潔劑產品。 發明内容 為改善目前市面上清洗衣物用之清潔劑所具有對皮膚 之刺激性及長：昇清潔劑之洗淨能力與效果，申請人發現添 加特定種類的陽離子性界面活性劑及蘆薈成份，可增強清 潔劑之清潔力，同時改善對皮膚之刺激性。 因此，本發明之目的係提供一種可增強清潔劑之清潔力 ，同時改善對皮膚之刺激性之清潔劑組合物。 實施方式 本發明之清潔劑組合物，以組合物總重量計，包括〇 〇 ι 200417605 (2) 發鹌說_續頁 至5.0重量％之PEG-5甲硫酸酯椰基銨（PEG_5 cocomonlum methosulfate)，及Oiss.o重量％之蘆薈成份。 本案發明人頃發現，選用特定種類之陽離子性界面活性 劑，即PEG-5甲硫酸酯椰基銨，可增強一般液體洗衣精 之洗淨效果，因此，本發明之清潔劑組合物之一主要成份 為PEG-5甲硫酸酷椰基铵。本文中所稱之「peg-5甲硫 酉曰挪基知」’係指含有聚乙二醇基及挪子基所形成之甲 石J5L S旨按鹽，其係—種陽離子性界面活性劑，在室溫下為 黃色之澄清液體，分子量約為546。本發明之清潔劑組合 物所使用之PEG-5甲硫酸酯椰基銨，可購自Goldschmidt Rewo GmbH &Co.，商品名為 REWOQUAT CPEM。 再者’為同時改善清潔劑中各種成份對皮膚所造成的刺 激，本發明之清潔劑組合物中含另一主要成份為蘆薈成份 。本文中所稱之「蘆薈成份」，係指可應用於工業上之含 有從蘆薈植物所萃取之萃取物或濃縮物。本發明之清潔劑 組合物所使用之蘆薈成份，較佳係商業上購得之蘆薈濃縮 液（商品名為Activera® 104 )，其係為無色澄清液體，pH 值約為5.3。 較佳地，本發明之清潔劑組合物，以組合物總重量計， 可進一步包括10.0至50.0重量％之其他界面活性劑。本文 中所稱之「其他界面活性劑」，係指此技藝中所習用之任 何種類之界面活性劑，包括陰離子性界面活性劑、陽離子 性界面活性劑、非離子性界面活性劑及兩性離子界面活性 劑。 200417605 (3) 適用於本發明中之陰離子性界面活性劑，例如但不限於 垸基苯橫酸鹽、燒基莕續酸鹽、坑基續酸鹽、烯烴橫酸鹽 、二烷基磺酸琥珀酸鹽、磺化脂肪酸鹽、石油磺酸鹽、烷 基硫酸鹽、聚氧乙晞烷基醚硫酸鹽、聚氧乙晞烷基苯基醚 硫酸鹽、烷基磷酸鹽、聚氧乙烯烷基醚磷酸鹽、聚氧乙烯 燒基苯基醚磷酸鹽及惠類等。 適用於本發明中之陽離子性界面活性劑，除前述之 PEG-5甲硫酸酯椰基銨夕卜，尚可選用例如但不限於一級至 三級脂肪酸鹽、四級銨鹽、烷基吡啶鹽及脂肪酸亞硝酸鹽 衍生物等。 適用於本發明中之非離子性界面活性劑，例如但不限於 聚氧乙烯烷基醚、聚氧乙烯烷基苯基醚、聚氧乙婦聚苯乙 烯苯基醚、多元醇脂肪酸酯、聚氧乙烯多元醇脂肪酸部分 酯、聚氧乙烯脂肪酸酯、聚甘油脂肪酸酯、脂肪酸二乙醇 胺、聚氧乙烯烷基胺、三烷基胺氧化物及脂肪酸二乙醇醯 胺等。 適用於本發明中之兩性離子界面活性劑，例如但不限於 胺基酸衍生物、烷基烷羧酸内銨鹽、磺烷基内銨鹽及磺化 鲁 胺基酸等。 較佳地，本發明組合物所含之其他界面活性劑為陰離子 性界面活性劑、非離子性界面活性劑或其混合物。更佳地 ，該陰離子性界面活性劑為直鏈烷基苯磺酸酯（LAS)、月 桂醇基氧化乙烯醚硫酸酯鈉鹽（SLES)或其混合物，該非離 子性界面活性劑為油酸、單乙醇胺（MEA)或其混合物。 200417605 (4) 本發明之清潔劑組合物較佳係以液態形式存在，此液態 形式即為技藝中所稱之洗衣精，其含以組合物總重量計， 至少40重量％之水，且具有黏度至少100 cps。 較佳地，本發明之清潔劑組合物，以組合物總重量計， 亦可包括1 . 0至2 0.0重量％之硬水軟化劑。本文中所稱之「 硬水軟化劑」，係指一般此技藝中所習用於各類清潔劑中 可防止硬水中的#5、鎂等金屬離子對界面活性劑造成失活 之金屬絡合物質，其可提高清潔劑中界面活性劑之去污能 力。適用於本發明清潔劑組合物之硬水軟化劑，例如但不 限於聚磷酸鹽、碳酸鹽、矽酸鹽、檸檬酸鹽、羧酸酯聚合 物（如聚丙醯酸酯）、螯合劑（如乙二胺四乙酸（EDTA)、三 乙酸胺（NTA)、羧甲基氧基琥珀酸（CMOS)、羧甲基氧基丙 二酸（CMOM)、二伸乙基三胺基五醋酸（DTPA)及二伸乙基 胺基五醋酸（DPA)等）、輕鹼、沸石及其混合物。 較佳地，本發明清潔劑組合物，以組合物總重量計，亦 可包括0.1至1 0.0重量％之抗沉澱劑。本文中所稱之「抗沉 澱劑」，係指此技藝中所習用於各類清潔劑中可防止已與 界面活性劑作用之污垢再附著於清洗衣物上之物質。適用 於本發明清潔劑組合物之抗沉澱劑，例如但不限於羧甲基 纖維素鈉、聚乙二醇、聚乙烯醇及其混合物。 較佳地，本發明之清潔劑組合物，以組合物總重量計， 亦可包括0.0 0 1至1 . 0重量％之防腐劑。本文中所稱之「防 腐劑」，係指技藝中習用於清潔劑中防止清潔劑遭受微生 物感染所引起變質及變色之物質，其並不影響清潔劑之洗 200417605 (5) 發_說_續頁 滌效果。適用於本發明之防腐劑，例如但不限於抗微生物 劑，如1，2-苯并異噻唑啉-3-酮（其商品名為Proxel GXL)。 較佳地，本發明之清潔劑組合物，以組合物總重量計， 亦可包括0.1至5.0重量％之酵素。本文中所稱之「酵素」 ，係指具有受質專一性之生物催化劑，其可分解污垢。適 用於本發明之酵素，例如但不限於蛋白酶、脂肪酶、澱粉 酶、纖維素酶及其混合物。 此外，為使清潔劑可含有其他之效果，本發明之清潔劑 組合物，以組合物總重量計，亦可含有此技藝中一般添加 於清潔劑之一或多種其他成份。舉例言之，為使清潔劑具 有香味，可添加0.1至1.0重量％之香精；為使清洗之衣物 纖維看起來更潔白，可添加吸收不可見紫外線並反射藍光 之0. 1至1.0重量％之螢光劑；為使清潔劑可同時達到殺菌 並避免衣物泛黃，可添加0. 1至1.0重量％之漂白劑；為使 清洗之衣物柔軟並防止靜電產生，可添加5至1 0重量％之 纖維柔軟劑；為使清洗過程中不致產生過量之泡沫，可添 加0 . 1至1.0重量％之消泡劑。上述各種成份可視需要依種 類不同而添加適當量於清潔劑中。 本發明將經由下列實施例進一步加以詳細描述，惟該等 實施例僅用以例示說明本發明之具體實施態樣，並非用以 對本發明範圍作任何限制。任何熟悉此項技術之人士可輕 易達成之修飾及改變均包含於本案所附申請專利範圍之 範圍内。 