TW200410402A - Manufacturing method of flash memory - Google Patents

Manufacturing method of flash memory Download PDF

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Publication number
TW200410402A
TW200410402A TW91135630A TW91135630A TW200410402A TW 200410402 A TW200410402 A TW 200410402A TW 91135630 A TW91135630 A TW 91135630A TW 91135630 A TW91135630 A TW 91135630A TW 200410402 A TW200410402 A TW 200410402A
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Taiwan
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layer
gate structure
substrate
conductor
flash memory
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TW91135630A
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Chinese (zh)
Inventor
Chih-Wei Hung
Cheng-Yuan Hsu
Da Song
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Powerchip Semiconductor Corp
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Priority to TW91135630A priority Critical patent/TW200410402A/en
Publication of TW200410402A publication Critical patent/TW200410402A/en

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Abstract

A manufacturing method of flash memory is provided. First, a substrate with a first gate structure and a second gate structure is provided, and the first gate structure and the second gate structure is consisted of a dielectric layer, a first conductive layer and a cap layer respectively. A tunneling oxide layer is formed on the substrate and a first spacer is formed on the sidewall of first conductive layer. A second conductive layer is formed on the source side of the first gate structure and the second gate structure and a source region is formed in the substrate. Then an inter gate dielectric layer is formed on the second conductive layer and a insulation layer is formed on the substrate surface of source region. A third conductive layer is formed between the first gate structure and the second gate structure, and a drain region is formed in the substrate.

Description

200410402 五、發明說明(1) 本發明是有關於一種半導體製 種快閃記憶體之製造方法。η且特別疋有關於一200410402 V. Description of the invention (1) The present invention relates to a method for manufacturing a semiconductor seed flash memory. η and in particular

先前#I 快閃記憶體元件由於具有可多次進行資料之户 j、=除等動作,且存入之資料在斷電後也不會=之: 揮發性記憶體元件。 ’、木用的一種非 典型的快閃記憶體元件係以摻雜的多晶 ,(Fl〇ating Gate)與控制閘極(c〇ntr〇i 。作子置閉 π置閘極與控制閘極之間以介電層相隔,而浮置其 底間以穿随氧化層(Tunnel 〇xide)相隔。當對快艮;二二 進行寫入/抹除(Write/Erase)資料之操作時,係_ 制閘極與源極/汲極區施加偏壓,以使電子注入s ;控 ^使電子從浮置閘極拉出。而在讀取快閃記憶體中的甲極The previous #I flash memory device has a user j, = division, and other operations that can perform data multiple times, and the stored data will not = after power off: Volatile memory device. 'A kind of atypical flash memory device for wood is doped polycrystalline, (FlOating Gate) and control gate (c0ntr〇i.) As a sub-position π gate and control gate The poles are separated by a dielectric layer, and the bottom is floated to be separated by a tunnel oxide layer. When performing fast write / erase data operations on the fast and the second, System _ Gate and source / drain regions are biased so that electrons are injected into the s; the electrons are pulled out of the floating gate. The forma of the flash memory is read

Hi控制閘極上施加一工作電壓’此時浮置閘極的帶 電狀態會影響其下通道(Channel)的開/關,而此通 /關即為判讀資料值「〇」或Γ i」之依據。 〈開 當快閃記憶體在進行資料之抹除時,係將基底、沒 (源)極區或控制閘極的相對電位提高,並利用穿隧效鹿 電子由浮置閘極穿過穿隧氧化層(Tunneling 〇xide)而4排 至基底或汲(源)極中(即Substrate Erase或Drain (Source) Side Erase),或是穿過介電層而排至控制閘極 中。然而’在抹除快閃記憶體中的資料時,由於從浮^間 m 10220twf.ptd 第7頁 200410402 五、發明說明(2) — - 極排出的電子數量不易控制’故易使浮置閘極排出過 子而帶有正電荷,謂之過度抹除(0ver_Erase)。备 抹除現象太過嚴重時,甚至會使浮置閘極下方之^道 = 制閘極未加工作電壓時即持續呈導通狀態,並導致^ : 誤判。因此丄為了解決元件過度抹除的問題,目前^界 出一種具有三層次閘極高密度的快閃記憶體。 ^ 請參照第1A圖至第1(:圖所緣示為習;一種快閃記憶體 之製造流程剖面圖。首先請參照第1A圖,提供一基底1 並於基底100上形成一層絕緣層(未圖示)與一層導&quot;體声 圖示)後,圖案化導體層與絕緣層以形成介電^102與曰 閘極104。然後,於基底100表面上形成穿隧氧化層並 在選擇閘極104上形成閘間介電層丨〇8。 請參照第1B圖,於基底1〇〇上形成材質為摻雜多晶矽 之導體層110,然後圖案化導體層11〇使其呈條狀分佈,且 導體層110之一部分位於選擇閘極104上方。接著,於導體 層u 〇上形成另一層閘間介電層丨丨2後,於閘間介電層丨工2 上形成另一層材質為摻雜多晶石夕之導體層114。 請參照第1 C圖,之後,圖案化導體層丨丨4、閘間介電 層112、導體層11〇與穿隧氧化層1〇6以形成控制閘極 114a、閘間介電層n2a、浮置閘極11〇&amp;與穿隧氧化層 l〇6a。其中,選擇閘極108、浮置閘極11〇&amp;、控制閘^極 11 4a構成快閃記憶體之閘極結構。然後,於閘極結構兩側 之基底100中形成源極區116與j:及極區118。 在上述之快閃記憶體之製造方法中,在形成控制閘極A working voltage is applied to the Hi control gate. At this time, the charged state of the floating gate will affect the opening / closing of its lower channel (Channel), and this on / off is the basis for judging the data value "0" or Γ i " . <When the flash memory is erasing data, the relative potential of the substrate, the (source) region, or the control gate is increased, and the tunneling effect is used to pass the floating gate through the tunneling tunnel. Oxidation layer (Tunneling Oxide) and 4 rows to the substrate or drain (source) side (ie, Substrate Erase or Drain (Source) Side Erase), or through the dielectric layer to the control gate. However, 'when erasing the data in the flash memory, it is easy to make the floating gate because the amount of electrons discharged from the pole is not easy to control because it is difficult to control from the floating m 10220twf.ptd page 7 200410402. The pole has a positive charge, which is called excessive erasure (0ver_Erase). If the erasing phenomenon is too serious, even the ^ track below the floating gate = the gate will continue to be in a conducting state when no working voltage is applied, and ^: misjudgment. Therefore, in order to solve the problem of excessive erasing of components, a flash memory with a high density of three levels of gates is currently being defined. ^ Please refer to FIGS. 1A to 1 (: the edges of the drawings are shown as Xi; a cross-sectional view of a flash memory manufacturing process. First, refer to FIG. 1A, provide a substrate 1 and form an insulating layer on the substrate 100 ( (Not shown) and a layer of "body acoustic diagram", the conductive layer and the insulating layer are patterned to form a dielectric layer 102 and a gate electrode 104. Then, a tunneling oxide layer is formed on the surface of the substrate 100 and an inter-gate dielectric layer is formed on the selection gate 104. Referring to FIG. 1B, a conductive layer 110 made of doped polycrystalline silicon is formed on the substrate 100, and then the conductive layer 110 is patterned so as to be distributed in a strip shape, and a part of the conductive layer 110 is located above the selection gate 104. Next, another inter-gate dielectric layer 丨 2 is formed on the conductor layer u 〇, and then another conductor layer 114 made of doped polycrystalline silicon is formed on the inter-gate dielectric layer 2. Please refer to FIG. 1C. After that, the patterned conductor layer 4, the inter-gate dielectric layer 112, the conductor layer 110, and the tunneling oxide layer 106 are formed to form the control gate 114a, the inter-gate dielectric layer n2a, Floating gate 11 &amp; and tunneling oxide layer 106a. Among them, the selection gate 108, the floating gate 110 and the control gate 11 4a constitute the gate structure of the flash memory. Then, source regions 116 and j: and a pole region 118 are formed in the substrate 100 on both sides of the gate structure. In the above flash memory manufacturing method, a control gate is formed

200410402 五、發明說明(3) 11 4 a之步驟中,由於浮置閘 罩對準之問題,因此造成浮 120a、120b無法正確的定義 11 〇a時若產生誤對準之狀況 之長度就會不相等,於是在 用源極區的兩記憶胞的通道 記憶胞程式化不對稱之問題 發日 有鐘於此,本發明之一 製造方法,利用自行對準的 $記憶胞的通道區長度不一 程式化不對稱之問題,並提 、 本發明之另一目的為提 法,利用自行對準的製程形 但可以避免兩記憶胞的通道 2加浮置閘極與控制閘極之 5率’並提升元件效能。 本發明提出一種快閃記 :列步驟:提供已形成有第 :底,且第一閘極結構與第 二二第一導體層與頂蓋層所 化層,並於第一導體層 —閑極結構與第二閘極結 ^成第二導體層。然後 極110a對於選擇閘極丨〇8有光 置閘極11 0 a下方之通道區 。亦即,在圖案化浮置閘極 ,則通道區120a與通道區12〇1) 操作此快閃記憶體時,因為共 區長度不一致,所以就會造成 ,導致5己憶胞彳呆作速度變慢。 目的為提供一種快閃記憶體之 製程形成浮置閘極,可以避免 致之問題,而可以防止記憶胞 高記憶胞效能。 供一種快閃記憶體之製造方 成「L」字形之浮置閘極,不 區長度不一致之問題,還可以 間所夾的面積,而提高閘極耦 憶體之製造方法,此方法包括 一閘極結構與第二閘極結構之 二閘極結構各自是由一介電 構成。接著,於基底上形成穿 之侧壁形成第一間隙壁後,於 構預疋形成源極區之^侧的侧 ’於基底中形成源極區,並於200410402 V. Description of the invention (3) In the step of 11 4 a, due to the problem of the alignment of the floating gates, the floating 120a and 120b cannot correctly define the length of the misalignment when 11 oa occurs. It is not equal, so the problem of asymmetry in the programming of the channel memory cells of the two memory cells in the source region arises. One manufacturing method of the present invention uses the self-aligned channel region length of the $ memory cells. A stylized asymmetry problem, and another object of the present invention is to mention the use of a self-aligned process shape but can avoid the channel 2 of the two memory cells plus the 5 rate of the floating gate and the control gate. And improve component performance. The invention proposes a flash memory: column step: providing a layer formed by a first gate structure, a second gate structure, a second conductor layer, and a cap layer, and a first conductor layer and a free pole structure. A second conductor layer is formed with the second gate electrode. Then, the electrode 110a has an optical channel for the selected gate, and the channel area below the gate 110a is set. That is, in the patterned floating gate, the channel area 120a and the channel area 1201) operate this flash memory because the length of the common area is inconsistent, so it will cause the 5th memory cell to stay idle. Slow down. The purpose is to provide a flash memory manufacturing process to form floating gates, which can avoid the problems caused, and can prevent the memory cells from having high memory cell performance. For the manufacture of flash memory with "L" shaped floating gate, it does not have the problem of inconsistent length. It can also sandwich the area to improve the manufacturing method of the gate coupling memory. This method includes a The gate structure and the two gate structures of the second gate structure are each composed of a dielectric. Next, after forming a first gap wall on a sidewall formed on the substrate, a side of the source side of the source region is formed in the structure ′ to form a source region in the substrate, and

200410402 五、發明說明(4) 成絕緣層。曰之:成:】介電層’並於源極區之基底表面形 氮化硬/氧:/閉極;間間介電層之材質為氧切/ 體材在形成第二導體層時,係依序於基底上來成m 接著二源極區之區域的圖案化光阻層 移除圖光阻層覆蓋之導體材料層。之後, 料展·、光阻層,並進行非等向性蝕刻製程移除導俨妊 ::::以體導層體。/广 通道區具有相同的二層)’ 可以使得相鄰記憶胞之 為共用源極區的兩記記:體時’因 i記憶胞程式化不對稱之_,心=記 本發明另外提出一種快閃、^ 係ϊ提供已形成有第-閘極結構之:Γ =第一閘極結構與第二閘極結構各自是由介電層、^二 導層體層所::壁:乂成:;氧化層一, 層導體二 固茶化九阻層覆盍預定形成源極區之 10220twf.ptd 第10頁 200410402 五、發明說明(5) 一 區域。然後,移除未被第—查 第一導體材料展銘Γ 案層覆盍之材料層與 :2體材科層後,移除第一圖案化光阻層。接 ^性蝕刻製程移除部分材料層與第-導體材料層,: 壁與第二導體層後,移除第 」層以 源極區之基底表ί形=㈣= ㈣構之間形成第三導體層,並於L: -導二:孫::!體層係作為快閃記憶體之選擇閘極;第 為”記憶體之控制閘極;:=作 氮化矽/氧化矽。 日 &lt; 利*馮虱化矽/ 體材2明成第二導體層時’係依序於基底上形成導 層。接著’移除未被圖案化光阻層 ;:」導字體形層由然後移除第二間隙壁後心 相同的長度於2在::ϊ相鄰記憶胞之通道區具有 區的兩記憶胞的通道區長度相=:己:’因為共用源極 匕問題,而可以匕:::;声免記:r …極(第二導體層)係形成%字形,λ度增加而浮且置 _ l〇220twf.ptd 第11頁 200410402 五、發明說明(6) 2極(Λ 二一導體層)與控制間極(第三導體層)之間所夹的面 積,而棱咼閘極耦合率,並提升元件效能。 =讓本發明之上述和其他目@、特徵、和優點能更明 顯易Μ,下文特舉一較佳實施例,並配合 細說明如下: UI ^ 斤 實施方式 第2 A圖至第2 F圖所繪示為本發明較佳實施例之一種分 離閘極快閃記憶體之製造剖面流程圖。 a首先,請參照第2A圖,提供一基底200,基底200例如 是P型矽基底,在此基底200中已形成有深N型井區2〇2盥位 於深N井區202上之P型井區204。接著,在基底2〇〇上依序 形成一層介電層206、一層導體層2〇8與一層頂蓋層210。 介電層2 0 6之形成方法例如是熱氧化法,其厚度例如是g 〇 埃至1 0 0埃左右。導體層2 〇 8之材質例如是掺雜的多晶矽, 此導體層208之形成方法例如是利用化學氣相沈積法形成 一層未摻雜多晶矽層後,進行離子植入步驟以形成之。頂 蓋層2 1 0之材質例如是氮化石夕,且其厚度例如是1 〇 〇 〇埃至 2 0 0 0埃左右,頂蓋層2 1 0之形成方法例如是低壓化學氣相 沈積法。當然’頂蓋層210之材質也可以是以四—乙基—鄰一 矽酸醋(Tetra Ethyl Ortho Silicate,TEOS)/ 臭氧(〇3)為 反應氣體源利用化學氣相沈積法所形成之氧化石夕等。 、 接著’請參照第2B圖,圖案化頂蓋廣210、導體層2〇8 與介電層206以形成頂蓋層210a、導體層208a與介電層 20 6a。其中,頂蓋層210a、導體層20 8a與介電層206a構成200410402 V. Description of the invention (4) Insulation layer. Said: Cheng:] The dielectric layer is formed on the substrate surface of the source region and nitrided hard / oxygen: / closed electrode; the material of the interlayer dielectric layer is oxygen cut / body material when forming the second conductor layer, The patterned photoresist layer on the substrate is sequentially formed into an area of m followed by the two source regions to remove the conductive material layer covered by the photoresist layer. After that, the material exhibition, photoresist layer, and an anisotropic etching process are performed to remove the lead :::: to guide the layer. / Wide channel area has the same two layers) 'can make adjacent memory cells are two records of the shared source area: body time' because of the asymmetry of the i memory cell stylization, heart = record The flash, ^ system provides the first gate structure that has been formed: Γ = the first gate structure and the second gate structure are each composed of a dielectric layer and a ^ second conducting layer :: wall: 乂 成: An oxide layer, a layer of conductors, a two-layer solidification, and a nine-resistance layer are overlaid to form a source region of 10220twf.ptd Page 10 200410402 V. Description of the invention (5) A region. Then, the first patterned photoresist layer is removed after removing the material layer and the: 2 body material layer that are not covered by the first-conductor material exhibition layer. A part of the material layer and the first-conductor material layer are removed by the adhesive etching process: After the wall and the second conductor layer, the third layer is removed to form a third layer between the base surface of the source region and the third-layer structure. Conductor layer and L: -Guide 2: Sun ::! The body layer is used as the selection gate of the flash memory; the first is the “control gate of the memory”: = for silicon nitride / silicon oxide. <Li * Feng lice silicon / body 2 when it becomes the second conductive layer ' A conductive layer is sequentially formed on the substrate. Then, 'remove the unpatterned photoresist layer ;:' ”The shape of the conductive font layer is then removed after the second spacer is the same length at 2 in :: ϊ Adjacent memory The length of the channel area of the two memory cells in the channel region of the cell is equal to :::: Because of the problem of sharing the source electrode, it can be used :::; Glyph, λ degree increases and floats_ l〇220twf.ptd Page 11 200410402 V. Description of the invention (6) The pinch between the 2 pole (Λ 21 conductor layer) and the control pole (third conductor layer) Area, and the edge gate coupling rate, and improve the component performance. = To make the above and other objects, features, and advantages of the present invention more obvious and easy to implement, a preferred embodiment is given below, and the detailed description is as follows: UI ^ Figure 2A to 2F The drawing is a cross-sectional flow chart of manufacturing a split gate flash memory according to a preferred embodiment of the present invention. a First, referring to FIG. 2A, a substrate 200 is provided. The substrate 200 is, for example, a P-type silicon substrate, and a deep N-type well area 202 has been formed in the substrate 200. A P-type is located on the deep N-well area 202. Well area 204. Next, a dielectric layer 206, a conductor layer 208, and a cap layer 210 are sequentially formed on the substrate 200. The method for forming the dielectric layer 206 is, for example, a thermal oxidation method, and its thickness is, for example, about g0 to 100 angstroms. The material of the conductive layer 208 is, for example, doped polycrystalline silicon. The method for forming the conductive layer 208 is, for example, forming an undoped polycrystalline silicon layer by chemical vapor deposition, and then performing an ion implantation step to form it. The material of the capping layer 2 10 is, for example, nitride stone, and its thickness is, for example, about 1000 angstroms to 2000 angstroms. The method for forming the capping layer 2 10 is, for example, a low-pressure chemical vapor deposition method. Of course, the material of the top cover layer 210 can also be formed by using chemical vapor deposition method using tetra-ethyl-o-mono-silicic acid (Tetra Ethyl Ortho Silicate (TEOS) / ozone (〇3)) as a reaction gas source. Shi Xi et al. Next, please refer to FIG. 2B, patterning the top cap 210, the conductive layer 208, and the dielectric layer 206 to form the top cap layer 210a, the conductive layer 208a, and the dielectric layer 20 6a. Among them, the capping layer 210a, the conductive layer 208a, and the dielectric layer 206a

10220twf.ptd 第12頁 200410402 五、發明綱⑺ &quot; --— 開極結構’且導體層208a係作為快閃記憶體之選擇閘極。 然後於基底200上形成一層穿隧氧化層212並於導體心 之側壁形成間隙壁2i4,穿隨氧化層212與間隙壁214之形 成方法例如是熱氧化法。 接著,言青參照第2C圖,於基底2〇〇上形成另 =6,此導體層216之材質例如是摻雜的多晶石夕,此導體 :216之形成方法例如是利用化學氣相沈積法形成一層未 推雜多晶矽層後,進行離子植入步 導體層216上形成一層圖幸化#阳風91β 9回茶化光阻層21 8,此圖案化光阻層 2」8覆盍預疋=成源極區之區域。然後,移除未被圖案化 :阻層2 1 8覆盍之導體層2! 6。移除部分導體層2】6之方法 包括濕式银刻法或乾式餘刻法。 —接著,明參照第2D圖,移除圖案化光阻層21 8後,進 灯一非等向性蝕刻步驟,而於頂蓋層21〇a、導體層2〇心之 :侧的侧壁上形成導體層2丨6a(間隙壁)。導體層2丨仏即作 為快閃記憶體之浮置閘極。然後於基底2〇〇上形成另一層 ®案^光阻層m ’此圖案化光阻層220暴露預定形成源極 之區域。接著,以圖案化光阻層22〇為罩幕,進行摻質植 ,製程222 ’已於相鄰兩導體層2“a之間植入摻質而形成 =極區224。植入之摻質包括N型摻質,其例如是磷離子或 砷離子。 接著明參照第2 E圖,移除圖案化光阻層2 2 〇後,於 導體層216a上形成閘間介電層226,並於源極區224之表面 形成絕緣層228 1間介電層226之材質例如是^化^氮10220twf.ptd Page 12 200410402 V. Outline of Invention &quot; --- Open-Pole Structure 'and the conductor layer 208a is used as the gate of choice for flash memory. Then, a tunneling oxide layer 212 is formed on the substrate 200 and a spacer 2i4 is formed on the side wall of the conductor core. The method for forming the through oxide layer 212 and the spacer 214 is, for example, a thermal oxidation method. Next, referring to FIG. 2C, Yan Qing formed another = 6 on the substrate 200. The material of the conductor layer 216 is, for example, doped polycrystalline stone. The method for forming the conductor: 216 is, for example, chemical vapor deposition After forming an undoped polycrystalline silicon layer, an ion implantation step is performed on the conductor layer 216 to form a layer of photochemical #yangfeng 91β 9 back to tea photoresist layer 21 8, this patterned photoresist layer 2 ″ 8 overlay疋 = area of the source region. Then, remove the unpatterned conductive layer 2 1 8 overlying the resist layer 2 1 8. Methods for removing a part of the conductor layer 2] 6 include a wet silver engraving method or a dry etch-off method. — Next, referring to Figure 2D, after removing the patterned photoresist layer 218, a non-isotropic etching step is performed, and the side walls of the top cover layer 21a and the conductor layer 20 center: A conductor layer 2 6a (spacer wall) is formed thereon. The conductive layer 2 is used as a floating gate of the flash memory. Then, another layer ® photoresist layer m 'is formed on the substrate 200. The patterned photoresist layer 220 exposes a region where a source is to be formed. Next, dopant implantation is performed using the patterned photoresist layer 22 as a mask. A process 222 'has implanted dopants between two adjacent conductor layers 2 "a to form a pole region 224. The implanted dopants It includes an N-type dopant, which is, for example, a phosphorus ion or an arsenic ion. Next, referring to FIG. 2E, after removing the patterned photoresist layer 220, an inter-gate dielectric layer 226 is formed on the conductor layer 216a, and An insulating layer 228 is formed on the surface of the source region 224. The material of the dielectric layer 226 is, for example, nitrogen.

第13頁 200410402 五、發明說明(8) 化矽/氧化矽層, — 間介電層226形成;法= 埃/6。埃左右。閘 矽J,再利用化學氣相沈積法;乳化法形成-層氧化 。絕緣層228之材質例如是氧成:化,另-層 成方法例如是熱氧化法。豆 疋虱化矽,絕緣層228形 226係在同一個步驟中/、,絕緣層228與閘間介電層 一層導體層230,此導體戶23。之然^麦,於基底200上形成另 石夕,此導體層230之开之材質例如是摻雜的多晶 形成-層未摻雜多晶?二 之。然後,於導體層230上形成一丁/子植入步驟以形成 圖案化光阻層232係成條狀分佈,;’此 =控制閉極。然後,移除未被圖案化光阻層2=== 式:2:去移r除部分導體層230之方法包括濕式银刻法或乾 式蝕4法。烴圖案化之導體層23〇 - 制閘極。 1 π芍厌閃圯憶體之控 /一接著,請參照第2F圖,移除圖案化光阻層232後,進 仃一離子植入步驟,而於導體層2〇8a 一側之基 淡摻雜區234。然後,於導體層230之侧壁形成間隙壁$ = 並於頂蓋層210a、導體層208a與介電層206a之側辟形成門 隙壁238。間隙壁236與間隙壁238之形成方法例如1先於曰 基底2 0 〇上形成一層絕緣層(未圖示)後,利用非等向性敍 刻法移除部分絕緣層以形成之。之後,進行另一離子植入 步驟,而於間隙壁238 —侧之基底2 00形成濃摻雜區24〇。 其中’淡推雜區2 3 4與濃接雜區2 4 0構成快閃記^體之彡及極 10220twf.ptd 第14頁 200410402 五、發明說明(9) 區2 4 2。後續完成快閃記憶體之製程為熟悉此項技術者 週知,在此不再贅述。 在上述實施例中’本發明係採用自對準之方式形成浮 置閘極(導體層2 1 6 a)’而可以使得相鄰記憶胞之通道區具 有相同的長度,於是在操作此快閃記憶體時,因為共用^ 極區的兩記憶胞的通道區長度相同,所以可以避免&amp;憶^ 程式化不對稱之問題,而可以提升記憶體之可靠度。 匕 第3 A圖至第3D圖所繪示為本發明較斧實施例之一種分 離閘極快閃記憶體之製造剖面流程圖。1 77 首先,請參照第3A圖,提供一基底3〇〇,基底3〇〇例如 疋P型矽基底,在此基底300中已形成有深N型井區3〇2盥位 於深N井區302上之P型井區304。然後,根據㈣圖至第2β 圖之製程,依序於此基底30 0上形成介電層3〇6、導體層 、頂蓋層310、穿隧氧化層312與間隙壁314。其中,頂 ί二3U體層308與介電層306構成閘極結構,且導體 ΓΓΛ/ 憶體之選擇閘極。接著,於基底300上 多體層316,此導體層216之材質例如是摻雜的 積:形成方法例如是利用化學氣相沈 成之。妙德曰未摻雜夕晶矽層後,進行離子植入步驟以形 成之然後,於導體層316上形成一声材料厗qi7 . 層317之材質例如县氣各坊巾成層材科層317,此材枓 是化與Λ i日分 亂化夕。此材料層31 7之形成方法例如 化砂,&gt; π 田然此材料層31 7之材質並不限於氮 =選;::以:;是=體細、頂蓋侧具有不同 …、後於材料層317上形成一層圖案化光 200410402 五、發明說明(10) =層3二,此圖案化光阻層318覆蓋預定形成源極區之區 材料声Vl 7’。移被\圖案化光阻層318覆蓋之導體層316與 渴式二m二部分導體層316與材料層317之方法包括 …、式敍刻法或乾式餘刻法。 行-:ΐί向圖而:除圖案化光阻層318後,進 中,導妒…Λ 3 隙壁)與間隙壁317a。其 為快閃記憶體之浮置閘極。然後於基底开層3:;即:乍 圖案化光阻層320,此圖案化光阻 n 形成另一層 之區域。接著,以圖索## @ θ 20暴路預定形成源極 入製_ Λ 二 源極區324。植入之摻質包括 =入摻質而形成 砷離子。 土修買,其例如是磷離子或 接著,請參照第3C圖,移除R安^ , 除間隙壁31 7a。間隙壁31 7a之J ==層32〇後,移 法。接著,於導體層316a上形成f:如是濕式蝕刻 極區324之表面形成絕緣層328 =二:層咖’並於源 如是氧化矽/氮化矽/氧化# #二b &quot;電層326之材質例 ,埃左右。罐電 成是7〇埃:7◦埃 形成一層氧化矽後,再利用化風&gt; *疋先以熱氧化法 石夕層與另一層氧化石夕層。絕緣二:相2尤積法依序形成氮化 石夕,絕緣層328形成方法例如是 ^質例如是氧化 328與閘間介電層326係 …乳化法。其中,絕緣層 门個步驟中形成的。 10220twf.ptd 200410402 五、發明說明(11) 然後,於基底300上形成另一層導體層33〇,此 33 0填滿兩導體層31 6a之間的間隙。導 q 是摻雜的多晶石夕,此導體層33G之形°之材質例如 化學氣相沈積法於基底30。上形成!如是先利用 ^ 層掺雜多曰石々厗尨 利用化學機械研磨法或回蝕刻法移除部分摻雜 ^ , 直到至少暴露出頂蓋層3 1 〇之表面。然,θ:曰’ 成-層圖案化光阻層(未圖示),此圖宰’阻土 &amp; 00 ^ 分佈,用以定義出快閃記憶體之控光阻層係成條狀 化光阻層覆蓋之摻雜多晶石夕層後控移除未被圖案 形成導體層330。導體層330即作為快二:$光阻層即可 極。 |邗4快閃記憶體之控制閘 接著,請參照第3D圖,進行一齙2 Μ 體層308 —側(預定汲極之那一侧) 入步驟,而於導 332。然後’於頂蓋層310、導體岸3二=〇形成淡摻雜區 形成間隙壁334。㈣壁334之形與介電層繼之侧壁 3。〇上形成-層絕緣層(未圖示成方利 移除部分絕緣層以形成之。之後,_專向性姓刻法 驟,而於間隙壁334 —侧(預定、及搞仃另一離子植入步 成濃摻雜區336。其中’淡摻雜區卩;'侧)之基底300形 快閃記憶體之汲極區338。後^ .也、/農換雜區336構成 熟悉此項技術者所週知,在此閃記憶體之製程為 在上述實施例中,本發明係 ώ 置閘極(導體層316a),而可以使對準之方式形成浮 有相同的長度,於是在操相鄰記憶胞之通道區具 探作此快閃記憶體時,因為共用源Page 13 200410402 V. Description of the invention (8) Siliconized silicon oxide / silicon oxide layer, the inter-dielectric layer 226 is formed; method = Angstrom / 6. Ah or so. Gate silicon J, and then use chemical vapor deposition; emulsification-layer oxidation. The material of the insulating layer 228 is, for example, oxygen, and the method of forming another layer is, for example, thermal oxidation. Bean lice silicon, the insulating layer 228 is 226 in the same step. The insulating layer 228 and the inter-gate dielectric layer have a conductive layer 230, which is the conductor 23. Of course, wheat is formed on the substrate 200. The material of the conductive layer 230 is, for example, a doped polycrystalline layer-doped polycrystalline layer? Two of them. Then, a step / sub-implantation step is formed on the conductor layer 230 to form a patterned photoresist layer 232 which is distributed in a stripe shape; ‘this = controllable closed electrode. Then, removing the unpatterned photoresist layer 2 === Formula: 2: The method of removing r to remove part of the conductor layer 230 includes a wet silver engraving method or a dry etching method. Hydrocarbon-patterned conductor layer 23-gates. 1 π 芍 Control of anaerobic flash memory / Next, please refer to Figure 2F. After removing the patterned photoresist layer 232, proceed to an ion implantation step, and the substrate on the side of the conductive layer 208a is light. Doped region 234. Then, a gap wall $ = is formed on the sidewall of the conductive layer 230, and a gate gap wall 238 is formed on the side of the top cover layer 210a, the conductive layer 208a, and the dielectric layer 206a. The method for forming the partition wall 236 and the partition wall 238 is, for example, 1 after forming an insulating layer (not shown) on the substrate 200, and then removing a part of the insulating layer by anisotropic engraving to form it. After that, another ion implantation step is performed, and a heavily doped region 24 is formed on the substrate 200 on the side of the spacer 238. Among them, the lightly doped region 2 3 4 and the densely doped region 2 4 0 constitute the shortest part of the flash memory. 10220twf.ptd Page 14 200410402 V. Description of the invention (9) Area 2 4 2. The subsequent completion of the flash memory manufacturing process is well known to those skilled in the art and will not be repeated here. In the above embodiment, the present invention uses a self-aligning method to form a floating gate electrode (conductor layer 2 1 6 a) 'so that the channel regions of adjacent memory cells have the same length. In the case of memory, since the channel region length of two memory cells sharing the ^ polar region is the same, the problem of & memory ^ stylized asymmetry can be avoided, and the reliability of the memory can be improved. FIG. 3A to FIG. 3D are cross-sectional flowcharts of the manufacture of a split-gate flash memory according to an embodiment of the present invention. 