TH58591A - Pesticides containing oxalic acid. - Google Patents

Abstract

DC60 (16/05/45) Concentrated and aerosolized pesticides and herbicides exhibit enhanced efficacy due to their addition with compounds that increase cell membrane permeability, suppress oxidative rupture, or increase the expression of hydroxyproline-rich glycoproteins.

Claims (1)

Revised 18/04/2017 (Chemical Formula) (56) where R1 and R3 are independent linear or branched alkyl groups, linear or branched alkynyl groups, linear or branched alkynyl groups, aryl or eralkyl groups ranging from approximately 4 to approximately 30 carbon atoms; R2 in each group of m(R2O) and n(R2O) are independent C2-C4 alkyl groups and m and n are independent ranging from 1 to approximately 30 and (hh) phosphate esters with the formula (Chemical Formula) (57) where R1 is a linear or branched alkyl group, linear or branched alkynyl groups, linear or branched alkynyl groups, aryl or eralkyl groups ranging from approximately 8 to approximately 30 carbon atoms; (ii) Anionic surfactants selected from groups consisting of fatty soaps, alkyl sulfates, sulfated oils, sulfated ethers, sulfonates, sulfosuccinates, sulfonated amides and iseth-thionates. Concentrated pesticides and insecticides are solid-acting agents containing glyphosate salts or esters present in concentrations that are biologically effective when diluted in the appropriate volume of water and applied to the leaves of sensitive plants. Oxalic acid or its salts are also present. (46.) The elements of claim 45, including additional surfactant components consisting of one or more surfactants, 47. Concentrated pesticides are solid-state insecticides containing glyphosate salts or esters present in concentrations that are biologically effective when diluted in the appropriate volume of water and applied to the leaves of sensitive plants. Other components include oxalic acid or its salts, and surfactants consisting of one or more cationic or nonionic surfactants. --------------------------------------------- 1. Aqueous concentrated pesticide and herbicide mixtures containing: water-soluble pesticides dissolved in an aqueous medium; water-soluble pesticides present in biologically effective concentrations when diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; surfactant components in a solution or suspension, emulsion, or stable dispersion in such medium, containing one or more surfactants; and compounds that increase the permeability of the thin membranes of plant cells to enhance the cellular uptake of the pesticide mixture in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture free of such compounds but otherwise containing the same mixture as the enhanced application mixture, where such compounds and surfactant components are present in a molar ratio exceeding 10:1. A mixture of claims under Article 1, whereby the pesticide contains herbicides. A mixture of claims under Article 2 where the herbicide contains glyphosate or its salts or esters. 4. A mixture of claims 3 whereby glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, isopropylamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 5. A mixture of claims under Article 4 where glyphosate is abundant in the form of potassium, mono-ammonium, triammonium, sodium, monoethanolamine, n-propylamine, ethylamine, ethylenediamine, or its hexamethylenediamine. 6. A mixture of claims under clause 5 where glyphosate is abundant in the form of its potassium, mono-ammonium, diammonium, or monoethanolamine salts. 7. A mixture of claims under Clause 1 where such compound and the said surfactant component are present in a molar ratio exceeding 15:1. 8. A mixture of claims under Clause 1, whereby such mixture has a cloud point of at least approximately 50°C and a crystallization point of no more than approximately 0°C. 9. A mixture of claims under Article 1, where such compound contains oxalic acid or its salts. 10. A mixture of claims 1 where the ability to permeate thin cell membranes is increased by calcium chelation in the cell wall or apoplast, providing a calcium-dependent protective response.11. A mixture of claims under Article 3 where the glyphosate concentration exceeds 400 g. Glyphosate a. e. 12 per liter. A concentrated herbicide mixture in water containing: glyphosate or its salts or esters, in solution in an aqueous medium at a concentration exceeding 455 g glyphosate a. e. Per liter, and compounds that increase the permeability of the thin membranes of plant cells so that when such a mixture is diluted in the appropriate volume of water to form an enhanced use mixture and applied to the leaves of sensitive plants, the cellular uptake of glyphosate is increased in plants treated with such enhanced use mixture compared to plants treated with a reference use mixture without such compounds but otherwise containing the same mixture as the enhanced use mixture. 13. A mixture of claims 12 where glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, isopropylamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 14. A mixture of claims under Article 12 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, containing one or more surfactants, with the surfactant component present in sufficient concentration to provide acceptable temperature stability of the mixture so that the mixture has a cloud point of at least approximately 50°C and a crystallization point of no more than approximately 0°C. 15. A mixture of claims under Article 12 where such compound contains oxalic acid or its salts. 16. A mixture of claims 12 where the permeability of thin cell membranes is increased by calcium chelation in the cell wall or apoplast, providing a calcium-dependent protective response.17. Concentrated aqueous herbicide mixtures containing: glyphosate is abundant in the form of potassium, monoammonium, diammonium, sodium, monoethanolamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine, or its trimethylsulfonium salts, in solution in an aqueous medium at biologically effective concentrations when the mixture is diluted in the appropriate volume of water to form a mixture. In increased use and applied to the leaves of sensitive plants, the compounds increase the permeability of the thin membranes of cells within the plant to enhance the cellular uptake of glyphosate in plants treated with the increased mixture. Compared to plants treated with a reference mixture without such compounds, but otherwise containing the same mixture as the increased mixture, the results show a difference. 18. A mixture of claims under Article 17 where glyphosate is abundant in the form of its potassium, mono-ammonium, diammonium or monoethanolamine salts. 19. A mixture of claims under Article 18 where glyphosate is abundant in the form of its potassium salt or monoethanolamine. 20. A mixture of claims 17 whereby the surfactant component is in a solution or suspension, emulsion or stable dispersion in an aqueous medium, containing one or more surfactants in total amounts of approximately 20 to approximately 300 g per liter of mixture. 21. A mixture of claims under Article 17 where such compound contains oxalic acid or its salts. 22. A mixture of claims 17 whereby the permeability of thin cell membranes is increased by calcium chelation in the cell wall or apoplast, providing a calcium-dependent protective response.23 A mixture of claims under Article 17 where the glyphosate concentration exceeds 400 g. Glyphosate a. e. 24 per liter. A mixture of claims under Article 23 where the glyphosate concentration exceeds 450 g. Glyphosate a. e. 25 per liter. A mixture of claims under Article 24 where the glyphosate concentration exceeds 500 g. Glyphosate a. e. 26 per liter. An aqueous herbicide concentrate mixture consists of: glyphosate, abundantly present in the form of its potassium salt, dissolved in an aqueous medium at a biologically effective concentration when the mixture is diluted in the appropriate volume of water to form an enhanced-use mixture and applied to the leaves of sensitive plants; and a compound that increases the permeability of the thin membranes of cells within the plant to enhance the cellular uptake of glyphosate in plants treated with such an enhanced-use mixture compared to plants treated with a reference-use mixture without such compounds but otherwise containing the same mixture as the enhanced-use mixture. 27. A mixture of claims 26 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, containing one or more surfactants in a total amount of approximately 20 to approximately 300 g per liter of mixture 28. A mixture of claims under Article 26 where such compound contains oxalic acid or its salts. 29. A mixture of claims 26 where the permeability of thin cell membranes is increased by calcium chelation in the cell wall or apoplast, providing a calcium-dependent protective response.30 A mixture of claims under Article 26 where the concentration of potassium glyphosate exceeds 300 g. Glyphosate a. e. 31 per liter. A mixture of claims under Article 30 where the concentration of potassium glyphosate exceeds 400 g. Glyphosate a. e. 32 per liter. A mixture of claims under Article 31 where the concentration of potassium glyphosate exceeds 500 g. glyphosate a. e. Per liter -----------------------------33. Concentrated aqueous pesticide mixtures containing: -------------------------------------------- Water-soluble pesticide mixtures dissolved in an aqueous medium; water-soluble pesticide mixtures present in biologically effective concentrations when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitized plants; surfactant components in a solution or suspension, emulsion or stable dispersion in such medium, containing one or more surfactants; and compounds that suppress oxidative rupture in plant cells, intervening with the plant's defense response in plants treated with such enhanced application mixtures compared to plants treated with a reference application mixture free of such compounds but otherwise containing the same mixture as such enhanced application mixtures, where such compounds and such surfactant components are present in a molar ratio exceeding 10:1. 