TW200411757A - Method for fabricating fine conductive traces substrate - Google Patents

Method for fabricating fine conductive traces substrate Download PDF

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Publication number
TW200411757A
TW200411757A TW91137959A TW91137959A TW200411757A TW 200411757 A TW200411757 A TW 200411757A TW 91137959 A TW91137959 A TW 91137959A TW 91137959 A TW91137959 A TW 91137959A TW 200411757 A TW200411757 A TW 200411757A
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Taiwan
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layer
conductive layer
etching
forming
circuit substrate
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TW91137959A
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Chinese (zh)
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TW578231B (en
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Sao-Hsia Tang
I-Chung Tung
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Phoenix Prec Technology Corp
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Abstract

A method for fabricating fine conductive traces substrates is proposed. The substrate is formed with a conductive layer on at least a surface thereof, and a patterned resist layer formed with fine traces layout is applied over the conductive layer. It allows the conductive layer to be defined with a reserved area and a corresponding to-be-removed area. Then, the conductive layer in the to-be-removed area is anisotropica11y and rapidly etched by an electric-field activated etch process. Finally, the conductive layer still remained in the to-be-removed area is completely removed by a dry etching process for improving the yield of fine conductive traces substrate. In addition, a thin sacrificial layer can be also deposited on the conductive layer for protecting said conductive layer in the dry etching process; this method used in the package substrates or circuit boards manufacturing process will effectively improve the yield of fine conductive traces substrate.

Description

200411757 五、發明說明(1) 【發明所屬之技術領域】 本發明係關於一種基板製法,尤指一種形成細線路基 板之製法。 一 【先前技術】 由於通訊、網路及電腦等各式可攜式(P〇rtable)產品 的大幅成長’可縮小I c面積且具有高密度與多接腳化特性 的 BGA、FliP Chip、晶片尺寸封裝(CSP, chip Size Package)與多晶片模組(MCM, Multi Chip Module)等封裝 件已日漸成為封裝市場上的主流,並常與微處理器、晶片 紐φ、繪圖晶片與AS I C等高效能晶片搭配,以發揮更高速之 運算功能’惟由於佈有導線之丨c封裝基板有其製程上之限 制,其傳遞晶片訊號與改善頻寬、控制阻抗等功能之受限 遂成為高I / 〇數封裝件的發展障礙,且由於基板製程佔有 封裝成_本的2 0 %至5 〇 %,因此在半導體晶片之積體電路製程 已縮小至0 · 0 9 // m且封裝尺寸亦不斷縮小至幾乎與晶片同 大(約僅為晶片之1 · 2倍)時,如何開發可與其搭配的細線 路fFine Circuit)、高密度與小孔徑之封裝基板,使基板 之豐層數降低,同時不致提高過多製造成本,無疑 f乃至其他相關電子產業進入下一世代技術之重要研發課 月1 P刷電路板(pCB )或丨c封裝基板製程已從 // m以上之繞敉 口 , 路尺寸:包括導線寬(Line Width)、導 距(S p a c e )與浮* , 办 ▼ ^ τ .、衣見比(Aspect Ratio),降至約 30" m, 更小之線路拉— 精度進行研發;習知上當基板導線尺寸名200411757 V. Description of the invention (1) [Technical field to which the invention belongs] The present invention relates to a method for manufacturing a substrate, especially a method for forming a thin circuit substrate. 1 [Previous technology] BGA, FliP Chip, and chip that can reduce I c area and have high density and multi-pin characteristics due to the rapid growth of various portable products such as communication, network, and computer Packages such as CSP (chip size package) and multi-chip module (MCM) have gradually become the mainstream in the packaging market, and are often associated with microprocessors, chip chips, graphics chips, and AS ICs. High-performance chip collocation for higher-speed computing functions. However, because of the process limitations of the C-packaged substrate with wires, its limitations in transmitting chip signals and improving bandwidth and controlling impedance have become high I / 〇 number of package development obstacles, and because the substrate process accounts for 20% to 50% of the packaging cost, so the integrated circuit manufacturing process in semiconductor wafers has been reduced to 0 · 0 9 // m and the package size is also When shrinking to almost the same size as a wafer (about 1 or 2 times the size of a wafer), how to develop a fine circuit that can be used with it, high-density and small-aperture package substrates, reducing the number of substrate layers At the same time, it will not increase excessive manufacturing costs. It is no doubt that f and even other related electronics industries will enter the next generation of important R & D lessons. 1 The process of brushing a circuit board (pCB) or c package substrate has been passed from a path above // m. Dimensions: Includes wire width, lead, and float *, to do ▼ ^ τ., Aspect Ratio, reduced to about 30 " m, smaller line pull — precision research and development ; Know the name of the board wire size

200411757 五、發明說明(2) m以上時,一般係採用成本低廉且蝕刻快速之傳統蝕刻 法,即如第3A、3B圖所示之濕蝕刻法(Wet, Spray Etching),其係採一強酸或強鹼蝕刻液a (Etchant)之擴 散效應(D i f f u s i ο η )與待钱刻薄膜2 〇 (導電層)之表面分子 行化學反應以完成钱刻移除’而除了高餘刻速率與低使用 成本外’此種減成(S u b t r a c t i ν e )钱刻法尚具有姓刻後之 導電層厚度均勻度(U n i f o r m i t y )較高之優點,且由於該姓 刻法係藉該姓刻液2 3與特定材料之化學反應所致,因此其 蝕刻選擇性(Select ivity)將較其他方法佳,而不致移除 不欲姓刻的其他材料,惟也由於此種濕式蝕刻為一等向性 (I s 〇 t r 〇 p i c )蝕刻,因此在向下蝕刻時將導致如第3 B圖所 示之底切(U n d e r c u t)現象2 6,影響製程之精度,此一濕蝕 刻法的質量傳遞(M a s s T r a n s ρ 〇 r t)精度限制將使其蝕刻之 導線尺寸難以再往下發展。 相較於傳統之減成蝕刻法,目前產業界係採可製造更 細線路之加成(A d d i t i v e )法以因應更高密度之基板,其係 以無電解銅於絕緣層上形成一電鍍晶種層(Seed Layer ) 層’以形成導電層之圖案,此一可分為完全加成(?!111厂 A d d i t i v e )法與半加成(S e m i A d d i t i v e )法之製程,係可避 免蝕刻時所遭致的問題,目前習知上係以可製作較細電路 的半加成法進行基板製程:如第4 A圖所示,先於絕緣層5 0 上之金屬層51進行表面粗化(Surface Roughening),復如 第4 C圖所示壓合形成一介電層52,且於第4 D圖中對該介電 層52鑽孔(Dr i 1 1 ing)以形成一盲孔53(B1 ind Via),接200411757 V. Description of the invention (2) Above m, the traditional etching method with low cost and fast etching is generally used, that is, the wet etching method (Wet, Spray Etching) shown in Figures 3A and 3B, which uses a strong acid Or the strong alkaline etching solution a (Etchant) diffusion effect (D iffusi ο η) and the surface molecules of the film to be etched 20 〇 (conductive layer) to perform a chemical reaction to complete the etch removal, except for the high etch rate and low This cost reduction (Subtracti ν e) money engraving method has the advantage of higher uniformity (U niformity) of the conductive layer thickness after the last name engraving, and because the last name engraving method borrows the last name engraving liquid 2 3 due to the chemical reaction with specific materials, so its selectivity will be better than other methods, without removing other materials that are not intended to be engraved, but also because this wet etching is isotropic (I s 〇tr 〇pic) etching, so when etching down, it will lead to the undercut (U ndercut) phenomenon shown in Figure 3B 2 6, affecting the accuracy of the process, the quality of this wet etching method ( M ass T rans ρ 〇rt) Wire size restrictions will make it difficult to re-etching down the development. Compared with the traditional subtractive etching method, the industry currently adopts the additive method that can produce finer circuits to respond to higher density substrates. It uses electroless copper to form an electroplated crystal on the insulating layer. Seed layer layer to form a conductive layer pattern. This can be divided into the process of full addition (?! 111 factory A dditive) method and semi-additive (Semi A dditive) method, which can avoid etching. At present, it is conventionally known that the substrate process is performed by a semi-additive method capable of making thinner circuits: as shown in FIG. 4A, the surface roughening is performed before the metal layer 51 on the insulating layer 50. (Surface Roughening), as shown in FIG. 4C, a dielectric layer 52 is formed by pressing, and the dielectric layer 52 is drilled (Dr i 1 1 ing) to form a blind hole 53 in FIG. 4D. (B1 ind Via), then

