TW200413503A - Method of inhibiting oxidation, water capable of inhibiting oxidation and use thereof - Google Patents

Abstract

The purpose of the present invention is to promote the reaction for decomposition of molecular hydrogen as a substrate contained in a water having hydrogen dissolved therein into active hydrogen as a product through a process, in which a hydrogen oxidoreductase (excluding the one already present in organism) or noble metal colloid catalyst acts on the dissolved hydrogen water, so that a matter in oxidized form attributed to electron deficiency or an antioxidant subject to be protected from oxidation can be improved to and/or maintained at reduced form filled with electrons.

Description

V. Description of the invention 0) [Technical field to which the invention belongs] The present invention relates to an anti-oxidation method, which uses a catalyst 2 to vaporize functional water and use it to remove a person's existing enzyme in the living body (but only As a pre-procedure, it promotes…: 存; the existence of two metals containing a gel, the decomposition reaction of the active ammonia, as a matrix to form an ecological or anti-oxidation to prevent oxidation ":: ;; :: the state of oxidation caused. 豕Aicheng W electron-reduced reduction state [prior art] For living organisms, oxygen is used for the purpose of oxidizing binutrients to obtain energy, or 3 sides are used in various oxygen addition reactions, but one side; # 于 生 所 requisite The dangers associated with this kind of tissue disorders have been accused of maintaining stability due to their oxidizing power, especially when the free radicals generated by metabolism are unstable, asymmetric electron nitric oxide (NO), etc. -..., super? (Reverse: ... electrons are called ⑽.), Hydrogen peroxide is called),-re-separation term m), via the alkoxy group 'In addition, hydroperoxy group ⑽ 2 ·), per ^) 44 kinds are called active (L 〇.) Can also be considered in a broad sense such as ^ 2, alkoxy will Isoactive oxygen is collectively referred to as "active oxygen type milk swim: base right: bottom, sometimes free radicals such as nitrogen hafnium are collectively referred to as swim 2. Here ... sex milk in the presence of iron ions or copper ions, will be J band Generate page 4 2030-5943.PF (Nl); Chiume〇w.ptd 200413503 V. Description of the invention (2) New reactive oxygen species. These accelerated reactive oxygen species are known to damage cells or DNA strands and are associated with many diseases by generating aging-promoting factors, lipid peroxides. Among them, the hydroxyl group (H0 ·) has the highest reactivity, and it is known as a reactive oxygen species that has a great harmful effect on cell damage and the like. In addition, skin inflammation caused by ultraviolet (UV) has been confirmed to be related to the generation of hydroxyl (H0 ·). In addition, it is known that an excessive immune response of an infected person at the time of viral infection causes the body to produce more than necessary amounts of reactive oxygen species necessary for maintaining balance, which may cause a toxic effect on the body. The reactive oxygen species with this toxic body is usually removed in vivo by an enzyme called SOD (Superoxide Dismutase). However, if the living body is out of balance due to stress or drinking, smoking, strenuous exercise, aging, etc., SOD will decrease, and the peroxide lipids caused by reactive oxygen species will increase, leading to myocardial infarction, arteriosclerosis, Various diseases such as diabetes, cancer, stroke, cataract, shoulder coagulation, cold, hypertension, and Alzheimer's disease reduce the physiological function of the living body, and cause problems such as human spots, freckles, and wrinkles. In addition, it is one of the major factors that cause degradation, turbidity, deodorization, and degradation of freshness of active oxygen species. As a result, the problems of causing a decrease in the value of the product and serious damage to productivity were blamed. The relationship between free radicals and oxidation, quality cracking, and decay has also been accused of manifestations and negative consequences. The fact that free radicals containing active oxygen species will decrease and increase the natural load of living is severe.

200413503 V. Description of the invention (3) (ubiquinone) An i so 1e), BHT special antioxidant or active. Moreover, these resistances, and the general concerns that arise, therefore, look forward to the previous antioxidant capacity, and to those who resist. BHA (butyl butyl methoxybenzene jjydroxy (di-tert-butyl hydroxytoluene dibutyl toluene), sexual oxygen scavenger, etc .. Antioxidants are chemical synthetic products, a large amount of use in the raw materials will have safety issues for the antioxidant object Gu oxidants in the process of reducing the other side will be by-produced by oxygen compounds will also be safe for anti-oxidants. Can develop an innovative technology, which can be equivalent to or better than the antioxidant power or eliminate active oxygen. The safety of the oxidized object or the reduction of the environmental load is high [contents of the invention] To provide an antioxidant, hydroxide reduction enzymes, metal colloids act on molecular hydrogen contained in hydrogen, and the object can become electronic safety or environment due to lack of electrons. The purpose of the load is to provide a kind of catalyst containing hydroxide. The present invention is to solve the problem, the method of visualization and the antioxidant function water, which is made by dissolving the oxytocin (except for those who are pre-existing in the body) or noble solution. The process in water promotes the decomposition reaction of the active hydrogen formed by the formation of the product in the hydrogen-soluble water as the matrix, resulting in the oxidation state It is desired to prevent the oxidation from being in a sufficiently reduced state, so that a high level of reduction to the human body can be expected. In addition, the present invention is to form an antioxidant function water with an antioxidant function in order to solve this problem, page 6 2030- 5943-PF (Nl); Chiumeow.ptd 200413503

, Enzymes (except for those pre-existing in the living body) or precious metal colloids in hydrogen, and the water formed by storing water can promote the decomposition reaction of the active hydrogen produced by the molecular hydrogen contained in the hydrogen-soluble water as a matrix. By using the decomposition reaction catalyzed by the aforementioned catalyst, the oxidation state due to lack of electrons or the oxidation-resistant object to be prevented from being oxidized can be reduced to a state with sufficient electrons. It is also an object of the present invention to provide an antioxidant, an anti-aging agent, a quality deterioration preventing agent, a preservative, a fouling preventing agent, a deodorant and a freshness maintaining agent containing the antioxidant function water. First, the present inventors will explain the thinking direction of the present invention before the outline of the present invention. (1) Thinking direction of the present invention The applicant of this case has previously applied for and has published it. The content of its content is cited in the re-published patent No. w099 / 0286 of this application to disclose the chloride ion index (hereinafter referred to as "PH") and oxidation-reduction potential (hereinafter referred to as "0RP") can be controlled independently of each other and the electrolyzer and electrolyzed water generator. The summary of the application is shown below. That is, it is an electrolytic cell and a reduction potential water = forming device, which includes an electrolysis chamber for introducing raw water, one or more separators for separating the aforementioned electrolysis chamber and the outside, and at least one or more electrode plates which are respectively provided inside and outside the electrolysis chamber to sandwich the membrane. Right, and the electrode plate provided in the electrolytic room is used as the cathode, and the electrode plate provided in the electrolytic room is used as the anode, and a voltage supply circuit is provided between the two electrodes, and the electrode plate in the electrolytic room is arranged in contact with the diaphragm or through a small gap. In the same device, the tpH value of raw water on the cathode side does not change much, but it can generate electrolytic reduction potential water (hereinafter, sometimes referred to as "reduction potential water") with a significantly reduced ORP value. Below, as long as it is not particularly limited

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"Electrolytic treatment" refers to the use of the above-mentioned through-water electrolytic treatment. ~ Inverse Only The present inventors inspired the present invention by performing a performance evaluation test on Jinsheng X: original potential water by using a reduction potential water generating device that has been passed ^ ^ ΠΤ — ^ Λ ^ Φ. Here, the reduction potential water system means a person whose ORP pH with a negative value of 0 Rp exceeds a predetermined value. The value of 叩 p 9 μ is considered. 〇 Whether the RP value exceeds a predetermined value is judged according to the following Nylenstein formula (approximate formula). 〇RP = -59pH-80UV) (Nilensted). As shown in Fig. 1, this equation shows that pH has a proportional relationship with ORP (the more the ORP becomes more negative the more the alkaline side). Therefore, a value corresponding to a pH value exceeding a predetermined value means that the value of the ORP is smaller than the value corresponding to the above-mentioned Neilstein formula. Water that meets this condition is called reducing potential water. When pH7 is substituted into the above-mentioned Nylenstein formula, the ORP is about -493 (mV). That is, water having an ORP of about j9 3 (mV) or less at ph7 corresponds to reducing potential water. However, there is still a slight difference in the concentration of dissolved hydrogen in the water that falls within the range of the reduction potential water as defined here. For this point, this point will be described in detail with the quantitative analysis method of the dissolved hydrogen concentration. First, the 'reduction potential water contains a considerable amount of high-energy electrons. This point can be known if it is measured by an 0RP meter. 〇Rp is an index showing the existence ratio of gasified substances and reduced substances contained in the liquid to be measured, and its unit is generally millivolt (mV). Generally, a '0RP meter will observe a negative 0RP value if the electrode used for the measurement is negatively charged', and a 'positive 0RP' value will be observed if the electrode used for the measurement is positively charged. In order to negatively charge the electrode for measurement, the test solution must contain

Page 8 2030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (6) High-energy electrons. Therefore, if the ORP value is negative, the measured liquid must contain high-energy electrons. In order to evaluate the performance of the reduction potential contained in the water, a light-emitting diode (hereinafter, referred to as the 仃 焭 lamp test) is used. This is based on the principle of the battery. Specifically, ^ Platinum and other electrodes 201 and diaphragm 203, and each of them have 3 ^ ^ / 79Π7 taxi into a test battery 209 with a cathode to 205 and anode to 207, in the cathode chamber -600 (mV The reduction potential of the water

Helmets 丄 π and 丄 r are respectively fed with tap water with an ORP of about +400 (mV), and then the electrode in contact with the cathode chamber 205 is connected to the negative terminal of LED211 and connected to the anode chamber led2u. The positive side terminal, and observe the continuous lighting state of LED2U. This means that through the LED 211, there is a current flowing from the anode of the battery 209 to the cathode. Further, the current flowing means that the electrons are flowing. This electron flows from the cathode to the anode of the battery 209, and the fact that the electron group with high energy is definitely contained in the water can also be considered experimentally qualitatively based on the consideration of the potential. In the above battery 209, alkaline electrolytic water (for example, 〇Rp is about -50 mV) or natural mineral water generated by a commercially available electrolytic water generating device is respectively put into the cathode chamber, and tap water is separately put into the anode chamber as the Reference 7 'Same as above, the negative terminal of the LED is connected to the electrode of the cathode chamber, and the positive terminal of the LED is connected to the anode chamber. No LED lighting is observed. This can be considered to be due to the fact that the existing experimental electrolyzed water or natural mineral water does not contain a high-energy electron group capable of lighting the LED. Also, in a commercially available electrolyzed water generating device, although the flow rate can be concentrated, 2030-5943-PF (Nl); Chiumeow.ptd Page 9 200413503 V. Description of the invention (7) Move the 0RP value to a negative direction. However, according to the above-mentioned Nylenstein formula, if the absolute value of the 0RP value at the PH value becomes smaller at this time, the LED is still not observed. For example, "In a commercially available electrolyzed water generator, as a result of increasing the flow rate, even if the 0RP value is -50 0 to -60 0 (mV) at a pH of about 10, the ORP value becomes smaller by subtracting the pH value" Therefore, the electron energy is weak. It is presumed that in the above-mentioned Nylenstein formula, if the ORP value cannot drop below about -67 (mV) when the pH is about 10, the LED may not be turned on. Although there are several types of LEDs, when using a battery with a three-layer structure such as the above-mentioned cells staggered, it can be observed that the color is blue or green, which requires a diode with a high voltage between the terminals of about 3V. There is continuous light at the reducing potential. Therefore, under the intensive research on the industrial applicability of high-potential electrons in reducing potential water, the suggestion that reducing potential water may have "potential reducing power" is particularly rampant, because in order for LEDs to light, Orp must tend to be quite Negative value, so the reducing potential water has a fairly strong reducing power. If the f-force can be derived, it is believed that it can be used in a wide range of industries including medical, industrial, food, agricultural, automotive, and energy. . Bright. Here 'is what is the state of the so-called "potential reducing power". For example, if vitamin acid degener is added to ordinary water such as tap water and then an oxidant is added, the reducing agent is not immediately reduced. This state can be considered as the value of the large ORP value and the oxidized south I ratio χ ν-bay M-shaped energy. A @ 白 remains the same as the evil, and the two are in the state of coexistence. At this time, the reducing power has not yet been exerted. Page 10 2030-5943-PF (Nl); Chiumeow.ptd V. Description of the invention (8) That is, the reaction of reducing the oxidant in water regardless of the reduction potential. The magnitude of the discharge and the discharge of the electron will not immediately occur. Rong County chose the question of "the energy of the electron contained in the reduction potential water." That is, the reduction force is exerted. For different questions, the question "how to do it, the inventor, etc." Can a bit of water play a reducing power? The idea of this life effect. Although the premise of "2:, #" is the premise of the application of a catalyst organism, it is thought that it should be used as a catalyst, especially for particles belonging to clusters. H. Shellfish metal ㈣ mentioned later (Gold Gold specifically mentions enzymes, ginseng heart agents, and enzyme activity to catalyze the reaction] ::: is: the catalysis of the academic reaction 'A is the substrate B is the product: 纟2: The reverse of chemical AB is the eight workers contained in hydrogen-dissolved water. This set is used in the case of the present invention in the product. And, the second: equivalent to the substrate, and the active hydrogen is quite clear. The effect of this enzyme The turn of the machine can be thought of as the encounter of the chemical agent and the middle: :: with a high-energy electron group and the oxygen wall. The energy barrier-envy ^ Subgroups have energy barriers that must be surpassed. The higher the energy, the higher the energy must be crossed Wall :: " "This" Xun. It means that the degree of reversion is also more and more. And the height b of the wall can not cross the wall because it is more than that of the electron group. As a result, the month b of Yi, ^ f It is also the same as 'Therefore, usually the electron should not be able to reduce the oxidant and move to the oxidant. You can think of it on page 11 203 (M943-PF (N1); Chiu_.ptd 200413503 V. Description of the invention (9) But' if there is The activation energy of the catalyst of the enzyme can be reduced. As a result, because the electron group in the oxidizable water is compared with the time when the movement is not completed in the case of a catalyst corresponding to the wall height, the clam moves quite smoothly and in this way, in Enzyme can reduce the oxidant. The South Energy Electron Group becomes Yung Shi II. The reduction potential of the water in another way means that the shield can be restored: T,,: If the reducing power can be exerted. And right shield; there is a potential reducing power ", you can think about it, and finally get: solution, Zhou break the seal". After various thoughts as a catalyst "open the key to the seal of the original potential water reducing power. After understanding the thinking direction of the present invention, Brief summary (2) Summary of the present invention 2.1 Antioxidant method The present invention provides an antioxidant method, the characteristic agent of which is a redox enzyme (however, bumai granules are in order to make catalysis through permeation) The process of removing the pre-existing organisms) or the noble metal dimers in the lice-soluble water promotes the decomposition reaction of the active hydrogen produced by the 1-like lice in the hydrogen-soluble water as a substrate, which will be caused by the lack of electrons. The oxidized state or the anti-oxidation object to be prevented from being oxidized can be reduced to a state with sufficient electrons. The inventors of the present invention are that the 0RP value of hydrogen-soluble water, such as electrolytically treated water or hydrogen bubble water, is negative. The fact that hydrogen is the most basic reducing substance and that hydrogen is generated on the cathode side during electrolytic treatment supports the above argument. '

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However, as in the field I hydrogen-dissolved water of the present invention, it can be understood that the reducing power is sealed in the original π < heart test direction. Therefore, it is very important to find that the process of removing the seal when the agent of the present invention acts on hydrogen-dissolved water. Related anti-oxidation methods are defined to have the hydrogen hydrogen dissolving water in addition to the absence of the chemical agent, the extensive oxidation function within the hydrogen potential is to prevent the return of oxygen here or with the above can be dissolved hydrogen concentration followed by the second An important point of the technical paradigm, then in the present invention, the third important aspect of the present invention is the meaning of anti-oxidation. The expression of the anti-oxidative force refers to the magnitude of the antioxidant force. "Effective" for the existence of these antioxidants. There is no room for antioxidants to play a role in related antioxidants. The first two elements are hydrogen dissolved water, and the second is destruction. When these three elements are organically bound, the original force of their seals is released, and the reduction mechanism can be used to highlight them. In the present invention, it is said that the oxidized state due to lack of electrons or the object can be reduced to a state where electrons are sufficient. It is roughly estimated based on the state of the 0RP value (such as the stability of the measured value of RPp). However, if you want to pay attention to the value, determine the value obtained by the quantitative method of the dissolved hydrogen concentration of the original pigment. —Element 'mentions that the present invention belongs to and is estimated to be Z · 1 · 1 lice bath water. Hydrogen-soluble water can be collectively referred to (sometimes also referred to as raw water) in the water of lice. In addition, the activated carbon-treated water, ion = come water, pure water, distilled water, natural water bottle water, and biological water (to be described later) are pure water, ultrapure water, and commercially available treasure. Of molecular hydrogen

200413503 V. Description of invention (11) etc., including all water. In addition, all the water in which an electrolytic co-reducing agent is added is within the technical scope of the present invention. = " The condition of chlorine water, regardless of its liquidity is acidic? Neutral slugs are pleasant, and in principle it does not matter whether they are dissolved or not. However, the anti-oxidation function exhibited by the invention is transparent ^ "produced by the electrons emitted by the process of active chlorine = existence; the higher the degree, the greater the anti-oxidation function can be expected to display. The water also includes alkaline electrolyzed water (or the original gas) that is generated by lifting hydrogen in the raw water between the anode and the cathode between the anode and the cathode through the diaphragm, or water that has been subjected to pressure filling treatment. Or batch electrolysis aquatic] m circle also includes hydrogen-dissolved water generated by the existing continuous continuous water containing hydrogen. The examples given here are only the minimum examples, and are not limited to this 1: that is: except in the present invention Techniques encircle: ..., it is clear that the water is not being drained # u For example, body fluids such as blood or lymph fluids (sometimes called bio-intestinal micro-organisms in the intestine, especially those with hydrogen Kinase microorganisms are refreshing, two-knife-shaped hydrogen is dissolved, and the hydrogen-dissolved water according to the present invention is also within the scope of this technology regardless of the biological water in which the t-shaped chlorine is contained in the seed. Furthermore, blood-t-shaped The location of hydrogen is not limited to the intestine, and it is estimated that it can be absorbed and distributed by the intestine. Liver _ = π The molecular hydrogen flowing in the blood is sent to various internal organs, such as the kidney, and stored in various parts of the living body. On the 7th, the molecular form stored in the living body is used. Hydrogen as reducing agent,

200413503 V. Explanation of the invention (12) As long as the acid kinase #, ^, +, main & • And the value of 0rp of _ is lower than that of Eni: Division = P --- 59pH_80 (fflV) The value obtained by the reduction potential is low. Of course, the reduction potential water includes the device developed by the applicant of this case. (Equipped with raw water electrolysis room, before separation = one or more diaphragms to the inside and outside, and one or more electrode plate pairs located inside and outside the electrolysis room, and the electrolysis room; depolarization plate as the anode, between the two poles Two ECG circuit, and the electrode plate outside the electrolytic cell is connected to the network or the diaphragm is set up through a very small gap), the water generated is not discharged ^ generated by other devices and it meets the reduction potential shown above, attached A mention is made of a device for generating water at a reduced potential! When the tank is decomposed, m will repeatedly cycle the electrolysis in a predetermined time. ^ 1 When the technology of flow-through project is shown in Table 1 below, etc., a reduction potential water with a high dissolved hydrogen concentration and a lower 0RP value can play a good reduction. Force (antioxidant power). 3 reduced electricity 4 mediators ^ f dissolved water at a saturated concentration at atmospheric pressure (using the quantitative analysis method of apricot sloppy, ^, pigment, and dissolved hydrogen concentration to convert the dissolved hydrogen concentration sound = hydrogen on j U is This is because the emulsified functional water of the present invention can be expected to exhibit high reducing activity and antioxidant activity. The reference examples of the hydrogen-dissolved water and the comparative example of water caused by the louse are different from each other. The relevant physical property values are used as examples. ^ The target water system is to pass Fujisawa city water through activated carbon tubing.

200413503 V. Description of the invention (13) Treated activated carbon treated water, treated with Fujisawa's ion-exchange tubing, passed through Sugatochu mineral water manufactured by Wolukanoo Co., Ltd. For: J ·, used by Calbee

Eaux Mineales d, Evi di evian "(S · A · des is taken as an example. In = is a kind of treated water-soluble hydrogen water, which is a kind of hydrogen-soluble water, which is used as a generator to dissolve plutonium. Min !, liters, speed: The 5 A solid after the continuous electrolysis treatment of the reduction potential water developed by the human, the same electrolysis conditions are used for the current electrolysis conditions (the circulating water volume is 2 :, the original, ::: bu, Use the same device to make the second reduction potential water after 30 minutes: and "j 仃 continuous-type electrolytic treatment gas foaming treatment 30 minutes after hydrogen treatment" Hydrogen water generation device for various comparison target water "Mini Mitz (stock) The electrolysis conditions of the company-made electrolysis "4" are ^ 1. The range of electrolysis under water is used as an example. ^ The alkaline electrolyzed water after electrolysis is used as

In addition, the water has a long time (Amm), an electrical conductivity step, a redox potential hydrogen storage concentration DH (mg / L), a water temperature / combined milk, and a degree D0 (mg / L). The various types of f used in seed solubilizing properties are taken as examples. In addition, when measuring the gauges manufactured by each excavation company, the gauges (including thermometers) use the formula "9620-l0D", and the form of RPf + K is "Bu 13" , The probe-shaped body form is "D-25", oblique 5 shares), 0RP meter manufactured by excavation factory, ECf manufactured by excavation factory; 2 is "930 0-1 0D", EC meter The formula is "9382-l0D", the body form of D〇 ^ + a is "D-24", the form of the probe body is "D-25", and the D0 meter manufactured by Probe Digging Co., Ltd. is ~ "9520- 1 0D", DH meter (soluble 2030-5943-PF (Nl); Chiumeow, ptd page 16 200413503 V. Description of the invention (14) Hydrogen storage meter) is made by the DKK (shares) system of East Asia, and the body form is " "DHDI-1", the electrode (probe) format is "HE-532 1", and the repeater format is "DHM-F2". Using these various types of instruments, measure various physical property values of the water to be compared. Table 1 The basics of various waters According to the properties of various waters that do not contain hydrogen, the pH value is ORP [mV] EC [mS / m] DO [mgyL] DH [mg / L] TfC] Live 1 carbon-treated water 7.31 308 16.15 8.65 0.000 22.2 Ouluganu pure water 6.00 395 0.11 4.52 0.000 23.3 Evian T [t] Activated carbon treated water 9.54 -735 22.30 3.22 0.900 27.5 Orugano pure water (not 5A) 1048 -760 5.60 4.45 0.425 24.2 Evian (refrigerated storage) 7_48 -530 56.10 5.25 0.460 15.7 30 minutes) Properties: pH 0RP [mV] EC [mS / m] D0 [mgyL] DH [mg / L] T [t] Live 1 carbon-treated water 11.00 -850 42.80 1.76 1.332 25.8 Oulu Shi pure water (non- 5A) 11.15 -850 52.30 0.94 1.374 31.9 Evian (refrigerated storage) 7.72 -635 45.10 1.46 1.157 24.2 Physical properties at the time of hydrogen foaming (30 minutes) P pH ORP [mV] EC [mS / m] D〇 [mg [] DH [mg / L] TO • Wealth 8.30 585 17.97 1.67 1.070 23.6 Oulu ΛΠδί pure water 6.40 -550 0.22 1.75 1.090 23.4 Evian (refrigerated storage) 8.25 -765 50.7 2.59 0.89 21.3 activated carbon treated water (sodium hydroxide) 11 . 00 -836 33.50 1.55 0.910 20.9 When electrolyzed with an electrolyzed water generator & 1® pH ORP [mV] EC [mS / m] DO [mgyL] DH [mg / L] T [t] Alkaline run R (Shoulders) 9.34 60 14.78 8.00 0.163 20.7

According to Table 1, it can be understood that when the dissolved hydrogen concentration (DH) measured by the dissolved hydrogen meter is used, the first reduced potential water after the electrolytic treatment using the reduced potential water generating device for one time can not only immediately effect the electrolytic treated water. It can also be dissolved in high concentration hydrogen up to 0.425 ~ 0.900 (mg / L). In addition, it can be understood that when the processing time is set to 30 minutes, the dissolved hydrogen concentration of the circulating electrolytic reduction potential water (second reduction potential water) and the hydrogen gas bubble water in the original reduction potential water generating device is compared with 0.89 to 1.0 relative to the latter. 90 (mg / L), the former can be dissolved up to 1.157 ~ 1.374 (mg / L)

2030-5943-PF (Nl); Chiumeow.ptd p. 17 200413503 V. Description of the invention (15) South-excited hydrogen. However, it is preferable to add a medium-to-small L ^ reducing agent selected from the group consisting of salt, thiosulfate, ascorbic acid, and ascorbate in hydrogen-soluble water as needed. The reason for this is to prevent the catalyst from producing two kinds: rapid oxidation, so as to make the dissolved chlorine in water as much as possible. Storage: (The dissolved oxygen concentration in hydrogen-soluble water is less than 2mg / i, 丨. 5 ^ preferably l ^ y / 1 or less, 0.5 mg / l or less, 0 mg / 1 or less, in order, the less the more the more, if this is further explained, if the hydrogen function of the catalyst is added: less than the chemistry that just reduces the dissolved oxygen When the equivalent amount of reducing agent is removed, the dissolved oxygen concentration (D0) (mg / L) drops to almost 0 (mg / L). Adding the same amount of hydrogen dissolved water that has not acted on the catalyst as a comparative example will not cause dissolution. The oxygen concentration D0 (mg / L) is much lower. ”This is speculated to be due to the fact that the sealed liberated hydrogen dissolved water originally had = the reducing power possessed by the agent was more powerfully drawn out. The reduction was accompanied by the statement 'If the present invention Antioxidant water and reducing agent or

When co-existing in the bottle, the additive is under the anti-sclerosis agent, can the additive η have a stronger resistance?丨 Out. Yi #, if the ascorbic acid and t-ascorbic acid of the present invention are packed in a bottle in a coexisting state, the ascorbic acid can be reduced in the anti-oxidant :::: to sustain its reduced state, so the reductive ascorbic acid can be changed Pull out forcefully. In this case, the amount added is only U

Reducing agents such as Si add oxides such as dissolved oxygen in the coexisting system, and σ is 彳. However, the amount of ascorbic acid is added in consideration of the antioxidant machine. Page 18 2030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (16) The pH value of the water or the lower limit of the recommended daily intake, etc. 2 · 1 · 2 catalyst The catalyst is a catalyst that has the activity to decompose the ^ -like hydrogen contained in the chlorine-soluble water into the product. The catalyst's catalytic function is essentially a smooth promoting molecule =. This function contains molecular hydrogen. Obtain electrons (if i points =, get 2 electrons; h2-2e-Zhan) and after the obtained = (including the concept of adsorption or storage in the catalyst), or provide, anti-oxidation object. In addition, in the case where the oxidation target electron is supplied to reduce the oxidation target itself in the oxidation state, the oxidation target is oxidized and the oxygen such as active oxygen is reduced. The technical scope of the catalyst of the present invention includes, for example, hydroxide. In addition, there are at least one kind of electromagnetism including hydrogen-containing kinase, secondary precious metal colloids, visible light, ultraviolet rays, and electron beams. The concept of precious metal colloids conceived in the present invention includes platinum, palladium and ruthenium. , Colloidal particles of gold, silver, baht, and salts of these precious metal elements, alloy compounds, etc., and mixtures of these. Regarding colloids of precious metals, you can refer to the contents of the record for the original materials. The contents of "Platinum Colloid Usage" and the surface ν〇1 · 21Νο · 8 (1 983) made by Namba Seitaro and Okura Ichiro are the gels mentioned in the invention. The general nature of the system is shown as a colloid, and the degree of addition is regarded as the function of the matrix. The hydrogen-like activity, the child-like chlorine activity, and the electrons are temporarily uncoupled. The concept is to include and reduce enzymes used in the chemical substance itself, or to choose self-contained waves. In addition, Rhodium, Rhodium, Iridium, Compounds, and other methods and applications for making or using the invention. In addition, it is estimated that the diameter is a particle in the range of 1 nm to 0. 5 "m of precious metal colloid. However, platinum colloid is used as the particle.