34. A mixture of claims under Article 33, whereby the pesticides and herbicides include herbicide 35. A mixture of claims under Article 34 in which the herbicide contains glyphosate or its salts or esters. 36. A mixture of claims under Article 35 whereby glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, isopropylamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 37. A mixture of claims 36 where glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, n-propylamine, ethylamine, ethylenediamine, or its hexamethylenediamine. 38. A mixture of claims under Article 37 where glyphosate is abundant in the form of its potassium, mono-ammonium, diammonium, or monoethanolamine salts. 39. A mixture of claims under Article 38 where such compound and the said surfactant component are present in a molar ratio exceeding 15:1. 40. A mixture of claims under Article 33 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, containing one or more surfactants, with the surfactant component present in sufficient concentration to provide acceptable temperature stability of the mixture so that the mixture has a cloud point of at least approximately 50°C and a crystallization point of no more than approximately 0°C. 41. A mixture of claims under Article 31 where oxidative breakdown is suppressed by direct inhibition of free radical-generating oxidases. 42. A mixture of claims 33 in which oxidative breakdown is suppressed by blocking the signaling step that directly triggers the activation of free radical-generating oxidases. 43. A mixture of claims under Article 35 where the glyphosate concentration exceeds 400 g. Glyphosate a. e. 44 per liter. A mixture of claims under Article 43 where the glyphosate concentration exceeds 450 g. Glyphosate a. e. 45 per liter. A mixture of claims under Article 44 where the concentration of glyphosate exceeds 500 g. glyphosate a. e. 46 per liter. A concentrated herbicide mixture in water containing: glyfolate or its salts or esters, in solution in an aqueous medium at a concentration exceeding 455 g glyfolate a. e. per liter; and compounds that suppress oxidative breakdown in plant cells so that when such a mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants, the plant's defensive response is omitted in plants treated with such enhanced application mixture compared to plants treated with a reference application mixture without such compounds but otherwise containing the same mixture as the enhanced application mixture. 47. A mixture of claims under Article 46 whereby glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, isopropylamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 48. A mixture of claims under Article 46 that includes a surfactant component in solution or suspension, emulsion or dispersion stable in such medium, containing one or more surfactants, with the surfactant component present in sufficient concentration to provide acceptable temperature stability of the mixture so that the mixture has a cloud point of at least approximately 50°C and a crystallization point of no more than approximately 0°C. 49. A mixture of claims under Article 46 where oxidative breakdown is suppressed by directly inhibiting free radical-generating oxidase 50. A mixture of claims under Article 46 where oxidative breakdown is suppressed by blocking the signaling step that directly triggers the activation of free radical-generating oxidases. 51. An aqueous herbicide concentrate containing: glyphosate, abundantly present in the form of potassium, monoammonium, diammonium, sodium, monoethanolamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine, or its trimethylsulfonium salts; in solution in an aqueous medium, the biologically effective concentration of the compound is achieved when the mixture is diluted in the appropriate volume of water to form an incremental application mixture applied to the leaves of sensitive plants; and compounds that suppress oxidative rupture in plant cells to infiltrate the plant's defense response in plants treated with such incremental application mixtures compared to plants treated with a reference application mixture without such compounds but otherwise containing the same mixture as the incremental application mixture. 52. A mixture of claims under Article 51 where glyphosate is abundant in the form of its potassium, mono-ammonium, diammonium or monoethanolamine salts. 53. A mixture of claims under Article 52 where glyphosate is abundant in the form of its potassium salts-------------------or its mono-ethanolamine 54. A mixture of claims under Article 51 whereby the surfactant component is in a solution or suspension, emulsion or stable dispersion in an aqueous medium, containing one or more surfactants in total amounts of approximately 20 to approximately 300 g per liter of mixture. 55. A mixture of claims under Article 51 where oxidative breakdown is suppressed by directly inhibiting the free radical-generating oxidase 56. A mixture of claims 51 where oxidative breakdown is suppressed by blocking the signaling step that directly triggers the activation of free radical-generating oxidases. 57. A mixture of claims under Article 51 where the glyphosate concentration exceeds 400 g. Glyphosate a. e. 58 baht per liter. A mixture of claims under Article 57 where the glyphosate concentration exceeds 450 g. Glyphosate a. e. 59 baht per liter. A mixture of claims under Article 58 where the glyphosate concentration exceeds 500 g. Glyphosate a. e. 60 baht per liter. An aqueous herbicide concentrate containing: glyphosate, abundantly present in the form of its potassium salt, in solution in an aqueous medium at a biologically effective concentration when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; and a compound that suppresses oxidative rupture in plant cells to induce a plant defense response in plants treated with such enhanced application mixture compared to plants treated with a reference application mixture devoid of such compounds but otherwise containing the same mixture as the enhanced application mixture. 61. A mixture of claims under Article 60 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in an aqueous medium, containing one or more surfactants in a total amount of approximately 20 to approximately 300 g per liter of mixture. 62. A mixture of claims under Article 60 where oxidative breakdown is suppressed by direct inhibition of free radical-generating oxidases. 63. A mixture of claims under Article 60 where oxidative rupture is suppressed by blocking the signaling step that directly triggers the activation of free radical-generating oxidases. 64. A mixture of claims under Article 60 where the concentration of potassium glyphosate exceeds 400 g. Glyphosate a. e. 65 per liter. A mixture of claims under Article 64 where the concentration of potassium glyphosate exceeds 450 g. glyphosate a. e. 66 per liter. A mixture of claims under Article 65 where the concentration of potassium glyphosate exceeds 500 g. Glyphosate a. e. 67 per liter. A concentrated herbicide mixture in water containing: glyfolate or its salts or esters, in solution in an aqueous medium at a concentration exceeding 455 g glyfolate a. e. per liter; and oxalic acid or its salts in a concentration such that when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants, plant growth is controlled to a greater extent than in plants treated with a reference application mixture free of oxalic acid and its salts, but otherwise containing the same mixture as the enhanced application mixture. ******************* 68. A mixture of claims under Article 67 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, which contains one or more surfactants. 69. A mixture of claims under Article 67 where the oxalic acid contains alkali metal salts, alkanolamine salts, alkylamine salts, tetraalkylammonium salts or aryltrialkylammonium salts of oxalic acid 70. Aquatic herbicide mixtures containing: glyphosate, predominantly in the form of its potassium salt, is dissolved in an aqueous medium at a biologically effective concentration when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of a wide range of sensitized plants; and oxalic acid or its salts are present in concentrations such that plant growth is controlled to a greater extent compared to plants treated with a reference application mixture free of oxalic acid and its salts, but otherwise containing the same mixture as the enhanced application mixture. 71. A mixture of claims under Article 70 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, which contains one or more surfactants. 72. A mixture of claims under Article 70 where the oxalic acid contains alkali metal salts, alkanolamine salts, alkylamine salts, tetraalkylammonium salts or aryltrialkylammonium salts of oxalic acid. 73. A mixture of claims under Article 71 whereby the surfactant composition consists of one or more cationic, uncharged, or anionic surfactants. 