TW200412274A - Method for cutting laminating sheets and laminating sheets and image display device - Google Patents

Method for cutting laminating sheets and laminating sheets and image display device Download PDF

Info

Publication number
TW200412274A
TW200412274A TW92129944A TW92129944A TW200412274A TW 200412274 A TW200412274 A TW 200412274A TW 92129944 A TW92129944 A TW 92129944A TW 92129944 A TW92129944 A TW 92129944A TW 200412274 A TW200412274 A TW 200412274A
Authority
TW
Taiwan
Prior art keywords
film
clamping
cutting
polarizer
light
Prior art date
Application number
TW92129944A
Other languages
Chinese (zh)
Other versions
TWI298662B (en
Inventor
Seiji Kondo
Kouji Kimura
Kazuki Tsuchimoto
Tomoaki Masuda
Original Assignee
Nitto Denko Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Denko Corp filed Critical Nitto Denko Corp
Publication of TW200412274A publication Critical patent/TW200412274A/en
Application granted granted Critical
Publication of TWI298662B publication Critical patent/TWI298662B/zh

Links

Abstract

The present invention relates to a cutting method for laminating sheets by precision cutting the cut surface of the laminating sheets that are cut rectangularly. The cutting method includes: a step of stacking plural sheets in the width direction and clamping the laminating sheets from opposite top and bottom faces by a clamping mechanism; a step of cutting the laminating sheets along the cut face with a rotating cutting tool under the state where plural laminating sheets are clamped together. The total area that is clamped by the clamping mechanism is 5 to 40% of the total area at both faces, being twice of the rectangular area of the laminating sheets. The clamping area includes four corners of the rectangular area, resulting in a non-clamping area that is not clamped by the clamping mechanism along at lest one of the long and short sides of the rectangular area.

Description

200412274 玖、發明說明:200412274 发明, Description of invention:

L發明戶斤屬之技術領域J 本發明是有關於將切斷為矩形之積層片之切斷面切削精 加工之積層片之切削加工方法、及藉該方法切削之積層片、以 5 及搭載有從該積層片得到之光學膜或光學元件之影像顯示裝 置。 L· JtTECHNICAL FIELD The present invention relates to a cutting method for a laminated sheet that is cut and finished by cutting a cut surface of a rectangular laminated sheet, and a laminated sheet cut by this method. An image display device having an optical film or an optical element obtained from the laminated sheet. L. Jt

將積層片(例如以光學膜層與黏著層形成者,亦稱積層膜) 切斷為預定之矩形尺寸時,係利用衝床用刀模等,對連續狀之 10 積層片之壓延材料進行切斷。該積層片作為偏光片使用時,係 以單軸或雙轴定向延伸加工,在切斷為矩形尺寸時以平行或略 平行於延伸方向切斷。這種情況,切斷面會產生纖維狀(鬍鬚 狀)破碎片。又,當含有黏著層時,黏著劑會因切斷時之壓力 而溢出。該破碎片之發生或黏著劑之溢出,會在後續步驟中成 15 為使品質降低的原因,故必須除去。When cutting a laminated sheet (for example, formed by an optical film layer and an adhesive layer, also referred to as a laminated film) to a predetermined rectangular size, the continuous rolling material of 10 laminated sheets is cut by using a die for a punch and the like. . When this laminated sheet is used as a polarizer, it is uniaxially or biaxially oriented and stretched, and when it is cut to a rectangular size, it is cut parallel or slightly parallel to the extending direction. In this case, fibrous (beard-like) fragments can be produced on the cut surface. When an adhesive layer is included, the adhesive may overflow due to the pressure at the time of cutting. The occurrence of the broken pieces or the overflow of the adhesive will cause 15 in the subsequent steps. This is the reason for reducing the quality and must be removed.

於是,目前已知的有在特開昭61-136746號公報中所揭示 之各向異性膜之切斷加工法。該加工方法係沿著具有各向異性 之膜之延伸軸施行切斷加工後,將切斷加工口切削加工。藉 此,可除去纖維狀破碎片等。 20 然而,上述先前技術中,談不上是以包含再現性之良好精 度來進行切削加工。亦即,將積層片切斷為矩形後,藉切削切 斷面來進行精加工時,仍必須包含再現性且以良好精度來加工 該精加工之尺寸。亦即,切削加工後,必須精加工為預定尺寸 之矩形。 5 【聲明内容】 本發明是有馨於上述實情而作成者,加,包含再現性且以_度 片、以及/之㈣加丄方法、及藉該方法切削之積層 4有從該縣片得狀絲膜或光學元件之 該課題係提供在將積 示裝置 影像顯 為了解決上述課題, 係將切斷為矩形之積層片 方法包含: 有關本發明之積層>!之糊加工方法 之切斷面切削精加工者,該切削加工 於厚度方向將多數片積層片於重疊之狀態下 從上下兩面將多數片之積層片夾持之步驟,·及 ’藉夾持機構 在夾持多數片積層片之狀態下 切斷面之步驟, 藉切削機構切削積層片之 、 述夾持機構之前述上下兩面之總夾持面積係相對 j層片之則述矩形面積之2倍而為5〜辦。,且夾持領域中包 =述矩敎四肖,㈣成前述矩形之-對長邊或-對短邊中 /、者上β又疋有不被兩述夹持機構所夾持之非夾持領域。 藉該構成,積層片在於厚度方向重疊多數片之狀態下,藉 夾持機構所失持。各積層片預储刀具切斷成預定大小。在失 持^係夾持位於最上面之積層片之上面、與位於最下面之積層 片之下面’本中賴發明人發現,藉由將上下兩面之總失持面 積設定成如下所述,即可以良好精度切削。 亦即,設積層片之上面(下面亦同)面積為s,則使總夹 持面積相對於2x s而為5〜4G%。又,在㈣時,包含矩形之 200412274 積層片之四角。又,並不是夾持矩形之全周長,而是針對構成 矩形之一對長邊或一對短邊中之至少一者,設定有非夾持領 域。藉採用這種夾持形態,可提供在將積層片之切斷面切削精 加工之際,可包含再現性且以良好精度進行加工之積層片之切 5 削加工方法。 本發明之適當實施形態可舉將下面側之夾持面積設定成 大於上面側之夾持面積。 使下面側之夾持面積大於上面側,可在安定之狀態下進行 夾持。 10 本發明之其他適當實施形態可舉位於夾持領域之夾持機 構係使用軟質材料。 使用軟質材料,可在不損傷積層片之狀態下進行夾持。 圖式簡單說明 第1圖是顯示切削方法之具體方法之圖。 15 第2圖是顯示切削方法之具體方法之圖(其他實施形態)。 第3 (a)〜3 (b)圖是顯示藉實施例之夾持領域之圖。 第4 (a)〜4 (b)圖是顯示藉比較例1之夾持領域之圖。 第5 (a)〜5 (b)圖是顯示藉比較例2之夾持領域之圖。 【實施方式1 20 利用圖式說明有關本發明之積層片之切削加工方法之適 當實施形態。首先,藉第1、2圖說明切削方法之具體方法。 <切削方法> 第1圖是顯示切削積層片之切斷面(端面)時,具有1個 旋轉刀具2 (相當於切削機構)之例。旋轉刀具2受旋轉驅動 7 200412274 但其旋轉中心不移動。取而代之的是,積層片1受驅動控制而 可在X (橫)、Y (縱)、Θ (旋轉)方向移動。藉由使積層片1 朝上述各方向移動,可切削切斷面之全周長。積層片1為矩形, 是長方形或正方形。 5 第2圖是顯示另一實施形態,其設有2個旋轉刀具2A,2B。Therefore, a cutting processing method of an anisotropic film disclosed in Japanese Patent Application Laid-Open No. 61-136746 is currently known. In this processing method, a cutting process is performed along an extension axis of an anisotropic film, and then a cutting processing port is cut. Thereby, fibrous broken pieces and the like can be removed. 20 However, in the above-mentioned prior art, it cannot be said that cutting is performed with good accuracy including reproducibility. In other words, when the laminated sheet is cut into a rectangular shape and the cutting section is used for finishing, it is still necessary to include reproducible and precise dimensions for the finishing. That is, after cutting, it must be finished into a rectangle of a predetermined size. 5 [Declaration content] The present invention was created with the above facts, and includes reproducible and multiplying methods by _degree slices and / or, and multilayers cut by this method. 4 The problem of the filamentary film or optical element is to provide an image of a display device to solve the above-mentioned problems, and the method of cutting a rectangular laminated sheet includes: cutting of the paste processing method of the laminated layer of the present invention >! For a surface-cutting finisher, this cutting process clamps a plurality of laminated sheets from the upper and lower sides in a state where the plurality of laminated sheets are overlapped in a thickness direction, and 'clamps a plurality of laminated sheets by a clamping mechanism. In the step of cutting the surface in the state, the total clamping area of the upper and lower surfaces of the clamping mechanism by cutting the laminated sheet by a cutting mechanism is 2 times the rectangular area of the j-layer sheet, and is 5 ~. In the gripping field, the moment = four moments of the moment, forming the rectangle of the above-for the long side or-for the short side /, or β, there is a non-clamp that is not clamped by the two clamping mechanisms. Holding field. With this configuration, the laminated sheet is lost by the clamping mechanism in a state where a large number of sheets are stacked in the thickness direction. The pre-stored cutters of each laminated sheet are cut to a predetermined size. In the misalignment ^, the uppermost laminated sheet is sandwiched between the uppermost laminated sheet and the lowermost laminated sheet, and the present inventor found that by setting the total misaligned area of the upper and lower sides as follows, Can be cut with good accuracy. That is, if the area of the upper layer (the same below) is s, the total holding area is 5 to 4G% relative to 2x s. In addition, the four corners of the rectangular 200412274 laminated sheet are included at the time. In addition, instead of the full perimeter of the clamping rectangle, a non-clamping region is set for at least one of a pair of long sides or a pair of short sides constituting a rectangle. By adopting this clamping form, it is possible to provide a cutting and cutting method for a laminated sheet which can be reproduced and processed with good accuracy when the cut surface of the laminated sheet is cut and finished. In a suitable embodiment of the present invention, the clamping area on the lower side can be set larger than the clamping area on the upper side. The clamping area on the lower side is larger than that on the upper side, and it can be clamped in a stable state. 10 In another suitable embodiment of the present invention, a clamping mechanism located in a clamping field may use a soft material. The soft material can be used for clamping without damaging the laminated sheet. Brief Description of Drawings Figure 1 is a diagram showing a specific method of the cutting method. 15 FIG. 2 is a diagram showing a specific method of the cutting method (another embodiment). Figures 3 (a) to 3 (b) are diagrams showing the clamping area of the embodiment. Figures 4 (a) to 4 (b) are diagrams showing the clamping area by Comparative Example 1. Figures 5 (a) to 5 (b) are diagrams showing the clamping area of Comparative Example 2. [Embodiment 1 20] A suitable embodiment of a cutting method for a laminated sheet according to the present invention will be described with reference to drawings. First, the specific method of the cutting method will be described with reference to Figs. < Cutting method > Fig. 1 shows an example in which a rotary cutter 2 (equivalent to a cutting mechanism) is provided when cutting a cut surface (end surface) of a laminated sheet. Rotary tool 2 is driven by rotation 7 200412274 but its center of rotation does not move. Instead, the laminated sheet 1 is driven to move in the X (horizontal), Y (vertical), and Θ (rotation) directions. By moving the laminated sheet 1 in each of the above directions, the entire circumference of the cut surface can be cut. The laminated sheet 1 is rectangular, and is rectangular or square. 5 FIG. 2 shows another embodiment, which is provided with two rotary tools 2A, 2B.

