TH56574A - A herbicide mixture containing glyphosate and bipyridylium. - Google Patents

Abstract

DC60 (11/12/44) A herbicide mixture is prepared which is useful for killing or controlling the growth of plants. The herbicide mixture consists of N-phosphonomethylglycine or its herbicide derivatives, bipyridylium or its herbicide derivatives, and a surfactant mixture consisting of one or more polyoxyalkylene trisiloxane surfactants and possibly other mixtures. The herbicide mixture can be prepared from solid, particulate, or liquid concentrates. A method for killing or controlling the growth of plants is also provided, consisting of a procedure of contact between the leaves of such plants with the herbicide mixture with water as the medium of this invention. A method for preparing solid, particulate concentrates is also provided. The herbicide mixture is prepared which is useful for killing or controlling the growth of plants. The herbicide mixture consists of N-phosphonomethylglycine or its herbicide derivatives, bipyridylium or its herbicide derivatives, and a surfactant mixture consisting of one or more polyoxyalkylene trisiloxane surfactants. One or more types of trisiloxanes, and possibly other mixtures, are used. The herbicide mixture can be prepared from solid, particulate, or liquid concentrates. Methods for killing or controlling plant growth are also provided, consisting of a procedure of contacting the leaves of such plants with the aqueous herbicide mixture. Methods for preparing solid, particulate concentrates are also provided.

Claims (211)

1. An aqueous aerosolized herbicide mixture useful for killing or controlling unwanted plant growth, containing glyphosate or its herbicide derivatives; bipyridyliam or its herbicide derivatives; and at least one surfactant in sufficient concentrations to allow for glyphosate uptake and translocation prior to leaf damage; bipyridyliam-induced uptake and translocation likely to be intersected by the subsequent uptake and translocation of glyphosate; where glyphosate (acid equivalent criterion) and bipyridyliam (cation equivalent criterion) are present in a weight ratio between 19:1 and approximately 100:1. 2. Aqueous aerosol herbicide mixtures with water as the medium, useful for killing or controlling the growth of unwanted plants, containing glyphosate or its herbicide derivatives; bipyridylium or its herbicide derivatives; and at least one surfactant; where glyphosate (acid equivalent) and bipyridylium (cation equivalent) are present in weight ratios between 11:1 and approximately 100:1, and glyphosate (acid equivalent) and the surfactant are present in weight ratios between approximately 0.5:1 and approximately 48:1. 3. Aqueous aerosolized herbicide mixtures suitable for killing or controlling unwanted plant growth, containing glyphosate or its herbicide derivatives; bipyridylium or its herbicide derivatives; and at least one surfactant in sufficient concentrations to allow glyphosate uptake and translocation prior to bipyridylium-induced leaf damage, which would likely interfere with the subsequent glyphosate uptake and translocation; where glyphosate (acid equivalent criterion) and bipyridylium (cation equivalent criterion) are present in weight ratios between 11:1 and approximately 100:1, and the mixture may be selectively formulated to contain alkyl polyglycosides, the characteristics and concentrations of which are insufficient on their own to allow glyphosate uptake and translocation prior to bipyridylium-induced leaf damage, which would likely interfere with the subsequent glyphosate uptake and translocation. 4. Liquid herbicide concentrates with an aqueous medium that may be diluted with water to obtain aqueous herbicide mixtures for foliar application. Such concentrates shall contain: glyphosate or its herbicide derivatives at a concentration of at least 120 g acid equivalent per liter; bipyridylium or its herbicide derivatives; and at least one surfactant, the nature and concentration of which such surfactant, when such a mixture is applied to the leaves of plants, the uptake and translocation of glyphosate prior to bipyridylium-induced leaf damage is likely to be interfered with by the subsequent uptake and translocation of glyphosate; where glyphosate (acid equivalent criterion) and bipyridylium (cation equivalent criterion) are present in a weight ratio between 1:1 and approximately 100:1. 5. Liquid herbicide concentrates with an aqueous medium that may be diluted with water to obtain aqueous herbicide mixtures for foliar application. Such concentrates contain: glyphosate or its herbicide derivatives; bipyridylium or its herbicide derivatives; and at least one surfactant, the nature and concentration of which such surfactant, when such a mixture is applied to the leaves of plants, the uptake and translocation of glyphosate prior to bipyridylium-induced leaf damage is likely to be interfered with by the subsequent uptake and translocation of glyphosate; where glyphosate (acid equivalent) and bipyridylium (cation equivalent) are present in a weight ratio between 26:1 and approximately 100:1. 6. Liquid, aqueous herbicide concentrates that may be diluted with water to obtain aqueous herbicide mixtures for application to plant leaves. Such concentrates contain: glyphosate or its herbicide derivatives; bipyridylium or its herbicide derivatives; and at least one surfactant; where glyphosate (acid equivalent) and bipyridylium (cation equivalent) are present in weight ratios between 1:1 and approximately 100:1, and glyphosate (acid equivalent) and the surfactant are present in weight ratios between 0.5:1 and approximately 50:1. 7. Liquid herbicide concentrates with an aqueous medium that may be diluted with water to obtain aqueous herbicide mixtures for foliar application. Such concentrates shall contain: glyphosate or its herbicide derivatives; bipyridylium or its herbicide derivatives; and at least one surfactant, the nature and concentration of which such surfactant, when such a mixture is applied to the leaves of plants, glyphosate uptake and translocation prior to bipyridylium-induced leaf damage, likely interfere with the subsequent uptake and translocation of glyphosate; where glyphosate (acid equivalent) and bipyridylium (cation equivalent) are present in a weight ratio between 1:1 and approximately 100:1, and the mixture may selectively contain alkyl polyglycosides, the nature and concentration of such alkyl polyglycosides, where by themselves they are insufficient to cause plant uptake and translocation. The glyphosate position prior to bipyridilium-induced leaf damage likely involves interference with the uptake and subsequent translocation of glyphosate. 8. Liquid, aqueous herbicide concentrates that may be diluted with water to obtain aqueous herbicide mixtures for foliar application. Such concentrates shall contain: glyphosate or its herbicide derivatives; bipyridylium or its herbicide derivatives; and at least one surfactant, the nature and concentration of which such surfactant, when such mixture is applied to the leaves of plants, glyphosate uptake and translocation prior to bipyridylium-induced leaf damage, should be interfered with by subsequent glyphosate uptake and translocation; where glyphosate (acid equivalent) and bipyridylium (cation equivalent) are present in weight ratios between 1:1 and approximately 100:1, and the concentrate, when devoid of dyes or coloring agents, has a Gardner color value no greater than 10. 9. Liquid herbicide concentrates with an aqueous medium that may be dissolved or dispersed with water to form aqueous herbicide mixtures for foliar application. Such concentrates shall contain: glyphosate or its herbicide derivatives in a concentration of at least approximately 50% by weight of such concentrate; bipyridylium or its herbicide derivatives; and at least one surfactant, the nature and concentration of which such surfactant, when such mixture is applied to the leaves of plants, glyphosate uptake and translocation prior to bipyridylium-induced leaf damage, shall likely be interfered with by subsequent glyphosate uptake and translocation; where glyphosate (acid equivalent) and bipyridylium (cation equivalent) are present in a weight ratio between 1:1 and approximately 100:1. 10. Liquid, aqueous herbicide concentrates that may be diluted with water to form aqueous herbicide mixtures for application to plant leaves. Such concentrates shall contain: glyphosate or its herbicide derivatives in a concentration of at least approximately 50% by weight of such concentrate; bipyridylium or its herbicide derivatives; and at least one surfactant; where glyphosate (acid equivalent) and bipyridylium (cation equivalent) are present in a weight ratio between 1:1 and approximately 100:1, and glyphosate (acid equivalent) and the surfactant are present in a weight ratio between approximately 1:1 and approximately 40:1. 