74. A mixture of claims 73 where the surfactant components consist of an eminated and alkoxylected alcohol with the formulas: (5) (chemical formula) (chemical formula) A (6) where R1 is hydrogen, hydrocarbil, or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms; R2 in each group x(R2O) and y(R2O) independently is C2-C4 alkylene; R3 and R6 independently are hydrocarbils or substituted hydrocarbils ranging from 1 to approximately 6 carbon atoms; R4 is hydrogen, hydrocarbil, or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms; hydroxyl, substituted hydrocarbil, -(R6)n-(R2O)yR7, -C(=NR11)NR12R13, -C(=O)NR12R13, -C(=S)NR12R13 Or together with R5 and the nitrogen atom to which it is attached, forming a cyclic or heterocyclic ring; R6 is hydrogen, hydrocarbil, or substituted hydrocarbil with 1 to about 30 carbon atoms, substituted hydroxyhydrocarbil, -(R6)n-(R2O)yR7, -C(=NR11)NR12R13, -C(=O)NR12R13, -C(=S)NR12R13 or together with R4 and the nitrogen atom to which it is attached, forming a cyclic or heterocyclic ring; R7 is hydrogen or linear or branched alkyl groups with 1 to about 6 carbon atoms; R11, R12, and R13 are hydrogen, hydrocarbil, or hydro Substituted carbil, R14 is hydrogen, hydrocarbil or substituted hydrocarbil with 1 to approximately 30 carbon atoms, substituted hydroxyhydrocarbil, -(R6)n-(R2O)yR7, -C(=NR11)NR12R13, -C(=O)NR12R13, or -C(=S)NR12R13, n is 0 or 1, x and y are independent, the average number from 1 to approximately 60, and A- is the agriculturally acceptable negative charge 75. Aquatic herbicide mixtures contain: glyphosate, predominantly in the form of its chiarammonium salts, in solution in an aqueous medium at biologically effective concentrations when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture for application to the leaves of a wide range of sensitized plants; and oxalic acid or its salts, in concentrations such that plant growth is controlled to a greater extent compared to plants treated with a reference application mixture free of oxalic acid and its salts, but otherwise containing the same mixture as the enhanced application mixture. 76. A mixture of claims under Article 75 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, which contains one or more surfactants. 77. A mixture of claims under Article 75 whereby the oxalic acid is composed of alkali metal salts, alkanolamine salts, alkylamine salts, tetraalkylammonium salts or aryltrialkylammonium salts of oxalic acid. 78. A mixture of claims under Article 75, whereby the weight ratio of glyphosate a. e. The oxalic acid ratio is between approximately 1:1 and approximately 10:1.79 A mixture of claims under Article 78, whereby the weight ratio of glyphosate a. e. The oxalic acid content is approximately 3:1 80. Aquatic herbicide mixtures containing: glyphosate or its salts or esters, dissolved in an aqueous medium at a concentration that is biologically effective when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of a wide range of sensitized plants; and tetraalkylammonium or aryltriylkylammonium salts of oxalic acid in concentrations such that the growth of plants treated with the enhanced application mixture is controlled to a greater extent compared to plants treated with a reference application mixture without such salts, otherwise containing the same mixture as the enhanced application mixture. 81. A mixture of claims under Article 75 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, which contains one or more surfactants. 82. The mixture of claims under Article 80, whereby the salts of the aforementioned oxalic acid consist of hexadexyltrimethylammonium halide, tetrabutylammonium halide, triethylbenzylammonium halide, tetraethylammonium halide, triethyl N-butylammonium halide, tetrapropylammonium halide, tetrabutylammonium halide, phenyltrimethylammonium halide, tetramethylammonium halide, myristyltrimethylammonium halide, cetyltrimethyl Ammonium halide, tetra-N-propyl ammonium halide, triethylbenzylammonium halide, trimethylbenzylammonium halide, benzyl triethyl ammonium halide, benzyl trimethyl ammonium halide, benzyl tributyl ammonium halide, triethylbutyl ammonium halide, tributyl ethyl ammonium halide, tribumethyl ammonium halide, dodecyl trimethyl Ammonium halide, hexadexyl trimethyl ammonium hydroxide, tetrabutyl ammonium hydroxide, triethyl N-butyl ammonium hydroxide, tetrapropyl ammonium hydroxide, tetrabutyl ammonium hydroxide, phenyl trimethyl ammonium hydroxide, tetramethyl ammonium hydroxide, myristyl trimethyl ammonium hydroxide, cetyl trimethyl ammonium hydroxide, tetra-N-propyl ammonium hydroxide, triethyl benzyl ammonium hydroxide, trimethyl benzyl ammonium hydroxide, benzyl triethyl Ammonium hydroxide, benzyl trimethyl ammonium hydroxide, benzyl tributyl ammonium hydroxide, triethyl butyl ammonium hydroxide, tributyl ethyl ammonium hydroxide, tributyl ammonium hydroxide, or dodecyl trimethyl ammonium hydroxide 83. A mixture of claims under Article 80, whereby the plant in question is a broadleaf plant. 84. An aqueous herbicide mixture consisting of: glyphosate or its salts or esters, in solution in an aqueous medium at a concentration that is biologically effective when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of a wide range of sensitized plants; a surfactant component in solution or suspension, emulsion, or dispersion stable in such medium containing one or more surfactants; and oxalic acid or its salts, where the concentration of oxalic acid or its salts and the nature of such surfactants is such that the first difference is between: (i) the growth rate of plants treated with the first enhanced application mixture prepared by diluting the aqueous herbicide mixture with water, and (ii) the growth rate of plants treated with a first reference application mixture free of oxalic acid and any of the aforementioned salts, but otherwise containing the same mixture as the first enhanced application mixture. More than the second difference between: (iii) the growth rate of plants treated with the second type of enhanced use mixture and (iv) the growth rate of plants treated with the second type of reference use mixture free of oxalic acid and any such salts but otherwise containing the same mixture as the second type of enhanced use mixture, where the mixture of the second type of enhanced use mixture differs from the mixture of the first type of enhanced use mixture only with respect to the characteristics of the surfactant system contained herein, with the second type of enhanced use mixture containing the following cationic surfactants selected from the group consisting of: ethoxylated tallowamine surfactants with the formula: (chemical formula) (3), where R is a mixture of pronounced alkyl and alkenyl chains derived from tallow and all m-n is the average number of approximately 15, where the weight ratio of glyphosate a. e. Furthermore, the second surfactant added to the mixture is approximately 2:1 cocoalkyltrimethylammonium chloride, where the weight ratio of glyphosate is a. e. The second surfactant used in the mixture is approximately 4:1 and POE(15)cocoalkyl monomethylammonium chloride, where the weight ratio of glyphosate a. e. For surfactants in mixtures, the ratio of the second type to a second surfactant is approximately 4:1. 85 A mixture of claims under Article 84, whereby the plant in question is a broadleaf plant (86). Aquatic herbicide mixtures containing: glyfolate or its salts or esters, in solution in an aqueous medium at concentrations exceeding 360 g glyfolate a. e. per liter; and oxalic acid or its salts in a concentration such that when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of broadleaved plants, plant growth is controlled to a greater extent compared to broadleaved plants treated with the reference application mixture. The reference application mixture differs from the enhanced application mixture only in that it is free of oxalic acid and its salts and contains ethylenediamine tetraacetic acid or sodium citrate 87. A mixture of claims under Article 86 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, which contains one or more surfactants. 88. A mixture of claims under Article 86 where the oxalic acid contains alkali metal salts, alkanolamine salts, alkylamine salts, tetraalkylammonium salts or aryltrialkylammonium salts of oxalic acid. 89. An aqueous herbicide mixture consisting of: glyphosate or its salts or esters, dissolved in an aqueous medium at a concentration that is biologically effective when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; and oxalic acid or its salts at a concentration such that plant growth is controlled to a greater extent compared to plants treated with a reference application mixture without oxalic acid and its salts, but otherwise with the same mixture as the enhanced application mixture; where the mixture has a density of at least approximately 1. 210 grams/liter 90. A mixture of claims under Article 89 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, which contains one or more surfactants. 91. A mixture of claims under Article 89 where the mixture has a density of at least approximately 1,230 g/L. 92. A mixture of claims under Article 91 where the mixture has a density of at least approximately 1,240 g/L. 93. A mixture of claims under Article 89 where the oxalic acid contains alkali metal salts, alkanolamine salts, alkylamine salts, tetraalkylammonium salts or aryltrialkylammonium salts of oxalic acid. 94. Aquatic herbicide mixtures containing: glyphosate, abundantly in the form of potassium, monoammonium, diammonium, sodium, monoethanolamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine, or its trimethylsulfonium salts, in solution in an aqueous medium at concentrations that are biologically effective when the mixture is diluted in the appropriate volume of water to form an increased-application mixture and applied to the leaves of sensitive plants; and oxalic acid or its salts at concentrations so that plant growth is controlled to a greater extent compared to plants treated with a reference-application mixture free of oxalic acid and its salts, but otherwise containing the same mixture as the increased-application mixture. 