1 77 First, referring to FIG. 3A, a substrate 300 is provided. The substrate 300 is, for example, a P-type silicon substrate. In this substrate 300, a deep N-type well area 300 has been formed. P-well area 304 on 302. Then, according to the process from the ㈣ diagram to the 2β diagram, a dielectric layer 306, a conductor layer, a capping layer 310, a tunneling oxide layer 312, and a spacer 314 are sequentially formed on the substrate 300. Among them, the top 3U body layer 308 and the dielectric layer 306 form a gate structure, and the conductor ΓΓΛ / memory body selects the gate. Next, a multi-layer layer 316 is formed on the substrate 300, and the material of the conductive layer 216 is, for example, a doped product: the formation method is, for example, chemical vapor deposition. Miao De said that after the undoped crystalline silicon layer, an ion implantation step is performed to form it. Then, an acoustic material 厗 qi7 is formed on the conductor layer 316. The material of the layer 317 is, for example, the county-level gas-towel layer 317.枓 枓 枓 化 Λ Λ Λ 日 日 日 分 分 分 夕 夕 夕 夕 夕. The method of forming this material layer 31 7 is, for example, sand removal. &Gt; Tian Ran The material of this material layer 31 7 is not limited to nitrogen = select; :::: yes = thin, with different cover side ..., after A layer of patterned light 200410402 is formed on the material layer 317. 5. Description of the invention (10) = layer 32. This patterned photoresist layer 318 covers the material sound Vl 7 'of the region where the source region is to be formed. The method of moving the conductive layer 316 and the two-part two-layer conductive layer 316 and the material layer 317 covered by the \ patterned photoresist layer 318 includes a lithography method or a dry-rewind method. Line-: ΐ 向 Directional diagram: After removing the patterned photoresist layer 318, proceed to enlighten ... Λ 3 gap wall) and the gap wall 317a. It is the floating gate of flash memory. Then, a layer is opened on the substrate 3: that is, the photoresist layer 320 is patterned, and the patterned photoresist n forms a region of another layer. Next, the source line _ Λ 2 source region 324 is scheduled to be formed by the map ## @ θ 20. The implanted dopants include: dopants are formed to form arsenic ions. For soil repair, it is, for example, phosphorus ions. Then, referring to FIG. 3C, remove R, and remove the partition wall 31 7a. After J == layer 32 of the partition wall 31 7a, the method is shifted. Next, an insulating layer 328 is formed on the surface of the conductor layer 316a if the wet-etched electrode region 324 is formed. The second layer is a silicon oxide / silicon nitride / oxidation source. # 二 b &quot; 电 层 326 An example of the material is Angstrom. The tank formation is 70 Angstroms: 7 ◦ Angstroms. After forming a layer of silicon oxide, the wind is used.> First, the thermal oxidation method is applied to the Shixi layer and another layer of oxidized stone. Insulation two: Phase 2 and special product method sequentially form nitride nitride, and the method for forming insulating layer 328 is, for example, oxidizing 328 and inter-gate dielectric layer 326 series ... emulsification method. Among them, the insulating layer is formed in one step. 10220twf.ptd 200410402 V. Description of the invention (11) Then, another conductive layer 33o is formed on the substrate 300, and this 330 fills the gap between the two conductive layers 31 6a. The conductance q is doped polycrystalline silicon. The material of the shape of the conductor layer 33G is, for example, chemical vapor deposition on the substrate 30. On formation! If it is first doped with ^ layer, it is used to remove part of the dopant ^ by chemical mechanical polishing method or etch-back method until at least the surface of the cap layer 3 1 0 is exposed. However, θ: said 'layer-layered patterned photoresist layer (not shown), this figure represents the' blocking soil &amp; 00 ^ distribution, which is used to define the photoresist control layer of the flash memory in a stripe pattern. The doped polycrystalline silicon layer covered by the photoresist layer is controlled to be removed without patterning the conductive layer 330. The conductive layer 330 is used as the second fast photoresistor layer. | 邗 4 Flash memory control gate Next, referring to Figure 3D, perform a 龅 2 Μ body layer 308-side (the side where the drain is scheduled) and guide 332. Then, a lightly doped region is formed on the cap layer 310 and the conductor bank 32 = 0, and a spacer 334 is formed. The shape of the wall 334 and the dielectric layer followed by the side wall 3. 〇-layer insulation layer (not shown in the figure to remove part of the insulation layer to form it. After that, the _ specific orientation lasting method, and on the side of the partition wall 334 (scheduled, and engage another ion The implantation step becomes a heavily doped region 336. The 'lightly doped region (卩)' side) of the substrate 300 is shaped as a drain region 338 of the flash memory. The rear region ^. Also, the agricultural replacement region 336 constitutes a familiar item. As known to the skilled person, the process of flash memory is that in the above embodiment, the present invention is a gate electrode (conductor layer 316a), and the alignment method can be formed to have the same length. The channel area of the adjacent memory cells is used for this flash memory because the shared source

200410402 五、發明說明(12) H的胞的通道區長度㈣,所以可以避免記憶胞 工 不對稱之問題,而可以提升記憶體之可靠声。 而且,浮置閘極(導體層316a)係形成「[ X。 二增力σ洋置閉極(導體層316a)與控“ ’二 間所夾的面積,而提高閘㈣合率,並提^體/330)之 雖然本發明已以一較佳實施例揭露 以限疋本發明,任何熟習此技藝者, =其並非用 神和範圍π,當可作各種之更動不:離本發明之精 護範圍當視後附之中請專利範圍所界者=本發明之保 10220twf.ptd 第18頁 200410402 圖式簡單說明 圖式簡單說明: 第1 A圖至第1 C圖為繪示一種習知快閃記憶體之製造流 程剖面結構圖。 第2 A圖至第2F圖為繪示本發明較佳實施例之快閃記憶 體之製造剖面流程圖。 第3 A圖至第3D圖為繪示本發明另一較佳實施例之快閃 記憶體之製造剖面流程圖。 圖式標示說明: 100、20 0、30 0 :基底 102、20 6、30 6 :介電層 104 :選擇閘極 106、312 :穿隧氧化層 108、112、112a、226、326 :閘間介電層 110 、 114 、 208 、 208a 、 216 、 216a 、 230 、308 、 316、316a、330 ··導體層 114a :控制閘極 11 0 a :浮置閘極 116、224、324 :源極區 118、240、338 :汲極區 120a、120b :通道區 202、302 :深N型井區 204 、 304 : P型井區 210、210a、310 :頂蓋層 214、23 6、238、314、317a、334 :間隙壁200410402 V. Description of the invention (12) The length of the channel region of H's cell is ㈣, so it can avoid the problem of asymmetry of the memory cell, and can improve the sound of the memory. In addition, the floating gate electrode (conductor layer 316a) is formed as "[X. The area between the two energized σ-sea closed poles (conductor layer 316a) and the control" ', which increases the gate coupling rate and improves ^ 体 / 330) Although the present invention has been disclosed in a preferred embodiment to limit the present invention, anyone skilled in the art is not using God and the range π, and can make various changes: The scope of intensive protection is subject to the scope of the patent, please be bound by the scope of the patent = the guarantee of the present invention 10220twf.ptd page 18 200410402 Simple illustration of the diagram Simple illustration of the diagram: Figure 1A to 1C Know the cross-sectional structure diagram of the flash memory manufacturing process. FIG. 2A to FIG. 2F are cross-sectional flowcharts of manufacturing a flash memory according to a preferred embodiment of the present invention. FIG. 3A to FIG. 3D are cross-sectional flowcharts of manufacturing a flash memory according to another preferred embodiment of the present invention. Graphical description: 100, 200, 30 0: substrate 102, 20 6, 30 6: dielectric layer 104: selection gate 106, 312: tunneling oxide layer 108, 112, 112a, 226, 326: gate Dielectric layers 110, 114, 208, 208a, 216, 216a, 230, 308, 316, 316a, 330Conductor layer 114a: Control gate 11 0a: Floating gate 116, 224, 324: Source region 118, 240, 338: Drain region 120a, 120b: Channel region 202, 302: Deep N-type well region 204, 304: P-type well region 210, 210a, 310: Cap layer 214, 23 6, 238, 314, 317a, 334: partition wall

