TH9340B - Finished coating equipment, coating methods for glass surfaces, compounds and mixtures for glass coatings, and coated glass substrates. - Google Patents

Abstract

The finished device for glass ribbon coating has exhaust ports on each side of the coating unit at different distances from the unit. This arrangement exposes the beginning and end sections of the ribbon to the coating vapor from the unit for different durations. Coating mixtures include tin-containing and silicon-containing precursors. The silicon-containing precursor has the following structural formula (chemical formula): R1 is an oxygen-free group available for peroxide formation, R2 is a functional group that allows the silicon-containing precursor to easily be converted into a silicon oxide coating, R3 is a crosslinking group for polysilicon atoms, and R4 enables complete bonding on the basic silicon atoms. Accelerators, such as phosphorus-containing precursors, can be used in conjunction with metal-containing precursors to increase the deposition rate of the coating. The deposited coating on the glass has regions where the weight percentage of silicon oxide and tin oxide varies continuously with increasing interface distance, with the furthest coating surface from the interface being the least affected. This glass-like coating is primarily tin oxide. Different regions within the coating exhibit varying refractive indices to eliminate iridescence resulting from the increased thickness of the tin oxide layer on the outer surface, giving the coated glassy object a neutral color. When phosphorus is used as an accelerator, the percentage of crystallinity is reduced to near 0, thereby reducing or eliminating the opacity of the coating.

Claims (89)

1. A method for coating a moving substrate surface to obtain a coating with a continuously varying chemical mixture as the distance from the substrate increases. This involves the following steps: Introducing the coating mixture vapor to a first location on the substrate surface. This vapor is then moved along a first region of the substrate surface in one direction, and a second region is moved along a second region in a second, opposite direction. The first portion of the coating mixture on the first region is maintained for a longer period than the second portion of the coating mixture on the second region, thereby coating the substrate with a coating whose chemical mixture continuously varies as the distance from the substrate increases. 2. A method of claim 1 in which the coating mixture contains at least two metallic precursors. 3. The method of claim 2, where the substrate is a glass substrate and the first direction mentioned is the direction parallel to the direction in which this substrate is moving in the majority direction. 4. The method of claim 3, in which one of the precursors containing a metal is chosen from a group of metals including tin, titanium, tungsten, and antimony. 5. The method of claim 2, which consists of performing the aforementioned tangent procedure at a second position समने टने सकल ... 6. The method of claim 5 involves coating the substrate in a chamber with an oxidizing atmosphere, and a curtain of inert gas is subsequently provided to prevent the oxidizing atmosphere from migrating to that location, where the inert gas curtain and the area between them define the boundary of the coating area. 7. The method of claim 6, in which the aforementioned chamber contains a bath of oxidizing molten metal and this substrate is a glass ribbon that supports the molten metal and slides it through the chamber along the surface coating location. 8. The method of claim 2 which accomplishes the aforementioned treatment procedure by placing total suction instruments on each side of the first position, where one suction instrument is located at a distance "X" from the first position and another suction instrument is located at a distance "y" from the first position, and furthermore, the ratio of x/y is greater than 1. 