95. A mixture of claims 94 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, containing one or more surfactants in a total amount of approximately 20 to approximately 300 g/L in the mixture 96. A mixture of claims under Article 94 where the oxalic acid contains alkali metal salts, alkanolamine salts, alkylamine salts, tetraalkylammonium salts or aryltrialkylammonium salts of oxalic acid 97. Aquatic herbicide mixtures containing: glyphosate or its salts or esters in solution at an effective concentration (biologically effective when the mixture is diluted in the appropriate volume of water and applied to the leaves of sensitive plants); and oxalic acid or its salts; where glyphosate is the active ingredient. e. And oxalic acid is present in a ratio by weight greater than 21:1 98. A mixture of claims under Article 97 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, which contains one or more surfactants. 99. Concentrated pesticide mixtures in water containing: water-soluble pesticides in an aqueous medium; water-soluble pesticides present in biologically effective concentrations when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; surfactant components in solution or suspension, emulsion, or stable suspension in a medium containing one or more surfactants; and compounds that increase the expression of hydroxyproline-containing glycoproteins, thereby increasing the mobility of pesticides to foleam in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture devoid of such compounds but otherwise containing the same mixture as the enhanced application mixture, where such compounds and surfactant components are present in a molar ratio exceeding 10:1100. A mixture of claims under Article 99, whereby the pesticides and herbicides include herbicide 101. A mixture of claims under Article 100 whereby the herbicide contains a phosphate or its salt or ester. 102. A mixture of claims under Article 101 where glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, isopropylamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 103. A mixture of claims under Article 102 where glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, n-propylamine, ethylamine, ethylenediamine, or its hexamethylenediamine 104. A mixture of claims under Article 103 where glyphosate is abundant in the form of its potassium, mono-ammonium, diammonium, or monoethanolamine salts. 105. A mixture of claims under Article 104 where such compound and the surfactant component are present in a molar ratio exceeding 15:1. 106. A mixture of claims under Article 99 whereby such mixture has a cloud point of at least approximately 50°C. And the crystallization temperature does not exceed approximately 0°C. 107. A mixture of claims under Article 99 where such compound contains oxalic acid or its salts. 108. A mixture of claims under Article 101 where the glyphosate concentration exceeds 400 g. Glyphosate a. e. 109 per liter. Concentrated herbicide mixtures in water containing: glyphosate or its salts or esters, in solution in an aqueous medium at concentrations exceeding 455 g glyphosate a. e. per liter; and a compound which increases the expression of hydroxyapropyl glycoprotein in concentrations such that when such a mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants, the mobility of such glyphosate to phloem increases in plants treated with such enhanced application mixture compared to plants treated with a reference application mixture without such compounds but otherwise containing the same mixture as the enhanced application mixture. 110. A mixture of claims under Article 109 whereby glyphosate is abundant in the form of potassium, mono-ammonium, gyammonium, sodium, monoethanolamine, isopropylamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 111. A mixture of claims under Article 109 that includes a surfactant component in a solution or suspension, emulsion or dispersion stable in such medium, containing one or more surfactants, with the surfactant component present in concentrations sufficient to provide acceptable temperature stability of the mixture so that the mixture has a cloud point of at least approximately 50°C. And the crystallization temperature does not exceed approximately 0°C. 112. A mixture of claims under Article 109 where such compound contains oxalic acid or its salts. 113. An aqueous herbicide concentrate is a mixture of: (i) glyphosate or its salts or esters in solution in an aqueous medium at a concentration that is biologically effective when the mixture is diluted in the appropriate amount of water and applied to the leaves of the target plant; (ii) a surfactant component in solution or suspension, emulsion or stable dispersion in the medium, and consisting of one or more surfactants; and (iii) oxalic acid or its salts, where the surfactant component is approximated by at least one surfactant of a selectable group consisting of: (a) phosphate esters with the formula: (chemical formula) (57), where R1 is a linear branched alkyl, linear or branched alkynyl, linear or branched alkynyl, aryl, or eral group ranging from approximately 4 to approximately 30 carbon atoms; R2 in each m(R2O) group is independent, i.e., C2-C4 alkylene; (b) Phosphate diesters with the formula: (chemical formula) (56) where R1 and R2 are independent linear or branched alkyl, linear or branched alkynyl, linear or branched alkynyl, aryl, or eralkyl groups ranging from approximately 4 to approximately 30 carbon atoms; R2 in each group m(R2O) is independent C2-C4 alkylene; and m is from 1 to approximately 30; (c) Etheramines with the formula: (chemical formula) (32) where R1 is a hydrocarbil or substituted hydrocarbil ranging from 1 to approximately 30 carbon atoms; R2 is a hydrocarbil or substituted hydrocarbil ranging from 2 to approximately 30 carbon atoms; R3 and R4 are independent hydrogen, hydrocarbil or substituted hydrocarbil ranging from 1 to approximately 30 carbon atoms; or -(R6O)xR6, R6 in each group x(R5-O) is independent C2-C4 alkylene, R2 is hydrogen, or a linear or branched alkyl group from 1 to about 4 carbon atoms, and x is the average number from 1 to about 50; and (d) monoalxoxylated quaternary ammonium salts with the formula: (chemical formula) where R1 and R5 are independent hydrogen or hydrocarbil or substituted dicarbil ranging from 1 to about 30 carbon atoms; R4 is a hydrocarbil or substituted hydrocarbil ranging from 1 to about 30 carbon atoms; R2 in each group x(R2O) is independent C2-C4 alkylene, R3 is hydrogen, or a linear or branched alkyl group from 1 to about 30 carbon atoms, and x is the average number from 1 to about 60, and X- is the agriculturally acceptable negative charge 114. A mixture of claims under Article 113 where glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, isopropylamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 115. A mixture of claims under Article 114 where the weight ratio of glyphosate a. e. The surfactant ratio is between approximately 6:1 and approximately 1:1. 116. A method for reducing the amount of surfactant in concentrated herbicide mixtures in water to achieve the desired level of growth control observed when the mixture is diluted with water and applied to plant leaves. The method involves adding oxalic acid or its salts to such mixtures. Such mixtures contain glyphosate or its salts or esters and one or more surfactants. 117. A mixture of claims under Article 116 where the weight ratio of glyphosate a. e. The ratio to oxalic acid mentioned is between approximately 1:3 and approximately 100:1. 118 A method for reducing the aqueous toxicity of herbicide mixtures without compromising control measures, specifically the observed growth efflux when the mixture is diluted with water and applied to plant leaves, was prepared. The method involves adding oxalic acid or its salts to the mixture. Such mixtures also contain glyphosate or its salts or esters. 119. A mixture of claims under Article 118 that includes a surfactant component consisting of one or more surfactants (120). Method of claim 118 where the weight ratio of glyphosate a. e. The ratio to oxalic acid mentioned is between approximately 1:30 and approximately 100:1.121 A method for controlling the growth of morning glory was prepared. The method consisted of applying a water-soluble solution to the morning glory leaves. This solution contained glyphosate or its salts or esters and oxalic acid or its salts. 