2030-5943-PF (Nl); Chiume〇w.ptd Page 19 200413503 V. Description of the invention (17) Body day: 'In order to improve the catalytic activity of the molybdenum molybdenum body, the particles in the paper "Kit such as the above Namba and other shields Female Entanglement, > Physical Practice and Use Method, "records the grains derived from the main residence of the hairpin: urge m high to fight for surface area, in the choice; And ‘the colloidal German special tarts’ as referred to in the present invention. . Furthermore, the precious metal colloid of the present invention strives for surface area, and the basin position is better. This is because the precious metal colloid has a large surface area, and the chances of contact with the lice will increase, which is beneficial to the view expressed by the precious metal colloid catalyst. The range of beneficial organic catalysts includes electron transfer substances such as coenzymes, ..., substances, organic compounds that assist its own function. 2 · 1 · 2 · 1 Candidate for electron transfer material 3 Electron transfer material is preferably, for example, an electron provider, and can smoothly accept electrons by hydrogen, hydrogen reduction enzyme hydrogen kinase, or noble metal colloids: ΐ ΐ The received electron pair has the properties of a circle / month and an oxidation target of the electron acceptor. Simply put, the transport house of the son of an electron-transporting substance. ~% Below 'lists the candidates for electron-transporting substances. In addition, although the electron-transporting substance is oxidized or reduced, the reduced-type electron-transporting substance is advantageous because it has extra electrons in advance, so that it is easier to emit electrons. (a) Methylene blue (methyiene biue (usually oxidized)) methyl sulfur chloride only, tetramethyl sulfur chloride only

2030-5943-PF (Nl); Chiumeow.ptd Page 20 200413503 V. Description of the invention (18) Chemical formula = C16H18C1N3S · 3 (H20) Reduced methylene blue refers to colorless methylene blue. (b) Pyocyanin chemical formula = C13H1QN2. . It is a 4-antibiotic-species produced by Pseudomonas aeruginosa. Pyocyanin can be reversibly oxidized = two colors are blue under test and red under acid. The reduced and reduced methylene blue (colorless methylene blue) are both colorless. (C) Phenazine methosulfate is abbreviated as PMS. Chemical formula = C14H14N2G04S. Phenazine methyl sulfate has a tendency to be easily photodecomposed.

(d) l-methoxy PMS was developed as a substitute for the photo-labile PMS described above and is stable to light. — (E) Iron-containing (I I I) ionic compounds / For example, there are various kinds of FeCl3, Fe2 (S04) 3, Fe (0H) 3 and the like. The original system was used as a reagent for ionizing Fe (+3) ion. Blood matrix iron that is thought to be present in red blood cells in heme. In addition, the properties of the iron ions that are different from each other in the blood-based group are different. In particular, if conjugated with ascorbic acid in vitro and in vitro, hydroxyl radicals (· OH) with strong oxidizing power will be generated, so it is not necessary only to be iron ions. However, in the body, if iron ions coexist with nitric oxide (NO), hydroxyl radicals (· 0H) are formed. F

200413503 V. Description of the invention (19) Gan In particular, the divalent iron Fe (2+) is a reduced form of the trivalent iron Fe (3+), but although the tritium reduced form still often causes oxidation to be excessive. Especially in the presence of a lipid peroxide, a radical-linked seal reaction is liable to occur. When iron (丨 j 丨) Fe (3 +) is reduced due to k ascorbic acid, it is the presence of a peroxidized lipid that generates radicals and forms a continuous seal reaction. That is, many lipid free radicals are generated, which is presumed to have an adverse effect on the body. (〇 reduced ascorbic acid (chemical formula = (: 6118〇6) exists in the living body 'but is absorbed in vitro, the human body does not synthesize.) (G) glutathione (chemical formula ciqHi7N306) is present in vivo Many SH compounds, it is speculated that humans also have a gene to synthesize this substance I. It is a polypeptide composed of 3 amino acids (glutamine-cysteine-glycine = Glu-Cys-Gly), which is ethylene glycol. Coenzyme of aldehyde enzyme, and it is known to function as intracellular reducing agent, anti-aging agent, etc. Facial glutathione has a mechanism for direct (non-enzymatic) reduction of oxygen (〇2) (h) Cysteine (Cys ) Eight solutions Γ Γ ί: Species are SH compounds, which are components that ingest protein and digest into the above-mentioned glutathione, and have eight distinct it: it is like glutathione, when two cysteine Cys knife also releases a lice atom with a disulfide bond (one s—s—) binding type cysteine. How to deal with wind lice (i) Benzoic acid (C7H6 02) A is too absent, but strawberry It contains about 0.05%. Basically, it has a non-enzymatic and effective digestion of free radicals.

200413503 V. Description of invention (20) The function of turning into water. (j) p-aminobenzoic acid (C7H7NO2) (10 gallic acid ((: 7116605) (3,4,5-trihydroxybenzoic acid) is widely present in the leaves, stems and roots of plants It is generally used as a food antioxidant (food additive). Its alkaline water is particularly strong. It tends to react with oxygen. Moreover, the catalysts exemplified here are only a few examples. Therefore, it should be understood that the present invention The hypothetical catalytic reaction includes other parameters such as physical external forces such as / JEL degree, ultrasound, or mixing. In addition, the concept of the product active hydrogen includes (H ·) and hydride ion (Hydride, η-). In addition, the catalysts described herein can be used individually and individually: a moderate combination of two or more. Basically, they are two daggers: the order of antioxidant objects is electronically communicated, but in addition to lice dissolved water— Enzyme (chlorokinase) -antioxidant water-electron transfer substance-antioxidant, enzyme) -electron transfer substance object, lice soluble water-Γ anti "object, or hydrogen soluble water = = anti-rolling object, etc. Electricity, up to 糸, can also choose to self-contain visible flowers at least one Use of electromagnetic waves in combination. External lines, electronics 2 · 1 · 3 Anti-oxidation objects Anti-oxidation objects are collectively anti-oxidants or anti-oxidation objects. The reducing power is not limited but is not excluded. For example, atomic hydrogen can also be used to dissolve it in addition to water. It is also similar to hydrogen-dissolving enzymes (hydrogen-stimulated * noble metal colloid electron transporters that start from the group of electron-transmitting rays). Oxidation-like gasification refers to the phenomenon in which electrons are removed from an object due to direct or indirect effects of oxygen, heat, light, pH, ions, etc. due to 200413503 V. Invention Description (21). Specifically, the oxidation target includes, for example, biological cells, objects to be cleaned in various industrial fields such as industrial cleaning, food cleaning, and even precision cleaning, and antioxidants such as vitamins, foods, and quasi-medicines. Products, pharmaceuticals, cosmetics, feeds, redox pigments, and water itself, etc. The resistance objects listed here are only the minimum examples, and it should be understood that they are not limited to this. Less second From the viewpoint of catalysts, the relationship between catalysts and antioxidants is discussed. The present invention is a catalyst that catalyzes the reaction of active hydrogen in the molecular hydrogen matrix product contained in hydrogen-dissolved water. Examples of the catalyst include hydroxide dikinase or precious metal colloids. Drunk often, corpses now consider adding hydroxide reduction to reducing potential water such as lice, (ie, the antioxidant function of adding hydrogen kinase: for example, when using lice kinase in weakly alkaline reducing potential water, These oxidants will be reduced on the co-survival oxygen equalizers of the drinking cells (antioxidants). When Qiu Jian, Ma Jiawu (antioxidants), the reduction potential water is reduced, In the presence of water, it will be used as the resistance of these additives to be dissolved in water which is estimated to be a reduction potential. It will dissociate into two atomic two; the wind (H.) is divided into protons in the presence of water. With electrons, the generated atomic atoms will be provided to the antioxidant object. Here, the concept of electron-generated electricity includes making the oxidation-resistant object itself:

2030-5943-PF (Nl); Chiumeow.ptd ίη " ϊ page 24 '" -------

SL clarified that (22) is used for the case where the antioxidant itself is reduced: ^ the target is oxidized, and the active oxygen is oxidized and the reduction potential water is added with a precious metal (Pt) or Colloidal metal colloids of palladium (Pd), such as antioxidant-containing water containing platinum). Example 1 p, the weakly demonstrative reduction potential water of the noble metal colloid catalyst body is added when drinking water containing peptone (or pectin (antioxidant object) if there is co-viability; the whole body cells will be reduced. Ugly in ancient times, lice 4, immediately when the oxidants (antioxidants), other additives such as reduced water and so on were measured as differentiating agents dissolved in the reduction potential water. The action mechanism was reversed and activated while dissociating It is 2 atomic hydrogens (H.). Protons and electricity are separated into atomic hydrogens (Η.) In the presence of water. When electrons are provided, the generated electrons are provided to the antioxidant object. This = itself reduction The situation 'and the antioxidant milk used for antioxidation: two, the case of reducing oxidizing substances such as active oxygen itself. Catalysis ;: Milk 1 can function as a hydrogen-soluble water such as reducing potential water and as Antioxidant objects such as catalase-reducing enzyme hydrogen kinase or noble metal colloid that catalyzes M, and digestive organ somatic cells are exhibited. In other words, the reducing power is only displayed when necessary, and it will not exert any effect when it is not needed. Role, and pay attention to its When studying the composition of ingredients, for example, reducing potential water is just ordinary water obtained by electrolysis of raw water. Therefore, it can be emphasized that even after showing reducing power, it is still ordinary water, and it will not have any adverse effect on the living body. Change the old

2030-5943-PF (Nl); Chiumeow.ptd p. 25 200413503

In other words, it can be seen that the positive effect of the target, but the negative effect, that is, the so-called side effect element does not exist at all, is a key difference from the elimination of previous antioxidants or active oxygen. Here ’s ^ ^ The paper "The X-ray Structural Chemistry of Hydroxyl Reductive Enzymes" (Spring — 8

Information / Vol. 4 No. 4 JULY 1999). The scholar published

Hydrogen-reducing enzymes are called prion kinases and are a protein widely found in bacteria. Generally it is a protein with metals such as iron and nickel, but it has recently been discovered that 70 of these novel hydrogen kinases do not have these metals. This molecule is used to make the electrons generated by the hydrogen decomposition smoothly perform various redox reactions in the bacteria. And because it directly controls the ratio of the proton concentration inside and outside the cell membrane surface, it is considered to play an important role in the metabolic system of bacteria related to ATP synthesis and degradation enzymes ". In another thesis, the scholar also used radiation to analyze the X-ray crystal structure of hydrogen kinase using a multi-wavelength anomalous dispersion method, and published "The central enzyme in a series of reaction systems for biological energy to obtain energy is the ATP synthesis and degradation enzyme." To activate this enzyme, it is known that the ratio of proton concentration inside and outside the cell membrane needs to be controlled. Hydrogen kinase has the role of redox catalysis of the molecular hydrogen around the membrane protein existing on the surface of the cell membrane. That is, the hydrogen kinase directly controls the concentration of protons inside and outside the membrane. Ratio, and control the role of ATP synthesis and degradation enzymes. Therefore, the hydrogen kinase has the possibility to make the biological energy metabolism smooth and important function. Understanding the three-dimensional structure of the hydrogen kinase has the structure of the most important energy metabolism in the life maintenance mechanism to understand the relevant parts of the structure The significance of the relationship with function ". The inventors have stated that "hydrogen kinase directly controls the proton concentration inside and outside the membrane.

2030-5943-PF (Nl); Chiumeow.ptd Page 26 200413503 V. Description of the invention (24) Proportion and control of ATP synthesis and decomposition enzymes. Because hydrogen kinase is expected to have an effect on organisms, it can be treated as "the proton indifference ratio of the antioxidant function body exhibited by the cognate cell level is improved, and the energy metabolism system is smoothly promoted." The 'redox enzyme of the present invention, Hydrokinase or expensive = "is a genus associated with or caused by the function of unispheres / macrophages, > ί is related to or caused by the invasion or inferiority of: ??? Medicine ::: two :: barrier or pathological Pre-treatment or treatment can also be t, |? Specific examples of drugs are as follows. # ，-In general, water has the following functions: quickly reach lipid membranes: cell membranes or blood-brain barriers and other parts of living organisms, which can be damaged by shellfish active oxygen. Hydrogen reduction can be achieved by injection, point counting, etc. Enzyme hydrogen kinase or precious metal colloids are sent separately or separately, in order to expect the healing effect of the damaged site. The hydrogen-reducing enzyme hydrogen kinase is a protein, and it is assumed that it is paired with Gong = Γ 伤 " When feeding by injection, drip, dialysis, etc., the immune mechanism of i 1 ^ may recognize that the enzyme is non-self and cause antigen and antibody six μ, which is a problem. In order to solve this problem, it is only necessary to apply the principle of leniency of the living body to the clinic. Oral tolerance refers to the non-reactivity to antigen-specific τ / B cells induced by oral / traumatic foreign antigens. To put it simply, even if the substance ingested by the mouth is an egg that can become an antigen. Page 27 2030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (25) White matter, as long as it is absorbed by the small intestine Substances can establish immune tolerance. This phenomenon is called oral tolerance, and this principle has been tried to apply to treatment. Through the clinical application of the principle of oral tolerance, it is speculated that a new treatment strategy for antioxidants should be opened. ^ 2 · Antioxidant Functional Water and Uses According to the present invention, an antioxidant functional water is provided, which is characterized in that it contains a catalyst hydroxide reduction enzyme (except for those pre-existing in the body) or noble metal colloid in hydrogen The water formed by the dissolved water can promote the decomposition reaction of the active hydrogen X formed by using the molecular hydrogen contained in the hydrogen-dissolved water as a substrate, and the decomposition reaction catalyzed by the front-contact catalyst can reduce the lack of i ::: The oxidized state or the anti-oxidation object to be prevented from being oxidized can be transported to a state with sufficient electrons. The anti-oxidant water of this composition contains the heavy water content of the present invention, lice dissolves water and catalyst, so as long as the antioxidant object can be encountered later, the hydrogen has the reducing power of its seal J < (4) According to & & + 玎 pj is liberated and the present invention = Γ, the concept that electrons are provided to the anti-oxidation object includes the oxidation state of the anti-oxidation object = the transformation object, which is used for anti-oxidation and anti-oxidation 4 Reduction of the ㈤it shape 'and the situation in order to keep itself in check. If you use the antioxidant function water of the above composition to supply μ field salamander with the large intestine as the object of oxidation: use it for drinking, and the force has almost been released, then close the right 11 = The large intestine is the potential reduction of the right lice. Therefore, for the problem of achieving the original goal as the f method. Precious metal colloids are preferably hydroxide reducing enzymes, hydrogen kinases, or treatments to adjust the reaction time of the catalyst. Page 28 2030.5943-PF (Nl); Chlumeow.ptd 200413503 V. Description of the invention (26) or operation . Here, the treatment or operation for adjusting the reaction time of the catalyst is shown in FIG. 3 or 4. For example, when a hydrogen kinase or a noble metal colloid reaches a target site such as a small intestine or a large intestine, the target of the original catalyst is started. Precious metal colloids are sealed in enteric capsules, or the temperature or pH of hydrogen-kinase-containing functional water is adjusted to prevent the enzyme hydrogen kinase from being deactivated. Also 'hydrokinase is considered to be the most suitable: about the degree of visibility ... all about chlorokinase, etc .; 9 weeks left and right ^ The treatment or operation of the catalyst reaction time belongs to the present invention. The present invention is a kind of Preservation of 'water in water' removes those present in the body) or the action of noble metal colloids on hydrogen = ^ water in water, which can promote the decomposition of molecules contained in the hydrogen-soluble water = matrix-forming products of active hydrogen. The chemical agent promotes the aforementioned reaction due to lack; the child's body can be used to prevent oxidation and prevent oxidation; the object can be used in two states, including drinking, injection, drip, and dialysis; Living body applicable fluid. Kind of make-up and makeup are specially used for dripping and transparent J-oxidizing function water for injection. When the point is used for a living body, t is to apply the blood of the straight two liquid state to the physiology of isotonic osmotic pressure. The anti-lice machine's pH s week system is about _.Η · 8 is better, for example: two • 5 is better). This day, osmotic pressure modulation 200413503 V. Description of the invention (27) '---- The substance is not particularly limited as long as it is physiologically tolerable. For example, various electrolytes (such as sodium, potassium, sodium, potassium, Water-soluble salts of inorganic components such as iron, steel, ferrite, phosphorus, etc.), glucose, hyaluronic acid f: class, proteins such as albumin, amino acids, etc. In addition, as long as the pH adjuster is tolerable, τ 'is not particularly limited. For example, various kinds of organic acids, inorganic acids, organic solvents, and inorganic materials can be used, and especially organic acids are preferred. As the organic acid, for example, citric acid, acetic acid, succinic acid, glucose, lactic acid, and malic acid can be used. For example, hydrochloric acid, phosphoric acid, and the like can be used. In addition, as the organic base, for example, citric acid, &, sodium gluconate, sodium lactate, sodium malate, sodium acetate, sodium maleate, sodium malonate, etc., and as the inorganic base, potassium hydroxide metal can be used. . In addition, for the purpose of improving the living body, specifically the symptoms of patients, add various electrolytes, amino acids, high-calorie ingredients, enteral nutrition ^ 4 medicinal solution ingredients, vitamins or antibiotics and other pharmaceutical ingredients to prepare this Invented the antioxidant function water, and used as an infusion. For the various electrolytes, for example, water-soluble salts such as 等, 卸, 办, 镁, 辞, 铁, 猛, 铜, 、, 峨, and 碟 can be used. Further, as the amino acid, for example, an essential amino acid, an optional amino acid, and / or a salt, an ester, or an N-fluorene group of the amino acid can be used. As the high-calorie component, for example, monosaccharides such as glucose and fructose, and disaccharides such as maltose can be used. It is considered that a biologically suitable liquid containing vitamins such as vitamin c and amino acids (good proteins) in the antioxidant function water of the present invention can be expected to activate biological immunity due to the following functions. That is, vitamins such as vitamin c are the same as the antioxidant functional water of the present invention.

200413503 V. Description of the invention (28) It has the activity of eliminating radicals, and has the enzymes responsible for metabolism (such as SOD, catalytic enzyme, glutathione peroxidase, interferon synthase, etc.) or interferon (It is a substance composed of sugar and protein, which has immunity.) It synthesizes or exerts its original function as a coenzyme. In addition, amino acids (good proteins) have important functions as raw materials for enzymes or interferons in living organisms. If there is excess (· 〇2_) in a certain part of the body, at this time, vitamins such as vitamin C or vitamin e and biological enzymes such as soD, catalytic enzymes, and glutathione superemulsifying enzymes will mutually Cooperate to eliminate (· 〇2_). Vitamins such as vitamin C or vitamin E will lice themselves during the reduction and elimination of (· 〇2_), so they cannot perform their original functions including coenzyme. It will cause the synthesis or original function of organism enzymes or interferon in the living body or decrease its immunity and reduce the immunity. C Calculate the vitamin phase Λ in the antioxidant function water of the present invention, for example, add a vitaminizing machine Λ Λ amine Base acid White matter) is suitable for living organisms due to anti-oxidation: 1ίΐ :: ;; (.〇2—), so that the original role of vitamins includes co-interference, which can promote the supply of amino acid-derived biological enzymes or: interferon-specific & The original function can be expected, so you can expect the living function of biological immunity :: vitamins and amino acids of the present invention, the anti-oxidation of the present invention is applicable to the body of the present invention; night, or amino acid-containing injections The two + organisms and fluids can also suppress the consumption of f-biotin 妁 that originally existed in the body, so that the vitamins can be dedicated to its function of enclosing people, so it can be turned according to the action illustrated here. On the 31st page, 2030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (29)-On the other hand, 'the use of precious metal colloids as catalysts is applicable to living bodies = safety must be guaranteed. Specifically, It is necessary to consider the biocompatibility of the precious metal itself, including the precious metal itself. For this reason, even if platinum is ingested or taken, it can be quickly excreted in the form of urine through the kidney, and it is approved by the Department of Health as a food supplement. (No requirement for added amount), considered not to The problem of biological affinity = 11. Another problem to be considered is that in order to make the noble metal colloid stable and uniform-dispersed in the oxidation function water, some dispersive training should be added. For this, for example, in drinking or For cosmetic use, those who have the function of a dispersant can be appropriately selected from those who can obtain food additives from the Department of Health. This month: Fat II: 丄 sucrose, which is used for cosmetics or pharmaceuticals, and has low irritation Pirocine ρ), etc. are applicable. In addition, it is recommended to be used as a recommended sugar fatty acid ester or polyvinylpyrrolidone (pvp), which can be adjusted as ^ Zhishi, dispersant or protective film (with a catalyst The constituents of the active use) are included in the scope of the treatment or operation of tonality and / or reaction time in the Shen Gu Zhu # catalyst activator "/ + c sigma patent month. Use development. ^ Want to respond to the following industrial fields The first is application in the field of medicine and pharmacy. Base water in non-pharmaceutical processes. In addition, as such, it can be used as an infusion preparation, a peritoneal perfusion solution, or a medicament. Furthermore, y is also used as a preservation solution for transplanting organs when it is used as an artificial dialysate (at this time, preferably, it can be transplanted as a living organ). Thereby, it is expected that the osmotic pressure can be controlled and treated privately by the active oxygen bow, the side effects of the medicine can be reduced, and the effects of pre-preservation of various diseases such as old age can be expected. Prevent and improve transplantation of organs

200413503

Anti-treatment process It is a therapeutic agent applied to skin tissue. For example, it can be used for the application of functional foods in the manufacture of cosmetics other than toners. For example, Ben 3 is used as an antioxidant food in the manufacturing process of food ingredients. Material water M it: :) Water processing: Application outside material water. Example ~, used as the base water of processed beverage water such as bottled water. Non-special dyeing, degrading and re-covering, fresh-producing contamination caused by clams, insecticides, washing before goods ;. For example, it can be used as a vegetable and a fruit to be degraded. It can be used as an antioxidant, quality agent, antifouling agent, odorant, and freshness-preserving agent in the manufacturing process of processed food. Use as a substitute for 剤. If the relationship between active oxygen-containing free radicals and oxidation, aging, quality deterioration, rot shellfish = fouling, deodorization and decline in freshness is explained, the performance of active oxygen-based radicals is cited as one of the important factors for the deterioration mechanism . As a result, the inclusion of active oxygen-based radicals can cause serious injuries such as health disorders, diseases, decreased physiological functions, degradation of cosmetic appearance, decreased product value, decreased productivity, and increased natural life load. It is also one of the reasons for the industrial loss caused by the susceptibility to illness, the difficulty of treatment, the increase of medical costs, and the loss of higher cost burdens such as opportunities for production or distribution. The best examples of car owners related to active oxygen are limited to sterilization, disinfection, bleaching, etc. In most cases

200413503 V. Description of the invention (31) Active oxygen species can only be free radicals of sexual oxygen species and are low-cost and use the emergency jk solution that the body will expose and then follow the floating emphysema and other active oxygen species as a guide when the organism is new When exposed to ultraviolet rays or radiation, when the burn is in a normal state or inactive and further dissociated, the feed or feed will not only be triggered or low, but it will increase when the formation is increased. These induced localized, but can not be removed later, and in other words, the potential physiological damage caused by live redox is rapid, and the range caused by human diseases is broader than that of the acute ring, the internal organs, and the metabolic rays. Many methods such as the above-mentioned exemplary oxygen reactions, which are caused by many organic fogs and residual active oxygen produced by coal materials, are left in a diseased state, which is a good effect of functional injury. Various industrial solutions or examples of a large number of active organs when transplanted, when causing a wide range of processes or old waste, and carcinogenic infection, oxygen or oxygen will be. In addition, the exhaust gas was exposed to the free type. Even when the initial retention state is exceeded, the formation of the bad shadow is different from the normal chemistry of the shadow. It also degrades or degrades. The present invention aims to provide the most efficient method for these living problems. Oxygen examples are limited to systemic burns during surgery, and only 3 times less in most cases during diving. When the material is accumulated, direct sunlight and exposed and denaturing substances or heavy metal cuts or cells are damaged, the compound will be activated, and when exposed to food with reactive oxygen species, chlorine organic solvents, etc., the role of the base, in the living body The growth of the amount of active oxygen during the end of the period also continues, or the active oxygen species will gradually reverberate. The response will increase in a chain, which is the opposite of f (non-radical reaction) or that the occurrence of reactive oxygen species suddenly became apparent on a certain day. For example, the live oxygen #, chronic oxygen caused by gas

200413503 、 Explanation of the invention (32) Pressure load is considered to be circulatory organs such as 嫱 P- / (specific fatty liver type) (especially insulin-independent type), liver cirrhosis type), dementia and stenosis Diseases (especially carcinogenicity) and other diseases (Guangte:] is a cerebral infarction type), malignant tumors (mainly due to increasing age (older and younger body hair, the second turn, related ^ ^ because of continuous fierce movements made # i , Physical exertion caused by physical exertion, balance, or ingestion of labor, such as abnormal breathing, nutritional flatness, and other activities, produce activity: aging and degradation such as insomnia or lack of exercise, or fatigue accumulation easily, cells = It is presumed that one of the major causes of the delay of the metabolism and the resumption of the old waste or the increase of the residual accumulation is the promotion or recovery of symptoms. 2: 2: The case of outside animals and plants is W, and the insertion and storage of reactive oxygen species t 2 Residual accumulation or exposure not only brings about various health hazards like the example of humans, but it also causes various health problems, such as premature damage, hazards, damages, and aquaculture, and aquaculture. In the milk industry Decrease, meat quality and fattening rate: disease rate = equivalent hair… low breeding efficiency and low yield and these low quality " results in productivity = low value. Low-low two. Mouth j shell caused by ==, The case of the feed itself is' exposed to ultraviolet rays and other active qi charm® lice, mixed with raw materials with active oxygen, etc., because of the residual hydrogen peroxide used in the production of vitamins and bleaching, it makes s or food The active ingredients are oxidatively decomposed, decomposed due to oil or fat, or decomposed or emulsified, and faded due to pigments or pigments

V. Description of the invention (33) Taste foods' or the unpleasant odors or foods that are accompanied by the environment; Floats with active oxygen species have free radicals in the content or are prone to unpleasant odors or allergies or inflammations. Environmental workshops such as damage to these cases promote the change of water shellfish. It ’s happening, but because the reactive oxygen species will ;; into the dioxin; t off the situation will be wrong. Bajin has greatly promoted this. It does not include free radicals containing active oxygen and antioxidants and aging and anti-aging agents of the Baobao Office. In the case of 1 mesh, the former turbidity preventive agent, deodorant and freshness preventive agent, Preservatives and stains are difficult, and the inventors are strongly convinced that the only solution is to have an antioxidant method and antioxidant function. The method has only the use of the present invention > β ^. In addition, it can exert anti-oxidant :: 2 ::: Sexual oxygen scavengers' side effects that accompany the use, so it can be at a high level ^ because the efficiency will not occur at all, and it can solve the difficulty of eliminating free radicals in previous reports. Many problems. The effects and effects of the invention are difficult to use or limit the use. As mentioned above, the invention is mainly a catalyst and the second a p7 element is hydrogen-soluble water. The first one is The object of ticking. Combined with the younger brother, the potential of hydrogen can be restored, and the two elements of the net are organically returned to its original force. The seal is released. Antioxidant action 200413503 V. Description of the invention (3 ^ '----- can be displayed. ^ ^ Antioxidation method and antioxidant according to the present invention Functional water promotes the decomposition reaction of active hydrogen formed by the formation of active hydrogen in the hydrogen-soluble water through the process of catalysis and hydrogen-dissolved water, which can change the state of oxidation caused by the child or prevent oxidation. Antioxidant target ΐ f: j! I is in a sufficient state, and it can be expected to reach a high level of human safety or reduction of bad load. The antioxidation method, antioxidative functional water and its application of the present invention can be used in It has a wide range from acidic to alkaline, and uses a basic elimination function. Therefore, the present invention is expected to exhibit good release to μ. Therefore, the present invention is expected to be used in humans, human beings to ferment microorganisms, culture cells, and other living organisms. Obstacles, and especially look forward to the use of fertility pressure or aging Second, processing, preservation and other products or processes; cultivation, fermentation: cultivation, decomposition, corruption, fouling, odorization, 谇 quality requirements to prevent decline in variable energy rate Degradation or decrease in activity, decrease in effectiveness, and further, in food, feed, pharmaceutical field cosmetics, detergents, deodorants, sanitary products treatment: mouth, quasi-drugs, fragrance It can also be expected to be useful in various industrial fields such as wood or packaging containers, animal breeding, aquatic products: food supplies, freshness maintenance culture, etc., plant cultivation, fermentation, or if the user is provided with specific aspects of the present invention, This can be easily played and described below. Select a few cases from the product group. Page 37 2030.5943-PF (Nl); Chiunieow.ptd