實例1 :洗衣精配方 200417605200417605 发明 发明, description of the invention (the description of the invention should state: the technical field to which the invention belongs, the prior art, the content, the embodiments, and the drawings. Briefly, the invention relates to the detergent composition. In particular, the invention is Concerning laundry detergent compositions with excellent cleansing power and low skin irritation. The prior art targets such as a variety of detergent products for washing clothes on the market, including traditional laundry detergents, Chenshine laundry detergents, laundry detergents, and soap shreds. Etc. Due to the different formulations such as the type and content of surfactants in various products, various cleaning products have different cleaning effects. In order to achieve a better cleaning effect, a larger amount can be added to the detergent Surfactants, but because surfactants are affected by hard water and irritating to the skin, and based on cost considerations, the use of surfactant types and contents is often limited, which also limits the cleaning effect of detergents. Therefore, At present, the market is still urgently looking for clothing that has excellent cleaning effects and can relieve skin irritation. Detergent products. SUMMARY OF THE INVENTION In order to improve the skin irritation and long-lasting cleansing properties of detergents used for washing clothes on the market, the applicant found that adding specific types of cationic surfactants and Aloe vera ingredients can enhance the cleansing power of the cleansing agent and improve the irritation to the skin. Therefore, the object of the present invention is to provide a cleansing composition that can enhance the cleansing power of the cleansing agent and improve the irritation to the skin at the same time. Mode The detergent composition of the present invention includes, based on the total weight of the composition, 〇2004 2004605 (2) Faquat_continued to 5.0% by weight of PEG-5 cocomonlum methosulfate, And Oiss.o weight percent of aloe ingredients. The inventors of this case have found that the use of a specific type of cationic surfactant, namely PEG-5 methosulfate comonium ammonium, can enhance the cleaning effect of general liquid laundry detergents. One of the main ingredients of the detergent composition of the present invention is PEG-5 ammonium methosulfate. As used herein, "peg-5 methionine" refers to containing The formazan J5L S formed by polyethylene glycol group and noryl group is based on salt, which is a kind of cationic surfactant, which is a yellow clear liquid at room temperature with a molecular weight of about 546. The cleaning agent of the present invention The PEG-5 cocoammonium methosulfate used in the composition is commercially available from Goldschmidt Rewo GmbH & Co. under the trade name REWOQUAT CPEM. Furthermore, to improve skin irritation caused by various ingredients in the cleansing agent, The cleansing composition of the