122. A mixture of claims under Article 121 where the weight ratio of glyphosate a. e. The ratio to oxalic acid mentioned is between approximately 1:30 and approximately 100:1. An aqueous herbicide concentrate containing (i) glyphosate or its salts or esters in solution in an aqueous medium at a concentration that is biologically effective when the mixture is diluted in the appropriate amount of water and applied to the leaves of susceptible plants; (ii) a surfactant component in solution or suspension, emulsion or dispersion stable in the medium and containing one or more surfactants; and (iii) oxalic acid or its salts, whereby the surfactant component is approximated by at least one surfactant of a selectable group consisting of: (a) amined and alkoxylated alcohols with the formulas: (chemical formula) (5) or (chemical formula) A (6), where R1 is a hydrogen or hydrocarbil substituted hydrocarbil ranging from 1 to approximately 30 carbon atoms; R2 in each group x(R2O) and y(R2O) independently is a C2-C4 alkylene; R3 and R6 are independent, either hydrocarbilites or substituted hydrocarbilites containing 1 to approximately 6 carbon atoms; R4 is a hydrogen, hydrocarbilite or substituted hydrocarbilite containing 1 to approximately 30 carbon atoms; hydroxyl, substituted hydrocarbilite, -(R6)n-(R2O)yR7, -C(=NR11)NR12R13,-C(=O)NR12R13, -(R6)n-C(O)OR7, -C(=S)NR12R13 or in conjunction with R6 and the nitrogen atom to which it is attached, forming cyclic or heterocyclic forms; R5 is hydrogen, a substituted hydrocarbil or hydrocarbil with 1 to approximately 30 carbon atoms, a substituted hydroxyhydrocarbil, -(R6)n-(R2O)yR7, -C(=NR11)NR12R13, -C(=O)NR12R13, -(R6)n-C(O)OR7-C(=S)NR12R13 or together with R4 and the nitrogen atom to which it is attached, forming a cyclic or heterocyclic ring; R7 is a hydrogen or linear or branched alkyl group with 1 to approximately 6 carbon atoms; R11, R12 and R13 are hydrogen, a substituted hydrocarbil or hydrocarbil; R14 is hydrogen, a substituted hydrocarbil or... Substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms, substituted hydroxyhydrocarbils, -(R6)n-(R2O)yR7, -C(=NR11)NR12R13, -C(=O)NR12R13, or -C(=S)NR12R13, n is 0 or 1, x and y are independent, being the average number ranging from 1 to approximately 60, and A- is the accepted negative charge. (b) Hydroxylated amides with the formula: (chemical formula) (7), where R1 is a hydrocarbil or a substituted hydrocarbil with 1 to 30 carbon atoms, R2 is a hydrogen or a hydrocarbil or a substituted hydrocarbil with 1 to 30 carbon atoms, and R3 is a hydroxyalkyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl. (c) Diamines with the formula: (chemical formula) (9), where R1, R2 and R3 are free hydrogen or a hydrocarbil or a substituted hydrocarbil with 1 to 30 carbon atoms or, -(R8)(OR9)nOR10, R3 is a hydrocarbil or a substituted hydrocarbil with 2 to 18 carbon atoms, R8 and R9 are free hydrocarbil. Substituted carbils or hydrocarbils with 2 to approximately 4 carbon atoms, R4 and R10 are free, which are hydrogen or hydrocarbils or substituted hydrocarbils with 1 to approximately 30 carbon atoms, m is 0 or 1, n is the average number from 0 to approximately 40, and X is -C(O)- or -SO2-. (d) Mono- or diammonium salts with the formula: (chemical formula) (10) or (chemical formula) A (11), where R1, R2, R4, R6 and R7 are free, which are hydrogen or hydrocarbils or substituted hydrocarbils with 1 to approximately 30 carbon atoms or -R8(OR9)nOR10, R6 is a hydrocarbil or substituted hydrocarbil with 1 to approximately 30 carbon atoms, R3 is a hydrocarbil or Substituted hydrocarbilites with 2 to approximately 30 carbon atoms, R8 and R9 specifically are hydrocarbilites or substituted hydrocarbilites with 2 to approximately 4 carbon atoms, R10 is hydrogen or hydrocarbilites or substituted hydrocarbilites with 1 to approximately 30 carbon atoms, m is 0 or 1, n is the average number from 0 to approximately 40, X is -C(O)- or -SO2-, Z is -C(O)-, and A is the agriculturally acceptable anion (e) Poly(hydroxyalkyl)amines with the formula: (chemical formula) (12) or (chemical formula) (12A), where R1 is a hydrocarbilite or substituted hydrocarbilites with approximately 4 to approximately 30 carbon atoms; Or -R4OR8, R2 is a hydrogen or hydrocarbil or a substituted hydrocarbil with 1 to about 30 carbon atoms, R3 is a hydroalkyl, polyhydroxyalkyl, or poly-(hydroxyalkyl)alkyl, R4 is a hydrocarbil or a substituted hydrocarbil with 2 to about 18 carbon atoms, R8 is a hydrogen or hydrocarbil or a substituted hydrocarbil with 1 to about 30 carbon atoms, R6 is -(R6O)yR7, R6 in each y(R2O) group is independent of C2-C4 alkylenes; R7 is a linear or branched alkyl group with 1 to approximately 4 carbon atoms, and y is the average number from 0 to approximately 30. (f) Alkoxylated poly(hydroxyalkyl)amines with the formula: (chemical formula) (15) where R1 and R2 are independent hydrogen, hydrocarbilyl or substituted hydrocarbilyls with 1 to approximately 30 carbon atoms, R2 in each independent x(R2O) group is a C2-C4 alkylene; R4 is a hydrocarbilyl or substituted hydrocarbilyls with 1 to approximately 30 carbon atoms, R5 is a hydroxyl alkyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl; x is the average number from 0 to about 30, and y is 0 or 1. (g) Di-poly(hydroxyalkyl)amines with the formula: (chemical formula) (18), where R1 and R3 are free, which are hydrogen or hydrocarbil or substituted hydrocarbils ranging from 1 to about 22 carbon atoms, R2 is hydrocarbil or substituted hydrocarbils ranging from 2 to about 18 carbon atoms, and R4 and R5 are free, which are hydroxyalkyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl. (h) Quaternary poly(hydroxyalkyl)amine salts with the formula: (chemical formula) (20), where R1 is hydrocarbil or substituted hydrocarbils ranging from 4 to about 30 carbon atoms, R2 and R3 are free, which are hydrogen or hydrocarbil or substituted hydrocarbils ranging from 1 to about 30 carbon atoms, R4 is a hydroxyalkyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl, and X- is the agriculturally acceptable anion (I). Diamines with the formula: (chemical formula) (23) where R1 is a hydrocarbil or substituted hydrocarbils ranging from 1 to about 30 carbon atoms; R2, R3, R4 and R5 free are hydrogen, hydrocarbil or substituted hydrocarbils ranging from 1 to about 30 carbon atoms, or -(R8)s(R7O)nR6; R6 is a hydrogen or linear or branched alkyl group ranging from 1 to about 4 carbon atoms, R7 in each free n(R7O) group is a C2-C4 alkyl; R8 is a hydrocarbil or substituted hydrocarbil with 1 to approximately 6 carbon atoms, n is the average number from 1 to approximately 10, s is 0 or 1, and x and y are independent integers from 1 to approximately 4. (j) Diamines have the formula: (chemical formula) (24) where R1, R3, R4 and R5 are independent hydrogen, hydrocarbil or substituted hydrocarbil with 1 to approximately 30 carbon atoms; Or -(R6O)xR7, R2 is a hydrocarbil or substituted hydrocarbil with 2 to about 30 carbon atoms, C(=NR11)NR12R13, -C(=O)NR12R13, -C(=S)NR12R13-, -C(=NR12)-, -C(S)-, or -C(O)-, R6 in each group x(R6O) and y(R6O) are independent C2-C4 alkyl groups, R7 is a hydrogen, linear or branched alkyl group with 1 to about 30 carbon atoms; R11, R12 and R13 are hydrogen, hydrocarbil or substituted hydrocarbil with independent C2-C4 alkyl groups, R7 is a hydrogen, linear or branched alkyl group with 1 to about 30 carbon atoms; R11, R12 and R13 are hydrogen, hydrocarbil or substituted hydrocarbils with 1 to about 30 carbon atoms, x is the average number from 1 to about 50, and y is the average number from 0 to about 60. (k) Mono- or diquaternary ammonium salts with the formula: (chemical formula) (25) or (chemical formula) (26), where R1, R3, R4, R5, R8 and R9 are free hydrogen, polyhydroxyalkyl, hydrocarbil or substituted hydrocarbils with 1 to about 30 carbon atoms; or -(R6O)xR7, R2 is hydrocarbil or substituted hydrocarbils with 2 to about 30 carbon atoms, R6 in each group, X(R6O) and y(R6O) are free C2-C4 alkyl, R7 is hydrogen, or alkyl group. (I) Secondary or tertiary amines with the formula: (chemical formula) (27) where R1 and R2 are hydrocarbils with 1 to approximately 30 carbon atoms, and R3 is the hydrogen or hydrocarbil with 1 to approximately 30 carbon atoms; (m) Monoalkylated amines with the formula; (chemical formula) (28) where R1 and R4 are independent hydrocarbils or substituted hydrocarbils with 1 to approximately 30 carbon atoms; or -R5SR6, R2 in each group x(R6O) is independent C2-C4 alkylene, R3 is hydrogen, or a linear or branched alkyl group from 1 to about 4 carbon atoms, R5 is a linear or branched alkyl group from 6 to about 30 carbon atoms, R6 is a hydrocarbil or substituted hydrocarbil from 4 to about 15 carbon atoms and x is the average group number from 1 to about 60 (n). Dialoxylated quaternary ammonium salts with the formula: (chemical formula) (29) where R1 is a hydrocarbil or substituted hydrocarbil from 1 to about 30 carbon atoms, R2 in each group x(R2O) and y(R2O) is independent C2-C4 alkylene, R3 is hydrogen, or a linear alkyl group. or branching from 1 to about 4 carbon atoms, R4 is hydrogen or hydrocarbil or substituted hydrocarbil ranging from 1 to about 30 carbon atoms, x and y are independent, the average number ranging from 1 to about 40, and X- is the agriculturally acceptable negative charge. However, given if R1 and R4 are apart from the alkyl(o) monoalkoxylated quaternary ammonium salts with the formula: (chemical formula) (30) where R1 and R2 are independent, are hydrogen or hydrocarbil or substituted hydrocarbil ranging from 1 to about 30 carbon atoms; R4 is a hydrocarbil or a substituted hydrocarbil ranging from 1 to approximately 30 carbon atoms, R2 in each group x(R2O) is independent C2-C4 alkyl, R3 is a hydrogen, or a linear or branched alkyl group ranging from 1 to approximately 30 carbon atoms, x is the average number ranging from 1 to approximately 60, and X- is the agriculturally acceptable anion (p). Quaternary ammonium salts have the formula: (chemical formula) (31) where R1, R3 and R4 in independent are hydrogen or a hydrocarbil or a substituted hydrocarbil ranging from 1 to approximately 30 carbon atoms, R2 is a hydrocarbil or a substituted hydrocarbil ranging from 1 to approximately 30 carbon atoms, and X- is the agriculturally acceptable anion. However, it is determined that R1 is not an alkyl