旋轉刀具2A,2B受驅動控制成僅可朝Y方向移動。又,積層片 1受驅動控制朝X、0方向。藉該構成,首先,同時切削矩形 之積層片1相向之長邊1 a,接著可同時切削相向之短邊1 b。在 長邊切削時與短邊切削時,只需改變2個旋轉刀具2A,2B之間 10 隔即可。又,在進行積層片1之切斷面切削時,係在將多數片 積層片1堆疊之狀態下進行。堆疊積層片1時,係使切斷面呈 整合之狀態。藉此,可同時加工多數片之積層片1,故加工效 率變佳。又,在進行切削加工之際,積層片1係在前步驟中事 先藉切斷裝置切斷為矩形等預定形狀。當然,切削方法並不限 15 定於第1圖、第2圖所示之方法。The rotary tools 2A and 2B are driven and controlled so as to move only in the Y direction. The laminated sheet 1 is driven in the X and 0 directions. With this configuration, first, the opposite long sides 1 a of the rectangular laminated sheet 1 are simultaneously cut, and then the opposite short sides 1 b can be simultaneously cut. For long-edge cutting and short-edge cutting, you only need to change the interval between the two rotary tools 2A, 2B. When cutting the cut surface of the laminated sheet 1, a plurality of laminated sheets 1 are stacked. When the laminated sheet 1 is stacked, the cut surfaces are brought into a state of integration. Thereby, the laminated sheet 1 of a plurality of sheets can be processed at the same time, so the processing efficiency becomes better. When the cutting process is performed, the laminated sheet 1 is cut into a predetermined shape such as a rectangle by a cutting device in the previous step. Of course, the cutting method is not limited to the method shown in Figures 1 and 2.

接著說明有關藉夾持機構所進行之夾持。為了使切削加工 安定進行,必須從上下方向將堆疊之積層片1夾持。這時,直 接受夾持機構之夾持力作用的是位於最上面的積層片1之上 面,及位於最下面的積層片1之下面。堆疊積層片1時,以堆 20 疊多數片尤其是10片以上為佳。 又,若設積層片1之矩形面積為S,則相對於矩形面積之 2倍(2x S),在夾持積層片1之際之上下兩面之夾持面積K為: K=2xSx (5〜40%) 藉此,可對切削加工之精度及再現性寄予期望。又,若以 8 200412274 下面側之夾持面積為ΚΙ,上面側之夾持面積為Κ2,則 Κ二Κ1 + Κ2 又,藉由使Κ1>Κ2,可使其為安定之夾持狀態。又,在夹 持時,必定使矩形之四角(第2圖中以lc表示)受到夾持。藉 5此,可使夾持更安定。在此所謂四角,係指切削加工後之矩形 (正方形、長方形)之積層片中,較端邊更内側之角部分。又 相向之一對長邊la、一對短邊lb當中至少一者形成有與失持 機構之非夾持領域。由於是至少一者,故可採取僅一對長邊Next, the clamping performed by the clamping mechanism will be described. In order to stabilize the cutting process, the stacked laminated sheets 1 must be sandwiched from the up-down direction. At this time, the clamping force directly received by the clamping mechanism acts on the upper surface of the uppermost laminated sheet 1 and on the lower surface of the lowermost laminated sheet 1. When stacking the laminated sheets 1, it is preferable to stack a plurality of sheets, especially 10 or more sheets. In addition, if the rectangular area of the laminated sheet 1 is S, the clamping area K of the upper and lower sides when the laminated sheet 1 is sandwiched is 2 times (2x S) the rectangular area: K = 2xSx (5 ~ 40%) With this, you can expect the accuracy and reproducibility of cutting. In addition, if the clamping area on the lower side is KI and the clamping area on the upper side is KK2, then K2K1 + KK2 can be made into a stable clamping state by making κ1> K2. When clamping, the four corners of the rectangle (indicated by lc in the second figure) must be clamped. With this, the clamping can be made more stable. Here, the four corners refer to the corner portion of the laminated sheet of the rectangle (square, rectangle) after cutting, which is more inside than the end edge. At least one of a pair of long sides la and a pair of short sides lb opposite to each other forms a non-clamping area with a dislocation mechanism. Since it is at least one, only one pair of long sides can be taken

la、僅一對短邊lb、或一對長邊la與一對短邊沁兩者之任一 10種。藉由採用這些夾持方法,可提高切削精度,使再現性良好。 藉爽持機構夾持時,進行夾持之夾騎料讀f材料為 佳,該軟質材料可舉由NBR、SBR,Si等形成之橡膠系材料或 高分子樹脂這種塑膠材料。又,這些軟質材料之硬度(打8八) 以60〜80。為佳。若硬於這個範圍以上,則積層片上會形成由 15夾持機構造成的壓痕,若軟於這個範圍以上,則會因軟質材料la, only a pair of short sides lb, or any one of a pair of long sides la and a pair of short sides. By adopting these clamping methods, cutting accuracy can be improved and reproducibility can be improved. When clamping by the holding mechanism, the clamping material is preferably used for reading. The soft material can be a rubber-based material such as NBR, SBR, Si, or a plastic material such as a polymer resin. In addition, the hardness of these soft materials (hitting 8 to 8) ranges from 60 to 80. Better. If it is harder than this range, an indentation caused by the 15 clamping mechanism will be formed on the laminated sheet. If it is softer than this range, it will be caused by soft materials.

之變形而發生位置錯動,使切削精度降低。這時的按壓壓力設 定為 2kg/cm2〜l〇kg/cm2。 又 <積層片之具體例> 積層片可使用藉黏著劑積層各種構件者,並無特別限制, 20 而本發明適用於光學構件。 光學構件可舉例如於偏光鏡之單面或雙面隔著黏著劑層 積層有透明保護膜之偏光片。 偏光鏡並無特別限制,可使用各種。作為偏光鏡者可舉例 如使聚乙神賴、部分甲祕化聚乙㈣系膜、乙稀•乙稀 9 200412274 乙酸共聚合物系部分皂化膜等親水性高分子膜内吸著碘或二 色性染料等二色性物質單軸延伸者、聚乙烯醇之脫水處理物或 聚氯乙烯之脫氯酸處理物等多烯系定向膜等。這當中又以聚乙 烯醇系膜與碘等之二色性物質形成之偏光鏡為佳。這些偏光鏡 5 之厚度並無特別限定,一般為5〜80/zm。Deformation causes positional displacement, which reduces cutting accuracy. The pressing pressure at this time is set to 2 kg / cm2 to 10 kg / cm2. ≪ Specific examples of laminated sheets > The laminated sheets can be laminated with various members by an adhesive, and there is no particular limitation. 20 The present invention is applicable to optical members. The optical member may be, for example, a polarizer having a transparent protective film laminated on one or both sides of a polarizer with an adhesive layer laminated thereon. The polarizer is not particularly limited, and various types can be used. As a polarizer, for example, a hydrophilic polymer film such as polyethylene glycol, partially methylated polyethylenimide-based film, and ethylene 9 200412274 acetic acid copolymer type partially saponified film can absorb iodine or two. Uniaxial elongation of dichroic materials such as chromatic dyes, polyene-based oriented films such as dehydrated products of polyvinyl alcohol or dechlorinated products of polyvinyl chloride. Among these, a polarizer formed of a polyvinyl film and a dichroic substance such as iodine is preferred. The thickness of these polarizers 5 is not particularly limited, but is generally 5 to 80 / zm.

將聚乙烯醇系膜以碘染色之單軸延伸之偏光鏡,可以例如 藉由將聚乙烯醇浸潰於碘水溶液中來染色,並延伸為原長之 3〜7倍來製作。亦可因應需要浸潰於含有硼酸或碘化鉀等水溶 液中。更可因應需要,於染色前將聚乙烯醇系膜浸潰於水中水 10 洗。藉由水洗聚乙烯醇系膜,不僅可洗淨聚乙烯醇系膜表面之 污垢或阻塞防止劑,且有使聚乙烯醇系膜膨脹來防止染色斑駁 等不均之效果。延伸係可在以碘染色後進行,或於染色之同時 進行延伸,或於延伸後再以碘染色皆可。也可在硼酸或碘化鉀 等水溶液中或於水浴中延伸。 15 設於前述偏光鏡之單面或雙面之透明保護膜,以透明性、A uniaxially-extended polarizer in which a polyvinyl alcohol-based film is dyed with iodine can be produced, for example, by immersing a polyvinyl alcohol in an iodine aqueous solution and stretching it to 3 to 7 times its original length. If necessary, it can be immersed in an aqueous solution containing boric acid or potassium iodide. If necessary, the polyvinyl alcohol film is immersed in water and washed before dyeing. Washing the polyvinyl alcohol-based film with water not only cleans the dirt or clogging preventive agent on the surface of the polyvinyl alcohol-based film, but also has the effect of expanding the polyvinyl alcohol-based film to prevent unevenness such as staining. The extension system may be performed after dyeing with iodine, or may be extended at the same time as dyeing, or may be dyed with iodine after extension. It can also be extended in an aqueous solution such as boric acid or potassium iodide or in a water bath. 15 A single or double-sided transparent protective film provided on the aforementioned polarizer, with transparency,