present invention contains another main ingredient, the aloe ingredient. The "aloe ingredient" referred to herein refers to an industrially applicable extract or concentrate containing an extract from an aloe plant. The aloe component used in the detergent composition is preferably a commercially available aloe concentrate (trade name Activera® 104), which is a colorless, clear liquid with a pH of about 5.3. Preferably, the detergent composition of the present invention may further include 10.0 to 50.0% by weight of other surfactants based on the total weight of the composition. As used herein, "other surfactants" refer to any kind of surfactants used in this technology, including anionic surfactants, cationic surfactants, nonionic surfactants, and zwitterionic interfaces. Active agent. 200417605 (3) Anionic surfactants suitable for use in the present invention, such as, but not limited to, fluorenylbenzene sulfonate, sulfonyl sulfonate, pityl sulfonate, olefin sulfonate, dialkylsulfonic acid Succinate, sulfonated fatty acid salt, petroleum sulfonate, alkyl sulfate, polyoxyethyl ether alkyl sulfate, polyoxyethyl alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkane Ether ether phosphate, polyoxyethylene alkylphenyl ether phosphate and benefits. Suitable cationic surfactants in the present invention, in addition to the aforementioned PEG-5 methosulfate coconut ammonium sulfate, for example, but not limited to, primary to tertiary fatty acid salts, quaternary ammonium salts, and alkylpyridine salts And fatty acid nitrite derivatives. Nonionic surfactants suitable for use in the present invention, such as, but not limited to, polyoxyethylene alkyl ethers, polyoxyethylene alkylphenyl ethers, polyoxyethyl polystyrene phenyl ethers, polyol fatty acid esters, Polyoxyethylene polyol fatty acid partial ester, polyoxyethylene fatty acid ester, polyglycerin fatty acid ester, fatty acid diethanolamine, polyoxyethylene alkylamine, trialkylamine oxide, fatty acid diethanolamine and the like. Zwitterionic surfactants suitable for use in the present invention include, for example, but not limited to, amino acid derivatives, alkylalkanoic acid betaines, sulfoalkyl betaines, and sulfonated leucines. Preferably, the other surfactant contained in the composition of the present invention is an anionic surfactant, a nonionic surfactant or a mixture thereof. More preferably, the anionic surfactant is a linear alkylbenzene sulfonate (LAS), a lauryl alcohol-based ethylene oxide sulfate sodium salt (SLES) or a mixture thereof, and the nonionic surfactant is oleic acid, Monoethanolamine (MEA) or a mixture thereof. 