SU638235A3 - Herbicide composition - Google Patents

Herbicide composition

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Publication number
SU638235A3
SU638235A3 SU772466802A SU2466802A SU638235A3 SU 638235 A3 SU638235 A3 SU 638235A3 SU 772466802 A SU772466802 A SU 772466802A SU 2466802 A SU2466802 A SU 2466802A SU 638235 A3 SU638235 A3 SU 638235A3
Authority
SU
USSR - Soviet Union
Prior art keywords
ethyl
sulfoxide
cyclopropylmethyl
herbicide composition
plants
Prior art date
Application number
SU772466802A
Other languages
Russian (ru)
Inventor
Ангас Макдональд Алан
Original Assignee
Стауффер Кемикал Компани (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Стауффер Кемикал Компани (Фирма) filed Critical Стауффер Кемикал Компани (Фирма)
Application granted granted Critical
Publication of SU638235A3 publication Critical patent/SU638235A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/20Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof
    • C07D295/21Radicals derived from sulfur analogues of carbonic acid

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)
  • Hydrogenated Pyridines (AREA)

Description

(54) ГЕДБИЦИДНЫЙ СОСТАВ(54) HEDBICID COMPOSITION

Таблица 1Table 1

Соединение, Compound,

Химическое название номерChemical name number

З-Циклопропилметил-К-этнл-К-бутил-тиокарбаматZ-Cyclopropylmethyl-K-ethnl-K-butyl-thiocarbamate

S-Циклoпpoпилмeтил-N-бyтил-N-циклопропилметилтиокарбаматS-Cyclopropylmethyl-N-butyl-N-cyclopropylmethylthiocarbamate

S-Циклoпpbr Илмeтил-N-гeкcaмeтилентлокарбаматS-cyclopropyl Ilmethyl-N-hexamethylthylene carbamate

З-Циклопропилметил-К-алилл-М-циклоиропилметплтнокарбаматZ-Cyclopropylmethyl-K-alill-M-cycloylpropyl metal carbamate

S-Цик.чoпpoпилмeтил-N-бeнзил-N-циклопропилметилтиокарбаматS-Cyc. Chopropylmethyl-N-benzyl-N-cyclopropylmethylthiocarbamate

З-Циклонропилметил-М-этил-Ы-аллилтиокарбаматZ-cyclonropylmethyl-M-ethyl-N-allylthiocarbamate

,nклoI poпилмeтил-N-этил-N-циклогексилтиокарбамат, ncloIpylmethyl-N-ethyl-N-cyclohexylthiocarbamate

S-Циклoпpoпилмeтил-N-этил-N-фeнилтиокарбаматS-cyclopropylmethyl-N-ethyl-N-phenylthiocarbamate

З-Циклопропилметил-К-этил-М-бензнлтиокарбаматZ-Cyclopropylmethyl-K-ethyl-M-benzylthiocarbamate

3-ЦиклorIpoпилмeтил-N-(l-мeтил-4-этилпентаметилен )тиокарбамат3-Cyclooropylmethyl-N- (l-methyl-4-ethylpentamethylene) thiocarbamate

3-Циклопропилметил-К,К-ди(циклоГ1ропилметил )тиокарбамат3-Cyclopropylmethyl-K, C-di (cycloG1propylmethyl) thiocarbamate

З-Циклопропилметил-М-гептаметилентиокарбаматZ-Cyclopropylmethyl-M-heptamethylentiocarbamate

Сульфоксид З-циклопропилметил-N, N-ди-изопропилтиокарбаматаSulfoxide Z-cyclopropylmethyl-N, N-di-isopropylthiocarbamate

Сульфоксид S-ЦиклопропилметилМ-этил-М-аллилтиокарбаматаS-CyclopropylmethylM-ethyl-M-allylthiocarbamate sulfoxide

Сульфоксид 3-циклопропилметилМ-этнл-К-никлопронилметилтиокарбаматаSulfoxide 3-cyclopropylmethylM-ethnl-K-niclopronylmethylthiocarbamate

Таблица 2table 2

ПродолжениеContinuation

Соединение, Compound,

Химическое название номерChemical name number

Сульфоксид S-цнклопролилметилN-эт fл-N-ЦиклoгeкcилтиO apбaматаSulfoxide S-cncloprolylmethylN-fl-N-CyclohexylthiO aptum

Сульфоксид 3-ЦИклопропилметилК-этил-М-фенилтиокарбматаSulfoxide 3-cyclopropylmethyl-ethyl-M-phenylthiocarbmate

Сульфоксид З-циклопропилметилМ-этил-К-бензилтиокарбаматаSulfoxide Z-cyclopropylmethylM-ethyl-K-benzylthiocarbamate