9. The method described in Claim 1, where the substrate is a glass substrate and a mixture of coatings, contains at least one silicon precursor which contains at least one silicon-oxygen bond. 10. The method described in claim 9, in which the aforementioned contact introduction step involves mixing this silicon-containing precursor with an accelerator to increase the rate of deposition of the silicon oxide coating on the glass substrate. 11. The method described in Claim 1, in which a mixture of coatings contains at least one precursor containing metal and at least one precursor containing silicon. 12. Method of claim 4 in which a precursor containing one of these metals contains tin. 13. The method of claim 1, which is further comprised of the action of the aforementioned tactile introduction step at a second position further from the first position. 14. The method of claim number 5, which includes the procedure of complete vapor venting from both sides of the first and third positions. 15. The method of claim 8, which has a ratio of x/y that is approximately greater than 1.2. 16. The method of claim 15, which has a ratio of x/y ranging from approximately 1.2 to approximately 50. 17. The method of claim 16, which has a ratio of x/y ranging from approximately 1.5 to 30. 18. The method of this claim, in which the substrate is a glass ribbon coated in a chamber with a reducing atmosphere and supported on a pool of oxidizing molten metal. 19. The method of claim 5, in which this substrate is a glass ribbon and is further comprised of a step of deposition of a single metal oxide layer onto a coating of a continuously varying chemical mixture. 20. The method of claim 19, in which a single metal oxide layer herein is tin oxide and this coating is a continuously varying chemical mixture composed of tin oxide and silicon oxide. 21. A transparent substrate with an amorphous coating on it, consisting of one or more mixed metal oxides containing up to 15 percent of the atomic number of elements distributed throughout, selected from the phosphorus, aluminum, and boron group, excluding phosphorus, aluminum, and boron from the mixed metal oxides. 22. A transparent substrate with an amorphous coating on it, consisting of a mixture of metal oxides with regions in the coating containing metal oxides in continuously varying ratios, without a predominantly layer of fixed-ratio metal oxides. Up to 15 percent of the atomic elements are distributed throughout, selected from the group consisting of phosphorus, aluminum, and boron. 23. Substance of Reputation 22, in which the substrate is a mixture of metal oxide glass, namely silicon oxide and tin oxide, with 70-100% by weight of silicon oxide at the glass interface and 70-100% by weight of tin oxide at the opposite glaze surface, and the recurring element is phosphorus. 24. Items under claim 23 containing 1 to 12 percent phosphorus atoms distributed in this coating. 25. A transparent substrate pursuant to claim paragraph 21, which is selected from a group of aforementioned metal oxides consisting of silicon, tin, titanium, tungsten, antimony oxides and mixtures of these oxides. 26. A transparent substrate pursuant to claim 25, the element of which is distributed throughout the coating surface is phosphorus. 27. A transparent substrate pursuant to claim 25, which is aluminum. 28. A transparent substrate according to claim 25, which is boron. 29. A transparent substrate pursuant to claim paragraph 25, which selects this metal oxide from a group comprising silicon oxides, tin oxides and mixtures of these oxides. 30. A transparent substrate pursuant to claim 29, the element distributed throughout the coating being phosphorus. 31. A transparent substrate pursuant to claim 29, the element of which is aluminum. 32. A transparent substrate pursuant to claim 29, in which the element is boron. 33. A transparent substrate pursuant to claim paragraph 22, which herein is selected from a mixture of metal oxides including silicon, tin, titanium, tungsten and antimony oxides. 34. A transparent substrate pursuant to claim 33, in which a mixture of metal oxides, namely silicon and tin oxides, is contained. 35. A transparent substrate pursuant to claim 34, the element distributed throughout this coating being phosphorus. 