TR201802707T4 - Steel plate for the production of lightweight structures and the production method of this plate. - Google Patents
Steel plate for the production of lightweight structures and the production method of this plate. Download PDFInfo
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- TR201802707T4 TR201802707T4 TR2018/02707T TR201802707T TR201802707T4 TR 201802707 T4 TR201802707 T4 TR 201802707T4 TR 2018/02707 T TR2018/02707 T TR 2018/02707T TR 201802707 T TR201802707 T TR 201802707T TR 201802707 T4 TR201802707 T4 TR 201802707T4
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 52
- 239000010959 steel Substances 0.000 title claims abstract description 52
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 230000003014 reinforcing effect Effects 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 230000005496 eutectics Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 claims description 2
- 229910033181 TiB2 Inorganic materials 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000000137 annealing Methods 0.000 claims 6
- 239000011265 semifinished product Substances 0.000 claims 5
- 238000005098 hot rolling Methods 0.000 claims 4
- 238000005097 cold rolling Methods 0.000 claims 3
- 238000005266 casting Methods 0.000 claims 2
- 238000001816 cooling Methods 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 238000003466 welding Methods 0.000 abstract description 3
- 239000002245 particle Substances 0.000 description 14
- 239000000919 ceramic Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 5
- 238000005245 sintering Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006355 external stress Effects 0.000 description 1
- 229910001234 light alloy Inorganic materials 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
- Resistance Welding (AREA)
- Laminated Bodies (AREA)
- Continuous Casting (AREA)
Abstract
Buluş hem içsel hafifleme hem de esneklik katsayısında bir artış bakımından performans seviyesi yükselmiş yapısal parçaların ya da takviye elemanlarının üretilmesini mümkün kılmaktadır. Buluş konusu çelik levhaların kaynak işlemi ile kolayca uygulanması bu levhaların özellikle farklı bileşime ya da kalınlığa sahip çelik parçaların birbirine bağlanması suretiyle daha karmaşık yapılar içerisinde dahil edilmesini mümkün kılmaktadır.The invention makes it possible to produce structural parts or reinforcing elements with increased performance in terms of both internal moderation and an increase in flexibility coefficient. The easy application of the steel sheets according to the invention by welding makes it possible to incorporate these sheets into more complex structures, in particular by connecting steel parts of different composition or thickness to each other.
Description
TARIFNAME Hafif Yapilarin Üretiminde Kullanilmak Üzere Çelik Levha ve Bu Levhanin Üretim Yöntemi Teknik Alan Bulus yüksek bir esneklik katsayisi (E), azaltilmis yogunluk ve yüksek bir dayanim özelliklerini ayni anda sergileyen çelik Ievhalarin ya da yapisal parçalarin üretimi ile Onceki Teknik Yapisal elemanlarin mekanik performanslarinin harici gerilim moduna (örnegin çekme ya da bükülme) ya da elemanlarin (levhalar, çubuklar) geometrisine dayali olarak EX/d (x bir katsayi) seklinde degistigi bilinmektedir. Bu durum yüksek bir esneklik katsayisi ve azaltilmis yogunluk özelliklerini ayni anda sergileyen malzemelere karsi bir ihtiyaci ortaya çikartmaktadir. DESCRIPTION Steel Plate for Use in the Production of Lightweight Structures and Production of This Plate method Technical Area The invention has a high modulus of elasticity (E), reduced density and high strength. with the production of steel sheets or structural parts that simultaneously exhibit Previous Technique The mechanical performance of structural elements depends on the external stress mode (e.g. tensile or or bending) or EX/d (x a coefficient) is known to change. This is a high coefficient of elasticity and revealed a need for materials that simultaneously exhibit reduced density properties. is taking off.
