TR2022008021T2 - COMPOSITIONS CONTAINING STABLE FUNGICIDAL COMPOUNDS - Google Patents
COMPOSITIONS CONTAINING STABLE FUNGICIDAL COMPOUNDSInfo
- Publication number
- TR2022008021T2 TR2022008021T2 TR2022/008021 TR2022008021T2 TR 2022008021 T2 TR2022008021 T2 TR 2022008021T2 TR 2022/008021 TR2022/008021 TR 2022/008021 TR 2022008021 T2 TR2022008021 T2 TR 2022008021T2
- Authority
- TR
- Turkey
- Prior art keywords
- molecular weight
- mixture
- fungicidal composition
- condensate
- composition according
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 189
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 115
- 150000001875 compounds Chemical class 0.000 title description 5
- 239000000417 fungicide Substances 0.000 claims abstract description 97
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 78
- 238000000034 method Methods 0.000 claims abstract description 27
- 239000012990 dithiocarbamate Substances 0.000 claims abstract description 26
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract 8
- 150000003839 salts Chemical class 0.000 claims description 33
- 239000005802 Mancozeb Substances 0.000 claims description 27
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 claims description 26
- 239000005825 Prothioconazole Substances 0.000 claims description 26
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 23
- 239000000575 pesticide Substances 0.000 claims description 19
- -1 Diniconase Ol Chemical compound 0.000 claims description 18
- 229930182692 Strobilurin Natural products 0.000 claims description 15
- 239000005730 Azoxystrobin Substances 0.000 claims description 14
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical group CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 claims description 14
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000005857 Trifloxystrobin Substances 0.000 claims description 9
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 claims description 9
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 claims description 4
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 claims description 4
- 239000005784 Fluoxastrobin Substances 0.000 claims description 3
- 239000005809 Metiram Substances 0.000 claims description 3
- 239000005823 Propineb Substances 0.000 claims description 3
- 239000005869 Pyraclostrobin Substances 0.000 claims description 3
- 239000005870 Ziram Substances 0.000 claims description 3
- JOXAXMBQVHFGQT-UHFFFAOYSA-J copper;manganese(2+);n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[Cu+2].[S-]C(=S)NCCNC([S-])=S.[S-]C(=S)NCCNC([S-])=S JOXAXMBQVHFGQT-UHFFFAOYSA-J 0.000 claims description 3
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 3
- 229920000940 maneb Polymers 0.000 claims description 3
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 claims description 3
- 229920000257 metiram Polymers 0.000 claims description 3
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- KKMLIVYBGSAJPM-UHFFFAOYSA-L propineb Chemical compound [Zn+2].[S-]C(=S)NC(C)CNC([S-])=S KKMLIVYBGSAJPM-UHFFFAOYSA-L 0.000 claims description 3
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 3
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 claims description 3
- YNWVFADWVLCOPU-MDWZMJQESA-N (1E)-1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pent-1-en-3-ol Chemical compound C1=NC=NN1/C(C(O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MDWZMJQESA-N 0.000 claims description 2
- PPDBOQMNKNNODG-NTEUORMPSA-N (5E)-5-(4-chlorobenzylidene)-2,2-dimethyl-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol Chemical compound C1=NC=NN1CC1(O)C(C)(C)CC\C1=C/C1=CC=C(Cl)C=C1 PPDBOQMNKNNODG-NTEUORMPSA-N 0.000 claims description 2
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 claims description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 claims description 2
- PXMNMQRDXWABCY-UHFFFAOYSA-N 1-(4-chlorophenyl)-4,4-dimethyl-3-(1H-1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC=C(Cl)C=C1 PXMNMQRDXWABCY-UHFFFAOYSA-N 0.000 claims description 2
- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 claims description 2
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 claims description 2
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims description 2
- BNYCHCAYYYRJSH-UHFFFAOYSA-N 1h-pyrazole-5-carboxamide Chemical compound NC(=O)C1=CC=NN1 BNYCHCAYYYRJSH-UHFFFAOYSA-N 0.000 claims description 2
- YABFPHSQTSFWQB-UHFFFAOYSA-N 2-(4-fluorophenyl)-1-(1,2,4-triazol-1-yl)-3-(trimethylsilyl)propan-2-ol Chemical compound C=1C=C(F)C=CC=1C(O)(C[Si](C)(C)C)CN1C=NC=N1 YABFPHSQTSFWQB-UHFFFAOYSA-N 0.000 claims description 2
- JERZEQUMJNCPRJ-UHFFFAOYSA-N 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol Chemical compound C=1C=C(OC=2C=CC(Cl)=CC=2)C=C(C(F)(F)F)C=1C(O)(C)CN1C=NC=N1 JERZEQUMJNCPRJ-UHFFFAOYSA-N 0.000 claims description 2
- OVFHHJZHXHZIHT-UHFFFAOYSA-N 3-(2,4-dichlorophenyl)-2-(1,2,4-triazol-1-yl)quinazolin-4-one Chemical compound ClC1=CC(Cl)=CC=C1N1C(=O)C2=CC=CC=C2N=C1N1N=CN=C1 OVFHHJZHXHZIHT-UHFFFAOYSA-N 0.000 claims description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 claims description 2
- BFTGQIQVUVTBJU-UHFFFAOYSA-N 5,6-dihydroimidazo[2,1-c][1,2,4]dithiazole-3-thione Chemical compound C1CN2C(=S)SSC2=N1 BFTGQIQVUVTBJU-UHFFFAOYSA-N 0.000 claims description 2
- MPKTWNYCNKUVKZ-UHFFFAOYSA-N Carbamorph Chemical compound CN(C)C(=S)SCN1CCOCC1 MPKTWNYCNKUVKZ-UHFFFAOYSA-N 0.000 claims description 2
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Abstract
Mevcut buluş, azol fungisitleri, ditiyokarbamatları ve yüksek ve düşük moleküler ağırlıklı formaldehit-aromatik sülfonik asit kondensatlarından oluşan karışımı içeren stabil bir bileşimdir. Mevcut buluş ayrıca, istenmeyen zararlıları kontrol etmeye yönelik bir yöntem olup; söz konusu yöntem, mevcut buluşa göre etkili miktarda stabil fungusit bileşimin zararlılara veya habitatlarına uygulanmasını içerir.The present invention is a stable composition comprising azole fungicides, dithiocarbamates and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensates. The present invention is also a method for controlling unwanted pests; said method comprising applying an effective amount of a stable fungicidal composition according to the present invention to the pests or their habitats.