36. A transparent substrate pursuant to claim 34, the element of which is aluminum. 37. A transparent substrate pursuant to claim 34, in which the element is boron. 38. The coating instrument, which consists of an instrument for vapor conduction on the glass surface; a first vacuum instrument located at a distance from the aforementioned vapor conduction instrument on one side of this instrument; a second vacuum instrument located at a distance from the aforementioned vapor conduction instrument on the other side of this instrument and in line with the aforementioned vapor conduction instrument; and the first vacuum instrument and the instruments for positioning the first and second vacuum instruments and the aforementioned vapor conduction instruments, which are relative to each other in such a way that the distance between the first vacuum instrument and the aforementioned vapor conduction instrument is defined as "x" and the distance between the second vacuum instrument and the aforementioned vapor conduction instrument is defined as "y", where the values of "x" and "Y" here are different. 39. The coating tool of claim 38, in which the ratio of x/y here ranges from approximately 1.2 to approximately 50. 40. The coating apparatus consists of a tool that includes a nozzle for directing vapor to the substrate, which has one opening; a first exhaust tool with one opening located at a distance from the aforementioned vapor directing tool on the other side of this tool; a second exhaust tool with one opening located at a distance from the aforementioned vapor directing tool on the other side of this tool and in line with the aforementioned vapor directing tool; and a tool for positioning the first and second exhaust tools and the aforementioned vapor directing tool relative to the substrate surface such that the surface area of the opening of the aforementioned vapor directing tool and the opening of the first exhaust tool are at a different distance from the distance between the opening of the second exhaust tool and this substrate. 41. A coating apparatus consisting of a direct vapor delivery device to the substrate, a first exhaust device located at a distance from the aforementioned direct vapor delivery device on one side of this apparatus, a second exhaust device located at a distance from the aforementioned direct vapor delivery device on the other side of this apparatus and in alignment with the aforementioned direct vapor delivery device and the first and second exhaust devices, and an apparatus for controlling the volumetric flow capacity of the aforementioned direct vapor delivery device and the first and second exhaust devices in such a way that the volumetric flow capacity of the aforementioned direct vapor delivery device differs from the volumetric flow capacity of at least one exhaust device. 42. Coating mixtures for vapor deposition on substrates, where the coating consists of a mixed layer of silicon and metal oxides in a predetermined ratio. The coating mixture comprises a silicon-containing precursor that can be converted to silicon oxide and a metal-containing precursor that can be converted to metal oxide, with a molar ratio of the metal-containing precursor to the silicon-containing precursor within the range of 0.001 to 50,000. The silicon-containing precursor is defined by the following structural formula (chemical formula), where R1 is a non-oxygen-containing peroxide bonding group, R2 is the functional group that enables the silicon-containing precursor to be easily converted to a silicon oxide coating, R3 is a crosslinking group that makes the molecule polysilicon, and R4 is the bond completer. R1 here is chosen from alkyl-containing groups. Or substituted alkyl radicals containing 1 to 10 carbon atoms; alkenyl or substituted alkenyl radicals containing 2 to 10 carbon atoms; alkinyl or substituted alkinyl radicals containing 2 to 10 carbon atoms; and aryl or aralkyl or substituted aryl or aralkyl radicals containing 6 to 11 carbon atoms; R2 consists of hydrogen, halogen, alkenyl or substituted alkenyl radicals