when R2, R3 and R4 are lower alkyls; (q) Etheramines with the formula: (chemical formula) (32) where R1 is a hydrocarbil or substituted hydrocarbil with 1 to approximately 30 carbon atoms; R2 is a hydrocarbil or substituted hydrocarbil with 2 to approximately 30 carbon atoms; R3 and R4 are free hydrogen, hydrocarbil or substituted hydrocarbils ranging from 1 to about 30 carbon atoms, or -(R6O)xR6, R6 in each group x(R6-O) is free C2-C4 alkylene, R6 is hydrogen, or linear or branched alkyl groups ranging from 1 to about 4 carbon atoms, and x is the average number ranging from 1 to about 50 (r). Diamines have the formula: (chemical formula) (33) where R1, R3, R4 and R5 are free hydrogen, hydrocarbil or substituted hydrocarbils ranging from 1 to about 30 carbon atoms, or -(R6O)xR7, R2 and R8 are free hydrocarbilene or substituted hydrocarbils ranging from 2 to about 30 carbon atoms, R6 in each group x(R6O) and y(R6O) are free C2-C4 alkylene, R7 is hydrogen, or linear or branched alkyl groups ranging from 1 to approximately 30 carbon atoms, x is the average number from 1 to approximately 30, X is -O-, -N(R6)-, -C(O)-, -C(O)O-, -OC(O)-, -N(R9)C(O)-, C(O)N(R9)-, -S-, -SO-, or -SO2-, y is 0 or the average number from 1 to approximately 30, n and z are independent, either 0 or 1, and R9 is the hydrogen or hydrocarbil or substituted hydrocarbil(s). An amine oxide with the formula: (chemical formula) (34) where R1, R2 and R3 are independent, which are hydrogen, hydrocarbil or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms, -(R4O)xR6, or, -R6(OR4)xOR5; R4 in each group x(R4O) The free R1 is C2-C4 alkylene, R5 is hydrogen or hydrocarbilene or hydrocarbilene substituted from 1 to about 30 carbon atoms, R6 is hydrocarbilene or hydrocarbilene substituted from 1 to about 6 carbon atoms, x is the average number from 1 to about 50 and the total number of carbon atoms in R1, R2 and R3 is at least 8. (t) Alkoxylated amine oxides with the formula: (chemical formula) (35) where R1 is hydrogen or hydrocarbilene substituted from 1 to about 30 carbon atoms, R2 in each group x(R2O) and y(R2O) are free C2-C4 alkylene, R3 is hydrocarbilene or hydrocarbilene substituted from 1 to about 6 carbon atoms, x is the average number from 1 to about 50 and the total number of carbon atoms in R1, R2 and R3 is at least 8. The substituted amines with the formula: (chemical formula) (36) where R1 is a substituted hydrogen or hydrocarbil or hydrocarbil with 1 to 30 carbon atoms, -R4SR6, or -(R2O)zR3, R2 in each group x(R2O), y(R2O) and z(R2O) are independent, i.e., hydrogen, hydrocarbil or hydrocarbil substitutes with 1 to 30 carbon atoms, -(R6)n-(R2O)yR7; R6 is a substituted hydrocarbil or hydrocarbil substitutes with 1 to 6 carbon atoms, R7 is a hydrogen or linear or branched alkyl group with 1 to 4 carbon atoms, n is 0 or 1, and x and y are independent, i.e., an average number of 1 to 60 (u) units. Dialxoxylated amines have the formula: (chemical formula) (36) where R1 is a substituted hydrogen or hydrocarbil or hydrocarbil substitutes with 1 to 30 carbon atoms, -R4SR6, or -(R2O)zR3, R2 in each group x(R2O), y(R2O) and z(R2O) are independent, i.e., hydrogen, ... C2-C4 alkyl groups, R3 is hydrogen, or a linear or branched alkyl group ranging from 1 to about 22 carbon atoms, R4 is a linear or branched alkyl group ranging from about 6 to about 30 carbon atoms, R5 is a linear or branched alkyl group ranging from about 4 to about 15 carbon atoms, and x, y and z are independent, being average numbers ranging from 1 to about 40. However, given that when R1 is an alkyl, either the sum of x and y is greater than 20 or R3 is in addition to hydrogen (v), the eminated and alkoxylated alcohols have the chemical structure: (chemical formula) (37) where R1, R7, R8 and R8 are each independent, being hydrogen, hydrocarbilized or hydrocarbilized. Substitutes include those with 1 to approximately 30 carbon atoms, or -(R11)s(R3O)vR10; X is -O-, -OC(O)-, -C(O)O-, -N(R12)C(O)-, -C(O)N(R12)-, -S-, -SO-, -SO2-, or -N(R9)-; R3 in each n(R3O) and v(R3O) group independently is C2-C4 alkylene, R10 is hydrogen, or a linear or branched alkyl group with 1 to approximately 30 carbon atoms; n is the average number from 1 to approximately 60; v is the average number from 1 to approximately 50; R2 and R11 independently are hydrocarbilene or trans hydrocarbilene groups with 1 to approximately 6 carbon atoms; R4 is a hydrocarbilene or hydrocarbilene group. Substituted carbils are those with 2 to approximately 6 carbon atoms; R12 is hydrogen or hydrocarbil or substituted hydrocarbils with 1 to approximately 30 carbon atoms; m and s are each independent, 0 or 1; R6 is hydrocarbil or substituted hydrocarbils with 2 to approximately 30 carbon atoms, -C(=NR12)-, -C(S)-, or -C(O)-; q is an integer from 0 to 5; and R6 is hydrogen or hydrocarbil or substituted hydrocarbils with 1 to approximately 30 carbon atoms. (w) Quaternary ammonium, sulfonium and sulfoxonium salts with chemical structures: (chemical formula) or (chemical formula) (40) or (chemical formula) (41) or (chemical formula) (42), where R1, R7, R8, R9, R10 and R11 are independent, hydrogen, hydrocarbil or substituted hydrocarbils. Substitutions range from 1 to approximately 30 carbon atoms, or -(R13)a(R3O)vR12; X is -O-, -OC(O)-, -C(O)O-, -N(R14)C(O)-, -C(O)N(R14)-, -C(O)O-, or -S-; R3 in each independent n(R3O) and v(R3O) group is C2-C4 alkylene, R12 is hydrogen, or a linear or branched alkyl group ranging from 1 to approximately 30 carbon atoms; n is the average number ranging from 1 to approximately 60; v is the average number ranging from 1 to approximately 50; R2 and R13 each independent are hydrocarbilene or substituted hydrocarbilene groups ranging from 1 to approximately 6 carbon atoms; m and s are each independent, i.e. 0 or 1; R4 is a hydrogen or hydrocarbil or a substituted hydrocarbil with 2 to about 6 carbon atoms; R6 is a hydrogen or hydrocarbil or a substituted hydrocarbil with 2 to about 30 carbon atoms, -C(=NR12)-, C(S)-, or -C(O)-; R14 is a hydrogen or hydrocarbil or a substituted hydrocarbil with 1 to about 30 carbon atoms, q is an integer from 0 to 5; R5 is a hydrogen or hydrocarbil or a substituted hydrocarbil with 1 to about 30 carbon atoms; and each A is the agricultural acceptable anion (x). Salts are amines or diammons with the formulas: (chemical formula) (43) or (chemical formula) (44), where R1, R4, R5, R6, R7 and R8 are independent, i.e. hydrogen or hydrocarbil or a substituted hydrocarbil with 2 to about 30 carbon atoms; and each A is the agricultural acceptable anion (x). The substituted alcohol has the formula: (chemical formula) (45), where R1 is a hydrocarbil or a substituted hydrocarbil with 1 to 30 carbon atoms, R2 in each group x(R2O) is independent C2-C4 alkylene, R3 is a hydrogen, or alkyl group. A linear or branched alkyl group ranging from 1 to approximately 4 carbon atoms, and x is the average number ranging from 1 to approximately 60, however, given that when R1 is an alkyl, either R3 is outside of hydrogen or x is at least 10; (z) a dialxoxylated alcohol with the formula: R1(OR2)xO------R3-----O-----(R2O)yR1 (46) where R1 is a hydrogen or a linear or branched alkyl group ranging from 1 to approximately 4 carbon atoms; R2 in each group x(R2O) and y(R2O) are independent C2-C4 alkyls; R3 is a hydrocarbilite or Substituted hydrocarbilenes with a range of 2 to approximately 30 carbon atoms, and x and y are independent, with an average number ranging from 1 to approximately 60 (aa) alkoxylated dialkylphenols with the formula: (chemical formula) (47) where R1 and R4 are hydrogen or linear or branched alkyl groups ranging from 1 to approximately 30 carbon atoms and at least one of R1 and R4 is an alkyl group, R2 in each group, x(R2O) is independent, i.e. C2-C4 alkyl; R3 is hydrogen, or a linear or branched alkyl group ranging from 1 to approximately 4 carbon atoms, and x is the average number ranging from 1 to approximately 60. (bb) Compounds with the formula (chemical formula) (48) or (chemical formula) (49) or (chemical formula) (50) or (chemical formula) (51) or (chemical formula) (52) or (chemical formula) (53) or (chemical formula) (54) or (chemical formula) (55), where R1, R9, and R12 are independent hydrocarbils or substituted hydrocarbils ranging from 1 to approximately 30 carbon atoms, or -(R2O)pR13;R2 in each group of m(R2O), n(R2O), p(R2O) and q(R1O) are independent C2-C4 alkyl groups, R3, R6, R11, R13, and R15 are independent hydrogen, or hydrocarbils or Substituted hydrocarbils with 1 to approximately 30 carbon atoms, R4 is -(CH2)yOR13 or -(CH2)yO(R2O)qR3; R5, R6, and R7 are free hydrogen, hydrocarbils, or substituted hydrocarbils with 1 to approximately 30 carbon atoms, or R4; R10 is a hydrocarbil or substituted hydrocarbil with 2 to approximately 30 carbon atoms; R14 is hydrogen, hydrocarbil, or substituted hydrocarbils. The number of freely replaced carbon atoms ranges from 1 to approximately 30, or -(CH2)zO(R2O)pR; m, n, p, and q are free, with the average number ranging from 1 to approximately 50; X is free, which is -O-, -N(R14)-, C(O)-, -C(O)O-, -OC(O)-, N(R15)C(O)-, -C(O)N(R15)-, -S-, -SO-, or -SO2-; t is 0 or 1; A is the agriculturally acceptable negative charge; And y and z are independent integers from 0 to approximately 30 (cc). N-acyl charcosinate has the formula: (chemical formula) where R is C8 to C22 N-acyl, commonly fatty acids with chain lengths C10 to C18 and X is the agriculturally acceptable anion (dd). Glycoside has the formula (chemical formula) n, where n is the degree of polymerization or the number of glucose groups and R is the