Description
TARFNAME STABIL FUNGISIDAL BILESIK IÇEREN BILESIMLER Bulusun teknik alani Mevcut bulus, stabil fungisidal bilesimleri sunar. Mevcut bulus, azol fungisitler, ditiyokarbamatlar ve yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatlarinin bir karisimini içeren stabil fungisidal bilesimlerle ilgilidir. Bulusun arka glani Mantarlar, dünya genelinde mahsul kaybinin baslica nedenlerinden biridir ve bu nedenle fungisitler, önemli bir pestisit sinifi olarak kabul edilir. Fungisitler, mantarlari ve bunlarin sporlarini öldüren veya büyümesini önleyen pestisitlerdir. Fungisitler, hastaliklara neden olan mantari inhibe ederek veya öldürerek mantar hastaliklarini kontrol etmek amaciyla yaygin olarak kullanilan spesifik pestisit türleridir. Pas, külleme ve yaniklari kontrol altina almak için kullanilabilirler.Fungisitler etki sekillerine bagli olarak çesitli yollarla ise yaramakla birlikte çogu mantar hücre zarlarina zarar verir veya mantar hücreleri içindeki enerji üretimine müdahale eder. Farkli siniflardaki fungisitler, büyüyen mahsullerdeki çogu majör hastaligin kontrol altina alinmasinda basarili olmustur. Ditiyokarbamatlar gibi inorganik kompleks bilesikler, mantar hastaliklarinin kontrolü için gelistirilen en eski kimyasallardan biridir. Bu kimyasallar mantardaki çesitli biyokimyasal süreçleri etkilerler ve bu nedenle çok bölgeli fungisit olarak adlandirilirlar. Bununla birlikte, söz konusu kimyasallar kontak etkili ve sistemik olmayan fungisitlerdir. Sadece kültür bitkisini hastalik enfeksiyonundan korurlar. Sistemik fungisitler 1960'lardan beri gelistirilmistir ve o zamandan beri yaygin olarak kullanilmaktadir. Bu tür kimyasallarin çogu tedavi edici ve yok edici olsa da, bölgeye özgüdür ve yalnizca tek bir biyokimyasal yolu etkiler. Bu tür çok bölgeli fungisit ve bir sistemik fungisit kombinasyonu, belirli bir süre boyunca bu tek bölgeli fungisitlere karsi bazi mantarlar tarafindan gelistirilen direnç dikkate alindiginda, çesitli fungisidal hastaliklarin yeterince kontrol altina alinmasi hususunda yaygin olarak kabul edilebilir bir yöntemdir. Fungisidal kimyasallarin maksimum etkinligini ortaya çikarmak için, agrokimyasal olarak kabul edilebilir eksipiyanlarla formüle edilmeleri gerektigi iyi bilinmektedir. Bu ekspiyanlar fungisitlerin aktivitesini artirmanin yani sira formüle edilmis ürünlerin fiziksel özelliklerini de degistirmektedir. 2 veya daha fazla aktif bilesen içeren bir ürünü formüle etmek, formüle edilen ürünün uyumluluklari ve stabilitesi gibi sorunlari öngörmenin zorlugundan dolayi gerçekten güçtür. Strobilurinler tarimda fungisit olarak kullanilan bir grup kimyasal bilesiktir. Bunlar, solunum zincirini Kompleks III düzeyinde inhibe etmek üzere hareket eden daha büyük Qol inhibitörleri grubunun bir parçasidir. Strobilurinler çogunlukla, kütikül içinde emildikleri ve daha fazla tasinmadiklari için uzun bir yarilanma süresi olan kontak fungisitlerdir. Yaygin olarak kullanilan bir strobilurin fungisit Azoksistrobindir. Bu koruyucu, tedavi edici, yok edici, translaminar ve sistemik özelliklere sahip bir fungisittir. Azoksistrobin, 100 - 375 g/ha uygulama oranlarinda asagidaki patojenleri kontrol altina alir: Iliman iklimlerde görülen tahillarda Erysiphe graminis, Puccinia spp., Leptosphaeria nodorum, Septoria tritici ve Pyrenophora teres; pirinçte Pyricularia oryzae ve Rhizoctonia solani; bagda Plasmopara viticola ve Uncinula necator; kabakgillerde Sphaerotheca fuliginea ve Pseudoperonospora cubensis; patates ve domateste Phytophthora infestans ve Alternaria solani; yerfistiginda Mycosphaerella arachidis, Rhizoctonia solani ve Sclerotium rolfsii ve seftalide Cladosporium carpophilum, çimde Pythium spp. ve Rhizoctonia solani; muzda Mycosphaerella spp; pekan cevizinde Cladosporium caryigenum; narenciyede Elsinoe fawcettii, Colletotrichum spp. ve Guignardia citricarpa; kahvede Colletotrichum spp. ve Hemileia vastatrix. Konazol fungisitler, kültür bitkilerinin korunmasi için tarimda yaygin olarak kullanilan genis bir bilesik grubunu temsil eder. Protiokonazol bir konazol fungisit olup, koruyucu, tedavi edici, yok edici ve uzun süreli etkiye sahip sistemik bir fungisittir. Protiokonazol bugday, arpa ve diger mahsullerde yapraktan uygulama ile, göz lekesi (Pseudocercosporella herpotrichoides), Fusarium erken yaprak yanikligi (Fusarium spp., Microdochium nivale), yaprak pasi hastaliklari (Septoria tritici, Leptosphaeria nodorum, Pyrenophora spp., Rhynchosporium secalis, vb.), pas (Puccinia spp.) ve külleme (Blumeria graminis) gibi hastaliklarin kontrol altina alinmasinda kullanilir. Tohum ilaçlamasi olarak Ustilago spp., Tilletia spp., Fusarium spp. ve Microdochium nivalelnin kontrolünde kullanilir. Mancozeb koruyucu etkiye sahip, genis spektrumlu, sistemik olmayan bir fungisittir. Mancozeb, çok çesitli tarla bitkileri, meyveler, kuruyemisler, sebzeler, süs bitkileri vs. görülen birçok mantar hastaliginin kontrol altina alinmasi için kullanilir. Daha sik kullanimlar patates ve domateste erken ve geç yaniklarin (Phytophthora infestans ve Alternaria solani); bag mildiyösünün (Plasmopara viticola) ve siyah kök çürüklügünün (Guignardia bidwellii); kabakgil mildiyösünün (Pseudoperonospora cubensis); elma karalekesinin (Venturia inaequalis); muzda Yaprak lekesinin (Mycosphaerella spp.) ve narenciye melanozunun (Diaporthe citri) kontrol altina alinmasini içerir. Mevcut bulusun mucitleri, bir azol mantar ilaci ve diger aktif bilesenlerin bir karisimini formülasyon olarak formüle ederken fiziksel uyumsuzluga dikkat çekti. Bu azol fungisitlerinin formüle edilmesi zor moleküller olarak kabul edildigi anlasilmistir. Fiziksel uyumsuzluk, topak veya jel olusumuna neden olur. Aktif bilesenler düzgün bir sekilde dagilmaz ve süspansiyonda çökmez. Bu tür formülasyonlar, süspansiyonda bir düsüse maruz kalir ve bu nedenle düsük performansa yol açar. Uyumsuzluk ayrica köpük olusumuna, tankta tabakalasmaya ve renk degisikliklerine neden olabilir. Mevcut bulus, yukarida bahsedilen komplikasyonlari gidermeyi ve ditiyokarbamat fungisitler ve diger aktif bilesenler ile azol fungisitin stabil ve etkili formülasyonlarini saglamayi amaçlar. Mevcut bulusun amaçlari Mevcut bulusun bir amaci azol fungisit ihtiva eden stabil bir fungisidal bilesim saglamaktir. Mevcut bulusun bir diger amaci bir azol fungisit, bir ditiyokarbamat, en az bir yardimci pestisit ihtiva eden stabil bir fungisidal bilesim saglamaktir. Mevcut bulusun bir baska amaci, istenmeyen zararlilari kontrol etmeye yönelik bir yöntem saglamaktir; söz konusu yöntem, mevcut bulusa göre etkili miktarda stabil fungusit bilesimin zararlilara veya habitatlarina uygulanmasini içerir. Mevcut bulusun özeti Mevcut bulus, bir azol fungisit, yüksek ve düsük moleküler agirlikli formaldehit- aromatik sülfonik asit kondensatlarinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil birfungisidal bilesim saglamaktadir. Mevcut bulus, bir azol fungisit ile yüksek ve düsük moleküler agirlikli formaldehit- aromatik sülfonik asit kondensatlarinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat içerir. Mevcut bulus, bir azol fungisit, bir ditiyokarbamat, yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatlarinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir. Mevcut bulus, bir azol fungisit, bir ditiyokarbamat ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatlarinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat içerir. Mevcut bulusa uygun bilesimler ayrica en az bir yardimci pestisit ihtiva eder. Mevcut bulusa uygun bilesimler ayrica en az bir strobilurin fungisit ihtiva eder. Mevcut bulus ayrica, istenmeyen zararlilari kontrol etmeye yönelik bir yöntem sunar; söz konusu yöntem, mevcut bulusa göre etkili miktarda stabil fungusit bilesimin zararlilara veya habitatlarina uygulanmasini içerir. Ayrintili tarif: Azol fungisitleri, formüle edilmesi zor fungisit siniflaridir. Mevcut bulus sahipleri tarafindan, azol bilesiklerinin kararli bilesimlerinin, yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatlari, türevleri veya tuzlarinin bir karisimi olan bir yüzey aktif maddenin mevcudiyetinde hazirlanabilecegi bulunmustur. Formaldehit-aromatik sülfonik asit kondensatlari, türevleri veya tuzlari sinifinda bilinen birçok yüzey aktif madde vardir. Ancak bunlarin tümü, yüksek ve düsük moleküler agirlikli kondensatlarin bir karisimi degildir ve dolayisiyla bu yüzey aktif maddelerin tümü, azol fungusit içeren stabil bilesimler saglamaz. Stabil azol fungisit bilesimlerinin sadece yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatlarinin bir karisimi olan formaldehit-aromatik sülfonik asit kondensatlari, türevleri veya tuzlarinin mevcudiyetinde hazirlanabilecegi bulundu. Daha tercihen, karisimin agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat içerdigi kararli bilesimler hazirlanmistir. Ayrica, formaldehit-aromatik sülfonik asit kondensat yüzey aktif madde, yüksek ve düsük moleküler agirlikli kondensatlar, bunlarin türevleri veya tuzlarinin bir karisimi olmadiginda, bu tür stabil bilesimlerin hazirlanamayacagi bulundu. Buna göre mevcut bulus, tek basina veya diger aktif bilesenlerle kombinasyon halinde bir azol