Bu ihtiyaç özellikle araçlarin hafifletilmesi ve güvenlik konularinin sürekli olarak söz konusu olan hususlar oldugu otomotiv endüstrisinde mevcuttur. Bu nedenden dolayi karbürler, nitrürler, oksitler ya da borürler benzeri farkli türlerden seramiklerin parçaciklarinin dahil edilmesi suretiyle çelik parçalarin agirliginin azaltilmasi ve esneklik katsayisinin artirilmasi hedeflenmistir. Gerçekte, bu malzemeler içerisine dahil edildikleri ve 210 GPa mertebesinde esneklik katsayisina sahip olan baz çeliklerin sahip oldugundan daha yüksek olan ve 250 ila 550 GPa araliginda seyreden çok daha yüksek bir esneklik katsayisina sahiptir. Bu sekilde, bir gerilimin etkisi altinda matris ile seramik parçaciklari arasinda bir yük transferi sayesinde bir sertlesme elde edilmektedir. Matrisin tane büyüklügünün seramik parçaciklari ile küçültülmesi de bu sertlesme durumunu artirmaktadir. Bir çelik matris içerisinde yeknesak sekilde dagilmis seramik parçaciklar içeren bu malzemelerin üretilmesi amaciyla toz metalürjisine dayali prosesler bilinmektedir: ilk olarak, kontrollü geometriye sahip seramik tozlar hazirlanir ve bu karisim çelik açisindan seramik parçaciklarin dis kaynakli bir katisina karsilik gelen çelik tozlar ile karistirilmaktadir. Karisimin tamami bir kalip içerisinde sikistirilir ve ardindan bu karisimin sinterlenmesinin gözlemlenecegi bir sicakliga isitilmaktadir. Bu prosesin bir varyantinda, sinterleme asamasi esnasinda seramik parçaciklarin olusmasini saglamak amaciyla metal tozlar karistirilir. Seramik parçacik dagilimina sahip olmayan çelikler ile P424I6527 karsilastirildiginda daha gelismis mekanik özelliklere sahip olmasina ragmen, bu tür bir proses bazi kisitlamalara maruz kalmaktadir: - Metal tozlarinin yüksek spesifik yüzeyi dikkate alindiginda atmosfer ile reaksiyona neden olunmamasi amaciyla bu proses dikkatli gelistirme ve uygulama kosullari gerektirmektedir. This need is especially the case of vehicle mitigation and the constant mention of safety issues. It is available in the automotive industry, where there are issues that are the subject of. For this reason ceramics of different types, such as carbides, nitrides, oxides or borides. weight reduction and flexibility of steel parts by incorporating It is aimed to increase the coefficient. In fact, these materials are included in and base steels with a modulus of elasticity of 210 GPa. much higher than normal and hovering in the range of 250 to 550 GPa has a coefficient of elasticity. In this way, under the action of a stress, the matrix and the ceramic A hardening is achieved by means of a charge transfer between the particles. of the matrix Reducing the grain size with ceramic particles also causes this hardening. is increasing. Uniformly dispersed ceramic particles in a steel matrix Processes based on powder metallurgy to produce these materials containing known: firstly, ceramic powders with controlled geometry are prepared and this steel corresponding to an external welded solid of ceramic particles in terms of a mixture steel mixed with powders. The entire mixture is compressed in a mold and then this It is heated to a temperature at which sintering of the mixture will be observed. This process is a In the variant, to ensure the formation of ceramic particles during the sintering phase. For this purpose, metal powders are mixed. With steels that do not have a ceramic particle distribution P424I6527 Although it has more advanced mechanical properties in comparison, such a The process is subject to some limitations: - Considering the high specific surface of metal powders, it can react with the atmosphere. This process requires careful development and application conditions so as not to cause requires.
-Sikistirma ve Sinterleme islemlerinin gerçeklestirilmesinden sonra dahi döngüsel gerilmeler esnasinda hazirlama sahalari olarak etki etmesi muhtemel kalinti gözeneklerin kalmasi mümkündür. -Cyclic, even after compaction and sintering processes residue likely to act as preparation sites during stresses pores are possible.
- Sinterleme islemi öncesinde tozlarin yüzey kirlenmesi (oksitlerin, karbonun varligi) dikkate alindiginda matris / parçacik arayüzlerinin kimyasal bilesiminin ve dolayisiyla da bunlarin kohezyonunun kontrol edilmesi zordur. - Surface contamination of powders before sintering (presence of oxides, carbon) Considering the chemical composition of matrix/particle interfaces and thus their cohesion is difficult to control.
- Parçaciklarin fazla miktarda ilave edilmesi durumunda ya da belirli büyük parçaciklarin varliginda, uzama özellikleri azalmaktadir. - In case of addition of particles in large quantities or in case of certain large In the presence of particles, the elongation properties are reduced.
- Bu tür bir proses az miktarlarda üretim açisindan uygundur ancak oldukça büyük bir ölçekte otomotiv endüstrisinin ihtiyaçlarini karsilayamamaktadir. - This type of process is suitable for production in small quantities, but requires a fairly large cannot meet the needs of the automotive industry on a large scale.
- Bu tür bir üretim prosesi ile iliskili üretim maliyetleri yüksektir. - The production costs associated with this type of production process are high.