17028. ptd 第7頁 200411757 五、發明說明(3) 著”如第4E圖所示形成一 | ^ ^令 …、龟解銅層5 4,並根據所設什之 導線如第4F圖般製作該雷你c ^ 電錢阻層55 (Resist Layer)之圖 案以形成電鍍銅56’而於第4G圖去除不必要的電鍍阻層55 =:mt導線層,此—製程所製成之封裝基板已可 將基板上之*,,泉尺寸加工至20至3 高效能之晶片與封裝件,惟若欲將導線精度再往下進展, 則復有製程精度無法克服之問題。又丹4下進展 至於一般用於半暮興制如^ 、 p , 1 . 、 ^ B 衣“之乾式姓刻法(D r y17028. ptd Page 7 200411757 V. Description of the invention (3) "Forming a | as shown in Figure 4E | ^ Order ..., torture the copper layer 5 4 and make it as shown in Figure 4F according to the wires provided The pattern of ^ resist layer 55 (Resist Layer) is used to form electroplated copper 56 ', and unnecessary plating resist layer 55 is removed in the 4G diagram. == mt wire layer, this—the packaging substrate made by the process It is already possible to process *, and spring sizes on the substrate to 20 to 3 high-performance wafers and packages, but if you want to further advance the accuracy of the wires, there are problems that cannot be overcome by the accuracy of the process. Another 4 progresses As for the dry-style surname engraving method commonly used in the mid-night period, such as ^, p, 1., ^ B clothing (Dry

Etching),不論是濺擊蝕玄彳Γ · % (Plasma Etchlng),iismr=g.Etchlng)或電聚 ^ /、非 # 向性(AniS〇tr〇Pic)之蝕 :性雖可達致較細之钱刻精度並縮小導線線寬 ===米(nm)…刻速率只適用於晶片厚度 需,同時,乾…係為一以該;敷所 理钱刻法,其餘刻選擇性並…轟K ?二刻表面之物 全程製‘作封壯苴钇介τ处1 ΐ心因此右採用乾蝕刻法 κ +衣基 可忐會有導電層遭受污毕之Η顆 口此,隨著半導體晶片上之製程技 ’、d1碭 級,現行之基板製程技術已漸不敷所需,如百;:、f奈米等 ,下導線尺寸之封裝基板確為t σ可2造出1 ^ 為唯有此-力…支術之突破,使得封//二發課題’因 路、更少叠層數與更低之成本有更細線 研發進展亦才有量產實現之可能。…與封裝技術之 【發明内容1Etching), whether it is splash erosion 蚀 ·% (Plasma Etchlng), iismr = g.Etchlng) or electropolymerization ^ /, non- # directional (AniS〇tr〇Pic) corrosion: Although the sex can reach the Fine money engraving accuracy and reducing the wire width === meters (nm)… the engraving rate is only applicable to the thickness of the wafer, at the same time, the dry… is the first one; the engraving method, the other engraving selectivity and… The whole process of making the surface of the second engraved K? Is made of the zirconium yttrium yttrium τ at 1 因此 center. Therefore, the dry etching method κ + clothing can be used, there will be a conductive layer subject to contamination. With the semiconductor The process technology on the wafer ', d1 level, the current substrate process technology is gradually insufficient, such as 100; f, nanometers, etc., the package substrate of the lower wire size is indeed t σ can be made 2 ^ is Only the breakthrough of this-force ... support technique, which makes the research and development of the second issue "closer, fewer stacks and lower costs, and finer line R & D progress, will it be possible to achieve mass production. … And packaging technology [Summary 1]