機械性強度、熱安定性、水分遮蔽性、各向同性等皆很優異者 為佳。透明保護膜之材料可舉例如聚乙烯對苯二甲酸酯或聚乙 烯萘二甲酸酯等聚酯系聚合物、雙乙醯纖維素或三乙醯纖維素 等纖維素系聚合物、聚曱基甲基丙烯酸酯等丙烯酸系聚合物、 20 聚苯乙烯或丙烯腈•苯乙烯共聚合物(AS樹脂)等之苯乙烯 系聚合物、聚碳酸酯系聚合物等。又,具有聚乙烯、聚丙烯、 環系乃至去曱莰構造之聚烯烴、如乙烯·丙烯共聚合物之聚烯 烴系聚合物、氯乙烯系聚合物、耐綸或芳香族聚醯胺等之醯胺 系聚合物、醯亞胺系聚合物、颯系聚合物、聚醚颯系聚合物、 10 I麵_系聚合物、聚伸苯基硫化物系聚合物、乙嫌 物、低知 、蜉系聚合 一苟軋乙烯系聚合物、聚乙烯醇縮丁醛系聚合物、烯丙酽二 聚合物'聚甲醛系聚合物、環氧系聚合物、 曰糸 合物辇▲日 ]述水3物之摻 奶寺也是可舉出之可作為形成前述透明保護膜之聚人物 例子。可舉將丙烯酸系或胺酯系、丙烯胺酯系或環氧系、产 氧系等之熱硬化型或紫外線硬化型之樹脂薄膜化者等。 透明保護膜之厚度一般為500/zm以下,以^3^“^ 仏。尤其以5〜200 // m為佳。 透明保護膜基於偏光特性或耐久性等點,以三乙隨 _ 纖維素 寻纖維素系聚合物為佳,尤以三乙醯纖維素膜為佳。又,# 右為 在偏光鏡之兩側設置透明保護膜之情況,則該表裡可使用由相 同聚合物材料形成之透明保護膜,亦可使用由不同聚合物材料 等形成之透明保護膜。 又,特開2001-343529號公報(W001/37007)中所記裁之 水合物膜’可舉例如含有(a)側鏈上具有取代及/或非取代酸 胺基之熱可塑性樹脂、及(B)側鏈上具有取代及/或非取代笨 基以及腈基之熱可塑性樹脂之樹脂組成物。具體例可舉含有由 異丁烯與N-甲基順丁烯二醯亞胺形成之交互共聚合物及丙埽 腈•苯乙烯共聚合物之樹脂組成物之膜。膜可使用由樹脂組成 物之混合押出品等所形成之膜。 又’透明保護膜以盡可能沒有著色為佳。因此,宜使用: 以Rth=[ (nx+ny) /2-nz] · d (唯,nx、ny為膜平面内之主折射 率、nz為膜厚度方向之折射率、d為膜厚)所表示之膜厚度方 向之相位差值為-如加^〜+75nm之保護膜。藉由使用該種厚度方 200412274 向之相位差值為-90nm〜+75nm者,可幾乎消除起因於保護滕之 偏光片之著色(光學性染色)。厚度方向之相位差值(Rth)又 以-80nm〜+60nm為佳,尤其以_70nm〜·^45nm為佳。 前述透明保護膜之未黏著偏光鏡之面,亦可施行以硬罩層 5 或反射防止處理、黏結防止或擴散乃至抗眩光為目的之處理。 硬罩處理係以防止偏光片表面之損傷為目的所施行者,可 藉由將藉丙烯酸系、聚石夕氧系等適宜之紫外線硬化型樹脂形成 之硬度或滑動特性上很優異之硬化皮膜附加於透明保護膜表 面等方式來形成。反射防止處理係以防止偏光片表面之外光之 10反射為目的而施行者,可按照習知之反射防止膜等之形成來達 成。又,黏結防止處理係以防止與鄰接層之密著為目的而施行 者0 15 20Those having excellent mechanical strength, thermal stability, moisture shielding property, and isotropy are preferred. Examples of the material for the transparent protective film include polyester polymers such as polyethylene terephthalate and polyethylene naphthalate, cellulose polymers such as diacetyl cellulose and triethyl cellulose, and polymers Acrylic polymers such as fluorenyl methacrylate, styrene polymers such as 20 polystyrene or acrylonitrile-styrene copolymer (AS resin), polycarbonate polymers, etc. In addition, polyolefins having polyethylene, polypropylene, ring-based or even plutonium structures, polyolefin-based polymers such as ethylene-propylene copolymers, vinyl chloride-based polymers, nylon or aromatic polyamides, etc. Fluorene-based polymer, fluorene-based imine-based polymer, fluorene-based polymer, polyether fluorene-based polymer, 10 I-plane polymer, polyphenylene sulfide-based polymer, ethylbenzene,聚合 -based polymerized vinyl polymer, polyvinyl butyral-based polymer, allyl 酽 dipolymer 'Polyoxymethylene-based polymer, epoxy-based polymer, 糸 糸 辇The three-mixed milk temple is also an example of a character that can be used to form the aforementioned transparent protective film. Examples thereof include thinning an acrylic or amine ester-based, acrylamine-based, epoxy-based, or oxygen-generating thermosetting or ultraviolet-curing resin. The thickness of the transparent protective film is generally less than 500 / zm, and ^ 3 ^ "^ 仏. Especially preferably 5 ~ 200 // m. The transparent protective film is based on polarizing characteristics or durability, etc. A cellulose-based polymer is preferred, especially a triethyl cellulose film. Also, # right is a case where a transparent protective film is provided on both sides of the polarizer, and the surface and the surface can be formed of the same polymer material. As the transparent protective film, a transparent protective film formed of different polymer materials, etc. may be used. The hydrate film described in JP 2001-343529 (W001 / 37007) may include, for example, (a) Thermoplastic resins having a substituted and / or unsubstituted acid amine group on the side chain, and (B) resin compositions of a thermoplastic resin having a substituted and / or unsubstituted benzyl group and a nitrile group on the side chain. Specific examples include A film containing a resin composition of an interactive copolymer of isobutylene and N-methylcisbutene diamidine and a propionitrile / styrene copolymer. The film can be a mixed extruded product made of a resin composition, etc. The formed film. Also 'transparent protective film with as little as possible The color is better. Therefore, it should be used: Rth = [(nx + ny) / 2-nz] · d (only, nx, ny are the main refractive index in the film plane, nz is the refractive index in the film thickness direction, d The film thickness direction indicates the phase difference in the film thickness direction-such as adding a protective film with ^ ~ + 75nm. By using the thickness of 200412274, the phase difference in the direction of -90nm ~ + 75nm can be almost eliminated It is caused by the coloring (optical dyeing) of the polarizer that protects Teng. The retardation value (Rth) in the thickness direction is preferably -80nm ~ + 60nm, especially _70nm ~ · ^ 45nm. The aforementioned transparent protective film The surface without the polarizer attached can also be treated with hard cover layer 5 or reflection prevention treatment, adhesion prevention or diffusion, or anti-glare treatment. The hard cover treatment is performed for the purpose of preventing damage to the surface of the polarizer. It is formed by attaching a hardened film with excellent hardness or sliding characteristics formed from suitable UV-curable resins such as acrylic and polylithic oxygen-based resins to the surface of a transparent protective film. The anti-reflection treatment is used to prevent polarizers. 10 reflections of light outside the surface , Can prevent the formation of the film according to the conventional reflection up to. Further, the adhesive-based prevention processing performed for the purpose of preventing adhesion between adjacent layers and by 01,520

又’抗眩光處理係為了防止外光在偏光片之表面反射而 礙偏光片透過光之目視辨認等目的而施行者,可藉由例如藉 /方式或紋加工方式等之粗面化方式、或透明微粒子之混 方式等適宜之方式於透明保護膜表面料微細凹凸構造來 成。前述表面微細凹凸構造之形成中,作為其中所含之微粒 者可使用例如平均粒子徑G.5〜5G//m之二氧化♦、氧化紹、 氧化鈦、氧化鍅、氧化錫、氧化銦、氧⑽、氧化銻等所形 之具導電性之無機系微粒子,及交聯或未交聯之聚合物等形 之有機系微粒子等之透明微粒子。形成表面微細凹凸構造時 微粒子,使用量係相對於形成表面微細凹凸構造之透明樹 100重里部’ 一般為2〜50重量部,又以5〜25重量部為佳。 可使抗眩光層兼作擴散層(擴大可視角機能等),使偏光片 12 200412274 過光擴散來擴大可視角等。 又,前述反射防止層、黏結防止層、擴散層或抗眩光層等 係可設為透明保護膜,此外亦可作為其他用途光學層而與透明 保護膜作為不同個體來設置。 5 前述偏光鏡與透明保護膜之黏著處理中,可使用各種水系 黏著劑。水系黏著劑可舉例如聚乙烯醇系黏著劑、明膠系黏著 劑、乙烯系乳膠系、水系聚胺甲酸酯、水系聚酯等。前述黏著 劑通常作為由水溶液形成之黏著劑來使用。The anti-glare treatment is performed in order to prevent external light from reflecting on the surface of the polarizer and prevent the polarizer from visually recognizing the transmitted light. For example, it can be roughened by lending / method or texture processing method, or A suitable method such as a method of mixing transparent fine particles is formed on the surface of the transparent protective film with a fine uneven structure. In the formation of the fine uneven structure on the surface, as the particles contained therein, for example, an average particle diameter of G.5 to 5G // m of dioxide, oxide, titanium oxide, hafnium oxide, tin oxide, indium oxide, Conductive inorganic fine particles in the form of osmium oxide, antimony oxide, etc., and transparent fine particles in the form of organic particles, such as crosslinked or uncrosslinked polymers. When forming the fine uneven structure on the surface, the amount of fine particles used is 100 to the weight of the transparent tree forming the fine uneven structure on the surface. It is generally 2 to 50 parts by weight, and preferably 5 to 25 parts by weight. The anti-glare layer can also be used as a diffusion layer (enlargement of the viewing angle function, etc.), and the polarizer 12 200412274 can diffuse the light to expand the viewing angle. The anti-reflection layer, the anti-adhesion layer, the diffusion layer, or the anti-glare layer may be provided as a transparent protective film, or may be provided as an optical layer for other purposes as a separate unit from the transparent protective film. 5 In the aforementioned polarizing lens and transparent protective film, various water-based adhesives can be used. Examples of the water-based adhesive include polyvinyl alcohol-based adhesives, gelatin-based adhesives, vinyl-based latexes, water-based polyurethanes, and water-based polyesters. The aforementioned adhesive is generally used as an adhesive formed from an aqueous solution.

前述黏著劑中藉著含有水溶性交聯劑而可使凝膠強度增 10 加,使黏著性提昇。聚乙烯醇系黏著劑中,可含有硼酸、硼砂、 戊二酸、三聚氰胺、草酸等水溶性交聯劑。水溶性交聯劑之添 加量並無特別限制,通常相對於聚乙烯醇等主材之固體成分 100重量份,而在40重量份以下,又以0.5〜30重量份為佳。 又,為了使交聯進行,前述黏著劑亦可變化pH。更,調製該水 15 溶液之際,可因應必要在前述黏著劑中混合甲酸、苯酚、水楊 酸、苯甲醛等防腐劑。By including a water-soluble crosslinking agent in the aforementioned adhesive, the gel strength can be increased by 10, and the adhesiveness can be improved. The polyvinyl alcohol-based adhesive may contain a water-soluble crosslinking agent such as boric acid, borax, glutaric acid, melamine, and oxalic acid. The amount of the water-soluble cross-linking agent to be added is not particularly limited, and it is usually preferably from 0.5 to 30 parts by weight relative to 100 parts by weight of the solid content of the main material such as polyvinyl alcohol, and less than 40 parts by weight. Moreover, in order to make crosslinking progress, the said adhesive agent may change pH. Furthermore, when preparing this aqueous solution, preservatives such as formic acid, phenol, salicylic acid, and benzaldehyde may be mixed with the aforementioned adhesive as necessary.