Hafif alasimlar söz konusu oldugunda seramiklerin tozlarinin sivi metal içerisine dis kaynakli olarak ilave edilmesine dayali üretim prosesleri de bilinmektedir. Yine bu prosesler de yukarida bahsi geçen kusurlarin çoguna maruz kalmaktadir. Ama özellikle parçaciklarin homojen dagiliminda zorluklar yasanmaktadir; bu parçaciklar sivi metal içerisinde topaklasma ya da çökelme / y'üzdürme egilimi sergilemektedir. Çeliklerin özelliklerinin artirilmasi amaciyla kullanilabilecek seramikler arasinda asagida belirtilen temel özelliklere sahip olan titanyum diborür (TiBz) özellikle bilinmektedir: Esneklik katsayisi: 565 GPa Yogunluk: 4.52 Ancak, TiBZ parçaciklarin dis kaynakli olarak ilave edilmesine dayali üretim prosesleri de yüksek bir Young modülüne (yüksek esneklik katsayisina (E)) sahip olan ve külçeleme yöntemi kullanilarak üretilebilen yüksek sertlikte bir çelik açiklamaktadir ve özellikle makinenin yapisal bilesenlerini gelistirebilen bir çelik ile ilgilidir. In the case of light alloys, the powders of the ceramics should be embedded in the liquid metal. Production processes based on welded addition are also known. again this processes are also subject to many of the above-mentioned defects. But especially difficulties are experienced in the homogeneous distribution of particles; These particles are liquid metal. It has a tendency to agglomerate or precipitate/float. The following are among the ceramics that can be used to increase the properties of steels. Particularly known is titanium diboride (TiBz), which has the following essential properties: Coefficient of elasticity: 565 GPa Density: 4.52 However, production processes based on the addition of TiBZ particles from external sources are also available. with a high Young's modulus (high modulus of elasticity (E)) and discloses a high hardness steel that can be produced using the relates to a steel that can improve the structural components of the machine.
Bulus yukarida bahsi geçen sorunlarin, özellikle de TIBz parçaciklarin varligi sayesinde daha yüksek esneklik katsayisina sahip çeliklerin büyük ölçekli ve ekonomik olarak temin P424I6527 edilmesi sorunlarinin çözüme ulastirilmasini amaçlamaktadir. Bulus özellikle çeliklerin dökülmesi durumunda belirli zorluklar sergilemeyen bir kesintisiz döküm üretim yöntemi saglanmasini amaçlamaktadir. The invention is due to the existence of the above-mentioned problems, especially TIBz particles. large-scale and economical supply of steels with higher modulus of elasticity P424I6527 aims at solving problems. The invention particularly a continuous casting production method that does not present particular difficulties in case of spillage aims to ensure.
Bulus ayni zamanda muhtemelen matris içerisinde homojen olarak dagilmis daha yüksek miktarda Ti82 parçaciklarina sahip çelikler temin edilmesini de amaçlamaktadir. The invention is also likely to be homogeneously dispersed in the matrix. It also aims to provide steels with Ti82 particles in large quantities.
Bulus ayni zamanda birim uzama degeri %8 oranina esit ya da daha yüksek olan ve direnç kaynagi da dahil olmak üzere farkli kaynak prosesleri açisindan uygunlugu yüksek olan yüksek mukavemetli çelikler saglanmasini amaçlamaktadir. The invention also includes those with elongation values equal to or greater than 8% and highly suitable for different welding processes, including resistance welding It aims to provide high-strength steels with
Bu gayeyle, bulus içerikleri agirlik cinsinden ifade edilen sekilde kimyasal bilesimi: saglayacak miktarlarda titanyum ve bor, opsiyonel olarak Ni s %1, M0 5 %1, Cr S %3, Nbs %01, V 5 %0.1 arasindan seçilen elementlerden birisi ya da birkaçi seklinde olan ve bilesimin geriye kalan kismi demir ve çeligin hazirlanmasindan kaynaklanan kaçinilmaz safsizliklardan meydana gelen bir çelik levha ile ilgilidir. For this purpose, the chemical composition of the invention contents, expressed in weight, is: titanium and boron, optionally Ni s 1%, M0 5 1%, Cr S 3% Nbs 01%, V 5 0.1% in the form of one or more of the selected elements and The remainder of the composition is inevitable from the preparation of iron and steel. It relates to a steel plate composed of impurities.
Tercihen, agirlikça % cinsinden ifade edilen titanyum ve bor içerikleri: -0.22 5 8- (0.45 X Ti) 5 0.35 seklindedir. Preferably, titanium and boron contents, expressed in wt%: -0.22 5 8- (0.45 X Ti) 5 is 0.35.