Сульфоксид З-циклопропилметилН-аллил-М-циклопропилметилтиокарбаматаSulfoxide Z-cyclopropylmethylN-allyl-M-cyclopropylmethylthiocarbamate

Сульфоксид S-ЦИклопропилметилN-гексаметилентиокарбаматаSulfoxide S-cyclopropylmethyl N-hexamethylenethiocarbamate

S-Циклoбyтилмeтил-N-этил-N-бyтилтиокарбаматS-Cyclobutythylmethyl-N-ethyl-N-butylthiocarbamate

З-Циклобутилметил-К-гексаметилентиокарбаматZ-Cyclobutylmethyl-K-hexamethyleniocarbamate

3-Циклoбyтилмeтил-N,N-дициклoпропилметилтиокарбамат3-Cyclobutythylmethyl-N, N-dicyclopropylmethylthiocarbamate

Сульфоксид К-циклобутилметйл-Ы, N-дициклопронилметилтиокарбаматаS-K-cyclobutylmethyl-S, N-dicyclopronylmethylthiocarbamate

З-Циклопентилметил-М-этил-К-бутилтиокарбаматZ-Cyclopentylmethyl-M-ethyl-K-butylthiocarbamate

S-mpem. Бутил-метил-М-этил-Ы-бутилтиокарбаматS-mpem. Butyl-methyl-M-ethyl-Y-butylthiocarbamate

S-mpem. Бутилметил-М-этил-К-циклогексилтиокарбаматS-mpem. Butylmethyl-M-ethyl-K-cyclohexylthiocarbamate

Сульфоксид S-mpem. Бутилметил-N-этил-К-в/ ор . бутилтиокарбаматаS-mpem sulfoxide. Butylmethyl-N-ethyl-K-in / op. butylthiocarbamate

Сульфоксид S-mpem. бутилметилМ ,1Ч-диаллилтиокарбаматаS-mpem sulfoxide. butylmethylM, 1CH-diallylthiocarbamate

Сульфоксид S-mpem. бутилметилN-гептаметилентиокарбаматаS-mpem sulfoxide. butylmethylN-heptamethylentiocarbamate

ПродолжениеContinuation

них надуксусной кислотой или лг-хлорпероксибензойной кислотой.they peracetic acid or lg-chloroperoxybenzoic acid.

В табл. 1 приведены отдельные соединени  общей формулы I. Из данных, приведенных в табл. 2, можно судить о гербицидных свойствах средства по изобретению.In tab. 1 shows the individual compounds of general formula I. From the data given in Table. 2, one can judge the herbicidal properties of the agent according to the invention.

Пример 1. Довсходовое применение.Example 1. Pre-emergence application.

Семена опытных растений (хлориса, щетинника , щирицы, капусты, щавел , ежовника и овсюга) высевали в подготов„тенную иочву и через 1 сут после этого обрабатывали препаратами действующих веществ в количестве 8,97 кг/га. После обработки сосуды , в которые были посажены семена опытных растений, помещали в теплицу и содержали их там в течение двух недель. После этого оценивали гербицидиый эффект - степень повреждени  обработанных растений в сравнении с контрольными - необработапными растени ми.The seeds of the experimental plants (chlorine, bristles, shchiritsa, cabbage, sorrel, Yezhovnik and oats) were sown in a prepared soil and after 1 day they were treated with active substance preparations in the amount of 8.97 kg / ha. After processing, the vessels in which the seeds of the experimental plants were planted were placed in a greenhouse and kept there for two weeks. After this, the herbicidal effect was evaluated - the degree of damage to the treated plants in comparison with the control - untreated plants.

0% -отсутствие повреждений.0% - no damage.

100%-полна  гибель растений.100% complete plant death.

Данные результатов опыта приведены в табл. 2.The results of the experiment are given in table. 2

Номера соединений соответствуют их номерам в табл. 1.The numbers of the compounds correspond to their numbers in table. one.

Пример 2. Послевсходовое применение.Example 2. Post-harvest application.

Опытные растени  (капусту, хлорис, щавель , ежовник, овсюг и фасоль), выращенные в услови х теплицы до определенного возраста (листь  бобовых растений почти полностью расправл ютс  и начинают образовыватьс  первые трехлистные листь ) обрабатывали препаратами действующих веществ в количестве 8,97 кг/га. Через 14 дней после обработки проводили оценку гербицидпого действи  и выражали ее в процентах аналогично примеру 1.Experimental plants (cabbage, chlorine, sorrel, leafberry, wild oats and beans) grown under greenhouse conditions to a certain age (the leaves of leguminous plants are almost completely flattened and the first three leaf leaves begin to form) were treated with preparations of active substances in an amount of 8.97 kg / ha 14 days after the treatment, the herbicidal effect was evaluated and expressed as a percentage as in Example 1.

