Λ 6 , Π 6 經濟部屮央榣準杓β工消费合作杜印製 199ϋ88 五、發明説明（ι) 本發明之解凍器1偽由磺成形板所構成。 在碩成形板2為由上面直接載置被解凍物而使之自然解 凍之底板所成，為視密度1.6g/cc以上，自X線繞射圖形所 求得之微晶（Crystallite) (Lc 002)大小為200埃（¾)以上 之石墨質組織所形成者。 底板構成材料之視密度若不足1.6g/cc,微晶（Lc 002) 不足200埃時，石墨結晶之磺質材料組織為不發達之情況 ，因熱傳導性能不足，故無法作急速解凍處理。 5戾成形板2之尺寸，依被解凍物之處理量及大小而定， 可適當的設定。通常，為在急速解凍時仍保持潛在熱能， 成形板之厚度以在至少為10丽以上較佳。 又，碩成形板2之表面，在長期使用時，為使被解凍物 不致被脱離之磺粉所污染，以薄層合成樹脂被膜，譬如氨 基甲酸乙酯（u「e t h a n e )樹脂、環氧樹脂、含氣樹脂等之被 負 膜所塗覆者較佳。 _ 在本發明中之磺成形板2,有腳部3較佳。 為使碩成形板保持穩定，在碩成形板2之下面設置有多 値腳部3。 此脚部3具有使磺成形板2之下面空氣流通性良好，容易 自外部補給解凍所需要之熱能而減輕解凍效率低下之性能 ，其材料以橡膠、塑膠所形成者較好。 本發明之碩成形板為將容易石墨化之石油焦磺或瀝靑焦 碩之粉粒體充填劑與黏結劑揉合，在板狀體成形後於非氣 化性環境中以達到1000C之溫度鍛燒，更在石墨化爐以 (請先間請背而之注意事項#艰寫本頁)( 木紙5fc尺度逍用中國S家標準（CNS) TM規格（210x297公;Ur) 31. 2. 20,000 3 Λ 6 η 6 經濟部中央櫺準局貝工消费合作社印製 ia90B8 五、發明説明（2 ) 2000C以上之溫度加以石墨化處理，其後利用表面加工製 造。對石油焦硪或瀝青焦碩之粉粒醱的黏結劑添加量為每 焦硝粉粒醱100重量份為40〜150重量份。 本發明之石墨質碩成形板具有優越之熱傳導性。 因此，在室溫下將被解凍物置於硪成形板上時，此成形 板本身具有之熱量快速地傳導至被解凍物，而進行被解凍 物之急速的自然解凍。 此解凍處理因時常在常溫以下，而且短時間内行之，卽 使在被解凍物為生肉或魚貝類時，滴水（drip)會大量産生 ，不致使肉或魚貝類之鮮度、風味降低。而且，因硪成形 板重量較軽，容易處理，材質方面亦全無毒性，不會有食 物腐敗之處，故衛生較佳。 在使用本發明之解凍器時，只需將被解凍物置於硪成形 板2上面即可。不需，要設置加熱裝置自外部補給加熱之能 置。 ' 在將多量之冷凍物連鑛解凍時，會消耗來自流通空氣之 解凍能量補給以上在硪成形板2之解凍能量，因解凍能力 極為低下，對解凍器送風，灑以溫水等方法，使解凍器之 解凍能量恢復，再進行解凍處理較好。以下說明本發明之 實施例。 實施例1 , 2及比較例1 將不同視密度及微晶（Lc 002)之三種石墨材料各自加工 ，得到長寬300M,厚10BB之磺成形板。將此成形板包覆 以氛基甲酸乙酯膜後，置於塑謬板上，在成形板上放置厚 (請先閲讀背而之注意事項再填寫本頁)一 本紙張尺度逍用中B B家樣準(CNS)甲4規格(210父297公龙）4 81. 7. 20.000張（H)Λ 6, Π 6 Manufactured by the Ministry of Economic Affairs, Ministry of Economic Affairs, Central China, β-Consumer Cooperative Printing Co., Ltd. 199ϋ88 V. Description of the Invention (ι) The defroster 1 of the present invention is composed of a sulfonate forming plate. The master shaped plate 2 is made of a base plate that is directly thawed and naturally thawed. It is a crystallite (Crystallite) (Lc) obtained from an X-ray diffraction pattern with an apparent density of 1.6g / cc or more 002) Graphite structure with a size of 200 angstroms (¾) or more. If the apparent density of the material constituting the base plate is less than 1.6g / cc and the microcrystalline (Lc 002) is less than 200 angstroms, the structure of the graphite crystal sulfonate material is underdeveloped. Due to the insufficient thermal conductivity, it cannot be quickly thawed. 5 The size of the forming plate 2 depends on the amount and size of the defrosted material, and can be set appropriately. In general, in order to maintain the potential heat energy during rapid thawing, the thickness of the formed plate is preferably at least 10 angstroms or more. In addition, the surface of the master forming plate 2 is used for a long period of time, in order to prevent the defrosted material from being contaminated by the sulfonated powder, a thin layer of synthetic resin film, such as urethane (u ethane) resin, epoxy Resins, gas-containing resins, etc. are preferably coated with a negative film. _ In the present invention, the sulfone forming plate 2 preferably has legs 3. In order to maintain the stability of the master forming plate, under the master forming plate 2 It is provided with multiple feet 3. This foot 3 has the performance of making the sulfonate