11. A mixture of any one of the claims 1-3, in which glyphosate and bipyridylium are present in a weight ratio between approximately 20:1 and approximately 80:1. 12. A mixture of claims 11 where glyphosate and bipyridylium are present in a weight ratio between approximately 30:1 and approximately 60:1. 13. A mixture of claims 1 or 3, in which glyphosate and surfactant are present in a weight ratio between approximately 0.4:1 and approximately 48:1. 14. A mixture of any one of claims 1-3, where glyphosate and surfactant are in a weight ratio between approximately 0.5:1 and approximately 17:1. 15. A mixture of claim 14 in which glyphosate and surfactant are in a weight ratio between approximately 1.1:1 and approximately 8:1. 16. A concentration of any one of claims 4, 6, 7, or 8, in which glyphosate and bipyridylium are present in a weight ratio between approximately 8:1 and approximately 60:1. 17. A concentration of any one of claims 4-8, where glyphosate and bipyridylium are present in a weight ratio between approximately 25:1 and approximately 50:1. 18. A concentration of any one of claims 4, 5, 7, or 8, where glyphosate and surfactant are present in a weight ratio between approximately 0.1:1 and approximately 50:1. 19. A concentration of one of the claims 4-8, where glyphosate and surfactant are present in a weight ratio between approximately 0.5:1 and approximately 30:1. 20. The concentration of claim 19, where glyphosate and surfactant are present in a weight ratio between approximately 2:1 and approximately 5:1. 21. Concentrated formulations of claim 9 or 10, where glyphosate and bipyridylium are present in a weight ratio between approximately 22:1 and approximately 90:1. 22. The concentration of claim 21 where glyphosate and bipyridylium are present in a weight ratio between approximately 40:1 and approximately 50:1. 23. The concentration of claim 9, where glyphosate and surfactant are present in a weight ratio between approximately 1:1 and approximately 40:1. 24. Concentrates of claim 9 or 10, where glyphosate and surfactants are present in a weight ratio between approximately 1.5:1 and approximately 15:1. 25. The concentration of claim 24, where glyphosate and surfactant are present in a weight ratio between approximately 2:1 and approximately 6:1. 26. A concentrated solution of any one of the claims 4-8, whereby the liquid concentrate has a cloud point of at least approximately 50 °C and a crystallization point no higher than approximately 0 °C. 27. The concentrate of claim 26, whereby the concentrate is a liquid with a cloud point of at least approximately 60 °C and a crystallization point no higher than approximately -10 °C. 28. The concentrate of claim 27, whereby the concentrate is a liquid with a density of at least approximately 1.16 g/L. 29. A mixture or concentrate of any one of the ten claims, where the surfactant and bipyridylium contained within it do not significantly oppose the herbicide activity of glyphosate. 30. A mixture or concentration of any one of the 1-10 claims, including dicarboxylic acid. 31. A mixture or concentration of claim 30 where dicarboxylic acid is selected from a group comprising oxylic acid, malonic acid, succinic acid, glutaric acid, maleic acid, adipic acid and fumaric acid and its combinations or mixtures. 32. A mixture or concentration of any of the ten claims, in which glyphosate or its herbicide derivatives contain glyphosate salts. 33. A mixture or concentration of claim 32 where the salt of glyphosate contains alkali, ammonium, C1-16 alkylammonium, C1-16 alkanolammonium, or C1-16 alkyl-sulfonium salts of glyphosate. 34. A mixture or concentration of claim 32 whereby salts of glyphosate are selected from a group comprising potassium glyphosate, monoammonium glyphosate, diammonium glyphosate, sodium glyphosate, monoethanolamine glyphosate, n-propylamine glyphosate, ethylamine glyphosate, ethylenediamine glyphosate, hexamethylenediamine glyphosate, trimethylsulfonium glyphosate and mixtures thereof. 35. A mixture or concentration of claim 34 where glyphosate contains potassium glyphosate. 36. A mixture or concentration of any one of the claims 4-8, where the surfactant does not contain an amount that has an alkyl polyglycoside effect. 37. A mixture or concentration of any one of the claims 4-8, where the surfactant contains an alkyl polyglycoside in combination with at least one additional surfactant. 38. A mixture or concentrate of any one of the 1-10 claims, where the aerosol mixture or plant growth control mixture does not exceed a similar packaged mixture containing trimesium glyphosate, diquete or paraquete, and an alkyl polyglycoside surfactant. 39. A mixture or concentration of any one of the claims 1–10, whereby such surfactant is further contained with one or more amine or quaternary ammonium salt compounds, each containing an alkyl or aryl agent of approximately 4 to approximately 16 carbon atoms and no more than ten ethylene oxide bonds within the compound, such compound being present in an amount which increases the compatibility of such surfactant with such glyphosate. 40. A mixture or concentration of claim 39 where such compound is selected from a group of amine or quaternary ammonium salts with the formula: or (chemical formula) (68) or (chemical formula) (69) or (chemical formula) (70), where R1 is a straight or branched alkyl or aryl chain of approximately 4 to approximately 16 carbon atoms; R2 is hydrogen, methyl, ethyl or -(CH2CH2O)xH; R3 is hydrogen, methyl, ethyl or -(CH2CH2O)yH, where the sum of X and Y is not greater than approximately 5; R4 is hydrogen or methyl; R6 in each independent n(R2O) group is C2-C4 alkylene; R5 is hydrocarbilene or substituted hydrocarbilene of approximately 2 to approximately 6 carbon atoms; and A- is the agriculturally acceptable anion. 41. A mixture or concentration of any one of the 1-10 claims, whereby the surfactant is selected from a group consisting of alkoxylated alkylamines, etheramines, and etheramine oxides. 42. A mixture or concentration of claim 41 where such alkoxylated alkylamine consists of a compound with the formula: (chemical formula) (61), where R1 is a straight or branched alkyl chain group consisting of approximately 8 to approximately 22 carbon atoms, where R2 in each group of (R2O) is independent of C2-C4 alkylene; and m+n is the average number ranging from approximately 0 to approximately 60. 43. A mixture or concentration of claim 42, where R1 is a straight-chain alkyl group ranging from approximately 12 to approximately 18 carbon atoms, and m+n is the average number ranging from approximately 2 to approximately 20. 44. A mixture or concentration of claim 43, where m+n is the average number from approximately 2 to approximately 10. 45. A mixture or concentration of claim 42 where such alkoxylated alkylamine contains alkoxylated dodecylamine, alkoxylated stearylamine, alkoxylated cocoamine, or alkoxylated tallowamine. 46. A mixture or concentration of claim 41 where such etheramine consists of a compound with the following structural formula: (chemical formula) (63), where R1 is a straight or branched chain hydrocarbon of approximately 6 to approximately 22 carbon atoms, R2, and R3 in each group of R2O and R3O and R5, independently are C1-C4 alkylene, m is approximately 1 to approximately 10, x and y are the average numbers such that x+y is from 0 to approximately 60, r is 0 or 1, and q is 0 or 1. 47. A mixture or concentration of claim 46, where R1 is a straight or branched alkyl group with approximately 8 to approximately 18 carbon atoms. 48. A mixture or concentration of claim 47, where R1 is a straight or branched alkyl group of approximately 10 to approximately 15 carbon atoms. 49. A mixture or concentration of claim 46 where each R2 is independent linear propylene, isopropylene, or ethylene; each R3 is independent isopropylene or ethylene. 50. A mixture or concentration of claim 46 where each R2 consists of linear propylene and m is 1. 51. A mixture or concentration of claim 46, where each R2 contains isopropylene or ethylene and m is between 2 and 3. 52. A mixture or concentration of claim 46 where each x+y is approximately 2 to approximately 20. 53. A mixture or concentration of claim 52, where each x+y is approximately 2 to approximately 10. 54. A mixture or concentration of claim 53, where each x+y is approximately 2 to approximately 5. 55. A mixture or concentrate of claim 41 where such etheramine consists of a compound with the following structural formula: (chemical formula) (64), where R1 is a straight or branched chain hydrocarbon of approximately 6 to approximately 22 carbon atoms, R2, and R3 in each group of R2O and R3O and R5, independently are C1-C4 alkylones, m is approximately 1 to approximately 10, x and y are the average numbers so that x+y is from 0 to approximately 60, r is 0 or 1, and q is 0 or 1, R4, is a C1-C4 alkyl, and A' is the agriculturally acceptable anion. 