Данные результатов опыта приведены в табл. 2.The results of the experiment are given in table. 2

В первом случае (довсходовое применение ) оценка дана средн   дл  семи видов растений, во втором (послевсходовое применение ) - средн   дл  щести видов растений .In the first case (pre-emergence application), the assessment was given to an average of seven species of plants, in the second (post-emergence application) it was estimated as an average for plant species.

Результаты опытов свидетельствуют о более высокой гербицидной активности соединений согласно изобретению по сравнению с известными аналогами, которые эффективны в дозе 22,4 кг/га.The results of the experiments indicate a higher herbicidal activity of the compounds according to the invention in comparison with the known analogues, which are effective at a dose of 22.4 kg / ha.

Claims (2)

1.Патент США jYg 3742005, кл. 260-455А, опублик. 1973 (прототип).1. US patent jYg 3742005, cl. 260-455А, published 1973 (prototype). 2.Патент Франции N° 2107342, кл. С 07С 155/00, опублик. 1972.2.Patent of France N ° 2107342, cl. From 07С 155/00, published 1972. Приоритет но признакам: 29.03.76 при R - трет, бутил, 28.04.76 при R - циклопропил, циклобутил , циклопентил.Priority but featured: 03/29/37 with R - t, butyl, 04/28/76 with R - cyclopropyl, cyclobutyl, cyclopentyl.
SU772466802A 1976-03-29 1977-03-29 Herbicide composition SU638235A3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US67121976A 1976-03-29 1976-03-29
US67122676A 1976-03-29 1976-03-29
US68110576A 1976-04-28 1976-04-28

Publications (1)

Publication Number Publication Date
SU638235A3 true SU638235A3 (en) 1978-12-15

Family

ID=27418223

Family Applications (1)

Application Number Title Priority Date Filing Date
SU772466802A SU638235A3 (en) 1976-03-29 1977-03-29 Herbicide composition

Country Status (21)

Country Link
JP (1) JPS52118425A (en)
AR (1) AR219067A1 (en)
AU (1) AU502225B2 (en)
BR (1) BR7701644A (en)
CA (1) CA1082721A (en)
CH (1) CH629652A5 (en)
CS (1) CS209881B2 (en)
DD (1) DD129610A5 (en)
DE (1) DE2712760A1 (en)
DK (1) DK137777A (en)
EG (1) EG12513A (en)
ES (1) ES457286A1 (en)
FR (1) FR2346328A1 (en)
GB (1) GB1537991A (en)
IL (1) IL51750A (en)
NL (1) NL7703325A (en)
NZ (1) NZ183691A (en)
PH (1) PH14094A (en)
PL (1) PL104608B1 (en)
RO (1) RO73259A (en)
SU (1) SU638235A3 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8007849B2 (en) * 2005-12-14 2011-08-30 International Flavors & Fragrances Inc. Unsaturated cyclic and acyclic carbamates exhibiting taste and flavor enhancement effect in flavor compositions

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3804873A (en) * 1971-03-18 1974-04-16 Gulf Research Development Co Process for manufacturing a liquid thiocarbamate
IT972188B (en) * 1972-10-09 1974-05-20 Montedison Spa CARBAMOIL SULPHOXIDE COMPOUNDS
FR2196120A1 (en) * 1972-08-14 1974-03-15 Stauffer Chemical Co Sulphonyl and sulphinyl thiocarbamates - useful as pre or post emergence herbicides, prepd by oxidn of corresp thiocarbamates
PH10781A (en) * 1973-03-29 1977-09-06 Stauffer Chemical Co Process of manufacturing sulphoxides

Also Published As

Publication number Publication date
DE2712760A1 (en) 1977-10-20
ES457286A1 (en) 1978-06-16
DD129610A5 (en) 1978-02-01
PL104608B1 (en) 1979-08-31
AU2285677A (en) 1978-09-07
JPS52118425A (en) 1977-10-04
PH14094A (en) 1981-02-10
GB1537991A (en) 1979-01-10
RO73259A (en) 1981-06-26
FR2346328A1 (en) 1977-10-28
DK137777A (en) 1977-09-30
IL51750A0 (en) 1977-05-31
IL51750A (en) 1982-01-31
PL197001A1 (en) 1978-01-02
NL7703325A (en) 1977-10-03
BR7701644A (en) 1978-01-03
AR219067A1 (en) 1980-07-31
NZ183691A (en) 1979-03-16
CS209881B2 (en) 1981-12-31
CH629652A5 (en) 1982-05-14
AU502225B2 (en) 1979-07-19
EG12513A (en) 1979-06-30
CA1082721A (en) 1980-07-29

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