containing 2 to 10 carbon atoms; (formula) - halogenated alkyl or perhalogenated alkyl radicals and their substituted derivatives. These include alkinyls, which have 1 to 10 carbon atoms, and alkinyls, or substituted alkinyls, which have 2 to 10 carbon atoms, in which R3 contains -S-; (Chemical formula) where R5 here is an alkyl or substituted alkyl radical containing 1 to 10 carbon atoms; (Chemical formula) where R5 here satisfies the definition above; (Chemical formula) where n is 1 to 10; and R4 is selected from the group consisting of alkyl, or substituted alkyl radicals containing 1 to 10 carbon atoms; alkenyl or substituted alkenyl radicals containing 2 to 10 carbon atoms; alkinyl or substituted alkinyl radicals containing 2 to 10 carbon atoms; and aryl or aralkyl or substituted aryl or aralkyl radicals containing 6 to 11 carbon atoms. 43. A mixture of coatings to claim 42, in the R1 part of which are alkyl or substituted alkyl radicals of 1 to 4 carbon atoms, alkenyl or substituted alkenyl radicals of 2 to 4 carbon atoms, alkyl or substituted alkyl radicals of 2 to 4 carbon atoms, and aryl or aralkyl or substituted aryl or aralkyl radicals of 6 to 9 carbon atoms. 44. A mixture of claims under Article 43 in which, in the R1 part, the alkyl or substituted alkyl radicals are included -CH3, -CH2CH2CH3, -CH2CH2-OH, -CCL3, -CH2CHCLCH3 or -CH2CCL2CCL3; the alkenyl or substituted alkenyl radicals are included -CH=CHCH3 or -CH=CH; the alkylenyl or substituted alkylen radicals are included -C=C-CH3 or -C=CH; and the aryl or aralkyl or substituted aryl or aralkyl radicals are included -C6H5 or -C6H4CH3. 45. A mixture of coatings to claim 42 in which the R2 part is chlorinated halogen; alkenyl or substituted alkenyl radicals of 2 to 4 carbon atoms, (formula)-halogenated alkyl or perhalogenated alkyl radicals and their substituted derivatives of 1 to 4 carbon atoms, and alkinyl or substituted alkinyl radicals of 6 to 9 carbon atoms. 46. The coating mixtures of the claim under Article 45, in the R2 part, contain alkenyl or substituted alkenyl radicals incorporating -CH=CHCH3 or -CH-CH3; (formula) - halogenated alkyl or perhalogenated alkyl radicals and their substituted derivatives incorporating CCL3, -CH2CHCLCH3 or -CH2CCL2CCL3; and alkinyl or substituted alkinyl radicals incorporating C-C-C3 or -CCC=CH2. 47. A mixture of coatings of claim 42 in which R5 contains 1 to 4 carbon atoms, and n is 1 to 4 carbon atoms. 48. A mixture of coatings of the claim under Article 47, selected R5 herein from groups consisting of -CH2CH3 or -CH2CH2CH3 and a non-reactive mixture of these groups. 49. A mixture of coatings to claim 42, in the R4 part of which are alkyl or substituted alkyl radicals of 1 to 4 carbon atoms; alkenyl or substituted alkenyl radicals of 2 to 4 carbon atoms; alkyl or substituted alkyl radicals of 2 to 4 carbon atoms; and aryl or aralkyl or substituted aryl or aralkyl radicals of 6 to 9 carbon atoms. 50. The coating mixtures of the claim under paragraph 49, in part R4, are alkyl or substituted alkyl radicals incorporating -CH3, -CH2CH2CH3, -CH2-CH2-CH, -CCL3, -CH2CHCLCH3 and -CH2CCL2CCL3; alkenyl or substituted alkenyl radicals incorporating -CH=CHCH3 and -CH=CH3; alkylenyl or substituted alkylen radicals incorporating -C=C-CH3 and -C=CH; and aryl or aralkyl or substituted aryl or aralkyl radicals incorporating -C6H5 and -C6H4CH3. 51. A mixture of coatings of the claim under paragraph 42, whereby R4 is selected from the group consisting of hydrogen, halogen, (formula)-halogenated alkyl or perhalogenated alkyl radicals and their substituted derivatives containing 1 to 10 carbon atoms. 52. A mixture of this claim under Article 51 in which the R4 fraction contains a chlorinated halogen, an alkynyl or substituted alkynyl radical containing 2 to 4 carbon atoms, (formula)-halogenated alkyl or perhalogenated alkyl radical or its substituted derivative containing 1 to 4 carbon atoms, and an alkynyl or substituted alkynyl radical containing 6 to 9 carbon atoms. 