56. A mixture or concentration of claim 55, where R1 is a straight or branched alkyl group with approximately 8 to approximately 18 carbon atoms. 57. A mixture or concentration of claim 56, where R1 is a straight or branched alkyl group of approximately 10 to approximately 15 carbon atoms. 58. A mixture or concentration of claim 55 where R2 consists of linear propylene, iso-propylene or ethylene. 59. A mixture or concentration of claim 55 where each R3 is independent, i.e., isopropylene or ethylene. 60. A mixture or concentration of claim 55 where the said R2 group consists of linear propylene and m is 1. 61. A mixture or concentration of claim 55 where R2 contains isopropylene or ethylene and m is between 2 and 3. 62. A mixture or concentration of claim 55 where each x+y is approximately 0 to approximately 20. 63. A mixture or concentration of claim 62, where each x+y is approximately 1 to approximately 10. 64. A mixture or concentration of claim 63, where each x+y is approximately 1 to approximately 5. 65. A mixture or concentration of claim 55, where R4 is methyl and A- is a halide charge. 66. A mixture or concentration of claim 55, where R4 is methyl and A- is a selectable anion from a group consisting of chloride, bromide, phosphate, sulfate, and glyphosate ions. 67. A mixture or concentrate of claim 41 where the etheramine oxide is composed of a compound with the following structural formula: (chemical formula) (65), where R1 is a straight or branched chain hydrocarbon of approximately 6 to approximately 22 carbon atoms, R2, and R3 in each group of R2O and R3O and R5, independently are C1-C4 alkylene, m is approximately 1 to approximately 10, x and y are the average numbers such that x+y is from 0 to approximately 60, r is 0 or 1, and q is 0 or 1, and A' is the agriculturally acceptable anion. 68. A mixture or concentration of claim 67, where R1 is a straight or branched alkyl group with approximately 8 to approximately 18 carbon atoms. 69. A mixture or concentration of claim 68, where R1 is a straight or branched alkyl group of approximately 10 to approximately 15 carbon atoms. 70. A mixture or concentration of claim 69 where each R2 is independent is linear propylene, isopropylene or ethylene. 71. A mixture or concentration of claim 70, where each R3 is independent, is isopropylene or ethylene. 72. A mixture or concentration of claim 71, where R2 consists of linear propylene and m is 1. 73. A mixture or concentration of claim 67 where R2 contains isopropylene or ethylene and m is between 2 and 3. 74. A mixture or concentration of claim 67 where each x+y is approximately 2 to approximately 20. 75. A mixture or concentration of claim 74, where each x+y is approximately 2 to approximately 10. 76. A mixture or concentration of claim 75, where each x+y is approximately 2 to approximately 5. 77. A mixture or concentration of any of the claims 1-10, whereby the surfactant contains the most widely dispersed surfactant. 78. A mixture or concentration of claim 77 whereby the most spreading surfactant is present in a sufficient proportion so that the surface tension of the herbicide mixture is less than approximately 25 dynes/cm². 79. A mixture or concentration of claim 77 where the most widespread surfactant is organosilicon or fluoro-organic. 80. A mixture or concentration of claim 79 where an organosilicon surfactant contains a polysiloxane surfactant. 81. A mixture or concentration of claim 80 where at least one of the siloxane groups has an attached portion containing one or more polyalkylene oxy or polyalkylene oxyalkyl groups. 82. A mixture or concentrate of claim 80 where the polysiloxane surfactant has the following formula: (chemical formula) (59), where R1 is -CnH2nO(CH2CH2O)m(CH2CH(CH3)O)qX, where n is 0 to 6, a is 1 to approximately 3, b is 0 to approximately 10, m is 0 to approximately 30, q is 0 to approximately 3, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are C1-6 hydrocarbils, either unsubstituted or nitrogen-containing groups; X is hydrogen or C1-6 hydrocarbils or C2-6 acyls. 83. A mixture or concentration of claim 82, where a is 1 to 5, b is 0 to 10, n is 3 or 4, m is 1 to approximately 30, q is 0, X is hydrogen or methyl, ethyl or acetyl groups, and R2, R3, R4, R5, R6, R7, R8, R9 and R10 are methyl groups. 84. A mixture or concentration of claim 82, where a is 1 to 5, b is 0 to 10, n is 3 or 4, m is 4 to 12, q is 0, X is hydrogen or methyl or acetyl groups, and R2, R3, R4, R5, R6, R7, R8, R9 and R10 are methyl groups. 85. A mixture or concentration of the claim 82, where the formula for the polysiloxane surfactant is, a = 1, b = 0, n = 3 or 4, m = 1 to approximately 30, b = 0, X = hydrogen or methyl, ethyl or acetyl group, and R2, R3, R4, R5, R6, R7, R8, R9 and R10 = methyl groups. 86. A mixture or concentration of claim 85, where a is 1, b is 0, n is 3, m is 8, b is 0, X is methyl, and R2, R3, R4, R5, R6, R7, R8, R9, and R10 are methyl groups. 87. A mixture or concentration of claim 82 whereby the polysiloxane surfactant contains one or more glycol or glycol derivatives. 88. A mixture or concentration of claim 87 where each glycol or glycol derivative contains 4 or more carbon atoms. 89. A mixture or concentration of claim 87 where such glycol or glycol derivatives have the following structure: HO(RaO)tRb, where the free Ra group is a straight or branched alkyl C2-6 group, t is 1 to approximately 4, and Rb is a hydrogen or a C1-4 hydrocarbil. 90. A mixture or concentration of claim 87, where glycol or glycol derivatives may be selected from: The group comprises only monoethylene glycol and methyl, ethyl, n-propyl, n-butyl and t-butyl monoethers and their diethers; diethylene glycol and methyl, ethyl, n-propyl, n-butyl and t-butyl monoethers and their diethers; propylene glycol and methyl, ethyl, n-propyl, n-butyl and t-butyl monoethers and their diethers; dipropylene glycol and methyl, ethyl, n-propyl, n-butyl or t-butyl monoethers and their diethers; tripropylene glycol and methyl, ethyl, n-propyl, n-butyl or t-butyl monoethers and their diethers; 1,3-butanediol. 1,4-butanediol, 2-methyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 2-methyl-1,3-pentanediol, and 2-methyl-2,4-pentanediol. 91. A mixture of any one of the claims 1-3 whereby the surfactant is present in a concentration of approximately 0.02 to approximately 10.7 g/L of the said herbicide mixture. 92. A mixture of claims 91 whereby the surfactant is present in a concentration of approximately 0.65 to approximately 6.4 grams per liter of the said herbicide mixture. 93. A mixture of claims 92 whereby the said surfactant is present in a concentration of approximately 1.33 to approximately 4.3 grams per liter of the said herbicide mixture. 94. A mixture of any one of the claims 1-3 whereby such herbicide mixture contains from approximately 2 to approximately 36 g a.e. per liter of glyphosate, approximately 0.02 to approximately 10.7 g per liter of surfactant, and approximately 0.025 to approximately 0.75 g c.e. per liter of bipyridylium. 95. A mixture of claims 94 whereby such herbicide mixture contains from approximately 4 to approximately 18 g a.e. per liter of glyphosate, approximately 0.65 to approximately 6.4 g per liter of surfactant, and approximately 0.05 to approximately 0.3 g c.e. per liter of bipyridylium. 96. A mixture of claims 95 whereby such herbicide mixture contains from approximately 6 to approximately 11 g a.e. per liter of glyphosate, approximately 1.33 to approximately 4.3 g per liter of surfactant, and approximately 0.07 to approximately 0.2 g c.e. per liter of bipyridylium. 97. A mixture of any one of the claims 1-3 whereby glyphosate or its herbicide derivatives are present in a concentration of approximately 2 to approximately 36 g a.e. per liter of such herbicide mixture. 98. A mixture of claims 97 where glyphosate or its herbicide derivatives are present in a concentration of approximately 4 to approximately 18 g a.e. per liter of such herbicide mixture. 99. A mixture of claims 98 where glyphosate or its herbicide derivatives are present in a concentration of approximately 6 to approximately 11 grams of acid equivalent per liter of such herbicide mixture. 100. A mixture of concentrated substances of claims 1-10 where bipyridylium or its herbicide derivatives contain diqueth, paraqueth or a mixture thereof. 101. A mixture or concentration of claim 100 where the dique contains the salt of the dique. 102. A mixture or concentration of claim 101 where the salt of the dique contains dique halide. 103. A mixture or concentration of claim 100 where paraquat contains salts of paraquat. 