10220twf.ptd 第19頁 200410402 圖式簡單說明 218、220、232、318、320 :圖案化光阻層 222、322 :摻質植入製程 2 2 8、3 2 8 :絕緣層 234、332 :淡摻雜區 240、336 :濃摻雜區 3 1 7 :材料層 11H· 10220twf.ptd 第20頁10220twf.ptd Page 19 200410402 Schematic description 218, 220, 232, 318, 320: Patterned photoresist layer 222, 322: Doped implant process 2 2 8, 3 2 8: Insulating layers 234, 332: Light Doped regions 240, 336: heavily doped regions 3 1 7: material layer 11H · 10220twf.ptd page 20

Claims (1)

200410402 六、申請專利範圍 ------- 1 · 一種快閃記憶體之製造方法,該方法包括下 驟: 提供一基底,該基底上已形成有—第一閘極結構與一 第二閘極結構,該第一閘極結構與該第二閘極結構各自是 由一介電層、一第一導體層與〆頂蓋層所構成; 於該基底上形成一穿隧氧化層,並於該第一導體層之 側壁形成一第一間隙壁; 於該第一閘極結構與該第二閘極結構預定形成一源極 區之一側的側壁上形成一第二導體層; 於該基底中形成該源極區; 於該第二導體層上形成一閘間介電層,並於該源極區 之該基底表面形成一絕緣層; 於該第一閘極結構與該第二閘極結構之間形成一第三 導體層;以及 一 於該基底中形成該汲極區。 2·如申請專利範圍第1項所述之快閃記憶體之製造方 法,其中該第一導體層係作為/選擇閘極。 3·如申請專利範圍第1項所述之快閃記憶體之製造方 法,其中該第二導體層係作為,浮置閘極。 4·如申請專利範圍第1項所述之快閃記憶體之製4 法,其中該第三導體層係作為,控制閘極。 每 5·如申請專利範圍第丨項所述之快閃記憶體之製造方 法,其中該閘間介電層之材質包括氧化矽/氮化矽/氧^化200410402 VI. Scope of Patent Application ------- 1 · A method for manufacturing flash memory, the method includes the following steps: a substrate is provided, and a first gate structure and a second A gate structure, the first gate structure and the second gate structure are each composed of a dielectric layer, a first conductor layer, and a capping layer; a tunneling oxide layer is formed on the substrate, and Forming a first gap wall on a side wall of the first conductor layer; forming a second conductor layer on a side wall on one side of the first gate structure and the second gate structure that is intended to form a source region; The source region is formed in the substrate; an inter-gate dielectric layer is formed on the second conductor layer, and an insulating layer is formed on the surface of the substrate in the source region; the first gate structure and the second gate are formed. A third conductor layer is formed between the electrode structures; and a drain region is formed in the substrate. 2. The method of manufacturing a flash memory as described in item 1 of the scope of patent application, wherein the first conductor layer is used as / selected a gate electrode. 3. The method of manufacturing a flash memory as described in item 1 of the scope of the patent application, wherein the second conductor layer is used as a floating gate. 4. The flash memory manufacturing method 4 described in item 1 of the scope of the patent application, wherein the third conductor layer is used to control the gate. Every 5 · The method for manufacturing a flash memory as described in item 丨 of the patent application scope, wherein the material of the inter-gate dielectric layer includes silicon oxide / silicon nitride / oxide 200410402 六、申請專利範圍 6·如申請 法,其中於該 源極區之一侧 於該基底 於該第一 第一圖案化光 移除未被 層; 移 進 成該第 7. 法,其 第三導 於 於 第二圖 移 層;以 移 8. 法,其 第三導 一第二 除該第 行非等 二導體 如申請 中於該 體層之 該基底 該第二 案化光 除未被 及 除該第 如申請 中於該 體層之 間隙壁 專利範圍第1項所述之快閃記憶體之製造方 第一閘極結構與該第二閘極結構預定形成該 的侧壁上形成該第二導體層之步驟包括:μ 上形成一第一導體材料層; 導體材料層上形成一第一圖案化光阻層,該 阻層覆蓋預定形成該源極區之區域; 該第一圖案化光阻層覆蓋之該第一導體材料 一圖案化光阻層;以及 向性蝕刻製程移除該第一導體材料層,以形 層。 y f利範圍第1項所述之快閃記憶體之製造方 Ϊ 一閘極結構與該第二閘極結構之間形成該 步驟包括: ^ ^ 上形成一第二導體材料層; 導體材料層上形成一莖_ ^ # ^ ^ , 弟一圖案化光阻層,該 ^層覆盍預疋形成該源極區之區域; 呑亥第一圖案化光阻声霜芸七》#〆 印覆盍之该第二導體材料 二圖案化光阻層。 ^利範目第7項所述之快閃記㈣之製造方 第一閘極結構與該笛_ 己^體之裟仏方 步驟t Θ k 第一閘極結構之間形成該 步驛之後更包括於 一 、茨第二導體層之侧壁形成200410402 6. Scope of patent application 6. As the application method, in which one side of the source region faces the substrate and the first first patterned light is removed from the unlayer; moved into the seventh method, whose first The third lead is to move the layer in the second picture; using the method of shift 8. Its third lead, the second, and the second row of non-equal two conductors, such as the application on the base of the body layer, the second case, the light has not been removed, and Except for the first gate structure and the second gate structure of the flash memory, as described in item 1 of the bulkhead patent scope of the bulk layer in the application, the second gate structure is intended to form the second side wall. The step of the conductive layer includes: forming a first conductive material layer on the μ; forming a first patterned photoresist layer on the conductive material layer, the resist layer covering an area intended to form the source region; the first patterned photoresist A patterned photoresist layer covered by the first conductive material; and removing the first conductive material layer by an etch process to form a layer. The manufacturing method of the flash memory described in item 1 of the yf range: forming a gate structure between the second gate structure and the second gate structure includes: forming a second conductor material layer on the conductor material layer; Forming a stem _ ^ # ^ ^, Di Yi patterned photoresist layer, the ^ layer is covered with pre-formed areas to form the source region; 呑 first patterned photoresistive acoustic frost Yunqi "# 〆 印 载 盍The second conductive material includes two patterned photoresist layers. ^ The first gate structure of the manufacturer of the flash memory described in item 7 of the Li Fanmu and the flute _ body ^ body of the step t Θ k is formed between the first gate structure and the step is further included in 1. Formation of the side wall of the second conductor layer l〇220twf.ptd 第22頁 200410402 申請專利範圍 ____ 半Λ ΐ申請專利範圍第1項所述之快閃記憶體之製造方 第三導體驟=、结構與該第二閘極結構之間形成該 於該基底上形成一第三導體材料層; 移除部分該第三導 於兮其&amp; μ W :導體材科層,直到暴露該頂蓋層; 於σ亥基底上ί[^成^一签二阁安/丨丨 ^ 1¾ ^ ^ ^ a.第一圖案化光阻層,該第三圖案化 光阻層覆盍預定形成該源極區之區域; 移除未被該第三圖案化光阻層覆蓋之該第三導體材料 層,以及 移除該第三圖案化光阻層。 、1〇.如申請專利範圍第1項所述之快閃記憶體之製造方 法’其中於該基底中形成該汲極區之步驟包括: 於該基底中形成一淡推雜區; 於該第一閘極結構與該第二閘極結構預定形成該汲極 區之一侧的侧壁上形成一第三間隙壁;以及 於該基底中形成一濃摻雜區。 11. 一種快閃記憶體之製造方法,該方法包括下列步 驟: 提供一基底,該基底上已形成有一第一閘極結構愈一 第二閘極結構,該第一閘極結構與該第二閘極結構自' θ 由一介電層、一第一導體層與一頂蓋層所構成; 疋 於該基底上形成一穿隧氧化層,並於該第i導體声 侧壁形成一第一間隙壁; 9之 於該基底上形成一第一導體材料層;l〇220twf.ptd Page 22 200410402 Scope of patent application ____ Half Λ ΐ The manufacturer of the flash memory described in item 1 of the patent scope, the third conductor step, the structure and the second gate structure are formed A third conductive material layer is formed on the substrate; a part of the third conductive material is removed; &amp; μ W: a conductive material layer until the capping layer is exposed; One sign of two cabinets / 丨 丨 ^ 1¾ ^ ^ ^ a. A first patterned photoresist layer, and the third patterned photoresist layer covers an area that is intended to form the source region; remove the third pattern The third conductive material layer covered by the photoresist layer, and removing the third patterned photoresist layer. 10. The method for manufacturing a flash memory as described in item 1 of the scope of the patent application, wherein the step of forming the drain region in the substrate includes: forming a lightly doped region in the substrate; A gate structure and the second gate structure are intended to form a third gap wall on a sidewall of one side of the drain region; and a heavily doped region is formed in the substrate. 11. A method for manufacturing a flash memory, the method comprising the steps of: providing a substrate on which a first gate structure and a second gate structure have been formed; the first gate structure and the second gate structure; The gate structure since 'θ is composed of a dielectric layer, a first conductor layer, and a cap layer; 疋 forming a tunneling oxide layer on the substrate, and forming a first on the acoustic side wall of the i-th conductor A spacer; 9 forming a first conductive material layer on the substrate; 200410402 六、申請專利範圍 於該第一導體材料層上形成一材料層; 於該材料層上形成一筮 m 9 ,.Ρθ ^ ^ 形戚第一圖案化光阻層,該第一圖案 先阻層覆盍預定形成一源極區之區域; 移除未被該第-圖案化光阻層覆蓋之該層與該第 一導體材料層; 移除該第一圖案化光阻層; 進行非等向性蝕刻製程移除部分該材料層與該第一導 體材料層,以形成一第二間隙壁與一第二導體層; 移除部分該第二間隙壁; 於邊第一閑極結構與該第二閘極結構預定形成該源極 區之該基底中形成該源極區; 於該第二導體層上形成一閘間介電層,並於該源極區 之該基底表面形成一絕緣層; 於該第一閘極結構與該第二閘極結構之間形成一第三 導體層;以及 於該第一閘極結構與該第二閘極結構預定形成一汲極 區之一侧的該基底中形成該汲極區。 12 ·如申請專利範圍第11項所述之快閃記憶體之製造 方法,其中該第一導體層係作為一選擇閘極。 1 3 ·如申請專利範圍第11項所述之快閃記憶體之製造 方法,其中該第二導體層係作為一浮置閘極。 1 4·如申請專利範圍第1 1項所述之快閃記憶體之製造 方法,其中該第三導體層係作為一控制閘極。 1 5·如申請專利範圍第丨丨項所述之快閃記憶體之製造200410402 6. The scope of the application for a patent forms a material layer on the first conductor material layer; a 筮 m 9, .Pθ ^ ^ first patterned photoresist layer is formed on the material layer, and the first pattern is first blocked Layer overlying a region that is intended to form a source region; removing the layer and the first conductive material layer that are not covered by the first patterned photoresist layer; removing the first patterned photoresist layer; The directional etching process removes part of the material layer and the first conductor material layer to form a second gap wall and a second conductor layer; removes part of the second gap wall; The second gate structure is intended to form the source region in the substrate forming the source region; an inter-gate dielectric layer is formed on the second conductor layer, and an insulating layer is formed on the surface of the substrate in the source region. Forming a third conductor layer between the first gate structure and the second gate structure; and the side where the first gate structure and the second gate structure are intended to form a side of a drain region; The drain region is formed in the substrate. 12. The method for manufacturing a flash memory as described in item 11 of the scope of patent application, wherein the first conductor layer is used as a selective gate. 1 3 · The method for manufacturing a flash memory as described in item 11 of the scope of patent application, wherein the second conductor layer is used as a floating gate. 14. The method for manufacturing a flash memory as described in item 11 of the scope of patent application, wherein the third conductor layer is used as a control gate. 1 5 · Manufacture of flash memory as described in item 丨 丨 of the scope of patent application 10220twf.ptd 第24頁 200410402 六、申請專利範圍 方法,其中該閘間介電層之材 矽。 匕括虱化矽/氮化矽/氧化 16·如申請專利範圍第1 1項戶斤、十、十A f法,其中於該第-閘極結構與二亥第2 該第三導體層之步驟包括: T亟結構之間形成 於該基底上形成一第二導體材料層; 第 導體材料層上形成一第二圖 層 ‘圖案化光阻層覆蓋預定形成該源極區之區域層該 未被該第二圖案化光阻層覆蓋之該第二導體材料 移除該第二圖案化光阻層。 1 7·如申請專利範圍第〗6項所述之快閃記憶體之製造 方法其中於該第一閘極結構與該弟一閘極結構之間开^成 該第三導體層之步驟之後更包栝於該第三導體層之^形 成一第三間隙壁。 7 1 8 ·如申請專利範圍第丨丨項所述之快閃記憶體之製造 方法,其中於該第一閘極結構與該第二閘極結構之間形成 該第三導體層之步驟包括: 7 於該基底上形成一第三導雜材料層; 移除部分該第三導體材料層,直到暴露該頂蓋層; 於該基底上形成一第三圖案化光阻層,該第三^案化 光阻層覆蓋預定形成該源極區之匾域; 移除未被該第三圖案化光陴廣覆蓋之該第三導體材料 層;以及 10220twf.ptd 第25貢 200410402 六、申請專利範圍 移除該第三圖案化光阻層。 1 9.如申請專利範圍第11項所述之快閃記憶體之製造 方法,其中於該基底中形成該汲極區之步驟包括: 於該基底中形成一淡摻雜區; 於該第一閘極結構與該第二閘極結構預定形成該汲極 區之一側的側壁上形成一第四間隙壁;以及 於該基底中形成一濃摻雜區。 2 0.如申請專利範圍第11項所述之快閃記憶體之製造 方法,其中於該材料層之材質與該頂蓋層、該第二導體層 之材質具有不同蝕刻選擇性。10220twf.ptd Page 24 200410402 6. Scope of patent application Method, in which the material of the dielectric layer of the gate is silicon. Silicone / Silicon Nitride / Oxidation 16. If the scope of the patent application is No. 11, household method, ten or ten A f method, where the -gate structure and the second conductor layer The steps include: forming a second conductor material layer on the substrate between the structures; forming a second layer on the first conductor material layer; a patterned photoresist layer covering a region layer intended to form the source region; The second conductive material covered by the second patterned photoresist layer removes the second patterned photoresist layer. 17. The method for manufacturing a flash memory as described in item 6 of the scope of patent application, wherein after the step of forming the third conductor layer between the first gate structure and the first gate structure, A third gap is formed on the third conductive layer. 7 1 8 · The method for manufacturing a flash memory according to item 丨 丨 in the scope of patent application, wherein the step of forming the third conductor layer between the first gate structure and the second gate structure includes: 7 forming a third impurity-conducting material layer on the substrate; removing part of the third conductive material layer until the top cap layer is exposed; forming a third patterned photoresist layer on the substrate, the third case The photoresist layer covers the plaque area that is intended to form the source region; removes the third conductor material layer that is not widely covered by the third patterned photocell; and 10220twf.ptd 25th tribute 200410402 The third patterned photoresist layer is removed. 19. The method for manufacturing a flash memory as described in item 11 of the scope of patent application, wherein the step of forming the drain region in the substrate includes: forming a lightly doped region in the substrate; A fourth spacer is formed on a sidewall of the gate structure and the second gate structure that is intended to form one side of the drain region; and a heavily doped region is formed in the substrate. 20. The method for manufacturing a flash memory according to item 11 of the scope of the patent application, wherein the material of the material layer, the material of the cap layer, and the material of the second conductor layer have different etching selectivities. 10220twf.ptd 第 26 頁10220twf.ptd Page 26
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