-I V. Description of the invention (35) For example, in the field of food, eight types of functional foods are added 4 Do not use :: use :? It is provided with the removal of highly active oxygen to prolong and maintain the freshness of fresh foods. Σ = & quality improvement or preservation of water as a specific companion for the use of water as an active ingredient ^ provides the antioxidant function of the present invention to maintain health and prevent diseases: : Or health foods, used for vitamins for health management and to improve the feed efficiency or productivity of Im feed additives or pet associations. Article 2 of the Ministry of Health Law (Japan) stipulates that the fields of medicine, cosmetics and medical appliances not only-'kou: Fengyi Music Products, adding additives to improve the quality of preparations, 2000, 4, adding additives or cosmetics to improve, beauty Maintain and shake for 4 years as a disease treatment and prevention, constitution component. 1, t 筚. Effective diseases ensured by health status or rapid environment; K = to be used for active health-related health-related oxygen, gastrointestinal medicine, cold medicine, oral rhinitis, etc. ^ I ® 田 十 / 、、 在 柰Use tooth S, mouth cooling agent, medicinal chemical Γ, "Use Zibu underarm odor preventive agent and physiological products in the field of ί: ί? Also, 'cosmetics are used in hair cosmetics, shampoos; soil lotions , Cream, lotion, mask, foundation, lipstick, face wash, soap, toothpaste, etc. High usefulness. In addition to the above examples, the present invention can also provide various anti-oxidation methods and oxidative functions The specific aspect, and the implementation form and usefulness of the present invention are limited to the above examples. [Embodiment] The best form to implement the invention is 2030-5943-PF (Nl); Chiumeow.ptd Page 38 200413503 V. Invention Explanation (36) ΐ: Detailed description of the figure 2 of ίΐ5 according to the diagram. The basic water (hydrogen-soluble water) of water can be used to generate the structure of the antioxidant machine of the present invention. The original potential water generating device 411, which is a basic example of the reduction potential, is used as the introduction port for the reduction potential water generating device 111, and the original i 2 is formed on the 4 A + w to introduce pure water. Electrolyte 2 is formed between the outlets 112. The outlet is particularly restricted, but the reduction power 3 in this example is not on the bottom. The bottom surface of the outer box on the Fanmu water generation device 11 is formed in a direction perpendicular to the paper surface. On the top surface of the external phase 114, there is a lead-out port 112 which is perpendicular to the preferable electrolyzed water. Back (directions are formed one after another, porous porosity partitions are provided on the left and right side walls of the reduction potential water generating device 丨 丨 = 1.15, 'Outside the membrane 115, the electrode plates are each set as the electrode on the opposite side of the contact. The main surface of the plate 11 7 is provided in the electrolytic chamber 113 respectively facing the electrode plate 116 on the side. The two pairs of electrode plates 1 16 and 117 are connected to a DC power source (circuit) 12 and are opposed to each other with a diaphragm 115 sandwiched therebetween. One of the pair of electrode plates 116 and 117 is applied with an anode voltage and the other electrode plate is applied with a cathodic voltage. For example, when the reduction potential water is generated in the electrolytic cell 113, as shown in FIG. The electrode plate 117 in the chamber 113 is connected to the cathode of the DC power source 12, and the electrode plate 116 provided outside the electrolytic chamber 113 is connected to the anode. When the electrolytic oxidation water is generated in the electrolytic chamber 113, the electrode provided in the electrolytic chamber U3 The plate 11 7 is connected to the anode of the DC power source 12 and the electrode plate 11 6 provided outside the electrolytic chamber 11 3 is connected to the cathode. Μ 2030-5943-PF (Nl); Chiumeow.ptd Page 39 200413503

锢 Covering holes The electrode plates 116 and 117 used in this example are made of titanium on the whole surface, and are formed by firing a precious metal consisting of one or more combinations of two or more selected groups. As described later, the electrode plates 116 and 117 are dug with a plurality of needles. It is preferable that the diaphragm 115 used in this example has the property that the water flowing in the electrolytic chamber 13 can easily penetrate and the flowing water is difficult to drip. That is, the original potential water generating device is formed in the electrolysis in the diaphragm 115 itself and in the very small gap s between the membrane 115 and the electrode plate 116, and the current is caused to flow between the two electrodes 116 and 117 through the water film. . Therefore, it is an important issue to improve the efficiency of electrolysis by sequentially entering and replacing the water constituting the water film. In addition, since water leaking into the diaphragm 115 must be treated if it leaks between the diaphragm 15 and the electrode plate 16, the water content is relatively low so as to prevent the infiltrated water from dripping. However, when a solid electrolyte membrane is used as the separator, since the solid electrolyte membrane itself has electrical conductivity, it can be omitted to form a very small gap s between the separator 115 itself and the separator 1 15 and the electrode plate Π 6. ^ Diaphragm 11 is an example, for example, the aggregate material is polyester non-woven fabric or polyethylene film material is vinyl chloride or polyvinylidene fluoride, titanium oxide or polyvinyl chloride, etc., and the thickness is 0 · 03. Porous membranes with an average pore size of 0.05 to 5 〇 and a water permeability of 1.0 C / cm 2 .min or less, or solid electrolyte membranes. When a cation exchange membrane is used as the membrane, such as NAF ION membrane made by DuPont, based on polytetrafluoroethylene, and an ion exchange perfluorosulfonic acid membrane can be used. , Or a copolymer of cation-exchange vinyl ether and tetrafluoroethylene, such as Flemings, manufactured by Asahi Kasei. On the other hand, one pair of electrode plates facing each other with the diaphragm 1 1 5 facing each other

200413503 V. Description of the invention (38) The distance between plates 116 and 117 is 0mm ~ 50mm, preferably 15mm. Here, the distance between the electrode plates 1 1 6 and 11 7 is 0. This means, for example, that the electrode films directly forming the groove-free electrodes are used on the two main surfaces of the separator 5 and substantially have the thickness of the separator 115 Minute. The non-grooved electrode may be formed only on the main surface on the side of the separator 115. In the case of using such a grooveless electrode, it is desirable to provide holes or gaps for the gas generated from the surface of the electrode to escape to the back side opposite to the diaphragm 15 on the electrode plates 116 and 117. In addition, the composition of the holes or gaps provided on the electrode plates 116 and 117 can also be adopted in the electrode plate provided on the electrolytic cell as shown in FIG. 5.

The distance between the electrode plates 116 and 117 provided in the electrolytic chamber 113 is not particularly limited, but it is preferably 0.5 mm to 5.0 mm, and preferably 1 mm. When using the reduced potential water generating device of this composition to generate reduced potential water, firstly, two electrode plates 116 and 117 provided in the electrolytic chamber 113 are connected to the negative electrode (-) of the DC power source 12 and will be provided in the electrolytic chamber The two electrode plates 11 6 and 11 7 outside 1 13 are connected to the positive electrode (+) of the DC power source 2 and voltage is applied to the two pairs of electrode plates 116 and 117 through the diaphragm 115 respectively. In addition, pure water is introduced through the inlet 111 to cause the electrolysis chamber to perform water electrolysis, and 2H20 + 2e--20H- + H2 f is generated on the surface of the electrode plate 117 and its vicinity.

Response. In addition, on the surface of the electrode plate 116 outside the electrolysis chamber 113 across the diaphragm 115, that is, between the electrode plate i i 6 and the diaphragm 丨 5, a reaction of H20-2e-2ΗΗ 1/202 is generated. The H + ions are contained in the separator 115 while passing through a part of the H + ions.

V. Description of the invention (39) = The polar plate 117 contains electrons 6. It becomes hydrogen and dissolves in the human yin. By this, the cathode side (ie, the electrolysis chamber 113 ^ electrolyzed water; reduced potential water with a more original potential (ORP) than the electrolyzed water previously produced with the diaphragm technology. "Electrolyzed water has lower emulsification and 0H-two changes The excess H + after the membrane 115 is because the reduction potential water containing hydroxide ions generated by the two in the electrolytic chamber 11 3 is reliable and hopeful that the reduction potential water obtained by the electrolytic treatment is in the desired pH field. Sleep i 歹 1: PH buffers such as phthalates, phosphates, and borate can be used as ==, etc .: The pH value of the raw water can be adjusted first. Because the reduction potential of the raw water = the setting of 11 will not make the pH of the raw water It ’s changed a lot. Specifically, for example, if you want to deviate the pH because you want to use it as a substrate for washing or drinking, you only need to adjust the pH of the raw water near alkaline to manage and adjust it. ^ As a beverage, injection, drip solution or dialysate, if you want to keep the pH at about the middle of the day, you can adjust the pH of the raw water near neutral for management and modulation. Moreover, if you want to use it as makeup Material, if you want to make the pH weakly acidic, just adjust the pH value of the raw water near the weakly acidic Management modulation is sufficient. Incidentally, the above-mentioned embodiment describes the reduction potential water generating device shown in FIG. 5, but the device is also applicable to the case of generating oxidation potential water. In this case, the device Connect the two electrode plates 11 7 and 11 7 in the electrolytic cell 3 to the anode (+) of the DC power supply 1 2. At the same time, connect the two electrode plates 11 6 and 11 6 located outside the electrolysis 11 3 to DC. Cathode of power supply 1 2

2030-5943-PF (Nl); Chiumeow.ptd page 42 200413503 V. Description of the invention (40) (-), and the voltages can be added separately through the diaphragm 5. Two pairs of electrode plates 116 and 117 opposite to each other, and pure water or the like is introduced through the inlet 111, and is electrolyzed to generate a solution on the surface of the electrode plate 117 and its vicinity to H20-2e _- &2; 2HHl / 2 · 02 Response. In addition, on the surface of the electrode plate 116 outside the electrolysis chamber 113 with the diaphragm 115 interposed therebetween, a water film between the electrode plate 116 and the diaphragm 115 generates a reaction of 2H20 + 2e-20H-+ H2 t. The OH ion is passed through while being contained in the separator 115, and part of it receives electrons e_ from the cathode plate 116, and becomes oxygen dissolved into the anode side to generate electrolytic water. As a result, the electrolytic water generated on the anode side (ie, in the electrolytic cell 3) can become oxidation potential water having a higher oxidation reduction potential (0RP) than the electrolytic water generated using the diaphragm technology. Since the excess OH- ions after passing through the diaphragm 115 will react with the H + in the electrolysis chamber jig to return to water, the pH of the oxidation potential water generated in the electrolysis chamber 1 丨 3 will be slightly close to neutral. That is, it is possible to obtain oxygen octave water having a low pH but a high ORP. The oxidation potential water containing hydrogen ions thus generated is supplied from the outlet 112. Incidentally, using the reduced potential water generating device ij shown in FIG. 5, two electrode plates 1 1 7 and 11 7 provided in the electrolytic cell 11 3 are connected to the cathode (-) of the DC power source 12 and at the same time, the device The two electrode plates 11 6 and 11 6 outside the electrolytic chamber 113 are connected to the anode (+) of the DC power supply 1 2 (effective area of the electrode plate ldm2), and the pH is 7.9, 0RP + 4 7 3mV in Fujisawa. Tap water per minute

2030-5943-PF (Nl); Chiumeow.ptd Page 43 200413503 V. Description of the invention (41) The electrolysis condition of continuous flow-through electrolysis is carried out at a flow rate of 1 liter and a fixed current of 5 A. At this time, the distance between the electrode plates 116 and 117 of the diaphragm cation exchange membrane manufactured by DuPont Co., Ltd. as the separator 115 is set to be 1.4 mm, and the distance between the electrode plates 117 and 117 in the electrolytic chamber 113 is 1.4 mm. As a result, immediately after the electrolytic treatment, a reduction potential water having PΗ = 9.03 and ORP ^ 720 mV was obtained, and the reduction potential water was left to stand still, and the pH was measured after 5 minutes, 10 minutes, and 30 minutes. As a result of 0RP, pH = 8, 〇RP = -70 6mV after 5 minutes, pH 8.11 after 10 minutes, 〇RP = -7110mV, and pH = 8 〇2, 〇Rp = -7 after 30 minutes. 7mV. In other words, although the pH of the treated water exceeded 9 at a point in time immediately after the electrolytic treatment, the pH of the treated water soon decreased and stabilized near pH8. It can be considered that the H + ions generated in the vicinity of the water film between the diaphragm 115 and the anode 116 passed through the diaphragm 115 to the electrolytic chamber, and then neutralized with the OH-ions in the same electrolytic chamber 113 to return to water. The sum reaction is promoted at any time even when the reduction potential water after the electrolytic treatment is left standing until the chemical equilibrium in concentration is established. Reduction activity / free beauty activity evaluation test of hydrogen-soluble water added with noble metal colloid catalyst soil β f

In the following, when the noble metal gum (colloid / colloid) is added to the hydrogen-soluble water of the present invention, the reducing activity or free radical deactivation exhibited by activation of the weathered inactive molecular hydrogen contained in the hydrogen-soluble water is activated. ^ Valuation test, examples and reference examples. < Conjugation In the above two evaluation tests, the reduction activity evaluation test was based on the evaluation of chlorotetramethylsulfuryl chloride only; Ci6h18C1N3S · 3 (Η2〇)) as the antioxidant, dagger, and free radical elimination activity. The test uses the free radical DPM (1,2-diphenyl_2-trinitr & phenyl

200413503 V. Description of the invention (42) As an antioxidant

Here, the principle of evaluation of reduction activity when using methylene dreaming objects that belong to the category of redox pigments will be explained. The oxidation type $ = antioxidant liquid (absorption maximum wavelength; about 6 6 5 nm, the following right is "M Authoritarianism" "Each βτMMMβ" is called beer blue) and it appears blue, but it becomes a reduced methylene blue (colorless methylene blue), and the color will change from blue to colorless. The degree of reduction of the blue color was evaluated, and the tongue 0, ′ was the reducing power. In addition, the reduced form of osmium blue will produce white dimers due to its low solubility, but if reoxidized, it will become the original oxidized form of methylene blue with a u color. That is, the color reaction of the aqueous solution of osmium blue is reversible. Wen Cheng

In addition, the principle of reduction activity evaluation when DPPH free radicals are used as antioxidant targets will be explained. D P P Η free radical aqueous solution (absorption maximum wavelength '· about 520 nm, hereinafter sometimes referred to as "DPPH") appears deep red, When DPPH is reduced by the reduction of free radicals, 'dark red will fade. The degree of discoloration was used to evaluate the radical elimination activity ', that is, the antioxidant power. In addition, the color reaction of DPPH free water solution is irreversible. &

The description of the evaluation test intends to (1) evaluate the reduction activity of electrolytically treated water with the addition of methylene blue as the addition of platinum colloidal catalyst, and (2) use the coloration of methylene blue as the addition of platinum colloid / palladium colloidal catalyst. Evaluation of reducing activity of hydrogen-soluble water (degassing treatment + hydrogen sealing treatment), (3) Reduction of electrolysis-treated water (addition before electrolysis treatment / addition after electrolysis treatment) by adding a platinum colloid catalyst to the color change of methylene blue Activity evaluation, (4) Evaluation of the color change of DPPH free radicals as the antioxidant activity of electrolytically treated water with added platinum colloidal catalyst, (5) Evaluation of the color change of DPP free radicals as the addition of hydrogen dissolved water Gas treatment + hydrogen sealing treatment)

2030-5943-PF (Nl); Chiumeow.ptd Page 45 200413503 V. Description of Invention (43). (1) Evaluation of the reduction activity of methylene blue with the addition of platinum colloid catalysis㈠ Electrolytically treated water (1-A), the test procedure for the evaluation of reducing power will be a standard slow saline solution made by Wako Pure Chemical Industries, Ltd. ) And 9. 丨 8 (aqueous borate solution) are made of pH buffered aqueous solution with pure night phosphoric acid, respectively. The following two types of dilutions = "basic water 6_86", "basic water 9.18". Furthermore, 0.6 g of a 4% platinum colloid solution of Tian Dao ^ was dissolved in Wako Pure Chemical Industries (stock: 500mL · made solution is called "platinum reference solution, and platinum US ° pan-distilled water C (Pt) system Calculated from the formula C (Pt) = (K6x 0.04 / 500mL, which is another 48mg / mL ·. And, using the above two basic waters 6 86 and 918 and “turn base solution”, each of 4 kinds and 8 kinds of samples were prepared. Aqueous solution as shown below. Soil> i. Basic water (6. 86) ', ^ • Basic water (6.86) 1 4941 ^ Add uranium reference solution 61 ^ to platinum-containing colloidal solution iii • Basic water ( 6 · 8 6) Aqueous solution iv · basic water (6 · 86) after electrolysis treatment was added to 1 494mL to turn the reference solution 6mL into a platinum colloid-containing aqueous solution, and the aqueous solution was electrolytically treated v · basic water ( 9. 1 8) vi · 1494 mL of basic water (9.18) platinum standard colloid solution containing 6 mL of platinum-containing colloidal aqueous solution vii · basic water (9 · 1 8) aqueous solution vi ii · basic water (9 · 1 8) Add 1 mL of platinum reference solution to 1 494 mL to make platinum gel

2030-5943-PF (Nl); Chiumeow.ptd p. 46 200413503

The aqueous solution, and the aqueous solution after the electrolytic treatment of the aqueous solution are shown in Table 2 below. Table 2 Sample number Basic 7j ^ 6.86 Basic 7j C 9.18 1 ii iii iv V vi vii viii PH 7.0 7.0 7.1 7.1 9.1 9.1 9.1 9.5 9.5 ORP (mV) 186 186 -625 -624 130 130 -745 -745 Platinum concentration U g / L) 0 192 0 192 0 192 0 192 Temperature quotient. C) 20 20 20 20 20 20 20 20 20 In order to check the reducing activity of the aqueous solution of each sample of a total of 8 kinds from i to viii above, 350 mL of each aqueous solution was added with methylene blue (lg / L concentration) solution IjmL It was adjusted to 74 · 4 # μ, and the methylene blue absorbance (A589; absorbance at a wavelength of 589 nm) of each sample aqueous solution was measured with a spectrophotometer. (1-B); Disclosure of Reference Examples and Examples (Reference Example 1) The methylene blue absorbance (A589) of the aqueous solution obtained by adding methylene blue to the sample water i without added catalyst solution (basic water 6.86) was used as Refer to Example 1, and the results are shown in FIG. 6. (Reference Example 2) The sample solution ii was added with an aqueous catalyst solution (basic water 6.86 + platinum solution), and the methylene blue absorbance (A589) of the aqueous solution after adding methylene blue was used as Example 2 in the test. Illustration. Ma Dong (Reference Example 3)

200413503 V. Description of the invention (45) 6. 8 Sample solution of this place (A589) as reference example 3, / methylene blue absorbance of the aqueous solution after methylene blue (Example υ The results are shown in Figure 6. Xie Lu 3+ sample-this water, add catalyst electrolyzed water (basic water 6. 86 + electricity (Α5 ^ 9) as "quot: this: after adding methylene blue aqueous solution and its methylene blue absorbance CA 5 8 9) as Example 1 is applied, and the face is shown in Fig. 6. The comparison between the fruit and the reference examples 1 to 3 is shown in (Reference Example 4) The sample water v has no added catalyst aqueous solution (basic water 9.18) and its methylene For Blue Absorption ™, refer to (Reference Example 5) Add the catalyst aqueous solution (basic water 9 ·) 8 + platinum 2 to the sample water ^ and add the methylene blue absorbance (A589) of the aqueous solution after adding methylene blue as the reference example 5 ' The results are shown in Figure 7. 乂 (Reference Example 6) Sample water V 1 1 was added to the electrolessly treated water (basic water 6.86 + electrolytic treatment) without added catalyst. The aqueous solution of arylene blue absorbs the sound of arylene blue (A589) As a reference example 6, the results are shown in Fig. 7. (Example 2) Sample water vi ii was electrolyzed before the catalyst was added. + 18+ substantially water electrolysis platinum reference solution) were added an aqueous solution after its alkylene Yue blue blue absorbance (A589) as the embodiment 2, the results in Reference Example against Example 4 ~ 6

200413503 V. Description of the invention (46) The ratio is shown in Figure 7. (1-C); Examination of the Examples The comparison of Example 1 and 2 to $ ^ # of Examples 1 and 2 is compared with that of Reference Examples 1 to 6, and it can be compared, regardless of its PH: = The chemically treated water and the reference example only have the addition of a catalyst for electrolytic treatment: ^ Special: sexual reduction 'and whether it has a reducing activity of 1: 1 for methylene blue aqueous solution. In addition, the electrolytically treated water added with the catalysts 1 and 2 is transparent and bright. For example, the blue color of methyl blue disappears. In addition, Α 4 β & \ penetrates the moon and it can be seen that the blue color of Asia disappears. In addition, it is impossible to visually recognize methylene blue with the addition of catalysts such as 1, 2 and 6; visually confirming that a large amount of white lice / synthetic water can be used. Said 巳 / children (reduced methylene blue). () The color change of methylene jade is used to reduce the activity of hydrogen (2-A) by adding platinum colloid / palladium colloidal soluble water (degassing treatment + hydrogen sealing treatment) to the catalyst (2-A); ）) Manufactured by Wako Pure Chemical Industries, Ltd. t ^ # ^ lMTris-HCl (PH7.4) ^ mMTris-HCHpH; i〇V ^ Diluted by 20 times with distilled water manufactured by Wako Pure Chemical Industries, Ltd. ^

Tris-HCl in 50 mM strength. These two types of sparse pendulums are hereinafter referred to as "basic water 7.4" and "basic water 9.0". Tian dilute the water knife

A solution of 0.6% of the prepared palladium colloid solution, 0.6 g, dissolved in Wako Pure Chemical Industries, Ltd. == 500mL of distilled water is called "reference solution". In addition, the concentration C (Pd) of the palladium reference solution is calculated in the same way as the colloid. (1) = 0.6 × 0.04 / 500mL, which is 48mg / mL. Next, take 84mL of basic water 7.4 and 90.

2030-5943-PF (Nl); Chiumeow.ptd p. 49 200413503

The Γ / Λ solution of the two ΪΛ is prepared to contain 121.7 " concentration MB, 7.4 for water and 9.0 for basic water. Then take 50 mL of the basic water 74 containing 0 and each of them from their respective degassing bottles, and repeat the operation of 3: undersealing hydrogen in a straight line. This operation: 糸 is to remove gaseous components other than hydrogen in lice / valley water. Do not collect the fine basic water 7 4: Hydrogen 9.0 3mL each, and then put them in a closed system. 4 2 = Quartz colorimeter tube, and then measure the Dangming reference liquid and palladium reference. Liquid, Mori reference, mixed solution with Moore ratio of palladium reference solution

Change in absorbance of methylene blue at time (ΔΑ572; change in absorbance at wavelength 572nm). (2-B); Disclosure of Examples (Example 3) The amount of platinum reference solution added in MB-containing hydrogenated water (including MB basic water 7.4 + degassing treatment + hydrogen sealing treatment) is only to make the platinum colloid The change in absorbance (A57 2) of methylene blue in an aqueous solution at a concentration of 190 was taken as Example 3, and the results are shown in FIG. 8 and FIG. 9 respectively. (Example 4)

The amount of platinum reference solution in MB-containing hydrogen-containing dissolved water (MB-based basic water 9 · 0 + degassing treatment + hydrogen sealing treatment) is only the amount of platinum colloid solution whose concentration of platinum colloid is 丨 90 # g / L and its methylene blue The change in absorbance (A572) was taken as Example 4, and the results are shown in FIG. 8 in comparison with Example 3. The difference between each sample water in Examples 3 and 4 lies in pH. (Example 5)

200413503 V. Description of the invention (48) The amount of the reference solution in the MB-containing hydrogenated water (including MB basic water 7.4 + degassing treatment + hydrogen sealing treatment) is only used to make the platinum colloid concentration 95 Vg / L The change in absorbance (A572) of the osmium blue solution of the aqueous solution was taken as Example 5, and the results are shown in FIG. 9 in comparison with Example 3. The difference between the sample waters of Examples 3 and 5 lies in the platinum colloid concentration. (Example 6) In MB-containing hydrogen-containing water (MB-containing basic water 7.4 + degassing treatment + hydrogen sealing treatment), the amount of the reference solution was added only to make the palladium colloidal concentration of 444 "g / L of the aqueous solution The change in absorbance of methylene blue (A57 2) was taken as Example 6, and the results are shown in Fig. 10 and Fig. 11. (Example 7) Hydrogen-containing water containing MB (basic water containing mb 9.0 + degassing treatment + hydrogen) Sealing treatment) The amount of palladium reference solution added was only the solution with an palladium colloid concentration of 444 # g / L, and its methylene blue absorbance change (A57 2) was taken as Example 7. The results are compared with Example 6 and shown in the first 〇. In addition, the difference between each sample water of Example 6 and Example 7 lies in the pH. (Example 8) MB-containing hydrogenated water (MB-containing basic water 7.4 + degassing treatment + hydrogen sealing treatment) The amount of palladium reference solution added is only water that makes the palladium colloid concentration 丨 丨 i # g / L, and its methylene blue absorbance change (A57 2) is taken as Example 8, and the result is compared with that of Example 6 Fig. 11 shows the difference between the sample waters of Example 6 and Example 8 in the palladium colloid concentration. (Example 9) In MB containing hydrogen Dissolved water (including MB basic water 74 + degassing treatment + hydrogen sealing

2030-5943-PF (Nl); Chiumeow.ptd Page 51 200413503 V. Description of the invention (49) ί) Water: wide turn to the upper standard: a mixed solution with a reference solution with a molar ratio of about 1 ϊϋ 谷 ϋΓ solution The amount of addition is only to make the precious metal, mixed ⑷ $ 二 体> Chen degree is 160 "g / L, and the aqueous solution of methylene blue A57) is used as Example 9, and 矣 吉 果 is shown in (Example 1 0) ^ 10 121 The same mixed solution as in Example 9 was added to hydrogen-dissolved water (MB-containing basic water 90+) to make water 2 = night Λ into Λ only to make the metal mixed (ship + handle) colloidal concentration 丄 U ,: blue The change in absorbance (A572) was taken as Example 10, and the comparison between Example 9 and Example 10 is shown in Fig. 12. In addition, the difference between each sample water of Example 9 and Example 10 lies in pH. (Example 11) in The same mixed solution as in Example 9 was added to the MB-containing hydrogen-dissolved water (containing MB basic water 7.4 + degassing treatment + hydrogen sealing place) to make it into an aqueous solution, and the amount of the mixed solution was added only to mix the precious metals (platinum + The palladium) colloid concentration was 80 # g / L 'The absorbance change of methylene blue in the aqueous solution (A572) was taken as Example η, and the results were compared with Example 9 It is shown in Fig. 3. In addition, the difference between each sample water of Example 6 and Example 8 lies in the colloidal concentration of precious metal (platinum + palladium). (2-C); Examination of Examples Comparative Examples 3 and 4 Figure 8 shows MB reduction activity in hydrogen-soluble water with added platinum colloid at pH 7 · 4 and ρΗ9 · 0. According to the same figure, there is no significant difference in MB reduction activity due to different ρΗ, both of which Shows high Mβ reduction activity. The ninth graphs of Comparative Examples 3 and 5 show platinum colloidal concentrations of 95 // g / L and 95 //

2030-5943-PF (Nl); Chiumeow.ptd 200413503

G / L ^ plus colloidal hydrogen-dissolved water showed dragon reducing activity. According to this figure, when the pin colloid concentration is high, the MB reducing activity also becomes high. It can be considered that it is effective to increase the concentration of the platinum colloid in order to increase the MB reducing activity. First, compared with the tenth diagrams of Examples 6 and 7, MB-reducing activity was exhibited in hydrogen-soluble water in which Pl 7 · 4 and ρ 9 · 0 were added with platinum colloid. According to the same figure, it is not seen that there is a large difference in MB reduction activity due to ρΗ not, and both show high Mβ reduction activity. The eleventh graphs of Comparative Examples 6, 8 are shown in the platinum colloid concentration.