forming plate 2 have good air circulation, and it is easy to supply the heat energy required for thawing from the outside to reduce the defrosting efficiency. The material is made of rubber and plastic The master forming plate of the present invention is a powdery and granular filler that is easily graphitized by petroleum coke sulfonate or leot coke master and a binder, and is formed in a non-gasification environment after the plate-shaped body is formed. For calcination up to a temperature of 1000C, please use it in the graphitization furnace (please note back to the first # hard to write this page) (wood paper 5fc scale, use Chinese S home standard (CNS) TM specifications (210x297; Ur ) 31. 2. 20,000 3 Λ 6 η 6 Ministry of Economic Affairs, Central Bureau of Economic Development Printed by Zuosha ia90B8 V. Description of the invention (2) Graphitized at a temperature above 2000C, and then manufactured by surface processing. The amount of binder added to the powder of petroleum coke or asphalt coke is nitrate powder per coke 100 parts by weight of granules is 40 ~ 150 parts by weight. The graphite master forming plate of the present invention has excellent thermal conductivity. Therefore, when the object to be thawed is placed on the forming plate at room temperature, the heat of the forming plate itself has Quickly conduct to the thawing object, and carry out the rapid natural thawing of the thawing object. This thawing treatment is often below normal temperature, and it can be carried out in a short time, so that when the thawing object is raw meat or fish and shellfish, drip (drip) ) It will be produced in large quantities, which will not reduce the freshness and flavor of meat or fish and shellfish. Moreover, because the weight of the forming plate is relatively light, it is easy to handle, and the material is completely non-toxic, there will be no food spoilage, so hygiene is better. When using the defrosting device of the present invention, it is only necessary to place the defrosted object on the top of the forming plate 2. No need, a heating device needs to be provided to supplement the heating capacity from the outside. When defrosting the frozen product ore, it will consume the defrosting energy from the circulating air to replenish the above defrosting energy in the forming plate 2. Because the defrosting ability is extremely low, the defrosting energy is supplied by blowing air to the defroster and sprinkling warm water. It is better to recover and then defrost. The following describes the examples of the present invention. Examples 1, 2 and Comparative Example 1 Three graphite materials with different apparent densities and microcrystals (Lc 002) were processed separately to obtain a length and width of 300M and a thickness 10BB sulfone forming plate. After covering this forming plate with ethyl urethane film, place it on the plastic board, and place it on the forming board (please read the precautions before filling this page) one BB Home Sample Standard (CNS) A 4 specifications (210 father 297 male dragon) 4 81. 7. 20.000 sheets (H)