straight or branched alkyl group, commonly ranging from 4 to 18 carbon atoms or a mixture of alkyl groups with an average value within that range; or (ee) glycosides with the formula: (chemical formula) where R1 is -CnH2nO(CH2CH2O)m(CH2CH(CH3)O)qX, n is 0 to 6, a is 0 to approximately 100, b is 0 to approximately 10, m is 0 to approximately 30, q is 0 to approximately 30, X is hydrogen or C1-20 hydrocarbil groups or C2-6 acyl groups, and R2, R3, R4, R5, R6, R7, R8, R9, R10 independent are groups with C1-20 hydrocarbil groups that are replaced or not replaced or nitrogen (ff) compounds with the formula: R1O(R2O)nX1 (47A) where R1 is a hydrocarbil group ranging from approximately 8 to approximately 22 carbon atoms, each independent n(R2O) group is C2-C4 alkyl group, n is a number ranging from 0 to approximately 60, and X1 is a carboxylate, sulfate, or phosphate (gg) phosphate diester with the formula; (chemical formula) where R1 and R3 are independent linear or branched alkyl, linear or branched alkynyl, linear or branched alkynyl, eryl, or eralkyl groups ranging from approximately 4 to approximately 30 carbon atoms; R2 in each group of m(R2O) and n(R2O) are independent C2-C4 alkylene; and m and n are independent ranging from 1 to approximately 30; and (hh) phosphate ester with the formula: (chemical formula) where R1 is a linear or branched alkyl, linear or branched alkynyl, linear or branched alkynyl, eryl, or eralkyl groups ranging from approximately 8 to approximately 30 carbon atoms; R2 in each group of m(R2O) is independent C2-C4 alkylene; and m and n are independent ranging from 1 to approximately 30; and m is from 1 to approximately 30 and (ii) selectable anionic surfactants from a group consisting of fatty soaps, alkyl sulfates, sulfated oils, sulfated ethers, sulfonates, sulfosuccinates, sulfonated amides and isethionates 124. A mixture of claims under Article 123 where the oxalic acid contains alkali metal salts, alkanolamine salts, alkylamine salts, tetraalkylammonium salts or aryl trialkylammonium salts of oxalic acid. 125. Solid pesticide and herbicide concentrates consist of: a water-soluble solid herbicide concentrate available in a biologically potent concentration when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture; and compounds that increase the permeability of the thin cell membranes within plants to enhance the cellular uptake of the pesticide mixture in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture without such compounds, but otherwise containing the same mixture as the enhanced application mixture, where the weight ratio of the pesticide to such compound is at least 2. 5:1 126. A mixture of claims under Article 125 that includes a surfactant component consisting of one or more surfactants under Article 127. A mixture of claims under Article 125 where such compound contains oxalic acid or its salts. 128. Aquatic herbicide mixtures contain: glyphosate salts or esters present in biologically effective concentrations when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; and compounds that increase the permeability of the thin membranes of cells within the plant to enhance the cellular uptake of the herbicide mixture in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture free of such compounds but otherwise containing the same mixture as the enhanced application mixture.129. A mixture of claims under Article 128 that includes a surfactant component consisting of one or more surfactants 130. A mixture of claims under Article 128 where such compound contains oxalic acid or its salts. 131. Solid pesticide mixtures consist of: a water-soluble pesticide present in a biologically effective concentration when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; and a compound that suppresses oxidative breakdown in plant cells, i.e., the compound that triggers the plant's defense response in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture devoid of such compounds but otherwise containing the same mixture as the enhanced application mixture, where the weight ratio of the pesticide to such compound is at least 2. 5:1 132. A mixture of claims under Article 131 that includes a surfactant component consisting of one or more surfactants under Article 133. A mixture of claims under Article 131 where such compound contains oxalic acid or its salts. 134. Solid herbicide mixtures consist of: glyphosate salts or esters present in biologically effective concentrations when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; and compounds that suppress oxidative breakdown in plant cells—compounds that trigger the plant's defense response in plants treated with such enhanced application mixtures compared to plants treated with a reference application mixture devoid of such compounds but otherwise containing the same mixture as the enhanced application mixture. 135. A mixture of claims under Article 134 that includes a surfactant component consisting of one or more of the 136 surfactants. A mixture of claims under Article 134 where such compound contains oxalic acid or its salts. 137. A concentrated solid pesticide mixture consisting of: a water-soluble pesticide present in a biologically effective concentration when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; and a compound that increases the expression of hydroxyaprotein-containing glycoproteins, thereby increasing the mobility of the pesticide to foleam in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture without such compounds, but otherwise containing the same mixture as the enhanced application mixture, where the weight ratio of the pesticide to such compound is at least 2. 5:1 138. A mixture of claims under Article 137 that includes a surfactant component consisting of one or more surfactants under Article 138. A mixture of claims under Article 137 where such compound contains oxalic acid or its salts. 140. Concentrated solid herbicide mixtures containing: glyphosate salts or esters present in biologically effective concentrations when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; and compounds that increase the expression of hydroxyapropyl glycoproteins, i.e., compounds that increase the mobility of the herbicide to foleam in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture devoid of such compounds but otherwise containing the same mixture as the enhanced application mixture.141. A mixture of claims under Article 140 that includes a surfactant component consisting of one or more surfactants. 142. A mixture of claims under Article 140 where such compound contains oxalic acid or its salts. 143. A concentrated solid pesticide mixture consisting of: a water-soluble pesticide present in a biologically effective concentration when the mixture is diluted in the appropriate volume of water and applied to the leaves of sensitive plants; and oxalic acid or its salts; where such glyphosate and such oxalic acid are present in a ratio of at least 2 by weight. 5:1 144. A mixture of claims under Article 143 that includes a surfactant component consisting of one or more surfactants under Article 145. A mixture of claims under Article 144 where the pesticides and surfactants are present in a weight ratio between approximately 2:1 and 30:1. 146. Concentrated mixtures of solid pesticides and herbicides containing glyphosate salts or esters present in biologically effective concentrations when the mixture is diluted in the appropriate volume of water and applied to the leaves of susceptible plants; and oxalic acid or its salts. 147. A mixture of claims under Article 146 that includes a surfactant component consisting of one or more surface-reducing agents. 148. Solid, concentrated pesticide mixtures contain water-soluble pesticides present in biologically effective concentrations when the mixture is diluted in the appropriate volume of water and applied to the leaves of susceptible plants; oxalic acid or its salts; and a surfactant component consisting of one or more cationic or nonionic surfactants. Solid-state pesticide-concentrated mixtures (SGMs) containing water-soluble pesticides in an aqueous medium; these pesticides are present in biologically effective concentrations when diluted in the appropriate volume of water to form an enhanced-use mixture and applied to sensitized plants; surfactant components in solution or suspension, emulsion or dispersion that are stable in water; such surfactant components consist of one or more cationic surfactants and one or more nonionic surfactants; and compounds that either enhance the permeability of the cell membranes within plants to increase the cellular uptake of the pesticide mixture in plants treated with the enhanced-use mixture compared to plants treated with a reference-use mixture without such compounds, but otherwise containing the same mixture as the enhanced-use mixture; suppress oxidative lysis in plant cells; interfere with the plant's defense response in plants treated with the enhanced-use mixture compared to plants treated with the reference-use mixture; or increase the expression of hydroxyproline-containing glycoproteins. This increases the mobility of pesticides and herbicides to folem in plants treated with the increased application mixture compared to plants treated with the reference application mixture, where the surfactant components and compounds are present in a weight ratio exceeding 20:1.150. A mixture of claims under Article 149, in which the pesticide and herbicide contains herbicide 151. A mixture of claims under Article 150 whereby the herbicide contains glyphosate or its salts or esters. 