Hydrogen-soluble water with 444 # g / L added palladium colloid showed MB reduction activity. According to this figure, when the colloidal concentration is high, the MB reducing activity also becomes high. This is considered to be effective in increasing the palladium colloid concentration in order to increase the MB reducing activity. Compared with the eleventh figures of Examples 9, 10, the hydrogen-soluble water containing the noble metal (platinum + palladium) colloid added to ρΗ7 · 4 and ρΗ9 · 〇 showed Mβ reducing activity. According to the same figure, it is not seen that there is a great difference in the reducing activity of MB due to different pH, and both show high reducing activity of MB. Fig. 13 of Comparative Example 9, 11 in the precious metal mixed (platinum + palladium) glue = two " g / L and 16〇 " g / L No MB reducing activity. According to the figure, when precious metals are mixed (turned

B) MB reducing activity becomes higher when the colloidal concentration is high. This can be thought of as making M

If the two activities are increased, it is effective to increase the colloidal concentration of the precious metal (platinum + palladium) 疋. Evening MR: If Figure 8 (Examples 3 and 4; Tongue addition of platinum colloidal hydrogen-soluble water) and Figure 10 (Examples 6 and 7; Addition of palladium colloidal hydrogen to dissolve 7B) ） Comparison 'can understand that although the concentration of Examples 3 and 4

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It is low, but shows the same MB reducing activity as that of Examples 6 and 7. Furthermore, if the molar concentration (#M) of the two is compared, the platinum colloid is 0.98 and the palladium colloid is 4.17 // M, which is lower for platinum colloid. Therefore, it can be said that the platinum colloid is superior to the palladium colloid in the meaning that the MB reduction activity expected for the precious metal catalyst of the present invention can obtain the same MB reduction activity with a small amount of use. On the other hand, if Figure 8 (Examples 3 and 4; MB reduction activity of platinum colloidal hydrogen-soluble water) is added and Figure 丨 2 (Example 9; [〇; adding precious metal mixed (platinum + palladium) colloids Compared with hydrogen-soluble water (reduction activity of 0), it can be understood that both show good MB reduction activity. Comparing the molar ratio (#M) of the two to the colloidal colloid is 0.98 // M and the precious metal mixed (transposed + colloidal) colloid is 10 μM, which is about the same. Therefore, it can be said that the platinum colloid and the precious metal mixed (platinum + palladium) colloid are expected to have the MB reduction activity expected from the precious metal catalyst of the present invention. ^ (3) Evaluation of reduction activity of electrolyzed water (added before electrolysis treatment / added after electrolysis treatment) by adding a color change of methylene blue to a platinum colloidal catalyst (3-A); The test procedure of the reduction power evaluation was prepared in accordance with the above ( 1—A) 6.86 200 0 mL of the same basic water, and 4 mL of platinum reference solution was added to 1 000 mL of it to prepare about 1 liter of platinum colloid-containing basic water 6.86. Another 100OmL do not add platinum colloid. Based on this, about 1 liter of base water containing no colloid is prepared, and about 1 liter of base water containing platinum colloid t 6 6 8 6 is prepared. Secondly, two samples were subjected to electrolytic treatment to obtain electrolytically treated water (argon-dissolved water). Only 2.8 mL of each was taken and put into a quartz colorimetric tube that had been replaced with hydrogen in advance. Then the platinum reference solution and palladium were measured. Reference solution, platinum

2030-5943-PF (Nl); Chiumeow.ptd Page 54 200413503 V. Description of the invention (52) The mixed solution of the quasi-liquid and palladium reference solution with a molar ratio of about 1 was added to the quartz cuvette when the absorbent was blue Change (ΛΑ5 7 2; absorbance change at wavelength 572nra). Then, only a methylene blue aqueous solution lg / LO · 14mL which had been sealed with hydrogen gas previously degassed was added to the cuvette without platinum colloid. Place two more cuvettes in the spectrophotometer and wait. Next, add a platinum colloid solution with a concentration of 48 mg / L to a platinum colloid-free colorimetric tube 2 // L 'Add another methylene blue aqueous solution that has been degassed with hydrogen beforehand to the colorimetric tube containing the original colloid lg / LO · 14mL, and started to measure the two cuvette solutions with a spectrophotometer. In addition, the colloidal concentrations added to the two colorimetric tubes were respectively adjusted to about 182 // g / L. (3-B); Disclosure of Examples (Example 1 2) The catalyst was electrolyzed by adding a catalyst (containing BM basic water 6. 8 6 + platinum colloid before electrolysis) before the measurement. The minimum value of the blue absorbance (A5 72; absorbance at a wavelength of 572 nm) was taken as Example 12, and the results are shown in FIG. 14. (Example 1 3) The minimum value of the methylene blue absorbance (A5 72) from the beginning of the measurement to 30 minutes after the addition of a catalyst electrolytically treated water (including MB basic water 6.86 + addition of colloid after electrolysis) was taken as Example 13, and The results are shown in Fig. 14 as in Example 12. (3-C); Examination of the Examples Comparative Figures 14 and 14 of Example 1 show the period of platinum colloid addition (electrical

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Before or after solution treatment) the MB reduction activity of the electrolytically reduced water at different times. According to =, it can be understood that adding a platinum colloid before electrolytic treatment results in a higher 0 reduction ° activity. The reason is currently under investigation, but it is presumed to be caused by the fact that activated hydrogen, which is fundamental to the reactivation of MB, invalidates the oxides and other oxides in the electrolytically treated water. This is the treatment of activated carbon containing platinum colloid = raw water, and after electrolytic treatment, the dissolved oxygen concentration of the treated water is measured immediately after the electrolytic treatment, and it is derived from the result that the dissolved oxygen concentration of the electrolytically treated water is almost zero. Inference. Based on this, it is not limited to the example of electrolytic treatment, and it can be considered that during the hydrogen sealing treatment or the hydrogen bubble treatment, the treatment 2 addition catalyst (platinum colloid) does not oxidize the oxidizing substances such as oxygen from the viewpoint of obtaining a high MB reduction activity Force is invalidated) is better. In addition, in the case of adding reducing agent to the raw water to obtain hydrogen 1 water-holding capacity, it can also be considered that it is better to add platinum colloid to the raw water as described above from the viewpoint of obtaining a higher MB reducing activity. of. In addition, the chemical agent is not limited to platinum colloid, palladium colloid, or a colloid of colloids such as platinum colloid and palladium colloid. The addition of a catalyst before the treatment is preferred from the viewpoint of higher activity. # U) Use the color change of DPPH free radicals as the solution to evaluate the antioxidant activity of adding platinum colloid to catalyze water treatment (4-A); the test procedure for evaluating the antioxidant activity is the same as the preparation of the substance in (1-A) above, as Check the antioxidant activity of each of the eight sample water samples i to viii shown in Table 2. In 16 mL of each aqueous solution, add 4 mL of DPPH (0.16 g / L concentration) solution to adjust the DppH molar concentration to 81.15 (// M), and after adding DppH3 points,

200413503 V. Description of the invention (54) The photometer measures the DPPH absorbance change of each sample aqueous solution (ΔΑδΜ; absorbance change of wavelength 540ηη). (4-B); Disclosure of Reference Examples and Examples (Reference Example 7) The DPPH absorbance of the aqueous solution after adding DPPH to sample water 1 without added catalyst solution (basic water 6 · 8 6) has poor DPPH absorbance (△ M ") As a reference example 7, the results are shown in FIG. 15. In addition, the tDppH absorbance change (ΔA540) in the same figure indicates the difference between the absorbance of the sample (background value) and the absorbance of samples 1 to viii (AA540). Therefore, the change in absorbance (ΔA540) of the reference example is 0. (Reference Example 8) The sample solution ii was added with an aqueous catalyst solution (basic water 6.86 + platinum), and the DPPH absorbance change of the aqueous solution after adding DPPH ( △ "" is used as Reference Example 8 and the results are shown in Fig. 5 (Reference Example 9) Dppjj 初 夕 I was added to the sample water iu without added catalyst electrolytically treated water (basic water 6.86 + electrolytic treatment), The change in DPPH absorbance (40) of the water bath after fi is used as Reference Example 9 and the results are shown in Figure 5 (Example 1 4) Xie Lu 1 sample @ 本 其 水 Γ with a catalyst electrolyzed water (basic water 6 86+ D40) ^ if ^ DPPH ^ ^ ^ ^ ^ ^ DPPH ^ ^ ^ «(Reference Example 1 0) 2030-5943-PF (Nl); Chiunieow. Ptd Page 57 200413503 V. Description of the Invention (55) The DPPH absorbance of the aqueous solution after adding DPPH to sample-free water (with basic catalyst 9.18) was treated with sample water v (as reference example 10, the results are shown in Figure 16). Also, the dpph absorbance in the same figure The change (△ A540) indicates the absorbance of sample v (background value), which is different from the absorbance of samples i to viii. (^ 4540). Therefore, the DPPH absorbance change (△ A540) of Reference Example 10 is 0. (Reference Example 1 1) In the sample water vi, the catalyst is electrolyzed with water (basic water 9. 8 + platinum reference solution). Dpph absorbance change of aqueous solution after adding DPPH (△

A 5 4 0) is referred to Reference Example 11, and the results are shown in FIG. 16. (Reference Example 1 2) The DPPH absorbance change (ΛΑδΑΟ) of the aqueous solution after adding DPPH to the sample water vii without added catalyst electrolysis-treated water (basic water 9.18+ electrolytic treatment) was taken as Reference Example 12 and the results are shown in Figure μ . (Example 1 5) The DPPH absorbance change (△ A 5 4 0) of the aqueous solution after adding DPPH to the sample electrolyzed water (basic water 9. 1 8 + electrolytic treatment + platinum reference solution) added with sample water ν iii was used as The results of Example 15 are compared with those of Reference Examples 10 to 12 and shown in FIG. 16.

(4-C); Examination of the Examples The results of Examples 14 and 15 were compared with Reference Examples 7 to 12 and examined. Example 14, Compared with Reference Examples 7 to 12, the electrolytically treated water with the added catalyst of 15 showed specific elimination of the free radicals of DPPH and showed high antioxidant activity or free radical elimination activity. By the way

2030-5943-PF (Nl); Chiumeow.ptd page 58 200413503 V. Description of the invention (56) — mention that the platinum colloidal catalyst is added before electrolytic treatment. In addition, as shown in FIG. 5, although Reference Example 9 is electrolysis-treated water without the addition of a catalyst, it is still considered to have DPPH radical elimination activity. This is considered to imply that, in the electrolytically-treated water in which a high concentration of hydrogen is dissolved, depending on conditions such as pH, an antioxidant activity can be expected to be exhibited without the help of a catalyst. (5) Evaluation of the antioxidant activity of the hydrogenated water (degassing treatment + rat gas sealing treatment) with the addition of the color change of the DPPH radical as the catalyst, (5-A) 'Antioxidant activity evaluation test steps and the above (2- A) Similarly, prepare "basic water 7.4" and "basic water 9.0", and then take 40 6 // M DPPH solution and basic water 7.4 and basic water 9.0 each 5OmL 'to vacuum pump After degassing for 10 minutes, the operation of sealing with hydrogen for 10 minutes was repeated 3 times. The purpose of this operation is to remove gaseous components other than hydrogen from the hydrogen-soluble water. '' Take the DPPH solution sealed with hydrogen, 0.3 mL, 7.4 mL of basic water, 2.7 mL of basic water, and 2.7 mL of basic water each, and put a quartz colorimetric tube replaced with hydrogen in a closed system in a spectrophotometer. The change in DPPH absorbance (^ 4540; wavelength change at wavelength 540nm) of the former and those without the addition of a platinum reference solution in the same colorimetric tube were measured within 30 minutes. (5-B), the disclosure of the examples (Reference Example 1 3) The DPPH absorbance change of an aqueous solution containing no platinum reference solution in hydrogen-soluble water (basic water 7.4 + degassing treatment + hydrogen sealing treatment) (A54 〇) As Reference Example 13, the results are shown in Fig. 17.

2030-5943-PF (Nl); Chiumeow.ptd p. 59 200413503

(Example 1 6) The addition amount of Zhongyou reference solution with hydrogen / combined water (basic water 7.4 + degassing treatment + hydrogen sealing treatment) is only an aqueous solution with a colloidal concentration of i9 () # g / L. The change in absorbance (A540) of DPPH is shown in FIG. 17 as the result of Example 16 ′ compared with Example 13. The significant difference between Reference Example 13 and Example 16 is the presence or absence of the addition of a platinum colloid.参考 (Reference Example 1 4) Taking the DPPH absorbance change (A54〇) of an aqueous solution without adding a platinum reference solution in hydrogen-soluble water (basic water 9.0 + degassing treatment + hydrogen sealing treatment) as a case study example 1 The results are shown in Figure 18. (Example 17) The amount of platinum reference solution in hydrogen-dissolved water (basic water 9.0 + degassing treatment + hydrogen sealing treatment) is only the DPPH of an aqueous solution with a platinum colloid concentration of 19 # g / L. The change in absorbance (A540) was taken as Example 17, and the results are shown in FIG. 18 in comparison with Reference Example 14. The difference between Reference Example 4 and Example 7 is the presence or absence of the addition of a platinum colloid. (5-C); Examination of Examples The 17th figure comparing Reference Example 13 with Example 16 shows that in p Η 7 · 4 with or without the addition of colloids, the hydrogen-soluble water has d ρ ρ η Free beauty eliminates activity. According to the figure, there is no reference example 1 of platinum colloid 3; [4 can only see the change in absorbance to the degree of natural discoloration within the measurement time (30 minutes), but the conventional examples 1 and 1 7 containing colloid Obvious DPP (R) free radical elimination activity exceeding the degree of natural complexion was observed. No difference was observed in the radical elimination activity of j) ρ ρ η due to the difference in p Η.

2030-5943-PF (Nl); Chiumeow.ptd

200413503 V. Description of the invention (58) Hydrogen dissolution followed by the addition of the catalyst enzyme hydrogen kinase, and the reduction activity of the examples and reference examples were evaluated respectively. When the catalyst hydrogen kinase was added to the storage water, ^ = For the insoluble molecular hydrogen that is hydrogen-soluble in the present invention Activation of the "original activity" :: capacity f water: contained in the valence test with the addition of precious metal colloid hydrogen dissolved water. Reduction activity evaluation Similarly, the reduction activity of methylene blue was evaluated using the original oxidative pigment. The principle of reduction activity evaluation is the same as that described above in Guigui. This is the same at this time, and duplicate descriptions are omitted. The catalyst that belongs to the catalyst has been explained (6) The reduction activity of methylene blue is used as an additive catalyst — the reduction activity of water (degassing treatment + hydrogen sealing treatment) = stimulating mother magic valley deposit (6-A); The reduction activity evaluation test procedure is the same as the above (2-A). Prepare "basic water 7 4" and "beauty 0", and take basic water 7.4 and basic water 90 each from 84 companies, and add 1 each. Ϊ́ίϋ 之4 mL of ΓΛ solution, each prepared to a concentration of i2i.?mM of M-containing basic water 7.4 and basic water 9.0. Next, 50 mL each of 0% of basic water and 90% of US water were used. After degassing by vacuum pump for 10 minutes, the operation of sealing and filling with hydrogen for 10 minutes was repeated 3 times. The purpose of this operation is to remove gaseous components other than hydrogen from the hydrogen-soluble water. # 外 ， 将 浓 !! 2 5 " Hydrogen kinase was diluted 4 times with distilled water and put into 1 mL of microcapsules for use, and nitrogen (inert gas) was sealed in the same capsule to remove oxygen. " Take 3mL each of the heart-containing basic water 7.4 and basic water 9.0 that have been sealed with hydrogen obtained in this way, and put this into a closed system into a quartz colorimetric tube that has been replaced with hydrogen in advance. When the prepared hydrogen kinase solution is added to the quartz cuvette, the absorbance change of the osmium blue (AMK). 2030-5943-PF (Nl); Chiumeow.ptd Page 61 200413503 V. Description of the Invention (59) (6-B); Reference Examples and Disclosure of Examples (Example 18) to dissolve water in MB containing hydrogen ( 7. 4 + basic water containing mb + degassing treatment + hydrogen sealing treatment) After adding the hydrogen kinase solution prepared as described above to the ## L aqueous solution, its methylene blue absorbance change (A 5 7 2) was taken as Example 18, The results are shown in Figure 19. (Reference Example 15) The methylene blue absorbance change of an aqueous solution containing no hydrogen kinase solution in MB-containing hydrogenated water (including mb basic water 7.4 + degassing treatment + hydrogen sealing treatment) (A 5 7 2) As a reference example 15, the results are shown in FIG. 19 in comparison with the examples in Example 8. In addition, the difference between each sample water of Example 18 and Reference Example 5 lies in the presence or absence of the addition of a hydrogen kinase enzyme. (Example 1 9) The absorbance change of the osmium blue of the aqueous solution after adding the hydrogen kinase solution 10 prepared as described above to MB-containing hydrogen-containing water (containing mb basic water 9.0 + degassing treatment + hydrogen sealing treatment) (A5 72) is Example 9 and the results are shown in FIG. 20. (Reference Example 16) The absorbance change of osmium blue in an aqueous solution containing no hydrogen kinase solution in MB-containing hydrogenated water (including mb basic water 9.0 + degassing treatment + hydrogen sealing treatment) (A 5 7 2) As a reference example 16, the results are shown in FIG. 20 in comparison with the examples 9-9. The difference between the sample waters of Example 19 and Reference Example 16 is the presence or absence of the addition of a hydrogen kinase enzyme. (6-C); Examination of Examples

2030-5943-PF (Nl); Chiumeow.ptd Page 62 200413503 V. Description of the invention (60) Check, the results can be listed as 1 ^ 1 and compared with reference examples 15, 16 and compared with 15, 16 The agent hydrogen-soluble water was reduced with the reference example, and only the addition was known: iso 'can make methylene blue specific. In addition, there are examples of methylene chloride-containing nitrogen-soluble water showing high reducing activity. Examples: ι9ϊ; Γ: When blue is visually confirmed, only the blue of methylene blue is recognized: m-water is colorless and transparent And it can be seen that the blue loss of methylene blue is 4 = 151916 and it is impossible to store water visually ... visually confirms the use of redox color exaggeration > Article 7, the longitude and latitude emulsification reduction titration of dissolved hydrogen The concentration quantification method has been analyzed. The reduction potential of the electrolyzed water generating device 11 developed by the people = = Hydrogen: In the electrolytically treated water, the measurement is performed:-The factor is determined by using a total hydrogen meter. However, the summary here is based on the measuring principle of converting the electrochemical substance into a dissolved hydrogen concentration in a table manner in the electrolytic reaction using the apricot 1 虱 lice meter, which depends on external factors such as the water liquidity to be measured. If the value becomes pure, it will be stored in the electrolyzed == explained in the above example, the electrolysis treatment without adding a catalyst to the agent (even if an oxidation-type antioxidant object is added), the pigment will not appear. Changes, but if the catalyst is added to the electrolytically treated water, if the pigment is added to the electrolytically treated water, the pigment can be displayed on page 63. 2030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (61) _β SI includes: color change. That is, the redox reaction of the redox reaction can be visually recognized by the "color change of the electrolytically treated element solution with the addition of a catalyst. Asahara Haramotosu") During repeated trial and error tests, the electrolytically treated water of the agent of the present invention is maintained. The greater the reducing power; the color change of m-blue from blue to transparent and the methylene blue dye found that the catalyst tends to produce 11% of the rapid reaction. That is, the added redox maintains the reducing power and the I understand that when the color of the dipper system is reduced to the full color of ψ blue, the difference is the difference in reducing power when the color πϊϊ is high ^ ;: there is a certain phase between the reaction speed of the color change of the reduced pigment methylene blue Xiao in the related industry, the inventors, etc. thought that after the research # 9 through the oxidation ## main film, this quantitative analysis of the addition of catalyst electrolysis, the feasibility of the reduction reaction (solubilized hydrogen concentration). It has obvious antioxidative power. Regarding the realization of the concept, it was found that it can provide a method for chlorination. It can be used to isolate the external catalyst and the metal catalyst. The amount of hydrogen dissolved in the dripping amount 'is determined according to the concentration of the hydrogen dissolved water in the hydrogen dissolved water. The cylindrical container and the A: can be closed by one end and the other can be opened for piston movement. ; = Put; inserted into the above-mentioned cylindrical container, can be freely made of dumplings, and is a partition that can be operated by a stirrer with a stirrer. Country 2030-5943-PF (Nl); Chiumeow.ptd Page 64 200413503 V. Description of the invention (62) An air-tight test device that is isolated from the external environment, and in order to be able to inject liquid into the test water storage room separated by the closed end of the cylindrical container, the inner side wall and the pier in a state of being isolated from the outside, Any one of the closed end, the inner wall, and the plunger of the cylindrical container has a liquid injection portion. The quantitative analysis method may be modified to drop a predetermined concentration of a redox pigment solution into a quantitative test water in the presence of a precious metal catalyst, and the precious metal The catalyst replaces the drop of the coloring change end point where the redox pigment produces a reduction reaction and the coloring change end point of the color reduction reaction with the redox pigment produces a reduction reaction

Quantitative analysis based on quantity as a method to quantify the hydrogen concentration in the test water. X (B) The purpose of the experiment is to use the following experiments to confirm that the solution containing the added catalyst electrolysis solution is no longer showing a reducing color reaction solution ('the following right,' until The total dropping amount of the added methylene blue added is dissolved (: equivalent point). It is the standard for quantitative analysis. Aberdeen 11 / Chen (potential antioxidant power) (0 Actual effect ^ Quantitative analysis method of stored hydrogen concentration The summary is the actual effective amount of the hydrogen-dissolving oxidizing power when the catalyst is added to the chemically inactive molecular gas contained in the water for 定量 S analysis, that is, the reducing power (anti-DH (mg / L)) exhibited by quantified eight pounds. The colloid acts as a catalyst, the effective concentration of dissolved hydrogen = the original pigment, and the redox titration of the addition of catalyst gas = methyl blue as the oxygen blue.) Lice store water is subjected to methylene (D) experimental steps 2030-5943-PF ( Nl); Chiumeow.ptd Page 65 200413503 V. Description of the invention (63) The basic experimental procedure is to prepare a number of sample water (the measured values of the dissolved hydrogen concentration and other characteristics), and add the sample water to the catalyst (platinum colloid) At the same time The methylene blue drop treatment is performed, and whether there is a correlation between the actual value of the dissolved hydrogen concentration obtained from the total dropping amount of each methylene blue, etc., and the actual value obtained in terms of the dissolved hydrogen is compared and evaluated. If there is any Related, it can be considered that the quantitative analysis of the dissolved hydrogen concentration by methylene blue redox titration, and the fact that the key substance exhibiting significant antioxidant function is dissolved hydrogen can be objectively and properly verified. According to this basic consideration, first, prepare A 40-fold concentration platinum reference solution having a 40-fold concentration of the previously described platinum reference solution was prepared. The platinum content of the 40-fold-concentration platinum reference solution, the degree C (Pt) of the platinum, was calculated from the formula c (pt) = 24gx 0.04 / 500 mL. 192mg / L 〇 Then 'prepared an aqueous solution of osmium blue at a concentration of lg / L (volume concentration; 2677.4 // M) and an aqueous solution of osmium blue at a concentration of 10 g / L (volume mol concentration; 26773.8 // M) The preparation of two different concentrations of methylene blue is based on the hypothetical determination of the concentration of hydrogen dissolved in water and the addition of different concentrations of methylene blue to reduce the amount of this solution. As a result, the experimental precision can be expected.提 咼。 However, platinum reference solution The platinum concentration and the MB concentration of the methylene blue aqueous solution are not limited to this, and can be appropriately adjusted according to the imaginary hydrogen concentration in the water to be measured. Secondly, a 50-fold concentration platinum reference solution 50 mL prepared as described above is different from the concentration 50mL each of two kinds of aqueous solutions of osmium blue were taken into separate degassing watts, degassed by a vacuum pump for 10 minutes, and then the operation of nitrogen sealing was repeatedly performed to adjust the 40-fold concentration surface after nitrogen replacement. The reference solution is soluble in methylene blue

Page 66 200413503 V. Description of the invention (64) fluid. The purpose of this operation is gas composition. Next, the jack was put into an acrylic laboratory. The long axis of the hollow tube was configured to form the bottom surface, and the small-diameter circular plate formed the side wall so that the platinum reference solution or MB in the measurement water storage chamber was formed. The cylindrical liquid injecting part made of Solco is designed to put the measured water into the test bait without putting the tester in the water state to be measured. In addition, when the measured water of 40 devices was collected into a solution, after that, the test device borrowing a syringe was changed only to the measured water storage room, and the measured water was collected to remove nitrogen (inert gas) from each solution. In addition to the airtightness tester of 20OmL of measuring water and a stirrer for magnetic stirrer. This tester is a piston-type closed structure, which is made by placing an acrylic circular plate in the direction of an acrylic cylinder at the end of one end. The open side is smaller than the grip inside the tube. Extremely small movers move freely in the long axis direction. The tester's w-type tester is separated from the bottom surface, the inner side wall and the quilt by an external environment and can be injected with 40 times the concentration of liquid in an isolated state. The formed solution injection portion. In addition, the rubber stopper for the syringe needle insertion can be inserted and removed freely. At this time, when the test water containing chamber of the tester with this composition is removed, the test water is quietly injected into the test water storage chamber, and then the fixed water storage chamber generates a gas phase. In this way, the test room can be closed to isolate the external environment. The surface reference solution and methylene blue aqueous solution are put into the test chamber. 'Try not to generate a gas phase in the syringe to suck the needle. The rubber stopper plunger of the solution injection part gently injects the solution. In addition, the example of the horse disclosed in this section ’as long as it can meet the requirements of raw materials being gas-tight, isolated from the external environment, and the volume of the water storage chamber can be measured.

200413503 V. Description of the invention (65) Liquids can be cast in an isolated state from the external environment. The blender used in the mixer can be operated under various conditions, and it can also be appropriately used: His rice maker. / 、 From two people, put the magnet under the bottom surface of the tester in which the water to be measured is placed.

Take Pl: 5 and 5 mL of a 40-fold-concentration platinum reference solution with 1 mL of nitrogen that has been replaced with nitrogen, and then insert it into the water chamber to be measured and mix thoroughly. "着" The above-mentioned methylene blue water of a predetermined concentration which has been replaced with nitrogen gas is injected in a small amount successively with a syringe under the visual observation of the color change on the -side. If the amount of methylene blue is more than the amount of methylene blue, the methylene blue will be reduced to ..., t 'But when the amount of magenta blood solution is gradually increased, it is added] The magenta dish is from jade color to colorless Color change. If you use points, you can get 1-inch 邗 饧 寺 from the methylene solution of the aqueous solution of methylene blue. 饧 Methylene monitor / Chen degree and a meter I of the added methylene solution of blue water can be used to determine the dissolved hydrogen concentration of the measured water. . (E) Method for finding the effective concentration of dissolved hydrogen

s t ί, once the table does not calculate the derivation process of the effective dissolved hydrogen concentration DH 5 in the measured water, the meaning of the effective dissolved hydrogen concentration DH will be explained. First, in the following description, the volume of the water to be measured is set to 2 L, and the methylene-M aqueous solution in which the water to be measured is added has a methylene M matrix of W- / L). Furthermore, in order to reach the equivalent point of the methylene blue water bath, if the total 1 is A (mL), the total amount of methylene blue molecules added (B (m〇i)) will change.

2030-5943-PF (Nl); Chiumeow.ptd Page 68 200413503 V. Description of the invention (66) becomes B = N · A (// mol / Lx mL) = N · A (m // mo 1) ... ( Formula 1) If the chemical formula of the methylene blue molecule is set to * MBC1, and the chemical formula of the hydrogen molecule is set to Z ', the reaction of the colloid-activated hydrogen molecule and the methylene blue-based molecule in the aqueous solution can be expressed by the following reaction formula . H2 + MBC1 —HC1 + MBH (Reaction formula 1) Here, HC1 is hydrochloric acid, and MBH is reduced methylene blue. According to the reaction formula 1'1 Mole hydrogen molecule and 1 Mole methylene blue molecule react, will produce 1 Mole reduced methylene blue molecule. In order to explain the electron transfer, the reaction equation is divided into two equations as a semi-reaction equation and written as follows. H2 — H ++ (HH 2 e-) ... (half reaction formula 1) MB + + (H + + 2e_) —MBH… (half reaction formula 2) The meaning of half reaction formula 1 is that one mole of hydrogen molecule emits two moles of electrons, The meaning of semi-reaction formula 2 is 1 mole of methylene blue cation, that is, 1 mole of methylene blue, which accepts 2 moles of electrons. Here, 1 mole of hydrogen molecule is 2 gram equivalents because it emits 2 mole electrons, and 1 mole of methylene blue cation, that is, 1 mole of methylene blue, is 2 because it receives 2 moles of electrons. Gram equivalent. As a result, the hydrogen molecule and the methylene blue cation, that is, the number of gram equivalents of methylene blue are both 2 ', so the hydrogen molecule and the methylene blue molecule have a 1-to-1 reaction in terms of mole ratio. Based on this, the total amount of methylene blue B added to the water to be measured is also the total amount of hydrogen molecules consumed. Therefore, ‘set the total amount of hydrogen molecules to be measured (m # mol) to C, then

Page 69 200413503

Equation 1 gives C = B = N · A (m // mol) ... (Equation 2) Furthermore, the volume of the measured water is 2000 mL, and the measured water is actually the volumetric mole concentration I of the chlorine molecule I (mol / L) is obtained by dividing the mole number C (mol) by the volume ^ (1). 'H2 (mol / L) = C / 200 (m // mol / mL) = C / 20 0 (/ zm〇l / L) ... (Equation 3) Further, the unit is converted to mass concentration (g / L) If the equivalent hydrogen molecule concentration is used as D, the following ratio of hydrogen molecule h2 is ^ lmol / 2g two H2 (// mol / L) / D… (Equation 4) Substituting Equation 3 into Equation 4 then D: 2C / 20 0 (// g / L) = C / 1 0 0 (# g / L) ... (Equation 5) This is the effective concentration of the hydrogen molecule in 200 mL of the measured water. The mass concentration of the above-mentioned effective hydrogen molecule is in the microgram order, but when converting to the milligram order, it is only necessary to multiply the numerator and the denominator by 1,000 each. D 2 C · 1 0 0 0/1 0 0 · 1 0 0 0 (mg / L) = C · 1 0-5 (mg / L) ... (Equation 6) So, from the relationship of Equation 2, Equation 6 The mole number C of the hydrogen molecule can be replaced by the total amount B of the arylene blue, so Equation 7 will hold. D = N · A (m #mol) 10_5 (mg / L) ··· (Equation 7) From Equation 7, we can know that the mass concentration D (mg / L) of the effective hydrogen molecules contained in the water to be measured can be determined by The volumetric mole concentration N (mmol / L) of Isatis indigotica multiplied by the total amount (mL) of the solution of Isatis indigotica to be added to reach the equivalent point.