200417605 (4) The detergent composition of the present invention preferably exists in a liquid form. This liquid form is a so-called laundry detergent, which contains at least 40% by weight of water based on the total weight of the composition, and has Viscosity of at least 100 cps. Preferably, the detergent composition of the present invention may also include a hard water softener of 1.0 to 20.0% by weight based on the total weight of the composition. The "hard water softener" as referred to in this article refers to the metal complexing substances commonly used in this technology to prevent # 5, magnesium and other metal ions in hard water from inactivating surfactants. It can improve the detergency of the surfactant in the detergent. Hard water softeners suitable for use in the detergent compositions of the present invention, such as, but not limited to, polyphosphates, carbonates, silicates, citrates, carboxylate polymers (such as polypropionates), chelating agents (such as ethyl acetate) Diamine tetraacetic acid (EDTA), amine triacetate (NTA), carboxymethyloxysuccinic acid (CMOS), carboxymethyloxymalonic acid (CMOM), diethylene triamine pentaacetic acid (DTPA) And diethylaminopentaacetic acid (DPA), etc.), light alkali, zeolite and mixtures thereof. Preferably, the detergent composition of the present invention may also include 0.1 to 1 0.0% by weight of an anti-settling agent based on the total weight of the composition. The term "anti-sedimentation agent" as used herein refers to substances used in this technology to prevent dirt that has interacted with surfactants from re-adhering to the laundry. Anti-settling agents suitable for use in the detergent composition of the present invention, such as, but not limited to, sodium carboxymethyl cellulose, polyethylene glycol, polyvinyl alcohol, and mixtures thereof. Preferably, the detergent composition of the present invention may also include a preservative in an amount of from 0.01 to 1.0% by weight based on the total weight of the composition. The term "preservatives" as used in this article refers to substances that are used in the art to prevent detergents from undergoing deterioration and discoloration caused by microbial infection. It does not affect the washing of detergents. 200417605 (5) Hair_speaking_continued Page cleaning effect. Preservatives suitable for use in the present invention, such as, but not limited to, antimicrobial agents such as 1,2-benzisothiazolin-3-one (trade name Proxel GXL). Preferably, the detergent composition of the present invention may also include 0.1 to 5.0% by weight of enzyme based on the total weight of the composition. The "enzyme" referred to in this article refers to a biocatalyst with specificity for substrates, which can decompose dirt. Enzymes suitable for use in the present invention, such as, but not limited to, proteases, lipases, amylases, cellulases, and mixtures thereof. In addition, in order that the detergent may contain other effects, the detergent composition of the