偏光鏡與透明保護膜之貼合可藉積層機(roll laminator) 等來進行。黏著劑之厚度並無特別限制,通常為0.05〜5/zm。 前述偏光鏡在實用之際,可作為與其他光學層積層之光學 20 膜來使用。關於該光學層並無特別限制,可使用1層或2層以 上之例如反射片或半透過片、相位差片(包含1/2或1/4等波 長片)、視角補償膜等用於形成液晶顯示裝置等之光學層。特 別是於本發明之偏光片上更積層有反射片或半透過反射片之 反射型偏光片或半透過型偏光片、偏光片上更積層有相位差片 13 200412274 之橢圓偏光片或圓偏光片、偏光片上更積層有可視角補償膜之 廣可視角偏光片、或是偏光片上更積層有亮度提升膜之偏光片 為佳。 反射型偏光片係於偏光片設置反射層者,係用以形成使發 5 自目視辨認側(顯示側)之入射光反射而顯示之類型之液晶顯 示裝置等者,具有可省略内藏背光等光源、容易達到液晶顯示 裝置之薄型化等優點。反射型偏光片之形成,可因應需要,隔 著透明保護層等而於偏光片之單面附設由金屬等形成之反射 層之方式等適宜之方式來進行。 10 反射型偏光片之具體例,可舉例如:因應需要而在業已施 行褪光處理之透明保護膜之單面上,附設由鋁等反射性金屬形 成之金屬薄片或蒸鍍膜來形成反射層者等。又,亦可舉使前述 透明保護膜中含有微粒子作成表面微細凹凸構造,且其上具有 微細凹凸構造之反射層者等。前述微細凹凸構造之反射層具 15 有:藉漫反射使入射光擴散而防止指向性或刺眼之外觀、抑制 明暗不均句等優點。又,含有微粒子之透明保護膜具有在入射 光及其反射光透過該保護膜時可使之擴散,而更進一步抑制明 暗不均勻之優點。反映出透明保護膜之表面微細凹凸構造之細 微凹凸構造反射層之形成,可藉由例如以真空蒸鍍方式、離子 20 鍍方式、濺射方式等蒸鍍方式或電鍍方式等適宜之方式,將金 屬直接附加於透明保護層表面之方法等來進行。 反射片亦可在按照該透明膜之適宜之膜上設置反射層而 作成反射膜等來使用,代替前述之於偏光片之透明保護膜上直 接賦予之方式。又,由於該反射層通常由金屬形成,因此若採 14 200412274 取該反射面為透明保護膜或偏光片等所覆蓋之狀態,則該使用 形態可防止因氧化導致之反射率降低,進一步可長期維持初期 反射率、以及可避免另外附設保護層等,因此更適宜。 又,半透過型偏光片係可藉由作成以上述反射層使光反射 5 且透過之半透明反射鏡等之半透過型反射層而得到。半透過型 偏光片通常設於液晶晶胞之裡側,可形成如下述類型之液晶顯 示裝置等,即,在相對較明亮之環境中使用時,使發自目視辨 10 認侧(顯示側)之入射光反射來顯示影像,而在相對較暗之環 境下,則使用内藏於半透過型偏光片之背側之背光等之内藏光 源來顯示影像之類型。亦即,在形成這種在明亮之環境下,可Lamination of the polarizer and the transparent protective film can be performed by a roll laminator or the like. The thickness of the adhesive is not particularly limited, and is usually 0.05 to 5 / zm. The aforementioned polarizer can be used as an optical 20 film laminated with other optical layers when practical. The optical layer is not particularly limited, and one or more layers such as a reflection sheet or a semi-transmissive sheet, a retardation film (including a 1/2 or 1/4 wavelength plate), a viewing angle compensation film, and the like can be used for formation. An optical layer of a liquid crystal display device or the like. In particular, a reflective polarizer or a transflective polarizer with a reflective sheet or a transflective reflective sheet further laminated on the polarizer of the present invention, an elliptical polarizer or a circular polarizer, polarized light with a retarder 13 200412274 laminated on the polarizer. A wide-viewing-angle polarizer with a viewing-angle compensation film further laminated on the sheet, or a polarizing film with a brightness enhancement film further laminated on the polarizer is preferable. Reflective polarizers are those that have a reflective layer on the polarizer. They are used to form a type of liquid crystal display device that reflects the incident light emitted from the visual recognition side (display side). It has a built-in backlight and can be omitted Light source, easy to achieve thinness of liquid crystal display device, etc. The formation of the reflective polarizer can be performed by a suitable method such as a method of attaching a reflective layer made of metal or the like to one side of the polarizer through a transparent protective layer or the like, as needed. 10 Specific examples of reflective polarizers include, for example, a metal film or a vapor-deposited film made of a reflective metal such as aluminum on one side of a transparent protective film that has been subjected to a matte treatment as needed to form a reflective layer. Wait. Further, the transparent protective film may include fine particles having a fine uneven structure on the surface and a reflective layer having a fine uneven structure on the surface. The above-mentioned reflective layer having a fine uneven structure has the advantages of diffusing incident light by diffuse reflection to prevent directivity or dazzling appearance, and suppressing uneven light and dark sentences. In addition, a transparent protective film containing fine particles has the advantage that incident light and reflected light can be diffused when the protective film is transmitted through the protective film, and the unevenness of light and darkness is further suppressed. The formation of the fine uneven structure reflecting layer reflecting the fine uneven structure on the surface of the transparent protective film can be performed by an appropriate method such as a vacuum evaporation method, an ion 20 plating method, a sputtering method, or an electroplating method. A method of directly adding a metal to the surface of the transparent protective layer is performed. The reflective sheet may be provided with a reflective layer on a suitable film according to the transparent film, and used as a reflective film, instead of the method of directly providing the transparent protective film on the polarizer described above. In addition, since the reflective layer is usually formed of metal, if the reflecting surface is covered by a transparent protective film or a polarizer, etc., the use form can prevent the reflectance from being lowered due to oxidation, and can be used for a long time. It is more suitable to maintain the initial reflectance and avoid the need for an additional protective layer. A semi-transmissive polarizer can be obtained by forming a semi-transmissive reflective layer such as a translucent mirror that reflects light through the reflective layer 5 and transmits the light. The transflective polarizer is usually located on the back side of the liquid crystal cell, and can be used to form liquid crystal display devices such as the following types. That is, when used in a relatively bright environment, it can be seen from the visual recognition side (display side). The incident light is reflected to display the image, and in a relatively dark environment, the type of image is displayed using a built-in light source such as a backlight built into the back side of the transflective polarizer. That is, in forming such a bright environment,

印約为光專之光源使用之能源’而即使在相對較p 可用内藏光源來使用之類型之液晶顯示裝置等上, 光片是有用的。 之環境下仍 半透過型偏 15 20 接著就偏光片上更積層有相位差片所形成之橢圓偏夫 或圓偏光片說明之。在將直線偏光改變為橢圓偏光戈口 或將橢圓偏光或圓偏光改變為直線偏光,或改變直線偏、> 光方向時’可使用相位差片等。特別是將直線偏光改變為厦 光或將圓偏光改變為直線偏光之相位差片,可使用所^ Η 長片(又稱λ/4片)。而1/2波長片(又稱λ/2 於改變直線偏光之偏光方向之情況。 橢圓偏光片可補償(防止)超扭轉向列(STN)型广Ε 示裝置之液晶層因複折射產生之著色(青或黃),可有咬2 於前述無著色之黑白顯示之情況等。更,控制二次_ 4 、: 由於亦可補償(防止)從斜方向看液晶顯示裝置之影像昉』The light source is used as an energy source for a light source, and a light sheet is useful even on a liquid crystal display device or the like that can be used with a built-in light source. In the environment, the semi-transmissive polarization is 15 20. Then, the elliptical or circular polarizer formed by the retardation film laminated on the polarizer will be explained. When changing linearly polarized light to elliptically polarized light, or changing elliptically or circularly polarized light to linearly polarized light, or changing linearly polarized light, > light direction ', a retardation film can be used. In particular, for a phase difference film that changes linearly polarized light to Xiaguang or circularly polarized light to linearly polarized light, the long film (also called λ / 4 film) can be used. The 1/2 wavelength plate (also known as λ / 2 is used to change the polarization direction of linear polarized light. The elliptical polarizer can compensate (prevent) the super-twisted nematic (STN) type wide-angle display device ’s liquid crystal layer due to birefringence Coloring (cyan or yellow), there may be bite 2 in the aforementioned black and white display without coloring, etc. More, control secondary _ 4 :: It can also compensate (prevent) the image of the liquid crystal display device viewed from an oblique direction.