Bir tercih olarak, agirlikça % cinsinden ifade edilen titanyum ve bor içerikleri: -0.35$B- (0,45x Ti) <- 0,22 seklindedir. As an option, titanium and boron contents, expressed in wt%: -0.35$B- (0.45x Ti) <- 0.22.
Titanyum içerigi tercihen: %4.6 5 Ti S %69 seklindedir. The titanium content is preferably: 4.6% 5% TiS 69%.
Belirli bir uygulamaya göre, titanyum içerigi: %46 S Ti S %6 seklindedir. Karbon içerigi ise tercihen: C 5 %0.080 seklindedir. According to a particular embodiment, the titanium content is: 46% S Ti S 6%. carbon content preferably: C5 is 0.080%.
Tercih edilen bir uygulamada, karbon içerigi: C 5 %0.050 esitligini karsilamaktadir. In a preferred embodiment, the carbon content: C 5 corresponds to 0.050%.
Krom içerigi tercihen: Cr 5 %0.08 seklindedir. Bulus ayni zamanda TIB: bilesiginin ötektik çökeltilerini ve opsiyonel olarak ortalama boyutu 15 mikron degerine esit ya da altinda ve tercihen 10 mikron degerine esit ya da altinda olan FezB bilesigini içeren yukarida belirtilen bilesime sahip bir çelik levha ile ilgilidir. The chromium content is preferably: Cr 5 0.08%. The invention is also known as TIB: compound eutectic precipitates and optionally the average size of 15 microns or below and preferably less than or equal to 10 microns containing the FezB compound relates to a steel plate of the above-mentioned composition.
Tercihen, Ti82 çökeltilerinin sayica %80 oranindan fazlasi tek kristal karakterindedir. Preferably, more than 80% of the Ti82 precipitates are of single crystal character.
P424I6527 Bulus ayni zamanda ortalama tane büyüklügü 15 mikron degerine esit ya da altinda, tercihen 5 mikron degerine esit ya da altinda, en çok tercih edilen sekliyle 3.5 mikrometrenin altinda olan yukarida açiklanan özelliklere sahip bir çelik levha ile ilgilidir. P424I6527 The invention also means that the average grain size is equal to or less than 15 microns. preferably equal to or less than 5 microns, most preferably 3.5 It relates to a steel plate with the properties described above that is sub micrometer.
Bulus ayni zamanda haddeleme yönünde ölçülen esneklik katsayisi 230GPa degerine esit ya da üzerinde olan, tercihen 240GPa degerine esit ya da üzerinde olan ya da tercihen ZSOGPa degerine esit ya da üzerinde olan yukarida açiklanan özelliklerden birisine göre bir çelik levha ile ilgilidir. The invention also showed that the coefficient of elasticity measured in the rolling direction was 230GPa. greater than or equal to, preferably equal to or greater than 240GPa, or one of the properties described above, preferably equal to or greater than the ZSOGPa value According to someone it is about a steel plate.
Belirli bir uygulamada, çelik Ievhanin mukavemeti 500 MP3 degerine esit ya da üzerindedir ve çelik Ievhanin birim uzama degeri %8 oranina esit ya da daha yüksektir. In a particular application, the strength of the steel plate is equal to or equal to 500 MP3. and the unit elongation value of the steel plate is equal to or higher than 8%.
Bulus ayni zamanda çelik parçalardan en az bir tanesinin nesnenin diger parçalarindan en az bir tanesine kaynaklanmis durumda yukarida açiklanan özelliklerden herhangi birisine göre bir çelik levha oldugu, diger çelik parçalarin bilesiminin ya da bilesimlerinin CrThe invention also means that at least one of the steel parts is separated from other parts of the object. any of the features described above caused by at least one that the composition or combinations of other steel parts, according to someone it is a steel plate cr
Claims (24)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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EP06291413A EP1897963A1 (en) | 2006-09-06 | 2006-09-06 | Steel sheet for the manufacture of light structures and manufacturing process of this sheet |
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TR201802707T4 true TR201802707T4 (en) | 2018-03-21 |
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Family Applications (1)
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TR2018/02707T TR201802707T4 (en) | 2006-09-06 | 2007-08-27 | Steel plate for the production of lightweight structures and the production method of this plate. |
Country Status (16)
Country | Link |
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EP (2) | EP1897963A1 (en) |
JP (1) | JP5298017B2 (en) |
KR (1) | KR20090043555A (en) |
CN (1) | CN101563476B (en) |
BR (1) | BRPI0716877B1 (en) |
CA (1) | CA2662741C (en) |
ES (1) | ES2659987T3 (en) |
HU (1) | HUE036845T2 (en) |
MA (1) | MA30698B1 (en) |
MX (1) | MX2009002411A (en) |
PL (1) | PL2064360T3 (en) |
RU (1) | RU2416671C2 (en) |
TR (1) | TR201802707T4 (en) |
UA (1) | UA95490C2 (en) |
WO (1) | WO2008029011A2 (en) |
ZA (1) | ZA200901377B (en) |
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CN113174545B (en) * | 2021-04-28 | 2022-12-09 | 上海交通大学 | In-situ nanoparticle reinforced FeCrB alloy with high-temperature oxidation resistance and preparation method thereof |
WO2024018255A1 (en) * | 2022-07-19 | 2024-01-25 | Arcelormittal | Method of welding a steel sheet comprising tib2 precipitates |
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Publication number | Priority date | Publication date | Assignee | Title |
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JPS59153837A (en) * | 1983-02-22 | 1984-09-01 | Sumitomo Metal Ind Ltd | Production of high strength cold-rolled steel sheet for press-forming use |
SU1122009A1 (en) * | 1983-07-19 | 1996-12-10 | Научно-Производственное Объединение По Технологии Машиностроения "Цниитмаш" | Corrosion-resistant steel |
KR100252237B1 (en) * | 1996-04-25 | 2000-04-15 | 정몽규 | Mg alloy for high pressure casting |
JP3478930B2 (en) * | 1996-08-29 | 2003-12-15 | 株式会社神戸製鋼所 | High rigidity and high toughness steel and method of manufacturing the same |
JPH10237583A (en) * | 1997-02-27 | 1998-09-08 | Sumitomo Metal Ind Ltd | High tensile strength steel and its production |
FR2819825B1 (en) * | 2001-01-24 | 2003-10-31 | Imphy Ugine Precision | PROCESS FOR MANUFACTURING A FE-NI ALLOY STRIP |
JP3592659B2 (en) * | 2001-08-23 | 2004-11-24 | 株式会社日本製鋼所 | Magnesium alloys and magnesium alloy members with excellent corrosion resistance |
JP3753101B2 (en) * | 2002-07-03 | 2006-03-08 | 住友金属工業株式会社 | High strength and high rigidity steel and manufacturing method thereof |
JP4213021B2 (en) * | 2003-11-25 | 2009-01-21 | 愛知製鋼株式会社 | High rigidity steel with excellent machinability |
JP4172424B2 (en) * | 2004-05-27 | 2008-10-29 | 住友金属工業株式会社 | Hot-rolled steel material and manufacturing method thereof |
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2006
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2007
- 2007-08-27 WO PCT/FR2007/001401 patent/WO2008029011A2/en active Application Filing
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- 2007-08-27 BR BRPI0716877A patent/BRPI0716877B1/en active IP Right Grant
- 2007-08-27 EP EP07823448.1A patent/EP2064360B1/en active Active
- 2007-08-27 RU RU2009108338/02A patent/RU2416671C2/en active
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- 2007-08-27 ES ES07823448.1T patent/ES2659987T3/en active Active
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JP2010502838A (en) | 2010-01-28 |
MX2009002411A (en) | 2009-03-20 |
CA2662741A1 (en) | 2008-03-13 |
MA30698B1 (en) | 2009-09-01 |
RU2009108338A (en) | 2010-09-20 |
ES2659987T3 (en) | 2018-03-20 |
JP5298017B2 (en) | 2013-09-25 |
PL2064360T3 (en) | 2018-06-29 |
BRPI0716877B1 (en) | 2017-05-02 |
HUE036845T2 (en) | 2018-08-28 |
EP1897963A1 (en) | 2008-03-12 |
UA95490C2 (en) | 2011-08-10 |
RU2416671C2 (en) | 2011-04-20 |
EP2064360B1 (en) | 2017-12-27 |
WO2008029011A2 (en) | 2008-03-13 |
CA2662741C (en) | 2012-02-07 |
BRPI0716877A2 (en) | 2013-10-15 |
KR20090043555A (en) | 2009-05-06 |
CN101563476A (en) | 2009-10-21 |
ZA200901377B (en) | 2009-12-30 |
WO2008029011A3 (en) | 2008-05-02 |
CN101563476B (en) | 2011-11-16 |
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