152. A mixture of claims under Article 151 where glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, isopropylamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 153. A mixture of claims under Article 152 where glyphosate is abundant in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or its trimethylsulfonium salts. 154. A mixture of claims under Article 153 where glyphosate is abundant in the form of its potassium salts, mono-ammonium, triammonium, or monoethanolamines. 155. A mixture of claims under Article 149 where the surfactant component and such compounds are present in a weight ratio exceeding 3:1. 157. A mixture of claims under Article 149 whereby a cationic surfactant is selected from a group comprising alkylamines, alkylkiamines, alkylpolyamines, mono- or chi-quaternary ammonium salts, monoalxoxylated amines, chialxoxylated amines, monoalxoxylated quaternary ammonium salts, dialxoxylated quaternary ammonium salts, etheramines, amine oxides, alkoxylated amine oxides, and fattyimitazoline; Nonionic surfactants were selected from a group consisting of alkoxylated alcohols, dialxoxylated alcohols, alkylphenols, alkylpolyglycosides, alkylphenols, alkoxylated glycols, alkoxylated mercaptans, glyceryl or polyglyceryl esters of natural fatty acids, alkoxylated glycol esters, alkoxylated fatty acids, alkoxylated alkanolamides, polyalxoxylated silicones, and N-alkylpyrolidone 157. A mixture of claims under Article 149 where such mixture has a cloud point of at least approximately 50 °C and a crystallization point of no more than approximately 0 °C. 158. A mixture of claims under Article 149 where such compound contains oxalic acid or its salts. 159. A mixture of claims 149 whereby the permeability of thin cell membranes is increased by calcium stenosis in the cell wall or apoplast, providing a calcium-dependent protective response.160 A mixture of claims under Article 151 where the glyphosate concentration exceeds 400 g. Glyphosate a. e. 161 per liter. A mixture of claims under Article 160 where the glyphosate concentration exceeds 500 g. Glyphosate a. e. 162 per liter. A mixture of claims under Article 161 where the glyphosate concentration exceeds 540 g. Glyphosate a. e. 163 per liter. A mixture of claims under Article 149 where oxidative breakdown is suppressed by direct inhibition of free radical-generating oxidases. 164. A mixture of claims under Article 149 where oxidative rupture is suppressed by blocking the process, providing a signal that directly triggers the activation of free radical-generating oxidases. 165. An aqueous herbicide mixture consisting of: glyphosate or its salts or esters, in solution in an aqueous medium at a concentration that is biologically effective when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of a wide range of sensitized plants; a surfactant component in solution or suspension, emulsion, or dispersion stable in such medium, consisting of one or more cationic surfactants and one or more nonionic surfactants; and oxalic acid or its salts, where the concentration of oxalic acid or its salts and the nature of such surfactants is such that the first difference is between: (i) the growth rate of plants treated with the first enhanced application mixture prepared by diluting the aqueous herbicide mixture with water, and (ii) the growth rate of plants treated with a first reference application mixture free of oxalic acid and any of the aforementioned salts, but otherwise containing the same mixture as the first enhanced application mixture. More than the second difference between: (iii) the growth rate of plants treated with the second type of enhanced use mixture and (iv) the growth rate of plants treated with the second type of reference use mixture free of oxalic acid and any such salts but otherwise containing the same mixture as the second type of enhanced use mixture, where the mixture of the second type of enhanced use mixture differs from the mixture of the first type of enhanced use mixture only with respect to the characteristics of the surfactant system contained in this, the second type of enhanced use mixture contains (POE2) cocoalkyl monomethylammonium chloride and POE(6) lauryl ether, where the weight ratio of glyphosate a. e. For surfactants in mixtures, the second type of increased usage is approximately 2. 5:1 166. An aqueous herbicide concentrate consisting of: (i) glyphosate or its salts or esters, in solution in an aqueous medium at a concentration that is biologically effective when the mixture is diluted in the appropriate volume of water to form an increased application mixture and applied to the leaves of susceptible plants; (ii) a surfactant component in solution or suspension, emulsion, or dispersion stable in such medium, consisting of one or more cationic surfactants and one or more nonionic surfactants; and (iii) oxalic acid or its salts; whereby the surfactant component is approximately composed of at least one selected surfactant. Obtained from groups consisting of (a) aminened and alkoxylated alcohols with formulas (5), (6), or (7); (b) hydroxylated amides with formula (7); (c) diamines with formulas (9), (24), or (33); (d) mono- or diquaternary ammonium salts with formulas (10), (11), (25), (26), or (31); (e) poly(hydroxyalkyl)amines with formulas (12) or (12A); (f) alkoxylated poly(hydroxyalkyl)amines with formula (15); (g) tri-poly(hydroxyalkyl)amines with formula (18); (h) quaternary poly(hydroxyalkyl)amine salts. (hydroxyalkyl) amines with formula (20); (i) triamines with formula (23); (j) secantary or tertiary amines with formula (27); (k) monoalxoxylated amines with formula (28); (l) dialxoxylated quaternary ammonium salts with formula (29); (m) monoalxoxylated quaternary ammonium salts with formula (30); (n) etheramines with formula (32); (o) amine oxides with formula (34); (p) alkoxylated amine oxides with formula (35); (q) dialxoxylated amines with formula (36); (r) quaternary ammonium, sulfonium or sulfoxonium salts with formulas (39), (40), (41) or (42); (s) diamine or diammonium salts with formulas (43) or (44); (t) compounds with formulas (48), (49), (50), (51), (52), (53), (54) or (55); (u) polyamines; and (v) fatty imidazoline; and where the nonionic surfactant component contains at least one surfactant. The selected surfactants were from a group consisting of: (a) alkoxylated alcohols with the formula (45); (b) dialxoxylated alcohols with the formula (46); (c) alkylphenols with the formula (47); (d) compounds with the formulas (48), (49), (50), (51), (52), (53), (54) or (55); (e) polyglycosides with the formula (62); (f) alkylphenols with the formula (g) alkoxylated glycols; (h) alkoxylated mercaptans; (l) glyceryl or polyglyceryl esters of natural fatty acids; (j) alkoxylated glycol esters; (k) alkoxylated fatty acids; (i) alkoxylated alkanolamides; (m) polyalcoxylated silicone; and (n) N-alkylpyrolidone 167. A concentrated solid pesticide mixture containing a water-soluble pesticide in a biologically effective concentration when diluted with an appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; a surfactant component consisting of one or more cationic surfactants and one or more nonionic surfactants; and compounds that either enhance the permeability of the plant's internal cell membranes to increase the cellular uptake of the pesticide mixture in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture without such compounds but in the presence of the same compounds as the enhanced application mixture; suppress oxidative lysis in plant cells, interrupt the plant's defense response in plants treated with the enhanced application mixture compared to plants treated with the reference application mixture; or increase the expression of hydroxyproline-rich glycoprotein, which enhances the mobility of the pesticide to the phloem in plants treated with the enhanced application mixture compared to plants treated with the reference application mixture. Where the ratio by weight of the pesticide to the said compound is at least 2. 5:1 168. A mixture of claims under Article 167 where such compound contains oxalic acid or its salts. 169. Concentrated solid herbicide mixtures consist of: glyphosate salts or their esters in biologically effective concentrations when the mixture is diluted in the appropriate volume of water to form an enhanced application mixture and applied to the leaves of sensitive plants; a surfactant component consisting of one or more cationic surfactants and one or more nonionic surfactants; and compounds that either increase the permeability of the plant's intracellular membranes to enhance the cellular uptake of the herbicide mixture in plants treated with the enhanced application mixture compared to plants treated with a reference application mixture without such compounds but in the presence of the same compounds as the enhanced application mixture; suppress oxidative lysis in plant cells, inhibit the plant's defense response in plants treated with the enhanced application mixture compared to plants treated with the reference application mixture; or increase the expression of hydroxyproline-rich glycoprotein, which enhances the mobility of the herbicide to the folem in plants treated with the enhanced application mixture compared to plants treated with the reference application mixture. Those treated with the aforementioned mixture (referenced as 170) A mixture of claims under Article 169 where such compound contains oxalic acid or its salts. 171. A mixture of the claims in Article 169 where the glyphosate and the surfactant are present in a weight ratio between approximately 2:1 and 30:1.