fungisidi içeren stabil bilesimler saglar. Mevcut bulusun mucitleri, çesitli formülasyon tiplerinde azollerin formülasyonunun gelistirilmesi sirasinda ortaya çikan fiziksel degiskenligi gözlemlediler. Sasirtici bir sekilde mevcut bulusun mucitleri, yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin, türevlerinin veya tuzlarinin bir karisiminin kullanilmasiyla azol fungisitlerini içeren stabil formülasyonlar veya bilesimler gelistirdiler. Bu nedenle, mevcut bulus, bir azol fungisit, yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatlarinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil birfungisidal bilesim saglamaktadir. Mevcut bulus, bir azol fungisit ile yüksek ve düsük moleküler agirlikli formaldehit- aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat içerir. Mevcut bulus, bir azol fungisit, bir ditiyokarbamat, yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir. Mevcut bulus, bir azol fungisit, bir ditiyokarbamat ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat içerir. Mevcut bulus, bir azol fungisit, bir ditiyokarbamat ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat içerir. Mevcut bulusla ilgili olarak, "yüksek moleküler agirlikli kondensat" terimi, numaralandirilmis ortalama moleküler agirligi 5000'den fazla olan bir polimer kondensati ifade eder. Özellikle numaralandirilmis ortalama moleküler agirlik, 5000 ila 50.000 arasinda bir araligi ifade Mevcut bulusla ilgili olarak, "düsük moleküler agirlikli kondensat" terimi, numaralandirilmis ortalama moleküler agirligi 5.000 veya altinda olan bir polimer kondensati ifade eder. Özellikle numaralandirilmis ortalama moleküler agirlik, 5000 ila 500 arasinda bir araligi ifade eder. Mevcut bulusla ilgili olarak, "yüksek ve düsük moleküler agirlikli kondensat karisimi" terimi, moleküler agirligi 5000'den fazla olan bir kondensat yüzdesi ile tüm kondensatlarin agirlik olarak %15'inden fazla olmayan bir polimer kondensati ifade Mevcut bulusla ilgili olarak, "yüksek ve düsük moleküler agirlikli kondensat karisimi" terimi, moleküler agirligi 5.000 veya daha az olan bir kondensat yüzdesi ile tüm kondensatlarin agirlik olarak %90'indan fazla olmayan bir polimer kondensati ifade Mevcut bulusla ilgili olarak, "yüksek ve düsük moleküler agirlikli kondensat karisimi" terimi, düsük ve yüksek moleküler agirlikli kondensatin bir karisimi olan bir polimer kondensatini ifade eder; burada karisimin yaklasik %90'a kadar olan ana bileseninin moleküler agirligi 5000lin altinda ve karisimin yaklasik %15'e kadar olan küçük bileseninin moleküler agirligi 5000lin üstündedir. Bir uygulama örneginde, bilesim, formülasyonun agirligina göre yaklasik %0,01 ila yaklasik %30 miktarinda yüksek ve düsük moleküler agirlikli kondensat karisimini ihtiva eder. Tercihen bilesim, formülasyonun agirligina göre yaklasik %1 ila yaklasik %20 miktarinda yüksek ve düsük moleküler agirlikli kondensat karisimini ihtiva eder. Mevcut bulusun bir uygulama örneginde, bir azol fungisit, bir ditiyokarbamat ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Bir uygulama örneginde azol fungisit; pirazol karboksamid fungisit, benzimidazol fungisit, benzotiyazol fungisitlerden olusan gruptan ve konazol fungisitler ise, imidazoller ve triazoller ile oksazol fungusitten olusan gruptan seçilmistir. Tercih edilen bir uygulama örneginde azol fungisit konazol fungisitlerden seçilmektedir. Bir uygulama örneginde konazol fungisit; azakonazol, bromukonazol, siprokonazol, diklobutrazol, difenokonazol, dinikonazol, dinikon azol-M, epoksikonazol, etakonazol, fenbukonazol, flukinkonazol, flusilazol,flutriafol, furkonazol, furkonazole-cis, hekzakonazol, imibenkonazol, ipkonazol,ipfentriflukonazol, mefentriflukonazol, metkonazol, miklobütanil, penkonazol,propikonazol, flukonazol, protiokonazol, kinkonazol, simekonazol, tebukonazol, tetrakonazol, triadimefon, triadimenol, tritikonazol, unikonazol ve unikonazol-P arasindan seçilmistir. Bir uygulama örneginde, tercih edilen konazol fungisit protiokonazoldür. Bir uygulama örneginde, bilesim, bilesimin agirligina göre yaklasik %0,01 ila yaklasik %50 arasinda bir miktarda protiokonazol ihtiva eder. Bir baska uygulama örneginde ditiyokarbamat fungisit amobam, asomate, azithiram, karbamorf, kufraneb, kuprobam, disulfiram, ferbam metam, nabam, tekoram, thiram, urbasit, ziram, dazomet, etem, milneb, mancopper,mancozeb,maneb,metiram,polikarbamat,propineb vezineb arasindan seçilmistir. Bir uygulama örneginde tercih edilen ditiyokarbamat fungisit ziram, mancopper,mancozeb,maneb,metiram,polikarbamat,propineb vezineb arasindan seçilmistir. Bir uygulama örneginde, tercih edilen ditiyokarbamat fungisit mancozebdir. Bir uygulama örneginde, bilesim, bilesimin agirligina göre yaklasik %10 ila yaklasik %99 arasinda bir miktarda mancozeb ihtiva eder. Tercih edilen bir uygulama örneginde, bilesim, bilesimin agirligina göre yaklasik %30 ila yaklasik %90 arasinda bir miktarda mancozeb ihtiva eder. Bir uygulama örneginde mevcut bulus, protiokonazol, mancozeb ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren bir bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Bir uygulama örneginde mevcut bulusa uygun fungisidal bilesimler ayrica en az bir Bu nedenle bir uygulama örneginde, mevcut bulus, bir azol fungisit, bir ditiyokarbamat, en az bir yardimci pestisit ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Bir uygulama örneginde, yardimci pestisit herbisit, böcek öldürücü, böcek büyüme düzenleyicisi, nematisit, termitisit, molluskisit, bakterisit, böcek kovucu, hayvan kovucu, antimikrobiyal, fungisit, dezenfektan ve sanitizer arasindan seçilmistir ancak bunlarla sinirli degildir. Tercih edilen bir uygulama örneginde yardimci pestisit bir fungisittir. Bir uygulama örneginde yardimci pestisit, sinirlandirici olmaksizin demetilasyon inhibitörü, kinon dis inhibitörü, süksinat dehidrojenaz inhibitörü ve kinon iç inhibitöründen seçilen fungisittir. Bir baska uygulama örneginde, yardimci pestisit kinon dis inhibitörüdür. Bir diger uygulama örneginde, kinon dis inhibitörü strobilurin fungisitlerinden seçilmistir. Bu nedenle bir uygulama örneginde, mevcut bulus, bir azol fungisit, bir ditiyokarbamat bir strobilurin fungisit ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Bir uygulama örneginde, strobilurin fungisit, bunlarla sinirli olmamak üzere Azoksistrobin, kresoxim-metil, pikoksistrobin, piraklostrobin, fluoksastrobin ve trifloksistrobin arasindan seçilmistir. Bir uygulama örneginde tercih edilen strobilurin fungisit azoksistrobin, trifloksistrobin ve piraklostrobin arasindan seçilmistir. Bir uygulama örneginde, bilesim, bilesimin agirligina göre yaklasik %0,01 ila yaklasik %30 arasinda bir miktarda strobilurin fungisit ihtiva eder. Tercih edilen bir uygulama örneginde, bilesim, bilesimin agirligina göre yaklasik %1 ila yaklasik %20 arasinda bir miktarda strobilurin fungisit ihtiva eder. Bir uygulama örneginde mevcut bulus, protiokonazol, mancozeb, trifloksistrobin ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren bir bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Bir uygulama örneginde mevcut bulus, protiokonazol, mancozeb, azoksistrobin ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren bir bilesim saglamaktadir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Mevcut bulusa göre bilesimler, emülsiyon konsantrasyonlari, islatilabilir tozlar, suda dagilabilen granüller, süspansiyon konsantresi, mikroemülsiyon, kapsül süspansiyonlari, granüller ve benzerleri olarak formüle edilebilir. Bir uygulama örneginde, mevcut bulusa uygun bilesimler kati bilesimler olarak formüle edilebilmektedir. Bulusa uygun kati bilesimler hazirlama islemleri sinirli degildir. Bir uygulama örneginde, mevcut bulusa uygun kati bilesimler asagidaki gibi hazirlanir: a) bir azol fungisitin, istege bagli olarak diger eksipiyanlarin ve yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin, türevlerinin veya tuzlarinin bir karisiminin harmanlanmasi; burada söz konusu harman, homojen bir karisim olusturmak için bir karisimda agirlik olarak %15'ten fazla olmayan yüksek moleküler agirlikli bir kondensat içerir. b) bir seyreltici ile karisim bulamacinin hazirlanmasi ve c) bilesimi elde etmeye yönelik granülasyonun ardindan bulamacin yas ögütülmesi Bir uygulama örneginde, mevcut bulusa uygun kati bilesimler asagidaki gibi hazirlanir: a) Bir azol fungisitin, istege bagli olarak diger eksipiyanlarin, istege bagli ek bir yardimci pestisitin ve yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin, türevlerinin veya tuzlarinin bir karisiminin harmanlanmasi; burada söz konusu harman, homojen bir karisim olusturmak için bir karisimda agirlik olarak %15'ten fazla olmayan yüksek moleküler agirlikli bir kondensat içerir. b) bir seyreltici ile karisim bulamacinin hazirlanmasi ve c) bulamacin yas ögütülmesi d) bilesimi elde etmeye yönelik granülasyonun ardindan istege bagli olarak ek bir Bir uygulama örneginde, mevcut bulusa uygun kati bilesimler asagidaki gibi hazirlanir: a) Bir azol fungisitin, bir ditiyokarbamat fungisitin, istege bagli olarak diger eksipiyanlarin, istege bagli ek bir yardimci pestisitin ve yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin, türevlerinin veya tuzlarinin bir karisiminin harmanlanmasi; burada söz konusu harman, homojen bir karisim olusturmak için bir karisimda agirlik olarak %15'ten fazla olmayan yüksek moleküler agirlikli bir kondensat içerir. b) bir seyreltici ile karisim bulamacinin hazirlanmasi ve c) bilesimi elde etmeye yönelik granülasyonun ardindan bulamacin yas ögütülmesi. Bir uygulama örneginde bulamaç hazirlama islemi sinirli degildir. Diger bir uygulama örneginde seyreltici sudur. Bir uygulama örneginde ögütme ve granülasyon sinirli degildir. Uygun granülasyon islemleri, örnegin püskürtmeli kurutma, akiskan yatakli granülasyon, aglomerasyon, tavada granülasyon ve ekstrüzyon ile granülasyon gibi granülasyon teknolojisinde açiklanan tüm geleneksel islemlerdir. Mevcut bulusa uygun stabil fungisidal bilesimler istege bagli olarak diger agrokimyasal olarak kabul edilebilir eksipiyanlari içerebilir. Örnekler arasinda dispersiyon ajanlari, islatici ajanlar, emülsiyonlastiricilar, süspansiyon ajanlari, köpük önleyiciler, penetranlar, gübreler, reoloji degistiriciler veya kivamlastiricilar, inertler ve bunlarin kombinasyonlari gibi yüzey aktif maddeler bulunmaktadir. Bir uygulama örneginde uygun yüzey aktif maddeler, tüm yaygin anyonik maddeleri ve iyonik olmayan maddeleri kapsamaktadir. Bir uygulama örneginde uygun yüzey aktif maddeler, bunlarla sinirli olmamak üzere, etoksillenmis nonilfenoller, lineer veya dalli alkollerin polialkilen glikoleterleri, alkil fenollerin etilen oksit ve/veya propilen oksit ile reaksiyon ürünleri, yag asidi aminlerinin etilen oksit ve/veya ile reaksiyon ürünleri ve/veya propilen oksit, ayrica yag asidi esterleri, alkil sülfonatlar, alkil sülfatlar, alkil etersülfatlar, alkil eterfosfatlar, ariIsüIfat, etoksillenmis ariIaIkiIfenoIIer, ör. tristiril-fenol-etoksilatlar, ayrica sülfatlanmis veya fosfatlanmis arilalkilfenol-etoksilatlar ve -etoksi- ve propoksilatlar gibi etoksillenmis ve propoksillenmis ariIaIkiIfenoIIer, Iignosülfonatlar, jelatin, arap zamki, fosfolipitler, nisasta, hidrofobik modifiye nisasta ve selüloz türevleri, özellikle selüloz ester ve selüloz eter, ayrica polivinil alkol, polivinil asetat, polivinil pirolidon, poliakrilik asit, polimetakrilik asit ve (met)akrilik asit ve (met)akrilik asit esterlerinin kopolimerizatlari ve metakrilik asit ve metakrilik asit esterlerinin diger kopolimerizatlari ve uzun zincirli yag asitlerinin mono alkil esterleri arasindan seçilmistir. Yag asitlerinin esterleri, yaklasik 10 ila yaklasik 24 karbon atomu içeren doymus veya doymamis asitlerden seçilen bir veya daha fazla asit içerir. Yag asitlerinin uygun esterleri, yaklasik 1 ila yaklasik 8 karbon atomuna sahip dogrusal veya dalli mono veya polihidrik alkollere sahip olanlardir. Bir düzenlemede uygun yüzey aktif maddeler Iignosülfonatlar, aril, alkil veya ariIaIkil sülfonatlar ve aromatik sülfonik asit kondensatlari gibi polimer kondensatlari arasindan seçilmistir. Bir uygulama örneginde, mevcut bulusa uygun bilesim ayrica seker, lignin ve bunlarin türevleri, polivinil pirolidon, nisasta, ksantan zamki gibi dogal zamk, guar zamki, karboksi metil selüloz ve bunlarin türevleri gibi yapiskan ve baglayici maddeler, çökeltilmis silika, pH degistiriciler, süspanse edici maddeler, sprey damlacik degistiriciler, pigmentler, antioksidanlar, UV koruyucular, uyumlastirici ajanlar, köpük önleyici maddeler, ayirma maddeleri, nötralize edici maddeler, korozyon önleyiciler, boyalar, koku vericiler, mikro besinler, yumusaticilar, yaglayicilar ve benzerlerini içermektedir. Mevcut bulus ayrica, istenmeyen zararlilari kontrol etmeye yönelik bir yöntem sunar; söz konusu yöntem, mevcut bulusa göre etkili miktarda stabil fungusit bilesimin zararlilara veya habitatlarina uygulanmasini içerir. Bir uygulama örneginde, mevcut bulusa uygun stabil bilesimler fungusit olarak kullanilmistir. Bir uygulama örneginde, mevcut bulusa uygun formülasyonlar bitkiler, bitki parçalari, tohumlar, fideler veya toprak üzerinde hasere kontrolü için kullanilabilmektedir. Bir baska uygulama örneginde, istenmeyen mantarlarin kontrol altina alinmasina yönelik bir yöntem sunulmustur; söz konusu yöntem bir azol fungisit, bir ditiyokarbamat ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesimin uygulanmasindan ibarettir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Bir baska uygulama örneginde, istenmeyen mantarlarin kontrol altina alinmasina yönelik bir yöntem sunulmustur; söz konusu yöntem bir azol fungisit, bir ditiyokarbamat, en az bir yardimci pestisit ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesimin uygulanmasindan ibarettir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Bir uygulama örneginde, azol fungisit protiokonazoldür. Bir uygulama örneginde, ditiyokarbamat fungisit mancozebdir. Bir uygulama örneginde yardimci pestisit baska bir fungisittir. Bir uygulama örneginde yardimci pestisit bir strobilurin fungisittir. Bir uygulama örneginde strobilurin fungisit azoksistrobin, trifloksistrobin veya fluoksastrobin arasindan seçilmistir Bir baska uygulama örneginde, istenmeyen mantarlarin kontrol altina alinmasina yönelik bir yöntem sunulmustur; söz konusu yöntem bir azol fungisit, bir ditiyokarbamat, en az bir strobilurin fungisit ile yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin ve bunlarin türevleri ve tuzlarindan olusan karisimi içeren stabil bir fungisidal bilesimin uygulanmasindan ibarettir; burada söz konusu karisim, agirlik olarak en fazla %15 olan yüksek moleküler agirlikli bir kondensat ihtiva eder. Mevcut bulus asagidaki örneklerle daha spesifik olarak açiklanmistir. Ancak, mevcut bulusun kapsaminin hiçbir sekilde bu örneklerle sinirli olmadigi anlasilmalidir. Mevcut bulusun verilen örnekleri içerdigi ve ayrica bulusun kapsamina dahil edilmesi amaçlanan bulusun yeni ögretilerinden ve avantajlarindan ayrilmadan degistirilebilecegi bu konuda uzman herhangi bir kisi tarafindan takdir edilecektir. Örnekler: Mevcut bulusa uygun protiokonazol ve mancozeb içeren bir bilesim asagidaki gibi hazirlanir: Içerik maddeleri Miktar (%agirlik/agirlik) Mancozeb (Saflik %86) 70,90 Protiokonazol (Saflik %98) 05,40 lignosülfonat 16,20 Yüksek ve düsük moleküler agirliga sahip 7,00 formaldehit-aromatik sülfonik asit kondensati karisimi köpük önleyici 0,50 Toplam 100,00 Islem: Tüm bilesenlerin önceden tartilmis miktarlari, homojen bir karisim olusturmak üzere bir karisim içinde harmanlanmistir. Karisima ait bir bulamaç 50 kisim su ile yapilmistir. Bulamacin islak ögütülmesi boncuk degirmeninde gerçeklestirildi ve ardindan granülasyon yapildi. Granüller, nem içerigi %2lnin altina ininceye kadar kurutuldu. Mevcut bulusa uygun protiokonazol, mancozeb ve azoksistrobin içeren bir bilesim asagidaki gibi hazirlanir: Içerik maddeleri Miktar (%agirlik/agirlik) Mancozeb 61,63 Azoksistrobin 4,28 Protiokonazol 4,18 Sodyum Lauril sülfat 22,41 Yüksek ve düsük moleküler agirliga sahip 6,00 formaldehit-aromatik sülfonik asit kondensati karisimi köpük önleyici 1,50 Toplam 100,00 Bilesim, örnek 1 için verilmis olan prosesle hazirlandi. Karsilastirmali Örnek: Protiokonazol ve mancozeb içeren bir bilesim asagidaki gibi hazirlanir: Içerik maddeleri Miktar (%agirlik/agirlik) Mancozeb (Saflik %86) 70,90 Protiokonazol (Saflik %98) 05,40 lignosülfonat 16,20 formaldehit-aromatik sülfonik asit 7,00 kondensah köpük önleyici 0,50 Toplam 100,00 Bilesim, örnek 1 için verilmis olan prosesle hazirlandi. Karsilastirmali Örnek: Protiokonazol, mancozeb ve azoksistrobin asagidaki gibi hazirlanir: içeren bir bilesim Içerik maddeleri Miktar (%agirlik/agirlik) Mancozeb 61,62 Azoksistrobin 4,10 Protiokonazol 4,10 formaldehit-aromatik sülfonik asit 6,00 kondensah köpük önleyici 2,00 Toplam 100,00 Bilesim, örnek 1 için verilmis olan prosesle hazirlandi. Mevcut bulusa uygun protiokonazol, mancozeb ve trifloksistrobin içeren bir bilesim asagidaki gibi hazirlanir: Seri Içerik maddesi Yüzde 1 Mancozeb 62,2 2 Protiokonazol 4,60 3 Trifloksistrobin 3,80 4 Iignosülfonat 12,0 Sodyum lauril sülfat 3,50 6 Yüksek ve düsük moleküler agirliga sahip formaldehit- 5,00 aromatik sülfonik asit kondensati karisimi Ksilen sülfonatin sodyum tuzu %40 6,00 köpük önleyici 1,50 Çökertilmis Silika 1,50 Mevcut bulusa uygun bir bilesimin fiziksel parametrelerinin incelenmesi Örnek 1 ve 2lde hazirlanan bilesimin fiziksel parametreleri test edildi ve Örnek 3 ve 4le ait karsilastirmali bir formülasyon ile karsilastirildi. Örnek 3 ve 4, yüksek moleküler agirlikta kondensat içermeyen formaldehit-aromatik sülfonik asit kondensati kullanilarak hazirlandi. Örnekler hazirlandi ve 14 gün ve 28 gün boyunca ortam sicakliginda ve 54 °C'de muhafaza edildi (hizlandirilmis isi stabilite testi). Kaydedilen veriler asagidaki tablolarda (Tablo 1-3) yer almaktadir. Fiziko-kimyasal Ortam 14 gün AHS 28 gün AHS Parametreler Mancozeb aktif içerigi Protiokonazol aktif içerigi 5,06 5,03 4,95 Süspansiyon Kabiliyeti 92,8 89,9 86,0 (Gravimetrik) We Elek % a/a Alikoyma Sifir Sifir Sifir Muhafaza AHSlde AHSlde edilen muhafaza muhafaza Gözlem "KW" . ?diev ?di'ev suspansiyon urunun urunun kabiliyeti süspansiyon süspansiyon kabiliyeti kabiliyeti Örnek 3 (karsilastirma) Fiziko-kimyasal Ortam 14 gün AHS 28 gün AHS Parametreler Mancozeb aktif içerigi Protiokonazol aktif içerigi 5,15 5,02 4,98 (Gravimetrik) We Elek % a/a Alikoyma Sifir Sifir Sifir Muhafaza AHSlye AHSlye edilen damlatilan damlatilan Fiziko-kimyasal Ortam 14 gün AHS 28 gün AHS Parametreler Azoksistrobin aktif içerigi 4,03 3,9 3,8 Protiokonazol aktif içerigi 3,89 3,76 3,76 Süspansiyon Kabiliyeti 91,26 90,5 We Elek % a/a AIikoyma 0,10 0,11 0,12 cinsinden) Muhafaza AHSlde AHSlde edilen muhafaza muhafaza suspansiyon urunun urunun kabiliyeti süspansiyon süspansiyon kabiliyeti kabiliyeti Örnek 4 (karsilastirma) Fiziko-kimyasal Ortam 14 gün AHS 28 gün AHS Parametreler Azoksistrobin aktif içerigi 4,10 4,02 4,0 Protiokonazol aktif içerigi 3,95 3,85 3,80 Süspansiyon Kabiliyeti 79,20 64,0 We Elek % a/a AIikoyma 0,15 0,20 0,22 Kalici Köpük (ml 50 52 56 cinsinden) AHSlye AHSlye damlatilanin damlatilanin .. süspansiyon süspansiyon GOZ'em kabiliyeti kabiliyeti Fiziko-kimyasal Ortam 14 gün AHS 28 gün AHS Parametreler Trifloksistrobin aktif 3,75 3,71 3,72 içerigi (%a/a) Protiokonazol aktif içerigi 4,35 4,32 4,31 Süspansiyon Kabiliyeti 91,4 88,0 We Elek % a/a AIikoyma 0,17 0,2 0,25 cinsinden) Muhafaza AHSlde AHSlde edilen muhafaza muhafaza Gözlem ürünün edilen edilen süspansiyon ürünün ürünün kabiliyeti süspansiyon süspansiyon kabiliyeti kabiliyeti Mevcut bulusa uygun bilesimler ile stabil formülasyonlarin elde edildigi gözlemlendi. Yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin bir karisimini içermeyen karsilastirma formülasyonu, süspansiyon kabiliyeti yönünden bir düsüs yasarken, formülasyonun süspansiyon kabiliyetinin sabit oldugu gözlemlendi. Bu sonuç, yüksek ve düsük molekül agirlikli polimer bilesenlerinden olusan bir karisim içermeyen bir polimer kondensat yerine bir karisim kullanmanin avantajini göstermektedir. Ayrica, karsilastirmali formülasyonun çok fazla miktarda köpük olusumuna yol açtigi kaydedildi. Saha deneyi: Bulusa uygun bilesimlerin (Örnek 2) Kahverengi hardalda (Brassica juncea) görülen Külleme hastaligina (Erysiphe cruciferarum) karsi etkililigi üzerindeki etkisini incelemek için bir saha deneyi yapildi. Gözlemleri karsilastirmak için Örnek 3 uyarinca bir karsilastirma formülasyonu da test edildi. Deneye ait ayrintilar ve sonuçlar asagida özetlenmistir: Matemal ve metodolo'ii: Sr. No. Özel Ayrintilar 1 Mahsul Hardal 2 Ekim tarihi 5 Kasim 3 Tedavi uygulama 8 Aralik 4 Arazi büyüklügü 12 m2 (6 m X 2 m) Deneysel Tasarim CRD 6 Tedavi Sayisi 3 (Üç) 7 Replikasyon Sayisi 3 (Üç) 8 Kullanilan Püskürteç Kullanilan Batarya Knapsack 9 Nozul Tipi Bos Koni Islem bilgileri: Islem No. Numune Formülasyon Dozu Uygulama saati T1 Örnek 3 1,5 Kg/ha Profilaktik olarak DAS T2 Örnek 2 1,5 kg/ha Profilaktik olarak DAS T3 Islemden -NA- -NA- Geçmemis Kontrol Gözlemler: 1) Hastaligin Siddeti %: Hastalik Yüzdesine iliskin Gözlem Hastaligin yapraklar üzerinde siddetli oldugu kaydedildi. Her arazide toplam 100 yaprak (rastgele seçilen 20 Bitki X her bitkinin 5 yapragi), Conn ve ark.'nin revize edilmis derecelendirme ölçegi kullanilarak hastalik altindaki enfekte alan yüzdesi olarak külleme bakimindan gözlendi. Külleme reaksiyonunu derecelendirmek için ölçeklendirin (0-9): Sinif/Ölçek Ayrintilar 0 Lezyon yok 1 Sporlanma olmayan nokta boyutu veya küçük kahverengi nekrotik benekler, %5'ten daha az yaprak alani lezyonlarla kaplidir 3 Belirgin bir kenar veya sari haleye sahip, yaklasik 1-2 mm çapinda küçük yuvarlak hafif sporlu daha büyük kahverengi nekrotik benekler, %5-10 yaprak alani lezyonlarla kaplidir Belirgin bir kenar veya sari haleye sahip, yaklasik 2-4 mm çapinda orta derecede sporlu, birlesmeyen daha büyük kahverengi benekler %11-25 yaprak alani lezyonlarla kaplidir 7 Yaklasik 4-5 mm çapinda orta derecede sporlu, birlesen daha büyük kahverengi benekler, %26-50 yaprak alani lezyonlarla kaplidir 9 Bol sporlu, hizla birlesen, %50'den fazla yaprak alanini kaplayan kenar bosluklari olmaksizin, çapi 6 mm'den fazla olan kahverengi ila siyah benekler Yüzde olarak tüm veriler, ark-sin dönüsümünden sonra ve ortalama Kritik Farkin (C.D.) hem gerçek hem de dönüstürülmüs degeri 0,05 anlamlilik düzeyinde analiz Gözlemler: Tablo: 01: Farkli islemlerin Hardalda görülen Külleme üzerindeki etkisi Islem No % Hastaligin T1 16,56 (8,31) T2 9,11 (2,64) T3 24,37 (17,16) Parantez içindeki rakamlar orijinal degerlerdir, CD: Kritik Fark Iki tedavi arasinda T2lde hastalik siddeti 9,11 olarak kaydedilmis olup, bu rakam T1lden (16,56) anlamli ölçüde daha düsüktür. Bu, T2'nin diger tedavilerden daha etkili bir sekilde kontrol altina alinan külleme hasarina sahip oldugunu açikça gösterdi. Böylece, mevcut bulusa uygun bilesimlerin, gerekli fungisidal aktiviteyi saglama hususunda etkili oldugu kanitlandi. Yüksek ve düsük moleküler agirlikli formaldehit-aromatik sülfonik asit kondensatinin bir karisimini içermeyen bilesimin, kabul edilebilir bir fungisidal aktivite yönünden etkisiz oldugu bulundu. TR TR TR DESCRIPTION COMPOSITIONS CONTAINING STABLE FUNGICIDAL COMPOUNDS Technical field of the invention The present invention provides stable fungicidal compositions. The present invention relates to stable fungicidal compositions comprising a mixture of azole fungicides, dithiocarbamates and high and low molecular weight formaldehyde-aromatic sulfonic acid condensates. Background of the invention Fungi are one of the leading causes of crop loss worldwide, and fungicides are therefore considered an important class of pesticides. Fungicides are pesticides that kill or prevent the growth of fungi and their spores. Fungicides are specific types of pesticides commonly used to control fungal diseases by inhibiting or killing the disease-causing fungus. They can be used to control rust, powdery mildew and blight. While fungicides work in a variety of ways depending on their mode of action, most damage fungal cell membranes or interfere with energy production within fungal cells. Different classes of fungicides have been successful in controlling most major diseases in growing crops. Inorganic complex compounds such as dithiocarbamates are one of the earliest chemicals developed for the control of fungal diseases. These chemicals affect various biochemical processes in the fungus and are therefore called multisite fungicides. However, the chemicals in question are contact-acting and non-systemic fungicides. They only protect the cultivated plant from disease infection. Systemic fungicides have been developed since the 1960s and have been widely used ever since. Although most such chemicals are therapeutic and destructive, they are site specific and affect only a single biochemical pathway. The combination of such a multisite fungicide and a systemic fungicide is a widely acceptable method of adequately controlling various fungicidal diseases, considering the resistance developed by some fungi to these single-site fungicides over a period of time. It is well known that to elicit the maximum effectiveness of fungicidal chemicals, they must be formulated with agrochemically acceptable excipients. In addition to increasing the activity of fungicides, these excipients also change the physical properties of the formulated products. Formulating a product containing 2 or more active ingredients is truly challenging due to the difficulty of foreseeing problems such as compatibility and stability of the formulated product. Strobilurins are a group of chemical compounds used as fungicides in agriculture. They are part of the larger group of Qol inhibitors that act to inhibit the respiratory chain at the Complex III level. Strobilurins are mostly contact fungicides with a long half-life because they are absorbed into the cuticle and are not transported further. A commonly used strobilurin fungicide is Azoxystrobin. It is a fungicide with protective, therapeutic, destructive, translaminar and systemic properties. Azoxystrobin controls the following pathogens at application rates of 100 - 375 g/ha: Erysiphe graminis, Puccinia spp., Leptosphaeria nodorum, Septoria tritici and Pyrenophora teres in grains found in temperate climates; Pyricularia oryzae and Rhizoctonia solani in rice; Plasmopara viticola and Uncinula necator in the bag; Sphaerotheca fuliginea and Pseudoperonospora cubensis in cucurbits; Phytophthora infestans and Alternaria solani on potatoes and tomatoes; Mycosphaerella arachidis, Rhizoctonia solani and Sclerotium rolfsii in peanuts, Cladosporium carpophilum in peaches, Pythium spp in grass. and Rhizoctonia solani; Mycosphaerella spp in banana; Cladosporium caryigenum in pecans; in citrus fruits, Elsinoe fawcettii, Colletotrichum spp. and Guignardia citricarpa; Colletotrichum spp. in coffee. and Hemileia vastatrix. Conazole fungicides represent a large group of compounds widely used in agriculture for the protection of cultivated plants. Prothioconazole is a conazole fungicide and is a systemic fungicide with protective, therapeutic, destructive and long-term effects. Prothioconazole is used in wheat, barley and other crops by foliar application against eyespot (Pseudocercosporella herpotrichoides), Fusarium early leaf