17028. ptd 第8頁 200411757 五、發明說明(4) 本發明之一目的在於提供一種高良率形成細線路基板 之製法。 本發明之另一目的在於提供一種具有非等向性蝕刻特 性且蝕刻選擇性高的形成細線路基板之製法。 本發明之再一目的在於提供一種可避免導電層表面出 現短路現象的形成細線路基板之製法。 本發明之又一目的在於提供一種蝕刻快速且易於控制 的形成細線路基板之製法。 為達前述及其他目的,本發明所提供之形成細線路基 板之製法,係包括:提供一於至少一表面上形成有一導電 層的絕緣層;在該導電層上形成一阻層,並圖案化該阻 層,以藉該圖案化阻層於該導電層上定義出一去除區與一 保留區;以電場活化電化學蝕刻方式不完全去除位於該去 除區之導電層;復以乾蝕刻方式完全去除位於該去除區中 所殘留之導電層;以及移除該圖案化之阻層,以令位於該 保留區中之導電層形成所欲之細線路。 本‘發明之形成細線路基板之製法復包括··提供一於至 少一表面上形成有一導電層的絕緣層;在該導電層上形成 一犧牲層,該犧牲層之材料係與該導電層不同;在該犧牲 層上形成一阻層,並圖案化該阻層,以藉該圖案化阻層於 該犧牲層與導電層上分別定義出一去除區與一保留區;以 電場活化電化學蝕刻方式不完全去除位於該去除區之犧牲 層與導電層;移除該圖案化之阻層;復以乾蝕刻方式完全 去除位於該去除區中所殘留之導電層;以及移除該位於保17028. ptd page 8 200411757 V. Description of the invention (4) One object of the present invention is to provide a method for forming a fine circuit substrate with a high yield. Another object of the present invention is to provide a method for forming a fine circuit substrate having anisotropic etching characteristics and high etching selectivity. It is still another object of the present invention to provide a method for forming a fine circuit substrate which can avoid the occurrence of a short circuit on the surface of the conductive layer. Another object of the present invention is to provide a method for forming a fine circuit substrate which is capable of etching quickly and easily. In order to achieve the foregoing and other objectives, the method for forming a fine circuit substrate provided by the present invention includes: providing an insulating layer having a conductive layer formed on at least one surface; forming a resist layer on the conductive layer and patterning the same The resistive layer is used to define a removal area and a retention area on the conductive layer by the patterned resistive layer; the conductive layer located in the removed area is not completely removed by an electric field activated electrochemical etching method; and the dry etching method is used to completely Removing the conductive layer remaining in the removed area; and removing the patterned resistive layer so that the conductive layer located in the reserved area forms a desired fine line. The method for forming a fine circuit substrate of the invention includes: providing an insulating layer having a conductive layer formed on at least one surface; forming a sacrificial layer on the conductive layer, and the material of the sacrificial layer being different from the conductive layer Forming a resist layer on the sacrificial layer and patterning the resist layer to define a removing area and a retaining area on the sacrificial layer and the conductive layer respectively by the patterned resist layer; activating the electrochemical etching with an electric field The method does not completely remove the sacrificial layer and the conductive layer located in the removed area; removes the patterned resistive layer; and then completely removes the conductive layer remaining in the removed area by dry etching; and removes the conductive layer located in the removed area.

17028. ptd 第9頁 200411757 五、發明說明(5) 留區之犧牲層,以令位於該保留區中之導電層形成所欲之 細線路。此外,本方法亦可於進行電化學蝕刻後、移除該 圖案化之阻層前,即先行以乾蝕刻方式去除位於該去除區 中所殘留之導電層。 其中,該電化學姓刻係以一外加電極施加一電場於一 化學式濕蝕刻過程中,以藉其電場之電流作為蝕刻液之帶 電荷離子的傳遞驅動力,產生一兼具有非等向性蝕刻與高 蝕刻速率之電化學蝕刻,以達至細線路與高均勻度之蝕刻 良率需求,並可藉由改變電場來調整各項蝕刻控制變因, 發f控制簡便之功效;同時,本發明並於蝕刻後段以一蝕 刻速率較慢之乾姓刻法取代電化學#刻法,以避免該電化 學蝕刻法產生過度蝕刻或底切之現象,並可將該去除區内 所殘餘的導電層完全蝕刻去除,以防止導線發生短路,此 外,亦可沉積一額外的犧牲層以保護該位於保留區内欲作 為導線之用的導電層,以防止材料選擇性較差的乾蝕刻法 污染該保留區内之導電層。 【實施‘方式】 本發明之形成細線路基板之製法的第一實施例係如第 1 A至1 E圖所示,其步驟依序包括在一絕緣層1 0之表面1 0 ’ 上^成一導電層20,接著在該導電層2 0上塗佈一阻層30, 並以一電場活性化姓刻方法(E 1 e c t r i c F i e 1 d - A c t i v a t e d Etching Process )依該圖案化之阻層3 0所定義的保留區 3 0 b與去除區3 0 a钱刻該去除區之導電層2 0 a,復以乾蝕刻 方法蝕刻該去除區中所殘留之導電層2 0 aπ,最終並將該位17028. ptd page 9 200411757 V. Description of the invention (5) The sacrificial layer in the reserved area, so that the conductive layer in the reserved area forms the desired fine line. In addition, the method can also remove the conductive layer remaining in the removal area by dry etching before performing the electrochemical etching and before removing the patterned resist layer. Among them, the electrochemical name engraving uses an external electrode to apply an electric field to a chemical wet etching process, and uses the electric current of the electric field as the driving force for the transfer of charged ions in the etching solution, resulting in a combination of anisotropy. Etching and electrochemical etching with high etch rate, to meet the needs of fine lines and high uniformity etch yield, and can change various etching control variables by changing the electric field, and the effect of f control is simple; at the same time, this Invented and replaced the electrochemical #etching method with a dry etching method with a slower etch rate at the back of the etching to avoid the phenomenon of over-etching or undercutting caused by the electrochemical etching method, and the remaining conductive in the removal area The layer is completely etched away to prevent the short circuit of the wire. In addition, an additional sacrificial layer can be deposited to protect the conductive layer used as the wire in the reserved area to prevent the dry etching method with poor material selectivity from contaminating the reservation. Conductive layer in the area. [Implementation Mode] The first embodiment of the method for forming a fine circuit substrate of the present invention is shown in FIGS. 1A to 1E, and its steps include sequentially forming a surface 1 0 ′ of an insulating layer 10 into one. The conductive layer 20 is then coated with a resist layer 30 on the conductive layer 20, and an electric field activation method (E 1 ectric Fie 1 d-A ctivated Etching Process) is used according to the patterned resist layer 3 The reserved area 3 0 b defined by 0 and the removed area 3 0 a are engraved with the conductive layer 2 0 a in the removed area, and the dry conductive method is used to etch the conductive layer 2 0 aπ remaining in the removed area. Bit