2030-5943-PF (Nl); Chiumeow.ptd Page 70 2U0413503 V. Description of the invention (68) Eight seeds (not measured in the skin, not only the knife (lice milk) produced in this test, but also the various 》 Baggong, the carbon of carbon dioxide (carbonic acid gas), etc. If the name of each milk molecule (oxygen) or dioxide is exemplified, it is divided into lice reduction reaction phase acid salt and hypochlorous acid. This 虱 σ has lice molecules, and hypochlorous must be used as an oxidant, except for 1; 8 ::: In the redox reaction, the main λα 1+ tablets are usually used. In the special case, it is not suitable for the helmet. In particular, as described here, h㈢ is used as an encounter agent in the test of Tian Yan Θ and methylene blood transporter. The preparation of J21 is used as a lice agent, which will not oxidize the sub-atomic blue into an oxidized sub-type. A basket ^ reduction, but said that the original type of methylene blue precipitation; methylene blue ..., or white methylene blue oxidized and changed back to the original CCP, the reduced type does not pass through methylene blue, active ^ Xi >, ^ Methylene i ° and 'because even if it takes quite 2 chlorine: two =: points: it will directly react with oxygen, etc. Blue reduction. B Figure 21 = Energy = equivalent of methylene aerobic molecules and other oxides, the amount of it, the coexistence of coexistent water to the equivalent amount of methylene halide :: $ lice knife set will be Consumption, and ^ Τ I π will also decrease with the amount of oxides. If this is considered, the hydrogen concentration of methylene g can be said to be subtracted from the dissolved [measured by dissolved T] Effective dissolved hydrogen concentration; Revised reference examples and examples of the gas concentration (F) in part f (Reference Example 17) The electrolyzed water generation device "mini with active slave filtration benefits" manufactured by Mitz Corporation Electrolytic ° bar with electrolysis range "4" at standard water volume

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t = alkaline electrolyzed water after continuous electrolysis treatment is used as the measured water, and = = 40 times the standard solution is poured into the measured water with a syringe. After stirring and mixing with a knife, one side is measured by visual observation. Under the change of water, a solution of methylene blue at a concentration of 1S / L (volume mole concentration; 2677. 4 // M) was injected into the water to be measured in a small amount by a syringe. The total injection volume of the same methylene blue aqueous solution up to the equivalent point was 1 mL, and the measured value of the dissolved hydrogen concentration DH obtained by substituting each value into the above formula 7 was 0.03 (mg / L). In this reference example 17, the measured values of one of the water correlation, redox potential (RPRPUV), electrical conduction, water temperature τ (0, dissolved oxygen concentration D0 (mg / L), and dissolved hydrogen concentration DH were measured. The actual measured value (mg / L) of the dissolved hydrogen concentration 讪 obtained in the above formula 7 is shown in Table 3, and the continuous measured value and actual value of DH are shown in Figure 23. In addition, on the day of measuring various physical property values The various types of instruments used in the field are the same as those described above. (Reference Example 18) The purified water that is treated with Fujisawa city water through an ion-exchange column made by Orugano Co., Ltd. is subjected to hydrogen gas. Bubbling treatment and cooling the temperature to 20 t: As the water to be measured, 1 mL of the platinum colloidal reference solution having a concentration of 40 times that of the above-mentioned atmosphere was replaced with 200 mL of the water to be measured. The cylinder was poured into the water containing chamber to be measured, and the mixture was thoroughly stirred and mixed, and the concentration of the measured water was visually observed on one side, and the concentration was 10 g / L (volume concentration; 2 6 7 7 3 · 8 μM) A solution of osmium blue is injected into the water to be measured with a small amount of syringe. The total injection amount of the solution of 6 · 2mL 'and the respective values are substituted into the actually measured value of the above formula is obtained within seven dissolved hydrogen concentration dh of 1. 66 (mg / L). This Reference Example 19 were measured for various physical properties related to water

200413503 V. Description of the invention (70) The values are shown in Table 3, and the measured and effective values of DH are shown in Figure 23. (Example 20) 'The basic water 6 of the sample water i above was subjected to continuous water electrolysis treatment at a flow rate of 5A per minute and a fixed current of 5A under electrolytic conditions. Water, and in 200 mL of the water to be measured, the above-mentioned platinum colloidal reference solution with a concentration of 40 times replaced with nitrogen was injected into the water chamber to be measured with a syringe, and the mixture was sufficiently stirred and mixed. After observing the color change of the water to be measured, a 10 g / L concentration (volume molar concentration; 2 6 7 7 3. 8 // M) aqueous solution of osmium blue was injected into the water to be measured with a small amount of a syringe. The total injection amount of the same aqueous solution of Isatis indigotica until the equivalent point was reached was 5.9 mL ′, and the values were substituted into the measured value of the dissolved hydrogen concentration DH calculated by Equation 7 above to be 1. 5 8 (mg / L). In this reference example, various physical property values related to the measured water are shown in Table 3, and the actual measured value and actual value of DH are shown in FIG. 23. (Example 21) The basic water 9 · 18 of the sample water v described above was subjected to continuous water electrolysis treatment at a flow rate of 1 liter per minute and at a fixed current of 5 A, and the electrolytically treated water was used as the measured water. In 200 mL of the water to be measured, the above-mentioned platinum colloidal reference solution imL having a concentration of 40 times replaced with nitrogen was injected into a test water storage chamber with a syringe and thoroughly mixed, and then visually observed on one side. Under the change in color of the measurement water, a 10 g / L concentration (volume molar concentration; 2 6 7 7 · 8 // M) aqueous solution of methylene blue was injected into the measured water with a small amount of a syringe. The total injection amount of the same methylene blue aqueous solution up to the equivalent point was 5.0 mL, and the values were substituted into the dissolved hydrogen concentration DH obtained from the above Equation 7. The measured value was 1.34 (mg / L). Various properties related to water measured in Reference Example 21

2030-5943-PF (Nl); Chiumeow.ptd Page 73 200413503 V. Description of the invention (71) The values shown in Table 3 are not shown in Table 3, and the actual measured values and actual results are shown in Figure 23 ("Implementing Example 2 2 ) = Wako Pure Chemical Industries, Ltd. standard buffer solution 4 · 〇1 (phthalein == 'Fenye) pH buffer solution diluted 10 times with purified water to j liters per minute: = 5 A below Continuous flow-through electrolytic sonication was performed under the conditions of fixed current electrolysis. The electrolyzed treated water was used as the water to be measured, and the above-mentioned water was replaced with nitrogen at a concentration of 40 times the platinum colloidal reference solution. After the needle was poured into the water containing chamber to be measured and fully mixed, the concentration of 10 g / L (volume Morr ice 2 6 7 7 3 · 8 // Μ) was observed on one side under visual observation of the color change of the water to be measured. A small amount of methylene blue aqueous solution is injected into the beaker I water with a small syringe. The total injection amount of the same methylene blue aqueous solution up to the equivalent point is 6.3 mL, and each value is substituted into the solution obtained by the above formula 7. The measured value of hydrogen concentration Dh is 1.69 (mg / L). This reference example 22 shows various water-related substances ^ The values are not shown in Table 3, and the actual measured values and actual values of DH are shown. Fig. 23 (Example 2 3) The basic water 6.86 of the above sample water i was subjected to continuous water circulation under the electrolytic condition of a fixed current of r 5 Α per minute 丨 liter flow rate (circulating water volume 乂 0.8 liter) ) Take 3 minutes of electrolysis-treated circulating electrolyzed water as the water to be measured, and at 200 mLt of the water to be measured, inject 1 mL of the above-mentioned nitrogen colloidal platinum colloidal reference solution with a concentration of 40 times into the measured water with a syringe. After fully mixing in the storage room, and visually observing the color change of the water to be measured, inject a small amount of 10 g / L (volume concentration; 26737 · 8 "M) of osmium blue solution into the syringe with a small amount. Measured in water. The total injection volume of the same methylene blue aqueous solution up to the equivalent point is 9.6 mL, and the values are substituted into

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The measured value of the dissolved hydrogen concentration DH obtained by the above formula 7 is 2. 57 (Reference Example 23: Various physical property values related to the measured water are shown in Table 3, and the measured value and actual value of DH are shown in FIG. 23. (Example 24) The basic water 9.18 of the sample water v was subjected to a continuous water circulation type (circulated water amount of 0 · 8 liters) at a flow rate of 1 liter per minute and a fixed current of 5 A for 3 minutes. Circulating electrolytically treated water after electrolytic treatment, and in 200 mL of the water to be measured, 1 mL of the above-mentioned 40-fold concentration platinum colloidal reference solution replaced by nitrogen was injected into the water containing chamber to be measured with a syringe and thoroughly stirred and mixed. Then, a solution of methylene blue at a concentration of 10 g / L (volume mole concentration; 26737. 8 "M) was injected into the water to be measured with a small amount of syringe under the color change of the water to be measured visually. The same amount of indigo blue aqueous solution has a total injection amount of 12.3 mL, and the dissolved hydrogen concentration obtained from the above formula 7)] JJ The measured value is 3. 29 (mg / L). The reference example 24 is water-related. Various physical property values are shown in Table 3, and the actual measured values and effective values of ⑽ are shown in Figure 23. (Actual Example 2 5) The same pH buffered aqueous solution as in Example 22 was used at a flow rate of 1 liter per minute and at a fixed current of 5 A under electrolytic conditions in a continuous water circulation type (circulated water amount of 0 · 8 liters) for 3 minutes The circulating electrolyzed water after the electrolysis treatment was used as the water to be measured. In 200 mL of the water to be measured, the platinum colloidal reference solution imL having a concentration of 40 times replaced by nitrogen was injected into the water containing chamber for the measurement with a syringe, and After fully stirring and mixing, visually observe the color change of the water to be measured, the concentration of 10 g / L (volume molar concentration; 26773.8)

2030-5943-PF (N1); Chiumeow.ptd Page 75 200413503 V. Description of the invention (73) The methylene blue aqueous solution is injected into the water to be measured with a small amount of syringe. The total injection volume of the same methylene blue aqueous solution up to the equivalent point is 12 · 4mL, and the values are substituted into the measured value of the dissolved hydrogen concentration DH obtained by the above formula 7 as 3 · 3 2 (mg / L) . Various physical property values related to the measured water in this Reference Example 25 are shown in Table 3, and the actual measured value and actual value of DH are shown in FIG. 23. Table 3 pH ORP [mV] EC [mS / m] Temperature T [ΐ] DO [mg / L] DH measured value [mg / Lj DH effective value [mg / L] Reference example 17 9.8 -171 17 21.6 2.67 0.18 0.03 Reference example 18 7.2 -623 99 21.2 0.02 1.34 1.66 #Examination case 20 7.0 -616 99 22.4 1.00 1.06 1.58 Reference example 21 9.2 -721 46 21.6 1.60 1.03 1.34 ~ #Examination case 22 4.5 -446 64 21.7 1.53 0.81 1.69 Reference example 23 7.1 -650 98 22.3 0.44 1.36 2.57 9.6 -764 54 22.3 0.45 2.20 3.29 4.7 -490 67 22.3 0.39 1.69 3.32 (G) The inspection of the examples is shown in Table 3 and Figure 23, because the DH measured value and effective value in dissolved hydrogen As the actual value becomes higher as the measured value becomes higher, it can be understood that there is a corresponding correlation. In addition, the DH actual value of the dissolved hydrogen concentration of Reference Example 18 and Examples 20 to 25 and the DH actual value of Reference Example 17 both showed high concentrations exceeding 1.3 (mg / L). In particular, the DH effective values for Examples 2 and 5 are shown in Example 2 with respect to the saturated dissolved concentration of molecular hydrogen water at normal temperature (20 ° C) and atmospheric pressure at about 1.6 (mg / l). Extremely high concentration of 2 · 5 ~ 3 · 3 (mg / L). Because the quantitative analysis test of dissolved hydrogen concentration used here uses water treated with activated carbon in advance (without adding reducing agent), and chlorine-based oxidizing substances such as hypochlorous acid are removed in advance, the residual in the water to be measured The oxidant can be considered to be mainly an oxygen molecule. In addition, even if the oxygen molecules are removed with activated carbon, once the measured water contacts the atmosphere, it will quickly dissolve into the water.

2030-5943-PF (Nl); Chiumeow.ptd p. 76 V. Description of the invention (74) Use of reducing agents to be active only However, it is difficult to remove tritium in the present invention. Only as long as the method developed by the applicant of the present application is applicable, the concentration is not increased as much as possible, and the = potential water generation device can be used to dissolve hydrogen and reduce the concentration of the emulsified substance of the milk 4 of the present invention as much as possible, and oxidize the functional water. Origin ...;: The combination of anti-drug agents is here, and it is important to try to be active against the gas of the present invention. The method of quantifying the dissolved hydrogen in reduced pigments is defined by the oxidative viewpoint of the present invention. The effective value of the gas / gas = the obtained dissolved hydrogen concentration M is better. If the value is greater than valley water, it will show 1.3 or more DH. Effective value, 1.8 or higher, 19 or higher 1.5 or higher, 1.6 or higher, 1 > 7 to 2.3 or higher, 2.4 or higher, 2 5.0 or higher, 2.1 or higher, 2.2 or higher, upper, 2 · 9 or more, 3 · 0 or more, upper, 2 · 6 or more, 2 · 7 or more, and 2 · 8 are all mg / L), and 1 or more, 3 · 2 or more, 3 · 3 or more (single Good. This is because it can be expected that the higher the effective value of the chlorine concentration in the valley of the present invention, the higher the antioxidant function of water. The idea of high water is for the determination of the hydrogen concentration in the hydrogen-dissolved water containing the method of lightning analysis and the treatment of the same hydrogen and water. The re-measurement of the apparent antioxidant capacity with respect to the two = ^ The measurement steps or procedures are as follows: the measurement of the dissolved hydrogen concentration by the hydrogen storage meter is fully satisfied, the cost is high, and the measurement accuracy is The concentration of dissolved hydrogen that can not be primed is often high. If the redox color used in the present invention can remove the measured water, its measurement steps or treatment are relatively simple, and the accuracy of the measurement is 7 6 < oxidized substances. point

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The reason is that the chemical reaction between the number of particles that permeate through the molecular hydrogen and the redox pigment is directly determined. Therefore, it has high precision and low cost. Evaluation Test of Free Radical Elimination Activity Using Adrenaline Oxidation Method in X0D Experimental System Next, a method for evaluating the free radical elimination activity using adrenaline oxidation method in XOD experiment system will be described below (A). In addition, the free radical elimination activity exhibited by the anti-oxidant functioning water (Anti Oxidant functioning Water (hereinafter sometimes referred to as rA0w)) used in the test method is to add a precious metal catalyst (platinum colloid / A palladium colloid / platinum palladium colloid) is taken as an example, and each of the following (B) represents an example and a reference example thereof. In addition, the X0D experiment refers to the improper use of xanthine oxidase (X〇D) to act on xanthine in an oxygen-soluble solution system, so that one of the oxygen emitted by the oxidation of kappa 17 shows that one of the oxygen is released. An experimental system (hereinafter sometimes referred to as "· Q〗-)" which is a super-emulsion anion radical by electron reduction (hereinafter referred to as "X0D experimental system"). (A) The free radical elimination activity evaluation test method using the adrenaline oxidation method in the X0D experimental system (A-1) The method for measuring free radicals of the longitude and latitude as envisaged is known, for example, "Free radicals and drugs" Guangchuan Bookstore (stock) Issue, ISBN 456749380X) Cytochrome c reduction method described in Nos. 1 33 to 141. This cytochrome c reduction method (see FIG. 24) uses a spectrophotometer to 'observe changes in the absorption maximum (wavelength of 55 nm) of oxidized cytochrome c over time' to determine the superoxide anion free radicals in the X0D experimental system (· Make oxygen

2030-5943-PF (Nl); Chiumeow.ptd Page 78 200413503 V. Description of the invention (76) Reduction of chemically modified cytochrome c (iron cytochrome c (Fe3 +) to oxidized cytochrome c (ferrous cytochrome to When the reaction of 2+) is blocked by a subject such as SOD or antioxidant, it uses the reactivity of a single electron reducing agent (· 〇2_). The measurement principle will be described in detail on the right. In the cytochrome c reduction method, In the case of (. &Quot; 〇2), the reduction reaction of oxidized cytochrome C is performed preferentially (or at the same time), = = oxidant and other subjects have eliminated (· 〇2_) reduction, then the oxidized cell color / original amount That is to say, the amount of reduced cytochrome C production will be suppressed (ascites cV slows down or tends to decrease). In this way, the reduction of cytochrome C will be reduced to a maximum of seven w (A55 0). If the element of time is also reduced The maximum absorption (A550) of the reduced-reduction type cytochrome C will be decreased by 1: 1, Ϊ, ί. The absorption maximum (A550) can be used to measure the SOD activity of the test subject. t 彳 1 丨 f ί Using the previous cytochrome c reduction method, such as class 0 activity was measured; the quality of the force: = Oxidative water, ascorbic acid, etc. have significant results, and when combined with the right subject, not only can't obtain high-precision measurement results. (.Θ〇- / I ΐ is the opposite of the original measurement results. This is the reason Or the reason why ascorbic acid is present. That is to say, the results of the present invention and the original scholars can be presumed to be because the full amount of (· 〇2-) was also repelled, and the excess reducing power reduced oxygen to two. In this way, not only the probiotic W ^ A soil, Tian I Bajing c suppress the original. For example, to lower the measurement results contrary to the original. Basic elimination activity evaluation ;: used in the present invention? Free of oxidation function water * '— Free radical reaction

200413503 V. Description of the invention ⑺) --- In the end, maybe the idea of reducing the adrenaline oxidation can be used. ▲ If reduced adrenaline is oxidized with a superoxide anion (· 〇 2_), it will turn into a red adrenaline pigment (oxidized adrenaline), and its absorption (A480) will increase. At this time, (d is used as an oxidant. Incidentally, reduced adrenaline is not easily oxidized by ordinary oxygen molecules, and even if it is oxidized, it does not show a red color reaction. That is, it is experimentally confirmed that reduced adrenaline Its absorption in the oxygen-dissolved solution (A48〇) will not increase. This means that the type of epinephrine is suitable for distinguishing ordinary oxygen molecules (〇2) and superoxide anion free radicals (D radical reaction) The test drug is used. The adenosine oxidation method (refer to Figure 25) first generates an appropriate amount (· (V) in the X0D experimental system. The generated (· 〇 2_) will be reduced to the oxidized adrenal gland. ^ ^ RH3- + · 〇2- + 2Η + — · rh3 + H202 • RH3 + 02 ~> RH2 + · 〇2- + h + RH2 + · 02- + H +. RH + H2〇2 • RH + 02 — R + · 〇2- + h + However, (RH3-) is a reduced adrenaline, (an oxidized adrenal gland (adrenal pigment). Reduced adrenal ^ ',. Glutenin and (· 〇2) in the physiological pH attached 〇2—) and reduced adrenal adenine === adrenaline can accelerate (. 轫 A A Jiang please; © Jing & 夂 2 夂 reaction Speed. This adrenaline oxidation method is a good method to set the reduced adrenaline I # ancient, g ^ diadrenaline molar concentration to about ImM " 2, reducing adrenaline can be observed There is a tendency to be oxidized due to, for example, iron ions. In order to remove the influence of external factors, it is necessary to co-exist the willow TA # chelating agent in the test solution. Bu Fa factor ~ page 80 2030-5943-PF (Nl); Chiumeow. ptd 200413503 V. Description of the invention (78) n If (· 〇 2) the reduction of adrenaline oxidation reaction preferentially (or ^ ^ agent advances, antioxidants and other subjects will be eliminated (· 〇 factory) reduction, then The amount of oxidized adrenaline, that is, the amount of oxidized adrenaline produced, will be inhibited by S2η. In this way, the absorption of oxidized epinephrine is greatly reduced, and the tendency will be relaxed. If the elements of time are also reduced, Taking into account, the absorption of oxidized f-adrenaline (A480) in each Guang'er will increase with 2 and decrease with Xiao 1. It can be measured by observation of absorption over time (A48〇). SOD activity (free radical elimination activity). The horizontal axis is the horizontal axis, and the absorbance (A480) is the vertical axis. Once the SOD activity can be expressed in terms of the absorbance (A48〇) and the distance (eight 480) per unit time (ΔΤ). That is, the slope of the graph (ZU / ΔΤ) can express SOD activity. Therefore, for the SOD activity diagram of the subject, when the slope of the SOD activity is large (the characteristic of the upper right slope), the SOD activity becomes smaller, otherwise, the SOD activity is positive. The smaller the tilt, the greater the SOD activity. However, from the viewpoint of high or low radical elimination activity, the radical elimination activity is relatively high compared with a small positive slope and a small negative slope. ^ The above is the measuring principle of free radical deactivation using the adrenaline oxidation method). Gu Fsheng UUJ) (A-2) test reagent activity) test • Wako Pure Medicine's free radical elimination activity of adrenaline oxidation method (sOD) The test reagents used are listed below. ① Dolbec phosphate buffer Physiological salt powder (pBS) · · Industrial ② Huang Hou Yin (2,6-dioxopurine) · · · Wako Pure Chemical Industries

2030-5943-PF (Nl); Chiumeow.ptd Page 81 200413503 V. Description of the invention (79) ③ Xanthine oxidase suspension (from cream) Manufactured by Tongren Chemical Research Institute · Heguang Pure ④ EDTA-2Na · 2 Manufactured by Shuwa Pharmaceutical Co., Ltd. ⑤1 mol / L Sodium Hydroxide Solution ··· Manufactured by Wako Pure Chemical Industries ⑥ L (+) -Ascorbic acid ··· produced by Wako Pure Chemical Industries ⑦ (±) adrenaline (d 1 -Adrenaline) The preparation method of the test reagents of Wako Pure Chemical (A-3) & The preparation methods of the test reagents listed in (A-2) above are as follows. ① Preparation of PBS buffered solution containing EDTA 500 ml of two bags of physiological salt powder (hereinafter referred to as "PBS") buffered with Dalbeccoic acid buffer were dissolved in 100 ml of distilled water and divided into two equal parts. "... Dissolved EDTA-2NaO. 19g. This was used as the EDTA stock solution. Take each of this solution as 0.5ml of stock solution, 49.5ml of EDTA-free solution and mix. The resulting mixed solution was EDTA-containing (1.9mg ) PBS buffer stock solution. In terms of PBS concentration, it is a 10-fold dilution. If there are multiple metal ions in the test water, the EDTA stock solution can be directly diluted 10-fold for use. In this case, the EDTA concentration is south. Removal of metal ions that cause the decrease in measurement precision. In addition, the purpose of preparing PBS buffer solution containing EDTA is to fix the pH of the solution to about 7 · 4 of physiological fluidity and prevent the measurement precision from decreasing due to metal ions. ② Preparation of 1.5 M xanthine solution Xanthine = 0.228 g and 0.23 g and 1 (mol / L) sodium hydroxide aqueous solution 80 drops was added to distilled water 3 50 m 1 and the yellow sigma was dissolved. Take 3 5 ml 1 and add EDTA-containing PBS buffer solution to make up 100ml.

2030-5943-PF (Nl); Chiumeow.ptd Page 82 200413503 V. Description of the invention (80) ③ The preparation of xanthine oxidase solution will be carried out to make the oxidase suspension in PBS buffer solution containing EDTA Dilute 100 times. This test solution should be prepared each time an experiment is performed. ④ Preparation of epinephrine solution ^ Put the stirrup and 100 ml of distilled water into a vial and stopper the rubber f ′ pierce the injection needle used and the injection needle connected to the nitrogen high-pressure cylinder into the rubber capsule. In this way, leave the Jiangren # ^ ^ m 4,… Place the vial of 3 distilled water on the stirrer table, while pouching ^ & milk into the distilled water, so that the inside of the distilled water completely replace the epinephrine, cover-treatment is carried out 30 minutes. After that, ‘15 g of kidney preparation A was put into a lid ’and slowly stirred with a stirrer’ to seal the nitrogen gas. This nitrogen chaos replacement performance is performed every time. The emphasis is on adding "only the end of inspection. The above is the adjustment of the adrenaline solution. Before the adrenaline is given, it is strongly taught to add xanthine oxidase (XOD) in the XOD experiment of adding the adrenaline (A-4) test sequence, and then add the XOD to the chamber in reverse order. After taking all the test drugs and the tested aqueous solution

Should be started at the same time as R, but the previous method i / is also called ~ < (· 〇2 ~), at which time the milk is not sufficiently formed when the test solution is added. In other words, the raw material for (· 〇 2) is still changed from the oxygen molecule to (· 〇 2) so that ('because the oxygen atom will not be obtained immediately from the time when X0D is added, / 〇 2) The amount of production is increased, so after the addition of the test solution, the dissolved oxygen of the raw materials is generated. 2) Xiang Dan ^ a, of ® are not being paid attention to, and $ is measured with a spectrophotometer (· 〇-) ' In the previous method (· 02 a), I am not sure whether it is generated every time

Page 83 200413503 V. Description of the invention (81) f ^ In these cases, it is preferable to add the EDTA 2pBS buffer solution, yellow throat solution, xanthine oxidase solution and distilled water for oxygen to the chamber and mix them first. After a period of time, that is, after the appropriate amount of (· (V) is generated, the test water and the adrenaline solution are added and the measurement is started. Therefore, the adrenaline oxidation method is based on the following test solution And the test water is sequentially put into the chamber. Also, the standby time is set as required. The volume of the chamber is 3ml, of which the test water and the oxidized distilled water each account for about 1/3 'The remaining 1/3 is the pH containing EDTA Buffer solution, xanthine solution, xanthosin oxidase solution and epinephrine solution, τ ① Add PBS buffer solution containing EDTA 30 0 // 1. ② Add xanthine solution 3 〇 ##. ③ Add oxygen The distilled water used is 9 00 ^ 1 (approximately 1/3 of the chamber volume). ④ Add xanthine oxidase solution 1 0 〇 // 1. ⑤ In order to generate an appropriate amount (· 〇2_), wait 5 minutes. ⑥ Add Tested water (liquid) 1 m 1 (approximately the volume of the chamber 1/3 volume) ⑦ Add epinephrine solution 4〇〇 # 1. ⑧ Quickly begin to measure the change in absorbance (A48 0) over time with a spectrophotometer. ⑨ To reconcile the difference in local concentration distribution of the test reagent in the chamber, wait 丨 4 〇 seconds. In other words, 'In principle, the measurement data from the measurement of radical elimination activity described later from the start of the measurement to the passage of 140 seconds is removed. The observation time of the change over time excludes the above-mentioned standby time ⑨ 40 seconds, set It is 15 minutes. This is because the elimination activity of free radicals between platinum and palladium cannot be seen in about 5 minutes or 10 minutes.

2030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (82) The obvious difference is again: through experiments, you can understand that even if you add yellow sigmaoxine oxidase at the end, you will be jealous of each test drug. All of them can to some extent grasp the elimination of free radicals: / reactions and determinations, or they have an appropriate tendency to generate soil in the X0D experimental system in advance. However, the method of the test solution is preferred, and it is possible to grasp the tendency of adding the solution after every 2). In addition, although the previous method takes a long time due to the generation of xanthine & di: base elimination activity, it takes a long time, and it is different, but it is difficult to verify the free radical elimination activity of water and the like. In ft time, it is necessary to grasp the difference in catalyst activity between Ji and Ji. In the previous method, it is necessary to grasp the factors of the business affairs. The example of the waiting time is set in the X0D experimental system. Examples and reference examples using the adrenaline oxidation evaluation test method are disclosed. I radical elimination activity (Reference Example 19). Distilled water (made by Wako Pure Chemical Industries, Ltd.) is used as the test water. In this regard, the sequential radical elimination activity data is referred to as Reference Example 19 and incidentally, this Reference Example 1 9 > y # 、 士 丄 ^ X 151 ^ ^ ^ ^ According to different page descriptions, the activity of free radical elimination between test strips of licease will be 4b. " Waiting 1 ^ batch- (Reference Example 20) Replace the distilled water (made by Wako Pure Chemical Industries, Ltd.) with hydrogen lice as the test water, and use the free radical elimination activity data in the same test sequence as 1 ί as ^ 歹 ·. Incidentally, the number of radical elimination activities of this Reference Example 20, page 85, 2030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (83) " '" " According to Reference Example 1 9 Similarly, when the test conditions of xanthine oxidase from different manufacturing batches are used, sometimes the radical elimination activity characteristics between manufacturing batches may be slightly different. (Example 2 6) The deactivation data of the platinum colloid concentration of 48 # g / 1 was added to the steamed water (manufactured by Wako Pure Chemical Industries, the same below) to the platinum colloid concentration of 48 # g / 1 as Example 2 6. (Example 2 7) The same platinum as in Example 26 was added to distilled water (manufactured by Wako Pure Chemical Industries, the same below), and the platinum colloid concentration of 96 // g / l of hydrogen was used to replace Aow as the test. Water was used in Example 27 as radical elimination activity data in the same test sequence as in Reference Example 26. Isolation of soil (Example 28) The same platinum reference solution as in Example 26 was added to steamed water, and A0W was replaced by hydrogen with a platinum colloid concentration of 192 # § / 1 as the test water, which was the same as that in Example ^ Example 26. The radical elimination activity data of the test sequence was used as Reference Example 28. Evening (Example 2 9) The same platinum reference solution as in Example 26 was added to steamed crane water, and hydrogen at a concentration of 384 // g / i was used to replace Aow as the test water. The test sequence was performed with radical deactivation W. Case 28. Yao Pei as a reference (Example 30)

200413503 V. Description of the invention (84) Add the same platinum matrix with a concentration of 768 # g / 1 of hydrogen as in Example 2 6 in distilled water to replace Aow as the test water. The test sequence was carried out for free radical elimination hydrazone, Example 30. The ant puppet was taken as an example (Example 31). The palladium reference solution described in Examples 6 to 8 was added to distilled water, and hydrogen at a colloidal concentration of 48 // g / i replaced Aow as the test water. 9 The number of free radical elimination activities carried out in the same test sequence. Wear it as a practical example (Example 3 2) Add the same palladium reference solution as in Example 31 to distilled water, and replace Aow with hydrogen at a body concentration of 96 / zg / 1 as the test water. The radical elimination activity data of the same test sequence were used as in Example 32. ... Ling She (Example 3 3) The same palladium reference solution as in Example 31 1 was added to distilled water, and hydrogen at a palladium colloid concentration of 192 / zg / 1 was used to replace Aow as the test water. In the same test sequence, the free radicals and elimination activity data were used as Example 33. (Example 34) The same palladium reference solution as in Example 3 丨 was added to distilled water, and A0w was replaced by hydrogen having a palladium colloid concentration of 384 // g / 1 as the test water, which was the same as that in Example 31. The test sequence of the radical elimination activity data was used as Example 34.

