SU695522A3 - Insecticide composition - Google Patents
Insecticide compositionInfo
- Publication number
- SU695522A3 SU695522A3 SU741994403A SU1994403A SU695522A3 SU 695522 A3 SU695522 A3 SU 695522A3 SU 741994403 A SU741994403 A SU 741994403A SU 1994403 A SU1994403 A SU 1994403A SU 695522 A3 SU695522 A3 SU 695522A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- propyl
- insecticidal
- butyl
- compound
- insecticide composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 4
- 239000002917 insecticide Substances 0.000 title description 2
- 150000001875 compounds Chemical class 0.000 claims description 5
- 230000000749 insecticidal effect Effects 0.000 claims description 5
- 150000003222 pyridines Chemical class 0.000 claims 2
- 239000000654 additive Chemical class 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 1
- 150000003582 thiophosphoric acids Chemical class 0.000 claims 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241000258915 Leptinotarsa Species 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 241000256248 Spodoptera Species 0.000 description 1
- 241000256250 Spodoptera littoralis Species 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/58—Pyridine rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Biochemistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
(54) ИНСЕКТИЦИДНЫЙ СОСТАВ каны атомами С, простые эфира наприйе э дисэкеан i те рагидрофуран ; сл ные эфиры;этиловый эфир уксусной-ки Лоты йетоны ацетон,мётилэтилкетон, диэтидкетон, нитрилы; ацетонитрил и др. П р и м ер 1. Получение О-этил-Н-пропил-S- 2 ,б-дихлорпиридил-(3) .-метил1-дитиофосфата. 14 г 2,б-дихлоргтиколил-3-хлорид раствор ют в 150 мл ацетонитрила. В раствор ввод т по порци м 16,9 г калий-0-этил-8-Н-пропилдитиофосфата . Реакционную смесь перемешивают 16 ч Яри кейна йой температуре. После отгонки растворител в :вво д т простой эфир промывают его вод и сушат сульфатом натри , свободным от воды. - Послеупаривани простогоэфира получают соединение формулы CHj-gJcr s л 5СзН7(н} , к С1 с рефракцией Кд : 1,57 40. АналогичШМ стгосрбом можно и следующйе соединени :(54) INSECTICIDE COMPOSITION of the cana by C atoms, ethers, for example, e diskean i te rahydrofuran; solid esters; ethyl acetate; Lots of ions acetone, methyl ethyl ketone, diethy ketone, nitriles; acetonitrile and others. Example 1. Preparation of O-ethyl-N-propyl-S-2, b-dichloropyridyl- (3).-methyl 1-dithiophosphate. 14 g of 2, b-dichlorgicolyl-3-chloride is dissolved in 150 ml of acetonitrile. 16.9 g of potassium-0-ethyl-8-H-propyl dithiophosphate are introduced into the solution in portions. The reaction mixture is stirred for 16 hours. After distilling off the solvent, the simple ether is washed with water and dried over sodium sulfate, which is free of water. - After the simple evaporation of the ether, a compound of the formula CHj-gJcr s l 5СзН7 is obtained (n}, c1 with refraction cd: 1.57 40. Similarly, the following compound can be used with the same method:
СоединениеCompound
Смертность после 3 дней,%Mortality after 3 days,%
LeptinotarsaLeptinotarsa
Spodoptera Spodoptera
decemlineafca littoralis , Х1 ОП . CHi-S-P 5-СН-СНз 2о N 1,5530. Формы применени пртепаратов обычные. . . Инсектицидное кишечноедействие. Посаженные в гсршки картофельные растени в стадии 4-5 .листьев погружают в полученную из 10%-ного эмульгируемого концентрата 0, водную эмульсйю испытуемого соединени . После присыхани осадка на растени хсажают по 5 личинок Spodoptera littoralis или Leptinotarsa decemline.ata встадии .iSj, ; Обработанные растени покрывают йласт ическйм цилиндром,; заделанным сверху проволочной сетью, чтобы предотвратить уход личинок. . После 3 дней Уценивают смертность./ Результаты испытани- приведены в аблице. . . : .Т а б л и ц аdecemlineafca littoralis, X1 OP. CHi-S-P 5-CH-CH3 2 N 1.5530. The application forms of the products are conventional. . . Insecticidal enteric effects. Planted potato plants in stage 4-5 of the sheet are immersed in a water emulsion of the test compound obtained from a 10% emulsifiable concentrate 0. After the sediment has dried on the plants, 5 Spodoptera littoralis or Leptinotarsa decemline.ata larvae of .iSj,; Treated plants are covered with a cylinder and a cylinder; wire netted over the top to prevent larvae from leaving. . After 3 days Mortality is exaggerated. . . : .T a b l and c a
,/Л, / L
. C. К-СзН.З. C. K-SzN.Z
-.1 хГЛ -.1 xGL
::р-5-сн,-( -С1 H-CjH S у/ :: p-5-sn, - (-C1 H-CjH S y /
С1C1
гН50 г;:gN50 g ;:
VciVci
uao-CjH S uao-cjh s
ClCl
, flm-CjHyS Y-Hflm-CjHyS Y-H
ClCl
100100
100100
100100
100100
CJIsO S/CJIsO S /
P-S-CH,4 / CjHs-CH-S V -ffP-S-CH, 4 / CjHs-CH-S V -ff
ИзвестноеKnown
С2Н50 и/C2H50 and /
Р-0-СНгЧч /)R-0-SNGHH /)
Claims (2)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH175673A CH574713A5 (en) | 1973-02-07 | 1973-02-07 | s-Picolyl phosphoridithioates - useful as insecticides, acaricides and plant-growth regulators |
| CH1777473 | 1973-12-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU695522A3 true SU695522A3 (en) | 1979-10-30 |
Family
ID=25688571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU741994403A SU695522A3 (en) | 1973-02-07 | 1974-02-01 | Insecticide composition |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JPS49109542A (en) |
| CA (1) | CA1053238A (en) |
| DD (1) | DD110751A5 (en) |
| DE (1) | DE2405189A1 (en) |
| FR (1) | FR2221459B1 (en) |
| GB (1) | GB1456896A (en) |
| IL (1) | IL44085A (en) |
| NL (1) | NL7401207A (en) |
| SU (1) | SU695522A3 (en) |
-
1974
- 1974-01-23 CA CA190,790A patent/CA1053238A/en not_active Expired
- 1974-01-25 IL IL7444085A patent/IL44085A/en unknown
- 1974-01-29 NL NL7401207A patent/NL7401207A/xx not_active Application Discontinuation
- 1974-02-01 SU SU741994403A patent/SU695522A3/en active
- 1974-02-02 JP JP49014018A patent/JPS49109542A/ja active Pending
- 1974-02-04 DE DE19742405189 patent/DE2405189A1/en not_active Withdrawn
- 1974-02-06 FR FR7403928A patent/FR2221459B1/fr not_active Expired
- 1974-02-06 DD DD176420A patent/DD110751A5/xx unknown
- 1974-02-06 GB GB545074A patent/GB1456896A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| IL44085A0 (en) | 1974-05-16 |
| FR2221459B1 (en) | 1978-01-06 |
| JPS49109542A (en) | 1974-10-18 |
| DD110751A5 (en) | 1975-01-12 |
| GB1456896A (en) | 1976-12-01 |
| IL44085A (en) | 1976-11-30 |
| CA1053238A (en) | 1979-04-24 |
| FR2221459A1 (en) | 1974-10-11 |
| NL7401207A (en) | 1974-08-09 |
| DE2405189A1 (en) | 1974-08-08 |
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