blight (Fusarium spp., Microdochium nivale), leaf rust diseases (Septoria tritici, Leptosphaeria nodorum, Pyrenophora spp., Rhynchosporium secalis, etc.). ), is used to control diseases such as rust (Puccinia spp.) and powdery mildew (Blumeria graminis). As seed treatment, Ustilago spp., Tilletia spp., Fusarium spp. and is used to control Microdochium nivalel. Mancozeb is a broad-spectrum, non-systemic fungicide with a protective effect. Mancozeb, a wide variety of field crops, fruits, nuts, vegetables, ornamental plants, etc. It is used to control many common fungal diseases. More frequent uses are for early and late blights on potatoes and tomatoes (Phytophthora infestans and Alternaria solani); bag downy mildew (Plasmopara viticola) and black root rot (Guignardia bidwellii); cucurbit downy mildew (Pseudoperonospora cubensis); apple scab (Venturia inaequalis); It includes controlling banana leaf spot (Mycosphaerella spp.) and citrus melanosis (Diaporthe citri). The inventors of the present invention noted physical incompatibility when formulating a mixture of an azole fungicide and other active ingredients. These azole fungicides have proven to be difficult molecules to formulate. Physical incompatibility results in lump or gel formation. Active ingredients do not disperse uniformly and precipitate in suspension. Such formulations suffer a decrease in suspension and therefore lead to poor performance. Incompatibility can also cause foam formation, tank stratification and color changes. The present invention aims to eliminate the above-mentioned complications and provide stable and effective formulations of azole fungicide with dithiocarbamate fungicides and other active ingredients. Objects of the present invention It is an object of the present invention to provide a stable fungicidal composition containing azole fungicide. Another object of the present invention is to provide a stable fungicidal composition containing an azole fungicide, a dithiocarbamate, and at least one auxiliary pesticide. Another object of the present invention is to provide a method for controlling unwanted pests; The method includes applying an effective amount of a stable fungicidal composition according to the present invention to the pests or their habitats. Summary of the present invention The present invention provides a stable fungicidal composition comprising an azole fungicide, a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensates and their derivatives and salts. The present invention provides a stable fungicidal composition comprising an azole fungicide and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensates and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. The present invention provides a stable fungicidal composition comprising an azole fungicide, a dithiocarbamate, a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensates and their derivatives and salts. The present invention provides a stable fungicidal composition comprising an azole fungicide, a dithiocarbamate and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensates and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. Compositions according to the present invention further contain at least one auxiliary pesticide. Compositions according to the present invention further contain at least one strobilurin fungicide. The present invention also provides a method for controlling unwanted pests; The method includes applying an effective amount of a stable fungicidal composition according to the present invention to the pests or their habitats. Detailed description: Azole fungicides are a class of fungicides that are difficult to formulate. It has been found by the present inventors that stable compositions of azole compounds can be prepared in the presence of a surfactant that is a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensates, derivatives or salts. There are many known surfactants in the class of formaldehyde-aromatic sulfonic acid condensates, derivatives or salts. However, not all of them are a mixture of high and low molecular weight condensates and therefore not all of these surfactants provide stable compositions containing azole fungicides. It was found that stable azole fungicide compositions could be prepared only in the presence of formaldehyde-aromatic sulfonic acid condensates, derivatives or salts, which are a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensates. More preferably, stable compositions are prepared in which the mixture contains a high molecular weight condensate of at most 15% by weight. It was also found that in the absence of formaldehyde-aromatic sulfonic acid condensate surfactant, a mixture of high and low molecular weight condensates, their derivatives or salts, such stable compositions cannot be prepared. Accordingly, the present invention provides stable compositions comprising an azole fungicide alone or in combination with other active ingredients. The inventors of the present invention observed the physical variability that occurred during the formulation development of azoles in various formulation types. Surprisingly, the inventors of the present invention have developed stable formulations or compositions containing azole fungicides using a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate, derivatives or salts. Therefore, the present invention provides a stable fungicidal composition comprising an azole fungicide, a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensates and their derivatives and salts. The present invention provides a stable fungicidal composition comprising an azole fungicide and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. The present invention provides a stable fungicidal composition comprising a mixture of an azole fungicide, a dithiocarbamate, high and low molecular weight formaldehyde-aromatic sulfonic acid condensate, and their derivatives and salts. The present invention provides a stable fungicidal composition comprising a mixture of an azole fungicide, a dithiocarbamate and high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. The present invention provides a stable fungicidal composition comprising a mixture of an azole fungicide, a dithiocarbamate and high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. In reference to the present invention, the term "high molecular weight condensate" refers to a polymer condensate with a numbered average molecular weight of more than 5000. Specifically, the numbered average molecular weight refers to a range from 5000 to 50,000. In reference to the present invention, the term "low molecular weight condensate" refers to a polymer condensate with a numbered average molecular weight of 5,000 or less. In particular, the numbered average molecular weight refers to a range from 5000 to 500. In relation to the present invention, the term "high and low molecular weight condensate mixture" refers to a polymer condensate with a percentage of condensate whose molecular weight is more than 5000 and not more than 15% by weight of all condensates. In relation to the present invention, "high and low The term "molecular weight condensate mixture" refers to a polymer condensate with a percentage of condensate having a molecular weight of 5,000 or less and not more than 90% by weight of all condensates. In relation to the present invention, the term "high and low molecular weight condensate mixture" refers to low and refers to a polymer condensate that is a mixture of high molecular weight condensate; where the molecular weight of the major component up to approximately 90% of the mixture is below 5000 and the molecular weight of the minor component up to approximately 15% of the mixture is above 5000. In an embodiment, the composition contains a mixture of high and low molecular weight condensate in an amount of about 0.01% to about 30% by weight of the formulation. Preferably, the composition contains a mixture of high and low molecular weight condensate in an amount of about 1% to about 20% by weight of the formulation. In an embodiment of the present invention, an azole fungicide provides a stable fungicidal composition comprising a mixture of a dithiocarbamate and a high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. In an application example, azole fungicide; Pyrazole carboxamide fungicide, benzimidazole fungicide, benzothiazole fungicides were selected from the group, and conazole fungicides were selected from the group consisting of imidazoles, triazoles and oxazole fungicides. In a preferred embodiment, the azole fungicide is selected from conazole fungicides. In an application example, conazole fungicide; Azaconazole, Bromukonazole, Siproconazole, Dichlobutrazole, Difenoconazole, Diniconazole, Dinicone Azol-M, Epoxyconazole, Etaconazole, Fenbukonazole, Flucinkonazole, Flushasol, Flutriafol, Furkonazole, Furkonazole-Cis, Hekzakonase Azol, ipntrifluconazole, mefentrifluconazole, metkonazole, miclobütanil, penconazole was chosen from propiconazole, fluconazole, protioconazole, quinconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole, uniconazole and uniconazole-P. In one embodiment, the preferred conazole fungicide is prothioconazole. In an embodiment, the composition contains prothioconazole in an amount of between about 0.01% and about 50% by weight of the composition. In another application example, the dithiocarbamate fungicide amobam, asomate, azithiram, carbamorph, kufraneb, kuprobam, disulfiram, ferbam metam, nabam, tekoram, thiram, urbasit, ziram, dazomet, etem, milneb, mancopper, mancozeb, maneb, metiram, polycarbamate, propineb. He was chosen from among the vezineb. In an application example, the preferred dithiocarbamate fungicide was chosen among ziram, mancopper, mancozeb, maneb, metiram, polycarbamate, propineb and vezineb. In one embodiment, the preferred dithiocarbamate fungicide is mancozeb. In one embodiment, the composition contains mancozeb in an amount between about 10% and about 99% by weight of the composition. In a preferred embodiment, the composition contains mancozeb in an amount of between about 30% and about 90% by weight of the composition. In an embodiment, the present invention provides a composition comprising prothioconazole, mancozeb and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. In one embodiment, the fungicidal compositions according to the present invention further comprise at least one. Therefore, in one embodiment, the present invention consists of an azole fungicide, a dithiocarbamate, at least one auxiliary pesticide and high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts. It provides a stable fungicidal composition containing the resulting mixture; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. In one embodiment, the auxiliary pesticide is selected from, but not limited to, herbicide, insecticide, insect growth regulator, nematicide, termiticide, molluscicide, bactericide, insect repellent, animal repellent, antimicrobial, fungicide, disinfectant, and sanitizer. In a preferred embodiment, the co-pesticide is a fungicide. In one embodiment, the co-pesticide is the fungicide selected from, but not limited to, demethylation inhibitor, quinone external inhibitor, succinate dehydrogenase inhibitor, and quinone internal inhibitor. In another embodiment, the co-pesticide is a quinone external inhibitor. In another application example, the quinone external inhibitor was selected from strobilurin fungicides. Therefore, in an embodiment, the present invention provides a stable fungicidal composition comprising a mixture of an azole fungicide, a dithiocarbamate strobilurin fungicide and a high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. In an embodiment, the strobilurin fungicide is selected from, but not limited to, Azoxystrobin, kresoxim-methyl, picoxystrobin, pyraclostrobin, fluoxastrobin and trifloxystrobin. In an embodiment, the preferred strobilurin fungicide is selected from azoxystrobin, trifloxystrobin and pyraclostrobin. In one embodiment, the composition contains strobilurin fungicide in an amount of between about 0.01% and about 30% by weight of the composition. In a preferred embodiment, the composition contains strobilurin fungicide in an amount of between about 1% and about 20% by weight of the composition. In an embodiment, the present invention provides a composition comprising prothioconazole, mancozeb, trifloxystrobin and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. In an embodiment, the present invention provides a composition comprising prothioconazole, mancozeb, azoxystrobin and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. Compositions according to the present invention may be formulated as emulsion concentrates, wettable powders, water-dispersible granules, suspension concentrate, microemulsion, capsule suspensions, granules, and the like. In an embodiment, the compositions according to the present invention can be formulated as solid compositions. The processes for preparing solid compositions according to the invention are not limited. In an embodiment, solid compositions according to the present invention are prepared as follows: a) blending an azole fungicide, optionally other excipients and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate, derivatives or salts thereof; wherein said blend contains not more than 15% by weight of a high molecular weight condensate in a mixture to form a homogeneous mixture. b) preparation of the mixture slurry with a diluent and c) wet milling of the slurry followed by granulation to obtain the composition. In an embodiment, solid compositions according to the present invention are prepared as follows: a) An azole fungicide, optionally other excipients, optionally an additional aid blending a mixture of the pesticide and high and low molecular weight formaldehyde-aromatic sulfonic acid condensate, derivatives or salts thereof; wherein said blend contains not more than 15% by weight of a high molecular weight condensate in a mixture to form a homogeneous mixture. b) preparation of the mixture slurry with a diluent and c) wet milling of the slurry d) granulation to obtain the composition followed by an optional additional In an embodiment, the solid compositions according to the present invention are prepared as follows: a) An azole fungicide, a dithiocarbamate fungicide, optionally blending other excipients, an optional additional auxiliary pesticide, and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate, derivatives or salts thereof; wherein said blend contains not more than 15% by weight of a high molecular weight condensate in a mixture to form a homogeneous mixture. b) preparing the mixture slurry with a diluent and c) wet milling the slurry followed by granulation to obtain the composition. In an embodiment, the slurry preparation process is not limited. In another application example, the diluent is water. In an embodiment, grinding and granulation are not limited. Suitable granulation processes are all conventional processes described in granulation technology, such as spray drying, fluidized bed granulation, agglomeration, pan granulation and granulation by extrusion. The stable fungicidal compositions according to the present invention may optionally contain other agrochemically acceptable excipients. Examples include surfactants such as dispersing agents, wetting agents, emulsifiers, suspending agents, antifoams, penetrants, fertilizers, rheology modifiers or thickeners, inerts, and combinations thereof. In an embodiment, suitable surfactants include all common anionic substances and nonionic substances. Suitable surfactants in an embodiment include, but are not limited to, ethoxylated nonylphenols, polyalkylene glycol ethers of linear or branched alcohols, reaction products of alkyl phenols with ethylene oxide and/or propylene oxide, reaction products of fatty acid amines with ethylene oxide and/or propylene oxide, also fatty acid esters, alkyl sulfonates, alkyl sulphates, alkyl ethersulphates, alkyl etherphosphates, arylsulphate, ethoxylated arylcylphenols, e.g. tristyryl-phenol-ethoxylates, as well as ethoxylated and propoxylated arylalphenols such as sulfated or phosphatized arylalkylphenol-ethoxylates and -ethoxy- and propoxylates, ignosulfonates, gelatin, gum arabic, phospholipids, starch, hydrophobic modified starch and cellulose derivatives, especially cellulose esters and cellulose ether, It was also selected among polyvinyl alcohol, polyvinyl acetate, polyvinyl pyrrolidone, polyacrylic acid, polymethacrylic acid and copolymers of (meth)acrylic acid and (meth)acrylic acid esters and other copolymers of methacrylic acid and methacrylic acid esters and mono alkyl esters of long chain fatty acids. Esters of fatty acids contain one or more acids selected from saturated or unsaturated acids containing from about 10 to about 24 carbon atoms. Suitable esters of fatty acids are those having linear or branched mono or polyhydric alcohols having from about 1 to about 8 carbon atoms. In one embodiment, suitable surfactants are selected from polymer condensates such as lignosulfonates, aryl, alkyl or arylalkyl sulfonates, and aromatic sulfonic acid condensates. In an embodiment, the composition according to the present invention also includes sugar, lignin and its derivatives, polyvinyl pyrrolidone, starch, natural gums such as xanthan gum, adhesive and binding substances such as guar gum, carboxy methyl cellulose and their derivatives, precipitated silica, pH modifiers, suspending agents. substances include spray droplet modifiers, pigments, antioxidants, UV protectors, compatibilizing agents, antifoaming agents, release agents, neutralizing agents, corrosion inhibitors, dyes, fragrances, micronutrients, softeners, lubricants and the like. The present invention also provides a method for controlling unwanted pests; The method includes applying an effective amount of a stable fungicidal composition according to the present invention to the pests or their habitats. In an embodiment, stable compositions according to the present invention are used as fungicides. In an embodiment, formulations according to the present invention can be used for pest control on plants, plant parts, seeds, seedlings or soil. In another application example, a method for controlling unwanted fungi is presented; said method consists in applying a stable fungicidal composition comprising an azole fungicide, a dithiocarbamate and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. In another application example, a method for controlling unwanted fungi is presented; said method consists of applying a stable fungicidal composition comprising an azole fungicide, a dithiocarbamate, at least one auxiliary pesticide and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. In one embodiment, the azole fungicide is prothioconazole. In one embodiment, the dithiocarbamate fungicide is mancozeb. In one embodiment, the co-pesticide is another fungicide. In one embodiment, the co-pesticide is a strobilurin fungicide. In one embodiment, the strobilurin fungicide is selected from azoxystrobin, trifloxystrobin or fluoxastrobin. In another embodiment, a method for controlling undesirable fungi is provided; said method consists of applying a stable fungicidal composition comprising an azole fungicide, a dithiocarbamate, at least one strobilurin fungicide and a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate and their derivatives and salts; wherein said mixture contains at most 15% by weight of a high molecular weight condensate. The present invention is explained more specifically by the following examples. However, it should be understood that the scope of the present invention is in no way limited to these examples. It will be appreciated by any person skilled in the art that the present invention includes the examples given and may also be modified without departing from the new teachings and advantages of the invention intended to be included within the scope of the invention. Examples: A composition comprising prothioconazole and mancozeb according to the present invention is prepared as follows: Ingredients Amount (% w/w) Mancozeb (Purity 86%) 70.90 Prothioconazole (Purity 98%) 05.40 Lignosulfonate 16.20 High and low molecular weight by weight 7.00 formaldehyde-aromatic sulfonic acid condensate mixture antifoam 0.50 Total 100.00 Process: Pre-weighed quantities of all components are blended in a mixture to form a homogeneous mixture. A slurry of the mixture was made with 50 parts water. Wet grinding of the slurry was carried out in the bead mill followed by granulation. The granules were dried until the moisture content was below 2%. A composition comprising prothioconazole, mancozeb and azoxystrobin according to the present invention is prepared as follows: Ingredients Amount (% weight/weight) Mancozeb 61.63 Azoxystrobin 4.28 Prothioconazole 4.18 Sodium Lauryl sulfate 22.41 High and low molecular weight 6, 00 formaldehyde-aromatic sulfonic acid condensate mixture antifoam 1.50 Total 100.00 The composition was prepared by the process given for example 1. Comparative Example: A composition containing prothioconazole and mancozeb is prepared as follows: Ingredients Amount (% w/w) Mancozeb (Purity 86%) 70.90 Prothioconazole (Purity 98%) 05.40 lignosulfonate 16.20 formaldehyde-aromatic sulphonic acid 7 .00 condensate antifoam 0.50 Total 100.00 The composition was prepared by the process given for example 1. Comparative Example: Prothioconazole, mancozeb and azoxystrobin are prepared as follows: a composition containing Ingredients Amount (%wt/wt) Mancozeb 61.62 Azoxystrobin 4.10 Prothioconazole 4.10 formaldehyde-aromatic sulfonic acid 6.00 condensate antifoam 2.00 Total 100.00 The composition was prepared by the process given for example 1. A composition comprising prothioconazole, mancozeb and trifloxystrobin according to the present invention is prepared as follows: Batch Ingredient 1 Percent Mancozeb 62.2 2 Prothioconazole 4.60 3 Trifloxystrobin 3.80 4 Iignosulfonate 12.0 Sodium lauryl sulfate 3.50 6 High and low molecular weight mixture of formaldehyde- 5.00 aromatic sulphonic acid condensate by weight It was compared with a comparative formulation of Examples 3 and 4. Examples 3 and 4 were prepared using high molecular weight condensate-free formaldehyde-aromatic sulfonic acid condensate. Samples were prepared and stored at ambient temperature and 54 °C for 14 days and 28 days (accelerated heat stability test). The recorded data are included in the tables below (Table 1-3). Physico-chemical Environment 14 days AHS 28 days AHS Parameters Mancozeb active ingredient Prothioconazole active ingredient 5.06 5.03 4.95 Suspension Ability 92.8 89.9 86.0 (Gravimetric) We Sieve % w/w Retention Zero Zero Zero Enclosure AHSlde AHSldered enclosure enclosure Observation "KW". ? Diev ? di'ev suspension product capability suspension suspension capability capability Example 3 (comparison) Physico-chemical Environment 14 days AHS 28 days AHS Parameters Mancozeb active ingredient Prothioconazole active ingredient 5.15 5.02 4.98 (Gravimetric) We Sieve % a/ a Retention Zero Zero Zero Storage AHSlye AHSlyed dripped dripped Physico-chemical Environment 14 days AHS 28 days AHS Parameters Azoxystrobin active content 4.03 3.9 3.8 Prothioconazole active content 3.89 3.76 3.76 Suspension Ability 91, 26 90.5 We Sieve AHS Parameters Azoxystrobin active content 4.10 4.02 4.0 Prothioconazole active content 3.95 3.85 3.80 Suspension Ability 79.20 64.0 We Sieve % w/w Alshetting 0.15 0.20 0.22 Permanent Foam (in ml 50 52 56) AHSlye AHSlye droplet droplet .. suspension suspension EYE ability ability Physico-chemical Environment 14 days AHS 28 days AHS Parameters Trifloxystrobin active 3.75 3.71 3.72 content (%w/w) ) Prothioconazole active content 4.35 4.32 4.31 Suspension Ability 91.4 88.0 We Sieve capability of the product suspension suspension capability capability It was observed that stable formulations were obtained with the compositions in accordance with the present invention. The suspension ability of the formulation was observed to be constant, while the comparison formulation, which did not contain a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate, experienced a decrease in suspension ability. This result demonstrates the advantage of using a mixture of high and low molecular weight polymer components rather than a polymer condensate that does not contain a mixture. It was also noted that the comparative formulation resulted in the formation of too much foam. Field experiment: A field experiment was carried out to examine the effect of the compositions according to the invention (Example 2) on the effectiveness against Powdery Mildew (Erysiphe cruciferarum) on Brown mustard (Brassica juncea). To compare the observations, a comparative formulation according to Example 3 was also tested. Details and results of the experiment are summarized below: Materials and methodology: Sr. No. Special Details 1 Crop Mustard 2 October date 5 November 3 Treatment application 8 December 4 Land size 12 m2 (6 m 9 Nozzle Type Empty Cone Process information: Process No. Sample Formulation Dose Application time T1 Sample 3 1.5 Kg/ha Prophylactically DAS T2 Sample 2 1.5 kg/ha Prophylactically DAS T3 -NA- -NA- Untreated Control Observations: 1) Severity of Disease %: Regarding the Percentage of Disease Observation The disease was noted to be severe on the leaves. A total of 100 leaves in each plot (20 randomly selected Plants Scale to rate powdery mildew reaction (0-9): Class/Scale Details 0 No lesions 1 Non-sporulating spot size or small brown necrotic spots, less than 5% leaf area covered by lesions 3 With a distinct edge or yellow halo, about 1 Larger brown necrotic spots -2 mm in diameter with small round slightly spores, 5-10% leaf area covered by lesions Non-merging larger brown spots with a distinct edge or yellow halo, approximately 2-4 mm in diameter with moderate spores, 11-25% of leaves area covered with lesions 7 Moderately spore-covered, larger brown spots about 4-5 mm in diameter, 26-50% leaf area covered with lesions 9 Abundantly spore-covered, rapidly coalescing, covering more than 50% leaf area without margins, 6 mm in diameter Brown to black spots with more than All data in percentage, after arc-sin transformation and both actual and transformed value of mean Critical Difference (C.D.) analyzed at 0.05 level of significance Observations: Table: 01: Effect of different treatments on Powdery mildew on Mustard Treatment No % Disease T1 16.56 (8.31) T2 9.11 (2.64) T3 24.37 (17.16) Numbers in parentheses are original values, CD: Critical Difference Severity of disease at T2l between two treatments 9.11 It was recorded as , and this figure is significantly lower than T1l (16.56). This clearly showed that T2 controlled powdery mildew damage more effectively than other treatments. Thus, the compositions according to the present invention have proven to be effective in providing the required fungicidal activity. The composition, which did not contain a mixture of high and low molecular weight formaldehyde-aromatic sulfonic acid condensate, was found to be ineffective in terms of acceptable fungicidal activity.TR TR TR
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