IflQORft_ill_ 五、發明説明（.？） 度重量200g之冷凍牛肉，進行自然解凍。又，成形 板之溫度為2 4 C。其結果示於表1。 實施例3 在 與 實 W& 例 2相同材質、 相同尺寸之硪成形板下方装設 橡 膠 裂 之 脚 部 於 四端， 在 成 形 板上 放 置與 實施例 1相同之 冷 凍 牛 肉 > 進 行 自然解 凍 〇 又 ,成 形 板之 溫度與 實施例2 同 樣 為 2AV 〇 其 结 果 示 於 表 1〇 比 較 例 2 使 用 視 密 度 1 . 38g/〇c m 晶 (L c 002)約 10 0埃之磺質材 料 所 形 成 之 硪 成 形板， 製 成 與 實施 例 1同- -尺寸、 同一構 造 之 解 凍 器 〇 使 此解凍 器 之 板 溫度 為 24Ϊ： ,如同 實施例 進 行 冷 凍 牛 肉 之 自然解 凍 〇 其 結 果 示 於 表 1 〇' 比 較 例 3 - 將 舆 實 施 例 1相同之冷凍牛肉在陶器皿上自然解凍。 其 結 果 示 於 表 1〇 bb 較 例 4 將 舆 實 施 例 1同樣之冷凍牛肉包1 β聚乙烯紙内， 浸於24 V 之 水 槽 内 進 行 熱交換 解 凍 〇 其 結 果 示 於 表 1〇 經濟部中央標準局貞工消伢合作社印製 81. 7. 20.000¾ (II) (請先閲讀背而之注意事項#填"本頁) 本紙張尺度逍用中B因家樣準(CNS)甲4規格(210x297公釐）5 199088^ 經濟部屮央櫺準局员工消费合作社印製 明説明（4 ) 表 Ho. 視密度 (g/cc) 微晶 Lc (X) 解味時間 (分） 滴水量 (cc ) #凍狀況 實施例1 1.63 300 29 5 外形不崩落，正常 實施例2 1.72 1100 19 4 外形不崩落，正常 比較例1 1.58 150 52 10 外形崩落 實施例3 1.72 1100 15 3 外形不崩落，正常 比較例2 1.38 1ΘΘ 58 10 外形崩落 比較例3 — — 68 17 表面凹陷，味道低下 比較例4 17 13 水份過多，表面産生 凹陷在24C牛肉之溫 度昇高過速，易腐敗 表IflQORft_ill_ V. Description of the invention (.?) Frozen beef with a weight of 200g is naturally thawed. In addition, the temperature of the formed plate was 2 4 C. The results are shown in Table 1. Example 3 A rubber cracked leg was installed at the four ends under the same forming plate of the same material and the same size as the actual W & Example 2, and the same frozen beef as in Example 1 was placed on the forming plate for natural thawing. In addition, the temperature of the molded plate was 2AV as in Example 2. The results are shown in Table 10. Comparative Example 2 was formed using a sulfonic material with an apparent density of 1.38 g / cm (L c 002) of about 100 angstroms. The shaped plate was made into a defroster of the same size and same structure as in Example 1. The plate temperature of this defroster was 24Ϊ :, as in the example, natural defrosting of frozen beef was performed. The results are shown in Table 10. Comparative Example 3-Naturally thaw frozen beef in the same manner as in Example 1 on ceramic dishes. The results are shown in Table 10. bb Comparative Example 4 The frozen beef pack 1 similar to Example 1 was immersed in a 24 V water tank for heat exchange and thawing. The results are shown in Table 10. The center of the Ministry of Economy Printed by the Bureau of Standards and Industry ’s Cooperative Society 81. 7. 20.000¾ (II) (please read the back-end notes # fill " this page) This paper is used in the standard B because of the family standard (CNS) A 4 Specification (210x297mm) 5 199088 ^ Printed instructions printed by the Employee Consumer Cooperative of the Central Bureau of Economics and Economics (4) Table Ho. Apparent density (g / cc) Microcrystalline Lc (X) Deodorization time (min) Drip (cc) #Frozen Example 1 1.63 300 29 5 The shape does not collapse, the normal example 2 1.72 1100 19 4 The shape does not collapse, the normal comparative example 1 1.58 150 52 10 The shape collapse example 3 1.72 1100 15 3 The shape does not collapse, Normal Comparative Example 2 1.38 1ΘΘ 58 10 Appearance of shape collapse Comparative Example 3 — — 68 17 Depression on the surface, low taste Comparative Example 4 17 13 Excessive moisture, depression on the surface The temperature of the beef rises too fast at 24C