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(Example 3 5), ... JC was added with the same periodical concentration as 768 // g / 1 of the same period as in Example 31. Anwida and Shangshangping were used to reduce the absolute moon & tick A0W was replaced as the test water, and in each case 31, the same test was performed with Chuan g & The order-free radical elimination activity data is taken as an example (Example 36). The distilled water was added to the case. The applicant made the granules based on the above-mentioned difficult "producing and using method" as the basis: points; Colloidal solution, so that the colloidal concentration is 66 = A0W as the test water, and the toilet goes to M 0 丨, Menla ^ l milk replacement ^ Xing Reference Example 19 The free radical elimination activity data in the same test sequence as implementation Example 36. (Example 3 7) The same platinum reference solution as in Example 36 was added to distilled water, and the AQW was replaced by hydrogen with a molybdenum concentration of 96 //, g / l as the test water, in the same test sequence as in Example 36. The free radical elimination activity data was taken as Example 37 (Example 38). The same platinum reference solution as in Example 36 was added to distilled water, and the platinum colloid concentration was 144 // g / 1 of hydrogen to replace Aow. As the test water, the radical elimination activity data in the same test sequence as in Example 36 was used as Example 38. Only (Example 3 9) The platinum glue was used. The distilled water was added with the same platinum reference liquid concentration of 192 / zg / 1 as in Example 36 to replace Aow as the test water.

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Example 36 6 uses the same test procedure as Example 39. (Example 40) The data of the radical elimination activity carried out were taken as the same platinum reference solution as in Example 36. A0W was replaced by the flip gas as the test water, and the data of the radical elimination activity carried out during the implementation was distilled water Add a gas concentration of 384 // g /; [Ziqi Example 3 6 Example 40 in the same test sequence. (Example 4 1) Example 41 was carried out in the same test sequence as adding hydrogen with distilled water at a concentration of 768 // g / i. (Example 42) Example 3 6 The same platinum reference solution was used, and platinum glue was replaced with A0W as the test water, and the free radical elimination activity data as the actual implementation was added in distilled water to be the same as in Example 26. The reference solution is prepared by mixing with a molar ratio of 1: 2 (Si + Ji colloid ', with a colloid concentration of 96 " g / 1 as a gas-gas replacement platform as the test water and / Examination Example 19 The same test Sequential free radical elimination activity data is taken as Example 4 2. (Example 43) The same (platinum + palladium) mixed colloid as in Example 42 was added to distilled water to replace the colloid concentration with 192 // g / 1 of hydrogen Aow was used as the test water, and the radical elimination activity data performed in the same test sequence as in Example 42 was used as Example 43. (Example 44)

Page 89 200413503 V. Description of the invention (87) Add the same (platinum + palladium) mixed colloid as in Example 4 2 to distilled water, and replace the a0W with hydrogen at a colloid concentration of 384 / zg / 1 as the test water. The data of radical elimination activity performed in the same test sequence as in Example 42 were used as Example 44. (Example 4 5) The same colloid (platinum + palladium) mixed colloid as in Example 42 was added to distilled water, and hydrogen at a colloid concentration of 768 // g / 1 was used to replace Aow as the test water. Example 2 2 The data of radical elimination activity carried out in the same test sequence were taken as Examples 4 and 5. (Example 46) A platinum (palladium + palladium) mixed colloid prepared by adding a platinum reference solution similar to that in Example 26 to a palladium reference solution similar to that in Example 31 and a palladium reference solution prepared in Example 31 at a molar ratio of 5: A0w was replaced by hydrogen at 144 / zg / 1 as the test water, and the radical elimination activity data in the same test sequence as in Reference Example 19 was used as Example 46. (Example 4 7) The platinum reference solution and the prepared (turned over + put) mixed replacement A0W as the radical deactivation of the test line were added in distilled water to add the same palladium reference solution as in Example 2 6 Example 3 1 Molar ratio 丨: 丨 was used to mix the colloids so that the colloidal concentration was 240 / zg / 1 of hydrogen & fixed water 'as in Example 46. Progressive data in the same test sequence was used as Example 47. (Example 4 8)

2030-5943.PF (Nl); Chiumeow.ptd Page 90 ZUU4U ^ 〇3 V. Description of the invention (88) 2 body = colloid A hydrogen with a degree of 336 // g / 1. * As the test results: ί 摅; Γ: The radical elimination activity data of the same test sequence was used as Example 48. (Example 4 9) = Add distilled water with the same reference solution as in Example 26 and implementation 3 = sample of the "liquid" solution mixed at a molar ratio of 1:20 3 body ^ colloid concentration of 432 " g / The hydrogen substitution A0w of 1 was used as the free radical elimination activity data of the test in the same test sequence as Example 4 9. (Example 50) X distilled water was added with the same platinum reference solution as in Example 26 and The reference solution was prepared by mixing the reference solution with a molar ratio of 1:25 (start + handle) and mixing with three bodies. The colloidal concentration of 528 // g / 1 of hydrogen was used to replace Aow as the test example 46. The data of the radical elimination activity carried out in the test sequence was taken as Example 5. (Reference Example 2 1) The test sequence of one f / loading sequence in (A-4) was changed when the water was distilled using nitrogen and the water was distilled. The free radical elimination activity data is used as reference example 21. The second test: the part of the sequence change is the part in which the lutein solution 300 and the Π oxidase solution 100 / U are added in the test chamber, that is, the replacement is removed (.G2_) generation system ', and the steam supply water for oxygen supply was increased from just 1 to 1 3 0 0 / z 1. (Example 5 1) Distilled water was added in Example 26 was mixed with the same embodiment of a platinum reference

2030-5943-PF (Nl); Chiumeow.ptd page 91 200413503 V. Description of the invention (89) " Example 31 The same palladium reference solution was prepared by mixing (platinum + palladium) mixed colloid with a molar ratio of 5: The hydrogen with a colloidal concentration of 144 // g / l was used to replace Aow as the test water ', and the radical elimination activity data measured in part of the test sequence described in (A-4) was changed as Example 5 丨. The above-mentioned test sequence is changed in the same manner as in Reference Example 21. (Example 52) A platinum reference solution similar to that of Example 26 and a palladium reference solution similar to Example 31 were added in distilled water to prepare a (platinum + palladium) mixture at a molar ratio of 1:10, and the colloid was formed. The concentration of 240 was replaced by g / 1 hydrogen as the test water, and the radical elimination activity data in the same test sequence as in Example 51 were used as Example 5 2. (Example 5 3) The same platinum reference solution as in Example 2 6 was added to distilled water and the palladium reference solution was the same as in Example 31. Molar ratio 丨 · 21 5 was mixed to prepare (platinum + palladium) mixed = colloid Let A0w with hydrogen at a colloidal concentration of 336 # g / 1 be used as the test water, and the data of radical elimination activity performed in the same test sequence as in Example 51 as Example 53. (Example 5 4) In a distilled water, a platinum colloid (platinum + palladium) mixed with a platinum reference solution similar to that in Example 26 and a palladium reference solution subjected to the same implementation at a molar ratio of 1:20 was added to make the colloid. The hydrogen substitution Aow at a concentration of 432 " g / 1 was used as the test and the free radical elimination activity data of Example 51 were performed in the same test sequence as Example 54. (Example 5 5)

200413503 V. Description of the invention (90) '---- Add the same platinum reference solution as in Example 26 and the same palladium reference solution as in Example 31 in distilled water to mix with Molar ratio 丨: 25 (platinum + Palladium) was mixed, and a colloidal concentration of 528 # g / 1 of hydrogen was used to replace Aow as the test water, and the radical elimination activity data in the same test sequence as in Example 51 were used as Example 5 5. (Reference Example 2 2) A standard buffer solution 6.86 (Phosphate saline solution) manufactured by Wako Pure Chemical Industries, Ltd. was diluted with a pure water to a pH buffered aqueous solution (basic water 6.86). As the test water, the radical elimination activity data of the test water according to the test sequence described in (A-4) was taken as Reference Example 22. (Reference Example 2 3) The same basic water as in Reference Example 2 2 6 · 8 6 was subjected to continuous water electrolysis at a flow rate of 1A per minute at a fixed current of 5A, and the electrolysis treatment was performed without added catalyst. Water was used as the test water, and the radical elimination activity data of this test water in the same test procedure as in Reference Example 22 was used as Reference Example 23. (Example 5 6) Take 6.86 1 liter of the same basic water as in Reference Example 22, add the same reference solution as in Example 2 6 to make the degree of Han 4 4 // g / 1 to prepare the basic of colloid containing platinum Water 6.86. This prepared platinum colloid-containing basic water 6.86 was subjected to continuous water electrolysis treatment under the same electrolytic conditions as in Table Examination Example 2 3, and one electrolytic treatment water was added as the test water before making the catalyst (A0W ). The free radical elimination activity data of the test water in the same test sequence as in Reference Example 22 was taken as Example 56.

200413503 V. Description of the invention (91) (Example 5 7) Take the same basic water as Reference Example 2 2 6 · 8 6 1 liter, add the same platinum reference solution as in Example 2 6 to make the concentration 9 6 // g / 1 to prepare basic water containing platinum colloid 6 · 8 6. This prepared platinum-colloid-containing basic water 6. 8 6 was subjected to continuous water electrolysis treatment under the same electrolytic conditions as in Reference Example 2 3, and one electrolytic treatment water was added as the test water before making the catalyst (A0W ). The free radical elimination activity data of the test water in the same test sequence as in Example 56 were taken as Examples 5 and 7. (Example 5 8)

Take 6.86 1 liter of the same basic water as in Reference Example 22, and add the same platinum reference solution as in Example 2 6 to a concentration of 9 2 # g / i to prepare basic water 6.86 with platinum colloid. This prepared platinum colloid-containing basic water 6.86 was subjected to continuous water electrolysis treatment under the same electrolytic conditions as in Reference Example = to prepare a catalyst, and one electrolytic treatment water was added as the test water (A⑽). The free radical elimination activity data of this test tritium water in the same test sequence as in Example 56 were used as Example 58. (Example 5 9)

Take 6.86 i liter of the same basic water as in Reference Example 22, and add a platinum reference solution with the same quality as that of reference 6 to a concentration of 384 " g / 1 to prepare a platinum-containing colloid η ^ The basic water of platinum colloid 6.86 was subjected to continuous water electrolysis treatment under the conditions of Γ: 丨 二 = Λ solution, and made & two t two two electrolysis treated water as the test water (a〇w). In Example 56, the radical elimination data of the same test sequence were used as Examples 5-9.

2030-5943-PF (Nl); Chiumeow.ptd Page 94 200413503 V. Description of the invention (92) (Example 60) Take the same basic water as 6.86 1 liter, and add it to Example 2 6 The same platinum reference solution was used to make the concentration 7 6 8 // g / 1 to prepare the basic water containing platinum victory body 6.86. This prepared platinum-colloid-containing basic water 6.86 was subjected to continuous water-pass electrolytic treatment under the same electrolytic conditions as in Reference Example 23, and one electrolytic treatment water was added as the test water before making the catalyst (A0W). The free radical elimination activity data of the test water in the same test sequence as in Example 56 was used as Example 60. (Example 6 1) Take 6.86 1 liter of the same basic water as in Reference Example 22, and add the same palladium reference solution as in Example 31 to a concentration of 48 // g / l to prepare basic water 6.86 with palladium-containing colloid. This prepared palladium-containing colloidal basic water 6.86 was subjected to continuous water electrolysis treatment under the same electrolytic conditions as in Reference Example 23. Before the catalyst was made, one electrolytic treatment water was added as the test water (A0W). The radical elimination activity data of the test water in the same test sequence as in Reference Example 22 was used as Example 61. (Example 6 2) 6.86 1 liter of the same basic water as in Reference Example 22 was added, and the same palladium reference solution as in Example 3 1 was added to a concentration of 96 // g / 1 to prepare a basic water 6 containing a palladium colloid. · 8 6. This prepared palladium-containing colloidal basic water 6 · 8 6 was subjected to continuous water-pass electrolytic treatment under the same electrolytic conditions as in Reference Example 2 3, and one electrolytic treatment water was added as the test water before making the catalyst (A0W ). The free radical elimination activity data of the test water in the same test sequence as in Example 61 was taken as Example 6 2. 2030-5943-PF (Nl); Chiumeow.ptd Page 95 200413503 V. Description of the Invention (93) < (Example 6 3) '' Take the same basic water as Reference Example 22 6.86 1 liter, add and implement Example 3 1 The same palladium reference solution was used to adjust the concentration to 19 2 / zg / 1 to prepare basic water 6.8 containing palladium colloid. This prepared palladium-containing colloidal basic water 6.86 was subjected to continuous water electrolysis treatment under the same electrolytic conditions as in Reference Example 23, to prepare a catalyst, such as adding 1 electrolytic treatment water as the test water (A⑽). The free radical elimination activity data of the test water in the same test sequence as in Example 61 was used as Example 63. (Example 6 4) Take 6.86 1 liter of the same basic water as in Reference Example 22, and add the same standard reference solution as in Example 3 1 to make the concentration 3 8 4 # g / 1 to prepare the basic containing colloid Water 6 · 8 6. This prepared palladium-containing colloidal basic water 6 · 8 6 was subjected to continuous water electrolysis treatment under the same electrolytic conditions as in Reference Example 2 3 to prepare a catalyst, and 1 electrolytic treatment water was added as the test water ( Aww), the data of radical elimination activity of the test water according to the same test sequence as in Example 6 丨 was taken as Example 64. (Example 6 5) Take the same basic water 6.86 1 liter as in Reference Example 22, and add the same palladium reference solution as in Example 3 1 to a concentration of 7 6 8 #! To prepare basic water containing palladium colloid 6 · 86. The prepared basic water 6.86 containing colloid was subjected to continuous water-pass electrolytic treatment under the same electrolytic conditions as in the reference example of the spring, and was made into a catalyst, and 1 electrolytic treatment water was added as the test water (A 〇w), the test water in accordance with the same test sequence as in Example 61, the radical elimination activity data as Example 65.

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(Example 6 6) Take the same basic water β · 86] as in Reference Example 22, and add the same fluid as in Example 26 to reduce the concentration to 6.86. This prepared platinum colloid-containing basic water 6.86 was subjected to continuous water circulation under the electrolysis condition of 5 A fixed current of 5 A per minute and a constant current of 5 cycles. (Circulating water amount 0.8L) Electrolytic treatment was performed for 3 minutes. Before the catalyst was prepared, circulating electrolytically treated water was added as the test water (Aow). The radical elimination activity data of this test water in the same test sequence as in Reference Example 22 was used as examples. 6 6. (Example 6 7)

Take 6.86 liters of basic water similar to that in Reference Example 22, and add the same platinum reference solution as in Example 2 6 to a concentration of 9 6 # g / i to prepare platinum colloid-containing basic water 6.86. This prepared platinum colloid-containing basic water 6.86 was subjected to a continuous water circulation type (circulating water liter) electrolytic treatment for 3 minutes under the same electrolytic conditions as in Example 66, and the circulating electrolytically treated water was added as a catalyst before making it as a catalyst. The test mash water (A0W) was used as the example 67 for the radical elimination activity data of this test water in the same test sequence as in Example μ. (Example 6 8) The same basic water 6.86 1 liter as that of Reference Example 22 was taken, and the same reference solution as in Example 26 was added to a concentration of 192 wi to prepare a platinum gum-containing basic water 6.86. This prepared platinum-colloid-containing basic water 6.86 was subjected to a continuous water circulation type (circulated water amount of 08 liters) electrolytic treatment for 3 minutes under the same electrolytic conditions as in Example 66, and a circulating electrolytic treatment was added before the catalyst was prepared. Water is used as the test water (A0W), and this test water is the same as in Example 66. 7

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V. Description of the invention (95) (The actual value of the radical elimination activity of the Γ line is used as the implementation details.

Take 6.86 i liters of the same basic water as in Reference Example 22 and add the same #reference solution to the plate to implement = 26 to make the concentration 384 # g / hx to prepare the basic water containing carcass 6.86. This prepared platinum colloid-containing basic water 6 MW was used in Example 66 under the same electrolytic conditions as the continuous water circulation type (circulating water amount ^ 8 liters) electrolytic treatment for 3 minutes. The treated water was used as the test water (A0W). The free radical elimination activity data of this test water in the same test sequence as in Example 66 was used for implementation (Example 70). The same as in Reference Example 22 was taken. Basic water 6.86 1 liter. The same platinum reference solution as in Example 2 6 was added to a concentration of 7 6 8 # g / i to prepare basic water 6.86 containing uranium colloid. This prepared platinum colloid-containing basic water 6 86 was subjected to a continuous water circulation type (circulated water amount of 8 liters) electrolytic treatment for 3 minutes under the same electrolytic conditions as in Example 66. Before the catalyst was prepared, the circulating electrolytically treated water was added to As the test water (A0W), the radical elimination activity data of this test water in the same test sequence as in Example 66 was taken as Example 70. (Example 7 1)

6.86 liters of basic water similar to Reference Example 22 was added, and the same palladium reference solution as in Example 31 1 was added to a concentration of 48 # g /} to prepare basic water 6.86 containing colloids containing palladium. This prepared palladium-containing colloidal basic water 6.86 was electrolyzed by a continuous water flow f cycle type (circulated water volume 0.8 liter) for 3 minutes at a flow rate of 1.5 liters per minute at a fixed current of 5A. Catalyst W adds circulating electrolytically treated water as the test water (Aow), and this test is performed.

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Radical elimination activity performed 5. V. EXPLANATION OF THE INVENTION (96) The fixed water was subjected to the same test sequence as in Reference Example 22. The data was used as Example 71. (Example 72) Take the same basic water as 6.86 丨 L, which is the same as that of Reference Example 22. Γ: Same as the reference solution so that the wave length is 96 to adjust the content: enter the gel and the body to apply this prepared content The basic water of palladium colloid is 6.86. The same electric parts as that of the implementation of Na are subjected to continuous water circulation type electrolysis treatment (water, denier = liter) for 3 minutes, and the circulating electrolysis is added before the catalyst is added. For the test water (A0W), the free radical elimination activity data of this test water in accordance with the test sequence of Example 7 was used as the implementation ^ (Example 73) Take the same basic water 6.86 1 liter as in Reference Example 22 Add the same palladium reference solution as in Example 31 to a concentration of 192 # g / 1 to prepare palladium-containing colloidal basic water 6.86. This prepared palladium-containing colloidal basic water 6.86 was subjected to a continuous water circulation type (circulating water amount of 8 liters) electrolytic treatment for 3 minutes under the same electrolytic conditions as in Example 66, and the circulating electrolytically treated water was added before the catalyst was prepared. As the test water (A0W), the radical elimination activity data of this test water in the same test sequence as in Example 71 was taken as Example 73. (Example 74) Take the same basic water 6 · 8 6 1 liter as in Reference Example 2 and add the same standard reference solution as in Example 3 1 to make the concentration 3 8 4 # g / 1 to prepare the basic Water 6.86. This prepared palladium-containing colloidal basic water 6.86 was subjected to a continuous water circulation type (circulating water amount 0.8 liter) electrolytic treatment for 3 minutes under the same electrolytic conditions as in Example 66. Cyclic electrolysis was added before the catalyst was prepared. Treated water

2030-5943-PF (Nl); Chiumeow.ptd page 99 200413503 V. Description of the invention (97) = the water to be tested (A0W), according to the embodiment of this test water? 1 Radical elimination activity data for the same test sequence are used. (Example 7 5) 6.86 liters of the same basic water as in Reference Example 22 was taken, and the same palladium reference solution as in Example 31 was added so that the concentration was 768 # g / 1 to basic water U6. This prepared basic water containing carcass 6% 6 was subjected to a continuous water circulation type (circulating water amount = 0 liter) electrolytic treatment for 3 minutes under the same electrolytic conditions as in Example 66, and a cycle electrolytic treatment was added before the catalyst was made. As the test water (A0W), the free radical elimination activity data of this test water in the same eighth test sequence as in Example 71 was used as the implementation. (Example 7 6) * The same as in Example 26 was added in distilled water. The platinum reference solution made platinum glue with a wave length of 384 // g / 1 to replace A0W as the test water, and the same as that of reference-21, the radical deactivation performed in the changed test sequence, / is listed in Example 7 6 . Ji Kang Zuo (Example 7 7) Qu added the same palladium reference solution as in Example 31 in distilled German water to replace Aow with hydrogen at an absolute concentration of 384 // g / 1 as the test water. Example 77. The radical elimination activity in the same test sequence was performed as described in Example 77. The vehicle was used as a reference (Reference Example 24). Ascorbic acid (AsA) was added to distilled water to make a concentration of 35 5 AsA aqueous solution as the test water. Reference Example 丨 9 The free radical elimination activity data of 5 M in the same test sequence was used as Reference Example 24. . , Proceeding 2030-5943-PF (Nl); Chiumeow.ptd p. 100 200413503

V. Description of the invention (98) (Reference Example 25) The AsA aqueous solution with a concentration of 71 # μ was added as distilled water with ascorbic acid (A s A) as distilled water, and the free radicals in the same test sequence as in Reference Example 19 were used. The elimination activity data is referred to as Reference Examples 2 to 5. (Reference Example 2 6) Add Ascorbic acid (ASA) in distilled water to make a concentration of 142 // M AsA aqueous solution as the test water, and use the radical elimination activity data in the same test sequence as in Reference Example 19 as Reference Example 2 6 . (Reference Example 2 7) As distilled water was added Ascorbic acid (AsA) to a concentration of 284 in AsA water as the test water, and the radical elimination activity data in the same test sequence as in Reference Example 19 were used as Reference Example 27. (C) Examination / Comparison of Examples Reference Examples 19 and 20 and Examples 26 to 30. Fig. 26 shows the platinum colloid particle size distribution 2 to 4 nm.) When the concentration is the main parameter, the picture of the platinum colloid-containing catalyst / valley water (A 0 W) The characteristic of free radical elimination activity exhibited over time. Here, the two reference examples 19 and 20 are used as a comparative control object to control the tendency of the 1/3 capacity of the tested water vapor free radical in the 3 ml capacity test chamber to eliminate the activity. In addition, replace the distilled water with the distilled water in Reference Example 2 instead of the distilled water as shown in the figure: 检: When the test 5, the free radical elimination activity of the two changes with time. The degree of removal of oxygen is the same, as a broad-body species that changes over time with the fact that the type does not eliminate the radicals. ^ Furthermore, the reference example 19 and 202 are compared according to the figure.

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Activity over time characteristics (hereinafter, omitted as "control characteristics" in the comparative example, it was found that since the absorbance was measured with a spectrophotometer (A48 ° changes at the time point Ux, it is omitted as the "time point")] 680 After the removal, the concentration of any of the radical elimination activities shown in Examples 26 to 30 plus ¥ (hereinafter abbreviated as "thematic characteristics" in the examples) is significantly lower than the control characteristics. That is, as long as the examples After a certain period of time, A0W of 26 ~ 30 can not exhibit good radical elimination activity in a wide range of concentrations. In addition, the theme characteristics of Examples 26 ~ 30 are fully analyzed, and platinum colloids will have a concentration dependence. It means that the thicker the concentration, the shorter the time required to eliminate free radicals. That is, the free radical elimination activity exhibited by Aow will increase according to the concentration of f platinum colloid. X, using platinum colloid as a precious metal catalyst, There is a time zone in which the concentration of any of the thematic characteristics of Examples 2 to 30 is significantly higher than that of the control characteristics. The reason for this is described later in the "palladium colloid to oxygen difficulty, catalyst activity, and hydrogen storage capacity" The project part will be mentioned, and will not be mentioned here (the same applies hereinafter). The comparison chart of reference examples 19 and 20 and examples 27 to 35 shows that the palladium colloid concentration is the main parameter for the hydrogen-soluble water containing palladium colloid catalyst ( A⑽) Over time, the characteristics of the radical elimination activity exhibited. According to the figure, when comparing the control characteristics of Examples 19 and 20, it was found that the subject characteristics of Examples 31 to 35 were in almost the time band from the time when the measurement was started. Those with low concentration (implementation, 31 to 33) have approximately the same characteristics as the control, but those with high concentration (example ^ ~ ^ have a tendency that the control characteristics are significantly lower. In other words, examples 31 to 35 can be used. Those with a high concentration of A0W (Examples 34 to 35) can exhibit good free radical elimination activity. Furthermore, if the subject matter of Examples 34 to 35 is special ^

200413503 V. Description of the invention α〇〇) " 1 " Fully analyzed ' It is found that the concentration of palladium colloid depends on the concentration. The thicker the concentration, the shorter the time required to eliminate free radicals. That is, the radical elimination activity exhibited by Aow will be increased depending on the degree of colloidal indifference. In particular, the subject characteristics of the high-concentration subjects (Examples 34 to 35) show that the absorbance tends to decrease significantly after about 44 seconds and about 230 seconds have elapsed from the start of the measurement. The reason is presumably that at a high concentration (Examples 34 to 35), the presence of (· 〇 2_) concentration (existing concentration) acts like a switch and actively eliminates free radicals. In addition, when a palladium colloid is used as the precious metal catalyst, the concentration of any of the subject characteristics of Examples 3 to 3 5 is lower than that of the control characteristic. The reason for this will be mentioned in the later section of "palladium colloids' poor reactivity to oxygen, catalyst activity, and hydrogen storage capacity", which will not be mentioned here (the same applies below). , Comparative reference examples 19 and 20 and examples 36 to 41 in the 28th figure show platinum gum, (particle size distribution, 2nm) concentration as the main parameter, the platinum colloidal catalyst containing hydrogen / valley water (A0W) exhibited free radicals Eliminates changes in activity over time. According to the figure 'comparing the pairs of free radicals and elimination activity of Reference Examples 19 and 20, it was found that after approximately 92 seconds have elapsed from the time of starting the measurement, Examples 36 to 41 have the subject characteristic S-or $ peacock. The characteristics are significantly low. That is to say: of examples 36 to 41, after a certain period of time, a wide range of "good radical elimination activity" can be performed ... Examples 36 to 41 will be fully analyzed, and #present platinum colloidal concentration will have Concentration-dependent, the time required to eliminate free radicals will be shorter. That is, the free radical elimination activity exhibited by aow will increase depending on the concentration of platinum colloids. The relationship between the particle size parameters of the TiBo colloid (particle size distribution 2 ~ 4nm / particle size knife cloth 1 ~ 2 ·) and the radical elimination activity is clear.