present invention may also contain one or more other ingredients generally added to the detergent in the art based on the total weight of the composition. For example, in order to make the detergent have a fragrance, 0.1 to 1.0% by weight of essence can be added; in order to make the laundry fibers look whiter, 0.1 to 1.0% by weight of absorbing invisible ultraviolet rays and reflecting blue light can be added Fluorescent agent; in order to make the cleaning agent sterilize at the same time and avoid yellowing of clothes, 0.1 to 1.0% by weight of bleaching agent can be added; in order to soften the washed clothes and prevent static electricity, 5 to 10% by weight can be added Fiber softener; in order to prevent excessive foam during the cleaning process, 0.1 to 1.0% by weight of a defoamer can be added. The above-mentioned various ingredients may be added to the cleaning agent in an appropriate amount according to different types as required. The present invention will be further described in detail through the following examples, but these examples are only used to illustrate specific implementation aspects of the present invention and are not intended to limit the scope of the present invention in any way. Modifications and changes that can be easily achieved by anyone familiar with this technology are included in the scope of the patent application attached to this case. Example 1: Laundry detergent formula 200417605
下列表一係有關本發明及市售之洗衣精配方。 表一The following list relates to the present invention and commercially available laundry detergent formulations. Table I
Ultra H-7 H-14 H-15 H-16 H-17 原料 重量計％ 重量計％ 重量計％ 重量計％ 重量計％ 重量計％ 去離子水 7 7 0 0 0 0 BA267% 0.2 0.2 0 0 0 0 水 52.58442 67.772 71.596 70.148 70.876 71.096 Dequest2046 0.3 0 0 0 0 0 擰檬酸鈉 3 3 4.5 4.5 4 4 NaOH 0.8 0 0.96 1.15 0.7 0.94 直鏈烷基苯磺酸酯 (LAS) 4.279 3.89 4.8 4.8 2.91 3.88 ΙΙΙΟ(ΙΟΕΟ) 14.5 4 5 6.65 9.87 9.87 25EO(BASF) 0 0 0 0 0 0 Sinopal 25EO 0 0 0 0 0 0 月桂醇基氧化乙晞 醚硫酸酯鈉鹽 (SLES) 15 11.43 11.4 11.4 10.2 8.77 單乙醇胺(MEA) 0.1425 0.114 0 0 0 0 油酸R216 1 0.8 0 0 0 0 proxel GXL 0.08 0.08 0.08 0.08 0.08 0.08 香精 0.3 0.3 0.3 0.3 0.3 0.3 聚合物460N 0.25 0.2 0 0 0 0 聚合物 Alcosperse 725 0.25 0.2 0.5 0.2 0.2 0.2 CPEM 0 0.5 0.5 0.5 0.5 0.5 蘆薈 0 0.2 0.05 0.05 0.05 0.05 NaOH 0.314 0.314 0.314 0.222 0.314 0.314 總量 100 100 100 100 100 100 AI 29.400349 16.001317 17.91612 19.56612 20.00253 19.99903 200417605 ⑺Ultra H-7 H-14 H-15 H-16 H-17 Raw material% by weight% by weight% by weight% by weight% by weight% deionized water 7 7 0 0 0 0 BA267% 0.2 0.2 0 0 0 0 Water 52.58442 67.772 71.596 70.148 70.876 71.096 Dequest2046 0.3 0 0 0 0 0 Sodium citrate 3 3 4.5 4.5 4 4 NaOH 0.8 0 0.96 1.15 0.7 0.94 Linear alkylbenzene sulfonate (LAS) 4.279 3.89 4.8 4.8 2.91 3.88 ΙΙΙΟ (ΙΟΕΟ) 14.5 4 5 6.65 9.87 9.87 25EO (BASF) 0 0 0 0 0 0 Sinopal 25EO 0 0 0 0 0 0Lauryl alcohol oxyethyl ether ether sulfate sodium salt (SLES) 15 11.43 11.4 11.4 10.2 8.77 Monoethanolamine (MEA) 0.1425 0.114 0 0 0 0 oleic acid R216 1 0.8 0 0 0 0 proxel GXL 0.08 0.08 0.08 0.08 0.08 0.08 0.08 flavor 0.3 0.3 0.3 0.3 0.3 0.3 polymer 460N 0.25 0.2 0 0 0 0 polymer Alcosperse 725 0.25 0.2 0.5 0.2 0.2 0.2 CPEM 0 0.5 0.5 0.5 0.5 0.5 Aloe 0 0.2 0.05 0.05 0.05 0.05 NaOH 0.314 0.314 0.314 0.222 0.314 0.314 Total 100 100 100 100 100 100 AI 29.400349 16.001317 17.91612 19.56612 20.00253 19.99903 200417605 ⑺
H-18 H-19 H-20 H-21 H-22 H-23 原料 重量計％ 重量計％ 重量計％ 重量計％ 重量計％ 重量計％ 去離子水 0 0 0 0 0 0 BA267% 0 0 0 0 0 0 水 70.666 70.582 70.446 67.92 68.15188 68.85188 Dequest2046 0 0 0 0 0 0 檸檬酸鈉 4 4 4 4.5 4.5 4.5 NaOH 0.94 0.7 0.7 1.15 1.1 1.1 直鏈统基苯續酸酉旨 (LAS) 3.88 2.91 2.91 4.8 4.8 4.8 ΙΙΙΟ(ΙΟΕΟ) 8.87 10.064 8.87 9.422 9.2 9.2 25EO(BASF) 0 0 0 0 0 0 Sinopal 25EO 0 0 0 0 0 0 月桂醇基氧化乙烯 醚硫酸酯鈉鹽 (SLES) 10.2 10.3 11.63 11.4 11.4 10.5 單乙醇胺(MEA) 0 0 0 0 0 0 油酸R216 0 0 0 0 0 0 proxel GXL 0.08 0.08 0.08 0.08 0.08 0.08 香精 0.3 0.3 0.3 0.3 0.3 0.3 聚合物460N 0 0 0 0 0 0 聚合物 Alcosperse 725 0.2 0.2 0.2 0.2 0.2 0.2 CPEM 0.5 0.5 0.5 0 0 0.2 蘆薈 0.05 0.05 0.05 0.05 0.04 0.04 NaOH 0.314 0.314 0.314 0.178 0.228 0.228 總量 100 100 100 100 100 100 AI 20.00003 20.26653 20.00353 22.33812 22.11612 21.48612 200417605 (8) H-24 H-25 H-26 ATTACK* 原料 重量計％ 重量計％ 重量計％ 去離子水 0 0 0 BA267% 0 0 0 水 68.75188 68.10288 68.52288 Dequest2046 0 0 0 檸檬酸鈉 4.5 4.5 4.5 NaOH 1.1 1.1 1.1 直鏈烷基苯磺酸酯 (LAS) 4.8 4.8 4.8 ΙΙΙΟ(ΙΟΕΟ) 9.2 9.67 9.2 25EO(BASF) 0 0.45 0.4 Sinopal 25EO 0 0 0 月桂醇基氧化乙烯 醚硫酸酯鈉鹽 (SLES) 10.5 10.5 10.5 單乙醇胺(MEA) 0 0 0 油酸R216 0 0 0 proxel GXL 0.08 0.08 0.08 香精 0.3 0.3 0.3 聚合物460N 0 0 0 聚合物 Alcosperse 725 0.3 0.2 0.3 CPEM 0.2 0 0 0 蘆薈 0.04 0.04 0.04 0 NaOH 0.228 0.257 0.257 總量 100 100 100 AI 21.48612 21.95612 21.48612 *市售洗衣粉無法確定其確切成份，但經測定不含 CPEM及蘆薈成份 200417605 (9) 發_說瞵續頁 實例2 :清潔劑之清潔力測試 清潔劑之清潔力測試，係使用商業上所購得之標準污布 A S 1 2及W F K 1 0 D作為清洗之對象物。a S 1 2係為1 0 〇 %純棉 料，其含有色素、油及牛奶污潰，係模擬一般常見髒物。 W F K 1 0 D亦為1 0 0 %純棉料，其含有皮脂分泌物，係模擬袖 口、衣領之髒物。測試方法係將洗衣精倒入含有硬度為3 〇 、100及300ppm的水（模擬台灣北部及南部之水質硬度），H-18 H-19 H-20 H-21 H-22 H-23 Raw materials% by weight%% by weight%% by weight%% by weight% Deionized water 0 0 0 0 0 0 BA267% 0 0 0 0 0 0 Water 70.666 70.582 70.446 67.92 68.15188 68.85188 Dequest2046 0 0 0 0 0 0 Sodium citrate 4 4 4 4.5 4.5 4.5 NaOH 0.94 0.7 0.7 1.15 1.1 1.1 Linear phenyl benzoate (LAS) 3.88 2.91 2.91 4.8 4.8 4.8 ΙΙΙΟ (ΙΟΕΟ) 8.87 10.064 8.87 9.422 9.2 9.2 25EO (BASF) 0 0 0 0 0 0 Sinopal 25EO 0 0 0 0 0 0 Laurethyl oxide ethylene ether sulfate sodium salt (SLES) 10.2 10.3 11.63 11.4 11.4 10.5 Single Ethanolamine (MEA) 0 0 0 0 0 0 oleic acid R216 0 0 0 0 0 0 proxel GXL 0.08 0.08 0.08 0.08 0.08 0.08 0.08 flavor 0.3 0.3 0.3 0.3 0.3 0.3 polymer 460N 0 0 0 0 0 0 polymer Alcosperse 725 0.2 0.2 0.2 0.2 0.2 0.2 CPEM 0.5 0.5 0.5 0 0 0.2 Aloe 0.05 0.05 0.05 0.05 0.05 0.04 0.04 NaOH 0.314 0.314 0.314 0.178 0.228 0.228 Total 100 100 100 100 100 100 AI 20.00003 20.26653 20.00353 22.33812 22.11612 21.48612 200417605 (8) H-24 H-25 H -26 ATTACK * original % By weight% by weight Deionized water 0 0 0 BA267% 0 0 0 water 68.75188 68.10288 68.52288 Dequest2046 0 0 0 sodium citrate 4.5 4.5 4.5 NaOH 1.1 1.1 1.1 linear alkylbenzene sulfonate (LAS) 4.8 4.8 4.8 ΙΙΙΟ (ΙΟΕΟ) 9.2 9.67 9.2 25EO (BASF) 0 0.45 0.4 Sinopal 25EO 0 0 0 Lauryl alcohol oxyethylene ether sulfate sodium salt (SLES) 10.5 10.5 10.5 Monoethanolamine (MEA) 0 0 0 Oleic acid R216 0 0 0 proxel GXL 0.08 0.08 0.08 fragrance 0.3 0.3 0.3 polymer 460N 0 0 0 polymer Alcosperse 725 0.3 0.2 0.3 CPEM 0.2 0 0 0 aloe 0.04 0.04 0.04 0 NaOH 0.228 0.257 0.257 total 100 100 100 AI 21.48612 21.95612 21.48612 * commercial laundry The exact composition of the powder can not be determined, but it is determined that it does not contain CPEM and aloe vera 200417605 (9) _ _ 瞵 Continued Example 2: Cleaning power test of cleaning agents The cleaning power test of cleaning agents uses commercially available ones Standard stains AS 1 2 and WFK 1 0 D are the objects to be cleaned. a S 1 2 is 100% pure cotton, which contains pigment, oil and milk fouling. It simulates common dirt. W F K 1 0 D is also 100% pure cotton material, which contains sebum secretion, which is a dirt that simulates cuffs and collars. The test method is to pour laundry detergent into water containing hardness 30, 100 and 300 ppm (simulating water hardness in northern and southern Taiwan).
再利用工業用標準洗浪機預溶5分鐘，溫度控制在2 5 土 0.2 °C，其中洗衣精之清洗濃度為1 · 1克/升。 進行清洗前，將AS 12及WFK10D利用含有及未含有 4 6 Onm之分光儀下測試其反射度。經清洗1〇分鐘後，再利 用分光儀進行相同之反射度測試。經由標準污布清洗前後 所造成之反射度改變，作為判斷清潔劑之清潔力，反射度 改變越大者，清潔劑之清潔力越強。It is then pre-dissolved for 5 minutes with an industrial standard wave washer, and the temperature is controlled at 2 5 soil 0.2 ° C. The washing concentration of the laundry detergent is 1.1 g / liter. Before cleaning, the reflectance of AS 12 and WFK10D was tested with a spectrometer with and without 4 6 Onm. After 10 minutes of cleaning, use the spectrometer to perform the same reflectance test. The reflectivity change caused by standard stain cloth before and after cleaning is used to judge the cleaning power of the cleaning agent. The greater the change in reflectivity, the stronger the cleaning power of the cleaning agent.
接著將含有前述根據本發明H14、H15、H21、H22&H23 配方之洗衣精與市售傳統洗衣精（ATTACK)針對AS 12及 WFK10D標準污布進行前述清潔力之測試。 測試結果如圖1至圖3所示。該等結果顯示，根據本發明 之洗衣精經添加蘆薈成份後可能影響其清潔力之表現，但 由於其添加PEG-5甲硫故g旨挪基按，可將整體清潔力之表 現提昇至與市售產品相當。 實例3 :消費者喜好程度調杳 於大台北及大向雄地區隨機分別選出200人，針對本發 明之洗衣精形式及市售洗衣精（attack)，進行清洗衣物 -13 - 200417605 (ίο) 隊槪帽 時及清洗衣物後喜好程度之調查。其結果如圖4所示。該 結果清楚顯示，本發明之洗衣精相較於該市售濃、縮、洗衣粉 ，在大多數的評估項目中具有接近之結果，然而尤其在洗 衣粉整體表現之評估中有關「聞起來像蘆薈的香味」項目 中，具有較為顯著之差異程度。 圖示簡單說明 圖1為本發明H14、H15、H21、H22及H23配方之洗衣精 與市售傳統洗衣精（ATTACK)，於25°C及水硬度1〇〇ppm下 ，針對AS 12及WFK10D標準污布進行清潔力測試，利用分 光儀所測得之結果。 圖2為本發明H21、H22及H2 3配方之洗衣精與市售傳統 洗衣精（ATTACK)，於25°C及水硬度30ppm下，針對AS12 及W F K 1 0 D標準污布進行清潔力測試，利用分光儀所測得 之結果。 圖3為本發明H21、H22及H23配方之洗衣精與市售傳統 洗衣精（AT TACK)’於25C及水硬度300ppm下，針對AS12 及W F K 1 0 D標準污布進行清潔力測試，利用分光儀所測得 之結果。 圖4為根據本發明之洗衣精及市售洗衣精（ATTACK)於 大台北及大高雄地區進行消費者喜好程度之調查結果。Then, the detergents containing the aforementioned formulas H14, H15, H21, H22 & H23 according to the present invention and commercially available traditional laundry detergent (ATTACK) were tested for the cleaning power of AS 12 and WFK10D standard stain cloths. The test results are shown in Figures 1-3. These results show that the laundry detergent according to the present invention may affect the performance of its cleaning power after adding aloe vera ingredients, but because it is added with PEG-5 methylsulfide, the g cleansing can improve the overall cleaning performance to Commercial products are comparable. Example 3: Consumer preferences adjusted to 200 people randomly selected in the Greater Taipei and Daxiangxiong areas, for the laundry detergent form of the present invention and the commercially available laundry detergent (attack), washing clothes-13-200417605 (ίο) team Investigation of the degree of preference when capping and after washing clothes. The results are shown in Fig. 4. The results clearly show that the laundry detergent of the present invention has close results in most of the evaluation items compared with the commercially available thick, concentrated, and detergent powders. However, in the evaluation of the overall performance of the laundry powder, the "smelt like There is a significant degree of difference in the "Aloe Scent" item. Brief description of the diagrams Figure 1 is the laundry detergent and commercially available traditional laundry detergent (ATTACK) formulated for H14, H15, H21, H22 and H23 of the present invention, at 25 ° C and water hardness of 100 ppm, for AS 12 and WFK10D The standard soiling cloth is tested for cleaning power, and the result measured by the spectrometer is used. Figure 2 shows the detergents of the present invention H21, H22 and H2 3 formula and commercially available traditional laundry detergent (ATTACK), at 25 ° C and water hardness 30ppm, the cleaning power test for AS12 and WFK 1 0 D standard stain cloth, Results measured with a spectrometer. Figure 3 shows the detergents of the formulas H21, H22 and H23 of the present invention and the traditional laundry detergent (AT TACK) commercially available at 25C and a water hardness of 300ppm. The cleaning power test was performed on AS12 and WFK 1 0 D standard stains. The results measured by the instrument. FIG. 4 is a survey result of consumer preferences of laundry detergent and commercially available laundry detergent (ATTACK) in Greater Taipei and Greater Kaohsiung according to the present invention.