No. 磺成形板 撖晶 冷凍鲔 冷浓蝦 解凍狀況 視密度 (g/cc) (Lc002) 0 A 解凍時間· (分） 滴水量 (CC) ------- 解凍時間 (分） 實施例4 1.72 1100 15 4 10 外形不崩落，正常 實施例5 1.72 1100 12 3 9 外形不崩落，正常 比較例5 1.38 100 54 15 30 鲔魚表面凹陷大蝈 之鮮度降低 比較例6 62 20 35 鲔魚水份過多，表 面凹陷大，蝦鮮度 降低 比較例7 14 16 8 鲔魚滴水置多變得 柔軟，而蝦鮮度降 低，尾巴發黑 本紙張尺度遑用中a Η家樣準(CNS)甲4規格(210><297公龙）6 81. 7. 20.000张（II) 請 先 閲 背 而 之 注 意 事 項 填 寫-本 頁 裝 訂No. Sulphur forming plate 泖 晶 frozen tuna cold thick shrimp thawing status apparent density (g / cc) (Lc002) 0 A thawing time · (minutes) drip volume (CC) ------- thawing time (minutes) implementation Example 4 1.72 1100 15 4 10 The shape does not fall, the normal example 5 1.72 1100 12 3 9 The shape does not fall, the normal comparison example 5 1.38 100 54 15 30 Tuna surface depression The freshness of the large grasshopper is reduced Comparative example 6 62 20 35 Tuna Too much water, large depressions on the surface, and reduced freshness of shrimp. Comparative Example 7 14 16 8 The tuna becomes softer when dripped, and the freshness of shrimp is reduced, and the tail is black. The paper scale is used. Specifications (210 > < 297 male dragon) 6 81. 7. 20.000 sheets (II) Please read the notes before filling in-page binding
經濟部屮央櫺準局员工消t合作社印M -^—- 五、發明説明（5 ) 由表1之實施例1及2及比較例1,在本發明之解凍器中， 不論為常溫與否，在短時間可自然解凍，造成冷凍牛肉外 形不崩落。 又，自表1之比較例2,即使為同樣的磺成形板，在視密 度小，石墨結晶不發達之碩質组鐵，自然解凍所需時間變 長，有多量滴水産生，在解凍後，易引起外形崩落。 再者，自表1之比較例3,習知之自然解凍法，解凍所需 時間長，滴水量亦多，不僅易變形，亦造成連解凍牛肉之 味道也低下。 更且，自表1之比較例4,在水解凍法，因解凍所需時間 短，滴水量多，解凍後之牛肉水份過多，造成味道低下。 又，除上述比較例3及4以外，習知之解凍法有（a)流水 解凍法，（b)吹風解凍法及（c)在不銹銷盤上之自然解凍法 。然而U)冷陳食品因與水直接接觸，故在解凍後不僅水 分過多，亦有造成排水污染乏危險性存在，（b)在被解凍 物表面空氣中水份凝結而使解凍之食品水份過多，滴水量 亦多，且有解凍時間過長之缺點。（c)因不銹銅之熱容量 小，故與冷凍食品接觸部份之不銹鋼板會迅速變冷而有解 凍速度降低之缺點存在。 因此，在本發明之解凍器中，將自然解凍之解凍時間明 顥地縮短，而且因解凍時滴水發生量少，在解凍處理後之 食品中，可防止外形崩落及味道之低下。 實施例4及5 ,比較例5 , 6及7 將厚度約20ΠΒ,重量約250g之冷凍鲔切H(slice)及約 本紙張尺度逍用中國B家樣準(CNS)甲4規格(2丨0X297公¢) 7 81. 7. 20.000張（II) (請先閲讀背而之注意事項#填寫本頁) 裝· 經濟部屮央標準局员工消费合作杜印¾ 19^088 五、發明説明（6 ) 25g之冷凍蝦，在以與實施例2及*施例3之同一條件下加 以解凍之情形（實施例4及實施例5),使用與比較例2同一 材質，同一尺寸之硪成形板之情形（比較例5),使用與比 較例3同一陶器皿之情形（比較例6),及與比較例4同一條 件下，在水槽中解凍之情形（比較例7 )，等加以檢討。 結果示於表2。 由表2之結果，在冷凍鲔及冷凍蝦之解凍之情形，若使 用本發明之解凍器時，可達成與冷凍牛肉之解凍情形同樣 的，使冷凍時間缩短，防止崩落，減少滴水量，防止鮮度 降低之效果。 [圜式之簡單説明] 圖1為依本發明將解凍器之一例予以画示之斜視圈。 Λ 6 η 6 (請先閲讀背而之注意事項#填寫本頁) 裝- 線- 本紙張尺度逍用中國國家楳準(CNS)T4規格(210X297公tf)8嗲三育 81. 7. 20.000¾ (II)Printed by the Ministry of Economic Affairs, Ministry of Economic Affairs, Employee Elimination Cooperative Society M-^ —- V. Description of the Invention (5) From Examples 1 and 2 and Comparative Example 1 of Table 1, in the defroster of the present invention, No, it can be thawed naturally in a short time, so that the shape of frozen beef does not fall. Also, from Comparative Example 2 of Table 1, even if it is the same sulfonate forming plate, the apparent iron density is small, and the graphite iron is not well-developed. The time required for natural thawing becomes longer, and a lot of dripping occurs. After thawing, Easy to cause shape collapse. Furthermore, from Comparative Example 3 of Table 1, the conventional natural thawing method requires a long time for thawing and a