53. The coating mixtures of this claim under paragraph 52, in the R4 part, contain alkenyl or substituted alkenyl radicals incorporating -CH=CHCH3 or -CHCH3, (formula) - halogenated alkyl or perhalogenated alkyl radicals or substituted derivatives incorporating -CCL3, -CH2CHCLCH3 and -CH2CCL2CCL3, and alkinyl or substituted alkinyl radicals incorporating C-C-CH3 and -CCC=CH2. 54. The coating mixture of this claim, R4 herein, is further selected from a group of alkoxides or substituted alkoxide radicals containing 1 to 10 carbon atoms, -CN, -OCN, and phosphine, alkylphosphine and diallkylphosphine, where the alkyl radicals herein contain 1 to 10 carbon atoms. 55. A mixture of coatings to claim 54, in which the R4 portion contains an alkoxide or substituted alkoxide radical containing 1 to 4 carbon atoms and an alkyl radical containing 1 to 4 carbon atoms. 56. The coating mixtures of this claim under paragraph 55, in part R4, contain alkoxides or substituted alkoxide radicals containing -OCH2CH3, alkyls or substituted alkyl radicals containing -CH2CH3, and phosphine, alkylphosphine, and dialkylphosphine containing -PH2, CH3PH, -PHCH3, and -P(CH2CH3)2. 57. The coating mixture of this claim, Article 42, shall consist of compounds selected from a group comprising tetramethylcyclotetrasiloxane, tetramethyldisiloxane, and triethoxysilane. 58. The coating mixture of claim 42, which includes an accelerator to increase the rate of silicon oxide deposition, shall be selected from a group of compounds containing nitrogen, phosphorus, boron and sulfur, and a mixture of these compounds in conjunction. Non-reactive radicals are obtained with the following structural formulas: (a) (chemical formula), (b) (chemical formula), (c) R10=S=R11, (d) (chemical formula), and (e) (chemical formula), where Y is chosen from the group containing nitrogen, boron, and phosphorus, and R10, R11, R12, R13, and R14 are chosen from the following functional groups: hydrogen, halogen, alkynyl or substituted alkynyl radicals with 2 to 10 carbon atoms, per-halogenated alkyl or substituted alkyl radicals with 1 to 10 carbon atoms, halogenated alkyl or substituted alkyl radicals with 1 to 10 carbon atoms, azyloxi radicals with 1 to 10 carbon atoms. Alkinyl or substituted alkinyl radicals, containing 2 to 10 carbon atoms; alkyl or substituted alkyl radicals, containing 1 to 10 carbon atoms; aryl or substituted aryl radicals, containing 6 to 10 carbon atoms; and alkoxide or substituted alkoxide radicals, containing 1 to 10 carbon atoms. 59. The mixture of claims under Article 42, including the following catalyst, which is Lewis acid. 60. A mixture of claims under Article 42, including, further, an accelerator which is a Lewis base. 61. The mixture of claims under Article 42, which includes the following accelerator, which is triethylphosphite. 62. This combination of claims 42, including a second type of metal-containing precursor, 63. A mixture of coatings comprising a silicon-containing precursor capable of being transformed into a corresponding silicon oxide at temperatures of approximately 750°F to 1500°F (400°C to 815°C) and having bonds (chemical formula) in the structural formula of this precursor, and a metal-containing precursor capable of being transformed into a corresponding metal oxide, and an accelerator, whose bonds (chemical formula) are (chemical formula) chosen from a group of alkyl or substituted alkyl radicals with 1 to 10 carbon atoms; halogenated alkyl radicals with 1 to 10 carbon atoms, preferably 1 to 4 carbon atoms, such as -CCl3, -CH2CHClCH3 and -CH2CCl2CCl3; Alkenyl or substituted alkenyl radicals containing 2 to 10 carbon atoms; alkinyl or substituted alkinyl radicals containing 2 to 10 carbon atoms; and aryl or aralkyl or substituted aryl or aralkyl radicals containing 6 to 11 carbon atoms, and which bond (chemical formula) is (chemical formula) where R2 is chosen from the group consisting of hydrogen, halogen, alkenyl or substituted alkenyl radicals containing 2 to 10 carbon atoms; (formula)- halogenated alkyl, perhalogenated alkyl radicals and substituted derivatives. These include carbon atoms from 1 to 10, and alkinyl or substituted akinyl radicals, which contain carbon atoms from 2 to 10. 