15 20041227415 200412274

之著色,故更適宜。圓偏光片在例如用以調整影像變為彩色顯 示之反射型液晶顯示裝置之影像之色調時很有效,且也具有防 止反射之機能。上述相位差片之具體例可舉如聚碳酸酯、聚乙 烯醇、聚苯乙烯、聚甲基甲基丙烯酸酯、聚丙烯或其他聚烯烴、 5 聚烯丙酯、聚醯胺之適宜聚合物形成之膜施以延伸處理而成之 雙折射性膜或液晶聚合物之定向膜、以膜支持液晶聚合物之定 向層者。相位差片可以是具有因應各種使用目的之適當相位差 者;所謂各種使用目的係例如以補償因各種波長片或液晶層之 雙折射造成之著色或可視角等為目的,而相位差片也可以是積 10 層2種以上的相位差片以抑制相位差等之光學特性者。 又,上述橢圓偏光片或反射型橢圓偏光片係將偏光片或反 射型偏光片與相位差片以適當之組合積層者。該橢圓偏光片等 可藉由在液晶顯示裝置之製造過程中將(反射型)偏光片與相 位差片依序個別積層,使這些片組合來形成,不過若為如前所 15 述之事先作成橢圓偏光片等之光學膜者,則具有品質之安定性 或積層作業性等優異、可提升液晶顯示裝置等之製造效率等優 點。 可視角補償膜係用以擴大可視角,可在當從不是垂直於畫 面、而是從稍微傾斜之方向來看液晶顯示裝置之影像時,使畫 20 面看起來較為鮮明。這種可視角補償相位差片係由在例如相位 差片、或液晶聚合物等定向膜、或透明基材上載有液晶聚合物 等之定向層者等所形成。一般之相位差片係使用在其面方向具 有單軸延伸之雙折射之聚合物膜,相對的,作為可視角補償膜 來使用之相位差片係使用於面方向具有雙軸延伸之雙折射之 16 200412274 聚合物膜、或具有於面方向單軸延伸且厚度方向亦延伸之控制 厚度方向之折射率之雙折射率之聚合物、或如傾斜定向膜之二 方向延伸膜等。傾斜疋向膜可舉例如:使熱收縮膜接著於聚合 物膜並加熱產生收縮力,在該收縮力之作用下將聚合物膜延伸 5處理或/及收縮處理者、或使液晶聚合物傾斜定向者等。相位差 片之素材原料聚合物係使用與先前在相位差片中說明之聚合 物相同者,可使用對於達到:防止基於因液晶晶胞之相位差之 目視辨認角之變化所產生之著色等、或好的目視辨認之可視角 擴大等目的上適宜者。 10 又,基於達成擴大好的目視辨認可視角這點等,可適宜地 使用以三乙醯纖維素膜載有液晶聚合物之定向層;特別是盤狀 液晶聚合物之傾斜定向層所形成之光學性各向異性層之光學 補償相位差片。 業已貼合偏光片與亮度提升膜之偏光片,通常係設於液晶 15晶胞之裡側來使用。亮度提升膜係具有當液晶顯示裝置等之背 光或自然光藉由從裡側之反射等而入射時,即反射預定偏光軸 之直線偏光或預疋方向之圓偏光,且使其他光透過這樣的特性 者,而將亮度提升膜與偏光片積層之偏光片,則使來自背光等 光源之光入射而得到預定偏光狀態之透過光,同時使預定偏光 20狀態以外之光不透過地反射,使在該亮度提升膜面反射之光經 由設於更後側之反射層等而反轉,再入射到亮度提升膜上,使 其局部或全部透過作為預定偏光狀態之光以增加透過亮度提 升膜之光量,同時供給難以為偏光鏡所吸收之偏光以增大可利 用於液晶顯示影像顯示等之光量,藉此使亮度提升者。亦即, 17 不利用党度提升膜、並以背光等使光從液晶晶胞裡侧通過偏光 鏡入射時,具有與偏光鏡之偏光軸不一致之偏光方向之光幾乎 全被偏光鏡吸收,而不會透過偏光鏡。亦即,雖然會依據所使 用之偏光鏡之特性而不同,不過大約5G%的光會被偏光鏡所吸 收,這種狀態下,可為液晶影像顯示等所利用之光量減少,畫 面會變暗。亮度提升膜可反覆使具有被偏光鏡吸收之偏光方向 之光不人射偏光鏡而被亮度提升膜暫時反射,更經由設於其後 側之反射層等使其反轉再入射到亮度提升膜這個動作,由於其 僅使該兩者間反射、反轉之光之偏光方向變成可通過偏光鏡之 偏光方向之偏光透過亮度提升膜供給於偏光鏡,因此可使背光 等光有效率地於液晶顯示裝置之影像等之顯示,使畫面變 亮。 亦可於亮度提升膜與上述反射層等之間設置擴散片。藉亮 度提升膜反狀偏光㈣之光雖朝向上述反射料,不過業經 设置之擴散片能使通過之光均勻擴散同時消除偏光狀態,而變 成非偏光狀態。亦即,擴散Μ使偏光恢復為原來的自然光狀 怨。該非偏光狀態、亦即自然綠態之光會反覆進行朝向反射 層等,經岐射料反射,再次通過擴散#再人_亮度提升 膜之過程。藉由如此於亮度提賴與上述反射層等之間設置使 光陝彳又成自然光狀恶之擴散片,可維持顯示晝面之明亮,同 日守減少顯不畫面之亮度不均,提供均一明亮的晝面。藉由設置 擴政片,初次之入射光可適當地增加反射之重覆次數、與擴 政片之擴散機能相輔相成,故可提供均勻之明亮之顯示畫面。 作為前述亮度提升膜係可使用適宜之例如··如介電體之多 或折射率各向異性不同之薄膜之多層積層體,透過預定 材光車由之直線偏光而顯示其他光反射之特性者,或如於薄膜基 卢持螺旋狀液晶聚合物之定向膜或該定向液晶層者,反射 5 A或右旋任一側之圓偏光而顯示其他光透過之特性者等。 Q此,使前述之預定偏光軸之直線偏光透過 提升膜中,益山 概之π度 、 糟由使該透過光於該狀態下使偏光軸聚集於偏光片 t入射’可抑制因偏光片產生之吸收損失,同時使其有效率地 ^ 一方面,將如螺旋狀液晶層之投下圓偏光之類型之亮 ^提相中,可於該狀態下使之人射於偏光鏡,但基 φ Αυ 收損失芦卧 ^ ,、乂點,且使該圓偏光經由相位差片而直線偏光化並入射 到偏光片。又,藉由使用1/4波長片作為該相位 偏光變換為直線偏光。 ® 在可見光域等之廣波長範圍中作為1/4波長片來發揮功能 之相位差片,可藉由例如將相對於波長550nm之淡色光作為 5 ι/4波長片發揮功能之相位差層與顯示其他相位差特性之相位 、㈢,例如作為1/2波長片發揮功能之相位差層重疊之方式等 侍到。因此,配置於偏光片與亮度提升膜之間之相位差片亦可 鲁 乂疋由1層或2層以上之相位差層形成者。 又,有關螺旋狀液晶層,藉由作成反射波長不同者之組合 且作成重® 2層或3層以上之配置構造,可在可見光領域等之 廣波長範圍中得到反射圓偏光者,並可據之而得到廣波長範圍 之透過圓偏光。 又,偏光片亦可如上述之偏光分離型偏光片,由積層偏光 片/、2層或3層以上之光學層者形成。因此,亦可為組合上述 19 200412274 反射型偏光片或半透過型偏光片與相位差片之反射型橢圓偏 光片或半透過型橢圓偏光片等。 前述積層上可使用黏著層等適當接著機構。在接著前述偏 光片或其他光學膜之際,該等之光學軸可因應作為目的之相位 5 差特性等來做出適宜之配置角度。 前述偏光片、或至少積層有1層偏光片之光學膜可設置用 以與液晶晶胞等其他構件接著之黏著層。形成黏著層之黏著劑 並無特別限制,例如可適當選擇丙烯酸系聚合物、聚矽氧系聚 合物、聚酯、聚胺甲酸酯、聚醯胺、聚醚、氟原子系或橡膠系 10 等之聚合物為基質聚合物者來使用。特別是丙烯酸系黏著劑, 其光學性透明性優異,展顯出適度之可濕潤性、凝集性與接著 性之黏著特性,在财氣候性或财熱性等方面優異,尤適宜使用。 又,除上述之外,再加上基於防止因吸濕等造成之發泡現 象或剝離現象、防止因熱膨脹等造成之光學特性降低或液晶晶 15 胞翹曲、進而有高品質且耐久性優異之液晶顯示裝置之形成性 等點,以使用吸濕率低且耐熱性優異之黏著層為佳。 黏著劑層可含有例如天然物或合成物之樹脂類、特別是如 黏著性賦予樹脂、玻璃纖維、玻璃珠、金屬粉、由其他無機粉 末等形成之充填劑、顏料、著色劑或抗氧化劑等可添加於黏著 20 層之添加劑。又,亦可使其為含有微粒子而顯示光擴散性之黏 著劑層等。 對偏光片或光學膜之單面或雙面附設黏著層時,可以適當 之方式進行。例如,可舉調製使基質聚合物或其組成物溶解或 分散於由甲苯或乙酸乙酯等適宜之溶劑之單獨物或混合物所 20 200412274 形成之溶劑中而成之10〜40重量%左右之黏著劑溶液,將之以 延流方式或塗工方式等適宜之展開方式直接附設於偏光片上 或光學膜上這種方式,或依據前述於脫模膜上形成黏著層,再 將之移著到偏光片上或光學膜上之方式等。 5 黏著層亦可作為不同組成或種類等之重疊層設於偏光片The color is more suitable. The circular polarizer is effective for adjusting the color tone of an image of a reflective liquid crystal display device in which an image is changed to a color display, and also has a function of preventing reflection. Specific examples of the above retardation film may include suitable polymers such as polycarbonate, polyvinyl alcohol, polystyrene, polymethylmethacrylate, polypropylene or other polyolefins, 5 polyallyl esters, and polyamides. The formed film is a birefringent film or an alignment film of a liquid crystal polymer, and an alignment layer of the liquid crystal polymer is supported by the film. The retardation film may have a suitable retardation according to various usage purposes; the so-called various usage purposes are, for example, for the purpose of compensating for coloration or viewing angle caused by the birefringence of various wavelength plates or liquid crystal layers, and the retardation film may also be It is a product with two or more types of retardation film with 10 layers to suppress the optical characteristics such as retardation. The elliptical polarizer or the reflective elliptical polarizer is a laminate of a polarizer, a reflective polarizer, and a retardation film in an appropriate combination. The elliptical polarizer and the like can be formed by sequentially stacking (reflective) polarizers and retardation films in the manufacturing process of a liquid crystal display device, and combining these sheets, but if they are prepared in advance as described in 15 Optical films such as elliptical polarizers have the advantages of excellent quality stability and lamination workability, and can improve the manufacturing efficiency of liquid crystal display devices. The viewing angle compensation film is used to expand the viewing angle, and when the image of the liquid crystal display device is viewed from a direction that is not perpendicular to the screen, but from a slightly inclined direction, the picture 20 surface looks more vivid. Such a viewing angle compensating retardation film is formed by, for example, a retardation film, an alignment film such as a liquid crystal polymer, or an alignment layer such as a liquid crystal polymer on a transparent substrate. Generally, a retardation film is a polymer film having uniaxially-extending birefringence in the plane direction. In contrast, a retardation film used as a viewing angle compensation film is used in a birefringent film having biaxially extending in the plane direction. 16 200412274 A polymer film, or a birefringent polymer that controls the refractive index in the thickness direction by uniaxially extending in the plane direction and also in the thickness direction, or a two-direction stretch film such as an obliquely oriented film. The oblique facing film may be, for example, a heat shrinkable film followed by a polymer film and heated to generate a shrinking force. Under the action of the shrinking force, the polymer film is stretched for 5 treatments and / or shrinking treatments, or the liquid crystal polymer is tilted. Orientees, etc. The raw material polymer of the retardation film is the same as the polymer described previously in the retardation film, and can be used to prevent: coloration caused by the change in the visual recognition angle due to the phase difference of the liquid crystal cell, etc., It may be suitable for purposes such as better visual recognition and widening of the viewing angle. 10 In addition, based on the point of view of achieving an enlarged visual recognition angle, etc., an alignment layer in which a liquid crystal polymer is supported by a triethyl cellulose film; particularly, an alignment layer formed by a discotic liquid crystal polymer Optically-compensated retardation film of an optically anisotropic layer. Polarizers that have been bonded with polarizers and brightness-enhancing films are usually used inside the 15 cell of the liquid crystal. The brightness-improving film has such characteristics that when a backlight or natural light of a liquid crystal display device or the like is incident by reflection from the back side, that is, linearly polarized light of a predetermined polarization axis or circularly polarized light in a predetermined direction is transmitted, and other light is transmitted. In the case of a polarizer in which a brightness enhancement film and a polarizer are laminated, light from a light source such as a backlight is incident to obtain transmitted light in a predetermined polarized state, and at the same time, light outside the predetermined polarized light 20 state is reflected without transmission, so that The light reflected from the surface of the brightness enhancement film is inverted through a reflective layer provided on the rear side, etc., and then incident on the brightness enhancement film, so that it partially or entirely transmits light as a predetermined polarization state to increase the amount of light transmitted through the brightness enhancement film. At the same time, the polarized light that is difficult to be absorbed by the polarizer is supplied to increase the amount of light that can be used for liquid crystal display image display and the like, thereby increasing the brightness. That is, when the light is incident from the inside of the liquid crystal cell through a polarizer without using a party-strengthening film, almost all light having a polarization direction that is inconsistent with the polarization axis of the polarizer is absorbed by the polarizer, and Does not pass through polarizers. That is, although it will vary according to the characteristics of the polarizer used, about 5G% of the light will be absorbed by the polarizer. In this state, the amount of light that can be used for liquid crystal image display and the like is reduced, and the screen will be darkened. . The brightness enhancement film can repeatedly cause the light having the polarization direction absorbed by the polarizer not to pass through the polarizer and be temporarily reflected by the brightness enhancement film. It can also be inverted and incident on the brightness enhancement film through a reflective layer provided on the rear side. This action only changes the polarized light direction of the reflected and inverted light between the two into a polarizer that can be supplied to the polarizer through the brightness enhancement film through the polarized direction of the polarizer, so that light such as backlight can be efficiently applied to the liquid crystal. The display of the image of the display device makes the screen brighter. A diffusion sheet may be provided between the brightness enhancement film and the reflective layer. Although the light of the reverse polarized light from the brightness-enhancing film is directed toward the above-mentioned reflective material, the diffuser sheet has been set to evenly diffuse the passing light while eliminating the polarized state, and it becomes a non-polarized state. That is, the diffused light M restores the polarized light to the original natural light. The non-polarized light, that is, the light in the natural green state, is repeatedly directed toward the reflective layer, etc., and is reflected by the diffusive material, and then passes through the process of diffusion # re-intensity_brightness film again. By arranging the diffuser between the brightness enhancement and the above-mentioned reflection layer to make the light shame become natural light, it can maintain the brightness of the display day, and reduce the uneven brightness of the display on the same day, providing uniform brightness. Day surface. By setting the expansion film, the first incident light can appropriately increase the number of repeated reflections and complement the diffusion function of the expansion film, so it can provide a uniform and bright display screen. As the aforementioned brightness-improving film, for example, a multilayer laminated body suitable for a film having a large number of dielectrics or films having different refractive index anisotropy can be used to display the characteristics of other light reflections through the linearly polarized light of a predetermined material light car. Or, if it is a thin film-based helical liquid crystal polymer alignment film or the alignment liquid crystal layer, it reflects 5 A or right-handed circular polarized light on either side and displays other light transmission characteristics. Q: By allowing the linearly polarized light of the predetermined polarization axis to pass through the lifting film, the π degree of Iyama, and the polarization axis caused by the transmitted light in this state to be collected on the polarizer t, can be prevented from occurring due to the polarizer. Absorb the loss and make it efficient at the same time ^ On the one hand, the type of circularly polarized light such as the spiral liquid crystal layer is dropped ^ can be made to shine on the polarizer in this state, but the base φ Αυ is closed The stagnation point is lost, and the circularly polarized light is linearly polarized through a phase difference plate and is incident on the polarizer. The phase polarization is converted into linear polarization by using a quarter-wave plate. ® A retardation film that functions as a 1/4 wavelength plate in a wide wavelength range such as the visible light range. For example, a retardation layer that functions as a 5 ι / 4 wavelength plate with a light color of 550 nm relative to a wavelength can be used. Phases and chirps that show other retardation characteristics, such as the way in which retardation layers that function as a 1/2 wavelength plate are superimposed, are available. Therefore, the retardation film disposed between the polarizer and the brightness-improving film can also be formed from one or more retardation layers. In addition, the spiral liquid crystal layer is made of a combination of different reflection wavelengths and a structure of two or more layers, which can obtain reflective circularly polarized light in a wide wavelength range such as the visible light field. As a result, a circularly polarized light having a wide wavelength range is obtained. Further, the polarizer may be formed of a laminated polarizer / two or three or more optical layers, as in the above-mentioned polarized light separation type polarizer. Therefore, it may be a reflective elliptical polarizer or a semi-transmissive elliptical polarizer that combines the above-mentioned 19 200412274 reflective polarizer or semi-transmissive polarizer with a retarder. Appropriate bonding means such as an adhesive layer can be used on the laminate. When following the aforementioned polarizer or other optical film, these optical axes can be arranged at an appropriate angle according to the phase difference characteristic of the objective. The aforementioned polarizer, or an optical film in which at least one polarizer is laminated, may be provided as an adhesive layer for adhering to other members such as a liquid crystal cell. The adhesive for forming the adhesive layer is not particularly limited, and for example, an acrylic polymer, a silicone polymer, a polyester, a polyurethane, a polyamide, a polyether, a fluorine atom-based system, or a rubber-based system can be appropriately selected. Other polymers are used as matrix polymers. In particular, acrylic adhesives are excellent in optical transparency, exhibit moderate adhesion characteristics of wettability, agglutination, and adhesion, and are excellent in terms of financial climate and thermal properties, and are particularly suitable for use. In addition to the above, in addition to preventing foaming or peeling due to moisture absorption, etc., preventing degradation of optical characteristics due to thermal expansion, etc., or warping of liquid crystal cells, it has high quality and excellent durability. In terms of the formability of the liquid crystal display device, it is preferable to use an adhesive layer having low moisture absorption and excellent heat resistance. The adhesive layer may contain, for example, natural or synthetic resins, in particular, adhesives, resins, glass fibers, glass beads, metal powders, fillers made of other inorganic powders, pigments, colorants, or antioxidants Additive can be added to 20 layers. Further, it may be an adhesive layer or the like which contains fine particles and exhibits light diffusivity. When an adhesive layer is attached to one or both sides of a polarizer or an optical film, it may be performed in an appropriate manner. For example, it is possible to adjust the adhesion of about 10 to 40% by weight of the matrix polymer or its composition dissolved or dispersed in a solvent or a mixture of suitable solvents such as toluene or ethyl acetate 20 200412274. Agent solution, which is directly attached to the polarizer or the optical film by a suitable expansion method such as a casting method or a coating method, or forms an adhesive layer on the release film according to the foregoing, and then moves it to polarized light On-chip or optical film. 5 Adhesive layer can also be set on the polarizer as an overlapping layer of different compositions or types