17028. ptd 第10頁 200411757 五、發明說明(6) 於保留區之阻層3 0 b移除。 其中,如第1 A圖,係為一例如封裝基板或習知印刷電 路板之單面絕緣層1 〇,並於其以環氧樹脂(Epoxy Resin)、聚乙酸胺(Polyimide)、氰脂(Cyanate Ester)、 玻璃纖維、雙順丁烯二酸醯亞胺/三氮阱(BT, B i s m a 1 e i m i d e T r i a z i n e )或混合環氧樹脂與玻璃纖維 (F R 5 )等材質所構成之表面1 〇 ’上,以一習知的薄膜沉積法 形成一導電金屬層2 0,其中,該薄膜沉積法可為一蒸鍍法 (Evaporation)^ It ^ ( Sputter i ng) > # M m: M (Laser Ablation Deposit ion)或各種化學氣相沉積法(CVD),而 該導電金屬層2 0之材料一般係以導電性較佳之銅(c u )為 主,亦可以鋁(A1 )、鉻(Ci〇或鎳(Ni )等金屬取代之,以作 為該基板傳遞訊號之導線材料。第1 B圖係表示於該導電銅 層2 0上塗佈一高解析度之阻層30,該阻層3〇係以樹脂 0^3:[11)、感光劑(36113:11^261〇及溶劑(8〇1¥6111;)依不同成 分所混合構成,其係以習知之微影(Ph〇t〇1 ith〇graphy)製 程經由‘曝光(Exposure)、頒影(Develop )與烘烤(Bake)耸 步驟,將一預先設計之細線路圖案(1^1^^11)轉移至該阻一 層30上,並藉此定義出一保留區(不蝕刻)與一去除區(待 名虫刻)’以進行後續之钱刻步驟。 第1 c圖係以蝕刻之方式將該導電銅層2 〇蝕刻出一預先 設計的細線路,惟由於本發明所針對之15// m以下之細線 路退較習知封裝基板之導線尺寸來得精細,因此一般用於 封裝基板製程上的習知濕蝕刻法與半加成法均難以達至此17028. ptd page 10 200411757 V. Description of the invention (6) The resist layer 3 0 b in the reserved area is removed. Among them, as shown in FIG. 1A, it is a single-sided insulating layer 10 such as a package substrate or a conventional printed circuit board, and epoxy resin (Epoxy Resin), polyimide (Polyimide), and cyanoester ( Cyanate Ester), glass fiber, bismaleimide / imide / triazine (BT, Bisma 1 eimide Triazine) or a mixture of epoxy resin and glass fiber (FR 5) and other materials 1 〇 On the above, a conductive metal layer 20 is formed by a conventional thin film deposition method, wherein the thin film deposition method may be an evaporation method ^ It ^ (Sputter i ng) ># M m: M ( Laser Ablation Deposit ion) or various chemical vapor deposition methods (CVD), and the material of the conductive metal layer 20 is generally copper (cu) with better conductivity, but also aluminum (A1), chromium (Ci) It can be replaced by metal such as nickel (Ni) as the wire material for transmitting signals to the substrate. Figure 1B shows that a high-resolution resistive layer 30 is coated on the conductive copper layer 20, and the resistive layer 30. Based on resin 0 ^ 3: [11), photosensitizer (36113: 11 ^ 261〇, and solvent (8〇1 ¥ 6111;) depending on the composition The branch is composed of mixed materials, which is a pre-designed thin line by the process of exposure, development, and baking in the conventional process of Ph0t〇1 ith〇graphy. The road pattern (1 ^ 1 ^^ 11) is transferred to the barrier layer 30, and a reserved area (not etched) and a removed area (to be etched by the famous insect) are defined to perform subsequent money engraving steps. Figure 1c shows the conductive copper layer 20 is etched into a thin circuit designed in advance by etching, but the thin circuit below 15 // m targeted by the present invention is finer than the wire size of the conventional package substrate. Therefore, the conventional wet etching method and semi-additive method generally used in the packaging substrate manufacturing process are difficult to achieve.

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17028. ptd 第12頁 200411757 五、發明說明(8) 此一電場活性化蝕刻法之蝕刻速率雖快,但卻也造成 其钱刻終點偵測(E n d - P 〇 i n t D e t e c t )之不易,而可能導致 過度#刻(〇ver Etch)之問題,且蝕刻液23的等向性化學 钱刻所造成之底切(Under Etch)現象亦可能超出本製程所 能接受之範圍,進而影響製程精度,惟若為防止上述現象 而提早中止蝕刻,又可能造成該去除區中蝕刻不完全的殘 餘導電鋼層2 0 a,,,導致封裝基板上導電線路的短路現象, 形成兩難之問題。本實施例針對此問題係如第1 C圖所示於 該待蝕刻之去除區尚殘餘有部分導電銅層2 〇 a,f (如約0 · 1至 0 · 5 // m)時’停止該電場活性化钱刻法,並改採一乾姓刻 法去除該殘餘導電銅層2 0 a,’,以解決前述問題,此係由於 乾餘刻法具有非等向性钱刻與钱刻速率較慢(每分鐘僅>1虫 刻數奈米)之特性’可付合此處需求’而由於乾餘刻法之 Ί虫刻擇性較差’因此此步驟係如圖所示仍保留位於該保 留區之殘餘阻層3 0 b,以避免進行乾式蝕刻時該保留區内 的導電銅層2 0 b受到不必要的蝕刻;該乾式蝕刻係,可採用 習知的4濺擊姓刻(S p u 11 e r i n g E t c h i n g )、電漿钱刻 (Plasma Etching)、反應性離子蝕刻(RIE,Reactive 1½ E t ch i ng)或雷射蝕刻(Laser E t ch i ng )等方法,笪 合濺擊與電漿蝕刻兩者之特性的反應性離子4 〃 ' 般 除17028. ptd Page 12 200411757 V. Description of the invention (8) Although the etching rate of this electric field activation etching method is fast, it also makes its end-point detection (E nd-Point Detect) difficult. And it may cause the problem of excessive #etch (0ver Etch), and the undercut phenomenon caused by the isotropic chemical etching of the etching solution 23 may also exceed the acceptable range of this process, thereby affecting the accuracy of the process However, if the etching is stopped early in order to prevent the above-mentioned phenomenon, it may cause the remaining conductive steel layer 20 a incompletely etched in the removal area, resulting in a short circuit phenomenon of the conductive lines on the package substrate, forming a dilemma. To solve this problem in this embodiment, as shown in FIG. 1C, the conductive copper layer 2a, f (for example, about 0 · 1 to 0 · 5 // m) is left in the removed area to be etched. The electric field activation method is used to remove the residual conductive copper layer 20a, 'by using a dry-cut method to solve the foregoing problem. This is because the dry-remove method has an anisotropic money engraving and money engraving rate. Slower (only> 1 nanoseconds per minute) feature 'can meet the needs here' and because of the poor selectivity of tapeworms in the dry-cut method, this step is still reserved as shown in the figure The remaining resistance layer 3 0 b in the reserved area is used to avoid unnecessary etching of the conductive copper layer 2 b in the reserved area during dry etching. The dry etching system may use the conventional 4 sputtering method ( S pu 11 ering E tching), Plasma Etching, Reactive Ion Etching (RIE, Reactive 1½ E t ch i ng), or Laser Etching (Laser E t ch i ng) Reactive ions that are characteristic of both strike and plasma etching

f 丁蚀刻法氣 較常使用之方法,此係由於其兼具有物理與化風 > 与— 薄膜的機制,可兼及非等向性蝕刻與良好餘刻^兩種去 需求,且其蝕刻速率亦較雷射蝕刻為快,以=擇彳生兩項 A現有枯化 言,反應性離子蝕刻法蝕刻後之薄膜輪廓可、章 又何而 運至8 〇。至f Ding etching method is more commonly used. This is because it has both physical and chemical winds and the thin film mechanism, which can meet both the anisotropic etching and the good clearance ^, and its The etching rate is also faster than laser etching. With the two existing options of A and B, the contours of the thin film after reactive ion etching can be transported to 80%. to

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9(l·。之垂直度,且其對蝕刻材料與其他材料的選 達至40 : 1。本實施例係採用含有氯原子或其他氣體、可 應性氣體2 4 ( R e a c t i v e G a s )進行該去除區内綠〜 %赞;¥電麵]展 2 0an之反應性離子蝕刻,可如第1D圖所示,传曰 銅層20an與反應性氣體24形成CuCl雨揮菸,祕力& 包 ^ '丨隹鋼雖較复你 金屬有較佳之導電性’但其生成物CuCl卻非一揮發性/、 之物質(一般需至2 0 (TC才可揮發),因此進行此乾^姓=子 製程時,可適當調高反應溫度或增加輸入電裝中的+力 (P 〇 w e r ),以較大之直流偏壓(D C B i a s )加強離子義^的 理0刻效應,提升銅蝕刻之速率與能力。 * 、勿 接著’當以乾钱刻法元全去除該去除區所殘餘之導# 銅層20a”後,即可如第1E圖所示去除該位於保留區且已= 部分乾蝕刻之阻層30b,去除阻層30b之方法係可# 士 η化 〜、』休百機溶 液(濕4 )或電漿(乾式)將阻層30b去除並保留該保留區内 欲作為導線用之導電銅層2 0 b,至於一般半導體製程常用 的濕式無機溶液去光阻法,由於其所採用之無機溶液如碎 酸或雙氧水,常可能會同時侵姓導電層20b,尤^ ^ 、足以在呂 作為導電層時,因此本製程中並不採用此一去阻層法。待 去除阻層後,即可得此一具有1 5 # m以下之細線路芙板: 籲本發明之第二實施例係如第2A至2G圖所示,其二於第 一實施例之製程中加上一道犧牲層40(Sacrif icial Layer)之沉積步驟,以於該蝕刻製程中避免該保留區内作 為導線用之導電銅層2 0 b遭到污染,其步驟依序包括°σ在一 絕緣層1 0之絕緣表面1 0 ’上形成一導電層2 0,接著在兮導 17028. ptd ΜThe verticality of 9 (l ..), and its choice of etching materials and other materials is up to 40: 1. This embodiment is performed by using a reactive gas containing chlorine atoms or other gases, 2 4 (R eactive G as) In the removal area, green ~% like; ¥ electric surface] exhibiting 20 an reactive ion etching, as shown in FIG. 1D, it can be said that the copper layer 20an and the reactive gas 24 form CuCl rain and smoke, mystery & Package ^ 'Although 隹 steel has better conductivity than your metal', its CuCl product is not a volatile /, (usually until 20 (TC can be volatile), so this dry ^ In the sub-process, the reaction temperature can be appropriately increased or the + force (P ower) in the input electronics can be increased. The larger the DC bias (DCB ias) is used to enhance the effect of the ionization and the copper etching. Rate and ability. * Do n’t continue with “When the remaining guides # 铜 层 20a” in the removed area are completely removed by dry money engraving, you can remove the part that is located in the reserved area and has = part as shown in Figure 1E. The dry etching of the resist layer 30b, and the method of removing the resist layer 30b can be # 士 η 化 ~, "Hubei solution (wet 4) or plasma ( Dry type) The resist layer 30b is removed and the conductive copper layer 20b intended to be used as a conductor in the reserved area is retained. As for the wet inorganic solution de-photoresistance method commonly used in general semiconductor processes, due to the inorganic solution such as crushed acid Or hydrogen peroxide may often invade the conductive layer 20b at the same time, especially when ^ is used as the conductive layer, so this process is not used to remove the resistance layer. After removing the resistance layer, you can get this A thin circuit board with a size of 1 5 # m or less: The second embodiment of the present invention is shown in Figures 2A to 2G, and the second is to add a sacrificial layer 40 (Sacrif icial Layer) to the process of the first embodiment. ) In order to avoid contamination of the conductive copper layer 20 b used as a conductor in the reserved area during the etching process, and the steps include ° σ on an insulating surface 10 of the insulating layer 10 in sequence. A conductive layer 20 is formed, and then the conductive layer is 17028. ptd Μ

第14頁 200411757 五、發明說明(ίο) 電層2 0上沉積一薄犧牲層4 〇,復再塗佈一圖案化之阻層 3 0,並以電場活性化钱刻方法依阻層3 〇上所定義之保留區 3 0 b與去除區3 0 a钱刻該去除區内的犧牲層4 〇 3與導電層 2 ’再移除保留區内剩餘之阻層3 〇 b,復以乾蝕刻方式蝕 刻該去除區中所殘留之導電層2〇a",最終將位於該保留區 内=剩餘犧牲層40b移除,·其中,該犧牲層4〇b係於乾蝕刻 步恥中用以取代第一實施例中之阻層3 〇 b,以保護該保留 區内之導電層20b免受乾蝕刻污染,此外,本實施例亦可 於去除阻層3 0 b前即先施以乾蝕刻步驟以去除該去 之殘餘導電層20a",不必限於一定得在去除阻層 可進行該乾蝕刻步驟。 sMb後才 不再i ί二:施例製程中與第-實施例相同之步驟此處即 絕緣乂 f坪細況明其增加之步驟:第2Α圖同樣係於- 電銅;2π,ΐ面士沉積一導電銅層20,再於第2Β®於該導 Μ '儿積一犧牲層4 0 ’該犧牲層4 0之沉積法係如、„ ,導電銅層20般可為蒸鍍、濺鍍、雷射蒸鍍或各種化風: 一種,由於該犧牲層40之作用僅為保護該 " v包銅層2 0 b,故其沉積厚度不需太厚且可為任竹- 非金屬材料亦可,僅需與該導電層上不同 二 亦即该犧牲層40之沉積厚度與使用材料均賴 遠=笔層20而定,此係由於最末步驟欲去除位於保留區二 :歹'餘犧牲層40b時,需顧及該去除藥劑之材料選性° :之=去除該犧牲層働時亦-併…保留作為ί 、’ ^曰2 0 b,一般我們可採用金屬錫(或者鋁、金、鎳Page 14 200411757 V. Description of the invention (ίο) A thin sacrificial layer 40 is deposited on the electrical layer 20, and a patterned resist layer 30 is coated, and the resist layer 3 is applied by an electric field activation method. The remaining area 3 0 b and the removal area 30 a defined above are engraved with the sacrificial layer 4 0 3 and the conductive layer 2 in the removal area, and then the remaining resistance layer 3 〇b in the reservation area is removed, followed by dry etching. The remaining conductive layer 20a in the removed area is etched in a manner such that it is located in the reserved area = the remaining sacrificial layer 40b is removed, wherein the sacrificial layer 40b is used in the dry etching step to replace The resist layer 30b in the first embodiment is used to protect the conductive layer 20b in the reserved area from being polluted by dry etching. In addition, in this embodiment, a dry etching step may be performed before removing the resist layer 30b. In order to remove the removed residual conductive layer 20a, the dry etching step need not be limited to removing the resist layer. After sMb, it is no longer two. The same steps in the manufacturing process as in the first embodiment. Here is the detailed step of the insulation 坪 f ping. The second step is also related to-copper; 2π, ΐ A conductive copper layer 20 is deposited on the substrate 2 and a sacrificial layer 40 is deposited on the conductive layer 2 ′. The deposition method of the sacrificial layer 40 is, for example, the conductive copper layer 20 can be evaporated or sputtered. Plating, laser vapor deposition, or various winds: One, because the role of the sacrificial layer 40 is only to protect the " v copper-clad layer 2 0 b, its deposition thickness need not be too thick and can be any bamboo-non-metal The material can also be different from the conductive layer, that is, the thickness of the sacrificial layer 40 and the material used depend on the distance of the pen layer 20. This is because the last step is to remove the second layer: 歹 ' For the remaining sacrificial layer 40b, the material selectivity of the removal agent needs to be taken into account:: = When the sacrificial layer is removed, and-and is reserved as ί, '^^ 2 0b, generally we can use metal tin (or aluminum, Gold and nickel

17028.ptd 第15頁 200411757 五、發明說明(11) 等◊材料作為犧牲層4 0,復於最末欲去除該犧牲層4 0 b時選 用可去除錫而不致侵蝕銅之化學溶液(例如脫錫夢劑)即 〇 第2 C圖係於該犧牲層4 0上塗佈一圖案化之阻層3 0,並 以前述之電場活性化蝕刻法如第2 D圖所示依該細線路之圖 案蝕刻該去除區中的犧牲層40a與導電銅層20a,而為避免 過度蝕刻與底切之現象,同樣於該去除區内留下一適當厚 度的殘餘導電銅層2 0 a ”後,轉以乾蝕刻法進行最末之蝕 刻,本實施例中由於已有犧牲層4 0 b保護該欲保留之導電 銅0 2 0 b,故可先於第2 E圖之步驟去除保留區内之阻層 3 0 b,其去除之方式係與第一實施例相同;之後並如第2 F 圖所示以乾式蝕刻法去除位於去除區内之殘餘導電銅層 2 0 aπ,以避免基板之短路現象,該乾蝕刻法同樣可採用反 應性離.子蝕刻法,惟本實施例中可設計其反應性氣體2 4之 組成成分,以改變#刻之材料選擇性,例如可控制使該反 應性氣體2 4其蝕刻導電層2 0 (銅)的速率與蝕刻犧牲層 4 0 (錫‘)的速率為1 0 : 1,如此則僅需使殘餘之導電銅層 2 0 aπ厚度(如為0 . 1至0 . 5 // m )與所沉積之犧牲層4 0 b厚度 相近或略大,即可確保當殘餘導電銅層2 0 a ’’已被完全移除 時φ該保留區内之犧牲層4 0 b尚餘有一定之厚度,而不致 侵蝕到不必要的導電銅層2 0 b,以發揮本實施例沉積一額 外犧牲層4 0的保護作用,並使其保護欲形成導線之導電銅 層2 0 b的功效較第一實施例更佳;第2 G圖即如前述,以一 不致侵蝕銅的脫錫藥劑去除保留區内殘餘之犧牲層4 0 b,17028.ptd Page 15 200411757 V. Description of the invention (11) Other sacrificial materials are used as the sacrificial layer 40. When the sacrificial layer 40b is to be removed at the end, a chemical solution (such as Tin dream agent), that is, figure 2C is coated with a patterned resist layer 30 on the sacrificial layer 40, and the aforementioned electric field activation etching method is used as shown in figure 2D according to the thin line. The sacrificial layer 40a and the conductive copper layer 20a in the removed area are pattern-etched. To avoid the phenomenon of over-etching and undercutting, a residual conductive copper layer 20a of an appropriate thickness is left in the removed area. The final etching is performed by a dry etching method. In this embodiment, since the sacrificial layer 4 0 b already protects the conductive copper 0 2 0 b to be retained, the resistance in the reserved area can be removed before the step in FIG. 2E. The layer 3 0 b is removed in the same manner as in the first embodiment; after that, as shown in FIG. 2 F, the remaining conductive copper layer 20 aπ located in the removal area is removed by dry etching to avoid a short circuit of the substrate. The dry etching method can also use a reactive ion etching method, but in this embodiment, The composition of the reactive gas 2 4 is designed to change the material selectivity of the etch. For example, the rate at which the reactive gas 2 4 can etch the conductive layer 2 0 (copper) and the etching rate of the sacrificial layer 4 0 (tin ' ) At a rate of 10: 1, so only the thickness of the remaining conductive copper layer 20 aπ (such as 0.1 to 0.5 // m) is similar to or slightly thicker than the thickness of the deposited sacrificial layer 40b. Large, it can ensure that when the residual conductive copper layer 2 0 a ″ has been completely removed, the sacrificial layer 4 0 b in the reserved area has a certain thickness, so as not to erode the unnecessary conductive copper layer 2 0 b, in order to exert the protective effect of depositing an additional sacrificial layer 40 in this embodiment, and to protect the conductive copper layer 2 0 b which is to form a wire, the effect is better than that in the first embodiment; FIG. 2 G is as described above To remove the residual sacrificial layer 4 0 b in the reserved area with a de-tinning agent that does not erode copper,

17028. ptd 第16頁 200411757 五、發明說明(12) 保留該形成細 以下之細線路 綜上所述 作一具有細線 |虫刻與餘刻材 方法亦兼有姓 本發明之 法,其他基板 效代換步驟亦 單面基板外, 程;同時,隨 勢,本發明除 半導體導線與 錄製程,、以及 惟以上所 用以限定本創 揭示之4精神與 皆由後述之申 線路之導電銅 的封裝基板。 ’本發明之形 路(1 5 // ra以下 料選擇性佳等 刻快速、成本 前揭各步驟並 製程或半導體 可用於本發明 亦可用於雙面 著電子工業高 封裝基板與印 光罩製程、光 大面積面板顯 述者,僅為本 作之範圍,舉 原理下所完成 請專利範圍所 層2〇b,而得此一具有15 am 成細線路基 )之基板外: 南良率優點 低廉與控制 不僅限於實 製程中以其 之方法中, 板、多層板 密度與高效 刷電路板外 碟(CD)與數 示器等其他 創作之具體 凡热習此項 的一切等效 涵蓋。 板之製法,除可製 亦具有非專向性 ,同時其電場控制 簡易之功效。 施例中所述之方 他材料或設備之等 且此一方法除用於 或軟板之細線路製 能運算之發展趨 ’亦可運用於例如 位式光碟(DVD)寫 基板製程上。 實施例而已,並非 技#者在本創作所 改麦或修飾,仍應17028. ptd page 16 200411757 V. Description of the invention (12) Retain the thin lines below the formation. In summary, make a line with a thin line | insect engraving and remaining engraving method. It also has the method of the present invention, other substrate effects. The replacement step is also a single-sided substrate, and at the same time, as the situation demands, the present invention, except for semiconductor wires and recording processes, and the above-mentioned four spirits used to limit the original disclosure and the conductive copper package are all covered by the application circuit described later. Substrate. 'The shape of the present invention (1 5 // ra, the selectivity of the material is good, etc. are fast, the steps and processes are disclosed before the cost, or the semiconductor can be used in the present invention, and it can also be used in the double-sided electronic industry high packaging substrate and printing mask manufacturing process The display of the large-area panel is only the scope of this work. For example, the patented scope is 20b, which is based on the principle. In addition, this substrate has a fine circuit base of 15 am). Control is not limited to the methods used in the actual manufacturing process, board, multi-layer board density, high-efficiency brushed circuit board (CD) and digital display, and other creative creations of all the specific hot topics covered by this equivalent. The manufacturing method of the board, besides being able to manufacture, is also non-specific, and its electric field control is simple and effective. Other methods or materials described in the examples and this method can be applied to the development of thin-line energy-capacity calculations of flexible boards or flexible boards, for example, in the manufacturing process of bit discs (DVD) writing substrates. It ’s just an example, it ’s not a modification or modification made by the technical person in this creation, it should still be

200411757 圖式簡單說明 【圖式簡單說明】 第1 A至1 E圖係本發明之形成細線路基板之製法的第一 實施例製程示意圖; 第2 A至2 G圖係本發明之形成細線路基板之製法的第二 實施例製程示意圖; 第3 A及3 B圖係習知之濕式蝕刻法的基板製程示意圖; 以及 第4A至4G圖係習知之半加成法的基板製程示意圖。 ΐφ 絕 緣 層 10’ 絕 緣 表 面 20 導 電 層 20a 去 除 區 導 電 層 20b 保 留 區 導 電 層 2 0aM 雀虫 刻 後 殘 餘 之導電層 23 姓 刻 液 24 反 應 性 氣 體 25 電 極 25a 電 極 之 陰 極 26 底 切 現 象 30 阻 層 30a 去 除 阻 層 30b 保 留 區 阻 層 40 犧‘ 牲 層 40a 去 除 區 犧 牲 層 40b 保 留 區 犧 牲 層 50 絕 緣 層 51 金 屬 52 介 電 層 5# 盲 孔 54 無 電 解 銅 層 55 電 鍍 阻 層 56 電 鍍 銅200411757 Brief description of the drawings [Simplified description of the drawings] Figures 1 A to 1 E are schematic diagrams of the first embodiment of the method for forming a fine circuit substrate of the present invention; Figures 2 A to 2 G are the fine lines of the present invention. Schematic diagrams of the second embodiment of the substrate manufacturing method; FIGS. 3A and 3B are schematic diagrams of the substrate manufacturing process of the conventional wet etching method; and FIGS. 4A to 4G are schematic diagrams of the substrate manufacturing process of the conventional semi-additive method. ΐφ Insulating layer 10 'Insulating surface 20 Conductive layer 20a Conductive layer in removed zone 20b Conductive layer in reserved zone 2 0aM Residual conductive layer after engraving 23 Name engraving liquid 24 Reactive gas 25 Electrode 25a Cathode of electrode 26 Undercut phenomenon 30 Resistance Layer 30a, removing resist layer 30b, remaining area resist layer 40, sacrificial layer 40a, removing area sacrificial layer 40b, retaining area sacrificial layer 50, insulating layer 51 metal 52 dielectric layer 5 # blind hole 54 electroless copper layer 55 electroplating resist layer 56 electroplating copper

17028. ptd 第18頁17028.ptd Page 18

Claims (1)

200411757 六、申請專利範圍 1. 一種形成細線路基板之製法,其步驟係包括: 提供一絕緣層,令該絕緣層之至少一表面上形成 一導電層; 在該導電層上形成一阻層,並圖案化該阻層,以 藉該圖案化之阻層於該導電層上定義出一去除區及一 保留區; 以電化學蝕刻方式不完全去除位於該去除區之導 電層; 以乾蝕刻方式完全去除位於該去除區中所殘留之 導電層;以及 移除該圖案化之阻層,以令位於該保留區中之導 電層形成所欲之細線路。 2 .如申請專利範圍第1項之形成細線路基板之製法,其中 ,用以形成該絕緣層之材料係選自由壞氧樹脂、聚乙 醯胺、氰脂、玻璃纖維、B T及F R 5所組成之組群之一 者。 3. 如争請專利範圍第1項之形成細線路基板之製法,其中 ,該導電層之材料係選自由導電性佳之銅、鋁、鉻及 鎳所組成之組群之一者。 4. 如申請專利範圍第1項之形成細線路基板之製法,其中 ,該阻層係為一高解析度之光阻層。 5. 如申請專利範圍第1項之形成細線路基板之製法,其中 ,該電化學之姓刻方式係為一電場活性化I虫刻 (Electric Field—Activated Etching)方式,其 4系酉己200411757 VI. Application Patent Scope 1. A method for forming a thin circuit substrate, the steps of which include: providing an insulating layer so that a conductive layer is formed on at least one surface of the insulating layer; forming a resistive layer on the conductive layer, And patterning the resist layer to define a removed area and a reserved area on the conductive layer by the patterned resist layer; incomplete removal of the conductive layer located in the removed area by electrochemical etching; dry etching Completely removing the conductive layer remaining in the removed area; and removing the patterned resistive layer so that the conductive layer located in the reserved area forms a desired fine line. 2. The method for forming a fine circuit substrate as described in item 1 of the scope of patent application, wherein the material used to form the insulating layer is selected from the group consisting of bad oxygen resin, polyvinylamine, cyanoester, glass fiber, BT and FR 5. One of the group. 3. If a method for forming a fine circuit substrate according to item 1 of the patent is claimed, wherein the material of the conductive layer is one selected from the group consisting of copper, aluminum, chromium and nickel with good conductivity. 4. The method for forming a fine circuit substrate as described in the first patent application, wherein the resist layer is a high-resolution photoresist layer. 5. For the method for forming a thin circuit substrate according to item 1 of the scope of the patent application, wherein the electrochemical method of engraving is an electric field activation (Electric Field-Activated Etching) method, and the fourth method is 17028. ptd 第19頁 200411757 六、申請專利範圍 '置一對電極與一可餘刻該導電層材料之餘刻液,以使 該電極之電場驅動該姓刻液進行一非等向性的電化學 名虫刻。 6. 如申請專利範圍第5項之形成細線路基板之製法,其中 ,該蝕刻液係選自可蝕刻該導電層材料之酸性溶液與 驗性溶液之一者。 7. 如申請專利範圍第1項之形成細線路基板之製法,其中 ,該乾#刻之方式係選自由丨賤擊#刻、電衆#刻、反 應性離子蝕刻(R I E )及雷射蝕刻法所組成之組群之一 φ者。 8. 如申請專利範圍第7項之形成細線路基板之製法,其中 ,該反應性離子蝕刻法所使用之反應性氣體係為一含 有氯原子(C 1 )之反應性氣體。 9. 一種形成細線路基板之製法,其步驟係包括: 提供一絕緣層,令該絕緣層之至少一表面上形成 一導電層; ‘ ’在該導電層上形成一犧牲層,且該犧牲層之材料 係與該導電層不同; 一 在該犧牲層上形成一阻層,並圖案化該阻層,以 _藉該圖案化之阻層於該犧牲層與導電層上定義出一去 除區及一保留區; 以電化學蝕刻方式不完全去除位於該去除區之犧 牲層與導電層; 以乾蝕刻方式完全去除位於該去除區中所殘留之17028. ptd page 19 200411757 VI. Application for patents' Set a pair of electrodes and a remaining etching solution that can etch the conductive layer material, so that the electric field of the electrode drives the etching solution for an anisotropic electrification Scientific name insect engraving. 6. The method for forming a fine circuit substrate according to item 5 of the application, wherein the etching solution is selected from one of an acidic solution and a test solution that can etch the conductive layer material. 7. For example, the method for forming a fine circuit substrate according to item 1 of the patent application, wherein the dry #etching method is selected from the group consisting of 丨 low strike # 刻, 电 众 # 刻, reactive ion etching (RIE) and laser etching. One of the groups formed by law. 8. The method for forming a fine circuit substrate according to item 7 of the scope of patent application, wherein the reactive gas system used in the reactive ion etching method is a reactive gas containing a chlorine atom (C 1). 9. A method for forming a fine circuit substrate, the steps comprising: providing an insulating layer so that a conductive layer is formed on at least one surface of the insulating layer; '' 'forming a sacrificial layer on the conductive layer, and the sacrificial layer The material is different from the conductive layer; a resist layer is formed on the sacrificial layer, and the resist layer is patterned to define a removal area on the sacrificial layer and the conductive layer by the patterned resist layer and A reserved area; incomplete removal of the sacrificial layer and the conductive layer in the removed area by electrochemical etching; completely removal of the remaining in the removed area by dry etching 17028. ptd 第20頁 200411757 六、申請專利範圍 導電層;以及 移除該位於保留區之犧牲層,以令位於該保留區 中之導電層形成所欲之細線路。 1 0 .如申請專利範圍第9項之形成細線路基板之製法,其中 ,該圖案化之阻層係於進行乾蝕刻之前移除。 1 1 .如申請專利範圍第9項之形成細線路基板之製法,其中 ,該圖案化之阻層係於進行乾蝕刻之後移除。 1 2 .如申請專利範圍第9項之形成細線路基板之製法,其中 ,該絕緣層係選自由環氧樹脂、聚乙醯胺、氰脂、玻 璃纖維、B T及F R 5所組成之組群之一者。 1 3 .如申請專利範圍第9項之形成細線路基板之製法,其中 ,該導電層之材料係選自由導電性佳之銅、鋁、鉻及 鎳等材料所組成之組群之一者。 1 4 .如申請專利範圍第9項之形成細線路基板之製法,其中 ,該犧牲層之材料係選自由錫、銘、金及錄等材料所 組成之組群之一者,惟其所選擇之材料需與該.導電層 之^才:料不同。 1 5 .如申請專利範圍第9項之形成細線路基板之製法,其中 ,該阻層係為一高解析度之光阻層。 1 6 .如申請專利範圍第9項之形成細線路基板之製法,其中 ,該電化學之蝕刻方式係為一電場活性化蝕刻 (Electric Field-Activated Etching)方式,其係配 置一對電極與一可姓刻該犧牲層與該導電層材料之# 刻液,以使該電極之電場驅動該蝕刻液進行一非等向17028. ptd page 20 200411757 VI. Patent application conductive layer; and remove the sacrificial layer located in the reserved area so that the conductive layer located in the reserved area forms the desired fine line. 10. The method for forming a fine circuit substrate according to item 9 of the scope of patent application, wherein the patterned resist layer is removed before dry etching. 1 1. The method for forming a fine circuit substrate according to item 9 of the scope of patent application, wherein the patterned resist layer is removed after dry etching. 1 2. The method for forming a thin circuit substrate according to item 9 of the scope of the patent application, wherein the insulating layer is selected from the group consisting of epoxy resin, polyvinylamine, cyanoester, glass fiber, BT and FR 5. One of them. 1 3. According to the method for forming a fine circuit substrate according to item 9 of the scope of the patent application, wherein the material of the conductive layer is one selected from the group consisting of materials with good conductivity such as copper, aluminum, chromium, and nickel. 14. If the method for forming a fine circuit substrate according to item 9 of the scope of patent application, wherein the material of the sacrificial layer is selected from one of the group consisting of tin, Ming, gold, and other materials, but the choice of The material needs to be different from the conductive layer: the material is different. 15. The method for forming a fine circuit substrate according to item 9 of the scope of patent application, wherein the resist layer is a high-resolution photoresist layer. 16. The method for forming a fine circuit substrate according to item 9 of the scope of the patent application, wherein the electrochemical etching method is an electric field-activated etching method, which is configured with a pair of electrodes and a The etch solution of the sacrificial layer and the conductive layer material can be engraved so that the electric field of the electrode drives the etching solution to perform an anisotropy. 17028. ptd 第21頁 200411757 六、申請專利範圍 生的電化學餘刻。 1 7 .如申請專利範圍第1 6項之形成細線路基板之製法,其 中,該蝕刻液係選自可蝕刻該犧牲層與該導電層材料 之酸性溶液與驗性溶液之一者。 1 8 .如申請專利範圍第9項之形成細線路基板之製法,其中 ,該乾钱刻之方式係選自由滅擊钱刻、電聚钱刻、反 應性離子蝕刻(R I E )及雷射蝕刻法所組成之組群之一 者。 · 1 9 .如申請專利範圍第1 8項之形成細線路基板之製法,其 φ中,該反應性離子蝕刻法所使用之反應性氣體係為一 含有氯原子(C 1 )之反應性氣體。17028. ptd page 21 200411757 6. Scope of patent application 17. The method for forming a thin circuit substrate according to item 16 of the scope of patent application, wherein the etching solution is selected from one of an acidic solution and a test solution that can etch the material of the sacrificial layer and the conductive layer. 18. The method for forming a fine circuit substrate according to item 9 of the scope of the patent application, wherein the method of the dry money engraving is selected from the group consisting of sterilization money engraving, electricity gathering engraving, reactive ion etching (RIE) and laser etching. One of the groups formed by law. · 19. According to the method for producing a fine circuit substrate according to item 18 of the scope of patent application, in φ, the reactive gas system used in the reactive ion etching method is a reactive gas containing a chlorine atom (C 1) . 17028. ptd 第22頁17028.ptd Page 22
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