200413503 V. Description of the invention (101) The 26th graph with platinum colloidal concentration of 2 ~ 4nm as the main parameter is compared with the 28th graph with platinum colloidal concentration of 1 ~ 2nm as the main parameter. To remove the influence of the degree parameter, for example, Example 27 and Example 37 were compared with the same platinum concentration parameter (96 # g / i). Example "From the start of the measurement, the absorbance reached a high + at about 320 seconds, and then the slow theme characteristic tended to decrease." After about 44 G seconds, the absorbance __ degree reached a few. In contrast, Example 37 was from the start of the measurement. After the peak of J = II = at about 760 seconds, the slow subject did not have a light absorption of almost 0 in the measured time zone. Erren: Γ 辰 Ϊ Same (384 " g / 1) Example 29 is compared with Example 40. Example 29 passed about 170 seconds from the start of the measurement, and was suppressed to almost 0 ′ and continued to =: Γ40Γ reached at the start of about 26 ° seconds. ] / The characteristics show a tendency to decrease rapidly. After the platinum catalyst used in the anti-emulsifying water, the particle size distribution can be shown by ㈣ 2㈣ / good ^ ^ The diameter absorbance is 2 to 4 nm, and the specific absorbance is suppressed to almost radical. Elimination of activity (because it will be better. Θ and shorter time), from this point of view, it is a comparison of reference examples 19 and 20 and examples 42 to palladium) mixed colloids (particle size distribution 2 to 4) No (when platinum + concentration is the main parameter, Uranium = free radical deactivation exhibited by mixed mol ratio η) (A0W) ::: Comparison of the refractory properties of free soil with reference to water in reference examples 19 and 20. According to the figure, the control of earth work deactivation Characteristics

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After about G seconds from the time of starting the measurement, Example 42 45bis: the degrees were significantly lower than the control characteristics. In other words, the mouth should be: Ϊ, A0W of 42 ~ 45 passes a certain degree of elapsed time, and the activity is eliminated by μ base. In addition, ㈣ ~ 45 Λ Λ ^ is fully analyzed, and it is found that the concentration of the (colloid) mixed colloid will be affected, that is, the thicker the degree, the shorter the time required to eliminate free radicals. The freeness exhibited by Α0Ι The radical elimination activity will increase depending on (platinum + palladium dolphin. It will be compared with the oral body wave length of Reference Examples 19, 20 and Example 4 6 to 50. Figure 3 0 shows the r + + colloid (particle size distribution 2 ~ 4nm, when the concentration is the main parameter, and the platinum and palladium mixed mole ratios are the secondary parameters, the free radical elimination activity exhibited by the dissolved water (A0W) containing (platinum + palladium) mixed colloid catalyst changes with time. Characteristics. ^ This figure compares the control characteristics of free radical elimination activity of Reference Examples 9 and 20. It was found that the concentration of any one of the subject characteristics of Example 46% was about 46% after about 52 seconds from the start of the measurement. Both are significantly lower than the control characteristics. That is, as long as the A0W of Examples 46 to 50 has elapsed to some extent, free radical elimination activity that exhibits good performance over a wide range of degrees can be achieved. Furthermore, Examples 4 to 6 to 6 The theme characteristic of 50% is fully analyzed, and it is found that the concentration of (platinum + palladium) mixed colloid will have Concentration dependence, that is, the more concentrated the time required to eliminate radicals becomes shorter. That is, the radical elimination activity exhibited by A0W will increase depending on the concentration of (platinum + palladium) mixed colloids. 'Comparative Reference Example 21 and Example 5 The third and third figures from 1 to 5 5 show the concentration of (platinum + palladium) mixed colloid (particle size distribution 2 to 4 nm,) as the main parameter, and the platinum: palladium mixed mole ratio as the secondary parameter. Hydrogen storage with (platinum + period) mixed colloid catalyst

2030-5943-PF (Nl); Chiunieow.ptd Page 105 200413503 V. Description of the invention (103) The radical elimination activity exhibited by water (A0W) changes with time, and 夂 Γ column == 6 ~ 5 " Department has been removed. Based on the control characteristics of the radical elimination activity of the "two" and the palpitations, it was found that in the 46 to 50 cases (. (V) production system has been removed, there is still a tendency to produce I OV). This point will be mentioned in the description of FIG. 37 described later, and the tendency of 'this formation (.〇2—) may depend on (turn + palladium) the k-degree of the colloid, and the thicker the concentration, the more it can be suppressed. The current = radical elimination activity will increase depending on the mixed colloidal indifference of the ⑷㈤ mixed colloid. The second phenomenon described in Figure 37 below will be summed up. It can be inferred that the higher the s Mol ratio, the more inhibited the production (. ~ _). w Λ ratio Λ Test cases 22 and 23 and Examples 56 to 60. Figure 32 shows the starting point of the colloidal platinum colloidal catalyst whose concentration is the main parameter, and the free radicals displayed by adding electrolytically treated water (A0W) are eliminated. The activity is shown in the graph. The subject characteristics of Example 5 " 〇 are at a low concentration (actually 5V ~ 2 control characteristics are approximately the same, but the high concentration person (Examples 58 to 60) is about 740,000 seconds after the measurement starts.) -The concentrations are all significant in the control characteristics. That is, as long as the longitude elapsed time of Example 58 ~ 60iAow is used, Jingyou can perform well in a wide range of concentrations. The subject of Examples 58 ~ 60 The characteristics are fully analyzed, and it is found that the platinum colloidal spread will have a concentration dependence, that is, the more the concentration is, the shorter the interval between elimination of free radicals will be. In other words, the free radicals exhibited by A0W will increase and the colloidal concentration will increase. Comparison of Reference Examples 22 and 23 and Examples 61 to 65 in Figure 33 shows that the palladium colloidal catalyst with the colloidal (particle size distribution 2 to 4 nm) concentration as the main parameter was added before =

200413503 V. Description of the invention (〖〇4) The developed characteristics of one of the electrolytically treated water (Aw). According to the figure, Examples 61 to 65:; = "Two time-varying examples ..." Although approximately the same as the control characteristics ^ v; in the low-concentration f (actually,) when about 320 seconds have elapsed since the measurement started, Ren: f, in contrast to Teke .; S, Shi / Chen are all showing low elapsed time, then: ί :: Example 63 ~ 65 of 4⑽ After a certain period of concentration, Hegu, Qu # > Shihaote fully analyzed and found that the palladium gel will change. That is, the colloid concentration increased when you continued to show the second place. In particular, the most peasant sounds. After about 830 seconds at 2 m, the absorbance will be significantly displayed. (Ω eight reasons speculated that it may be at a high concentration (Example 65). The effect of the positive elimination of the 2 deuterium (existing concentration) is like a switch-, Comparative Reference Examples 2, 2, 3, and Example 6 3 to 4 of Figures 6 to 7 0 矣 1000> Platinum colloidal catalyst with a concentration of $ 6 postbody (particle distribution 2 ~ 4ηιη) as the main parameter Tim = Electrolyzed treated water ( Gang) the free radical elimination activity exhibited by time, according to the delta chart, the theme characteristics of Examples 66 to 70 are in low-concentration producers (actually about, seconds: hours, any concentration is significant) The low sore prince also has 5 brothers. As long as the ΑΟΨ of Examples 68 ~ 70 passes through a certain J-pass, it will be able to perform a good free radical elimination in a wide range of concentrations: the characteristics of the theme of Examples 68 ~ 70. Fully analyzed and found that the glue is "^ / Chen dependency", that is, when the concentration is higher, the free radicals are required to be removed. Page 1072030-5943-PF (Nl); Chiumeow.ptd 200413503

Will become shorter. That is, the free radical elimination activity exhibited by A0W will increase depending on the body concentration. The 35th graphs of Reference Examples 22 and 23 and Examples 71 to 75 show that the concentration of palladium colloid (particle size distribution 2 to 4 nm) is the main parameter. Free radical elimination activity exhibited by aging of electrolysis treated water (A0W) added before the palladium colloidal catalyst over time. According to the figure, the subject characteristics of Examples 71 to 75 in the low-concentration subjects (Examples 71-72) tend to start to decrease slightly after 95 seconds have elapsed at the start of the measurement, but the high-concentration subjects (Examples 73 ~ 75) When about 650 seconds have elapsed from the start of the measurement, the concentration of any one is significantly lower than the control characteristic. That is, as long as the A0W of Examples 71 to 75 elapses to some extent, free radical elimination activity exhibiting a good range of concentrations can be achieved. In addition, the subject characteristics of Examples 71 to '75 were fully analyzed, and it was found that the concentration of palladium colloid has a concentration dependency, that is, the thicker the concentration, the shorter the time required to eliminate free radicals. That is, the radical elimination activity exhibited will increase depending on the palladium colloid concentration. In particular, those with a high concentration (Examples 73 to 75) at the start of the measurement showed that the absorbance tends to decrease after each of about 650 seconds, about 420 seconds, and about 230 seconds. The reason is presumably that at a high concentration (Examples 73 to 75), the presence of (· 〇 2) the concentration (existing concentration) acts like a switch and actively eliminates free radicals. ^ This is to clarify the relationship between the parameters of electrolysis conditions (a course of electrolysis / cycle electrolysis) and the elimination activity of free radicals in a platinum colloidal catalyst. Try to add a piece of electrolytically treated water before the platinum colloidal catalyst as the test water. The comparison is made by adding the circulating electrolytically treated water before the platinum colloidal catalyst as the% chart of the tested water. To remove the effect of the concentration parameter, for example,

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(1 92 # g / i) Example 58 is compared with Example 68. EXAMPLES The characteristic of the slow theme tends to decrease after approximately 680 seconds has passed since the measurement started, and the characteristic of the slow theme tends to decrease. By about elapsed, the second is suppressed to almost zero. In contrast, in Example 68, the peak of the absorbance was reached after about 620 seconds passed from the measurement point k. Among them, the physical characteristics tended to decrease, 'to about 8300 seconds, the absorbance reached one degree ^ and reached several "0. Second' The platinum concentration parameters are the same (384 " g /.). Bismuth Example 59 is compared with Example 69. Example 59 /

The peak of the absorbance is reached at about 2 seconds, and then the slowness of the theme = I decreases, and the absorbance-degree is suppressed to about 2 after about 660 seconds. In contrast, in Example 69, about 400 hands were passed at the start of the measurement: up to: the absorbance was high, and then the subject characteristics became slower: right :: the absorbance was almost suppressed to 0 after about 500 seconds. The above two breaks are used to generate the electrolytic strip used in the antioxidant functional water of the present invention; "i (the electrolysis before the addition of the quasi-carbohydrate catalyst), the cycle electrolysis can exhibit a good free radical elimination activity (due to It takes a short time to solve the problem), from this point of view / yes and the suppression of the first degree of goodness to a few other, for the solution parameters of the electrolytic solution

The relationship between electrolysis) and free radical deactivation activity is tested. Adding an electrolysis treatment water to the electrolysis agent is the test. Adding the electrolysis treatment water before the catalyst is 3 5 = palladium gel ratio. In order to remove the influence of the concentration parameter, the example =: = 3 * 5 is shown as a pair (192 / zg / i) of Example 63 and the example is advanced. The comparison characteristic phase Λ of reference examples 22 and 23 starts from the measurement.

200413503 V. Description of the invention (107) In the time zone, J: Φ the first 4 shi, π a α, although the main communication characteristics have been low, but there is a tendency to slow down the ancient well. In contrast, the awkwardness, such as 7q + + Β, shows that it takes about 65 0 seconds for the level I * to rise again. Tendency, but the degree is almost suppressed. Absorb light after 86G seconds ^ t, M.I65 ^ m5. ^ ^ ^ ^ M 768, g / Ι) point to about 68 ". 〇 or so = production: from the start of the measurement When Λ ^ (and the peak of photometric peak) showed a slow rise, there was a tendency of a slow decline in the measurement ϊ ί Ϊ ί. In contrast, the second drop of Example 75 =, the point is the peak of the absorbance, and then the theme characteristics appear slow: : =, Γ The absorbance is almost suppressed to 0 after about 320 seconds. 佟: 二 / The electrolytic conditions used to generate the antioxidant functional water of the present invention (however, electrolysis before the addition of palladium colloid catalyst), the cycle electrolyzer is better than one From the viewpoint of good ion-releasing elimination activity (because the time required to suppress the absorbance to almost zero) is short. From the viewpoint, it is better. Figure 36 shows the Asa aqueous solution (a〇W) with the AsA ruler's grain / Chen degree as the main parameter. The present characteristic of free radical elimination activity changes with time. According to the figure, the concentration of free radical elimination activity exhibited by the AsA aqueous solution of Reference Examples 24 to 27 is lower than those of Reference Examples 丨 9, 20. That is, it may be It was confirmed that the reference examples 24 to 27 of the aqueous solution of iAsA exhibited a wide range of free radical elimination activity as previously known. Moreover, it was confirmed that the free radical elimination activity exhibited by the aqueous solution of AsA from Examples 24 to 27 was previously known and could depend on the concentration. Moreover, comparing the free radical elimination activity exhibited by the A s A aqueous solution with the free radical elimination activity exhibited by the antioxidant function water of the present invention, it can be understood that, for example, the antioxidant function water of Example 75 is far superior to the reference

2030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (108) One column of tiAsA aqueous solution, which can match the asa aqueous solution of reference examples 25-27. The colloid is difficult to react with oxygen and catalyzes the hydrogen storage capacity. When the antioxidant method and antioxidant of the present invention are applied to an oxygen-soluble system such as a living body, there is a large barrier in the body. In order to oxidize nutrients to obtain energy, the relationship between various oxygen addition reactions required in the body is the essence of the problem here. It is dissolved in the anti-oxidant water two catalyst to react oxygen with chlorine to return to ordinary water system. = Precious metal colloidal catalyst utilizes activated hydrogen to reduce single electrons, and counter-elimination object (.〇factory) is generated, resulting in attenuation of radical elimination activity. The higher the activity of the two-earth catalyst, the more it tends to expand. Also, = radical elimination activity The higher the activity with the trade (quote), the more the radical elimination activity will be attenuated. Therefore, 'Yes: Ja, a fundamental problem that is not easy to solve. &Amp; 人 In order to solve this essential problem, the inventors and other efforts Kanasha = Precious metal catalysts, especially the colloidal colloids, tend to be less reactive with milk than the colloidal colloids. Based on this finding, further discussion of metal catalysts that can be used in the present invention should be based on this finding. Concerned = element, when considering these three elements for poor oxygen reactivity, catalyst activity, and hydrogen storage capacity, from the viewpoint of the total force, a good catalyst is a palladium colloid, and the present invention is completed. First, the basis for judging the comparison between palladium colloid and platinum colloid will be explained.

200413503 V. Description of the invention (109) 'The 37th figure of Comparative Reference Example 21 and Examples 76 and 77 shows that the difference in the type of the metal catalyst is used as the main parameter (fixed concentration) of the catalyst-containing chlorine-soluble water (A0W). The free radical elimination activity changes over time. In addition, in Reference Example 21 and Examples 76 and 77, the (· (V) production system was removed. According to the figure, Example 7 6 Although the (· 〇) plant) production system was removed, the subject matter was born at the beginning of the measurement. After about 140 to 2000 seconds from the time point, the absorbance reached a peak value of about 〇 ^^ g (about 160 seconds). In addition, the absorbance slowly increased from the start of the measurement to about 8 to 60 seconds. In contrast, the subject characteristic of real expansion = 77 is approximately the same as the reference characteristic of Reference Example 21, and the absorbance has not particularly increased. These phenomena are presumably the subject of implementation, and the property is at the beginning of the measurement. Active until about 160 seconds elapsed? The u2U ΐ ΐ (.〇2_) was exhibited by the antioxidant functional water of the present invention for 8680 seconds, and the absorbance turned into a slowly rising tendency. It was recognized that m to about .b ^ ^ ^ ^ ^ ^ ^ ^ ^ ^ t? ^ Eliminate the occurrence of (· 02-). So that the second cannot be suppressed, unfold the water-soluble, water-soluble, water-soluble ^ 〇 糸 (in this ^ 〇 展开) The mechanism of Ming Zhi's hydrogen colloidal catalyst is inferred. Fresh colloidal catalyst and palladium Figure 38 It shows the coexistence of hydrogen and the water dissolving machine. The effect of uncolloid catalyst is shown in the figure, the surface hydrogen and oxygen will be reduced by activated hydrogen-electron). At this time, the carcass catalyst will be adsorbed to the dissolved (.H) in the system. An electron is transferred to oxygen (oxygen-activated lice (.H) loses one electron and is separated by H +

200413503 V. Description of the invention (110) The form of the element is released to Fengzhong f Γ, ~ ττ I, ^, ^ m ^ (hereinafter, the repeated description about this is omitted). That is, the oxygen itself is used to pass through the membrane; the i A 6, MI 4 # gel catalyst is generated by the one-electron reduction of the activated hydrogen, and the original elimination is generated. The platinum colloid catalyst will be adsorbed on the prepared catalyst. W 7 2) : 丄 Return and attached to the dissolved hydrogen and (.〇2-) in the 糸, and a lightning strike released by the activated rat (· Η) will be reduced by 乂 々 λ person / ^ or oxygen two electrons. Transferred to (· 〇2-—) ((.〇2-) one electric dynamo suppressor). That is, (· 〇2-) itself uses a transcolloid catalyst to perform a 20% (0,) meeting due to activated hydrogen, and uses two "ions" present in the plutonium to ionically combine to form a peroxide rat (H2 02 ). After or at the same time, the molybdenum colloidal catalyst will transfer one electron released from activated nitrogen (· H) to hydrogen peroxide (H2 02) ((H202) as it adsorbs the dissolved hydrogen and hydrogen peroxide (H2O2) in the system. ) One electron reduction or three oxygen reduction of oxygen). That is, (H2O2) itself is generated by a one-electron reduction by activated hydrogen through a platinum colloidal catalyst (· 0H). After or at the same time, the platinum colloidal catalyst will transfer an electron released from activated hydrogen (· Η) to (· 〇Η) ((· 〇Η) electrons with the adsorption of hydrogen and (· 〇Η) dissolved in the system. Reduction or four-electron reduction of oxygen). That is, (· 〇ιι) itself uses an electron reduction through activated hydrogen through a colloidal catalyst to generate 0Η-ions. The generated 0Η- will be ionically combined with the Η + ions to form water (40) and stop this series of reactions. The above is the mechanism of the action of the surface colloidal catalyst in the aqueous solution in which hydrogen and oxygen coexist. In contrast, the mechanism of the action of the 'palladium colloid catalyst is as follows. Fig. 39 shows the mechanism of action of a palladium colloidal catalyst in an aqueous solution in which hydrogen and oxygen coexist. When explaining the mechanism of action of the Is colloidal catalyst, the point of great difference between the mechanism of action of the above-mentioned platinum colloidal catalyst and that of the aforementioned platinum colloidal catalyst is the Ministry of Origin of Reactivity to Oxygen 2030-5943-PF (Nl); Chiumeow.ptd Page 113 200413503 5 The description of the invention is divided into (111) points, so the explanation will be centered on this point, and repeated explanations other than that will be omitted. As shown in the figure, the palladium colloidal catalyst adsorbs dissolved hydrogen in the system, but does not actively adsorb oxygen, or even passive adsorption (palladium colloidal catalyst that collides with oxygen) has difficulty in activating hydrogen (· H). One of the emitted electrons is transferred to a tendency (does not reduce oxygen molecules). Therefore, the original elimination object (· (V) is hardly generated. The subsequent mechanism is the same as that of the platinum colloidal catalyst, and the coexistence of the colloidal catalyst and the hydrogen dissolved in the system is used to separately exist in the system (· (Plant 0), hydrogen peroxide (H2O2), or (· 0H) reduction, finally generating water (H2 0) 'and stop this series of reactions. Here,' as the property of the palladium of the preferred noble metal colloidal catalyst of the present invention is added Narrative, the palladium atomic number 46, atomic weight 106.42, was a transition metal atom discovered by Wollaston in 1803. Its name is named after the previously discovered little confusion star Pa 11 as (the goddess of wisdom of Greek mythology). A precious element with only 24 million tons on the earth. Palladium has a good ability to absorb hydrogen. It has a capacity of 740 to 938 times its own volume of hydrogen. It is often used in hydrogenation catalysts or storage. The most concentrated plutonium is used as a catalyst. The complex is also used as a catalyst for the production of acetamide from acetamidine. Other uses, such as metal or decoration for dentist treatment. Furthermore, the reaction of the antioxidant water of the present invention is roughly classified as having Unpaired electrons, such as T, have strong second forces of unpaired electrons = radicals: and it is not presumed that the anti-chemical machine of the present invention is used; examples of the two are :) the corresponding effect of free radicals (atomic ^ radicals) ) 'While exhibiting free radical elimination activity :: free 々 耵 π

200413503 V. Description of the invention (112) In order to use the strong reducing power of the original anti-oxidant function of the present invention, the mouse-selective dependent term is used to correspond to the oxidizing substance (sometimes' busy, will give atomic hydrogen Electrons), and selectively exhibit reducing activity. Here, selectively exhibiting reducing activity is considered to be based on the interphase of the atomic gas plate \ chemical substance, that is, according to the valence electron theory, occupying the atomic side ^: = orbital The valence electrons flow into the easiness bar Z of the lowest orbital side of the oxidizing substance and exhibit selective reducing activity. If a specific example is used as a reference, the substance Vitamin B2 is dissolved in the test water of the hydrogen-soluble water (A0W) of the palladium-containing colloidal catalyst (192 ^ curvature) of the present invention, and vitamin B2g will not be active. This example is inferred because the antioxidant function water of the present invention, = reducing atomic hydrogen does not donate electrons to oxidizing substances (Xin B, so it does not exhibit reducing activity. That is, it can be said that atomic hydrogen and oxygen (vitamin B2 ) The phase is not good. Furthermore, the oxidation will be: due to the reducing activity of Γ / the upper methylene blue. The inference of this example is the elbow electricity, and the oral lice substances (oxidized methylene blue = original activity. Also That is to say, it can be shown that the children's shoulders are still very good. The sexual desire of the atomic wind and the oxidizing substance (methylene blue) makes the antioxidant function water of the present invention better. The better method can test you. ^^ Reactive wave lice of the above-mentioned reaction objects (converted by the effective value of the dissolved hydrogen concentration under the co-saturation of redox pigments), lice; lice; the precious metal catalysts that have been included in the quantitative analysis method of chronometers themselves absorb or 'Make the hydrogen-soluble water contain p. 1152030-5943-PF (Nl); Chiumeow.ptd 200413503 V. Description of the invention (113) Quantitative analysis method of DH using redox pigments The following additional examples are disclosed to show the use of the above-mentioned oxidation Reduction of pigment An additional example of the DH quantitative analysis method. (Example 78) The same electrolytic catalyst treated water as the test water (A0W) was added before the same catalyst as in Example 73. 'The nitrogen gas will be replaced by the test water 200mi. The reference solution at a concentration of 40 times is turned over to 1 m 1 into a test water containing chamber with a syringe, and the mixture is thoroughly stirred and mixed. Then, under the condition that the color of the test water changes visually, 10 g / l concentration (volume mole concentration) 26773 · 8 // M) a small amount of methylene blue aqueous solution is injected into the test water with a syringe. The total injection amount of the methylene blue aqueous solution when the end point is reached is 7 · 8 m 1, and each value is substituted into the above formula 7 The calculated measured value of the dissolved hydrogen concentration DH is 2.09 (mg / 1). The tested water-related physical properties of Example 78 are shown in Table 4 and the actual value of the dissolved hydrogen concentration dh is shown in Figure 40. (Example 79) The same basic water as in Reference Example 22 was subjected to a continuous water circulation cycle (circulated water amount 0.8L) under the same electrolytic conditions as in Example 71. The electrolytic treatment catalyst was added without circulating electrolytic water for 3 minutes. The test water will replace the above in 200 ml of the test water 1 ml of a platinum reference solution with a concentration of 40 times the gas was injected into the water containing chamber of the test solution with a syringe, and the mixture was thoroughly stirred and mixed, and at the same time, the concentration of the test water was changed to 10 g / l (volume molar concentration 26737). · 8 // Μ) A small amount of aqueous solution of indigo blue was injected into the test water with a syringe. When the end point was reached, the total injected amount of the aqueous solution of indigo blue was 8.5 mi. Substituting each value into the above formula 7 The measured value of the dissolved hydrogen concentration DH is 2. 28 (mg / 1).

2030-5943-PF (Nl); Chiumeow.ptd Page 116 200413503 V. Description of the invention (114) It is shown in Table 4 that the tested water-related physical properties of Example 79 are shown in Table 4, and the total value of the dissolved hydrogen concentration 卯 is shown in page 40. Illustration. (Example 80) Activated carbon-treated water obtained by treating Fujisawa city tap water with an activated carbon column was added with the same palladium reference solution as in Example 31 to a concentration of 384i to prepare palladium-containing colloidal activated carbon-treated water. The palladium-containing colloid activity prepared by this treatment was treated in the same electrolytic conditions as in Example 71. Continuous water circulation was performed (10.8 liters of water). The electrolysis treatment catalyst for 3 minutes was not added. Cycle = solution. Water was used as the test water. (A0W): Put 2ml of the lice gas 40 times concentration platinum reference solution lml in 200ml of the test water and inject the test water with a syringe. After the mixture is fully stirred and mixed, i test the test water with Discoloration :, 'Pour methylene blue at a concentration of 10 g / 1 (volume concentration 26773.8 " M) into the test water with a syringe. When the end point was reached, the total injection volume of the methylene chloride was 9.7 ml, and each value was substituted into the above formula 7 to obtain the measured value of J degree M of 2, 6G (mg / 1). Fig. 40 shows the verification of 8G in this embodiment. The performance table is not shown in Table 4. The actual value of the dissolved hydrogen concentration DH is shown in (Example 8 1). Water treatment = Activated carbon treatment of Fujisawa tap water after activated carbon column treatment. Water circulation type (cycle treatment = 柞 & Mo Li) 3 is the electrolytic treatment catalyst of bismuth without added cycle electrolysis (as the test water UOW), it will be replaced in the test water 20001111 by the agricultural degree The reference solution imi is injected into the test water containing chamber with a syringe and mixed with the knife, and then the test water is visually changed on one side.

200413503 V. Description of the invention (115)-Next, the methylene blue water with a concentration of 10 g / l (volume concentration 26 773 · 8 #M) was injected into the test water with a syringe. When the end point was reached, the total injection amount of the methylene blue water solution was 10.6 ml, and the values of the dissolved hydrogen concentration DH obtained by substituting each value into the above formula 7 were 2.84 (mg / 1). The water-related physical properties of the test in Example 81 are shown in Table 4, and the actual value of the dissolved hydrogen concentration DH is shown in Figure 40. (Example 8 2) Activated carbon treated water in which Fujitasawa tap water was treated with an activated carbon column was added with the same palladium reference solution as in Example 31 to a concentration of 192 to prepare a palladium-containing colloidal activated carbon-treated water. This prepared palladium-containing colloidal activated carbon-treated π water was subjected to a continuous water circulation cycle (circulated water amount 0.8L) for 3 minutes under the same electrolytic conditions as in Example 8.0. The electrolysis treatment catalyst was not added with a circulating electrolysis place, and water was used as a substrate. The test water (Aow) will replace the above-mentioned nitrogen 40-fold concentration platinum reference solution in 200ml of the test water, and the m 1 will be injected into the tester's harvesting chamber with a syringe and fully stirred and mixed. Under visual change of the color of the test water, inject iOg / i concentration (volume concentration 26773.8 #Magic blue methylene blue aqueous solution y 1 into the test water with a syringe. When the end point is reached, the methylene blue water , The total injection volume is i 2. 0mi, substituting each value into the above-mentioned formula 7, the measured value of the stored hydrogen concentration DH is 3.21 (mg / l). The test-related water-related physical properties of Example 80 are shown In Table 4, the actual value of the dissolved hydrogen concentration M is shown in FIG. 40.

Page 118 200413503 V. Description of the invention (116) Table 4 pH ORP [mV] EC [mS / m] Water temperature Tc] ϋΗBuying effect 値 [mg / L] Reference example 17 9.8 -171 17 21.6 0.03 Reference example 18 7.2 -623 99 21.2 1.66 Example 78 7.1 -650 98 22.3 2.09 Example 79 7.1 -650 98 22.3 2.28 — Example 80 7.8 -645 15 22.3 2.60 Example 8-1 8.9 -707 15 18.0 2.84 Example 82 7.4 -605 14 18.0 3.21 Antioxidant This water (A 0 W) has a longevity effect on nematodes (C!). Caenorhabditis eiegans (hereinafter referred to as C. eikan 3 still) and fruit rope, mice, rats Juxtapose is widely used internationally as an aging model for multicellular organisms. Moreover, the entire genomic sequence of C: has been determined, and it can be combined with expression analysis methods such as gene destruction or GFP fusion gene to be used to explore the function or mechanism of the individual hierarchy such as human genetic disease cause genes or cancer genes. The live test tube attracted attention. In particular, he proposed that the most common lifespan of wild-type C · e & w is about as short as that of Yotori (see "Aging at the molecular level" by Naoto Ishii: Talking about social workers (20 0 1), 102 ~ 103). · When de dog ^ is an experimental animal, the effect of antioxidant water on animal life can be discussed in a short time. When the present inventors obtained the above-mentioned document "At the molecular level | ^ Aging of Tokai University Medical Science Assistant Professor Naoki Ishii", the author helped implement the discussion using wild-type C: feeding water as the guide and energy water (AOW), Test on the effect of life. Here, the "gas generation" "chemical water" refers to the test procedure for feed-water (A-2) of each test group 1 of purified water and antioxidant function water, and the insects are allowed to stand still in item ④. ^ ~ 0 hours of exercise

200413503 V. Description of the invention (117) The water used for operation and the operation of judging the life and death of insects in the pupa, or the operation of agar ^ dribbling water on the surface of the agar medium, etc. The description is as follows (A), the same test examples and reference examples are described as follows (B), and the results of the same tests and investigations are explained c). In addition, this test is based on "Reactive Oxygen Oxygen Project Measurement Method and Main Pathological Physiological Model" Supervised by Naoya Taniguchi: Cell Guardian's Book Soil Experiment, 1st Issue, Xiu Runsha (Stock), 1 994, 288 ~ 2 Page 92 "Aging Model" / Mid-State Physiological Model "Supervision by Naoya Taniguchi: Separate Cell Engineering Experiment Series" Shurunsha Co., Ltd. ", 1 994, pages 29〇 ~ 292" 2 · Lifetime under various oxygen concentrations "Measurement") (hereinafter, references are omitted as "based on the steps") ° The above "aging model" is cited in this note f ° However, 'this experiment is to investigate the effect of changes in feeding water on the life of c. Elegans, It is special, so it will be changed according to the steps. The description of this test plan is centered on the part that changes according to the procedure. (A) Summary of test day (A -1) Reagents used in this test The reagents used in this test are as follows. ① (5-Fluoro-2'-deoxyuridine: FudR) · · · Made by Wako Pure Chemical. ② S buffer (s buffer) Sodium vaporization: NaCl (0.1M). Potassium Dish: Potassium Phosphate (pH6.0) Because C · e / e polyMS is hermaphrodite, it is necessary to prevent mixing with progeny

2030-5943-PF (Nl); Chiumeow.ptd p. 120 200413503 V. Description of invention (118). Therefore, in accordance with the steps, the test drug FudR was used to prevent C. Yixuan Liu from showing offspring. The purpose of using the S buffer is to remove the influence caused by the difference in ρ Η. (A-2) Test procedure ① According to the test procedure, collect the wild-type first-stage larvae cultured simultaneously. In a 9 cm culture orphan containing an agar medium, put about 50,000 to 10,000 worms. When this operation is performed, the worm age is about 4 days. ② Take an appropriate amount of S buffer with a transfer pipette and place it in the upper petri dish. Then use the transfer pipette to suck up the worms and S buffer in the culture JHL and transfer it to a test tube (diameter 1.5mm). The test tube is left standing in a vertical state, and the bug will sink to the bottom of the test tube. After the worms have precipitated, be careful not to suck the worms. S buffer (supernatant) in the test tube is gently sucked away with a pipette. Thereby, the worms in the test tube were collected with the S buffer in the test tube removed. ③ Take out an appropriate amount of the insects collected in the above test tube (about 100 ~ 200) and distribute it into 2 test tubes (i.e. 5mm diameter, 1 ~ 2ml capacity). One of the two test tubes was used as a control group (purified water of Reference Example 28 described later), and the other was injected with test water (antioxidant function water of Example 83 described later). ④ Cover the openings of the two test tubes, and place the two test tubes in a horizontal position for 3 hours. Cultivation ⑤ Move the worms in the two test tubes placed horizontally to two 91 ^ cultures and leave them to stand overnight at room temperature. ⑥ Prepare a 3 cm agar-containing petri dish (20 pieces) with a slightly dry surface. A drop of coliform bacteria was added to each of the 3 A knife-edge culture dishes and the force center. In this way, the insects will be concentrated in the center due to bait, which is convenient for observation.