large amount of dripping water, which is not only easily deformed, but also causes the taste of the defrosted beef to be low. Moreover, in Comparative Example 4 from Table 1, in the hydrolyzing method, the time required for thawing is short, the amount of dripping water is large, and the beef after thawing has too much moisture, resulting in a low taste. In addition to the above Comparative Examples 3 and 4, the conventional defrosting methods include (a) running water defrosting method, (b) blowing defrosting method, and (c) natural defrosting method on stainless pin. However, due to direct contact with water, cold-aged food not only has too much water after defrosting, but also has the risk of causing poor pollution of drainage. (B) The moisture of the defrosted food is condensed in the air on the surface of the defrosted object. Too much, the amount of dripping water is also large, and has the disadvantage of too long thawing time. (C) Because the heat capacity of stainless copper is small, the stainless steel plate in contact with frozen food will quickly become cold and have the disadvantage of a slower defrosting speed. Therefore, in the defrosting device of the present invention, the defrosting time of natural defrosting is shortened, and the amount of dripping water generated during defrosting is small. In the defrosted food, the appearance of the food is prevented from collapsing and the taste is reduced. Examples 4 and 5, Comparative Examples 5, 6 and 7 Frozen tuna with a thickness of about 20 ΠB and a weight of about 250g were cut into H (slice) and about the size of the paper. The Chinese B family sample standard (CNS) A 4 specifications (2 丨0X297 public ¢) 7 81. 7. 20.000 sheets (II) (please read the backing notes first # fill in this page) Outfit · Employee's consumer cooperation Duan of the Central Standards Bureau of the Ministry of Economic Affairs ¾ 19 ^ 088 V. Description of invention ( 6) 25g of frozen shrimp, when defrosted under the same conditions as in Example 2 and * Example 3 (Example 4 and Example 5), use the same material and the same size as the comparative example 2 The case (Comparative Example 5), the case of using the same ceramic ware as Comparative Example 3 (Comparative Example 6), and the case of thawing in the water tank under the same conditions as Comparative Example 4 (Comparative Example 7), etc. will be reviewed. The results are shown in Table 2. According to the results in Table 2, in the case of thawing frozen tuna and frozen shrimp, when using the thawing device of the present invention, the same situation as that of frozen beef can be achieved, which shortens the freezing time, prevents collapse, reduces the amount of dripping, and prevents The effect of freshness reduction. [Simple description of the circular pattern] FIG. 1 is a squint circle showing an example of a defroster according to the present invention. Λ 6 η 6 (please read the back-end precautions # fill in this page) Pack-Line-This paper scale is easy to use China National Standards (CNS) T4 specifications (210X297 male tf) 8 嗲 三 育 81. 7. 20.000 ¾ (II)