104. A mixture of any one of the claims 1-3 where bipyridylium is present at a concentration ranging from approximately 0.025 to approximately 0.75 g c.e. per liter of the said herbicide mixture. 105. A mixture of claim 104 in which bipyridylium is present at a concentration ranging from approximately 0.05 to approximately 0.3 g c.e. per liter of the said herbicide mixture. 106. A mixture of claim 105 in which bipyridylium is present at a concentration ranging from approximately 0.07 to approximately 0.2 g c.e. per liter of the said herbicide mixture. 107. A mixture or concentrate of any of the claims 1-10 where glyphosate or its herbicide derivatives contain salts of glyphosate, and bipyridylium or its herbicide derivatives contain salts of diquethate. 108. A mixture or concentration of claim 107 in which glyphosate or its herbicide derivatives contain alkali metal salts, ammonium, C1-16 alkylammonium, C1-16 alkanol ammonium or C1-16 alkylsulfonium of glyphosate, and bipolydylium or its herbicide derivatives contain diqueth halides. 109. A mixture of any one of the claims 1–3, in which glyphosate or its herbicide derivatives are present in a concentration of approximately 2 to approximately 36 g a.e. per liter of such herbicide mixture, and bipyridylium derivatives or its herbicide derivatives are present in a concentration of approximately 0.025 to approximately 0.75 g c.e. per liter of such herbicide mixture. 110. A mixture of claim 109 where glyphosate or its herbicide derivatives are present in a concentration of approximately 4 to approximately 18 g a.e. per liter of such herbicide mixture, and bipyridylium derivatives or its herbicide derivatives are present in a concentration of approximately 0.05 to approximately 0.3 g c.e. per liter of such herbicide mixture. 111. A mixture of claim 110 where glyphosate or its herbicide derivatives are present in a concentration of approximately 6 to approximately 11 g a.e. per liter of such herbicide mixture, and bipyridylium derivatives or its herbicide derivatives are present in a concentration of approximately 0.07 to approximately 0.2 g c.e. per liter of such herbicide mixture. 112. The concentration of claim 9 or 10, where the concentration is a solid, particulate matter that is soluble in water. 113. A concentration of claim 9 or 10, which is further composed of a highly dispersible surfactant present in a sufficient proportion so that the surface tension of the resulting mixture, obtained by dissolving or dispersing such solid concentrate in water, is a convenient concentration less than approximately 25 dynes/cm². 114. Concentrated formulations of claim 9 or 10 where glyphosate or its herbicide derivatives are present in concentrations of approximately 50% to approximately 95% by weight of such particulate matter. 115. A concentration of claim 114 where glyphosate or its herbicide derivatives are present in a concentration of approximately 60% to approximately 90% by weight of such particulate solids. 116. Concentrated formulation of claim 115 where glyphosate or its herbicide derivatives are present in concentrations of approximately 65% to approximately 85% by weight of such particulate matter. 117. Concentrates of claim 9 or 10 in which bipyridylium is present at approximately 0.5% to approximately 3% by weight (c.e.) of such particulate matter. 118. The concentration of claim 117 where bipyridylium is present at approximately 1% to approximately 2.5% by weight (c.e.) of such particulate matter. 119. The concentration of claim 118, where bipyridylium is present at approximately 1.3% to approximately 2% by weight (c.e.) of such particulate matter. 120. Concentrated formulations of claim 9 or 10 where glyphosate or its herbicide derivatives are present in concentrations of approximately 50% to approximately 95% by weight of such herbicide mixture, and bipyridylium or its herbicide derivatives are present in concentrations of approximately 0.5% to approximately 3% by weight (c.e.) of such particulate solids. 121. Concentration of claim 120 where glyphosate or its herbicide derivatives are present in concentrations of approximately 60% to approximately 90% by weight of such herbicide mixture, and bipyridylium or its herbicide derivatives are present in concentrations of approximately 1% to approximately 2.5% by weight (c.e) of such particulate solids. 122. Concentrated formulation of claim 121 where glyphosate or its herbicide derivatives are present in concentrations of approximately 65% to approximately 85% by weight of such herbicide mixture, and bipyridylium or its herbicide derivatives are present in concentrations of approximately 1.3% to approximately 2% by weight (c.e) of such particulate matter. 123. Concentration of claim 80 where the polysiloxane surfactant is present at approximately 5% to approximately 40% by weight of the particulate matter. 124. Concentration of claim 123 where the polysiloxane surfactant is present at approximately 7% to approximately 30% by weight of the particulate matter. 125. Concentration of claim 124 where the polysiloxane surfactant is present at approximately 10% to approximately 25% by weight of the particulate matter. 126. Concentrates of claim 9 or 10 where such solid particulate concentrates consist of approximately 50% to approximately 90% by weight of glyphosate, 0 to approximately 1% by weight of antioxidant, 0 to approximately 2% by weight of antifoaming agent, approximately 5% to approximately 40% by weight of surfactant, and approximately 0.5% to approximately 3% by weight of bipyridylium. 127. The concentrate of claim 126, whereby such a solid particle concentrate consists of approximately 60% to approximately 90% by weight of glyphosate, 0.2% to approximately 0.8% by weight of antioxidant, approximately 0.2% to approximately 1.5% by weight of antifoaming agent, approximately 7% to approximately 30% by weight of surfactant and approximately 1% to approximately 2.5% by weight of bipyridylium. 128. The concentrate of claim 127, whereby such particle solid concentrate consists of approximately 70% to approximately 85% by weight of glyphosate, 0.3% to approximately 0.5% by weight of antioxidant, 0.6% to approximately 1.0% by weight of antifoaming agent, 10% to approximately 25% by weight of surfactant, and 1.3% to 2% by weight of bipyridylium. 129. Any concentrate of claims 126-128 where the glyphosate mentioned contains ammonium glyphosate, the antioxidant mentioned contains sodium sulfite, the surfactant mentioned contains Silwet 800, and the bipyridylium mentioned contains diqueth. 130. A concentration of any one of the claims 4-8 where the surfactant is present in a sufficient proportion so that the surface tension of the herbicide mixture is less than approximately 25 dynes/cm². 131. A concentrated solution of any one of claims 4-8, where the surfactant contains an etheramine surfactant. 132. A concentrated form of any one of the claims 4-8, where the surfactant contains organo-silicones. 133. Concentrated solution of claim 132, whereby the surfactant contains polysiloxane. 134. A concentrate of any one of the claims 4-8 where glyphosate or its herbicide derivatives are present in a concentration of approximately 5 g a.e. per liter to approximately 550 g a.e. per liter of such liquid concentrate. 135. Concentrated formulations of claim 134 where glyphosate or its herbicide derivatives are present in concentrations of approximately 50 g a.e. per liter to approximately 450 g a.e. per liter of such liquid concentrate. 136. Concentrated formulation of claim 135 where glyphosate or its herbicide derivatives are present in concentrations of approximately 150 g a.e. per liter to approximately 350 g a.e. per liter of such liquid concentrate. 137. A concentrate of any one of the claims 4-8 where bipyridylium is present in a concentration of approximately 0.1 g c.e. per liter to approximately 50 g c.e. per liter of the liquid concentrate. 138. The concentrate of claim 137 where bipyridylium is present in concentrations of approximately 1 g c.e. per liter to approximately 40 g c.e. per liter of the liquid concentrate. 139. The concentrate of claim 138 where bipyridylium is present in a concentration of approximately 3 g c.e. per liter to approximately 35 g c.e. per liter of the liquid concentrate. 140. A concentrate of any one of the claims 4-8 where glyphosate or its herbicide derivatives are present in concentrations of approximately 5 g a.e. per liter to approximately 550 g a.e. per liter of such liquid concentrate, and bipyridylium or its herbicide derivatives are present in concentrations of approximately 0.1 g c.e. per liter to approximately 50 g c.e. per liter of such liquid concentrate. 141. Concentrated formulations of claim 140 where glyphosate or its herbicide derivatives are present in concentrations of approximately 50 g a.e. per liter to approximately 450 g a.e. per liter of such liquid concentrate, and bipyridylium or its herbicide derivatives are present in concentrations of approximately 1 g c.e. per liter to approximately 40 g c.e. per liter of such liquid concentrate. 142. Concentrated formulations of claim 141 where glyphosate or its herbicide derivatives are present in concentrations of approximately 150 g a.e. per liter to approximately 350 g a.e. per liter of such liquid concentrate, and bipyridylium or its herbicide derivatives are present in concentrations of approximately 3 g c.e. per liter to approximately 35 g c.e. per liter of such liquid concentrate. 143. A concentrated solution of any one of the claims 4-8, whereby the surfactant contained is an alkoxylated alkylamine. 144. A method for killing weeds or controlling the growth of unwanted plants consisting of a procedure of contact between the leaves of such plants and the herbicide mixture of one of the three claims. 145. A method for killing weeds or controlling weeds or unwanted plants consisting of the following steps: (a) diluting one of the liquid concentrates of any of the four or eight claims in a convenient amount of water to form a work mixture; and (b) applying the effective weed-killing amount of the work mixture to the leaves of the weed or unwanted plant. 146. A method for killing weeds or controlling weeds or unwanted plants consisting of the following steps: (a) diluting a concentrated solid particle type of claim 9 or 10 in a convenient amount of water to form an application mixture; and (b) applying the effective weed-killing amount of the application mixture to the leaves of the weed or unwanted plant. 147. Method for preparing a solid particulate concentrate consisting of a mixture of glyphosate or its herbicide derivatives, a highly spreading surfactant, and bipyridylium. 148. Any of the claims 144-147 shall apply, whereby the surfactant contains the most widely spreading surfactant. 149. A method of claim 148 where the most spreading surfactant is present in a sufficient proportion so that the surface tension of the herbicide mixture is less than approximately 25 dynes/cm². 150. Method of Claim 148 where the most widely dispersed surfactant consists of organosilicon or fluoro-organic compounds. 151. Method of Claim 150 where an organosilicon surfactant contains a polysiloxane surfactant. 152. Method of claim 151 where at least one of the siloxanes has an attached portion consisting of one or more polyalkylene oxy or polyalkylene oxyalkyl groups. 153. Any of the claims 144-147 apply, where the polysiloxane surfactant has the following formula: (chemical formula) (59), where R1 is -CnH2nO(CH2CH2O)m(CH2CH(CH3)O)qX, where n is 0 to 6, a is 1 to approximately 3, b is 0 to approximately 10, m is 0 to approximately 30, q is 0 to approximately 3, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are C1-6 hydrocarbils, either unsubstituted or nitrogen-containing groups; X is hydrogen or C1-6 hydrocarbils or C2-6 acyls. 154. Method of claim 153, where a is 1 to 5, b is 0 to 10, n is 3 or 4, m is 1 to approximately 30, q is 0, X is hydrogen or methyl, ethyl or acetyl group, and R2, R3, R4, R5, R6, R7, R8, R9 and R10 are methyl groups. 155. Method of claim 153, where a is 1 to 5, b is 0 to 10, n is 3 or 4, m is 4 to 12, q is 0, X is hydrogen or methyl or acetyl group, and R2, R3, R4, R5, R6, R7, R8, R9 and R10 are methyl groups. 156. Method of claim 153, where the formula for the said polysiloxane surfactant, a is 1, b is 0, n is 3 or 4, m is 1 to approximately 30, b is 0, X is hydrogen or methyl, ethyl or acetyl groups, and R2, R3, R4, R5, R6, R7, R8, R9 and R10 are methyl groups. 157. Method of claim 156, where a is 1, b is 0, n is 3, m is 8, b is 0, X is methyl, and R2, R3, R4, R5, R6, R7, R8, R9, and R10 are methyl groups. 158. Method of claim 153 where such polysiloxane surfactant is further composed of one glycol or glycol derivatives or more. 159. Method of claim 158 where each glycol or glycol derivative contains 4 or more carbons. 160. Method of claim 158 where the glycol or its glycol derivatives have the following structure: HO(RaO)tRb, where the free Ra group is a straight or branched alkyl C2-6 group, t is 1 to approximately 4, and Rb is a hydrogen or hydrocarbil C1-4 group. 161. Method of claim 158 where glycol or glycol derivatives are selected from the group. It consists of monoethylene glycol and methyl, ethyl, n-propyl, n-butyl and t-butyl monoethers and their diethers; diethylene glycol and methyl, ethyl, n-propyl, n-butyl and t-butyl monoethers and their diethers; propylene glycol and methyl, ethyl, n-propyl, n-butyl and t-butyl monoethers and their diethers; dipropylene glycol and methyl, ethyl, n-propyl, n-butyl or t-butyl monoethers and their diethers; tripropylene glycol and methyl, ethyl, n-propyl, n-butyl or t-butyl monoethers and their diethers; 1,3-butanediol; 1,4-butane. Diol, 2-methyl-1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 2-methyl-1,3-pentanediol and 2-methyl-2,4-pentanediol. 162. Method of claim 153 whereby a mixture or application compound is applied to pastures at a rate resulting in the use of polysiloxane surfactants of approximately 0.1 to approximately 9 pounds a.e. per acre of such pasture. 163. Method of claim 162 whereby a mixture or application compound is applied to pastures at a rate resulting in the use of a polysiloxane surfactant of approximately 0.25 to approximately 5.5 pounds a.e. per acre of such pasture. 164. Method of claim 163 whereby a mixture or application compound is applied to pastures at a rate resulting in the use of a polysiloxane surfactant of approximately 0.55 to approximately 3.5 pounds a.e. per acre of such pasture. 165. Method of Claim 153 whereby a mixture or compounds of application are applied to pastures at rates resulting in the use of glyphosate at approximately 0.5 to approximately 12 pounds a.e. per acre, polysiloxane surfactant at approximately 0.1 to approximately 9 pounds a.e. per acre, and bipyridylium at approximately 0.01 to approximately 0.5 pounds a.e. per acre of such pasture. 166. Method of Claim 165 whereby a mixture or compounds of application are applied to pastures at rates resulting in the use of glyphosate at approximately 3 to approximately 9 pounds a.e. per acre, the surfactant polysiloxane at approximately 0.25 to approximately 5.5 pounds a.e. per acre, and bipyridylium at approximately 0.025 to approximately 0.25 pounds a.e. per acre of such pasture. 167. Method of Claim 166 whereby a mixture or compounds of application are applied to pastures at rates resulting in the use of glyphosate at approximately 4.5 to approximately 7.5 pounds a.e. per acre, polysiloxane surfactants at approximately 0.55 to approximately 3.5 pounds a.e. per acre, and bipyridylium at approximately 0.0625 to approximately 0.15 pounds a.e. per acre of such pasture. 168. The method of claim 147, which is further comprised of the combination of antioxidants, glyphosate, antifoaming agents, highly spreading surfactants and bipyridylium. 169. The method of claim 168, which is further comprised of: mixing the antioxidant and glyphosate to form the first mixture; mixing the antifoaming agent and polysiloxane surfactant to form the second mixture; mixing the said mixture with the first mixture to form the third mixture; mixing bipyridylium with the third mixture to form the particulate solid. 170. Any one of the claims 144-147, 168, or 169, where glyphosate or its herbicide derivatives contain glyphosate salts. 171. Method of claim 170 where salts of glyphosate consist of alkali metal salts, ammonium, C1-16 alkylammonium, C1-16 alkanolammonium, or C1-16 alkylsulfonium salts of glyphosate. 172. Any of the claims under Articles 144–146 shall, by means of such mixture or application mixture, be applied to pastures at a rate that results in the application of glyphosate of approximately 0.5 to approximately 12 pounds a.e. per acre of pasture. 173. The method of claim 172 where such mixture or application mixture is applied to pastures at an effective rate of glyphosate application of approximately 3 to approximately 9 pounds a.e. per acre of such pasture. 174. Method of claim 173 where such mixture or application mixture is applied to pastures at an effective rate of glyphosate application of approximately 4.5 to approximately 7.5 pounds a.e. per acre of such pasture. 175. The method of any one of the claims 144-147, 168 or 169, where bipyridylium or its herbicide derivatives contain diqueth or paraqueth. 176. The method of claim 175 where the dique contains the salt of the dique. 177. Method of claim 176 where the salt of diqueth contains diqueth halide. 178. Method of claim 175 where paraquat contains salts of paraquat. 179. Any of the claims under Sections 144–146 shall, by means of such mixture or application mixture, be applied to pastures at a rate that results in the use of bipyridylium of approximately 0.01 to approximately 0.5 pound a.e. per acre of pasture. 180. Method of Claim 179 whereby the said mixture or application mixture is applied to pastures at an effective rate of use of bipyridylium of approximately 0.025 to approximately 0.25 pounds a.e. per acre of said pasture. 181. Method of Claim 180 whereby the said mixture or application mixture is applied to pastures at an effective rate of use of bipyridylium of approximately 0.0625 to approximately 0.15 pounds a.e. per acre of said pasture. 182. In accordance with any one of the claims 144-147, 168 or 169, where glyphosate or its herbicide derivatives contain salts of glyphosate, and bipyridylium or its herbicide derivatives contain salts of diquethate. 183. The method of claim 182 by glyphosate or its herbicide derivatives consisting of alkali metal salts, ammonium, C1-16 alkylammonium, C1-16 alkanolammonium or C1-16 alkylsulfonium salts of glyphosate, and bipyridylium or its herbicide derivatives consisting of diqueth halide salts. 184. Any of the claims under Sections 144–149 shall, by means of such mixture or its application mixture, be applied to pastures at a rate resulting in the use of glyphosate of approximately 0.5 to approximately 12 pounds a.e. per acre of pasture, and bipyridylium of approximately 0.01 to approximately 0.5 pounds c.e. per acre of pasture. 185. Method of Claim 1184 where such mixture or application mixture is applied to pastures at an effective rate of glyphosate of approximately 3 to approximately 9 pounds a.e. per acre of such pasture, and bipyridylium of approximately 0.025 to approximately 0.25 pounds c.e. per acre of such pasture. 186. Method of Claim 185 whereby the said mixture or application mixture is applied to pastures at an effective rate of glyphosate application of approximately 4.5 to approximately 7.5 pounds a.e. per acre of such pasture, and bipyridylium at approximately 0.0625 to approximately 0.15 pounds c.e. per acre of such pasture. 187. Method of claim 147 where the maximum dispersible surfactant present in a sufficient proportion so that the surface tension of the mixture obtained by dissolving or dispersing such concentrated solid particle in water is a convenient concentration less than approximately 25 dynes/cm². 188. The method of claim 147 where glyphosate or its herbicide derivatives are present in a concentration of approximately 50% to approximately 90% by weight of such concentration. 189. The method of claim 188 where glyphosate or its herbicide derivatives are present in a concentration of approximately 60% to approximately 90% by weight of such concentration. 190. The method of claim 189 where glyphosate or its herbicide derivatives are present in a concentration of approximately 70% to approximately 85% by weight of such concentrate. 191. Method of claim 147 where bipolydylium is present at approximately 0.5% to approximately 3% by weight c.e. of such concentration. 192. Method of claim 191 where bipolydylium is present at approximately 1% to approximately 2.5% by weight c.e. of such concentration. 193. The method of claim 192 where bipolydylium is present at approximately 1.3% to approximately 2% by weight c.e. of such concentration. 194. The method of claim 147 where glyphosate or its herbicide derivatives are present in concentrations of approximately 50% to approximately 90% by weight of such herbicide mixture, and bipyridilium or its herbicide derivatives are present at approximately 0.5% to approximately 3% by weight of such concentration. 195. The method of claim 194 states that glyphosate or its herbicide derivatives are present in concentrations of approximately 60% to approximately 90% by weight of such herbicide mixture, and bipyridilium or its herbicide derivatives are present at approximately 1% to approximately 2.5% by weight of such concentration. 196. The method of claim 195 where glyphosate or its herbicide derivatives are present in concentrations of approximately 70% to approximately 85% by weight of such herbicide mixture, and bipyridilium or its herbicide derivatives are present at approximately 1.3% to approximately 2% by weight of such concentration. 197. The method of claim 147 where the said surfactant contains polysiloxane surfactants which make up approximately 5% to 40% by weight of the said concentration. 198. The method of claim 197, whereby the polysiloxane surfactant is present in approximately 7% to 30% by weight of the concentration. 199. The method of claim 198, whereby the polysiloxane surfactant is present in approximately 10% to 25% by weight of the concentration. 200. Method of claim 197 where the solid particulate concentrate contains approximately 50% to approximately 90% by weight of glyphosate, 0 to 1% by weight of antioxidant, 0 to 2% by weight of antifoaming agent, 5% to 40% by weight of surfactant and 0.5% to 3% by weight of bipyridylium. 201. Method of claim 200 where the solid particulate concentrate contains approximately 60% to 90% by weight of glyphosate, 0.2 to 0.8% by weight of antioxidant, 0.2 to 1.5% by weight of antifoaming agent, 7% to 30% by weight of surfactant and 1% to 2.5% by weight of bipyridylium. 202. The method of claim 201 whereby the solid particulate concentrate contains approximately 70% to approximately 85% by weight of glyphosate, 0.3 to 0.5% by weight of antioxidant, 0.6 to 1.0% by weight of antifoaming agent, 10% to 25% by weight of surfactant and 1.3% to 2% by weight of bipyridylium. 203. Any of the methods of claims 200-202, where the glyphosate in question contains ammonium glyphosate, the antioxidant in question contains sodium sulfite, the surfactant in question contains Siiwet 800, and the bipyridylium in question contains diqueth. 204. Method of claim 168 or 169 where such antioxidant contains sodium sulfite. 205. Method of claim 168 or 169 where such antioxidant contains ascorbic acid. 206. Method of claim 168 or 169 where such antioxidant contains Y-14088 anti-foaming agent. 207. The method of claim 169, which continues with the purification of the said particulate solids, 208. The method of claim 207 where such purification consists of passing the concentrated, solid particulate matter through the first mesh sieve and then through the second mesh sieve. 209. The method of claim 208, where the first mesh sieve consists of 12 mesh sieves. 210. Method of claim 209, where the second mesh grid consists of +40 mesh grids. 211. A mixture or concentrate of any of the claims 1-10, in which the surfactant is chosen from a group consisting of: (a) an alkoxylated poly(hydroxyalkyl)amine with the formula: (chemical formula) (11), where R1 and R3 are independent hydrogen, hydrocarbilyl or substituted hydrocarbilyls ranging from 1 to approximately 30 carbon atoms; R2 in each case of the x(R2O) group is independent C2-C4 alkylene; R1 is a hydrocarbilyl or substituted hydrocarbilyls ranging from 1 to approximately 30 carbon atoms; R5 is a hydroxyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl; x is the average number ranging from 0 to approximately 30, and y is 0 or 1; (b) Di-poly(hydroxyalkyl)amines with the formula: (chemical formula) (14), where R1 and R3 are independent, either hydrogen or hydrocarbil or substituted hydrocarbil ranging from 1 to approximately 22 carbon atoms; R2 is hydrocarbil or substituted hydrocarbil ranging from 2 to approximately 18 carbon atoms; R4 and R5 are independent, either hydroxyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl, defined as, however, where R1 and R3 are methyl, R2 is in addition to octylene; (c) Alkoxylate amine oxides with the formula: (chemical formula) (31), where R1 is hydrogen or hydrocarbil or substituted hydrocarbil ranging from 1 to approximately 30 carbon atoms; the R2 groups in each x(R2O) and y(R2O) are independent, either C2-C4 alkylene; R3 is a hydrocarbilite or substituted hydrocarbilite with 2 to approximately 6 carbon atoms; R4 and R5, each independent, are hydrogen, hydrocarbilite, or substituted hydrocarbilite with 1 to approximately 30 carbon atoms, -(R6)n-(R2O)yR7; R6 is a hydrocarbilite or substituted hydrocarbilite with 1 to approximately 6 carbon atoms; R7 is a hydrogen or straight or branched alkyl chain with 1 to approximately 4 carbon atoms; n is 0 or 1, and x and y, independently, are average numbers ranging from 1 to approximately 60; (d) Dialoxylated alcohols with the formula: R1(OR2)xO ---- R3 --- O --- (R2O)yR1 (42), where R1 is independent, is a hydrogen or straight or branched alkyl group ranging from approximately 1 to approximately 4 carbon atoms, R2 in each case of independent x(R2O) and y(R2O) is a C2-C4 alkylene, R3 is a hydrocarbilene or substituted hydrocarbilene ranging from 2 to approximately 30 carbon atoms, and x and y independent are an average number ranging from 1 to approximately 60. (e) Compounds with the formula (chemical formula) (44) or (chemical formula) (45) or (chemical formula) (46) or (chemical formula) (47) or (chemical formula) (48) or (chemical formula) (49) or (chemical formula) (50) or (chemical formula) (51), where R1, R9 and R12 Free R2 is a hydrocarbil or a substituted hydrocarbil containing 1 to approximately 30 carbon atoms, or -(R6O)pR13; in each group m(R2O), n(R2O), p(R2O), and q(R2O) are free C2-C4 alkylenes; R3, R8, R11, R13, and R15 are free hydrogen, or hydrocarbil or a substituted hydrocarbil containing 1 to approximately 30 carbon atoms; R4 is -(CH2)y-OR13 or -(CH2)yO(R2O)qR3; R5, R6, and R7 are free hydrogen, hydrocarbil, or a substituted hydrocarbil containing 1 to approximately 30 carbon atoms, or R4; R10 is a hydrocarbil or a substituted hydrocarbil containing 2 to approximately 30 carbon atoms. R14 is a hydrocarbil or a substituted hydrocarbil with 1 to approximately 30 carbon atoms, or -(CH2)zO(R2O)pR3; m, n, p, and q are independent, being the average number from 1 to approximately 50; X is independent, being -O-, -n(R14), -C(O)-, -C(O)O-, -OC(O)-, -N(R15)C(O)-, -C(O)N(R15)-, -S-, -SO-, or -SO2-; t is 0 or 1; A- is the agriculturally acceptable anion. and y and z are independent, i.e., integers from 0 to approximately 30; (f) Aminated alkoxylated alcohols with the formula: (chemical formula) (1) or (chemical formula) (2), where R1 is hydrogen or hydrocarbil or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms; R2 is the group in each x(R2O) and y(R2O) dependent on C2-C4 alkylenes; R3 and R6 are each independent, i.e., hydrocarbil or substituted hydrocarbils ranging from 1 to approximately 6 carbon atoms; R4 is hydrogen, hydrocarbil or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms, hydrocarbil replaced by hydroxyl, -(R6)n-(R2O)yR7, -C(=NR11)NR12R13, -C(=O)NR12R13, -C(=S)NR12R13. Or in combination with R5 and the nitrogen atom to which it is attached, forming a cyclic or heterocyclic ring; R5 is a hydrogen, hydrocarbil, or substituted hydrocarbil with 1 to about 30 carbon atoms, a hydroxyl substituted hydrocarbil, -(R6)n- (R2O)yR7, C(=NR11)NR12R13, -C(=O)NR12R13, -C(=S)NR12R13, or in combination with R4 and the nitrogen atom to which it is attached, forming a cyclic or heterocyclic ring; R7 is a hydrogen or alkyl group, straight or branched chain with 1 to about 4 carbon atoms; R11, R12 and R13 are hydrogen, hydrocarbil or substituted hydrocarbil, R14 is hydrogen, hydrocarbil or substituted hydrocarbil with 1 to about 30 carbon atoms, hydroxyl substituted hydrocarbil, -(R6)n-(R2O)yR7, C(=NR11)NR12R13, -C(=O)NR12R13, or -C(=S)NR12R13, n is 0 or 1, x and y are independent, being average numbers from 1 to about 60, and A is the agriculturally acceptable anion; (g) hydroxylated amines with the formula: (chemical formula) (3) where R1 is a hydrocarbil or substituted hydrocarbil with 4 to about 30 carbon atoms; R2 is a hydrogen or hydrocarbil or a substituted hydrocarbil with 1 to about 30 carbon atoms, and R3 is a hydroxyalkyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl; (h)diamine with the formula: (chemical formula) (5) where R1, R2 and R5 are independent hydrogen or hydrocarbil or a substituted hydrocarbil with 1 to about 30 carbon atoms or -R8(OR9)nOR10, R3 is a hydrocarbil or a substituted hydrocarbil with 2 to about 18 carbon atoms, R6 and R9 are hydrocarbil. or specific hydrocarbils with approximately 2 to approximately 4 carbon atoms, R4 and R10 are free, which are hydrogen or hydrocarbils or substituted hydrocarbils with approximately 1 to approximately 30 carbon atoms, m is 0 or 1, n is the average number from 0 to approximately 40, and X is -C(O)- or -SO2-; (i) mono- or diammonium salts with the formula: (chemical formula) (6) or (chemical formula) (7), where R1, R2, R4, R5 and R7 are free, which are hydrogen or hydrocarbils or substituted hydrocarbils with approximately 1 to approximately 30 carbon atoms or -R8(OR9)nOR10, R6 is a hydrocarbil or or substituted hydrocarbils with approximately 1 to approximately 30 carbon atoms, R3 is a hydrocarbil. or substituted hydrocarbils with 2 to about 18 carbon atoms, R8 and R9 are hydrocarbils or substituted hydrocarbils with 2 to about 4 carbon atoms, R10 is hydrogen or hydrocarbils or substituted hydrocarbils with 1 to about 30 carbon atoms, m is 0 or 1, n is the average number from 0 to about 40, X is -C(O)- or -SO2-, Z is -C(O)-, and A' is the agriculturally acceptable anion; (j) poly(hydroxyalkyl)amines with the formula: (chemical formula) (8) where R1 is a hydrocarbil or substituted hydrocarbils with 4 to about 30 carbon atoms or -R4OR5, R2 is hydrogen or hydrocarbils or substituted hydrocarbils with 1 to about 30 carbon atoms. (k)di-di-di-di-di-di-di(hydroxyalkyl)amines with the formula: (chemical formula) (14) where R1 and R3 are independent hydrogen or hydrocarbil or hydrocarbil substitutes with 1 to 22 carbon atoms; R2 is a hydrocarbil substitute or hydrocarbil substitutes with 2 to 18 carbon atoms; and R4 and R5 are independent hydroxyalkyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl; (l) Quaternary poly(hydroxyalkyl)amine salts with the formula: (chemical formula) (16), where R1 is a hydrocarbil or a substituted hydrocarbil ranging from 4 to 30 carbon atoms; R2 and R3 are free, which are hydrogen or a hydrocarbil or a substituted hydrocarbil ranging from 1 to 30 carbon atoms; and R4 is a hydroxyalkyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl; (m) Diamines with the formula: (chemical formula) (19), where R1 is a hydrocarbil or a substituted hydrocarbil ranging from 1 to 30 carbon atoms; R2, R3, R4, and R5 are free, which are hydrogen, a hydrocarbil, or a substituted hydrocarbil ranging from 1 to 30 carbon atoms; or -(R8)s(R7O)nR6, where R6 is a hydrogen or alkyl chain. (m) Secondary or tertiary amines with the formula: (chemical formula) (23) where R1 and R2 are independent hydrocarbils with 1 to approximately 30 carbon atoms, and R3 is a hydrogen or hydrocarbil with 1 to approximately 30 carbon atoms; (o) Monoalkoxylated amines with the formula: (chemical formula) (24), where R1 and R4 are independent, either hydrocarbils or substituted hydrocarbils ranging from 1 to about 30 carbon atoms, or -R5SR6, R2 in each case of the X group (R2O) is independent, either C2-C4 alkylene, R3 is hydrogen, or a straight or branched alkyl chain group ranging from 1 to about 4 carbon atoms, R5 is a straight or branched alkyl chain group ranging from 6 to about 30 carbon atoms, R6 is a hydrocarbil or or (p) Quaternary ammonium dialxoxylated salts with the formula: (chemical formula) (25) where R1 is a hydrocarbil or a substituted hydrocarbil with 1 to approximately 30 carbon atoms, R2 in each case of independent x (R2O) and y (R2O) groups is C2-C4 alkylene, R3 is hydrogen, or straight or branched alkyl groups with 1 to approximately 4 carbon atoms, R4 is hydrogen or a hydrocarbil or a substituted hydrocarbil with 1 to approximately 30 carbon atoms, x and y independent are average numbers from 1 to approximately 40, and X- is the agriculturally acceptable anion; (q) Quaternary ammonium monoalkoxylated salts with the formula: (chemical formula) (26), where R1 and R5 are free, either hydrogen or hydrocarbil or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms, R4 is a hydrocarbil or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms, R2 in each case of the x-(R2O) group is free, either C2-C4 alkylene, R3 is hydrogen, or straight or branched alkyl groups ranging from 1 to approximately 30 carbon atoms, x is the average number ranging from 1 to approximately 60, and X- is the agriculturally acceptable anion; (r) Quaternary ammonium salt with the formula: (chemical formula) (27) where R1, R3 and R4 are free hydrogen or hydrocarbil or substituted hydrocarbils containing from 1 to about 30 carbon atoms, R2 is hydrocarbil or substituted hydrocarbils containing from 1 to about 30 carbon atoms, and X- is the agriculturally acceptable anion; (s) Etheramines with the formula: (chemical formula) (28) where R1 is a hydrocarbil or a substituted hydrocarbil with 1 to approximately 30 carbon atoms, R2 is a hydrocarbil or a substituted hydrocarbil with 2 to approximately 30 carbon atoms, R3 and R4 are free, which are hydrogen, hydrocarbil or a substituted hydrocarbil with 1 to approximately 30 carbon atoms, or -(R5O)xR6,R5 in each case of the group x (R5O) is free, which is a C2-C4 alkylene, R6 is hydrogen, or a straight or branched alkyl group with 1 to approximately 4 carbon atoms, and x is the average number from 1 to approximately 50; (t) Diamines with the formula: (chemical formula) (29) where R1,R3,R4 and R5 are free, which are hydrogen, hydrocarbil or a substituted hydrocarbil with 1 to approximately 30 carbon atoms, or -(R6O)xR7, R2, and R8 are independent hydrocarbilites or substituted hydrocarbilites ranging from 2 to approximately 30 carbon atoms; R6 in each case is the independent x (R6O) and y (R5O) groups; C2-C4 alkylenes; R7 is hydrogen, or straight or branched alkyl groups ranging from approximately 1 to approximately 30 carbon atoms; x is the average number from 1 to approximately 30; X is -O-, -N(R6), -C(O)-, -C(O)O-, -OC(O)-, N(R9)C(O)-, -C(O)N(R9)-, -S-, -SO-, or -SO2-; y is 0 or the average number from 1 to approximately 3; n and z are independent 0 or 1; and R9 is hydrogen, hydrocarbilite, or substituted hydrocarbilite. (u) An amine oxide with the formula: (chemical formula) (30) where R1, R2 and R3 are free, hydrogen, hydrocarbil or substituted hydrocarbil - (R4O)xR5, or - R6(OR4)xR5;R4 In each case, the x(R4O) group is independent, i.e., C2-C4 alkylene; R5 is a hydrogen or hydrocarbil or a substituted hydrocarbil ranging from 1 to approximately 30 carbon atoms, R6 is a hydrocarbil or a substituted hydrocarbil ranging from 1 to approximately 6 carbon atoms, x is the average number ranging from 1 to approximately 50, and the total number of carbon atoms in R1, R2 and R3 is at least 8; (v) dialxoxylated amines with the formula: (chemical formula) (32) where R1 is a hydrocarbil or a substituted hydrocarbil ranging from 6 to approximately 30 carbon atoms, or -R4SR5, R2 in each case the x(R2O) and y(R2O) groups are independent, i.e., C2-C4 alkylene; R3 is a hydrogen or alkyl chain or branched group of approximately 1 to approximately 4 carbon atoms, R4 is a straight or branched alkyl chain of approximately 6 to approximately 30 carbon atoms, R5 is a straight or branched alkyl chain of approximately 4 to approximately 15 carbon atoms, and x and y are independent, being the average number from 1 to approximately 40. (w) An amineted alkoxylated alcohol with the following chemical structure: (chemical formula) (33) where R1, R7, R8, and R9 are each independent, being hydrogen, hydrocarbil or hydrocarbilized groups. Substitutions range from 1 to approximately 30 carbon atoms, or -(R11)s(R3O)yR10; X is -O-, -OC(O)-, -C(O)O-, N(R12)C(O)-, -C(O)N(R12)-, -S-, -SO-, -SO2-, or -N(R9)-; R3 in each case of the n-group (R3O) and the v-group (R3O) independently is C2-C4 alkylene, R10 is a hydrogen or straight or branched alkyl group ranging from approximately 1 to approximately 30 carbon atoms; n is the average number ranging from 1 to approximately 60; v is the average number ranging from 1 to approximately 50; R2 and R11 independently are hydrocarbilenes or substituted hydrocarbilenes ranging from 1 to approximately 6 carbon atoms; R4 is a hydrocarbilene. or substituted hydrocarbils with 2 to about 6 carbon atoms, R12 is hydrogen or hydrocarbil or substituted hydrocarbils with 1 to about 30 carbon atoms, m and s each independent is 0 or 1, R6 is a hydrocarbil or substituted hydrocarbils with 2 to about 30 carbon atoms, -C(=NR12), -C(S)-, or -C(O)-; q is an integer from 0 to 5, and R5 is hydrogen or hydrocarbil or substituted hydrocarbils with 1 to about 30 carbon atoms; (x) monoalkoxylated amines with the formula: (chemical formula) (34) where R1 is hydrogen or hydrocarbil or substituted hydrocarbils with 1 to about 30 carbon atoms; R2 in each group x (R2O) and y (R2O) are independent, C2-C4 alkylene; R3 is a hydrocarbilene or substituted hydrocarbilene with 2 to approximately 30 carbon atoms; R4 and R5 are free hydrogen, hydrocarbilene or substituted hydrocarbilene with 1 to approximately 30 carbon atoms, -(R6)n-(R2O)yR7, or R4 and R5 together with a nitrogen atom to which they are attached, forming a cyclic or heterocyclic ring; R6 is a hydrocarbilene or substituted hydrocarbilene with 1 to approximately 30 carbon atoms; R7 is a hydrogen or alkyl group, straight or branched chain with 1 to approximately 4 carbon atoms; n is 0 or 1, x and y are independent, being the average number from 1 to approximately 60; (y) quaternary ammonium, sulfonium and sulfoxonium salts with the formulas: 229(35) (chemical formula) (35) (chemical formula) (36) or (chemical formula) (37) or (chemical formula) (38), where R1,R7,R8,R9,R10, and R11 are independent, being hydrogen, hydrocarbil or hydrocarbilized. Substitute for groups ranging from 1 to approximately 30 carbon atoms, or -(R13)s(R3O)vR12; X is -O-, -OC(O)-, N(R14)C(O)-, -C(O)N(R14)-, -C(O)O-, or -S-; R3 in each case of the n-group (R3O) and the v-group (R3O) independently is C2-C4 alkylene, R12 is a hydrogen or straight or branched alkyl group ranging from approximately 1 to approximately 30 carbon atoms; n is the average number ranging from 1 to approximately 60; v is the average number ranging from 1 to approximately 50; R2 and R13 independently are hydrocarbilene or Substituted hydrocarbilites have 1 to approximately 6 carbon atoms, m and s are each independent, i.e., 0 or 1; R4 is a substituted hydrocarbilite or hydrocarbilites with 2 to approximately 6 carbon atoms, R6 is a substituted hydrocarbilite or hydrocarbilites with 2 to approximately 30 carbon atoms, -C(=NR12), -C(S)-, or -C(O)-; R14 is a substituted hydrogen or hydrocarbilite or hydrocarbilites with 1 to approximately 30 carbon atoms, q is an integer from 0 to 5, R6 is a substituted hydrogen or hydrocarbilite or hydrocarbilites with 1 to approximately 30 carbon atoms, and each A' is the agriculturally acceptable negative charge; (z) Diamine or diammonium salts with the formula: (chemical formula) (39) or (chemical formula) (40), where R1, R4, R5, R6, R7, and R8 are free, hydrogen or hydrocarbil or hydrocarbilized. (aa) alkoxylated alcohols with the formula: R1O-(R2O)xR(41), where R1 is a hydrocarbil or a substituted hydrocarbil with 1 to about 30 carbon atoms, R2 in each case of the independent x(R2O) and R9 are C2-C4 alkyl groups, R3 is a hydrogen, or a straight or branched alkyl group with 2 to about 6 carbon atoms or -(R2O)pR9-, m and n each are the average number from 0 to about 50, and p is the average number from 0 to about 60; (aa) alkoxylated alcohols with the formula: R1O-(R2O)xR(41), where R1 is a hydrocarbil or a substituted hydrocarbil with 1 to about 30 carbon atoms, R2 in each case of the independent x(R2O) and C2-C4 alkyl groups, R3 is a hydrogen, or a straight or branched alkyl group with 1 to about 4 carbon atoms, and x is the average number from 1 to about 60. 60; (bb) Alkoxylated dialkylphenols with the formula: (chemical formula) (43), where R1 and R4 are free, either hydrogen or straight or branched alkyl groups ranging from 1 to approximately 30 carbon atoms, and at least one of R1 and R4 is an alkyl group, R2 in each case is a free x(R2O) which is a C2-C4 alkylene, R3 is hydrogen, or a straight or branched alkyl group ranging from 1 to approximately 4 carbon atoms, and x is the average number ranging from 1 to approximately 60; (bb) Diamines with the formula: (chemical formula) (20), where R1, R3, R4 and R5 are free, either hydrogen, hydrocarbilene or substituted hydrocarbilene groups ranging from 1 to approximately 30 carbon atoms, or -(R6O)xR7, R2 is a hydrocarbilene or substituted hydrocarbilene groups ranging from 2 to approximately 30 carbon atoms; C(+NR11)NR12R13, -C(=O)NR12R13, -C(=S)NR12R13, -C(=NR12)-, -C(S)-, or -C(O)-, R6 in each case of groups x (R6O) and y (R6O) are independent, i.e. C2-C4 alkylene, R7 is hydrogen, or alkyl chain or branched groups ranging from approximately 1 to approximately 30 carbon atoms, R11, R12 and R13 are hydrogen, hydrocarbil or Substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms, x is the average number ranging from 1 to approximately 50, and y is the average number ranging from 0 to approximately 60; (cc) mono- or diquaternary ammonium salts with the formula: (chemical formula) (21) or (chemical formula) (22), where R1, R3, R4, R5, R8 and R9 are independent hydrogen, hydrocarbils or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms, or -(R6O)xR7, R2 is a hydrocarbil or substituted hydrocarbils ranging from 2 to approximately 30 carbon atoms, R6 in each case of which the x (R6O) and y (R6O) are independent C2-C4 alkyl groups, R7 is a hydrogen, or a straight or branched alkyl group. (dd) Alkyl alkoxylated phosphate with the formula: (chemical formula) (52) where R1 and R3 are independent straight-chain or branched alkyl groups, straight-chain or branched alkyl groups, straight-chain or branched alkyl groups, aryls, or eralkyl groups ranging from approximately 4 to approximately 30 carbon atoms; R2 in each group m (R2O) and n (R2O) are independent C2-C4 alkyl groups; and m and n are independent integers ranging from approximately 1 to approximately 30; or (chemical formula) (53) where R1 is a straight or branched alkyl, straight or branched alkynil, straight or branched alkynil, aryl, or eralkyl group ranging from about 8 to about 30 carbon atoms; R2 in each m group (R2O) is independent, i.e., C2-C4 alkylene; and m is from 1 to about 30.