Page 121 200413503 V. Description of the invention (119) ⑦ Use the single-lead platinum thread described later to move the worms from the two ⑤ cm petri dishes that were left at room temperature overnight to the above ⑥ 3 cm prepared orphan , Each piece = only, a total of 10 pieces. The 100 worms were used as a type 7 colony. When there are two test groups, each test group performs this operation. When carrying out the operation of separating the worms, perform the operation of adding the drug to the heart. In addition, the single-lead platinum wire is a self-made tool. A platinum wire with a length of about 3 cm and a diameter of about 500 ~ 100 # m is installed in the narrow mouth of the transfer suction device of 3 cm. Cut to an acute angle and fold it into a right angle at about 5mm at the front end. For each use, sterilize the front end (the part that will contact the insect or agar medium) with a flame. The method of use is to hook the worm from bottom to top. Put the worm hook on it ’and touch the front end of the platinum wire gently to the agar, and the worm will move to the soil lipid medium by itself. ⑧ = Said (the principle of this test is every other day) check the life and death (day age) of each group of insects. It is determined that the single-lead platinum wire is used to lightly touch the worm's head, or the water drops T 2 2f should be judged to be dead. If the agar medium is dry (B), the apricot expansion system 2 and the dehydrated droplet 2 are dropped on the surface of the agar medium. C Β) Disclosure of Bei Shi Example and Reference Example (Reference Example 28)

(, Matter of fire) 豹 A leopard ancient KU active column activated carbon-treated water (when purified water is fed = water, according to the X * life ^ material reference reference in (a_2). Live == two of them? / Liquid at 1 liter is the same size as Reference Example 28), so that the palladium colloid concentration is 192 # g / l, and

200413503 V. Description of the invention (120) ------------ Flow rate of 1.5 litres per minute and 5A fixed current electrolysis conditions for water circulation type (circulated water 0.8 litres) electrolytic treatment ( It is equivalent to two cycles of maggots and only treated for 1 minute. The catalyst was added to the cyclic electrolysis treatment and hydrolyzed to feed water before the catalyst was obtained. The nematode & life data obtained according to the test procedure described in (A-2) was used as Example 83. (C) Comparison and comparison of test results and results of Reference Example 2 of the reference example 2 (group of using purified water as breeding water) and Example 8 3 (group of using ^ oxidative function water as breeding water) The figure shows the effect of the colloidal catalyst-containing electrolyzed water (Aow) on the life span. ° This test uses the Student's t-test to test the significant difference in the average life difference between the two independent groups. The results are shown in table 5.

2030-5943-PF (Nl); Chiumeow.ptd Page 123 200413503 V. Description of Invention (121) Table 5

Student's t-test: Test results of hypothetical equal-dispersion 2 samples (fe risk rate 0.1%) Antioxidant machine * Di water average life 20.05 17.75 Dispersion 16.66 14.98 Observation number 99 95 Dispersion of pool 15.84 and hypothetical average Difference 0 Degrees of freedom 192 T 4.02961 P (T £ t) one side 4.02E-05 Ding boundary 値 one side 3.13325 P (TSt) two sides 8.05E-05 Ding boundary 値 both sides 3.34199 Verification result: Because t = 4.03 > t boundary 値 both sides (3 · 34), so the "average life expectancy of the two groups with antioxidant function water and clean water as C · e / egara's breeding water is the same" & hypothesis, so τ has antioxidant function The average lifespan of water as the breeding water for C · e / egara (20.05) is 2 3 longer than the average lifespan of the group using purified water (17.75). The difference between the two is significant. (T (192) = 4.03 τ SD: 0.57 τ ρ < 0 · 〇〇ι) As shown in Table 5, when the hazard rate is 0.1%, t = 4.〇3> t boundary value for the side (3.34), so the " Antioxidant functional water and purified water as 1 C_ Kanzhi's two groups of breeding water have the same average life span. "Fake children here" using antioxidant functional water as The average life expectancy (20 · 05) of C · feeding water groups was longer than the average lifespan of the group using water purification (17.75 days) ^ days, and the difference between the two was significant. (T (192 ) ^ 4. 03, SD = (K 57, · 3 p < 0.001). Here "((t (192) = 4.03)" represents the value of $ 192 degrees of freedom for t, and SD represents the difference between the average lifespan of the two groups. Standard deviation, n = — The p-shirt of i-inch is not dangerous.

2030-5943-PF (Nl); Chiumeow.ptd Page 124 200413503 V. Description of the invention (122) Based on the results of the test, it can be considered that the antioxidant function water inhibits the oxidation barrier from active milk, making nematode eyegayTs Extended life. Tongue oxygen can cause toxicity to living cells by generating oxidative barriers to intracellular molecules such as proteins and nucleic acids. That is, oxidative barriers from active oxygen species ^ aging-related events were clarified by the study of nematodes and fruit flies (refer to Shi and Jing Ming, "Mechanisms of Life-Span Determination in Nematodes", Cell Engineering v〇1. 21 N 〇7 2002; Agarwal et al., Proc. Natl. Acad. Sci. USA, 91 12332-12335, 1994; Larsen, PL, Proc. Natl.

Acad. Sci. U.S.A., 90, 8 90 5-89 0 9, 1 9 93; Sohal, r S ·, etc., J. Biol · chem ·, 2 70, 1 5 671 -1 5674, 1 995, etc.). This test is the same as these studies, confirming the results related to active oxidation barriers and aging. The present invention has been described in the embodiments, reference examples, and examples: ί Ϊ is an example of a redox pigment, but the oxidizing element that can be used in the present invention is not limited to this. For example, a linker can be used, 3. Acidic yellow pigment, acidic yellow pigment-25, acidic yellow pigment -19, acidic orange pigment M, acidic green-2 UK green pigment 25, acidic purple pigment 43, acidic brown pigment blue pigment -9, acid blue pigment: n pigment: 31, acid blue pigment_3, acid pigment-47, acid blue pigment—59 ', acid blue pigment—45, acid blue 1 1 rj Blue pigment-7, Acid blue pigment-113, Acid blue pigment-158, 王 王王孤 巴 京 酸 红 素-", Acid red, Acid red pigment_2, Bajing 18, Acid red pigment-27, Acidity 200413503 V. Description of the invention (123) Red pigment-3 7, Acid red pigment-5, Acid red pigment-5, Acid red pigment-87, Acid red pigment-88, Acid red pigment-91, Acid red pigment -92, Acid Red Pigment—94, Acid Red Pigment—95, Acid Red Pigment—11 1. Bath Pigment —2, solvent melanin_3, solvent blue pigment—7, solvent blue pigment—11, solvent blue pigment—25, solvent red pigment—3, solvent red pigment—1 9, solvent red pigment—23, solvent red pigment—24 Solvent red pigment-7 3 / direct yellow pigment-3, direct yellow pigment-9, direct yellow pigment-12, direct yellow pigment-59, direct green pigment-; [, direct green pigment-6, direct green pigment-59 , Direct brown pigment, direct brown pigment_6, direct melanin_4, direct melanin-22, direct melanin—38, direct blue pigment- 丨, direct blue pigment-6, direct blue pigment—53, direct blue pigment—86, Direct blue pigment 106, direct red pigment-2, direct red pigment-28, direct red pigment-79, disperse yellow pigment-3, disperse yellow pigment-5, disperse yellow pigment-8, disperse yellow pigment 42, as leaf pigment 60, disperse yellow pigment 64, disperse orange pigment 3, disperse orange pigment 30, disperse purple pigment 26, disperse purple pigment 28, disperse blue pigment 1, disperse blue pigment 26, disperse red pigment i, disperse red pigment 4, disperse red Pigment 60, Disperse Red Pigment 65, Disperse Red Pigment 73, Reduced Yellow 2, reduced green pigment 1, reduced green pigment 3, reduced brown pigment 1, reduced gramine pigment 3, reduced melanin 25, reduced blue pigment 1, reduced blue pigment 4, reduced blue pigment 2 0, reduced red pigment 1 0, reduced red Pigment 4 丨, pigment yellow pigment, pigment yellow pigment 3, pigment yellow pigment 10, pigment yellow pigment 12, pigment yellow pigment 13, pigment yellow pigment 14, pigment yellow pigment 17, pigment yellow pigment 24. Pigment Yellow Pigment 55, Pigment Yellow Pigment 81, Pigment Yellow Pigment 83, Pigment Yellow Pigment 93, Pigment Yellow Pigment 94, Pigment Yellow Pigment 95, Pigment Yellow Pigment 97, Pigment 200413503 V. Invention Explanation (124) ^ pigment 98, pigment yellow pigment 99, pigment yellow pigment ⑽ = / 110, pigment yellow pigment 116, pigment yellow II: Λ two pigment yellow pigment 151, pigment yellow pigment 154, color Pigment inspection pigment 5, pigment orange pigment 12, pigment pigment 14, pigment orange 1, pigment 36, pigment orange pigment 38, pigment orange pigment 40, pigment pigment 43, pigment green pigment 4 , Pigment Green Pigment 7, Pigment Green Pigment &, J Pigment Green Pigment 10, Pigment Green Pigment 36, Pigment Red Pigment i, Pigment Purple:? Pigment Purple Pigment 19, Color Purple pigment 23, pigment purple pigment 33 :, pigment pigment 25, pigment melanin i, pigment blue pigment 2, pigment blue 15: pigment blue pigment 16, pigment blue pigment 17, pigment blue pigment Factory 8, Pigment ^ Pigment 24, Pigment Red Pigment j, Pigment Red Pigment 3 Pigment Red Pigment $, 48: 1, Pigment Red Pigment 48 48: 4, Pigment Red Pigment 49 5 3: 1, Color Pigment Red Pigment 5 7 63: 2, Pigment Red Pigment 64 Pigment Red Pigment 88, Pigment Red Pigment 48: 3, Pigment Red Pigment, Pigment Red Pigment 5 2: 1, Pigment Red Pigment, Pigment Red Pigment 6 〇, Pigment Red Pigment, Pigment Red Pigment 81, Pigment Red Pigment 83, Pigment 11 2, Pigment Red Pigment 1 2 2, Pigment Red Pigment 123, Pigment Red Pigment 144, Pigment Red pigment 146, pigment red pigment 149, pigment red pigment 151, pigment red pigment 166, pigment red pigment 168, pigment red pigment 170, pigment red pigment 丨 74, pigment red pigment 175, pigment Red pigment 176, pigment red pigment 177, pigment red pigment 178, pigment red pigment 179, pigment red pigment 185, pigment red pigment 187, pigment red pigment 208, food yellow pigment 3, food green pigment 3, Magenta Pigment 6, Food Red Pigment 17, Basic Yellow Pigment 1, Basic Yellow Pigment 2, Basic Yellow Pigment u, Basic Pigment Red Pigment 9, Pigment Red Pigment 22, Pigment Red Pigment 38, Pigment Red Pigment 2030-5943-PF (Nl); Chiumeow.ptd p.127 (125) 200413503 sex orange pigment 1, basic orange pigment 1 1, basic green pigment 4, basic purple pigment 3, basic purple pigment 4, alkaline Basic purple pigment 10, basic purple pigment 14, basic brown pigment 1, basic blue pigment 1, basic blue pigment 3, basic blue pigment 9, basic blue pigment 2 Red pigment 5, Basic red pigment 5, Basic red pigment 9, Basic red pigment 18, Mordant yellow pigment], Mordant yellow pigment 3, Mordant orange pigment 1, Mordant red pigment 26, Mordant melanin u, Mordant blue pigment 13 Mordant blue pigment 29, Mordant red pigment 3, Mordant red pigment u, Mordant red pigment 1, 5, Reactive yellow pigment 2, Reactive yellow pigment 3, Reactive yellow pigment 17, Reactive orange pigment 1, Reactive orange pigment 2, reactive orange pigment 16, reactive purple pigment 2, reactive melanin 5, reactive blue pigment 2, reactive blue pigment 5, reactive blue 7. Reactive blue pigment 丨 9, reactive red pigment 1, reactive red pigment 3, reactive red pigment 6, reactive red pigment 17, reactive red pigment 22, reactive red pigment 41, and the like Acridine yellow G, alizarin, indantamine, indole aniline, indocyanine green, urethionone, uropurine, p-ethoxycristine hydrochloride, m-cresol purple, o- -Benzophenolphthalein, benzophenone red, crocetin, chlorophyll (a, b, c, d), chlorophenol red, neomethylene blue, neutral red, vanramine blue b, acid salts, fluorenyl violet Essence, pyocyanin, sulfonated indigo, saffron τ, phenol saffron, gabri blue, naru blue, diphenylamine, dibenzyl cyanide, nitrodiphenylamine, ferrospirin, N-phenylanthracene acid , 2, 6-dichloroindole sodium phenol, sodium 4-diphenylamine sulfonate, Ν, Ν-diphenylbenzidine, cinnabarin (antibiotics), toluidine blue, riboflavin (vitamin B2 ), Tetrazolium blue salt, tetrazolium blue reduced type (Di formazan) and the like. Among them, from the viewpoint that the color change in this titration is the same as that of methylene blue, it is preferable to use methyl viologen, where

2030-5943-PF (Nl); Chiumeow.ptd Page 128 200413503 V. Description of the invention (126) Lamin blue B hydrochloride, neutral red, continuation 彀 m, 2,6_dichloro · benzophenone Sodium / sodium sodium, N, N-diphenylbenzidine, cinnabarin (antibiotic), toluene blue, etc. ☆, 々ί: ί ί 3 In the implementation form, reference examples, and examples, platinum is used as an example of the precious metal colloidal catalyst used in the analysis of Ϊ 2 2 I, but 疋, shellfish is not a colloidal catalyst. Limited to ΓII, Γ indium, Shu, gold, silver, baht, and other precious metal elements =: colloidal particles such as mouthpieces, compounds, etc., or a mixture of these, finally, this is the γ g I + treatment of the present invention. The modification example at that time describes the "re-example of hydrogen; J = treatment = mouth, etc. = will turn colloid; body = etc. = reminder, ί treatment target site. Then q officials use-check: ΐί: ί : =; The plant is repressurized in the room,-the surface is gradually increased from the room or the room: supply to the re == plant slowly rises. At this time, the left side is s. And, for example, the chlorine gas composition oxygen content is adjusted to chlorine account for It is negligible because it is very small, and other pores (other gas components due to the body environment,-the surface from the room? Or the outside of the room = about 1 hour inside, I, toilet disgust look at the patient's appearance. Allow patients to be treated at the site of ^ ^ ^ ^ Γ, ^ λ 4 f ^ Λ (anti-oxidation target): the patient's body absorbs hydrogen discs that are contained in biological fluids (hydrogen-soluble water) Lung beer suction or skin exhalation meets the target site, and is common to the same target site :: Η 2030-5943-PF (Nl); Chiumeow.ptd page 129 200413503 5. Description of the invention (127) will be partially eliminated in The same as the active oxygen species of the target site. According to the hydrogen repressing treatment method, the therapeutic effect of the target site can be expected.

mil 2030-5943-PF (Nl); Chiumeow.ptd Page 130 200413503 Brief description of the diagram The first diagram is a diagram showing the Neilstein formula. Fig. 2 is a diagram illustrating Chuanda TFn 丄 Fig. 3 is a view of a lamp-free test. ^ ΰ ^ This figure illustrates an application example of the present invention. Fig. 4 is a schematic view showing a cleaning system 100 using the present invention. The fifth figure of the semiconductor substrate with several emulsification methods is a, which shows the use of the semi-reductive potential water generating device U basin of the present invention, the washing plate 100, and the sixth figure. The first figure shows the methylene blue structure. \ 之 向 长 ^ 面 图。 Electrolytic treatment of colloidal catalyst ^ Color change for adding platinum Figures 8 to 9 show the results of the evaluation test with Methylene Redox II ^ ^ Hydrogen solubility of colloidal catalyst too A 'Color change for adding platinum Figure 10 ~ Figure 11 shows the results of the reduction activity evaluation test. Hydrogen-soluble water of the palladium colloidal catalyst was added in accordance with the color change of osmium blue. Figures 12 to 3 show the results of the original evaluation test. Precious metal mixed (platinum + palladium) glue was added to the color change of 7 T solitary, and the result of valence test was performed. > Evaluation of the reducing activity of nitrogen-soluble water of a bulk catalyst for reducing activity. FIG. 14 shows the results of an evaluation test of the catalytic reduction activity of electrolyzed treated water (electrolysis, pasteurization, and addition of platinum colloids). Addition / electrolysis Addition after treatment) Figures 15 to 16 show the results of the color change of electrolytic mulch with platinum colloidal catalyst added with DppH. At 7th place, the test results of the evaluation of anti-gasification activity are shown in Figures 17 to 18, which show the anti-oxidation of hydrogen-soluble water added with DppH catalyst ^ (removal of 1 _ soil color changes and M demulsification + wind-sealed treatment). IM page 131 2030-5943-PF (Nl); Chiumeow.ptd 200413503

Chemical activity evaluation test results. f & change and add milk treatment + hydrogen sealing treatment) Figures 19 to 20 show the results of the hydrogen-soluble water (de-reducing activity evaluation test results) using a methylene enzyme hydrogen kinase catalyst. Figure 21 of reducing drops ~ Figure 22 illustrates the method for quantitative analysis of the dissolved hydrogen concentration using the redox pigment. ',', Emulsification value = To illustrate the measured value and actual value of the dissolved hydrogen concentration dh of various sample water Figure 24 illustrates the cytochrome Figure 25 of the c reduction method. Figure 25 is a diagram illustrating the adrenaline oxidation method. Figure 26 shows the free radical elimination activity exhibited by uranium-containing lice-soluble water over time, with the concentration of the transcolloid as the main parameter. The figure shows the concentration of palladium colloid as the main parameter, and the free radical elimination activity exhibited by the palladium-containing lice in water over time. :: Μ Figure 28 shows the platinum colloid concentration as the main parameter, and the graph containing platinum. Free radical elimination activity exhibited by water as a function of time. Figure 29 shows the concentration of (platinum + palladium) mixed colloid concentration as the main spring " ° + handle) of the hydrogen dissolved water of the mixed colloid catalyst '( Time-varying Characteristic chart: Soil 4 deactivation • Figure 30 shows the concentration of (platinum + palladium) mixed colloid as the main parameter, and the platinum ratio of platinum and palladium as the secondary main parameter. Figure 31 shows the concentration of (platinum + palladium) mixed colloid as the main parameter, and the figure shows this a molar ratio as the sub-primary parameter, including (platinum + ) Mixed Colloid Catalysis

2030-5943-PF (Nl); Chiumeow.ptd Page 132 Schematic illustration of the hydrogen-soluble water of the agent, ^ Figure 32 shows the free radical elimination activity with time. Special surname added an electrolytic treatment, carcass The concentration is the main parameter, and the platinum colloid catalyzes the second. Sex illustration. The elimination activity of free radicals exhibited by the water over time: The former figure 3 shows the ^ addition-channel electrolytic treatment of water, the body concentration is the main parameter, and the palladium colloidal catalyst is a property chart. The free radical elimination activity exhibited by k changes with time = ς Figure 34 shows the surface electrolysis treatment of Mito with added surface curvature; == parameters, the former graph of the colloidal catalyst. Table 35: Changes in radical elimination activity over time. Figure 35 shows the concentration of palladium colloids as the main component, and the cyclic palladium colloidal catalyst was added. Figure 36 shows the change in free radical elimination activity over time. Figure 36 shows the main parameter of AsA solution in water. // All = 7 The graph shows the difference between the types of precious metal catalysts as the main parameter: Second, the time-dependent change of free radical elimination activity shown by catalyst-containing chlorine-soluble water. ^ You ffl f I: The mechanism of action of platinum colloidal catalyst in aqueous solution of the coexistence system of oxygen and oxygen. FIG 39 represents a nitrogen ~ Di-t plurality dead of milk left J £ ,, memory Mi based catalyst of palladium colloid aqueous solution with the machine 1 at first turn. FIG. 40 shows the actual value of the argon dissolved water concentration DH in the examples. Figures 41 to 42 show the two-stage electrolytic treatment of a platinum-containing colloidal catalyst

2030-5943-PF (Nl); Chiumeow.ptd Page 133 200413503 Schematic illustration of the effect of water (A0W) on the lifespan of nematodes. Symbol description S ~ gap; 1 2 ~ DC power supply; 112 ~ lead outlet; 1 1 4 ~ outer box; 11 6 ~ electrode plate; 2 0 1 ~ electrode; 2 05 ~ cathode chamber; 2 0 9 ~ chamber; And 11 ~ reduction potential water generating device 111 ~ inlet; 113 ~ electrolysis chamber; 115 ~ diaphragm; 11 7 ~ electrode plate; 203 ~ diaphragm; 2 0 7 ~ anode chamber; 21 LED

2030-5943-PF (Nl); Chiumeow.ptd p.134

Claims (1)

ZUU413503 6. Scope of patent application 1 1 · An anti-oxidation method, which recognizes, collects, and extracts (but only removes those present in the body in advance) or: The process of making lice redox enzyme in hydrogen-dissolved water, Promote the formation of active hydrogen by using a colloidal catalyst as the substrate to form the product. Active hydrogen II: The oxidation state or the reaction to be prevented caused by the molecular particles contained in the Shen will be due to the lack of sufficient electrons in the reduced state. Emulsified antioxidants can become # 2. Antioxidant formulas such as those in the scope of patent application 苴 > Hydrogenase is a hydrogen kinase.彳 ', 刖 metal 32: = antioxidant method of Ί1, wherein the aforementioned precious metal colloid catalyst includes a box, & salts of these precious metal elements, Renjindouren ruthenium gold, silver, baht and itself, And mixtures of these. Method of colloidal particles such as 5, 5, and compound, 4 The oxidation resistance of any of the items 1 to 3 in the 4th item is at the anode and cathode: water containing hydrogen, including alkaline electrolytic water through the diaphragm, or ^ Original = filled treated water generated on the cathode side during electrolytic treatment / ', bubbling wind (aeration) or even pressurizing, 5. If any one of the scope of the patent application, the first to the third The anti-negative method, wherein the ORP value of the aforementioned hydrogen-dissolved water is 0 RP with a negative value of 0 R than that of Nilenstat II, and corresponds to a pH reduction potential water. Temple type, 〇RP = -59PH-8〇 (mv) The value obtained is still low. Method 6, .Πί around the anti-oxidation of any of the 1st to 5th (using oxidation to reduce oxygen ' Saturated concentration at atmospheric pressure is stored in the storage water. (Solution 2030-5943-PF (Nl); Quantitative analysis method for dissolved hydrogen concentration of emulsified reduction pigments; Chiumeow.ptd, page 135, 200413503.) 6. Application for patent scope Hydrogen concentration actual value conversion ) Hydrogen. 7. As described in the scope of patent application No. 1 ~ method, wherein the aforementioned hydrogen-soluble water is the electrolytic reduction potential water produced by the anti-oxidation of any one of the two members, the water produced by the water generation device The electrolysis room and the above-mentioned electricity are separated from each other. The original equipment is installed: the electrolysis room is sandwiched between the inside and outside of the electrolysis room. The plate is an anode and pressurized between the two poles: electricity = an electrode plate provided outside the electrolysis room is in contact with the aforementioned heart = electricity ^ application patent scope m. The method, wherein the above-mentioned hydrogen-soluble water is demulsified on demand Square thiosulfate, ascorbic acid, ascorbic sulfate, At least one of the original agents was selected from the group of “Bang Feng”. 9) For example, item 8 of the scope of the patent application—wherein the aforementioned anti-oxidation object is due to electron hypoxia 1: Oxidation method. The entire object to be oxidized includes living cells. Resentment or want to prevent ι〇. An antioxidant function water, characterized by the original enzyme ('Huai, in advance the removal of the organism, the emulsification of i also act on ammonia-soluble water in order to promote the promotion of molecules in the two-body catalyst The shape of hydrogen as a matrix forming product of active hydrogen :: Medium]: Second, lack of Lei Zaosuo; skin a, corpse knife long time 'will be due to the electricity in the oxidized state or want to become enough electrons Anti-emulsification target energy of reductive emulsification-Λ1, 'Shen: f's 10th range of antioxidant function water, of which, the wind-emulsifying reduction enzyme is hydrogen kinase. Page 136 200413503 VI. Application for patent scope 12. If applied Antioxidant function water in the scope of the patent No. 10, the aforementioned precious metal colloid catalyst in beans includes platinum, palladium, rhodium, indium, ruthenium, gold, silver, baht and salts, alloy compounds, complex compounds of these precious metal elements, etc. Body particles themselves, and mixtures of these. 13. For example, the antioxidant functional water according to any one of claims 10 to 12, wherein the catalyst is subjected to a treatment or operation to adjust the catalyst activity and / or reaction time. 1 4 · The antioxidant function water according to any one of items 丨 0 to 丨 3 in the scope of patent application, wherein the aforementioned hydrogen-soluble water is all water containing hydrogen, and the raw water is processed between the anode and the cathode through a separator. The alkaline electrolyzed water generated on the cathode side during the electrolytic treatment, or the water that has been bubbled (aerated) in the raw water or even subjected to pressure filling treatment. 15. The chemical-resistant functional water according to any one of the items 10 to 14 of the scope of the applied patent, wherein the aforementioned hydrogen-soluble water represents a negative value of 0 Rp and a value of 0 RP at pH is more than the Nylenstein formula; 〇Rp = _59pH_8〇 (mV) ^ lower reduction potential water. Value 16. If the η water in any one of items 10 to 15 of the scope of the patent application, wherein the aforementioned hydrogen-soluble water is dissolved in atmospheric water at atmospheric pressure, it is used: quantitative analysis of the dissolved hydrogen in the reduced pigment The method is based on the calculation of the dissolved mouse concentration (effective value) of hydrogen. 17. The water according to any one of the items 10 to 16 in the scope of the patent application, wherein the aforementioned hydrogen-dissolved water is generated using reducing potential water;: = electrolytic reduction potential *, the reducing potential water generating device = 入Raw water electrolysis chamber, one or more compartments that separate the aforementioned electrolysis chamber from the above = page 137 2030-5943-PF (Nl); Chiumeow.ptd 200413503 And at least one pair of plates, which are located inside and outside the electrolysis chamber to sandwich the diaphragm, and the electrode plate provided in the electrolysis chamber is used as the cathode: the electrode f is used as the anode, and the voltage is applied between the two poles. The electrode plate is in contact with the aforementioned diaphragm or through-hole = the aforementioned device. j. Gap breaking 1 8 · If the scope of application for patents No. 丨 0 ~ No. 丨 7: water, the aforementioned hydrogen-soluble water in * is added with a reason as needed: a reducing agent. At least 19. A bio-suitable liquid is selected from the group of articles. It is characterized by the anti-oxidation of any one of items 10 to 18: == rail enclosure made for use in the body, including drinking. # & Main ingredients, makeup and other uses. , For main shot, for drip, for dialysis, for chemistry. 0—A kind of antioxidant, its characteristics ▲ main " 18 21 ^ ^ ^ ^ ^ ^ 10 ^ any of items ~ 18: :: oxygen :: : The tenth anti-lice functional water is used as the Λ 22.-a kind of quality deterioration preventing agent, the main component of agriculture. Any of the 10th to the 18th Hanxi will be a kind of preservatives with a patent scope of 23 ·, which is specially used as the main component. Antioxidant of any of the 18 items ^ At ',,' Applicable to the 10th to 94th month of the patent scope of functional water as the main component. 2 4. 5 kinds of anti-turbidity agent, anti-oxidation in any one of items ~ item 18; dagger function paste No. 10 25.-a kind of deodorant, pot b ^ as the main component. Eight, * refers to the 10th to the 10th in the scope of patent application 2030-5943-PF (Nl); Chiumeow.ptd Page 138 200413503 VI. Application scope of patent 1 The antioxidant function water of any one of 8 items as the main component. 2 6. —A kind of freshness maintaining agent, which is characterized in that the antioxidant functional water of any one of items 10 to 18 of the scope of patent application is used as the main component. 2030-5943-PF (Nl); Chiumeow.ptd p. 139 111