或光學膜之單面或雙面。又,設於雙面之情況,亦可在偏光片 或光學膜之表裡作成不同組成、種類或厚度等之黏著層。黏著 層之厚度可因應使用目的或黏著力等適宜地決定,一般為 1〜500 // m,又以5〜200 // m為佳,尤以10〜100 // m為佳。 10 在供於實用之前,以防止其污染等為目的,對黏著層之露 出面暫時貼附脫模膜覆蓋住。藉此,在通例之處理狀態下可防 止接觸黏著層。脫模膜除了上述厚度條件外,可使用例如將塑 膠膜、橡膠薄片、紙、布、不織布、網、發泡薄片或金屬薄片、 這些薄片的積層體等之適宜之薄片,因應需要而以矽氧系、長 15 鏈烷基系、氟元素或硫化鉬等適宜之剝離劑施行塗層處理者等 依據習知之適宜者。Or one or both sides of the optical film. In addition, when it is provided on both sides, an adhesive layer with a different composition, type, or thickness may be formed on the surface of the polarizer or optical film. The thickness of the adhesive layer can be appropriately determined according to the purpose of use or adhesion, and is generally 1 to 500 // m, preferably 5 to 200 // m, and more preferably 10 to 100 // m. 10 Before being put into practical use, the release surface of the adhesive layer is temporarily covered with a release film for the purpose of preventing contamination. This prevents contact with the adhesive layer in the usual processing state. In addition to the above-mentioned thickness conditions, a suitable film such as a plastic film, rubber sheet, paper, cloth, non-woven fabric, net, foamed sheet or metal sheet, a laminate of these sheets, etc. may be used as the release film. Suitable strippers such as oxygen-based, 15-chain alkyl-based, fluorine or molybdenum sulfide, etc., are applied according to the conventionally suitable ones.

又,本發明中,形成上述偏光片之偏光鏡、透明保護膜或 光學膜等、或黏著層等各層上,可藉例如柳酸酯系化合物或苯 盼系化合物、苯并三氮σ坐系化合物或氰基丙稀酸系化合物、鎳 20 錯鹽系化合物等之紫外線吸收劑來處理之方式等方式,使其具 有紫外線吸收能等。 前述光學構件(偏光片、光學膜等)可適當地使用在液晶 顯示裝置等各種裝置之形成等。液晶顯示裝置之形成可以習知 為基準來進行。亦即,液晶顯示裝置一般是藉由將液晶晶胞與 21 200412274 黏著型光學膜及因應需要之照明系統等之構成零件適當地組 合並裝入驅動電路等來形成,本發明中,除了使用藉本發明形 成之偏光片或光學膜這點外,並無特別限定,可依據習知之方 法。有關液晶晶胞也可使用例如TN型、STN型或7Γ型等任意 5 類型者。Moreover, in the present invention, the polarizer, transparent protective film, optical film, or the like, or the adhesive layer forming the above-mentioned polarizer can be exemplified by a saurate compound, a benzyl compound, and a benzotriazine sigma system. The compound or a cyanoacrylic acid compound, a nickel 20 sodium salt compound, and the like are treated by an ultraviolet absorbent, etc., so that they have ultraviolet absorption energy and the like. The aforementioned optical member (a polarizer, an optical film, etc.) can be suitably used for forming various devices such as a liquid crystal display device and the like. The formation of a liquid crystal display device can be performed based on a conventional method. That is, a liquid crystal display device is generally formed by appropriately combining a liquid crystal cell with component parts such as an adhesive film of 21 200412274 and a lighting system in accordance with requirements, and incorporating the driving circuit into the driving circuit. The polarizer or optical film formed by the present invention is not particularly limited in this respect, and may be based on a conventional method. As the liquid crystal cell, any of five types such as a TN type, an STN type, or a 7Γ type may be used.