64. The coating mixtures of this claim under Article 63 are selected from the group of compounds of the aforementioned metals, including tin, titanium, tungsten, and antimony, and mixtures of these compounds. 65. The coating mixture of the claim in Article 63, in which the aforementioned metal compound is a tin compound. 66. A mixture of coatings to claim 63 in which, in the R1 part, these are alkyl or substituted alkyl radicals of 1 to 4 carbon atoms; perhalogenated or substituted alkyl radicals of 1 to 4 carbon atoms; alkylenyl or substituted alkylenyl radicals of 2 to 4 carbon atoms; and aryl or aralkyl or substituted aryl or aralkyl radicals of 6 to 9 carbon atoms. 67. The mixture of coatings of this Patent 66, in the R1 part, contains alkyl or substituted alkyl radicals incorporating -CH3; -CH2CH2CH3 and -CH2CH2OH; perhalogenated or substituted alkyl radicals incorporating -CCL3, -CH2CHCLCH3 and -CH=CH3; alkylenol or substituted alkyl radicals incorporating -C=C-CH3 and -C=CH; and aryl or aralkyl or substituted aryl or aralkyl radicals incorporating -C6H5 and -C6H4CH3. 68. The mixture of coatings of this claim 63, in the R2 part, consists of alkenyl or substituted alkenyl radicals of 2 to 4 carbon atoms; halogenated, perhalogenated or substituted alkyl radicals of 1 to 4 carbon atoms; and alkinyl or substituted alkinyl radicals of 6 to 9 carbon atoms. 69. A mixture of coatings to claim 68, in the R2 portion, which includes chlorinated, alkenyl, or substituted alkenyl radicals incorporating -CH=CHCH3 and -CH=CH3; halogenated, perhalogenated, or substituted alkyl radicals incorporating -CCl3, -CH2CHClCH3 and -CH2CCl2CCl3; and alkinyl or substituted alkinyl radicals incorporating C-C-CH3 and -C=CH2. 70. A mixture of coatings of claim 63 which (chemical formula) is (chemical formula) which selects this R3 from the group consisting of: -S-; -(chemical formula) which R5 in this is an alkyl or substituted alkyl radical containing 1 to 10 carbon atoms (chemical formula); (chemical formula) (chemical formula) which n is 1 to 10. 71. The coating mixture of the claim under Article 70, which (chemical formula) is (chemical formula), R4 is selected from a group consisting of alkoxides or substituted alkoxide radicals containing 1 to 10 carbon atoms; alkyls or substituted alkyl radicals containing 1 to 10 carbon atoms -CN; -ONC, and phosphine, alkyl phosphine and dial phosphine, which alkyl radicals contain 1 to 10 carbon atoms. 72. A coating mixture of the claim 70 in which R5 contains 1 to 4 carbon atoms and n is 1 to 4. 73. The coating mixture of this claim, Article 72, in which R5 is composed of -CH2CH3 and -CH2CH2CH3 radicals. 74. The coating mixture of this claim under Article 71, in the R4 portion, contains alkoxide or substituted alkoxide radicals with 1 to 4 carbon atoms; alkyl or substituted alkyl radicals with 1 to 5 carbon atoms; and alkyl radicals with 1 to 4 carbon atoms. 75. The coating mixtures of this claim under Article 74, in the R4 portion, contain the alkoxide or substituted alkoxide radicals -O-CH2CH3, the alkyl or substituted alkyl radicals -CH2CH3, and the alkyl radicals -PH2, CH3PH, -PHCH3, and -P(CH2CH3)2. 76. The coating mixture of this claim, Article 63, in which the accelerator is Lewis acid. 77. A mixture of coatings of the claim under Article 63 in which the accelerator is Lewis base. 78. The mixture of the coating of this claim under Article 63, in which the accelerator is water. 79. The coating mixture of this claim, Article 63, in which the accelerator is triethylphosphite. 80. A mixture of coatings to claim Article 63, in which the accelerator is ozone. 81. The coating mixture of this claim under Article 63, which selects this accelerator from aluminum compounds. 82. The coating mixture of this claim 63 shall be selected from aluminum compounds of the following structural formulas (chemical formulas), in which at least one substituent of R15, R16, and R17 is the same or different, and shall be selected from the hydrogen-containing, halogen, 0-R17 groups in which R17 is a branched, branched, or substituted alkyl radical of 1 to 10 carbon atoms; -S-R16 in which R16 is defined above for -OR17-NH2; and NR19R20 in which R19 and R20 are branched, branched, or substituted alkyl groups of 1 to 10 carbon atoms, with the substituent being selected from R15, R16, or R17. 83. The coating mixtures of this claim under Article 82, which include the substituted alkyl radical groups R15, R16 and R17, consist of: alkoxide radicals with 1 to 10 carbon atoms; alkyl radicals with 1 to 10 carbon atoms; halogenated or halogenated alkyl radicals with 1 to 10 carbon atoms; alkenyl radicals with 2 to 10 carbon atoms; alkyne radicals with 2 to 10 carbon atoms; aryl or aralkyl radicals with 6 to 11 carbon atoms; CN;-OCN; Phosphine, alkylphosphine, and dialkylphosphine radicals, in which the alkyl group has 1 to 10 carbon atoms and -OH. 84. A mixture of coatings to claim 83, in which R17 includes alkoxide radicals of 1 to 4 carbon atoms; alkyl radicals of 1 to 4 carbon atoms; halogenated or halogenated alkyl radicals of 1 to 4 carbon atoms; alkenyl radicals of 2 to 4 carbon atoms; alkinyl radicals of 2 to 4 carbon atoms; and aryl or aralkyl radicals of 6 to 9 carbon atoms and alkyl groups of 1 to 4 carbon atoms. 85. A mixture of coatings of the claims in Article 84, in which R17 includes alkoxide radicals containing -OCH2CH2CH2CH3; alkyl radicals containing -CH2CH2CH3; halogenated or halogenated alkyl radicals containing CL or CCL3; alkenyl radicals containing -CH=CH2; alkinyl radicals containing -C=CH; aryl or aralkyl radicals containing C6H5 and these alkyl groups include -PH2, -PHCH3, -P(CH2CH3)2. 86. The coating mixture of this claim 63 shall select this accelerator from compounds of nitrogen, phosphorus, boron and sulfur with the following structural formulas: (a) (chemical formula), (b) (chemical formula), (c) (chemical formula), (d) (chemical formula), and (e) (chemical formula), from which Y is selected from the group containing nitrogen, boron and phosphorus, and from which R10, R11, R12, R13 and R14 are selected from the following functional groups: hydrogen, halogen, alkynyl or substituted alkynyl radicals with 2 to 10 carbon atoms; perhalogenated alkyl or substituted alkyl radicals with 1 to 10 carbon atoms; Halogenated alkyl or substituted alkyl radicals containing 1 to 10 carbon atoms; azyloxi radicals containing 1 to 10 carbon atoms; alkinyl or substituted alkinyl radicals containing 2 to 10 carbon atoms; alkyl or substituted alkyl radicals containing 1 to 10 carbon atoms; aryl or substituted aryl radicals containing 6 to 10 carbon atoms; and alkoxide or substituted alkoxide radicals containing 1 to 10 carbon atoms. 87. A mixture of coatings of the claims in Article 86 in which this functional group includes alkenyl or substituted alkenyl radicals with 2 to 4 carbon atoms; perhalogenated alkyl or substituted alkyl radicals with 1 to 4 carbon atoms; halogenated alkyl radicals with 1 to 4 carbon atoms; azyloxi radicals with 1 to 4 carbon atoms; alkylenyl or substituted alkylen radicals with 2 to 4 carbon atoms; alkyl or substituted alkyl radicals with 1 to 4 carbon atoms; Aryl, or substituted aryl radicals, which contain 6 to 9 carbon atoms, and alkoxide, or substituted alkoxide radicals, which contain 1 to 4 carbon atoms. 88. A mixture of coatings of claim 87 in which the halogen of this functional group contains chlorine, alkyl or substituted alkyl radical of this functional group contains -C=CH2; perhalogenated alkyl or substituted alkyl radical of this functional group contains -CCLH2; halogenated alkyl or substituted alkyl radical of this functional group contains -CCH2CH3; aceloxy radical of this functional group contains -OCOCH3; alkyl or substituted alkyl radical of this functional group contains -C=CH; alkyl or substituted alkyl radical of this functional group contains -CH3, -CH2CH2CH3; The aryl or substituted aryl radicals of this functional group include -C6H4CH3, and the alkoxide or substituted alkoxide radical of this functional group includes -OCH2CH2CH3. 89. The coating mixture of this claim 63, selected from the group of triethylphosphite, trimethylphosphite, trimethylborate, PF5, PCl3, PBr3, PCl5, BCl3, BF3, (CH3)2BBr, SF4 and HO3SF.