可形成在液晶晶胞之單側或兩側配置偏光片或光學膜之 液晶顯示裝置、或於照明系統中使用後照燈或反射片者等之適 宜之液晶顯示裝置。這時,藉本發明形成之偏光片或光學膜可 設置於液晶晶胞之單側或兩侧。於兩側設置偏光片或光學膜 10 時,該等可以相同,也可以不同。更,在液晶顯示裝置形成之 際,可於適宜之位置將例如擴散片、抗眩光層、反射防止膜、 保護片、稜鏡陣列、透鏡陣列薄膜、光擴散片、背光等適宜之 零件配置1層或2層以上。Suitable liquid crystal display devices can be formed on one or both sides of the liquid crystal cell with a polarizer or an optical film, or a backlight device or a reflector used in a lighting system. At this time, the polarizer or optical film formed by the present invention can be disposed on one side or both sides of the liquid crystal cell. When polarizers or optical films 10 are provided on both sides, these may be the same or different. Furthermore, when forming a liquid crystal display device, suitable parts such as a diffusion sheet, an anti-glare layer, an anti-reflection film, a protective sheet, a holmium array, a lens array film, a light diffusion sheet, and a backlight can be arranged at appropriate positions. One or more layers.

接著說明有關有機電致發光裝置(有機EL顯示裝置)。一 15 般而言,有機EL顯示裝置係於透明基板上依序積層透明電極、 有機發光層及金屬電極而形成發光體(有機電致發光發光 體)。在此,有機發光層是各種有機薄膜之積層體,已知的有 例如由三苯胺衍生物等形成之正電洞注入層、與由蔥等之螢光 性有機固體所形成之發光層之積層體,或這種發光層與紫蘇烯 20 衍生物等形成之電子注入層之積層體,甚或這些之正電洞注入 層、發光層及電子注入層之積層體等具各種組合之構成。 有機EL顯示裝置是以下述原理發光,亦即,藉由外加電 壓於透明電極與金屬電極,使正電洞與電子注入有機發光層, 再藉這些正電洞與電子之再結合所產生之能源激發螢光物 22 200412274 質,被激發之榮光物質恢復基態時會將光放射出來而發光。所 明途中之再結合機構與一般二極體相同,由此可預測到,電流 與發光強度相對射卜加電壓—出伴隨整流性之強烈非線性。 在有機el顯示裝置中,為了取出在有機發光層之發光, 5必須至少一側之電極為透明,通常是使用氧化觸(ιτ〇)等 透明導電體所形成之透明電極作為陽極。另一方面,為了要使 電子注入合易進行,提高發光效率,於陰極使用玉作函數小的 物質是很重要的,通常是使用Mg_Ag、A1_u等金屬電極。 在這種構成之有機EL顯示裝置中,有機發光層係由厚& _ 10 lOnm之極薄之膜形成。因此,有機發光層也與透明電極相同 地可使光兀全透過。結果,非發光時從透明基板表面入射、透 過透明電極與有機發光層而以金屬電極反射之光,會再次往透 明基板表面側透出,因此從外部目視辨認時,有機el顯示裝 置之顯示面看起來有如鏡面。 15 在έ有藉;^加電壓來發光之有機發光層之表面側具有透 明電極1¾ 4有機發光層之裡面側具有金屬電極之有機致電發 光毛光體之有機EL顯示裝置中,可於透明電極之表面側設置 _ 偏光片,同時於透明電極與偏光片之間設置相位差片。 相位差片及偏光片由於具有使從外部入射並以金屬電極 20反射之光偏光之作用,因此藉該偏光作用可產生使金屬 電極之 鏡面無法從外部目視辨認之效果。尤其是以1/4波長片構成相 位差片且將偏光片與相位差片之偏光方向形成之角調整為冗 /4,即可完全遮蔽金屬電極之鏡面。 亦即’入射到該有機EL顯示裝置之外部光,因偏光片而 23 200412274 僅有直線偏光成分透過。該直線偏光一般藉相位差片成為橢圓 偏光’不過特別是當相位差片為1/4波長片、且偏光片與相位 差片之偏光方向形成之角為7Γ/4時會變成圓偏光。 5亥圓偏光透過透明基板、透明電極、有機薄膜而以金屬電 5 極反射,再透過有機薄膜、透明電極、透明基板,於相位差片 再次變成直線偏光。然後,由於該直線偏光與偏光片之偏光方 向垂直,故無法透過偏光片。結果,可完全遮蔽金屬電極之鏡 面0 (貫施例) 接著,說明有關實施例及比較例。準備講求加工精度或精 加工精度之用於液晶顯示裝置之偏光膜50片作為積層片,在 厚度方向積層。積層片之矩形尺寸為255mmx 195mm。切削切 斷面後之精加工尺寸為250mmx 190mm。 目疋,糟第3圖說明由實施例進行之夾持領域(按) 15 20Next, an organic electroluminescence device (organic EL display device) will be described. Generally speaking, an organic EL display device is a light emitting body (organic electroluminescent light emitting body) in which a transparent electrode, an organic light emitting layer, and a metal electrode are sequentially laminated on a transparent substrate. Here, the organic light emitting layer is a laminate of various organic thin films. For example, a positive hole injection layer made of a triphenylamine derivative and the like and a light emitting layer made of a fluorescent organic solid such as onion are known. Or a laminate of such an electron injection layer formed by such a light-emitting layer and a perillene 20 derivative, or even a laminate of a positive hole injection layer, a light-emitting layer, and an electron injection layer. The organic EL display device emits light by the following principle, that is, by applying a voltage to the transparent electrode and the metal electrode, positive holes and electrons are injected into the organic light emitting layer, and then the energy generated by the recombination of these positive holes and electrons is used. Excited fluorescent substance 22 200412274 mass, when the excited glory substance returns to ground state, it will radiate light and emit light. The recombination mechanism on the way is the same as that of ordinary diodes, so it can be predicted that the current and the luminous intensity are relative to the applied voltage—a strong nonlinearity with rectification. In an organic el display device, in order to take out the light emission in the organic light emitting layer, at least one side of the electrode must be transparent. Generally, a transparent electrode formed of a transparent conductor such as an oxide contact (ιτ〇) is used as the anode. On the other hand, in order to facilitate electron injection and improve luminous efficiency, it is important to use a material with a small jade function as a cathode. Usually, metal electrodes such as Mg_Ag and A1_u are used. In the organic EL display device having such a configuration, the organic light emitting layer is formed of an extremely thin film having a thickness of < 10 nm. Therefore, the organic light-emitting layer can transmit light as much as the transparent electrode. As a result, light that is incident from the surface of the transparent substrate and reflected by the metal electrode through the transparent electrode and the organic light-emitting layer at the time of non-emission will pass through the surface of the transparent substrate again. Therefore, when visually recognized from the outside, the display surface of the organic el display device It looks like a mirror. 15 There is a borrow; ^ a transparent electrode is provided on the surface side of the organic light-emitting layer that applies voltage to emit light. 4 Organic light-emitting organic EL display device with a metal electrode on the inner side of the organic light-emitting layer can be used as a transparent electrode. A _ polarizer is provided on the surface side, and a retardation film is provided between the transparent electrode and the polarizer. Since the retardation film and the polarizing film have a function of polarizing light that is incident from the outside and reflected by the metal electrode 20, the effect of making the mirror surface of the metal electrode invisible from the outside can be produced by the polarizing effect. In particular, a phase difference plate is constituted by a 1/4 wavelength plate and the angle formed by the polarizing plate and the polarization direction of the phase difference plate is adjusted to redundant / 4, so that the mirror surface of the metal electrode can be completely shielded. That is, the external light incident on the organic EL display device is transmitted only by a linearly polarized component due to the polarizer. This linearly polarized light is generally made into an elliptical polarized light by a retardation film '. However, when the retardation film is a 1/4 wavelength plate and the angle formed by the polarization direction of the polarizer and the retardation film is 7Γ / 4, it becomes circularly polarized light. The 50-degree circularly polarized light passes through the transparent substrate, the transparent electrode, and the organic thin film and is reflected by the metal electrode, and then passes through the organic thin film, the transparent electrode, and the transparent substrate, and becomes linearly polarized again in the retardation film. Since the linearly polarized light is perpendicular to the polarization direction of the polarizer, it cannot pass through the polarizer. As a result, the mirror surface 0 of the metal electrode can be completely shielded. (Examples) Next, examples and comparative examples will be described. Fifty polarizing films for liquid crystal display devices, which require processing accuracy or precision, are to be laminated and laminated in the thickness direction. The rectangular size of the laminated sheet is 255mm x 195mm. The finished size after cutting is 250mmx 190mm. Now, Figure 3 illustrates the clamping area performed by the embodiment (press) 15 20

之形狀)。第3⑴圖顯示上面側之夾持領域,⑴顯 側之炎持領域。無論上下面,四角皆包含於夾持領域。Shape). Figure 3 shows the clamping area on the upper side and the inflammation holding area on the upper side. The upper and lower corners are included in the clamping area.

係針對相向之—對長邊3,與短邊%形成非夾持領域。. 側係沿著矩形全周長與對角線形成失持領域。在此… 爽持位置之四角及全周長,係指位於切削加1後之積 置’以該位置失持積層片時,積層片之切削預定部分: 线領域露出之狀態。唯,當使用軟質材料料 亦可連同該夾具與積層卜如肖,卜心__為 面側之失持面積為Sx〇.12( 12%), 叫總和為·。)下面側之夹持面積為 24 200412274 第4圖顯示比較例1之夾持領域。如(a)所示,上面側係 矩形之全周長皆被夾持,(b)亦相同。(b)與實施例之構成相 同。上面側之夾持面積為40%,下面側之夾持面積為48%,總 和為44%。 5 第5圖顯示比較例2之夾持領域。如(a)所示,上面側僅 夾持矩形之全周長,(b )與第1比較例相同。上面側之夾持面 積為26%,下面側之夾持面積為48%,總和為37%。 接著,將進行切削加工時之評價結果顯示於下。就MD方 向(延伸方向)、TD方向(與延伸方向垂直之方向)求得以上 10 述之250mm><190mm為目標尺寸時之標準偏差。又,使樣本數 n=15 〇 表1 標準偏差 MD方向 TD方向 實施例 0.025 0.019 比較例1 0.033 0.025 比較例2 0.03 0.023 從該表中可得知,實施例之不均之值很小。比較例1由於 15 夾持面積過大,故不均很大。比較例2雖然夾持面積適當,但 由於使上面側之矩形全周長為夾持領域,故不均變大。因此, 可清楚得知藉本發明之切削方法是很優異的。 第3圖所示之夾持領域係顯示本發明之1例,而本發明並 不限定於此。 20 【圖式簡單說明】 第1圖是顯示切削方法之具體方法之圖。 25 200412274 第2圖是顯示切削方法之具體方法之圖(其他實施形態)。 第3 (a)〜3 (b)圖是顯示藉實施例之夾持領域之圖。 第4 (a)〜4 (b)圖是顯示藉比較例1之夾持領域之圖。 第5 (a)〜5 (b)圖是顯示藉比較例2之夾持領域之圖。 5 【圖式之主要元件代表符號表】 1…積層片 la…長邊 lb…短邊 lc…矩形四角 2…旋轉刀具 2 A,2B…旋轉刀具 3···夾持機構 3a…長邊 3b…短邊 26It is aimed at the opposite—to the long side 3, and the short side% to form a non-clamping area. The side system forms a mismatch area with the diagonal along the full perimeter of the rectangle. Here ... The four corners and full perimeter of the holding position refer to the position after cutting plus 1 'when the laminated sheet is held at that position, and the planned cutting part of the laminated sheet: the state where the line area is exposed. However, when a soft material is used, it can also be used together with the fixture and the laminate, such as Bu Xiao, and Bu Xin__ is the face-to-face miscarriage area is Sx0.12 (12%), which is called the total. ) The clamping area on the lower side is 24 200412274. Figure 4 shows the clamping area of Comparative Example 1. As shown in (a), the entire perimeter of the upper rectangle is clamped, and (b) is the same. (B) The configuration is the same as that of the embodiment. The clamping area on the upper side is 40%, the clamping area on the lower side is 48%, and the total is 44%. 5 Figure 5 shows the clamping area of Comparative Example 2. As shown in (a), only the full perimeter of the rectangle is held on the upper side, and (b) is the same as the first comparative example. The clamping area on the upper side is 26%, the clamping area on the lower side is 48%, and the total is 37%. Next, the evaluation results when cutting is performed are shown below. For the MD direction (extending direction) and the TD direction (direction perpendicular to the extending direction), the standard deviation when 250 mm > < 190 mm as the above-mentioned target size is obtained is obtained. The number of samples is n = 15. Table 1 Standard deviation MD direction TD direction Example 0.025 0.019 Comparative example 1 0.033 0.025 Comparative example 2 0.03 0.023 As can be seen from the table, the value of the unevenness in the examples is small. In Comparative Example 1, since the clamping area was too large, the unevenness was large. In Comparative Example 2, although the clamping area is appropriate, since the entire circumference of the rectangle on the upper side is the clamping area, the unevenness becomes large. Therefore, it is clear that the cutting method according to the present invention is excellent. The gripping field shown in Fig. 3 shows an example of the present invention, but the present invention is not limited to this. 20 [Brief description of the drawings] Figure 1 is a diagram showing the specific method of the cutting method. 25 200412274 Figure 2 is a diagram showing a specific method of the cutting method (other embodiments). Figures 3 (a) to 3 (b) are diagrams showing the clamping area of the embodiment. Figures 4 (a) to 4 (b) are diagrams showing the clamping area by Comparative Example 1. Figures 5 (a) to 5 (b) are diagrams showing the clamping area of Comparative Example 2. 5 [Representative symbol table of main components of the drawing] 1… Laminate la… Long side lb… Short side lc… Rectangular four corners 2… Rotary cutter 2 A, 2B… Rotary cutter 3 ·· Clamping mechanism 3a… Long side 3b … Short side 26

Claims (1)

200412274 拾、申請專利範圍: 1. 一種積層片之切削加工方法,係將切斷為矩形之積層片之 切斷面切削精加工者,該切削加工方法包含: 於厚度方向將多數片積層片於重疊之狀態下,藉夾持 5 機構從上下兩面將多數片之積層片夾持之步驟;及 在夾持多數片積層片之狀態下,藉切削機構切削積層 片之切斷面之步驟, 又,藉前述夾持機構之前述上下兩面之總夾持面積係 相對於積層片之前述矩形面積之2倍而為5〜40%,且夾持領 10 域中包含前述矩形之四角,而構成前述矩形之一對長邊或 一對短邊中之至少一者上設定有不被前述夾持機構所夾持 之非夾持領域。 2. 如申請專利範圍第1項之積層片之切削加工方法,其係將下 面側之夾持面積設定成大於上面側之夾持面積。 15 3.如申請專利範圍第1項之積層片之切削加工方法,其中位於 前述夾持領域之夾持機構係使用軟質材料。 4. 一種積層片,係藉申請專利範圍第1項之積層片之切削加工 方法切削而成者。 5. 如申請專利範圍第4項之積層片,其中該積層片為光學膜用 20 材料。 6. —種光學元件,係在光學元件之單面或雙面設有申請專利 範圍第5項之光學膜用材料者。 7. 一種影像顯示裝置,係搭載有申請專利範圍第5項之光學膜 用材料者。 27 200412274 8. —種影像顯示裝置,係搭載有申請專利範圍第6項之光學元 件者。200412274 Scope of patent application: 1. A cutting method for laminated sheets, which is a finisher who cuts the cut surface of a rectangular laminated sheet. The cutting method includes: In the state of overlapping, the steps of clamping the laminated sheet of the plurality of sheets from the upper and lower sides by the clamping 5 mechanism; and the step of cutting the cut surface of the laminated sheet by the cutting mechanism in the state of clamping the laminated sheet of the majority, The total clamping area of the upper and lower sides of the clamping mechanism is 5 to 40% of the double area of the rectangular area of the laminated sheet, and the four corners of the rectangular shape are included in the clamping collar 10 field to form the foregoing. At least one of a pair of long sides or a pair of short sides of a rectangle is provided with a non-clamping region which is not clamped by the clamping mechanism. 2. For the lamination process of laminated sheet according to item 1 of the scope of patent application, the clamping area on the lower side is set to be larger than the clamping area on the upper side. 15 3. The method for cutting laminated sheets according to item 1 of the patent application scope, wherein the clamping mechanism located in the aforementioned clamping area is made of a soft material. 4. A multi-layer sheet is made by cutting the multi-layer sheet using the cutting method of patent application No. 1. 5. The laminated sheet according to item 4 of the patent application scope, wherein the laminated sheet is made of 20 materials for optical films. 6. —An optical element, which is provided on one or both sides of the optical element with the material for the optical film of item 5 of the patent application scope. 7. An image display device, which is equipped with a material for an optical film according to item 5 of the patent application. 27 200412274 8. —A kind of image display device, which is equipped with the optical element in the 6th scope of the patent application. 2828
TW92129944A 2002-10-29 2003-10-28 Method for cutting laminating sheets and laminating sheets and image display device TW200412274A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002314056 2002-10-29
JP2003352065A JP3871332B2 (en) 2002-10-29 2003-10-10 Lamination sheet cutting method

Publications (2)

Publication Number Publication Date
TW200412274A true TW200412274A (en) 2004-07-16
TWI298662B TWI298662B (en) 2008-07-11

Family

ID=32715753

Family Applications (1)

Application Number Title Priority Date Filing Date
TW92129944A TW200412274A (en) 2002-10-29 2003-10-28 Method for cutting laminating sheets and laminating sheets and image display device

Country Status (3)

Country Link
JP (1) JP3871332B2 (en)
CN (1) CN100402227C (en)
TW (1) TW200412274A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006106016A (en) * 2004-09-10 2006-04-20 Sumitomo Chemical Co Ltd Polarizing plate and manufacturing method therefor
CN106891378A (en) * 2017-03-13 2017-06-27 赢家时装(赣州)有限公司 A kind of air pressure hangs yarn platform and its cutting method
CN115179347B (en) * 2022-06-10 2023-08-01 天活松林光学(广州)有限公司 Cutting fixture, use method and cutting equipment

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61136746A (en) * 1984-12-03 1986-06-24 Nitto Electric Ind Co Ltd Cutting work for anisotropic film
DE3613316C1 (en) * 1986-04-19 1988-02-18 Wolfgang Mohr Device for cutting stacked, sheet-like material
JPH03166098A (en) * 1989-11-21 1991-07-18 Amagasaki Kosakusho:Kk Automatic chamfering machine
JP2787038B2 (en) * 1994-06-06 1998-08-13 セイコープレシジョン株式会社 Substrate positioning and gripping device
JP3657853B2 (en) * 2000-05-02 2005-06-08 三菱電線工業株式会社 Manufacturing method of laminate film
CN2448534Y (en) * 2000-11-15 2001-09-19 杨绍坚 Clamp of machine for cutting shaped CD

Also Published As

Publication number Publication date
JP3871332B2 (en) 2007-01-24
TWI298662B (en) 2008-07-11
CN100402227C (en) 2008-07-16
JP2004167672A (en) 2004-06-17
CN1498720A (en) 2004-05-26

Similar Documents

Publication Publication Date Title
KR100830392B1 (en) Production method for polarization plate, polarization plate and image display unit using it
KR100664429B1 (en) Method for producing polarizing plate, polarizing plate and image display device using the same
TWI363886B (en)
KR101348469B1 (en) Polarizer, optical film using it, image display unit using them
TWI296065B (en)
TWI295384B (en)
TWI382208B (en) A retardation adhesive layer, a manufacturing method thereof, an adhesive type optical film, a manufacturing method thereof, and an image display device
KR100832761B1 (en) Process for producing polarizing film, polarizing film obtained thereby and image display apparatus utilizing the same
US20060107811A1 (en) Laminate-cutting method, cutting device, and laminate-cutting pedestal
JP4293543B2 (en) Polarizer, production method thereof, polarizing plate, optical film, and image display device
JP2008102274A (en) Polarizer, polarization plate, optical film and image display apparatus
KR20070011257A (en) Optical member, method for producing same, and image display employing same
JP2004117482A (en) Method for manufacturing polarizing plate, polarizing plate, and image display device using same
TWI254805B (en) Process of producing a polarizer, polarizer, polarizing plate, and visual display
JP2005326831A (en) Optical member, method of manufacturing the same, and image display device applying the same
JP2004148419A (en) Cutting method for laminated sheet, laminated sheet, optical element, and image display device
TW200403488A (en) Method for manufacturing polarizer, polarizer, polarizing plate, and image display
JP4293537B2 (en) LAMINATED SHEET CUTTING METHOD, LAMINATED SHEET, OPTICAL ELEMENT, AND IMAGE DISPLAY DEVICE
TW200412274A (en) Method for cutting laminating sheets and laminating sheets and image display device
TWI354126B (en)
TW200422153A (en) Cutting method of a laminated sheet, optical element and picture image display device
KR20020079415A (en) Manufacturing method for oriented film, polarizing film, polarizing plate, and visual display
JP2004125817A (en) Polarizing film, polarizing plate, compensation polarizing plate, display device, and in-house manufacturing method
JP2006017747A (en) Method for producing polarizer, polarizer, polarizing plate, optical film, and image display device
JP2003185838A (en) Method for manufacturing oriented film, polarizing film, polarizing plate, and picture display

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees